SCIENTIFIC ABSTRACT MESHCHERYAKOV, A. I. - MESHCHERYAKOV, A. P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001033620016-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: June 21, 2000
• Sequence Number: 16
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

MESECHMAKOV, Aleksey 1111-h, FKYGIN, L.M., otv. red.; ABARBARCHUK, F. 1,
_ -
Z.A., tekhn. red.
[Crosscutting and boring macninos and the tool) SboeAno-bnro-vye ma-
shiny I invtrument, Moskva, Gos. naur;hno--tekbn. izd-vo lit-ry po
gornomu, dolu, 1961. 76 p. (MIRA 14M)
(Boring machinery)

NOVOZHILOVq Mikhail Galaktionovich, prof., doktor tekhn.nauk. Prinimal
uchastiye MESHCHERYAKOV, A.I., dotsento ZURKOVy P.E,p prof,p
retsenzent-i-MLO KAURWJ, A.M., red.izd-va;
P f
BEESSLAVSKAYA, L.Sh., tekhn.red.; BOLDYREVA, Z.A., tekbn.red.
(Open-pit mining] Otkrytye gortwe raboty. Moskva, ~os.nauchno-
tekhn.izd-vo lit-ry po gornomu delu, 1961. 471+ p.
KIRA 14: 6)
(Strip mining)

/4 'z-
KESHCMYAKOV, Aj.
- -
Hath of higher nervous function tests In man. Zhur. 77a.narw.
deiat. 4 no.4:574-580 JI-Ag '54. (KIRA 8:3)
1. Otdal patofiziologichookogo I klinichaskogo izuchaniya uchashchikh-
oya spetsiallafth shkol Institute, defektologli APH RSFSR.
(CENTRAL HERVCUS SYS-TEM. physiology
higher nervous funct. tests in man, technic)

NESHCEMRUMV, A. 1.
ft4ft
Conference on problems of the physiology and pathology of vocal
activity. Top.paikhol. 2 no.2:126-128 Mr-Ap 156. (KLYA 9:8)
(Speech., Disorders of)

,(///, " "r i ~ /' " .,~ / , ~
IILTBOVSKIY, V.I.; MESHCHRRYAKOV, A.I.
Conference on problems of the physiolog7 and pathoph7siolog7 of
higher nervous activity in children. Vop. psikhol. 2 no-5:184-
189 3-0 156. (MIRA 10-1)
(Child study)

nSlICHERYAJEOV, A. 1.
Cybernetics and some problems in psychophysiology. Top. pgjkhol.
3 no.2:163-166 Kr-Ap '57. NLRA io.0
(Psychology, Physiological) (Gybvnetics)

i ,, ~ I,F.,-, ,, i1-,!,/'"
LUROVSKIT. V.I.; RESHCHERTAKOV, A.I.
Conference on problems in morphology. physiology. and
biochemistry as related to age. Vop.paikhol-3 no.3:180-183
XF-je '57. (MLRA 10:8)
(Age) (Physiology)

LURITA, A.R.; nVVM, H.S.; ZISLIRA. N.B.; TINOGRADOVA. O.S.; LUBOVSKIT.
V.I.; KRUCHERTAKOV-,-A.I.; MATYUSHKIN, A.R., red.; LAUF. T.G..
tekhn.red.
(Retarded children; studies on characteristics of the higher
nervous activity of oligophrenic children] Umstvanno otstalyi
rebenok; ocherki izuchaniia osobennostai vysehei nervnoi daia-
tallnosti detai-oligofranov. Pod red. A.R.Luriia. Moskva. 1960.
201 P. (MIRA 13:10)
1. Akademiya pedagogicheskikh nauk RSFSR, Moscow. Institut
defektologii.
(MMALLT HANDICAPPM CHIT-TYR

ItESHCIEMYAKOV, A. I.
Some problems of image in connection with the peculiarities
of the mental development of the blind deaf-mute child.
Vop. psikhol. 6 no.4:111-120 Jl-A,-, 't'0. (MIRA 13:9)
1. Institut defektologii Akademii pedagogicheskikh nauk
RSFSR, Moskva.
(Deaf-Rducation) (Orientation)
(Blincl--Education)

Hmuraynov, A.m.
Using thiocarbamide In the colorimstric determination of phosphoric
acid. Pochvovedents no.3:88-90 Nr '56. (MLSA 9:8)
1. Tadzhikskiy sallskokhozyaystvennyy inatitut, Kafedra agrokhimii
i pochvovedenlya, Stalinabad.
(Soila-An&lLysis) (Phosphoric acid) (Ursa)

A. 14.
Ritighcheryakov, It. E. "01, the ;A.,iit f~' '~ e i - ! irudy i*a-z~..-'r . v03.
in-ta, 19U, ls-;ue- 1, 1W, u. i-33-7C,--'-'I'i .2~. items.
-~' C :U-326L, 16 April 1~63, (Letopis '~~hurn;o'- Ir.%I:n 11G. ~, L,,L!)

1. W-MCHMAPOZ A. 14., MEAT, A. L:.
2. USSR (600)
4. Ner7ous System, Sympathetic
7. Pterygopalitine ganglion. Arkhiv anat.gist. i embr. 29 No 5. 1952
9. Monthly List of Russian Accessions, Library of Congress, Fahruarg -1953. Unclassified.

MSHCHERYAKOV A.14.;SYSILK, N.S.
-
Discussion on F. A. Volynskii's and 3. P. Hel-an's article Synapses
of certain abdominal organs. Arkh. anat., Moskva 30 no.2:94-95 M&r-
Apr 1953. (CU4L 24:3)

KESHCHMAKOV, A.H.;KOROTKOW, A.G.
Role of the posterior spinal radices in innervation of the gastro-
intestinal system. Fisiol. zh. SSSR 39 no.4:443-45.0 July-Aug 1953.
(CIAL 25:1)
1, Department of Human AnatonW and Department of Fhy~loloa of Kazan'
State Medical Institute.

on a, s 'acyl

/,,~.Tbe colorimetric determinati
2~1 rc
V T
NR
h
k
r
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M
-
ea A.
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Nailk, Akad. Nauk TahUh,
And ownpkx
Ole- rmctians baweett ;Ijiuorca
p-
coglp(%-. !.bamd that- it was p ~ ~.i- i
b '
~
a
to obtain phosphamolybdc-nurn blite vihich is stable
period of I.S* awntlis. The re=tiou conditions Were
established. Areducitigu,-ciitofthiotireawi~.listicl3yivlds
the plic--phonialybdenum blue whic:i,is stable for 6-8 lirs.
if not heated. Either of tfiLze methods- can be used for the
COlorimetric dem, of phrxip1wric acid and phaipliates.

M.

MESHCHERYAKOV. A.M.
.......
Method for the colorimetric determination of molvbdenum. lzv. Otd.
est. nauk All Tadzh.SSR no. 17:3-15 156. (KIERA 11:8)
1. Kafedra agrokhimii i pochyovedeniya Tadzhikskopo selikhozinatituta.
(M,Olybdenum--AnaIyE;is)
(Colorimetry)

USSR / Human and Animal ';Aorphology - Nervoua System. S
Abs Jour Fief. Zhur. - Diol., No. 22, 1958, 1-')14~,l
Author Meshcher-yakov-,. 1,- 11. ; Korotkov, J'%.. G.
Inst fazan-- Medical Institute
Title Experimental Norphological Materials To-.-ard the
Study of the Sources of Innervation of the Ductua
Deferens.
Orig Pub Sb. nauchn. rabot, Kazansk. med. In-t, 1957, No.
4, 60-69
Abstract In 55 cats and dogs the hypogastric and pudendal
nerves viere trcnsected, along with the anterior
roots of the sacral division of the 31~1nJ cord,
the ductus deferens (DD), and the Internal 2,)er-
matic artery. in addition, the ganglii- of the
sacral division of the truncus eympathIcus were
removed, as well as the pelvic plexus and tale
Card 113

USSP / Human and knimal Morphology - Nervous Syctem- S
AbB Jour pef. Zliur. - Blol., No. 22, 19'--8,
ganglia of tae celiac plexus. DU w--,.-I- 3_-c,'..n that
the DD has both L sympathetic and a parasympathe-
tic Innervation. The sympathetic nerves (SN)
reach the DD through the hypogastric nerves, the
Internal spermatic plexus, and from ~angl'_a of
the lumbar and sacral divisions of tho G.-A.-.-,~,athe-
tic trunk. The SN supply the DD as elther Inde-
pendent nerve bundles or separate fib,rs, or via
bundles of nerve fibers of other origin. In the
pelvic plexus the S11 are not interrupted but pass
through it and proceed to the smooth mucc'_~ layer
of the wall of the DD. Paraaymppthetic fibers
pass to the -_D through the ant,~rior roots olf the
spinal nerves and course with the pelvic p,,_~raeym-
pathetic nerves and the pudendal nerve. These
fibers, as preganglionic fibers, are interrupted
Card 2/3
USSR / Human and Animal Morphology - Nervous System. S
Abs Jour Ref. Zhur. - Biol., No. 22, 1958, No. 1~)34Pl
In the cells of the ganglia of
the processes of which, In the
extend to the wall Of the DD.
DD there are mult1polar nerve
differences In the Innervation
noticed between cats and dogs.
the pelvic plexus,
form'of fibiers,
In the wall of the
3ells. No distinct
of the DD were
Card 3/3

