SCIENTIFIC ABSTRACT KRUGLYAKOVA, G.I. - KRUGLYKH, A.A.

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• Sequence Number: 6
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

IMUGLYAKOVA. G.1.; YASISSUIA, A.A.
-welt
Magnetic susceptibility of zinc blendes as a function of the displacement
of zinc in them by iron. Izv.AN SSSR. Ser.geofiz: no-3:225-227 Hy-Je '53.
(RUA 6:6)
1. Akademiya uauk Ukrainskoy SSR. Institut geologii -nolexn7kh lskopayemykh.
(Magnetism) (Sphalerite)
Clarifies the relationship of magnetic susceptibility
to chemical compn. Investigate magnetic susceptibility, using A.G.Kalashnikov's
system torsion b2lance. Establish that magnetic susceptibility of zinc blendes
can be represented as a linear function of the per cent of substitution of zinc
by iron.
258TBh

,,UUGLTAKOVA, G. I.
Affect of accessory minerals on the formation of reverse polarity rock
maselfso IsvoAN 38M. Berogeofise no*2:214-217 7 135. Oa" 9:7)
l.Akademiya nauk USM. Institut geologii polesnykh lekopayezykh,
(Xagnation, Torrential)
Pe

SOV/169-59-6-,5678
TTanslation fromi Referativnyy zhurnal, Oeofizika, 1959, Nr 6, pp 36 - 37
(USSR)
AUTHORt Kruglyakova, 0. 1.
TITLE- Using the Value of the Residual Magnetization Vector for the
Oeologlcal Interpretation of Geomagnetic Data
PERIODICAL% Novosti neft. tekhn. Geologiya, 1958, Nr 5, pp 29 - 33
ABSTRACT., The author rVorts, that it is expedient for an exhaustive inter-
pretation of I Tnagnetic survey data to determine not only the
vector of the inductive magnetization 11 depending on the maatetlo
susceptibility of rocks, but also,the vector of the residual
magnetization Ir' Becal2ne the rocks a *re demagnetized in the
course of time, the ratio Ir/I is inversely proportional to the
time passed since the moment of the rock's orlglnatlon, Hence,
-this relation may be utilized for determining the stratigraphic
and, partly, also the absolute age of magma formations charac-
terizing the structure of the basis and, sometimes, also of the
Card 1/2 sedimental rocks. The curve of the dependence of the ratio 1,/1i

SOV/169-59-6-5678
Using the Value of the Residual Magnetization Vector for the Geological
Interpretation of Geomagnetio Data
on the age of rooks is given;thid ratio I./I. is approximately zero for the
Arshean era, but for younger formations the ratio increases with an In-
or4asing rate and attains a value of 40 a;id more for rook3 of the Tertiary
period. The considerable Importance of investigating the vector of residual
magnetization for -the studv of the paleomagnetism is emphasized.
M.V. Sokol'skly
Card 2/2
N

240) -
AUTHORt Kruglyakoy,,,-G,-.-1,-.. BOY/20-123-3-17/54
TITLE: The Dependence of the Magnetic Susceptibility of Salts on the
Content of Water in Them (Zavisimoot, magnitnoy vospriimchivooti
soloy ot soderzhaniya v nikh vody)
PERIODICALt Doklady Akademii nauk SSSR, 1958, Vol 123, Ur 3, PP 443-445
(USM)
ABSTUCT: The antatio magnetometer of S. Sh. Dolginov is very often used
for the determination of the magnetic susceptibility of rocks.
It is advantageous to graduate this apparatus according to the
relative methodq using paramagnetic salts. Various salts( which
can be anhydrous or hydrated) are used for the graduation ofthis
astatic magnetometer by field- and atationary magnetic
laboratoriess Anhydrous salts: CoCl 2' COS049 Niso 41 N'Cl2t W047
MnCl 21 POS04(NH4)2SO4 0 Crystal hydratest CoOl 2* 6H209 COSO 407H2 Ot
Niso 4*7H20, Nici 2* 6n 20, MASO4-5112 0, MnCl 2*4H 20,
FeSO 4 (NH 4)2SO 4* 6H 20 . The dependence of the magnetic
susceptibility of a salt on ito water content is not described
Card 1/3 by a straight line between the maximum value of the magnetic

The Dependence of the Magnetic Susceptibility of SOV/20-123-3-17/54
Salts on the Content of Water in Them
susceptibility of the anhydrous salt and the zero value of the
magnetic susceptibility which corresponds to 10% of distilled
water. The author in short describes the investigations carried
out in order to find the dependence of the magnetic suaceptibilitr
of the salt on the water content. This dependence tan be
characterized by a broken line. The higher the magnetic
susceptibility of an anhydrous salt, the sharper the breaks of
the lines. In some cases (of low magnetic suaceptibility)t the
breaks are hardly noticeable. The first part of the curve
connects the magnetic susceptibility of the anhydrous salt with
the magnetic susceptibility of its crystal hydrate, it
characterizes their mechanical two-phase mixtures of various
percentages of the 2 phases. If the added water increases in
quantity, more and more molocules of the anhydrous salts are
hydrated and magnetic susceptibility decreases to the value of
the magnetic susceptibility of the fully hydrated crystal
hydrate. The second part of the curve characterizes the
two-phaeg mixture of the crystal hydrate with the saturated
solution of the salt. It connects the magnetic susceptibilities
Card 2/3 of the crystal hydrate and of the saturated solution of the

The Dependence of the Magnotic,Suooeptibility of SOV/20-123-3-17/54
Salts on the Content of Water in Them
given salt, characterizing their mechanical mixture. The third
part connects the magnetic susceptibilities of the saturated
solution and of distilled water. According to these consideratiaasp
the concentration of the salt in the solution may be deduced
from the magnetic susceptibility of the solution. There are
I figure and 2 Soviet references.
ASSOCIATIONt Institut geologii poleznykh iskopayemykh Akademii nauk USSR
(Institute of the Geology of Useful Minerals of the Academy of
Sciences, UkrSSR)
PRESENTEDs JunelO, 1958, by Ve N,-Belov, Academician
SUBMITTED: June 10, 1958
Card 3/3

SUBBOTIN, S.I.; WNDARE14KO,, A.P.; KRUGLYAKOVA G I (Kruhliakova, H.I.];
KLUSHIN V.I.1 G. I (FetkoVeh H.I.]
f F
Progress in geophysical studies of veatern regions of the
Ukrainian S.S.R. during the Soviet regime. Pratei Inst.
geol kor;kop. AN URSR ItI18-148 159. (MIRA 14:6)
tUkraine--Prospecting--.Geophynical dattO

S/049/60/000/01/022/027
E201/9191
AUTHORS: Kruglyakovaq G.I., and Kruglyakov, V.V.
TITLEs ---Thvl~ee = Meature of Lava Flow on Remanent
%vXagnotization in Rocks
PERIODICAL: Izvestiya Akademii nauk SSSR, Seriya geofizicheskaya,
1960, No 1, pp 158-160
TEXT: The experiments:were carried out on basalt deposits in
Berestovets and Yanova Dolina in Volyn (Ukrainian SSR). The lava
streams were between 12 and 14 m, thick. It was found (Table on
p 160) that the vector of remanent magnetization In basalt refleots
the geomagnetic field existing during the period of formation of
the rock only in the portion where lava flow was laminar. If lava
solidified below 675 OC the direction of the vector of remanent
magnetization could differ greatly from the direction of the
geomagnetic field of the given period even in portions where the
flow was laminar. The edges of lava streams, where turbulent
motion occurred, had random magnitudes and directions of remanent
magnetization which were not necessarily related to the magnitude
and direction of the geomagnetic field of the given geological
Period. It follows therefore that in paleomagnetic investigation",/
Card 1/2

8/049/60/000/01/022/027
320LE191
The Effect of the Nature of Lava Flow on Remanent Magnetization
irk Ro cks
one should use samples near lava craters, and then only the central
portions of lava streams.
There are 1 table and 4 references, 3 Soviet and 1 Eng'-ish.
ASSOCIATION: Akademiya.nauk USSR, Institut geologii poleznykh
iskopayemykh
(Institute of Geology of Useful Minerals, Academy of
So-l-ences I u1craMan 30)
SUBMITTED: January 81 1959
Card 2/2

7A
AF-'
KRUGLTMVAP G.L.-
Relationship between magnetic anomalies and therelief of the
terrain. Truft NIZHIR no.16139-51 W. (MM 34:3)
(YApatio anaWliee)

s/169/62/000/008/004/ogo
E202/E192
AUTHOR: Kruglyakoval G*I*
TITLE: The possibilit`y-o-f-Wtu~dying age relationships of
rocks adcording to their state of magnetisation
PERIODICAL: Referativnyy zhurnal, Geofizika, no.8, 1962, 9,
abstract 8 A 44. (In the Symposium: 'Sostoyaniye i
perspektivy razvit'iya geofip. metodov pGiskov i
razvedki polezn. iskopayemykh' (tThe present state and
perspectives of developing geophysical methods of
locating and prospecting for useful minerals$),
Gostoptekhizdat, 1961, 509-512).
TEXT: Periodic changes in the polarity of Earth were
established on the basis of palcomagnetic studies. Once the
changes in the polarity are known in sufficient detail they may
be used to develop a geochronological scale which is useful in
studies of sedimentary barren beds. In the case of eruptive rocks
the relation between the magnitude of the residual magnetisation
vector and the magnitude of induction has also to be considered.
Card 1/2

