SCIENTIFIC ABSTRACT LARIKOV, YE.I. - LARIN, B.A.

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CIA-RDP86-00513R000928630010-2
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December 31, 1967
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SCIENTIFIC ABSTRACT
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ANTIPINP L,Mo; ZHIGACHj A.F.; LARIKOVO Ye.l., POPOVO A.F. Direct single-stage oyntbesis of triisobutylaluminum. Khim. prom. noo2:97-100 F f63, (MIRA 16:7) (AMuminum. organic compounds) 1ARIKOV, Ye. I.; ZHIGACH, A. F.; POPOV, A. F.; KULIKOVSKAYA, T. N.; I ---VWr-PM-YA . N. V. - Thermal decomposition of aluminum alkyls. nim prom no. 3: 171-174 Mr 164. (MIRA 17:5) SAKHAROVSKAYA, G.B.; KORNEYEV, N.N.; POPOV, A.F.; LARIKOV, Ye.I.; ZHIGACH, A.F. Reaction of trialkylaluminum with water. Zhur. ob. khim. 34 no.10: 3435-3438 0 164. (MIRA 17:11) 87 01- IRi UR/OD64/65,/000/0014/00WO015 66'1.786*21s547*356.21313*b-12,V:66.091 AM -h; 1. M.) Zhigachi 3A Larikovj' To! I Pop ~,A ~F. UT &i of tlrii aluminum sobutyl -XI proiz~phle;3n6Btf, no, 4-,:-:* 31~. 44-c 6s k-aya talic U41tiofi` 441ation organic synthenis -:-.TO -me i - orgam COM&Uild), bye -:'MMRLCT'i-" -The-*- iisobutylaluninum -is complex, slowing -conversion of alindnam in tr ~-dowrI r-a.ft-er- 2-3 -hours -treatment because of oxide coating. This conversion of ~activated by different methods was examined. Wo induction period, char- eteristic of single-stage uymthesis, vas observed in any of the experimenits. a rate of hydration increased with rise in temperature. At 150C the a1wrdrurna had ur reacted: completely in 3-5 hours. Further heating at that ter~perat e led to uer- in content of alwainum bound in the reaction products and to an increa5e of aluminum iii i'dbutane. This is due to thermaill decomposition of diisobutylaluminam hy&-idef Such decomposition my be suppressed by adding isotru!IleneAo the reacting roasso Wealiaents show that the conversion of alwdx= indiisobutyl- a, Uwam bydride takes place much more rapidly than the single-stage syntbasiB um 4 -I - I -1 -, 10 m. --,, ~-- M: - .. ~ JD -ACCESSION.-YM APS021971 0286/68/000/014/0023/0023 ~669771.--547.419.6 AVniOR'.,'_-:~Zh r- P - 0v A_J'.~, S11 vestrovi",T) Arono,4, M. I.; Larikov, ~ q azarov, - S. Y -W Xorneyev4. 11. 5 _77 77: 1~_Yljj_5 Class 12, No'. i'M80 ' SO,URCE.~,,-.:, .,-~'By.~in6-t,in'.~izobrete~liy .i~-tovarpykb, znaXov,--no. 14 1965, 23 _.~a_iuminum;,'ID er- metal-ftpro uctl'o d t, altuninwn powder TOftb- --JKdS owd- n-,-_pow er.me aiiuam -7-7_7 ARSTRA&,- -This Author's Certificate introduces a metbc5d for activating ayluminum by Pul-i-drizing. it in a cavitation mill with a shielded electric drive. The method is 5#jplified, ding the aluminim for 3-10 hours until the particle size is T $UBMITTED ~.OF661 SUB'COM HP , . ~ , OTHER.": 060 VOLIPIN, M.Ye.; ILATOVSKAYA, M.A.; _IAUKQV,. _~e.. I.q KHIDEKELI, M.L.; SHVEIISOV, Yu.A.; SHUR, V.B. Nitrogen fixation on hydrogen-activating transition metal complexes. Dokl. AN SSSR 164 no.2:331-333 S 165. (MIRA 1. Institut elementoorganicheskikh soyedineniy AN Institut khimicheskoy fiziki AN SSSR. SubmitteL 15, 1965. 18:9) SSSR i February t 02')9'~ 67 *:-w1v,,) /M NRI AR6033145 SOURCE CODE: UR /0064/66/000/010/0020/0022 AUTHOR: Bezukh, Ye. P.; Zhigach, A. F.; Larikov, Ye. I.; Popov, A. F. bRG: none~ TITLE: Synthe~;is of methyialuminum sesquichlorid~_ and trimethylaluminum SOURCE: Khimicheskaya promyshlennost', no. lo, 1966, 7hO-7h2 B TOPIC TAGS: methylaluninum sesquioxide, trimetbyl aluminum, synthesis, propellant) 01-0J77.-A.