SCIENTIFIC ABSTRACT MILYUTINA, M. I. - MIMICA, M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001134330004-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: July 31, 2000
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

MOKSUSHIN, B.G,;.!.ILYUTINA# X.I*
11xperimenta.1 study of laminary systems. X1. The spontaneous formation
of unimicellar layers of colloidal ferric hydroxide on the surface of col-
loidal solutions. Kollold. Zhur. 15, 212-15 153. (KLRA 6:5)
(CA 47 U0.18:9105 #53)
1. Ural Polytech. Inst.. Sverdlovsk.

UTtN-hk

r
1 N 1) 7-(
m
enev, V., Milyutina, "'I.v Sharova, A. K. and Shtin,A.P.
TITILE: Preparation of an Acid Sulphate of Trivalent Titanium.
(0 poluchenii kisloy sernokisloy soli trekhvalentnogo titana).
PERIODICAL: "Zhurnal NeoreanicheskU Khimii" (Journal of Inorganic Chemisti
To=II, No.2, pp.465-467 (U.S.S.R.) /YS'7.
The formation of a violet-coloured crystalline precipitate
in quantities strongly dependent on sulphuric-acid
concentration was observed when working with reduced acid
oolutions of titanium. To determine the composition of the
precipitate and elucidate the conditions leading to its
formation was the object of the work described. The solutions
used contained either 15.25, 25.0 or 37.5 g/litre of TiO
initially, and the final contents of this and of sulphuric
acid were determined. The results are tabulated and indicate
that with 700 - 100 g/litre of H 0 precipitation occurs to
90-97%. Analysis of the salt peeptred with careful
exclusion of oxidation gave the composition Ti (SO )'H2SO4.8H2C
It is a crystalline powder soluble in water, dilutt
sulphuric and hydrochloric and concentrated sulphuric acids.
It is recommended as a source of trivalent titanium for
analytical work. There are three references, one of which
is Russian. 1 Table.
Received April 26, 1956.
Card 2/2

I-qLYUTMA, M.I.; SHTIN, A.P.; SHAROVA, A.K.
Studying the interaction of trivalent titanium oulfate with
sulfuric acid. Titan i ego spiavy no-5:301-396 161. (MIRA 15:2)
(TitanivAo4btallurgy)

s/828/62/000/000/010/017
E039/E42O
AUTHORS: Sharova, A.K., Demenev, N.V., Polyakova
I V.M.'
Milyutina, M.1.
TITLE: The physico-chemical basis of methods of separating
titanium and the earth acids
SOURCE: Razdeleniye blizkikh po svoystvam redkikh metallov.
Mezhvuz. konfer. pd metodam razdel. blizkikh po svoyst.
red. metallov. Moscow, Metallurgizdat, 1962, 116-123
TEXT: This work was undertaken because the properties of the
fluoride complexes of Ti and Nb and their solubilities in various
mineral acids are of importance in the development of separation
processes. It is shown that the optimum.conditions for the
separation of Ti and Nb from H2SO4 sol-ution are: 106/' H2SO4,
1% HF and 100A KC1. From a study of the interaction of potasiium
salts with Te and Nb in H2SO4 a method is developed for separating
,these elements from medium and strong acid solutions. This
separation depends on the principal valency change in Ti. When
a potassium salt is introduced in H2SO4 solution containing Ti
(180 to 250 g/litre H2S04) the double sulphate of Ti and K is
Card 1/2

S/828/62/000/000/010/017
The physico-chemical basis ... E039/E420
precipitated. When Ti and Nb are present in solution both metals
are precipitated in the form of isomorphous compounds. However,
if Ti is present in the trivalent form, it is not precipitated and
the Nb is separated from it in the precipitate in the form:
"12SO4(NbO)2(SOII)3-4H20, Data are:-obt.ained on the solubilities of
Nb and Ti in the Ti02-SO3-1-120 system over a wide range of f12SO4
concentrations (180 to 1000 g/litre) and the conditions for their
separation found. The separation of Nb and Ti is attained by the
successive fractional precipitation of Ti in the form
Ti2(SO4)3-H S04-8HOO and then the niobium sulphate complex
(N'14)kN'b6O3M4)l23-*21HqO with an acidity of 800 to
900 g/litre HPSOIj. Th~ product of this process contains 98.26 to
98.80' Nb205
/0 and 0.3 to 0.5% TiOp. As a result of this
investigation the above methods are recommended for the separation
of Nb and Ti. There are 2 figures and 2 tables.
Card 2/2

ACCESSION NR: APS009949 UR/0078/65/010/004/0883/0888
AVrHOR: Milyutina, H. L; Sharova, A. K.; Titova, Z. M.
7-
4
khiti T
a~ y z 4N
r
::'TbftC TAG8 o 'comp
nrgan c-aynthe's ~8: jaraen a -ound, cheiical
,reaction, precipitation, thermal analysis
,ABSTRALT: The precipitation of niobium arsenate from sulfuric acid solutions was
studied. Niobium arsenate was precipitated with sodium arsenate. The amount of
'niobiu-m arsenate, pr~,cipitate, its composition and properties were also studied.
:The data on the precipitat--on of niobium with sodium arsenate are shown in fig. 1
iof the Enclosure. It is found that the optimum conditions for the precipitation of
inioblum arsenate are:150-300 g/t of sulfuric acid; about 4% of Na2HAsO4*7H2O BOIU-
!.tion; As2O5:Nb2O5c (10-20):l; aging of precipitate for 20 hrs. Niobium arsenates
are formed by reaction of sodium arsenate with niobium in sulfluric acid as follows-
+-NazHM0,, (Nb()2)SIIM04* + Na2S04
Card 1/3

L 52373-65
~17JACCZSSIOX NR.- AP5009949
Thermal and cbe'acial''inilys-is :of thai arsenates andAntermediate-dehydration prvuuv.
!showed the following'compounds: 2A205-M2050H20t 2Nb2Os'As2OS*H70 and 2NbZO5-
AS205. The existence of a large number of x-ray diffraction lines indicates the
',crystal-line nature of.2Nb2OS*A.8205 or M604AS207. The remaining niobium arsenate
,hydrates are amorphous, Orig. art. has: 6 figures and 2 tables.
)ASSOCIATION: none
41SUBMITTED: 27Nov63 ENCLi 01 SUB CODE: IC &e_
INO REF SM 009 OTHER: 002
Car4 2/3

a
1 14
jilih-
Mrii 3/3

XCESSION NE: AT4042097 S/2768/63/000/007/0079/0083
WTHOR; Sharova, A.K.; bUlyutina, TVLL
ITLE: Separation of nioblum and titanium (M) in sulhiric'.acid solutions.
MMCE: AN SSSR. Urallekiy filial. Institut khfmii. Trudy*, no. 7, 1963.' Khimiya i
ekhnologiya redkikh metallov (Chemistry and technology of rare metals), 79-83,
70PIC TAGS: niobium, titanium, nfobium purification, titanium purification, electrolytic
-eduction, titanium reduction
LDStRACT: The authors investigated the possibility of separating titanium (M) from qiobium
V) in strong sulfuric acid solutions on the basis of the increase In formation of an Insoluble
itanium.(P compound with increasing concentration of the acid. A curve showinz the yield
f precipitate versus acid concentration Is shown In the Enclosure. Analysis of thp-precipitato
Jentified it as T12(S04)3'112SO4' 81120. Solutions of 600 - 900 g/L H2504 containing T102
nd Nb 0 In proportions of 6:1, 4;1, 2:1, and 1:1 were then used In experiments In which
2 6
he TiO -was precipitated In the above form by electrolytic reduction, while the nioblum re-
aained in the solution. The process is Illustrated by diagrams. OrIg. art. has: 6 figures
'and 1 table.
Card 1/3
7

-AC
CESSION NR: AT4042097
ASSOCIATION: Institut khImil, Urallskiy filial AN SSSR (Chemical Irwtitute, Ural. Brano
AN SSSR) h/
SMb=TED-. 00 EXCL; 01
SUB CODE: IC NO REF BOV-. 0u7 OTHF.Ii- 000
A
2/3.