The possibility of studying age ... s/169/62/000/008/004/09()
E202/EI92
This ratio will be close to zero in the case of more archaic, and
will approach maximum in the came of recent formations. On these
bases, having determined the quantity of the above relation for
the samples of various ages, it is possible to use this parameter
in determining the age of crystalline rocks. Certain massifs of
the Ukrainian shield were studied, for which the relation between
the magnetisation and age was established.
~Abstractorls note; Complete translation.-'~
Card 2/2

KRUGLY'll-XiVA, G.J.
Reuults 0
paloomagnetic studica of tho Ukrainian crystalliro
mausif and adjacent region. Izv. A14 SSSR. Ser. geofiz. to. 2:23"1-
24J, F 161. (IMU 14:2)
1. Institut geologii poleznykh ishopayerrIkh AN
Mraine-Rocki3.."Magne tic proportics)

- KRUGLYAKOVA, C.I.
Results of paleomagnetic research in tYe Ukraine. Izv. AN SSSR.
Ser. geofiz. no.lltl674-1678 N 161. (YJRA 14:11)
1. Akedemiya nauk USSR, Institut geologil poleznykh 15kopayemykh.
(Ukraine-Rocks-Magnetic properties)

BORISGVt A.A.; KRUGLYAKOVA, G.I.
Deep-seated structure of the earth's care at Transcarpathia.
Izv. AN SSSR. Ser. goofis. no.llsl497-1501 N 162.(MIM 15:3-1)
1. L'yovskiy filial Instituts. geofisiki AN UkrSSR.
(Transcarpathia-Sartli,-Interna1 structure)

KRUGL740VA, G.I. (Soviet Union)
Interpretation of magnetic anomallea and the dAp tectonic
structure in Transcarpathia. Geofix kozl 13 no.2tl75-200
164.
J4

-Z'lIFt.9neF.IZM I &errmcmiya, v. 3 . I I
-Rog I
nm -ul-emloula MRg et-le f - tie anmmnly, magnetic sur~Vaying.!
Lia
-q 1 Lr Y!a;, -ng

ACC NR: AI'7008912 SOURCE CODE: UR/0215/66/000/OLI/0068/0077
AMCEOR: 1:niglyakov, V. V.; Kruglyakova G
W,G: Leninprad Division, nst tuto or arrostrial Magnetism, the lonospher
anid F~idio Wave Propagation (Instltut Zomnogo inagnatizma, lonoafery I
rasprostranenlyn radiovoln, Leningrildskoye otdoleniyo)
TITL;: Importance of epetrogenic, curves for interpreting the apatial
distribution of tile geomgnotic field
SOURCZ: Sovetsknya goologlyap no. 11, 1966, 68-77
TOrIC TAGS: geonagnatic field, geophysics
SU3 COX,; 08
a jUS TRACT:
1ho paper begins with a discussion of the imporLancu of a I=wl-
edge of tho distribution of the geomagnotic field for dotoiv:in - tl
In, io
presence of mineralization and a description of the gwma,;-notic fielf!
of the 5outhern Urals at different hni&t.
Fig. 1 saows ZIT, anctaalio3
at a height of 6 kr.; Fig. 2 is the same for J hoigbt of .30 ka; Fig. 3 is
a diagram of the block structuro of t1io Souti-iorn Urala. The Southern
Urals have a block structure and the blocks aro separatod by a notwork
of doop faults of different ago. The now data which can be obt."Win4
from, the uzo of opoirogonic curves (supplementing other mothods-) is the
main part of the articla, It is zhown that their use in analyzing the
thicknossos and rates of accumulation of aodlments within this area
(from the Precambrian to the Upper Paloozoic) gives important informa-
tion on the characteristics of development of those blocks and the
L,-ar4 1/2 UDC: 550.38

ACC NR, A117008912
hizitory of dovolopment or tho region as a whole. Specifically. by'
corparizon of the geophysical fields of the blocks and the character or
sedizientation it Is possible to establish for each block: whether the
,oophysical riold of the region is caused only by the influence of the
pct,.,oZ;raph1c composition of the roctc3 forming tio basemont or if t-ho
gootoctAjiv~c charactoftitics of the area al.-o play a role. Comparison
of t2ho pattern of spatial distribution of the ma;-,netic field and ttlio
cliaractor of twdii4ontation nake3 it possible to datoct deep faults
,,=ng tho 3urface faults ', the ti;rao thoy vore formod and the poriods. of
tac~,r raxi;~~tu activity. The deep faults in the Southern Urals dotectod
by 'L~ils zo.hod aro of importance in ovaluating tho motallogom/ of t~lo
arc.a --' tho condItiona or or* formation. Arolysia or the opelrogonio
CUr;es can be usod for correlation of faultn In relation to an ovaluation
of their role In mineral formation. Origo art. hass 4 figures. SJ;IRS.,
39,719
2

KRUGLYAKOVA, I.F.
Comparative evaluation of the depressive action of some drugs
on the retinal vessels. Vestn. oftal. 76 no,4134-38 Jl-Ag'63
(KIRA 1721)
1. Kafedra glaznyk-h bolozney (zav. - prof., O.I.Shershevskaya)
Novokuznetskogo iLstituta usovershenstvovaniya vrachey.

I Che
USSR/ mistry - Peroxides Jun 4,-
"Is There a Higher Peroxide of Hydrogen!" Prof N.
Emanuel', K. Ye. Kruglyakova, Inst of Chem Phys,
Acad Sci USSR
vrirodal, vol 41, No 6, PP 103-105
Assitzr-s that the peroxide kG4 exiats in aq solns
of H2%, because (1) reaction kinetics show that
the nwaber of active centers producing deconpn of
R,O_ (HO2 radicals that combine to form'9204) is
ie
undiminished after chilling and reheating of the
soln; (2) the amt of oxygen evolved is less than
that which corresDonds to the amt of hydrogen
peroxide decomposed; (3) this discrepancy becozr-s
smaller when the soln has been aged fc.- 1 mo at
room tenLp; (4) evolution of oxygen is delayed after
acidulation of CaO4 with di-I acid.

- --- -IRMLYAKOVIL, Y-.--Ye

-6 ;%J'jjj!dj + ju .16 12 +
Ing 1-4-1 +
ell
Ifl, I I.I, A
lei
1 6
Is
lilt
"(5 Al

AUTHORS: Kruglyakova, K. Ye., and Emantiell., N. M. 62-1-2/21
TMZt Kinetic Characteristics of the Reaction of Propane Oxidation with
Oxygen with Chlorine Admixtures in Quartz Crystal Vessels (Kinet-
icheskiye kharakteriBtiki reaktaii, okisleniya propana kislorodom,
B dobavkami khlora v kwartBevykh soaudakh)
PERIODICAL% Izvestiya Akademii, Nauk SM,, Otdoleniya KhiAcheskikh Nauk,, 1957,
No. 1, pp. 18-28 (U.S.S .R.)
ABSTRACTt Investigations were conducted to determine the effect of chlorine
admixtures in oxygen used for the oxidation of propane at various
atmospheric presamvB and temperatures ranging from 250 to 3550.
It was found that wall additions of Cl accelerate the propane
oxidation process and increase the yield of oxygen-containing
compounds, An increase in temperature from 250 to 3550 is followed
by a noticeable increase in the amount of peroxides in the oxidation
products and the time needed for maximum concentration of the peroxides
Card 113

62.~
4;gI2
Kinetic Characteristics of the Reaction of BMpane Oxidat on th
Oxygen with Chlorine Admixtures in Quartz Crystal Vessels
decreases. The introduction of larger Cl-additionB was found to be
impractical because it does not increase the yield of valuable
oxygenous products and the deep-burning processes are stimulated.
The total amount of carbonyl. compounds uas determined by the ordinary
bydroxylamine method and it is shown that the error in determining
the carb;jnyl compounds, due to the presence of peroxides which also
zeact with the hydrochloride of the hydroxylamine,, was no higher than
3 - 5% of their total content, The content of acetaldehyde,, formaldehyde.,
organic acids and peroxides reaches its mmcLmum within 1 min, The
peroxide, being an intermediate miDlecular product, is being slowly
consu.med, whereas the acetaldehyde, formaldehyde and organic acids
remain unchanged during the continuing oxidation process. The gaseous
reaction products includes 002,, Co,, and unsaturated hydrocarbons. The
nature of the peroxides forming during Cl- catalyzed oxidation of pro-
pane is described as a mixture of hydrogen peroxide of isopropyl and
hydrogen peroxide.
Card 2/3 Graphs, drawing. There are 9 references, of which 7 am Slavic.

