SCIENTIFIC ABSTRACT MIKHAYLOV, B. B. - MIKHAYLOV, B. M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001034010001-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 13, 2001
• Sequence Number: 1
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT


MIKKALMV, B.__P.. ZHERDEVA, L. G.. KARASEVA, A. A.. VOMESERSKAYA. &. V..
ALTSHULER. A. E.. KROL, B. B.. OROCKO. D. I.. AKIMOV, V. S.. AGMIXV. A. V. .
DRUMININA, A. V.
"Producti,)n of Lubricating Oils and Paraffin from Sulfurous Oils
in the USSR.'
Report subvdttad at the Fifth World Petroleum Congress, 30 tUY -
5 June 1959. New York Cit:,.

/-4 Y Z- f V,
Category :USSR/Gonorrl Froblowis lrolol,---, of T,,rcliinr
Abs Jour tRof Zhur - Flzilcr~, No 1'57, i'bc -5`2,-~
Author t'~',ikhcylov, B.G.
Title :-Conco-r=ngTho Probl(m of th(-- Connuction 7"ct-.-,,- :i thc~ ILC Urs, -
in Physics nnd Chc~-,i.,~try in the Second- ry
Orig Pub iUch. znp. YolRbu!-hs!-. pod. in--tr-, 1-15', 1,
Abstract No obstract
Card 1/1

UL'IANOVv N.A.# kand.tekhn.nauk; MIKHAYIDV, B.I.
Performance of the elastic driving ~beel on hard-surface ground.
Avt. prom. no.5:25-27 My 160. (MIRA 14:3)
1. Sibirskiy avtodorozhnyy institut.
(Automobiles-Wheels-Testing)

- MIKHAY-WV, B.I., inzh.; ULIYAKOV, N.A., kand.tekhn.nauk
Automatic adjuBtment of motor grader operat4one. Stroi.i dor.
maeftinostr. 5 no.7:6-7 Jl 16o. (MIRA 13:7)
(Automatic control)
(Graders (yerthmoving michinery))

2b241 61/000/008/008/008
S/11
D215YD302
.HORN Mikhaylov, B.I.
TITLE.* Transistor anemometer
PERIODICAL3 Priboroetroyeniye, no 8- 1961, 27 - 28
TEXT: This paper describes the construction, operation and appli-
cation of a portable transistor anemometer designed for use in
research and scientific work, The instrument Is capable of measur-
ing the velocities of gases ranging from 1 cm/sec to several tens
of meters per second, In the working temperature range of 00 to
600C the performance is stable, and the error does not exceed ? %.
The instrument is driven from a battery. The power consumption is
0 12 watts. The unit is connected to a measuring fori; by means of
a flexible tube. The fork consists of a tubular root with a trans-
mitter at one end and a handle at the other. The transmitter is
electrically connected to the electronic unit by means of 3 con-
ductors, two of them being screened and the screen itself acting
as the fourth conductor- The circuit diagram is shown in Fig. 2-
Card 1/3

Transistor anemometer ...
X2,41 61/000/006/008/008
~;/.i I
D215YD302
Tba transmitter consists of a bridge energized by a sinusoidal os-
ciltAtor- T and T are electrically identical sundry elements lo-
cated in pWnted h9.1low heads, The working transmitter head T1 has
two openings OP',7 mm in diameter, located on the axis of symmetry.
The diameter of the openings is increased if air velocities ex-
ceed 6 m/sec.. The resistance of the thermistors depends on the ve-
locity of medium and their temperature difference T2 is an am-
blent temperature compensating thermistor, The Abalance signal Is
amplified and the output current, proportional to the velocity of
gas passes through an indicator (50 ILA f.s.d.)~ T3is a correcting
thermistor. k6 is a balancing potentiometer. The amplifier is tem-
perature stabilized by means of a.c. and d.c, negative feedbacks,
The power supply is 6 volts. The compensating capacitor C5 (560
pF) is used only if the bridge cannot be balanced. There are 2 fi-
gures.,
Card 2/3

62/000/001/005/011
D201YD302
AUTHOR: Mikhaylo v, B.I.
TITLE: A shunt temperature compensated t),ermi5tor t).C-rmorlut
PERIODICAL: Priborostroyeniye, no. 1, 1962, 19 - 20
TEXT: The author gives a short analysis of the. mf2tl,ol of de.Sicn
and the characteristics of a shunt compensated thermistor therro,..----
ter for remote measurement of the temperature ranCe - 22 to + 550C
� 1 % (practically independent of temperature), siraultaneo~;sl y ~'. t
9 control points. The circuit (Fig. 1b) employs resi&tors 1',,' CIL;)
having a negative temperature coefficient of approximately 0.0007.
The temperature compensating shunt is connected across the ralvan~---
meter. It consists of resistors R 1 and R2 and a thermistor T. Part
of the current flows in the shunt and if at a constant si,;-,nal the
current changes owing to a change in the ambient, the shun. will
compensate this current V;Lriation, the current flowine thro ;Ch the
galvanometer will remain constant And depend only on the value of
the signal. The galvanometer, the shunt and the circuit of the sen-
Card 1/2

0
,/11 62/000/001/'(5/011
A shunt temperature_, D201YD"'02
sing element form a brid,,,c ind tkio io adji,:-tcl so Uiut the :~('ro le-
flection corresponds to - 220C and max. deflection t~) + 85'0c, which
means that the value of R 1 is equal to the resistance of th-
mistor at - 22 0. The sensing element consiqts of a M(-Ii v-Llue
(4.56 kilo ohms) thermal resiatunce type MIT. BeCaLISC of ,, 1-.rl,,e
C 'I ev r ry
.3-read in thermal r03i3tance an] tliermistor ch.,racteristj , ,
'.rument has to be individually calibrated. There, -ire 4 f ij-',Zrt
1 b.
0
I T)If
r1 FN
Card 212

MIMILOV#-B.11
Inertialess electric speedometer. Priborostroanis no.4.29-20
Ap '62. (KIM 1514)
(Speedometers)

NIKITINAv Awffr M-SMISTAN, G.S.; MIKWLOV, B.M.;
KMHMOVAP L.re. WANNOWM
Fluorescence of solutiora or certain substituted polyemlis.
Opt. I spektr. 14 no.5-x655-"3 My 163. (MM l6s6)
(Unsaturated compounds--Spectra)

XIKHATLOV B.M. konstruktor-, KOLOIAIYER, M.G.. konatruktor.
_'11
New small-sized roller. Avt.dor. 19 no.1:24-25 Ja 156.(MLaA 9:5)
Pollers (Xarthwork))

MIKHAYLOI, B.M.
Role of vegetatIve ~,-ver ~r, lwc-ru, weatr.erlrig j,, t~,e mmmta:in
ri-gir,ri,,i of the Liber.'ar Shlell. r)c)kl. All SSSh 157 no-4056-858
Ag 164 WIRA 170)
1. ay,,adumlkoin StraAh-,~-ym.

BOYTSOVA, Ye.P.; KILZINA. Te.A.; MIMYLOT. B.M.; OTWHKIY. U.K.;
r
ROSSOYA. S.M., redaktor; GMW.-~....~0VOIdmichaskikly redaktor.
Deology of the southwestorn region of the Turgay Gates]
Geologita, tugo- zapadnot chant i 'Turgat skago progiva. Moskva. Goo.
nauchno-takha. Izd-vo lit-ry Ip geologil i okhrane nedr. 1955.
154 p. (Leningrad. Vassolusayl goologichemkil inatitut. Trudy,
Vol. 5). (XLBA 9:5)
(Targay Gates--Geology. Stratigraphic)

HIKUAYLO'I, B.M.
M ~,
Determining indices of refraction of clay fractions of rocks by
means of the Pedorov stage. Inform.abor.VSMI no.2-68-71 '55.
(MA 9: 11)
(Refractive index)
(Clay--OptIc%1 properties)

MI XHLYLOV, - B. K. ---
Remats of staining mixtures of clayey minerals with vetbylsue blue.
Informi.abor.763GII no.2:71-76 '55. (IM" 9:11)
(Methylene blue) (Clay)

MIKHATLOV, B.H.
I
Noutmorilloulte frou varsigated lower Orst&:sous deposits of Klya
Valley In Western Siberia. Uch.x&p.L~n.un no.188:106-116 '35.
(Kiya Valley-Koutmorillonite)
(KJA 9:8)

" -, - - ~ 1 - , II ;- ~- -" , ! , , $ r ~
MIKHATIQL.J~ -
Menem.ogical and petrographical characteristics of clay formations
of the upper Cretaceous and Faleocene In a section -f the Pokurskayn
key well in Western Siberia. Mat. VSEGBI Litol. no.1:77-91 156.
(MIRA 11:2)
(Khanty-Mansiyok National Territory-Clay)

