SCIENTIFIC ABSTRACT MAYANSKAYA, V.G. - MAYANTS, M.L.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001033020012-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 98
• Document Creation Date: November 2, 2016
• Document Release Date: June 14, 2000
• Sequence Number: 12
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Tissue Therapy
sep/Oct 51
"'~Weatment of Exudative Diathesia," V. G. May-
.aukaya, (Preliminary Report) Chair of Chi.3.-
Ai*n's Diseases of the Pediatric Faculty, Pon-
tov State Medical Inat
-."Top Fed i Okhran Mater i Detn Vol X3X, No,5,:
40, 41
41een and ouprarenal tissue transplants 11
.,pnve cond in exudative diathesis. Suprarimal
T
..,M lant alone gIves beat resilt. I Issu*
Iberijy reduces 12 ritation and night restltiexi-~' I:,
avis in children. Aloe extract cleexe A
192"

BEXTSKIY, V.N.; MAYAKSKKYA. V.G.
Problem Of multiple eosinophille granalomas of the bone. PedlatrIle.
no.1:68-70 J&-F 955. (XWA 8:5)
1e Is kafedry I kliniki goopitallnoy pediatril (say. prof. F.D.
Davydov) I ksfear7 rentgenologii (sav. prof. A.I.Dambrovskiy)
Rostovskogo-na-Donu medAteinekogo Inetituta.
(ROSIROPHILIC GRANULOMA, in Infant and children,
multiple)

MAyprrlv-T~ TI,%-,
.,(xia changen in th& functional state of the blood coagulation E7stem
In axperimental isosensiti5ation. Rrobl. go-mat. i perel. krovi
no-3216-119 165, (MA 18?10)
1. X-ifedra patclogichoskoy flziolngii (zELv. - prof. M.A.Yerzin)
Kazanskogo maditsinakogo instAtuta.

Gh,allge3 in the u 1'~ b, ;: 1-a :~' t?~a hemc,,-ca~~: t-- n system
in autoL3entiltazation. ,,-~,'Y K"-Z. gos. red.
2 V 164.
1 . KELf(,dra crrjs~---,y f -Z.
K,- zLns kogo med ' T-s , ri,:-.kc~,o 1 z.6 t

K&YANSKIL, D.N.
Fu= tional state of the- bllrlc4 coagulatlon 11 n ~-*rB i ul-
zation. P4t. fiziol. I ekap. temp. 9 r4o.2s65-46 Mr-Ap 165.
'IIIFA 1~--5)
XafzAra patofiziologil (zuv. prof. M.A.Yerzin) Kazannkogo
instituta.

MAYA14SKIY D.N.
ChaTiges i4n the anticoagulating capacity of the blood, in
autosensitizati-or. Vop. med. kh:lm. 11 nc.4-24-27 ~!-Ag '65.
MR4
1. Kafedra. patologicheskoy flnologii Kazanskogo posudarstvennogo
mad-Itsinskogo instituta.

.-W-e
MMMIN, V.,'..; ~J.,,Y.rN,;.~'Y, G.M.
Therapeui-"c in 6-r-~!J-
mt~. znenl. d-ru4. !,-k. :-liq?

MAYANSKlY, G.1-1.
Therapeu~,-.'c , '- virseng and Eleutherococcus ~r c4lronj,~
radlation sicknF, -,r .-)ob. DVYAN SSSR no.19:131-134 163.
(MIRA 17:1-1)
1. Biologo-Tlocl.vvrin5~.; InstAtut dullnevostochnogo filiala
Sibirskogo cod(~leri4y~~ A'4

"Eicrott c. 01. of c a
'y 0: 1fa
-l-Ii',4-t4.(-d - Or li-rar-~v a,,:(., an, rciri.* ifi-:

IVAUOV, Boris Nikolayevich: MALIN. Ivan Mikhaylovich; SOTIITSNV. Vynchaslov
Aleksandrovich; MTRUM, Viktor Livovich; SHNNYDER. Roman Izrayle-
vir,h; )WT#qR~IY, losif JsaakOvICh;-3(TAIWVA, Volys Petrovne; AHUFYU-
NOV, V.O., rotsajis--en-t--.-Mgbfti-Sfi"TM, L.J.. red.; SWOLWA, YO.M.,
tekhn.red.
(Technology, of the manufacture of electric instruments) Tekhnolo-
giia elektropriboroatroeniia. Moskva, Gos.enorg.izd-vo, 1959.
590 P. (MBA 13:4)
(Electric apparatus and appliances)

o629h
25 (2)
AUTHORSt
47SOV/119-59-11-8/13
Ivanov, B. N., Engineer, Mayanskiy, I.I
Engineer
TITLE: A Semiautomatic Device for the Winding of Flat Spiral Springs
PERIODICAL: Priborostroyeniye, 19599 Wr 11, pp 20-21 (USSR)
ABSTRACT: This semiautomatic device was produced at the Leningrad
"Vibrator" Works according to a' design by 1. 1. Mayanskiy. By
means of this device it is possible to coil springs from an
endless band, and all operations are mechanized. It is used
for the production of springs for electric measuring devices
producing the repelling moment. The semiautomatic device shown
in figure 1 is discussed in detail with respect to all its
parts and its mode of.operation. Five to six bands are first
united in a bunch, after which this bunch is arranged by
means of a special appliance, and is then wound flat by means
of a drum. By means of this semiautomatic device it is
possible to coil springs of different cross sections and
dIfferent numbers of turns. The quality of the springs
manufactured in this manner is described as being considerably
better than that of springs wound by hand. There is
Card 1/1 1 figure.

[Romemede Instruments for visual instruction in rathematics] Saw-
delInye uchebno-nagliadnye posobiia po matematiks. 2. izd. Pzskva,
Goo. uchebno-pedagog. Izd-vo, 1958. 66 p. ()CMA 11:10)
(Mathematical inetramBute)

WANSK~~~~~ EELOV, M. , red.; TREBUKHOV p W. p
- tokbn. red.
[Hom=Me visaal aids in solid goom-etry] Samodellmys nagliadmye
posoblia po.stereoinetrii. KostrorrA, Kostromskoe knizhnoe izd-
(MA 15:4)
vo, 1959 8.1 P.
iGeoroetry, Solid)
(VisuAl aids)

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M

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"o 000-0069 Goodie 0 0 0 * 0 0
0 0 000

/ -1 1 Z-)
7 ~/) ,
R.- LUMOZVYABSKAYA, R.G.
Recovery of metals from waste solutions by means of ion exchpnge.
TSvet.met. 27 no.2:33-37 Mr-Ap '54. (MIRA 10:10)
1. Gintsvetmet.
(Ion exchange) (Ketals)

