SCIENTIFIC ABSTRACT LEZHAVA, T. I. - LEZHNEV, N. N.

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SCIENTIFIC ABSTRACT
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55138-65 ACCESSION NR; AP5012347 gallium potential. when the metal is broken In a gallato soltition at 50C. When the surface is renewed the electmde potential becomes more negative and then it r--tur-ns gradually to the initial value. The most negative value of the potential corre- k sponds to a clean, active, electrode surface and the gradual positive shift of the is a result of oxidation of the gallium surface. It was irJund thar the s-3tion3r-y potential of liquid gallium coinci(Aes with the equilibrium pu'entla- ~~-e --~r~,fential shift for a solid gallium elerlj."(Je is smallest when ~he -)xide flilm an its surface is rapidly dissolved. This takes place when the concentraton of alkali and temperature are high. The activation energy for reduction of gallium ions is Q kcal/mol. This activation energy was calculated taking equilibrium pctential into account and does not change with a change in polarization. Orig. art. ha-s. 4 figures and 2 tables. ;~ASSOCTATION* Tnstitut Fizicheskoy khimii M-ddemii natly, GSSR (Institut2 of Physical: -Chemistry, Academy of Soiences;SGSR) SUBMITITD- 24Jul64 ENCL: 01 SUB CODE: UM, IC R, REF Sol/, 001 Card 21/13 OTHER: 001 I-12HAVA, T.I.;VAGRAMYAN, A.T. Passivation of the surface of liquid and solid gallium in the process of electrodeposition. Elektrokhimlia 1 no.3:321-325 Mr 165. (MIRA 18:12) 1. Institut fizicheskoy khimil. AN SSSR. 1EZHAVA, V, Contemporary geomorphogical processes of the upper Iora Basin (up to the village Udzharma) (in Georgian with summary in Russian]. Trudy Tbil. GU noo62:211-222 157. (MIRA 11:7) 1,Tbilionki7 gosudaretvennyy univeraitet imeni Stalina, kafedra geomorfologii. (Iora Valley-Geology, Structural) LICHAVAO V.M. Mudflov (Gyartsioni) along the right bank of the Alazani River from the Headvaters to the Vantis-Khevi River. Trudy Geog. ob-va Grus. SSR no-3:101-114 '58. (MIRA 12:9) (Alazani Valley--Landslides) ASTAXHOV, N.Ye.; LEZRAVA, V.M. River robbery In the lower reaches of the Tezami River (Georgian S.S.R.) Trudy Geog.ob-va Gruz.SSR 4:93-99 '59. (MIR& 13:1) (Tesaxi River-Gooloff, Structural) 1__jq!ZHk1LA I- V. M. Had flows in the basin of the Iiapiani-ILhavy River; the left- banktributary of the Iori River. Trudy Geog.ob-va, Grus.SSR 4:101-108 159'. (MIRA 13:1) (Ijaplant-Khavi itiver-Alluvium) 0 0 a 0 0,10 a 07-0-0:# I, it At a a J/ .1 2l J, A, _k J Z AA Of M It I _ 00 00 00 1 Tbs Wad a# (WfUl"rit *Aa newly cultivated Image, ' ' ._00 7 brif". llormy obul %`. s &m$ 4bAXA- wr Y. i-00 _ , , 1 "lie alle I &J 09 /hit? 1w. Niv M. (Ist tile lmi. of W.. statt firld T%pt -00 it "Vt. liti.l. (flat 111V "Vosin vatimil. all wtsi. r1olirt limis "I"Or-4-111-11lix -CPO vwlvtw~ 1-Y filr$$ V%chwilLe aild fit *0 alill if 400 '111allet 04111. 641 tile wbortfillit coillplet, by lmwv, Thrv , ) l 1 " 0 ate almas ChalAcirrital try 0 .11101irs 1114.1lifily il 4*0 IIIJIMIlry C14110111 of �WtiVt K, 11114611 111041ifilY ill 111C 019. f i 00~ ng o m;!rtawr still sitall desm, of nittitim,stim. Lisn ki of h i e e y iicv!ly s,clainied soils Im a laffle cffcvt AM t ~.j roe *0 Knott AM gram both oft the fertili" ar"I The unfillififell '! 00 4r 11 will K fellilim. 0414T.1 to newly tuttlys(ril WAI. OW Ykid' Of 0%t% IIAX SAM Potato- in 1114M taw,. W. R. lirim !100 00* No* -14 P ro It W of a niqu man 1 Alit, JM All 1. 1 a Ila it -it- 3,- 0 0 0 AD 0 * 00 _ 00 _ _ .,I to, sludge 96 I.,,,dv la,f i,,.(h14KYdr -'000. with 141- ,-ili And V.,Y 3 fcftllltcr V.1 WOM*' Jj,)jJ %hullce WILS t "I ctvo- IiA~ sc~l the y1c - ~, MIf- ft"n fm wg- beet to I he P-111t dio,111141-d a' CO"' of tile fert itiltv %* M. U.Cr. rhe Iffect'vellc4s "line fell, .hell U.-I w CA Killectiveavem ~11 using trace elements on vineyards. A. 1). Mroagariobvill and SO- mhem. Nirliuralloo. Arml, -VOrildin-kil SAX). A I "Od4o i 1,140griwipaiv S.S.S.R. 10, No, 11. W-110 f 10m.-MmIts of expla, u%-et:l yvar-4 with 1-2 ka./hoc. tare If mind 34 kii.11lectaft lie mulded to lef Wirer Showed a high efficacy fur tim mlemletrients (1) " mosparvil with -F-K ItrUtised and untcrUlized controls in increasing the harvems psirtkulmly wbgn grown on carlmnate-coaq. soil. I tLroduced no change in the fruit. If. Oatfield KIIIAGARISHVILIq LEZILAVA, V.V. filter-press waste as fertilizer in beat aultureso Boobohchoulya Akad, Is* Gruzin-. looto 17-22 150. (CA-47 nP.'i1:1162q'I53) --U 1. LLIZHAvA, v. V. 2. USM (600) /+. Viticulture 7. Effectiveness of mineral fertilizers for the grape vine. Soob. AN Gruz. SSR 11-No. 6, 1950. 9. Month List of Russian Accessions, Library of Congress, APril 1953, Uncl. Country USSR Category: Cultivated Flai.,ts. Grains, Abs Jour: RZhBIol., No 22, 1958, No 100219 Author ;Lezhava, V.V~ Inat :JoiT-ZUre-n-ce Insts, AS Georgian SSR Title :Materials-on the Study.of the Effect of Granular Superphosphate on the Yield of Winter Wheat. Orig-Pubt Tr. In-ta poehVoVedt AN Gruz8SR, 1957, 8, 161- 169. Abstract: fn 1952-1954t on the carbonate aliuvial-meadow soils o.f Kartalinskaya-plain and on weakly pod- zolle soils of.Imeratlya, experiments were c_onducte&on..:the.study of the effectiveness of applying under winter wheat the granular P. In comparison with the powdered, and also with Card 1/2 Card 2/2 LEZREBRUKH, G. 0. Lezhebrukh. G. 0.- "The fundamentals of the 16~ ~alogical system of a-rding, Is in the sy4ponium: Naudh.-isoled. trud7 (Nau&.-iggled. In-t sherst. prom-sti), Moscow- Leningrad, 1949, P. 5-29, - Bibliog; 5 items SO: U-h934, 29 Oct 53, (Letopla 'Zhllrn! I I nykh Stittey, No. IC"', 19!;9).' Lzmamm, G~Qop kandidat-tekhnicheskikh sauki WIPONEM, T.T., inshener. "'Ifficient techuslogy is processixg staple fiber is fise-comb spinning of wool. Tekst*PTOM016 no0'4:27-31 Ap 156. (MM 9:7) (loolem-and worsted spinning) LL?ZHKBRUKH, G,O., kand.takhn.nauk -W.-Wpwmw~ Carding conditions and formation of the re4,irn layer on the mountings of the cardlng dr=. flauch.-tssl,trudy VORIShersti no.18glO-26 163. (MIRA 1881) LPhZEIKBRMM, G.O..,Imnd.tqkhn.nauk; CHUYKOVA, V.I..,iuzh. ,Automatic control of silver weight on roving machines.. Tekst. ,prom. .1.9 no.2:25-31 7 '59. - (MMA 12:5) (Spinning machinery) (Automatic control) VIZUBRI , G.O., kand.tekhn.nAuk Affect of some parameters of the carding process on its results. Tekst.prom. 20 no.8:27-29 Ag 160. (MIRA 13:9) (Carding) LEZHEBRUK-H.,-,G..O.., kand.tekhn.nauk Detecting defective spindles and reducing yarn breakage in woolen I manufacture. Tekst.prom. 22 no.1:35-40 Ja 162. (14IRA 15:2) 1. Rukovoditel' pryadillnoy laboratorii TSentral'nogo nauchno- issledovatel'skogo instituta shersti. (Woolen and worsted spinning) 11j. -L -27765-66----EWr (I) ----IJP(,d)-: :-WWjGG-- L-ACC NR, AP6007630 SOURCE CODE: UR/0141/66/oog/001/0057/0060 'AUTHOR: Gracheva, M. Ye.- L6 .zhen, A. S. ORG;~ Institute of C~e:,Physics'of Aimnsphere, AN SSSR (Institut fiziki atmosfery AWSSSRY -TItLE.',:,'F1u6tuati:6a~ ith variable df4ntensity of:light propagating im a medium w -Aurbulenc'e characteristics SOURCE: IVUZ.: Radiofizika, v.- 9,,no. 1,1966, 57-60 TOPIC TAGS:~- light:p-ropagations atmospheric turbulence ABSTRACT-.- Light propagation is considered for a case when the source and the receiver are placed at 1 m and 70 m above the Earth's surface, respectively; the slanted path length, 600 m; zenith angle, 840; unstable stratification of the atmosphere and free convection 'conditions are considered. For uaiform turbulence conditions, the mean square of fluctuation of the logarithm of intensity of a planar monochr.omatic wave it; given by: 1,23 06L""', where k a Zyr / A L is,the wave path, and Ch is the !'structural constant' ':'4, (z.,) (zlz.)