USSR / Human and Animal Morphology - Nervous System. S
Abe Jour : Ref. Zhur. - Biol., No. 22, 1958, No. 101478
Author : Meshcheryakov, A.-M.
Inat : Kazan Medical institute
Title : Experimental Morphological Analysis of the
Structure of the Pudendal Nerve and the Inter-
Relations Between It and the Vegeative Nervous
Plexus of the Pelvis.
Orig Pub : Sb. nauchn. rabot. Kazan8k. med. In-t, 1957, No.
41 116-124.
Abstract : In 150 preparations from 100 cadavers of persons
of varying ages (beginning In the embryonic
stage) and In 35 preparations from cadavers of
dogs, cats, monkeys, sheep, horses, cows, and
pies, It was shown that the pudendal nerve (PN)
Is a complex nerve, consisting, in addition to
Card 1/2
Card 2/2 PC;

UCSP Human and Anim2l XOrP-.~010~~Y., Normal
9706P
.,bs Jour R Zh 0
Author MeBhc errako
Inst Kazan i.e(lic:31 In-tit"te Striict,,re of nn.
Expe rime ntal--~ orp!,0109ic Anall,13is Of tl-e
Title 1. -
Srigentes an, T:ieir Pnrticipation in the of' Nerve
Plexuses of the :,bdoninal Cavitl-,, and Pelvis.
Orip Pub t Sb. nauchn. rahou Kazansk. med. in-t, 191:7, v7p. )j,105-115
Abstrac, 5 o, erperiments on 50 cLts, the nerves of the
.t - In thret, serie J.
pelvis in t:~(, c. vity nf the jlr~ill cj- -J1 .-interior
,9,1)cr.j1 r;i, ~c-- rit thf! Vidnill col-d k,,f- -~.-rtebral canal$
or ill rio,*I-s of th,, marpinal s.ympoUlot I(' t ri~: rj t.hc ,,n( r;J1
. Aftf- "1, -6 j -
region on ot.. si-les) Vipre cut . r ~-/ 11 (", I I , fl, tho
materi,-l w3s sti-i-d, follmiin- irnpr-,.-~i ic"', Ccc-dinp to
Pi I I shovskiy_'roo-Lavrent 'yev. T',e au~',C.r ccr.ClL~Ies- t'r-.at
Card 1/3
USGR / Human and Animal i orpholo-i1r, Normal and Pathnio icic_
Nervous Systep
Abs Jour R Zh Bic-.) 110 21) 195e, No 97068
nervej
sensory (somatic), symPathetic (SN) ane, ppras: mp,3 the tic/(IN
participate in oelvic plexus (pp). SH from formations of
hypogastric plexuses and of nodes of the :aqrr~-inal sympathetic
trunk of tl,,e szcral region are postganglionic; they run
throuFh P_.~ without interruption, and end in the smocth muscles
of the PelAc oy '7an5. PT!, starting in the pcrasympathetic
nucleus of the spinal cord, nass throuph foi-,iptions of 2-h
anterior sacral r2dicles., and enter into pudental and pelvic
nerves. . ')
1~, runninr t:1rough the formation of the nudental
ner,ve, enter into PI pnd end there wit'i a ner~cellular
apparatus on the cells of PP nodes. P-,.- which run through
the formation of the pelvic nerves, pass tl-,rou-h into the
cavity o: toe siu:ll ;)elv,.g and, with one ol' t;:eir narts, end
on the cells ).~ nodes of the ex':.ramural p rt of PP, and with
ti '.e oVer - on the cells of the intrami,rcl port of PP; their
third pcrt runs to the nodes of mesenteric plex"'Ses.
r1ard '2/3

USSR / Human and Ani-mal Morp"oloc-y (Normal and S
Pathological). Nervous System. Peripheral
Nervous System.
Abs jour : Ref Zhur - Blologiya, No 4, 1959, NO- 1~9~5'~
Author : Meshcheryakov,-A.- M.,
Inst : Not given
Title : Comparativo Anat.omy of Inferior
and Superior Hypogastric Plexuses of Man
and Some Vertebrates
Orig Pub : V sb.: Izbr. vopr. morfol. nervn. sistemy I
krovosnabzh. nervov. Chelyabinsk, 1958, 51-57
Abstract : On the cadavers of 10 humans, 6 sea urchins,
2 carasslus, 4 pikes, 10 frogs, 10 lizards,
7 wild ducks, 3 chickens, 2 susliks, 2 rabbit3,
4 Euinea pigs, 10 cats and 10 dogs, It was
shc,,Arn that the inferior mesenteric (IM) and
Card 1/4
55

USSR / Human and Animal 1,1orphology (Normal and
Pathological). Nervous 3ystem. Peripheral
Nervous System.
Xbs Jour Ref Zhur - 31ologiya, No 4, 1959, No. 16-953
superior hypogastric plexuses (jHP) In man
and animals or1w inf
,Inate from the erior
mesenteric ganglion (IG), aortic plexus (AP)
and others. IG In man consists of 1-5
separate nodules, In other mammals of 1-4,
and In lower vertebrates it is not always
f6und. By means of visceral branches I'T is
connected with the 1-3rd lumbar ganglia of
the sympathetic trunk and through the AP
it is connected with solar, superior mesenter-
1c, kidney and adrenal plexuses. SHP In man
lies on the ventral surface of the abdominal
aorta; it consists of nodules of various sIZe
and form. In cats, dogs, guinea pigs and
Card 2/4

USSR / Human and AnJmal MorpholoGy (Normal and
Pathological). Nervous System. Peripheral
Nervous System.
Abs Jour Ref Zhur - Biologlya, No 4, 1959, No. 16953
others, instead of SHP there are hypogastric
nerves which originate from the caudal-
mesenteric ganglion. In fish, amphibians,
reptiles and birds these nerves are still
not differentiated and are in direct
connection with blood vessels. From IG and
AP, branches run to the Inferior mesenteric
artery, forming on it the plexus of the
same name. Secondary plexuses, which
originate as a result of division of the
inferior mesenteric plexus, are In turn
divided Into smaller plexuses. In cats,
dogs, guinea pigs and others the left colic,
S-shaped and superior rectal plexuses are not
Card 3/4
56

"'SSR / Human and Animal Morpholoby (Norm-11 and
Pathological). Nervous System. Peripheral
Nervous System.
Ab3 Jour Ref Zhur - Biologlya, No 4, 1959, No. 16967
Author shc!,-c~~ryak~ovA~.M.
o~
0t 7
, V~r
Inst
Title Participation of nn. Erigontos In the
Formation of Nerve Plexuses of the P'jlvIs
and Abdominal Cavity
Orig Pub : V sb.: Izbr. vopr. morfol. nervn. sistemy i
krovosnabzh. norvov. Cgelyabinsk, 1958, 5-11D
Abstract : In three series of experiments on 50 cats,
either pelvic nerves In the cavity of the
small pelvis, or all anterior spinal-cord
sacral roots or all ganglia of the sacral
region of the marginal sympathetic trunk (M;3T)
Card 1/3
"Ind
Pathological). Nervous System. Puripheral
Nervous system.
N
Ab3 jour Rof Zhur 3iologiya, "o 4, 1959, No. 16967
w u r,~- a,.- c t. o n , d .It was shown that [3orLafI__,
sympathetic and parasympathetic nerves (P,,,:)
Participato In the pelvic plexus (p).
Sympathotic nt~-rvcs from the hypo.,rastric P and
from the ganr 0
~,lla of MST are Post,,_zangllonic and
pass thro-,_~gh the polvic P without Interruption.
PN of the sacral section, beginnin6 from
the parasympathetic nucleus of the spinal
cord, pass In the make-up of 2-4 anterior
sacral roots and enter into nn. erigentes
and n. pudendus. The parasympathotic fibers,
which run In the make-up of the pudendal
nerve, enter the pelvic P and terminat,:~ on
th-, cells of its ganglia. PN which run in
Card 2/3
67