ACCESSION NR: AT4042097
as
8
ENCLOSURE: 011
f60 700 YOU R, 5 04 t r1A
Fig. 1. Decrease in the content of trivalent TI In EDlution (in g/L) in relation to sulfuric
acid concentration (g/L). The T102"cont6nt In the original solutions was 18. 5 (1). and
39 (2) g/L.
Ca-~d 3/3

ACCESSION NR: AT4042098
S/2768/63/000/007/0085/0069
AUTHOR: Milyutina, M. I., Sharova, A. K.
;.TITLE: Fractional precipitation of titanium and nioblum sulfates from solutions of sulfuric
;::acid
SOURCE:. AN SSSR. Ural Iskly filial. Instttut khimfi. *Trudy*, no. 7, 1963. Kh1miya i
tokhaologiy'a redkikh metallov (Chemistry and.technology'of rare metals), 85-8'9
TOPIC TAGS: titanium, niobium, tantalum, titanium purification, niobium purifidation,
fractional preci Itation, metal sulfate fractionation 1
P
ABSTRACT: 'A solution containing 245 g/L H-2SO 48 g/L 710 10.25 g/L Nb 0 and
21 2d
3. 52 g/L Fe,C~ was used in a study of the succe6iKve precipitation of titanium ;n Wiobium
in the form ot their low-valence sulfates. - Titanium reduced electrolytically to Ti+3, was
precipitated (as Ti '11 SO * 8H 0) by adding sulfuric acid to the solution to. a
2(804)3 2 4 :2
concentration of 800-900 g/L. The'Nb+3. and Nb+6 remaining In the solution was then
precipitated In the form of ammonium gultate-nJoblate, (N I(Nb 21H
H4)6 603) (804)121" 20!
7_7

ACCESSION NR-. AT4042098:
by adding ammonium sulfate th the solution to a conidbntration of 7. 5%. 98-99% pure it
Nb20 with less than 0. 5% T102 was then obtained from the precipitate in yields ol up to
71. 5? by oxidation, conversiqp into hydrates, dryin and calcining. 'Tantalum is not
9
precipitated by the procedure.` "The analyses'Were 6arried out by Lhb. Asst. G. V. :i
Milovldova.11 Orig. art. has: 4 tables.
ASSOCIATION: Institute khimUt Urallskiy filial AN SSM (Chemical Institute, Urals
Branch of the AN SSGR)
SUBNWITED: 00 ENCL: 00
am CODS: Ico IM NO REF SOV's 007 OTHER: 001
f
2/2.
Card

N1 L y U TI~MA, N, 4,
137-58-5-9317
Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 5, p 75 (USSR)
AUTHORS: Tarabayev, S. 1. , Budon, V. D. , Matveyeva, K. T. ,
Milyutina, N. A.
TITLE: Dir~ectLe`acin~g6f Lead From Sulfide Concentrates (Neposred-
stvennoye vyshchelachivaniye svintsa iz sul'fidnykh kontsentra-
tov)
PERIODICAL: Izv. AN KazSSR. Ser. gorn. dela, metallurgii, str-va i
stroymaterialov, 1957, Nr 4 (15), pp 59-65
ABSTRACT: The process of direct and selective leaching of lead from
sulfidic polymetallic concentrates by means of acidic chloride
solutions was studied under laboratory conditions as well as on
a larger laboratory scale. Optimal leaching conditions for ex-
traction of up to 97-98% of Pb are shown. Along with Pb, Cd
(96% of it) and Ag also pass into the solution. Cu, Au, and Bi
remain entirely in the cakes. The behavior of Zn depends on
the nature of the initial raw material and on the conditions of
leaching.
Card 1/1 1., Lead--Production 2. Lead ores--Processing G.S.
3. Chloride solutions--Applications

SOV/ 137-58-9- 18793
Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 9, p 91 (USSR)
AUTHORS: Tarabayev, S.I., MilyutinaA,_A., Budon, V.D., Dostanova,
Z. Kh. e__ ~.-
TITLE- Precipitation of Lead From Chloride Solutions. Communica-
tion II. (Osazhdeniye svintsa iz khloridnykh rastvorov.
Soobshcheniye II)
PERIODICAL: Izv. AN KazSSR. Ser. gorn. dela, metallurgii, str-va i
stroymaterialov, 1957, Nr 5 (16), pp 30-36
ABSTRACT: An examination is made of methods of precipitating Pb from
chloride solutions. Experiments were run on the crystalliza-
tion of PbCl? by chloride solutions during the cooling of solu-
tions resulting from the leaching of Dzhezkazgan concentrates.
The resultant PbCIZ was smelted with mineral coal and CaC03
at 800-9000C to free the metal. Extraction of Pb in ingot form
came to 93.5Z56. It is established that the method of crystalliz-
ing PbCIZ with subsequent smelting of the metal from the PbC12
in the presence of C and CaC03 makes it possible to obtain
metal of adequate purity without prior cleaning of the solutions.
Card 1/2 The tendency of the solutions to become "exhausted" after Pb

SOV/137-58-9-18793
Precipitation of Lead From Chloride Solutions. Communication II.
precipitation when they are used as return solvents is verified. For Com-
munication I, see RZhMet, 1958, Nr 5, 9317.
N. P.
1. Lead chlorides--P-rocessing 2. Lead--Separation
Card 2/2

P=TRIAO N. A.: VAGter Tech Sol (dise) -- "The problem of hydrolysis of the
- --
chlorides o?'t-eavy nonferrous metals". Alma-Ata, 1958. 12 pp (Acad Sol Kazakh
SSR, Inst of MetallurSy and Ore Dressing), 150 copies (HL, No 4, 1959, 127)

TARABAIEV, B.I.; MILYUTINA, N.A.
Settling filtration, and vashing of sinter cake following
the leachng of concentrates In chloride solutions, IzvAN
Z&zakh..WR.Ser.met.,obog.i ogneup. ho.2t26-31 058.
(Hydrometallurgy) (M3FA 16s2)

MILTUTINA.-K.L.; TARABiTSVp S.I.
Hydrolysis of heavy nonferrous metal chlorides. IsY.AN Jazakh.
SSR.Ser.zet., obogA ogneup. no.2t56-64 158. (KER4 l6s2)
(Nonferrous xetalv~ ~ tallurgy) -(Hydrolysis)

MILMIZAe ISAKOFAs R.A,; TARABAYV, Sol&
~thod of determining the vat*r of orystallIzAtIoni In Matal
bydratee iy the use of r~dloactlvo isotopes. Ust. Al Muakh.
SSR 14 200'38" w too (MM 11LOO
(Crystallization, Water of) (11adloactive tracers)
(Rrdrates-Auslysla)

X 1 1,
o a
*44
-qav
4.1
4i
o -oil
-
14
-a I-o-.134,
all-
.14 1 11 1 t .
RAW
Ut
1 :5 :'.

MILYUTIRL.
Observations on Ter*do navalim during its setting and the initial
period of boring Into wood LwIth sumary In Angliahj. Zo#l. zhur.
.18 n*.4-.520-536 Ap 159. (KIRA 12:5)
l.ChaIr of Invertebrate Zoologyg biological-ftWegical Faculty,
Noscow State University.
(Shipworm)

s/ir/6,V000/002/035/144
AOO6/A1Ol
AUTHORS: Polyvyanskiy, I. R., Milyutina., N. A.
TITLE- Tellurium concentration and extraction of silver and lead from
cupel dusts
PERIODICAL: Referativnyy zhurnal, Metallurgiya, no. 2, 1962, 25, abstract 2092
("Izv. AN KazSSR, Ser. metallurgii, obogashcheniya i ogneuporov",
1961, no. 2, 10-17, Kaz. summary)
TEXIP: Results are given on laboratory experiments on the melting of
cupellation dusts with Na2 and Cin graphite crucibles and an electric furnace.
S04 0
Optimum conditions are: 1,000 C; holding time - 20 min; Na2S04 amount - 15 to
20% of the dust weight; carbon 4 - 5%. The degree of extraction (in %) is:
into the alloy - Pb 98.5, Ag 99.5; into the thiosalt melt - Te 98; Zn 94;
Se 90.
A. Tseydler
[Abstracter's note: Complete translationi
Card 1/1