NyAIAT~ ~ A -t'
137-58-5-9352
Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 5, p 79 (USSR)
AUTHOR: _Ma ~ants,,�_ D_
TITLE. Rational Systems for Leaching Various Types of Zinrc Concen-
trates (0 ratsional'nykh skhemakh vyshchelachivaniya t5inkovykh
kontsentratov razlichnykh tipov)
PERIODICAL. Tr. soveshchaniya po metallurgii tsinka, 1954, Moscow,
Metallurgizdat. 1956, pp 9 3-1 12
ABSTRACT~ In examining a number of systems for leaching various con-
centrates, the author makes use of data from operating plants,
research work, and foreign literature. Single-stage batch leach-
ing followed by additional leaching of the thickened pulp is re-
commended for roasted concentrates with high SiO?, As, and
Cu content. Continuous two-stage leaching is recommended for
high-quality roasted concentrates. An intensified leaching regi-
men can be applied to such concentrates, the conversion being
effected by increasing the current density and the acidity of the
spent electrolyte. The system of "reverse" leaching of highly
siliceous, roasted concentrates should be tested out on a pilot-
Card 1/1 plant scale. L. P.
1. Zinc ores--Processing 2. F_1ectroQYsis--App1:_cations
3. Electrolytes--Properties

M 4 Y14 A ;r ~'~ A 137-58-5-9364
Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 5, p 80 (USSR)
A UTHORS: Mayants, A.D., Orlova, S.I., Barotitskayb, F.I., Shvarts,
2. M.
TITLE Employment of Various Oxidation Agents in the Production of
Zinc Sulfate From Solutions Resulting From Leaching of Pow-
ders and Sublimates of Zinc Production (Polucheniye tsinkovogo
kuporosa iz rastvoiov ot vyshchelachivantya pyley i vovgotiov
tsinkovogo proizvodstva s primeneniyem razlichnykh okisliteley)
PERIODICAL: Sb. nauchn. tr. Gos. n. -i. in-t tsvetnykh met. , 1957, Nr
13, pp 134-146
ABSTRACT: Leaching of dusts and sublimates of zinc production was car-
ried out under laboratory conditions. After being previously de-
contaminated of As, the solution underwent crystallization of
ZnS04. Pyrolusite, atmospheric 02, and gaseous C12 served to
oxidize the admixtures contained in the solution after leaching.
It was found that standard ZnS04 can not be obtained by employ-
ing pyrolusite. Most rational method is the employment of atmo-
spheric oxygen in which case practically all of the Zn is obtained
Card 1/2 in the form of standard technical sulfate which is suitable for any

137-58-5-9364
Employment of Various Oxidation (cont. )
application. If advanced purification of the solution is difficult, gaseous C12
may be utilized as an additional oxidizing agent in place of the atmospheric
Oz.
L.P.
I Zinc sulfate--Productiori 2. kl~Sen I c--Separat ion 'i. Zir",
4. Oxygen--Applications 5. Chlorine--Applications
Ca rd 212

Al 17 Y )q /I T ~11 17. 21).
137-1958-3-4550
Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 3. p 11 (USSR)
AUTHORS: Barotitskaya, F. I., Mayarits, A. D.
TITLE: Use of Centrifuges for Pulp Separation in Zinc Hydrometallurgy
(Opyt primeneniya tsentrifug dlya razdeleniya pul'p v
gidrometallurgii tsinka)
PERIODICAL: Sb. nauch. tr. Gos. n.-i. in-t tsvetn. met., 1957, Nr 13,
pp 171-176
ABSTRACT: A semi-industrial G-450 centrifuge (a model corresponding
to the industrial centrifuges AOG-800 and AO-V-1800) was tested
as a periodic action unit. As a continuous -action centrifuge an
experimental model of the NOGSh-T centrifuge was tested. An
industrial VSB vibration separator was also investigated. Tests
were performed to investigate the effectiveness of centrifuges
employed, instead of thickener, frame and disc type filters and
a separator, in order to decrease the content of solids in the
upper sink of the thickener. As was shown by preliminary
production-C05t figures, the employment of AIDG-1800 centrifuges
Card 1/2 may be advantageous in the dehydration of thickened slurries.

137-1958-3-4550
Use of Centrifuges for Pulp Separation in Zinc Hydrometallurgy
Cakes obtained through centrifugation of thickened slurries con-
tained 20-40 percent water and 4-8 percent of water-soluble Zn.
A.Sh.
Card Z/z

AUTHOM - if ayants, A.D. and Barotitshaya, r.l. 130-38-3-8p1
TITLE: Hydrometallurgical treatrLeat of high-silica zinc concentrates
(0 gidrometallurgicheskoy pererabotIce vysolroh-remnezemistykh tsinho-II'Ll
kontsentratov.)
PZRIODICAL: Tsvetryye Iletally, Nr.3. pp. 46 - 47 (US-S-11)
ADSMCT - Experiments -.re briefly described whicli have showu that. "return"
leachin,- is applicable to materials containing acid-s(.-luble natural
zinc silicates. Formation of silicic-acid -e1 with a coucentrate
containing 41 .50 anI 14.36~1 '92S04 soluble Zn and Si02, respectively
was avoided by using the variant of the method in which the pulp is
prepared in a neutral sclutivri. spent electrolyte then ijeiii.T added to the
the pulp at a rate rd-iich prevents the value of the p11 falling below
3.0 durin, th~~ process. A i-inc recovery in the solution of 89-89"
was obtained. There ar,- 4 references of .,ihich 2 are Slavic-
ASSOCIATION,- Gintsvotmet
AVAILABLE- lljibr~r,,- of C:onErt-
1. Z-inc-Purification 2. Minerals-Separation-Test results
3. Zj-n,; s-3.1icateo.-Cheraical reactions
Card 1/1

UTANTS, A.D.; BAROWSKATA, F-1-
--
Hydrometallurgical processing of CaPPer-sinc cOnesutrst0s, Ptul-
TSIIN tsvet. not. no. 7:21-25 158a (MIRA 11:7)
(Hydromstanow)
(copper)
(zinc)

T_~J/
136-1-0/20
AUTHORS: Mayants, A.D. and Barotitskaya, F.I.
TITLE: Use of Flocculants in Pulp Settling in Zinc Production
(Primeneniye flokulyantov pri otstaivanii pul'p v
tsinkovom proizvodstve)
PERIODICAL: Tsvetnyye Metally, 1958, No. 1, pp. 4-4 - 4? (USSR).
ABSTRACT: After briefly reviewing some applications of flocculants
in pulp settling abroad and in the USSR and a series of tests
by the Gintsvetmet organisation with zinc-manufacture pulps and
a variety of flocculants, the authors discuss further laboratory
tests by this organisation, carried out in 1956-57 in collab-
oration with works personnel. Promising results were obtained
with Separan 2610 (Dow Chemical Co.) and these were confirmed
on pulp samples 6-8 and 100 litres in volume, corboxymethyl
cellulose also being used and the effect of stirring conditions
being studied. The results of full-scale tests of Separan
10-25 mg/litre) with neutral pulps at the Chelyabinsk Zinc Works
elyabinskiy tsinkovoy zavod) are tabulated (Table 1) and dis-
W
cussed. A total of 150 9 of the flocculant was added as solution
5 m upstream of the thickener. These confirmed the laboratory
tests and wexe followed by further laboratory tests to determine
the effect of the additions on the electrolytic deposition of
Cardl/2 zinc. It was arranged that Separan remnants or decomposition

