SCIENTIFIC ABSTRACT KRYLOVA, G. V. - KRYLOVA, L. M.
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CIA-RDP86-00513R000826830010-3
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December 31, 1967
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SCIENTIFIC ABSTRACT
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Polymers on the Bnnis of Reaction Products of 5/191/60/000/005/006/020
Furfurole With Diacetone Alcohol and Boron- B004/BO64
containing Ester of Diacetone Alcohol
insoluble and unmeltable after 23 minutes, Instantaneous hardening
occurred in the presence of 3 % benzene sulfonic acid. The coke number
was 64 - 65 %, the heat resistance according to Zhurkov, 2500C. Moreover,
the boric acid enter of diacetone alcohol was produced from diacetone
alcohol and boric acid tributyl ester (molar ratio 3 : 1), fractionated
in vacuo, and the fraction corresponding to the boron content of the boric
acid ester (3.2 %) used for the reaction w1th furfurole. It took places
A) Dissolved in organic solvent, with 3 % NaOll. referred to furfurole. an
a)catalyat. No resin wan formed after beating to 90 950C for 24 hours.
B Without solvent, NaOH being the catalyst. A 10 - 11 hours' heating to
1200C yielded 65 - 70 % resin. C) Without solvent, the CDC (SBS) type
cation exchanger beine the catalyst. Heatinj- to 1200C yielded already after
6 hours 65 - 70 ~ resin with a coke number cf 69 %, and a heat re3:stance
of up to 4000C. These polymers may be well combined with epoxy-, phenol
formaldehyde-, Qr furfurole acetone resins. Thus, it Is possible to raise
the heat resistance of these resins. There are 1 figure, 4 tables, and
6 referencess 2 Soviet, 3 US, and 1 British.
Card 2/2
with g-iruid-in aAtr-ra- fllvnidir- A,+Arr. Af f'xr".n -IA5 ar~~
PETROV, D.F.1 SANKIN, L.S,;.KRYL..OVA,.G,V,
Polyploid forms of Fragaria vesca and.F. orientalle. "IYudy
TSSB8 no. 2t65-68 164. (MIRA 17:9)
AZAROVA, M.M., kand. ekon. nauk, dots.) BAUTINA, N.V.., kand. ekon.
nauk, dotsol DOBRUSHIN, I.M., kand. skon. nauk; MAXWNIXO,
T.P., kand, skon, nauk, doto.1 TOLYPIN, U.M., kand,ekou
nauk, dots.1 KOZODOTEV, I.I., doktor okon.nauk, prof., red.;
WSIA, L., red.; MITINA, M., red.; DARONYAN, M., aladshiy
red.; KRYIDVA, I., mladshiy red.; NOGINA, N., tekbn. red.
(Chrestomathy in economics] Khrestomatiia po politichaskoi
ekonomii. 2.p parer. i dop. izd. Moskva, Sotsekgiz, 1963.
798 p. (Economics) (MIRA 16:4)
GULAINYAN , :'.hacb4k Grigorlyevich; TATIXIYPJ , Gurgen Arserovich;
MITIVA, M.,, red.; KRYLOVA, I., mlad. red.
[Technological progress and lphor organizationj based on
materials from chemical and machinery industry enterprises]
Tekhnicheakii progress i organizatalia truda; po, raterialam
predpriiatli khiricheakoi I mashinostroitollnoi promychlenr-iti.
14oskva, Izd-vo "14ysll" 1961.. 213 p. (MIRA 17 8)
KkL'TS,rV, Nikolay Aleksandrovich,.KRYLOVA) I.p red.
I .-- I . -
(Material and moral incentives for labor In induntry]
Fateriallnoo i morallnoe atimulirovanie truda v pro-
myshlennosti. Floskvap Mys1l) 1965, 94 p,
(MIRA 18:2)
FOLUSHCHUR Nikolay Grigorlyevichl BAKOVE'r,',KIY, 0., r#-d...-.
irdtid. red.
(Main problems or the economics of the fuel-powr base of
the U..S.S.R.] Oanovrqe voprosy ekonomiki topliyno-energetl-
cheskol. bazy SSSR. Moskva, Mysll, 1965. 132 p,
(VJRA 18:4)
IRTIANA, I.A.
prevention and therapy of myocardial Infaretion
by antiCO(LgUlantOo Sov.med. 23 no.4:43-47 Ap '59.
NIM 12:6)
1, Is )akfedry goopitalinoy terapli (snv. - prof P.To.14tkonekly)
II Moskovskogo meditsin kogo Inatituta, Iment U.I.Pirogova I
torapevtiohookogo otdol:niya (zav, IA.Xrylova) poliklinild
No.68 imeni profo A.7.Reyna (glavnyy vrach Tej.Gur'yeva)
Hoskvoretakogo rayon& Hoskvy.
(ANTIC(L-GUIAMS, th;r;cuse
nVocardial in a t (jue))
(HTWAIMIAL INYARCT, ther.
anticoagulants (Ras))
gi i-~
qb~r,
rir
L Pr-)4/Pc-14 'I
ACCES."'ITION' NRS AP3001425 -S/0138/63/000/004/0001/0005 tj
ATTMA: Shatalov V11-1 199 v M~_~ Yry*lR,!~j, 1. A.; Artemov, V, M.t 1:~,
Korbanova, Z. otrdko
fik --D V, I. F.; 72ftimk~yp
A.
TITLE:,: Low-temperature j2pIpIrizillu tutadiene-sit. ene rub'ter with a eftrbon black-
oil fill~F-
IOUMCE: Kauchuk i rezina,tno. 4# 19% 1-5
TOPIC TAGS; polynngrintion, Car!,,on black filler, oil filler, butadiene rul.),,-'er,
styrene rubber
APSTRACT: Studies were condu ed on the preparation of stalle disporsions of
-.rarious types of carbon black, . th nd without mirfacc-active su'~Nstances. The
latter incltided p5tasqi= r sinate, Leukanol, and ar=on-i%= casel.nate. The dis-
pe.rilons were prepared in ball mills, in 4,et rdl1q, and by n--~ans of a vl~ratcr.
Th~-, kin,~tic and a~Tre,-,,ate stal,ility of the deternitned.
~o!;-Inate nni Leukanol produced dispersions wl-ie.-'h did not so~;,nratn for se7err,-' days.
V-e oil enulnion wan prepared with the aid,of stet.-ric ccid ani
The curl-on black dinpersion was mixed with the lAtex of 1-,,itndiene--3ty~rene rubber
Card 112-
L 21 6,
A10CF531TON YRt AP30101425
aryl into It was introduced the oil en-w2sion. The coagulation of this !rass was bent
achtt~ved by pouring it into a 9% solution of sodiu:-, chloride containinj Z_3u1fur10
acid-at 40C. -It was found-that
_the Introduction- of carbon '-.,lack into 'he Istex
previous to coavulation had a favorable effect on the tochnolo!?4.ca_1 properties of
-the vulcanizates a
M~ perrAtted the processinj of rubbers w-th a hilher rolecular
wei-ht. The KhAF4.rand of carbon Iblack and the u3c of potassium rcsinale as c7~ulsi_
fier produced vulcanized rut-bers of superior strcncTth ani a!.-rasive properties, with
a hither modulus of elasticity and with a better adhesion to the cord. Pa3y*nkovi
N. V. . Pondaryev, A. Ye.) and 13eritasevich, T. V. participated in the .:o,-k*-- OHg.
art. has: 3 tal-les.
ASSOCIATION: Voronozhskiy zavod sinteticheskocro kauchuka i Voronezhskiy shinny*y
-
zavod (Voronezh Synthetic Rubber Plant and Voronezh 'rire-Plant)
SUBMITTED: 00 DATE ACQi I30,v-a7f,3 ENCL:
SUE CODE! 00 NO REF SOV: 002 OTFLPs 002
Card 2/2
ACCESSION NR: AP4011308 S/0069/64/02~/001/0057/0060
AUTHORS: Kry*lova, I. A.; Pospelova, K. A.; Zubov, P. I.
'6.Z . . ............
TLILE; Stabilizing aqueous dispersions of carbon black with surface
active agents
SOURCE: Kolloidny*y zhurnalg v. 26, no. It 19649 57-60
TOPIC TAGS: carbon blackj channel black, stabilirzed aqueous suspen-
sion,"Leukanol stabilized carbon black, rubber filler, dispersion
stabilization, specific surface, NAP carbon black, Ukhtin channel
black
i ABSTRACT: Aqueous suspensions of NAF carbon black and Ukhtin channel!
black stabilized by Leukanol and by the potassium soap of hydroganK.:
ated rosin were compared. The specific-surface area of the 3tabil-
i ized aqueous carbon black is less than that of the channel blackp
I indicating greater aggregation of the carbon black particles and more
strongly coagulated structures. The lesser stability of the NAF
carbon blacks-apparently improves contact of these particles with
latex globules, causing more effective reinforcing of rubbers in
Card 1/2.
