SCIENTIFIC ABSTRACT KUZNETSOV, V. A. - KUZNETSOV, V. A.

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• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

U- INJ E T o v V
ARTYI.TKHOVP 0. Y., MOGILIFER, A. I., PRONCROV, V. A.
V. Y., C!U%-Rr-X)V, L. A. ANI LFYP INI'XIY, . 1.
"ExreriTnental studies of some of the physical features of
Jeryll-5um-noderated intermddl-ate reactors."
Report su,mitted for the IkEA Seminar on the Physicz5 of East ;Md Inbernediate
Reactors, Vienna, 3-11 Au(":, 1961-
Acad. Sci. USSR Moscow

KUMETSOV, V. A.; CILD-UUV) L. A----
"Experimental studY Of Some methods of compensation of high excess reactivity."
report submitted for 3rd Intl Conf) Peaceful Uses of Atomic Energy, Geneva,
31 A149-9 Sep 64.

MNETSCYV, V.A.
Symposium on exponential and critical "rimenta. Atom.
energ. 16 no.2t171-172 7 164. (MIRA 170)

V.A.
14-1-11

P"'023370 Investigation of the Surface Tension of the Alloy
Lasul-Codmiunt on the Boundary Wills in Iten Eutectics
LICI-KCI apol In Vacuum. (Russion.) It A Wuyti,fwv~ %I I
kok ond
Y, lit I
'
1W
Ar
&R
a
u
. 2, no.
un k b5btf. Uct. 21, IU3:J, p. 1197-
1199.
Investigates clectrocapillary phenomena Of 5UTfaCC tcnsion in
vacuum. All measurements were made at temperatures

bovo 450C. Graphs. 11 ref.
:

.5 C-N V ) V - 01
UW1 Cbeemistry - ftysical chemistry
--------------- 4-UL,
Authors 4 Kumetsov, V. A.; Ashpur, V. V.; ard Poroshina, G. S.
="~- A aim,
Title face tension of thallium amalgam in a vacuuia
ierlodical 1 Dok. AN SSSR 101/2j 301-304, Nar 3.1, 1955
I The surface tension of thalliwa amalgam was investigated in accordance with
the method of maximum pressure in the drop 6y means of a special: gravitation
instrument. The minimum observed on the iao-%"hermal curves representing the
surface tension of the investigated thalliun, amalgam is explaineds first by
the relatively small difference in the surface ten'sion of the amalgam cam-
ponent and secondly by the reaction between the amalgam components. An
Increase in temperature reduces the rate of reaction# and the m1nimum on
the surface tension isotherms is equalized. Nine U&9R references (1928-
1953). Graphs.
Institution i The A. H. Gorkiy Ural State University) Sverdlovsk
Presented byt Academician A. N.' Frumkin, October 1, 1954

KEMUTSOV, V.A.; GROAROVA, I.G.
Causes of the foaming of pickling solutions. Zhur.prila.Wm. 29
no.5:688-692 Xy 156. (XLU 9:8)
1. Ural'skLy go~uMwstvonW universitst Imeni A.M. GorIkogo.
(Xistals-Pickling)

5(2), 24M SOY/156-59-2-12/40
AUTHORS: Kuznetsov, V. A., Zagaynovaq L. 3. Klevtsova, It. P.p
TITLE: The Investigation of Electrocapillary Phenomena on Thqllium -
Gold Alloys ( Iseledovaniye elektrokapillyarnykh yavloniy na
splavakh talliy-zoloto)
PERIODICAL: Nauchnyye doklady vysehey shkoly. Khimiya i khimicheekaya
tekhnologiya, 1959, Nr 2, pp 268-272 (USSR)
ABSTRACT: The dependence of the potential maxima of the electrocapillary
curves upon the composition of the metal alloys has not yet
been clearly fixed. The papers by S. V. Karpachev, A. G.
Stromberg and collaborators (Ref 1) with amalgams are mention-
ed. The present paper deals with the investigation mentioned
in the title at 4500 and a gold content of the alloy of
between 0 and 46% by atom. Thallium was supplied by the
Chimkentskiy ovintsovo-tainkovyy zavod (Chimkent Lead- and
Zinc Works . A eutectic mixture of lithium- and potassium
chloride served as electrolyte. Figure 1 shows the electro-
capillary curves for thallium and thallium. - gold alloys.
They show that the addition of gold leads to an increased
Card 113 surface tension at the boundary alloy - electrolyte. With in-

SOV/156-59-2-12/46
The Investigation of Electrocapillary Phenomena on Thallium -- Gold Alloys
creasing gold content the maximum of the electrocapillary
curve shifts in positive direction. A. N. Frumkin (Ref 4) ex-
plainc this shift of the potential of the zero-charge by the
fact that the added metal (gold) occupies a certain part of
the surface layer. The surface density of thallium, and gold
are calculated on this basis according to the formula of
Gibbsj it is shown by table 1. The adsorption of Au becomes
more and more negative with increasing gold content. For
the composition of the surface the equation of E. A. Guggen-
heim and N. K. Adam (Ref 7) was used. Table 2 gives the sur-
face concentration of TI and Au and the degree of occupation
of the surface layer.,With increasing gold content in the
alloy the degree of occupation of the surface by Au rises and attains
0.28 at a gold content of 45.9% by atom. The approximation
character of the calculation - which is carried out on the
assumption that the dimensions of the TI.- and Au particles
are equal in the surface layer and in the alloy - is regarded
as justified by the fact that the deviations of the Tl-Au-
alloy from the law of the ideal solution are inconsiderable.
Card 2/3 This is shown byfigure 2. It is, therefore, possible to

