SCIENTIFIC ABSTRACT KUZNETSOVA, A. G. - KUZNETSOVA, A. K.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000928220002-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 20, 2000
• Sequence Number: 2
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

ACCESSION NR: AP4018057
C113 pla
ople
\0-C_C=C_$lCll'Cl
[is
1-chlomethyldi~nothylsilioon-3-mothylbutin4-l-ol-3 and 1-ohlormethyl-
dimethylsilicon- rnethylpentine-1-01-3 are'described f~or the first
t
time. n.-butyl ~l-chlormethyldimethylsilicon-3-methylbutine-1) ace
is obtained and determined* Orig. art. has: 2 tab.les.
ASSOCIATION: Institut neftekhimicheskikh protsessov Akademii nauk
Azerbaydzhanskoy SSR (Institute of Petrochemioal Processes, Academy oif
Sciences, Azerbaidzhan SSR)
.SUBMITTED: 25Dec62 DATE ACQ: JqM%r64 ENCL; 00
-SUB CODE: CH NO REP SOV: 005 OTHER: 010
C&431~
,----------------------

SIN, ~;HJNUN, G.14.; KIZIETS)OVA, A.G.
-ow-~
Continuous method of the reduction of cuprous chloride baby,- metal-
lic copper. Trudy MITI no.47-.103-1-10 'U,.
Solubility of copper monoch-loride In aqueous solutions of NaCl,
NaC1 -j CuC12 and NaCl + Na2SO4. lbid.:1.11-114 (IMPLA 18:9)

E-W(MVENP(j) RM
Aee'NR' A?6000992 SOURCE 001EX UR/M86/65/000/022/0061/0061
r- Zr-
el, '/) Z) :D SS
AUTHORS: Kusnotmovap A. G.; Ivanov, V. 1. 55
lea.
ORG I none
TITIZ: A method for obtaining polymethylphenyl siloxanes,~ Class 39# No,, 176419
SOURGEt Byullaten' izobrateniy i toyarnykh znakovp no. 22, 19650 61
TOPIC TAGSs polymero siloxaneo hydrolysis
ABSTRACT: This Author Certificate presents a method for obtaining polymethylphanyl
siloxanes by co-bydrolyzing with unter a mixture of organochlorosilaned at a tempera-
ture of 50--60ro To simplify the process# 65-80 parts (by weight) or water are
taken per hundred weight parts of the organoahlorosilane mixture.
SUB COM, n/ SUBM UTEs 04Apr63
V-)
UIDC t 678.

YI-1-140ro"I'DVAp Yf,.Lel A.G,
"rcr J."
I aratLon of boric acid trf clil^lrlc acid: It-,!I r
'~ 9 1 0
Uvratoo. Zhur.-,xild.khivio 38 vo,31:2403-240,; 1-1 165,
(MEU 18%12)
Jo hvikovakiy 'eh!.cji),o-tekhnologicheskiy inatitu. li.1,
Mend"loyevas FulmittAd October 17, 1963,

EWP(J)/EWT(m)/r IJP(0
L 20809-M
ACC M AP6005948 (A) SOME CODE1 UR/Olgl/66/000/002/0015Ad
AUTHORt Kuznets=,,..Aj.,q.
ORGt none
Sol oc"ording to the
TITLEs Study of the composition of polymethYlPh9'Wl0il0xBn a
particle size,.
SOURCE$ plagticheskiye massy,, no. 2, 1966, 15-19
TOPIC TAGSs siloxane. condensation reaction, catalytic polymerization g silanev
sulfuric acidt polymer, fractional distillation
ABSTRACTs Composition of polymethylphow1lailoxanes M obtained by hydrolytic
condensation of trimetbylablorosilane (II) and methylpheny1dichloroallan (111)
according to the Scheme.,-
2(C11,),S1C1+na1"4,S1Cj,+
-~MWIOPWUSIO)A(Clls), + 2(n + J)HC1 (1)
(n I)V4Q7
(2)
has been Investigated, Samples of Ip obtained with ratios of MIN 201
--Card- 1A UDO

L 20809-66
ACO NRs AF6005948
2:5; 2:7; 2t91 and 2:1 by hy&o3,ytio condensation only (method 1) and by hy-
drolytic condennation followed by troatmant with.nulfuric acid (method 2), were
fractionally distilled (up 'to 250C/1--22 mm), and the residues were fractionated
by reprecipitation. Molecular weight distribution curves were plotted from the
molecular weights of each fraction. The results indicated that the content of
polymers of low molecular weight decreasen with increased amount of III. Products
obtained by method 1 were considerably more dispersed than those yieldad by zeth&
2. Apparently sulfurio acid acts as: a) a dehydrating agent facilitating the
condensation reaction and formation of high molecular weight products$ b) a
catalyst inducing regrouping of high molecular woight'I and leading to a balaiwed
distribution of polymers according to molecular weight#' Orig. art. has$ 4
tables, 5 figures, and I equation*
SUB COM SUBM DAM' none/ ORIG REF 1 002
Oard 2/2'.
Now

Ewr /TjE__W
-ACC-Nti-AP-6030848 A,N) SOURCE CODEt IM/0191/66/000/009/0022/0024
AUTHOR: Kuznetsovat As G.1 Ivanov, V. 1.
ORM. none _X
TITLE: _Hydrochloric acid-induced catalytic rearrangement of polymethylphenylfjiloxanle I
SDURCE: Plasticheakiye !Jasy, no. 9, 1966, 22-24
TOPIC TAGS: silicone, silicone lubricant , Lllfr4j_lr~SYS , IWOROCHA.OjelC IfL710
ABSTRACT: A study has been made of the feasibility of using HM as the catalyst in
the catalytic rearrangement of polymethylphonylelloxane liquid polyTers. q1t in noted
that catalytic rearrangement is used to ensure a more unifo ompoaltiod 0
and to Improve its physico-chemical propertieWhhe use of"HCel, which is formed in
the hydrolytic condensation of the organoERTo-rosilanes, in lieu of H2904 would 0imp'
the preparative method by making hydrolytic condensation and catalytic rearrangement
r a
a one-step operation. The experiment involved catalytic rearrangement in thep esencp
of 35% HM or 75Z H2SO4, and comparison of the catalytic-rearrangement products with
one another and with the hydrolytic-condensation product. The criteria used in the
comparison were the silicon-content, refractive-index, viscosity, and moleculat-weight
distributions, It was found'that HU was an suitable a rearrangement catalyst as
H2SO4- Orig. art. has: 5 figures.. [SM)
SUB CODE: III SUBM DATE: none/ ORIG REP: 004/ OTH REP: 008/ ATD PRESSA073
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USSR/Ghemistry - Detones, 1;3-Butadiene JanAeb 1948
Chemistry - Acetylene, Derivatives
"Acetylene Derivatives., Part LVIM-The Chemistry of Divinyl KetOneG,, X, the Addition
of Hydrogen Sulfide to B, B -Dimetbyldivizrylke tones " I. N. Nazarov, A. I. Kuznetsova,
Inst of Org Chomp Aced Sci USSR, 9 pp
"Iz Ak Nauk SSSR, Otael Xhim Nauk" No 1
Details study of the mechanism of the compounding of hydrogen sulfide vith Bp B -
dimethy1diviny1detone, showing simple method of obtaining unsaturated ketothiol
(II), thiopyron'(V), and diketosulfide (VII).
PA 66T28
Inst. Organic Chem., Dept. Chem. Sci. AS.

XYZNEVOVA
USSR/Chemistry - Acetylene, Derivatives Aug 48
Chemistry - Synthesis
"Acetylene Derivativeez No 78, Combination of Hydrogen Sulfide With 1-Metboxy-5-
Alkyl-4-Hexene-3-0n," I. N. Nazarovo A. 1. Kazneteova) I. A. Gurvich, Inst Org
Chem, Aced Sci USSR, 4 pp
"Zhur Obshch Milmii" Vol XVIII (LXXX), No 8
Action of hydrogen sulfide on 1-methoxy-5-gakyl-4-on-3 in solution of 70-95%
alcohol in presence of sodium acetate at temperature of 00 produced 1-methoxy-5-meth-
ylbaxane-thiol-5-on-3 with a yield of 50%,, 1-mothoxy-5-methylbeptane-thlol-5-on-3j
and 1-methoXY-5-mothylootane-thiol-5-on-3 with yield of 25%. Action of hydrogen
sulfide on msaityl oxide in solution of 70% alcohol in presence of sodium acetate
at temperature 00 produced 2-mathyl-pentane-thiol-2-on-4. Submitted 7 Apr47.
PA 19A9TI4
Mr.) Inst. organic Chemistryp Dept. Chem.:Sci. AS.

