SCIENTIFIC ABSTRACT MERKULOV, V. V. - ,MERKULOVA, N. A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001033610015-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: June 21, 2000
• Sequence Number: 15
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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2Lt9O7 -4 -7
-5/0109/641009/009/1570/1560
ACCESSION NR; AP4045479
AUTHOR: Kashin, A:. Merkulov, V. V
Problem-of scattering of -electromagnetiewaves
rou h-surface
9
SOURGF,,,~-;Radiotekhnika_ i -elektranik
a,-V., 9.- no. 1964, 1578-1580
electromagnetic %,,ra%re, radio wave -scatter
TOP!(, TAGS.
,~iBSTRACT: A theoretical proof ls-oLfered that if.a-pla'n+ e vertically polarized
tr n a r
61 e comag G-tic wave strikes rough pe f ect- conductance surface at a grazing
w -was
-.1 ang e the ringe effect:associated with the Kirchhoff approximation ( hich
usually R,~%glc t d) -ma fumai - - - - - -
e be essential. For a certain correlation ion given in
0 rized wave, no
-~y reach 3 . For-a horizontally pola
the article, the angle.m. 0
10
-the-:1 ringe effect- is~ nece as ary--Or lig... art- has _---Z_~figures
17 formulas.
,3_
,ASSOCIATION: none
E;NCL: -00
SUB1,1ITTED: ZOJun63
'-ODE* F_ M
NO R E'll,
SUB
SOV: 001 -HER: 000,
Cwd

IL 40366-66 ED tr I( I/T1
;ACC NR: AP6014247
;AUTHOR: Merkulov, V. V.
i ORG: none
TITLE: Directive gain of antenna arrayi having random- po si tioned radiators
SOURCE: Radiotakhnika i elektrorxika, v. 11, no. 5, 1966. 928-930
TOPIC TAGS: antenna array, antenna directivity
ABSTRACT; Linear cophased arrays with random-positioned radiating elements
are briefly considered. This approximate formula is developed for the average
ivalue of the directive gain:
2d 2 Here, N is the number of radiators in the array.
2 1- - d is the average spacing between tbA radiators.
1+U- M(I + 2d -') -The mean-square deviation of the directive gain
N I from its average value is given by:
3OURCE CODE: UR/0109/66/011/005/09?8/0930
Card I UDC: 621.396.673.4

L 40366--66
ACC NR: AP6014247
The validity and accuracy of the above fornm1as were verified an
2 a digital computer; directive gains of 250 arrays, each
IIV(i + zd) comprising 20 radiators, were computed. Orig. art. has:
13 formula& and I table.
SUB CODE: 09 SUBM DATE: 18Aug6S ORIG REY: 001
:-Cczcd

PLYATSKIY. Vladimir Hikhaylovich; POLYANSKIY. A.P., inzhener, retsenzent;
I KMKUWV, V.V.. inzhener, retsenzent; KRYLOV, V.L. inzhener.
redakto7,!mPMMWA, I.A.. izdatellskiy redaktor; ROZHIN. V.P..
tekhnicheskiy reclaktor
(Founding under pressure] Utle pod davleniem. Izd- 3-e. perer.
Moskva, GoaAzd-vo obor.promVshl., 1957. 462 p. (MIRA 10:9)
(Die casting)

MERKULOV, V.V., brigadir puti
Need for consolidated track maintenance forces. Put' 11 put.khoz.
5 no.12:21 D '61. (MIRA 15:1)
1. -'Iukhinichskaya distantsiya Moskovskoy dorogi.
(Railroads--Maintenance and repair)

KERKUDOV, V.Ye.
--wWOMM"..
Ways of carrying out the over-all mechanization of coal minirg.
Makh. trud. rab. 10 no.8:6-9 Ag '56. (.'URA 9: 10)
1. Nachallnik Takhnichaskogo upravlantya Hinistarstva ugollnoy
promyshlennosti SSSR.
(Coal mining machinery)

ME UL40V V ikt or T f
ASTAKHOV. A.V.. c)tvetstvennyy rodaktor;
tekhnicheakiy redaktor
[Technical progress in Soviet coal mines] Tekhnicheskii progress
na ugollnykh shakhtakh SSSR. Moskva, Ugletekhizdat, 1957, 32 p.
(Coal mining machinery) (KLRA 10:9)