SOV/156-59-2-12/48
The Investigation of Eleatrooapillary Phenomena on Thallium - Gold Alloys
neglect the effect of the mentioned differences. The average
value of the potential of the zero charge referred to one
electrode of melted lead in a euteotic mixture of LiCl and
KC1 was found to be equal to -0.28 v . The authors thank
Academician A. 11. Frumkin for the interest he displayed In
their work. There are 2 figures, 2 tables, and 10 referencest
9 of which are Soviet.
PRESENTED BY: Kafedra fizicheskoy khimii Urallskogo gosudarstvennogo, uni-
verniteta imo A. M. Gor1koeo
(Chair of Physical Chemistry, Ural State University imeni
A. M. Gor'kiy)
SUBMITTED: July 22t 1958
Card 3/3

21, (7) SO-1/78-4-4 -26/4-4
.AUTHORS*, Zvyagintsevp 0. Yet, Kuznetsovg V. A.
TITLE: On Complex Compounds of Hexavalen'. Uranium With Hydroxylamino"
(0 komplekanykh soyedineniyakh shestivalentnogo ura,.ra s gidro-
ksilaminom)
PERIODICAL. Zhurnal neorganicheskoy khimii, 1959, Vol 4, Nr 4, PP 8641-866
(USSR)
kBSTRACT- The authors investigated the complex formation of hexavalunz,
uranium with hydroxylamine in dependence of the pH "ialuc of t-1-e
solution. When mixing A solution of uranyl nitrate with F. nout-ral
solution of hydroxylammonium, chloride or hydroxylammonzium
sulphate with a PH value of 8 and more, uranium is retained as
a complex in the solution. At PH < 8 yellow, difficultly so!v_ble
crystals are formed. These crystals are insoluble in some -c:z-
ganic solvents. The formula rNH OH) UO H 0 resulted f_= tho
. 3 2 4 2
analysis. The complex solution of hydroxylammonium. uranate
(pH,,', 8) remains stable for several months. From these
uranium cannot be reduced or precipitated even by the actioz, :~f
Card 1/3 alkali liquor at high temperatures. In the case of a largo ex-

SOV/78-4-4-26/44
On Complex Compounds of Hexavalent Uranium With Hydroxylamine
ceso of hydroxylamine and a pH value of9.5 li,5ht absorption cor-
responds to the Lambert-Beer law. With the action of metharoiic~
hydroxylamine on an alcoholic solution of uranyl nitrate an
amorphous precipitation of the composition IF130~12UO4 ccc-lre'
The authors synthesized alkali salts of the uranyl-,~qd_ro_,-.y1arin,_
compounds in a ratio of Me ; U - NH2 OH = 1 : 1 : 2 (Mt., ~ thc 1 on ut'
the alkali metal). Further, the authors prepared the siailex
uranyl compounds with hydrazine, mono-, di-, and trimethylamine,
di-, mono-, and triethylamine as well as ethylenediamine. No
detailed experiments were made with this compounds, The fa7low-
ing formula is suggested for soluble complex compound3 of tha
uranyl ion with hydroxylaminei
Me ONH 3 U0 4]
1HONH 3
The dilute aqueous solutiori's of pure compounds of this com-
position can be hydrolyzed with the formation of sodium uraraiCc,
The authors investigated some properties of the compounds ,,u^-h aa
Card 2/3 solubility, density, and electric conductivity. The alectri('.-

f, SOV/78-4-4-26/44
On Complex Compounds of Hexavalent Uranium With Hydroxylamine
conductivity of the compounds with Me = Nat K is given in a
table. There are 1 figure, I table, and 7 references, 1 of
which is Soviet.
SUBMITTED: November 5, 1958
Card 3/3

SOV/80-32-2-48/56
AUTHORSs Kuznetsov, V.A., Antipina, A.A., Buryakovskaya, R.I.
TITLE: Investigation of the Specific Electric Conductivity of Aqueous
Solutions NaClea + NaOH in the Temperature Range 75 - 950C
(Issledovan ye uAellnoy elektroprovodnosti vodnykh rastvorov
NaCl.NAS + NaOH v oblasti temperatur 75 - 950)
PERIODICAL: Zhurnal prikladnoy khimii, 1959, Vol XXXII, Nr 2,
PP 456-458 (USSR)
ABSTRACTt The specific electric conductivity of saturated NaCl + NaOH
solutions is very important for the electrolysis of salt
solutions. Experiments were carried out at temperatures of
75, 80, 85t 90 and 950C. The results are shown in a table.
There is 1 Soviet reference.
ASSOCIATIONt Ural'skiy GosudarBtvennyy universitet imeni A.M. Gortkogo
(Ural State University imeni A.M. Gor'kiy)
SUBMITTEDs September 23, 1957
Card 1/1

5 fk 4) 1,4r r-,
SOV176-1-'3-?--16
IISA
AUTHO, ,
K,.iznetsnY, V. A.p D'yaIkovaj T, D., Mal't3S7a PO
, V.
TITLB's luves'~Aigatlon of Electrocapillary Phen=,era ir, Bismuth -
C64mii;z Allcys and of the Surface Tersion of Thess AlIoys 'in
Va,l,x-m
PORIODICALt Zhirnal rizicheakoy khimii, 1959P Vol 33, Nr 7, pp 1551-1559
(USSR)
ABSPRAM In spite of sqveral papers devoted to ojectr,;capillary
phenomena (EP) of alloys (A)t some problems have n,-,t ys,,t been
solvel 9-j-1h as are the influenoe exoroisel by the alloy oompo-
all-.,Un upon the potential maximlip. of tIv,;- electrocapillary line.
I-- adIdition. to an investigation of (EP) a study of the surface
tpns~on of (A) would be oonvonlent~ aspeAally a oomparison of
f,h.,-: adscrption phenomenfA at the bourdar'ea be-~w4en mets! -
61ectrolyte and metal - vacuum. Pertinent ir7estigatlone wcre
c,arT'.od out on the bismuth - cadmi,=i alloy, using a autr-:-;tt,.,
LICI .. KCI melt as an electrolyte. The ~Ientroaapillary lines
were plotted by means of a capillaTy elect:romete-- (Fig "). The
allcy-surfaie tensi3n was measur9d by the method of maximum
piess-urA -in the drrpp (Ilefs 31 10)) on a ao-,~alled cravitation