j I* N.; GURMCHp Is A.
p. 2148 Acetylene derivatives. 104. Investigation of heterocyclic compounds. X.
New method of synthesis of tetrahydro-ethlopyronee by the action of hydrogen sulphide
on vinylallyl-ketones. Zhurnal obabchel khimii 1949, Vol. 190 No 12
Translated Contents Lists of Russian Periodicals No 11, April 1950. Department of
Scientific and Industrial Research.

nmimp'MAO As 16
"Acetylene derivatives. 105. Inveitigation of hetorocyclic compounds. X.
Synthesis of /.-othinyl tetr9hydro-thiqrjran-I+,-ols by condensation of acetylene with
tetrahydro-,,~-tuopyrones,
1. N. Nazarov, A. 1, Xuznetsova and A. V. Topchiev and YO. M. Paushkin.ff (p. 2164)
10: JournAl of General Chemistry (Zhurnal Obshchei Fldmii) 1941), Vol. 19, 11o. 12

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A
'-tGwChjeALjstj7
1 7
jl~7P,petylene Derivatives,, 139, Heterocyclic Compounds.,-
~of the Acids-of the~Thiopyrane Seri"
~'6y,bbndensation of Tetrahydro-Thiopyrone With Cyamo-
4caijc: and Bro'noacetic Esters,F 1. 1. -Nezarorui. 1.
fxusu~tsova'~~ of Org Chem, Acad Sci USSR
ZburMbshch Xhim, Vol 22, No 5, PP 835-847
'DesciiIes methods showing that these substances'c4=
~,be. uied as starting materials in the synthesis 'Of
1~"iologically active compds,and medicines.
26=2

xds"b 86% A. 1.
M/Che mistry - icetylene berIvatives S'teroids ~un 52
nAcetylene Derivatives. 140. Heterocyclic Cornpounds. XV1. Synthesis of Sulfone
Analogues of Steroid CoiVounds With a Thiopyrane Ring B.It Is No NazaroYi Is A,
Gurbich, A. I. Kusnetsovag Inet of Org Chem, Acad Sci USSR
"Zhur Obshch Khim" Vol XX17p,No,6j pp, 982-984
By means of the diens ccndensAtions a synthesis was developed for the let time
for obtaining sulfone analogues of steroid ketones with the sulfur in the B ring.
The.A and B rings are joined in the trans- position, the C and D rings in the
cisposition, The above product does not form the uimal carbonyl derive, while
its hydrogenated products easily yield 294-dinitropnenyl hydrazono.
21BT22

OZE-MOVA, A. 1.
wMiChemistry - )~catyiene Dorivativoa Jun 52
"Acetylene Derivatives. 21a. Heterocyclic Compounda. XVIL Structure hnd
MechAninm of Formation of Tetrahydro- Y-Thiopyrones and Their Reduction by
Kizhner's Methodo" L No Nazarovas To Ao Gurbichj, A. I. Kuznotsova,- Inst of
Org Chem, Acad Sci USSR
"Zhur Obahch Khin" Vol XX:[I, No 6, PP 984-989
Sulfur heterocycles prepd by the action of H2S on vW allyl detones have a
6!-Hembered sturcture. On reduction of tetrahydro- (, -thiopyrone by Kizhner's
method the corresponding thtrehydro thiopyronOB were obtained in a 60% yield.
The yield of 2-mothyltatrahydro-l-thiopyrone-4-one was improved. Discussed
the mechanism of Ita formation.
218T23

M Ln m T n' 0 V i C, k.- I
USSR/Chemistry - kcatylene terivatives Polycyclic Sulfur - Owtaining Conpounds ~un 52
"Acetylene Derivatives. 142. Heterocyclic Compounds* XVIII. Diene Synthesis on the
Basis of Dioxides of Substituted -Thiopyrones," I. N. Nazarov, I. A. Gurbich,
A. 1. Kuznetsova, Inst of Org Chem, Acad Sci USSR
I'Zhur Obshch Khim" Vol XXIIp No 6. pp 990-998
~,ben a glacial acetic acid soln of tetr~hydro_ t/-thiopyrone dioxides is treated
with Br and heated, a high yUld of mono- and dibromosulfones is obtained. Upon
heating with sodiun. acetate in acetone, HBr is split off, and the dioxides of ~/
-thiopyrone and of dihydro-l-th:Lopyrone are formed with a 70-80% yield. Describes
the results of the synthesis. The capacity of the tetrahydro- '~ -thiopyrone
dioxides to take part in the dione synthesis depends on the position of the
substituent in the nucleus. Methyl groups in the r~ -position to the carbonyl
group makes kiene condensation difficult; the methyl group in theff-Tosition to
carbonyl makes it impossible below 2000.
218T24

-I F,U 1,117. 10" Tn.
Thiochrw=nones
Acetylene drivatives. Part 143. Heterocyclic compounds. No. 19. Stereoisomerian of
hydrogenated thiochromanones. Zhur. ob. khim. 22j no. 79 1952.
Mon List of Russian Accessions Libmry of Congress.. Novemberp 1952. Unclassified*
Rt

'-!--OVI 1. ;'.t G"VION, I.A., YU,-JU-,TSIOVA, A.I.
Sulfones
Acetylene derivatives. Part 144. Heterocyclic conpounds. No. 20. Stereoisomerism
of hydrogenated thiochromanones. Part 2. Zhur. ob. khim. 22 no. 8, 1952.
9. Monthly List of Russian Accessions, Library of Congress, Novemberp 195 Uncl.

NAZAROV, LIN.; VJMnMOVA, A*L,
-------------------------
Acetylene derivatives. Report 132. Heterocyclic compounds. P13rt 28.
Synthesis of certain derivatives of tetrahydro- f-thlopyrones. Izv.AN
=R Otd.1-him.nauk no-3:506-512 My-Je '53. OMBA 6:8)
1. Inatitut organicheekoy khimil Akademit nuuk SSSR.
(Acetylene derivatives) (Wopyrones)

V.s'SR/Ch*nIntz-,, Sulhtr Orgaxic CoripouAds; Steroids ITOV/Doc 53
PSYnthesis of Sulfur Analog% of Steroid CompouiLds b7 Mine Onadonsatics of
Cyclic Gamma,-Kotatulfonss With BicyclIc Dienos, "I.N. Fazarov, I.A. Gurvich,
A. I. luzaltROVAL
Iz Alc 11puk SSSR, OW, No 6, pp 10c)1-1099
Syxthsg12ed a number of tetracyclic kotomulfouen (amour, them compd- having the
structural skeltous of thiapyranophonathreno and thiochromanoiud-aae) *Ad
investigated their properties.

P. . . I I . . , ., -- ~ .,:,
. ,, I I . - , ~ - - I z .-,. .: - .

1 1. -r- - -.,;. - - 1 .1 1 ~ . .

50) sov/62-59-4-15/42
AUTHORS: Nazarovj I. N., Ftuzneteova, A. I., Kuzneteov, N. V.p Titov,
Yu. A.
TITLE: Diene Condensations of 1,3-Dimethylbutadiene With Asymmetric
Dionophilic Compounds (Diyenovyye kondeneataii 1,3-dimetil-
butadiyena a nenimmetrichnymi diyenofilami)
PERIODICALt Izvestiya Akademii nauk SSSR. Otdoleniye khimichoskikh nauk,
1959, Nr 4, pp 663-667 (USSR)
ABSTRACTs In the present work the condensation of 1,3-dimethylbutadione
with methyl acrylate and methylmethacrylate and with acrylo-
nitryls was investigat8d , By heating 1,3-dimet lbutadiene with
methyl aorylate at 220 a mixture of adducts (VI and (VI) in a
yield of 60~ was obtained. The aoymmetrin. isomer (V) was pre-
dominant. The ad gucts were dehydrogenated on carbon-supported
palladium at 350 . The saponification of the dehydrogenation
products gave a 26 t 1 mixture of known 2,4- and 3,5-dimethyl-
benzoic acids. The condensation of 1,3-dimethylbutadiene with
methyl methaorylate at 220 gave the adducto (VII) and (VIII)
in a yield of 76~j the asymmetric isomer (VII) being again
Card 1/2 highly predominant. The saponification of the adducte gave a

'SOV/62-59-4-15/42
Diane Condensations of 1.3-Dimethylbutadione With Asymmetric Dienophilic Com-
pounds
mixture of liquid acids. The dehydrogenation of the mixture on:
carbon-supported palladium gives a mixture of trimethylbenzenes.
The oxidation under pressure of this mixture diluted with
nitrogenous acid gave an 18 t I mixture of trimellitic and tri-
Mesio Saida. By heating 1,3-dimethylbutadiene with acrylonitryl
at 220 a 13 : I mixture of cyclic nitryle (IX) and (X) 'was ob-
tained in a yield of 74%. Their structure was proved by- the do-
hydrogenation to corresponding aromatic nitryls, which formed
294- and 3t5-dimethylbenzoic acids upon oaponification. Thus it
has been shown for the first time that nixtures of structure-
isomeric adducts are formed by the condensation of 1,3-disub-~
stituted butadienes with asymmetric dienophilic compounds.
There are 5 references, I of which is Soviet.
ASSOCIATIONj Institut organicheskoy khimii im. N. D. Zelinskogo Akademii nauk
SSSR (Institute of Organic Chemistry imeni N. D. Zelinskiy of
the Academy of Sciences, USSR)
SUBIAITTEDt July 9, 1957
Card 2/2