-, where z. is a fixed Card 1/2 UDC: 535.3: 551.51 A ACC NRi AP6007630 level, is equal to 213 for. dynamic turbulence or 4/3 for free convection. The veracity of the above formulas was checked by experiments staged in the summer of 1964 in a flat steppe terrain. Light flicker was measured along with mean tempera- tures and wind velocities; also, Richardson numbers were calculated from gradient measurements. A "satisfactnry" agreement between theoretical and experimental results is reported. 'In conclusion, the authors wish to thank V. 1. Tatarskiy and A.'S. Gurvich for. the direction of the project and valuable advice. Orig. art. has: 2 figures and 5 formulas. [031 SUB CODE: 08i*,ZO.~/. SUBM DATE: 31May65 ORIG REFi 005 OTH REF: 001 ATD PRESS: 2. Z_ 2 INUMN, M.0. settjng~.up simple universal electric, meters in electrotechnical practical work. Pqlitekh.obuch. no.4:32-33 Ap '57. MRA 10:7) 1. Shkola lo. 2 g. Yenakiyevo Stnlinakoy oblastiji, (Blectric meters) GERMAN, E.D.; RAYEVSKIY, A.B.; LEZHENIN,.,,V.M. Inhibition of e=lsion polymerization. Vysokom. soed. 5 no.lOil496-3498 0 163, (KRA 1W) 1. Voronezhokiy filial nauchno-ioBledavatellskogo instituta sinteticheakogo kauchaka imeni S.V. Lebedeva. 14 ANTIPOVO L.A.,, inzh.; ]=HEpKKoVj p!Ssp inzhe; STAVTSEV9 B.N., inzh. Seleetion of parameters for working units of a motor grader. Stroi i dor. 8 no.12t4-5 D163 (MIRA 170) FFMOIRV, Ye.P., inzh; AHTIPOV, L.A., inzh; LEZHEPEKOV, BeS.9 ingh, SOKOLOV, L.V., inzh. New self-propellpd graders from the Orlov factory. Stroi. i dor. mash. 6 no.5:4-7 MY f6l. (KMA 14:6) (Graders (Earthmoving nachinery)) ANTIPOV.1 L.A.p inzh.; LEZHEPEKOV, B.S., inzh.; STOTSEV., 3.11., inzh.; FEDOROV, Ye.P., Improving the design of motor graders at the Orlov Factory. Stioi.i dor.mash. 7 no,2:7-9 F 162. (MA 15..5) (Graders (Earthmoving machinery)) 1EMUSKOV, Ivan Petrovich. LEZPEFEKOV, Ivan Petrovich. Hemr rakes the wealth of our collective farm. Moskva, Gos. izd-vo sellkhoz. lit-ry, 1954. 45 P. (Peredovoi opyt v sel'skom k~oziaistve) 05-19501) 513255 -1,45 LEZHEFEKOV, F.F. - Traffic safety, aesthetic appearance of road installations, and established standards for the design. Avt.dor. 28 no.10:19-20 0 165. (MIRA 18:11) LazHip3XOyA.~. The problem of mental diseaFes in influenzal encephalitlo, Tops pisikh i xLevr. no-3-.19-Z6 158. (KERL 12:3) 34 Iz II Leningradskoy poikhnnevrologicheakoy bolvnitsy. (39CEPHALITIS) (DRIMMA) (PSY(;HOSM;) LENFIFIEKOV, F.F., inzh. Bituminous and tar emulsions in Czechoslovakian road construction. Avt. dor. 24 no.7:28 11 161. (MIRA 14:7) (Czechoslovakia--Road materials) SOV/120-59-4-47/50 'AUTHORS:Goldobin, A. N., Lezheyko, L. V TITLE; A Device for BleG-t-r-0-1--Y-'ti-ic--SEi'arpeiling of Point Probes with Control of the Quality of the Point PERIODICAL: Pribory i tekhnika eksperimenta, 1959, Nr 4, pp 156-157 (USSR) ABSTRACT; The authors describe a variant of.the electrolytic method of sharpening point probes. A device is used which sharpens a probe by periodic immersion of the latter into an electro- lyte and removal of the probe from the electrolyte at a con- trolled rate. This rate depends on the diameter of the orig- inal rod or wire and the rate of dissolution of the probe mat- erial by the electrolyte. The device makes it possible to produce rapidly point probes with the quality of the point controlled continuously by means of a binocular magnifier or a binocular microscope MBS. Alternatively, the point may be projected on a screen and its quality judged from its magnified image. The device is shown schematically in Fig 1, and its photograph is given in Fig 2 (numbering of details In both figures is ihe same). Five support rods are fixed to an ebonite base I Four of the support rods ( 2 and 3 ) are used to mount the main part of the device and one such rod 4 carries a small lamp 13 A d.c. motor 6 with Card 1/3 01V SOV/120-59-4-47/50 A Device for Electrolytic Sharpening of Point Probes with Control of the Quality of the Point a worm reductor 7 rotates a crankshaft mechanism 12 The crankshaft and a small roller 11 convert the rotation of the motor shaft into a vertical up-and-down motion of a rod 9 which carries a clamp 23 to hold the probe. The electrolyte is placea in a beaker 22 on a moveable table 21 . The motor is supplied through a potentiometer (or a rheostat), which is used to alter the rate of rotation of the motor shaft and thus the rate of the up-and-down motion of the probe. D.c. current is supplied through terminals (15 in Fig 2) to the electrolyte and the probe; this current is also controlled by means of a potentiometer. A binocular magnifier 17 or a microscope has its own stand separate from the device itself. When wires of 0.5 mm diameter and thinner have to be sharpened into probes, the rate of up- and-down motion produced by the motor may be too small; for this purpose the device can be used without the reductor 7 and the motor 6 - the crankshaft is then rotated manually by means of a knob 20 . The following parameters can be varied in this device: (a) the electrolyte composition and density, (b) the current density through the electrolyte Card 2/3 SOV/120-59_L~-4?/50 A Device for Electrolytic Sharpening of Point Probes with Control of the Quality of the Point and the probe, (c) the rate of immersion of the probe into the electrolyte and the rate of its removal from the electro- lyte. The rates of immersion and removal determine the dura- tion of action of the electrolyte on various parts of the probe point. The device can be used to produce uniform symmetrical cone-shaped probes of any metal and to improve the quality of probes already sharpened or to reduce the probe dimensions. There are 2 figures and 3 references, 2 of which are English and 1 German. ASSOCIATION: Institut poluprovodnikov AN SSSR (Institute for Semi- conductors, Academy of Sciences)USSR) SUBMITTED: July 149 1958. Card 3/3 29704 S/!81/61/003/010/036/036 (I/ Y-5', /hT-?, 11,60, W/1) B125 B102 AUTHORS: Goldobin, A. N., Lezheyko, L. V., and Sharnopollskaya, Ye. T.' ; TITLE: Piezoelectric resistance in tellurium PERIODICAL: Fizika tverdogo tela, v. 3, no. 10, 1961, 3247 - 3249 TEXT: A study was made of the change in resistance when monoCrystalline tellurium specimens of different concentrations were subjected to uniaxial elongation between 77 and 450 0K. The specimens had been previously annealed in order to obtain an ordered structure. In this way, the temperature dependence of the piezoelectric resistance was unified to some extent. Present data refer to the constant n 33 =AQ/QZ of piezoelectric resistance (current and stiess Z are directed along the trigonal crystal axis). N f(-!) is almost linear in the region of impurity conductivity, 33 T and displaysthe characte--i, ic deep minimum when passing to the region of intrinsic conduction. This temperature dependence was measured for an impurity concentration N A - 2.1015 cm-3. The constant of the piezoelectric Card 1/4 2ty 1~ X61/003/010/036/036 Piezoelectric resistance in... B125 B102 resistance depends greatly on the impurity concentration. The highest piezoelectric resistance is observed in the region of intrinsic conduction, and may be qualitatively described by a change of lattice parameters and by the narrowing of the forbidden band. As a consequence, the number of carriers excited by thermal motion also changes. Under these premises, the following holds: d-InQ F- a - 1 n , where a 0 - (4np/N2))-1/2. (2) was -a ~(a-l A dZ ( . a+1 + hn derived under the.premise thati-p//-n remains constant under load. 2 dln Q/dZ- E/2kT holds at high temperatures (np> NA , a>>I). Under these conditions, the pressure dependence of the forbidden band width is given by (3-5 � 0.1)-10- 11 ev-cm 2/dyne for specimens of different concentrations. The change of resistance in the case of uniform pressure has the same sign ik as in the case of elongation. This is explained by the existence of crossed atomic chains in