USSR/Hmin~i 111d AlliLlal MO.'-j?hU1,-;LZr -~ (1-1,;rLial aiA. Pathilic4cal)S
Nervous SysteLa. Periplaeral Nervous Syste:.-i.
Abs Jour Ref Zliur Biol., 11~, 6, 1959, 261o6
Author Meshcheryakov, A.M.
L-ist
Title On the Problem of Parasympathetic Nerves of the Sacral
Rer;ion, Report 2.
Orri.,7 Pub V 9b.: lzbr. vjpr. morfol. nervn. sisteLly i krovos,L3b7~i.
nervov. Chelyabinsk, 1958, 16-22
Abstract It was shown on cadavers of 100 huramis (50 adL'-tts, 40
children, 10 embryos), 6 d-)~;s, 4 -.~nrkeys, 5 sheep, 8
horses, 2 cows, 2 piUs and 8 cats that padental nerve
(PN), aside from somatic, mitains also sy-irpathetic a--id
parasympathetic fibers which participate in the form-
tion of pelvic plexus (PP). S)Txpathetic fibers enter
into the coETposition of FN in t1le region of tl-.e simll
pelvic from the nodes of the sacral rejon, Df the
Card 1/2
L8

NIESHCHERYAKOV, A.M.; KORDTKOV, A.G.
Valarii Ilikolaevich Murat; on his 60th birthday. Ark-h.anat.gist.i
embr. 39 no.11:128 N 160. (MIRA 14:5~
(MURAT, VALERII NIKOLA-EVICH, 1900-)

NES'PC=AKOV, A.!~.
Importance of the ratio between acid aund the anions ---I
colori-metric determLnatlor. of phosphcirus. Pachvovede.-Ae no. 2:
75-80 F 165 (mT7,,*~ 1~:l)
1. Tadzhikskiv sel-tskok-ozyaystve-rry,, Dunhanbe.
S~abmitted August 1, 1963.

KIISHCHICRYAKOV, A.N.
---, !a* Ik6tween bromides and morphine. Farm. i toka. 19 no.5:
22-24 3-0 '50'. NLRA 10:3)
1. Kafedra farmakologii (zav. - prof. A.K.Sangaylo) Sverdlovskogo
maditsinakogo instituta.
(MORPHINE. antagonists.
bromides (Rua))
(BROMIDES. antagonists.
morphine (Rue))

I-L3HCH-~:Mi~OV,, A. N.
"r I
Reialr of Wimaged Concrete by the Method of Cementation," Gidrotekhnicheskoye
Stroitelstvo, I.Ioscow, 1947.

GARICHEV, I.A., inzh.; RESHCHERYAKOV, A.V,, inzh.; KHEYFETS, V.B.
Nov methods of ma-king antiacepage curtains. Gidrstroi-31 no.2:14-12
F 161. (KIRA 14:3)
(Soil percolation) (Grouting)

MESHCHERYAK07, A.N., inzh.
Cylindrical enclosure for the underwater repair of wrickat
gates of draft tubes of the Dnieper Hydroelectric Power Station.
Energ. stroi. no.Z7:50-60 162. (MIRA 15:9)
1. Treat "Gidrospetastroy".
(Dnieper Hydroelectric Power Station.-Maintenance and repair)

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'L
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0 0 Components of "fety fuels. It N. Andit-q,ir, A P 1 1-11 ... K III, I'tt'-f I", Xl I", W. FOLI" V"M
so Mrsheficir#iWol. - vid A It Pelf- J APPIWd (,he. I. "` 1, 2 1:1 .; " .1, 1 47' 1. 1. It, ..' '.I o. I
19, ON-W191MItal - Ill file -49, 1 " ' t2j 1-1 1, -ov I"'J.1 by
00 9 fur high ttuffing. explumuto-dr, high-ctAtic hydirtwattom
the folliming wvfr ~,Iyi)IbrMzrt1: 11) Diturr of ditsotmilyle"'
1 44:15. d" hi-1 ... l -70 1 (1 I-1-ropvt
so
se -00
at U'. 20- -Ith of Ill,
I., th.-Il crit'hiAlly -00
p.tvitfito, ra-loo, oy-f [It, t 1,
. ..... 'loit roe
go 411hr~ajnel,mp, 12M9 C,M.
ywided 7'_' g. of the fr,,tion b. 2.1ol-27,11% b 24# 5", 1 =00
sod '10 1'
000 letriflin (IV), bi, the ~alfle "Irtho,l I tctrj!in 0
00.3 ywid"I Mg. of th, fr.o it.... 1, ~141) of fit,- theory
)Vrpyltx-Ijjettr. fly file "ote crietho,1. t6i A niat of
%ttodard Haku fl.k~tlctac. ort4ne no N 117 1. with 17", it,
give X 72.,%; calrd. trazirig A of 11 - 11MA. ;7, Addo. 4 goo
Ill to r-lum .1 N 70.0, lp- N 71 2. 5 -1.
phi of (14)" i-141le pt~_ fix the Illiat oilly A MI it
171 A osi%t. of 7.5';. ewohne (A 67 1) with 25" 1, da-1.1-
1. J" 1~1". -105 lf~ve N
I WRIS ;' 0 0
1-W 1412. %aled. N' It)-, uail. of 7W ii.t.dia, *it If
j too *
N. Thon
Ipt
M
so
410. S L ddTALLLMGKAL LITERATUSE CLAMINO'KATION
It* 0
It goo
iT- a it IF JA 0-0 1 -W of 'i a a ) 0 T -~t - -
EfUs At of 0 a 0 R 0 if a a 9 111 K to M It a Kill a I , [A
0 00 0 is a * 0 4 0 0 0 0 0 0 *is 0 0 0 0 0 0 0 0
1440 0 000 so 0000 00 0 * * 0 -o-q-A-e- a 0 000006000 960011

000 GO OGG 000 0 So go OGG I
#00900060006066 0
A 8 1. 9&--J AL- A.A. Q It 3 1W V !---AII AA N CC 9VU
4r.
5521. OXIDATION OF TRIISOBUTYLEME. 14sghobqrXAkkQV. A.P. (Dokiady kkad.
Nauk S.S.S.R. (Rep. Aced. Sol. U.S-.S.R.), *1948, vol. 60, 339-
400. The trilsobutylene obtained by Butlerov (J. Rues. Phys.
Chou. Soc.. 1879, vol. U, 197) has been shown by Whit-wre
j (J. Amer. Chou. Soo.. It?41, vol. 68, 2045) to te n =Irture of 1:
1-dImeopentylethylone and 2#2t4t6t6-p*ntuwthyI-3-h~pt~n~. Oxidn
of trIlsobutylene under varying degrees of severity yielded meld
Gov mixtures of different m.p., the yield decreasing with rigs of m.p.
The higher m.p. acids (91-90C.) obtained L7 the milder selective
oxidn conditions (200C., 6 vol. 50% H2S04 with gradual addition
of an equal wt (on the bydrocarbon) of K2Cr2O7 contain a 711ter
proportion of methl-tert-butylneopentylacetic acid. (L
lee
40W
U VI 1. -0 Lt 4 sta I V-IA Joe
;OP ro is W Is 4 It 09 in A1 X4
.T.,.- 0 * 0 * 0
41A. 0.-A- 0 a 0 a 4 a 0 0 0 0 0

.,SjiCh:-Z-jAY,GV) A. F.
FA -/7T-J'- 4
USSR/Chemistry - Tri-Isobutylene Apr 194k
Chemistry - Oxidation
"The Oxidation of Tri-Isobutylene," A. P. Hashcher7a-
kov, 2 pp
"Dok Ak Nauk SSSR" Vol LX, No 3
Discovery of new method for oxidation of tri-ioobuty-
lone permits a selective oxidization of isomers for
purpose of obtaining mixtures of acid with not
readily accessible methyl-tributylneopentilacetic
acid. Sabmitted by Acad A. N. Neameyanov 24 Feb 1948.
7 4