Card 113 , A speciall
davioe d3signed by P. P. Puga:,,hev,'.rh (Refs 42

I,vjP '7_,l
:f Elo-:~trccajillary Phenomena, in SOV/76-33-0 .6/40
Cadm--`.~jnn Alloys and of the Surface Tension of Tbese Alloys in Va-=Lm
glass vesael (Fig 2) was used fr)r ani a method --ailler dsBn.T!.Ihe.I
w9a appliel ta a determinati-:-r- of the density of the all-~y unde7
dllsccussi~)n. M. YagofaTova assist--td in 'he last-mentioned
measurements. The (EP), sArTa,,,e tensl~)n "ST), and density (D)
k (EF), Tab!-)a
W-are Investigated(at 450 Ce Reaults (Tab,1116
^ A An
f~v , . , (ST) and D) lea tc ths f,.,I'A.nwirg
lr.(~:T-Eiseing Bi zoncentration. in the (A) reduftes the (ST) at the
bounda.- between the (A) and ~he elpatroypte as ciiII as in
The (ST~ is most strangly Toduce4 at low BI -~Y--i4rtTaticnsq at
wh1oh also the potuntial maX4MUM Lf th,~
A t_o~apjjjary lines
(EL) is strongly abifted in tyh,~- opposits- diraction. Calculations
of the adsorption r BI at the boundary bot-ween (A) and
olert:rolyte at the Potential maxJmwr, (PM) )f the (EL) indicated
that there exists a linear de;endenae between the shift of the
(PM
of the fEL) and the surface ocn.~,-.nt ration oi, . The authorq
then explain measurement rosl-,Its cn. the (ST) in vacuum in
,onneo
tion with modern theorias sf the (ST' of binari systems,
and raloulate the (ST) isothermal lines by an equation Civen in
Card 2/3 reference 5. The essential dlfforen~e betmeer. the exper.1mentally

jrn-estigafio.n of Electrocapillary Phenomens, in SOY/76_7 3-7-16/40
.11
Bismuth - CadmIum Alloys and of the Surface Tension of These Alloys in Vaculit
Cbtalned and calculated (ST) values (Table 3) is explained by
interatomic reactions; the authors further give an explanation
of the difference between the individual interatomi3 distances
in the surface layer and inside the (A). The similar!t~- between
the isothermal lines of the (A) surface tension in vacuum and
at the boundary between the (A) and the electrolyte indicates
eq~;al composition of the (A) surface layers in both casee.
There are 6 figures, 3 tables, and 19 referenoes, 17 of which
are Soviet.
ASSOCIATIONs Urallskiy gosudarstvennyy universitet im. A.M. Gortkogo
Sve-rdlovsk (Ural State University imeni A.M. GorIk!,y,S-TPrdlovsk)
SUBMITTEDs vaniiE~ry 2, 1958
Card 3/~

IM
50)
AUTHORS: Kuzneteov, V. A., Aksenov, V. I., SOV/20-128-4-35/65
TITLE: Zero Charge Potentials of Tellurium-Thallium Alloys
PERIODICAL: Doklady Akaiemii nauk SSSR, 1959, Vol 128, Nr 4,
PP 763-766 (USSR)
ABSTRAM. The system Te-Tl was chQsen because the two components
- according to data by S. Karpachev and A. Stromberg (Ref 1)
have very different zero charge potentials facilitating the
determination of the dependence of the zero charge potential
of an alloy on its composition. The zero clLirge potentials
were determined by investigating the electrocapillary
properties of the liquid metals and alloys. The potential
of the capillary electrode 8 Was referred to an electrode of
fused lead, the experimental temperature was 4750. Figure 1
shows the electrocapillary curves of the two components and
their alloys. An addition of T1 (up to 25 atom%) to Te
lowers the maxima a max of the electrocapillary curves. At
a high content.of Tl, amax increases again. Similar observa-
Card 1/3 tions were made by A. N. Frumkin and A. V. Gorodetakaya (Ref 4)

Zero Charge Potentials of Tellurium-Thallium Alloys SOV120-128-4-35165
on the electrocapillary curves of Hg and T1 amalgam. They
explained thie phenomenon by the fact that the field of
the electric double layer influences the adsorption of the
alloying constituents in the surface film. Figure 2 shows
the dependence of the zero charge potential on the composi-
tion of the alloy. With an increasing content of Tl, the
zero charge potential shifts in the negative direction.
According to A. N. Frumkin, this is explained by a varying
charge of the T1 adsorbed on the surface film. 0 2 is
determined - the fraction of the surface film occupied by
particles of the second component (Tl). From the equation
da max r 1dp, - T12dP2 ( "l - Gibbs' surface density of
Te, r2 the same for TI, 91' P2 - chemical poten 's tor
Te and Tl), an equation is derived for P - 0: Q ).tL1CFjLax
1 2 dP2
The activity of T1 was determined by measuring the 414atro-
motive force of the concentration chain Tl/eutectic mixture
LiCl +XCI + 2% by weight of TlCl/alloy Tl-Te. The measure-
Card 2/3 ment results are given in table 1. Figure 3 shows the