the tellurium crystal structure. In the i urity d region intellurium, where already at 77 0K impurities are ionizeZ the Card 2/4 297o4 S/181/61/003/010/036/036 Piezoelectric resistance id... B125/B1O2 carrier'ooncentration cannot be affected by a change of the band width. In addition, an elongation by which no new impurity centers are produced can change only the hole-mobility tensor. The experimentally observed dependence of n 33 on NA has not been sufficiently clarified so far. To acquire a complete knowledge of the nature of the piezoelectric resistance in the impurity region, it is necessary to study the effect of elongation on the Hall effect and on other parameters of Te in this region. The high piezoelectric resistance between - 20 and + 200 0C is a point in favor of the usability of tellurium crystals for constructing strain gages. A. R. Regell is thanked for discussions. There are 1 figure and 4 references: 1 Soviet and 3 non-Soviet. The three references to English-language publications read as follows: P. W. Bridgman. Proo. Amer. Acad. Sci.p 72, 159, 19381 J. Bardeen. Phys, Rev., 11, 1777, 1949; J. D. Long, P. Li. Amer. Bull. of the Amer. Phys. Boo., 1958; J- S. Blakemore, K. C. Heaps, Phys. Rev., 117, 667, 196o. ASSOCIATION: Inetitut poluprovodnikov AN SSSR Leningrad (Institute of Semiconductors of the AS USSR Leningrad) Card 3/4 Piezoelectl*ic resistance ill... SUBMITTED: June 28, 1961 Card 4/4 29704 sli a l/61/oo3/olo/036/036 B125 B102 27-66 L 177 ACC NR: AT6001332 SOME CODE: UR/0000/65/000/000/006410073 EWr(l)/El-ir(m)/EEC(k)-2/ETC(e)/EVIG(m) EWP(t), IJP(c) RDVI/JD/GS AUTHOR: Goldobin, A..N.-. Lezhevko, V. O.RG;. 5 TITLE: Temperature dependence of the piezoelectric affect in tellurium SOURM A11 AzerbSS R. Institut fiziki. Selen, tellur i ikh primeneniye (Selenium, tellurium and their utili_z_a_t_16n-). Baku, Izd-vo All AzerbSSR, 1965, 64-73 TOPIC TAGS. tellurium, piezoelectric modulus, temperature dependence, electric tensor analysis, metal physics, piezoelectric property APSTRACT: A theoretical and experimental analysis was made of the temperature de- p9ndence of the piezoelectric effect in tellurlum in order to clarify the structure of the valence zone. The piezoelectricresistivity tensor (quarter rank) was given with' eight inderendent parameters: 'ff I I i w1Z i "13,- R14 1w3l -, "33, W41 and 1r44. A schematic diagram of the respective orientations (voltage-strain) necessary to de- termine these eight parameters is presented and methods for measuring these were described. A variable loading arrangement was used in measuring the voltage drop. The samples were'cut!, etched about 100P and annealed at 3200C for 30 hours. The Card 1/2 L 17727-66 ACC NR; AT6001332 changes in the parameters were given as a functionof temperature ranging from -100 to 2000C. The results varied considerably depending on the parameter and on the im- purities which ranged from 5e1014 to -8.1016 cm-3. In the temperature range of 77 to 200.0K, a.weak dependence was observed for some parameters in the region of impuri- ty conductivity. Several relations are given for pn conductivity in terms of the ,effective density,of-states in the conductivity region and in the valence band and Iof.the resp ective.energies for these regions. These formul as satisfactorily explain the ' urity and temperature dependence of the effect. The larger values obtained IMP -for W33 and ull are explained in-terms of the dependence of carrier mobility on effective mass for the particular lattice directions involved. Transducer applica- of tellurium for conditions of deformation or vibration are recommended es- pecially in the low temperature region since some coefficients exhibited such a weak dependence on temperature. Orig. art. has: 6 figures, 7 formulas. _20/ OTH REF: 005 SUB CODE:. 11,. SUBM,DATE: IOMar65/ ORIG REF: 003/ A A id L---7,l=L-D0', V. F. 11 ~ -I- ~. ci, - L:, 11 'h'-' 1 ~ E-!-- 11 C r. P." - ' + "Th-3 History of "he DliocOvel- Of I Loningmd "Anto lrnAt, Leninfirad, 1,?53- jeri 54) SO: Sm 432, 'Kar 55 1 112-2-2588 Translation from: Referativnyy Zhurnal, Elektrotekhnika, 1957, Nr 2, P.1 (USSR) AUTHOR: Lezheyko., V.F. TITLE: The laws of the Electric Current Establish by V.V. Petrov (0 zakonomernostyakh elektricheskogo toka, ustanovlennykh V.V. Petrovym) PERIODICAL: Uch. zap. Leningr. gos. ped. in-t, 1955, Nr 103, pp. 305-309 ABSTRACT: Analyzing the work of the talented Russian scientist, V.V. Petrov, published in 1803 under the title "News of the Galvani-Volta Experiments", the author under- scores the services rendered by V.V. Petrov as the first Russian investigator in electricity and the founder of national electrical metallurgy.-who, in his conceptions of the electric current anticipated Oersted, Ampere and Ohm. Card 1/1 S.M.G. 'V'a V 117-58-5-14/24 AUTHORs Kurochkin, V.D., Chekmeney, V.F. and Lezhnev, A.G. TITLE: Grinding of a Cutting Instrument by Means of a Multiple Thread Grinding Wheel (Shlifovaniye rez1bovogo instrumenta mno- goritochnym shlifovaltnym krugom) PERIODICAL: Idashinostroitelig 19582 Nr 5, PP 30-32 (USSR) ABSTRACTs For the sake of economy.and efficiency, the cutting of inte- rior and exterior threads is being done at present on tape, gauges and multi-thread rollers by means of multiple-thread grinding wheels. In accordance with the new technology, thread-cutting instruments up to a pitch of 2 mm are cut with a multiple-thread grinding wheel. Grinding is done in two operations requiring 2 wheels. For the preliminary out/ a grinding wheel of a slightly softer metal is used as com- pared with that of the final grinding. Thread-cutting on taps M6xi, M8xl.25 and MlOXl-5 is done in two passes and on taps M12xl.25, M12xl.75, M142, M16xl.5 and M16x2 in three passes (2 preliminary and 1 final). Grinding wheels are provided with multiple thread by means of rollers with annular thread. The rollers are made from carbon steel Card 1/2 UBA, U10A and U12A. The rollers are subjected to a thermal 117-58-5-14/24 Grinding of a Cutting Instrument by Means of a Maltiple Thread Grinding Wheel treatment to a hardness degree of Rs= 58 - b2. The rollers themselves in the course of production get a preliminary thread cut with a multiple thread grinding wheel and are finished with a single thread grinding wheel. For cutting annular thread, a special device on the adjusting plate of the screw cutting lathe is used. It seryes to fix the required thxead pitch (see figure 2). The rolling-on of thread on a multiple thread grinding wheel requires 15-20 minutes; the speed of rotation of the grinding wheel is thereby cut down to 1.8 m/sec. Effi- ciency in tap ihread-cutting by means of multiple-thread grinding wheels hawincreased "more than twice". Figure 3 shows stets of thread-cutting instruments ground by this new method. There are 3 figures and 2 tuables. AVAILABLEs Library of Congress Card 2/2 1. Cutting tool&-Grinding processes 1 V~K.; S"TFoll A.'r. Ilf"HNERY 1 9 Recovery of cRrbon dla!t,-Ifjde during the formation of raycn cord on PN-300-1 machines. Khim. volok. no.5,-45-48 '65. WRA 18,,101, 1. Vsesoy-uznyy naucllmo-issledovatellakiy inatitut iskusstvennogo volohm (for Lezhnev), 2. GosudarsWennyy komitet khimlche~skoy promyshlennosti pri Cosplane SSSR (for Serkov). KRYLOV, B.R., inzh.t. LEZIRT-17. -*,...... inzh. Mechanized processingg of oscillo grams. From. energ. 18 no.9: 12-14 S 163. (MM 16:10) UaLOVP B.F., inzh.; ~ ~HNEVp A.F., inzh. I I Voltage regulation in low .Poor 220-380 volt lines. Prom. energ. 18 no.5:22 My 163. (MIRA 16:6) (Electric power distribution) LIZMW, A,P* , inshe Using asynchronous couplings for regulating ventilators. Nakh.* i elsko sets@ sellkhes, 17 no.2t3~-37 1599 (KIRA 12:6) lJoningradskly sel'skekhosymystvann" Institut. PYLOV, BaF*;. 1!