SCIENTIFIC ABSTRACT LOSEV, V.A. - LOSEV, V.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000930610002-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 2
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

A SANDROVSKIT, B.F.; TOLODI11TA, N.G.; YXMCMMM, A.A.; IZABOLINSKAYA,
R.K..; KOGOSOVA, L.S.; LOSEV V.A , KAYTULINA, S,?,; NIKOLAYBTS,
V,P,; OMITAYMO, R.N.; RICHIM, S.G.; CHEMSSM, L.P.:
7USHMICH, M.S.: TASEIC 0. T.T.
Basic pathophysiological peculiarity of the vital activity of
person with one lung and the functional disorders attendant on
it..Pkxt.,klin.i terap.tub. no.8:4-11 158. (MIRA 13:7)
1. Iz Ukrainskogo nauchno-issladovatelle.kogo instituta tuberku-
leza im. akad. 7.G. Yanovskogo.
(LUITGS--SMBRY) (YMABOLISM)

CMARKASSKIY, L.P., kand.med.nauk; IOSEV, V.A., kand.med.nauk; SVIRYAKIN, V.T.
Experimental data on changes in the blood circulatory system,
respiration and blood following resection of the lung. Probl.
tub. 37 no.4;88-96 '59. (MIR& 12:10)
1. Iz patofiziologicheskoy (rukovoditell - deyBtvitellnyy chlen
A19F SSSR prof .11-N. Gorev) Ipatologoanatomichesko7 (rukovoditel' -
dotsent V.F.Yur'yeva) laboratovi7 Ukrainakogo nauchno-issledovatel'-
Bkogo instituta tuberkuleza (dir. - doteent A.S.Mamolat).
(LUNGS, surg.
exper. resection, eff. on blood, blood cire. &
resp* in rabbits (RUB))
(BLOOD
eff. of exper. lung resection in rabbits (Rue))
(BLOOD CIRCUIATION
game)
(RESPIRATION
same)

LOSEV. V.A., kand.med.nauk (I:Lyev)
Some indexes of the respiratory funetion of the body following
PneumonsotouW, Yrach.delo no.6t595-598 is 160.
(KMA 13t7)
1. Tlkrainakiy nauchuo-looledovatell'skiy inatitut tubarkalaza
imani akademika T.G. Tanovskogo.
(LUNGS--SMIMY)
(RISPRATION) (BWOD--OXYGBN COMNT)

ALEKSMROVSKIYO B.P.; VOLODINA,, N.G.j GOREV,, V.P.1 YE14CHENKO, A.A.;
.1?,ABOIJMKAYA.. R.M.; ~OGOSOVA, L.S.j LOS~~[,J~,A.; MAYTULIKA., S.P.;
JaNOWMTS, V,P.; O*LIYAMKO, S.G.; CHEITMASSKIYj
~.P.j YUSHMICH, H.B.1 YASHCHENKO, T.T.
Compensation of'tlie principal functions of the organism within 3-4
years after pheumonectozy. Probl. tub. 38 no.2:47-53 160.
M~A 1~ Ill)
1. Iz Ukrainskogo nauchno-issledovatellukogo inatituta tuberkuleiza
(dir. - kandidat meditsinakikh nark A.S.Mamolat):
(LUNGS--SURGERY)

LOSEV, V.A.; SHINKARI, I.P.
-------- --
Some indices of the respiratory function of the blood in animals
of various ages. Vop. geron. i geriat. 4:62-66 165.
(MIRA 18:5)
1. Institut gerontologil AMN SSSR, Kiyev.

ACCESSION NR: AP4018163 S/0191164/000/003/0024/0025
AUTHOR: Losev, V. B.; Ry*skalova, M. F.
TITLE: Production of methyl-(phenylaminomethyl)-diethoxysilane
SOURCE: Plasticheskiye massy*, no. 3, 1964, 24-25
TOPIC TAGS: methyl-(phenylaminomethyl)-diethoxysilane, production, process.,;
arylaminoalkyldiethoxysilane, amination, diethoxysilane
A13STRACT: The incorporation of polar groups in organosilicon polymers over-
comes some of their low mechanical and adhesive properties. Methyl-(phenyl-
aminomethyl)-diethoxysilane is such a compound. This technical grade material:
can be produced in increased yields (76%) by reacting aniline with the mixture
of products obtained by esterifying methylchloromethyldichlorosilane (without
separating the methylchloromethyldiethoxysilane), filtering to remove the ani-
line salt, and subsequently vacuum distilling the low boiling fraction from the
filtrate of the reaction mass. Orig. art. has: 1 equation.

ea.
L 27790-6 EWT(11)/EPA(B)-2/EPF(c)/T/gwP(J)/EPR P-4/Pr-VPs--4/Ft-20 W/W/Mf
ACCESSION NR: AP5QG4312 8/0191/65/000/002/0026/0028
ALTMOR- Rogdanov 1. P.; Crebenshchikov&,G. V., Lo Bj; Mishcheako, M.
Molchanov, B. .1 Fee 0v, T.1-T-..
TME: Study of the thermal degradatiokf polychloroorganoviloxane polymer
SOURCE: Plasticheakiye massy, no. 2, 1965, 26-28
TOPIC TAGS: silicorganic polymer, orgenceiloxane, polychorceiloxane, polymer thotr
oxane polymer, chlorinated
mal degradation, phenylail polymer
ABSTRACT: The effect of chlorination of the phenyl radical or, the thermal stabili,
ty of Polydimethylptien~yisiloxanes(~ras studied experimentally. The thermal proper-~
ties of polydimethyl-t pory-aImet y1chloro, polydimethyldichloro- and polydinethyl-
trichlorophenylailexane were determined by recording the thermal effects of pMR1__
__LysisNo 800C on Kurnakovia pyrometer, by measuring the pyrolytic weight los to
30000#
1000C,\ and by analyzing the gaseous decomposition products generated up to I
The non-halogenated polymer showed a small exothermic affect at 530C, while the
chloritke -substituted specimen exhibited stronger exothermic effects at 550-565C,
the height of the peaks increasing with the number of chlorine stoma Chlorine
Card

__4
L 27790-65
A=SSION NR: AP5004312
containing specimens started to decompose at lower temperatures, and the rate of
gas generation and the percentage of bonded chlorine split off ab hydrogen chlor-
ide both increased with the degree of chlorination. The amount of hydrogen liber-
ated as 02 or methane as compared with the initial hydrogen content of the methyl
groups decreased in the chlorinated polymers, indicating a shielding effect of
chlorine with respect to7the stability of the methyl. Canerally, the thermal at&-,
bility decreased with Lacteaming chlorine coatent. orig. art. has: 3.figures and
I table.
ASSGCWIOMt Monis
SUBMITMI 00 ENCL: 00 SUB COM 00# W;
ND REP 8011 002 OMRS 002
Card 2/2

50)
AUTHORS: Voronkov, M. G., Candidate of Chemical SOV/3.0-58-12-39/46
Sciences,.~.osevV_ B.
TITLE: Chemistry and the Practical Application of Silicon-Organic
Compounds (Yhimiya i prakticheskoye primeneniye
kremnlyorganicheskikh soyedineniy) All-Union Conference
at Leningrad (Veeso3-,uznaya konferentsiya v Leningrade)
PERIODICAL: Vestnill: Akademii nauk SSSR, 19519, Nr 12,
PP 97 - loo WSW
ABSTRACT: The 2.Conference wari held from September 25 to
September 2?. ',-,ore than 650 persons from various
townn of the Soviet Union as well an from foreign
countries took part in the nonfPr,.Yrice, among them also
indurtry futrotionaries. The conference was organized
by:Otdeleni.ve khirdrheuki~h nauk ( Department of
Chemical Sciences), Institut khimii silikatov Akademii
naul: SSSF (Institute of Silicon Chemintry, Academy of
Sciences, USSR), Vsesoyuznoye 1,.hirlicheskoye obshchestvo
.Card 1/6 im.D.I.Mendeleyeva (All Union Chemical Society imeni

Chemistry and the Practical Application of Silicon- SOV/30-58-12-39/46
Organic Compounds. All-Union Conforence at Leningrad
D.I.Mendoleyev), Gusudaritvennyy komitet Soveta
Mini.,~trov SSSR po khimii ( qt~-fe Committee for Chemistry
of the USSR Council of Mlnisters)and Leningradskiy
sovnarkhoz (Leningrad Economic Council). Lectures
dealing with the following Gubjects were held at
the plenary sesnion by :K.A.Andrianov: "On the
Particular Features and Prospects of the Development
of Silicon-Organic Chemistry in the Soviet Union";
V.Bazhant :"On Work Within the Field of Silicon-
Organic COMPOLVICIS LIt the Chemiral Institute of the
Czechoslovakian Academ- of Sciences". Conference work
was carried out in 4 scction~: Monomers, polymers
and their practical appliCtLtiOrk, 113 WC11 as analysis
and physico-chemical research meNjods.
N.N.Tishina, K.A.Andrianov, S.A.Gol tsov et al.
showed the possibility of developin,_~!e
g a new technological
method for the purpose of obtaining phenyltrichloro-
silanes.
Card 2/8 I.V.Trofimova, K.A.Andrianov, S.A.Golubteov gave

Chemistry and the Practical Application of Silicon- SOV/30-58-12-39/46
Organic Compounds. All Union Conference at Leningrad
new data on the synthesis of trichlorosilane by
the interaction of hydrogen chloride with silicon.
P.Rostaishevskiy gave a report on the works carried
out by Polish scientioto in the field of methyl-ethyl-
and phenylchlorosil'ane.
M.Ye.Dolgaya, Ye.A.Chernyshov, I& Yaiang-liang spoke
about methods of synthetizing aromatic silicon-
organic monomers by the interaction of hydroisilane
with aromatic hydrocarbon in the presence of catalyzers
with formation of the compound Si-C and separation
of hydrogen.
N.F.Orlov, B.N.Dolgov and M.C.Voronkov reported on
th e results obtainfl--d by raeans of a new method of
synthetizing triorgano-voiloxy derivatives.
G.I.Nikiahinj A.D.Petrov and S.I.Sudykh-zade spoke
about the behavior of various dichloroalkanes and
dichloroalkenes with chloric atoms at the conditions
of a direct synthetization. -
Card 3/8 V.A.Ponomarenko, A.D.Petrov et al. gave a report