14IKHATWT. B.M.
--l. 1-1 - ~]kiect of absorbed cations on the color of suspensions of clays of
different mineralogical composition, stained with mathjrlene blue.
Hat. VMZ1 Litol. no.1-159-161 156. (MIRA 11:2)
(Clay) (Cations)

f
A13UKHTIN. N.1.: BOGRATSOVA. T.E.; BUCH, 6.-J. G.S.;
GOIMMVA, L.Y.; :~OMOV, V.I.~
NIKLYOROVA. K.V.; NIKOLAYAV, N.I.; ?00t~VSXAYA. I.M.; ?My. T.Y.:
PROTS, R.N.; HAVSKIY, E.I.; SnAIJT~'t;R. Ye.V.-. XPSHTM. 5.V.;
YAKOVL19VA, S.V.; FEOD(YT'YEV, K.K., rfid-jktor izdatelletva; KASHIMA,
P.S.. teirhnicheek-iy redhk-tor
[Concise field manual for a comprehensive geological survey of the
Quaternary] Kratkoe polevoe rukovod8tvc po kompleksnoi geologiche-
skoi 9"emke chetvertichnykh otlozhenli. Sost. N.I.Apukhtin i ir.
Moskva, 1957. 201 p. (WLRA 10:9)
1. ALwdemiya nauk SSSR. Geologicheakty tnetitut. 2. Morkovelcty
geologo-razvedochnyy institut (for Shantser). 3o Geologicheakiy
Institut Mmdemli nauk SSSR (for Ntkiforove, Ravskty, Golubeve)
3. Veeooyuznyy Nauchno-issledovatel'shy geologicheskiy institut
Kintaterstva geologii i okhrany nedr SSSR (for Geneshin, Bogretsova.
Mikheylov). 4. Voyerino-Inwhenerneye akademiye im. KuWbysheve (for
Pooov). 5. Trest "Hoageolnerid" (for Prints). 6. Severo-Zapednoye
goologicheakoye upravleniye (for ADukhtin)
(Geology, Stratigraphid

VIKUWVA, H.F.; ZVYAGIII. B.B.; -,BZRLIN. T.S.; OMSHNIKOVA.
Ye.I.; SHAKHOVA. R.A.; IYANOVA. I.I.; TATARINOV. P.M., prof.. red.;
GICYSIAR, A.U., prof.red.; DOHINIKOVSXIY. V-11.. kand.geolngo-
minerelogicheakikh aauk. red.; KNIPOVICH. Yu.N.. kand. geologo-
minerelogicheakikh nauk; SKUROY. A.A.. kand. goologo-minarnlogiche-
skikh neuk; FRANK-KAMENCTSKIY, V.A., kand. geologo-minerelogiche-
skikh nauk; BABINTaRV, II.I., red.izd-va; KRYNOCHKINA, K.V.. takhn.red.
(A methods manual on the petrographic and mineralogical study of clays]
Metodicheekoe rukovodstvo po petrografo-mineralovic-hoalroau izu.cheniiu
glin; trudy Institute. Soot. kollektivom evtorov pod rukovudstvoc N.Y.
Vikulovoi. Moskva, Go3. nauchno-tekhn. izd-vo lit-r7 oo geol. I
okhrane nedr, 1957. 447 P. (MIRA 11:2)
1. leringrad. Veesovuznyy goolopicheakiy institut. 2. Chien-
korrespondent Ali SSSR (for Tatarinov)
(Clay)

MIMYLOV, B.H.
Indirect determination of the iron content in loose oolitic
ores. Razved. I okh.nedr 24 no.10:23-25 0 '58.
(14I]RA 12:2)
1. Vseeoyuznyy goologicheakiy nauchno-teeledovatellakly inatitut.
(0011te) (Iron)

MIKHAYLOV, B.M.
Determininfr theidanger of silicosis from fine dispersea rocia.
Inform.sbor. VSEGEI no.16:143-148 '59. (MIRA 1~j;3)
(LUNGS--DUST DISEASES)

HIKHAYLOV, B.M.
Methods and problem of lithdfacies mapping in closed
areas. Trudy VSECEI 72:21-27 162. (KM 15:9)
(Geology--Mapa)

MIKHAYLOV, B.M.
Lithofacies maps in geolog-cal surveying of closed areae.
Sov. geol. 6 no.7:136-140 J1 163. (MIRA 16:8)
1. Vaesoyuzny-y nauchno-iseledovatellskly geologicheakiy
institut.

L 69u_66 ciT(N)/EUP(k)/IUA(*)/T/rAP(b)/Ce(,r)/DiP(t) IJP(s) JD/M'f
M=SION %Mt AIPS000060 0102661641000/023JO068100"
AUTHMs GISIFUMM, S. 0.1 amsd4va L. A I Iblasy",I it
... ...... KftGTSWS-A I I MMYLOW, 3'. 14.
"!, I ------------- T"
TITUI Filler Material for V114182 eltesim alloys with a high Contest ;I
came 49, we. 166221
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MMON By". Igobf. A tower. makew. so. 31. 1964. 64
TWIC TAM titsaim. titesim alley. beta titsolum alley. voldiss. filler vice.
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"STUM Me AutIWW Certificate iotgo"460 a t1tasimb-teds ISUOV alley for
Vou"a Citemium alloys with a kidl Coateme of i ohm . I* 66M the 1"I Mae-
able fair mW such titudom allsp mW to impowe do Onzality *I do vaU =44,
the filler alley cutalm Im-41 U mA 6-M No*
sommus mem OW 00 9n 0=4 IN. 19
On An m=s 3146

.ER-SAf,,K.-SYAN,
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-ac:*Iicr of

L 3loo4-66 IJP(c) JDfJG--
AM MKI AP6007782 ',()IIRCF rol)E: UR/0136/66/000/002/0080/0082
AUTHOR: Moiseyev, V. N.- Glazunov, s. r:.; Mikhaylov, B. M.
ORG: none
TITLE: High strength titanium Oloys
SOURCE: Tavetnyye metally, no. 2, 1966, 80-82
TOPIC TAGS: titanium alloy, alui-Lnum containing alloy, molybdenum containing alloy,
vanadium containing alloy, chromium containing alloy, iron containing alloy, alloy
mechanical property, alloy heat treatment, high strength alloy
ABSTRACT: A serie%lof high strength titanium alloys containing up to 302 molybdenuLn
up to 6% aluminumlind small amounts of iron, chromium, and vanadium have been de-
veloped. ITT-o-y'Tn-gots weighting up to 6 kg were melted in a vacuum arc furnace and
rolled into sheets 1.2 mm thick. Sheet specimens were annealed at 800C for 30 min,
furnace cooled at a rate of 2-3 C/min, annealed at 750, 800, or 850C for 15 min,
water quenched.and aged at 450-500C for 4-16 hr. It was found that alloys contain-
ing 8-10% molybdenum had the highest strength, 150 kg/mm2; additions of up to 41
aluminum caused a further increase of tensile strength up to 160 kg/MM2. Further in-
creases in strength can be obtained by alloying with 1% Iron, 1% chromium, and 2-52
vanadium, which strengthen both the a- and 0-phases. Seven such alloys were melted,
cast into ingots weighing up to 40 Kg, which were forged into 80 x 80 mm billets at
Card ____112 ___ - UDC;_ 069.295:620.18

L _J!004-~~_
ACC NRs AP6007782
1050-850C, and then into bars 12 or 22 mm in diameter at 950-750C. These alloys
were tested in the fully annealed or heat-treated (annealed, quenched, and aged)
cond4tions. Annealing at 800-850C for 30 min followed by furnace cooling at a rate
of 2-4 C/min ensured a relatively high tensile strength, 105-125 kF
,/mM2, at an
elongatton of 1&-21% and a reduction of area of 45-632. Annealing at 800-860C
followed by aging at 450-500C increased the strength to 160-170 kg/MM2 and lowered
the elongation to 4-92 and the reduction of area to 20-31%. Annealing at 720-800C
and alging at 450-550C produced a strength of 148-155 kg/mm2, an elongation of 6-12
and a reduction of area of 32-502. It is concluded that at+6 alloys containing adei-
tional alloying elements can be strengthened to a high level by annealing and aging.
However, prior to heat treakwent they should be subjected to intensive plastic defor-
mation at temperatures of the a+6 region. Orig. art. has: 2 figures and 3 tables.
(AZI
SUB CODE: 110 13/ SUBM DATE: none/ ATD PRESS:tf
Card 2 / 2

L 29950-66 -.WP(k )/EWT(m)/1/E-NPLw)/E_Y_'_PAt )ZET IIJP(c) -
JD 1W
ACC NRs AP6017298 (A) SOURCE CODE: UR/0136/66/000/005/0080/0082
AUTHOR:
Glazunov, S. G.; Moiseyev, V. N.; Mikhayluv, B. M.
ORG: none
TITLE: Heat-resistant titanium-clad titanium alloys
SOURCE: Tsvetnyye metally, no. 5, 1966, 80-82
TOPIC TAGS: titaniu all 1, alloy cladding. titanium clad alloy, allo property
in
Y
ABSTRACT: Heat-resistant titanium alloys are suscept4ble to craLekinp during hot and
warm rolling due to t sufficient plasticity of he metal a- roiling temperatures.
An attempt has been mhaed to improve the plasticityl y claddigk1rot1h unalloyed titan-
t
ium. Two alloys, OT4-2~6.5Z aluminum,-f-..W -manganeseT -and an imported alloy
(8% aluminum, IX molybdenum, 12 vanadium) were clad KI pack rolling. Cladding made
it possible to lower the temper ure of heat rollin 'to 1050C, which considerably
reduced the effect of oxidationtinal rolling to a thickness of 2 MM was done at
750-550C. Cladding was found to lower somewhat the tensile and yield strengths but
to increase the ductility. For example: clad OT4-2 alloy sheets had a yield strength
of 88.8-91.2 kg/mm2, a tensile strength of 95.0- ~'7.3 kg/mm2 and an elongation of
22.5-24.5% compared to 93.4-95.6 kg/mmZ. 103.7-105.5 kg/mm2, and 12.8-14.6 for
unclad sheets. As the test temperature was increased, the difference became less
pronounced. The ductility of unclad specimens was greatly reduced when sheets were
Card