~0M Qornppo'uo' ONZ-OR10F ABSTRACT: Direct one-step preparative methods for nethylaluminum sesquichloride,(a mixture of Al(CH3),C1 and AlCH3Cl,) and trimethylaluminum are described. Methyl- aluminum sesquichloride was synthesized in a sealed reactor (Popov, A. F. and K. N. Korneyev, Author Certificate 168691. 1962, Byul. izobr, no. 5, 1965) from iodine- activated PA-4 aluminum powder or ASD-T aluminum powder and metbyl chloride in cyclobexane solution at a 2/3/4.65 constant initial molar ratio. The optimum prepara- tive conditions were determined (see Table 1) to be 50-70C for 6-7 hr. The process was tested on a previously developed continuous reactor for ethylaluminum sesquioxide (Zhigach, A. F., A. F. Popov, and Ye. P. Bezukh Byulleten' tekhn.-ekonom. informats' GOSINTI, v. 2, 1962, p. 39). TtLimethylaluminum was synthesized as follows: I I 2A1 + 3Mg + 6CH3C1 -.,, 2Al(CH3)3 + '3MgCl2 from AST-D aluminum powder PMr-4 magnesium -J~ TjP~ Card 1/3 1 UDC:___ 47.256.2 AR6033145 Card Table. 1. Effect of temperature and reaction time on the methylaluminum sesc UjQXJ At yield anjO-, reaction ate 4; Compa3iticn of )verall Average Reaction the reaction ield of reaction.. time 4~ 0 cts produ z eactions , rate 0 , ased on P, Alt 1 Aal C IURF, Al, hr) E- 1 ASD-T aluminum powde r 20 30 51,2 48.7 15,9 0,004 20 50 54,2 45,8 6r,. 5 0,0166 20 60 54 ~ 8 45.2 99,0 0.0247 20 70 , 54,8 45 99,1 0,0246 20 go !0,0 50:0 99.5 0.0248 20 110 46.0 54 0 95.0 0,0238 20 130 29.0 71:0 65,0 0.0163 70 140 0 0 90.0 45,0 0,0113 20 150 8:0 92.0 : 22,0 0,0055 2,5 55 8,0 52,0 39,2 0,078 5 55 48,9 " " 76,5 0.066 6 55 50,4 49,6 97,3 0.081 to 55 50.0 50,0 99,0 0,046 1.5 55 50,5 49,5 98,1 0,033 20 55 49.8 50,2 98,0 0,024 PA-4 aluminum powder 70 70 - .' 7 0 ~ O. 1 47 1 5 - 1~.O 0 1 0.071 7 7D 0 0 0, , ~ . ~ 88.0 0.062 10 70 8-9 0 0,044 LAA 2J94~7 AR 3jj4 5 and methyl chloride in cyclohexane solution at a constant 2/3/6/3 initial molar ratio. The optimum preparative conditions were determined (see Table 2) to be 120C for 5 hr. Table 2. Effect of temperature on trimethy3ELluminum yield and reaction rate (Reaction time, 5 br) Composition of the Overall Average yield of reaction reaction products reaction rate, 00 products mol/(g- R Al(CH3)3 Al(Clik based or atom-hr) O P4 Al, % -100 68 6 31,4 83 2 167 1,1 0 :105 67:8 32 2 .86:5 0 173 : 72 7. 27:3 97,5 0 195- '-' 130 69:5 30,5* a5,0 0:170 ' . 150 65,8.' 34.2 47.S 0,095 The drop of Al(CH3)3 yield and reactIon rate at higher temperatures was explained as its t-hermal decoMpgaitiQn catalyzed by titanium contaminating the aluminum. Orig. art. has: 2 tables. SUB CODE: 07, 19/ SUBM DATE: none/ ORIG REF: 006/ OTH REF: 030/ ATD PRESS: 5099 awm ACC NR, W6035823 SOURCE CODE: URIO'4-fiiaiObO'10'20~OD~616630~~ (N) INVENTOR: Antipin. L. M.; 2~ondarevskaya, L. B.; Vladytakayat N. V,; Danilovs S, I.; V;iigaach, A. F.; Larikov, Ye. I.; Snyakin, A. ORG: none 1 TITLE: Method of synthesizing lithium-aluminum hydride. Class 12, ',.a. 186983 SOU'RCE: 1--obrateniy4. promyshlenyye obrAztsy, tovarnyyc znaki, no. 20, 1966, 30 I'TOPtC TAGS: lithium aluminum hydride, chemical synthesis ',BS- IRACT: This Author Certificate introduces a method of synthesizing lithium- rluzniaum hydride by a reaction of sodlum-aluminum hydride with lithium chloride in die:hyl eter. To accelerate the process, it,is carried out with additions of aluminum trialkyls. In a variant of*the synthesizing process, aluminum- trialkyls are added in a quantity of 1-7%. SUB CODE- ' 07 SUBM DATE: .220ct64/ Card i /i UDC; 661.968.546'621'34'11 IARIKOV, Yu.11. , inzh. Reduction of copper-oxide rectifiers. Avtom. telem. i sviaz' 2 no.12:34 D '58. (HIRA 11:12) I.Kzyl-Ordinakoy distantaii