SCIENTIFIC ABSTRACT DANILOVA, A. K. - DANILOVA, A. V.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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Ili%, and v,AIk S- Is a 1~1- 1, fh~ ..." 1,40 - .."I -d ...... I.-I , t h~ A the ~Sjj. ( " h", hen, A, "I it,. t 1 wall VA. 41111411; I d4rin* 111A, pf'.1L.-Ind flri-I I I ,.,A,, III rxx Alrbife 41141 YA'Ik ,I ,,, 111, . j 14-1", ,, --A.Mduring .11r.A.AlIA"Arr As )tits fb~ I.-I ..... . .... A. w 48 0 ,J list Arxx whair ItittArAl.d An J.- mAdd---f ,I f"t, _ rh. _IA -11I.At 'A'-f 11111, Vt~.(_n . -- w -.1 -h .4 .400 0 hv cgg v,4k dts~ra-f in list, --nw ,-nth, I 1 A 0 : - _ntmi of the trAgg Y-4k a, bigh-i is, Jum )b, * I A 11.11 and (at Ili the rwit- ,( PAinx duck, I, huh. .10 0 940 TIAV mfh,_w,, M , ~ ~ I", h. I, .1, 1 Its-- -mim ,( I I.A, . A,g, -4 1'. kmj, d- L Will II.I.Arl- ir A. I., 4h. k .40 A.I"c.j the exi; y,,Ik 11% 1~2- - Is st.ma p-1- i r1w cjs ortsill, " s"tall mss 1- . IIIAIII(I" rhr ctruteut Ali 11,0 is highel, while Alit -nivnt -( t-temi 41911 ash to AirvaWt Th, mwtmr ahw of th~ -,v v.,Ik -.00 A. hishre. the 11,0 cAmiciii I. imalb f mful A It, 1 .4 A 1- 1.1 A. higheir The obirtakatic us sort ,it ii-pitis, dw riggi Itic 2 :0 0 A 0 snouthis was IQj in thrramsetJ the RvAnapand 12~, As, that i,40 0 met It- IIA, PAIns dus k F 1. Dunlap a . . , U At . I Ap I I I AS All .1 1 1 Its A, 1, 1, AM m's .44 R"m ttlbwq ... e 0 9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 : : : : : : 0 0 0 0 0 0 * dt 0 0 4 0 0 0 0 0 0 0 0 0 0 a 0 0 0 0 DA,"ILO'-"A. A. -CIJ A. L~. anc 'Funda.-ne als of Feeding I-TI., published from (!t. Aca"~ i:ia:--ioe C,.)raz,)vani., v P7 1. ~A. "';%'I I i~". . . I . I - . . . _ ', .--. A.., k. , :'I'm, ., .-lu, . , I I o"; V 1;o';1'.~:.- - .~ i 6\~ p 'I ..... 1: 1: , *~'; t " ~ , It . ";.; i .,.! i ~iu -~ ;.; 13" j t~ . , -,*, . F: V oul r :, ,4 *V DKNIWVA, A.K.,prof. Some problems of avian witrItion at the llth International Congress on Pon1try Brooding. Ptitaevodstvo 9 no.1:31-35 Ja 159. (KIU 12: 1) (Poultry-Feeding and feeding stuffs) (Pomltry research) VANNOVA, A.K., prof., doktor sallskokhos7a7stvann7kh nauk. Significance of the chick-pea in rations for chicks. rtitsevodetvo 9 no.2:35 Y '59. kKIRA 12:3) Ohick-pes,) (Poultry--feeding and feeding stuffs) Tr, -0 r rar a n OL f, KOZHINA, I.S.; DANILOVA, A.S. Preparation of' trans-isolimonene. Zhur. ob. khim. 31 no. 110781- 3788 N 16.1. (MIRA 14:11) 1. Botanicheakiy institut Akademii nauk SSSR i Laningradskiy gosudarstvennyy universitet. (14enthadiene) DANILOVA, A.S. Structure of the thermal isomerIzation of ascuridole. Part 1: Reaction of the thermal isonerizatIon prod,,:r-. of ascaridole with hydrogen halides. Zhur.org.khim. I no.3:522-525 Mr 165. (N',:.P,A 18:4) 1. Leningradskiy gosudarstvennyy urdversi; *.