5(2), 5W SOV/76-4-1-34/48
AUTHORS: Bergman, A. G., Kuznetsova, A. I.
TITLE: The Solubility Diagram of the Tornary System H 2O-KC1-CaC12
Prom the Temperature of Complete Solidification to 3000
(Diagramma rastvorimosti troynoy sistemy H 20-KCl-CaC1 2 at
temperatury polnogo zamerzaniya do 3000)
PERIODICAL: Zhurnal neorganicheskoy khimii, 1959, Vol 4, Nr 1,
pp 194-204 (USSR)
ABSTRACT: The reciprocal solubility of potassium and calcium chloride at
lower and higher temperatures was investigated by a visual-
polythermic method. At first the binary systems CaCl 2-H20 and
KCl-H 20 were examined and completed. Twelve sections were
examined for the plotting of the solubility diagrams. Ten
crystallization zones may be seen in the diagram: Ice, KC1,
KC1.nH2Op CaCl 2* 6H209 CaCl 204H2 0, CaCl2 92H20, CaCl 2- H20, CaCl 20
a- and P-KO1,CaC1 2' The modification a-YCl*CaCl 2 exists from
+37.8 to +1960. At a Mghpx temper ure the compound changes to
Card 1/2 modification P-KCloCaQ1 On the asis of the results obtained
. 20 1

SOV/78-4-1-34/48
The Solubility Diagram of the Ternary System H 2 O-KCl-CaC12 From the Tempera-
ture of Complete Solidification to 3000
thePhase diagram of the ternary system H 2O-KCl-CaC12was
plotted from the solidification point -50-50 to the melting
points of the anhydrous components. In the system 8 triple
nonp~variant points occur whose characteristics are shown in
table 4 together with data concerning the solid phaseB.
There are 7 figures, 5 tables, and 25 references, 16 of which
are Soviet. I
ASSOCIATION: Institut khimii Akademii nauk TadzhSSR i Ro3tovskiy gosudarst-
vennyy uhiversitet (Institute of Chemistry of the Academy of
Sciences Tadzhikskaya SSR and Rostov State University)
SUBMITTED: July 8, 1957
Card 2/2

5 (3)
AUTHORS: Nazarov, I. N.v Titov, Yu. A.9 SOV/62-51-7-17/38
Kuznet
TITLE: Orientation of the structure of the Diene Condensations of
2-Phanyl-butadiene and of Trane-i-phenyl-butadiene With Un-
symmetrical Dienophiles -(Strukturnaya napravlennost, ai-
yenovykh kondensatsiy 2-fenilbutadivem i trans-l-fenil-
butadiyena a nesimmetrichnymi diyenofilami)
PERIODICAL: Izvestiya Akademii nauk SSSR* Otdeleniye khimicheakikh naukt
1959, Nr 7, pp 1270 - 1279 (USSR)
ABSTRACT: The present paper is a continuation of a systematic investiga-
tion of the rules governing the diene synthesis for the orien-
tation of the synthesis in order to obtain certain structures.
carried out in the authors' laboratory. The synthesis of the
uneymmetrically substituted dienes with unsymmetrical dieno-
philes can be carried out by two methodal i.e. under forma-
tion of two struoture-isomerio adduots;fNearl always the mix.-
ture of these two structure isomers (R a 1,2~ is produced.
This formation is assumed to be influenced by the nature of
the substituents in the two compounds. The influence is in-
Card 1/3 vestigated here in the diene condensation from the two dienee

Orientation of the Structure of the Diene Condensa- 207/62-59-7-17/38
tions of 2-Phenyl-butadione and of Trans-l-phonyl..
butadiene With Unsymmetrical Dienophiles
mentioned in the title and different unsymmetrical dienophJle3.
The scheme of the condensation is assumed as it follows:
G H 0 ( 0 + ( X 0 H ,,0 '**-x
6 6H5 6 5
The condensation was carried out with the eaters of the
acrylic I methaorylio acid? and styrene. The para- and meta-
adduct; (111) and (IV) are formed by the condensation with
the methyl esters of the acrylic acid. The yield of metaiso-
more in already in the condensation with methaoryl eaters low
and does not exist in the case of styrene. The investigation
of the structure and spatial orientation of the trans-1-phe-
nyl-butadiene was carried out with the same dienophiles. Meta-
isomers were in all cases found in the adduct. A reduction of
the content of trans-ortho adducts could be found in the trans-
Card 2/3 ition from the acryl- to the methacryl eater compared to the

Or~entation of the Structure of the Dione Condensa- SOT/62-53-T-1T/338
tiorn of 2-Phonyl-butadiene and of Trans-1 -phonyl-
butadiene With Unsymmetrical Disnophilos
cis-ortho adductas The transformation schemes as they are ob-
tained from the reactions, are represented and the transforma-
tion and synthesis is described in detail in the experimental
part. There are 25 references, 5 of which are Soviet.
ASSOCIATION: Institut organicheakoy khimii im. ff. D. Zelinskogo Ak-ademii
nauk SSSR (institute of Organic Chemistry Imeni if. D. ZdLinskly
of the Academy of Sciences, USSIDN
SU13MITTED: October 22, 1957
Card 3/3

50) SOV162-59-8-12142
AUTHORS: Nazarovq 1. N., Titov, Yu. Avg -KW&0""r-L1k-
TITLE: Structural Orientation of the Diene Condensation of Isoprons
With Unsymmetrical Dionophile
PERIODICAL; Izvestiya Akademii nauk SSSR. Otdsleniye khimioheskikh naukq
1959, Nr 8, pp 412-1420 (USSR)
ABSTRACT: The present paper contains a systematical investigation of
the diene condensation of isoprene. In most cases it has so
far been possible only to obtain the para-adduot, one of
the two theoretically possible structural isomers. Petrov and
Sapozhnikov (Ref 1) also obtained the meta isomer (1940)s
The authors in previous studies of the separation of the
meta isomer from the isoprene a4duot with the methyl *store
of acrylic aM mothearylio soide had reported cn this wb*t (Rat 9).
It could also be demonstrated that the diene condensation
of the dimer of isoprene varies in its reaction mechanism
in relation to the reaction temperature. Thus the synthesis
was carried out at vagioua temperatures, just as in reference 9
(20, 1209 200 and 400 ). The structural formulas of the
various adduotB obtained and their formation processes are
given* It is shown that the meta Isomer yield increases with
:Card 1/2 mounting teiperatures. Furthermore an investigation was made

BOV162-59-8-12142
Structural Orientation of the Diens Condensation of Isoprene With Un-
symmetrical Dienophils
of the influence of the substituente on the meta adduct.yield.
Results showed that at an increase of the volume of the
substituent in position a the meta adduct yield decreases.
In order to investigate the said influence iBoprene was con-
deneed with the eaters of acrylic, methaorylic, and a-igo-
propylacrylic acids. From the condsheation of isoprene with
acrylic acid, its methylester and nitrile as wall as scrolein
the two structural isomeric adducts can be obtained in a ratio
1 : 1. The results concerning the adducts found by various
methods of synthesis are compiled in tables 1-3. The indi-
vidual methods are described in the experimental part. There
are 3 tableo and 16 referencest 8 of which are Soviets
ASSOCIATION: Institut organicheekoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR
(Institute of Organic Chemistry imeni N. D. Zelinskiy of the
Academy of Sciences, USSR)
SUBMITTED: October 22, 1957
Card 2/2

5 (3)
AUTHORS: NaZarov, I, N,t Titov:, Yu. A., SOV/62-59-9-13/40
TITLE: The'Structural Dependence of Diene Condensations of 2-Alkyl
Butadienes With Asymmetric Dienophiles
PERIODICAL: Izvestiya Akadamii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959,.Nr 9, pp 1595 - 1604 (USSR)
ABSTRACT: The diene condensation of 2-propyl- (1), 2-isopropyl- (2), and
2-tert.-butylbutadiene (3) with eaters of the a-substituted
acrylic acid(methaerylic- and a-isopropyl acrylic acid) was car-
ried out for the investigation of the influence of the volume of
the substituent in the diene and dienophile on the directionof
the diene synthesis. The synthesis occurred by beating the diene
and dienophile mixture at 2000 during 2-10 hours. (1) condensed
with methylacrylic acid ester yielded the adducts I and Ill
(yield 81%), from which they obtained a mixture of para- and
meta-isomers of the phthalic acid (2-4 ; 1) by the action of
barium salts. (1) with methacrylic methylester (yield 65%*)
yielded a mixture of the adducts (III) and (V). By saponifica-
tion and separation with barium salts again p- and m-derivatives
Card 1/2 of the adducts w6re obtained (3-4 : 1). Condensation of (2)