TSEFT, A.L,; 14ILYUTIXL,_!I!,.j VABILIYEVA, V.A-
- 1.
Leaching of mixed Dshezkazgan ores by chloride'solutions.
AN Kaxakh.SSR.Ser.mwt... obogei ogneupe noo2:64-72 1619
Oshezkanan-Copper ores) (LeachIM)
1xv.
(KIRA 14:8)

TSEFT, A.L,; VASILihVA, V.A.; 14ILYUTINA, N.A.
Leaching of mixed Dzhezkazgan ores by solutions of sulfuric acid
containing salts of trivalent iron, Re#ort w o2. Izv.AN Kazakh.
SSR.Ser.metep obog,i ogneup. no.2:73-84 11. (MERA 14:8)
(Daboakazgan-Copper ores) (Leaching
g

s/B17/62/bo5/ooo/oo3/612.
Aoo6/Aloi
AUTHORS: PolyvyanW, I. R., Milyutina, N. A.
TITLE: Joint.-pr6cessing of tellurium-containing products of the lead
industry..
SOURCE: Akademiyaknauk Kazakhskoy SSR. -Institut metallurgii i obogashche-
niya. Trudy. v. 5, 1962, Tsvet.naya metallurglya, 57 - 68 C
FG: Melting with sodium sulfate, and reduction melting with soda slags
Q3odium antimonate melt slags) were the two methods used in the joint processing
of tellurium-containing products for the purpose of extracting lead-, precious
metals and antimony Into the crude lead, and tellurium into the matte-slag melt,
with subsequent hydrometallurgical processing -of t~he latter. The obJect of -the
exp~priments was: determining the effect of temperature and duration of melting
upon tellurium concentration in the matte-slag melt, and upon the yield of lead,
silver and antimony into the crude metal; determining the tellurium concentra-
tion in the melt and the extraction of lead, silver and antimony into the crude
metal, depending upon the charge.composition, and analyzing tha joint melting of
Card 1/2

s-./8i7/62/005/000/003/012
Joint processing of... Aoo6/Alol
cupellation dust, antimonous slag and reguline lead. It was found that the most
efficient method for the joint'~processing of the aboye-mentioned materials was
reduction melting to sodium slag. The optimum conditions are: 1,0500C; time
of holding the melt at this temperature: 20 min; optimum composition of the
charge: 60% hntimonate melt slag, 50% reguline lead.and 5% carbon (of the
dustweight). The products oimelting cuppelation dust with antimonate slag are
analyzed and show that tellurium.can be fully extracted in-to the sodium slag
melt, and lead, silver and antimonylinto the crude metal. The.melting process
-yields two products: 1) crude,lead in which are concentrated 97.4 - 90 lead,
95.5 - 100% silver and 97.6 - 98.9% antimony; 2) alkaline melt: tellurium
extraction is 99-3 - 99-9%, the matte-slag mplt,contains up to 1.34% tellurium.
An amount of 0.05 to 0.001% tellurium remains in the.~crude lead. There are 3
'figures and 8 tables.
Card 2/2

N . A .
POLYVYANWrf p I.Re;
Hydrometallurgical. processing of fused sodium matte from sodium
sulfate smelting of cupellation dusts. Trudy Inst-,-met. i olvvg.
AN Kazakh. SSR 6&64,71 163.
Treatment of alkali.malts obtained in the smelting of tellurium-
bearing materials. Trudy Inst. met. i obog. AN Kazakh. SSR
6:72-76 163* (MIRA 16slo)

'lil,NlV('- F., . F,
:,, 1. ,
7
the aqueous cl' t.-ungsten-TrIoll vaenum coniain=u
.4-:n oodlum matte. Tiudy Inot. in~:f.. I c;bog. I kh. SSR 22:154-
nic, I t
1~,O 165. (mi-a 18:10)
go

I
A , ,. - - '71NA, IN. I . , `7',W EV, L. N.
DO LY IVrYf,!--tNYY D. ,"IU".
Sevarating tungsten apd riolybdontim in alkali Bulfids- oclutiors,
Trudy Inst. met. :1. cbr,,g,. t,'. Kazakb. SSR 12:161-167 16-5.
(MIRA 18!10)

''I
)MUTIN"T. ~ -
wAn"
- I Solvent for zinc sulfate. Khim.volok no.6:68 163.
, ... I ~,
- 1. Krasnoyarskiy zavod.
(MIRA 17t1)

VOLMVA#.,Te.A.; KILYUTIHA, N.P.
Investigating t~e graduated circle of gonlowters. Trudy MIK
no.3.6s42-0 151. (MIRA 11SQ
(Goniometers)

DRUMB , A. Ye.~,_ N. V.
Removal of hydrogen sulfide of iron hydoxide suspensions from
shale gas. Trudy V14IIT no. 11:269-276 162. (MIRA 17:5)
!- - I..

ANNUPARINS. O.G.; ZUBOVA, Z.F.; GMIYENKO, U.M.; MILYTJTIUA. R.I.
Obtaining immune serums against epidemic encephalitis. Vop.virus.
2 no.4:248-251 Jl-Ag 157. (MIRA 10:12)
(BUGNPULITIS. EPIDEMIC. immunology
Russian-tick borne, prod. of i=Le sera (Rue))

1. ODIN"PSOV, P. 14. : MII,YU'1'1,'JA, 6. V.
2. U~~R (660)
4. Wood - Chemistry
7. Swelling of cellular walls of spi-uce wood in sulfuric acid and in acid Sol tio!Is of
glucose. Larv. PSH Zin. Akad. Vestis no. 9. 1950
9. Monthly List of Russian Accessions, Library of Congress, March 1953. Unclassifled.

- V -1. - -. .- :~- - " . , ". : - - - --- " .. --- ~ - ~ - : 1. - .
- --~ f-lff, - - : -, -- -- . - ~ -~ - - . . - - .
M. T-1 "' T - '* , R - - U.
.1
of fir-wwd ..,t a.;

0 45. In
7
~gin led 122
milady at big er Acid conerm, whHe the cellulose
wedably only In the add above the 55% conen.
I the bulk wood depended primanly on the
of the interctilular sabstance. The secondary
in the direction toward the center of the cells.
A

L Y V,
USSR / Cultivat-od Plants. liz~dicinal Flcz,,Lts. Lssonti--il
Oil 21~,;atci T-IoXic Plants.
llbsJour : iRcf Zauj~ - 3-Jol. , '~-`o 34853
Authors : Kalnin'sn, A. I.; RupooTs, Z. li.; I-Iilyutcina, 3. V.
Tnst : l,tv33R
T it 1 o : ':)-tudr of tho ~icc,,roi,3 Lo~if of thz) NcedlErs of
Figbly ResinifoTous Pines
Ori- Pub z Izv. AN Latv3SR, 1957, 13, 79-87
r
Abstract : 3y ajjatc~-
a ,ic,,l co-marison i:oc,'U'liods, it lvros found
t'-l,,vt rosin productivity of tno comiaon pine in-
crc~,sos vr"th th~a amount -,nd sizo of tlno contrzl
L
and poriphoral m3in ductz in thc cx~-roaG
-- SuIchov.
Card 1/1

MMGBYBVA, Y.N.; MILYUTINA. S.V.
Mweerweel- morphologypLnd proportion of the cell valls of
heleaelluloii'Md cellulose fibers of sprace-brought sibout by
thervAl processing. Gidroliz. i lesokhim. prom. 4-no.30-5 158.
(Nipi 11:5)
1, Institut lesokhosyaystvennykh problem AN retviyokoy SSR.
(Spruce) (Holocellulose) (Cellulose)
A