ACCESSION NR: AP4011308
latex.
i"The authors thank N. N. Lezhnev under whose direction the carbon
Iblack analysis was conducted."
Orig. art. has! 4'Figures and 2 Tables. 7 Z
ASSOCIATION: Institut fixicheskoy khimii AN SSSR Moskva (Institute
of Physical Chemistry AN SSSR)
SUBMITTED: 28may63 DATE ACQ: 14Feb64,, ENCL:-.00
SUB CODE: MA NR REP SOV: 004' OTM:'001
2/2
Card
rg
WfLOVA. T.A.; ZADIONCHIM0, V.S.; MARIYINOV, A. j.;
Polyclinical prevontion and n-ticcoafArint tr-I'.~.ont of r4isorders
y blood circulation. So!;.Me, . .18 11
of the coronar .11. -
165. (Ma RA M 12)
1, Kafedra gospJtallnoy terapit (zav. - doy-.tvitelln,,71 chlen
A1411 WR prof. F.Ye.Lukomakiy) II Moskovvixgo m,2dItsivf:'r.-vgo
in i3tituta Imeni I';I.Pirogova i rolikllnika Nlo.68 (plavryy
vrach Ye.F.Gurlyeva).
A
Ef fit '- tuf surface-active agents on the ntrcngth Chqr8ct(!ri3tlcn
of the vul .,tkn I za ten c f ca.-bon bl,, ck cx t~? ndA ~'. F A - "-O,O~r, ru b ~*- r .
Knuch. I rez. 24 no.12W-14 Ii ). (MT-,A 1,11:12)
1. !nstitu-1. fiz'cheakry, khimll' ;-T: Vcrc;n-~,-hr-k,,Y,
5fntptA,Jle,qkov knunhu)w Im. 3.M. Kirova.
SHRETER, Alekney IvanovJcb, kand. biol. :nauk,,,KRYLOVA,, Irina I'vovna,
kand. biol. nauk; STAROSTENKOVAO M.M.0 red.~, 11AzAr,.-O-VA-",---A'.-S
tekhr.. red.
[How medicinal plants are found] Kak nakhdiat lekarstverxqo raste-
niia. Moskva) Izd-vo *Znaniep" 1962. 37 p. (14ovoe v zhizni,
nauke, takhnike. VIII Seriia. Biologlia. i meditsina, no.8)
(IMU 15 -.6)
(BOTAIIYO MEDICAL)
KRYIOVA, I.I.
Distribution pattOrns Or some lift! forms. Bot. zhur. 49
no.9tl237-1247 S '64. (~IIRA 17s12)
1. Vaesoyuznyy nauchno-Issledovatel'skly institut lekaratvonnykh
aromaticheakikh rasteniyo Moskva*
~n
Ail-
in
do-
KRTLDVA. I.L.
Development of regenerative shoots In the pine and beach [with
summary in Inglish]. Biul.MOIP.Otd.biol. 63 no.3:105-111 Mq-Je
158. (MIRA 12:3)
(PM) (DEMB) (PMEHERATION (BOTANT))
KaYLOVA, I.L.; IIUYOSXLITSVA, I.Y.
A survey of v", tation of the Karch Peninsula. Bot.shur. 44
no.11:1616-1624 1 159. (MIRA l3t4)
1. Inatitut Iona I drevesiny Akademil nauk SSSR, g.Xrannoyarsk,
(Kerch Peninsula--Plant co=unities)
KRYLOVA, I.L.
Growth of pines in the Crimean Mountains as an indicator of
environmental conditions. Biul. MOV. Otd. biol. 65 no.1:91-100
Ja-F 160. (MIRA 13:7)
(CRIMEAII MOUNTAIVS-PINS) (GROWTH (PIANTS))
KRYLOVA I. L.
Shortened ohoots in the pim familYs Biul. MOIF. Otd. biol, 65 no*5:
n6-ng 8-0 160, (KrPA 13 s 12)
(PINE) (BOTANY-MORPHOLOGI)
-JWWVAg I L kandebiol,nauk (Moskva)
%protection and developmnt of natural reoourcca of tho Crimeael
Primda 50 no.LM.IM Ja 161. (KMA 1411)
(Crimea-Natural renourcou)
KRYILVAP I.L.
Use of botanical Indexes in the determination of some climatic
boundaries. Trudy MOR W06-209 164.
(MIRA l7112)
:I_ -:-. . % . F.-i-
USSR/Chewlstry - Catalyst* May 52
~ftActive Centers and Nechanisa of the Oxidation of
Sulfur Dioxide,- V. 1. Sbekhob&lov&, I. V. KrYlOT&,
N.I. Kobozev, x6scow'state U imenj M.V. Lomonosov
"Zbur Piz Khi-" Vol XXVI, No 5, pp 703-T18
The elementary centers of the oxidation of sul-
fur dioxide are the monoatomic ensembles Ftl
and Pdl, no matter what the chm nature of the cat-
alyzing setal (i.e., Pt, Pd) and the carrier my
be. The activity of the monoatomic Pt ensemble
does not depend very strongly on the nature of the
carrier. The observed dependence of activity on
the dog of filling of the carrier's surface is in
219"
accordance with-the eqs.of the theory of active
ensembles. The carrier may affect activity by its
geometric structure and Its inhomogeneity of sur-
face. The latter effect is apparent only when
tb*rp -is a high diln of the catalyst layer on the
surface.. The fact that single Pt and Pd atoms
&M. active proves the purely oxidative character
of the.process and refutes Wieland's dehydrogen&_
tion theory (i.e., bYdration of sulfur dioxide
followed by dehydratiou)) because the action of dia-
toysic ensembles is required by this theory,
219"
C5
USSR/Chemistry - Catalysts JV 52
I
"The Catalytic Oxidation of S02: JI. The Kinetics
of the Oxidation of SO in the Region of Atomic and
Crystalline Films of PYA~inum and Palladium," V. I.
Shekbobalova, I. V. Krylova and N. 1. Kobozev, Mos-
cow State U
rl
"Zhur Fft Dim" Vol 26, No 11, pp 1666-1672
The authors identified the active centers of Pt
metal catalysts, during the oxidation of S02, be-
girzaing with very thin X-M-amorphous films of Pt
on silicagel, and eading vith clearly cryst cata-
lysts. As characteristic properties., they singled
cut the, xpecific form of the kinetic 1" of S02
CKIdation and the magnitude of the energy of ac-
i1vation. - They detd that the peculiar form of
the kinetic law discovered for the catalytic ox-
idation of S02 on Pt wire remains accurate for the
thinnest Pt film on silicagel; also, that the
oxidation of SO2, on Pd is also subject to this
1xv. This was confirmed by the identical struc-
ture of the active centers of (Ptl) and (Pd
They detd that the energy of activation, of 102, cz-
idation on Pt is const, beginning with very thin
films of Pt on silicagel. and ending with the cryst
catalyst; this energy was equal to 19,000 small
calories. On Pd the energy of activation was
equal to 27,000 small calories. To the authors.
(2) 242T15
all the above demonstrated the identity of active
centers in amorphous (atomic) and cryst catalysts.
In this case, the elemental active center is the
a Ingle atom Pt, or Pdl, fixed by the surface of
the carrier, vhether silicagel or cryst Pt. The
authors conclude that the crystal phase of Pt has
no practical effect on the character of the active
centers, and therefore plays no determining role
in the catalytic process.
ion: of
C a tr, 1
,"V ~)4.
oqkvnp
SO: orAPPI 284, 26 '10
I V 1954.
tho ilp
plic&tIon
Of
"~~O"Ow O'ller c)f
Voscov C. ni ",nthoda o;r
0 19 !-~V 54. V* Lo."ono:3ov,
'il-,5`!~.,` , - z . ., I - . I ~ I. , -7; ~- ~, *~,,:,~ 4 i - 4~ FM~ AWE~,
, - I ., , ': - ~-;; .I ~MR
m
- I %f, -, , wr .1 ~ I . -
I', H v I I J Lf Ll i
iitalaLnii I I u,
-M==="
I.T.; ICSOZIV, N.T.
Manstochemistry of active ceaters, Part 3. A magnetic study of the
photographic process@ Zhur. fis. khts. 30 no.11:2483-2488 N 156.