136-1-9/20
Use of irlocculants in Pulp Settling in Zinc Production
products should be present both in the treated electrolyte
with which the bath was filled and in the neutral solution
foro electrolysis; electrolysis continued for 3 days at
35 G, current density being 400 A/m and acidity 100 - 110
g/litre H~:,SO,,; in a further series, 10, 50 and 200 mg/litre
of SeparaM wdre added directly to both liquids and electro-
lysis was carried out for one day. Both series show that
the flocculant has no deleterious influence on zinc electro-
lysis. The possibility of Separan accumulation is discussed
and further research flocculants, their synthesL- a-nd use with
zinc manufacture pulps is urged. There are 3 tables and
6 references, 2 of which are Russian, 3 English and 1 German.
ASSOCIATIOR: Gintsvetmet
AVATT-A LE: Library of Gongress
Card 2/2

WANTS J, A. ~. - BA F. 1.
_, ROTITSKAYA,
Properties of pulps in zinc production deteraining their
rate of nettling. Sbor. nauch. trud. GINTSVET14ET no-15:511-
538 159. (MIRA l1,:1,)
(Zinc--Metallurgy)
(Leaching)

SOV/112-58-Z-2424
Translation from: Referativnyy zhurnal, Elektrotekhnika, 1958, Nr 2, p 102 (USSR)
AUTHOR: Mayants, B. A.
TITLE: ic-Arc hisert Pipe Welding (Elektrodugovaya, svarka trub pri
pornoshchi vstavki), USA (SSbA)
PERIODICAL: Energokh-vo za rubezhom, 1956, Mr 5, p 39
ABSTRACT: Bibliographic entry.
Card I 11

",v JTrl ' '
I I ~ - . ~� '.ta-ne..,
Pirinp asw2 , I - - I . . .
T-lb . ro.l:-! -,- J .- I .
(Umte- I- - '. -- -

i.ly .,
- , ~~ - - - --i
'I . -. ~ - _ _:~ I ~ I -,
I ~ - t I ,, - r;~ -n , - I .. , 1 . _ ] q , - 4- - r,,. -; - - - ". - .
111; 11 . r~ . , : . i, -,- -, I- ,- . . I . ( 1 1 :t - - : ; )
( n , .") ~~ 4-- !1,, 4 1 ~.- ~. -- A , , a ! ~ '. rl " (, e" I - .", 1 ! ;, )

KkYA TS, B.A., kand.tekhn,.nauk
Testing results nf a now mmebanical fly-ash collector. Blek. sta.
no.4 Supplnmant:26-27 Jl-Ag 058- (14IRk lltlO)
(Germany, West--Fly ash)

WANTS, B.A-.1umA.tekhn.n&uk
- -", - ftsumtic ash removal In large electric paver plants (from
"Combustiou,O'no. 12, 1957). Inergokhoz.za rub, no.1:15-
17 Ja-F 159. (MIRk 12:4)
(United States--kah disposal)

PITANTS..B.A.9 kand.telchn.nai*
Insulation for high temperature steam. Energokh02. za rub.
no.2:41-42 Mr-Ap 160. (MIRA 13:6)
(Insulation (Heat)) (Steampipes)

KW5VBTOYA, I.V.; HAYANTS, D.Tu.; SHINKEVICH. V.I., dotsent, kand.
tekhn.navk, obsbehly-14C.-'
[Collected problems on projective drawing] Sbornik sadach
po, proaktsionnoun cherchaniiu. Obshchala red. N.I.Minks-
vichs. Ninsk, Red.-Izd.otdel BPI im. I.Y.Stalina. 1959.
219 pe (MIRA 12M
(Mechanical drawing) (Geometrical drawing)

khn.nauk,
-91y" Ip . _XANTSMOVA, 1-Y.; SHINKEVICH, IN.I., kand.te
I
NIF -
red.; CHEMAK, I., red.; STEPANOVA, N., tekhn.red.
[Mechanical drawing) Hashinostroitallnoe cherchenie. Pod
red. N.I.Shinkevicha. Minsk, Gos.izd-vo BSSR, 1959. 222 p.
(MI" 12:8)
(Mechanical drawing)

-- w"
SHINUTICH, N.I. 9 kand. tekhn. =~kp dotsent; 14ATANTS D Tu ; MANTSVETOVA,
I.V.;KONTSEVMA9 T., reZ;~~~'*,
[Collection of probleims concerning tbreadedt welded,, amd riveted
Joints] Sborx" madach po rezIbMm soadineniiar. Obsbebaia red.
N.I.Shinkovicha. Minskv Redaktsionno-izdatellakii otdol BPI in.
I.V.Stalluas 1961p 93 P. (MM .14:7)
(Screw tbreads) (Welding) (Rivers and riveting)

SHINKMCH, Nikolay losifovich,, kand. tekhn. nauk., dotsent; MANTS
Dora Yullyevnat MANTSVETOVA,, Irim Vvevolodovua; fiwio,
Sh.l., te)dm, red.
[Manual on welded., threaded and riveted joints] Spravocbnoe po-
sobie po mrMm. rez1bovyr i anklepochnym soedinanilam,
Minsk, Izd-vo 1.1-va vysshego,, orednego spetsiallno o i profes-
sionallnogo obrazovaniia BSSR,, 1961. 298 p. fMIRA 15:2)
(Screw threads) (Electric welding)
(Rivets and riveting)

MANTSVETOVA, Irina Voe,rolodovna; L*147p, p9ra -1~4''yevna;
AKALOVICH, IN., red.; KISLYAKOVA, M.p tekbn.
[Projection drawing, with a collection of problems)
Proektsiomoe cherchenie so sbomikom zadach. Izd.2*., pe-
rer. i dop. Minsk, Izd-vo Y-va vysshego, srednego spetsi-
allnogo i profassionallnogo obrazovaniia BSSR, 1963. 369 p.
(MIRA 16:12)
(Mechanical drawing-Instruction) (Projection)
00-0