signalizatoii i ovyazi Kazakhokoy dorogi. (Electric current rectifiers) LUSKINA, B.M.; SYAVTSILLO, S.V.;.LARIKOVA, G.G. ------- Determination of titanium and aluminum in triethylaluminum production wastes. Plast.massy no-3:16-L8 162. (MIRA 15:4) (Titanium-Analysis) (Aluminum-Analysis) LUSKINA, B.M.; SYAVTSIIW, S.V.; BEREZOVSKAYA, B.Ye.; IARIKOVA., G.G. Analysis of waste waters from the manufacture of organosillcon products. Plast.massy no.5s6l-62 163. (MIRA 16:6) ('Oewage-Analysis) (Silicon organic conpounds) SHTiFMAN, L.M.; SYAVTSILLO, S.V.; LAUKOVAq G.G. Determination of the content of tri"~ aluminum. and diallyl aluminum *dride by the electromatric, method.' .rudy Kom.anal.khim. 13: 325-330 163. (MRA 16-.5) (Abiminum compounds) (Electrochemical analysis) TERENTIYE;V., A.P.;-- KOVA, G.G.; BONDAREVSKAYA, Ye.A. UBe of aluminum lithium bydride in analysis. Report ND.13 Determination of active hydrogen in organic substances in ethyl other solutions. Zhur.anal.kbim. 18 no.4:511e4519 Ap 163. (MMA l6s6) 1. H.V.LomDnoBov Mscaw State University. a (Organic, coupoundB) (Hydrogen-An lysis) I (Aluminum lithium hydride .L U689-~66 WT(m)/EWP(t)/B0(b) IJP_(c.) JD -ACC - NR.' AP6005878 SOURCE CODE: LIR/0075/65/020/010/1054/1058 -Ye. A.; FYA41dlo, G. Ye. -AUFHOR:: Terentlyev, A. P.; Larikova,.Go G.; BondarevskaVa. ORG: Moscow State University in.'M. V. Lcmonosov (Moskovskiy gosudarstvennyy uni- -,';TITIX: Lithium aluminum n analysis. Report No~ 2. Determination of 4V_ k i -dell Aithium aluminum hydride content -'Zhurnal analiticheskay kbimii, V. 20, no., 10, 1965,~1054-1058 ~TOPIC.TAGS: hydride, lithium compound, aluminum compound, volumetric analysis 'ABSTRACT:~~Apreviously described technique for determining active hydrogen in or- _'ganic substances by,means of LiAlH4 wasused to check the lithium aluminum hydride of ethdr solutions and the composition of solid LiAlH4. A weighed sample -was -decpmposed with,ethyl alcohol, and the hydrogen evolved wasdriven with the vap- ,..-,Or of the boiling ether into an azotometer filled with a 1:1 water-ethanol mixture, wbich absorbed the ether.- vappr.'j!rom the. azotometer, the hydrogen was transferred nto ia, eudiometer for volume.measurement. Analysis of three samples of 100% LiAlH4 1/2 DAYMAMV, A.Tu.;. VZUM, B.F.; LARIJOVA. M.G.; DMITRIYWA. N.K. - __ Refining tin from admixtures by the metbod of zonal smelting. TSvet. met. 29 no-8:51-58 Ag 156. (MLRA 9:10) (Tin--Metallurgy,) YEGOROV, M.N.; 1ARIEDVA, V.I. Complex inflation method of gastric function test in certain gastro- Intestinal diseases. Ter. arkh., Moskva 24 no.1:22-36 Jan-Feb 52. (CLML 21:4) 1. Professor for Yegorov. 2. Of the Therapeutic Sanitary Administration of the Kremlin (Head-F.I. Yegorov, Corresponding Member of the Academy of Medical Sciences USSR). tol-kcat V.I. TWOROT9 MoNoo-profeBsor; LARIKOVA, V.I. (Moskva) Vee of various anticoagalants in z7ocardial Infarction and in stenocarais. Klin. med-i 32 no.5*-45-51 )V 154. NWA 7:7) (A]~GINA PECTORIS, therapy, ~ *iLaticoagulants) (MYOCARDIAL IWARGT, therapy, *anticoagalants) (ANTICOAGUIAMS, therapeutic use, *angina pectorle & nvocarial Infaret) WLGAMA/Sol.id State Physics Mechanical Properties of Crystals B-10 and PolycrystallIne Substances Abs Ref Zhur - Fftikap No 5. 1958, iio m45 Author Larikow L. inst !