I (Mm ioM
1. Wookovskly goondarstvexW univorsitat In. N.Y. Losonosafto
(Photographic chemistry)
AUTHORSt Krylova, I.V., Kobozev, N.I. 76-i2-ig/27
TITLE: The Uspoloohemistry of Aotive Centers (Uagnetokh1miya &ktivnykh
toentrov). V. Photooatalytio and Photmagnatio Effoots 'Kith Ad-
sorption- " OryaWline Catalysts (V. YotokataliticheskLy I
fotomagnitnyy effekty u adeorbtaionnykh I kristalliohaskikh
katalizatorov) -
FMUMICAL: Zhurnal Fixicheskoy Xhimii, 1957, 'Vol. 31, Ur 12, pp. 2725-2732 (USSR)
ABSTRACT: The present raport arose frcm an observation durin the investigation
of the magnetochemistry of a photographio prOce3s of 13. it has
turned out that with a permanent illumination of ttR silver preolp-
itated by the photolysis of AgOl, with a meroury-quarts-lamp, the
magnetizability of the silver inoreases very intensely and that it
passes over from the range of diamagnetism to that with a oonsider-
able paramagnetism. Consequently, there Is also a photocatalytio
effeot besides the photomagnetio one. In this oontext the investiga-
tion of the aotion of radiation on the magnetical and oatalytical
roperties of other metals (Pt, Pd) at various pbysioal states
sorption-layers, blaoknesa) was carriaa out. The following system
M
card 1/3 were invastigatedt i.) Catalysts of adsorption: Pt/SiO2 withs. degree
The Magnstochamistry of Active Centers. V. Photooatalyt4-o 76-12-ig/27
and Photomagnetio Effects With Adsorption- and Crystalline
Cata3ysta
of filling !,X a 0-0178, Pt/A'203 with CC = 0-001 1 Pd/S'02 with
.k - 0.01. 2.) Platinum- and palladium-blacImess. The basic result
r
of this wor1c consists in the determination of the photosensitive-
ness of the metals with respect to their magnetioal and oatalytioal
properties " a substantial increase of the two effects at the
transition of powders to the adsorption-layers (to the metals on
the oarTiers). This difference consists in an approximately 100
times decrease of the exposure time in the case of the adsorption-
layers in omparison with the Voy4ers (in view of obtaining the ame
photomapatic and pbotoo&talytio affect). With platinum and palla-
dium the radiation with a non-filtrated light of a mercury quartz
lamp produces & decline of catalytic activity with simultaneous in-
amaze of paramagnetism. In the next work it will be explained that
the photoaansitiveness shows a certain distribution in the spectrum.
The assumption Is expressed that the effoots found here are corre-
lated, with the formation of exo-eleotrons under the action of light.
The met&l-atcra and their ensembles can be considered In this can-
text as eleatron-4onors and the tm-p-levels of the carrier can be
considered as their acceptors. In the case of dielectric carriers
Card 213 return of the exo-electrons to the metal ions is rendered very
The Magnstochemistry of Active Centers. V. Photocatalytic 76-12-19/27
and Photomagnetio Effects With Adsorption- and Crystalline
CaLtalys t3
difficult since there in very little probability for these electrons
to reach the carrier-oonftotive-sone &M with this th&t zone, wbich
represents a oomm song with the adsorbed He+-ions. In this way
there is vM little prdbabi2ity given for a reversibility of the
ionization process wA a quick obtainina of photomegmetio *M photo-
catalytic effects in guaranteed. - With metals, the picture is in-
verse. There is a wiae conductive zone which requires the necessity
of a longer exposure (to light). The primary cause for the decline
of the catalytic activity at illumination is presumably the forma-
tion of non-aotive ions instead of the active ahsorbea metal atoms.
The non-aotive ions lose the catalytic properties on account of the
loss of the valance electrons and their capture by the trap levels,
or by the adsorbed pa. There are 5 figures, and 18 references, 11
of wtdoh are 31avic.
ASSOCIATICK., Mosoom, State University iment, N.V.Lomonosov (Mookovskiy gosudarstvanW
universitet im. X.V.Lomonosova).
SUBMITTED: October 5, 1956
AVAILABLEt IAbrary of Congress
Card 313
86778
-.1150 2201. 120111 'X91 S/076/60/034/011/002/024
b B004/Bo64
AUTHORSs Krylova.--T. V-, Ogarev, V. A,, and Kobozev, N. I. (Moscow)
TITLEt The Effect of the Electronic Properties of the Carrier on
the Photosensitivity of Platinum Catalysts
PERIODICAL3 Zhurnal fizicheskoy khimii, 1960, Vol. 34, No. 11,
pp. 2408 - 2413
TEXTe In contrast to the negative results of other researchers, the
authors succeeded In proving that preceding exposure to light of metal
catalysta, i.e., of platinum on silica gel or platinum black, reduces
their activity (Ref- 4). The present paper deals with the photo-effects of
a platinum catalyst applied to various carriers. Boneblack, germanium, and
bismuth were such catalysts. Their activity was determined by measuring
the decomposition rate of H202' The light source was a ITPK-2 (PRK-2) lamp.
A comparison of the results obtained for Pt on silica gel and platinum
black with those of Ref- 4 led to the following conclusions: The decrease
in the catalytic activity of platinum during exposure to light is assumed
Card 1/2
8677A
The Effect of the Electronio,Properties of the S/076/60/034/011/002/024
Carrier on the Photosensitivity of Platinum B004/BO64
Catalysts
to be due to photo-ionization of the active platinum atoms and their
transition into inactive forms of ions. The photosensitivity of the
platinum catalysts depends on the electronic properties of the carrier,
The broader the forbidden zone of the dielectric carrier, the more
difficult is the return of the electrons to the :onized centers, -the
higher is the concentration of the photoionized, deactivated Pt atoms and,
accordingly the greater is the decrease of activity. If, instead of a
dielectric isilica gel), a semiconductor (carbon, germanium) or a metal
(Bi, Pt) is used as a carrier, the smaller forbidden zone in semiconductors
and the absence of a forbidden zone in metals will increase the probability
of a return of the electrons to the ionized platinum atom, and the effect
of light will decrease. Therefore, Pt on silica gel showed the highest,
on carbon or Go.& medium, and on platinum black the least decrease of
catalytic activity after exposure to light. I. A. Zubovich is mentioned.
There are 8 figures and 6 references, 5 Soviet and 1 US.
ASSOCIATION% Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosova
(Moscow State University imeni U. V. Lomonosov)
SUBMITTEDt January 17, 1959
Card 2/2
2 e^i"
3/076/61/035/004/014/010
2 4. 'j -;tD 10 ~gl 116U, J,T'~ Bio6lB201
AUTHORSt 'J~g_jqY�j__1AA* tand Kobozev, N. Ia.
TITLEs Magnetochemistry of active centers.
TI. Magnetic properties of crystal phosphor catalysts
FERIODICALt Zhurnal fizicheskoy khimli, v. 35, no. 4, 1961, 911 - 916
TEXTt In continuation of an earlier paper (Ref. 31 1. V. Krylova, M. N.
'Danchavokayap N. I, Kobosev, Zh. fiz. khimii, 29, 1684, 1955) on the ca-
talytio and luminescence properties of two catalyst systems (crystAl
phoophors from zinc oxidep applied to silica gel (ZnO/_SiO2), and copper-
-activated zinc sulfide (ZnS*Cu)), the authors of the present paper
8tudied the mWetic properties of thece two catalytic systems. The cata~~"",
lysto of the type ZnO/SiO2 which were examined here contained very dif- '!
ferent amounts of zinc oxide (the covering density aL varied between 0.0002
and 0.1 of the monomoleaglar layr), and the activated zinc sulfide cata-
lysts contained from 10- to 10- .g Cu per g of ZnS. The ZnO/SiO2 cata-
:Card 1/5
A
22&'16
"~agnetochemistry of active
S/076/61/035/004/014/018
B106/B201
lysts were prepared by stirring fine silica gel powder into the solution
of a given amount of zinc nitrate; after a 24-hour standing time the :;,,)-
lution was vaporized0together with the silica gel, the catalyst wan dried,
and heated up to 400 C for three hours, to allow the remainiiig zinc nitrate
to decompose completely. The ZnS*Cu catalysts were prepared by impregnat-
ing zinc sulfide with a copper nitrate solution and subsequent heating up
to 8000C (without melting). The authors ayplied Faraday's method to
examine by a scale of 1. 11. OzeretskovakiyOn system the dependence of the
magnetic susceptibilities X of the two catalyst systms on the covering
density ot of silica gel with zinc oxidep or on the content of the Cu acti-
vator in the US luminophore. The investigation yielded the following
resultat (1) In case of a strong dilution of the luminophore layer (ZnO)
on the carrier (SIO 2) and a low content of the activator (Cu) in the
luminophore (Zns), the magnetic susceptibility of the specimen goes
through a very high mtxi6umg iseot a paramagnetization of the diluted
layers takes place in the same way as in metals. -he height of the maxi-
mum is even indicative of a hyperparamagnetism. of diluted layers. The
Card 2/5
22006
S/076/61/035/004/014/016
Magnetochemistry of active ... B106/B201
susceptibility referred to I g of the luminophoze appliedp or to I g of
the activator contained attains at high degreee of dilution values of
4 (at ot -4), or of 106 621) Urlits
10 -6. ZDO)Sio 2- 5'10 (at CuvZ',Sw1-5*10_ I - umber
1. 10 To make this v~iry strong paramagnetL!jm fit th,,j po:ijible n
of Bohr magnetona per particlep one must assume that each ZnO or Cu+
particle causes the paramagnetization of a large zone of the carrier
latticep this zone being considerably larger in the lattice of the ZnS
semiconductor than in the lattice of the 5102 dielectric. (2) A close
relationship oxists between the magnetic and the luminc-4cence properties
of luminophores. The magnetic susceptibility and the duration of after-
glow of ZnS*Cu-type luminophores depend In perfectly the same manneron
the content of the Cu activator. This marked similarity is indicative of
the fact that the hyperparama3metiam is possibly related to the circum-
stance that many trapping lev.)ls of sufficient depth and heavily occupied
by electrons are formed In th-a lattice of the carrier iinder the effect of
the adsorbed or the dissolved activator. Mention to MBAs- of a paper by
Card 3/5
Magnotuc)wmlo try (A antivo~ ...