L 29950-66
ACC NRo AP6017298
exposed to temperatures of 400-500C for 100 hr, while the ductility of clad speci-
mens remained almost unaffected. Cladding also greatly improved the formability and
weldability of both alloys. No separation of cladding from the base material was
observed during any of the tests. Orig. art. has: 3 tablos and 2 figures. (FHI
SUB CODE: 11, 13/ SUBM DATE., none/ ATD PRESS.,
Crd 2/2

L 23000-W-' - KW(z)1WFhWtft-Mt) Ii W JD/JG
ACC W157AP6012144:
souflcz.conz:.uR/ohi3/66/000/COT#10060/0060
-ninmr
4 Moiseyevi-V. I.; Glasuilow, S. G.; MMayl9j. D.-H Metelkin.-Y. To
ORG: none
a sAs 40, No. 180351
TITLE:. A. titant-base alloy. CI
SOURCE: Izebreteniya, proqrshlennyye obraztsy, tovarrWe znaki, no. 7, 1966, 6o
1-7 1-7
TOPIC TAGS: titanium s~-Icyq AumiauzL containing alloy, moLybdenum containing alloys
vanadium containing alloy, qkrLndum contal3lig alloy, iron containing alloy
-1-1 1-7 V)
ABSTRACT: This,Author Certificate introduces a titanium-beae alloy containing
aluminum, molybdenm* . vanadium, and chromium. To improve the mechanical amarties
the alloy has the following chemical comyosition: 2-6% aluninva, 6.9% molybdenum,
1-3% vanadium, 0.5-.-.-2% chromium, 0-5% iron, and the rest titaniua.
061
SO: COM U/ SuBm U". an65/ ATD PRE

M-M~MMIA
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ab DOU-00 Kei4 1~ 11 1 )1 F `-'J
AR6016287 SOURCE CODEs UR/0269/66/000/001/0046/00461
ALITHORS s Sidorov, V. V. ; Andrianov, Y. S. Mikha6ylov, B. K. 1 Poicrovskly,_ 0. B
Smolyakov, B. P.
TITLEi Combined meteor station KG-U-W~~'
SOURCEs Ref. zh. Astronomiya, Abe. 1.51-374
REF SOURCEt Sb. Meteorn. raoprostr. radiovoln. No. 2. Kazan', Kazansk. un-t, 1964,
3-19
TOPIC TAGS: meteor observation, meteor tracking, radio echo, upper atmosphere
ABSTRACT: 1, general discussion of the combined meteor station KGU-M2 developed at
the Radio Lstronomical Problems Laboratory KGU (Problemnaya radicastrononicheakays.
iaborat~,ciya XGU) in pr%ented. The station is intended for studying the properties.
,:,.'L tha upper atmosph9re y radio reflections from meteor tracks, the phynics of
meteoric ionization, and some problems of meteor astronoaq. The main consideration is
given to a description and analysis of noise prevention and station operation
synchronization devices. Recommendations for its further improvement are given.
Resume' ITranslation of abetrao!7
SUB CODEt 03
Cord _V I ---
UDCi__523-164.e~

L 46881-M
EWT -16 -6TO 0 6 to 0 1
ACC NRi AR0162ea SOURCE CODEs UR/02249 /00-46/00467
AUTHOR: Mikha
ylov. B. K.
TITLEs Indicator for recording the form of reflected pulses
SOURCE: Ref. zh. Aetronomiya, Abe. 1.51-377
REF SOUPCEt Sb. Meteorn. rasprostr. radiovoln. No. 2. Kazan', Kazansk. un-t, 1964,
53-56
TOPIC TAGSt meteor observation, meteor tracking, radio echo
ABSTRACT: A three-dimensional indicator is described. It permits recording of
reflected pulses in large scale with the simultaneous plotting of the amplitude-time
characteristics of the meteor 'echo. The causes of possible errors with the determina-
tion of distortions occu~~r-ing at reflection are considered. Abstract ZTranalation ofi
abstract7
SUB CODE: 03
Card 1/1 A- UDC, 523-164-6

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00 C A. 23. "S). The forlonatiom, of Identilvill glylvolso by hydratwo of an ozktt and toy
00
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and Chernowa, X. G. (p. 282)
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SO. journal, of Genflitd Chemistry (ZhiirrEl Obshchpi Kh1m.1i 1 1)-2, Vol 12, 'lc, 5-1~.

P.
"Synthesis of polycyclic compoundF. .-be-)--opyrenc." Ll. anJ
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the usmw. to VIM. dtw pomp is
CdKr Sam. am acdvmw GUMbs. 30%,
-1.840mmindmaw. M.
=6=
Aom. 191-2- then baLmm). a (QA
:V"pkrw
stugur (Irm 3.4 6. am) 60
WNW damw cl "emut=
cre"am"
ZA
dkid m. 17 4:
pcw- IN-6*
MA 9.) WKI PtUar-thm"am 2 g. fter) ve
25% al
(A) ((- b-.- t0H); fiffem. a. OWEN
StOH). n 0J.&Jjw g.
016=60ill); plat. m. 141-
MOM
I BI L A MTA&Lt�WOA UTMTWI CIAUVICATWO
~ a~2nlm
Ar do a, - - - ildi atil "fan
a
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eas
,&Oss 00004100,000W6004
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70

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- -
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4
06 to *A *: fol"Oftim
s *1 9: -
.
104sewhykathcoce". TbA
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f
bU ' -T 4a
O
OA
Cquedwity of ft" "W"
L

*0

00 0.~
alftykatknhomo Lac^ 'Oda&" withcrka &w "g
at IOV, to give 9 M
di(*i

gas
MLP, IB4--193-
R T -
do
!-so

doe
as*
100
44TA&C~AL L11940WO CL"WKSfOM
seem
Iffew bosp Of log foi4s, *ki 4.9 .1.
Mor It 4yr a if. 7 0 0 - I w a
S 'W 'a 11 low Ll
0 0 0 * Ce 0 0 0 0 0 0 0 0 0
8-0 0-0 0 0 0 0 00000000

III f MtelinAsm of
-9ijit Milt 0 X.
W elic 'Ier
cifl, o n.,I sitives of A!Ith,figne
le M~
so rum i
f -
II Hip. 'k.. u ""M
12d. tits lid. f.
A. 40, 47121-The formation of the metal dvrivs. was
as follows: tile hydrovarboo in a 1: 1 ouxt. of pure I
if[el and FtzO and a quantity of l;lass licud, were charged
left ', flit fl;6k ill a N fill:-. ;ibd %,ilh Sliced 1110:11;.
111'. cleAcd fl:iqk tvalt Mialcen ryn-)(m) br,i.. then it V-tubc
wris ittliched. tbomOl I lf-g if whil-11 WN was affilrd %%-'.t11'
cooling, while tilt- 2ntl 1('g NVL14 CCIIIISLOVII to a iraRomeler.
-:o1ell owt:ll %%,I% rroolve,el
After standing o 5 lit. tile liver(
and tile prodi-ris wfirkill till. Aothrart-ol: (211 g g.
Na, 150 mi. C,11~ kt-(), ;,it,[ o '-fittiv. allo. if Nhl
gave 7.4 g. ziollo.., , I, , 1 :1 I~ va,vs Ulf, mt,;
C', If., and (:.I I. . ool :js g. cry;l. produrl-;, sit. MS
102.15j", froto 0--It tf114 I, -Pflt i,/ 9,t0 -1/11; wir"
,inthracene, it; I ;It I (It-ii I-MAO . "'.. .'I'lAill.d.
tile Uilloet Ilo,, alld tile. f-I'llit.
dehydrogeii-t-I ,illi -, :,I '-'Ill 20": licalov--l ,fill pi,ri,-
tivid gavv fit 17-1 1 ',
tilt motlo let fimit fill., fit'
whil -I little
Ali(),, G-11 ... -1 I-Y Ir,-.1 .... .. I will, ~11-
anth,,ursirpor,dr,io J'I'l
"killoll, o1. 7.1 Sit f(rool 'fil. 1-1(1111
dilie,-t Is VI it, 10.41i If ~.I- m I I I. ..... ... " I 11, !, 21
2lie, give,, RIP 'I, P? '411".1 Ilykillf III,-, it. 1,; 1
I ',' (Irmn Cjio I 1~. fil"I J,~.rr"fol'd
II'l- I I- g. McCl, gave !"In anthrucesic and 7(,"/',, mix
leg ed
i),Io (iiiiictiiyl-[),11)-diliytlroatititt-.tctne avid 9-incthyl-9,10.
I levou: file MINI, -1-1 Ion -1.
~g_
9 Nal 150 nit. C.1 I.-UtiO, and 5'g. McCl gave, 0. 1 1; 1,2-
bell Mot bracenc, nfter tile sepn. of which ilir tt-timmitig
-till -livils-ngrnated by hcatii)g S ;,?),)
imif, was 1(
irtalill %,tilt pice-ii arid. give - a picrale, tit 171 r,,-1
Mitch s:~,vv I I K fr,,,- lt)-,iirlh.ri-1,2-hen.,in!isr#irelie, Ill
1 10 1" 111, ololh.r Nqwnq g;- -- 's ,10 1
-,, j:fhr,I,e,?r, ill. -.I" :ill fill nf g 14 rnIil-1t_1c,1
"Ill, ('111. 01"
, , Cill.) Aothe.,-,j.r (11) g 2 g h.
-Id all '(11ov. of MCI Rav,-AO fill iolu:d C,ll,, c1l"
Cji.. A 1 1;'. atititracc,tv. .,od All; crijitc,l -od, dthydrop
dt-rivs_ df-hydroliviiat if psi ill tht:%r by S remitted in i'(Jln-
AmIlera-
crof '20 P ), I g !J, sold I'l g Mt-cl gavu filtu evapli. of
fit,- 1111~21 K cl% o In fi:, 101 1which 11flef
'1. 1. with 1, 1 .7, lit, -it Foll"wed I)Yj
hu Befell; willi I little CIL 11, illin 0 -,'Y) 1W, g:lvu g-
1, frt'.11, 1.1,
-tit M,hil Jot fr-,te lifl.l-
,ilh
Vt. 1.1 -11 1~1 ..... ... -
t-l 11-v -o ill, pr-l-
.11 , 11, 1 id fmm I I I I k, C, I I . ...... ga vv
m. %I - 1 .4 ill,
0"..). ',1 A.I&, ..f NI I Ill 1.. 11"