~fia 'Uhiversity, Sofia., Bulgaria Title On the Problem of Anomalous Softening of Lead-Tin Alloys at Room Temperature Or1g Pub :,-DDk1. Bolgo :AN,, 1957., 10, No 1, 65-68 Abstract An investigation ims made of the change in hardness in natural aging of lead-tin alloys containing one to 19% tin. It was established that there exists an initial aging stage in which the gmitur the percentagd of tin~.1he faster the increase in hardness. By fixation of the state reached at room tempera- ture through rapid quenching to -600C.. it was possible to show the presence of an initial strengthening in natural agirg even, in alloys with 15 to 19% tin. r(banks to the rapid aging in the initial stage at room temperature, this strengthening has previously escaped observation. An explanation is offer- ed for the considerable discrepancy between the literature Card 1/2 BULGARWSolid State Physics - Phase Transitions in Solids E-6 Abs Jbur, Ref Zhur Fizikap No 5., 1958., No 10638 Author Iarikow L. Inst Sofia University, Sofia., Bulgaria Title Mechanism of Natuxul Aging of Lead-Tin Alloys Orig Pub DDkl. Bolg. AN., 1957.- 10, No 11 69-72 Abstract The course of the process of aging of lead-tin alloys is divided Into four stages: 1. The latent period., character- ized only by a slight reduction in the electric resistivity. 2. The period of spontaneous decay of the solid solution;- characterized by a fast increase in the hardness.. a sharp decrease in the electric resistivity,, and a change in the lat- tice parameter in accordance with the abheme of the heterophase decay. -3. The period of coagulation of the new phase in the relaxation of the principal phase in the lattice, a phase characterized by simultaneous rather weak decrease of both the hardness and electric resistivity with the lattice para- meter remaining constant. 4. A period of recrystallization in softening; during this period the drop in hardness and Card 1/2 LARILOVA, E. and PARFENOVA E. - U.B.S.S. "Les transformations gdochimiques de certains 616ments de la nature" report submitted for the 6th T-ntl. Congress of ;'joil Science, ..Paris, FralICE 28 August 1956 LARIN, A., kandidat kbimichookikh nauk. ~!-,s ~~,, Nei detergents. Prom.koop. no.1*25-26 A '57. (MIRA 10:4) (Washing powdero~ IARIN A "First photographys of the other side of the moon." Rovirvwj by A.Tarin. Sov.foto 20 no.1:22 Ja 160. (mm 13:5) (Iunar probes) (moon-Photograpbs,-Maps, el.-,c.) LARIN, A.; PLOTNIYOV, A. Letters to the editor. Voen. znan. 37 no.12:20 D 161. (MIRA 14:11) 1. Predsedatell Kominternovskogo raykoma Dobrovollnogo obshchestva sodeystviya armii, aviatsii i flotu, g. Voronezh (for Larin). 2. Starshiy instruktor oblastnogo komiteta Dobrovollnogo obshobestva sodeystviya armii, aviatsii i flotu, g. Kuybyshev (for Plotnikov). (Voronezh--Military education) (Kuybyshev--MUitary education) LARIN .., -, z ~~ i - Road to the world of beauty. Prof.-tekh. obr. 20 no.5-.6-7 Itr '-63. (MIRA 16.7) 1. Direktor bobruyskogo pr-~)fessional,"no-tekhniehoskogo uchilishcha No.15, Belorusekaya SSR. (AesthetiGS ... Study and teaching) i- '. 14(5) sav193-58-12-9116 AUTHOR: Shekhtm6n, Yu.M., Khranov, I.F., and Tarln A.A. T=: Filtration in the Surrounding Zorte of the Well During the Hydraulic Frac- turning or Formations (Filltratsiya v prizaboynoy zone skvazhiny pri gidrarlicheskam razryve plasta) PERIODICAL: Neftywoye khoryWtvo, 1958, Nr 12, Pp 40-45 (USSR') ABSTBPXT: Yu. M.-Shekhtman. (Ref 1) presented a method for calculating the fluid in- flux.into'a sand-filled-vertical fracture. The present article aims to verify and Improve this method of calculation so as to facilitate its practical iLpp1Ic&tion,- The authors take's. vertical fr,acture vhich is symmetrically located in relation to the well and apply to it Shekhtman's formula,for.the condition at the end of the fracture. Assuming that a -c and b = c they present the formula as follows -9 2 yydx + q -c) ( -c _4x 40, y 0), -Vx 2 q(c) (0 < x