Chemistry and the Practical Application of Silicon- SrjV/3o-5:8-12-39/46
Organic Compounds. All Union Conference at Laningrad
on the catalytic affiliation of hydrosylanes to
unsaturated compounds.
V.F.Ifironov, V.A.Ponoiarenko, A.D.Petrov et al. spoke
about the comparison of the properties of organic silicon-,
germanium-, and tin-compounds.
S.I.Sadykh-zade, A.D.Petrov, B.N.Dolgov, and N.P.
Kharitonov apoke about new methods of synthesis of
simple organo-silicon vinyl ether.
A.H.Nesmeyanov, R.Kh.Freydlina and his collaborators
dealt with thermal and catalytical telomerization of
hydroxylanes with olefins.
Yu.K.Yurlyev recommended a catalytical method of
synthesis of silacyclopentane from furan and silane.
N.S.Nametkin, A.V.Topchiyev et al. reported on the
research of the reaction of chloromethylation of
silicon-organic compounds'.
M.G.Voronkov et al. showed that the organosiloxane
easily change over into heterolytic fission repctions
Gard 4/ 8 caused by the influpnce of nucleophilic and electro-

Chemistry and the Practical Application of Silicon- SOV/30-58-12-39/46
Organic Compounds. All Union Conference at Leningrad
Card 5/ 8
philic reagents.
A.G.Kuznetsova, K.A.Andrianov and D.Ya.Zhinkin gave
new data on the common hydrolysis of aequimolecular
mixtures of diethyl-dichlorosilane with phenyltri-
chlorosilane.
B. Lengyely T. SzekeJgA.Cg;uppon (Hungary) reported on
results obtained by physico-chemical investigations
of the process of hydrolysis- and condensation reactions
of methylchlorosilane mixtures.
S.N.Dzhenchellskaya, IC.A.Andrianov, Yu.K.Petrashko gave
data on working results within the field of cata-
lytical polymerization of the hydrolysis products of
di- and tri-functional compounds.
M. Itud"err-
(Czechoslovakia) reported on the investigations
carried out of the polymerization of octamethylcyclo-
tetrasyloxanes under the influence exercises by alkalis.
K.A.Rzhendzinskaya, I.K.Stavitskiy gave a report on
the synthesis of chlorine-containing polysiloxane-
caoutchouc SKT_Kh5.
N.B.Baranovskaya, A.A.Berlin et al. suggested compounds

Chemistry and the Practical Application of Silicon- SOV/30-58-12-39/46
Organic Compounds. All Union Conference at Leningrad
on the basis of liquid polydimethylsyloxane which
solidify at normal temperature.
A.I.Glukbovaq K.A.Andri:,.nov et al. grave a report
on obtaining a heat-stable rubber-like polymer.
.A.V.Topchiyev, N.S.Nametkin and collaborators spoke
about the polynerization of unlimited silicon hydro-
carbons by making use of a complex catalyzer triethyl-
aluminum tetrachloro-titanium.
A.A.Zhdanov and K.A.Andrianov spoke about the synthesis
of polymers with anorganic chains.
V.V.Korshak, G.M.Frunze, E.V.Kukharskaya, D.N.Andreyev
reported on polyamides which are composed from silicon-
containing dicarboxylic acids and posses.a. higher
elasticity than similar polymers.
L.H.Volkova, K.A.Andrianov and assistants reportea
on a method of increasing the mechanical strength
of silicon-organic polymers.
I.Ya.Guretskiyt A.P.Kreshkov, and P.A.Andreyev under
Card 61 a various conditions investigated the interaction of a
number of silicon-organic compoundo with cellulose nitrates.

Chemistry and the Practical Application of Silicon- SOV/30-58-12-39/46
Organic Compounds. All Union Conference at Leningrad
N.P.Kharitonovt and Biff.Dolgov suggested a new material
for heat-, moisture-, and electrical insulation
on a silicon-organic basis to be used instead of
enamellcoatings.
B.A.Kiselev, Z.A.ZinovIyev et al. produced a hydro-
phobous glass Textolite on the basis of polyester
compounds which contain silicon-organic compounds.
bl,.Ya.Borodin ., Z.I.Kazakova, et al. obtained heat-
resistant and solid foam material on the basis of a
combination of silicon-organic polymers with phenol-
formaldehyde- and epoxy-resins and nitrile rubber.
A.P.Kreshkov dqlivered a . port on the successful
analysis of-silic6n-organic compounds and gave an
outline on further prospects of development.
S.V.S~avtsillo, A.P.Kreshkov, A.P.Terentlyev et al.
problems of the elaboration of control
methods for the production of silicon-organic monomers
and .polymers. , V/
Card 7/8 1 - Cerm~&., D. Snobl, M.' Dvorak (Czechoslovakia)

Chemistry' and the Practical Application of Silicon- SOV/30-5,9-,17-39/46
Organia,.Xompounds, All Union Conference at Leningrad
discussed resulta obtained by the radiographic
determination of the activity of silicon-copper
alloys which are used for the direct synthesis
of methyl,,;h1orosilanes.
In concli~sion D.P.Novikov spoke about the present
stag4 of development and the plans for the further
development of the production of silicon-organic
compounds in the USSR. A number of measures was
:Fecommended for the further development of the
discussed field of science and technical engineering.
A committee was elected forthe purpose of working
out the nomenclature of sillcon-organic compounds.
The authors of the present article rcjrr~!t that no
reports were delivered at the conference on theory
of technological processes or on the caloCLat.Lon and
design of chemical apparatus.
Card 8/13

AUTHOR: Losev, V.B. cov/80-59-1-39/44
TITLE: Joint Condensation of Substituted Esters of the Orthosilicic
Acid and the Ester of the Orthosilicic Acid With Poly Esters
(Sovmestnaya kondensatsiya zameshchennykh efirov ortokremnevoy
kisloty i efira ortokromnevoy kisloty :j poliefirom)
PERInLdCAL; Zhurnal prikladnoy khimii, 1959, Nr 1, pp 225-227 (USSR)
ABSTRACT; When the plienyltriethoxynilane or it-s mixture with diethyl-
diethoxysilano or with tetranthoxysilane is combined with the
poly ester, a chemical process takes place because of the in-
teraction of the ethoxyl groups of the or6anic aryl-(alkyl)-
ethoxysilanes or their mixturf,~ with the hydroxyl groups of the
producing new silicon-organic
resin. This reaction result8 in ci
compounds. Their properties and characteristics, such as
acid numbers, etc are presented in the tabular and graphical
forms.
There are 3 tables, 1 graph and 4 references, 3 of which are
Soviet, and 1 English.
SUB7'ITTED: December 31, 1957
Card 1/1

AUTHOR: Losev, V.B.. SOV/60-59-1-44/44
. I X_z ~ 1 - ": -~+
TITLE: All-Union Conference on the Chemi3tr~- :~-ni P.-cact4ca-, 4
of Silicon-Or6anic Compounds (Vsescyu~:ney_. konferontoiya p0
khimii i prakticheskoinu pri!~_,cneni3ni krenneor-anicheskik-h ooye-
dinoniy)
PERIODICAL: Zhurn;_- I-;~rikladnoy lzhimii, 1959, 1r 1, PP 2_31-24C (USS11110
ABSTRACT: The 0econd All4nion Conforonce on the Chemistry and Practical
Application of Silicon-Oroanic Compounds was held in Lenin,,_-rad
from 25 to 27 September 1950, It was organized by the Technic-
al Sciences Department and Institute for Chemistry of Silicates
of the USSR, the All-Union Chemical Society imeni D,I.
Miendeleyev, the State Committee for Chemistry of the USSR
Council of Ministers and the Council of National Economy of
the.Leningrad Economical region. Over 650 specialists took
part in the work of the Conference. The Conference heard
over 100,repprts, including reports delivered by the scien-
tists Prom China, Czechoslovakia, Poland I- Hungary and Yugos-
lavia. Thi! vris opened by a plenary meeting in which
CorreBponding Member .: AS USSR K.A. Andrianov delivered
a review report on the basic stages and development line in the
Card 1/5 synthesis of polymer silicon-organic compounds. The Con-

SOV80-59-1-44/44
All-Un.ion Conference on the Chemistry and Practical Application of Silicor,
Or~7,anic Compounds
ference work was divided into 4 sectiona: 1. silicon-oreanic
monomers, 2. silicon-organic polymers-, 3. analysis and
physico-chemical methods for investigating si.licon-organic
compounds, and 4. practical application. The following re-
ports were delivered to the Oonference: by 11T.N. Tishina,
K.A. Andrianov, S.A. Golubtsov, U.I. Kafyrov and R.L. Da-
rashkevich on the reaction of phenylizing the trichlor-
silane; by I.V. Trofimova, K.A. Andrianov and S.A. Golubtsov
on the synthesis of tric'-,ilorsilane; by M.Ye. Dol-aya, Ye.A.
Chernyshov 4nd T,i M=ng-liaig on the synthesis of aromatic
silicon-organic monomers; by TI.F. Orlov, B.H. Dolgov and
M.G. Voronkov on the new synthesis methods of trialkyl-
(aryl)-siloxiderivative elements of the III, IV and V groups
of the periodic system; by G.I.,.Nikishin, A.D. Petrov, F.I.
Sadykh-zade on the behavior of various dichloralkanes and
dichloralkenes; by V.A. Ponomarenko, V.G. Cherkayev, G.V.
Odabashyan, N.A. Zadorozhnyy and A.D. Petrov on the catalytic
adding of hydrosilanes to unsaturated compounds; by Ye.P.
Mikheyev, G.N. Mallnova et al. on the catalytic interaction
of alky1dichlorsilanes with benzene and its derivatives; by
V.F. Mironov, V.A. Ponomarerko, G.Ya. Vzenkova, I.Ye. Dol--iy
Card 12/5 and A.D. Petrov on the synthesis of germanium-organiG com-