-q' . DANILOVA, A.S.; PIGULFVSKIY, G.V- Structure of the product of ascaridole thermal isome-ization. Zhur.ob.khim. 33 nc.6:2076-2077 Je 163. (MIRA 16:7) 1. Leningradskiy gosud&rstvennyy wniversitet. (Ascqridcle) (Isomerization) DANILOVA, A S.i BA."ABANOVA, L.P.i RYABININ, A.A. E-hinocy9t.1c acid in thm root,-; (:,J' -,-,~j-r.(,pO,JtjjM qrl.helininlicum L. Zhur. ob.khim. 34 ncl.2V706 F 164. rMIRA 17:3) 1, Lanin~,-rqlskiy 94,et- .J.1 04111 go* 1 I 004 ~ W ogle COMMON"= d S-8giAMI-I kow M&M Union Chem J. GM. Cheats n"Cla. Su., .6 Malay (30 J. I" If. dMia. sW 35 CC. lah won tIMCA dowly th 33.3g. A106 mW at two temp. 24 lan.. then a fast. ats 4o.-61; latter adals. of HCI the mom waas estd. with IftlO. from w" then vam obtsiaell awd CQMpL%_. on of which Rualywd for (diamos"hilh- oweptia1w acid. M. Ids-70'. 0. 191-2% SW Izat; it treat dasawas that the lot two arem indivithsal cdmpds.. White the 3rd wit a mixt. of Uwm. &uaaw caualectiltdow (a CSt =to . Was. of the above tubstamm. The odoct by A*.. Con, RtOH am 4.=: oi! 8 -sisthaw ##Oak (flow litoll"p. .0 (1). an. 1W70, (El eltdr. M. taw star t).awpAtheo M. m. 191-2" (Et stur. an. 304)" (Ireals twou)). The I an tant wpd. by RION crysto. of tbek St cdcM I form an exinw. M. 10-we ((No Ccla); maw of H an. It", (decompas.. from C611.0j; Cleumemaeli re4scUm of I g*vv the car- r"PalsAwd &M ' acid. us. WIOO* (from RION) (ES .taw. bb 190-17which. can beadull with PA In Phue. laidej Map C., 48c MV a, 4, 0 0 0 0 0 0 0 0 0 a 0 a Ole ~%, A 0 0 Wo 0 0 0 0 0 0 oj" FS ^eta gave tu. 101-2* Yfum HIM) (atrawe. m. 147-6* (hum RIOND. reduced with amatkamisted Zo in Ila-PbMe to 1jj.4.- an 04. (from MOM. Clemmmeeta mducsion at U cave the co- "Spowdeval bwyrk "ad, M. 109~10* (from pear ether), which. on cyrfizattion with PA In budift PbMe. Fave an uoww of the k4*p4rawuLArvvw dirrit.. a. 133-4 (from HtOlIH01iM- to- lt?J-7t)*) dunring that I vad u wit :ds= Zu to III. tkm am 7 1 (3 g.) in 50 cc. 10'1~ XAA~0. was doarty UW Wish 30 x. 30e. Na-I!4 amulcant at room temp. the . I (3-4 Ian.) adda. of water, the Wit. t Weed 2 lam. - estd. with RIO to Mamma: the Tama" ah" W" hatro, ducd with the MA he dk. Bob. aacidifed ar" HO (3%) add~31u~"; eteem'. after bolifus to- 13 naba. ud. 11 the mint. tru eztd. B KtoO. the hatter *aid. with 2% Nallco.. am The w3khutl Mao voln. was fmj of wall"d and trtatted with an cumu of Sa (Off). foGoared by COt trealitums of the heated win.; the diustat wass lacizad with 3DCT H&S04 and ead. with EtoO to *0 the Asclovor acid. m. 6"' (from EtOll). M. on I a 0 'd a a a I N M 9 M a 3 4 b141 0 0 0 0 0 0 0 0 6 0 0 0 0 0 0 111 6 0-0-0 0 0 0 0 0 0 0 * 0 00004000 age goo goo was gee goo see Igo a gee !See moo see too i. , .. . . I , . . . ! :-- ~ I ~ I I . . ! - . :. .1.1 .1 . I . t . . k F- . . - , y 9 . I , . .. . : - . : I I : . I & & 'IF . : I . I I USM/hoolstry - MaUldm, Sawalo Jun 48 Chw8try - Retramoine, Prm senecio BM4111180418 *StU4196 Of Ssm*io OUse Alkaloids,* R. Kmovalovs, A. Dantio", kjkglojd&l S"I AU_Unjov 80,_Res Chem_ Phar In8t 1mml S. Ordzhonlkldzop Noscow, 5 pp 0zhur Oboftch