ICRK=V, V.Ye.
%WQMAWQ%k~~- --
Completion results of the plan for introduction and use of
new coal mining equipment in 1956. U901' 32 no.5:2-6 Kr 157.
(MLRA 10:5)
1. Machallnik Tekhnicheskogo upravleniya W-nisterstva. ugollnoy
promyshlennosti SSSR.
(Coal mining machinery)

BUCHNEV, V.K.# prof., doktor takhn. nauk; KAI-DIN7 R.A.9 dotsent; KORABLEV,
A,A.p kand. tekhn. naiik; MONIN9 G.I.9 in2h.; BELYAYEVp V.S., kand.
tekhn. rauk, inzh.; ALF =F-11KO, V.D., inzh.;
ILISHTM, A.M., kaid-F. tekhn.nauk; GEIZSKULv M.N., kand. tekhnnauk;
KOBISHCHANOV, M.A., kand. tekhn.nauk; DOBtIOVOLISY.IY. V.V., kand.
tekhn. muk; MALYSHEV, A.G., inzh.; VOROPAYEV, A.F., prof., doktor
tekhn. nauk; LIDIN9 G.D., prof., doktor tekhn.nauk; TOPCHIM , A.V.,
prof.; VEDERITIKOV, V.I., kand. tekhn.nauk; KUZIYICH, I.A., kand.
tekhn. nauk; LEYTES, Z.M., inzh.; SYSOYEVAq V.A., kand. tekhn. umuk;
MELAMEDv Z.M., kand. teklm.nauk; CHKRNAVKIN, N.N., inzh.,-
KARPILOVICH, M.Sh., inzh.; L.G., inzh.; BOGOPOLISKIY,
B.Kh., inzh.; FROLOV, A.G., doktor tekhn.nauk; KHVOST0Vv F.K.9
inzh.; BAGASHEV9 M.K., kand. tekhn. nauk; KAMINSKIY, I.B., inzh.;
PETROVICH, T.I., inzh.; ZHUKOV, V.V., red. izd-va; LGIILINA, L.N.,
tekhn. red.; PROZOROVSKAYA, V.L., takhn. red.
[Mining engineers' handbook]Spravochri gornogo inzhenera.
Moskva, Gos.nauchno-tekbn. izd-vo lit-ry po gornomu delu, 1960.
(MIRA 14: 1)
(Mining engineering-Handbooksg menuals, etc.)

AUKSEYZV. To.T.: APENCHERKO. S.3.; BASOV, A.P.; BAUSIN, A.P.; EZRSRADMY. Los.;
YBLM. N.A.; GIHZEM GUSEV, S.A.; DAHILOV, G.T.; DOWIIH, Nose;
MMHINIX, N.H.; YZFIKOV,V.S.; ZAVADMT. N.V.; ITASHEGMY. N.V.;
KARAKIN, F.P.; KWHKAH, G.I.; WWIOV. S.P.; KfldnWV To V -NIXODIKOT,
P.I.; PAHIMTOV, U.S.; PTATAMV, L.V.; RODI -1, 1.1., mwmv. No so;
STRUM, B.I.; SAMCHKI3, S.M.; SAMSONOV, N.H.; SINITSYN. N-.A.;SCSMIDV,
A.A.; SOWPOT, S.G.; GHRLYSHEV, S.G.; SHCFDWKIN, A.Ye.
?odor Nikolaevich Krylov; obituary. Torf. prom* 35 no.6:32 158.
(KIRA 11: 10)
(Kr7lov. Fedor Rikolaevich, 1903-1958)

MERKIJIA)Y,_YqvgemV; BRUSNICHKO, N.S., kand. tekhn. nauk, retsenzent;
----YURK-EVMH, M.P., inzh., red.;-SHCHF.TLVINA, L.V., tekha. red.
(Antifriction porous alloys]Antifriktsionnye poristys splavy.
2., izd. ispr. i dop. Moskva, Mashgiz, 1962. 68 p.
(MIRA 16:2)
(Bearing metals)

m 15R A'U 1. 0 Yj X e. A.
SMJORTOV, A.Ye., fesaor, doktor takhnichasikh nauk; ~WKULOV, :~ 're.A.1,
dotsent, kandidat tekhnicheakikh nauk; BABICOT,
PETR07SKAYA. Ye.. tokhnichaskiy radaktor
[Planning city streets) Prooktirovania gorodakil-I dorog. Moskva,
Izd-vo HinIsterstva kcmmunallnogo khosiaistva RSFSR. 1952. 495 p.
[IfIcrofilml OURA 7:10)
(Streets)