SOV80-59-1-44/44
All-Union Conference or~ 11he Chemistry anu Prn.ctici:J Applic~-iticn of
OrGanic Compounds
pounds; by S.I. Sadykh-zade and A.D. Petrov on the synthesis
of silicon-organic vinyl ethers; by A k1f. 71esmeyvnov, P.7
Freydlina, A.A. Karapetyan and Ye.T-,. Chukovskaya on the
thermal t1elcmerization of silicon hydrides with ethylene;
by A.G. Kut6iietsova,, K.A. Andrianov and D.Y--. Zhinkin on the
basic reaction for obtvainina polyorganosilicoxane reuins; by
S.11. .0zhenchel'skaya, K.A.. Andrianov and Yu.K. Petrashko ori
the production of soluble polymers with increased viscoiity;
by K.A. Rzhendzinskaya and I.f.. Stavitukiy on the synth-E;is of
the chlorine-containing polysilicoxane rubber LSJKT-Kh5;_bY
N.B. Baranovskaya, A.A. Berlin, IM.Z. Zakharova and A.I. Mizi-
kin on the vulcanization of liquid and rubber-lik-e polydi-
methylsilicoxanes at room temperature; by A.I. Glukhova, K.A.
Andrianov, L.N. Kozlovskaya and K.F. Kalushenina on the ob-
taining of a rubber-like substance from the polydimethyl-
silicoxane; by A.A. Zhdanov and K.A. Andrianov on the syn-
thesis of'polymers with inorganic chains; by V.V. Korshak,
G.M. Frunze, E.V. Kukharskaya and D.I: Andreyeva on the syn-
Card 3/5 thesis of polyamides from silicon-containing dicarbonic acids;

SOV/60-59-1-114/44
All-Union Conference on the Chemistry and Practical -Application of S-41-icon-
Organic.Compounds
by L.M. Volkova, K.A. Andrianov, G.Ye. Golubkov ' L.N. Makaro-
va, and V.A..-Odinets on the introduction of polar groups into
organic radical at the ailicon atom; byl-T.Ya.'Guretskiy,
A.P. Kre3hkov and P.A. Andreyev on the~methods of combinine
silicon-organic polymers with high-molecular organic sub-7
stances; by U.P. Kharitonov and B.N. Dolgov on the-new
thermo-humidity-electro-insulation materials based on sili-
con organic-substances; by B.A. Kiselev, Z.A. ZinovIyeva,
Ya.D. Avrasin and P.V. Davydov on obtainifig..a hydrophobic
glass-textolite based on polyester binders; by M.Ya. Borodin,
Z.I. Kazakova, A.P. Koroleva and.V.A. Popov on thermo-re-
sistant and durable foamy materials based on silicon-organic
resins; by N.V. Kalugina and M.G. Voronkov on the application
of silicon-organic substances-for water-repqlsing impregna~
tion; by Ye.K. Maminov o'n their application for leather im-
pregnation; by N.A. Afoachikov, G.V. Kolobova, P.N. Mikhay1nv,
and M.G. Voronkov on their application for glueing, paper;
by V.N. Khramova and A.P. Kreshkov on raising the cement-
frost-resisting px6perties; by S.V. Syavtsillo,'Ye.A. Bon-
darevskaya, A.P. Kreshkov, B.M. Luskina, A.P. Terentlyev,
V.T. Shemyatenkova and L.N. Shtifmazilon the analysis methods
Card 4/5 of monomer and polymer compounds; by K.K. Popkov on the

SOV/60-59-1-44/44
All-Union Conference oii the Chemistry and Practical Application of Silicon-
Organic Compounds
EspectrL~l determination method of alkylchlorsilanes; by Yu.Ya.
11 roscopy of 3ilicon-organic
MiIrhuylenko on the infrared spect
corat,)ounds and by A.V. Topchiyov, G.11. Panchenkov, N.S. 111amet-
in, A.A. Gundyrev aiidKu Chtang-li on temperature dependence
K
I
of Ihe viscoaltv dens-ity of certain ailicon-or-anic coo-
pounds. TI',,e Conference s,~,lected -a 3peClal commission for
elaboratin.- a uniform nomenclature of silicon-organic com-
pounds. The next, third, all-union eoiference on the chemistry
and practical application of silicon-organic compounds is
scheduled for 1960.
Card 5/5 uscomm-Dc-6o.881

LOW., V.B.; ASTAKHIN., V.V.
---------------
ottaining semifiniabod'mittatial'f6r the 1-58 varnisho Biul.tekbe-ekonw-
inform.Goo.naudh.-~iselainst-iib~ii&- i tel&siiifbrms no*7:22-23 162,
1 (Fo2ymrs) (Vamish and varniehing) (MIRA, 15:7)

KOLPAKOV, A:Leksandr Lavrentlyevich; PSEVI~ Vladimir Porizovich-,
IVAHOV~ S.M.J, red.; ATROSECMKO, L.Ye., tekbn. red.
[Bountiful cbemistry of orgamosilicon compounds]Shchedraia
kremniiorganika. Moskva., Izd-vo "Znaniep" 1962. 3715. (Novoe
v zhiznis, nauke, tekbnike. IV Serila: Tekbnika no.2
NIRA 2-5:32)
(S'-!Acon organic compounds)

B/079/63/0',43/001/019/023
D204/D307
;:AIJTHORS: ~osevt V. B. and Borisov, M.*F.
:TITLE: Synthesis of organosilicon compounds containing the
Si-C-N bond
-.iPERIODICAL: Zhurnal obBhchey khimii,-v. 33, no. 1, 1963, 258-260
TEXT: 2,296,6-tetramethyl-4-(4-aminobutyl)-2,6-disilAmorpholine
:'(compound I, b.p. 117'o/1 mm Hg, n 20 = 114586, d 20 = 0.9253, MR
D 4 D
i 2.68) and bia-1,4-(2,2,6,6-tetramethyl-2,6-disilamorpholine-4)bu-
.-..-jtane kcompound II, b.p. 1570C/1 mm Hg, m-p. 390C) were synthesized
~..,Jby replacing theo(-chlorine in 1,2-bis-(chloromethyl)tetramethyl-,
~rdisiloxane (A) with tetramethylenediamine (B). A was added drop-
iwise, over 40 min, to molten B; the temperature was allowed to
Irise to 14000, then fell to 12000. The mixture was heated for 5
'hours at.that temperature. The products were extracted from the
!cooled mixture with anhydrous toluene (which was then distilled off)
-Land were distilled under vacuum. The stracturesof I and II were'
lCard 1/2

F $/079,/63/033/001/019/023
!Synthesis of organosilicon ... D204/1)307,
-.1confirmed by ir spectroscopy. Diethylaminom.ethylmet4yldi-iso-pro-
i 0 20 20 1 1
'I-poxysilane (b.p. 73.5 0/5 mm Hg, n = 1,4185, d = 0,8686 MR
I P 4 0 D
'71.01) and diethilaminomethylqimethylethQxy.~)tlane (~,pj 1
~6 0/20
Imm Hg, N20= 1.42321 a 20 m OtBR779 MH 50~2)'Worp .prepqrpd by re-
D
~'acting, respect~Vej P41o; oigOVUyIjqet4y:~ pro Ipoxyatlane and
4:L qR t
with diethylamine, by,heatin-g at
OOCI for,6 4ra, in 6i.4 and 34.8% yields. There are 2 figures.
;ISUBMITTED: February 1.2 1962
Card 2/2

LOSEV, V.B.;RYSKAIDVA, M.F.
Prodiiation of meth-,-,l (phenylaminomethyl)-diethoxvsilane. -
Plast.massy no.3:24-25 164- (MIRA 17:3)

ACCESSION NR: Ai4028547 3/0191/64/000/004/0026/0027
AUTHORS:,L V V. B.; Astakhin, V. V,
TITLE: Interaction of haxwethyloyclotricilazane with bivalent
phenols
SOURCE: Plasticheskiye massy*, no* 4, 19640 26-27
TOPIC TAGS! hexamethylcyclotriallazane, reaction, rupture, oyolotri-
silazane, Si N bond polymert 31 0 0 bond,polymer, silox7phenylene
polymer, viscosity, thermomeohanioal property, vitreous polymer,
elastic state
ABSTRACT: The reaction of hexamethylorolotrisilazane with resorolno*l~
and with hydroxyq u1none was Investigated to 'determine the possim
bility*of obtaining polymers oontaining SI-N or SI-0-0 bonds* The
reaction results Ir. the rupture of the ellazane ring and formation
Iof siloxyphenylene-containing polymers and-ammonia:
x(PWAM%+ 3nHOQWH...
Card 4

ACCESSION NR: AP4028547
3t4-0CH40b-1.NK, + (38 - 3) NH,
CH,
IThe products are viscous dark colored polymers; their relative vis-
'cosity is shnwn In
fig. 1. The 'Low yield (6106551) Is explained by
!the sublimation if the phenols from the reaction mixture even though
they were used In a 3:1 molar ratio with respect to the oycloallazanot
compound, The thermomeohanioal properties of the polymers were. exa-
mined (fig. 2)e The resorcinol, polymer Is vitreous to*-400 and
highly elastic at -30 to -i250; the transition from vitreous to the
highly elastic states of *the hydroxyq~tlnone products is in the -40
to -350 range. Origo art* has: 2 figures and 1 equation.
'ASSOCIATION: None
-SUBMITTED: 00 DATE ACQ: 281pr64 E110L: 02
SUB CODE: OC NR REP SOV: 002 OTHER: 000
2/4
Card