MAYANTS. Dora Yul,!yevi-, a; 1,'INTSVETOVA, Irim Vsevolodcr~,Yiu;
- --6
1 ~~SiY631fcvich, kand. tekhn. riauk, dots.; TETEhINA,
L.N., red.
[Col.lec'.Aon of problems on rnec~hanic&l drawing; tb-reacied,
welded and riveted lio-1-ritsl Sbornii( zaduch po cht.,rheniiii-
rez'bovye, svai-riye i zaklepochrrye soedinentia. 2. izu.,
perer. i dop. Pinsk, Vysshaia sl-.kola, 4-1,7 p.
(milaA 18, 2)

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teal ROVIMS maw Rin-53-15 Oftheir dopelode-ace upon parmstan
i the tweltagnaing ~Irless- DoMady Akod. Ned
Tell it Noe 11
SSSR T?VS.) 50, 121-124 (1945). (Russian)
Let W be a matrix of ordet a. The proMem 6 to design a
11UNIST10121 MA OmYhigsl rapidly convergent iterative scherne for computing on
methods eigenvalue A and corresponding 6genvector r of W. Oven
some initial approximations 4 ra. The approath con "WTV" I
Mal
hen is the iterative sointim of the non-linear o*em al
equatkwo (*) (W-XE)P-O (E-unit matrix), vjb*t to, the
restriefian -.0). Wier afswfthn~by.
t1se authoor and by4ftlMn did not always converre On'
were of the eydic via~vtepcategoryj but one is nm i I.'.
Which is CjA%W4 to work always. at the Wat of ow.
Posed
matrix inmaim per sW
the author amnm,
In the faviewees inoution
without lose of qe6emlity..by subtrwilng WiSE from W. tie
0" paMflow W into onbhotrices of orders I is
WV

7--
WA wlites pa.El.x]r. Then, given Ai, x&, he gctsAi+t. xw
by IU fbrmnlai
Where a-%
11 Ow Gmt. appmImat;on Is good enougb, some saving of
t%ft results from the alternate formula
-w,(B
-Then we n6w #Omsnias kw tMiputing t6 Jtrivaovtpw
*j* Sir! tbAiVkp"*tw4M'VAkh Wdepen&Thim
~D 2 w 0" 6. d* $am. i - --
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cm-~- .-
0606 the Vateid
00669.19. A Mid,the last
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floquandits cl pasratomk 094"08. L S. MArIffis. -00
i
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U111LIM); cf. C 4 40. 49-r". Putthrr of
00 Ar nuith. Oval wk~ 'A the CIL.? L 1,*,I,tbc
11cill 1.1 the Irrsun .00
00 j VOINA j4W%% W till 0-011-011-C POUP 44 ""')' "t the
1:
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at a Ono

HAYANTS, L. S.
'Theory of Characteristic Frequencies and Certain of Its Applications.0
Sub 24 Nov 4?, Physics Inst Imeni P. N. Lebedev, Acad Set USSR
Dissertations presented for degrees in science and engineering in
Moseov in 194?
SO: Sm No. 457, 18 Apr 55

Sp6atrs, Bimnd
Taeteriitjo Frequencies," L. S. JIBOR
oory_of Cb&
Nc.
xmt*,, mwr,ir zo -f
va~ ljj~j.. '4;"t Ilia
ecu "'S".9 rl~' pless
t
u o.
GIB,
outd) ;Jta Aug.
030 ck ftlai~cai, 0t
a Imeal
Um
Co

1*0000600060000000
IOU*
0 C 9 tV 6 it A L 4 01 0 tQI
---- ---
0
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' A"eve
a A a a 0, AV a
141, -14, -Nt
I W, k114'9.
IVMSM. too P" uwj txdtwl *Am
pmetwivau we mOj~9m#d%* MU wFt331m
mumuttod 10 W8304" ""I*K- jo ViNt""
pttq tjtMWfp A*) tuoqwap&a jvMjsKwqj dwo
mm) tift "MV1 -4"=Q*Ah 1"twe P-4 J-\
frdpuO ma ft" ft- wpqwj q (46" 1 -4"9

wpmm 0 was& womwed Pa

MOW
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;Al
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lip *0

&,A
if
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it,
umsamme-jet of Temperals- bpromArs" Of Dl'
Irttk r,,,.,AWty mm Ausle of I- Of DW-
'k. 6. th, c"O"eirr-wove abuse. (In fi-sian.)
TA N=A F brku". 7 coo
19. W. P. coo
nj r3lati d[4cl-
Prrm-ms thmetwal baws cA pulbuil
suination of thv A- MJW~ fiewhs of det-imiti- x**
in glytvlb at 3.22 (..on. at. tabulstird and rWed.
0
Flpt-riinental inrthod is (h,"bed.
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SAISON0,45 W4#-Tjm- las"llboll RI&AS1 &A 0" As&
--"-; is
119.4
1.1t0fMI 0.0.0 *g a

MAVANI-45,
3618 The ElImInuflon of Depenclent C-d1nale In he
I S: "I
7%epry of-)LIbratinn of
National &4ence FounUe"1810"110 1110ecu P'.
It,.. T.111tion, . W.-juy
p r1gWJ In Doklady Akademh Nauk SSSR, v. 89, 1053, p.
4ilo)
DeMdent coordinates were introducrA in addition to In-
=1_.1 cam in order to tate advantage of symmetry of Ow

MAY"", L. S.
~S~/Phjaies Molecular 0oclUatibno 21 Nar 53
I-T
PElimination of Dependent Coardinates in.the Theory of
..-,.6scillations of Multiatomic Molecules,'L~i. S. Mayants,
~'~~*ratov Pedagogic Inst
DO SSSR, Vol 89, No 3, pp 423-426
Computations of additional relations between syetems
of-coordinates were obtained in watrixform Vj.'~M. A.
Yellyashev (Cf. "Oscillitions of Molecules" 1949).
Uthor considers this problem to be purely mathematical
derives solutions by means of linear algebra.
by Acad G. S. Landsberg 8 Jan 53.
272M

SUBJECT
AUTHOR
TITLE
PMODICAL
USSR/MATHEMATICS/Theory of functions URZ 1/2 PG - 333
KOVALEV I.F., MAJANZ L.S.
k new method for the computation of partial derivatives of the
roots of' the characteristic equation with respect to parameters.
Doklady Akad. Nauk 108, 175-178 (1956)
reviewed 10/1956
Lot be given the matrix W the elements w k1 of which depend on the parameters
t 0 . 1p2p ... M). Lot the eigenvalues of the characteristic equation
)W - )LEI - 0
be ~V-17'n. The author gives the following formula for the computation of
partial derivatives of the eigenvaluest
Sp( a W fi)
i, i -ti
~)tj Sp A
where A(') denotes the matrix adjoint to W E andA(') is its transpose.
'a W r.-< i )
The computation of is not difficult, while for the computation of A
an artifice must be applied since w - NE - o. Denoting B - w - Wjr6 and

Doklady Akad. Nauk 108, 175-178 (1956) CARD 2/2 PG - 333
writing B in the form
B ---I
JJBO
v b
where B0 is the submatrix of (n-1)-th order, u is a column, v is a row and b
-J(i)
means an element, then for IL one obtains the formulat
B0-1 UVB c- '_:_-B 0-1u
c-(')
A
0
INSTITUTIONt Educational Institute, Smolensk.