Zero Charge Potentials of Tellurium-Thallium Alloys BOV/20-128-4-35/65
dependence of F(1) on the alloy composition. A: strong
2
deviation from Raoultts law is ascertained. This suggests
that the surface film consists of dipoles and is not mono-
molecular. Similar phenomena were observed for the Tl amalgam
by A. N. Frumkin and N. S. Polyanovskaya (Ref 6). Therefore,
the potential shift for mono- and bimolecular layers was
computed (Table 2), the assumption of a bimolecular layer
showing a better agreement with the experimental data. The
computation of 0 2 confirms the assumption made by A. N. Frum-
kin (Ref 4) stating that the shift of the zero charge
potential is directly proportional to the fraction of the
surface film occupied by the metal added. There are 3 figures,
2 tables, and 7 references, 6 of which are Soviet.
ASSOCIATION: Urallskiy goaudarstvennyy universitet im. A. M. Gor1kogo
(Ural State Univer-Ity imeni A. M. Gor'kiy)
PRESENTED: April 13, 1959, by A. N. Frumkin, Academician
SUBMITTED: March 5, 1959
Card 3/3

URABASIT, A.G.; HDSXfZV. L.I.-.- EUZIIMSOV, V.A.
Coextraction of trace elements in the extraction of chlorides vith
ether. Zhur.neorg.khim. 5 no.6:1358-1365 Je 160. (MIRA 13:7)
OEttraction (Chemistry)) (Chlorides)

3/076j60/6'34/05/23/038
/P BO1O/BOO2
AUTHORS: Kuznetso Zag ovat Lo Sot Ivanovaq Go Poo
'tie r-t-sova. M. -P6
TITLE: Investigation of Rlectrocapillary PhenomenYin Tellurium
Gold Alloys
PERIODICAL: Zhurnal fizicheskoy khimiiq 19609 Vole 34g No- 59
PP. 1077-1082
TEXT%. Investigations of electrooapillary phenomena in pure liquid metils
had already been carried out by S. V. Karpaohey. A, 0, Stromberg,
-1Qob.9rRin# Yy. P. lordan,, E. N. Rodi&in , V, A. Smirnov, and L,. I.
Antro-oov.-'It was found among other things that a sh-Rtof the potentials
of the zero charge is directly proportional to the concentration of the
added metal in the surface layer* To confirm this statement, the authors
of the present paper investigated the electrocapillary phenomena of Te.-Au
alloys at 485 0C in the concentration range of 0-44 atoo Au. The tellurium
activity was determined by the Knudsen method. Results of investigations
(Fig. 1, electrocapillary curves) show that the addition of Au to Te leade
to a rise in the surface tension between the phases. The potentials of the
Card 1/2

Investigation of Elootrocapillary Phenomena S/076j6O/O34/O5/23/O38
in Tellurium - Gold Alloys BO10/BOO2
peaks of the eledtrocapillary curve do not change with the alloy composi-
tion and are in agreement with the potential of the peak of the olactro-
capillary curve of pure tellurium (i.e., 0.6 v with respect to an electrode
of molten lead). This fact is discussed on the basis of the theory worked
out by A. N. Prumkin concerning electrocapillary phenomenal and is explair_s~
by the fact that gold occupies the surface layer to a low degree only
(maximum 5%), The adsorption of To and Au, as wall as the degree of thoir
surface layer occupation were calculated (Tables I and 2)o Tellurium is
adsorbed positively and gold negatively in the surface layer, i.e., gold
is considerably more surface-inaotive than tellurium. A paper by A. V.
Gorodetakaya and Ra M. Vasenin is mentioned in the text. There are 2
figureag 2 tableaq and 11 raferences: 8 Soviet, 2 German., and I Engliah.
ASSOCIATION: Ural'skiy gosudarstvennyy universitet im. A. M. Gortkogo,
Sverdlovsk
(Ural State University imeni A. M. Gorlkiy, Sverdlovsk)
SUBMITTED: July 21, 1958
Card 2/2

81576
S/076/60/034/06/31/040
BO15/BO6i
AUTHORSt Kuznetsov, V. A. Klevtso va, M. P., Zagaynova, L. S.,
vayntraubt L-73. Korobova, T. A. kSverdlovsk)
TITLE: Investigation of Contact Potential Differences Between Sn and
Sn-Te Alloys and the Eleotrocapillary Phenomena on Sn-Te
Alloys
PERIODICALs Zhurnal fizioheskoy khimii, 1960, Vol. 34, No. 6v
pp. 1345-1350
TEXT: On account of his investigations of the electrocapillary phenomena
on thallium amalgams (Ref. 1), A. N. Frumkin estiblished that the dif-
ference in the potentials between the metals in the point of zero charges
is similar to the differences in the contact potentials between the same
metals in a vacuum. Experimental tests of this assumption were carried
out several times as by S. V. Karpachev and A. G. Stromberg (Ref. 2),
0. Chaltykian and M. Proskurnin (Ref. 3), and V. A. Smirnov and L. I.
Antropov (Ref, 4); few reliable results were, however, obtained. In this
case the above examinations were carried out for this reason, as it was
Card 1/3