6P-1-2/23.
Kinetic Characteristica of the Reaction of Propane Oxidation with
Oxygen with Chlorine Admixtures in Quartz Crystal Vessels
ASSOCIATION: Academy of Sciences USSR, Institute of Chemical Physics
PUMNTED Bri
SUBX=t June 8, 1956
AVAIUBZZ i IdbraT of CauMes
Card 3/3

5(4),
AUTHORS: Kruglyakova, K. Ye., Emanuel', IN. V. SOV/62-59-3-6/37
TITLE: Some Particular Features in the Behavior of Intermediate
Molecular Substances Durin,f,, Propane Oxidation (Onobennosti
povedeniya molckulyarnykh promozhutochnykh veahchestv pri
oki3lonii propana)
PERIODICAL: Izvestiyh Akademii nauk son1l. Otdclonlyo khimicheakikh nauk,
1959, Nr 3, pp 417--424 (USSR)
ABSTRACT- In the present paper the attempt was made to explain the role
of some oxidation products - acetaldehyde, methyl alcohol,
acetic acid - during the development of the reaction by
kinetic methods. Besides, the problem of the nature of the
maximum yield of one of those products (acetaldehyde) was
experimentally investigated. In figure 1 the kinetic curves of
the formation of intermediate products are presented. Under
given experimental conditions it could be seen that propane
is consumed durinC the formation of acetaldehyde, formaldehyde,
and methyl alcohol in practically equal quantities. The
effect exerted by acetaldehyde additions (1.78P 4-3v 5-5 %)
on the formation kinetics of the intermediate products is given
Card 113 in fij7ure 2. It was proved that these additions increase the

Some Particular Features in the Behavior of Inter- SOV/62-59-3-6/37
modiste Volocular Sitbutancon DurJnl-, Propane Oxidation
oxidation rate of propane, whereby acetaldehyde, formaldehyde,
and apparently methyl alcohol are formed. The maximum concen-
trationa of the oxidation products remain the same as in
experiments withatit additions. The addition of acetic acid
(0.20 r1t) and methyl alcohol (2-7 1"')) does not affect their
yield (Table). BI means of tagged stoma it was proved that the
maximum concentration of acetaldehyde represents a special
case of the dynamic equilibrium. Apparently in the moment of
the maximum concentration both the formation and consumption
of this product are retarded,, This might be due to an inter-
action of the intermediate products with the radicals of the
chain, wherein less active centers are formed which guirantee
the retarding effect. The lacking activity in dimedone,
derivatives of formaldehyde confirms the assumption that the
latter in not formed from acetaldehyde but indepcndantly of-it.
The value of the specific activity of carbon monoxide a 125
impulses per minute. mg and C02 (132 impulses per minute mg)
indicates that CO and C02 are not only formed from
Card 2/3

Some Particular Featureu in the Behavior of Inter- -0V/62-59-3-6/37
mediate .11olecular Substances During Propane Oxidation
acetaldehyde but also in another way. There are 4 figuresp
1 table, and 18 Soviet references.
ASSOCIATION: Institut khimicheskoy fiziki Akademii nauk SSSR (Institute
of Chemical Physics of the Academy of Sciences, USSR)
SUBMITTED: May 30, 1957
Card 3/3
.v-,

sov/62-59-6-8/36
Emanuel't
5M y
KruglyakOvat
AUTHOR51 iation Of Propane Induced by Chlorine in
TITLE$ Kinetics Of the Oxil erent SN (Kinetike, v Gosudakh a nasadkOY
p"ks& Vessels at 1Xff okieleniya propane,
iatsiirovannogo khlOrOm
pri raznykh S/V). naut 653h- otdeleniye khimioheskikn nauki
PERIODICAL, Izvestiya Akademii _ 1010 (USSR)
1959, Nr 6, pp 1o05 sibilitiss of observing
f introduction the different POO process mentioned in
ABSTRAM By way 0 etion which 000ure witn the I d be ob-
the chain rea with in brief ~Hefe -17)- It coul
e are dealt m.raised upon the
the titl iderabl* influence is is to sayl by their
served that a Con end of the vessel, that vestigation
process by the wa e made Ofe For the i
shape and the material they ar el.was used made Of
reported on'in the present Paper a vess sisting of
gle,ss which was equipped with an insert con tore
sodium type Out with difrerent dia.39
glass balls Of the same investigated with a mixture of
(5950.7 ma). Oxidation was of 346 1 at first in a vessel
03a8 10 2Jti at-a temperature the reaction kineticein figure
Card 1/3 without-aft insert.( .curves of
Kinetics
Packed Ve Of ths Oxidation of Propane Induced bY Chlorine in :;0T162-59-6-8136
addle at Different SIV
Card 213
ln this case already no agreement with the data Given in
reference 18 could be found. (These data were obtained by using
a quartz vessel f6r the reaction). When using the ball shaped
inserts the reaction was considerably accelerated (mostly if
the balls had a diameter of 1.7 mm), but on the other hand the
yield In aldehydes decreased. It is because of this accelera-
tion that the reaction may also be carried out in the presence
of chlorine without inflammation of the mixture (Fig 2). in
this Cade the chlorine (0-5%) despite of its accelerating the
proceed also secured a high yield In aldehydes. The kinetic
curves which all (witho and without addition of chlorine that
only influenced the yield In aldehyde.) exhibit an S-shape may
easily berepresented by the autooatalytic function of the first
order, if only not the Initial but the final concentration of
the product is taken as standard for the reaction intensity.
Thus the reaction is self-accel rating and the Insert only
influenced the ramification of Ohs chains as with this ball
t
shaped Insert a reaction surface is formed which takes part
in the process of ramification. The peroxide which otherwise

Kinetion of the Oxidation of Pronane Ii.duced by Chlorine 3OV/62-59-6-8/36
in Packed Vessels at Differant S/V
as intermediate product disturbs the reaction may without any
difficultiea be decomposed on the burning surface. There are
8 figures and 18 references, 13 of which are Soviet.
ASSOCIATIONs Inatitut khimioheskoy fiziki Akudemii nauk SSSR (Institute
of Chemical Physics of the Academy of Sciences, USSR)
SUBVITTED3 August 23, 1957
Card 3/3

5 Wo 5 (4)
AUTHORSs Kruglyakovaj K. Te.0 Emanuel', 11. M. SOV/62-59-7-9/38

TITLEt Aotivation of the Container Surface by the Reacting Mixture
C3H8 + 02 in the Presence of Chlorine (Aktivataiya poverkhnosti
sosuda reagirayushchey ameyslyu C 3Ha + 02 v prisutatvii khlora)
PERIODICALt Izvestiya Akademii nauk'S33R. Otdeleniye khimicheakikh nauk,
1959, Iqr 7# pp 1211-1215 (USSR)
ABSTRACTs By way of an introduction there is a brief reference to own
papers and to papers of Sergeyev and Shtern (Ref 2), Kalineako
and Voyevodskiy (Ref 3) being in connection with the problem
under review. This paper reportn on the discovered activation
effect as it in called in the title. The existence of the effect
was concluded from the initiating effect of the surface of the
container on the oxidation in the abnence of chlorine followinir
exnerimento with chloroinitiated oxidation of propane.
The apparatus on which the experiments were carried
out is described in paper reference 5. The reaction kinetic
curves with and without Ae addition of chlorine at 3350 are
plotted in figure i. The chlorine influences strongly the yield
Card 1/2 of acetaldehyde. This influence of the chlorine could only be
04 -
H

Activation of the Container Surface by the Reacting SOV/62--59-7-9/38
Mixture C3H8 + 02 in the Presence of Chlorine
ASSOCIATION:
SUBBITTED:
Card 212
noticed in quartz containers with a glass splinter filling. In
containers made of other material also the formation of
formaldehyde wns influenced. There are accordingly two ways
independent of one another to produce both aldeby, den. A
production scheme of both aldehydes in -iven (for the formaldelvda
according to the schomo of Somenov and Shtern (',Iefe 41 6)).
Furthermore, the yield of fonialdehyde -jid acotaldehyde in
investigated in dependence on the reaction temperature and
addition of chlorine. In fiGure 3 alco the secondary effect of
chlorine in to be aeon (decrease of the yield of aldohydea at
high temperatures). There are 4 figuren and 6 S,,viot references.
Institut khimicheskoy fiziki Akademii nauk SS3R (Institute of
Chemical Physics of the Acade.V of Sciences, USSR)
October 24, 1957

ti IX0
AUTHORS-
TITLE:
PERIODICAL:
82689
S1062 60/000/008/002/012
B004YB054
Kruglyakova, K. Ye. and Emanuel', N. I.
Macroscopic-------- nelOxidation in
stages ifi the Reaction of Props.
the Presence of Chlorine
Izventiya Akademii nauk S"MR. Otdeleniye khimichenkikh nauk,
1960, No. 8, pp. 1342.-1347
TEXT: Various investigations (Rofij. 1-4), --in scoll an pa!)vrn by V. T,
Urjzko and M. V. Polyakov (110f. 5), 1% ';. Yeniko~opov iml '% ~'on;iruva
(Ref. 6), studied the kinetics of oxotheruic Chitin hi measuring
the development of heat in tho ronction inixture. The exintence of two time-
separated macroscopic stages was obsorved. The authors npplied -this method
to study the course Of propane oxidrition. Fip. 1 slkovks the cvivves of heat
development rind prounure0variation foi- the stoichiomotric mixture
C3He + 02 at 340 and 35B C and 244 torr. The heat development shows a maxi-
mum. The linear course of the function log Ap - f(t) corresponds to Semenov's
law on the initial stage of branched chain reactions. With addition of 2%
by volume of chlorine, the character of heat development changes. Fig. 2
Card 1/5