The Structural Dependence of Diene Condensations of SOV/62-59-9-13/40
2-Alkyl Butadienee With Asymmetric Dienophiles
yielded.the adducts (VII) and (VIII) which formed as p- and
m-isomera of the phthallc acid (ratio 3 : 1). In the course of
the investigations it was established that the inoreaso of the
volume of the alkyl substituents in the diene- and dienophile,
the:quantity of the meta-isomers reduced in the mixture of the
adducte. The results are interpreted by the increase of space-
obstruction at the increase of the substituent volume. There
are 10 references, 3 of which are Soviet.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Ak&demii nauk
SSSR (Institute of Organic Chemistry imeni N. D.,Zelinakiy of
the Academy of Sciences, USSR)
SUBMITTED: October 22, 1957
Card 2/2

5 (3:) -.90V/2o-124-3-26/67
AUTHORS: Nazarov, I. It., Academician (Deceased), Titov, Yu. A.,
Kuznetuova, A. 1.
TITLE: ---The Structural Orientation of the Diene-Condennationa of
1- and 2-Alkylbutadienoa With Asymmetric Dionophiles
(Strukturnayn napravlonnost'kiyenovykh Vondoneatoiy 1- 1
2-alkilbutadiyenov a nesimmetrichnymi diyenofilami)
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 124, Nr 3, PP 586-588
(USSR)
ABSTRACT: For the pu=pose of a systematic study of the influences of
various alkyl nubstituents in the diene and dienophile on the
proportion of the resulting isomers, diene-condensations of
eaters of acrylic acid, methacrylic acid, and a-isopropyl-
acrylic acid with looprone, 4"-propyl-I P-loopropyl- wid
2.. tort i ory-butyl-4111 Uld lame, w1 Well na with 111parylone,
1-inopropyl-p 1-butyl- an(] 1-tertiary-butyl-biitadione were
carried out. All condensations were effected by beatiBg the
components in stool ampullae for several hours to 200 C,
with the addition of 0.1 - 0.21,t hydroquinone as a polymeriza-
tion inhibitor. The ratio of the structural isomers was de-
Curd 1/3 termined by means of dehydration over 15-20i"il palladium coal

SOV/2o-124-3-26/67
The Structural Orientation of the Dieno-Conlonoutionn of I- and 2-Alkyl-
-butadionen With Asymmetric Dienophilas
at 340-3500C, oxidation of the resulting alkyl benzoic acids
-or dialkyl benzenes into a mixture of isoneric phthalic acids,
and separation of their barium salts by means of crystalliza-
tion. - It was found that, with an increasin,- alkyl substituent
volume at the 2-alkylbuta(lionen and dienophIlea, the reaction
becomes increasingly selective. The relative share of the meta-
isomer in lowered rapidly no compared wit-:t that of the para-
icomer. In the I-alkylbutalienea, however, an opposite selec-
tion occurs, and the share of the metaiconers rises. - This
difference can be explained by the strong, influence of steric
factors. With an increasing oubatituent volume and a fjimultaneoue-
ly increasing reptilsion, there in a rise in the yield of that
isomer which in formed via aterically loss irapedad transitional
complexes. There are 2 tables and 13 references, 3 of which
are Soviet.
ASSOCIATION: Institut organiclieskoy khimii im. N. D. Zelinokoao Akademii
nauk SSSR
(Institute of Organic Chemistry imeni N. D. Zelinskiy of the
Card 2/3 Academy of Sciencea, USSR)

50) SOV/2o-126-3-35/69
AUTHORSs Titov, Y u. A., Kuznetsova, A. 1.
TITLEs The Ele o tronio Nature of Substituents in Diene and Dienophile
and the Structural Trend of the Dione Synthesis (Elektronnaya
priroda zamestiteley v diyine i d*onofile i strukturnaya naprav-
lennost' d1yenovogo sinteza)
PZRIODICkLs Doklady Akademii nauk SSSRI 1959t Vol 126, Nr 3,
PY 586 - 580 (USSR)
ABSTRAM At diene condensations of asymmetrioally substituted dienes
with asymmetric dienophiles, 2 structure isomers are possible,
one of which is predominant. Such structural selectivity in
absolutely connected with the mechanism of diene synthesis.
Its study can constitute one of the ways for determining the
mechanism of this important reaction. For studying the problem
last mentioned in the title, the authors chose the acrylic acid
and styxol as dienophilea. These two substances were introduced
in diene condensations with 1- and 2-substituted dienes. The
results obtained are compiled in table 1. It indicates that
the subatituents studied hore do not show any distinct differ-
Card 1/3 ences as to their adjusting influence on diene condensations

The Electronic Nature of Substituenta in Diene and SOV/2o-126-3-35/69
Dienophile and the Structural Trend of the Diene Synthesis
in spite of their variable electronic properties. Nevertheless,
the ratio of the resulting polymers depends, to a certain de-
gree, on the nature of aubstituents. The latter can be put
in a aeries as to their adjusting influence on the diene followst
Cl~ CH 3O> 0 6U5 > CH3
Table I shows the condensations of the 2-substituted butadienes
with asymmetric dienophiles. Table 2 shows the same for 1-sub-
stituted butadienes. On the basis of the results obtained, the
authors conclude that by the transition from an electron- trans-
mitting to an electron-receiving subatituent in the diene or
in the dienophile the structural trend is not reversed as it
should be in an ion mechanism of the diene synthesis (Refs 1t2).
Therefore, the ion mechanism should be rejected as it cannot
explain the course of reaction. A mechanism of the diene synthe-
sis by kinetically independent free radicals with an open chain
(Refs 3,4) also seems to be unacceptable as it is incompatible
with an existing tial selectivity of the reaction (Ref 5)-
Card 2/3 The fact (Refs 6, that at a diene decay no free radicals arise

The Electronio Nature of Substituente in Diene and SOV/2o-126-3-35/69
Dienophile and the Structural Trend of the Diens Synthesis
also speaks against it. It seems that for the diene synthesis
the mechanism with a homolytio regrouping of electrons in the
range of a cyclic transition complex is most probableg the
latter being stereoohemically similar to the adduct. This paper
continues the invantigAtions atarted under the dirsotion of
1. N. Hazarov. There are 2 tables and 7 references.
ASSOCIATIONs Institut organicheskoy khimii Akademii nauk SSSIL (Institute of
Organic Chemistry of the Academy of Sciences, USSR)
PRESENTEDt Uarch 39 19599 by B. A. Kazanskiy, Leademician
SUBMITTEDs February 271 1959
Card 3/3

JUZAROY, I.R.; TITOV, Yu.A.; XUZNITSOVA, A.I.
Struat"al orientation of diens condensations of 1-alI71butadienes
with unsymmetrical dienophiles. lsv~LN SSSR Otd.kblm.nauk
no-5:879-886 My 160. (MM 13:6)
1. Institut organichaskoy khImII Iveni N.De Zalizwkogo Akademii
nauk SSBRO
(Butadiene) (Piperylens) (Acrylic acid)

W55
2- UOSI S/062/60/000/010/008/018
B015/Bo64
AUTHORS, Titov, Yu. A. and !jUZ etBovat A. 1.
TITLE: Structural Orientation of Die ne Condensation of Butadiene-1-
-- garboxylic With Acrylic
.Acid and Styrene
Acid
i 'I
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1960, No. 10, pp. 1810-1814
TEXT: The present paper continues investigations on the laws of diene
synthesis commenced under the direction of 1. N. Nazarov. A condensation
of butadiene-,I-carboxylic acid was carried out with acrylic acid and
styrene, the structural isomers in the reaction products were separated,
and their ratio determined. Acrylic acid and styrene were chosen as
dienophiles since the former contains an acceptor substituent and the
latter a donor substituent, Thus, the influence of the electronic
character of the substituent upon the ratio of the structural isomers
may be studied. Both condensations were made at 1500C, and lasted six
hours. A mixture of ortho- and meta-adducts in a ratio of 8.8 : 1 was
Card 1/3