81578
Investigation of Contact Potential DifferenOe8 3/076/60/034/06/31/040
Between Sn and Sn-Te Alloys and the Eloctrc- B015/BO61
capillary Phenomena on Sn-Te Alloys
to be assumed that tellurium would be surface-active with respect to tin,
and thus a large difference in contact potential between Sn and Sn-Te
alloys can be detected at low tellurium concentrations. The measurements
were carried out at 4500C and sz~jo-5 torr in an apparatus (Fig. 1)
similar to the one in Ref. 3, and a special ampule (Fig. 2) was used.
The vacuum contained a iRH-461M (VN-4619) preliminary vacuum pumpj an
MM-40A (MM-40A) diffus on pump, and %JBT-2 (VT-2) thermocouple- and
,~U-3 (VI-3) ionization-vacuum gauge. Yin purified by zone melting from
the Sverdlov 'skiy reaktivnyy zavod (Sverdlovsk Reagent Works) was used.
The potential differences were determined by the method of the displace-
ment of the diode characteristics. The diagrams obtained (Figs. 3, 4)
of the differences in the contact potentials between Sn and Sn-Te alloys
with 0.02 and 0.15 wt% To show that the difference is 0-07 v or 0-15 v,
The electrocapillary curves (Fig. 5) for Sn and Sn-Te alloys of the
above concentration show that according to expectations, To is surface-
activ'e with reference to Sn. The potentials of the zero charge are thus
shifted to positive values, and the size of the shift is similar to the
difference in the contact potentials between Sn and the above Sn-Te alloys
Card 2/3

'1578
Intestigation of Contact Potential vilferenc-.3j 8/076/60/034/06/31/040
Between Sn and Sn-Te Alloys and the Electro- B015/Bo6i
capillary Phenomena on Sn-Te Alloys
(Table). Finally, Academician A. N. Frumkin is thanked for his advice,
and the collaborator of the Institut elektrokhimii A14 SSSR (Institute
for Electrochemistry of the AS USSR) N. A. Shurmovska-va as well. A paper
by M. V. Smirnov (Ref. 5) is referred to. There are 5 figures, 1 table,
and 12 references: 11 Soviet and 1 American.
ASSOCIATION: Urallskiy univereitet im. A. M. Gor1kogo (Ural University
imeni A. M. Gorlkiy)
SUBMITTEDi October 109 1958
Card 3/3

KUZNETSOV, ZAGABOVA, L.S.
Zero charge potential if indium. Zhur. fiz. khim. 35 no,7:2640
ji '61. (MIRA 14:7)
1* Ural'skiy gowidarstvennyy universitet im. A.M.Gorikogoj,
Sverdlovsk.
(Indium-Electric properties)

23815
e1/020/61/138/001/020/023
B101/B231
AUTHORS: Kuznetsov, V. A.v Zagaynova, L,. S., Loginova, N. P.,
I;~,MtEieva, I. Ya~, Onopriyenko. N. S., and Tsimbal, L. Ye.
TITLE: Contact potential differences between some liquid metals and
their alloys
PERIODICAL: Doklady Akademii nauk SSSR, v. 138. no. 1. 1961, 156-158
TEM This is to continue the authorn' researoh on contact potential
differences between liquid metals and their alloys (ZhFKh, 34, 1349 (1960)),
The contact potential differences were determined thermoele;,-tronically by
recording the volt-ampere oharacteristios of a diode with once the pure
metal and then the alloy being used aa anode., Based upon the assumption
that the contact potential difference is approximately equal to the
difference of the zero charge potential and on the grounds that there is
a great difference between the zero charge pot,-rittals. it appears
advantageous to determine the contact potential differeac~- (CPD)
partioularly between Zn, Cd. T1, and Bi on the c)re hand, and their
respective alloys with Te on the other,. Difficulties that arose were due
Card 1/t

23817'
3/02 61/1~8/001/020/023
Contaot potential differencei betwe-!n_ B 101 YB2 31
to the fact that Zn and Cd hal~,e an "xcessively high vapor pressure and
that a number of these metalA, innlu5!va of Bi. form zompounds with Te.
The oontadt potential d ifference was, therefore, datermInted : 1) for Sn
and Sn-Tl alloy (23.8 % TI) (Fig,, 1); 2) for T) and TI -Sn alloy (49.8%Sn)
(Fig, 2A); 3) for TI and TI-Te alloy (50,9 % T-3) ~Fig. 2b); 4) for Bi and
Bi-Te alloys (3.6 ~5 Te and 9 Yo TA)~ Bi. and Sn were to be filed mong the
purity ~,lass 8-3 (V-3); TI contained about 0.02 % of Fe, Pb, and Cd
impurities (speLtroscopicaily d-;termit:ed by R. Gutkl na). Te was twice V<
distilled in a vacuum. All the measurements were made at a temperature
of 4500C, The method appliod was d,~aTr-'Lbid it. the above-mentioned
reference. Results; for Sn/Sri. iTl. CPD~0.17 vj for T1/T1 -Sn CPD.O..25 V1
for T1/T1 +Te CPD-0.65 v; fr.~.r Bt/Bi iT,~~ CPD=0.3 and 0.35 v, respectively.
Fig. 3 shows the zero ~;harge potentia'Is for SA-Te alloys as a function of
their composition. This implies that the CPD between the metals and their
alloys under consideration is close to the difference of the sero charge
potentials, which has proved to be valid also for Bi/Bi Te ifference of
zero charge potential with 3.6 % To equal to 0.25 v, with 9 ~Te equal to
0.33 v), The fact that the volt-ampere characteristics of TI-Sn, Tl-Te,
and Bi-Te alloys are shifted In pcsitive direction indicates that the work
Card 2/0