're iv w v'
4 -C
Figure 2
1hermomechanical properties of polymers based on hexamethyloyclo-
!:trisilazane with resorainol (1) and with hydroxyquinons (2)
iCard

LOSEV, V.B.; MOLOKMOV, Yu.K.; NAZAROVA, D.V.
-- 7
Third All.-IThlon Conference on the Productiz)n and App23.cation of
Organosillcon CompoD-,ds. Plast.masffy no.9%1.,.2 264. (MIRA 17,-10)

-_ -- -;. - E _.-1- .."T *.2
n !:Fkk s, -2, !~FFt. zT/_?i
ACCESST01,1 NR: AP5004312 S/0191/65/000/002/0026/0028
AIMOR: Bogdanov, 1. F,; GrebenshchikovaG. V.; Logey V. B.: Mishchenko, M. L.;
MoIchanov, B. V.; Farberov, 1. L.
TTTLE: Study of the ther=l degradation of polychloroorganosiloxane polymers k
SOURCE: PlastichesIttye massy, nn. 12, 1965, 26-28
TOPTC TA(;S: silicorganic polymer, q~tganos'loxane, polychorositoxane, polymer ther-
mal degradation, phenylsiloxane pol;Q~_r, ~chforinaied polymer
effecf* of-chlorinatior.-of the :PhemyL zadicaL on. the the;rmal stabcli-
ty of POI dirde5LaZI loxane 1~,as studied-expertmentally'. The thermal proper-
A
ties of polydimethyl-, polydimetfiylchloro, polydimethyldichlaro- and polydimethyl-
trichiorophenylsiloxane were determined by recording "he thermal effects of pffol-_
y5is('~to 800C on Kurnakov's pyrometer, by measurinj the pyrolytic weight loss to
1000C," and by analyxing the gaseouo decotaposition products generated up to 1000C.
The non-halogenated polymer showed a small ex3thermic effect at 530C, while the
chlorine-substituted specimen exhibited stronger exothermic effects at 550-565C,
the height of the peaks increasing with the number of chlorine atom;. Chlorine
Card 1/2

L 27790-65
-A=
-JO
__J
an e rate-d
th f-
AI_4be_d2 a-6_42 ~or*met~-a~ni~t!,---*--s~~z-do~m-g-a---re~it-t-w--i-t-tCE-h6-~i-n-!EfiI hydrogen content of the methyl
,groups decreased in the chlorinated polymers, indicating a shielding effect of
chlorine with respect to the stability of the meth 'vi. Generally, the thermal sta-
bility decreased with increasing chlorine content. Ortg, art. has: 3 figures and
I tablP.
ASSOCIACION: None

-Ay
TITLE., Reaction of an organocyclosilazane th dihydroxypolyorganosiloxanes
SOURCE: Zhurnal obahchey khimii, v. 35, no. 2, 1965, 396-397
,-[TOPIC,'TAGS: il disiloxane, trisiloxane, silazane, cyclosilazane, polymer
ABSTRAM A study has been made of the reacticm of organocyclosilazares with
dihydroxypolyorganosiloxanes. Dihydroxydimethyldip~ienyidiniloxane or 4ihydroxytri-
Q+-thyltriphenyltrisiloxane was condensed wl~h lot ris ilazane E,.t ZWC
ye P r Q F Y
f ed Lh-- r -c t i-la
'S1
+ 3AH 0-6- OR
At li-4ti
VH
Card 1/2
man. waMmkkad
r4.04, iggp'-
7M
y

-L 27415-65
ACCESSION Hit., AP5005558
m1, N 0 1 - 0 1 - 0H + (3a - 3)NH$
R
(I. TI)
Is, A = GH,, R, = C4H,; (11) 8, R 10, R m CH*, R'm CJ3~,
7he cryoscopic rwlecular weight vas 5100 for I and 4981 for Il. Orig. art. has:
1 table and I formula.
ASSOCIATION: no-ne
SUBMITTED*. 29Jun64 ENCL: 00 SUB GODE: Cpr-
NO REY SOV: 000 0MR 001- ATI) PRESS: 3192

I PIIAUI.OV, Yu.Kh.; 14DISFYPI, A.F -
NADZHAFOV Yu 8 , IDSEV 2,;._
TUBYNI~As~v -8~- 11
Heats of combustion of some nitrogen-contairing organoa!k(,-xys-jilanes.
Zhur. fiz. khim. 39 no-5:1220-1223 My '6r. (141P.A IM".
I

DASHEVSKIY, Lev Naurnovich, kand. tekhn. naukj POG-REBIDSKTY,
Solomon Beniaminovich, inzh.; SqXABARA. Yek-aterina
Alekaeyevna., kand. tekhn. nauk- Prinimali achastiye-
LOSEV. V.D.---ABATYS1O)IKOVA, L.M.; ZORDIA, Z.S.;
ORLOVA.. ZUBATENKO, A.Ya.; PAVLENKO, Yu.S.p inzh.,
retsenzent; GLITSHKOV, V.M.p akademik, red.
rThe "Kiev" computer; its design and operationl Vychish-
tel1naia mashina "Kiev",- proektirovanie J. ekspluatatsiia.
Kiev, Tekhnika, 1964. 322 p. (MIRA 17:11)

IDSEVY V.D. [Losiev, V.D.I~ SE2,04OVSKIYYA.G. [Semenovalkyip A.H.]
Device for checking trigger circuits. Zbir. prats' z obchys.
mat. i tekh. 2--111-113 161. (MRA 15:2)
(Pulse circuits-Testing)

LOSEV, V.F.p inzh.; SEREDENKO) E.D.p inzh.
Automatic unit for shaking out cores from castings.
Mashinostroonie no.6:9-10 N-D 165. (MIRA 18:12)

5.2200 78237
S 011/8 0 - 8/~J
AUTHORS: Losev., V. I., Nikiforova, V. S.
TITLE: Brief Communications. Germanium in Coal
PERIODICAL: Zhurnal prikladnoy khimii, 1960, Vol 33, Nr 3, PP 730-
732 (USSR)
ABSTRACT: This is a short review of the various theories on the
mechanism of the accumulation of germanium in coal,
and of the several methods of extraction, such as
combustion, halogenation, ultrasonics, and gamma ray
exposure. The authors found that up to 30% of the
germanium contained In coal can be extracted on
bromination as water-soluble germanium tetrabromide.
From 19 to 33% of germanium contained in brown cGal
was extracted by subjecting the latter to ultrasound,
The yield was increased to 80% by combining the action
of bromination with that of the ultrasonics- There
are 14 Soviet references.
9UMITTIED: December 8, 1958
ar 171

PlUNOVSKIY, I.I., kand. tekhn. nauk; ZIHIVOTKO, B.I., kand. teklm.
nauk; RUKTESHELI, S.V., kand. tekhn. nauk; SHTOMPELI,
B.N., kand. tekhn. n~auk; BUTVIU)VSKV , F.A.p inzh.;
KORZHENEVSKAYA, R.A., inzh.; LOGVINOVICH, I.P., inzh.;
UTEVSKAYAp L.I., kand. tekhn. nauk-, RUNTSO, A.A., kand.
tekhn. nauk; NAGORSKIY, I.S.., kand. tekhn. nauk;
TERPILOVSKIY, K.F.., kand. tekhn. nauk; kand.
tekhn. nauk; YAROSEEVICH, A.A., kand. tekbn. ~~;
KATSYGIN, V.V.,, kand. tekhn.nauk., red.; BOROVNIKOVA, R., red.
(Problems of the tpehnology of mechanized agricultural produc-
tion] Voprosy tekhnologii mokhanizirovannogo sel'skokhoziai-
stvennogo proizvodstva. Minskp I,,,d-vo "Urozhpi.11 Pt.2. 1964.
336 p. (MIRA 17:7)
1. TSentrallrjyy naucbno-issledovatellskiy institut mekhani-
zatsii i alektrifikatsii sellskogo kho2yaystva nechernozennoy
zory SSSR.

KUTUSIW, F.Mi.,kandidat meditsinekikh nauk; LOSSV, V.I.
Analysis of electrocardiographic. data in cases of patent Botallo's
duct. Vop. okh. mt. i det. 2 uo.;4-56-63 Kr-Ap '57 (HERA 10:4)
1. Iz klairargicheakoy kliniki usovershenstvovauiya vrachey
(nachallnik-deyetvitellnyy chleu MW SSSR prof. P.A. Kuriyanov)
(BLIGTROCARDIOGRAM) (DUCTUS ARTKRIOGUS)

LOSEV,
Evaluating the functional state of the cerebral cortex in children
with congenital heart defects on the basis of electroencephalographic
data. Vop.okh.mat. i det. 3 no-3:66-73 J1-Ag 158 (MIRA 11:8)
10 Is.kliniki detskikh bolezney (nachallnik - proff M.S. Maslov)
Voyenno-maditainakoy ordena Lenina okademii imemi S.M. Kirova)
(CHIMML CORTEX)
(BUCTRONNORPIULOGRAM)
(HEART--ABNORMITIES AND MEFORKIT13S)

KUTUSHEV, F.Kh., kand.med.nauk; LOSEV, V.I.
------------
Cardiac disorders in patent ductus arteriosue. Pediatriia
37 no.7:9-13 Jl '59. (MIRA 12:10)
1. Iz khirurgicheskoy kliniki usavershenstvovaniyr, vrachey
(nachallnik - deyatvitel'nyy chlen AHN SSbR prof.P.A.Kupriyanov)
i klinilci detskikh bolezney (nachal'nik - deystvitel'nyy chlen
AMN SSSR prof.H.S.Maelov) VGyenno-meditsinakoy akademii imeni
S.K.Kirova.
(DUCTUS AR2UIOSUS. PATHNT, case reports,
cardiac disord. in operated & non-operated
cases (Rue))