82689
Macroscopic Stagen -in the Renction of Propane S106 601000100810021012
Oxidation in Lhe ilreonace of Chlorine B004YB054
shows the course of reaction at 3270C. There are two maxima. the first
after 25 sec, the second after 600 sea. Figs. 3-5 sho" the courre of re-
action with di9ferent chlorine additions (3-5~, 8%) and temperatures
(340, 358, 372 C). The existence of two maxima is explained by the course
of two degenerate branched chain reactions. The authors give the following
reaction diagram- B + R -10- C + R (1); C -4 2R ~2); A + R1 -10 D + Q1 (5);
D + C --b- 2R1 (4); R --.Yo loss (5); R' --b- lose (6 , where B is the initiating
admixture, A the initial substance, R and C the free radical Lnd the end
product of the first reaction, R1 and D the free radical and the end product
of the second reaction. The linear breaking-off of the reactions (5) and (6)
is caused by the loss of radicals on the walls of the vennel. The authors
write down the differential equations for tho reaction substituto th,~
experimental data for concentration, as well an the conntants, and obtain
the kinetic curves Fig. 6 for B, C, and D by means of niimerical integration.
The equution AT 1A a k(Q1W1 + Q2W 2) is written down for the tic-tit develctpmentj
where Q1, Q2 denote the thermal ort,ect of the firat Lint] aecotH stfAge_ re-
2/d~. (It _
spectively, W -dB/dt; W - dD/dt; k - R f t il, I I
2 1
vessel, 4 mean heat conductivity of' thc i'viic-iiie,
Card 2/3
-7

82689
Macroscopic Stages in the Reaotion of Propane S/062/60/000/008/002/012
Oxidation in the Presence of Chlorine B004/BO54
14ciL thi., OqU~tlon exhiliito of raiscLift ;irrOngolin to the experimont1j,
do ~ mi 0in j.,ji L I o,,0(', L.,1/11 1? . Vhe wiLhora thrwk 0. G. Knorre for the
discau~i,jll. There urd f (1,dre" und 7 Soviet reforencea.
ASSOCIATION: Institut khinioheskoy fiziki Akademii nauk SSSR
(Institute of Chemical Physion of the Acadomy of Sciences
USSR)
SUBMITTED: January 28, 1959
Card 3/3

KRUGLYAKOVA, K. 1W, and NIKOLAYVA, 11. V. (USSR)
"Inhibition of the Radiation Depolymeriz;;.tion of DUA by I-Ohibitors
of Radical-Chain Processes."
Report presented at the 5th Int~-.rnational Biochemistry Congress.
Moscow, 10-16 Aug 1961
71.71 _1717
7777"

KRUGLYAKOVA, K. Ye. Cand Chem Soi -- netios and chamism of A chlorine-
initiated reaotion of Us oxidation of propane." Moe, 1961 (Hoe Order of Lenin
and order of lAbor Red Banner State Univ im M. V. Lomonosov. Chem Faculty).
(KL, 4-61, 187)
-70-

34759
S/020/62/142/003/027/027
B144/BIOI
AUTHORS: Nikolayeva, N.
Baynahteyn, B.
Member AS USSR
V., KruC1y&kava,_1. Yp,._Kivelev, N. A.,
K., and Emanuel', N. M., corresponding
TITLE: Reduction of radiation damage of DNA molecules in the
presence of propyl gallate (PG)
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 142, no. 3, 1962, 713-715
TEXT: The present study concerns the protective effect of PG on 0.007%
D111A solutions which were prepared from the spleen of rats and diluted in
0.1 M ammonium acetate, p1l 6.2, to 0.0015%. The.intr~'nsic viscosity[
of 25 dl/g corresponds to a molecular weight of-,,3-10 , the coefficieni
of molar extinction 6 (r)260 mg ' 6450. Doses of 66,000, 168,000, and
336,000 r were applied with a D-2 (BF-2) short focus x-ray teat apparatus
(8 ma, 75 kv, Mo anode, without filter), dose intensity 135,000 r/min.
One-stage carbon replicas were examined in an IEM-5G electron microscope,
accelerating tension 80 kv, magnification la-25,000 times, The damage
Card 1/3
4

Reduction of radiation damage...
q
3/020/62/142/003/027/027
D140101
percentage increases from 50 through 75 to 100% after irraliation doses
in the above-mentioned sequence. In all cases addition of PG guarantees
a 40 - 50';v' protection of DNA molecules (Fie. 1~. The size of the DNA
molecule fragments is greater with PG addition than without. Further
studios are needed to decide whether these fragments are incompletely
decomposed molecules of the 'initial DNA or a result of croas-linking
facilitated by PG. PG addition after irradiation and testing of DNA
and PG as to their biological activities may solve this problem. There
are 2 figures and 19 references: a Soviet and 11 non-Soviet. The four
most recent references to Englieh-language publications read as follows:
A. R. Peacocke, B. N. Preston, Proc. Roy. Soc., Ser. B, 153, No- 950, 90
(1)60); R. La-.arjet, H. Ephrussi-Taylor, N. Rebeyrotte, Radiation Res.,
Suppl. 1, 417 (1959); F. M. Defilippes, W. R. Guild, Radiation Res., 11,
389 (1959); P. Alexander, K. A. Stacey, IV Internat. Congress of
Biochemistry, Vienna, 1 - 6 Sept., Symp. IX, 1958,
SUBMITTED: September 30, 1961
Card 2/3

S/020J62/142/003/027/027
Reduction of radiation damage ... B144/B101
Fig. 1. Change in intrinsic viscosity of DNA solutions before and after
x-ray irradiation.
Leigend: (1) control (before irradiation)l (2) irradiation with PG additionj
(3) irradiation without PGt (a) hours; (b) dl/g.
Card 3/3

LMITS, D.V.; MUGLYAKOVA, K.Yc.; PMTNIKGVA,, H.S.; MOULLI, N.M.
Suppression of the development of vegetable tumors (potato
eaWwr) by inhibitors of radical processes. DoklAN SWR 145
no.1:212-zu n 162. (ML 15:7)
1. Vaesoyuznayaimcbno-iseledovatellskaya stantsiya po ralm
kartofelya Voesoyuznogo institute. zashchity rasteniy i Institut
khimichaskoy fizW JW SSSR. 2. Chlen-korrespondent AN SWR
(for Vmmiel'),
(Potato wart) (Gallic acid)

ACCESSION ZIR: AP300010 S/0O62/63/0O0/W5/0789/0M
AUTHOR; Sholinas So Iq Bogo2pbAdys Vo Aq !n!~,
~-At
TITIZ: Antioxidative effectiveness of some hydroqiainone derivatives
.SGURCE: AN SSSR. Izvestiya. Otdoleniye khWicheskikh nauk, no.' 5# 1963,, 799-793'
~TOPIG TAGS: antioxidantso hydroq4none derivatives# Mannich reaction
ABSTRACT: The authors describe the synthesis of the following compounds by smino-
'mothylation using the Hannich reaction: (1) 2,5-bis-(dimethylaminomethyl) hydro-
,quinone; (2) 2,3-bis-(dimethylamirxnathyl)-5-isopmpylhydr*quinono; (3) 205-bis-
-(diethylamin=ethyl)hydroqd.none; and (4) 2-diethylamir=othyl-4-cathoxvphenol.
Compounds M-M proved to be wore effective antioxidante than hydroquinone and
propylgallate when tested under standard conditions with methyl oleate at 90C and
alli 0 sub 2 pressure of 300 mg Hg for 20 minutes. .13ubstitution of mixed alkyl and
aminomethyl groups (compound 1) increased the antioxidative effectiveness to 5
times that of hydroquinone. Subutitution of a secondary aminomethyl group in the
.0-position in the monoothyl other of hydroquinone (compound 4) had no effect on
the antioxidative properties. "The authors express their gratitude to No M.
Emanuel'- for his continued interest in their work." Origo art. has: 2 figures,
.1 formulap and 1 4bles
.Card
Yi,
J,

ACCESSIO14 NR: AP3000120
A=IATIOM: Instiiut khimicheskoy JUild Akademij nauk sssR (Institute of
Chemical Physics, Acadow of Sciences SSSR)
samnum: 22jun62 DATE ACQ: 12 Jun63 ENCI: 00
1SUB CODE: CH NO REF SOVt 003 OTHM: 004
,Card 2/2

