SCIENTIFIC ABSTRACT LEVICH, V.G. - LOVICH, V.G.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000929510016-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 16
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

UW %gineering -Wind waves
caw 1/1 Flub, 22 8/52
.Authors t Levichp V. G.
Title N
if-turhidence on the generation and damping of wind waves on
the surface of a liquid
Periodicalt Dok.:-AN &98R 101/40 615-618p Apr 1,1955
Abstract Amstiming that the wind velocity (U) is knownp a method is described for the
theoretical computation of the amplitude of wind waves on the surface of
a liquid. Conditions under which the turbulent movement of a liquid io
formed and the effect of this turbulent movement on the generation and
damping of the waves are discussed. Formulas, which allow the theoretical
figures-to be compared with the experimental data armresented. Eleven
references: 1 German, 3 English and 7 USSR (1925-19 Graph.
Institution Acad. of Sc., USSR, Institute Of Physical Chemistry
Presented byt Academician,M. A. Leontoiich, December 22$ 1954

Vim L"". DHay Akee. JJJ. A
09MI-TI104 AbMAS& Ia based as dw
!LM nowd tub pw" of tM dbpmW pUm, whicb
Its diffullm Coeif, The reduced viscosity lowers
*%htly the rate of coaguJadim. The effects are d1wumsed
C
if the enidopg an the vu der Weak forces. the Brownian
am= no., the pnotom of
::rot etc. 34 a..

/Y" I"
AUTHWs Leviah, V.G., Kyamlin, V.A. 76-11-11/35
TITLIs The Xotion of Xercury Drops in a Yield of Gravity and in a Xagastio
Field (Dvizheniye rtutmykh kapell v pole tyashesti I v magaitnom,
pole)
PERIODICALs Zhurnal Fisicheskoy Xhimii, 19579 Vol. 31, Nr 11. pp. 2453-2457 (USSR)
ABSTRACTt Here the motion of mercury drops in the electrolyte is investigated,
where the total system. is located in the field of gravity vA the mag-
netio field. The computation. which was carried out in a system in
which the drop was located, resulted in the followings Besides the
vertical fall in the field of gravity an additional motion of the drop
is created in a direction which in vertical to the field of gravity
an won as to the magnetic field. The value for the velocity of motion
is dbUined and its order of magnitude is evaluated. There Is i Slavic
reference.
Card 1/2

h'_ r1ft/O
20-3-23/52
ATTTHORSt Koutetskiy# Ya. Levich, V. G.
.TITLE# Use of a Rotating Disk-Electrode in the StWy of
Kinetic and Catalytic Processes in Electrochemistry (Primenoniye
vrashchayushchegoeya diskovogo eloktroda k izucheniyu kinctiches-
kilkh I kataliticheEkikh protsessov v elektrokhimii)
PAIMICAM Doklady All SSSR, 1957, Vol. 117, Er, 3o Pp. 441 - 444 (USSR)
ABSTRACTs The present paper shows that the rotating disk as a device for the
investigation of kinetic and catalytic currents offers considerable
advantages as against the droplet electrode. Unlike what is the
case with the simple electrode, processes on the rotating disk take
place during steady operation. It is just this that facilitates the
easy derivation of the formulae for the computation of complicated
cases of reactions. This is an essential condition for the study
of the velocities of kinetic reactions, Besideel the study of stea-
dy processes is also experimentally more simple, FInallyp it is
possibleg in the case of the disk, also to vary experimental con-
ditions considerably by modifying not aily the pH-value of the so-
lutions but also the rotation velocity of the disk. The authors do
not Intend here to deal with the entire manifold of the various
Card 1/3 kinetic and catalytic processes, but the present paper explains

