SCIENTIFIC ABSTRACT LEVITSKIY, E.A. - LEVITSKIY, I.YA.

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SCIENTIFIC ABSTRACT
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ILTSOUSHVILI, Y&.R.; VROVA, I.S.; IJVITEKIT. I-A- - Sublimation of molybdenum oxide from aluminum-molybdenum cat&lysts. Zhur.prikl.khim. 33 no-3:734-736 Mr 160. (MIRA 13:6) (Molybdenum oxide) (Aluminum oxide) (Catalysts) ,f - 3/149/*61/000/002/004p 17 AOo6/AOO1 AUTHORS$ Levitakiy, E.A., Shchepachav, B.M. TITLEs Developing a Method of Preparing Basic Salt of 5/6 Aluminum Oxy- chloride PERIODICALt Izvestlya vyashikh uchabnykh zavedenly, Tsvetnaya metallurglya, 1961, No. 2, PP. 71 - 75 TEXTz Toprepare aluminum oxide or hydroxide with required properties, reprecipitation of aluminum hydroxids is employed where aluminum hydroxide is con- verted into a soluble neutral salt by treatment with acid. 117his water-soluble product is subjected to repreoipitation by adding alkali whi~2hneutralizea the solvent. Since this process consumes large amounts of expensive reactive agents, reprecipitation would be improved by using a soluble aluminum comp-o,.Lnd which is closer to the hydroxide Itself in respect to the .3hemical composition. E.A. Lev- itskly proposed a method of precipitation aluminum hydroxide frcm a aolution of basic salt - the 5/6 aluminum oxychlorlds (A12(OH) Cl). This method reduces the consumption of reactive agents for the repreolpita5 Uon of one ton of oxide ty Card 1/7 3/149/6 1/XO/tO 2/004P 17 A006/AO01 Developing a Method of Preparing Basic Salt of 5/6 Aluminum Oxyohloride a factor of 4 - 6; the technology in simple and eoonomiaal. A12(04)5Cl is well soluble In water and offers a series of properties which make It extremely suit- able for large-scale industrial use, This compound was studied by various authors, Including Academician V.A. Kargin (Ref. 2 - 4), M.Ye. Shishniashvill and E.D. Uznadze (Ref. 5). various investigations were made with 5/6 o)rychloride ef aluminum using synthetic methods (Ref. 4, 6 - lo), although none of the methods can be employed as a basis for an efficient industrial process. rhe authore d9veloped a method of producing 5/6 aluminum oxyahlorlde from semi-products of alumina industry by accelerated carbonization prooess, conducted according to the following scheme: Card 2/7 S/149/61/000/002,ft4/t17 A006/AO01 Developing a Method of Preparing Basic Salt of 5/6 Aluminum Oxychloride Desilicificated aluminate solution of alumina production CO 2 -iAccelera ed carbonizatio Hyd4te pulp f_Filtration= Mother soda solution Aluminum hydroxide H20 Wash water Al~H) 3 HCl i0mrs-5-0 Tvg A12(OH Cl solution L, )5 jEvaporatioN Concentrate4 Al Cl solution V 2(01) 5 Card .3/1 A127'T~OH)l s/149/61/000/W2/004/017 A006/AOOl Developing a Method of Preparing Basic Salt of 5/6 Aluminum Oxychloride The aluminate solution intended for carbonization should not contain over 60-70 g/1 A1203 at a 1.5 caustic ratio. The product is washed in distilled water. Filtration is recommended to be carried out in a vacuum-filter drum with subsequent repulping and repeated filtration. Dissolving of Al(OH) in hydrochloric acid with the formation of 5/6 aluminum oxychlorlde does not depeni on the concentration of the acid as stated by E.D. Uznadze and.M.Ye. Shishniashvili (Ref. 5). The use of freshly precipitated aluminum hydroxite permits the use cf hydrochloric acid of any concentration since this precipitate Is able to interact with lower oxychlorides. The method of obtaining 5/6 aluminum oxychlorlde from Al (OH) 3 and hydrochloric acid is based on the conclusions made by V.A. Kargin and L.K. Lepin' (Ref. 4, 6) that each of the b-asio chlorides is stable within a certain pH range of the medium in the solution. The optimum pH value for 5/6 aluminum oxyohloride is 4 - 4-5. Two methods of dissolving aluminum hydroxide In hydrochloric acid are suggested: 1) at a constant pH of the medium, mixing and heating (:Lhe pH value is maintained by adding HCl at a level of 4 - 4.5 (Ref. 16); 2) by adding the whole stoichio- metric amount of HC1 for the formation of A12(O")5Cl with subsequent heating up to boiling and intensive stirring. Both methods may be combined. When dissolving Al(OH)3 in HC1, solutions of A12(OH) 5Cl with 80 - 140 g/.' A1203 concentration are Card 4/7 8/149/61/000/1002/004/W7 A006/AOO 1 Developing a Method of Preparing Baa:rd Salt of 5/6 Aluminum Ox7chloride 0 obtained, 'The density an4 v1sooalty of the solution,'depanding on A120* conoqn. tration, are',ahown in Pigiires 2 and 3. When evaporated to a concentratlon of about 250 g1l of A120-4, the solution is galled. The gel Is dried to powder (Figurm powder ifi 0.95 - 0.97 9/cm . at an average size 4P 5)* The Weight orAl2(OH)5C1 of the particles of I - 2 mm, This product Is well soluble in water and can be easily stored and transported. Figure 2j its --I A I I the Al (OH) C1 solution Dependence of density of I Is on the concentration of A120~ 200a. $17 50 ro 04 IN .139 fig IV IV Card 5/7 8/149/61/000/1002/'004/017 A006/AO01 Developing a Method of Preparing Basic Salt of 5/6 Aluminum Oxychloride Figure 3: Figure 41 .The dependence of vinobalty of the A12 Natural drying of A120H gal at (OH) C1 solution on concentration of 200C Yl 5 05 at 2DOC A12 .40 4 0 160 900 Card 6/7 s/149/'6 I/OW/U02/'004/1017 A006/AOOI Developing a Method.of.Preparing Basic Salt of 5/6 Aluminum Oxychloride Figure 5: Drying of Al(CH) 1 gel at 950C and storage: ~14 of dried powder 9 air at 200C 30 6,;~c 4 0 R cym. There are 5 figures and 16 referencest 12 Soviet and 4 non-Soviet. ASSOCIATIONSs Krasnoyarskiy institut, tavetnykh metallov (Krasnoyarsk Institute of Non-Ferroua Metals); Kafedra metallurgii letkikh metallov (Department of Metallurgy of Light Metals) ~t~~t May 17, 1960 25 Card .7/7 . .. ... nln NOW KITSOBASHVILI,- Ye.R.;- KURKOVA N S ; LIKHOBABE14KO, V.S.;, LEVITSKII, B.A.; KUZIMINA, T.N.; i~&IciEV*A, V.F.; MASOLCVA, F.A. Effect of the conditions under which the bydrox4de precipitates on the mechanical durability of aluminum oxide. ~;. AN SSSR. Otd. khim. naulc no.9:245-250 F 161. (MIRA 14s2) 1, Institut'neftekbimichepko o sinteza AN SSSR. (Al LEVITSKIY, B.A.; MAKSIMCV, V.11.: MAKHENKC, I.Yu. Pilymeric character of 5/6 basic aluminum chloride and the possibility of a higher bdsicity if aluminum hydroxychlorides. DokI. AN SSSR 139 no.4.-884-887 Ag 161. (MIRA 14:7) 1. Predstavleno akademikom V.A. Xarginym. (Aluminum chloride) IZVITSKIYI R.A.; XMIMOV, V.11. Composition of hydrolysis products in alumimm chloride solutions, Dokl. AN SWR 141 no.4:865--068 D 161. (KIU 14: 11) A 1. Predstavleno akademikm I.V. Tanamyevym. W=Jim- chloride) (Hydrolysis) KATSOBASHVILI., Ya.R.; KURKOVA, N.S.; LEVITSKIY, L.A.; ROMILNOVSKIY, B.V. Fteparation of active opherical aluminm oxide. Xhim,prom n0.13 26-30 Ja 162. iKMA 15s1) I* Izwtitut neftekbimicheokogo ointeza AN SSSR. (Alumln= axide) MAXARFSKO, I.I.; LEVITSKIY, E.R. Resochin In clinical internal owdicino and its poasible side effects. Sov. mod. 27 no.3:72-78 Mr 164. (MIRA 171ll) 1. Kafedru propedertichookoy terapil i profeasionallnAh zabolevaniy sanitarno-giglyanicheakogo fakullteta (zav. - daystvitelinyy chlen A-41N SSSR prof. Ye.M. Ureyev) I Moskovskogo ordena, Lenine, meditsinskogo in- ntituta, imwA Sechenova i 24-ya Moskovskaya gorodskaya bolliLitea (glavnyy vrach V.P. UspenBkiy). SUMAROKOV, A.V.; LEVITSKIY, F.R.; MIKHAYIDV, A.A. Charactarlsticm of the phonocardlogram In extrany3tole and cardiac fibrillation. Sov. med. 27 no.lsl4-19 J& 164. (MIRA 17:12) 1. Kafedra terapli (zav.