-PATANTS, LeBo
NOWWOMPM=
CalenUtione of isotopic vibration displacement of zero enerC7 of
MItIntoxic: molecules$ by the spectroscopic data. Probl. kin. i
)mt. 9:345-353 '57. (NDA 1113)
(Spectrum, Molecular) (Liquids, Kinetic theory of)

AUTHOR Mayants, L.S. SOV/51-5-4-4/21
TITLE; 'Onth; ~Possibllity of Identification of GIs- and Trans-Isomers
(With Respect to the Double Bond G==G) in Di-Bubstituted Derivatives
Of Ethylene From Their Vibrational Spectra. (0 vozmozhnosti
identifikataii tsis- I trans4zaaerov ~otnositellno dvoynoy
avyazi G==G) dvuzameshchenaykh proizvodnykh atilena po knlabstallnyji
speictram). I. Statewent of the Problem. ~O-Vibrations. (Fostanovka
vo~rosa. & - ko labaniya)
FMODlG&Ls Optijca i Spek-troskopiya, 1958, Vol 5, Nr 4, pp 369-377 (USSR)
ABSTBACTs The author discusses the possibility of identificatioii of cis- and
trans-isomers of ethylene derivatives from their Raman and infrared
spectra. Calculations vrera made for cis- and trans -conf 1gu rations ef
G2H2ZY and C2H2(CH21)(CH2Y) molecules, -where X and Y may be atomi or
1groulps of atoms. Pigs 1 and 2 show schematically the two types of
molecules. A model calculation is carried out for H--G::::G plane
vibrations (p-vibrations) of G2H2XY and G2Eg(CH2X)(CH2Y) molecules.
After analysing the dependence of 4-vibrations on various parameters
the author shows the limits of applicability of the principle of analoe;y
Card 1/2 in identification of cis- and trans-isomers of such compounds using

BOV/51-5-4-4/21
On the Possibility of Identification of Cis- and Trans-Isomers (With Respect to
the Double Bond C==C) in DI-Substituted Derivatives of Ethylene From Their
Vibrational Spectra
p-vibratione. For G2HZ(02X~(02Y) moleoAles identification of
trans- and cis-isoiners, using 'p vibrations, should be made with great
caution and only if force fields in such molecules and in those used
as standards are known -with sufficient accuracy. The author thanics
I.V. Obrelmov for his interest. There are 2 figures, 1 table ani
9 Soviet references.
ASSOCIATION:Institut eleraentoorganicheskikh soyedineniy, AN SSSR, Optichesknya
laboratorlya (Institute for El"wnt&1-zrganj1c 0*z*6w4v j AeadetW ;of Scienc
of the U.S.S.R., Optical Laboratory).
SUBLITTEDt November 1, 1957
Card 2/2 1. Ethylene derivatives--Spectra 2. Raman spectra 3. Infrared spectra

AUTHOR. Mayants, L.S. SOV/51 -5-4-5/21
TI TLE: A~np~roved ~Method~o Calculation of Purtial Derivatives of Normal
Vibrational Frequencies of Polyatomic Molecules with Respect to
Various Parameters (Us overs hens tvovannaya metodika vychislaniya chastryk-In
proizvodnykh ot chastot noriaallnykh kolebaniy mnogoatoranykh Wolefoul
po razlichnym parametran)
PSR:EODIC&L: Optika i Spektroakopiya, 1958, Vol 6, ITr 4, pp 376-383 (USSi?)
ABSTRAZT: The frequency toi=44ri-) and form (P1) of the i-th normal vibratioL
of a molecule may be obtained by solving the equation er er 11, where
7( = T-l.U, T-1 is the kinematic coefficient matrix, and U is the
force constant matrix. To calculate the partial derivatives of Ul
voith respect to force constants mu Yie use the equation
Ju
0
'where
OL Pi and
Gard 1/2 gT satis f lea 'Aip-I To calculate the partial derivatives cf ty
Wpi L

BOV/51-5-4-5/21
A,n Improved Method of Calculation of Partial verivatives of lJormal Vibra~~ional
Frequencies of Folyatomic Molecules with Respect to Various Parameters
with respect to parameters mT (kneplat'c coefficients depend only
on these parameters) the follovdrig equation Is used
a aT4 .0.
whore U Calculation of (6U/6mu) and (21T 6m ) presents no
u ri
difficulties. The value of 741 is obtained together viiL )~ using the
method described in Refs 5.4. The author sho*s~~how to calculate -p4i
using the same method. The paper is entirely theoretical. There
are 5 Soviet references.
ASSOCIATION Institut elementoorganicheskikh soyedineniy, AV SSSR (Institute for Elemen
al Organic Compounds, Academy of Sciances of the U.S.S.R.)
SUBMITM- Rovember 10, 1957
Card 2/2 1. Mlecules-Vibration 2, Vibration-Mathematical analysis

507/51-5-5-4/23
All THOR L.S.
TITLE; On ,he Poskiibility of Idaztifica-Uon of Giz- and Trans-Isalars
(With Respect -ro the Dou~lo Bond G=aj~ in Di-Substituted
of Ethylene from -,iiair Vibrational Spectra. (0 vozuozhnosti
identifikataii tui6- i trars-izi-x:o3rov (ottiositallno dvo",noy sv-ani
G==G) d-vuzw,,iashchor-iiykhpxoly2,voorylrli otilaria po kolobatollnyw z3p,)-~
11. G;r--G Vibrationri. C-lial Vi~rutions. )[,p Vibratioris.
(II. C,=G-kolabazii~a. C-Sal-lcol3baniya. J./.,-kolebaniya)
PERIOD13a; Optilca i Spaktrozkopiya, 1958, -131 5, Yr 5, pp 511-519 (US..d,
iLBSTRA.GT; In the proceding paper tFarc 1, Ref 1) the author shovied i
posisibla to identify ats- aa! - eans-ijimars of ethylene deriv-,7iv-
from their vibrational spoctra P-L-d discasued the use of f5 vibr-,-.-
(planar deforriational t;---'-S' vibra-jons) for this parpose. 7h,.;
papei iB a emUnuatlon of Fuf-,, I and it considers identifica-cioL,
cia- ana t4~uns-iscmara6 k;==%; vibratiou5, G-Hal vibra-':i-r.L,
X.13 vibrations , knon-planar vibrtrions re",-'ad to rotation of
==G and C==G"*" t;rcrupe. &cout thrj double bond C==C and -1o of
Card 113 G==C bond out of the ~~Z and G planes The La3thodr. of c- --',.A.LA-AUU