23962
S/103/61/022/007/008/008
6 0 D252/D302
AUTHORS: Lyub*nslciy, I.A., Milyutina, V.A. and Pozin, N.V.
(Moscow)
TITLE: Pulse-frequency telemetering transmitter
PERIODICAL: Avtomatika i telemekhanika, v. 22, no. 7, 1961,
934-938
TEXT: The pulse-frequency telemetering device ChTI-1 is designed
for measuring small d.c. voltages. It produces rectangular pulses
of duty ratio 2, which are proportional to the measured voltage.
Noiseproof telemetering channels require a narrowing of the frequen-
cy range; hence the frequency range of the pulse produced by the
device was chosen from 5 to 15 cycles. The device uses transistors.
Fig. 1. shows a block-diagram of the device: low-frequency filter 1,
d.c. amplifier 2 which contains a modulator-converter of d.c. into
a.c., an a.c. amplifier and a rectifier, pulse-generator 3, and unit
4 for retransforming frequency into voltage. The transmission fac-
tor for the closed system is approximately I/P for large values of
C ard 1/~

23962
S/103
/61/022/007/008/008
"Wlse-frequency telemetering... D252/D302
k13 (k being the transmission factor of the direct channel, and
of the feedback channel). The placing of the filter in the direct
channel permits (due to the absence of lag elements in the feedback
channel) considerably simplifying the amplifier circuit by excluding
the phase-sensitive stage. For comparison, the expressions for the
transfer function are given: a) filter in direct channel
kl(p) - Icl(p)k2k3 I = k21C3 I
I + kj.(p)kqk3P aP2 + bp + c + kT___A
b) filter in feedback channel
k"(p) - k2k3 = k2k3 k2k3
1 + kl(p)k2kp (I ap + bp + c + k2k313
here kj(p) a 1 - is the transfer function of the RC-fil-
ap2+ bp + c
ter, k2 - the amplification factor of the amplifier, k3 - the volt-
age-into-frequency transformation factor. The transient functions
for a) and b) are respectively
Card 2/5

S/103 23962
,/61/022/007/008/008
Pulse-frequency telemetering... D252/D302
h1(t) k2k3 2le-P2t_ P2e-Plt
c + k2k3P (l P1 - P2 ) 9
hil(t) k2k3 c + Ple-p2t P2e_plt
c + rc2k35 PI P2
are the roots of ap2 + bp + c + k 0. From
where p, and P2 2k3A
the relationships for a two-link RG-filter it follows that for
stable operation of the circuit it is necessary that the time-con-
stant of the first link should be much larger than that of the sec-
ond link. The device incorporates a torque-balance technique. One
of the advantages of the chosen circuit is the possibility of con-
siderably increasing the input resistance of the device, and that
is due to the compensation of the input signal by the feedback volt-
age, in the circuit of the measured voltage. A new type of magnetic
modulator M (with transverse excitation) is used. Its transmission
factor is approximately 0.8 - 0.9 and does not depend on the voltage
and frequency variations of the supply source and on the temperature
Card 3/5

23962
S/103/61/C22/007/008/008
Pulse-frequency telemetering... D252/D302
of the surroundings over a wide range. The modulator is practically
inertia-free. The a.c. amplifier consisto of triodes of type P13B
and P14 (triodes PI,P2,P3,P4)- P5 is a blocking generator. The
device was laboratory-tested, and has the following main character-
istics; pickup-voltage range; 25 milliv., input resistance of the
order of 50 k , stabilization time of frequency: 0.5 sec, size:
255 x 215 x 140 mm. Owing to the new type of magnetic modulator,
the design was considerably simplified compared with previous de-
vices (ChIS-D-1 or ChIC-D-2). The high-ohmic input results in
greatly increased sensitivity (10-8v) as stated in A.M. Pshenichni-
kov (Ref. 4: Staticheskoye peredayushchee ustroystvo chastotno-
impuls'snoy siste teleizmereniya, Avtomatika i telemekhanika,
v. 18, no. 5, 195T~. The device can be used for transmitting read-
ings from a wide variety of d.c. pickups with small output strength,
including themoelement pickups, and pickups with bridge circuits,
e.g. gas-analyzers for telemetering the methane concentration in
mines. There are 4 figures and 4 Soviet-bloc references.
SUBMITTED: December 29, 1960
Card 4/5

MILYMINAO Te.l.
Weasures for decreasing the incidence
Zdrov.Ros.lader. 2 no.1:20-24 Ja 158.
of tonsillitis In 5verdlowske
(KLM 11:2)
1. Zmvejuyushchays Sverdlowskin gorodakin otdolon sdrawookhroneniya.
(SWDLOVSK-TONSIM-DISAASM)

MILYUTINA, Ye.I*
* Sverdlovsk conference of ohyolcianR serving medlcnl di4tricts.
%drny.Roe.]Peder. 2 no.3:43-45 Mr 158. (MIRA 11:1)
(SVERDWVSK--PUBLIC HEALTH)

MILYUMM9 Ye.I.; TIOSKOVAq G.N.
Ar4lysio of visits to medical institutions by vorkero of industrial
enterprises. Zdrav. Roo. Feder, 4 no, 4.,24-26 Ap 160o
(MIRA 13:10)
lo Iz Sverdlovskogo gorzdravotdela.
(SVERDWVSK-DjSWES-REPORTING)

BI.GARYATSKIY, B.A.; FELIDSHTEYN, Ya.L; IEBEDINSKIY, A.I., doktor
fiz.-matem. nauk, otv. red.; MILYUTINA, Ye.N., red.
(Collection of articles] Sbornik statei. Moskva, Nauka.
No.12. 1965. 56 p. (MIRA 18:10
1. Akademiya nauk SSSR. Mezhduvedomstvennyy geofizicheskiy
komitet. IV razdel programmy MGG. Polyarnyye siyaniya.

MnytiTINA yi., V.
33546
O~~=Os--ti Klinicheskikh i~~;n V zavisimosti Ot i~ovmya Rineniya Periferichosidkh
Nervay. Trudy Xurskogo Gos. Ned. In-Ta, T.119 Vyp. 2, 1948, c. 161-66
SO: Iatopis' Zhmrnallnykh Statey, Vol 45, Maskya, 1949

MILfUTIINA,j--Ye.-,V. - -- !-- .. . . - I . - . .
"Early Semiotics and the Development of Clinical Phenomena in Multiple
Sclerosis." Sub 16 Jan 51, Central Inst.for the Advanced Training of Physicians.
.rr-.g k,. q-:
Dissertations presented for science and engineering degrees in Moscow
during 1951.
SO: Sum. No. 480, 9 May 55.

MILYUTINAq I V.p assistant
Etiological kinship of multiple sclerosis and acute disseminated
encephalowyelitis an the basis of experimental data. Sbor. trud.
Kursk. goo. mad. inst. no.13t249-253 158. (MIPA 1483)
1. Is Inatituta. wirusologii AMN SSSR (sav, laboratoriyey - prof.
A.K.Shubladso) i 1r1JnJkJ nervmyM bolesney Kurskogo gasudaretvannogo
meditsinakogo instituta (sav. --professor N.I.0.olik).
(MULTIPLE ScLnwht) (IMEPHALWYELITIS)

MILYRIMP Yeavot asniatent
1~
Clinictal picture of the initial period during the acute course of
multiple sclerosis. Sbor. trud. Kurok,~_kos. mod. inst. no-13t254-
257 158. (MIRA 14:3)
1. Udinikl nervn7kh bolesney (sav. - prof. N.I.Golik) Kurskogo
gosudantvannogo moditsinskogo inatituta.
(MULTIFLZ SCUMIS)
or

GOLIKj N.I.; MILYUNNA, Ye,V
Some results of clinical and pathomorphological atudy of' multiple
sclerosis and acute encephalomyelitis. Vest. AMI SSSR 16 no.6:
35-45 161- (M-iA 15;1)
1. Kurskiy moditsinskiy institut.
(MULTIPLE SCLERWIS) (ENWHALOMIELITIS)

GOLIK~ Nikolay Ivmiovich; H11ILlInj. -' - - ' 7,
-)(eyS!3niy!j Vasillyevna; GOTUTSE
?.I., red.; PETROVA, II.K., tekhn. red,
(Multiple sclerosis and acute disseminated encephalomyelitis]
~!nozhestvermyi skleroz i ostrye disseminirovamiye entsefalo-
rcielity. Moskva, Medgiz, 1962. 113 P. (MIRA 15t12)
(EfULTIPLE SCLE,=IS) (EEGURALmaFlins)