~V-, A.P. Automatic. cbarging of materials an the sintering conveyer belt system. Biul. TSUCIR no.3:36-37 161. (MIRA 14:12) 1. Cherepovetakiy metanurgibhookiy 2avod. (Sintering-Equipment and supplies) IJOUM, A.V. . inzh. 'Use of a bitumen-latex emulsion and plastic concrete in supporting mine shafts. Shakht, atroio 7 no,,2:16-17 F 163. (KM 16:3) 1, Mikbaylovskiy uchastok-Belgorodskogo ishakhtostroyupravlaniya,tresta Shakhtspetastroyo (Mine timbering~--Equipment and suppUes) (Waterproofing) ABRAWAN, A., inzh. (Izhevsk); LEMNET, B., inzh. (Izhevsk); PESHMIONOV, N., master sports, (Izhevskr- From a road to a racing motorcycle. Za rul. 21 no.7:20 J1 163. (MIRA 16:8) (Motorcycles) LE ZEINLY ) D. A. The crew works the co-=mnist way. Razved. i okh. nedr. 30 no.6: 56 Je 164. OURA 1720) 1. Trest "Poltavaneftegazraz7edka". 'T LEZHNEV, E,I., inzh. Calculation of the traction characteriotics of electromagnets with'i-otau armatures. Vest. elektroprom. 33 no.11:73-75 N v62. (MIRA 15:11) (Electromagnets) . . LEMM, G. 'Strengthen the control of the Gommunal Bank over construction. Fin. SSSR 16 no.1:61-63 Ja '55. (MLR& 7:12) (White Rasaia--Construction industry--Finance) (White tussia--Banks and banking) .!V058/61/000/008/043/044 A058/Aiol, AUTHORS: Berdyyev, A. A., Lezh-riev, K. B. TITLE t Investigation of absorption wrives- At. high frequencies PERIODICAL: Referativnyy zhurnal, Fizika, no. 8, ~,96i, 348, abstract 8Zh587 ~,("Izv-.`AN TurkmSSR. Ser. fiz.-tekhn. khAm. i geol. n%-no. 6, 1960, 127-13P) TEXT: 'The authors describe the block diagrain and electric cire-jit of a "tdp, for measuring- absorption.- of-ultrasonic, wove&,1n liquids in the _.frequency range. -5 - z2OO:Mc. -~Oa this zetup.. one- Pan measure ths tamperature dependen(jes.of th6l absorption and'of -the velocity. The- weasuremaZITI., razigs for attenuation.was 0.2,'.- 4;O00-.db/cm~- The measurement ~ error of ultv,%zanic a~bsarptlcll and velocity doibs:,.not.-axo9ed,3%,-and 0.5%, respectively., D. L. [Abstraoter!s notes Complete translation] Card 1/1 BERDYYEVp Ultrasound absorption in benzene and thiophene at frequencies under 300 mo. I%v.AN 'Vurk.SSR.Ser.fiz.-tekh., WmA gool.nauk no.3:104-106 163. (MIRA 17:3) 1. Fiziko-tekhnicheskiy institut AN Turkmenskoy SSR. 7- S/046,/63/009/001/020/026 B104/Bie6 AUTHORS: Berdyyev, A. A., Lezhnev, N. B. T IT LB: On the problem of ultrasound absorption measurements in liquids N;RIODMILt Akusticheskiy zhurnal, v. 9, no. 1, 1963, 113 - 115' TEAT: In equipmeut commonly used for the measurement of ultrasound ab- sorption in liquids, the attenuation in a sainple is compared with gauge attenuation in an r-f attenuator. The subjecti-ie errors which wiy arise --.---from comparing both signnls on an oscillograph screen and the beat due to the superposition of the gauge pulse and the pulse from the sample are eliminated by a n 'ow method suggeuted heret the acoustic and iteasurin..", circuit units have separated start-up (Fig. 1). - The arrangenent works on 20 -/250 Mc. The synchronizing unit (1) triggers (with a frequency of 1 k0 a) the modulator (2), which produces rectangular pulses. These pulnep start up the hi-h-frequency generator (3). This generator send3 r-f pulBep quartz-e;itter to the :j1. The ultrasound pulses passing both through the liquid and through the quarti delay lines G I and S21 aIre converted by a Card 1/2 S/046/63/009/001/020/026 On the problem of ultrasound... B104/B186 quartz receiver q2 into r-f pulses. This signal isshown on the oscilloscope screen. The error of this mcthod is I There are 3 fig- ures. ASSOCIATIONt Fiziko-tekhnicheskiy institut AN Turkmenskoy SSR, g. Ashkhabad (PhyBicotechnioal Institute AS Turkmenskaya 3SH, Ashkhabad) SUBMITTLeDs March 22, -1962 3 Fig.,1. Experimental arrangement. 4 5 , W_j Card 2/2 EWTW V -4 w1i _AFj_9/ASD/4PG0 Pq FiCCESSION KA; tAVOOZOBZ ~~S/Z728/62/008/000/0 9/ 01 0048~ RS:,.., Be rdy*pv, A. A.*, ~-ILasillyeva~ M. G.; Lezhnev, N. B. AUTHO TITLE: Investigation of the absorption of ultrasonic waves in several liquids -!SOURCE: AN Turkm SSR. Fiziko-tekbniche'skiy institut. Trudy, v.8,1962, 19-48 TOPIC TAGS: ultrasonic wave absorption, ultrasonic property liquids, optical measurement, ultrasonic absorption, pulse methodp ultrasonic absorption: Measurement ABST _per~re orts the results _e4erlmental investigations of a.. RACT: pa p -of Pulse-type equiprMentl6r, 'the measurement of the absorption of ultrasonic (US) -wave's injkqidsr~vithin the frequency range from 5 to 200 mcps. The investigation 4.... genera ze 8u H s The:'Ae Its of similar *studles made over the past two years. The iab,iorpilon investigations were. performed-by optical and pulse methods. The thods Were based on th ph the diffract ~opiical-rneasurement mi e enomeron of. ion of light ing-Ahrougli-a m dium-fn.whJch.US-wave-s--Aft -pass: e ti he-sour ca propaga ng --'-'-d- -th- sentinstance,was:a-spherl al -pressu Jahd Lpment use in' e pre 6- extrahigh re ;z- lamp,~.-SVDShw-~00i__'c. able o equency-rang f tingjmLthe. fr a-frorn-5.0! gi. Via ~p c-4- ----The.- a-Cous-Ftic generator -consisted of piez'o-jRa3qzplateletu. The us -pse -V::1798Y-Z3' CCESSIOM-NRi AT30OZO82 r opagated vertically downwapd. .The liquid investigated was 'placed aye we e pr a vessel made of high-grade opjical_gjjsfAtWith plane-parallel walls. The bottomV as -vessel w lined with glass wool to avoid the superposition of running and r:eilec'*ed wavesIn conditions of loiW absorpt!on. The measurements were t ParfoFrned In monochromatic -light'. measurement of the absorption of US waves was ac~!omplished'b ment of the brightness of the Image.of the y a measure -b6'arn at various points, It' U -S was assumed that at the low acoustic amplitudes er H np the intensity of the diffracted ght would be proportional to the sqt~~Tw. of th4, amOlitude of the.US oscillations.. The brightness was measured by means of tw .,,plaotographs taken on fine-grain photographic ~plates With uniform, emulsion., All photographs -were -developed -with the same--type- o-f-d-e-Wiloper under Identical devel- opment conditions* Control measurements of the absorption r---)efficient-in toluene -not- -exceed ----*T`ptk The--overa a howe -4 that-the-~error--o _M.eagureme -aid Cent __7 eme o III e . pu I i-e 7e-j- - 1cl ont ation:block *ent Comprise - a synchr z which, on'the o--. cdntroilis'a_~oweep generat r which'at-various sweep rates affords-a ne 0 measurement-df the absorption for various lengths of the acoustic path, and, on 1the other hand, -controls a modulator which, in turns. produces rectangular pulses ~which serve for the'actuating of the high'-frequency (HF) generator. The Hr !generator emits radio puloco which are delivered to the quartz radiator. The ~ultra-acoustic Pulse. thus.-obtained-propagates -in a. delay. line and, -after Irisslng 4 --- --- - -:LQa 2/3 grEF- ........ ... .. .. .. . ........ ..... C WR*~ AT1002082 A PESSION thiou~h the Is. again trans formed. into radio pulses by means of a -ntl s a r and.. his signal subseqiLie y I m ified in a RFreceive iqu4rtz receiver. :T P1 delivered to in oscillograph. The.-absorption is determined by varying the thick- I ping Th' ness of the. test liquid.and measuring,the resulting dam of the signal. e f equipment operates.on 12 fixed frequencies in.the range from 5.5 to 200 mcps.- cuttry. And the acoustic a te ent e1 'ctronic cir e compon e yo m employed are h .''Idesc."ibed. i, The Anvestigationlof the -absorption of. US waves in nonassociating Ao~ . T 11 ~ p' x;y1ol, "Chloral) is inve stigated in detail, _ and it is- ixtures (--enzol, m-xylo - IfOund that:'. (a),, The: addition-. of a. small'quantity of weakly absorbing liquid to a sir6ngly absoibinj liquid decreases the absorption coefficient sharply; (b) an' equation is developed on the basis of simplified considerations to explain and p1redict the observed sharp,decrease In absorption coefficient in such circum- stahces;, (c) -the absorption doefficient increases linearly with the temperaturee Th~ investigation was also extended to the absorption coefficient of associating -ide), andanabsorption miktur4s-(methy1alcohol, ethylalcoholp isomamylchlor x,imum was found to exist in all the of ma mixtute'dinvastigated. The presence Ithis maximum is explained by the formation of a, new compound. Orig. art.. has,' a, and a 3-page electronic -parts list. ]1G numbe red equations, .12 figures, ~,Aable AS~qOCIATIOK: ITM.