BCOATSKIT. G.. kandidat takhnichaskikh nauk; KUCURMO, K.. starshiy
propodavatel 1; DMISBMW, L.
,UAOIS:
wPlanning city streets". Reviewed M>,A.M.Stramentov, I.A.Karkulov;
'~FW.Sogait-s-kii, IL.KuchsreakK,-L.D9nissa7o. Zhil.-kom.khos. 4 no.3:30-31
154. (PI-RA 7:6)
1. Nachallnik Takhnichookogo otdols Kiyovskago tramvayno-trollaybus-
nogo upravleniya (for'Banisanke)

KMLVIWV. Yefipl_..4f-an4soyeviaL;,,PXTROY, Vyschealav Koristantinavich [deceased];
Georgiyevich; YUDIN, Vasiliy Aleksandrovichi
Prinimali uchastiye: DUBROVIN, Ye.N.; SLAVUTSKIY. A.K.; BAMOVA.
Ye.A.; BLATNOT. M.D.; KVDRYAVTS19V, O.K.; SAMOYI;OV, D.S.; FWDLYAND,
A.G.. BRONSRTM , L.A., red.; RACH&VSKAYA. M.I.. red.izd-va;
LELYUKHIN. A.A., tekhn.red.
[Urban transportation and street construction] Gorodskoi transport
i dorozhno-mostovoe khoziaistvo. Moskva, Izd-vo K-va kommun.khoz.
RSFSR, 1959. 473 P. (HIM 12:8)
1. Sotrudniki Akademii kommunallnogo khozyaystva im. K.D.Pamfilova
(for Barkova, Blatnov, Kudryavtsev, Samoylov, Fridlyand).
(Transportation) (Streets)

SAVIDOV, N.A.;~Mm
Method of preparing cast gating systes parts in graphite colds.
Lit. proizv. no.10--41 0 t6o. (Mm 13:10)
jFounding)

DUBROTIlT. Te., dotsent; MMULOV, Te., dotsent; TURCHIMIN, E., doteent
Precast reinforced concrete city pavements. Zbil.-kom.kboz.
10 no.9:27-29 160. (MM 13:9)
1. -lafedra dorog Vaesoyuznogo saocbnogo inzbenerno-stroitel'nogo
instituta.
(Pavements, Concrete)

MERKULOV, Yefim Afanaelyovich, dots., kand. tekhn. nauk; DUBROVIN,
dots., kand. tekhn. nauk; TURCHIKHIN,
Emmanuil Yakovlevich, dots., kand. tekhn. nauk; YUDIN, Vasiliy
Aleksandrovich, dots.1 kand. tekhn. nauk; Prinimali uchast4.ye:
SLAVUTSKIY, A.K.1 dots., kand. takhn. nauk; ZAYTSEV, L.K., inzh.;
ZAMAKHAYEV, M.S., red.; OVSYANNIKOVA, Z.G., red. izd-va
(Examples of the design of roads and public transportation systems
in cities]Primary proektirovaniia dorog i setei passazhirskogo
transporta v gorodakh. (By] E.A.Merkulav i dr. Moskva, Gos. izd-
Vo "Vysshaia shkola," 1962. 265 P. (MIRA 16:2)
(Road construction) (Rapid transit)

DUBROVIN, Ye.N. dotsent; ~IERKUlDV_,Ye.A., dataent; TMHIM111, FAA.
dotsent
Uselprecast reWorced concrete in zvM canstruction.
Gorg khoz. Moak. 36 no.9:17-20 S 162 (MIRA 15:10)
1, Vaesoyuznyy zaochnyy inzhenerno-straitellnyy institut.
(Prestressed concrete construotion) (Moscow-Road construction)