4
HILYi"INA,' Ya..Ta.; SIMMOVICH. Ye I.; DIMAND, S.V.
Results of malaria an d helminth infections control in the Moldavian
S.S.R. Ned.paraz. i parsz.bol. 26 no.5-.588-592 5-0 '57. (NIU 11:2)
1. Is Haspublikenskoy manitarno-spidemiologichaskoy stantsit
(glavnyy vrech A.Kovaley)
(MAIARIA. prev. & control
in Moldavian Russia (Rua))
(EMIMM 1OWTIONS. prev. & control
same)

Decoll it' It a 0 1 Xide ill different volveato
Kh. S. 11F.& 'y
amir ,tit anti L4, I. Milytit igkuil H., yd~
~1,a, r V I'll --1-: - m I , ,
- , I I'l, atm. 0;.' at
. ) -: c W
.-ii --in tile a ti,enc,
Bi:O, demmi-- a z!w arne "ate in C.H.. AcOE1, ind
AcOl I whtti tjie --cii e, 0.19)1:;5 rnuie~).; ,t a cancn. of
0.18.11 tnol./I., it jct~unlIN-rjci 7 tlnlcj A:j IIL%t in ACORt. And
4 fliae, as fwit in Ar.CJR as in C41 I.. In in:eWnc the ratc oL
decompri. is twice that in CjI16, and In CCl,, Ph;ClIj, di-
butyl phthaNte, and psoutlocumetle about the saine wi in
-Wis, _Mth-deatluing- Couca. Of -,B7401-la C41h the-Y Ill-
DOL
-:,--.of detcrras .
ZGEL -.e&
hold for either C(),. or lizOl-I - Alaeoncri.cf0.185MOIC/l.
in PI1.CH* the Yield of HZ61f Is twire ih.Lt in C.1.4; ill
dibutyl plithalate 1.4 tilues; In pscudocumme 3 times; in
acetone twice; and in AcOll 5 times. The yield of CO,
fit dibutyl phthal[Ji~ is the same as that fit CjHj; in CCI_
re, in ri:CH2j V, less; In acetom- Ya less' and- In
Z110MI01 and MOM, I/i leo. Decompri. in the presence of
vinyl cojnpds. I- C&I-14 at 751 ff:~-ults in a demuAetj yieM
dOzOllandCOf. 'rhewoactiorielreaittibute4taLtchitin
decom it. ot Bz,Ot. There tlre 2 type3 of dtmiiptu:
unimor deeonilln- of peroxide into bmizoatt rudicalt. anti tit -
teractior. of peroxide with mot. reacting components.
lack Weiner

,~Oerd_~ 1A
t Kilyubiriskaya, R. I., a*A Bagdasaryan, Kh. S.
Title t Study of the machaniam of radical reactions. Part 3- Decomposition of
bansoyl, paroidde and Its p, POL-dinitro- and p,, pl-dimsthW-derlvatives
In benzene and nitrobanzane.,
Periodical Zhur. Fla Kh1m., 28P 3d. 5, 797 800,,-May 1954
.1bstract, i The decommosition of benzoyl neroxide and its dinitro- and dlmthoxy-
derivatives in benzene and nitrobanzons was* used as an axwple to prove
the value of the polarity of.molecules and free radicals for the process
Of radidal reactions. The polarity of radicals may at tims have a dou-
ble effect on the rate of radical reactionsi At distances up to the sun
of.1he van -dor Whale radii, the opposite polarity of the reacting compo-
nents.should be favorable forthe radicalreaction by Increasing the num-
bar. of collisions. Seven references: 6-USSEt; 1-USA. Table.
-Institution -t The L. Ya. Karpov Physico-Chamical Institute, Koscow.
Subutitted t July 3s, 1953

MILYUTINS . R. I., Cand Chem Sci -- (diss) "Radical Reactions
I -
of Benzoyl Peroxide in solutions." Mos, 1957. 15 pp (Min of Che-
mical Industry USSRO Order of Labor Red Banner Bel Res Fhysicoche-
mical Must im L. Ya. Karpov)p 110 copies (KL, 50-57, 118)
- 10 -

MILY07 . SKI rY,
Mj/a3d
An'lav"Uptian. of th u4AFat reactions mechadtaf. IV.'
,a
-The MfAn of When IformAtIon during the
and'M4.1trobell yl droMe, der-ompositlanift
.Vrffd R

in the
either
0.02A
in
j
_When
and ihi D content iff the solvent pernfitte-d-the
of the sourcts of Phs ar O&XC4H,COtH formed.
it In Ph. during the deroiupn~ of RzjOt in deu-
was 45177 of the D content in CtHe, and 48%
rmed 48%; 'theft vpluts were independent from
mp. (75--100',' or the Bzs% coucn. (betwew
ttnole). In ibc-decompn. of (4-0,N'CJtCO)r
3befixe only 4 N ptc. =51% D.
Whue 6.NC;Wx.5.14 ~- cuklimid 10.5%, D.
zeuc~ 42% V vim found [a the -dinittobiphenyl-, the OjIf-
The author draws the can-
rJusim that. bb)hczxyls are For~~d by the ad4p. ofAUhenyt
(or- nitropbenyt) rad" to the Cjfg (6r Ph N%l . with
the formatim of a PbC.Ifs - raTjW, and a subsequeM br=k-
fog Qwv of an Ff (ot 0) (rem the mdical by the F?enzoyl
(or ultrobenzoyl) radical. The reacUon of brtdidng- away
of R (or. D) occurs with no actope effect.
W.

AUTHORS." Milyutinskaya, R. I., BaLdasarlyan, Kh. S-, 76-32-2-29/38
TIT16 Investigation of the Mechanism of Radical Reactions
(Issledovaniye mekhanizma radikallnykh reaktsiy)
V. Decay of 4-Nitrobenzoylperoxide in Toluene
(V. Raspad perekisi 4-nitrobenzoila v toluole)
PERIODICAL! Zhurnal Fizicheskoy Khimii, 1958, Vol. 32, Nr 2, pp. 428-432
(USSR).
(... , ~ , ~ , ''':1 ~ ~ _'.
ABSTRACT; Data were obtained in earlier works by the authors (refimrence -1)
which prove the assumptions of rederence 3 concerning the schema!
of the formation of diphenyl in the decomposition of nitrcben=
zoylperoxide and its substituents in aromatic solvents according
to (1) and (2). The radical occuring in (1) and (2) can in a
special case also be a benzoate radical. The there obtained re-
sult agrees with the mechanism of the formation of nitrobenzoin,
acid (according to reactions (1) and (2), where X denotes a
nitrobenzoate radical) from reaction (3). In this connection the
following problem appaers; can a nitrobenzoate radical dissolve
Card 113 out a movable hydrogen from the alkyl group belonging to the a:ro-

Investigation of the Mechanism of Radical Reactions 76-32-2-29/38
V. Decay of 4-Nitrobenzoylperoxide in Toluene
matic ring? In order to solve this problem the authors investim
gated the decomposition of It-nitrobenzoylperoxide in toluene
partly deuterized in the methyl group$ as well as in toluenf~
partly deuterized in the ring. The results obtained showed
without any doubt two ways for the formation of nitrobenzoi-,,
acid: the reaction (3) that is R - NO2C6H43 R CH 3' and the
reaction (4). Data are given by means of which the share of
nitrobenzoic acid obtained by reaction (4) as well as the.
kinetic isotopic effect in this reaction can be determined.
The equations (5) and (6) for the deuterium sontent, in nitroben-
zoic acid (obtained in the toluene deuterized in the ring o-r the
methyl group) are given. From these the equation (7) for the iso-
topic effect is obtained. The values calculated accordi _ng to thi,7
equation are within the limits of from 1,79 to 2,17. The
effect in the reaction of the dissolving out of hydrog,~n from thi
toluene by the No 2C6H4COO radical (reaction W) is equa! t,~ i.;92
The share of the nitrobenzoate radicals which react according to
reaction (3)-in the concentration of peroxide in the solution from
0,16 M and looo - amounts to 0,365.
Card 213 The work was discussed with S. S. Medvedev.