23815
ootential'differences betreen...
Conact 3101/3231
-is greater.than in, pure ftietal. In conformitly
lunction in these alloys
w4th the z
ero charge potential difference (Fig. 3), Sn-Tl alloy shozo
'he opposite effect. The authors*thahk Acadea4cian A. ". Frumk-n fox a
discussion. There are4'figures'and 5 references: 4 Soviet-bloc and
non-Sov iet -bloc.
im. L. Gortkogo
-ASSOCIATION;- :Urall.skiy go.sudarstvennyy univer8ituet
.(Ural.State University im. A. M. Gorlkiy)
?RESENTED: December 10~. 1960, by A. N. Frmkin, Academician
SUBMITTED: November 25t, 1960
Card 3/0

KUZNETSCV, V.A.; SINYANSKAYA, R.I.; PORTNAYA, G.N.; VOLYNSKAYA, M.P.
Blectrocapillary phenomena in Te-Ag anoys and surface tension
of these alloys in a vacuum. Izvovys,ucheb,zavo;khim#i khimetelch,
5 no, ,3:428-432 162o (AURA 15:7)
1. Ural'okiy gosudarstvennyy universitet, imeni A.M. Gorikogo.,
kafedra, fizicheskoy- lehi m4 i .
(Tellurium-silver alloys)
(Surface tension)
(Blootrocapi3-lary phenomena)

KUZKMOV, V,.kj.;,.POPOVA, I.B.; DUPLINA, L.N.
Electrocapillary phenomena on Tl - Bi al-loys and their surface
tension in a vacuum. Zhur. fia. khim. 36 no.4:880-884 Ap
162. (KM 15:6)
1. Ural'skiy universitet.
(Eleotrocapillary phenomena) (Thallium-bismuth alloys)
(VaoUUM)

3/076 1 100110191023
,/63/037
B101/Bia6
AUTHORSt Volynskaya (Kievtoova), M. P.,. Kuznetsovj_ V. A., Balanoval S.A.
TITLEs Electrocapillary effects on Tl-Sb alloys
PERIODICAL: Zhurnal fizicheskoy khimii, v. 37, no. 1, 1963, 18-6 189
TEXTt Tl and Sb, chosen because their zero-charge potentials differ con-
siderablyl were used to investigate the deperidence of the zero-charge
potential on the composition of binary alloys. The zero-charge potentials/
of TI and Tl-Sb alloys were determined from the maximum potential of
electrocapillery curves at 4750C. A mixture of-molten LiCl-KC1 served as
electrolyte and molten lead as reference electrode. Since a solid phase
precipitated at 4750C it was not possible to investigate alloys containing
more than 63 at% of Sb. The emf of the-galvanic elements, type
Tl_ jLiCl-YCl + 3% by weight TlClj Tl-Sb alloy, was.measured in order to
determine the activities of Tl and Sb. The curves representing the activi-
ties differed only slightly from Raoultos law. The electrocapillary curves
show that the surface tension acting on the interface alloy-electrolyte de-
creases with increasing content'of Sb, and that the zero-charge potential
Card 1/2

8/076/63/037/001/019/029
Electrocapillary effects on Tl-S~ alloys B101/Bj86
shifts toward the positive direction. The adsorption of TI and Sb at tho
surfaceg the gurfaoe concentration of the t-no oomponento and the portion 0
,
,of the surfooo oooupiod by the two components are calculated. The following
Valuee are given for the Sb continent given in atomic parts (G TV9Sb)*- 0.05,
zero
o.30, 0.67. The
40, 0.52, 0.47; o.63,
0.82, 0.15; 0.20, 0.65, 0.33; 0?
.
1
0 + Yo
.charge potential was calculatedlfrom the equation A9`- y
l1 Tl
a
O
o
i
For the 5b"'content in atomic parts, 0 90
- 9
)*Q
' 9
(?
S
b
T
1
Sb
r
1calcul and expe
-0-31, -0-42;
are given; 0-05, -0-45, -0-53;:*0.'20, -0.39, -0-46; 0.40,
.
.
o.63, -0.20, -0-30. The discrepancy between the values of TO as calculated'
and those obtained experimentally is attributed to,the fact that the applied '
equation takes no account of a certain type,of interaction of the alloy co.m-
ponents. There are 4 figures and-2 tables.
ASSOCIATION: Urallskiy gosudarstvennyy univerBilet im. A. M. Gor1kogo
(Ural Stat.e University imeni A. M. Gorlkiy)

SUBMITTED: October 28, 1961 17,

Card 2/2

KUZNETSOV,, V.A.; ZAGAYNOVA, L.S.; DIYAKOV, A.A.1 XOTEGOVA, A.A.
Eleatrocapillary phenomena on zinc-tin alloys and the surface tension
of these alloys in vaouo. SlektrokhImiia 1 no.6t676-681 Je 165.
(KRA 18:7)
1. Urallskiy gosudarstyemyy un iversitet imeni Gortkogo.

KUZI.TTSOV,, V.A.; PA11TELEYEVO, V.V.
Hydrotherral synthesis of rutile. Kriatallografiia 10 no.3:
445 MY-Je 165. (MMA 18 -.7)
1, Institut kristallografli AN SSSR.

S/07o/62/007/002/022/022
4-/ WOO E132/El6o
AUTHORS: Shternberg, A.A., Kuziminal I.P., and Kuznetso,-i.~
TITLE: Apparatus for growing single crystals from the
melt tinder pressure
PERIODICAL: Kristallografiya, v-7, no.2, 1962, 334-336
TEXT: It is difficult to grow crystals of ZnS from the
melt because of the high vapour-pressure of the components.
A closed furnace, with Mo wire heaters Zr02 and sand
insulation, capable of working at abov; 18000 under a pressure
of 200 atm N21 is described. Crystals of ZnS up to 3 cm long
wtiro
There are 3 figures.
ASSOCIATION; Institut kristallografii AN SSSR
(Institute of Crystallography, AS USSR)
SUBMITTED: June 26, 1961
Card 1/1

SHTERNBERG, A.A.; KUZNETSOV, V.A.
Crystallization of corundum from the gaseous phase using seed
crystals. Kristallograftia 9 no.lsl2l-123 Ja-F 164.
(MIRA 170)
1. Institut kristallografli AN SSSR.