Rhin" Vol XMI (r=), No 6 Studles struotwe of somomilln. Concludee that It IN IL GY0110 OthW of retronecine vith a moleoulg of d1basic senicifillic acid. 4=b gAg?28 CZEChOSLOVAKIA V. - TOMASEK, V. ; MIKE3, 0. ; DANILOVA, A.3.; 301LM, F. Institute of OrgFinic Chemistry nnd Biochemistry, Czechoslovak Academy of Sciences, Prague - (for all). Prague, Collection of Czecho3loyril-, Chemical Co=iiinicationg, No 11, November 1965, PP 593 - 9 "On proteins* Part 98, Tho disulfide bonds of bovine dip- trypsin." thill"t'Is tst %Oltoclo specto. VII Allial-J. It-., wirlo spolat'll % I I . "'.1 14 % K- Aill k li"" I'l I.. I.... .. k, "1-'.,A,.IA4-, (."' i .1,4m.. 4j. I, , , " "I I J, 11 . 1, - In 11). 14- IV, "I I . " , N I Q ~ , '-rude pr-Milo. Kith F1,41 A.4 11-1 " ILJ,wf.. %fo vrtth hw 1%1"0 1 I,ft t.hmd r4 -- ~112 14' it, 1711 7',. hilr r-ling h, " "wI'dow., "I I-Wil :LI - k-if( 1, ~ P. ."I,. .' I., I I I I 1117 7 3 f...... FW11 A, 'a'4, Qt All' It", fit f I hh ?I mictImo, IV "Ic"I if-) It, 11-1 IIYII".I- It JIT- ;l Milt I I ~c wsidu, 4 1 tic alkalmh, Aict I hc mit,.d I-,,( v L 110, -J oilh III-- -m,rd, vO I-) d/-, I. N . $I, fit 1. 1.41 _' 4", A. 0 M wit, ,, IV, 1 141 V I'V t%in 11 ..... I'.." ith k Ik 11, m I h, pt, - cts'l of \li,()Il 4 . %I k-L.J.'d ~p Aftwows a seneds "ed*g VII AlkaWds ftom sooods feltudi A % Pantf .. . .... I R b,,.,-A ... j G'a ( km V V i R j0, "WW tiff 111.'Af A I-Al IKM I her C .1 43, 2.1wfl" k N I , Sirrathows, dmtwe. and banstormanocas of 1-- I-ethosy- 1(6 ~-matphtbcajl Vropixank acift S I "wrtitc-eikara A 'V' Danduva. ...,art A A I, b,-m-k-, IS All, 'T'nT6n-'('hrt,, hist Xl,~. I A., tif,rikkel Altom If (-- 1O.Till '.!II(IW'jl1 Addit uf 120 if AICI, ifh ~tm-ia laid I,- U41 of I I jjO W a ---, aa,lay4ruir fit 10 lies . Irlting .1ji-I A firma "I'l 11,A(mil I hr~ 1. 111, 5' Fre .1tr, Om 'Isual armament "', K "","I an IV-rV, artlers. fii.im,n .I thi, 1,% r,flumnit 41 he% with *K) nil. VtOll ."d :111 nil. -mcl I 1'.~ '. .,.,I ~V'ln Inman Floff pve 14.4 (" Af I"a"'I "11 2 C I-11hilo"W i olv- b; ,I-, 41c ki III X.- the , f"e, ar.1" an IA2 3' 'I" wall In MI I If If file is mn in C". the v,dd L, much lowet and flit I-CJ1,C0 pre,lonunji" I p.mfml by an IN unati,riv purifi-1, ,1 1111 5' 1 "-r. an 14&-A' I with N.ItCl yields ra-1. an~ hwb. la~ttrcf with Mir "M in. - the : 111) astraloar. an 24#11 1 , flak. an 1b. to ,I,- I'v Fintl fill If '14 1, - I (-1 411 tr.," Fr, III k1ernmeraw" "'b" I-. ~ H, I "'-f o" -~' h- c-'- : , rt, IM 7' 1- aiq VtOlf, A., I'v : -"j" 4.1 Wit ...... I h, IL 11.4" ~ mA."j t" L,I-. ."I, I I If far L It.... -fuel.., K." 'th'-l 4-1 ~ki 4 * Or"m ..I Fl. .11 1 ..... i" 'h' Z %f~ '."Iog gave " mr(ko"I .-d ,, %I I Wellusing rith" rva -ith A,4)lf.lflfr Cave the .7410 -41, - I 1.10 t 7 f frmn F, ( -11 , St.. mian 4 ~!lt , ~14- %a-fig i~, 1 7'~ C %1,4 K ALOWHA'll'O Nil an 3n -1 h- r f I I I .4 liar ,It, . so 11 1, 10 1 '11, 11, , )I(1 W-1 mg 11) rVaill p- 11 C, I I ~.