Thm catapaUthom and atsuctwir of dilsabutylonvo and tri
k"butlidn" fasmad (Fain i-butyl MICOW undirr th. k."m
sacs, at $uUu*ts &d#4 A 1, SI.Ju %I I
and A - I). I'virov (A-4i ~-J- P~S-S %1- "" 1
,1kaj. .%ouk S.S..~.R_ 04fel. Abim. V,Ikk IOR).
Refluxing 1.2 L 40-1;110[t Witt) 1.21 M" H'SO, f, hr-
And sep%.. washing. and drying the Mg. IAV(r - 94- -,!, ~"-:
ds. and jYijjobulvlrxt%, with -m, 30", dii-koivirm-, The
-o't'lcd '.1
It ... *1"W -1-1 11"'t 1"
Al. "n 'N'to "I'l A..'
("o,"h'I p-I.- 1~ 1;.( t't'*
1,
044, Of I JiMS. mod i"',
NJ., 1 401,21; Cutifittoation %&' had I'v 14,1111m, 'pri Ir.4 ~J th,
minixI.. and of their hYlifoOMAIIII-I 141-111,11 10. 1141huhli.
r( al.. ('..1 38. 14271). The votire ocietiv trartiou m thi.
I-a,m' - Ki.m 1he Conlim : - -
'5" IL 151, 1. And 10C,
-'.3.4-itiowitivi anal~,c Th,, "bijowd -
.1th that( "maos"I tr"m L..t at it h
th, Nm"dn (t
K-'-I Ith
oodi- t C .1 35. IVA411 "1111,6111", I'v 'I".1 ......... 1, ,-1
ICA- the Hutlet- Avid JJ Ro,, i'hv~ ( h- 147
. I?(-,:i i. it, 1117(114711) 1. m. 6.5 7" t-all, mi i~s
virldlog thi, M, V.1'r 'm's . b ~"17' i1i'". '1: -0~%o. .~?
1 440.9; the free arld ga'r a donril'. fri'd ,I sit C'11. Thi,
'ni'lall"n pr-hjo. .1, Or"13cal .1111 111- fr"o' Ito-Imly
Ir", '-Jr fr"m I-boti,lvo' al W C. N1 ~-"Ijj-tv

17-:13W!hysics Combination "I p r i! i7 ry r.,c r r
Study of the 'IeFree -,I -~rr; G-rta I n A-1 colic ss ttr--J' r.e
~:omE ngt-' on ---:c,-. t t c-rinF o f 1-1`7~-t
inst c-'L Or~,, Cher., 'A.Cad Lci U3,3R,
"~-'hur H.kSrer i Teoret Fiz" Vol C.". , 'lo
Shows 1hy subl.ect Jl.nc-(-.'ftl-*~~ i1.
of a'cchol-~ (Tentame'.hyl etl~,,irrl, tl-n 1, 1
r c 7, E. n t w i ~,, c7 4- c n n

lei fifla tsbil ty io w a A h1v
&.-JL- ga It J. a j a L AL N Alk
00
00
so L!tkryvkr K-mist Folyotrat t
HunChrian Journal of Chomistry
vol. 46 195C,
t~ci. 12 docamber
0
90"
e a e 12 e a a a a 0 o a a o a
11 jj u id z w v If ;F 0 v tj 0 60 is
A
-09
"00
1 11106
UOO
1 -41 a-# 0 .4. 4v JPIF.
r -, . I I, I It, W- T T
n #A I 1 6 1" 0 IS a a I
I# so Is d 01 9 1 (1 cc M I I 7A #AQ
0 0 0:6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6 0 0 0 0 4, 0 0 0 0 0 0
41 0 0 0 0 0 0 0 0 0 0 0 Mi 0 6 0 0 0 0

Usa/chemistry Hydrocarbons Sep/Oct ~5I
and
Tlitl6obutetes by-the Koudikov Ri&ction, 'j A..P.
*ahchj~kyakov, L. ~K. PetrDva, Inst of Org Chem,
Aced Sci-USSR
"Iz-At Sauk SSSR, Otdel Xhim Waukn No 5, PP 576~-581
P,nn carefuI3,T~Iisolated of-form -cf-trii-idbutene
di.iiiopeutylethyferie)--4itthiisized 4-ucq]0eixtyl-6,6-
dimethylh~6ptene-3-63,6-2 and ~5~-beqpettyl-2,727-
irimethyloctene-4-oue-3. From, diisobutene eynthe-
sized ^2,5,T,7-tetrametiqloctene-4-one-a3.
199w
USSR/Chemistry - Hydrocarbons SeP/Oct 51
(Coutd)
Maracterizes all 3--products. DiacusseB Teaction -
u0chv=izu and determlaes colapu of initial triiso-
butene (mixt of and j&-forms).
195T17
E-
P

-1
. 7 , "", ! , ".
j, ,,, . - '. -1 1, r. .
"Ihe life and work of 'iTkolai -.1exandrovich 71-il r- zha-,; . " ~. . -. . ,
Rrilr-zhaevii, -H. N. wid ~k�hchery,~~ov. A. F. (p. 1-,P25)
~ ~ *--rj-~jj 1 .~". , "')"
C,: journal of Getj(-rui t~ry (Z', ir-iLl . 1 1. , . I " ~ , '~C, 'I.

HESHCHkIRYAKI)V, i..P.; PETROVA. L.V.
Cleavage of the elm2entp of hydrogea halides from monohalides of hydro-
carbons of the C H2 2 aeries. Bull. Acad. Sci. U.S.S.R., Div. Cnan.
Sci. f52, 165-9 Nng"L translat.ionh
(CA 47 no.19:9896 153)

USSR/Chemistry - Hydrocarbons J06U/Feb 52
"Splitting Off of Elements of Hydrogen Halides Frcm
M=ohalogen Derivatives of Hydrocarbons of the
CnH2n+2 Series," A. P. Meshcheryakov, L. V. Petrova,
Inst of Org Chem, Acad Sci USSR
"1z Ak Nauk, Otdel lQiim Nauk" No 1, PP 152-156
KOH in alc will splic the hydrogen n-eded for
formation of hydro6:fn halides from halogen hydrins
of dimethyl neopentyl carbinol (2Cl(I) 2,4,4,-
trimethylpentane). The hydrogen splits off from
the most highly hydrogenated C-atom, of a methyl
208T12
USSR/Chemistry - Hydrocarbons Jan /~'eb 52
(Contd)
rather than a metb-Lvzne group, contrary to ZaytsyevIa
rule. This exception to the rule can be explained
,by presence of the neopentyl radical, just as the
addn of hydrogen bromide to neopentyl ethylene is
the only exception to MarkovrAikovs rule. The
quantity of the$ -form in di-isobutene depends on
the conditions under which it is obtained. Di-
I
isobutene obtained by Butlerov,s method contained
the highest uantity (approx 20%). A much sma.1ler
quantity (10;) was obtained in the splitting off of
HCl with alcoholic alkali from 2 Cl (or 1) 2,4,4-
trimethylpentane.
2O&=
0
~14
-:4

ab, V-1T
lie,
Teti
..........
wy.

Ari A P
AWIM04'"Mud S.S.S.R., Itsi(.
lezy Or Soedinenil, Sbornsk 2,
537i.fteating with stirring a mixt. of 50 g. KOH, 2.5 1.
HO, and 365 S. KMnO4 at 50-5* while over I hr. ld8 g.
triMbutylene is added, followed by 4 lus. at &&-Wa, stir-
ring without heating 0 hrs., cooling, steam distn., addn. of
150 ml. MeOH to the ftask residue, filtration of MnO3, and
concu. of the eq. filtrate gave MeICCO~X in residual suln.
This treated with 350 mi. 15% HjSO4 and extd. with EtIO
gave o evapn. of the dried ext. and distn. of the residue
21.5% AlesCCO:11, b. IIJ2--4*. G. M. Kasolapoff

OSSR/Chemistry - Hydrocarbons 1. Jul 52
"Synthesis of Hydrocarbons of the Composition Clo-C
With Two Quaternary Carbon Atoms," A. F. Meshcherya
Ye. I. Erzyutova, A. D. Petrov, Corr Mem, Acad Sci
USSR
"Dok Ak Nauk SSSR" Vol LXXXV, No 1, PP 111-113
2-chloro-2, 3, 3-trimethylbutene and 3-chloro-3, 4,
4-trimethylpentane are comparatively uareactive in the
Srignard-Wnertz synthesis leading to hydrotarbona
with 2 quaternary carbon atoms. 2,2,2,-Trimethyl-3-
ethylpentane, 2,2,3,3-tetramethyi-Pentane, 2,2,3,3,5-
patntamethylhexane, and 2,2,3,3,-tetr&methyIhexene-5
Vere synthesized and characterized. On the ezample
of the synthesis of 2,2,3,3-tetramethylhezene-5, it
vas shown that using an alkyl halide with a double
bond in the beta position does not, increAse the yield
of hydrocarbons contaiiaijag,, 2 rows of quaternary
czxbon atoms.
224T16

I
q

MEN

of 2 3 -irlmod
kir, and
YSA
k4
Nat4 10S5'M57-iQl
,
llydrage ion of 2 )
-mat lvl-lptnltt:n4,o le~At 2 DD
l~ '

-1 -; I'l . - --- - : ---, - 7
U'ver 15 g. AhOi and 30 -0. N
v
t
entanol. - (1),
d- A IIN* rimetia-6)a -druill *80-
1.4381 at
of I irly

7d 2
mi
3 4-turartgov
tanc And 2 3
3-trimet1hylo:
n
,
,
e
at'.
pnnlanc If the hidrogenatiOlflis run aver bli on 910j
280-MV 2,3-diruethylbumne is fo ed. .1 (2-5 ar.4 fj
r1l
I
Nlg in Et3O.treated with 27.3 g. AcCl gave A-5.690
'159, w1dch pyroll ~ at
9,--7*, .&M, tiU 1.42 2t
W* over g-lasa wrKA tij mixed 2,3,3-trimabyl-4-pentana and -
A b
identified by oxidalon in Y.-
phys, con~L-. 2,',3-Tf!mwhyljn!ntahe was prepd, by the
*
rau I ur
r gnud tu; L ?rofluci, b. ll,!-14,5
, d 0,727.5,
of 2,3-dim
-v,-ve the ztd.-aitalog, b: d:11 O.K:173. .42,? 1.408,
94-5
(2,44.j.