22006
5/076/61-
I
Blob/W01
N. I. Kobozev, V. B. Yovdokimov, I. A. Zubovi(.h, and I. N. Ma!11~3ev
(Ref. Is Zh. fiv.. khimli, 26, 1349o 1952), wiivr4, the magllt~tic properties
of applied motallic outalyst3 have been utudlod. There nre 3 fignirs.,139
2 tables, and 7 referencom, 5 Soviet-blon nnd 2 The two
referonc(!3 to English languago jublicationo rl~tid ~%!i followes K. O.,ihimaj
H. Nagano, J. Chem. Phys.# 23, 14'731 19551 S. Z,irach, J. Virkevich, J.
Phys. Chem, 60, 1598P 1956).
ASSOCIATIORt Moskovskly goaudarstvennyy univf.-roite,, im. M. V.
Lamonosava (Mopcow State UrAver!;Ity imeni M.V. Lomonosov)
SUBMITTEDs July 28, 1959
Card 4/5
KRYLOVA, I.V.; OGAREV, V.A.; 1.0BUZEV, N.I. (Moscow)
Effect of the nature of gas on the photocatalytic activity of
platinum catalysta. Zhur,fIz.khIm. 3) no.10:2311-2315 0 '61.
(MIRA 14:11)
1. Moakovskiy goaudarstvennyy univeraitet iment Lomonosova.
(Photochemistry) (Catalysts) (Platinum)
ME
T 111;4 A.33.; YODW-Ev, N.J.
,Lh jV1, ) - . _i. ; -, 1. - - ;
Study of er-Aalpti by the t,-.othcd of exoolectmn ealsoicn.
35 nc.11-2657-2660 N 161, O"IRA 14:32)
1. ~i,qkovokly CosudarAveim universitet imeni 14monosovao
Y
(Catalyol, -
(Electrons)
UYLOVA, I.V., kand. khim, naik (translator]; KObOZEV, 11.1.# prof.,
46;~~r ~.,; MiUYIMA, G.M., ied.; POTAMiKOVAj Ye.S., tekhn. red.
(Exoelectronic emiBsion) Ekzno3,ektronnaia emissia. Y-oskva,
lzd-vo inostr.lit-r7p 1962. 306 p. (14IRA 150)
&PF(q)/M(j)/Wr(n)/T3DS PFFTC/ASD Pr4 Wd
A.CC-1-ISION NRs AT3002359 SA932/62/001/002/015:5/0U8
XTZEMRS: Kobozov, 11o I*; M7*lova, 1. V.
60
TI'nZ: Catalysts as photosensitive systerA
ZCURCZ: Kataliz T vro'sahey shkole; trudy* I Yevhvuzovskoro Soveshchaniye, po
katallzup zoo 1, pto Ze Moscowl Izd-vo rook, un
T01PIC TAG3: catalyst, platinum, H Bub 2 0 sub 2p P~otocatslytic effect, 9 sub 2"
palladiump Ar
AW-AALICT, The affect of irradiated 31ght on tbo activity of metallic plsti=
catalyst as been studia-do The decomposition of H 0 2 was used as a controlling
process. The metal was atudiad in various dispersion forms as black powders or
in an adsorbed from on various carriers. Photocatalytio effect was obsorv~d in
In both metallic and adsorbed catalysts# in case of platin= this affect consists
in the decrease of catalytic activity after its irradiation with lighto, The
decrease of activity Is greater when the catalyst Is Irradiated In an Inert
atmosphore Of 112 and Ar# and smaller whon It is In,adiated with light In bydroLmn
atmosphore. It is suggested that the decr6aeo in activity of platinum. catWets
takes place by means of ionization of rt atoris and the strengthening of -the
Cord 20/2
.J
L 13533-63
ACU'SSION ITH: AT30OW52
valence electron trapped at the carrier lavele In. case of the irradiated palladlur.
ceitalysta wheireby the activity is incroased, the explanation to that tho alootron
transfer leads to the origination of two unpaired electrons at the palladium atom,
la which ease its catalytic activity is higher* The photocatalytio effect on rt
catalysts greatly depends on the electrical proportion of' the carrier* 'Tbe great-
er the restricted zone of the carrijr (or dielectrics), the greater-is the proba-
bility of ionization of the Pt atomms which am adsorbod on this carrier, and con-
.vorsely, with a decrease In the width of the rastricted tono, thi pusalbility of
the oloctronia transfer between the carrier and the adsorbed platinu= incroaats*
Thua, ;ho probability of the return of the valence electron to the plectin= atom
also increases, In accordance with thle the greater decrease of eativity through
irradifttion with light Is observed In the 0680 Of Platin= on silieasgvI and the
ammllest activity is 08or"d in ease of platinum blaalco Orig. art. beat 3 figures*'
A~;SOCLMON! Xbimicb2skly fakulltot Moskovokogo gosudaratvonnogo universitata
(Do psrtmnt of C heniatrZ, Moscow S tate U niveraity)
S=111-LD1 00 DATE Aft 10T=63 MCM 00
SUB COM-;'* CH NOW SOV: 003 00=1 OOZ
Card
-___-_- - , . I
5/051/62/012/005/015/021
E075/EI36
AUTHORS: Krylova T.V Shashkov, A.S. , and Kobozov, N. 1.
TITLE: Investigation of cx-,r,Lzllopho8phors ZnS.Cu by the
V
method oC oxoelectronic emission
P-:-'RI C; DI CAL: Optika i spektroskopiya, v.121, no.5, io(;2, 635-636
TeXT: A study was made of the influence of additions of Cu,
on the intensity of luminescence, exoelectronic emission and
catalytic activity of ZnS. The phosphor samples were prepared
from melt by heating in air at 800 *C. The emission was excited
by X-rays and luminescence by ultraviolet light. Catalytic
activity of the samples was measured by the docckmposition of
methanol between 360-35U 9C. It was shown that non-activated ZnS
gives comp ratively weak emission. Small additions of Cu
(7-5 X 10-9 and 7.5 x 10-4 9/9 ZnS) give sharp emission maxima at
140 and 260 OC. The latter maxima wore shown to correspond to
maxima of catalytic activity at 330 OC. Thus the experiments
demonstrated that the luminescence centres have a connection with
the catalytic centros and exoelectronic emission, and that the
Card 1/2
m
Investigation of arystallophosphors.. 5/051/62/012/005/015/021
E075/EI36
latter is a promising method for the investigation of lunilnemeence .i- I,-
contres, olectro"ic emis3ion and catalytic action.
There are 2 figures.
SUBMITTLD: August 3, 1961
Card 2/2
AUTHORSs
TITLEs
PBRIODICALs
S/1 63/000/001/004/008
D20"YD307
4
Shaahkovp As Be, Krylova, I. V. and Kobozev, N. 1.
A study of the eintering of silver black by eX06160--:,
tronio emission
Moscow. Universitet. V88tnik. Seriya II. Xhimiya,
no. 1, 1963t 18-22
,TEXTs The aim of the present work was the study of catalytic and
emissive properties of silver black in dependence on temperature
and previous thermal treatment. Ag black was obtained by the re
duction of A 5NO3with ammoniacal hydrazine-sulfate at 000, and was
fired in H in the temperature range 50 ~- 6500C. The catalytic
2
activity was assessed by the decomposition reaction of H 0,,, at 20l
30 and 4000; the energies of activation corresponding to 2vfiriously
pre-treated Ag batalyate were also measured, The catalytic aoti-~
vity of Ag black was ,found to decrease as the firing temperiture
was raised tov25000, remained constant for firing temperatares
Card 1A.!
S/18 63/000/001/004/008
A study of the aintering D204YD307
0
of -250 to 55000, and fell sharply in specimens fired at higher
e enera
temperatures. Th ;ies of activation were rei3pectively--,5500
__~mole for specimens fired at 50 - 25000 and
cal/mole and -7000 oal
250 - 60000, The exoeleotronio emission increased slightly between
50 anA 25000t (for specimens fired at 200 and 2500C), and increased
further between 250 and 55000, the sharpest,emission peak appear-
ing at 55000. The emission fell sharply at higher temperatures.