Structural Orientation of Diene Condensation S/062/60/000/010/008/018
of Butadiene-l-carboxylic Acid With BO15/B064
Acrylic Acid and Styrene
obtained in the condensation with acrylic aold. The rutio Qf tho
atruat"n! 140moro for trkno-orth0ioomor t ein-orthoiaomor *as found to
be 8.6 % 1. The ortho-oriented adducts and the -trans-isomers predominated
also in the styrene condensation products. The polarity of the diene and
dieneopbilic molecules was found to be of no importance in the structural
orientation of diene synthesis. The latter is somewhat weakened by the
introduction of an acceptor substituent into the diene, or of a donor
substituent into the dienophile, and becomes stronger if the diene
contains donor substituents and the dienophile acceptor subatituents.
A similar phenomenon can also be observed in diene synthesis (Refs. 6-8).
The technique of condensation and hydrogenation of the adducts is
described. There are 11 references: 1 Soviet, 7 US, 2 German, and 1
British.
ASSOCIATION: Inatitut organicheakoy khimii Im. N. D. Zolinckogo Akademii
nauk 83SR (Institute of Orgall1c Chemietrl imeni H,j1'____
Zelinakiy of the Academy of Sciencou'USSR)
Card 213

Structural Orientation of Diene Condensation
of Butadiene-l-carboxylio Acid With
Acrylic Acid and Styrene
SUBMITTED: May 13o 1959
84855
S/062/60/000/01o/m/oie
B015/B064
Card 3/3

84856
S/062/60/000/010/009/018
22-003, lKli 11~70 B015/BO64
AUTHORS: Titov, Yu. A. and Kuznetsova~ A. 1.
TITLE: Structural Orientation of the Diene Condeneationelof
2-Methoxy Butadiene,and Chloror)rone With Asymmetric
Dienophilee I I
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1960, No. 10, PP- 1815-1819
TEXT: The diene condensations of 2-methoxy butadiene and chloroprene
were carried out with acrylic acid and styrene, the para- and meta-
isomers separated from the mixture of adducts, and their ratio
determined. The condensations were performed by heating (at 1500C for
5-12 hours) the mixture of the diene and the dienophile in benzene in
steel ampoules. In the condensation with acrylic acid, the ratio between
para- and meta-isomer in the adduct mixture was 8 : 1, in the
condensation with styrene, 12 : 1, in the condensation of chloroprene
'with acrylic acid, 9,3 : 1, and with styrene, 14.4 : 1. Thus, it was
Card 1/3

84856
Structural Orientation of the.Diene S/062/60/000/010/009/018
Condensations of 2-Methoxy Butadiene and B015/Bo64
Chloroprene With Asymmetric Dienqphilee
found that in all condensations of 2-methoxy butadiene and chloroprene,
mixtures of the two kinds of structural isomers are formed, with the
para-oriented adduct predominating in th~, mixture. The amount of the
meta-isomer does not change essentially, The structural orientation of
chloroprene and styrene is somewhat more pronounced than that of
2-methoxy butadiene and acrylic acid. The lack of any essential difference
in the ratio of the structural isomers of dienes and dienophiles with
various kinds of substituents may be regarded as an argument in favor of
the homologous reaction mechanism of diene synthesis. The techniques of
the individual condensations are described. The present work forms part
of the investigations commenced under the guidanoe of I. N. Nazarov.
There are 19 references: 9 Soviet, 2 Gorman, 4 US, 1 French, 1 Japanese,
and 2 British.
ASSOCIATION: Institut organicheskoy khimii im. N. D. ZelinskogoAkademii
nauk SSSR (Institute of-Organic Chemistry imeni N. D.
Zolinskiy of the Academy of Sciences USSR)
Card 2/3

84856
Structural Orientation of the Diene S/062/60/000/010/009/018
Condensations of 2-Methoxy Butadiene and B015/B064
Chloroprene With Asymmetric Dienophilee
SUBMITTED: May 13, 1959
x
Card 3/3

5.3831,5.36oo 77367
SOV/79-30-1-28/78
AUTHORSt Nazarov, 1. N., Kuznetsova, A. 1.
TITLEt Dimerization of Chloroprene
PERIODICAM Zhu rnal obahchey khimii, 1960, Vol 30, Nr 1, pp 134-138
(USSR)
ABSTRACTs Chlor8prene was stored in the dark for 2 years at
15-20 , in the presence of 3% pyrogallol. A mixture
of!dimera (45%) was formed, and subjected to fractional
distillation.. Of the possible dimers below, only 10111,
and V were known to form from chloroprene at 60--650.
C1 C1 C1 C1
H-CHS
Al
C1 H-CHS
Card 1/3

Dimerization of Chloroprene
C1 C1 C1
M (VI)
77367
SOV/*79-30-1-28/78
In this work the presence of I, III, Vand VI, as well
as of a significant amount of IV, was shown. IV is
apparently formed in Bomewhat greater yield than IIIj
this is analogous to the dimerization of isoprene. The
work was complicated by the lack of stability of some
of the products formed and by the difficulty of convert-
ing them into known substances for the purpose of
structure determination. There are 9 references, 4
Soviet, 3 U.S., 2 U.K. The U.S. and U.K. references
are: W. H. Carothers, et al., J. Ara. Chem. Soc. 53
4211 (1931); J. G. Brown, et al., J. Chem. Soc.: 1944,
Card 2/3 101j R E. Forster, et al., J. Am. Chem. Soc., 70, 2302

Dimerization of Chloroprene 77367
SO'V/79-30-1-28/78
(1948 1 A. C. Cope et al., J. Am. Chem. SOC., 70,
4948), ibid, 72, 3056 (1950); A. McCoubrey, J.
Chem. Soo., 1951, 2931.
ASSOCIATION; Institute of Organic Chemistry, Academy of Sciences,
USSR (Institut organicheakoy khimii Akademii nauk
SSSR)
SUBMITTED: January 15, 1959
Card 3/3

5.3400
AUTHORS: Nazarov, 1. N., Kuznctsova, A. I.
TITLE: DimerIzatlon of 2-Phenylbutaflieno
PERIODICAL: Zhumal obahchoy Ichimit, ig6o, voi Nu i, pp 1.,-j9-
11111 (USSIl)
ABSTRACT: The pooaibility of dimerIzation of' 1'!-phcny1bUtQ-1 tone with
formatlon Of' InCta-SUbStltLft(~d (JUT101-5 (III "')nd (IV), and
also of eight -~Membcred dimers (V) and (VIi wzi3 [rive.,sti-
gated. C4113 (~Ifa c,115 (~113
\/\c.11-, 0\c-cl12
call,./ C'% c 11. cells
C6115 C611% C61f,-
Card 1/5
M)

Dimerization of 2-Phenylbutadiene 77-168
SOV/"(c)- 30 -1 -2
2-Phenylbutadiene
a 1-year storage
crystalline (77%)
crystalline part,
were isolated for
(I) OVCV Pd/C forins
In the presence of pyrogallol, after
is converted (75%) into a mixttire of
and li?uid,~20,%) dimers. From the
dimev 1) )9%) and dimer (II) MOW
the first time. Dehydrogenation of
tei-phenyl (,'-.10%) .
Coll, C4113 Coll.,
LOCO113
C
C6113 C113
Dimcr_(II) la easily dehydrogetiated to 1-(l rphe nyl) -
ethyl 4-phenylbenzene (VII) In 80% yield; (~Ii) is easily
oxidized with JINO-- under pVe.'3SL1VC to p-plienylbenzo-
hcnone, in 82% Yfeld (MI) 101-10'fl. FVOM 11CIUld (111TICL'
~
(Iafter recryntallization, diotit'lution, bind dehydrot;e-na-
card 2/5 tion) terphenyl an(I (VIT.) vjcrL- loolatea. OxidiA,1011 of

Dimerization of 2-Fhenylbutadlene
dehydvagenated Broduct:3 with 11110.~ fravf,- p-phonylbenzo-
phenone (m,,-) 10,1 ), and a small zimakint of ni-phenyl-
ben,".ophenone (yteld iz not goLven) whielh Indicates the
pvesence of the mcta-subc-itituted dImet, (IV) In the
starting, mixture.
C4116
::I!!. HNO
(I V) 4
(I, )" C 0 C a I I
m-Phonylbcnzophenone was ayntlicaLzed, as followu
3-ph enyl- A2_ cyclohexanone (4 g) (VII) was reacted with
benzylmagnestum chloride formlng (aftev hydrolysis) 1-
phenyl-3-benz 11- n113- cyclohexadlene (IX) (4 *15 g, bp
219-221 (1) mm~), which on dehydvogenation ovet, Pd/C and
oxidat ~on with 11NO3formed m-phenylberizophenone, In 511.5%
(rnp 80
Card 3/5

-------- - ---
Dimovization of' 2-Phenylbutadtenc
\A
0 \c1lorldl-,
jV111) 0 X)
Dimerization of 2-phenylbutadlene at 220-2~O0 fovms a
crysta)line mixture of dimers (80%), from which (1)
(57%) and (H) (12%) were 18olated. Fvom the liquid
pavt, 1,2-dibenzoylethane (X) was Isolatcd, which shows
4 8
the preoence of 1,4-diphenyl- Z~ ' -cycloactadiene M,
in the liquid part of mixture.
(v) c$11,cOc112c14jc.Oc$11O+ 110OCC112culcooll
M
Thus, dimevization of dicne with an at-0111,-MC 3Ub-0;[t-
uent (2-phenylbutadicric) f'oL-m3 rrio:;t of the thcovctlc~tlly
Card 4/5 po.,3oiblc d1mers, (I), (II), (IV), and (V). C30111j)OUnd (II)