ACCESSION NR: A4000127 810062
163/000/00/OM/OM
K. He
AUTHOR: Smiraov,, Lo Do; Molina# So Iq q Dyumayw,
TITLE: Space restricted 3-a3qpyr1d1nae* Report 29 4nthesis &W the study of the
antioxidizing properties of mme 2#6-4i&lJq1-3-ca7pyrid1nas and 2*6-diallql-4-
(diaLkylamino)iaothyl-3-oxypp,idlnoo
SOURCE: AN SSSR. Izvestiya. Otdoleniye khimichaddkh naukp no. 5, 1963,F 890-893
TOPIC TAGS: s7nthcais of 2-&Ik;yl-3-ax7~-"athylpyridinam, antioxidants, 2-athyl-
6-met1iyl-3-oxypyridine
A3STRACT: Me present work is devoted to the synthesis &W study of the properties
of antioxidants 2,6-dialkyl-3-Qm7pyridines and 2,6-dialkyl-4-(dialkyladno)mathyl-
3-oVpyridines, whose stru.,tures are closely related to vitamin B6. The synthesis
of a minber of 2-alkvl-3-oxy-6-~methylpyridines by reaction of 2-acyl-5-asthyll^urans
with =monia has been realit6do The antioxidative effect of a=e 2#6-di&lJq1-%1+-
diaL'-.71=inomothyl-3-*:qpyridinea has bm studied in the oxidation r-Action of
methyloleate. Me =at effective antioxidant was found to be 2--athyl-6.Mathyl-3-
oxypyridine. The introduction of direthyladnmethyl, mathylpiperidine and methyl-
raorpholine groups into the 4th position of 2,6--di&1Vq1-3-ozypyridine* practically
Card

ACCESSION NR: AP3OOaW
eliminates the antioxidative properties of these materials. "The authors wqwess
their gratitude to N. H. Emanuall for his continued interest in this work.".. Orig.
art. has: 1 table,.~l graph,:'=4 I equation.
ASSOCIATION: Inatitvt khimichaskoy finiki Ak&ladi nauk SM (Institute of Chemi-
cal Physics,, Acadwq of Sciences SM)
sumiTTED: 29jun62' OATS AOQ: 12Jun63 ENCLx 00
,SUB %OODE: CH NO MW SOT: 002 OTIM: 010
Cord 212

L 12717-63 W (j)/EPF(c)/EWT(l)/EWT(m)jBDS A.FFTC /ASD rc-4/Pr-4 lrd/RT4/JFW
ACCESSION M AP3002301 S/0062/63/000/00'6/1143/1143"
AUTHOR: Emanuel', N. M.; Kruglyakova, K. Yo.t Vichutinakiy, A. A.; Vasil'
R. F.
.ijiluminescence of solutions of dasoxyribonucloic ac
TITLEi Che idj(DRNA) after
irradiatiorPUlth x-rays
SOURM AN SSSR, Izvo Otdeleniye khWcheakikh nauk, no. 6t 1963, 1143
TOPIC TAGSs chemilumine sconce, dosoxyribonucloic acid (DRKA), x-rays, irradiation,
peroxides, recombination of radicals
Y,.'--RACTi A low intensity thsailuminescence has been discovered following irradia-
+-~cn of DRNA solution. Thu intensity falls exponentially with time. It was shown
chemically that the peroxideE arising from irradiation of DRKA decompose according
to the same law at approximately the same rate. The c-hemil=inesconce may arise
from recombination of radicals formed froa peroxides produced in the irradiation.
ASSOCIATION: Inatitut khimichlkoy fiziki Akademli nauk SSSR (Institute of Che=i-
cal Physics, Academy of Sciences SSSR)
SUBMITTED: 25 Feb 63 DATE ACQ: 16 Jul 63 ENCL% 00
SUB CODE : 00 NO REF SOV: 004 OTHERt 000
Card 1/1

SAMOKHVALOV G.I.; BUDAGYANTS, M.I.; SHAKHOVA, M.K.: SHOLINA, S.I.;
KR~dLYAKOVA,,,K.Ye.; NIKOLAYEV, R.P.; ROMANO'JA, A.F.
7-Alkyl derivatives of quercetin and their antioxidizing
effectiveness. Izv. AN SSM. Ser.khim. no.9:1617-1621 S 163.
(MIRA 16:9)
1. Institut khimicheskoy fiziki AN SSSR i Vsesoyuznyy nauchno-
issledovatellskiy vitaminnyy institut.
(QuareetiR) (Antioxidants)

W7 ',"aa RM

llc-,xj~ctiain rear- i n- i
i- th- Inhihition of the LarA I r ci mu zu
T77~-,-
ICEM
~-WA

ZHIZHINA, G.P.; ZYBIIIA, D.L.; KRUGLYAKUIA, K.Ye.; EMANUEL', N.F.
Kinetic characteristics of the degradation of peroxide compounds
in irradiated DRA solutions. Dokl. All SSSR 158 no.4:935-938 0 164.
(HIRA 17:11)
1. Inbtitut khImIcheakoy fIzikI All SSSR. 2. Chlon-korresFondent
AN SSSR (for Emanuel').

MAMLIP N.M.; KRUGLYAKOWA, Y.Yn.; 1"HIMINA, G.F.; ViCHUTIN5UY, A.A.;
VASILITFVP R.F.
Chemiluminesconca of DNA solutionn rollowine X-ray Irradiation.
Trudy MOV. Otd. blol. 21019-M '65. (MRA IP40

KRUGLYAKOVA, K.Ye.; ULANOV, R.P.j ZYBINA, D.L.; EXANUELI, N.Y.
Kinetic characterlatlc3 of the effect, of chemleal mitagens (et'hyl-
enimine derivativen) on DNA. Dokl. AN SSSR 11S1 no.3:718-720 Mr '65-
(MIRA 18:3)
1. Chlen-korreapondent AN SSSR (for Entnuell).

wit- -c 3 upo f
Id. Dc,1.3 . AN S I 1~,3
hhlm'~;helll-r f.z**K,- All
All SL~R ( f-or !~,irv
L

ZHILITSOVA, V.M.; KRUGLYAKOVA,,.K.Ye.; ULANOV, B.P.; GINIIN, L.G.
Kinetics of DNA denaturation following ultraviolet Irradiation,
Dokl. AN SSSR 164 no.1;198-200 3 165. (MA 180)
1. Voesoyuznyy zaochnyy politekhnicheskiy Institut I. Institut
khimicheskoy fiziki AN SSSR. Submitted March 25, 1965.
i 177 ~! :"~; ~ - --- -

S A PR I I IpA.N.; FJ,()(,IIKO, E.V.; YRUGLYAKUVA, K.Yo.; r:fl! !I.! J
Effnct of tho inhibitors of radiral reactionn on the kinetics of
the change In free radical content In the orl,,nnr of mice in
exForimental leukem.1a. Dokl. All SSSR 166 no.3:71.6-748 Ja '66,
(MIR], 19:1)
1. InstItut khIm,cheskoy fizlki All SSSR. 2. Chl,.n-korrevlondent
All SSSR (for Flumnuell). Submittad kigwst 27, 191'6.

ACC NRi
SOURCE CODEs UR/0216/66/000/0D2/0W183/011 6.
AUTHOR., Faianm2lty N. X.; Burlakova Ye. B.; Kruglyakova K, Te.t Sapezhinski I I
j_ ~ t - 79 0_ a
ORG: In-atitute of Physical Chemistry, AN SSSRp Moscow (Institut khimicheskoy fisiki
,&-e
AN SSSR)
TITIE: Studies on free-radical reactions following irradiation of model system 99
the role of radicals in radiation inj= --Iq
SOURCE: AN SSSR* Izvestiya. Seriya biologicheakaya, no. 2, 19661 183-196
TOPIC TAGSi free radical, irradiation effect, radiation injury, recombination
reaction, protein, free radical stabilization# electron spin resonance, exchange
reaction, D91dative recombination of the radicals of irradiated proteins
tBSTRACT1
s a two-stage procass: peroxide radical formation and disproportionation i
.(during which chomoludnesconce arises). Analysis of electron spin
resonance and o)Wgon absorption by irradiated proteins reveals that the 4
,reaction procoods through a transfer of free valence. The authors concluded -
from the results of the electron spin resonance studies and chmoluminescence
'that an exchange reaction is possible between the radicals of irradiated
proteins and the inhibitors of free-radical reactions.
Free-radical reactions play an important part in rediation-induc ENA
ed FA
04
'degradation. Study of the action of vartow Inhibitors showed that gall a
.acid, pherfloWlamine, and o dim derival h e
i0ye r d1f "Tekeg .60
effect or rragirat a a on animals ~n'vtfca"terdksth it- te5gr 6f
protection is eat y relhted to the antiradical activity of the inhibitors
d fre8graj6cal re tign.A. %ig. art hash %6iWss AM 2 ta~jesf WPHS]
W
~B DA : llDe ~5
),E: Olr-