DO-9=MV* D*Ya.9 kand. tekhn. raiuk; LOW, V,?L.p insh.
Reconstruction or the D-263-B steam gararator into a water boller
for temporary beating of buildings tinder construction, lkv,,cbo trudy
NInboatroin no,IMO-125 16" (14MA 19t2)

ACC NRt APS012444 SOURCE CODE: UR/00,91/65/000/012/0005/0007
AUTHOR., j '~XA (Engineer)
L
ORG; no n e
Electroch mi al deoxygenation of water in hot water su-pply'systems.
SOURCE: Energetik, no. 12, 1965, 5-7
TOPIC TAGS: water supply system, oxygeng electrochemistry
ABSTRACT* -The author considers-the use of iron-aluminum electrodes connected to a dc
power s I- for deoxygenating the water In hot water 'supply systems. The diagram of
up 'L
a sectlonal reactor for implementing this reagentless method of water treatment is
given in the figure.. Rectangular steel housing 1 contains cathodes In the forms of
perforated steel plates 2. Located on the.plates is textolite anode panel 3 holding
aluminum strip-anodes 4 so that each subsequent strip overlaps the preceding one. The
first strips are locked by panel insert S. The last strip has a contact lead 6 which
is insulated from the reactor housing. The anodes are covered by textolite plate 7
and pressed down by steel cover S. The reactor has a pipe branch tn the bottom for
washing. The insulation reduces oxygen content from,10 to 1 mg/Z after deoxygenation.
-The proposed chemical method Is more economical than conventional filtratiin and de-
aeration, Orig. art.-has:. 4,figures, 2tables.
Mi_621.187*137
1/2
C
ard

.~ . I,. i~ll~~4vz- I- ~ - '~$,

LAPITSKIT, Mikhail Andreyevich; ASTVATSATUROV, Gayk Gareginovich;
KOZLOV, A.M., retsenzent; LOSU, V.N., insh., retsenzent;
KOPIMIN, P.A., in2h., red.; TlkHU'OV, A.Ta., tokha.red.
[Squipment for diamcanting, assembling, and adjusting diesel
tractors] Oborudovanie dlia razborki, sborki i regulirovki
dizelInykh traktoroy. Moskva, Gos.nauohno-tekhn.izd-vo maabl-
nostroit.lit-ry, 1960. 139 p. OURA 13:7)
(Tractors--Maintenance and repair)

ARTE241YEV, Yu.N., kand, tekhn. nauk; ASTVATSATUOV, G.G., in2h.,-
BARABPIIOV) V.Ye.9 inzh.; BARYKOV, G.A., inzh.; BISEOVATYY, S.I.,
inzh.; GALAYEVA, L.M., inzh.; GALIM1111, A.S., kand. tekhn. rauk;
GALICHENKO, I.l.,-inzh.; GMICHAR, I.S.t kand. tekhn. nauk;
DEGTYAREV, I.L., kand. tekhn. nauk, DYADYUSHKO, V.P.0 inzh.;
YEWAAKOV, I.H., inzh.; ZHOTKEVIGH, T.S., inzh.; ZUSMAHOVICH, G.G.,
inzh.; KAZAKOV, V.K., inzh.; KOZLOV, A.M., inzh.; OiOLEV., N.A..,
inzh.; KRIVENKO, P.M., kand. tekhn. nauk; LAPITSKIYj M.A., inzh.;
LEBEDEV, K.S., inzh.; LIB&RMAN, A.R.., inzh.; LIVSHITS, L.G... kand.
tekhn. nauk;-LOcEV, V.N., inzh.; LUKANOV., M.A., inzh.; LIUBCMIKO,
A.M.9 inzh.; WEDOV, A-.M., kand. teldin. nauk; MATVEYEV, V.A..,
inzh.; ORMISYJY, N.N., inzh.; POLYACBENKO, AN., kand. takhn.nauk;
POFOVP V.P., kand. tekhn. nauk; PUSTOVAILV, I.I., inzh.;
PYTGHENKO, P.I., inzh.; PYATETSKIY, B.G.., inzh.; RABOCHIY, L.G.',
kand. tekhn. nauk; ROLIBIN, Ye.M., inzh.; SELIVAITOV, A.I., dok-tor
tekhn. nauk; SEMENOV, V.M., inzh.; SKOROKHOD,. I.I., inzh.; SLABODCRIKOV,
V.I., inzh.,- STORCHAK, I.M., inzh.; STRADYNOV, F.Ya,; kand. tekhn.
nauk; SUKHINA, N.V., inzh.; TIMOFEYEV, N.D., inzh.; FEDOSOV, I.M.,
kand. tekhn. nauk; FILATOV, A.G., inzh.; KHODOV, L.P., inzh.;
KHROMSKIY, P.A., indi.; TSVETKOV, V.S.,, inzh.; TSEYTLIN, B.Ye.,
inzh.; SHARAGD, A.M., inzh.; CHISTYAKOV, V.D., inzht; BUDIKO, V.A.,
red.; PESTRYAKOV, A.L. red.; GUREVICH, M.M., tekhn. red.
(Continued on next card)

ARTE241YEV, Yu.N.- (continued) Card 2.
(Manual on the repair of machinery ard tractors] Spravocbnik Po
remontu mashinno-traktornogo parka. Pod red. A.I.Selivanova.
Mosk7a, Sellkhozizdat. Vols.1-2. 1962. (KMA 15:6)
(Agricultural rachinery-Maintenance and repair)
(Tractors--Maintenance and repair)

,too 00 so*** 000-0 0 0 0 6 0 0 ajf;
of I
1 4 1 a 0 it 11 ally )ISO UNI Iffnii 11 is is A 0 0 A A? R U13 Me h1j) OPP& A, Mai id"Ve
a a -I- ~1_ C-2-j
J_ I A - I-
go 111 7-
A
fee
a
of A Preparation Vi xullur suid AMAM"aluns sulfate In the I
pr"ence ad a ftialral, L. L. guimin and V. P~ Loav.
00 C jA$M% CA*aw. (U. S~ & R.) 12. l7754M'DTMW,-"
00 li7o 19 9). ct. C. A. 30. 4W. 7WI.--Tbv reaction -00
2NI1111302 + (NHi)tSO# - Z(Nifd)tSO# + S + HaO
66 W" carried out in the presence of Se. S and a COISJYYA -04
obtained by heating VN114)03~ to WV. Sr or 8 was .00
finely ground o" p"-cd through st anee with MXX)
ir openings per 9q. cm. The required amt. of the catalyst .0
was Own shaken in a 100-M!, measuring O&A for 10 min. Ago
a witlathesoln. Se wu completely dissolved and the win. be-
came trampasent and acquired a brownish cot-or. The
catalyst contS. thlostitfate and polythionates was prelod.
by beating The neutral rcecd. min. of (NIR4)#80* for I by.
at *)0*. The yellow soles. oblained was added to the
Ir VIUM"I JIM)"
trawlion juixt. T) '00 W1111001 CStAlyJaIS At SO 0
is very slow, while in ilic presence of catailysts unslarr the
-4 above conditions It amounts to a 165e utilbration of SOV 3
0 A very satisfactory conversion witsobtalik-d in the presence xv 0
of 0AW33 S. Se In 10 rid. of the soln. by beating for 2 Jays.
53 at 100% A temp. of 1501 permitted the use of only 0.137
k8, of Sr W cu. m. of win. for one by. The cffcct of 8
at 100' was '-significiant, even with 0.1021 S. of the
catalyst per 10 ml. of the soln. Expts. with the third
catal I were entirely un3atidactory. A, A, B. b0 0
N't
RO
bo 0
Aid-ILA 02TAttIORGICAL UTERATOE CLASSIFICATIC
V 1 Now" .4p '1- Oat
4V a0- It a a AM L I "V_-Go 0 4 1 Or IN 6 4 a TF
0 n oaf- *at an 'I* ttalf ICKKWR 11114 #14,
11 # 0 0 0 0 0, 0 # 0000 & 0 *
00 1: : : : : : : : : : : : : : 0 0 0 : :1: : : 0000000 of 0 g 0 0 * * 0,

LOSEV, V-.Po,-Aspirant --
"The Agg3. of Mineral Pigments
-egative Stability Of Organosuspensions
ow drder
in a Hulticomponent Dispersion Medium." Cand Chem Sci, Mose
of Lenin Chemicotecbnological Inst jineni D.I- Ylendeleyev, 10 Nov 54.
(VN, 29 Oct 54)
Survey of Scientific ajid Technical Dissertation Defended at USSR
Higher Educational Institutions (10)
SO: Sum. No. 4811 5 1W 55