V

-----------
USSR Physical Chemistry. Molecules. Chemical Bond B-4
Abs Jour Ref Zhur - Khimiya, No s, 1957, 25790
Author A.P. Mashcheryakov, M.I. Batuyev, A.D. Mat-veyeva.
1rult i Andamy of Soienoeu of USSR
Title Synthesis of Tertiary Butyl Hydroperoxide &nd Ditortiar),
Butyl Peroxide and Their Optical Study in Lif~it of Ques-
tion of Hydroren PGroxide Structure.
Orie, Pub i Izv. AN SSSR, Qtd. khim. ri., 19155, No 4, 742-749
Abstract Tertiary butyl hydroperoxide (I) and ditertiary butyl ',y-
droperoxide (II) were prepared by alkylation of I mol of
27% If202 with 2 mols of monotertiary butyl sulfuric acid
(III) at 0 to 100 in the duration of 4 to 5 hours; the
yield was 80%. 11 is separated from I by the treatment
vrith a 10 to 201/o NaOll solution at 0 to 10o. III is propa-
red b-i the absorption of isobut-y1ene by the 63~. ~T So at 0
6
to 20 . Spectra of combined scattertrw, of I mid If are
Cam 1/2 - 33 -

A JT- ~ U 3a t uy -,v C, v v L-- va A.D. 3 2 9
TIT L- C, t 11 v e 1 r
t
Is ou 't, L.,:u .~e i I
,
C- r 3 v
Cl_,4
_R I 'I';- -'A L
r
.5 in, inciinatll f L) -4 n
first time 't~j 31t!~.,,,v b, ni :,luli,
described in a serf's cf pa!~--rs. was a!L;o
of .-,.ciche-ical
Llri: e:Lhayev, V
ol
t-r:.e- cit to t r, i u' r
1.~D~ at
;,-al
a:,,, c t s i
e ~~rres- -,L)n6ii-, i:j Q 1~ w i t e
ff-ictlon oll t r i z,r n ar~ :.a r fz rir,~ s' .',l r t h L ro -
J. L r - L ~l 1, a v e G 1,::.:3 t a-. ea r ~i fo r.iim, i o.. o f n ir, -
es t po 1, a I d -'C, 1-t c , .,A -1,~: -ii. t:lc ioy;e,-, L st:l-~es Qf ;Jzd~ -
:----vizaticn. .,rt- it vi 2, s a i i , e c~tI . L t'.-l ~- a j S 1.~lp t i 0 11 c o,, -
a i t 'D 1c; J:) 1 e iii tne
Carc 1/ E c- t .--r3 (by
2 1 - -- C,! L::~- -

f
t I
inveroloi. 1s, tc tnt~ lae
I t U klxll I 1~ f- c ~ t: r
C;! 1
Institute o' :'ineral Fuels, AS USSR (Institk.t -c,ryuc,-, h
ik
iJSk%j. a~ t~ , - ., r. -,, - ~ - ~, i rvfi ik . ......
i - i.,.
AVAI ~~A 1, i b
1. Isobutylene-Polymerization

14, F
A vJ I A P. , P~AI-2v-,
;'IT LZ: Mono-
cnloroan.,1yc.riL;e i:,3tcra o1 Ui.j i~_ A~;i,-
k; tokio lot iz .,c r i o v
i o 1 1 n c;,/
PERIODICAL: A, OWeleniye
r lob I
ABSTHACT: a11me..-.o(;_; fu~' thu prok.:,4,.;tior1 u." r~fcre:-~C,S 1-4)
thu cuL"i~-tic :i_tnoz of syntlicsis desurvc special attc.,.t_i6:..
Esp,~ciallj tnosQ 'based u-n the ai'..,.ane basis and of "hc anh, crides
and chloroanhydrid-,:j ,)f thk-- or dibasic U,i(is . In the 2rc-
s~nt paper the aUL:.C~1'3 r-,)ort tnat for th~ first ti;,ie fro- cor-
alkenes anr! c~iloroan.-,-drides accovdin,- to t,:e cata-
1, tic .:.,t.-.od -x~,re s `-'Ieto-7-deccne ac' 2
et:"~/ 1 - C, c t c, -7 -n:~ c c. t (, d e? a%0 nc.
dodekane acid; 7,7,
8-triz.et'-yi-6-*-c,to:~e:~,:nar.,e rcid; 7) 6, -1 c d
b f. a i n ed 'cj 6 fo r e c: ~.,s ~; f e 1 nt - rj~an I c z; e s iC3 T,1 e re
.9. r 0 b r e fe r (.n c e -i 2 w ch -3 r I av c -
1/2
bard ,

0 TI t t h i t, t A 1 0 ri 0-
A 0 1 A'~ I C i t,41 0 f j i: A S i
1!~s t -4 t1 t i ~;`: cj cy k;; i i. i,, 41 i I i ~..-i'~o -o A
S j L L JAy 1-~3, 1",-17
AVAILA3LI:.. Librtr, of'
1. Keto acid3-Synthe5iS
C a r a 2,/ 2

AUTHORS: Meshchery-~.-ov, A. P., ^,11.%,:hovtqev, V.G. 1~_2 - rl~-6-2 '7 7
TITLE: The Synthecis of 1-Cyclo-)i~oi)yl-2-C,,,clohexyleyclopro,-,,tno
(Sirtez 1-tsiklopropil-2-tsiklol,-eksiltzil-.Iol)ro,):r.,i)
PERIODICAL: Izvestiya AknJerii nati!: MR, Otdoloniye
19 50, Nr 6, ?d - 720 - 7-`/ ( US 5R )
ABSTRACT: In the present paper th authors describe a mc.,thod of s--Ilt"ct-
ization wihich they wor~-ed out for 1-c.-clo;~ropyl-2-cyclohexyl-
cyclopropane. Besider, the a~.ithora tried to obtain 1-cycloorop-11-
-2-he:~ylcyclopro~lane fron 11 enantovoy"aldehyde (?) and net.,-l-
cycloprop, Ike t~ one under the sa--!e conditio-~n. Irigte;,.d of an
a-octenylcyclopropyl 'zotone, tetradecere-6-on-8 was, howejer,
obtained. A new met'iod of obt-inin.- r nione from
I _ 5-rhlorine-2-i~et :
acetoprop,vlalcohol -Lnd hydrochloric acid ,,,ac wDr~~erl out. T".e
condensation of methylcyclopropylk-,2 tone under the action of
catalysts (alcoholic KOH, C 2H 5 ONa, Ba(011) 21 B -- (3H)2'11-_ , 1i a OLT,
KO11) was investi.,_,ated. 2,,!r,6-tricyc1opropyl-2,4 epox-, -hexanon-6
Was ohtained. There are 7 refereces, I of which is Soviet.
Card 1/12

The Synt:.esis of I-Cyclo,ro~jl-2-Cyc'Lohc---,71c-) Ic I oj~ro ,--n p- 60,7/ 62 - - 8-,~ -, ~ .- -
ASSOCIATION: Listitut or[.~-anicheskoy 1-hiriii im. IN D.Zelir 2koco Al-zade.'.Iii nauk
SSSR (Institute of Or~:anic Che-.iistry imeni N.D.-elinskiyAS USSR)
SUBMITTED: January 21, 195C
1. F'rapanes--Synthesis 2. Ketones--Condensation 3. Alcohols
--Chemical reactions 4. Rydrochioric acid--Chemical reaction.L~
5. Catalysts--Performance
Card 212

HESHCMYAKOV, A.P.; PWROVA, L.V.; YEGOROV, Yu.P.
Reactivity of .4, p -unsaturated ketones and f~-halogen ketones in
Kizhner reactions. Zhur.ob.khim. 28 no.9:2588-2595 3 158.
(MIRA 11:11)
1. Institut organichaskoy khimii AN SSSR.
(Ketones)