ACC NRi AP6030025 SOURCE CODE: UR/0020/66/169/005/1203/1205
AUTHOR: Nikolayevat N. V.; Semenova, L. P.; Kruglyakova, K. Ye.
ORG: none
TITLE: Fractionation of irradiated and protected DNA with propylgallate on a
cellulose anionexchange column
SOURCE: AN SSSR. Doklady, v. 169, no. 5, 1966, 1203-1205
TOPIC TAGS: DNA, DNA fraction, column chromatography , radiation damage,, ion exchanSc
chromatography
ABSTRACT., It in known that propylgallate, an Inhibitor of free radical reaction,
protects DNA from radiation damage. DNA extracts from living cells
are heterogeneous in molecular weight and ion exchange chromatography I
with propylgallate has been found an effective means of separating
DNA fractions and distinguishing native and irradiated.DNAs. T~e ion
exchange chromatography system is described and some experimental re-
sults presented. IWA-50; CBE No. 11J..
SUB CODE: 06/ SUM DATE: 29May65/ ORIG RM 003/ OTH REF: Oll/
Card
7.1047.9
-4,

AUTHOIiL3 Z C-7- 77 - ~7 -5 -712--,
Broydo, I.I. ; Kruglyakova, L . V

~he Relation of the Regolutio-E-7f S,Pll Details in the
1.11ultiple Copying to t~o Nature of the Openutive Light Beam
(zn'!iqimoDtI rRzrPshorAya molkikh dettiley 1~ri
Ot khPV9Vt'II'ft
E"I I C D I CA L r rin 1 rinu chnoy 4 1~ r I k la dnny f o t oCrif t r 4 4,
195FI, Vol 3
lir PP 'J59-361' (USSR)
,
ABSTRA"T: The object of the study to determine how the
tion of small details at various stages of the du,,;Iicati,ir,
procegs was effected by replacirie, the -.-jhite li,73ht sour-p by
ultra-violet ard usine a parallel CCry4n;- b-am in~-~tf,,H (if --I
diffuzed one. For the experiment, A, louln.1,1-
nc~C;a~ive A and positive IMZ photo,~,rapi-.1c mate-rials used.
The resolution of the various raterialo b~r th~
n. I them
contact method, p oiectin6 a special line pattein to
'ind latt?r measurin& the dluit-oe of wai;
carrIP-3 out in both white and ulti,a-vjolat 11glit. .;'ho
.rig pruceE33 went thrrugh five .tageo, yieldint; 2 -rtermediate
t,.,io dupli,,ateo and oric final 1:oo,tivc. The re U -
t i on of the pat tern I iries -wa!3 de t n h case
C, L d 2 -Nan f ound that tie re3olv. t ion (,;f I d eta` I f-al'.:~

S07-77-3-5-7/21
The Relation of the Resolution of Small Details in the Multip'le Copying
the Nature of the Operative Light Beam
during copying, particularly in the first stages. The
resolution can be considerably im~rcved by ultra-violet
light instead of white and a parallel coT~ying beam instead
of a diffuse form. Further experiments showed that alter-
ing the development conditions had little effect on resolu-
tion and that the use of an ultra-violet parallel copying
beam is a more effective means of improving the resolution
of small details in multiple-oopyinE than the use of special
films with a high resolving power. There are 3 tables, I
graph and 2 Soviet references.
ASSOCIATIONs Loningradnkiy institut kinoinzhonerov (Lenin6rad Institute
of NDtion Pictdre Engineers)
SUBMITTEDi January 12, 1957
1. Photographic films--Processing 2. Photographic film-Test
results
Card ~/2
.4

OSHZYSKIY. LA.; DANCHICH, V.Y.; AVDIYEIIKO, T.G.; ARKHlXGXL'SKlY, A.Y.;
OAK, A.M.; MIYANTSZV, Yu.P.; ZILIBSKIY. V.9.; IVAROV, P.'S.; ITASHCHWO,
P.R.; XALININA, M.D.; KRAVCHZNKO, A.G.; KOTLYAROVA, A.V.-, KRUGLYAKOVAL-
M.D.; LEVIKOV. 1.I.; LIBKIND, R.I.; NIKOLAYEVA, N.A.; NAUKWO, T.Y.;
-TRINOW, I.B.; PRISTAZHNIKOV. V.8.; PUBEDINSKAYA, L.P.; PCKALYUKOV,
S.N.; POPOV, A.A.; SCLOKWSZV, M.N.; TARASOV, I.V.; PILOHMMO. A.3.;
SHISHOV, Te.Le; SEMIMAN, L.I.; TAXUSHIN, M.P.; ZVORYKINA. L.K.. red.
lzd-va; LOKILINA, L.N., takhn.red.
(Horisohtal mining In foreign countries] Provedenie gorizontallnykh
vyrabotok za rubashom. Moskva, Ugletakhtsdat, 1958. 342 p. (91RA 12:4)
1. Xharkov. Yeasoyusnyy nauchno-iseledovatelltikiy Institut organizateii
I makhanizateli ahakhtnogo strottelletva.
(Mining engineering)
f

DUMNIN, N.N., iwnd.tokhn.nauk; DOROSKMO, G.N., kand.takhn.nouk;
-KOTLTAROVA, A.V.. lnzh.; IRMIAKOVA, 14*De, inzh.; TCLOYICH,
CHMOVSKATA, T.P., red.izd-va; SMYAR, S.Ta.. tekhn.red.
(Shaft sinking in the U.S.S.R. and in foreign countries] Opyt
prokhodki stvolov shakht v SSSR i za rubashom. Xoskya, Goo.
nauchno-tokhn.isd-vo lit-ry po, gornomu dalu. 1960. 257 p.
(KIRA '13:11)
1. Kharkov, Ukrainskiy nauchno-iseledovatell6kiy institut
organizatsii i mokhanizateil shakhtnogo stroitalletva.
(Shaft sinking)

RZZNIK, I.D.; YOURNSENSKIT, P.I.; KRUGLYAKOYA, M.S.
Moisture of flue gases du ation of oxidized nickel
ores, TSTots mote 31 no. 7151-55 JI '58- (MLRA 1118)
1. Gintey6teat* (litakel-Motallurgy)

I.D., KRUGLYAKOVA, M.S.
Sulfatization of oxides of cob-Ilt, nickel, copper and lead in
Tilicate melts. Sbor. nauch. trud. GINT3V--A'IBT no.15:138-163
59. NPA 14:4)
(Nonferroua metals-,Motallurgi)

REZNIK, I.D.; KIUJGLYAK(IVA, M.S.
Laboratory investigation of the behavior of Vpsum in the presence
of slag as applicable to shaft furnace sm6lting of oxidized niokel
ores. TSvet.*met. 33 no.6183-84 Jo% IAO. (M:[Rk 14:4)
(Nickel-Metallurgy)

REZNIKY I.D..; FUGLYAKOVA, H.S.
Mechanism of sulfuration in the shaft smelting of oxidized
nickel ores with calcium sulfate. Zhur. prikl. khim. 33
no.n.-2449-2458 N 160. (MIRA .14:4)
(Sulfuration) (Nickel--Metallurg7)

RKZNIK; I.D.1 KRUGLYAKOVA. M*S.
laboratory investigation of gypsum behavior in the presence
of slag as used in the shaft Awmoo smelting of oxidized
nickel ores. Sbor. much. trud. Gintsvetmeta no.18:275-
299 161 X'MIRA 16:7)
(Nichel-449ta-11urgy) (Gyps=)

REMIX, I.D.; KRUGLYAKOVA, M.S.
Sulfuration of iron ailicatee and magnetite by aulAw vapor
arid sulfur dioxide, Sbor* nbucho trude Gintsvetmeta. no*18:
300-306 161. (KM 16:7)
(Sulturation)
(Nickel industry-By--products)

S/136/62/000/006/004/005
E071/E435
AUTHORS: Roznik, I.D., Kruglyakova, M.S.
TITLE: On the cause of irregularity in the composition of
matte on shaft smeltinj of oxidized nickel ores with
gypsum
PERIODICAL: Tsvetnyye metally, no.6, 1962, 80-83
TEXT: It was found difficult to control the composition of matte
on smelting oxidized nickel ores with gypsum in shart furnaces.
According to previous investigations the presence or molten slag
loads to a rapid docomposition of gypsum even in a reducing
atmosphere, while without slag, gypsum is fully 'transformed into
calcium sulphide. In the present work the velocity of the
interaction of calcium sulphate with metallic iron in the presence
of slag (25,1% Fe, 31.%4' S1021 16.6% CaO, 0.1% MgO, 0.2% A1203
and < 0.150' S) in the temperature range 900 to 10009C was
investigated. The procedure consisted of heating amixture of
finely ground components in corundum crucibles in a stream of
nitrogen; the S02 evolved was absorbed and the residue in the
Card 1/2

S/136/62/000/006/004/005
On the cause of irregularity E071/E435
crucible analysed for sulphide and sulphate sulphur. In the
absence of slag, sulphate sulphur rapidly reduced to sulphide;
the prosenco of slag slowed down the reaction but the removal of
sulphur with gas was insignificant. The proportion of metallic
iron present in the mixture had a decisive influence on the transfw
of sulphur into the sulphide form. In the presence of slag and
an insufficient proportion of iron, UP to 47% of sulphur is
removed as the 9A5 S02. If there was an excess of iron (in
respect of equation: CaS04 + 4Fe = CaS + 4FeO) All sulphur
transformed into sulphide. The following mechanism of
sulphidization is postulated: gypsum mainly decomposes with the
evolution Of S02 which, together with elementary sulphur, is
absorbed by iron, reduced to metallic and ferrous forms. On the
basis of this mechanism a number of features of shaft smelting of
oxidized nickel ores with gypsum are explained. There are
2 figures.
Card 2/2