a w W w
7

Otp OW10,11 AND Oeaftiirifl ma,ig
4110 it
1001,
00

* Thip v&vctwe of 4adwateno Item Ime viewr^"-
llan"vUrams-Ore Clime.
14

,
.
o '"
physg( w, 4101
z 600,
'
mrj-
mssml is
(V
I

4
- 1
t
1 m
,
(.
m
I,#C11. JWIIA~V. 1ANS-11M. S4404. PittifilIq
I Owl
s
it
4
.
21 , "
iffir
v
'"'thatt dwas tbm 1 0 to"Mukiwe v1scial (

r 11 CiLdtal ttfurtUree Of anthrWV1W CIMAUtUiCS WV6.
of the "Ute. M% of the full re"mw~
.1.11

0 Basically. Wj .111 w3thr3wene Is mpremst"I by
ttw Auvren structum 4 at-
i
77"1 stmct:m
.
n,
3 lp by the strtwtun with numo
rmo,kitable bamb
t
,
e
links. eaka. ofthvititervitntak distam" by the Pruner
1- mif" abuta 0.03 A. lea than thum .4"twi
,
a
13 , -
-
6
'IV the rMthmiat Pauling, th,.k..Y,awf Reach (C.A.JO.
lawo). if. N1 Laic"tel clog
~
Q
or's
"Go
Qq)

feel
IIo*

a oil
w#441m ctalloomwo

-
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-
Ing 441
x
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4 V
0
0
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.
6
A ft a dik m ah 6
0-0 -0 - 0
0
0
e

N11KW,YLOV, B. M. Dr. Chem. oci.
Dissertation: "lnvestigation in the Field of' Anthracene and 1, 2-
Benzantkiracene." Inst of Organic Chemistry, Acad Sci US6R, 12 Jun 47.
SO: Vecriernyaya Moskva, uun, 1947 (Project ffl7636)

:7t
-0---
..- .'
-wf
tb
V . . . - -- - - -- -- V
fit
it V-1sr. --at. 4V Iw a. omkd 16 tea -Wwe Shaking .11 jnjjr~ lit MOM tunilf. -
Vic ad(I
twr AT111 0.30 9. 1 Addh, of 1.0 N. I
"Ith ew recoverrl front a- ~im win
- - ~~ - T t. X1 tq war ic~ fr
kict-A t-n it
..20 160) 0A tz t n-I at ovtr
Its td
an' I_Z03 In - I -
It,-. --and
it d
-4'guo 77 lus to, 2147 (fro t
If, min, fell Ivith I r'
ayor ei c, -stirred w E
11113. at 40* 'firre %v I Oro, lavt~ va -itlilti 4:1,
but-kewping I IN .
1-13r, ~Utljnvcvpe. ~'Ijutf (I'Ma 0 05 g~
and AJ In nil. told
P, un 2 4 3haken
I's) It. Rj thon tic~lted with awtst Ina
M. gusi-w~ ettlyfam 03 c docturpc'. vAd wattr, arut exta.
rfipY, fulloweOy Jecompa-'With 140
whhTt
147 Zm-S Ir
-;-)O~~Jfruq dit;-
Ito
4 wif
7t
'W7

1, r
UM/Chemistry - Cyclic Compounds Jul/Aug 48
04 chemistry - Synthesis
"S~mtheoie of Polyoyolio Compounds," B. M.
Mikhaylov, Inat Org Chan, Acad Sci USSR, 6j pp
"1z Ak Nauk SSSR, Otdel Rhim Nauk" No 4
Studies action of lithium and n-butyl-lithide (1)
cm meao-brome derivatives of anthracerse. Estab-
2.1shea that vhen lithium reacts vith 9, 10-
d1bromnthracene (I-1), one halogen atom is replaced
bjy metal. When one equivalent of I reacts vith
9-brom and II,9-an~hryl lithide and 9-brom-10-
antkryl lithide are formed. These cAm be used in
eynVesis. When tva equivalfinta of I rmot vith no
Am 8/49W-
/Chemistry - Cyclic CoMounds (Contd) Jul/Aug 48
two balogen atoms are replaced by metal. Submitted
6 Nov 1946.

WOW

-1. -111-11 -_4
V
Synthesis of polycyclic compcunds. New preparalion of homol(gs (:f 1,2
benzanthracene. B- M. Mikhailov and T. K. Kozmmskaya. Doklady . I kad.
Nauk S.S.S.R. 59, 509-11 (1948); cf. C. A. 42, 63501. Li (0.05 g.), 0.25 g.
BuCI, and 7ml. abs. E12() are shaken 2 hrs. in a Schlpnk flask fil:pd dith N,
the BuLl soln, under N treated with 0.5 g. 10-bromo-1,2-benzanthracene In dry
pure C6116,shaken 7-10 min., poured on Dry Tre, and treated il"- .4a~er, giving
60% 1 2 benzanthracene-10-carboxylic acid, IM. 218-20 0; the neutral products
contal~ 23% 1,2 benzanthracene. Tf in the abov'e expt. 'he mixt. is treated 41th
an excess of Mel In Et2C instead Of C02 and heated 2 ~,rs. at 400 in a c2csed flask,
treatment dith water and evapn. give *-'0% 10-methyl-1,2-benzathrricene, m.14C-10
(from benzene-alc.) . Etl instead cf Mel si-mila-ly gave 47.51 lr'-ethyl-1,2-
benzanthrucene, m. 113.5-140 (fromEtCH).
G. M. Kc.3clafrff

I]BBR/Chemi8tr,y - CYclIc Conr;ounde YarlApr 49
Chemistry - Alkali Metals
OWYntheses of Polycyclic Compounds," B. M. Mikhay-
lov, A. W. Blokhina, Inst of Org Chem, Acad. Sci
tow$ 14 pp
*Iz Ak Vauk SSSR, 6td-il Xhim Nauk" No 2
Investigates reacticn between Bodi,= anA I '-t 1) 1 ~xm
addition products with anthracene and 1, 2 -b an
antbxaoene and alkyl halides. DiscoverF, ec ta of
(1) mature of alkali metal, (2~ nature of hali&e.,
and (3) magnitude of hydrocarbon radical in alkyl
balide on course of process. Ertabl18hes that
J-3/49TIl
US&/Chealetry - Cyclic Cozpoimda Mr/Apr 49
(Contd)
reaction between lithium compounds of multinuclear
hydrocarbons and alkyl chlorides is a preparative
Wthod of obtaining meohomologues of anthracene,
It 2-bentanthraceze and their 9, 10-dihydro deriva-
tIves. Submitted 7 Apr 48.
Ab 43,149T11

V'.
PA5o/49-111_~
MR/Choudetry Anthmoone fty/jw 49
Chemistry Synthesis
"Synthesis of Polycyclic Compounds: IV, Metalizing 9,
10-DOydroanthracene and 9, 10-Dibydro-1, 2-Benzanthru-
cene,- B. M. Mikhaylov, A. N. Blokbiza, Inat of Org
Chem, Acad Sol USSR, 71 Pp
"Iz Ak Nauk SSSB, Otdel Kh1m Naue No 3
Studies the reaction of metalizing these substances,
vith vk-butyllithium and phenyllithlus, shovivg pro-
ducts to be monometallic and dUmtallic hydrocarbon
derivatives. These reactions have application In the
synthesis of single-displaced derivatives of 9, 10-
dihydroaptbracene. Submitted 7 Apr~ 49.
:�A9T12