ACOESSTON .1401.) AP4012287 S/0070/64/OP9/001/0123/0124
AUTHOq: Kuznetsov~ V. A.
TITLE: Rate of surface growth on cLoriindum wider hydrothermal conditions
SOIMICE: Kristallografiya, v. 9, no. 1, 1964,~123-124
TOPIC TAGS: corundump crystal surface, surface growth ratbt hydrothermal conditionp
seed rod, autoolavel thermocouple, euHace crack# inclusion, seed orientation
ABSTRACT: The rates of growth of various crystalline surfaces on leucosapphire
have been studied. Experiments were conducted in steel 130-150 cm3 autoclaves
lined with silver and heated in a resistance furnace with a bottom heating element.
Temperatures were measured on the interior wall with two thermocouples, one placed
at the level of melting and the other,at the level of crystal growth. The tempera-
ture drop between the two zones was 50-60C, and the temperature at-the melting zone
was 590-600C. The level in the autoolave vrao held constant and the pressure did
not exceed 1500 atm. Crushed boules bf leucosapphire and faintly 6olored ruby were
used as source material. A 1911o aqueoits solution of soda with %; of 'NaCi served as
solvent, and ruby rods 3-4 mm long and 100 mnL long were used as seed crystals. -In
.Card 1/2

ACCESSION NOt AP4012287
the course of growth surfaces (oooi), (Mo), (10% and (2243) developed. The
growth rate of the first three types was determined by measuring their thicknesses.
The last type suffered distortion too rapidly to allow accurate measurements.
While the absolute velocities of growth changed with various factorst their relation
to one another remained constant at 100:20:1. Differently oriented rods favored
the development of different eurface6, varying in the density of cracks and inolu-
sions. This proves that proper orientation is extremely important in hydrothermal
production of corundum crystals. "The author thanks A. A. Shternberg for help in
this work." Oiig. art. has: 1 photograph.
ASSOCIATION: Institut kristallografii AN SSSR (Institute of Crystallography AN
SSSR)
SUBMITTEM 12Mar63 DATE ACqs 1qFeb64 ENCL: 00
SUB CODE: PH, CH NO REF SOV: 001 OTHM: 001
Card 2/2

ACCESSION NR: AT4040560 S/2564/64/004/000/0144/0147
AUTHOR: Kuznetsov, V. A.
TITLE: Zinc sulfide crystals grown from a melt
SOURCE: AN SSSR. Institut kristallografti. Rost kristallov, YA, 1964, 144-147
T Cj~-,IC TAGS: zinc sulfide, crystalline zinc sulfide, zinc sulfide crystal, crystal growth,
zinc sulfide monocrystal, crystal structure, crystal impurity, homogeneous monocrystal
A13STRACT: Using the apparatus previously described by the author (kristallograftya, 7,
vy*p. 2, 1962), which permits upwaTd-dirceted crystallization at a controlled rate under
high pressure, monocrystals of ZnS were grown for a ZnS melt at up to 1800C and a
pressure of 100-200 atm. of argon or nitrogen (unspecified in.-individual experiments).
The cooling rate was 0. 5-1. 0 degrees/min. and the-crystallization rate was 0. 5- 1. 0
mm/min., 7he distribution of.Cu-, Fe-, Ca-, Si-, Mg~, and Al-impurities, contained In
the original ZnS, In the obtained monocrystals was ex=ined by spectral analyipts. no
impurities were generally found to retreat into the upper section of the crystals before the
advancing front of crystallization. The monocrystals obtained were generally nonhomogenec

ACCESSION XIkv AT4040560
and showed a characteristic band pattern in polarizod light produced by alternating cubic
and hexagonal crystalline layers. Attempts to obtain pure cubic and hexagonal crystals
by heating mixed crystals at 860-1100C for 5 - 150 hrs. produced(at 1100C for 5 or 10
hrs.) a homogeneous hexagonal phase. Orig. art. has: 2 tables.
ASSOCIATION: Institut kristallogrifii AN SSSR (Institute of Crystallography, AN SSSR)
SUBIOTTED: 00 DATE ACQ: 02Ju164 ENCL: 00
SUB CODE: SS NO REF SOV: 002 OTHER: 010
~c.,d. 2/2

ACC NR, AH6018034 M o n o g- "r-a-p- h --- U-R/
KuznetsOV, Vladimir Aleksandrovich
........ .. .... ..
4ayout and design of marine nuclear reactors (Komponovka i raschet
reaktorov atidovykh yadernykh ustanovok)yRoscow, Izd-vo "Transport,"
1966. 218 p. illus., biblio., tables. 2000 copies printed. Text-
book for higher marine engineering institutes and for the Odessa
Institute of, Harine Engineers
TOPIC TAGS: marine nuclear propulsion, marine engineering, marine
propulsion, nuclear propulsion, nuclear power plant
PURPOSE AND COVERAGE: This is a textbook intended for the course
"Marine Nuclear Reactors," offered by higher marine engineering
institutes and by the Odessa Institute of Harine Engineers. It can
be also used by ship's mechanics engaged in the operation of marine
nuclear reactors. It gives a systematic presentation of the basic
types ofmarine nuclear -reactors. their desigu,.parameters, materials
used, and auxiliary systems,
TABLE OF CONTENTS (abridgadlt
Ch. 1. Selection of basic parameters for marine nuclear reactors -- 3