- deystvitallnyy chlen AMN SSSR prof. Ye.M. Tareyev) sanitarno-gigiyenicheakogo fakullteta I Moskovskogo ordena Lenlna meditainakogo instituta Imeni I.M. Sechenova I 24-y Gorodskoy klinicheskoy bollnltsy (glavnyy vrach V.P. Uspenakiy). IJMTSKIr, 1. R. (Moskva) Rheumatic and nonspecific Infectious (rheumatoid) arthritis. Felld. I akush. 27 no.5:3-8 My 162. (MIRA 15:7) (ARTHRITIS, RHKUMATOID) (REUMTISM) ANDROSOVA, S.O.;APROSINAP Z.G.; BEZRODUM, A.A.; VEMEL, Me.; VINOG FADOVA, 0. M. ; IL ; HAKARENKO, I.I.; MAKSPANOVI, D.A.; PO EVA, L.H.; SUMAROKOV, A.V.; SHATROV, N.N.; SHAPIROp L.A.; TAIMEV , Te.M., prof., red.; MELINMOV, Ye.B., red. (Occuletional diseases] Professionallnyo bolezni; ucheb- noe pvsobie dlia studentov eanitarno-gigienicheakikh fa- kul'ttitoy. Pod red. E.M.Tareeva. Moakya, 1963 p. 223 p. (MIRA 16:6) 1. Moticow. Pervyy meditsinskiy institut. 2. AMN SSSR (for Tareyov). (OCCUPATIONAL DISEASES) KHOMKO,M.V., dotget.~i I L:-:';ITSKIY, F.A. Fraotures of the shinbcne malleoll. in miners. Trudy Vkr. nauch,-isole inst. ortop. 1, travm. no.15tl69-194 959 (MIRA 16t12) la, Iz kafedry gospitallnoy khirurgii (zav.kafedro- R.V. Bogoolavokiy) Stalinakogo meditsinskogo ir-- doteent A.M.Ganicbkin). LIVITSKIT, Y.Ao A rare case of bilateral hernia of the anterior tibial mscleo Ortop. trarm. I protez. 20 no.8.-65-46 Ag '59. (MIRA 12111) 1. Is Stalinskoy oblastuoy tromatologichookoy bolluitsy (glavvy vTach - ?.Go DobroTa) i Stalinakogo tauchno-looledovatellskogo instituta traymatologii I ortopedii (diro - kand,wed.nauk T*A. RaTenko). (ma, maclas & tendons) KHAVKINO M.L.j SHTUTINp A.Yaq LMTSKIYo _-F.A.; TRIFONOVAq A.D. Mikhail Vasillevich Khovenkoj an hio 60flh birthday@ Ortop, traym. i protez, 21 nos 9M S 160o (MIRA 13M) (KHOVMOP MIKML VASILILTICH9 1900-) LEVITSKIY, F.A. I Report an the 51vt oession of the Donotok Society of Tra=atc,"n-- gioto and OrthopedlBtae Ortopeptravmoi protese 2-2 noe091-92 AP 161a (DOVETSK. -ORTHOPEDIC SOCIETIES) (MIRA U,:11) LZMAY,NA, Z,P., reforent; TKACII~XKOl S.S.9 referentp kand.meditsinskikh nauk; OSILA, A.I.p referent, dotsent; SZhDYlJKr P.P.v referent; KOSTRIKOVj V.Sop referentp kand.moditsinskildi nauklLaj~ ~.p referent; BiIOLGKAYAp Ye.Iol referent; TKAC116VA, 3,Got referent GALICHMOp V.Ye.j referent; UYLK9 A.S.p referentp kand.moditsinskikh nauk. Reports on meetings of societies of truixatoloeists and orthopedists. Ortop. travin. i protez, 21 no. 7:78-95 JI 160. (1,1M1 13:10) (ORTEOP-MIC SOCIETIES) LEVITSKIY, G.D.: LEVIH, Tu.I. ............ Extrusion press for porcelain insulators. Patent U.S.S.R. 76,469, I)ac.31, 1949. (CA 47 no.19:10194 '53) Bills.,y ~ r ,I .A "Kc 1. A. btilnv~n. ?Pvls-w-!(t b..- En,,. for ",v~ orodlintion of tl~ln MAVh. s~rot. (1, No. Ori, 1()r,2. Monthly List of Himplan Avregginnn. Librr,,ry of Cnrireqn, 3e,,)Ien~,er ,LEVITSKIY, G.D., inzh. Studying the compressive properties of an auger nechanirM. Stek. i ker. 21 no,10:26-31 0 164. (KrRA 18:11) I. Gosudarstvennrf issledovatellskly elektrokeramicheskiy I institut. i i, f-r I USSR Plant Diseases. Diseases of Cultlvattd Plants fl- 3 Abs Jour Ref Zhur - Biol. ,, No 6, March 195",, No 2.3001 Author Levitskly, G.D. Inst Not Given Title New Fungicides In Controlling Grape Mildew Orig Pub Vinodelie I vinogradarstvo SSSR, 1956, No 4, 39-40 Abstract Experiments of the Kabardin frAt.-berry experimental station (Nallchik) on the Galan variety proved that in grape mildew a 1 and 2% solution of fuclazin (a 20% preparation of ferrous dithiophenol) is equally as toxic as Bordeaux liq7AId. 1he grapes were sprayed on June 4 and 24 and July 15- The advan- tage of fuclazia consists In the simplicity of preparing a working solution and in the fact that it does not diaript the assimilating function of the leaf. Diiiitrothiocyanogenbenzol in concentrations of I and 1-5% also produces a positive effect in controlling grape mildew, although a somewhat weaker one than faclazin. No burns were observed in treating plants with either Piclazin or dinitrothiocywogenbenzol. Card 1/1 BULAVIN, Ivan Anisimovicb, doktor tekhn. nauk; JENITSKIY,__G.D.p inzhol reteenzent; USMSKIY, X.G., redAzd-va; MODEL', tekhn. red. (Fachinery for the manufacture of fine ceramic articles) Ha- shiny d1la proinodetva tonkoi keramiki. lzd.2,, dop. i perer. Moskva., Maohgizj, 1962. 43.0 p. (MIRA 15:3) (Ceramic industrioe-Equipment and supplies) LEVITSM', 0.1) inzh. Matl-Aumatical analysis of the operation of the screw in a vacuum press. Stek. i ker. 20 no.8131-38 Ag 163, (MIRA 16M) 1. Cosudaretvannyy iasledavatellekly elektrokeramichaskiy institut, TARASENKOO G.T. (Turitounko,, H*T&jj kund,modenauk; MAKARENKOVV.A., nauchnyy sotrudnik; UNITISKlY, G.M. P,(.vytalkjiP II.M.], nauchnrl notrudnik Case of perforation of an ovarian cyst In a woman in the eighth month of pregnan,.ly. P--,d., akunh. i gIn. 23 no.4:3 of cover 161. (141 ILA 17: 1) 1. Akushersko-ginekoloi;i~:!,Lc.,~k,,)yc otdeleniyo (zav. - prof.S.F.Vino- gradova (VY-nohradova, S.P.J Ukraln3kogo nauchno-isoledovateliskogo instituta okhrany materln3tva I detstva im. deroya Sovetskogo go- yum& prof.P.M.Buyka (direktor - kand.med.nauk A.G.Pap [Pap, A.H.1). ..60 P. 'Woi I-so SID -00 00 O.jLL4wkdff.'- Run. -00 lit fcw 111st transfer 00 from am Poo, 20 00 ce 0 so 00 a 0 60 000 God #Soo 000 8*0 LIS 0 U00 ILI AV. t allL u It &1 10 U 0 b to V a ar 0 0 00 0 0 0 0 0 0 0 0 0 : : : : 0 0 0 &&Sooilloilt 0A.0 0 1,EIITSKIY, G - S. Iznosoupornoe khromirovanie. Kiev, ",rishr-iz, 1948. 64 p. Wear-resisting chroming. L, SO: Manufacturing and "lechanical Engineering in Vic SoviA Unior, Idbrary of ConLTess, 1953. LEWITSKI11, G. S /5 745.64 .Iki Khrornirovmiye DeLaley Mashin i Instrum-nLa (Chrome ?lating of Machine Parts and Instruments) Kiev, ~'Iashviz, 1951. 225 P. Illus., Diagrs., Tables. "LiteraturO: p. 222-(2211) - ~t ~~fm'e-4' " - A - 4~ 44L~- 1 -6 -6 KOSTMOT, V.A..-. GONGRARMO, I.S.; LIVITSKIT G.S., Inshener, retsenzent. . *~ ~ 1 --- I . . V- r (Reconditioning autosobile and tractor pam] Toostanoylonle ayto- traktornykh detalel. Kiev, Go@. nauohno-tokhn. itd-vo mashinostrolt. I sudoetroia. lit-ry [Ukr. otd-niel X95). 94 p. (MIRA 7:7) (Tractors-Repairing) (Automobile&.