*- -00 DATE ACQi 2~Aj;z~ BUCLO.. 00 COM. Al PH -No WISM.- 002 GTIM. 000 3113 LEzmw., N. b. Now technology, and labor safety requirements. Zhel. dor. tranvr. 45 DO-1:46,49 J& 163. (MIRA 16t4) 1. A&challnik Glavnogo vmehebno-sanitarnogo upravleniya Ministerstva putey soobohobaniya. Railroads-Safety measures) ndustrial hygiene) R ~EDTMVJ- A.A.; VASILIIEVA, M.G.; IEZHIEV, N.B. Absorption of ultrasonic waves in sew liquids. Trudy fiz.-tekh. inst, AN Turk. SSR 8:-'9-48 162o (Ultrasonic waves) (MDU 15:3-1) !ACC VR: AP6016833 SOURCE CODE: UR/0046/66/012/002/0247/0250 JAUTHOR: Berdyyev, A.' A. Lezhnev N B. ORG* ZhYki=_tv_c_bWWa Institute. AN-Turkmenian SSRj Ashkhabad (Fiziko-tekhnicheakiy institut AN Turkmenskoy SSR) TITLE: Method of investigation of acoustic of 1~qq_k4a at frequencies 300 - 1000 Mcs SOURCE: Akusticheskiy thurnal,, v. 12, no, 2, 1966, 247-250 TOPIC TAGS: liquid propertyo acoustic property, acoustic equipment, cavity reno- .nator, relaxation process ABSTRACT: This is a continuatio of earlier work by the authors on the absorption 0 ds at of ultrasound in organic liquids at high frequencies (Izv. AN Turlanenskoy SSR, *ser.1 3 FTKh i GN, 1963, v- 3, 3D4-1o6 In view of the fact that the earlier high- frequency investigations were devoted either to the design of sound generators or to the use of high frequencies for investigation of solids, the authors have in- vestigated the properties of liquids at frequencies above 300 Mcs. The experiment Iwas ba-sed on the method of nonresonant excitation and reception of sound by piezo- ,electric quartz slabs and rods placed in coaxial resonators (Fig. 1). Some pre- I A liminary experiments made prior to the design of the resonator are described. The 1,.Card uDc: 534. 8 + 532.12 ACC NRt MbOlbbB Fig 1. Diagram of final measuring element design. I - Central rod of resonator, 2, 3 - outer case of reao-*~-[- "atort 4 ~ plungert 5 a "ling loop measuring equipment and the method were standard and described earlier (Akust. zh. v. 113, 1963). New data were obtained for several liquids at 20C and 3 frequencies, as listed in the table: Sao "21 %ekl so met --------------------------- water 2/1, 7 23,8' 24 2 77 8 78 5 8t:0 A Acetone 272 24 1 23, 6 M one o 755 495 ; p 775 349 469 07 0 0. 1 78:2 Chloroform .365 MO.- 12460 -522.* AW . 460:0' ' 9/3 Card ACC NR: Ar6o16833 :The results indicate that relaxation effects occur at these frequencies In some 'Of the liquids. The authors thank M. I. Shakh ron the late FjF.-A-.-Bd-zhu1W ,V and iYa. L. Golldfarb for supplying the liquid samples,, and the VNMW Research Insti-' 3 fig'ues and I-fa-Wle--, itute for preparing the quartz roda. Origo art* has. iSUB CODE: 20/ SUBM DATE: 26Dec64/ ortiG imp: ooB/ om nr: oog Lrd 3/3 ZARIFIYANTS, Yu.A.; KISELEV, V.F.; IEZHNEV, N.N.; NOVIKOVA, I.S.; FEDOROV, G.G. I Epthesis and functional analysis of oxygen complexes on a our- fAce of freshly cleft graphite. Dokl. AN SSSR 143 no.6:13%- 1361 Ap 162, (MIRA 1594) 1. Moskovskiy gosuda.Tstvennyy uftimersitet im. M.V.Lomonosova i Nauchno-issledovatel skiy instittit shinnoy promysKlAnnosti. Predstavleno akademikom H.M.Dubininym. (Graphite) (Surface chemistry) (Oxygen compounds) C*f Oddadn W the tewho W-M-41 ome of Ph"ll ?111 the Intlortic"I 1wr"L VOW too awl 11111111tikski-Olmopt it I with it bettott' man 6 -13% do #ftt lbs.1pall '~'thmfstquf to shm I 1W pdynw. W a a Omm" 1. Fromexpts.w. a 12.3 t 1W and It a 12.6 m At 1 1101 JOD wJ 1101. t1w role of comnlilltm of I IS I mlent 4 : Ili hillial em", but hiclual gob 11W Imp. It 110 WO lionot Imaidis lue-OKIlum wit tlwwlivtcmttf$ .1 dumd by adds - of 0. W-A. ib". arm 44 the low fat* of t=t 7P.WhIl - -'/A - I b- by not a be "MVO + a War" U at mte. + do own. It W bat any ff. in smobw to the of bydroemboms. the race of 11mr chain I W " A9sdW4dRT 4112MYS at 0 on W th WrW'.rtC pro" am to 00 It"I ftb- staom. and the late Wi of the Opel wig drt4, b Commumplim of .7 The otimer bated C*k' lf~, -which, on e. The chain WWh bekm where pffOR1111 (AM/A). It 6. for the Ist I -n Walk, dwids ,be imelmortion P"W. RWL - of an conics. (in mot.11. seej for the Na butodirmat I WIP at 90 MW JODI, J(PW m O.gDmW 1.61. UP i-0-131111WOM, lop W, - 0.90med JAI, IfFbi -0-131111141 OJDj 101*4 an AAMSM111.119. listed lit lultidlitm tit the ImAyin" 1# the Awhmt 0410, '7 U.6r, That, awl 4.70 (X 10 The activation -rAr#y In that temp. Interm Is 22.8 S. Than L-A 22 slow" of sammike of swim" p4low ill the pmom" d A. It. KITIllmlly 01111 1. is. KA,W,., two. 34'rm 1 rdul, %via walk final p;,At4 Is"Irclur -lut-m, M Ilie Sliti-oxi"its, und 1.1ficaylloct.i. and It"A its oxygm ;it ?,V. tut Ila. Ille mill"Allit A J U04114111140 Amino Via, -)- I,t miwd its the suck hyl akuluill all I gilt 1 41 he (flits. 'I ItV "gid 011401C %bAl %itiOuntlW us 411V gtt 44 &Ile 111111. I)Lfltuw %4 p %mools ilitivaw ul I wa.. A111-1 Inaval 004 inkserwelis u( mifir w1wrlorali-m in she lilill Initially. Thr oiductit"i pC16A uruxidA14,11 ImIlvol p WaN olat-1 ows... The 11111imul tit -01A allmar m Off, ris A Owwom olm-lulilel .4 thr 111114 till movil 1411 11 at 1110 lato a. Soliniticture of rubbers and tb* roloselivilly. A. S. Kus'"tinskil aml N. N. lxshnry. Doklad Akad. Sawk S_%*..S~k. 70, ]WIA[IONGAij dellis. :1 the rates of au,.%idail,in lot IN 44 1 guita-glerche hytitocAflAcou I lQuital 11111but Ityllmv.1f twill (11). bufallielle. r v 1111). .1 Inliddirlir fighlorl Itillo (it)",;, 11tilible bolids Ill the Main chain (IV). allal a hu Ialliette rubber with We' doubk- ~I. "Hit ill the litaits chaiii IV). the conouniptic"i i1the Ill. hiWor, added ill tile initial 4ol I' 'A 12"' lul'bef- 6 64 ItUrAr tuitctkwi I'( -lw lilfw- i-. III, wr I% tvis%t.. ato.I .1mg-m, Ill the' Allove miley. I'lle F"I" "I' ,he auttacatalylk. fix,olliOll ul (), after vousulliplion Of tile it babitur flat,. tile .4itic Older. Con-luently. the o%Wi&&I,jljty of a rubber is drtd. not by th~Ictistholthe in.4.cluji",spillial configuration, =,,, Of almnatic rillog. 1,491 -10y fly tile 1,0. .0 J,wobor 19 in thewswil"Ichui.l. Thera or of conun'l.tioll u( inhibitor C.Airillitoild, tif lite I Ate 'it III,, litilowy act ill illifialital of l4ts,41. kill" jw) ,,,I ""cu,"'. (k) W the illitill. firn"' the ifill1biliOll We dala. Jt IL?I)9nJ it V& - 1. .2"Ild X%4.11; 3; 1 UD 14 III) loml,11111 .11.31, 171.1-1 an', "M7, lamt Is 2 =-.s .1"1 ;.157-3; ltv~ 4.141 a And 2S6.3; I At any temp.. tv or k tv) '110 1.7o. 33 1) 4ml W.11. a fill"T fillivii.al 44 lite doillile-littold CoutclIt Ill the Thi, itifiliclue In"filluillatc% QvvT the ptilivillal C11.1fil. -ular. the ousbi. nN%illlr rfl",1. ill 11 tithef oil lkirti, ill tile et"lliattrAtI441 ~llt~ III 04Y old '"'C' floor we vivation energy fill 0i, hin-listic ill I), by -I dinshIr 1-1-1 14 tile principal rhain ii 21 3 ktol. per lisole (or all tile rutit", I ill tile i,lv vhAIIIq air Pfacti. viollv 4,1 44 Whilmica. atill Itild"p, .41 Ille LIV ..I mot.,vataNtie UJIJUIJ Of Ujilt .111 IttiV~iMiff enTISY a LN; N ILLMI. tlel mole. F,,t tile nearly ~td. butyl lubber. the litte Of . it III ittliihia,w ii irprewatted by a Wolocu line. voiLmullpliq IntIL411y, tile nioll. mact.. with Ch IA~trr At situple than at double btm-l.; - ."