Investigation of the Mechanism of Radical Reactions 76-32-2-29/38
V. Decay of 4-Nitrobenzoylperoxide in Toluene
There are 1 table, and 7 references, 2 of which are Sov1sto
;ISSOCIATION: Physico-eh~.emical Institute imeni L. Ya. Karpov, loscow
(Fiziko-khimicheskiy institut im. L. Ya. Karpova, Loskva)
SUBMITTED; December 12, 1956.
. '..~.:.7 .;._ .'.~ 1,.;,Nitro,bompqW&-rDecomposition
3. Toluene--Chemical reactions
2. Benzoyl peroxide--Decompositior
Card 313

S7,5~~O 0
44)
LUTHORSt
TITLE:
PIRIODICALs
ABSTRACTs
Card 1/2
68348
Bandasarly-n- TO- 9-,
Milyutinskays,
5/076/60/034/01/043/044
B004/B007
A New Method of Investigating the Reactivity of Organic Com-
pounds to Radicals
Zhurnal fizicheskoy khimii, 1960, Vol 349 Nr 1, pp 234 - 235
(USSR)
The authors describe a variant of the method of competitive
reactionsp which was worked out by themselves. It in based
upon the application of tagged radicals and the determination
of the reaction products by means of.isotope dilution. Thus it
is possible to use the tagged radicals in low concentration
(0 .01 21/1)9 so that the reactions of these radicals may be
neglected. The authors describe carrying-out of their method
in the case of the reaction of the phenyl radical with aro-
aatic compounds. L table gives the data for the reaction of
benzoyl peroxidelin a mixture of benzene + CCI 4, nitroben-
0
zene + CCI4 , naphthalene + CC1 4' and cumene + CC14 at 100 .

68348
i Now Method of Investigating the Reactivity of 5/076/60/034/01/043/044
Organic Compounds to Radicals BO04/B0O7
The reacticn constants found agree with the data obtained by
employing other methods. Att present the authors employ the
method described for systematic investigations. There are
I table and 3 references, 1 of which is Soviet.
ASSOCIATIONs Fiziko-khimicheskiy institut im. Lo Ya. Karpova Moskva
(Institute of Physical Chemistry imeni L. Ya. Karpov, Moscow)
SUBMITTEDt June 16, 1959
Card 2/2

,57 3 N 0 (A) 68856
AUTHORSt MiliztInskaya, R. I.y Bagdamarlyan, S/076J60/034/02/021/044
- - -0. B010/B017
TITLEt Investigation of the Mechanism of R di &I Reactions. V1. On the
a AWith Amino*
Reaction Mechanism of Bonzoyl Peroxide
PERIODICAL: Zhurnal fizichoskoy khtaii, 1960, Vol 34, Nr 2, PP 405-412 (USSR)
ABSTRAM S. P. Gambaryan (Refs 102) had already observed that amines react
rapIdl with bensoyl peroxide. 0. A. Chaltykyan (Ref 4) and Nornor
(Ref 55 found that free radicals are formed in this connection.
Since the reaction kinetios proper has been little Investigated
the authors tried In the present case, in continuation of previous
investigations (Ref 7), to obtain a direct proof of the formation
of free radicalsO~n the reaction of bonsoyl peroxide with secondary
&Minos. The polymerization method and the reaction with diphonyl-
pierylhydrazine were appliodp and the kinetic Isotope effect in the
bongs of the hydrogen atoms in the amino group with deuterium
was determined. 1-douterium aniline and 19-douteriua diphonylanine
were produced by(shakin out with heavy water, ae,,o(1-diphenyl-A-
picry1hydrazine WE-KI and the corresponding hydrasyl (DPPH) waa
produced by E. A. Mietryukov according to the method of Renn-
Card 1/3 Goldschmidt (Rof 8). The polymerization kinetics of nothyl-

68856
Investigation of the Mechanism of Radical Reactions. S/OT6/60/034/02/021/044
VI. On the Reaction Mechanism of Bonsoyl Peroxide DOIO/DOIT
With Amines nothacrylateliniti&tod by the benzoyl peroxide diphonylasins
mixture was investigated according to The dils,tomstric method by
Z. A. Sinitsyns.. The value k - 1-17-10 91P (- 16400/RT) 1/mol sec.
(1) was obtained for the blaolocular constant of the reaction with
diphonylazinsp and the value k - j.e6*jo4exp (- 10700/RT) 1/mol
see. (4) with aniline. A comparison of the constant of the re-
action rate (Tables 1p2) shown that the constant does not change
in the exchange of protium with deuterium, i.*. no isotope effect
takes plac*9 and thus the transition of hydrogen from the smine to
bonsoyl peroxide does not influence the reaction rate. Kinetic ox-
periments on the reaction of bonsoyl peroxide with snilinos substi-
tuted in the ring have also been carried out (Table 3). The con-
stants of the Arrhenius equation for the bonsoyl-paroxide reactions
with amines are mentioned (Table 4), and the reactions are dis-
cussed from the point of view of the reaction theory of electron
transition. The bonsoyl-peroxide reaction with diphonylamine takes
place clearly with the formation of free radicals which are cap&blo
of cleaving off the hydrogen &ton from DPPB*E, and which offset a
polymerization of m*thylaothaeryl&to. The efficacy of the benzoyl
Card 2/3 peroxide diphonylamine mixture in bringing about the polymerization

68856
Investigation of the Nechanion of Radical Reactions. 3/07-6/60/034/02/021/044
V1. On the Reaction Mechanism of Bensoyl Peroxide DOIO/9017
With Amines
of methyla4thacrylato was found to be about 0.001 at 250. A paper
by A. S. Kuslainskiy and L. G. Angert in mentioned in the text.
There are 4 figuress 4 tables, and 19 references, 9 of which are
Soviet.
ISSOCIATIONt Fisike-khImichoskly institut in. L. Y&. Karpov:,Noskva (Institute
of Pbysloal Chemistry imeni L. Ya. Karp* , No* V)
SUBMITTED: May 12, 1956
Card 3/3

BF.AFORD I K.[Bamfordy C.H.1; BARB, U.[Barbs W.G.3; DZMIIBS, A.
(Jenkins, A.D.]; ONION~ F.(Onyonj F.F.1; GRITMKO, T.M.,
kand.khim. nauk, (translator]; MIIYUTI?ISKAYA, R.I., kand,
khimi nauk~ (translator]; PRAVE=IKOVO A.B., kand 0
nauk [translator); NAL331SKIY, Yu.M., kand. khim, ;a1,11 . red.1
KHODETSKAYA, Z.F., red.; PRIDANTSEVA, S.V., tekhn. red.
(Kinetics of vinyl polymerization by radical mechanime) Nine-
tika radikallnoi polimerizataii vinilovykh soedinenii. [By] C.H.
Bamford i dr. F-oakva,, Izd-vo Inostr. lit-ry,, 1961. 345 Pe
Translated from the English. (MIRA 15:3)
(Vinyl compound polymers) (Radicals (Chemintry))

36520
S/081/62/000/006/017/117
T-) Y B166/B101
AUTHORSs Bagdesarlyan, Kh. S., Milyutinskaya, Ro I.$ Trosmanq Ee A*#'
Borovkbva,, V. A.
TITLEs Quantitative studies of radical reactivity by the compotiti*
reaction ipethod
PERIODICAL: Referativnyy zhurnal. Xhimiya, no. 6,* 1962, 53, abstract
6B360 (Tr. po khimii i khim. tekhnol. Gorlkiy no. 1, 1961, 1
12 - 17)
TEXT: Using a method described earlier (RZhKhim, 1960, no. 2406341)o,
measurements were made of the relative rates of attachment of phonyl
radicals to aromatic rings (rate constant k1) and of the separation rates
of hydrogen from alkyl benzenes by phenyl radicals (constant'k ra-
2)' SOP&
tion of chlorine from carbon tetrachloride was taken as the standard
reaction (constant k 3).' The following values of the constants wore obtained
at 1000C (the first figure is k the second figure is k t benzene
1/k39 2/k3).
Card"1/2