MAKARE17KOV, V.V.; MESUCHERYAKOV. A.P.; PANCHRITKOV, G.M.; PLATE, A.F.;
SH=IT. IT.I.; TAEDVUVMT, V.V.
Effect of the structure of individual h7drocarbons and others on
their combustion rate. Izv. vys. ucheb. zav.: neft' i gaz 2 no.4:
71-78 '59. (MURA 12: 10)
l.Moskovskiy institut neftakhimichookoy i gazovoy promy'shlonnosti
im. akad. I.M. GubkIna.
(E~rdrocarbons) (Ethers) (Combustion)

5M SOV/62-59-8-26/42
AUTHORS: Batuyev, 1% 1., P., Matveyeva, A. D.
TITLE: Raman Spectra of Divinyl Acetylene
PEhIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 8, pp 1485-1487 (USSR)
ABSTRACT: The spectra were photographed by mejns of the spectrograph of the
type ISP-51 with the Hg line (435a ). The individual lines
obtained for the compound CH 2 - CH-C-=C-CH-CH2 are given. Within
the range of the triple bond two basic frequencies (intensive
doublet) were obtained at 2165 and 2206 cm- ,and four
frequencies in the range of the double bonds (intensive doublet),
1 1
at 1566, 1601 om- , and two weaker lines at 1629 cm- . The
appearance of the doublet is due to the possibility of the
existence of rotatoryisomere. The splitting-up of the
frequencies of the double bonds is interpreted as the splitting
of the frequency of the bond oscillations of two identical double
bonds in each of the two possible isomers. The great number of
lines (44 as against ~O in the case of one form only) is
Card 1/3 considered to point to the probable existence of both isomers.

Raman Spectra of Divinyl Acetylene SOV/62-59-6-26/42
The multiple bonds must, according to thra energy minimum of the
bond system, lie in one plane. On this condition the two isomers
(the cis (I) and trans forms (II)) art, possible. The authors
continue by attributine the several lines obtained tothe two
isomers by means of comparing them with the infrared spectrum.
The lines are also interpreted as reaulting from the mutual
influence of double bond - triple bond and double bond - double
bond. A table lists the frequencies of the oscillations of the
individual bond types. It follows that the triple bond in (1)
with a hi.-h electron density corresponds to a pair of double
bonds with a reduced electron donsity, while the triple bond in
(II) with a reducod electron density corregponds to a pair of
double bonds with a high electron density, The elt;ctron shells of
the C atoms of the triple bond in M are mort-, asymmetrical than
in (II) so that there is a greater influence of this bond upon
the double bonds in (I) than there is in (II). In the liquid
Card 213

Raman Spectra of Divinyl Acetylene sovl62-rg-6-26142
phase both isomeric forms are encountered; however, there is a
marked preponderance of the trans form. There are 1 table and
9 references, 4 of which are Soviet.
ASSOCIATION: institut ' goryuchikh iskopayemykh - Institut organicheskoy
khimii im. N. D. Zelinskogo kkademii na~ik SSSR ( Institute of
Mineral Fuels; Tnstitute of Organic Chemistry imeni
N.D. Zelinskiy of the Academy of Sciences, USSR)
SUBM."TTED: January 21, 1959
Care

5 (3)
AUTHORS: bleshcherjakov, A. P., Glukhovtse7, V. 7,. 17OV/62-59-8-28/42
TITLE? Preparative Method for the Synthesis of ble thylpy ol opropylke tone
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr B!, pp 1490-1492 (USSR)
ABSTRACT First of all a gurvoy of the development of the preparative
method for the above mentioned compound Is given and the
following Soviet scientists are cited: IdzIkovskaya and Vagner
(Ref 11), Demlyanov and Pinegin (Ref 12), Rozanov (Ref 15)9
Slobodin and Shokhor (Ref 16), Zelinakiy and Dentgin (Ref 18),
D'yakonov (Ref 19). Acetopropylehloride was synthesized as the
initial product for the ensuing synthesis of methyloyclopropyl-
ketone. In the course of this process the method used up to now
could be improved so as to permit a yield of 7(f/v instead of 6e/o.
Methyloyclopropylketone was obtained from acetylchloride and
caustic potash with a yield of 95% compared to the maximum
yield of 76% which has so far been obtained. A descriDtion of
the syntheses and the physical data of the materials obtained
are given in the experimental part, There are 27 references,
11 of which are Soviet.
Card 1/2

Preparative Method for the Synthesis of Methyl- SOV/62-59-8-26/42
cyclopropylketone
ASSOCIATION: Institut organicheskoy Ichimii im. N. D. Zelinakogo Akademii nauk
SSSR (Institute of organic Chemistry imeni N. D. Zelinskiy,
Academy of Sciences, USSR)
SUBMT TTED: February 9, 1959
.A.
Card 2/2

5;34oo.
AUTHORS:
TITLE:
PERIODICAL:
ABSTRACT:
77088
sov/62-59-12-32/43
Freydlin, 1., Kh., Me v
shcheryako A. P. , Gorshkov,
V, I., and Glukhov tsev,
Brief Communication, Selective Reduction of Methyl
Cyclcnropyl Ketone Over the Zinc Catalysts
Izvestlya Akademil nauk SSSR. Otdeleniye khimich-
eskikh nauk, 1959, Nr 12, pp 223-1-2239 (USSR)
In catalytic reduction of methyl cyclopropyl
ketone, two groups can be reducedi the carbony-7
group and t-hi, trimiethy-lene ring:
(:113 1:11 (011) (At
-(Af, (:If (Off) cIf,-C1f' -(:If, (11)
Clf~-("o C11, C11" CH, 1111)
C11, 01 Ctl
[:If,
Card 1/3
The authors have found that Zn and Zn-Cu catalysts
Br-ief Communication. Selective Reduction of 77088
Methyl Cyclopropyl Ketone Over the Zinc sov/62-59-12-32/43
Catalysts (in the temperature interval 80-160 0 and 130 atm
pressure) cause selective reduction of the carbonyl
group, according to path (I) of the a8ove equation,
while Cu catalysts ftrst cause (at 80 ) hydro-
trimethylene r ng (path III
genation of the
01-Pentanol is formed above 125 This behavior of
methy'l cycloproPY1 ketone during nat'plytic reduction
is similar to the reduction of -unsaturated
ketones (and aldehydes). There are 2 figures;
2 tables; and J.0 references, 7 Soviet, 3 U.S. The
U.S. references are: V. A. Slabey, P. H. Wise, J.
Am. Chem. Soc., 71, 3252 p949); R. V. Volkenburgh,,
K. W. Greenlee, J. M. Derfer, C. E. Boord, J. Am.
Chem. Soc., 71, 3595 (1949); W. F. Bruce, G. Mueller,
J. Selfter, J. L. Szabo, U. S. Pat. 2494o84, Chem.
Abstr., 45, 177 (1951).
ASSOCIATION: N. D. Zelinskiy Institute of Organic Chemistry of
the Academy of Sciences, USSR (Institut organicheskoy
Card 2/3

Brief Communication. Selective Reduction of 77088
Methyl Cyclopropyl Ketone Over the Zinc soli/62-59-12-32/43
Catalysts
SUBMITTED:
khimii imeni N. D. Zelinskogo Akademil nauk SSSR)
May 4, 1959
Card 3/3

5 3
T.
A
Meshcneryarcv, A. e
T I T LE ~Ynt~-esis -f 1 ente- I z
-f -"-.e -F.-r:n cf
3,-itlerov's Tri-,s :/3--fc=-,, -.riizcb-.~~--ena 3utiercva'
PEKODICAL: Dok'-ady Akade--9-4i 1~5.), VcI 124, Nr 4, i~!~ 826-821-',
N
U 13 SR,
A-B 3 RA C T -
) ascri'j-ed tne s~.~uctur
A. M. Butlercv e of the ab~ve-
mer,~~--cned corr.-.ound tc t-e tra.-s-butylene that was synthesized
by him 'or the tize. La7-~~r ~n, t-e:, sczlent~-stS prcved
J 'Ref= 2 -c
t`.at tr-4 sobuty'ene 3 a m ml x - e -~ f 4 -4, e
us, the ~rc'-, lem ~~: '-e `,2= ref er-ed h e q-,.; S
not yet betvn sc Ived. :t -.was --e:-ef:;re f ini
the vv-ys of syn-,-esiz:.ng y d r o c arb c n an d t c 3 t s
properties. J~ch a wa~- -vas 6~:owr "y ..e cf
di-tert-butyl isop.-cpy! I. T.-a a,;~',Lrs fcund ",&-
therein the primary dehydrat:--.n -,s aci-I med-,-:z,
Ln this case, the double bond is snifted from the /3 - towar.
an (X -posit'Lor. and the skeleton cf the s~(:-.thesized alkene , s
changed. The dehydfation n-rr~cesses ~erfcrmed by t,e
Card according to Zigler Ref 2) -r. t'-.2 acticr Z~i