-Aspairing) PHASE I TREASURE ISLAND BIBLIOGRAPHICAL REPORT AID 447 - I BOOK call No.: AP638691 Author: LZVITSKIY, 0. S. Full Title: INCREASING EFFICIENCY IN ELECTROPLATING PROCESSES Transliterated Title: Uskoreniye protseasov gallvanicheskikh pokrytiy Publishing Data Originating Agency: None Publishing House: State Scientific and Technical Publishing House of Literature on Machine Building and Shipbuilding ZNaBhgizf7 Ukrainian Division, Kiev Date: 1954 No. pp.: 158 No. of oopiest 4,000 Editorial Staff: The author expresses acknowledgement to Barmashenko, Nadezhdin, Edigoryan, Chichellnitakaya, Bondarenko, Solovey, Felldmanp, Zazimko, Antonov, Berlyant and others. Text Data Coverage: In this monograph the present stage of eleotroplating pro- duction is examined and means of Improving the quality of coating and of increasing productivity are indicated. The author characterizes the present stage as a transition from an average-quality coating- the same for all plated articles - to better qualities differentiated for each specific group of articles in relation to their purpose. The changes in mechanical, physical and chemical properties of plating V3 Uskoreniye protsessov gallvanicheskikh pokrytiy AiD 447 - I depending on the conditions of production are discussed. They are illustrated with examples from nickel, copper, and ohrome-plating. Examples of increased efficiency in processing are analyzed. Special attention is given to problems of the distribution of current on electrodes and in the electrolyte. The effect of the current density on the required quality of plating is demonstrated. The equipment and the organization of production are described. In Ch. I., a brief history of electroplating from its origins, based on the works of the Russian Academician B. S. Yakobi, to contemporary Soviet investigations is given. Many names of Soviet scientists are cited. Electroplating shops in some Soviet plants are mentioned. The monograph is written on the basis of Soviet theoretical and experimental investigations. Only the problems of particular Interest for Soviet engineers and technicians are dealt with in detail. The author refers to his earlier work "Chrome Plating of Machine Elements and Tools" (Mashgiz, 1951) which describes the technique of the process according to principles exposed in this monograph. The book Is provided with illustrations, tables and diagrams. TABLE OF CONTENTS PAGES Foreword 3-4 Ch. I Present Stage and Development of Electroplating Production 2/3 5-20 Uskoreniye protsessov gallvanicheskikh pokrytiy AiD 447 - I PAOES Ch. II Principles of Electroplating Deposition of Metals, 21-121 Corrosion-resisting plating; Wear-resisting plating; Pro- tective decorative plating; Properties of electrolytes; Electrocrystallization of the deposit; Dependence of the properties of electrolytic deposits on the conditions of their production; Nickel plating; Copper plating; Distri- bution of the direct current in the electrolyte and electrodes; Principles of uniform coating; Increasing ef- ficiency in electroplating processes. Ch. III Equipment 122-141 Ch. IV Organization of Production 142-156 Purpose: The book is intended for engineers and technicians working In the field of electroplating J.~;vilities: Kiev Regional Division of the All-Union Scientific and Technical Society of Mechanical Engineers (VNITOMASH); Division of the Technology of Electrochemical Productions of the Order of Lenin Polytechnic. Kiev No. of Russian and Slavic References: 19 Russian Available: A.I.D., Library of Congress. 3/3 OONCHARICHKO, lonstantin SomenovIcht LIVITSK11- G.S., Inzhener, retsensent; LOOM, F.K.. insbaner. rodaktor; ib-HO-YE.-H.S.. redaktor; RUDINSKIT, Ya.V., tekbnIcheekly redaktor. [Con6ise electroplating manual) Kratkil spravochnik gallyanotakhniks. Kiev, Gos.nauchno-tekhn.Izd-vo ansh1nostrottellnol lit-rjr, 1955. 223 P- (Ilectroplating) INITSKIYO Geo%41., Sergeyevich; SXKMffUK, I.Me; S=YtM. T.K., Inshener, rT, T&J., takhatcheskiy redaktor. [Chrome plating of machine parts and tools] Khromirovante detalei mashin I instruments. Kiev, Goo. isd-vo machinostroitalluol lit-ry 1956. 265 p. (Chromium plating) (MLRA 9:55 AUTHD11BsDimbitskiy, I'.N. and LevitWAciyt Gf-Wo 97-5-8/13 TITM yrme'for tr&ngportimg large rel orde concrete panels on a lorry without trailer, (Ferma dlya perevozki krupmykh zhelezobetomWkh paneley na avtomashine bez pritsepa). PERIODICAL:."Beton i Zhelezobetoe (Concrete and Reinforced Concrete) 1957t -Nd.5t -.1p.213, tUOUIL), ABSTPACT: The-bize of the transported panels is 4.8 m (wide) x 6,P4 m (long)F. It was found impossible to transport them on oreL_ inary lorries, The use of trailers was found to be unsatis- factory. The illustrated construction solves this problem. It was designed by I.1f.Dimbitakiy of the Stalinskpromstroy faotori. It comprises an "LO-shaped frame with 2 inclined platforms pivoted onto the ends of the frame. These plat- forms are kept in the inclined position by 2 cables tightly stretched by a spring couplimg and screw. This construct- ion is mounted on the lorry chassis ZIL - 151 (3 W1 - 151). The weight of this construction is 500 kg. This lorry was tested by.transportinf; long reinforced concrete units weigh- jr 8 ing 4.5 t. of C.8 - 6.4 m length and of . m width. The tests were carried out on un onsolidated roads for 2 months, in double-shifts. The lorry proved to be satisfactory and Card 1/2 no breakage of panels occurred'. The advantage of arrange- LEVI i~ixi Y, i. I LL'VIT'--KIY, 1. 1. "Catalytic Dehydrogenation of Ethylcyclohe:(are andthe Ethylcyclohexane Fraction of Casolines of Direct Distillation." Sub 19 Jun 52, Inst of Orpnic Chemistry, Acad Sel USSR. (Dissertation for the Degree of Candidate in Chemical ScJences). SO: Vechernaya Moskva January-December 1952 by 'own Tbr *&ark b t" I:rT 34% %"1 IW44. PI.C at .v&. with 47% a catall-to 02 We 2-d pa-C ;Rml- od -P-'g 1.4479. dl wt with NA s"Inalic 4~apr&-- 0 thwatim 4 wutbm I AAAV w,.t warbs"Ir. ,.Ibr dw In- As"" Pvf 0 .0 the 36% -'JI*'7h"qj'w. with all, uJAMN V he "b jbq"AfIw.2"'I-" KOtIAIW- Zlb A)" A b Slor"BOW-271"" 0 of 310% t1opW diptil- Itic It. 12 9 6 deby. ,,go, am-- 11A) ps, V 1 49-,o. d WIL 6. IL-A ., ,,K,o, *Iding IS Y,,,.,;* b-M '11,zlc Irg"I Ibc hylbragrne .44 tcd 0v" -rbe ast'l only it 14% dM"w ill. -a 3 or laim Con evitaly-to at ,,1127 -340 110c"m in fww p kbytlt Icad I, Id tYAt IIW age" ba- 'wng) 0 lAffew NAVV Olly fconts. id Mot At""" dll., p. his cm Kt an t !csult. of i he i Abef cove. k 6 RIAS of bawre ""oft In no sawyda daily 00724we". N. 1. mansia am 1. 1. low. chem. Aftd. &J, DA.H.R. Moseriblill. . im GMM. Kilisla. Wasi fell, Muk-M.