IA
-4n Ilse v Vicce-li lf
cnten (lie 11: zi
-own
; gg~
VIVO *--g
HIM

'U26"k-65 EWT(m)/EPF(0)/DrU(v)/J:UP(J)/T Pc--J4/Fe-5/Pr-4 DI/9'
!ACCESSION M-705-61469,1i UR/Olgi/65/000/oO610048/0050
678.6751126.026-3.06t621.622.5:
AUTHORt Be]A7. V. A.; Vlasova, K. 9.1 M11222yaj 9. 1., Hutto, R. A. Kestel'san,
V. .1 Losev, V. P.1 Dervoyed, N. A.1 Samokhvalov, V. V.
TITLE: Kaprolona /a new material for antirriction coloings
ISOURCEI Plasticheakiye massy, no. 6, 1965, he-5o
ITOPIC TAGSi antifriction coating, friction, caprolactam, polycaprolactent coatinal
Kaprolon
ABSTRACT. ing "Kaprolon" tifrietion coat
- The'feasibility has been shown of apply
Un s and the effect of the coating method and substrate temperature on coating
I" 2Less has been studied as well as the microhardness, wear res-_:tance, and ;d-/
thic
hesion of the coatings. Kaprolon is a new polysmide prepared by anionic polymer.;-
r
izatiorl of c-caprolactam at 140-200C In U.-~ presence of alkaline ini*,iators and
;various activators. Kaprolon,_wbose mechanical properties are said to exceed those--.
iof ordinary polycaprolactam by a factor of 1-.5s is usually used for manufacturing.
imachine parts by machining. It was found thst~the most uniform coating could be
applied by a "vibration-fluidized bed" method. The.bigh hardness and good aftesion
card

f

L
53*45
-
ACCESSION HR: Ap5oi4694

(maximum- at - 230-250C) of such coatings from Kaprolon make it a suitable material
i for preventing veer of friction parts. Test-stand experiments using distilled wa-
ter as a lubricant showed that Kaprolon coatings exhibit greater wear resistance
i
than ordinary polycaprolactam coatings applied under the came conditions. Similar
iresults were obtained in oervicit tests. Service teste,exceeding 18 montha'in du-
1ration donfirmed the-reliijbility of the coatings. Orig. art. ban: 5 figures. [SM)
ASSOCIATIONs none
SUBMITTISI). 00 EHM, 00 SUB COM HT F
110 REP BOYS 007 -OTMt 001 ATD PRE961 4011

Cwd 2/2

AMAN, V.141.;
N.I., RUTTO. R.A., JIES"IEI
-LASOVA,
BELYY, V~Aq V
V.1,.. -TIED, lat"OF-INALOV, A-V-
St
N G w"tifriction coatlngv. Plast.Irtlzs
r~z~~ 160 (MIRA 18:
no.

MEM, Lyudvig; SHKOP, Ya.F., inzh. (translator]; 12~.,JLJ%,nauchnyy
red.; VASILIYBV, L.V., nauchW red.; RDWIM. B.V., red.;
RAKOVI S.I., tokbn.red.
[Practical training of masons] Proizvodstvennoe obuchenis
kartenshchika. [Translated from Czech] Moskva, Vseu. uchebuo-
Vedagne izd-vo Trudrazervizdat. 1958. 155 P. (IfIRA 12:1)
iCzechoslovakia-Misonry-Study and teaclAng)

r of** 0 0.0-0 0 $s0 Go*** a of 0
~Af
A, -1
A
td4. -Y. V. LAMT, No
1. 1. Tres ka, (MI.Ih.. Lab.1 Effibli-Mom"w). -V. and the identify between the IF veltwe I" the Center sew
I- PA le, sat the edge remains sJqP at smaller 1. Ulken
Cent. ~LLSS,Jtj 19,350-64 1945).-A Pool a( C31badic
in., In 413am., Is made the cathode. "d a fig ring prAarization 6 gradually raised. the fr4lowing movement
90 1~'Iilc I
.41 t the anode. The boLn. is 0,02 N HXZN(h + 0.02 of the cathode surface h; obscn-od. At small -P values
00 N HN'01. The potential v (referred to X =10112d clOc- the M"YeMU"t 6 moderate and directed from the center I
0* ttode) of various tho& and the total cut- towardstheedge. When -Is at the edge reaches the e.W- 0411
rent suegigth I 1-n the center of the cathode trocapillary max., a ring forms neer the edge; on furtlw
*0 p toure rapidly than near the edge. nrmseof- 00
I firut lacr"WS with I, OF It moves to"rds the cent" of the catho&
a then reaches a max. a little greater than new Me ville, lumi end OiAapprur%. As long as the ring 6 visible, HI rapidly .00
# decreases when -v further increases. At very great po- movt,% toward% it both (rm intide and outside. The
I"i""S (at -0, 1.6 V. or more) there 6 no VA. twe- ftivctuent is wratir or tioneximcut after the disappiestrance
t"tt the center and the edge, anti I lncrca~,q with ;: of the ring. The current-r. curves and the fig move. q wegs
this lHanch If is evolved, When nwuls err diffrirni in a soln, of OM N US% + O.o3 N
mplilly. Along
i~l applied voltage is again reduced, a bystesesis of polasiza- HNSOi, but whatever the u4n. the tffems are esplaitird by 200
-3 floalsobserved. ThtsurfaceiretuAltispularistdatunaller the influence of v mg tufface tension And the influence of log
achationon.p. Tim Polarographic tu&%. of tic InOAM Y
Its(.N;O,) + 1).fN)5S 11%O, is suppresseil it 12(),00() ob" ~*q
are inskitc-1 into the external circuit. This is explained
I-Y the hy,fetesis of s-larizatirit. When the external IV.
1,141411147C R is visuall, I Increases when the His it glow .
vary with the drop 11N cc, the
When R is hig, I dties not .1
AAL! CA, 6 higis whet) drop fonnation starts, I;u- rwlarization
AAAM created by the hillt c.d. pm. (sts during the whole growth 400
1.-4 It of the drop. the HK surface is not agiwed, ane. no polaro-
P"W 0o0
~_g graphic $ties. occurs. J. 1. 'dikerman
Itow Ask's
we
101-3410 vilios? 'fit ofti, 0#1 044116M, f1iiii iw 43%v Ist
U a 4, 00 1 t 4 a .0 v- 0 9 0 1
it a a A it it fta A
it It a
Zo 0 0 0 0 0 0 411 0 0

LOSZV. V. V.
n2lectrochemical Behavior of Iron In Hot Concentrated Solationn of
Allmli." Sub 25 Ort 51, Inst Ph7sicril Chemistry, Acad Set USSR.
Dissertqtions presented for science and engineering degrees In
Mogcow during 1951.
SO: Sum. No. 480, q Ma',V 55

1. LOSV, V- V-
2. TissR (600)
4. Iron and organic cations unon electrachemica11 behavior of Iron in
7. Effect of jalogen Ions -
acidic solutions- 'DOkl Ax sm No. 3 1953-
9. n-ntkl-x List of Russian Accessionsy Library of Congressy ____jRriLl-1953, uncl-
I -

DOLIN, P-I-; LOSEV, V- V..; LTJKOVTSEV, P-D-; MEDVEDOVSKIY, P-D-
I
tor. 4-' 775-776 je 153. (MM 6;5)
Letter to the Idi .. P.khim. 22 no.6: r5,-Iiistory)
(]llectrochamist

L V. V".
LATIM, Wendell Mitchell; TAUV.Y.V. translator; AUTITAXOT. 1.1-9
translator. ASTA13DV ;fosoor, redaktor; OGAEDZHMOVA, N.A.*
redaktor-, SRMVAUW, V.I., takhnicheskiy redaktor
(Tbe oxidatiou states of the elements and their potentials in
aqueous solutions, Translation from the Inglish] Okislltelfrqrs
sontolantia elementov i ikh potentsialy v vodnykh rastvorakhe Pareyod
a angliiskogo V.V.Loseva, I.I.Tret'lakova. Pod red. X.V.Asts.Oova,
Moskva, Isd-vo inostrp"nol lit'ry, 1954. 400 p. (MLRA 823)
(Electrolysis) ',0xidation) (Chamical elements)

ROOM T
L
_ call--iCftyl. %Vhw the 10(n ton.

Tb,, eL-,#wb6mI&z1 babAvivt 049&-_~n L-A 71-~
. ;;~d
I (I W12 f1101c I*C,lj, t,-, LZ4 - -
l
~
e" r
~

C

If
;~njll (reft:Ted t-
h St 80' wms APF~rox. 10
I.V Na~j
I
-
e
t
t
i t
rr 4
l A
,in I tit Fr in WY N'U 4
~
- 101 f rA
'h
11 V .

3rd

rA
'A Mh

F,1
V-
Too during th~ 2m
lave stac-_ -ad up t.
4r

10SNY, V. T.
-, ~- - ~,',
1.
Blectrochemical oxidation of iron and steel in hot concentrated alkali
solutions. Zhar.prikl.khIm.29 no.6:948-950 Je 156. (MLRA 9:9)
l.Inatittit fisicheakoy khimii Akademli natte SSSIL
(iron oxides) (Steel)

/~be enoda sclriaa fjf-A~
ol,,tained bl! Zct,12"'R, 14
T
jj,

LOSIT V T
:Pffect of surface-active substances on processes taking place on
cadmium amalgams J)okl.AN SSSR 107 no-3:43g-435 Mr 156. (MLRA 9:7)
l.Inatitut lizichaskoy khimii Akademii nauk SSSa. Piredstavlano
akedemikom A.N.Frumkinym.
(Surface-active agents) (Blectrodes, Amalgam) (Cadmium alloys)

WN6

IDW, V V - KARANOV, B.N.
I
Adsorption of surface active substances on an Iron electrode in
alkali solution. rzv.AN SSSR Oti.khim.neuk no.4:414-420 Ap 157
(MIRA 10:11)
1. Institut fizicheskoy khimii AN SSSR.
(Adsorption) (BlecOodes) (Surface active agents)

Tagged atom technique used for the study of the rates of forward and
reverse processes in heterogeneous reactions. Trudy Inst. fiz. kbim.
no.6:20-PS '57. (MIIRA 11:10)
(Blectrochamistry) (Tra are (Lbemistry))