-. .". %,at. IIII 126 A" ...... I- all Vb, 1; -rhth,4 ~"SA 121 Z' -PAAvd'~.1" ail"t. I st'rall."'ar. 1-- FtI)fI jtO tie, A ill lirnwinit and offnecionk acids A~ V .d..Va atut XIA k ...... ",.& 1. 4 )OR11,41A kite All- lJohiidt, AW K 71. 31S 1 1W. " AS. adit hV41,11r-m -4 1,1:: Tplivitt- v WhI. an ut-l't 6, "1 . ..Ji,o W.. m A, !:,. at .1th Ill, sel- I ...... .-I " I-o its, It"Ir"Iyous of .4 .-Olum m fill, --1, tm,ma -Sms~ -ft, pla"o-ak, a-t %III (Ill hcAtil"fla ....d 1111. C.1144. I.M. 41 43 )..1 .. a *I.,.* file tIl.p 14W 11 t.k. up 2 It, YWLI- do", 1'. sal-'I .11h 1,01,; Itcl all- the CnIfesillssnilinj sskj"sif I.kj L4'. J,"tW*l 'Jill If* ledt'. ilit", tw-jucl frm, 111 11, ,, , It ApI.-Ar. I., Ill, a 'I. and 1 a trans tu"tirr 4 cove, ~tmoterr lim"al'Alwo "I III al CIR-1, go- ill, J, 14, d"', Ift, V. M m*, while if, an oil 11 A.- fit d.11, . of 11:1 13 lt.' 1.!" 0 tw-llull I It NO, lisi, ))I. i Nit .4 sj C./ho.. -.1 . Ilk 1'. of, "'. 1, in 114 V .[ot, 1,, 2-1.1 kt. A,% I,%, : "" rhm"t""I " 6 A, Olklacul I fill M.- Triblu., lyphal 4 01F CIA.. wnt, 1'.'s lia" are ammuclatly tt"I In 'Julask Acid lic-t., fill- -e m'sw fs~ lq~llt-j I,v et(hel 4 the 1- .... j_, If,( 11,0111, 11 w( ,, V,' 01.011 (pit) (11MOO 1.11, -Its .4 h.h -f ,( ~Awfvtllm.. '", .111101,11 1-1 1- -~fthfisll the rmy-t J,q ..... 14 A la ch. A %o 11di V. 1)311110VQ and R "on 'Td on kidze ATWnVo-ft-tfi-enCzPha - V-4f ft,,. fTO rmG !~Ijs!., Sjoscgw). Zhtir. Ubs, thri hisim. Z2, 2.N17-V(l952)-- (C[IIUI)7 ext. of 14 kg. -,f the maccratcd plaut previd. in Pric-qence of 10% N114011, votkLd tip %it t.te Lonveittiouml 0 t miumer. yielded a ruixturc -1 products, which, let stand in HtO solu., deposited 1.22 ) . new substance, named pInn- log"ine. CqH,,0,N, m. 21 ~ -20*, 1.1 o 30.9*; It CI jalt, de- 170111p. VS-30*; Itratc, fit 159-60* (from 11,0)-. Chfora. aurntt, ni. 151-2 t; nirlboxi-Ve, 5ulid which is dillicult to purify. The liquid rrsidue 1 itified by steam di%tn. and the distillate treated iCith picric & cid gave a picrale ro. 140-50' And n pirrate tit. 1*-',1-7* (fro it litOll, then 'rout RtOAc). - The Ist piernte, in. 151- 3 on f irtlicr purification, YiCldvd an alkaloid, Cjs[1,10N, uainvd in-licaine; the hiftc, picrnte(m. 127-9* after purification), g;t,c an alkaloid named indic- amint. C,4[f?,ON, which is au unsaid. substance. Both lattvr alkaloid% are liquidi C.. M. KosolapofT DANILOVAt &,~'niigv; w AT. .48.691a. H. Lal.~ C,jedcal Abst Vol. 48 Not 9 u-., -in 10ri. 1% 1. USSR/Chemistry - Alkaloids Aug 53 "Investigation of Alkaloids of Senecio Species. Vill. Alkaloids from Groundsel (Senecio sarracenius) A. DanilovEi,- R. Konovalova r P. Massagetov, and ~M. Garina, All-Union Sci-Res Chemicopharm Inst im. S. Ordzhonik!.dze Zhur Obshcn Khim, Vcl 23, No 8, pp 1417-1421 Isolated two new alkaloids, sarracine Cl&H27 0 5N and sarracine N-oxide C,5k7 06N, from a groundsel (Senecio sarracenius). Sarracine picrate and bitar- trate were obtained as well az the picrate and chloroaurate of sarracine If-oxide. 