_A6C_N A I---- - __
AM6018034
tCh. II. Principles of the arrangement of reac-tors and the basics oU
thermophysical calculations -- 43
~Ch, Ill. Neutron-physical calculations -- 85
ISupplements (reference tables) -- 184
jBibliography 215
ISUB CODEs 189 21j 13/ SUBM DATEt 24Jan66/ ORIG REFt 022/
'OTH REFS 004

KUZNETSO11 .,,V.A.; MATYUSHENKO, L,A.; KAGANOVICH, R.I.
Adsorption of fluoro- and chloro-substituted acetic acids at
the solution/air and solution/mercury interfaces. Elektrokhimiia
1 no,3:369-373 Mr 165, (MIRA 18:22)
1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova.

KMVETSOVj,,V.A.; IPWKIN,, B.B.
Adsorption of some derivatives of pentafluoro- and pentachlarobenzere
at the solution,~- air and solution - mercury interfaces. Elektro-
kbi-i's, 1 noOM53-3-156 8 065. (MMA 18:10)
1. Moekovskiy gosudarstvannyy universitet imeni M.Y. Lemonosova.
- -W

MIUMMAt V.1.1 XUSN OVO V.A.
Interaction of sodium audds Wrate with Its metaborate.
Shuroneorgekbin, 10 no,121258!62590 D 165.
(HIPA 1911)
-t,*~wl~-~-2

LUIUSHM, X,1. [Lulmohou, I.I.1; 1UZNWSOV A. C.Kuzneteou, V.A.]
, - I- V.0-
Some problems in the use of Isotopes in solving geolbgical MA
gooohemioal problemso Yeatsi AN BSSRs Bardix.-takh.rav. =4194-106
16o. (KMA 130)
(Raidolvalboyes) (Geological research)

t~ Al 5
LUKASHOUj K.J.; KUZNYATSOUp U.A.
Action of elementary pVticles in geochemical processes. Vestal.
AN B&9R*Ser,fi;,-tekh.nav. no.104-83 162. (MIRA 160)
(Particles (Nuclear physics)) (Geochemistry)

ACCESSION NRt AP4014232 S/0201/63/000/w4/0085/0091
AUTHORS: Lukashev,, K. I.; Kuznetsov,, V
TITLE: Interaction between geochemical and cosmic processes and certain geochomical,
problems
SOURCE: AN BSSR. Izvestiya. Ser. fiz.-takhn. nauk, no. 4j, 1963j, 85-91
TOPIC TAGSt geochemical processp geological proCOSS, Cosmic pr0Ce55p solar enerap
cosmic dusty astronomic phenomenas chemical elementp isotope formation, oroganyp
:volcanism., earth structures meteor composition
ABSTRACT: This article presents complex interrelations between.goochemical and
cosmic processes in the light of new data obtained from the cosmic flights. This
interrelation is based on the exchange of matter between earth and cosmos and on
the effect of cosmic rays with the earth's matter. The scope of this effect is
greatly affected by solar activity which also causes the cyclicity in the goo-
chemical processes on the earth, By now the identical nature of chemical and iso-
tope composition of matter on the earth and in the cosmos has boon pr*ven. It is
'also known that the distribution of chemical elements in the cowas in doterminid
1/2
4.

ACCESSION NR: AP4014232
by; 1) their nuclear structure; 2) their resistance to radioactive decompositionp
spontaneous fission, and nuclear reactions; 3) cosmic phenomena such as nat=V of
the processes involved, evolution,, the state of cosmic bodies# their interaction
.with one another, etc* Cosmic matter occurs in a state of permanent migrationp the
scale of which varies from the atcmic displacements in crystallin lattices to the
:reaction between cosmic rays and earth matter* The most vital problem at this time
ipertains to the genesis of chemical elements. It is being studied by using new
discoveries in the field of the physics of elementary particles and by theories
bearing on the subject of geochemistry.
ASSOCIATION: none
SUBMITMs 00 DATE ACQ: O3Feb64 ENCLs 00
SUB COM CH9 AS NO RU SOV: 004 OTMI 005
Card 2/2

K-T-; -'UZITETTSOV~ V.A.; LUIUSIDN, V.K.
Geochefaical types of weathering surfaces in White Russian
I-olLsye. Dold. All BSSR 8 no.7:455-458 164. (,,,IIRA M10)
1. Laboratoriya gookId.-aicheskikJi problem IJI US 3 11.

WFASHEV, K.l.; B21MOV, V.A.
Ralationdhip between Vno,,hemicnI and coamic tprone!i:jes and some
geuchemical problori. "'cof-sI AN rIS)Sk. "er. fiz,-tekh, mvb no#41
85-91 163. (lif-TRA 17:12)

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-00
On. No. 1. 19-20.. KUM, pff.
@m. Zhor. 1010. No: 11. 24,-K. found a simituity W a
no. of tkv Kwmuk Alstau and the wuilwastito Altai Its
4"WtG vW vonsicim a poWbk puttic maectiou c4
tlow pwApexhkb may be misted to definite ", struc-

deposits we Misted to the wtstrin
wt #A the Kustwo-k
Tbr"wst ,ulhm of 114A.ifue.
r
tum into the ormthm"flu Altai g4rakm (Katall eltdain't
Ibc
tions an amdruwd by the Stol. citaracterfat" 71=
deposits. W. R. titan

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lit SdPAWO -0 1 14114*9 -48 aftv am 14644110.1 i4l, M "0 4 1
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