A
1119td CAMP114111411441 Of lobliftillitit' 1-011 (110110 tf-~001WWA-
11. b9. 1141khAtil- Ai,,l A. N. ftl-Altwsi (Avai
All-i Namb S-S S.K.-
i"I. Akom Natili 1950. Alf 16 Na .1tirs not
,uld to f4pittlit"Ar 41t ... Phil,- 1.1 Addis AJA)Wly anil
1114WU Ito or Alkali nst-ldh d,l,l Is, I i,tt nf4vtOr kill Us
I,. I A. 1-4 I-Irl.11 tit CAllilifiell.
Imeo:tll'
't 11. (C .4. 32, tnit tile 0 1I,NCjI.NII Pit is not
miced ASIA "Kh Willi I'l. -Olr, alitttut. irsirmis "I the tisair
Are led 419 4 N stir Asti -r tile asisle hirat"I to red beat.
411-86% of a protturt All. 171 2' is sitstammi Making
1 8. [in 20 list it Nistria Natus. tit
e WAIC41 011113411 ;01 5 tit' pruilucirs a ft-d-chervy ii:uluos. (ul.
ed by tj of 9,J04044 93041474PAAPAWWSIAIW~
,..,y W .c 1--ted MAki. PAN14off Of 1611CCI into SWIS
A fflllt~ fillifC. After COaCn. alki SILAIL4 MAI with HALO
C.II.. 0.h I in
141 2' Off"ll C.11, N101110. in-4 Of %1e011. Chor..
sominglisphy oil lite amill.-I -as AW Is its Ist-ft riker
awe WS asillul. 1) IT a SIA( .411-Me drilt, it-vial yKill
%) (efutiou Witt; sets, cob") and 1) J (Clufloon
with pett. ether ant When the reaction with Na
was run 71) b". the fricids were unchanged. %lei glows
tiOr'. da-Me dirris, nd 17', 1 Similarly EtCl or Etl
heated I hir. its 44)* and let *14rul 40 Wis.. qa,. 41-41,
mul 17'..
TO As fell wila. of I). r. ',I .,VA IQ ydfLwntkmvac
am 1 8 "thruvato 4"ll (1.3 1. %& in IQ MI. (3,1CE).
waa 0,filtil It 7 a, 0,i04jhy1jf0j)IICIIAfi11V in (Iff
osersom: "went. imin.lute furmatuin All ill* ui-NA dMv
tuuk plate and lite 1A.1141 l1ralm'sil sib %IVCI Cave 11",
1. bit", auto 0.4 a. 9.11)
dift Itsmanthitis... low 1, %. .1".. (1... 1
-Sri 4 it A.-Icthf,l 6-1 Is 1 4 1 ...1 V1 , " I-,
11h.sx? !0.Iu,d,Ad
is-, .1-t. 1i'llis
IClution with "if.) Palisade Of lifittlen. -)-At- 0-4-1
mi-lication Of kill it-N:A dfIlY (41-11 1 4 I~ And
lm gave, "I.." treatment .1111 1-10, 410) -4
Jejujilto Willi ( .11. 1'114), Ater llij-
JT, 0.11) b", .1 1-1 .1.4
.1,1 %Iv,cu, It. It , I
Vile), Alml the di-Nis iterfs, Irian I it I ca,t A
Itt-Mll CdkW J11141 t-Olls-1 hear. 11".1-Cat sib
followed by V411.41,A). gave 1) AN A,Idn it I it
9.10.0hydrophenallne lit 17 Ant 1% on
Nola. of IVA (frisas 53 1`1111t .,4,1 0 Is is 1.10 in Posts
with krecooling gavir a tstlaultnous ppt 4Y,10.4 4650.1,0
militia ~ of 7 a Mei gave A livrim mcirtism
sind J)Ptn 01 1,11, IfCAIMMI "Ilh ilpil Aild EV41111 'It tilt
uts lair" fla., 77" '11 M, ds-11. ,11,1 Ow u.slA -irk""I
tit, A.Mmis I it I its Im'l %-list, 1" )-lit j .1 .06 .... 4 1
fflA4 1. lei I ilia 9t.81.1 Al lit.
j. Ifel Stove 411cr the astral ir,domml Arm
Mrs, q.WAAjd.I0.p4e*yj.,
j.
17 5 (from litoll). It the IIIIIA-1 12111t is heatni Willi
shaking 10 lit.- as 511 fol' I"Ore iteut,nirsit %jils %get.
there are ni-14ined It -1 1. Pls,. 0 13 a 9. jt).,ljMrtl)Vj
11,10-ditlYtittilthrOatine7s) P4 x 1, An-I 'I 'Is)
.,Ill tht,
stbuvr. thus At mrsaAl least, J'hl.i I.). 1., 1. h,i, t
clevairil trails sin rach.,,lo, rr-ton. yes-him, ihs,

Actwe of PROSPAIW64 peoll"hilwids; and pon(ab'"itillis
an gauu4c"e and Its doriviruwasp It NJ hilithillov,sn'l
% I ,is Pilmov-1- t- --l V-ptl I"Aluil , A-I
,.J.j :jrj. U.S.Sk,) /b., sk-lwAsul A*,- 4) 1-
chrits ) jo. am"5% timm - rhe ftAC(IAMI Of AMILF&AVIII!
ofatimulcCland
A.111sa ttW 111WOO twimilikMill 41141 the tiflillUct then SPlitil
,.IV 114:1. 411.1 tic) ki-flusteng 2, u dulltz'"'W, 2.11 Wis.
.-A list dly Cliff. I tit 1,1%r 11.6 s
1o4 IV'. - "Aind mid I g i4dId - ho tkt V,
vii 14, with 11.47 S fectivereli atithroic, tic, a il-thirii .,list
,if O'Cis give after IM hn tit rtkno trials O.M 9.10-
111 :1114-10" And 1 4 A il-cf I,tfv
ifcatilig the V-cl dcriv with 11cl. III C.11. .1 [if, 64"
.',1 7'; ..1 the 9,10-lii-C) frri, . whik- jAnding 1) I,ym gt
-scm teusp~ gi- 34.4l,".. 11CAtills 94sr-mit-miiII&T-tru,
-.tb PCI, in C.JI. 3 bra. VAve 34-51:;
thralfitt. M. Moca CJW. m. 210.5-11' (m re-
1-t-1 cr"tu.). K"' it th lanthrAmit Omilirly
with 1-6. 10 h. in, 41'1'# ga-Ze 2L4"-. 9-wsr9AjW-Iu~4kr,,-
,)oj&4jjx#. ill, 179-111)" (froIn 91011). Addis. of 3 07 a.
Pill. 1,. ;.' g Authfill-ritt ill Calls 14VV A hilill. P41114-411Y tic-
IxAttlivit tile dilstipinkle. which vzukularl in ;.N) costs , anti
01
IvApn. titter wAxlunj gave 96.4,f SO-btumumthirmue. to
1401-1,Wom ECOM. interruption u( the reaction dies,
11) min . gave in.
04 ~7*. Shuilar reaction of 9-cliksroanthn-vne in 20 min.
g.ve M.2- 0-cishwo-10-brusnownthrumnse, while 9-bromo-
.W.ne in 24 Ism C-Are 94.6,; 9,J0-d&bromswxArcw~,
m. 21P-29'. 9-StethyUmthracene in a isimilAr reactiot:
in it? min. gave 4.1-37, In.
1"t) 3". Jim", the ;Bra tcActionj so viA the I'llf,
[it, 1411itt. (" At K01101,11004

c A
/0
Preparation of acenaplithylene 11 %1 NI'Ll-il- -.1
4 A N . "h.' . 6, 1 A ~'.' I f C., 11 Vb, ,, it)
I . 116 1 : 9.10 . I k ..'s. .' , I.. V f.. ..... . 1 17. , i.,.
..I ... ... ~' 1%. 1 .1 4- . . ... . ...
-I .... . I. U., I.- - ,, .. I I.. ! . . .. ~.. .
,. .W. I IAO III. . Ih. . ,, ..: ..
jlk~ .1, . '.. _,I Q 3 - . " f'-f I ...... " .' I..., ...... I-,
. ,-In ..# I F- ---I J- I t- I-- L .11.. . . %I K

H. U. Mikkaliov and N. G. Chcraovi oklady
AU KA S.S.S. k 10. 2.37-4K 19W) -Since many metal-
Wis. comptio. coats. 2 alkalli-metal atotin exist in mlorleu
of colored forms. dqieafli~s" th or atr'euce of
polar solvents Me gt*O to Cn=i-%7tV possibility of
EW actuAly taidog part in the formation of colaml forms
was invtatiggated Making 0.5 g PhC:CM and 0 05 g
.Ikvd Ll in 00-75 mi. dry MrO in a N-fillcd settled tube ovrf
WO lits. aW mech. reinoval of the red product. drying to
wago to essentially con-Aant wt., and treatment with
FIrO-MeOff gave J,0.2j4*jr~p"y1dkai;*, in 210, N',
the wt. difference betsztn the latter and the fed complex,
with allowance for the U content fobtained by titratiou of
thea Layer) rave the couspo. of (be cooviolex us oomliins-
ion o I aml. ydrwarks, 2 ajows Le and I nol. FjsO. poo-
sibly formed sdoubl McgJanof hiC:,gandadoubly
of We. It & suggested it Et.0 may form an
!=gz r of many odser complexes :~dixul~
stances it,. Ph.C.Na. when prepd. in Et&O soln
believed that all allmli-nietW org. compds. ut of 2 types
those with a C-M boad of essentially co~akzt type with
airtly kinic character, and those whkb Art colored "
9:11, a true complex ionic structure class I Lmvcri metal-
alkyls and metalaryts which are "conductors in Et.0
solit. M KO-Ol.puff