5W SOV/20-122-1-24/44
AUTHORS: Budovq G. M., Losev, V. V.
TITLE: The Investigation of the Electrode Processes on Zinc Amaleam
According to the Method of the Radioactive Indicators
(Izucheniye elektrodnykh protsessov na amaP,-,ame tsinka
metodom radioaktivnykh indilatorov)
PERIODICAL: Doklady Akademi--* nauk SSSR, 1958, Vol 122, Nr 1, PP 90-93
(USSR)
ABSTRACT: The purpose of this paper is the measurement of the exchange
currents on zinc amalgam by application of mdioactive indica-
Uors to6ether with polarization measurements and of the de-
termination of the anodic and cathodic maximum currents. Such
a combined investi.-ation permits distinct separation of
that interval of the concentrations of the amalgam and of
the solution in which the velocity of the exchange is limited
by the stage of discharge-ionization, and not by the diffu-
sion of the radioactive particles. Yoreover, this combined
investigation permits comparison of the experimental polari-
zation curves with the theoretical curves. The authors used
Card 1/4 a previously described (Ref 2) method which was improved by

SOV/2o-122-1-24/44
The Investigation of the Electrode Processes on Zinc Pmalgam According to
the Method of the Radioactive Indicators
somemodifications. The exchange current was measured in an
atmosphere of nitrogen at 25 0 C in the concentration inter-
val 0,00008 - 0,97 M of the amalgam in solutions of
0,0001 - 0,20 1.1 ZnSO4. These samples were acidified by
H2 so4(0,005 M) with an admixture of MgSO 4 in order to main-
tain a constant ionic stress (ionnaya sila). Accorditig to
preliminary measurements, the exchange current only slight-
ly depends on the number of the revolutions of the mixer.
This result applies to a wide interval of concentrations of
ZnSO4 (0,01 - 0,20 M). The results of the measurements of
the exchange currents and of the maximum anodic and cathodic
currents are given in 2 diagrams. The maximum currents are
directly proportional to the corresponding concentrations.
The curves lg 1 0 - 1g C~and 1g i 0 - 1g C p are composed of
2 parts of different inclination. i 0 denotes the exchange
current , C a and Cp - the volume concentrations of the amalgam
and of ",he solution. In the region of low concentrations, the
Card 2/4 coefficients of the inclination are similar to 1, and the

SOV-/20-122-1-24/44
The Investigati on of the Electrode Processes on Zinc Amalgam According to
the Method of the Radioactive Indicators
corresponding parts are parallel to the straight lines for
the maximum currents. In this region of concentrations, the
velocity of the transition of the radioactive particles in-
to the solution is not limited by the stage discharge-ioniza-
tion, but by 'he diffusion of these particles. At higher
concentration;, the exchange current increases more slowly
if the concentration increases. The results of this paper
agree sufficiently well with those ofobher authors. Also
the polarization curves were found; the experimental points
agree well with the theoretical curves. The authors thank
Academician A. IT. Frumkin for useful advice. There are 4
figures and 15 references, 7 of which are Soviet.
ASSOCIATION: Institut elektrokhimii Akademii nauk SSSR (Institute of
Electrochomistry7AS USSR)
Fiziko-khimichenkiy institut im. L. Ya. Karpova
(Physico -Chemical Institute imeni L. Ya. Karpov)
Card 3/4

FRMIX, A.K., akademik, otv.red.; YESIN, O.A., prof., red.; ZHDAVOV. S.I.,
red.; KABANOV. B.N., prof., red.; KOLOTYRKIN, Ya.M., dokt.kh1m.
nauk, red.;,L f V V red.; IUKOVTSEV. P.D., prof., red.;
SOLOVOY]WA, Z.A.9 red.; STMOM, MOP Prof., red.; FLORIANOVICH,
G.M., red.; YEGOROV, N.G., red.izd-va; PRUSAKOVA, T.A,, tekhn.red.
EProceedinge of the 4th Conference on Electrochemistry, October
1-6, 1956) Trudy 4-go soveshchaniia po eleitrokhimii, 1-6 oktiabria
1956 g. Moskva, Izd-vo Akad.nauk SSSR, 1959. 867 P. (MIRA 12:5)
1. Soveshchaniye po elektrokhimii, 4th, Moscow, 1956.
(Electrochemistry)

Pf
0 ~s
.'i OD
4-1
'lop
-rl
4-1
'04
m
43 0
In
co
eg.
0
u
to

k

coo
:
c 3c

j NE

AUTHORS:
TITLE:
68167
SOV/20-129-6-34/69
Budov, G. M., V.
Investigation of the Electrode Processesion Indium Amalgam
by the Method of Radid-a-ctive Indicators
Vol 1~99 IT -1324
PERIODICAL: Doklady Akademii nauk SSSR, 10/59, 'ir 6. pp 1321
(USSR)
ABSTRACT: The method mentioned in the title has already been employed
by the authors when investigating the anode process of zinc
amalgam (Refs 1, 2). In order to avoid the addition of a 3ur-
face-active substance, which is necessary for the purpose of
preventing concentration polarization, the authoischose indium
amalgam for their investigation, because only a low exchange
current occurs in the discharge of the indium ion. 1n'14 was
used for radiochemical measurements. The authors investigated
the dependence of the rate i of the real anodic process on the
0
potential at 20.0 + 0 .01 ataan In-amalgam concentration of
0.002-0.9 M in solutions of 0.0004 - 0.03 Y, In(CIO 4)3 + 0.01 11
HC104 and additions of NaClO 4 for the nurpose of keeping ion
Card 1/3 strength constant. As shown by figure 1, a linear dependence of

6 8 163'
SOV/20-129-6-34/0'9
Investigation of the Electrode Processes on Indium Amalgam by the Method
of Radioactive Indicators
Ig ia an the potential was found to exist, where the straight
line for the strength of the exchange current at equilibrium
potential and different concentration of the In ions agrees
with the rate of the anode process recorded at the same veloci-
ties. Figure 2 shows the dependence of i on the potential in
the case of different amalgam concentratflons, The cu:-ves of the
anode process shift with increasing amalgam concenti,tion in a
negative direction, in which case, hovever, their inclination
coefficient remains constant and corresponds to a transfer-
coefficient P = 2.20+0.07, Por the purpose of determinin,- the
latter, the measured dependence of the exchange current on the
equilibrium potential at a varied amalgam concentration and
constant concentration of In in the solution (Pig 3) was used,,
The value of a was determined with 0~9140.02. On the basis of
the linear dependence between the logarithm of the excbange
current and the potential of amalgain at a constant !,oncentration
of In(Clo4)V and as the sum a+p nearly equals 3, il.e. is
near the total number of electrons taking part in the electrode
process, the authors conclude that among the conditione select-
Card 2/3 ed, the rate of the electrode process is determined by a stage.

6 8'16 7
SOV/20-129-6-3-4/69
Investigation of the Electrode Processes on Indium Amalgam by the
of Radioactive Indicators
of the ionization and discharge of the In.-ion, A simultaneous
splitting-off of several electrons is improbable, 'In the dis-
solution of In on the anode, IV-he three aingle-electrar, sta6es
are therefore assumed: In -* In'+' + e, In+ - in2+ + c-;
In 2+ -* In3+ + e. It is proven that stag? In 2+ -), In 3+ f- e is to
be considered as limiting the rate of the process,because this
case agrees with the experimentally found results. It is further
mentioned that also in the process developing on the electrodes
of the bivalent metalsq the coefficients 0 and a have hil-hly
divergent values. The authors thank Academician A,, N. FrTtmkili
for his valuable advice. There are 3 fir-ures anu ~) reierencesq
8 of which are Soviet.
ASSOCIATION: Inatitut elektrokhimii Akademii nauk SSSR (Institute of-Electra-
chemistry.Rf t .he Academy of Sciences, USSR). Nauchno-iseledova-
tellakiy fizi~7o-k-hi6i-ch--e-s-k-i:y-i-rIT4Uut im. L,, Ya. Karpova
(Scientific Research Institute for Physical Chemistry imeni
PRESENTED: May 12, 1959, by A. 11. Frumkin, Academician
SUBMITTED: April 28, 1959
Card 373

6 0
AUTHORS: Losev,, V. V., lyfolodovq A. 1.
TITME- The I fluence ~rercioed by the Anions on the Anodic Dicsolution
of Indium Amalgam
PERIODICAL: Doklady Akademii nauk SSSR, "960, Vol 1309 Nr I j PP I! 1- 114 (USSR)
ABSTRACT; After having given a survey of publications dealing with anodic
processes the authors establish that the accelerating anion
effect on the anodic dissolution of metals has not yet been
explained* Since the ordinary polarization measurements are
-endered,difficult in the oase of considerable distance from the
equilibrium potential due to concentration polarization, since,
however, they cannot be carried o-.t near the equilibrium
potential due to the occurrenoe of an larvwse prooem '. ',e authors
combined the polarization measurementb with radiochemical
measurements. Thus one of the two electrode prooessesican be
et,ldied with an equilibrium potential and also with a strong
invexse process (Refs 7-10). The influence exeraiU3d by the
sodium halide- and sodium sulfate concentration on the velocity
i of the trne anoaic p:zocess of dissolution of 0.1 M indium
a
Card 113 amalgam in 0.01 M In(C!,,0 4)3 + 0.01 -M K01O3waa invostigated

67955
The Influence Exercised by the Anions on the S07120-130-1-31169
Anodic Dissolution of Indium Amalgam
at 200 and with constant ionic strength (3 M) which was
maintained by the.addition of HaClO V Figure I shows the radio-
chemically determined dependence of i & on the potential. The
ionization of In occurs also with strong cathodic polarization.
Figures 2 and 3 show the dependence of i a on the potential
,for concentrations of HA',804on 0.05- 0-9 MP N&Cl on 0-05
2-7 M. N&Br.on 1.10-3 --2,7,M and N&J on 1.10-3 _ I M. A Uaear
dependence exists betweIon and i a. With inereasipg conceutration
2-
C OfZo and.Cl the curves of i shift into negative direction.
4 r4
x
The experimental data correspond to the equation i. M k0 where
X is equal to I for low concentrations, with increwsing
concentrations it also increases. It follows therefrom that the
ion 50 2- and Cl- take an active part in the anodic process. For
Card 2/3 4