Synthesis of 2,4,4-Trimethyl-11-Tert-B-;7yl Pente:~e-2 30V/2---124-4-271
-,he A -Form Of 3ut7_~-rcv, 5
HC1 at -"CG and .3` by wa~- Lf A- 0 221-~
2
formaticr, of a mix-,;xa of -:3_Kef~es ex--las--vely
bent
e r.-~ as we- as ~cs~iz_-
--n -rdJer to remole
the sVeleton -,h-a at,t'~crs a I e Id L C'~n _Q
metLud of xanthatior. 'Ref E,,e- j.n 'his case, however, :`ey
could synthesize for the frs~ t:::ie, on tlll~~ le~:ylrat;.on ~f
di-tert-bl.ityl isc~ropyl `-e crdinary de"aydraticn
product mentioned th~_ ir additicn tc t,e Isomers
Cn - cx~ia' a~etcra -ind hexanet'ny_
acetone were jsol*ated. Th-2f,3 q r~?fererces, 5 cf which. ars~
Scviet.
AS,30CIATIO? z Instit,;t crganic~,.esk,./ D. Zelinskcgo Akadem_~~_
nauk SSSR (Institute of OrEani_- "nemistry Imeni D~ Ze-:r;~ki-I
.of the Academy cf S_-_Jences, Ussiq,,
PRESENTED: July 28, 1-058, by A. A. Ba.9-nd-n, kcademic:.ar.
J
SUBMITTED julY 17, 19~~8
Card 2/2

5 (3)
AUTHOfit: Meshcherypl-rn'. A 12~ SOV120-128-1. 2q/58
TITLE: Density and Families of Isoalkanee
PERIODICAL. Doklady Akademii nauk SSSR~ 1959.; Vol 126; Nr 1 pp 95 ~48 (USSR)
ABSTRACT: The data computed by the author by a method by Tatevskiy (Ref 13),
the experimental data (Refs 7,10). and the data calculated by
Francis (Ref *12) served for plotting a d-Lagram of tbr, increase
in the density of isoalkanes with the composition C k' FAg 1),
Isoalkanes of the kind 6"'20
R H R H
I I
R C R and R C, ..)n -C H,
R R R
have the highest density, Isoalkane groups with the same number
of different wjbtypei cf atomin linkages but of different
structure are knovm as famill,ee of isoalkanes. By computing of
the density of one of the family members, the density of ary
other member of the respective familj can be found with
correctness to three significant figures. With increasing
molecular weignt, the number of families increases; and at a
Card 1/2 higher bpan,~hing degree of the al-kane mole--.ule the density of

Density and Families of isr-,alkanes
SOV12C-.125-1
any isomer gradua:ly gTows until a maxiarom i.a attal,aed~
Cont-rary *o the lower alkanas C 7H16 'CaH,, each -,f -afti,:h ~-,onta--Lns
an isomer with a maximum density the higher a-1,-kan,-.s exhibit whole
alkane families with a maximum or apprc.ximakivily ma-(im-um dang.1ty
Proceeding from wi Investtgation of .-.hemjcs,1 stTuct.,.iraa foraluias
of all members of the alkane family the fr~.rmerly menti--)nEd fa.-I
allows fcr a of the hydrocarbon th~ zynthesi., c~f vthl-,h
reqlaires that smallest steri:: hirid-ranres isomerization Ptieriomena.
and disscc'-atiou of init'al ~..ompouuda be si~rmount-ei The term
fautily may also be used for claaaifyine, other hydr,5r;-1.rb,--,n g-oups
pa�tia,,z'Aa-,-1.y of highesij-~ isoallcanes: acetylene hydr-*.,curb.-ns
Thdre axe 1 figure and 21 refer&nt~ss '0 of which ire Soviet
ASSOCIATION; Institut organi~,heskt-)y khimii im, IN. D, Zelinskcg~- Akadem-,i nauk
SSSR (Institute of Organi- Chemistry imeni N. D. Zeliriskiy of
the Academy of Sciences U-3SR)
PRESENTED: April 10, 19~-qj by B- A. Ka2anskiy A~ademi.:iaz-
SUBMITTED: April 9., 1959
Card 2/2

i i 0 i
T J T LEI
la! 1
P ER 10 D I C" A L:
A F-, S), T

t I,
T'a b 1,
c:l I, c- (:If
(A 1,

Ca cd

Rea-
C LL i
:L 'i

Re a-; v!
ASSOCIATIO'N"
SUBMTTTED~
N. D.
3
m D J S S E;
Ma.,y
Ca,-d --.,!

t4 E-

WLGIY, I.Ye.
Reaction of alkenes with diazoacetic eater in the presence of the
catalyst CuSO 4. Izv.AI SSSR Otd.khim.nauk ao-5:931-934
My 16o. (MIRA 13:6)
1. Institut organicheakoy khimii imeni N.D.Zeliaskogo Akademii
nauk SSSR.
(Copper sulfate) (Olefins) (Acetic acid)

MIESHCHERYA.K02-AG-P, -
Synthesis of peroxides based on Isobutylene. Sbor. nauch. rab. Inst.
fizeorg. khim. Ali BSSR no.8:3-12 160. 14:3)
1. Pastitut oraanirhPqkov 1614-44 im. N.D. Zelinskogo AN SSSR.
. (Butyl peroxide) (Propoe)

MESHCIMYAKOV, A.P.; DOLGIY, I.Ye.
Wfect of the temperature on the reaction of alkenes with eth7l
diazoacetate in the presence of copper sulfate actiln-0 as a catalyst.
Izv. AN SSSR Otd. khIm. nauk no.10:1874-1876 0 160. (MIRA 13:10)
1. Institut organicheakoy khimil im. H.D.Zelinskogo Akademii nauk
SSSR.
(Olefins) (Acetic acid) (Copper sulfate)

I.AB6H(-;-HFWAKOV, A.F.; GLMIQVTSEV, V.G.
Vinyl etbprs of methyl- and dimath,,Ic 'iclol.rorylcarbinols. Izv.
( tJ7 I 'I -
AN SSSR.Otd. khim. nauk no.11:2042-2043 N 16C. .RA .11)
1. Institut organicheskoy kbimii Ali SSSR.
(Ethers)

80057
S7 ~17 00 S/02 60/132/01//31/064
B011YB126
AUTHORS- Kachinskaya, 0. N , T2g.2yeva.L S. Kh., Meshcheryakov, A. P.,
Skuratov, S. M.
TITLE: Heats of Combustionto~f 1,1-Dimethyl-2-alkyl Cyclopr
PERIODICALs Doklady Akademii nauk SSSR, 1960, Vol. 132, No. 1, pp. 119-122
TEXT: The heats mentioned in the title were measured in the liquid phase. The
authors give calculation formulas for all compounds of the above-mentioned
homologous series. Temperature determination methods are described in Ref. 7.
The substances analyzed were synthesized by the methods given in Ref. 8. They
contained (according to Raman spectra) no alkenes. The authors analyzed 1,1-di-
methyl-2-ethyl cyclopropane, 1,1-dimethyl-2-propyl cyclopropane, and 1,1-di-
methyl-2-n-hexyl cyclopropane. Table 1 shows the heats of combustion of these
compounds after 2 final distillations. From this it can be seen that their heat
of combustion has not changed after the last distillation. By using the additive
method concerning types and sub-divisions according to the hypothesis of V. M.
Tatevskiy (Refs. 1, 2), the authors derive the general formula for calculating
the said heats (1). For 1,1-dimethyl-2-n-alkyl cyclopropane (alkyl - any
Card 1/3

80057
Heats of Combustion of 1,1-Dimethyl-2-alkyl S/020/60/132/01/31/064
Cyclopropanes B011/B126
radical, from ethyl on, that is, when n >v 7) the equation (1) assumes the form
of (2). From the values of the heats of combustion of 1,1-dimethyl-2-ethyl- and
1,1-dimethyl-2-hexyl cyclopropanes and from the ascertained value A22
(156.2 3kcal/mole), the heats of combustion af 1,1-dimethyl-2-propyl-, 1,1-di-
methyl-2-n-butyl-, and 1,1-dimethyl-2-n-amyl cyclopropane were calculated. These
heats (- AHO) and the heats of formation (-AHO) are set out in table 3. As can
c f
be seen from the given data, the calculated and the experimentally obtained
heats of combustion agree. Concerning the stressed three- and four-membered rings
the question still remained open, as to whether such a ring influences the prop-
erties of the side chains. It follows from the data given here that the cyclo-
propane ring does not influence the character of the bonds in the substituting
alkyl, from ethyl on. This conclusi;n can apparently also be extended to alkyl-
cyclobutane compounds. Thus, the heats of combustion of compounds of the 1,1-di-
methyl-2-n-alkyl cyclopropane (n-alkylethyl and higher substituents) series can
be calculated from equation (3). Equation (4) has the same object. From the
heats of combustion of 1,1-dimethyl-2-ethyl-, 1,1-dimethyl-2-n-propyl-, and
1,1-dimethyl-2-n-hexyl cyclopropanes, as well as from the values of A 22 (see
Card 2/3