-L 22715m-66
ACC NR e. AP6=935
~Tlg 1,-~ 1 and 2Ferrite cores;
3 -slid 44!* excitation vindi~gs;
and 6.- vindivgs of.the.two-
frejusimay. recording;, .
Tand 8 - windings of the llftglo~ol,

readout*
ft"Uency 'q

9* hanC I figure
Sm.comt DATEj 9XJ=64

U
SUBJECTi USSR/Welding 135-4-12/15
AUTHORt Merkulov Y,,e,.F., Professor.
TITLEt Repairing Automobile Cylinder Blocks by Cold Welding.
(Method kholodnoy savarki blokov avtodvigateley).
PERIODICALt "Svarochnoye Proizvodstvo"q 1957 # 49 P 27.
ABSTRACT: The method described has been developed by the author in co-
operation with engineers Polyushking Zhuykov and Stadniychuk.
It donsiste of following operations:
Dirt is removed from cracks by washing the block in a sodium
hydroxide solution at room temperature under 3.5 - 4 atm pres-
sure; the cracke are chiseled out at an angle of 450 and the
resulting grooves must not be (if possible) over 5 am wide
and deepj the grooves must be carefully cleaned by file and
brush. Only a nickel electrode of 3.5-4 mm diameter may be
used for this repair (all other materials have proved to be
not suitable.) It must be coated by a compou.nd of 75-80 ~v chalk
or tooth powder and 20-2q % water glasal the coating must be
0.2 mm thick.
Card 1/2

AUTHOR: Merkulov, Ye.F. 136-6-14/26
TITLE: Antifriction Aiuminium-lead Bronze (Antifriktsionnaya
a3,yumisdyevo -ovintsovava bronza).
go
PERIODICAL: Toyetnyye MetallY, 1957, No.6, pp. 6? - 69 (USSR)
4
ABSTRACT: At present, only small quantities of aluminium-lead bronzes
are being made in the USSR. The author who has had considerable
experience in this field, deals with the production, properties
and uses of this material. The present product has the comp-
osition 92.95ro Al, 5.5 - 5% Cu, 0.6 - 0.5% Fe, 0.4 - 0.7/6 Si,
1.5 - 1966 Pb; its cost and consumption are only about 1/11
and 1/2, respectively, of those of tin bronzes. In the author's
experience the best charge for smelting- in a Kaliman-type
furnace is 8701o Al, 5% Cu, 2016 FeSi (68-721/6) and 6% Pb, 1% of
the charge weight of potash being added and charcoal being used
to prevent oxidation. Careful chagge preparation and a final
crucible temperature 8f 940 - 950 C are desirable. The alloy
is cast at ?10 - ?50 C with precautions to prevent cracking.
Examination of micro-structures has shown that the lead forms
a solid eutectic solution with the cop.,er and aluminium; lub-
ricant penetrates the pores if the alloy. The alloys have
been successfully used to replace 7 - 11% tin bronze in variDus
Card 1/2machines. The mecnanical 'croperties, lubricated friction

Antifriction Aluminium-lead Bronze. 130-6-14/26
coefficient and density are tabuiated toEether with values for
bronzes 6]~010, 6AIO-2 and 6pUk3-4.
AVAILABLE: Library of Congress
Uard 212

SMOPAROT, Alsk-sandr 41eksandrovich; USTINOV, Turly Timofayevich;
0 K.G,', Insh.. retsenzent; PARTMOYN. G.A.. Inzh.,
rat senzent,-KIROZOT, re.F., Inzh.. red.; TASILIYKWA. T.P.. red,
izd-va; SPMMSUYA, O.V., tekhn. red.
[Assembling industrial equipment] Montazh promrBhleunogo oboradovaniia.
Moskva. Goa. nauchno-takhn. izd-vo mashinostrolt. lit-ry, 1958. 316 p.
(Rachinery-Arecting work) (MIRA 1117)

PHASE I BOOK EXPLOITATION SOV/4119
Merkulov, Yevgeniy Fedorovich
Antifriktsionnyye poristyye splavy (Poroas Bearing-Alloys) Moscow, Mashgiz, 1960.
51 P. 4,000 copies printed.
Reviewer: N.A. Filin., Doctor of Technical Sciences., Professor; Ed.,: I.M. Slitskaya;
Ed. of Publishing House: I.A. Borodulina; Tech. Ed.: O.V. Speranskaya; Manag-
ing Ed. for Literature an the Design and Operation of Machinery (Leningrad
Division, Mashgiz): F.I. Fetisov, Engineer.
PURPOSE: This booklet is intended for technical personnel in the machineauto-
mobile tractor
.0 ,instrument, and ship-building industries.
COVERAGE: The booklet deals with recently developed porous beaxing alloys, their
physicochemical compositions, metallographic properties, manufacturing methods,
and uses. TIje porous aluminum- lead- copper babbitt alloy, 'kAl'kusiPn (85-5-95-5
Al, 1-5-5-5 Cu, 0.1-0.2 SJ,2-5-8-5 Pb, 0-3-0-4 Fe),patented in the Soviet
Union in 1950, is described, as are also porous aluminum-lead bronze and porous
cast iron,, used for making parts with sliding surfaces. Emphasis is given to
Card-t/Ir'