67955
The Influence Exercised by the Anions on the BOV/20-130-1-31/69
Anodic Dissolution of'In.dium Amalgam, .
N&Br and'NaJ (Fig 3) also an increase in the exchange current
with increasing concentration of Br- and J- ions was observed.
The experimental data are interpreted by the occurrence of
different types of ions in the different concenbration ranges.
i k [In] [ J-] exy F#.T') ho lds for iodine where 2.32.
The authors refuse the explanation of the accelerating effect of
the J and Br- ions due* to the change of the structure of the
electric double layer. It seems to them more probable that the
halogen i6ne (except F-) and sulfate ions take an ~%ctive part in
the anodic ionization of In. In conclusion it is mentioned that
the authors thank Ya.M. Kolotyrkin for advice. There are
4 figures and 21 references, 10 of which are Sor--Eet,
ASSOCIATION: Nauchno-issledovatel2skiy fiziko-khimioheskii institut im.
L.. 'Is. Karpova (scientific Research Institute of Physical
Chemistry imeni L. Y&. Karpo )
MSENTED: June 169 1959 by V.A. Kargin, Academician
SUBMITTEDs June 12, 1959
Card 313

87411
Ll 600
B/020/61/135/006/027/037
B004/Bo56
AUTHORS. Losev, V. V. and Molodov, A. I.
TITLEs The Mechanism of Anodic Dissolution of Indium Amalgam in Acid
Solutions
PERIODICALs Doklady Akademii nauk SSSR, 196o, voi. 135, No. 6,
pp. 1432 - 1435
TEXT: It was the purpose of the present work to investigate the action of
PH upon the anodic ionization of metals. The experiments were carried out
with indium amalgam. Polarization was measur'ed, and furthermore, the
dependence of the anodic and cathodic processes on the acidity of the
5olution varying from 9.5-10-4 M to 3~3 M HC10 4 was radiochemically deter-
mined. For the anodic process (rate i a), the linear dependence of log i a
on the potentiul (p was found. The inclination of the straight line
corresponds to the experimental transfer coefficients P . 2.2. With in-
creasing acid concentration (from 9,5-10- 4 to 0,5 M) the exchange current
Card 1/3

87411
The Mechanism of Anodic Dissolution of S/020/60/135/006/027/037
Indium Amalgam in Acid Solutions B004/BO56
10 drops from 1-10-3 to 2-10-5 a/cm 2, Within the range of concentration C
of HC10 4 from 5-10- 3 to 0.2 M, linear dependence of log i a on log C was
found. For the anodic process, the equation i a ' k[in][ii']-1exp(Pq)F/RT)
(1) holds, where A u 2.2. The complex character of the cathodic process
is caused by the hydrolysis of indium ions. Besides the ions In(H 0)3+,
2+ 2 6
the ions In H 20 5 OH appear. The rate of the cathode process is given by
i . k"[In(H 0) OH2+jexp(-aTF/RT) - k"K [In(H )3+][H 0+]_1-ex~,(-a?F/RT)-
k 2 h 20 6 3
5
Kh is the coefficient of hydrolysis. This equation represents the experi-
mental data~ The easier discharge of the hydrolyzed ions is explained by
the action of the OH-groups which facilitates the electron transition.
The production and discharge of multiply charged metal cations takes a
step-wise course. B. N. Kabanov and DI I~ Leykis are mentioned. There are
3 figures and 13 references, 5 Soviet, 4 US~ 1 Czechoslovakian, 1 Danish,
5 German, and I Japanese,
Card 2/3

137411
The Mechanism of Anodic Dissolution of Indium St/020/60/135/006/027/037
Amalgam in Acid Solutions B004/BO56
ASSOCIATIONs Fiziko-khimicheskiy institut im. L. Ya. Karpova (Physico-
chemical Institute imeni L. Ya. Karpov)
PRESENTED: July 8, 1960, by A. N. Frumkin, Academician
SUBMITTEDs - July 7, 1960
Card 3/3

j3UDOV, G.M. V-J!
Eleo"trochemica2 dissolition and formation of amalgams on a atationarY
electrode. Zhuroprikl,khim. 34 no,10:2289-2295 0 161,
(KMA 14:21)
L.Institut elektrokhimii AN SSSR i F,iziko-khimicheskiy institut
ineni L.Ya.Karpova.
(Amalgams) (Blectroobomistry)

WSE;V; V.V.1 MOLODOVp A,I. (Moscow)
_ -------
Radioactive-tracer tecImique for measuring exchangerate between
mercury and mercurous salts. Zhur.fiz.IdUm. 35 no.11:2487-2493
N 161. (MIRA 14:12)
1. Fiziko-khimicheskiy institut imeni L.Ya. Karpova.
Dlercury-Isotopes)
trcury salts)

LOSEV V.V.
j , DEMBFD'!SI(IY, M.A., MOTLODOV, A.I. AND GORDDETSKIY, V.V.
"Padiochemische methode zur untercuchung der kinetik von
elektrodenprozessen an gie'uallelektroden.11
Report submitted to the Intl. Committee for Electrochemical thermodynamics
and kinetics, Rome, JX%j Italy 2h-29 Sep 1962

_..T~EV,---V.--V.; BUDOV, G. M.
Study of electrode processes on amalgams by means of rad.-*ochem-ical
and electrochemical measurements. Part 1. Zhur. fiz. khim. 37
no. 3,078-585 Mr 163. (MIRA 17:5)
1. Institut elektrokhimii AN SSSR i Fiziko-khimicheakiy institut
imeni Karpova AN SSSR.

LOSEV, V.V.; Gljfr-,D,,-t.T,)K!'Y, V.V.
Effect of fthe acidity of so-'.~ticn on th-- electrode processes
on a bismuth arzll-am elecl'rGds. Zhur. fiz. khiin. 37 no.4-.
U2-849 Ap 163. (MIRA 17:7)
1. Flziko-khimicheskiy Institut imeni LaYao Karpova,

BUDCYV, G.M.; IDSEV, V.V.
Electrode processes on amalgams studied by means of radio-
chemical and electrochemical measurements. Part 2. Zhur.
fiz. khim. 37 no.5:1023-1028 My 163. (MIRA 17:1)
1, Institut elektrokhimii AN SSSR i Fiziko-khimicheakiy institut
imeni L.Ya. Karpova.

BUDOV,, G.14.; LOSEVII-Y.Y.
Electrode processes on amalgams studi-d by means of radiochemical
and electrochemical measurements, ZkAtro fizo khim, 37 no.6:1230-
1235 Je' '63. OMA 16:7)
1. Institut elaktrokhimii AN SSSR i Fiziko-khimicheskiy institut
imeni L. Ya,, Karpibva.
(Electrodes) (Amalgams)

BUDOV, G.M.; LOSEV9 V.V.
Radiochemical and electrochemical studies of electrode processes on
amalgams. Part 4. Zhur.fiz.khim. 37 no.7.-1461-1466 JI 165.
(MM 17:2)
1. Institut, elektrokhimli AN SSSR i Fiziko-khimicheskiy Institut imeni L.
Ya.Karpova, Moskva.

LOSEV 3_1. kv MOLODOV, A.I. (Moskva)
.11~,_(MOskva); DENBROVSKIY, M.A. (Mos a);
Apparatus for measuring the exchange current and true rate of the
anodic process on amalgam electrodes with the aid of radioisotopic
tracers. ~hur.iiz.khim. 37 -no.8:1904-1907 Ag 163. (MIRA 16:9)
1. Fiziko-thimicheskiy institut im. L.Ya.Karpova.
(Electrodes) (Radioactive tracers) (Amalgams)

8/62 o/63/1'40/00'5/022/02 9
BI 901DI 02
Mo 16,
AUT!'0113: 4aggy V V.- Jov, A. I
TTTSEV. The effeat If fluorine ions on the anodia dissolution of.
indium, amalgam and some laws governing the electrode
-proceasen involving complexes
k "'SSR. Doklody, v. 148, - 5, 19630
PERTODICAL: X naii no
1114-1117
1, 1960) the authors
TEXT: Au in T)revious investigations (DAN 130, 11
studied LVe vay~fluorine ions affecL the anodic prooerisea by examining
Oin poInrizatio n ourvea Lojether with radioohemical measurements in 0.1 M
I nd.itim amalgam in a solution of 0.01 M In(Clo 4)3 + NaClO 4 + HC10 4 with:
'Additions of Nup (0.01-0.2 m) at conatant ion strength and pli 1.3. The
2
're current den
exchan6 sitj i (a/cm ) was measured as a function of the
0
potential at various Na7concentrations was found to drop exponentially
wiIhAncreaoing.i. almost independently ofthe NaF concentration.. The-
0
'Card 1/4

S/020/63/148/605/022~029'
The effect of f luorine ions. on the ... D190/BI02
'polarization curves however differed
~onstderably for different NaP
-p)+.complexca predominant in th
concentrations. 'Shen not only the hl n
p
solution take. part in the electrode processes, but also other o
omplexes
ri~ with the former, the processes
in equilib. m
A. M -4 WO + M"+ + pX- MX
r). 'm+qx---mx(n-q)++ne; MX'(FII-q)I'+(P-q)x-~*_MX
P
13. M+pX--MX(n-P)*+nc.
will also oo.cur a-t the same time. A refero-to the contribution of the
simple hydrated metal ions, C" -.;o that of the non-predominanV, and B to
-that of the,predominant complexes. The rates of the anodic and cathodic
p
-.processes are then given by
-)qeP&P1nr + k's IM) ix-f?"FIRT
A + 4 IM) Ix
+ VF/Rr x (n-q)+ le-aggFIR T
IM X "17P)+ I C"PIR r (2)
P
Assuming t'hat all a can be replaced by a and. all Pi by and tbat,
Card 2j'
.4