S/061 62/000/006/017
_/I 17
Quantitative studies of radical... XBB101
0.235; nitrobenzene 1.0; 0.1; naphthalene 5; 0; toluene 0-48; 0-33;
isopropyl benzene 0.98; 0.85; polystyrene 0.62; 0.06. The polar
substitutes - the electron-donor and slactron-acooptor--~46ti*ato.the
phenyl rings. There is no marked separation of hydrogen from the aromatic
rings. The rate of hydrogen separation from the alkyl groups of poly-
styrene is considerably lower than it is from isopropyl benzene, which is
apparently attributable to the steric factor. LAbstracter's notes Complete'
tr&nalationi
Card 2/2

L 19745-65 wrW/Z?(c)/kWP(j) Pe-It/Pr-4 ASD(p)-3/hAVMW_ RM/14LIC
ACCEMON NR. AT4049866 S/0000/64/000/000/0266/0271
AUTHOR: Bagdasartyan, Kh. -S. *na Z. A6 Milyutinsk -Vt
7-
lp
TrrLE: Kinetic study on the effect of antioxidants during the oxidaLion of rubber. 1.
Kinetics of the uninhibited oxidation of rubberL
SOURCEt Khimicheskiye svoystva 1. modifikatsiya polimerov (Chemical properties and the
modification of polymers); sbornik statey. Moscow, Izd-va Nauka, 1964, 265-271
TOPIC TAGS: -synthetic rubber, rubber oxidation kinetics, antioxidant, benzoylperoxide,
azodilbobutyronitHle'.-
ABSTRACT: The kinetics of oxidation of 0. 1 g specimens of sodium-butadiene rubber
were studied at 60-IOOC under constant oxygen pressure in a thermostat equippeU with a
differential manometer, and also with oxygen circulation and freezing out oi the decom-
positior products in a cold trap. The specimens were purified by reprecipitation and de-
positeu from benoerte solution as approximately 0. 1-mm. thick films. The tests showed
fiat oxidation rates increased during an Initial period, and that this lag period does not
depend on the presence of inhibitors or their consumption. A second and nearly stationary
period was followed by the rapid decrease of oxidation rates in the third and final period.
The initial period was not affected by removal of oxidation products, nor by the thickness
:C Ord 1/2-:

L 19745-65
A(',r'ESSIOlq.NR: AT4049866
of a--e ~flm, ~ and addition of up to 3. 58% benzoylperoxide or 4. 68% azolsobutyrodinttrile
dL& nG-, change the rate of the stationary process, although the initial peetod decreased.
The concentration of peroxides was determined in Fome runs by iodometric titration, re-
veal.ag a stationary peroxide concentration of 23 Pnd 14.5 m-mol/mol monomer at 80 and
106C respectively, within an error of 2 and 3 nunols. The kinetic model was based on a
,. as species for rate etermination.
radical chain reaction with branching and R. and RO? d
Th- itationary rate was found to be proportional to oxygen pressure and to increase with
te. .-ature; the effective activation energy was approximately 15 kcal/mol, the branching
fae. was at least 0. 35, and the rate constant for decomposition of rubber peroxide was
(2. (). 5). 10-2 min -1 with an activation energy of approximately 21 kcal/mole. "The
dec. -?osition of benzoyl peroxide in rubber was studied by E. A. Trosman in the authors'
lab. -Ltory. The authors thank A. S. uzlminskiy ond L..g-.--A_ng-ert for helping with the
work and evaluating the results. 11 Orig. art. has- 1 table, 4 figures and 18 formulas.
ASSOCIATION: Fiziko-khimicheskiy Institut fm. L. Ya. Kgrpoa -Ustocochemical
--lubj~Ae)
SUBMITTED: 18Jul63 ENCL: 06
SUB CODE: MT,OC
card ~:ft/

h
"-1103 Je
-1 k 1 i,o Z k A ~y in a L-, uu,

MTLYUTINSKAYA, R.I.; BAGDP-SARIYA11", Kb.S~
New data on the sensitized fcrnution of caticn radip-als in
the low temperature radiolysis of films coni~aining aromatic
amines. Zhur. fiz. khim. 38 Mr 164.
(MTRA 17-7)
1. Fiziko-khinncheskiy instit-,it im-e-roi --.Ya. Karpova.
0

17~141YW_l Ale 041
PHASE I BOOK EXPLOITATION SOV/5537
Panasenkova) Ye* ed.
Issiedavaniya kriticheskikh parametrov reaktornykh sistem; sbornik statey (Study
of Critical Parameters of Reactor Systems; Collection of Articles) Moscow,
Gosatomizdat, 1960. 117 P. Errata slip inserted. 3,600 copies printed.
Tech. Ed.: N.A. Vlasova.
PURPOSE: This collection of articles is intended for nuclear physicists and
engineers of nuclear power plants.
COVERAGE: The book contains previously unpublished original articles concerned
with the theoretical calculation of neutron fluxes and of critical pararieters
(critical masses and volwoes) of various reactor systems: uranium-graphite,
uranium-beryllium., and water mixtures of uranium and plutonium. Individual
articles present tables and graphs used in the determination of the dependence
of critical parameters on the relative concentration and the character of the
fissionable material and the moderator,, as well as on fuel enrichment for a
wide range of neutron energy spectra. The following are mentioned- P.A. Gavrilov
(scientific editor of the collection), and S.I. Sokolov, L.N. Spakhova,
-Gard_l/.j_

Study of Critical Parameters of Reactor Systems (Cont.) SOV/5337
Marchuk, G.I., G.A. 11yasova, V. Ye. Kolesov, V.P. Kochergin,,
L.I. Kuznetsova, and Ye. I. Pogudallna. Critical Messes of
Aqueous Mixtures of Compounds of Uranium and Plutonium 57
Zagrafov, V,G,, Interaction of Systems of a Fissionable Substance
in a Scattering Medium 74
Kamayev, A,V,, B,G, Dubovskiyp V,V, Vavilov, G,A, Popav, Yu.D.
Palamarchuk, and S,P. Ivanav. Experimental Study of the Interaction
Effects of Two Suberitical Reactors 101
Marchuk, G.I.,, B.G. Dubovskiy,, V.V. Smelov,, and Z.N. Milyutina.
The Design of Sectionalized Nuclear Plants 107
AVAILABLE: Library of Congress
C.Q=L4A- JA/dwm/mar,
7-29-61

ACCESSION NR; APOW469
S/0190/64/0O6/0()6A098Al03
AUTHORSs Bagdasarlyan# Kh. S.; Xilyatinskayaj. R. I&
'TITLE: Kinetic investigation of the action of inhibitors of rubber oxidation
SOURCE: Vy*sokomoleku1yan*Mye soyodineniyap v& 6. no* 6. 1964s 1098-1103
TOPIC TAGSs rubber oxidation inhibitor, oxidation induction periods Molecule
lifetimes oxidation initiators sodium butadiene rubber
ABSTRACT: The authors studied the inhibited oxidation of sodium butadiene rubber
in the temperature interval 90-10OPo They found that the duration of the induction,
period for various inhibitors varies by a factor in excess of 100. The amount of
oxygen utilized during the induction period is from 10 to'1000 times the amount of
,the added inhibitor* The inhibited oxidation of rubber has been analyzed for the
icase when the reciprocal of the rubber-peroxide decomposition constant is much loss*
than the induction period. Thwinduction 'Period T may be represented by the
approximation T~~Sxo(I-S)Vins where is is the inhibition coefficient (ranges from
0 to 2)s x. the initW concentration of the Inhibitors 6 the regeneration
coefficient of the inhibitoor (ruges from 0 to I)# and V thq initiation rate*
&d t! 1/2 -------

ACCESSION NR: AW0489
Regeneration of the inhibitor molecules is probably due to disproportionation of
the inhibitor radical and the polymer radical. The addition of an oxidation
initiator diminishes the induction period in such a way as to suggest that the
initiator radical react4s directly with the inhibitor molecules. The conclusion an
0 the effective regeneration of inhibitors is based on the assumption that the true
1.4 amount of absorbed o.Vgen in the induction period in near the"threshold value ob-
served by experiment. If the first value is mudi larger than the-second, it is
then necessary to determine the absolute value of P/(l-r) In order to explain the
causes for differences in the efficiency of the inhibitors. OrIge arto hass 1
~figure, 2 tables, and 17 forwilas.
ASSOCIATICH: Flaiko-khlideheekly institut :Lmo V. Lo Karpova (Physicochmical
Institute)
'suwnms i8jui63 ENCLs 00
T----iSUB CODEs XT 90 FZF SM 002
OTHERs 002
2/2
raA7.