& a~ . ctni,t. atiol. wt. is attained. axid4litin litticeet1% at a %lintrt lAtt? timinly at the double Immid, cot lh~ prim-sSW vlwio,. Ajq~rcntly I-is chain, Ili all vam--,.liaihIc butitiv its tile plincipoll vitaist iilr cunkidefAbly sumo t-t- than Jo the %We chains. Th6 appli" not tiotly 14) fractison with 0,. but almi with mosir an't intits. avill., N. I'llon 4 SAME modmAW droo. A. q. Kilsotomom A U. G. MAMILI- DMAWy Akold. A 4AM"",W. 11'"9110, It. 319-21; CA,.. Ak-, l"do. 44. VA. ollwalim of VqAkmiwd 611alliene. %lyleftewl" " KrA, INsolls 2%. line nXide 1%. st"to o"hihilor) #1.4* asthl"Ortl to allef"Al I ft" fif fvf/ Amills lilt. al 2m C./min p"Coel at the imortuct" %tAge of rm"implit" ;:( the Ishibilor at a emst3nl ralt , hich iq Arroilry than the rate rif partly thelt"al inhibiltof ovid4liom At the some lemptrAtulf. The lhr"w.4 the atlivoli ni Ill# junemes iq The cX In Ike pmence CJ ..Ywn is to 0C.I.Oce lk Rumba of =bt(me fill-fillf 0% 0%ompa"d wilb the ntimber at the mme lenilwyotart in the pica we of nitnv" ; thils At 2(1*. 40% 101, W, AM MA, C the (i m Irm le-tweively in O%ygm 0. 4w so, 7. 41,11"21 and in nitingen Ift 198, NO, 111111i wild 216. Arx 7"2* The Axing obf We% nuel Valranistall.m. ([is Its , siam) A. S. Kumvio,kh and %. N. [A-A-110M. 1.11,4111111 NOmy- V. 11, Nov. 1101, p. i luffil.-Sive o)( %mviral fixtims nn the alstive. Craplo.. 11 Diffusion of oxygen &nd oxidation of rubber in tkj presence of ghlawl-2- naphthLiamine. A. S. 7 1 minkli . - L, T.._ Shani n, and)%_L_~~ (Hawil- lasledovatel, Inst, Re;lnov ol Prom, MP, S.S.S.R.) Doklady Ak-ad. Nauk - S.S.S.R. 79,467-70 (1951). -Under const. Op pressure po, the rate of oxidation (measured by the rate of consumption of the antioxidant phe~yl-Z-naphthylemire) of films of Na butadiene rubber 30-40,u thick is const. With varying po (10-760 mm.), the rate w of the inhibited oxidation increases approx. proportionally to the square root of the conen c of dissolved 02# v = kici. The rate of oxidation w -f(c4 and the diffusion coeff. D of the dissolved 02 are by D( - Oelat) i w, where x-re distance from the middle of the film. In the case of inhibited oxidation, D can be considered const. Solution of the above partial differential equation is difficult because the right-hand member is not linear. In its steed, the linear equation ) - *Ial~ ) j k2c, is solved, with k2 detd. from the condition that the algebraic sum of the deviations of the approx. rate k2c from the.actual rate kl-vr-4 in the concn. range from zero to c should be zero. Thie gives, at 1200, k2 = B-15 X 10-5 sacs-1. Solution of the linear equation gives c as a function of-x and t. 'In a film 1 cm. thick, with both sides exposed to oxidation, stationary distribution of 02 Over the thickness is estab- lished, at 1200, in 14 bra., and in a film 0.1 cm. thick In 10-15 min. Practically, on account of the actual dependence of the rate on c~ (rather than on c)p stationary distribution Is attainad somewhat later. It can, however, be concluded that all- A, A: Inhibited Qjdk rubbers. "A. S. Kuz'minskil-and OU, . M. I Is.-Khins. VYSO OVIOkkul. 1R. N. Le2bnpv _ saedjx#sW,,7Se*W 7-o1 Konf. VYjOk0Molekjd. SoedinMi- yam 1952, 90-8.-The Initiation of inhibited oxidation of - rubbers Is detd. by the disappearance of N-Oheayl-2-naph- The initiation reac- ld K hl) i . a ng to je WLM' (K accord to tion or th% Inhibited oxidgtion has an jcjivatlon energy tit , 22.0 cal./mole for any Polymer which does not colitain elec. tronev. groups. The reactivity of the Polymers to oxida- tion depends on the concu. of double bonds. Thedegrecor Polymerization, configuration of the chains, presence of arornatic rings, 'etc.' have practically no influence on this rate. The WetiO6 of 0 with double bonds in the side chzins of butadiene rubbers has an activation energy of 27-8 cul./mole. The oxidation 61 polyisobutylene in the pres- ence of N-phenyl-2-naphthylamint has a temp. th~gshhold below whi h I iti ti d c n a on oes not take place. The.jiAMbIted oxidatir of Butyl rubber Is shown by oxidation of. the poly- mer cha as and addn. of O.to the doubt- bonds - H.. B Noether N T I , iu $ Mechanical: achviii0i Of the iniftAlon OL.Orldfitim Or A. -49.rKuzmin ki 1. KA.-Malzil's and N. N. JA~nlv.- Ah$M. 2 J-ts.-Khim. vysokomole' kaj: Socarnt"Ir. Vvklddy~7-4 Konj. Vysakemlekul. Saedixeniyam. 1952, .99-107 The'pffe (extension of rubber -br 50% of its original length at 2BO cycles/mIn.) on the in- % h bited'oxidation of vulcanized and, unvulcanized rubbers wds detd..' Theactivation energy of butailiencrubber to ln~ hibited.oxidation at 70-80* during mastication drops from' .22.6 to 8.46 cal.lmole, the activation energy. of vulcanized - butadtene-beuze~e: rubber on tnmh. stretching.(M c e/- yd minjut 123-143? drops from 21.0 to 18.1 cal./mole. At the same time the pre-exp6nential.factor of the Arrhenlus equation decreases. The destructive effect Is due to the I presence -c; 0, since, in a N atm. at 20. 60, and 100% the rubber Is 2, 10, and .105 times as stable, resp,,'than with present. D. Noether UM/chemixtry - Rubber Vulcaniza I Mar 52 tion Accelerators '.The Joint Influence of Phenyl-beta-naphthala- E-4 ,1q4 u4ne, Sulfur, and Vulcanization Accelerators on tbe oxidation of Rubber," A. S. Xuz'minskiy, X. Lezbnev, Sci Res Inst of Rubber Production '"Dok Ak Nauk SSSR," Vol 83, No 1, pp 111-114 Sulfur and vulcanization accelerators bave a great effect on the oxidation processes of rub- 'ber. These processes in turn have a great ef- feet on the mech properties of the rubber. 234TT .Phenyl-beta-naphthalamine and su.1fur-were tested on sodium-butadiene rubber and curves showing the rate of consunption of each were -plotted. It was shown that sulfur is consumed faster than phenyl-beta-naphtbalamine. Presented by Acad 'P. A. Rebir4er 11 Jan 52. 234T,T LN CTI 0.1 UMB/Chemistry - Synthetic Rubber 21 Oct; 52 'Me Connection Between Oxidation and Change in Strucl, ture of Butadiene -Styrene Rubber," N. N. Lezhnev, A. S. Kuzlminskly, Sci Res Inst of Rubber Ind, Min of Chom Ind USSR Dok Ak Nauk sssR11 voi 86, No 6, pp 1147-1150 A theoretical curve was calcd for the change in e1as_. tiozity during oxidation at 1000 of heat-vulcanized butadiene -styrene rubber contg 1% phenyl-be+%a-naph- thalamine. Exptl data fit the curre satisfactorily emd'thus a connection is establishe& between the 01im, pro ess based on the decompn of active peroxid*.~: and the change"in mecb properties'during tbe', oxidation of rubber. Presented by Acad P. A. R,ebinder 15 Aug 52. 2 LEZMM, N. 'd recta of j)henyl-"&phthylAmiffr,-9MIW',O -Id getelarstars n the oTidation of rubber. evTsclentific R~ Ch I In qt. Rithh" T"d- VOZEWROURner FTe-MGM f 352-5(t9.r%3j.--S6! C.A. 46. 8887i.- C. C. Ul Inmbited nev (Sd. R~. T paxiu. Li LZZHM, N.N.; KM'KINSKIT, A.S. Influence-of the chemical nature of carbon black on the proper- .ties of thermovulacanizates of the divinylstyrene polywre. 