80057
Heats of Combustion of 1,1-Dimethyl-2-alkyl S102 60/132/01/31/064
Cyclopropanes B011YB120'
above) and A21 /=263.238 kcal/mole) which are given in publications, the authors
calculated the increment c' which occurs in equations (1) and (2). It was shown
that c - 851-74 kcal/mole. The values of c' calculated for - AHfV RM, and Vx
are shown in table 2. It has now become possible to work out the heats of
combustion not only for normal, but also for (from the second C-atom in the alkyl
radical on) branched 1,1-dimethyl-2-alkyl cyclopropanes. In this case equation
(1) assumes the form of equation (5), The value of the coefficients Aij for the
C-C bonda of different sub-types of branched alkanes can be taken from
publications (Ref. 1)., There are 3 tables and 6 references, 5 of which are
Soviet.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosova,
(Moscow State University imeni M. V. Lomonosov)
PRESENTED: December 22, 1959, by A. N. Nesmeyanov, Academician
SUBMITTED: December 16, 1959
Card 3/3

la6HCHEIMIKOV, A.P.; HTILOVA, L.V.; GLUII,(,VTSLVI V.G.
Synthesis of d-L-p tri-f and teti-csubstiti:tled cycloprop--ne
hydrocarbons by the Kiohner reaction. izv. 117 ~ESSR. Otd.
khim. nauk no. 1:114-1-19 Ja 161,, (:,:rl 14:2)
1. Insitut organichoskoy khJmii im. Zelinskogo U,' 35S*R.
(cyclopropane)

MESHCHERYAKOV, A.P.; DOLGIY, Lye,
Synthesis of dir--thylalkyl6yelopropylearbinols and methyl alkyleyclo.-
propyl ketones. Izv.Afi SSSR OtA.khim.nauk no-3:496-501 YX 161.
(MBA 14:4)
1. Institut organicheskoy khimli imeni N.D.Zelinakogo Akademil nauk
SSSR.
(Methanol) (Ketones)

23591
5106 61/000/005/008/009
rc 10 -L., 2, Z ID S B118YB220
ALTHORS3 Shostakovskiy, M. F., Oracheva, Ye. P., Meshcheryakov, A. P.,
and Glukhovtsev, V. G.
TITLE: Polymerization of the vinyl ether of methyl cyclopropyl
carbinol
PERIODICAL3 Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
nauk, no. 5, 1961, 924 - 927
TEXT: In Ref. 1 (B. A. Zakharov et al., Dokl. LYSSSR, 122, no. 59 814
(1958)), it has been stated that the double bond of the vinyl ethers has
an increased nucleophilic character which manifests itself in various
addition reactions, transformations, andespecially in the polymerization
reaction. For the study of the conditions of polymerization of the com-
pounds CH CHOR (I), the vinyl ether of methyl cyclopropyl carbinol is
of special 'interesti JH 2
CH 2 - CH-0-Cg-C t (II).
I n\C1 H
C~3 2
According to the rule of Markovnikov, the cyclopropyl group of this ether,
Card 1/3

23591
062 61/000/005/008/009
Polymerization of the ... B11FJ/B220
as possible carrier of the propenyl group, is able to add various polar
compounds. Moreover, this ether may be of interest as teat substance for
the synthesis of different polymers in the polymerization and copolymeriza-
tion reactions. The present paper describes the polymerization of the
vinyl ether of methyl cyolopropyl carbinol in the presence of the initia-
tors FeCl 3 and azonitrile isobutyric acid under optimum conditions for
the polymerization of the vinyl a,14,,l ethers. It has been found that com-
pound (II) shows higher reactivity auring polymerization in the presence
of a 5 ~4 solution of iron perchlortde (in dioxane) than vinyl alkyl ethers
(I) under the same conditions. First of all, this is evident from the fact
that the polymerization of the ether (II) begins at OOC and the highest
yield in polymer is obtained at a temperature of -17 to -200C whereas other
vinyl alkyl ethers polymerize at boiling temperature only. The reason for
such diverging temperatures of polymerization is the different stability
of the ozonium complexes of these compounds (I, II):
CH
CH - CH-OR 1:3 H2
(111) 2 CH2 - CH-Q-CH-C (IV)
H(FeCl3ON) 2(FeCl3OH~ 2
Card 2/3

225~
S/O 2 61/000/005/008/009
Polymerization of the... B118/B220
Evidently, complex (IV) is of lower stability; its decomposition is
effected at a low temperature resulting also in the formation of a polymer
at lower temperature. The use of azonitrile isobutyric acid as initiator
instead of FeCl 3did not give any results. There are 3 Soviet-bloc refer-
ences. ey
ASSOCIATIONt Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (institute of Organic Chemistry im. N. D. Zelinskiy,
Academy of Sciences USSR)
SUBMITTED: October 12, 1960
Card 3/3

MESHCHERYAKOV, A.P.; GLUKHOVTSEV, V.G.; LEMIN, N.N.
I-Cyclopropyl-2-oe--furylcyclopropane and its transformations.
Izv.A?l SS.c'R.Otd.khim.nauk no.10:1901-1903 0 '61. (KIRA 14:10)
1. Institut organicheskoy khimii im..,"I.D.Zelinskogo LN SSER.
(Cyclopropane~

MESHCHERYAKOV, A.P.; ERZYUTOVit, Ye.I.; GO CHUT41-I [Kuo Chlun-ij
Catalytic synthesis of isoparaffin hydrocarbons of the conposition
C20 - C33 of high density. Izv. AN SSSR Otd.khim.nauk no.12:2198-
2203 D ,61. (MIRA 14:11)
1. Institut organicheskoy khimii im. N.D.Zelinskogo AN SSSR.
(Paraffins)

_!~S~IIC~Oll ~A.P. ; CLUKHOVTSEV, V.G.
Preparation of 1-cyclopropyl-2-(butanone-11-ol-49)cyclopropane.
Izv. MI SSSR Otd.khi-n.nauk no.12:2248-2250 D '61. (MIRA 14:11)
1. Institut organicheskoy kbimii im. N.D.Zelinskogo AV SSSR.
(Cyclopropane)

MESHCHEU~PY-,-A~P,;- PETROVA, L.V.
Synthesis of 3,3,4-trimethyl-l-pentyne and 2.3.3,8,8,9-hexamethyl-4,
6-decadiyne. Izv. JVI WSSR Otd.khim.nauk no.12.-22;-0-2252 D 161.
(VdRA 14:11)
'L
1. Institut organicheskoy khimil im. N.D.Zelinskogo All SSSR.
(Pentyne) (Decadyine)

I-ESHCHEMAKOV, A.P.; DOLGIY, I.Ye.
3ynthesis of certain compounds having two adjacent three-
membered rings. Dokl. AN SSSR 139 no.6:1379-1382 Ag 161.
- (MIRA 14:8)
1. Institut organichaskoy khimii im. N.D. Zelinskogo AN SSSR.
Predstavleno akademikom B.A. Arbuzovym.
(Qyclic compounds)

MESHCHERYAKOV, 'I.P.; GLUKHOVTSEV, V.G.
Synthesis of 1,3-dicyclopropyl-2-but,-,ne-l-one. Izv, nN L"55R -itc.-
khim.nauk no.1:176-178 ja 162. 1,: 1 )
1. Institut organicheskoy khimii im. N.D.Zelinskogo All SSSR.
(Ketone) (Cyclopropane)

-1-Fi.-
F7-"~

31,662165100010310TT) 018
7

eaction of
w- t-
diazoacetic 'eater wi a:
B 01~B186

-
yiel'
b.p. -110 0
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d
j1 I
42 7a 20

Lim H& d
- ~0-9214
mw- ,
:
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t 4~';

yl.'-~estdjr o -the -nebpen
& 2o
carboxylic.acU

ield:~5,9A~ 20'

b 'p- 85 `86 0/15mm Hg
7 . . 20
Oo9054~'~nD7 -A-4342t
. ...
-

Assocr TiO1
6, Ins i u -Ze ins o kkadeviii
t
tl orq'anich k k:--'khi*i im 90
e o
nauk SSR: (Ins.titute of Organlo ciiemistry imeni K.:D*-
~7 iT OT.'~the Academy' of
Zelinsk 3 ie, es USSR)

a zic
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