SyntUds of ghwhaftgaak asmadc compmada with
Utwum re sets. ~ Y. ~IikhAljqy and N F. KucheruvA
DokUdy Ited Nout 'S-V R. 74. Aijibr.1
cvne dor- um reAct with PCI. In the presence d AICI,. % li&
PC4 leads only to Cl deris-s. Aryl Li deTivi wtth P hjluj~
in EtO readily gave P dcriva. Thus 3 PhLi and 1108 pvc
01% Pk*P; I-Cmll,U gave 27% m. 2779 t9".
while 9-phenanthryflithium gave 72% Irs-9-plitmanthr 'vt
plimpkint. m. 37"' (from MePh); 9-anthryliithium gage
20% W-914WAryipAospkint arzage-ired, m. 270-3*. while 9-
bromo-106anthryllilbium gave yellow
tkryi)p&ospAist.tu.2W-8*(IrocnNfePb). Sirridsrly.theLi
dffiv. front 10-brorno-1.7,beamothriwene gave S4.6% t,"-
yellow. m. 192-4' INKI,
in Ht.0 simaw % Pk.PO. 38-1, U-C.1f,).P0, 49-1,
tri-9=-W1wj1p1ospAime oxide, Tn. 3&"*, &5% Im-
(1,2 1sAr-l0--yI)p4osp4ioee oxide. m. 191-3' (from
EtIO-beozene), alteration of the proportions of the reagents
faikd to yield pmducts other than R,M. Use of Cjf~
NPOCI.. (ollowed by hydnilysts, gave 64% P4,M11. m
192-4-. '1% m. 194-2(W; 9-phenanifiryl-
lithium (I mokilmole chloride) SAVC 2 acids.
phoiphom.4 erW. m, 72"*, anddi-9-phen2m hrylphotphimc,
ivid, givit.4 IOWA No tall, In 33% and 477c Yield. yesp
G Nt

The cam"ples nature of Ili~, colored organic conirunds of
01111bab Ma,"W It %I "fil,flAl6v And I'. he, n- ,
(0 Arad. MeIl %-I. 1' .9 S R . 1wjj3F 14kad.
Noah S.S.S.R. 74, 'ACV 4~%iljblll By ,mil,kir elementary
janjivitis, P%.C\'& lei anin Ili Pliothil-tuAllir formsla~vv
,.let of th,- ",,I,; F tile tril,tme fM,Cf
OEW'; tedwe hY 5-bkk and Mark- I (.A S.
) to detect that complex was due to Incomplete &%&I"
Tbe curilcogmading ti complex hall the compa. VbCLj.ZE
and the structure JMCJ -JEt#01i,0K1ij * Furthn cilm.
lexts in Blot) Sulu are: PhC CPb.,2.Va.2E. PhCII C.
-2N.i.E, MICH CPbg.2Lj.,F, and the anthrAcirrit j.1)
M
complexes .4 2L&.;.E and A.2NA.E. in the Utter com-
ples, SchIrrik. ft at (C.A. 4, ISM), failexi to detevi the F
-InIf 10 faulty AIIJIYSJS TtV W10*1114 411101t ('11111111rill"
Were 141131IM91 III %)I1$ III the C(WI`rsp~tI,1Illfi Amint 141401
C1,11, ~,\. kit. \ (#luck 1, llhcll C I'll, .1 Ll I'l, N (Carml-
1140,1111,C \Jlh _,I, I.I.NWAlb-f 0--I Ph't Nil), .1
-Nt- I-,I,-\ A "A CIIII.111CII III H,\
Na-A And I'l- I 4-1~. N, Ph.
C.Cl'bq in 111INXI" NI'h Ili
(red). and the ewresixmiling Lo complex 4purpiv--J~
The presence ,1 '-1 inelA (M. toniq in the Phcif L'I'll,
complexes with Bi.N suggests the structure jPhC11.l/ -
Uhl) 1M-,NLi,j 1. Of lite J, possible structures of the
J PhrC N11h "mpleavs, the iniat plaumbic out to (I'hA-* It -
NPIII It-wkilifficturialbuundl tothrl.'Al,an
rather than the N worn Ut the Phic Sph. The m-al
plausible structures Mg the HitO ",nipieset are. r.p .
jPh,CUCI'h,j JU-Uht.1 ' will \. C11h.j jEt.4i N.-
Wit.1 '. The leurtutev pr,,Wnnl 1- the ,th,-r oajdc-s
are; 1-If Mil.) I N.) %A I IV1,1
and -LjI IFt.0-Li I?L(d

Synthoflis of 4-bitimsylparacwic: acids it NI. %IIIIIIAlt"
lk*?. oblIkkel Kkim.-(J. CKci. Client I Zt. 3m
Addn- of di-19t bentYlsucirinste 00 9 ) and IS g~ EtOiClf
to 5 C. Va In 10 If. abs. RtOlf with Ve cooling. keeping .1
days at 0~2* &n4 5 days at room lemp . Adda of ke. extn
ith 20, acidification of the &q Isla, and its Wn. with
t.0 Car. W.6% PkCHCM(CO,F,)Cll(('IIOI('(Nf'I The
;
crude ester reduced with At-IIS JA'14timnus. J ptaki
Chow. $4, al(INO)l ovemlahl in UtIO at 2.V So fhr prr-
file* of a lilts* 1100 gave 32.5 a umb-IiIIII.I. 1,44 11-C",
thtl (10 g j ml n
lost Most and yielded 72.8 g. tnsx~l El pm--ji,- -h.,h
after WVvial distas. were setid Into Ow -fid f. --
I% W. IN . ItO-2*. and the liquotl 1-m. 1%. 171
I mm' dge I.IW2 The toilet (5 i it ' I-I'd 4 it'-
10', IICI govt 4.49 S. d- 4 41 . ,, "'.
tirmn HItC)--pkr. elbeir). white %imel.ir hydruiv- tile
i4id fit" ;sve an acid m. 134 5-5.0* tfrom It,(), III,
latter kept to mrso at IRD-2004 6 firs, changed its in p And
when crystd, from MOO-petf. ether it m. to.) 3 1.01P 4nd
did not difiress the in P~ of I. M K-I.t.47
/10

UNT/Chemistry - Pbarmaceutica.19 Jul 51
Organic Lithium Compounds
"Organic Lithium Compounds of 1, 2-Benzaathracene
and Their Conversion," B M. Mikhaylov, T. K.
Kazicinskaya, Inst Normal and Pathol Morphol, Acad
Ned Sci U~"SR i-I
"Zhur Obshch Khim" Vol XXI, No 7, pp 1276-1283
Org Li compds of 1, 2-benzanthracene (not obtain-
able by action of U on halogen derivsi are
sn;oothl.v prepd by action of n-BuLI. or PhLi on halo-
gen derivs and can be used successfullj for synthe-
als of homologues and 0 derivs of 1, 2-
191=5
UM/Cbemistry - Pharmaceuticals Jul 51
(Contd)
be=anthracene. Synthesis of 10-ethy,1-1, 2- ben-
h cene and higher homologues requires une of
1,.2-benzanthryl-10-lithium obtained vith aid of
Phu.
191M5

UM/c4emistry - Phewmtbreme Aug 51
Derivetives
"Research Into the Phen3nthrene Series. I. Syn-
thesis of Phenanthrene Derivatives With the Aid
of Organic Lithi= Compounds," B. M. Mikhaylov, N.
G. Chernova, Inst of Gen and Exptl Pathol, Acad
Ned Bel USSR
-Zhur obshch Khim- Vol XXI, No 8, pp 1517-1524
To synthesize phenanthrene derive, use of or_, U
compd of Phenantbrene bas advantage as to rate of
conversion and yield over methc>d using org Mg
compds. Prepd several new phenanthrene derive
using org Li compds. Bromination of phenantbreme
UMR/Chemistry - Phenanthrene Aug 51
Derivatives (Contd)
&~d'q-methylphenanthrene with FBrq yields 9-bro-
mophenanthrene and 9-methyl-10-*tromophena-athreme,
resp.