3)okl.AN SM 110 no.1:108-111 S-0 656. OUAM 9r: 11) 1. Nauchno-issledovatel'skiy inatitut resinovoy prowyahlonnosti. Predstavleno skademikox P.A.Rebinderom. (Carbon black) (Rubber. Synthetic) A/ /V Call Nrt AF 1154947 -AUTHORS:. Kuzlminskiy, A.S., Lezhnev, N.N., Zuyev., Yu.S. TITLE: Oxidation of Natural and Vulcanized Rubbers (Okisleniye kauchukov I rezin) PUB.DATA: Gosudaratvennoye nauchno-tekhnicheskoye izdatel'stvo khimicheskoy literatury,, Moscow, 195T, 319 PP-j 5,000 copies ORIG.AGENCY: None given EDITOR9: Babushkina, S.I.; Tech. Ed.: Lurlye, M.S. PURPOSE: The monograph Is intended for scientific and engineering personnel of the rubber industry, and for specialists in allied fields of chemical technology. Card 1/10 Call Nr: AF 1154947 -Oxidation of Natural and Vulcanized Rubbers (Cont.) COVERAGE: The book discusses aging of natural and vulcanized rubbers caused by oxygen, ozone, high temperature, light, mechanical stress and catalysts. Methods of studying aging and preven- tion of aging are reviewed. Personalities mentioned include: Angert,-L.G., Belitskaya, R.M., Degteva, T.G., Lyubehan- skaya, L.I., Mayzells, M.G., Peschanskaya, R.Ya., Popova, Ye.B.' Postovskaya, A.F., Mitrova, N.G., Shemastina, Ye.V., Shokhin, N.A., Shanin, L.L., Kargin, V.A., Medvedev, S.S., Dogadkin, B.A., Dolgoploskiy, B.A., Reb-Inder, P.A. SlonLtskiy, G.L., Bartenev, G.M., Abkin, A.D., Reii;_ linger, S.A. There are 42 references, 19 USSR, 20 English, 2 German, 1 French. There is a bibliography at the end of each chapter. Card 2/10 Call Nr: AF 1154947 Oxidation of Natural and Vulcanized Rubbers (Cont.) TABLE OF CONTENTS Preface 5 Tntroduction, 7 Bibliography 12 Ch. I Themal Oxidation of Natural and Vulcanized Rubbers 13 1. General considerations 13 2. Effect of high temperature on natural and vulcanized rubbers 22 Card 3/10 Call Nr: AF 1154947 Oxidation of Natural and Vulcanized Rubbers (Conte) 3. Structure of~naturai rubbers and their reactivity ' to oxygen 28 4. Free (autocatalytic) oxidation of natural x~ubber 35 5. Oxidation of natural rubber in solutions 53 6. Oxidation of natural rubbensin the presence of antioxidants 55 7. Oxidation of natural rubbers in the presence of various Ingredients of vulcanized rubber mixtures 76 8. Oxidation of vulcanized rubbers 89 9. Catalytic oxidation of natural rubbers under the action of metals ofalternate valency 100 Card 4/10 Call Nr: AF 1154947 Oxidation of Natural and Vulcanized Rubbers (Conte) 10. Action of various oxidizers on natural rubber 110 113 Bibliography r,h. II W Natural and Vulcanir-led Rubbers by Air by Light) 118 118 1. General considerations 2. Oxidation by light 125 3- Effect, Of light on various natural rubbers 142 4. Role of rvbber-mixture ingredients in the action 145 of light on natural and vulcanized rubbers Card 5/10 Call Nr: AF 1154947 Oxidation of Natural and Vulcanized Rubbers (Cont.) 5. Protection of vulcanized rubbers from the effect of - light 153 Bib liography 163 Ch. III Aging of Natural and Vulcanized Rubbers by Air (Effect of Ozone and Light and Ozone) 168 1. General cwnsiderations 168 2. Effect of ozone on -undeformed natural and vulcanized rubber 171 3. Effect of ozone on deformed vulcanized rubber 173 4. Structure of natural rubber, its chemical resistance to ozone and cracking ozone 180 Card 6110 Call Nr: AF 1154947 Oxidation of Natural and Vulcanized Rubbers (Cont.) 5. The role of some ingredients in cracking of rubber by ozone 183 6. Combined action of light and ozone on vulcanized rubber 186 7. Increase of vulcanized rubber resistance to cracking by ozone 193 Bibliography 200 Ch. IV Oxidation of VulcanZwtes oubjected to Mechanical Stress 2o4 Bibliography 218 Card 7/i0 Call Nr: AF 1154957 Oxidation of Natural and Vulcanized Rubbers (Cont.) Cho VI Methods of Testing the Aging of Natural and Vulcanized Rubbers 250 1. Chemical methods of testing 251 2. Mechanical methods of testing 260 3. Methods of accelerating aging of rubber A Bibliography 291L Card 9/10 Call Nr: AF Oxidation of Natural and VulCanized Rubbers (Cont.) 1154957 Cho VII O-Vgen Diffusion and Solubility In Natural and Vulcanized Rubbers 298 1, Oxygen Solubility in natural and Vulcanized rubbers 298 2. Oxygen diffusion in natural and Vulcanized rubbers 303 3. Solubility of ingredients in rubbers 310 4. Oxygen diffusion and kinetics of rubber oxidation 314 Bibliography 318 AVAILABLE: Library Of Congress Card 10/10 5(4) 07HORS: Lezhnev, N.N~, Nikitina, T.S., Kuzyminskiy, A.S. SOV/63-4-3-23/31 V11LE: PERIODICAL; ABSTRACT: Card 1/2 On the Modification of the Surface of Carbon Blacks by the Action of Ionizing Radiation Xhimicheskaya nauka i promyshlennost', 1959, Vol 4, Nr 3, pp 407-408 (USSR) The strengthening effect of carbon black is determined by the ad- sorption properties of its particles. The surface may be modified by radio-chemical a0dition of various compounds. The irradiation was carried out by a CoOO source of 22,000 g-equ. Phenyl- P-naphthyl- amine, mercaptobenzothiazol, sulfur and rubber of the type 8KS-30A were physically adsorbed. The mechanical properties of the vuleaniza- tes were studied on the Polani dynamometer. A considerab' -3 effect is obtained by irradiating carbon black with rubber chemically adsorbed on its surface. There are 2 tables. SOV/63-4-3-23/31 On.the Modification of the Surface of Carbon Blacks by the Action of Ionizing Radiation ASSOCIATION: Nauchno-issledovateliskiy institut rezinovoy promyshlennosti (Scien- tific Research Institute of the Rubber Industry) Card 2/2 5W ' SCV/2o-125-5-29/61 AUTHORS: Kuziminskiyj A. S., Zaytseva, V. D.p ~2~ TITLE: On the Suppression of the Catalytic Effact of Polyvalerit Metals in Rubbers (0 podavlonii kataliticheskogo deystvi-a polivalentnykh metallov v kauchukakh) PERIODICAL; Doklady Akademii nauk SSSRI 1959, Vol 1251 Nr 5, pp 1o57 - 1o6o (USSR) ABSTRACT: The suppression of the catalytic effect of polyvalent metal ions contained in rubbers is an important, though hitherto little investigated problem. This Cap is partly filled by the present paper. The behavior of metal salts was investi,,,ated in divinyl-styrene rubber as viell as in natural rubber. The authors determine the rate at which oxy-,ren is absorbed by rubber at various temperatures and the variation of rubber structure from the viscosity of its solution in benzene. The results obtained by these investi.ations aro sho,,,rn by 3 dia- grams. It was found useful to investiEate the binding of metal ions to stable, catalytically inactive complexes. These Card 1/4 complexes (which are apparently formed by an electron of the On th6 Suppression of the Catalytic EffecG of SOV/2o-125-5-29/61 Polyvalent Metals in Rubbers d-layer of the Cu ++ -ion or by 5 elect.rons of Fe... and Mn++ not joined in pairs) show a complete blocking of the central ion by the molecules of the addend, so that transition of the electrons from this ion to the substratum (peroxide of rubber) or vice versa becomes impossible. The firct part of the present paper deals with the ability of metal salts to form complex compounds with the various ingredients of rubber mixtures, viz. in low-molecular compounds and in the rubber substance. The binding of the copper ion by the antioxidant in the benzene solution was investigated by observing the fluorescence of the solution of these substances in benzene and alcohol. The conditions warranting the complete extinc- tion of fluorqscence are given by a table. As the extinction of fluorescence may be brought into connection with the blocking of the ion, it indicates a decrease of the possibi- lity of a valence transition and consequently a decrease of the catalytic activity of the metal ion. The authors then investiC;ated the possibility of the formation of tile afore- Card 2/4 mentioned complex compoundain the rubber substances. The On the Suppression of the Catalytic Effect of SGV/2o-125-5-2c/61 Polyvalent Metals in Rubbers compoinids of iron and rubber with certain components of rubber form stable complex compounds, which may be obtained by the precipitation of acid or basic aqueous solutions from them. The componehts which had not participated in the reaction must then be carefully washed out. The composition of these compounds is shown by a table. The relations of the molecules of organic compounds to the metal atoms, as shown in these tables, can in most cases not be represented in form of a definite structure, and therefore this problem is in need of further investigation. The reaction between the complex-former and the metal in the rubber medium develops completely but slowly. 