20-3-23/52
Vae of a Rotating Disk-Electrode In t1w Sttdy of Matle wd
Odalytio Prooesses in Elea trochemi atry
the characteristic method for the solution of problems occurring
during the study of kinetic and catalytic processes on the basi3
of individual examplej. As a first example a kinetic quasi-steady
process is investigated, which develops in accordance with the
scheme k
A B (voluas ), A ---* C (electrode). The computation
is followed siep by step. In the second characteristic example the
volume reaction for the scheme 2A k B ij defined and io thus
ZLU
k2
of bimolecular character. There are 7 references# 4 of which are
Slavic.
Card 2/3

ft-3.23/52
Use of a Rotating Dink-Blootrode ft VID Btxft Of MINUO AM dtaiytiO
Processes in Electrochemistry
ASSOCIATIONs Institute for Physical Chemistry All USSR (Institut fiziebeekoi khi-
mii Akademli nauk SSSR)
Institute for Physical Chemistry of the Czechoslovakian AN
(Institut fizicheakoy khimii Chekhoulovatakoy Akadeaii nauk)
PRESENMI March 13# 1957f by A. H, Frumklnt Academician
SUBMITTEDs January 189 1957
AVAILABLEi Library of Congress
Card 3/3

IntyAlIOV, V.A., LIVICH, V.G.
Theory or%-.--.J'.ctrIc double layer at the bmwd"Y Of &
metal - electrolyte tnt*rf&cOo Nek.vop.ingh-fili. no.3:~-
27 '58- (Surface chemistry) (Illectrolytes) (MIEA 12:5)
1

LLMCH., V. G.; KREKEW., L. Ya.,* TAUEMMI A. B.; HATASSON) E. M.;
"The resistance of eimil ions and suspensions in cm-iection vith the stabilizing
action of structure-mechanical properties of protective surface layers,"
repcrt pre"atea at the Iow-th All-Unim Caawwma an Colloldal ChmIOU7.,
ThI11418 O*wgbn fWj 12-26 MW 1958 (Kall zbLzr 20,5, P.677-9. 158, Muibum, A.3)

AUTHORS:. Ivanov, Yue Bojlkni-~~~ 76-32-3-14/43
TITLE: The Convective Diffusion in a Binary Liquid System in
the Critical Region
(Konvektivnaya diffusiya v dvoynoy shidkoy sist*me v
kriticheskoy oblasti)
PERIODICALt Zhurnal Fisich koy Xhimiiq 1958, Vol. 32l Nr 3.
PP- 592-597 (U:SGR)
ABSTRAM Gibbs (ref 1) had already observed that the motive
force of the diffu on process represents the gradient
of the partial (oh:!ioal) potential. The vanishing of the
diffusion coefficient at the critical point in liquid
binary systems was for the first time observed by I. R.
Kriohetskiy et al (ref 2)~and (in the same laboratory) more
exactly . . by Yu. V. Tsekhanskays. (ref 3). In her
determinations the latter used a t6tkting Alsk- of compressed
terephthalic said, f6r Al&- the process of
solution was investigated triethylamine.
The results of the solution-velooity values of the rotating
disk at 2900 X Imeasured:snd calculated according to the
Card 1/3 formula for the diffusion current. obtained by Levichq are

The Convective Diffusion in a Binary Liquid System in the 76-32-3-14/43
Critical Region
graphically represented. It is found that the applied
formula and the theory of convective diffusion
respootivolyg are not to be applied to the critical region*
Them., -the' depiWasies- n of the diffusion coefficient znd*xf. the
solutidn on the., cozefttrafton - of rtft- dlrftstft *dbutwlie , *wt be
taken Jzbq ectoubt,
From the mathematical derivations
which were performed,, "Itfolaan Soong .0therw.-that, ~the
oalculaticns can be performed near the disk with the
application of the derivation according to larman. From a dia-
VM. SLVirg the theoretical and experimental*3 Iforf We dependence
the flow(;j) &tLthe..SdrfftCGfOZthG_djAk* on the solution
concentration o. where both values *;inoide vell, it follovs
that the obtained expression of the density of flow possesses
a general character for all solutions and ftr tbo'bk1tical
domain of oonoontrationp,where the fl6w of substance
possesses a low dependence on the concentration o and is
proportional to-V-W . The numerical value of the Soefficient'
and its dayentftnetft o0 are connected with some values of
Ca:rd 2/3 constants and can possess different values in different