3011/51-5-5-4/23
On the Possibility of Idontification of Cis- Lrid TnAnz-Isol~-,rs Oi~r :~"pact tc
tha Double Bond 0==G) in Dt-Substi'Wtod Deriyatlvab of UthylEma from their
Vibrational Spectea. II. G=:G Vlbx,,~icrs - (;--Val '~ibr--tiojis. )L,,p iibrulAons
and the ncraenclature are uai-e ts in Par-~ I. iL6uin ;2H2-Y a&
G2H2(GH2HACH2YJ wodals are conf-idered. It is foum! 'hut froi.. 4-h-3
rela-Ava posi+,ion of The G-01 froquency cis- and ---rans-isom4rs if
G2H2(GH2Y)Gl moloculou ",! be reliably identified, since the j--~;l
frequency of the trans-configarr,+ion Ghould be higher than tho
frequency of the cis -confi6pu ration, if ali the valence angles dt the
carb-c,n atcaLs vhich are board by the dcuble boLd (i.e. angles GK1,2
and /91,Z) are equal to about The cl.5- and tranB-isoners cf
G2H2WH2XACH2Y) mnlOculus laa~ be Identified frw the position cf the
C==C frequency, provided that the force field of the 02H2G2 group ~,i:e
the angles ml,,> and p1,2 aro "he swie in the stadied Liolecule and in a
Card 2/3 mclacule used as a standard. The id6Dtification of the cis- and

SOV151-5-5-4123
On the Fossibility of jdentificttiOn of ~is- and Trans-Isowers kMth Respec-
the Double Bond G=zGj in Di-Sabsti'Luted Uarivutiveu of Ethlene frof~ their
Vibrational Spectra. II. k;mm;; Vibrdtlons C--Hal Vibrations. XP Vibrations
trans-isowers of (;2H2kGH9Xj(GH~Yj Liolaculas from frequencies iS
not :~Aiable, if i;~Oro is :-,(d aort~xin-:, ~hi-. tho force field of the
molecule and th.3 an6lbs 411,2 /11,? bLro tha same In 'he woleculas
studied and that used as a The author thanks I.V. 0Lr-j1i:--v
for his intert-st. YharQ a:e * tdLlal, and I SoviaT reforarce.
SUBMITTED: NovaAer 1, 1957
Card .3/3 1. Ethylene derivatives 2. Nuclear isomers--Spectra

24(7) SOV/51-6-5-5/34
M THORS Mayants, L.S., Fono-7, Ye.W. ar.4 M.1,
Ti TL3- - Calculaticu ef 1,1-.arazterictiz! i, "'chn-pounds of Ph,"phonls
(Ras ahet kharak-t a r, st:,- so jed u at J~zsfr)m)
Charicterizti.: Vikxati~,~c.g of t~-,N PSr,.'1 a;s~d FQB,-3
k-fj'
K-313, P013r.-, P-23,13 a&% PIbBrl-)
PAjODI -"--L OptiLa i SpaLtr~~z1ft-~-:1kY-sm Iq5-z 7-1 li- F .5Pa-5S-3 (USSR)
ABSTRACT: T-.e -~,aner r6n:rr,,~ t!ie of vibrationz; of siw-~Ia
nole-71ii-tib vMi ar.4 PzZ PSV31.3 and FSE'r5.
Folln,sing A11,3,:~ a:-L" (2e,~ -t is c.:;-uxad~ tyA-t tlie aquilil~rivjl
ccafiguratic.a:-, :~f &-'I ttDs3 :,.e t,,) the G5v rro-j-.) (seei
c!,. p 5~;Z) and t--ia-, f-:!j-cw.!a can be writtGm ZPY.-,,
iv~~ar.q Z = 0 or S' ~:-,d Y = C,~. It f~-'IL-xs tylat six fundamerA&I
"-a c,)rt,4rrv2 J.~- t1- vli%ritic~nal spa-!tra of the ZPY-z
molac-,A&s: t!%ro-e of v~sse be Pally synnstric ane.
A~jad. in tfteir calaulatiors t'~s
r. u I ~a (Rsfra 4-..4)and the following
Se7,3--alit-i54 acecd1ratas, uf tl-.a .Ond
p--Z am" L) ZI,w Of ". '.a 7
IaS (J.
Card 1/2 an,' Z--P--.tj (1 2, ::=~.In&ts.3 were danoted by letters

3OV/ 51 -6-
Calculation of Oharacteristic Vibrations Lc I.onoounds of Phos9horu:;.
Vibrations of the 11"oloculas PO-zr,3, PSC13 und ?3r,3.
qj, Wk (k J, J) and rRspectivaiy. The equilibrium bond lonartn;;
b'~. N-0 = 1 3.. i - ~p it _." A 1 0
rere taken to 8 ?--'l = 2.02 1, P-S = M.4 '
i~--Br = 2.1P. ;,.n6PIes and Z--P--Yi were assumed ro be
tetranedral. 'me forage constants were ch-)sen to obtain the bast
possible agroement betmoon the CaLculated and obsorval Raman and
infrared absorption fraou;)ncles. Designations of tho force constants are
'An rable I and tneir values kin 1()6cm-2) in Table 2. -rho calculations
yielded frequaiiclas and fonas ef -the nornal vibratiom of the four
moleculea and tho sansit1vtties of tf,5-ia frequencies -to changes in tt..3
force constants, atomic mavsa~, . b.:~,cd Iong-ths and angles - Tho results
are -ivon in Tabips 3-5. The fora of fully s~=otric vibr~ztione V,
(P--0 fr3craenciaa in PO,'1,3 and *.-~%13.,-3 and F--S frequenAim in M31.3 and
v
PSBr3) snould, strict!v, be by th3 eoordiwte ',) bat -rable
shows that it is rt v
t q, f and cF. Ther-~
1 fi-Ire, 5 tables aiJ f tire Jovj3t,
2 - ,:i!jan and I Fremcli.
June 'I. I~irS