270r32 117' USSR/Chemistry - Alkaloids Sep 53 "Investigation of Alkaloids of the Senecio Species. IX. Structure of Alkaloids from Senecia sarrace- nius," A. Danilova and'A. Kuzovkov-j All-Union Scl- ReBearch Chemo-Pharmaceutical Inst im S. Ordzhoni- kidze, Moscow Zhur Obshch Xhim, Vol 23, No 9, pp 1597-1600 It was established that the new alkaloids sar- racine and N-oxide of sarracine, isolated from Senecio 6arracenius, are diesters of the amino- glycol platinecine with cis- Q* -dimethylacrylic 26BT35 (angelic) acid and an unsaturated acid with the composition C H80 , designated sarrac1nic acid. The latter aced ;L the carbon frame of methyl- etbyl-acetic acid, differing from it by the pres- ence of a hydroxy-group and a double bond. 268T35 DANILOVA, A. V. froall Seved. SarTacenius T7, Chemical Abstracts 1 N -Y 2 5, 1954 O l Ch i t e em rgan s ry ...... flu Iilfl~ M w, ill% 11"It'll KI fillk k;lfi it ~, 1 2 ' . ,: Ill td, ., jell t if ~ 11, gI t p4;! vv. , , n , )t)t ~j tilrij varber ir:,f t fit' It I I In.) I q. r,f plat , 1,11 , !! Im f tile III, .' rv - I '! it ml t he 1,1, . ill & It I pi -I im 1".'r i,irit h N I I ( ) II :I I, J)"'. ibk t. I'\ %It, In :Ilnl,.t ".-InrA Substanre, 1, N*. fit I Irma Nf(!,Cf )) , ~' I - "1 6' (p,[, 1" .1 1107 5 .4 .1 1-hl-iiju,41r, Ill I !~f h " , Rv. Ill, t I'm if t h I it It 7 , lhi,t ield ~ - rrucine This AkA. I"id 0111, appi, ,, t.- It, V .,xi,fe of j,j,rj. live. Thi, t, un- , firilit of b, if, forrij,ti-i fr,aii -run ill, with 11,0, Nt ,7~~ 1Y 1.4 6) V4, h, / pERSHIN, G.N.; FAIST-sKATA, Te.N.; DANILOVA, A.V.: MIWVANOVA. S.N. Chemotherapeutic effect of deachlorobiomarcln. Farm. i toks. 17 no.5:3-0 IS4. (KLRA 7:11) 1. Vseaoyuznyy nauchno-iseledovatellakly khtmiko-farmataevticheakiy institut imeni S.Ordshonikidae. (ANTIBIOTICSO deschlorobiomycin HC1. phamacol.) mlqjpp~w- 4gaw. t tic CIFOMi k tw Om"ge Lat. sm- abod 26 gi WIMA 4, aw 1-14 xi Am- *"dim, w" a talmi; am clicksa.- fts** Of w 2.70 X, t2a had$ WOW *od&udi* to kfgh. kh lisma g&" jr (st M. -.- "U0 sot a" MAWWOOL*w9a. in. 77 G. M. 77 Y v., m I AUTHORS: Koretskaya, N. T-; Dpnilova, 1. V.;-Vtkin, L. M. 19-2-58/~8 TITIEi Svnthesis of Harmine Derivrtives, Part 1. (Sintez nroizvodnyk~ germina. I.) PERIODICAL: Zhurnal Obshchey Khimii, 191;7, vol 2, No 2, pp. ~42-545 (U.S.S.R.) ABSTRACT: This report describes the s-nthesis of certain harmine derivatives for pharmacological investigation. The new harmine derivatives were identi- fied as rnd-N-(beta-diethylamino)-et~ylhprmine, dichlorohydrate; P~-R- chlor-(beta-diethylamino)-hamine ethylate, hydrochloride; Ind-N-benzyl- harmins; Py-N-iodomethylate Ind-N-b4-nzylharmine: Py-N-chloramethNIRte of Ind-N-benzy1harmine, et~,yl ether cf norharmine carboxylic acid. The authors obtained new derivatives of tetrahydroharmins, namely, Py-N-(beta- diethyl~Rmino)-ethyltatra~,ydrohamine; tetrahydronorharmine cbrboxylic acid. Card 1/2 T1,ere are 5 references, none of which are Slavic. V Synthesis or Harm'.ne Derivativos. Part 1. 