Dimerization of 2-Phenylbutadiene
77-,168
.1
SOV/79-710-1-29/78
was isolated f6r the first time (mp 57-980, colorless
plates). There are 6 references, 3 Sovlet, I German,
1 U.S., 1 U,K. The U.S. and U.K. references are: G. F.
Woods, J. W. Tucker, J. Am. Chem. Soc., 70, 2174
11. 11. Hatt, AlPilgrim, E. F. Stephenson, J. Chem.
0
soc ., 1941, 4
ASSOCIATION: Institute of' Organic Cheml-,3try, A;~-demv of Sclencc-3, USSR
(Institut organicheskoy khtmil Akademli nauk SSSR)
SUBMITTED: January 15, 1959
Card 5/5

Use of thin a7mination chrmatography for the separation of steroid
Compounds. Had. Pra.. 15 no,2%57-Q F t6l. (MIRk_:L4:3)
lo Inatitut orpnichelkoy *'Wi i~eni R.D.Zelinakogo,AN SSSR.
(aRauToGRaffr) (STEROIDS)

KUZNETSOVA. A.Io.
Using thin-- 'layer chromatography for the separation of steroid
compounds* Dokl,AN SSSR 138 no.3s592-594 W 16-1. (MM 146)
I# Institut orgadch eakoy Waft ft, N,D,Zelinskogo AN SSSR. Pred-
otavleno akademikom B.A.Kazan kimo
(Chromatographic analysis) (Steroids)

KUCHEROV, V.F.; KUZNETSOVA, A.I.. MAVROV, M.V.; ALEKSEYEV, Ye.F.
Chemistry of polyenic and polyacetylenic compounds. Heport
N0.31 Ir-oxyacetylans- and vinylacetylenecarboxylic acids
and some of their tranaformations. Izv.AN SSSR.Dtd.khim.nauk
no.3s484-490 Mr 162. (KRA 150)
1. Institut organlohedkoy khimii im. N.D.Zelinakogo AN SWR.
(Acetylene compounds)

AKHREM, A.A.; KUMETSOVA, A.I.;,TITOV, Yu.A.; LEVINA, I.S.
Separation of acetylenic alcohols and glycols by means of thin
"layor chromatography on aluminum oxide. Izv.AN SSSR Otd.kbim.-
nauk no.4:657-661 Ap 162. (MIRA 15:4)
1. Institut organichookoy khimii im. N.D.Zelinskogo AN SSSR.
(Alcohols) (Chromatographic analysts)

AKHREM, A.A.; KUZNETSOVA, A.I.
Thin layer chrmatography. U11p. khim. 32 no.71823-859
JI 163. (MIRA 16:8)
1. Institut organichookoy MAU AN SSSR imeni Zelinskogo.

ARKMII) Afanusly AndreyevIchj_j1X-QL,LY4 Llpk--,zn r, vna;
S red. L 1, rid Q -Xv=0
SIMUKOVA, N.A. P
[Thin-layer chromatography] Tonkouloinala khromatogra-
flia. Mookvaj Nauka, 1964. 174 p. WIRA 17:9)

USSR/ Biology Phytopathology.
Card 1/1 Pub. 22 - 39/40
Authors -1 Na6talynat 06 Do; Voronkelich, 1, V,) and KvirMeova, A, 16
Title New bacterial disease of raspberr-y
Periodical i Dok. AN SSSR 99/3v 483-484p Nov 21j, 1954
Abstract I The physiological and pathogenic charaateristice of a now bacterial
disease affectiin raspberry plants are described and the causes of the
disease are analyzed, Three USSR references (1935-1950)o Illustration.,
Institution: Agricultural Institutep Saratov, and tits Moscov Branch of the All-Union
Institute for Plant Protection, Moscow
Presented by: Academician V.-N, Shaposbnikovs.July 7. 1954
ire

SEDIVGHENXO, Yu.G.;KUZNMOVA, A.I.
;_.wMwWawVWAW=WWWWWr
Combined method of preparation, of the brain and modification of stains
fOT the stu4Y of cellular and fibrous system. Arkh. vat., Moskva 29
no.4:83-89 July-Aug 1951 (G1XL 23:2)
P&tho-Architeo:onio
1e Of the
IsboratorY (Head -- Doctor Medical Sciences
Yu, G. Shavohanko), Central Institute of Psychiatry.0irector -m- Docent
D. Yo. Melikhov), Mintstzy of Public Health RSYSH.

. , 7 f? .- !
, . . r : ,

i,, I !I- , I ,-'_ , I
SUIM10, S,.I,, kand.t~khn.nwakLIUZWSOTA, A.I., inzh.
Preparation of coke oven charges from Kuznetsk Basin coal$ by
selective crushing. roke i kbim.no-9:3-7 157. (MIRA 10:12)
1. Nusnatakiy metallurgichefikiy kombinat.
(Coal preparation)

68-10-5/22
ATJTHDRS:Lukanin, A.A. and_juz.RqtsoTa,-A,.1,
TITM From Experience of the Control of Heating Coke Ovens on the
Kuznetfik Metallurgical Combine (Iz opyta regulirovaniya
obogrevs, koksovykh pechey Xuanetskogo Metallurgicheskogo
Kombinata)
PERIODICAL: Koks i Khimiya, 1957, Nr 10, pp.18-20 (USSR)
ABSTRACT! Temperature measurements in the plane of the axis of coke
ovens at 3 different heights during the last five hours of
the coking period were carried out (Table 1). Mean final
temperatures in the tar line plane are given in Table ?-'. On
the basis of the above measurements some control (methods of
control not specified) of heating ovens was effected. As a
final temperature in the tar line plane 10000C was established.
There are 2 tables.
ASSOCIATION: KuznetakMetallurgical
kiy Kombinat)
AVAILABLE: Library of Congress.
Combine (Kuznetskiy Metallurgiches-
Card 1/1

KUPERMAN, F.r.; NIKITIR, Yu.I.; RAKOV, V.V.j WKINp V#Z,; MNETSOVAp
Aj.
Characteristics of largo-dimeniaon coke ovens in connection
with the coklbg of ohaqes of Kuznetsk Basin coals. Koks i
khim, no.l2t22-27 #62, (MEFti 16:1)
1, VostoobW 1pglekhIm1vheWdy inatitut (for Kuporma
~mb-Amt (MV, Mit't, USMIAt
(Coke ovens)

KUZECTSOVAl A.I.
Cultivation praotices for reforestation purposes in pine
forasts of northern Karelia* TrutV Kar,fil, AN SSSR Ao.'16t
82-93 159. (KM 1314)
(Karelia-Pins)

B'II-7K , Aleksandr Georgiyevich; K=XW�M. A.I.,prof,p redo;
SMUMA, G.F., red.; PWRMtXATA, T.I., takha.red.
(Reclaiming now land from forest and brushwood) Oavoenie
novykh samell ls-pod lose I, kustarnikov. Pod red. A.I.
Kusnetsovol, Irkatskj lrlmts~oe Wshnoe izd-vo, 1960. 89 P.
(Km 14:2)
(Irkatek Provinoe-Reolamation of land)

Special features of establishinp forest plantatima by surface
unite in sod covered cutover areas. Trudy Kar. fil. AN SSSR
no.25t86-98 161. (MIRA 14:9)
(Refore3tation)

i Y Y t, i,-,-i T-P~i -,~Lj A, -L,.t :~jmjf, ri~ t. ry-,
~T T, T~Ti. j- T
"Rarliochemical Investigation of the Stability of Soluti=3 Of Additives in
Oils." P. 107.
in book dtudy and Uac of Petroleum Products, moscow, aosteptekhizdat, 1957, 213 pp.
This collection of articles gives the results of the sci. res. work of the AU Sci.
Res. Inst. for the Processing of Petroleum and Gas for the Prc4uction of Synthetic
Liquid.

f ,0y--,- 17
S S-,; -SMYNROTA-,-Rj1i-.-.-SWR-,-G. I.
DVA, A. I.
Radioehemical analysis of the stability of additives In oil.
Trudy VNIX NP no.6:107-116 057. (,( IRA 10:10)
(Lubrication and lubricants) (Radioactive tracers)