-The well. dwe in The catalytic delivilrogesswitirs" of Phyt. "ilk increasing d4". of I by imart ildesslaw to itut do roult of mouslary factors nick " MVVMWM of pairealm" or. " III Often wisitumict. doe to Ithartie Owton, but gueply this rinsalt ad dimplat"a"t of the @squil. Pbttt $it I + 11, In Savor oft. bro"ho about by bmt dils. Tbeprodof ihit III swipplissit by now espa. an a WD, catalysel (80 sull lit 678% allowing Am ille convei actually c4mft my t1= to opit. %kh mWild. Phill. pawail of differcut F-- "Wtin p from 4121 to 2-40 I.A. ftW"t/kr - (2-4 to 19,11 in* A. calm"Ar.). shir yWd lif catalistale Wveb of ta Allmust 96% Isom Almat p In 1.2 up, MW the Control of I in can tly tba Joan reach iWirwWromit oilvil. T= ii^ as the eqW. degr dehydre tim of Me Without ISOM.. tk 4141111. cu:f~x - 04M Ill. wbarr a - awn 11 forwasid in "in dithydrogestations of I Oak 1. K a OAW. .Theeklitelthosquill.oridile.wilbin It Its/swilmlilift kfim by the "litmO +Xic#+J;+ Kill)& - K(l + a " 40. Thin equation Iss" iftled upts, wilk lubts. phat + 14 cont%?D-90 am* exptJ. d~V of . ron, 0, 4ill 1608- " roinghty. % lislie" the caw. cum. TUW dim pmw i.altributed 90 & IVA . - of ills pely- wkb:tf I.. TIW vi" of I releli"t I" 111IM I'Aswil aft slightly litshill than villboat ~lldn. Kq thr rawtol Mrs. with a assilelol Alt It'"t dilwal/ ,a"&* pbul. able sallow. 00"4ka in JX + 1)4$ + xNe - x + I a it. Nitillo. wltb.'LV M mole St Astrr with I hi: wom 'Within 1.3re. clewly, The Okrvwti~ III *be vielill I fissitaightid.. ilk -,I isdue not to a wpgw~on llf issuleMIA14t situ Isal to a %bill .4 ills, Mud. in 1a"41 Ull"tisi, its tbr prtwmv of Ih. lm-iv"w#UAIbn " alwayv i1vt-l".j. it trutAul, &I-plust Owh4"Opl."'blis with N,, uwwS to mutitall misalwe"Italakm 4 The tilerts wif dda and 01 IbC 111CFFAVIll VWIJ- With wirearis amt. .4 St. l1w riefel a$ the rat.lymir Irons lot 9,, IL%% On sith 1110tir, list d-lerdmot-ul.as A* at ilmodiiiatlegivi.44ths %ills.5i, -lawtM f- I -W 1o4 1 bit 1, ...... it 0 li I'll%#, Ifts VA 0% 046tit. .4 'it PC. IwAr - latt 41w flilAl J.41- .14 lordws"iAlkAl %IV k'"VI I-T X.Ml I.", Ill.. liw A.1 higuir", I'libdi-l"ih Y IstAlugail"I I'l a 41,w, Ot alko -A lbrestalivi fly 1.011, *MI. .4 plim'. WA.My 4as I-emkillo. Obtse, wa till-w-th" 4w usidillerm, 41fluvot. Ifirlitirm" rAll W&CI 'wl lisidlus 1-4 0 h J 0 0 Amt 4:1 ll + It. -- CO +1- 1100, arol 1., 11111) * C - CID f I I@. At CqMA1 -kVV" 9-1 ddII I IIW VIN lit Ill I all h 110) UV it 4 go I),.% lbir YWLI with Clh, N. Than !7,MI-KTYt T.T. 0 " Thootetkal and experimental yklAo a 11111 to I tk It dtogination of a 9ft r du (13-8. dehydroptsation Of KIM over ~1-6340 and was contpared with the data by revious "ken cf. Wenner and Dybdal. C.A. 41,3722A Onth4tbasl%jthermadynamkd&fAtbetwU. dehydrogenation of RtPh can be n1d. The theoretical yield DIstyrene rlws from 8.7% at 4V' to 82.4% at 6274. Over an AKr-hfo catalyst the Yield actually rim lrozz:3.7% at 424* to 30.8% at 02TV. while the theoretical and the exptt. yields differ concipondinggI by t.9 and 21.6% under shese conditions. The activity an AIN catalyst remains low even at W'. but the resol(s obtelned alawst do not dif- fer from those obtained under simW conditions (&25-760) over an Al-Cr-Ifo, c*WysL Hipts. In which the equil. charatter has been established (cf. C.A. 46. 108181) show Independence of the actual leld of tyrene an the ; , velocityal the reaction numi-cf. ~;.&Z V.. C-4.42.37M. Tile deviation observed between the expd. and theotetical- yields can be directly ascribed to the loss of estalyzate caused by side reactions and cannot he ascribed merely to Lick of equ!~_ M. Kospla /V L 1,11:" q-t I;,,,I. J 3; 1 1 Y 4 1 it , ,mlt t'l!i It o w Ij i,; 2 1 03.111,14 LIVITSXIT, 1. 1.; SHUMN, N. 1. wwww"W""."W"M High temperature contaot-catalytto dehydrogenation of othyloyclohazans. Report no.2. Thersodynanic equilibrium of the dehydrogenation of ethyl bansone prodaced from sthyloyolohexAns. Izv.AN WSR Otd.khts.nank no.6:1012-1016 N-1) 1530 (nU 6s12) 1. Institut organichaskoy khisli Alcadexii nauk SSSR, (Dehydrogenation) (Ithyl bensene) (Cyclohazane) Specific chmirattEf Of actian of wplrr TIIPOr ta CAUI)-~C dehydio;ensition ol erhylb~enzene. J. 1. p~d N 1. * SlitilkiTi (logi Giri: Chem., Arnd,T~'T.77:~"b.R- Meyuow). t)'*L..iy -Ik~l vu-ab P 92 1W.3 d 'A 1 42 46 7 I;C Ith f- !-N~ 1--I :1--l-, 111L, .& Oaf't' ;I- th~ tiim vill, --kv, huf m-T 1- 1-- ad-ptiull -, ty f... 11-0 Etl'~'A!'o val r "IIIE's, ut 4YW )~tl 'n a lumok Ill ow.-~- ~A. 1--] 11,41 't th, K ta Vqvw -5(4),5(3) AUTHOR: Levitakly, 1. 1. BOV/62-59-3-7/37 ................ '. TITLE: 36me Regularities in the Yield of Olefins During Catalytic Aromatization of Paraffin Hydrocarbons (0 zakonomernostyakh v vykhodalh olefinov pri kataliticheokoy aromatizataii para- finovykh uglevodorodov) PERIODICAL: Izvestiya Akalemii nauk SSSR. Otdeleniye khimicheskikh nauk, 1959, Vr 3, Pp 425-432 (USSR) ABSTRACT: On the basin of the data given in reference 7 the equi- librium constants of the dehydrogenation of n-alk&neo and the corresponding yields of olefins were calculated (Table 1). It may be seen from them that the values of the equilibrium constants considerably increase on the transition of butenes to the corresponding pontenes, but loan on the transition of pentenes to hexenes. It is believed that the values of the equilibrium constants of the corresponding cis- and trans- hexenes will leas differ from those of cis- and trano-hoptenes. For this reason it was assumed in approximate calculations that the equilibrium constants of the dehydrDgenation of hexane and heptane to the corresponding hexenes and heptenes Card 1/3 are the name. On the basis of experimental data obtained by Some Regularities in the Tield of Olefins During sov/62-59-3-7/37 Catalytic Aromatization of Paraffin Hydrocarbons various authors by the catalytic aromatization of n-heptane (Refs Op9) the experimental values of the ratio PC7 H14 PH2 were compared with the equilibrium constants. PC7H16 From these data the yield of unchanged heptane and reaction products in mol% of the heptane transmitted and the ratio of partial pressure were computed (Table 2). It may be seen from this comparison that the degree of dehydrogenation of heptane to heptene is such a considerable one that the yield of the latter is not only determined by the rate of direct reaction but also by the rate of counter-reaction. The regularities known from publications in the yield of olefins during the catalytic aromatization of paraffin hydro-carbons may be derived from the thermodynamic calculations of the equilibrium yields of the olefins. These regularities may thus be due to the dependence of the olefin yield both on direct Card 2/3 and counter reaction. The modern concepts of the mechanism So~me Regularities in the Yield of Olefins During SOV/62-59-3-7/37 Catalytic Aromatization of Paraffin Hydrocarbons of catalytic aromatization of paraffin hydrocarbons were developed without considering the dependence of the yield on the rate of counterreaction (hydrogenation of olefina). For this reason these concepts ought'lto,be checked. There are 4 tables and 15 references, 8 of)wbl-h are Soviet. V, ASSOCIATIOV: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii nauk SSSR (institute of Organic Chemistry- imeni K. D. Zelin- skiy of the Academy of Sciences, USSR) SUBMITTED: July 21 1957 Card 3/3 5W SOV/62-59-4-7/42 AUTHORSi Gonikberg, M. G., Levitskiy, I. I., Kazanskiy, B. A. TITLE: Investigation of the Influence of the Hydrogen Pressure on the Rate of the Heterogeneous Catalytic Isomerization of Cyclohexane (Issledovaniye vliyaniya davleniya vodoroda