Porous Bearing Alloys SOV/41_19
the mechanical and econouic advantages of porous aluninun-or iron-base alloys
over tin-base alloys in the manufacture of bearings, bushings, and other parts.
The fact that porosity facilitates lubrication through oil impregnation and re-
duces friction and wear is pointed out. No personalities are mentioned. There
are 5 references: 4 Soviet and I English.
TABLE OF CONTENTS:
Foreword 3
Introduction 5
Ch. I. Porous Aluminum--- Lead Babbit ('Allkusip") T
1. Chemical ccmposition of "ellkusipr' 7
2. Charging, melting, and lining of bushings for bearing bcrfes 'With
"altkusipn 10
3. Techniques of lining bearings vith mallkusip3l 12
4. Machining of bushings; assembly and clearances in assembling
automobile engines 14
Card 2/4

LAPINSKIY. L.G., inzh.; HKW9MOY, Te.Te., inzh.; PASHCfUMO. I.N.,
inzh.; TAMIN, T.L. inzh.-, GCLVMA. I.A., red.; FMX-
SITSKATA. S.M.. tekhn. red.
(Structural cementing materials] Stroitollnys rastvory.
Moskva, 1959. 22 p. (KRA 14:5)
1. Russia (1923- U.S.S.R.) Ministerstvo sel'skogo kho-
zyaystva. Normativno-iseledovatellskays stantsiyD.
(Plaster) (Mortar)

MERKUIDVA -.- -A.I.
Foreign bodies discovered in mental patients. Trudy Gos.nauch.--issl.
inst.psikh. 27:389-392 161. (MIR-k 15:10)
1. Permskaya psikhonevrologicheskaya bollnitsa. Glavnyy vrach -
N.S. Ivanov.
(FOREIGN BODIES (SURGERY)) (MENTALLY ILL)

MMMLOVA,A.I.. innhener
Effect of the design and shape of wooden crates on the quantity
of wood used. Standartizataila no.3:64-68 My-Je '55.
(141RA 8: 10)
1. Moskovskiy lesotakhnicheskiy inatitut
(Wood-using industries)

HEMLOVA. A.I.
Strength of nail joints of wooden parts in the manufacturing of
boxes. Trudy NILtary no.2-96-103 158. (MIRA 13:12)
(Boxes)

MMVr=VA, A.I., assistant
Tangential stresses along the area of effective contact caused by
external friction of vood and metal. Hauch. trudy MWI no.8:57-62
158. . (MIRA 130)
(wood) (Metals) (Friction)

G,V.-, VE.-,iKUDWA, A.I.; FUNANIN, G.I., red.
[Artificial fur; a textbook] Iskusstvennye mekha; uchebnoe
posobie. ',,.oskva, Zaochriyi in--t sovetsko-. torgovii, 1963.
35 p. (Y.IKA 18:3)
1. Za:veduylishchiy kafedroy tovarovedeniya pror4-yshlennykh
tova-rov Zaochnogo instituta savetskay torgovLi (for Kutyanin).

-MERKULOVA, A.I.; TSEREilITINOV, B.F.
Determining the content of looee pile fibers in fur fabrics. Kozh.-
obuv.prom. 6 no.10:23-27 0 264. (MIRA 18:1)

MERKULOVA, F. M.
"Chrovar,y of the Skeletal Muscles of Sheep Affected With Ramonchosis." Cand
Vat Seis, Want State Zooveterinary Inst imeni 11. E. Bauman, Min Agriculture
and Procurewnt., Rlyanovskj 195). M, No 5, Jan 55)
6urvey of Scientific and Technical Dissertations Defended at USSR Higher
Educational Institubions (12)
so: sm. No. 5569 24 Jun -4-5

MKULIOVV D.M., inzh.; -!~KULO~VA, G~.M., inzh.
Assembly of precast reinforced concrete arches from the ice.
Transp.stroi. 12 no.10:20-21 0 162. WMA 15:12)
(Krasnoyarsk-Bridge construction)
(Bridges, Concrete)