79-2-58/58 ASSOCIATION All-Union Scient1fic Research Chemical Fharmaceutical Institute imeni S. Orrlzhonikidze PRESENM BY: SUBMITTED: March 18, 1956 AVAILABLE: Library of Con&-,ess Card 2/2 5 (3) &UTHORS: Danilovag_4~. V., Utkin, ko.zyreva, G. V. , Syrneva, Yu. I. TITLE. A New Alkaloid Which Is an Isomer of alkaloid, izonernyy platifillin~z) PERIOEICI,L: Zhurnal obohchey kh-imii, '959, Vol "., 7z, ?,'1`-'436 ('J'--l ADSTRACT; ?latyphyllin bitartrate is irep~.Y~!d fr,)j,,l '.I:e lrov!le,ived .-,enecio platyphyllus. As to it3 chemical structure the is i~ diester of platyriecin and the ~;e:.eciiic ici~ ('-.of In the procesoirio of the industrially manufactured -ilcoholic .:.other liquids a new base which ha~ been call:~,*. neoplat.y:k-11in was obtained on separation :ind recrystalli-ation of pl-,typhyllin bitartrate. As to composition :nd functional c~roups, this new brize is identical with i ,~latyphyliin. P;ieir busicit- and infrared absorption spectra (Fi , sh;~w little differ-2nce, 'out as far as the physical properties are concerned, the ceo7-latyphyllln and its salts differ from platyphyllin ind ito salts. The bitzxtr---te of neoplatyphyllin shows well pronounced -,ho1iiolyt1c and spaomolytic properties. As to uctivity ...:~do if ictill it is closely related with platy-~*llin, but it is ~WiCL :13 toxic. Card 1/3 Alkaline and acid hydrolysis of both co;-.-,-)u..~-" yicl-i V-t- !"L.e A New Alkaloid which Is an Isomer of Platyphyll'in, ~)7/79- 7) -7-7 2/87 products. The authors assume t~-~t the t:iffere..c2 ~,et-veen both bases is due to thu steric co.~,Ii,-ar.jti -~ !)', ,)-e acil cemiponeat of their molecules because, s in '-.nown, 1.1!e ":-,ecinic- acids ~-:ith double bonds show in addition to the OT~tiC-! i30MaCJ-SM also the geometrical one (Ref 2). The structure of the -ez:ecinic acid corresponds with the formula (1) (`Ief 3). lzi ,.--.er to investigate further the properti6s of both compoundc t,.e -!!.-uloids were reduced vith LiA111,. The result--Lrt trivale.-.*. --c-ohols had to possess structure II), accordiLIg to the stra~.:'-ire of the senecinic acid. The chemical and 3pectroocopic re-ults obtained confirm the asnumption of the authors that t,e different spatial configuration of the esterifying acids ic the cause of the difference between neoplatypl-.yllin and clut.",%hyllin. The formation of a trivalent alcohol from the senecinic aci-.1, by treating it vrith alkali liquor, which is q 'uaiit-tivel~i -'ifferent from the alcohols obtained by di,-ect reduction if the -lkaloids, confirms the observation th t the "necinic" acids so -ir -ted bl- alkaline h,-drolyvis of the alkaloids of the speci-~~f- -enecio - osoess a configuration which differc frr,,:: that in enter into Card 2/3 the composition of the aikal-,id :~,.oleculeF:. ':`here -re I figure I A Now Alkaloid Which is an Isomer of Flatyphyllin and 3 references, 2 of which are Soviet. ASSOCIATION: Vsesoyuznyy nauchno-is.,ledovatellskiy ',Lhi,:,.ik;D-far,.aatsevtiihesk.y institut imeni S. Ordzhonikidze (All-1,Tni-)n --'oientific Chemico,pharmaceutical Research Institute imeni :~. Ordzhonikidze) SUBMITTED: Llay 25, 1958 Card 3/3 A J 1, 11 J 1). L V X PITLE A 1,,.,i I M., Afl.'J"MV-r Th- I I I c f.