na skorost' getero- genno-kataliticheakoy izomerizataii tsiklogeksana). Communica- tion i. Kinetics of the Isomerization of Cyclohexan( 0,Ter a Tungsten Sulfide Catalyst (Soobshcheniye 1. Kinotika izomerizatsii taiklogeksana na vollfram-sullfidnom katalizatore) PERIODICAL: Izveotiya Akademii nauk SSSR. Otdeleniye khimichaskikh nauk, 1959, Hr 4, pp 611-616 (USSR) ABSTRACT: In the present work the isomerization of cyclohexane and methyl cyclopentane on the induatrial W32 catalyst under hydrogen pree- sure has been investigated. The first series of experiments was conducted at a degree of dilution of 19-24 H2 ) and at (6 , C6H12 temperatures of 320 3400, 3700 420 and 8300 (Table 1). This Card 1/3 shows that the isomerization at ;20 and 340 becomes weaker sov/62-59-4-7/42) Investigation of the Influence of the Hydrogen Pressure on the Rate of the Heterogeneous Catalytic Isomerization of Cyclohexane. Co=munication 1. Kinetics of the Isomerization of Cyclohexan Ovmwa Tungsten Sulfide Catalyst when tpe total pressure is increased from 50 to 250 atmospheres At 370 othe yield of products changed only slightly. At 4000 and 430 the yields increased strongly. The selectivity of the process showed only a small change with temperature but decreae- ed upon an increase in pressure. To clarify the observed effect another series of experiments was conducted in which the action of the hydrogen and cyclohexane partial pressures on the con- version of cyclohexane waa oDeerved. 9esulto obtained during ex- periments carried out at 430u and 340 with conatant contact time, partial pressure, and cyclohexane feed rate but with dif- ferent hydrogen partial pres3ures are given in table 2. It is seen that the increase in hydrogen partial pressure has 8nly a small influence on the Intensity of isomerizBtion at 430 , where- as this intensity is strongly reduced at 340 - It has been found that the kinetic order of the reaction with cyclohexane in the range inve3tigated equals 0.4. Table 3 gives the result8 of the series of experiments conducted with cyclohexane at 340 and Card 2/3 constant hydrogen pressure. It has been found that the rate con- SOV/62-59-4-7/42 Investigation of the Influence of the Hydrogen Pressure on the Rate of the Heterogeneous Catalytic Isomerization of Cyclohexane. Communication 1. Kinetics of the Isomerization of Cyclohexane Over&Tungsten Sulfide Catalyst stant of the reaction at 430 0 does not depend on the hydrogen partial pressure. The intensification of the inomerizntion ob- Gerved at this temperature upon an increase in total pressure is due to the longer contact time. It has been found Thai the logarithm of the rate constant of the reaction at 340 decreases linearly upon an increase in hydrogen partial pressure. There are 2 figures, 3 tables, and 4 references, 3 of which are Soviet. ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii nauk SSSR (Institute of Organic Chemistry imeni N. D. Zelinskiy of the Academy of Sciences, USSR) SUBUITTED: July 2, 1957 Card 3/3 S/062/60/000/006/016/025/XX B02O/BO6O AUTHORS: Levitskiy, I. I., Gonikberg, M. G. TITLE: Study of the Effect of Hydrogen Pressure on the Rate of Heterogeneous Catalytic Isomerization of Cyclohexane. Communication 2. Dependence of the CyclohexanelIsomerization Rate on Partial Hydrogen Pressure, Temperatu e, and WS2 Grain Size PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk. 1960, No. 6, pp. 996-1000 TEXT: The authors' previous paper had brought the results of a study of isomerization of cyolohexane to methyl. cyclopentanelin the presence of WS2 in a continuous system under Eydrogen pressure. These results showed the effect of hydrogen pressure on the isomerization rate of cyclohexane to be dependent on temperature. Variations in the character of the dependence of the isomerization rate constant of cyclohexane on the partial hydrogen pressure at temperatures from 3200 to 4300C may be caused by the passage of reaction from the kinetic into the diffusion region, and this Card 1/4 Study of the Effect of Hydrogen Pressure 3/062/60/000/006/016/025/XX on the Rate of Heterogeneous Catalytic B020/BO60 Isomerization of Cyclohexane. Communication 2. Dependence of the Cyclohexane Isomerization Rate on Partial Hydrogen Pressure, Temperature, and WS2 Grain Size Ideration. The said is the problem studied in the artic~le under con94 passage can be established from variations of the apparent activation energy with temperature, and experiments were made to this effect at 3200, 3400, 3800, 4100, and 4300C, for different partial hydrogen pressures (Table 1).. Logarithms (log kpH2 ) of the rate constants are given as a function of the hydrcgen partial pressures (Fig. 1). The dependence of the logarithm of the reaction rate constant on temperature is shown in Fig. 2. The values of log k. from equation (1) log kpH2 - log k. - CPH2 where k0 is the value of the reaction rate constant extrapolated for PH2 - 0, and c is a temperatire-dependent empirical constant as well as the values for d from equation (2) of the reacticn rate k Pc.4 e**d PH are given in Table 2. Data on the effect cf the 0 C H 2' 6 12 Card 2/4 ~;' Y~' -.1; g7 Study of the Effect of Hydrogen Pressure S/062/60/000/006/016/025/XX on the Rate of Heterogeneous Catalytic B020/BO60 Isomerization of Cyclobexane. Communication 2 Dependence of the Cyclohexane-laomerization Rate on Partial Hydrogen Pressure, Temperature. and WS2 Grain Size catalyst grain size on -.yolohexane isomerizaticn at 3400 anJ 50 at. ` are indicated in Table 5. Constant3 a and b from the empir1ral eqliaticn (2)) k a i b.p-0-5 are given in Table 4, Results obtaired shcw that the PH H 2 2 reaction in the temperature range 3200 +c 390C takes place in the empirical region, and above 3800 passes over into the diffusion region. The apparent activation energy in the kinetic region amcuntq tc abcut 30 kcal/mole. The retardation of cyclohexane iaomerization with increasing partial hydrogen pressure is not due to diffusion factors but is characteristic of the kinetic region of the reaction course. Ye. A. Udalltsova, laboratory assiatant, and Yu. 1. Ry2hcv, mechanic, took part in the investigation. There are 3 figures, 4 tables, and 2 Soviet references. Card 3/4 Study of the Effect of Hydrogen Pressure S/062/60/000/006/016/025/XX on the Rate of Heterogeneous Catalytic B020/BO60 Isomerization of Cyclobexane. Communication 2. Dependence of the Cyclohexane Isomerization Rate on Partial Hydrogen Pressure. Temperature and WS2 Grain Size ASSOCIATION; In8titUt organichegkoy khimi! im. N. D. Zelinskogo Akademii nauk SSSR (institute of Organi,% Chemistry Iment N. D. Zelinakiy of the Academy of Soien-ces USSR) SUBMITTED; December 22, '958 Card 4/4 S/062/6O/OOO/OO7/OO9/O17/XX B004/BO64 AUTHORS: Gonikberg, M. G., and Levitskiy, I. I. TITLE: Study of the Influence of Hydrogen Pressure on the Rate of the fleterogeneous-catalytiA Isomerization of Cyclohexane. Communication 3. A;alysis of the Reasons for the Inhibition of Cyclohexane