BOGGKOLOVA, P.A.; KATARGINA, G.P.; TUTKETICH, V.Y.; MUMOVA.-G.P.
Abdominal reflexes in diphtheria in children. Fediatrila 37 no.9:88
3 '59. (KIRA 13:2)
1. Iz 11 Moskovskogo meditsinskogo instituta imeni N.I. Pirogova.
(RULMS) (DIMHARIA)
-CL'~ ~-, ',-~

MERKULGVA I.A.,- TITY.OV, A.N.
Annealing e1ectrical resistarce allois in a nvrnr-,g--n ;--~mos.phere.
Biill.tekh.ekon.inform.GoEr.nauch.-issl.inst.nauch.i tekh.inform.
-IMa*10:8-9 0 164. (MIRA 18-4,

K0%WVAp I* Pop and ILRADS-KAYA, I. A,
"Concerning Delayed Changes of the Brain After X-Ray Irradia-
tion," by T, A. Rradskaya and 1. P, Merkulove, Division of
Pathomorphology (head, Prof B. S. Khominskiy) and Division of
Iloentgenology (head, Prof Ya. I. Geynisman), Scientific Research
Institute of Neurosurgery, Ministry of Health Ukrainian SSR
,director, Prof A. I. Arutyunov, Honored Worker of Science, Vest-
i adj2Lo il, Vol 31, No 2, Mar/Apr 56, pp 7-13
The purpose of this research was to study the delayed morphological
changes occurring under the action of fractional doses of X rays on the
brain,
Tests were run on seven dogs which were subjected to two courses Lf
irradiation with a 5- to 5 1/2-month interval between courses and a total
dose of 5,400-12,200 r.
Photomicrographs of cortical tissue 11-14 months after irradiation
show delayed changes arising after protracted fractional irradiation by
massive X-ray dcses, Morphologically, they appear in the form of injuries
of blood vessels, nerve filaments, cells, and glia and have a definite re-
lationship to the dose and time aftotr irradiation.
S LAM I ~_S- ~

-KMULOVA,,-L,-
Laboratory manager. NTO 4 no.12:13 D 162. (MM 16:1)
1. Uchenyy sekretarl Vladimirskogo oblastnogo pravleniya Nauchno-
tekhnicheskogo obahchostva stroitellnoy industrii.
(Building materials-Testing)

VA, K. I
CHALOV, P.I.; MUSIN, Ya.A.; T' 'VA, T.V.; L
'38 in secondary inera-
Isotope shlft --~,-ween and jr-
of some hydrothermal de-o.--its. Ater,,_ enej-g. 19 no.1:82-84 71 '65.
OC-111, 18:7)

BFUM, Ye.S.; WRKULOVA, K,,S.
Determination of the solubility of a disodiim salt of
ethylenediaminatetraacetic acid (t.-ilon B), Zhur.prikl,
khim. 37 no. 5:1155-1156 My 164. (MIRA 17-7)
1, Vsesoyuznyy nauchno-issledovatellskiy i. korstr-uktorskiy
institut khimicheakogo mashinostrayeniya.

ROMKO. Mi.l., ~nnd.med.uauk; KEIKULOVA, H.I., kand.med.nauk
Testosterone propionate and its use in rosacea Icaratitis. Oft.
shur. 12 no-5.,270-273 '57. (NIRA 13:6)
1. Is Ukrainakogo nauchne-looledovatel'skogo inatituta glaznykh
bolezuey imeni prof. Girshmana (direktor - chlon-korrespondent
AMU SSSR prof . I. I. Varlmlov).
(TESTOSYMNE) (COMM-DISEASES)

03382
5/190/62/004/002/013/021
BI 10/-BlOl
AUTHORS: Petrov, K. A., Nifantlyev, E, Ye., Khorkhoyanu, L. V.,
Merkulova, M. I~, Voblikov, V. F.
TITLEt Phosphorus-oontaining polymers. III. Application of the
Arbuzov roaotion for polymerizing othylene alkyl phosphitea
PERIODICAL3 Vyaokomolekulyarnyye soyedineniya, 1. 4, no. 2, 1962, 246-249
TEXTs The method by A. Ye. Arbuzov et al. (Izv. AN SSSR, Otd. khim. n.,
1950, 357) can be used for producing polyphosphonates from cyclic
phosphinites. In the present study, polyphosphonates were similarly
synthesized on the basis of ethylene alkyl phosphites (I). Alcohol was
aCded dropwise to 126.5 9 of ethylene chlorophosphite, 300 ml of ether,
and 152 g of triethylamine; the mixture was left standing, filtered off ,
heated for 30 min, and (I) was obtained by double distillation. Cyclic
phosphites contain an alkoxy group besides the cyclic ester group.
Polyphosphonates are formed under catalytic action of methyl iodide on
ethylene alkyl phosphite during 3 ht heating at 1300C in Ar atmrsphere:
Card