- N 1- M Alkai- !.A M-L H :H7 A cm, C'j C(CHII co Placrunecine 41 nakro:Ic-t~;yit) (:LL; z I t an I --utl " ! i, ,-. I " - by hydruly,~:1~3 -v, I w t. wil~-,h `iavo v t wt,ve Ale-al-id (a colorle8L; liqiAd, a D (mP (,mp mucrophyllii,t, pl,:i,at- r,ip -c-) j2 - 2 ~4 (-) ) .Tht,-v- I Clerman, 1 U.K., I U.:'. Dit'- a-A U.K. ref-.-ence~3 ave: Adams, Hamlin, J . Am. S -15 7 (P)42 C,-~Iveri,).,, L. W. Smlt:., A4.;tral. J. lil~lm. ic), U4 (ic-7). ASSOCIATIONt S. OrdmorilkidZe Al L-Unlort S.~It-i,tll',--Research ~: i j~- rn I ca Pharmace.itleal Iri~~l It-ite (vJ "y y nau c h n Issledovatel Iskly In,stitut linerii S. S U BM iTT ED: D--,~ember ~~j, C,ird 3/3 DARILOVA,._A.T.; KOIWSKATA. N.1.; SHVICTS, Z.I., UTKTN. L.M. Few method for obtaining platyphylline from Senecic platyphyllus. Had.prom. 14 no.4:2&30 Ap 060. (NM 13:6) 1. Teesoynan" nauchno-iseledovatel'skiy khimiko-farmtsayti- cheskiy institut Imeni S. Ordzhonikidze. (PLATTPHMIXI) DANILOVA, A.V.; KORETSKAYA, N.I.; UTKIN, L.M. Structure of "renardin" alkaloid (from Senecio renardi). '?art 2. Zhur. ob. khim. 31 no. 1-1:3815-3818 N 161. 6-M~A 1-4: 1-1) 1. Vsesoyuznyy nauchno-isaledovatellskiy khi-miko-farmatsevticheakiy institut imeni S. Ordzhonikidze. (Alkaloids) EC) 3 Z/ E3 14 AUTHO-US Garik"yanov, N.S., Danilova, A.V. and Sha-idullin, R.R. TITLE: Electron paramaZnetic resonance ancl a.)sorption spectra in the visible reZion of alcohol In(, .1ycerin solutions of Ti*++ PE:',I3DICAL: Optilm i spektros"'Zopiya' V. ~' 11c). 212 - 215 TZXT: A study-is reported of CFR Lines of rlie ~;recn and violet modificatioiLs of TiCl H 0 solutions. ~-Ivcerj.n ai.d a'Psolute alcohols ~methyl, eLYT" and isoprop)-l)-wore kiFed as t1le solvents, The lipecimens were rapidly in thin Z;Iass capillaries since alcohol solutioiis of Ti salts were fouiicl t'o be unstable and oxidized to Ti"~~. -Ieasure:-.:e:its were c~%ri'ie~! out at 9320 'MC/s using tae standard raclios )ectrometer 77 0 -1301 (RE-1301) at 400, 295 and K. T'-, eline widta doter-mined as ti-ie distance between the maxim-,Li Xn,! minim"I~m of the fir3t ~,Qrivative of the absorption curve. T*,ie results of line- .;idt:-i measurements and the spectroscopic splittin~r factor at Card 1/5 5/0~1/62/01~-) / 0 02/0071VC14 Electron paramacLnetic .... E032/E-114 T = 205 OK are -iven in Table 1. T:,,e in-eisitv )f *,,,,a EP-Z lines ~r. liquid violet glycerin and alcohol solutions, is vorv low Co.m:-,ared with t:ie intensity due to _-reen ~;lyceriu solutions. It is therefore considered that the EPR I.Lnes of \riolet solutions are e.