7-
32530
1z ()I s/o65/61/000/012/004/005
0 E194/E135
AUTHORS: Zaslavskiy, Yu.S., Shor, G.I., Shneyerova, R.N.,
Kuzne1Lq_qxA*__&,1_,_, and Lebedeva, F.B.
TITLE i Reducing the corrosivity of extreme pressure (E.P.)
additives without impairing their effectiveness
PERIODICAL3 Khimiya i tekhnGlogiya topliv i masel, no.12, 1961,
39-43
TEXTt Previous work by the authors has shown that whereas
anti-corrosion additives should have strongly bonded sulphur or
phosphorus in the molecule, E.P. additives should easily release
sulphur, phosphorus or chlorine to form compounds on the metallic
surfaces at high contact temperatures. This explains the well-
known correlation between good anti-wear properties and high
corrosivity. A combination of anti-wear and anti-corrosion
additive components should overcome the effect of delayed E.P.
action in high-speed friction tests. In surfaces subject to high
speed friction there is not always time for the E.P. additive to
operate. For laboratory tests of two component additives the
Card 1/ 5

32530
Reducing the corrosivity of .... sA65/61/ooo/ol2/0o4/005
E194/E135
authors developed radiotracer methods of determining the chemical
activity of E.P. additives in oils in the presence or absence of
friction. The chemical activity of the E.P. additives was
assessed by determining the kinetics of solution of radioactive
steel in oil or of copper which was activated with Agilo.
Determination of the chemical activity relative to radioactive
vopper and steel were made with various sulphurised and
chlorinated organic compounds and mixtures of theme. For example.,
In tests with copper foil at a temperature of 150 OC it was found
that chemical activity of the sulphur-containing additive
d1benzyl disulphide and that of chlorinated wax were both much
less than the chemical activity of A mixture of these additives.
A mixture containing base Oil Plus 3% dibenzyl disulphide plus
7% chlorinated wax gave the best E.P. protection in the four ball
test. When 6% of barium alkyl phenolate dissolved in
oxpropylated alkyl-phenol was added to the oil containing
dibenzyl disulphide and chlorinated wax there was a marked
diminution in corrosivity of the oil without impairment of the
E.P. properties. However, the reduced corrosivity to copper
lasted for only ten hours. The anti-corrosion properties of
Card 2/ 5

32530
Reducing the corrosivity of s/o65/61/000/012/004/005
E194/E135
phosphorus-containing compounds were also tested on the
assumption that effective protection of metallic surfaces against
corrosion by atoms of chlorine and sulphur can be achieved by
creating, not a molecular, but a more continuous atomic film which
is less penetrable. To create such films the phosphorus-
containing compounds must be soluble in the base oil and release
phosphorus at considerably lower temperatures than the
decomposition temperatures of the E.P. components. It was indeed
found that the use of phosphorus-containing additives ensured
effective reduction of corrosion of steel at an oil temperature
of 200 OC in the presence of a mixture of dibenzyl disulphide and
chlorinated wax. Moreover, four ball machine tests showed that
the E.P. properties were not impaired. Tricresyl phosphate had
no anti-corrosive effect, whilst triphenyl phosphate caused a
marked reduction in corrosion. By using phosphorus-containing
anti-corrosion components in blends with more chemically active
E.P. additives, effective blends may be made using chemical
compounds that hitherto have been rejected because of their high
corrosivity. E.P. oils were tested on a friction machine in which
Card 3/5

32530
Reducing the corrosivity of s/o65/61/000/012/004/005
E194/EI35
the rubbing surfaces are the ends of two hollow cast iron
cylinders of 16 mm external diameter, one of which was radioactive.
The tests were made at a speed of 600 r.p.m. with a load of
2.5 kg/cm2 for a period of one hour. Typical test results show
that the base oil gave a mean wear rate of 66o impulses/min of the
counteri the 'base oil Plus 3Y* of additive J13-6/9 (LZ-6/9) plus
7% chlorinated wax gave a wear rate of 1920 Impulses/min. The same
plus 0.5% triphenyl phosphite gave a wear rate of 840 impulses/min.
Thus the triphenyl phosphite reduced the corrosivity of the E.P.
oil to the level of the base oil. There are 3 figures, I table
and 17 referenceal 11 Soviet-bloc and 6 non-Soviet-bloc.
The four most recent English language references read as follows$
Ref.111 J.S. Elliot, N.E. Hitchcock, E.D. Edwards.
Hypoid Gear Lubricants and Additives. J. of the Institute
of Petroleum, v.45, no.428, 219-235, 1959-
Ref.12t F.T. Barcroft. A Technique for Investigating Reactions
between E.P. Additives and Metal Surfaces at High
Temperatures. Wear, V-31 no.6, 413-500, 196o.
Card 4/5

32$30
Reducing the corrosivity of .... s/o65/61/000/012/004/005
E194/E135
Ref.14i R.B. Campbell, L. Grunberg. Study of reactions of metals
with sulphur and phosphorus compounds by pulsed
temperatures. Paper no.RICC/32 at the International
Conference on the use of isotopes in Physics and Industry
(Copenhagen, September 6-17, 1960). Izd. MAGATE, Vena,
,1961.
Ref.15t G. Hugel. Chemical nature of extreme pressure lubrication,
Lubrication Engineering, v.14, no.12, 523-526, 1958~
ASSOCIATIONt VNII NP
Card 5/5
'~X

NAGIBIKAO T.D.1 YASEKKOVAI L.S.j ALIKBEROVA,, G.I.; XORABLEV, Yu.G.j
KOZIN, V.S.; ZHAROVA, A.S.j VASHUNINA, N.D.
Phenol-containing SKDF-10 rubber. Kauch. i rez. 24 no.11:2-3
165. (KMA 19 a 1)
1, Institut organichaskoy khimil Imeni Zelinskogo AN SSSR i
Moskovakiy institut tankoy khimicheekoy tekhnologii imeni
M.V. Lomonoaova.

SOURUX W SAY1000=7000270007-
AUTHORI Negiblas, T. D.; Taseakova I At kka- If.-Uev, Tu. G-#
I -
ashunin x D
lk-wan ~Vr~p- uxnateo"s-Al. - -A ";V.45.. . a -W - 144
W SS514 Fla,
ORGS Instft'U'te Of Orsanic Chemistry In. Zelinski AN SSSR Institut organichaskay
khivdi AN SSSR); Moscow Institute of Fine Cmheid a
(Mookovokly Institut toWy kbfi~~skoy tekhnologit)
4),
TITIEs Phenol-containins rubber F-10
SOURCgi Kauchuk i resins, an. 11, 1965t 2-3
TOPIC TAGSs synthetic rubber* phenol containLng rubber, copolymer
ABSTRACTt Phano I-cont &Laing rubbere hrn been prepared by emulsion covoly"rization
at 60C of butadis" and dienthyl(winylethynyl)(4-hydroxyphenyl)mthanalt)-" the
presence'of di"oeminoboax"a and hydroquinons. The best chemical, physical and
mechanical properties were exhibited by copolymers containing 102 of I(SKDF-lO rubbe
IR absorption spectra indicated that copolymris&tion occurs via the double band of
1. SXDt-10 rubber* can be w1canised by such agents as sulfur, pbsool-formaldshyde
resins, or hexajothylsas tatrsniom. The formulation of the Kixtures, the properties
of the rubbers, vulcanization metbods, and the vulcanisate properties are described
In the source. The properties of KOT-10 vulcanizates are sLaLL&r to those of 101W
difte-stymo. ff~W30 canisates, but their fatIgue stren t) In cospression Is
IT,- 1.1p
Ceed 1/2 UDCt 676.762.2-134.647t546/547.07.00
r

ACC Nib AP5ffF6"-
tvice as high " that of M-30 vulcavisstes. 1M-10 Latex Laprepat Compost-
tions exhibit onhan#%W Adbaslou.
SUB ODDIt Kt/l,6-5sM DAM soom/ ORIC IM 003/ ATID PUiS:
i ~jl~v

KUZIP,TSOVA, A. I.: Master Chem Sci (dies) -- "The chemical characteristics of
the salt deposits of southwestern Tadzhikistan". Staliabad, 1.958. 19 pp
(Aced Sci Tadzhik SSR, Inst of Chain, Rostov-na-Donu Stata (1) '150 copies
(KL, No 13, 1959, 101)

OBIGBKINA, R.G.; KMIMrSOVA, Avle; BERGYAN, A,G*
Salt deposita of southern Tajiklotan. Report Ho.l: Survey, of
studies made of the salt deposits of nouthern Tajikietan. Trudy
AN Tadzh. SSR 84t137-145 159. (MIRA 13:3)
(TaJIkistan-Salt)

MVIVESOVA, A.I.; BERWIAN. A.G.
Salt deposits of southern Tajikietan. Report 71o.5: Classification of
nntural salt waters. Trudy AN TvLdzh. SSR 84:187-193 159.
(MIRA 13;1)
(TaJiMstan-Salt)

KMNLTSOVA. A.I.; BERGUN. A.G.
-
Salt deposits of southern Tajikistan. Report No.6: Salt deposits
of the Kafirnigan River basin. Trudy AN Tadzh. SSR P)~:195-212
'59. VIRA 130)
tKafirnigan Vallay-Galt)