MILYUTKIN, A. F., Cand Agr Sci -- (diss) "Growing of sugar
0
sorghum for silage in Balanhovskaya Ablast." Saratov, 1957.
19 pp (Min Agr USSR, Saratov Agr Inst), 150 coPies (EL, 1-58,
120)
- 78 -

ANOSOV, V.I.; SAVOSTIN, A.M.; PINES, V.G.j,~~~~7TKINA,,_I~.yl_lqROPOLISKAYA, M.A.;
FEDOTOVAp N.I.; SAMO)afVAIDV,, G. I.
Preparation,of Y-.,y-dimethylallyl alcohol and isopropenylethyl
alcohol from.the product resultingfrom the condensation of iso-
butyleng. 4ur. ob. khim. 31 no./+:11~4-1157 Ap 161
jKERA 14:1+)
1. Vsegqy~znyy nauchno-ioaledovatellski vitaminnyy institut.
(Butenol) (Pentenol

SOV/137-58-7-1538
Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 7, p 208 (USSR)
AUTHORS: 1patyev, V.V., Ivanova, M.A., Milyuts, G.B.
TITLE: Formation of Scale on Z5% Iron-nickel Steel in Air Containing
Water Vapor and Sulfur Dioxide (Okalinoobrazovaniye na 25-
protsentnoy zhelezo-nikelevoy stali v vozdukhe, soderzha-
shchem vodyanoy par i sernistyy gaz)
PERIODICAL- Uch. zap. LGU, 1957, Nr 227, pp 48-58
ABSTRACT: Investigation of the kinetics of the oxidation and the struc-
ture of scale on steel containing 23.60/6 Ni ar 750-9800C in dry
air, moist air (10-20% H20), steam, and moist air with addi-
tion of 1-51o S02. The rate of oxidation was determined by the
method of periodic weighing during a tes-. lasting up to 120 hrs.
It was determined that an increase in the humidity of air up to
10-1516 sharply increases the speed of oxidation of a given
steel. Addition of 1-516 S02 to the moist air at 750-8000 shows
no appreciable influenced on the rate of oxidation of Ni and
steel. The structure and the order of sequence of layers of
scale on steel recall the scale forming on Fe under analogous
Card 112 conditions. Unoxidized Ni concentrates in the inner

SOV/ 137-58-7-15385
Formation of Scale on Z57o Iron-nickel Steel in Air (cont.)
heterogenous layer of scale and its content in this layer is 150-200% higher
than in the original steel. FeO as a separate layer in the scale forms only
on addition to the air of - 1016 H20. The comparative thickness of this layer
increases with an increase in the humidity of the medium. Addition of up to
5% SOZ does not change the appearance of the scale formed.
V. S.
1. Nickel steel--Scale 2. Nickel steel--Oxidation 3. Nickel sTeel--Moisture
factors
Card 2/2

VOIMKOV. W, MILYY, K.
Testing notlon-plature projectors In workshops and repair stations. lluomkhm
nik no.10:33-37 0 053. (NLRA 6:10)
(Moving-ploturs, projectors)

KMZ*.-T.
TMMMMY
FMODICALs SPULZMEFESUTO Voif home. 69 1955
KUsq To Problems of ou"lemostary constructions in connection with the 9
oredtion of dw~Uifts; alsop reauts by Js Varody wd A* Hedry. p. U0.
Moutbly list of Sest gurepean Accovelons (SW) LC9 Vol. So No. 2g
Febrwu7 1959o Vaclass*

I;.
Investigation of conditions for operation of steam boilers, p. 92s
EPb7MGEPFXZET, (Epitoipari Tudomanyos Egyesulet) Budapest, Vol. 5.,
No. 4. 1956
SOURCE: East European Accessions List (EFAL) Library of Congress,
Vol. 5, No. 11, November 1956

II I i" , i 1*1 1
M ( L :- I - , 'I ~ ` -
MILEARAYS, Ya.: SHADRIN, T. (Kielovodek); FZDCROT, G. (Rostov-na-Donm).
Compiensating background noise. Radio no.6:44 Je 157. (MIJU 10:7)
(Asplifiers, Electron-tube)

MIS" Ve
Possibilities of divelopment in nandfictmring* boilers for central heating;
also, remarks by R. Tarjan and others. p. 400
MWtGU ES ATCMTWHffM. (Snergiagazdalkodast. Tudomanyos Egyesulet)
Budaput, Hungary. Vol- 12, no. 7/89 "Ir/lumt 1959
Mmthly List of Rest Zuropew Accessions (VAI) LCj, Vol. 8. no.11
Navvaber 1959
Uncl,

MIIZ, Viktor
Economic problems in central comodity hot water supply machines
connected with hot water district heating suatemoo Energia eo at=
33 no.1/20_4-4la-F 160.

MILZ, Viktor
Diversion of gas combustion products. --Epulotgepesset 11 no-5918&-190
o 162.

MIIZ, Viktor
Operational expenses of central heating installations of
dwelling houses. Epuletge-peszet 12 no.6:224-2Z7,,240 D'63-

MDWKOP O,A. . inzh.
aw Slight rapid dryIng of laboratory specimens before preparatlon.
Sbor. DonUGI no.2524/r-50 '62. (MMA 16:6)
(Coal-Analysis)

Urica. :.l. 3ez~~ak, V.
"The effect 'of antibiotLisand antiseptics in vitro on Ithe onena bacterial I'lora
and on IN'lobsiella rhinoscleromatis." P. 175.
(Yu~-osLavla. Vol. 1, 1951,.Zagrob.)
L>
SO: '.-bnthly List of FafA Euro-oe 1,,C~~-g5lons, Vol. 2, i"o. 9, Lj:ora-i-j of Con~;r---is!:, Soutc:--bcl
19,5_3, Uncl.

VRANCIC, Jirina; MMCA, Milorad
FiMing of Endamoeba, histalytica in chronic chorioretinitis. Radovi
med.fak.p Zagreb 7 no.2:149:453 959.
(ANNUASIS diag)
(CHOROID die)
(RITMTIS diag)

MIMIGA,M.
Skin tests in gastrointestinal diseases. Acta med. iugool. 13
no-3:351-356 159.
1. Clinique Nedicale do la laculte do Medecine do Zagreb.
(GASTROINTISTINAL DIBXASJB diag.)
(ALLIRGT diag. )

CA, MUoradq -Dr.; KRSNJAVIq Bogdan, Dr.
Strongyloidiasis. Clinical and epidemiological considerations on
25 cases. Lijec vjes 82 no-7/8s-561-373 060.
1. Iz Klinike za unutarne bolesti Medicinskog fakultsta i Parasitoloskog
odejela Centralnog bigijenskog zavoda NRH u Zagrebu.
(STRONGYLOIDIMIS epidemiol)

GALINOVIO-WEISGLASS, Marija; ?VAG, Ivo
JULTL
Aero-biological investigations ih Zabreb and on the Island of Rab.
A. Investigation on fungi. Had.-med. fak. I eb. 10 no.1:25-38 162.
(AIR MICROBIOLOGY) (FuNaIT

VOLARIG-MRSIG, Iva; WHIGA, Milorad; MALJEVAG, Ivo
Aero-biological investigations in Zagreb and on the Island of Rab.
B. Investigations on pollen. Had. med. fak. Zagreb. 10 no.1:39-46
162.
(Polim)