USO/Choodstry - Sennnt5iracene Deriva- Doe 51
tives
"Action of Phosphorus Pentokh-lides on 1, 2-Beasm-
Z7 tbracene and Its Derivatives," B. M. Mikhaylov,
t T. K. Ko"'riskaya, Inst. of Norm and Pathol
lbrphol, Acad Med 6ci USSR
"Zhur Gbehah Khim" Vol XXI, No 12, pp 2184-2188
Pound that PC15 and PBr5 halogenate compds of 1,
2-benzantbracene series. Action Of PC15 on 1, 2-
'bem=athmcene (I) and 3, Z-benuwtbr~mp
ITI) ~rielded corresponding 10-chloro-deriva. PNr
fia tiLe same action as Br2 on I, II, and 9-metzwU
19"a
UMB/Chemi try - Benzantbracene-Deriva- Dee 51
tives (Contd)
and 10-methyl-1,2-benzantbracene. PBr5 reacted
with 10-bromo-1,2-benzanthracen to form 9, 10,
10-tribromo-9, 10-dibydro-1, 2-benzanthracene.
TAtter conversion occurs :in like manner under
action of Br2 in presence of pyridine.
n4

'USSR/Chemistry - Lithium Compounds 21 My 51
"Constitution of Organic Compounds of Alkali Metals:
Lithium Aryls and Their Ether Addition Compounds,*
1;. 16. Mikhaylov, N. G. Chernova, InEt Norm and
Pathol Morphol, Acad Med Sci USSR
"Dok Ak '-.iuk SSSR" Vol LXXV111, No 3, pp 489-492
Prior work by authors (1950) established that W& and
Li derivs of triarylmethyls, phenylated ethyletic
hydrocarbons, debydrodrivs of condensed polynuclear
hydrocarbons, and azoraethines (organometallic compdo
that are colored and conduct electricity) are com-
plex compds contg ether or tertiary amine. When
180T10
USSR/Chemistry - Lithium Compounds 21 May 51
(Contd)
pheryl, alpha-naphthyl 9-phenanthryl, or 9-anthryl
Li is prepd by reacting n-BuLi with aryl bromides
in benzene, simple ArLi compds are formed. In
ether 6oln, complex Li aryl-ether adducts are
forned.
186Tlo

-1KHAYLOV, B. 14.
USSR/Cbemistry - Organophosphorus 1 Jun 51
Compounds
"New Method for the Preparation of Primary Aryl-
phosphonic Acids," B. M. Mikhaylov, N F. Kucher-
ova, Inst Normal and Path Morphol, Acad Med Sci
USSR
"Dok Ak Wauk SSSR" Vol LXXVIII, No 4, pp 709-711
DescribeB synthesis of primary arylphosphonic
acids by reacting lithium aryls with dipiperidine-
N-oxychlorophosphine, and subsequent hydrolysis
of resulting aryldipiperldine-N-oxyphosphines.
184T10

HMAYLOV, B. M.
WOR/Cbenistry - Sulftv Cmpounds in. SeP 51
"A New Type of Reaction Between Thiolic and Un-
saturated Compounds," B. M. Mikhaylov, A. N.
31okbina, Inst of Org Chem, Acad Bel USSR
"Dok Ak Nauk SSSR" Vol LM, No 3, pp 373-376
fte action of thioacetic acid on anthracene occurs
at the 9,10 positions Pnd consists of the addn
of 2 radicals of CH CLU- rather than 2 thiol groups.
21=9

USSR/Chemistry - Pharmaceuticals Jan- 52
-"Zynthesis oil Polycyclic Compounds. XVI. Prepa-
ration of Meso Derivatives of Anthraceue Using
Organic Lithium Compounds3" B. M. Mikhaylov, V.P.
Bronovitskaya, Inst of Gen and Exptl Path, Acad
Ned Sci USSR
"Zhur Obshch Kbim" Vol XXII, No 1. pp 147-162
Studied reaction of meso-h&logen derivs of an-
thracene -,rith n-BuLi and PhLi, leading to for-
mation of org Li compdo of anthracene series.
PhLI is recommended due to absence of side re-
actions which occur in case of n-BuLl Prepd
USSR/Chemistry - Pharmaceuticals (Contd) Jan 52
number of meso derivs of anthracene. Replacement
of 2 Br atoms in dibrom derivs by 2 Li etoms
under action of excess PhU occurs to inconsider-
able extent. Meso-chlordlerive Ao not react with
PhLi. Org Li compds of anthracene series are rtl-
atively stable in ether.
207W_
~4
~11

UM/Chemistry - Pharmaceuticals Jan 52
"Research in the Naphthacene Series. I. Addition
of Alkali Metals to 1,2,3,4-Tetrahydronaphthacene.
Conversions of Bimetallic Compounds of 1,2,3,4-
Tetrahydronaphthacene," B. M. Mikhaylov, A. D.
Chinayeva
"Zbur Clbshch Khim" Vol XXII, No 1, pp 162-166
Li and Na are added to 1,2,3,4-tetrahydronaphtha-
cene (I) in ether or in dimethyl ether of ethylene
glycol (II). Org Li campd of I is hydrolyzed by
II into mono-Li compd. Action Of C02 or MeCl on
di-Li compd of I yielded, reap, 1,,2,3,.4,6.,11-
207T-I_Q
LWR/Chemistry - Pharmaceuticals (Contd) Jan 52
hexahydronaphthacene-6,11-dicarboxylic 'acid or
6,3.1-,dimethyl-1,2,3,4,6,11-hexahydronaphthacene
in form of cis- and trans-isomers.
20M0

tA % L-:~. tA Pt L 0 -f t& - M -
USSR/Chemis4 - Pflosphorus Organic Compounds
Medicine - Cancerogenic substances
may 52
"Synthesis of Triaryl. Phosphines and Triar7l Phosphine Oxides Using Lithium Organic Campo
B. M. Mikhaylov, N. F. Kucherova; Inst of Normal and Pathological Morpholody, Acad Hed Sci
USSR.
Zhur Obshch Khim, 22, No 5, Pp 792-797, 1952
Aromatic Li compds can be used as reagents for the Wthesis of carbocyclic pbosphorus
compds. Triaryl phosphines are obtained by the action of lithium aryls on PC13, and
triaryl phosphine oxides are formed by the reaction between lithium aryls and phosphorus
oxichloride. With this method, the simplest members of the groups of phosphine derivs
contng both tri- and tetracyclic fWdrocarban radicals can be obtained.

~_~Akwf~yt_vl\ IN lb
KIKHAYLOV, B.14.; CHINAZVA, A.D.
-
Haphthacens series. H. Lithium-organic compounds of 1,2.3,4-tatra-
hydronaphthacens and their transformations. Zhur. Obahchey Khiz. 22,
1887-90 152. (KLRA 5:11)
(CA 47 no.14:6924 153)

USSR/Chemistry - Organo-Lithium Compounds 11 Jun 52
"Complex Formation in a Series of Organic Compounds of
Lithium, B. M. Mikbaylov, N G. Chernova, Inst of
Normal and Fathol Murphol, Acad Med Sci SSSR
"Dok Ak Nauk SSSR" Vol LXXXIV, No 5, pp 967 - 970
Tnere are 9 theoretically possible types of compda of
lithium having a coordination number of 4. They are
complexes of lithium with ethers, dioxanes, amines,
and hydrocarbon radicals. Omwkw comPds of aromatic
Li ierivs were also found o exist. Dioxane and amine
complexes were prepd. Presented by Acad A. N. Nesmey-
anov 8 Apr 52. OW r/ 3

KIKHATLOV, B.K.-. CE19RNOVA, M.G.
Structure of metallic compounds of aromatic ketones. Doklady Akad.
Nau S.S.S.R. 85. )41-4 '52. (KLRA 5: e.)
(CA 47 no.15il'467 153)

n
r'

j, r,",

-iA
ttrd.,:
tut Vw TA OVA,
c7a sow
*A
K, ifaca, V - -,-f " .,
-,oAdm d 11 --
f
Pid jhw,S6.*ik -t-a Ob' 'Aga
*601 M. We
(Cff- a
jal. cg. C.Ao I , .4iJA
CLTC
to ir 1,
lot 0 suo Cc r iia~,a TA
tach ()On
tulaal
049 Se On ',Motq% WT x6 ice kad
likii too
at'. so 4,lt4fx
iiiM
lit Ohth~rsz;6- . t~"Ca qkU MIMI
49 r- y I in. - 01" ;g a 0(
eimuv(cr6ic(O 71A the (0m the
ad ;Vh~~fim
U the
gslp~-~,a
,,,,detdte,=
id.
t x
d.' emso Uwe them
Ois cap cave a VP~e4 got- who& at%~ jig ~.tj wz WON
I. at taut)
9=9 witu pum Off,
Bob" (,,ig, u) Is Uea~ij7drmw Of Ut wa
wecii e-" F, - cu=daa - . .
t,ed C11 . , a
bined Ott% bkk tv* 14 CPf' ~IIMI the, Otwi
~he bwi: conipt" taked UP
Oiar ~rfth
doe
tA

M~. WME
Milk uxthp 12t4ktWUa tdwiib ta
AM
7M:

Structure of the molecule of diqters o[lialbUS"a to its
homologous substances.
_..ban , A-i '1,,g and
im-1. Va. r. Fig. 17, 7lb- 19 .-pure
9-methylatithracene (in. 70.5-86.5*) was t ormtd Into
Its drimer (m. 228-228.5') by irradiation of Its ace-
tone solu. by a IIg arc-la , and recrystn, Absorption
spectra of thL crystah; ME, 2 electronic transitions.
The first series of broad ab%orption bands begins with a
strongly polarized triplct X - 3900.1; 40D4.5; 4030.5
A.; the seLond series has a long-wave firrilt of absorp-
tion at A - 2560 A. for nue polarization and 26M A. for'
the other. This spectrum is eutimly different from the
monomer spectrum. The photochem. rezction takes plam
not only in soln. but also by irrruliation of monomer crystals;
It cun be detd. by tLe loss of birefringence. Tht trans-
formation is effected by a change in the valence bond which
leads to a configuration situilar to that of hydrated anthra-
ceue derivs. The aromatic structure Is lost in the central
riug. S. Pakswer
'y
L