REZNIK, I.D.; KRUGLYAKOVA, H.S.
Interaction of gypsum with metallic iron in the presence of slag
as applied to shaft furnace smelting of oxidized nickel ores.
Zhur.prikl.khim. 35 no.6tl237-1242 Je 162. (KIRA l5s7)
(Nickel ores) (Gypsum) (Iron)

REZNIKp I.D.; KOVALEV, D.Ya.,; XUDRIN, AA.; TIJMASGV, V.F.; GRITSKOVA, V.T.;
KRUGLYAKOVA, M.S.
Depletion of waste slags from shaft furnace smelting of oxidized
nickel ores In electric crucibles. TSvet. mot. 36 no.9t22-28
S 163. (MIRA 16tlO)

ALIMOV, Aleksey Petrovichj GCL 11, INSKrY. Leonid Voynovich;
KIIUGLYAKOVA,, Mariye DAitriyovnal SKOROBOGATYY, G.I.p
r~tseinienAj YATMIKU.- V.D'.-,-'rbtsenzent; GRABILIN, Yu.N.,
Otv. red.
(Mechanization of auxiliary proceoses in the building of
coal mines] Makhanizatsila vopor:ogatellrykh protsessov v
shakhtnom stroitallstvb. Moskva, Nedra, 1965. 178 v.
(VIIRA l8t9)

HFZN1K, I.D., kand. tekhn. nauk; LYUMKIS, 1.',.Ye.j KOVALYS, D.Yn.; TUMASOV,
VJ.- KPUGLYAKOVA,.~.S.; CRII-)KOVA, V.T.
F -- . ...--
Perlodle process of depletJnF waste slags from the shaft-
furnace smelting of oxidized n1ckel ores with the help of
an electric hearth. Sbor. nauch. trud. GIntsvetmeta
no.23tl5l-163 165. (MIRA 18M)

J (j ~ 1,4 ~'o -A
15-57-7-9454
Translation from: Rererativnyy zhurnal, Geologiya, 1967, Nr 7,
p 105 (USSR)
1UTHORS: Fridman, N. G.
TITLE: The Use of Phase fins fnalysis for Studying the Processes
of Dehydration of Hydrated Minerals (Primenonlye fazo-
vogo gazovolyumeti-icheakogo analiza dlya izuehenlys
protsessov obezvozhivaniya gidratirovannykh mineralov)
PERIODICAL: Tr, Kazanqk. fil. AN SSSR, sor. kh1m. n., 1956, Nr 3,
pp 83-87.
t-BS TR tC T: The authors have studied the dehydration of minerals
(gypsum,th5drous borates, hydroboracite, carnallite, and
polyhal e in order to explain the kinetics of the
dehydration process. They used the nonautomatic
burette of Berg, 1.5 m long with a volume of 7 mm to
8 mm. Calcium hydride served as the reagent. The
investigations were made at various temperatures. The
maximum temperatures of dehydration, obtained from the
Card 1/2 thermal curves of Kurnakov, were taken as a basis.

15-57-7 -9454
The Use or Phase Gas Analysla for Studying (Cont.)
Subsequent; determinations were carried on at lower temperatures.
After 2.5 to 5 minutes, depending on the rate of dehydration, a
detectable quantity of water was given off, equivalent to the
volume of H obtained in the gas burette. The method permits
.rapid and accurate acquisition of dnts on the dehydration of
minerals in small samples.
Card 2,/2 Ye. S. Kabanova

ACC ARi -AT7001042 SOURCE CODG-i UR/2733/63/000/004/OJij/0138
ALTHOR: Kruglyakova, V, 1,
' =I IN Mal
O,1G: nono %,#
"HotAtIon Sholl with Small Central Opening Under the Influonoo of Symmetrical
and Inversely Symmotrical load"
14ningrad, Isslodovaniya po, Uprugostl i Plastichnouti, Ho 4, 65, pp 123-158.
Abstracti A pronentation of a unified method for do.tormina.tion- of. e,tressax near
the small tontral oponing in rotap4on Gholla under the influence of symmotrical
and invorsoly,symmRtrical loadstl"Tho solution is in a form, convenient for
practical use. In contiii'Ct~~- most proyioua works on the subject, the method
suggostod has a simplification which involvon m1mmotrical doformation only in
:the coafficients of -the equation. In the atross and disp)Lacemont oxproaBlons,
the trigonometric factora are retainede 'Origo art* has: 13 figuros, 10 forniliwp
and 1 table ;* rJPRS , 35,9!ff ' - *
TOPIC TAGSt shell structure dynamics# shell deformation
SUB CODEs 20 SUBM DAM s 3J+Apr64 ORIG REFs 014 / OT11 RFM 021
-77

GOLOVAIT, A.T., doktor tekhn.nauk, prof. (Hos".a); XRUGLYANSKIY,
inzh. (Hookva)
Circuits for the excitation of asynchronous variable-frequency
generators. Xlektrichostvo no.5:31-36 Yy 160.
(HIRA 13:9)
Meotric generators)

SOURCE CODE t
AUTHOR: Dobrow love I. L; Tverdin, L. Me; KruglYanskiyo L He
ORG: none
TITLE: Scientific and technical seminar on seinioonductor power converters and
their application in modern automated industry
SOURCE: Elektrichestvo, no- % 19652 91-93
TOPIC TAGS:* e1 ectric engineering conference, electric power engineering, industrial
automation, semiconductor device, automation equipment, rotary electric power
converter
A13SMACT: IM-e article 'riep"orits on the proceedinza at the seminar hold on 1-3
.October 1964 at the Ma"Kh SSSR (Exposition of the Achievement of the 11ational.
Fconony USSR). Wonty-five reports were made by representatives of over ten
,scientific and industrial organizations in the electric power field. The
remarks dealt with the proere3s and status of semiconductor techniques
in power system applications and the prospects for the future. 7he next sub-
ject was the errect, of physical phenomena accomparqin-, various semiconductor
r.anufacturo tochniquos on the parameters of the circuit componenta (rectiftor*)e
7hero followed sevoral papers on power oonversiont ffto one frequency to anothert
,from single-phase to three-phase or to D.C., motor-Sonorator Sy3taM3, and rec-
tifiors. A few papers wore devoted to the application of thyristor3 to electric
to electric drive systems for speed control of D.C. and A.C. asynchronous (in-
d.uction) motors. Statio converters and inverters were considered next and some
~i

ACC NRs AP6004793r
papers wore presented on varioU3 industrial applications of power conversion
systens, e.,,. in tlo chemical and motanurgical industry, in machine tool
operation; and also on the application of pulse-time and pulse-width control
zet-hods. . Aile the seminar vias bein,, conducted, the participants had an
op2or'VwAty to see a special exhibition prepared by the VDM. A resolution
recoi--nending further development In Vie-fiold. of semiconduotora for power
drives was adopted at the conclusion of the seminar. Zj_PR_S7
SUB CODE: 09j, 13 SUEM DATE: none
Q~
Ciud 2/2
61

I '); i . -!",
1, ~ '-.- "," 1 4Y.'. I . . , . .". " 1- , - , ; .. '.
.,i1 -
"nsr-ritifle ond .- .7-', 11, ". .,:'
find Oe!r une irl i ;-Ci:. - fl
. I - I ~ . . - c ~.~ r
Elnk':-10.,~.~tvo ", -0
(MIEA 18:6)

KRUGLYANSKIY, M.R.;, CHUPRUNOV, D.I., red.; PAIIISHINA, L.N., red.izd-va;
_9-1)._~iekhno red*
f:r
(Handbook
admission to specialized schools of the U.S.S.R.]
Spravochnik dlia postupaiushchikh v srednie spetsial'nye
uohebaye savedeniia SSSR (tokhnikuny, uohiliehcha, shkoly) v
1959 g. Moskva. Goe.izd-vo OSovetskain nauka," 195 370 P.
&IRA 12:8)
1. Russia (1923- U.S.S.R.) Hinisteretvo v sehago obrazovaniya.
(Technical edi

KRUGLTAIISKIT, H.R.1 KISEM, M-M-9 red.; aRIGCHCHUN, L.I., takhn.red.
[Handbook for students entering special secondary schools of
the U.S.S.R. (technical schools) in 19601 Bpravochnik Me
postunniushchikh v erednis spot ialInva uchabnya savedentin
SM t-takhnikumy, uchillshchat :hkoly) v 1960 g. Hoskva, Oov,
Isd-vo "Tymohnia shkoln,O 1960. 358 p. (HIRA 1315)
1. Russia (1923- U.S.S.R.) Ministeretvo vyeshego i arednego
spetsiallnogo obrasovanita,
(Technical education)
;Al

LRVQLWjXM Mikhail.Ssmavlovich; BESSONOV, L.A., doktor tekhn. neuk,
prof., retsenzontl STRAM, A.G.tzed.
[Hapdbook of electrical onginearigglglektrotekhrAcheakii spra-
voohnik. Belgorod, Belgorodakos Imisfinoe iad-yo, 1962.' 4741 p.
(KIRA 16:2)
(Electric enginesring~Hsndbooksj manuals, etc.)