XT.7zlip"'SoVA, A,I,i BERGRAY, A~G-
Salt deposits of scutherA Taiiklotan,'Report No.7s Balt
depogite of the Ukhah-Tovau Ooup and the salt lakes of the Dshiltkull-
Vishne-Pyudsh group, Trudy AN Tadsh, 8SR 84t213-22) 159,
(MIRA 131A
(TajWatan,--Sa1t)

DVORKIle-SAMMKIT, T.A.I_XUZUBTSOVA, A.I.
Distribution of certain rare and rare earth metals in granitoids,
and pegmatites of the northern Baikal region. Geol. i geofis.
no.5.:40-53 160. (MIRA 13:9)
1. Vostoohno-Sibriakiy filial Sibirskogo otdeleniya AN SSM
(Baikal region-Metals, Rare and minor)

B/007/61/000/002/002/004--
B107/B217
AUTHORS: Grudinin, M. I.v Kuznetsova, A. 1.
TITLEt Distribution of nickel, chromium, and cobalt in the gabbro-
peridotite rooks of the basin of the Tyi river (northern
Pribaykal'ye)
PERIODICAL: Geokhimiya, no. 2p 1961v 162-168
TEM The rooks of the NyurundukanBkiy and Davyrenskiy massif were studied.
The most important rooks ares dunite, consisting mainly of olivine poor in
iron (0 - 7~ fayalite) and of smaller quantities of enstatite or diopsides
apinel, magnetite, chloritep talcumt and serpentine; saxonitep consisting of
foraterite (70 - 80%), enstatite (20 - 2W, green apinel and magnetite
(2 - 3%); lherzolite, consisting of 60% olivine (up to 15% Fa), 15 - 20%
diopside (_15_T_caFeS'206)9 5 - 7% enetatite (5% FeSio 3), and approximately
1% light-green apinel and ore. Verlitep consisting of iron-magnesium-Olivine,
diopside and inconsiderable quantities of isometrical bytownite grains.
Peridotites with vein-like plagioclase separations have a kelyphite structure
Ca~rd~

3/007J61/000/002/002/004
Distribution of ... 3107/B217
and a complicated mineralogical compoeitiont besides olivine there are
diopside, enstatite, plagioclase, spinel, ore, and minerals which developed
on plagioclasep zoisitep epidotep albite. Small flakes of biotite (lepido-
melane) occur in the ultrabasitea of the Davyrenskiy massif, spinel is
lacking. The masoif is much more differentiated until the occurrence of
quartz diorites. Magnetite and chromium magnetite (a - 8-37 �0.01 A) occur
in the ore veins. Moreover, sulfide mineralization with pyrrhotite and
small quantities of chalcopyriteg pyrite, pentlandite, and sphalerite is
found. The analyste N. G. Taskina and L. V. Komarova carried out complete
silicate analyses of the most important rocks at the authors' institute
(Table 1). A. 1. Kuzneteova analyzed a series of samples quantitatively
for Hip Cog and Cr in the spectral laboratory of the Institute; accuracy
is +8 - 10%. Moreover, So, Sr, V, Pb, Zr, and W were found, the content
in the Nyurundukanskiy massif reaches hundredth % of Be and tenth % of V.
The mean values for the individual rocks of both massifs were calculated
from the determinations of Ni, Cog and Cr (Table 2). The connection be-
tween nickel and magnesium content is illustrated in Fig. 1 (Nyurundukanskiy
massif) and Fig. 2 (Davyrenskiy massif); the nickel content in the latter
rises in proportion to the magnesium content up to 30% M90 and remains then
C

Distribution of ...
:S/007/61/000~002/002/004
B107/B217
constant. This is connected with the formation of sulfidesp into which
nickel enters preferably. Purthermorep Hip Cr, and Go were determined in
olivinesp orthorhombio and monoolinic pyroxenes, and in the magnetic frao-
tions (Table 3)- No massif shows considerable 'chromium enrichmentl the
high content in olivine is due to the mechanical addition of ore. The change
of the chromium content with the MgO content in the Nyurundukanskiy massif
is parallel to nickel; in the Davyrenakiy massif, the chromium content con-
tinues rising also over 30fa MgO. The cobalt content rises only inconsider-
ably. The Nyurundukanskiy massif has less cobalt but more chromium and
nickel than the Davyrenakiy massif. The ratio Cr)Ni>Co in the dunites indi-
cates that the latter formed earlier than the basic rocks. This fact was
pointed out by V. V. Lyakhovioh* There are 2 figures, 3 tables, and 4
Soviet-bloo',refetehobb.,:.
ASSOCIATIONs Vostochno-Sibirskiy geologicheakiy institut SO AN SSSR (East
Siberian Geological Institute of the Siberian Branch of the
AS USSR)
SUBMITTEDs April 259 1960

KUWETSOVA, A.1s, asalatent
GrItIrilsin of tl;e rIght-wing joc-lalicts and thalr views cn the
ol tuati on of the working clai33 of France. Trudy LIVT no,492
1 3-80 164 (IMIRA IBO)

A U L R P r ~ju V 1-1 , -7, . ;& .
Dissertation: "Questions of the Dynamics in a Chain-Drive Gear.* Cand Tech Sci,, Moscov
Machine Tool and Tool Inst imeni I. V. Stalin, 23 Jun 54. (Vochernyaya Xoekvat Hoecov,
14 Jun 54)
SO: SUM 318v 23 Dee 1954

EFROS, S.M.; FOYCHINOVA, Ye*S.; fUNETSOVA, A.K.
Determination of zinc and nickel ions in an electroly-tic bath of
nickel black. Trudy LTI no.48:169-174 '58. (MIRA 15:4)
(Zinc--Analycis) (Nickel--Analysis)

28204
jl~ 27 S/194/61/000/005/026/078
D201/D303
AUTHOR; Kuznetsova, A.K,
TITLE: Analysis of stresses in structural elements-using
the WY -6 (EMBU-6) electric integrator
PERIODICAL: Referativnyy zhurnal, Avtomatika i radioelektronika,
lio. 51 1961, 349 abstract 5 B245 (Tr. 1-y mezhvuz.
nauchno-tekhn. konferentaii po elektr. modelirovan-
iyu zadach stroit. mekhan., soprotivleniya material-
ov i teorii uprugosti, B.m. Novocherk. politekhn.
in-t, 1960, 70-79)
TEXT: The problem of applying the electric integrator EMBU-6 to
solving problems of the theory of elasticity as described by a bi-
harmonic equation is considered. A short description of the inte-
grator is given and the procedure in solving the problem is ellain-
ed. The following problems may be solved by the inte ator: I Dis-
tribution of stresses at corners of massive. frames; 2FDetermination
Card 1/2

AM
S/194/61/000/005/026/078
Analysis of stresses... D201/D303
of stresses around the openings of water discharge tunnels under
the influence of hydrostatic pressure; 3) Analysis of stresses of
the head of a massive counterpart dam; 4) Analysis of thin rectangu-
lar plates for bending by transverse loading etc. The solution of
such problems by using the electric integrator takes e- 1-2 man-
weeks and the accuracy obtainable is 3-57a. Certain deficiencies
of the electric integrator are pointed out. 4 figures. 7 references.
Z-Abstracter's note: Complete translation,-7
Card 2/2

M ~~ ~ ~--- -- - - I- - ~-,-- --- - . -- ---- --- - -,- .- - -77--,-
w -------
- ~, -- k

VARVAKp P#M*, profe, doktor takhn.nauk, stershly nauchnyy sotrudnik;
GMIRXAV, 1.0., stars'hiy insh.; MIROMMICHMO, N.M., Insh.;
PRBMCHMSKIY, N.D., insh.j Prininali uchantlye: AMM, I*Yao,
starshiy nauchMy sotradnik; DLUGACH, M,L, starshiy nauchnyy
sotrudnik,, PGBYRI, 3.A., insh.: - =---kQYA A K Inzh.; PETRA-
L.=A-- 62A
SEMNI, R.N., insh.; WMAN, Ya.L., red,
lxd-va; LABINOVA, N.N., red,izd-va
(Tables for designing rectangular slabs] Tablitsy dlia rasohata
priamougollnykh plit. Pod red. P.X.Varvaka. Kiev, lad-vo Akad.
nauk USSR, 1959, 418 p, (KIRA 12M)
1. Institut atr'o'itellnoy mokhaniki Akademii nauk USSR (for Varvskj
Guberman. Amiro. Dlugach). 2. Voonoyusnyy proynktno-isynketellskly
i nauchno-isaledovatellskiy institut "Gidroproyektm im. S,Ya.Myuk
(for Hiroahnichenko, Predtachanakly, Bobyr', Kumeteove, Petraahanl,,
Sokollakly).
(Concrete construction-Tables, calculations, etc.)
(Concrete slabs)