S041/51-7-2-5/34
AV THORIS Mayants, L.S. , Popov, Ye.M. and Kabach-ni1c, M.I.
TI TLE 3alculation of the Characteristic Vibrations of Phofiphoruz Compcnindz 00?.acaet
kharakteristichnykh kolebaniy soyedineniy foefora). Ii. Charaeterjot!.c-
4
Vibrations of the (CH,30)3PO and (CH30)3FS Molecules (11. Kharaktaristichnyy6
kolobaniya molekul (CH30)3FO i (CH30)3PS )-
Fr,~RIOD10AL: Optika i spektroakopiya, 1959, Vol 7, Nr 2, pp 170-17? (USSR)
105 TRACT: In Part I (Ref 1) the authors reported the results of calculation of the
normal vibrations of the POC13, FOBr3, nC13 and PSBr3 molecules and
discussed vibrations of these molecules corrosponding to the P ~ 0
and P ~ 3 frequencies. It was shown tnat the symmetrical vibration 11~,
of the four molecules mentioned above has not quite the form charactori5t-lc
of the Q coordinate, which refers to the change of the P == 0 or
P ~ 3 bond lenrth. In ord er to d etermine the ef f eat of coord Inates
which are further from Q~ on the vibration Yl, the authors calculated the
fluily sywietric vibrations of the (CH30)SPO and (CHP)3PS molecules for
cartain estimated values of the force constants and they determined the
sensitivity of frequencies to change5 of these constants. Of the
possible rotational isomers of the (CH30)3PO and (CH30)3PS molecules
Card 1/2 four Laodels were selected (figure on p 171). The models I and Il have
I

SO'V/51-7-2-5/34
Galcelution of the Characteristic Vibrations of Phosphorus Compounds. II. Characteristic
Vibrations of the (01i.30),zP0 and (CHSO),3M Molecules
the synmetry C.3V, the model III has G3 symmetry (the C--O bonds lie
in the plane normal to the third-order axis) and the model IV has
CS symmetry. The results obtained (Tables 2-6) and those of Part I
(Ref 1'j"'lead to the conclusion that the vibration -#i Is very characteristic
in form and frequency of the coordinate 0. and related coordinates.
The P ~ 0 and P--O frequencies are used to show that the models I and III
are most likely isomers in solutions of (CH30)3M - There are 1 figure,
6 tables and 20 references, 11 of which are Soviet, 5 English, 3 Geman
and 1 frcm an international journal.
SUBMITMD: November 24, 1958
Card 2/2

S/051/60/008/02/010/036
AUTHOR: Mayants, L.Sp E201/E391
TITLE: Calculation of Derivatives of the rrequencies and Forms
of Normal Vibrations of Molecules in the Case of Symmetry
- V
PERIODICAL: Optika i spektroskopiya, 1960,rVol 8, Nr 2,
pp 199 - 205 (USSR)
ABSTRACT: The frequencies and forms of normal vibrations of
molecules are calculated separately for each type of
symmetry from the appropriate equation. The present paper
deals with methods of calculation of derivat7ives of the
frequencies and the forms of normal vibrations using
separate equations for each type of symmetry. It is shown
that one can calculate derivatives also in the case of
degenerate vibrations, even when the change in the parameter
considered disturbs the molecular symmetry. The paper
entirely theoretical. There are 4 Soviet references.
SUBMITTIED: May 21, 1959
d J

A19THOR: ~~ts 8/02 DJ6 0/131 /01 /013/06 0
DOI 3,12007
TITLE: A Nsithdd.Ibr Numerical Solution and
Numerically Awayzing Solutions of Homogeneous systems of
Linear Algebraic Equations of General Form
It
PERIODICAL: Doklady Akedemii asku'r SBSR, 1960, Vol 131, Nr 1, PP 51 - 54
(USSR,
ABSTRACT: The numerical solution of homogeneous systems of linear algebra-
ic equations of the form (A - XZ)X - 0 (in matrim-notation, where
A and B are matrices of n-th orderl X m a colmn-matrix with
n elemental A - a number) is particularly difficult because both
matrices are singular. The method described in the present paper
is suited both for non-singular matrices A and B and for cases
in which one of then or both are singular simultaneously. This
method consists in proper application of the following opera-
tions: 1) Numerical solution of the above equation (i) at one
arbitrary value of the root of the *ocular equation )A - XBJ - 0.
2) Transition to equation (3): (P) - AB(l))XI - 0 with the
matrices AM and B( I) of (n-I)-st order. Equation (3) has solu-
Card 1/3 tions with the same k-values as also equation M. 3) Transitio V

A Nothod for Numerical Solution and Numerically 31020160113110110131060
Analyzing Solutions of Eomogensous Systems of B0130007
Idnear Algebraic Equations of General Form
from the numerical solution of equation (3) (which corresponds
to the root of the seoUlat equation (4):
JP) - AB(')l - 0) to the corresponding solution of (1). in (1)
the order of the matrices In reduced so long until it equals 2.
(1) may be solved according to an iteration.method developed by
the author* The considerations for the above-mentioned reduction
of the order of the matrices are described,. if JAI - 0 and
JBI - 0 hold,, three cases are possible; Though the matrix X(O)
satisfies the equation AX - 01 it does not satisfy equation
EX - 0. 2) The matrix X(O) satisfies these two equations, but
though matrix Y(O) satisfies 'the equation with the transposed
matrix AY - 00 it does not satisfy the equation BY - 0. 3) The
matrix X(O) satisfies the equations AXaO and BX=09 and matrix
Y(O) satisfies the equations 'A"Y a 0 and Bmy a 00 In case 1) X(O)
C&rd 2/3 satisfies equation (1) when X - 0, and because of EXIO) ~ 0 the
t/

A
A Meth9d for Numerical Solution and Numerically 3/020/60/131/01/013/060
Avqslysizg solutions of Homogeneous systems of B013/BD07
Linear Algebraic Equations-of General Form
order of matrices A and B way be reduced in the above described
manner. In case 2) Y(o) satisfies the equation 61 - XB)y 0
when A a 0. Also in this came the order of the matrices A and
may be reduced in the above described manner. in order to re-
duce the order of the matrices i and _B_ in came 3),, it is neces-
saryp e.g., to omit the first line and the first column of these
matrices* The further course of the calculation is shown step
by step. All formula* and calculations written down here can be
simplified if matrices A and B are symmetric or if B - E holds.
There are 3 Soviet references.
ASSOCIATION: Inntitut elementoorganichookikh soyedineniy Akademii V-Suk SSSR
(Institute of Elemental-orizanic Compounds of the Academy of
PRESENTED: November 14, 1959, by 1. V. Obreimov, Academician
SUMITTED: October 27, 1959
CW 3/3

MAYANTS, J. S.
Calculating the derivatives of the frequencies and forms of
normal vibrations of Uolecules in the presece of symmetry* Opt.
i spektr. 8 no-2:199-205 1 160. (MIRA 13:10)
(Molecules-Vibration)

MAYAUTS, La,zarl Solomonovich; KITAYGORODSKIT, A.I., doktor fiziko-mtem.
nauk. otv.red,.; GtMff, K.F.. red.lzd-va; SMCHWO. G.F..
tekhn.red.
ETheory and calculation of vibrations of molecules) Teorlia i
raschat kolebanii molekul. Moskva, Izd-vo Akad.nsuk SSSR. 1960.
526 p. (KM 13:11)
(Molecular theary)