33382
3/190/62/004/002/013/021
Phosphorus-containing polymers ... B110/B101
C11.0
OR, nj )Pon
CHSO CH" I c1l'o
P-OR -- CHs- P - oclixti'i
I it
0
on OR
~--CHJ'J [OCHICH,J OCIT'Gil'i
It 11 In
0 0
The structure of polyethylene heptyl phosphite was proven as follows:
OC71115 /0
OCHSCHS - P1 nCIC~,CH,'P - C1 + nCICAs
11 n. C1
0
The degree of polymerization depends on the CH 31 amount, the reaction
time and temperature. Optimum wast (1) small CH 51 amount; (2),,j2O - 30
hr, the reaction time depending on the molecular weight of the monomer,
Card 2/3

333b2
S/190'62/004/002/013/021
Phosphorus-containing polymera... B1107B101
the reaction temperature, and the CH I concentration; (3),,,160 - 2000C,
depending on the molecular weight (hexyl and isooctyl compounds-:
16o - 1760C; nonyl and decyl compounds: 2000C). The polymers are viscous,
colorless, and odorless liquids soluble in organics. Some of them are
highly thermostable (polydecyl ethylene phosphite enduresPCI + HOR -- I >P-OR
CHI-O CH, - 0
was also synthesized. There are 2 tables and 5 references: 4 Soviet and
1 non-Soviet. The reference to the En-lish-language publication readsas
V
follows: A. K. Sherrill, J. Amer. Chem. Soc., 5--2, 1985, 1930.
SUBMITTED: February 9, 1961
Card 3/3

ACCESSION NR: AT4017411 S/OOOO/63/oOO/OOO/OO86/OO8q
AUTHOR: Petrov, K. A.; Nifant'yev, E. Ye..; Sopikova, 1. 1.; Merku lova
.TITLE: Phosphorylated po)ysaccharides. Ill. Phosphorylation of cellulose by
dial kyl-(aryl )phosphites
SOURCE: Tsellyuloza i yeye proizvodny*ye, sborn;k statey ~Cellulose and its
derivatives). Moscow, 1963, 86-89
TOPIC TAGS: polysaccharide, cellulose, phosphorylated polysaccharide, cellulose
phosphorylation, phosphorylation, dialkylphosphite, d;arylphosphite
ABSTRACT: On the basis of the authors' previous work, the following studies were
conducted: (1) phosphorylation of cellulose by di-O-chlocoethylphosphite, di-j3-
fluoroethylphosphite, and diphenylphosphite; (2) reaction of cellulose phosphite
with tetraethylmethylenediamine; and (3) reactions of-cellulose phosphite with
chloral, diethyldisulfide, ethylsulfenechloride, and ethylthiocyanate. In the
phosphorylation, 0.5 9 of cel lulose (cotton wool , thread and co rd), dehydrated by
washing with absolute alcohol, was reacted at 110, 130, 150 or 165C for 30 or 60
hrs. with 25 9 of the rea gents in a stream of nitrogen at a pressure of 50-60 MM
Hg. After removal of the excess phosphite by filtration, the product was washed
with M-_thanol and ether and vacuuni-dried over P20 The AP and C1 content of 4.27-
Card 1/3

ACCESSION NR: AT4017411
8.56% and 2.97-9.06%, respectively, was found in the product, obtairad
from cotton wool, while lower results were achieved with viscose thinad
.and cord. Di-B-chloro- and di-B-fluoroethylphosphites were found to
be better suited for the reaction. In the reaction' with tetra-
ethylmethylenediamine and disulfides, conversion of cellulose phos-
phites into a-hydroxy- and a-aminophosphonates and thiolophosphates
was also accomplished by the reactions
OCIISCHICI 0
OC112CHICI
-cellulose OP cellulose op
Oil
,and
i /OCIISCHICIGIHISCIAH&SCI-19 0
i cellulose op cellulose -OP-9caGliza
qOrig. art. hass 1 table.
ASSOCIATION: none