-cclusively due to a sniail amiowit of ~;recn asymmetric complexes of the form: 7+. Ti(CH 011) C1 Ti(C,11 o1'.) Cl, 3 4 2-~ , -LT'C:2'l~-'0'1)4C12-". '; 1~ 74 and Ti_C H (OH)-! cl')~ 1 3 5 -)- lk In supercooled alcohol and glycerin violet soluti,,ns of' Ti t. e c e ~Qs is a large low-symmetry f i e.Lci co;-,i,)c)n eiit clue ~ o ),11-t c ,:ie s econd coordination sphere ( the ciot ion is f rozei) a r, -C i.-3 reason, in t.he super-cooled state each parana3netic Ti i on in violet molutions contributes to the intonsity of tj-,e EPR jj;-jps. At room temperature, on the other hand, owing to the lonL~ apin lattice relaxation time, Ti+~ , does not --;-;~Lnificantly to t'ie intensity of the EPR lines. As t:ie roj:-.i toz.,,:)c-~-ature ;.6 Card 2/5 E.',~ctron r c, L~ 14 -L*,;zic:i oul t !ic comp,,mjit c) V I ow-s rmiict i-,,, c " oco 4- 7 i ion tends to avera_-e out and e1ectron -A'o-s3r-3tion is eiitirely daie to Zr(,e., -3 w rJ 0 0. !).is be(-ji LiscLl to L:-- :,c It ~X-c of Lreen coi;iplc,~es in violet soiki~ i, - z,,:i ~1~1 L Ii U r e - I t;ic Solveat, all' t:-1(- ;I;Its are ziverl i;L was t.,.en chec'ezed by carryi.-,~; 0;.~ ,,ta3 foLini~ t:iat the abrorption in t:10 V.1 f; i 1) 1 L;.re iii ~,ood . greet~.ient with t:ic al)ov(,, lntei-drotat 1,)!l of L:IL, EPR s,?ectra. Taere are 2 tables. S'~B\il'17ED: June 9, 1961 ,- ard 3/5 r,-).i par a ....... .... To 1, it, I 13 %111 T I I AbNI C I J I Ir V u: 3 Z3 2 (Y. 10TO IW !taCT 111) 11 :1 11 if j1TV 21 10'; 11 It Oll 4.1 11-11VA.1 jl~,CTROl will." 1; 21 Card 5/5 0.5 12 ~2 i.A-12 DANILOVAY A.Y.; KORETSKAYA, N.I.; UTKIN, L.M. New alkaloid from Senecio othonnae M.B. Zhur.ob.khIm. 32 no.2:647-648 F 162. (1,111](A 15:2) 1. Vsesoyuznyy nauchno-issledovatellskiy khimiko-farmatsev- ticheskiy institut imeni S.Ordzhonikidze. (Alkaloids) KORETSKAIA, N.I.; DANI-LOVAY A.V.-;-,- UTKIN, L.M. S',ructure of jaconecic and jacolinecle acids. Zhur.w.khim. 32 no.4:1339-1345 Ap 162. (MIRA 15:4) 1. Vsesoyuznyy nauchno-issladovatel'skii khimiko-farmatsevtickieskiy irstitut imeni S.Ordzhonikidje. (Jaconecic acld) GAFLIFIYANOVO H.S.j DANILOVA, A.V.; sHAGIDULLIN, K.R. Zlectron paramagnetic resOfmce and absorption spectra in the visible region in alcoholic wd glycerine solutions of Ti"'. Opt.i spektr. 13 no.2-.212-215 Ag 162. OUM 15:11) (Piramagnetic resonance and relaxation) (Titanium,--Spectra) KCRETSKAYA,, II.I.; DANTILOVA, A.V.; UTKIN, L.M. Structure and interralation between senecic and epoxyjaconecic acids. Zhur.ob.khim, 32 no.11:3823-3827 PI 162: ;',141RA 15:11) 1. Vsesoyuznyf nauchno-issledovatellskly kl-,'-Miko- fw-matse,srtichoskiy iimtit-ut imeni '. Urdshonikidze. 0 (Scnecic acid) (Jaconecic acid) Of I PCV, DANILOVA, A.V.; KOPETSKAYA, N.J. Structure and propertles of senec~phylllnr-- --'. 35 no.3.584-5R? Mr '65. 18 4" 1. Vaesoyuznyy nmuchnn-"Rsled(-,va~.elli;t:,v "hrmn* sf;vti~,.heskly Institut imen,' 3. ge posw ~Jume,,W>ck 15 ~7 D HL