The Convective Diffusion in a Binary Liquid Sys%,,!t kn the 76-32-3-14/4)
Critical Region
solutions. There are 4 figurei -aid 4 ruference3, ft of
which are Sovipf~
SUBMITTED: November 3, 1956
Card 3/3

AUTHORS: Xoutetskiyq Ya., Levich, V. G. SOV/76-32-7-17/45
TITLE: The Application of the Rotating Disk Electrode for the In-
vestigation of Kinetic and Catalytic Processes in !~lectro-
chemistry (Primenaniye vrashchayushchegoeya 4i"kovogo elektroda
k izucheniyu kineticheskikh J. katalitichookikh protsessov v
elektrokhimii)
ME IODICAL: Zhurnal fizicheskoy khimiij 1958# Volt 32, Nr 7, pp.1565-1575
(USSR)
ABSTRACT: The electrode reactions# the course of which is closely con-
neoted with chemical side reactions in the volume of the
solutionp have recently been investigated eyatematicelly. '-he
reactions may be divided into two groups: the so-callodkizedc re-
actions in which one of the products of the chemical reaction
in the inner volume of the solution diffuses to the electrode,
and enters into the electrode reaction; this can be represent-
ed by the scheme exchange electrode
nA k -4, mB 3 C
17 k
Card Ili 2

SOY/76-32-7-17/45
The Application of the Rotating Disk Electrode for the Investigation of
Kinetic and Catalytic Processes in Blectrochemiaty
The second group are the catalytic reactions in which the
substance participating in the electrode reaction is partly
regenerated in the exchange reaction into which products of
ths)slectron reaction enterl this taken place according to the
scheme: exchange electrode
nA + mB -+C C ---* I A
The Investigation& of these two types of reactions have hither-
to been carried out by means of the dropping mercury electrode,
it is, howeverg assumed that the method mentioned in the title
offers some advantages, as the processes take place within
th#teady regime; thus, calculation formulae fo4complicated
reactions may be obtained. On the other hand in the case of
disk electrodes besides the properties of thA eolutions also
the angular velocities of the rotation may be modified within
a wide interval, by which fact the experimental technique is
simplified, By means of some examples of kinetic and catalytic
processes the limit-diffusion currento at the surface of the
Card 2/4 disk electrode are calculated. A kinetic process of quasimo-

S011/76-11 2-7-17/45
The Application of the Rotating Disk Electrode for the Invcrtira-tion of
Kinetic and Catalytic &'rocesses in Electrochemistry
lecular character is investigated as first example as the
constants of the reaction velocity A -=-> B depeni on the con-
,PC
oentration of any of the substances Wbeing in the nolution.
The calculations were carried out for the case D / D 2 in
the convective diffusion according to L. R. B090LIZ01 they
are printed in the DAII USSR. A value 6 k of the thickness of
the layer of the solution at the electrole surface in ae-
termined in which the reaction takes place kinetically (not
in equilibrium). The authors mention the poper .7ritten by
Budovakiy (Ref 6) In which reactionn of biaoleculhr character
as well as catalytic reactions of a qua:~inolcculur ch,,racter
are described, There are 8 referoncee, 3 of which are ")ovlct.
ASSOCIATION: Akademiya nauk SSSII,Institut fizichoskuy khimii.,P1!oskva;-
Chekboslovatskaya Akademiya nouk IIr,3titL-t fizichaskoy khl-lii)
Praga
'r- gu5
(Moscow Institute of Physical Chemistry,.%S lJ3S?;- - -
Inatitua of Physical Chemi3try of the Czechoslovakian Aca-
Card 3/)r demy of sciences)