Measurements of magnetic susceptibility on catalysts fired at dif-
ferent temperatures ahowed'aloo that increa,bed emissivity is con--
nected with reduced diamagnetism. It is suggested that at low
temperatures the catalysts contain a high p~ropoition of an amor-
jphouBq chemically active atomic phase coverIng the crystals. After
jiring and exposure to itirg a surface film of AG
20 is formed. The,
oncentrat.ion of this active phase is reduced after firing
surface c
'to 50 - 25000, whilst catalysts -fired at 300 - 50000 possess a
finely crystalline surface with a small proportion of the atomia
~phase. Tho.orystals become coarser at 55000, decreasing the ape-
joific surface of the catalyst. There are 5 figures.
2/3
J~ 'I-
Y-
S/189/63/000/001/004/008
A atudy of the eintering D204/D30.7
ASSOCIATIONs Kafedra fiziaheakoy khimii (Physical Chemistry De-l-,
partmont)
SUBMITTBDi Pebruary 12# 1962
Card 3/3
fZ,
L 1 2~-,6 EFF(,c)/EWT(I)/EWT(N)/BD9tES(w)-2.-- - AF?1C/ASD/E5D-3/IjP(C)/
SSD rr" ab_4, . RMIWW
LCCESSION M AP3004982 S/OOT6/63/03T/008/1851/18547
AVrHORSs Shaskovp Ao 3.1 Krylova, X. Va; Kobozey F. 1.
T3TLEs Study of adsorption catalysts by exoslactronic emission
BOURCEs Zhurnal, fiz. khimiio vo 37t no. Bo 1963o 1851-IIB54
TOPIC TAGSt adsorption catalystq catalyst I exoslectronio emissiong platinumf
hydrogen peroxideq barium sulphate
ABSTRAMo Authors studied a aeries of catalists of Pt/BaW4 type vith a varied
platinum content. The reflecting properties and magnetic susceptibility of the
catalysts vere studied in addition to the catalytic and emissive properties.
Small additions of platinum result in intense activation of the exoelectronic
emission with PaSOV They are catalytically inactive in the decomposition of
hydrogen peroxide. Appearance of catalytic activity in the platinum coincides
with the region of exoelectronic emission decrease and light reflection.from the
carrier* Analysis of magnetic susceptibility showed that catalysts with a small
platinum content are paramagnets and those vith a platinum concentration of
0.0018 to 0.0036 g1g BaSo are diamagnets. Authors conclude that these results
confirm the mechanism fouid earlier during the investigration of the luminescent
Card 1/2
L 18321-63
ACCESSION NRs IP3004982
properties of adsorption catalystse. Orig. art* hast 5 figures.
ASSOCIATIONs Moskovakiy gosudarstvenny*y univenitet M. V. Loomonosovs, (Moscow
state univereLt Khimicheskiy fakulltat (Chemical faculty)
SnMITTEDs 20Sep62 'DATE ACqs 063op63 ENCLs 00
Sn CMEs PHO CH NO P" SM 1 004 CTHMt 003
Card' 2/2
4;
KOBOZEV, No I.; KRYL40VA, 1. V.; SHASHKOV, Ao So
"The effect of electron properties of support upon exoelectron emission and
catalysis."
report submitted to 3rd Intl Cong on Catalysts, Amsterdam, 20-25 Jul 64.
Moscow State Univ im Lomonosov.
KRYLOVAPI.V,j FILONERKO, A.P,.j KOBOZEV, NI,
Effect of irradiation on the catalytic activity of plz,4num
during hydrogenationo Zhurofit,kbims 39 nooll%2742-27440 N
165. (MIRA l8il2)
1. Mookovskil goaudarstvannyy universitst imeni M,V,
Lomonooova.,
SHASHKOV, A.S.1 KRYLOVA, I.V.
Decomposition of hydrogen peroxide on copper catalysts. Vesto
Moak, un, Sere 2tKhim, 20 no* 507-41 S-0 165. (MfRA 18:12)
1. Kafadra fizicheskoy khimii MoBkovakogo goaudarstvennogo
urLiveraitata. Submitted Sept, 7,, 1964,
t is it v a w
004 M &NOAP'LIP001111
0
0 p
of
go
s ae 4 0 a ML a At a AZO
--ee
-00
mylkwpeadw"Osseddo. K-T-K Rod.
00 pAsod proomsoomm (U.S. s. lit.) vw.
Gmwf
-00
a I obtWond w"k s o4as sod 21, 40k'@ A10%. &I
a 601186 On VOW! INSIO 04 VA Mlw4wuvv k% whowe"d
00 w4. %Iwo doe vim moold. %be arwal" obe"M bav* a
diam. 44 2 owsm.. 8 9. wr lt~ we w" %maM A. A. R.
441 -00
041 a
90 j
go
00
:60
Goo
too
goo
goo
400
oww
14
30 too
too
a I $.It ita41 aittamosm:44 t"486 vim asswom ON see
'Y-MI-ii -I' I- a -W- ~7
u it of 40
0 to a a It 4 14 K Od " 11
d +-0
0 g g
Is ,
0 : . *lee Os o 0
p V,
LPYLCVA, K. T. - Osno-r,-:,.p-
I Mynii I -.'Atj ri na
prirody, Novaya sarlya. W. 7r,~!., vy.-. 179-90-
BiblioEr. 110 nazv.
30 1 betotri a Zhurnal 'riykh 3titay, Vol- 47, 1949
TARSHAVWIT* 3,1o1 JMTIDTAI K~T9
Underlying principles of establishing the age of wrine rodents,
Hat. k pasn. founy i flary SSSR. Otd. xoOI. no.17rl?9-190 148.
(mica) (Tooth) (XIBA 11t3)
BPecu3larities of Seasonal Dymmica of Micro-populations of Mice and
Field Mice during Periods of Decreased Population".
Dok. Akad. Nauko 611 No. 59 1948.
KRTLOTA, K.T.; SaILOVA, U.S.-; SH1WV, X.M.
Characteristics of the ecology of the jird (Rhombomys opimis Licht.)
durIng the winter porlod In the northern Aral Sea region. BIul~NOIP
Otd.biol. 59 no.2:3-14 Mr-Ap 154. (NM 7:6)
(Aral Sea region-Rodentia) (Rodentia--Aral Sea region)
KWWWA, Y. T.,, SITUT-MA. E. S.
"Certain ecologienl characteristics of the yoll(m mamot in northern
J
PrIarallye which are inportant, in the eiizootolo;-y of t1he p. 20
Desyato;re Soveshchnniye po parazitologicheskim problerar. i
-,)rirolnooc"l:a,rjm bolQznyam. 22-29 Oktyalbryrt Y)459 (Tenth 'jonference
'on PF,,rftsltolojTlc:,l Problems and Diseaser with t'oci 72-29
October 1959), lllos(~ow-Lenlngrad, 11).59, Acnderrq of Medi~nl Sciences
1,101 2,15lipp.
v137il'i anA Aarilrmy of Scffinco3 USSR,
Aralamorekayn Antiplague Station
T:l
IT,
KRMVA, K.T.; MYSOV, -A,I,
To:tin4fnav pqiu'ons for use in contr*Lling the greater gerbil and
it actoparasites, Biul,, Mojp. Otd. biol. 65 no.51135 S-0 160.
(KM 13 s 12)
(ROM"IMMS) (IMECTICIDES)
w, ~,T!i
KRYIDVA, I.T.; VARSHAVSKIY, K~; SMIUVA, S--H1=, R.N.
KCKMINA I M. G,
Characteriotice of interepecifla oontaot in colonies of thegreater
gerbil (Rhombomyo opimus Llobti)*in the northern pari of the Aral
Sea region* Zools thur. 40 no.3t434-446 Mr 161. (MIM 103)
1. Aral Sea Anti-Plague Station and Aral Bilanch of the Moscow
Society of Raturalistes
(Aral Sea $tWon---C6rbils as carriers of disease)
'5xF
Criterion for the determination of group invalidism In patients
with bronchial asthma. Mu.med.shur. 41 uo.1:21-24 Ja-Y 160.
WRA 13:6)
1. Is TSentrallnogo nauebuo-Issledovatel'skogo Institute eksper-
ticy trudosposobnosti i organizateii trade. Invalidov (direktor -
prof, D.L GrItsteylob I say, klinIkoy - prof, L.I. 76gallsou).
(DISABILM VALUATION) (ASTHYA)
ACC NRt AVIOG'1802
A 6~ SOURCE CODE: UR/oo8o/67jc4o/cV,1/0061/0066
AUTHOR: Borisovaq Z. U.; Kryloval L. A.
ORG: none
TITIS : Electric conductivity and microhardness of glasses of the arsonic-phosphorus-
1selenium system
SOURCE: Zhurnal prikladnoy khimiA9 v. 40p no. 1, 196?j 61-66
TOPIC TAGS: arsenic compound*1 selenium compound, phosphorus compound, glass property
ABSTRACT: The electric conductivity and microhardnoss of glasses obtained by gradu-
ally replacing Arsenio with phosphorus in vitreous AsSol and AsSG2 were studied.