Isomerization Whon Increasing the Hydrogen Pressure PERIODICAL: Izvestiya Akademli nauk SSSR.. Otdolerive khimicheskikh nauk, 1960, No. 7, Pp. 1170 - 1177 TEXT: The study of the isomerization of cyclohexane to methyl cyclopentane in the presence of WS (Refs. 1.2) resulted in a 2 considerable reduction of the rate constant when increasing the partial pressure of H 2 from 50 to 250 atm, This effect bqcnmv smaller when the temperature was increased f1cm 320 0 to 3800C The authors aimed at finding the reanons for this effect and Card 1/4 Study of the Influence of Hydrogen S/06 60/000/007/009/0!7/XX Pressure on the Rate of the B004YBO64 Heterogeneous-catalytic Isomerization of Cyclohexane, Communication 3 Analysis of the Reasons for the Inhibition of Cyclohexane Isomerization When Increasing the Hydrogen Pressure made three assumptions for this purpose: 1) The adsorption equi- librium of cyclohexane is shifted under the action of the hydro- static pressure,, 2) Cyclohexane alsorptlon is reduced by covering the surface of the catalyst with adsorbod H 2' 3) Hydrogen exerts a specific influence upon the lacmerization process In the course of four test aeries at 3400 C with a hydrogen - nitrogen mixturt, zr pure hydrogen and pressures tetween 50 and 200 atm, it was found that at constant partial pro3sure of hydrcgen, the rate of isomer.,- zation is independent cf the total prosoure. Th-is, assumption 1) was disproved. The study of adoorpticn a9 n f~inctlon of tomperaturu and pressure showed the foll3wing result: there is nc basic difference between the adsorption of H 2 and of N2 between 3000 and 4000 C and 10 - 4000 atm. Thus, assumption 2) becare laiprobab.e Card 2/4 Study of the Influence of Hydrogen S1062 ,/60/000/007/009/017/XJr Pressure on the Rate of the B004/BO64 Heterogeneous-catalytic Isomerization. of Cyclohexane. Communication 3 Analysis of the Reasons for the Inhibition of Cyclohexane Isoirerization When Increasing the Hydrogen Pressure Therefore, the authors discussed the third assumption of a specific role of H 2' They assume three stages of the process: C H ___% C H + H H CH (b); 6 12r- 6 10 2 (a)' C6H1O__)C5 7 3 1 C H CH f H ----.C H CH (c). On the assumption of an equilibrium 5 7 3 2 1 5 9 3 in the stage (a) and an activating action of the adsorbed hydrogen, they arrive at the equation w - kKf( a , p/pO..5)pO-5 H2 C6H12 which gives a good representation of the experimental lata. w denotes the reaction rate, k the rate constant of the stage (b), K_ the Card 3/4 Study of the Influence of Hydrogen 3/062/60/000/007/009/0!7/XX Pressure on the Rate of the B004/Bo64 Heterogeneous-catalytic Isomerization of CyclohexanR. Communication 3, Analyols of the Rsajons for the Inhibition of Cyclohexane Isomerizaticn When Increasing 'he Hydrogen Pressure equilibrium constant of the stage (a), f, a proportionalIty soefficient a and P are empirical coefficients. The ratio a/0 could be datermine-i only approximatively. It was about O.-j at "COO C, and 0-2 at 4000C The authors mention I- R. Krichevskiy, R. S_ Kallvarskaya, M. I. Temkin, N. D. Zelinskiy, M, B. Turova-Polyak. and R~ D, Obolentsev. The laboratory assistant Ye. A, Udalltsova and the mechanic Yu., 1, Ryzhov took part, in the work- There are 2 figures, i table, and 18 references: 12 Soviet, 5. US, and I Fretirh. ASSOCIATION: Institut organichookoy khim:i im N. D. Zelinskogo Akademii nauk SSSR (Institute of Organic Chemistry imen N. D Zel,1,nsk!Y__ 11f +h4 Ae-Adamv mf S-lanrov nqqR) SUBMITTED: December 22, 1956 Ca-rd 4/4 T"p) T. X.. 1. 77- MNIQLIZALt A. 0' Zf, he V !Q. N- oI V4 ---qthYI-.h!*phenf O-~r ~00!'Vr-lro- b'I Do "r.llrjm ft%..ra-es fobs ~ It I rwot7. C.tslytt~ 'Ithij Inc to the of the e!hy 4"1.0 0 m t* mproselte.- t'y T :sz-4 -fwrw -he mmett~c atc~s Con '.&C' -.h t~%v atsyst -Ith*l the si,are. -.?,a "a' .on .!3 C,--. t '~tel fc. 2721in (at tt. S;*z* ~eioz ; 0 P-S..r* Im ;ms.n-t 0r -&.0r V;ro- &-I zur- an -0.1. az *, of tr.030 rolleitta -1 a r-lft~qr P-01.1~..- 6. ze-S.r 0-d 6'MIyx*.j by t~ro~cnetrtc tttrat-2-. a C-O~Ztttt-n for br~,Inat*n or the thiovw~t rrc; -:.,e sss*-~.S vroWcts. colloc%.i I~ a r'13-0ter. -ere bnal? Z. t?w or~sst arparaws. (74, I - , -); n; 1.51~0. d. !Jtmltt*A. ty Ye. L. 001.,ir e Beal rvs-'~ts -1 It -stre byz e.0ttcr, r "I C"14*0 , ",n, r the3v *,4 tne de- :, ! a. - ps,10,1 ti s'C ,. h7orwem. , t.h . '. 'a rlsa:-ons. So .Ch i's b"&~I'c oft or he sl--* chat, (ohly O~Z-0.'T : f ~satwrstoi hy4roiarb*nv m" de. ~Irel- rq r='I In Ire CASCO.3 Q cw-d 2/3 I T%q -1qd !'C-&D9 0.7 YI-MI.Oph-1. 0:1 cc2 e - *all =sx, - alt.. cgs I Ir. I., er-.ert~ r. . t e r.r~'O-u! - ire".~Irar th 8!1.0-. tnat 'lle- the :orj"1.10~% 0! .the 0"Vrl- ,enej- The~ a-* tables: and rIM; IS not W ne T.Cre~:Q. 1. t mcelt U.3. sn't U.K. - , - - " x. A=. czwm. soc., Tc. ;.,;"* 3ynlr,.:t%z X. T. 1~1 ~:954); W. S Zr~qrsc-: T X. Pat.--ic. 7h . -I -~)l - - 11~1;--rj 01?5~); Farto'e' I . i 3. ~ I ( 14 & rat :)Orl'att,ts Lon crn' Thtontene ond : AMSOCTATION- V~ D. !'Wt-te vf 0-Fl"T ("st" At zeltlskogo) 1/3 S/020/61/137/003/020/030 B103/B208 AUTHORS: Levitskiy, I. I. and Gonikberg, M. G. TITLE: Effect of oxygen and water on hydrogenation and isomerization activity of the tungsten - sulfide catalyst PERIODICAL: Doklady Akademii nauk SSSR, v. 137, no- 3, 1961, 09-611 TEXT: The objective of the present study is to explain the influence of a) oxygen- and b) water traces upon the activity of the industrial WS2 catalyst. For this purpose# the authors have studied (Ref. 2: Izv. AN SSSR, OKhN, 1959, 611) 1) the hydrogenation of benzene, and 2) the isomerization of oyolohexane under hydrogen pressure by applying the continuous method. They used commercial electrolytic K 2 with an 02 content up to 0,1% in unpurified state, or freed from 02 by means of granulated copper. All experiments were conducted on one single catalyst sample (28 g, 12 ml, grain size 3-5 mm, mixed with 60 ml 8orcelain scrap of equal size). Ad 1); Hydrogenation temperature was 310 C (according to Card 1/6 S/020/61/137/003/020/030 Effect of oxygen and water on ... B103/B208 ]'OCT (GOST) no. 3022-45), pressure 250 atm. Ad 2): The temperature was 3700C, the pressure 150 atm. Tables 1 (benzene hydrogenation) and 2 (cyclohexane i9omerization) present the results. The authors conclude from them that: A) the catalyst is considerably activated by using purified H2 in case 1); B) the effect of purified H2 is reverse in case 2), although not to such a high extent as in case 1); C) the above effect is reversible in both cases if purified and unpurified H2 are used alternately. Further experiments of the authors permit the assumption that the hydrogenation activity of the catalyst is not suppressed by the water formed from 02, but by 02 itself. Water, on the other hand, induced no change of the isomerization intensity of cyclohexane. The authors explain the results in case 1) as follbws: 1) The water possibly blocks the catalytic surface, in spite of its negligible concentration in H2. In this