ACCESSION NR: AT4017411
SUBMITTED: )2Apr62
SUB CODE: OC
ATD ?IIESS: 3045
NO REF SOV: 006
ENCL: 00
OTHER: 002
Card- 3/3

is fluumts6s net oil If a Is M is It If a?v All ISO ban 16Y 10jr1ev
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all d4ld. B. A. Nikki, ''VA NI- S- NlcrLuWva' "Pat"
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TCLAted chmkdjy hut Contain Yoxiable q-11-
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oc*c io 4jiftfy adsorptim &W (left;
the Old- of Patticies It is McessarY that the pankle. -00
be thoroachly waihtd wA that they be subject to tw
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_pd. samples of tl&So~,
and M4 D on voloudy pte
FbCsID.. B&GA AM A#&Cs(k. For MSO~, the Pawth
roe
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000 and the emanatim atathads gaw. retp, tbe vaWce 22.4. '**
sod
17.4, 12.7 asul IN X 10- C. 0 0
the lit. 3rd, and 4th methods gave 24.1, 20.1 and -1-5.4 X
IWR- H&SO.; fo, phe'O'. 16.5. 9.Q. 11.5. for
HaCtO., 493. 48.8, 53.1. Fw AgCro. the values wem
8
7
1.4,
.7 and 9.1; in this case oWy tftc mkyowopk
method is appikable with certainty as the RA jon is o( Coo
isurnorphms with the Air iam F. H. Ratb iana
go*
&%@.I a 419TALLUMMAL LiTeRATWE CLAIINKATION
ta., 6iii-iii. --- --- ---- - , -- -
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woo
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A- a4''/ ,I I , I re .." 4e m %;/
I
l,ecociWil at the ilmws and ads at UltmgfA- N' S %"Fkulov&
Sl. 347 3491 AIIAIVw"14~
it -re .0.4 .4,ej -*~, 11, H ,; s . 11041. ~ .% j &I
KkvcfA-

t~lv alxw
104 L a I
~-,C-IAX
Dv(U=IUAff= d am no d the Walm d Watmobt. SC S. met-
kujo:v&-JCcmp(. read. Acad. Sts. U.R.S.S., 1041, $L 459-460)-
The calculation of the age of the waters of 'Watresta from the He/A
ratio accardingto the tutthodof Savtscheako Ktv" 22-02 x 101 yeam
C. R if

I-ERKULUiA, 1,i. S.
USSR/CHEMISTRY - IONS
ADSORFTION
Nov/Dec 48
OThe Nature of Ion Absorption by Clays and Soils: Iv, Absorption of Heavy Metal Ions
by Clays and Soils Under Dynamic Conditions, " I. N. Antipov-Karatayev, M. a. Pasvik-
!,Qilopina, M. S. Markulova, V. 1. Grebenshewtkova, Soil Institute, and Radium
Institute, Acad Sci USSR, 5 -Dp
"Kolloid Zhuru Vol X., No 6
Experiments show that the method of sorption filtration can be used for quantitative
studies of interchange and adsorption processes in soils under dynamic disequilibrium
conditions, and that it facilitates establishing a quantitative relationshipbetween
the static absorption capacity and the dynamic activity of soils. Submitted 22 Yar 47.
PA 65/49TIl

MOLOvA , m,. s.
USSR/Chemistr7 - Radium Absorption
"Absorption of Radium on Lead Sulfate in the Presence of Surface-
Active Substances," V. G. Khlopj-n, M. S. Merkulova, 12 3/4 pp
"Iz Ak Nauk SSS-R. Otdel Khim Nauk" No 5.
SePAct 49
Experiments with adsorption of radium on PbSO In presence of alu*inun
ions, dye Ponceau 4R, and humic acid showed: 3~r;sence of surface-active substances
in solution hinders kinetic Interchange of ions between solution and surfaces
of crystals, thereby hindering all phenomena whose basis depends un kinetic
interchange of ions. More time was needed to achieve a state of equilibrium
in presence of surface-active substances. In cases where they formed compounds
with ions of crystals (these compounds being only slightly soluble in solvent),
kinetic interchange of ions between crystal surfaces and solution is stopped
completely. lo obtain accurate results in stidy of primary adsorption of ions
on crystalline adsorbents in presence of foreign substances, experiment must be Bet
up to that concentration of ions of adsorbent, precipitation, and recrystallization
of adsorbent can be controlled. Submitted 7 Sep 48.
FA 149T27
RLA4~' &4&-l A'5 Ll Jj

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