In tho vitreous -Droducts AsXP(,-X)Sol. and Asx~p (I-x) S02-5 obtained, ranged from
izero to unity. Their electric conductivity was ound to decrease by three orders of
nacnitude ux)on substitution of phosphorus for arsenic. The energy of oloctric con-
ductkivity i~croasod corrospondi~gly by 0.? oV. The observed decrease of conductivity
is apparontly duo to the greater strength of phosphorus-soloni=. bonds as compared to
that of ar.-onic-solonium bonds. The change in the natura of conductivity in 'glasses
of compositions AscP(I-X)So2. upon substitution of nhosDhorus for arsenic is due to
the fol-nation of tetrahedral r1rUc'tUr'91- units PS The microhardnoss of the glasses
05 2ig. art. has: I figure and I table.
decreases as arsenic is replaced by phosphorus.
SUB CODE: 07,201 SUBM DATEI 29Jan65/ ORIG REF: oog/ OVJ REF: ()o1
bard -----.-----.~UDQ-~-537-311+539-53 -'546.18'19'23-161.6
Yjtylfjvl,, L.D., ansiitent
Olmning of the bag of watern in late prognancy toxornias.
Sbor. nauch. trud. Ivan. Con. med. In3t. no.2V:299-304
163, (HIRA 19:1)
1. Iz kafedry akunherntva i ginekologii (JLsy)olnyayushchiy obya-
zannosti zav. kafedroy - dotsent M.A. Timokhina) I kafedry pato-
fiziologii (zav. kafedroy prof. S.S. Poltyrev).
"M p~m-~
i~ 7,
UYLOVA, L.D., assiaLent
Antitoxic function of the liver and proteins of the blood
serum In late pregnancy toxemian. Sbor. nauch. trud. Ivan. goo.
med. inst. no.28:305-310 163. (MIPA 19:1)
1. 1z kafedry akuohorstva I ginekoloril (1spo1nyayuvhchiy obya-
zaruioatl zav. kafedroy - dotsent M.A. Timokh1na) I kafedry pa-
tofiziologii (2av. kafedroy - prof. S.S. Foltyrev) Ivanovskogo
goaudarstvennogo maditsinskogo instituta (rektor dotsent
Ya.M. Romanov).
GREEENI, L.K., akademik; BAYDUGANOVA, Ye.P., nauchnyy sotr.;
SAVCHENKOj P.Te., kand. blol. nauk; GREBEHI, Te.K.,
kand. sellkhoz. nauk;.KRTWVA. L.F., nauchn. sotr.;
SIDOROVA, L.M., nsuohn.-sotr.; SOROKINA, V.I., nauchn.
sotr.; BAGMET', M.I.; LAWROKO, Te.L.; KHOkHLYUK, A.G.;
PASHKEVICH, M.K.1 BRYZHNIXO K.A.1 LUZHKOV, M.A., kand.
sellkhos. nauk; BALASHOV, N.T., kand. sellkhos. nauk;
ZHELIKHOVSKrY,, V.I., redaktor; POTOTSKAYA, L.A.,, takhn.
red.
[Ukrainian Wl~te Steppe swine] Ukrainskaia stepnaia belais,
poroda svinel. Pod obahchei red. L.K.Grebenia. Kiev, Gos-
sellkhozizdat USSR, 1962. 252 p. (MIRA 16:5)
1. Ukrainskiy nauchno-isaledovatellskiy institut shivotno-
vodstva stepnykh rayonov im. M.F.Ivanova "Askaniya-Kova."
2, AN Ukr.SSR i Vassoyusnaya akademiya selfskokhozyaystven-
nykh nauk im. V.I.Lenina (for L.K.Greben'). 3. Ukrainskiy
nauchno-looledovatellskiy.Inatitut zh4votnovodstva stepnykh
rayonov im. M.F.Ivanova "Askaniya-Nov.~" (for Bayduganoys).
4. MalitopollaXaya gosudargtirennaya plemennaya stantsiya
(for Bagmet, lazorenko, Michlyuk). 5. Spetsialist sovkhoza
"Komsomolsts" Stavropollskiy kray (for Br7zhnik).
(Ukraine-Swine breeding)
A.V., UPIPIANOVAP I.N.; YAKOVUVA, fl.l.j
Organophosphorus complex. foming
AN SSSR no.3t Ser. khim. nauk no.'L:77-P! 161~
1. InstItut noorgatilchcskoy khimd~ E lb~r~ikrigf) t".,
AN ')!-~.,R, Novosibirsk.
VOISIITEYN, L.H.; KRYLOVA, L.F.1 140GIIZVXINA, M.F.
Reaction of methionine vith Reiset's second bass chloride. Zhur.
neorg. khim. 10 no.9sl976-1979 S 165. (HIM 1BL10)
1. Movosibirskiy gosudaretvenM univeroitat.
DA -
Yo-.14. ; PANSILI NA, M.M., 'KEW P., DIM NK('I.' T.~,4. ; 'MMOVA L. I.
PAIMIENKOP A
ZMA1101, V.V.,, `!*114I!,S,
Residual strevo^q in b'.-Ile-3 Tih-le steel. Stan. J instr.
36 no.8:217,-~9 A;r .65. 0,:I!tA 18:9)
GILACHWA. Q-S-; KRTLOVA, L.I.
Structure and mineralogical features of the rare-metal deposit In
the upper Seywhan Valley, Inform. sbor. VS10I no.9sl3-24 159o
(KIRA 13:12)
(Seywhan Valley- Cobalt)
CYMER, 0"
IST
81880
2'1i -50 s/i2g/WoOO/08/007/009
B073/9135
AUTHORS: Zhetvin X.P. Podvoyskiy, L.N (Candidates of Technical
Sciences), and Krylova, L.I. (Engineer)
TITLEi Brittleness~Iof _C-o1_d__D_r_a_w_n_3Feel Khl8 11~
PERIODICkLa Metallovedeniye i termicheskaya obrabotka metallovq
1960, No 8, pp 30 and 35-38
TEXT: kcaording to data publishqd in literature the strength
and ductility of high chromium steelsOand also the wear resistance
depend to a great extent on the stRe-ture and composition 6f the
carbides. In selecting the heat treatment regime it is necessary
to bear in mind that to obtain carbide in the equilibrium state
requires long heating in the range of perlitic transformation.
There is a further complication that steels with high contents of
chromium and carbon are prone to overheating if heated above
1200 OC. To determine the influence of the individual stages of
the technology on the embrittlement and for selecting optimum test
methods on specimens from current production batches, the authors
investigated the influence of storing at room temperature and at
below-zero temperature, the influence of tempering and also the
Card 1/9
81880
0/129/60/000/08/007/009
E073/H135
Brittleness of Cold Drawn Steel Khl8
influence of plastic deformation. The investigations vere
carried out on the steel Kh18 (0.9% C; 0.7% 14n; 17-19% Cr;
0.6% Ni; VO.8% Sl; Acl 830 OC; Arl 810 00. It was
established that an Increase In the normalization temperature
from 1000 to 1200 OC leads to a decrease in the hardness from
2.8 to 3.9 mm (measured from the diameter of a Brinell
indentation) owing to an increase of the content of residual
austenite in the steel. It can be seen from the data given in
Table 1 that In the case of normalization at 1000 OC tempering
brings about an increase in ductility, whilst in the case of air
hardening from 1200 OC tempering reduces the ductility and
increases hardness. Storage at temperatures of -5 to -10 OC for
14 days reduces the ductility in the case of air hardening, both
with and without annealing. On the basis of the obtained results
(Tables 1-6) the following conclusions are arrived at.
1) Prior to rolling the metal should not be heated above 1150 OG
since In the case of overheating the structure of the rolled metal
will contain residual stable austenite.
2) Storage of hot rolled metal at room temperature or at below
zero tem eratures Is not permissible for normal rolled and for
Card '^1L? K
81880
8/129/60/000/08/007/009
H073/Rl35
Brittleness of Cold Drawn Steel Khl8
overheated metal. In normal rolled metal the brittleness is due
'to residual stresses which occur after cooling the metal in air
and in overheated metal it is due to austenite-martensite
transformation.
3) Directly after rolling the material should be tempered at
720-740 OC for removing the stresses and for partial decomposition
of the residualaustenite. Tempering of hot rolled metal enables
obtaining a perlite-troostite structure, removing thereby the
after effects, of overheating.
4) For ensuring the required properties for cold working the
following regime is recommended% isothermal annealing at 880 OC
for 3 hours followed by cooling at a speed of 30 OC/hour to 700 OC,
holding at that temperature for 1+ hours and then cooling in the
furnace to 650 OC followed by cooling in air.
5) The authors also recommend isothermal annealing for
increasing the ductility of the overheated metal.
6) In producing wire from the steel Kh18 it Is necessary to ensure
a minimum duration of the storage of the cold worked, non heat
treated wire which should not exceed 8 hours.
Card 3/4
81880
6/129/60/000/08/007/009
Brittleness of Cold Drawn Steel Kh.18 9073/E135
The X-ray structural analysis was carried out by Engineer
Belostotskaya TsZL Zlatoustovsk Metallurgical Combine.