M7-

W Subwtudda Wills
t1A, A6 "t the &HMO mews.
%TT-vt r,&,C.*=,,`a;d V. P,BPM'WM"ftkay&- 11". JhAM
KIWO. 23,
loom 44 9, Sa, mul 34 ad. AcOM wnz MUM over 2
to. Z6 I LA ad.rotod. HC1. them diki. with lfro ymnor
=6ylautswoue, -vLkh was rellm-ed 9 hrs. with 6 C. Za
'j.
and 100 0. 2M. NaOll yielding 712.7% 2-methykL-
thraLene. ru. 20"*. This (3 1.) in 75 ml. cold M was f-,
aPerheatingotiastemn 4'
bath until H9r evolution comed, the reaction mixt. ykilded
rosmaxAra4m (1)
7547o crude or 6350 pure: 2-
M. 944-5.5* (from of 2 g. 2-met%yI-9,IG-
I in RW and by-
X dibrimcnnt5ractne to 0.0M moliis PhL
drolysis of the mixt. after O-Ze hr. with )1eOH-RtjO
and HgO, gave 24% 1, m. 93-5*; tha mother lkjw gave
a mitt. (J.81 g.' of 2-methyl-9(aad 10)-hcomoan
% m. 43-W*
Similarly O-OW moles FhM in solu-treaied
i with 1 g. 2-methyl-9-lormoanthracenie, then treated with
1.58 ff. Mel, gave 60.790 2,"i=dhy14ntkr=,-". m. 8'--2.
PuLl (from 1A0 BuCl, 0.21 g. L1, and 30 ml. Et.0)
treated with 2 g kept 0.5 Ju. then.poured on Dry fee
Al 7% S-mitAylaxibr-, e-9 carbaxyUc acid, m. 197-4
rjeLle' Ann. 212. 35(18M)i C.A. 6, 2=11.
Th's (0.9 g.), treated with 0.63 g. Dr in C% at 0* the;i';
heated on Aeam bath as above, gave 50% 2
m. 229-M.50 (from7
QW. OxidL thyla
-t, ed w;th Cr(h in AcOll It gave 2-me I-
i thraquinone. To 3 g. 2-methyl-9,1"tamounthracem-.1
was added 0.729.,.-PhLi In EtO-CJls; after 80 min. the
Mixt. was treated with Dr' 3 2-WA30--g-
q Ice yielding 5976
kroffwalitruccoa-10-carboxylic "id,
hom dU. RtOll). '17hus &;unometallle coLipds. of alka
e
metals behave as nucleophilk reagents. In such compdo.
with the wetal being in o-positlon In respect to a on.
stitent tkere is es~abtished %L link between the metal an
the betero-stain, tbut Li similar to a If-bona, which a
ently coutrals the orientation phenomena. G - X-i,

KlIKFAYLOV, B. M.; KOZMV:~:FAYA, '". K.
Benzant racene
SynU.esis of deriv,-~tives uf j, LI-acc--' --b-i.zc.%~ w.t. *-.,, ~ t ~ . t' .. .~.
rearent!7. 'Tur. ji. khLm. 2-) , N'.-'. I '.. :
9. Monthly List of Russian Accessions, Library of Congress, --, . 1953. Unclassifi-4.

KUHAYLOV. B.H.; KCXMINU&YA. T.K.
S~mthesls In the boazanthracene series with the aid of lithium reagents.
Mmir.ob.khtm. 23 no.7:1220-1224 J1 '53. (KI-RA 6:7)
1. Institut normal'noy i patologicheakoy norfologii Akademii meditainfikikh
nauk SSSR. (13onzanthracens series) (Lithium)

'YL
f7
Fff
;71
~77qp,
MR. M EN'U.
Atdd -vo
IJ-

~SSR/Oi~ganic Chemistry - Synthetic Organic hemiBtry, E-~
Abst Journal: Referat Zhur - KhimVa, No ., (/_
Author: Mikhaylov, B. M., and Ter-6tirkisyan, G. S.
Institution. Academy of Sciences US~;R
Title: Relative Reactivity of t'le Methy" Group in the Berzene Homologs off
4 -Methylpy rid Ue
Original
Periodical: Izv. AN SSSR, Section on Chemical Sciences, 1954, 140 5,
Abstract: The reactivity of the in picollne (1), iepidine ~11i,
(:H3-grouP
benzo-'epidiDe (III), 1,,6-benzolepidine (IV), 9-methylacridine M,
9-methyl-1,2-benzacridine (VI), 9-methyi-3,4-benzacridine (VII), 9-
methyl-1,2,7,8-dibenzacridine (VIII), and q-methyl-3,4,5,6.dibenZ-
acridine (IX) has been studied ii. the condensation with m-N02CACHO
W. It has been established that the reactiv-ity of the investigated
compounds in the reaction is expreaaed by the series I , II / II / 1V
and V ~ VI > VII > VIII > IX and, as a result, that the mobility of
the hydrogen of The GT 3-group Ln the benzene homologs of I depends
Card 1/3

both on the number and on the position of the benzene nuclei condensed
with the pyridine molecule. A mixture of 0.19 mole of,6.,6-dinaphtyl-
amine, 0.19 mole (CH CO)20 (XV, and 26 gms anhydrous ZnC12 is heated
for 5 hours at 185_1~00. The CH 3COOH is distilled off and the resld,,e
heated 30 minutes at 250-2600, followed by repeated treatment with
10% H2S04 and neutralization with 29% NH40H; VIII is obtained in yields,;
of 46.8% (crude), mp (SUCCessive crystallization frcri benze:.L-,
ethylacetate, and alcohol). Chromatographic purification of crude
VIII yields an isomer with mp 215-2160. A mixture of 2.7 moles of ri
and 5 ml of XI is heated in a sealed tuLe for 1.5 hours at ..-) notu-s
at 150-1530; the contents of the tube are dissolved in 20 ml CA'
The solution is treated with 30 ml 6 N HC1; 4-(m-n1trostyry.1)-pyridine
is obtained by the neutralization of the HCI-solution (yield, 46.2~);
the umrsac-ued II is recovered as the semicarbazone after extraction
with benzene (yield 47.85%, based on Il charged). Similar procedures
were used in the condensation of tne above-named benzene homologs of 1
with X and of II with o-N02CACHO. A mixture of 2.2 moies of the
hydrochloride of 111, 2 2 moles of X, and 1-~ mole of XI is refluxed
3 hours; 10 ml of water are added after cooling and the solution is

LfSSR/()tganic Chemistry - Synthetic organic Chemistry, E-2
Abst Journal: Referat Zhur - K_I~jya, No
Abstract: made alkaline with 25% NH40H. The precipitate is washed twice with
3-ml portions of alcohol; the yield of m-nitro-benzylidene-5,6-
benzolepidine Is 30%, mp 168-1690 (from alcohol). Similar methods
were used in the 3yrltnesiij of ii-dimethyi-aminot)eDzylidene-5,b-
benzolepidene in yields of 2t.11%, 'DP 2-C-5-171-50 (from alcohol);
ni-nitrobenzylidene- 1,`,-berizo~ epidine in yields a' o%, mp
1570 (successive -~.-yqtalllization frcui methy! ard ethy, aicohol); FIn-
9- (n -dimethy Laminostyry., ) -2 -me thy iacridine in yields of' )4~ (crude),
mp 225-2260 (successive crystallization from CH OH and a mixture of
benzene and petra~,--*zn et4er ). Condenaation of ~ and X -ujaec UV-ir-
,6- -:~-acrydil) -ethanol (X11): a
radiation yields a-(m-ritrophenyl)- 1
mi-xture of 7 mmoiea of VP 7 mmo--es of X, and 14 ml of C6H6 is Lr-
radiated with W light for 100 hours in a N2-almospherej the yield
Of XII is 54%, mp 146.5-147,50 (successive crystallization from
benzene and dioxane). Similar methods were used in the condenBa-
tion of X with I!, III, and V1.
Card 3/3

ttWlAdr.th~-westem_paq,.qf the Turp-Pnek.-d6pression
--;!Dok'. AN, SSSR -08/4 W441#, ~OA '1- '1954-
09M pk -erosion crust of the
adne
ralogicalampstr io ~rooerttss of the
..nort -westerd.- Part of ~the Turkansk-ds~riasion are described. Beidela-
iiii'-which.'As -gradually being dis'plaaid,: by kaolinite and montmoril-
".1onite appear'to be the:. bi~ sic-.'TilinerAs
-of the erosion crust. Three
Nrenkes 195 ." D
usm-ire (1149- QW:," raw.
, "thitit.Ut, ion- "'An4kii6h; Scientific` Res4aich Geological 1xistitute
P, e t'4- b -A ict~n~ -Nalivkini:j~m. 2~6,: 1954.

n7
At lb
pp_a
Jw
We=
t1k
gin
o ir fit
g
jo'.
pb 4
-Ijt t- it I;jj t::
In

72.
..... .....
. . . . . . . . . . . . . . . . . . . . . . . . . ot
r0
.71 4-4 llivao - P 1~1
ta
W. A
32
At bert
WV
BOX
scilul lfpmh dr J'y
td.,
tho, LKI o6tk

AMF a
lit*
it
7f E 'T
Ka& Q E~_~ gr&