case, the adsorption of water had to be much grentor than that of benzenel 2) the semiconductor properties of W32 are changed by water which is known to have either acceptor or donor properties, Card 2/6 S/020/61/137/003/020/030 Effect of oxygen and water on B103/B208 depending on the kind of.adeorben.t. The authors believe that the con- centration of free electrons on the catalyst surface is reduced by adsorption of water, and the hydrogenation of benzene is thus retarded; 3) the inhibitory effect of,O2 is hardly,due,to surface blocking. The semiconductor properties of the catalyst are more likely to be changed by 02 which is knowt~to be an acceptor of free electrons on various semi- conductors; 4),H2 with traces,of water (or 02 which are-transformed to water),accelerates the reactions proceeding According to the ionic mechanism. The inoreaoing-aotivity of-isomerization-in calle 2) is thus ex~licabls. The authors conclude from their results.that reactions 1) and 2.),may be "regulated" with respect to the selectivity of the catalyst. They,assume that.this "regulation'l.may also be effective in the hydrogena- tion of other compounds on other sulfide catalysts. Ye. A. Udalltsova and,Yu* I. Ryzhov took part in this study. A piper by I. A. Makarov is mentioned. There.are 2 tables and 6 Soviet-bloc references. Card 3~16 3/020/61/137/003/020/030 Eff4dt of oxygen and water on *.1 Bl03/B2O8 ASSOCIATION. Institut organicheskoy khimii im. N.-D. Zelinskogo Akademii nauk SSSR (institute of Organic Chemistry imeni H. D. Zelin0kiy of the Academy of Sciences USSR) PRESENTED: November Ilt 1960, by B. A. Kazanakly, Academician SV~MITTED:- November 4, 1966 Card 4/6 UDALITSOVA, Xe*A.; GONIKBERG9 H*G. I- Production of pare cyclohexans by the catalytic hydrogenation of benzene containing thiophene. Zhur.jrikl.khim. 35 no.1:204-206 Ja 162. (MMA 15:1) 1. Institut organicheakoy I-himii imeni N.D.Ze:inalrogo AN SSSR. (Cyclohexan ) (Benzene) (*drogenation) LEVITSEn,.I.I.1 GONIUM, M.G.; KLMM, Kh.M.; KOADRATITEV, DJL Water promoted plati=-alumina catalyst, Report J1o*1: Hydrogenation of benzene, IzvoAX &1-3R.Otd.kWz.nauk no.7slI69- 1174 J1 '162. (KUU 15:7) Is In9titUt organicheskoy khimii im. N.D.Zelinskogo AN SSSR. (Benzene) (Hydrogenation) (Catalysts) IEVITSKIY. I.I.: GONIKBERG, M.G.; MINACHEV, Kh.M.; KONDRATIYEV, D.A. Water-J)romoted alumina-platinum catalysts. Report No.21 Dehydrogenation of cyclohexane. Izv.AN SSSR Otd.khin.nauk no-5098-801 My 163, OURA l6t8) 1. Institut organicheakoy khimii AN SSSR. (Cyclohexane) (Dehydrogenation) (Platinum catalysts) LEVITSKIY, I.I.; GORKBERG) M.G.; MINACHEV, Kh.M.; KONDRATIYEV, D.A. Effect of water on the activity of alumina-platinum catalysts with various metal content. Izv. AN SSSR. Ser. khim. no.Us 2065-2066 N 163. (MIRA 17:1) 1. Institut organicheskoy khimii imeni N.D. Zelinakogo AN SSSR. 4-1. 'j .13 -,"L' G(;NltilLil(i, M.:;.j MINACH?,V, Kh.m..; i3nG(jM(.w-,l,, v.i. Change of rut,~- an,! dli~- -'rn f-f Af -'!,, r the hJgh--tenprature h~drcgeri tririf.7ew. ~f an Dokl. AN SSSR 158 nn.'11-43123-IJ26 () 164. W-14 1-1:1u) 1. Inititut crganlchezkoy khlml' im. AN, ')L'.,R. PredsinvIeno akpdemikom B.A.Kazanskir.. LEVITSKIY,j,j~I.; UDALITSOVA, Ye.A.; BOGOMOD3V, 'I.I, Qhqnge in the fridrogenating and isomerIzIng activ!ty of --hXC=10 oxide in the pur-Ification of catalysts by removing oxygen and water. Izv.AII S,'SR.Ser.khIm. no.9:1691-1693 S 164. (MIRA 17:10) 1. Institut, organicheskoy khimii Im. N.D.Zelinskogo AN SSSR. LEVITSKIY , Ivan Ivanovichj kand. sel tkhoz. nauk; V.OROZOV, Lii--. , red. (Willow and its use; based on materials from Ue examina- tion and management of willow stands in the lower Volga) Iva i ee ispol'zovanie; po materialam obsledovaniia i le- soustroistva ivniakov Nizhnoi Volgi. Yoskva, Lasnain pro- nVshlennost', 1965. 97 p. (MIRA 18:9) LZVITSXIY, I.K. Preparations for the Sixth World Youth and Student Festival. Tekst. prow, 17 no.7:48-50 JI 157. (Km 100) (Youth-Congresses) (Textile fabrics) TWIMIROV, Boris Mikhaylovich, doktor takhn.nauk; J4jIZSXIT_,_j,X,,_jnzh.. reteenzent: STYATOSLAVOY, N.I., kand.takhn.nauk, retBenzent; KOPBLIVICH, Te.l.. red.; KOGAN, T.V., tekhn.red. [Aialyels of opention processes on opener-picker machines) Analiz proteessa na mashinakh razrykhlitallno-trapalinogo agre- gets* Moskva, Gosennuchno-takhn.izd-vo lit-ry po legkoi pro- mrshl., 1959. 175 P. (MIRA 12:10) (Cotton machinery) LEVITSKIY, I-N. mechanical drive for the RP-5 presser. Obm. takh. opyto CHIP] no.W18-21 156. (MIRA litio) (Textile machinery) LEVITSKIY, I.N. Form3tion of fiber windings on scutching drums. Izv. vys. ucheb. zav.; tekh. tekst. prom. no. 3:70-74 '58- (KIRA 11:7) 1. Kostromakiy taketil nyy Institut. iTextile machinery) Max) SUSLOV, Hikolay Nikolayevich; UTITSEIT. korl 111kolayevich; KAKETETA, Y.S,, red.; SEGAL', N.M., red.; ME .. ,-- Le.Taft-t ekhn. red. Clquipment assembly and repair in enterprises for the primary processing of bast fibers] Montash i remont oborudovanita zavodov pervichnoi obrabotki lubianykh volokon. Moskva, Gos. nauchno-takhn.izd-vo lit-ry po lagkoi promyshl., 1959* (Kfgl b!4) (Textile machinery) - LIVITSKIT, I.H. Selecting an efficinet method for fiber retrieval from the scutching tow in flax processing factories. Izv.vys.icheb.xav.; tekh.takst. prom. no.6:45-31 160. (MIRA 14i1) 1. Xostromskoy tekstillnoy Institut. (Flax) LVITSKIY I. N. as a is tent 11-~~~~ - Automatlc feeding of straw to Bteam-engine burners without the use of cyclones. Tekst.prom* ZO no-7170-72 Jl 6o. (MIRA 13:7) 1. Kostromakiy tekstilluyy lustitut. (Stokers, Mechanical) (Steam engines) LEVITSKIY,--I.N.,,_ assistent FeedIng of scutching whstes to the shaker vithout the um of cyclones. Tekot.prom. no.2:8-13 V 163. (MIRL 16:4) 1. Kafedra pervichnoy obrabotki1ubyavVkhvo1okon Kootrom8kogo tekhAplogicheakogo instituts. (Flax processing machinery) LINITSKIT, I.P. Now design for assambly-type bob Cutters. Avt. I trakt. prom. nn.6042-43 Ja 056. (MIJtA 9: 9) 1. Minskty avtosavod. (Milling) ___ImvITSKIT,_T.P_._, inihener. %"mom I-IMP "Utpawn"'d-aidisation of cutting tools. Kashinostrottell no.6-5-8 Je 157. (MM 10:?) (Outting tools--Standards) LBVITSKIY. 1.P., inzh. Gaugefor r-heckIM external screw thrends. Xash.Bel.. no.6tl7l-173 '5~,. (Screw threado-Measurement) (miRA 13:6) LEVITSKIY, I.P. I ~------- Machining cylinders of the dumping gear of a motortruck. Stan. i instr. 35 no.1:40-41 Ja 164. (MIRA 17:3) DOLZHANKOV, Andrey Timofeyevich. kandidat takhnichaskikh nauk; ZOLOTARRY, G.A., kandidat tokhnichaskikh nauk; LVITSKIT, I.S., karAidat takhnicheakikh nauk; SANIXOV, Y.M., kandMr-Tathnicheskikh nauk; PASTRTAKOVA, S.V., redaktor; FJDOTOVA. A.Y., tekhnichaskly redaktor [Repair work] Remontnoe delo. Moskva. Goo. izd-vo selkhoz. lit-ry, 1956. 559 p. (MLRA 9:9) (Machinery--Mintenance and repairs) DOLI,HHUKOV, Andrey Timofeyovich, dots,, kandetakhn.nauk; ZOIAYTAREV, G.A.