There are 6 tables and 8 referencess 7 Soviet and I German.
ASSOCIATIONs Zavod "Serp i Molot"
(Serp i Molot Works)
Card 4/)+
.18-7100, 18-7500 R 5 " 1!4
SOV/129-60-2-7/13
AUTHORS: Zhetvin, N. P., 11~)Jvoy.,,kly, L. 11. (Cindidates of
Technical Sclenct.B),
TITLE: InVest4,ML1011 or D--carburizatior, Kinetics of Ball
Bo-~avin,t~ Steel D,wini, Ifeat Tn.-atmt:tit
PERIODICAL: W,-tallovedcnlye I tend-che-31,w a o1jra1b-.)Lka inctallov,
1960, Nr 2, pp 37-42 (USSR)
ABS'lli Tae experiments on the above .-ubject were carried out
at the laboratory of' ""Serp 1 inolot" Plarit (zavod
.:Jerp I molot"). Silice, It 12 MI.' 1,1~,Ult to
oeparate processes of 3cal(~ for,:v "oAd decarburiza-
t1011, Which proceed ""ti-lation ")f
Cal-ban conce[Aration In th'. aftev scale
removal wao selected azi 4--arb-trIzation.
After thoroull,h, L;tmly of' iii Initial
1-olled itate, ShKh~)- oteel 2-00-1-10; Cr,
:3, 0.020;
Card I
J
ul' b-!arb11V1zUt1()11 Kinetic;:, 7 Y
Steel Doring, fleat Tr,.,-atvi~,,rit I'D
t'1, Ball Beavinf-,
11 < 0.02'(%) vj(~.rv heat, -tr:--at~!d Ln a .1,ab,.)r;1t,-.,)ry i~-lectrlc
r.wil'fle fi-!vnace at '(0(), 720, 740, 760, 78~), b00, and
~1?00 f.,, witil 1~ojdjjjv 'ro-j 1 In, w 16 1 4 n
medium and In a L~ -ibe wlt!~ cast
1.1,011 C111P,3 w1thout ucc-(.,:,~; ol' air. To the
role oi.' the Initla! ILn tfi~- dc.,carburiza-
ti-on proceoo, 8zimpleo with ,-.caie cit" oriprin
and thmm, irvichined for complete removal of (:i~-cavb--irized
layer werc heat-trt~ated. ca:,Lplei, Were
ctudled microscopically, etc:iod for-Ocale vemDval, and
machIned Cor determ1wition of' carbon content at 0.20,
0.110, arid O.r'-)O mm depth. Fi,~,ireo 1-4 Illustrate the
result.; of these teots.
Card 2/9
Inveotigration of'
of Ball B~,,ariri,~,, Steel D,ivliv~ H,-;tL llli-atiw.~it
-016 . . ......
sm/.i~)() -6o-2 -7/13
Fig. 1. E r f e cl' of' tc-iriperall'uru (j% wa-laticil of carbon
content at 0.2 mia (V~pth durliql aiiric:alin- in oxidizing
.1
mudillin fol. el"Ilt (1) ~,t~,Lmplen; (2)
,ix
FIPICL; With -v"ale.
Card 3/9
Inve:ititration ot' D-2carburizatior, 7 7:
2 -7/13
of a.Lll B-2aj,.jjj,- "teel Diviria' Hr,,at 'Tr,--af,-%t-nt
b)
48
0,601 8 10 1"
IDp L I ;Af
Card 4/9
2. Effect of time on variation of carbon content
at 0.2 trun de th during anneal tnj,-, at 8000 C: (a) in
the tube; (b5 In oxidizInZ me.~diiurii; (1) machined sample;
(2) sample witti scale.
Investigation of Decarburization Kinetics
of Bull Bearing Steel During Ifeat Treatment
77594
SOV/129-6o-2-7/13
Fig. 3. Variation of carbon content In scale-
covered annealed speclinew after annealing for 8 hr
~a~ at 7200 C; (b) at 7800 C; (1) after annealing;
2 before annealing.
Card 5/9
Investigation of D--carburization Kinetics
of Ball Bearing Steel Daring Heat Treatment
77591;
SOV/129-6o-2-7/13
az At 40 M M
034-~-nde~ the, jut-&Cc,
Fig. 4. Variation of carbon concentration (1) after
annealing in oxidizing medium; (2) after annealing
in tube; (3) before annealing in tube; (4) before
annealing in oxidizing medium.
card 6/9 The following conclusions were -made as a result
Inve3tigation of' D--- carburll,, Lit IYinctleo 775~,4
of Ball Bearing Steel During Ileat Treatiric-rit SOV/129-6o-2-7/13
of the study: (1) D,carburization processes in
ShKh9-t3teel do riot develop at tc.-,iperatures below
71100 0 and holdlii~., up to lu hv. T:-ils concerns annealing
of metalo with ov w1thout !.I,, uxLd1:,1ng mediiLm or
In the tube fIlled with c=ft iron chips. (2)
Dr~carburizatlon proeeosos (R,vct1Gp at turiperatl_WeS a-
bovC 71100 C W16 Itil- I-Ilt- 11:3 Jtt~d With t ~drle - For
muchlried i3artipleo ln med1lim decurburization
otartO at: 760D C, 8 fir; 780' C, 8001) C,
2 fit,; 8200 C, I fir, (3) !~.,)r ;cale -cove red jpecimeris
alid for Jj)QC!1ne1IJ WIAII 4 j)LT'V.1LO11;J1y deC,1rIjA1'1Zed
ourface layev, oltvht cZtvLuv1,z ,al, (up to 1.8%)
itarto at 700-800' C du~.! to dl?Tualoll prot-'ejoes.
However, carbon contt-iit never i-v,,,iches that of the
Mitial carbon mdritc-rit 1.TI (4) Co;i.51derabie
carburlzation ;A' iuvi*ace layt.r ol' ~;cal,_-covervd
'jp(.(A.Mv
ms 111d.I.cateo ',ho ac..i.lon of, Jca1c
durlit", hoal, tl.eatmt~n".
No decarbuvllzat.1~)11 ".;aL; Olt.; (:,.".-(J or',
Card 7/9 m!,t,;h1nt.d or, norimachl tied a ~:.iivface
~k!
~YU p;i
Inve--tigatl !i ol' D.-.-cavljurizat!,,.j.~
of Ball IY_-4vIr,j, Steel DurIng lfett .,0"'I'.12'~,t -P -7/13
Initially dcpA'c--,.-_.-(I o~' for
8 kir at maximum C L-1 a f Illed
With cl;!.'
h'it
wai not e a 1
c
va !I e (I bal 1 -bour I rirltt, e It,~:nIvu a' 7,
for th,!purpo.-t-
jt temperaturez-, abovt' 760" C for tl'~rtn 6 hr 12
not perTiiltterd. P'Le4l"Lti,I of ,--,lie,,I ~:,,umlz2i,uduc"
promotes decarburizat lou. ( th )In or"Iev to dcc-rease
the annealing. period and " empera t ure cirop~; ir,
metal, it i:; nece.3oary to provIde ip-a-ei be1,wt'-e:1
metal parts and decrease wclch*~. of metal. chavge in 'U!-,e
Furnace. (9) -Pearlit,c gva-In structur!-, 13 ;--od-uced,
acrozss the total cvos:.'~ o~" ~,o-d 'by annealin';
sized component,,;I-n tube- (Vor rel'.eving and
structure equal'Lzatlon ) at r,,,axI,-%,;m tc,-,-,pevutures of
71100 C and inaxlmimi holdlrl'r~' tlmo- of 10-12 -.r. B r i g h';
74c)O C lead,; to the fori-,~,at.11on of
annfiallng -tl)ov(
Card 8/9
616 P., vo
d'a -3
'Illvld OOTOW
~j PuT, if 0JV.
.UoqaTlo jo 11"I 011141,10cl Xr.'TT-)UJT)T
1140IJIVIDOCSISV
2uTarq Ta-)I~~ 9uTJoarJ TIT-lq JO
10 110TIPSTICI-aA11I
ACC NRt AP6031651 SOURCE CODE: UR/002o/66/170/001/0139/0142
AUVOR; tubov, P. I.; Kiselev, A. V. jjkr-Z~pv , L. M.; Sukhareva, L. A.; Lygin,
V. I.
ORG: Institute of Physical Chemistry, AcadecV of Sciences,SSSR (Institut fizicheakoy
1,'khimii Akademii naUk SSSR)', Moscow State University im. M. V. Lomosov (Yaskovskiy
gosudarstveanyy universitet)
TITLE: '-'-'ffL%ct of molecular interaction between polymers and solids in the
mechanical properties of polymer coatings
SOURCE: AN SSSR. Dokl'ady, v. 170, no. 1, 1966, 139-142
TOPIC TAGS: polymer- coating, molecular interaction, Werinp --wza4d, internal
stress, 6WMi=gMVehgth, -==W;wg adhesion A"Z-,
ABSTF iudy has been made of'thed interaction of polymer functional groups
with filler surfaces, and of the effect of this interaction on. the internal stresses,
strength, and adhesion of'polymer coatings. 7he experiments were conducted with
i P41-1 polyester resin or FL-50 akyd resin, and aerosil filler, both nonmodified or
i modified with actadecylamine. 'The interaction was studied by IR spectroscopy.