I
LANDSBERG~ G*S.j, akad. [deceased); WANTS., L,~.S, doktor fiziko-natem. nauk;
RATUrEV, H.L., doktor khi%-.-n--aa-j-11AffSHANSYAYA, F.S.j, kmA. fiziko-
imatem. ingn ; SMIN, Kh.Te... 1-and. fiziko-ratem. nauk; ARANOVICH, P.M.,
kand. khim. nauk; BYALOVA, ~.V.j, nlad. nauchrjyy sotr.; ROTTKOVA, S.V.,
nlade nauchMy sotr.; RABINOVICB, N.7a,j mlad, mauchmy sotr.; BERK--
GOT, V.G., red. W-va; GOLIJBI, S.F.p tekbn. red,
[ScatterIng of light and Infrared spectroscopy; bibliographic index
for 1928-19401 Rasseianie aveta I infrakrasnaia spektrookopiia-,
bibliograficheskii ukazatell 1928-1940. Moskva, Izd-vo Akad. nauk
SSSR.. 1961. 1,5i P. (MIU 14-- 11.)
1. Akademiya nauk SM. Komiosiya po spektroskopii. Sektor seti
spetsiallrykh bibliotek.
(Idght-Scattering-Bibliograpby) (Spectrump Infrared-Bibliograpby)

POPOV, Ye.M.; KABACHNIK, M.I.; 14AYAVTS, L.S.
VIbration spectra o-f organophosphor-us compounds. Usp.khim. 30
- n~,7:846-876jl 161. (MIRA 14:8)
1. Institut eieniontoorganicheskikh soyedineniy AN SSSR.
(Phosphorus organic compounds-Spectra)

i*OTJ~Rl,-)~.-Ri,li-.-..-..il-ri.--Kbaiia..-Po spektr 3kopil. AXZssRt,vyp. it 19649
TAGS-, -Influence coeffi-ciento molecular vibration theory,
illbifi?~ The-Iransformation properties of the matrix U do not

r~:,V~-,!-~,~-,~ -, :--~

MAYANTS, L.S.; GALY.,Jill, Ye.G.
I a
Characteris~Ar, nature cf deformiation b~ -- -. : . ,. - -~, , -
. I -
hydrocarbons. i spektr. 16 nc,.5:'7z,4--'52 '~; '--.

MAYANTS, ll.~.
A -1 ' ctlw i n g I` r tf:e c ple. n- e r f cr:; i: ~.,,i -. - .., 7 . - . I ...
lq,Olek,iL~ar vanrailic~~-,s Ein,,. ,&-,a+.ed -*~', . .
no. 5: 753-162 " I , I . I
,Y U-,.

ikOOESSION NR: AP4033400 S/0076/64/038/003/0623/0631
AUTHOR: Mayants, L. S. (Moscow)
TITLE: In tramolecular reaiTangements and molecular vibrations
SOUROE: Zhurnal tizicheskoy khImil, v. 38, no. 3, 1964, 623-631
TOPIC TAGS: molecular vibration, molecular rearrangement, isomerism,
inversion, intramolecular regrouping
ABSTRACT: Intramolecular regrouping Is every dot of molecular con-
version Into one or several other molecules,.specifically Into another
Isomer or configuration. In this broad sens6 intramolecular re-
grouping plays an important role, since one of the stages of many
chemical reactions Is -the decomposition of some molecules Into parts..
Intramolecular regrouping is possible only with an appropriate change
of the Inner coordinates. Such changes, howevert may occur only due,
to intramolecular oscillations. Therefore, the possibility of any
rea=angement Inside a moleoule Is sesociated with the possibility
lof the necessary changes of the Inner coordinates, due to intramoleau-
ilar oso:13-lations. In every specific case the establishment of the
*0801b lity of a imffloient closeness of approach of the nuclei

~OOESSION.NR: AP4033400
1 parts of the molecule around
during the rotation of the individue, W
.some bonds Is of no consequence If the molecular etructur6 Is known.
in equation has been derived for the rate constant, using the her-
monic oscillator approximation and taking Into account the effect
'of.anharmonicity. This treatment shows that the activition energy
concept 1e not applicable to Intramolecular rearrangement. In
principle these processes can take place at absolute,,zero. The
article treats cis-trans isomerism as one of the examples of Intra.-
molecular rearrangement-and the Inversion of ammonia as the second
example. .Orig. art. has: 2 tables and 24 equations.
LSBODIATION: Institut elementoorganichesUlkh soyedinenly,Akademii
asuk SSSR (Institute of Elemental Organic Oompounds, Academy of
Sciences,.SSSR)
SUBMWED: O7Nar63 ZNOL: 00
PUB OODE: AP NR REP SOV: 009 OTHER: 006
2/2

C,.,I~Pmj T**Q#j,WAmj 1,.S.
Ca2cuUtIon of the V'IbratiWal epectra of C.HtGb,2Cj4s,
Zhursatriek.ts'AbInt. 6 no,52785-797 .5-0 165, .4 #
181)p)
-1. Ti",st.4tut slemantoureanicheakl.kh V
&k!*rm!t+Atl ~hrjlh 40 1965.

I
MAYANm,,9,. .0L.LGALIFEM. Ye~%- !.TFRBVKP, B-S~
Sms simpli�3a-ticna La r!a7cuJ-q-t-'ng molao)lar vibrations, Opt. i
spaktr. 18 nl-.!e933-93"f My 1~5. (MIRL 18:10)

MAYMITS, L.S.
Distribution of probabilitief; for tle of a
polyatomic molecule in a vi lira U onal stationary state. Doid. 9i
SSSR 164 no.4:852-855 0 165. (~,IRA 18:10
1, Inatitut elementoorganicheskikh soyediiieni.,;, AN L'L_':Ft. S,,Ibmittcd
March 17, 1965.

. MAYANTS., L.S.; AVERBUKH, B.S.
New approach to the calculation of intensities in vibrationa'L
spectra of molecules. Dokl. AN SSSR 165 no*5:1119-1121 D 165.
(MIRA 19:1)
1. Institut elementoorg&nicheskikh soyedinenly AN SSSR. Sub-
mitted April 29, 1965-

YAYANTS~ H. L.
Khimicheskaya Tekhnologiya voloknistykh.mdterialov (Chemical technology of
fibrous materials, by S. V. Shmelev, M. L. Yayants,, I. V. Rogova. Moskva, Gizlegprom,
1949
323 p. Illus., Diagrs., Tables.
"Literaturall P. 322
SO: N/5
668.663
.35

MAUNTS, M. L.
23353 kmsiteU d3ya sherstya my protnyahlonwf;ti. tekstil. prom-etl) 1942-t
No. 7, c. 39-31
SO: LEMPIS NO. 31, l9h9

W MAYP) 14 T S, V), L - -96~~.w
!~!m -m-ftm.."ra-
.Ea~