3 diagrams contain data concerning the kinetic oxidation of rubber in the presence of complex compounds (formed immediately in the carboniferous medium of the rubber), and also concerning the synthetized complex compounds introduced into a rubber. The bound metal ions exercise no influence whatever upon the rate of oxida'.ion or upon the structural. variation of rubber, i.e. they lose Card 3/4 their catalytic activity. Therefore, rubbers able to form On the Suppression of the Catalytic Effect of S01112o-12r-9-29161 Polyvalent Metals in Rubbers complex salts with the ions Cu ++ , Fe ... I etc have a greater stability with respect to the salts of polyvalent metals than the rubbers used for their production. There are 3 figures, 2 tables, and 6 referencesq I of which is Soviet. ASSOCIATION: Nauchno-issledovatellskiy institut rezinovykh i lateksnykh izdeliy (Scientific Research Institute for Rubber- and Latex- Products) PRESENTED: January 3, 1959, by P. A. Rebinder, Academician SUBMITTED: December 22, 1958 Card 4/4 -9/138/61/000/011/005/0r)7 A051/A126 AUTHORS: Lezhnev, N. N., Terentlyev, A..P., Novikova, I. S., Kobzeva, T. A. TITLE: The chemical nature of the surface of carbon black PMUODICAL: Kauchuk i rezinaA no. 11, 1961, 21 - 27 TW- The author!m have developed a new method for the quantitative deter- mination. of certain;~oxygen funotional groups present in carbon black, and have tested the validity of methods previously'iised. A rapid and accurate method for the determination of active hydrogen in carbon blacks, using an ether solution of the Grignard reagent, was also developed, in addition to a method for the alkali- metric titration of the acidic groups of the carbon blacks withcatstic soda and sodium carbonate. By assuming that the caustic soda reacts with all the acidic groups and the sodium carbonate only with the carboxylic ones, the phenol and carboxylic groups in the carbon blacks were determined. The general nitrogen in the carbon black was determined by the Kjeldahl method. The latter is a variation of the method introduced by A. P. Terentlyev and B. M. Luskiniy. Combustion can be carried outin 4 hours, and chromic acid is used as the oxidation catalyst. Coll- clusions are drawn on the nature of the oxygen bound with certain carbon blacks 1.7-Owd~1A S/138/61/ooo/oii/oWow The chemical nature of the surface of carbon black A051/A126 from the developed methods and by comparing the obtained results with data of other non-Soviet authors, &r*ata of carbon black investigation using the para- magnetic electron resonance method. However, a large portion of tbeczygen in the channel black has not been identified. The most complete identification of oxygen was made for that bound with experimental carbon black of the WD(MIR) type. Data of the channel black analysis, both of the initial and of that containing chemically adsorbed neozone A (D), cb 2 HA (F2NA) and also captax MET (MI3T) led to the assumption that these substances react with oxygen-containing radicals of carbon black at the position of the weakest-bound hydrogen atom (RN-R and RS-11). It is pointed out that carbon black chemically interacts with various ingredients of rubber and probably with raw rubber or polymer radicals. Thus, the following are thought to be chemically actives 1) various oxygen-containing groups, 2) sul- fur-containing compounds - in the case of carbon blacks, produced on the basis of petroleum and coal, 3) free radicals on,the surface - non-coupled electrons of atoms of carbon and oxygen and possibly atoms of sulfur and nitrogen, bound Iry chemical bonds with carbon atoms of the carbon black crystalline lattice. The sulfur-containing groups are thought to have the structure > C = S and --YC - SH. The active hydrogen is thought to be In the groups - C4 and -->C - 0 - H. Re- ~O H Card 2/3 S113816110001011100510(Y7 The chemical nature of the surface of carbon black A051/A126 sults, obtained:elarified the.mechani6m-of,interaction between the carbon black and accelerators of vulcanization and anti-oxident of the secondary aromatic amine type.. A satisfactory correlation is derived in a comparison of. the theory of polymerization and hydrocarbon oxidati6n with two cases investigated 'by the auth- orst Channel black processed with MMI channel black processed with F214A. There are 2 tables, 1 figure and 14 referencest 6 Soviet-bloc and 8 non-Soviet-bloc. The references to the 3 most recent English-language publications read as follows- H. V. Drushel, J. V. Hallum, J. Phys. Chem.,* 62, no. 1, 110 (1958); G4 Kraus, R. L. Collins, Rubb.-World, 139, 219 (1958); M. Beroza, Analyt- Chem., 25i 177 (1958). ASSOCIATIM Nauchno-issledovatellskiy Institut shinnoy promyshlennosti (scien- tific Research Institute of the Tire Industry) Card V3 37177 8/138/62/000/004/oo4/oc)8 0 A051/A126 AUTHORS: Kuz'minskiy A.S.; Zaytseva, V.D.; Lezhne TITLE: Protection of natural and synthetic rubber from catalytic oxidation under the action of copper and iron ions PERIODICAL: Kauchuk I rezina, no. 4, 1962, 10 14 .TEXT: A study was made of the causes for the different effects of ingre- dients on the catalytic oxidation of NR (smoked sheets) andCKC-30A (SKS-30A) in the presence of iron and copper. It is assumed that metals with changing valenc:L-s can speed up both the reaction of initiation as well as that of chain development. The reaction which determines the rate of initiation is the decomposition of hydro- peroxide under the effect of metals. The authors discuss the activation of oxygen and the formation of active intermediate compounds of metal ions with oxygen. The,, possibility of repressing the accelerated oxidation of NR and SKS-,30A in xylene solutions and the solid state was investigated by binding the metal,lons Into cat., alytically inactive complexeS. Certain rubber ingredlento Garved au the addends in the complexes. Obtained data led to the following conclusions: 1 ') the higher the concentration of the metal ions in the rubber solution, the faster its viscos-, Ca rd 1.13 S/138/62/000/004/004/008 Protection of natural ..... A051/A126 ity drops; 2) the catalytic activity of the copper ions with respect to the rub- ber oxidation is much higher than the catalytic activity of the iron ions; 3) certain ingredients introduced into the rubber mix have the ability, partly or completely, to suppress the catalytic activity of the copper and iron ions. A further study was made of the catalytic oxidation In the rubber solutions in the presence of~anti_aging agents containing amino- and hydroxyl groups, of acceler- ators containing sulfur and an amino- group in the molecule, and of a vulcanizing agent. The following conclusions were drawn: the accelerators of vulcanization (tetrame thylthiuramdi sulfide, sodium die thyldithiocarbamate) and anti-aging, age (n-oxyphenyl-fl-naphthylamine, dinaphthyl-n-phenylendiamine, dioxydiphenylamine), form firm compounds with the metal ions of varying-valency metals, not having any ~catalytic activity with respect to natural and synthetic rubbers, but character- istic of the metal ions themselves. These compounds most probably have the ~`s'tructure of intercomplex slats. Certain complex compounds, formed by the metal Aon of varying valency, and deactivating substances, are strong inhibitors of rubber oxidation. A new method for synthesizing effective inhibitors is recom- mended. There are 5 figures and 1 table. The reference to the rMst recent English- -language publication reads as follows: 9.A.Martell, M. Calvin, Chem. of the Metal Card 2/~ ZPj S/138/62/000/004/oo4/008 Protection-of natural ..... A051/A126 Chelat Compoun d (1952). ASSOCIATION: Nauchno_issledovate~skiy institut re~inovoy promyBhlennosti i Nauohno-issledovatellskiy institut rezinovykh i lateksnyldi izdcliy. .(Scientific Research Institute of the Rubber Industry and Soientif- ic Research Institute of Rubber and Latex Articles) KUZIMMKIY, A.S.; ZAYTSEVA, V.D.1-LEZHNEV, N.N. Protecting crude and vulcanized rubbers from cata2ytic wddation under the effect of copper and iron ions. KauclUj rez. 22 no.4:10-3.4 Ap 162. (MA 15:4) 1. Nauchno-isaledovateltakiy institut reminovoy promyshlennosti i Nauchno-issledavateltakiy institut rezinovykh I lateksnykh izdeliy. (Rubber) (Oxidation)