The results of the experiments given in graphic form indicated that the mechanical
properties of polymer coatings are highly dependent on the nature of the molecular
interaction between polymers and solids. Orig. art. has: 4 figures.
SUB CODE: 11, Zo/ SUBM DA%t o7Nc65/ ORIG REF.- 008/ OTH REF: 001
Card upc: 541.68
Iridencleinis in glauccma, Test.oft. no.6t24-Z7 161o (MA 14tl2)
1. Kafedra glaznykh bolesney (zav. - prof.P.Ye. Tikhomirov)
Leningrodskogo 15anitarno-gigiyonichookogo moditsinakogo inatitutao
(GLAUCCMA) (IRIS (=)-ZURGERY)
XRYLOVA,,,j!j,tq MERTSALOVA, O.D.
Variation of density in the free atmoophere over some regiona
of the northern hemisphere. Trudy KIIAK no.30:119-132 165.
(MIRA 18:12)
_Z_
CC NRi AP50134ri SOUPCE CON: OR/03711/G6/000/002/0292/0295
AMMOR; Zubcjv, P. I.; Sukhareva, L. A.; Grozin3kaya, Z. P., Krylov M.; Kochkin,
D. A. ; Rz-i~
y, Acad,:,my ef Srv~,ncnu (Tn!;t1tot flzicli. 1,
OPG: Institute or Phx5lcal chemistr
k I I i M I i-a J-, e m, !'I , 'na A - Gt' I) fi Y
TJ T 111': Study of the physiccuechanical properties of na tyrouia I -bane coatings
SOURCE. Hekhanika polimerov, no. 2, M6, 292-295
TOPIC TAGS: polymer structure, protective coating, nolid physir-11 pvc-perty, solid
mechanical property, adhesion
jr),
ABSTRACT: A two-component DystcIn obtained by co1'o,1Y_t-")FJz1nV n!yjen,~Iwlth malelc anhy-
dride in t1je proportion of 1:1 at GOOC without catalyst or colvent was studied. The
mochanism of forming war. investigated by studying the internal stresses, the Structure
of the coatings, and the strength and adhesion characteristics. Kinetic data on in-
ternal stresses showed that the forming process is practically complete after one hour
c)f curing and that the limiting value of these stresses Is Independent of the condi-
tions under which the coatings were formed. TIA effect of forming temperatum or, the
structure Was studied by IR spectroscopy. Coatings formed fTon) acetone solutionn were
Card 1/2
UDC: 670:539.4019
ACC NRt AP6013477
found to have a weak _qdhjp.,icn to glass (6-7 kg/cm2), but those Fomed from solutionr
of styromal in dimethy1formamide had a higher adhesion (25 kg/cm2). The elasticity
of the coatings Increased upon addition of triettlylene._13jycol. diester of meth~a~ilc
a c 1 d H An increase In the latter gradually lowemd the physicemcchic-mical clilrac-
0
`Ei~~;Istics 0~ the coatings. Coatings most etable to the action oF h1rh tcrporature~s
wetv those obtained from solutions 'in d1methylfor-.-kimi(!-:! cc)ntaining up to '110' TGM.
O1'iY,. JIt. has,, 6 f1gures, I table.
SUB CODEt 07,11/
SUBM DATC: 2lJuo65/
ORTG, REP- 005/ mo mr, o,*,,o
LCard 2/2
L G4
..ZLE,_
'ACC NRi AT5028836 S oi~E' _CCM i -UR/2667/65/0-00/030/0119/0132
AUTHOR: K yloya, L.M.; Mertsalova. 0.B.
ORG; none
TITLE: Variationlof ali ~~in the free atmosphere over certain regions of the
r~ densit
northern hemisphere
SOURCE: Moscow. Nauchno-issiedovatellskiy irjAD_ty_t_&er_QkjimatDj.0g". Trudy, no. 30,
1965. 0 korrelyatsionnykh zaviaimostyakh texperatury I davlenlya v svobodnoy atmosfere
(Correlations of temperature and pressure In the free atmosphere), 119-132
TOPIC TAGS: free atmosphere, atmapheric density, atmospheric pressurep
atmospheric temperature
ABSTRACT: Methods were developed for the determination of the root mean square devi-
ation of the air density, using observation statistics of air pressure and temperature
The problem has recently gained importance due to progress in aviation and rocketry
necessitating air.density evaluations at higher altitudes. Geographical, altitude and
seasonal distributions of density and of density deviations were computed and presen-
ted in form of graphs and tables, and their salient features discussed. The air densi-
ty was calculatedfrom the equation of state
? - WR-rv 10 y/m
where, - air density In grams/meter, p - pressure in mbi R - gas constant, equal to.
Card 1/3
L 26531-66
ACC NRI AT5028836
2870.4 .103 ergs/gram.degreel Tv- virtual temperature. The humidity was neglected *and
actual temperature was used instead of the virtual. A punch card sorting method was
Jevised tomeetthe difficulty in processing density data referred to isobaric instead
a) b) C)
b)
winter
Sumer
to 20 30 07 0 V 20
30 0 00 ZO
Fig. 1. VertIcII'Vistributiod of the mean square deviation of air density fort
a) Coral Harborl b) 'Keflavik; c) San Juan.
of to the actual given altitudes Data processi ag was.accomplished on an electronic coma
Card 2/3
puter. The air density deviation.c~ is related to the deviations of pressure, C~ , and
fcmperature,C~, by the Dines.fnrmlITR (2)'.
V'r( F_r I
(2)
P + 2rp,
where r - is the correlation coetticient between pressure and temperature. The re-
sults re0aled presence of disturbed layers, having increasing density deviati .ons with
altitude. Fig. I shows this phenomenon for three stations; it can be explained by the
behaviour of the correlation coefficients, on the basis of (2). A physical explanation
was folind in the restructuring of the temperature fields in the passage from the tropo.
spheric to the stratospheric regimes. Due to paucity of stations with high level datal
no geographical map of density devintion3 was made. Tnstead, a density distribution
w..s leveloped for a vertical section over a geogr"phical line based on 12 stations, rM
ning from the Antile islands over North America. and Canada (rdmonton) to Greenland,
Iceland and over Central Europe to Aden in the south of the Arabian peninsula. The
large deviations of density over Canada during winter show the result of frequent arc-
tic air invasions down to the 500 latitude. Orig, art. has: 4 figures, 5 formulas and
2 tables.
SUB CODE: 04
Card
SUBM DATE: 00
MIG REN Oll 0111 REP: 001
FREYDLIN,,L.Kh.1 LITVIN., Ye.F.; ZHUKOVA., I.F.; Prinirmal uchastiYu
10MOVA.9- L.K.
Investigation of hydrogenation reactions of piperylene atereolso-
more on a akeletal nickel catalyst. Neftekhimiia I no.2:213-217
Mr-Ap 161~'~ (MIRA 15:2)
1. Institut organiche k khimii AN SSSR im. W.D. Zelinskogo.
(PipGrY1:ne7 (Hyd'rogonation)
AUtalyste, Nickel)
..........
1-4 17
~ I , . I -, ~. ;-I I ~1 2 .- .. '..w
DROBKINJ A.Ye.j Prinimali uchastiyes ODLUBINSKAYA, M.A.; XRYWVA,, L.M.;
MFMXDVAj V,M,
Naphthalene and ammonia content of oil~ahale gae. Trudy VNIIT no.lOt
91-95 161. (Oil shales)(Naphthalone)(Anwnia) (KDtk 150)
BiBUSHKIN, A.A.; GOLIKOVA, V.S.; KRYLOVA. L.M.'; KIWLIFELID, ra.M.;
ZUB(JV, P. 1.
Use of infrared spectrometry in studying the kinetics of the
formation of polymer coatings. Izv. AN SSSR. Ser. fis. 27
flo.7:978-980 163. (MIRA 16:8)
1. Inotitut fisichaskoy khimii AM SSSR.
(Solid film) (Spectrum, Infrared)
;#7
BABUSHKIII, A.A. (14oskva); KRYWVA, L.M. (Mosk-ia); rjf)!?I,'#*, A.I. (X03kva)
Interpretation of the Infrared absorption opectru of formaldehyde
in aqueous solution. 7hur. fiz. khi.-%. 38 rc.10:23hl-2366 0 164.
(MPTIA 18:2)
1. Institut rizicheskoy khimii AN SSSR.
BABUSHKIN., A.A.; KRYLOVA, L.M. (140akVU)
Interprntation of the Inrrazed spectra of water-soluble phenol-
formaldehyde resin. Zhur. fit. khIm. 38 no.lOt2367-2371 0 164.
(MIRA 180)
I. Intititut fizichaskoy khImIJ AN S3-11R.