# dots*, kand.tekhn.mauk; LEYIKOV, A.A., dote.imnd.tekhn.nauk; IXVITSKIY, I.S., dote., kand.takhatuauk; SANIZOV, Y.M., dote., Roziu. M.A., red.; SHLRUOV, A.G., red.; SOKOLOVA, 11.H.j tekhn.rede [Metal technology and repair work) Takhnologiis matallov I remontnoe delo. Moskva. Goo. i2d-vo sellkhoz. lit-ry, 1957. 542 p. (Metals) (MIRA 11:4) (Agricultural aschinery--Haintenence and repair) ABELVICHI A.A.j ARTEMIYEVt Yu.N.; VLASOV# A.P.1, GALIMINq A.S.; YE;VSIKOVp A.V.; IVANOV, G.P.; KOROLEV, N.1.1 LE _..__SITBK37-,-J-Z-;-JJVSHITS, L.G.; HELXOVv M.P.; NAZAROVj II.I.; NOVIKOVj M.P.; POPOV9 V.1a.1 TEPWVp A.G*j-, BAKHAR3Vq A.P.9 inzh.p retsonzent; SAVELOYEV# 79.7a., red. izd- va; MODEL', B.I., tekbn. red.; ELIKI09 V.D.t tekhn. red. [Technological aspects of the repair of crauler vehicles] Tekbnolo- giia remonta gusenichrWkh mashin. Moskva, Gos. naucbno-tekhn. Izd- vo mashinoetroit. lit-r7 1960. 466 p. (M IRA 14 t 7) (Crauler vehicles-44aintenance and repair) DOLZIMUKOV. A.T., kand.tekhn.nauk;..h~~I 5,,_kand.tekbnnauk; B" IKOT, T.M., kBnd.tekhn.nauk; ROSIN, M.A.. red.; IffWA* V*X*# tokhn.red. [Repair work) Remontnoo dolo. lxd.2., dop. i parer. Xoskys, Goo.izd-vo sellkhoz.lit-ry, 1960. 535 p. (MIRA 1423) (Agricultural machinery--Maintenance and repair) ASKIWAZI, Boris Moiseyevicb, kand. tekhn. nauk; LEVITSKIY,-I-S.p kand. tekhn. naukp retsenzent; HISHIN, I.A., kand. tekhn. nauk, retsen- zentj KOCHERGIN., K.A.p kand.tekhn. nauk, red.; KURKPIVA, G.N., red. izd-va; PETERSON., M.M.p tekhn. red. (Finishing of metal surfaces by heating] Chistovaia obraboUA po- verkbnostei metallov e podogrevam. Moskvap Gosonaucbno-tekbn*izd- vo mashinostroit.lit-r-y. 1961o 94 Ps (MIRA 14:12) (Metals-Finishing) (Surfaces (Techno:Logy)) LEVITSKIY9 Is set Doc TECH S I "METHODS of SOLVINO Qt- itia"Y USED IN AORICULTURE." NERAL PROBLEMS OF LENINGRAD-PU SHKINq 1961. (MIN OF AOR RSFSR9 LENINORAo AoR INST). (KL9 3-619 213) 164 IZVITSKIY, I.S.,__doktor tekhn.nauk Determination of average distances in transporting machin,3ry to repair stations. Mekh. i elek. sots. sellkhoz. 20 no.3:44-45 162, (MIRA 15:7) le Moskovskaya sel'skokhozyayatvennaya akademiya imoni KA, Timiryazavas (Agricultural machinery-Repairing) (Agricultural machinery-Transportation) KOLESNICHENKO, Vadilly Vasillyevich; YEFtOnEYEV, Petr Vasillyevich; LEVITSKIY I~S , doktor tekhn. nauk,, red.; MELINIKOVA, G.P,, red.; PERSON, M.N., tekhn. red. (Laboratory and practical work onthe fundamentals at repairing and the study of materials]Laboratorno-prekticheakie saniatila po oanovam, materialovedeniia I remontnogo dela. Pod red. I.S. Levitskogo. Moskva,, Proftekhizdat, 1962. 158 p. (MIRA 16:2) (Engineering laboratories) (Machinery-Maintenance and repair) OELI TAMN , A. 1 . p dokto,- It 3k ht,. nnuk, p.-ot'. ; -LLY 1TAi Y, do? tor tekhr. muk, pref, , rot sunzent; K~ N!~T , Yu..'.. . kand. ekon. nauk, retsenzent; Slilh-I N?,I D.E., pr~r., k zaal. deyatell riviki 1 tekhrd~l R-F:?, rinuchn. ree. [Fundamentals of the theory of the ri,jnr of' Osnovy teoril sta.-milq ot"shin. Monkva, lzri--vo "Lashino. U, ~ ~ 9troenic," IT,",. 403 1). ;..P, '. P: ,, ~ LEVITSY~T.j I-S- ard crgtinizatlw, (,f F Urals baLIXILe rAMO Gor.zhuro nc,.3:12-li duction at the Iforthc, (MI[I.A 1.8:5) Mr 165. 1, GlavnyY ekonomist Severourallikikh I-,oksitorjrkh rudnl~ovo ,-ICA c ~ i~ w lmpmd*wo of the "nount ot town &"mbod on thr olglitotodswbomt I r i 161 (;,Wk Kh rt,.v M,ar Uni, ), f,' task t A- 'I k. J9, It ILI., lik IT~ I ff"14 It u-I Arv CA 45. 4 I'd. R. I'1. s I-Otic in ~~7nt, r-, L-F,VITSKLY) I. Ya. r-,Ychanr"3 of ,~lltiple ratl7rVi . vestir.ation Dls~:ertat on* In- irharlko'lf 195" Cj (harlkov StLtc J) G,,,d Cher, o I ,10 54. N SO-. 3%~ 2841 26 'Nov 1954 c1chan ge of cnld-.~m. -l"fOrIS ':Ilbol:4 ~,~Wra!cfj to (of :?,%I rr ;!,.Rttvd V y the catim 1q, M1, Bu+ "for ~.'A+and K*~i,,tud;-.;lovi Wofatit.ll. Tl'+~ 'N'ONtit W.11 Witll A 11! CAU1, + Niself f-r MgCii + 17~Wlj, ;t.tshc4! frtt of Cl-, aml ncrc,-n,-d flamigh a 0,2-mm. !~Vc it "kere fl,n 'U"rrml ividl Iff) fill, "t rh~n (Ictil. by Ole 1!5~1.tl 1"th., 1"'. Tlv~ tvjlllts vicle f-aINI fly the Gapon erillatioll, Cle Vag"Icr clop;tical ,-quation, nad the l"'A"MV4 Nik,,V%kif e'lliation. All equa. tirms wrre foond applicible to the ,Ys1.ejn% M11-lied. In ~flmojt all C~L~!.% a, W419 c(loal to Off: 5-am of the !nax. Cfg- c-,padty obtaiacd for rach ii~-divid.;.,fl cation. In aN cilil.*; Mor %fai desorllc4 in n Fmallcr dci,.rte Ovin were Ca ;Md 11u. 11. Investi7ation of the ezrhango of Wit Mg + ~, and Da I , cn!lons from a mechanical inhavre and an adsurben- saturatti with each of th~sa lons riepmately for Ila * nud K * as aflected by the concentration of the NV I.,xing iorz. 1W. of Wofatit-11 'A(.,rc ~ ild. ~vwtratdy with Ca", Nix", fir l3q*1' and equal ~u'~mtWf:3 of each 2 ro~~rc mixeii tarcthtir. The mults were ii.-kigoup; to t1jo5c previatiFly quoted, but the following rjr(lvr oi dc3orption war, obtained: C-% > Mp > Mt. 6W ~ 2 d 4]FN -. . Re aud Al swoub-Ar or comb Ntd Willi 4awbent _i U- A-Ak4 c ( - ,,, t A-madw 1m-* 1 Vdtli 100 IW. of 03 N KCI (PHA.W-10.0(1) or Mr.- 'Cis (9,11 The pH was amttolkd by addivig HO, &Ud XOl~t*thMKCl DOID-AUd HCl to the MgC 41016. 10: 'equil. soIns, the pIT was lowered appreciAbly. A] and Fe I* samples of Oe equil. solne. wtm detd. by m~thotl%,- 'The ad-4arption cApacity for Fe was 103.0 and for At 64.3 Ing,eqmv./100 g. The drvjq)tiou of Fe iva3 40-00 &u4 of ~Albfj-70%. The actimrtiotm on Wof;%tit in the fl * and K * 1017-Mi WM PTaCtiCAM' Identical. The d6placcuient vI At unrl Fe dropped vvith incjeaiing pli of the XCI and Mg~lj solm. The dissiNcensvn tof Fe by K a sit! Nig was luclelmud- ,eat of the preittice of At on the adsorf-tnt. In all cuws rul -tactio betwrta the adstalicia a !Wl" ini d FX1 m -a r uc. t n . p. -tiars of Fc* Imounting Up to wasabur,m: If Ml! 6 'it ' I on m ti excliang tiff b " anti wofatite. A, allI I YR.-Tirildi[Vtte Univ. Kharkov). 0 jwr. -7- o 10, IT-1r,095.177-Whin aii milITITMIRr K contil. cptime B, C,' und 1) k eflitilibrattA w;Ill it soln. of a cation A. the equation - K(111c, e. Wds if thew cations an d6plitccd independently from vich other; rI. 171. and r, are the amtq. remaining III the eitchang", Cl. Cl. mAd it are the equil. voilctis., an(] 11m, I/m. and Ils are the villencies of 11. C, and D. rc., This cq1tatirm was cow5rmed by zquilibrating ",Oforaitn" cuntff. mf.. Ca. and Pe with KCI, AlgC1,, or AICI.; fit these exptq. the const. K wa4 OW245, O.Y)2_70, and 0.00128, resp. When "wofatites" contg. NII., Ca, anti Fe were treated with KCI, Mir". and A103, K waq 0.00139. OMIO, and 0.00081, resp; In all instances. pli of the equil. aoln. was Jess (e.g., 2.5'Instead 61 0) thitn'that of the Initial soln. The exchange capacities of the adsmimsts for all Ions In- !olvtd were dtid. J. J. Biltuman X'_ lld~l AX ImITSKIr, K.A.,jushener. The 12th plenary session of the International Rectrie&l* -3w4- ugertng Commission In Xoscow. 31laktrichestvo 8:91-92 157. - 4 %Rk lotg) 1, Ucheuyy nektrW' *Yetskogo komiteta Nezbdunarodnoy elsktrotekh- nicbmakey koulseli, ('Koscov--Blectrio anglueering-Congresses)