KRUGLYASHOVP V.H.
Experimental v ork of rural- school students. Blol.v shkole
no.64&42 " 162. (KMA 16%2)
1. Tambovskiy podagogichaskiy inatitut*
(Tasibov Provinoe--Agriculture--Sxperipentation)

UGRYLVOV, V.M. - KRUGLYI N.M.; VDIARSWA, Ye.N.; KCCHKOV, A.A.,
red.
(Therapeutic gy=Astics in injuries to the spine and spinal
cord) Lechabnaia giranastika pri povrezhdeniiaLkh pozvonocb-
nika i spinnogo mozga. Moskva; Medtisinap 1964, 182 p.
(MIRA 17:5)

SOV/126-7-6-10/24
.AUTHORS: Amonenko, V. M., Kru o-A-wArr-and Tikhinskiy, G.F.
t!E11YAU
TITLE: vacuum Distillation of Chromium
PERIODICAL: Fizika metnilov J metallovetialliye, 1959, Nr 6,
pp 8611-8711 (USSR)
ABSTRACT: Impurities in chromium make it brittle and difficult
to deform at high temperatures and decrease its
usefulness an a heat-resisting alloy base. Much work
(Refs 1-10) has been done on its purificati n. This
included vacuum distillation* (Ref 1) at 10-9 mm Hg and
14000C with condensation on a surface at unspecified
temperature, which, as shown in Table 1, failed to effect
any improvement. The authors describe their own work at
a laboratory of the FTI of the Ac.Sc., UkrSSR on
chromium distillation in a high vacuum onto a heated
surface. The method has been rei)orted (Ref 11). The
temperatures of distillation and condensation can,
assuming the applicability of RAo%L1t1s law, 'be calculated
for the particular purification required. Fig 1 shows a
general view of the installation, provided with a high-
vacuum and backing pumps. Evaporation was effected from
Card 1/3 alumina or beryllium-oxide cruclioles heated by tungsten

Vacuum Distillation of Chromium 30V/126-7-6-10/24
or molybdenum wire spirals, and condensation in a ceramic
column internally coated with tantalum sheet (Fig 2).
Temperatures were measured with a type OPPIR-09 optical
pyrometer and all experiments were at 10`1 mm fig. Chromium
samples produced by the alumino-thermic and the
electrolytic methods were distilled: the initial and final
compositions are shown in Tables 2 alld 3 respectively.
Distillation was effected at 1250-15000C, the condensing-
column temperature being 950-12000C. The chromium was
deposited (Fig 3) in the lower and middle zones. No
purification from iron or aluminium resulted for the
alumino-thermic material and these elements, together with
carbon and silicon, were also the most difficult to
eliminate from electrolytic chromium. It was found$
however, that by passing the chrunitim vapour through a
filter of chromium-oxide 1)owder, the aluminium present in
the chromium is oxidized and its content in the refined
metal falls to 0.001-0-003 but that of oxygen rises to
0.03%. By passing the vapour through zirconium turnings,
Card 2/3 the silicon content could be reduced to 0.001%.

.Vacuum Distillation of Chromium
SOV/126-7-6-.10/24
Simultaneous purification to 0-003, 0.001 and 0-005% Al,
Si and C, respectively, was obtained by fusion in air of
either form of chromium with 5% tungsten before
distillation The micro-hardness of chromium distilled
at 10- 1 to 1;_7 mm, HS was determined with a type PHT-3
machine, the resulte (Table 4) showing that the softest
material is that distilled at the lowest pressure.
Freshly-distilled chromium had considerable plasticity,
but on storage in air this decreased due to the absorption
of nitrogen, oxygen and hydrogen (Table 5).
There are 4 figures, 5 tables and 13 references, 2 of
which are Soviet, 10 English and 1 German.
ASSOCIATION: Fiziko-tekhnicheskiy institut AN UkrSSR (Physico-
technical Institute, Ac.Sc., Ukrainian SSR)
SUBMITTED: February 25, 1958
Card 3/3

9 0 9 1E 1 1) 1
AUTHORS: Krugly'~d,, A.A a lov V.'S Lt ri (I Ti: is!,: j.GF
TITLE: Recrys tall i z-a ticm T"of BexZL1~:iy-,
PERIODICAL: metallo% i '1,:l ~)j hr 1.
pp 148-1~-l ('U'3SR)
ABSTRACT: Higb-pur-111-y N37yllium high *'r-svmm'
wa5 u~!ed in this work to
This boryMimi containad tho
io--3,,-,~ qu; jo-3;,6* Fe; lo-3,-.' All; M!1; 10"11, NI;
2 x 10 C a 31. 03, jc.* N'51
The speciraerl~; werti mado in ~hi,~ form of r.-,.utos, 0.8 r-M
by condensation of boryllinm vapnue-1, in h-19h
va-cuuin (approximately 10-6 mm Hgr~ on a ba-c~-.Ing
at" a temperature of 250 OG. i n c) -,C1 e :n to c r. s i) an i f o-.:-iri
structure, the plattis were subj~~ctad f.~) de-frxiaat-lon by
301,-v' alonc, the width by iop,~zited -ollLin- -at room, temperature
in air (the reduc.-tion in area in ea~-11 r:)Iling v-as
approximatoly 0.3,1,',), follo,,:,id b7 ann3aifr.6 at 700 OC fr,-.
Card 15 hours. In order to sLu(J,, the
1/2 speoimens w,)re again def,)r~med by 25;'j the --,,idth by
rolling under the same con,-Utioiis in two diructicnz- at

Recrys tall iza tion of Beryllium
right-anglos to each of tlle
specimens after these I.-: in Figs
and Fig 2,a. Fig shf-)ws t!,,c-~ Jopend-Ince ',`io duratior
of the recrys tall i zat, ion proceos -,r, tao f3mperaturo of,
,jfU-jT- ijj~) fjp~aj &,'
isot'llermal arAlwaling , -114
F.Ig 4 -,)i(,)ws tl,e del) orden,.-c oji, t1l') a-Ver;iji;c. gra.111 liazmpta-
oil the time of lsothe-,-mal annoilinic In
coordin; too . Or., tho basis of t`o
ractivation oriox~gy of li-.Atioyl -~f 11.13"If
doformo~l by"' alon- tts wid 1, e~t,.~ tc, 11)(~
In
21 Xcq!/ at,~m. Tj--o
, vrowtn in finely
C
arO
2/2 tcm.
Thc,re aro ~' f".11gui-es -n,, of w`-,;
Soviet and 2 Engliz!i,
ASSOCIATICN: 10)ar-liovskly i ko -e I..,Ii!"Lc:v USSR
U;,,.r . .1;
SU BM I TT ED: 1-5, 1959

85043
IZIS' 210901~ S/126/6o/olO/004/012/023
,2 6,,~-W ~ 0 E021/E4o6
AUTHORS: Ivanov, V.Ye., Amonenko, V.M., Tikhinskiy, GeFe and
KruglyRh,-X-.A.
% - .
TITLE: Refining Beryllium by Vacuum Distillation
PERIODICAL: Fizika metallov i metallovedeniye. 1960, Vol.10, No.4,
PP-581-585
TEXT: Previous work (Refs.11 to 14) had shown the possibility of
purifying beryllium from certain elements despite similar
volatilities of these elements and beryllium. The present work
was carried out using a diffusion pump giving residual pressures of
10-5 to 10-6 mm Hg. A beryllium oxide crucible was used for
evaporating the beryllium, heated by molybdenum spirals. The
condensing column, placed over the crucible, is shown in Fig.l.
Condensation took place on the molybdenum plate on the inside of
the column. The condensation surface was heated to 900 to 1100 C
(measured by a pyrometer and by thermocouples) and the optimum
temperature was determined. Fig.2 shown the ratio of the impurity
content in the original material (q2) to the impurity in the
condensate (ql) plotted against the temperature of evaporation
(I - iron, 2 nickel, 3 copper, 4 Rillcon). Fis-3 allows
Card 1/3

85043
S/126/6o/olO/004/012/023
Eon/Oo6
Refining Beryllium by Vacuum Distillation
the change in manganese content with increasing column temperature.
A similar change occurs with aluminium. Fig.4 shows that 85 to
90% of the original material can be distilled before the impurity
concentrations increase to any extent. Fig-5 shows a column with
baffles which has been used very successfully. The table gives
the chemical composition of the initial beryllium (second column)
and the beryllium after distillation (third column using a simple
condensing column, and the fourth column using baffles). The
purest beryllium is obtained in the middle zone and is 99.99% apart
from oxygen (0.6%) and carbon (0.02%). The carbon originates from
oil vapours from the diffusion pump, and the oxygen from sublimation
of the crucible material (BeO) and reactions between beryllium and
the crucible material to form Be20- The microhardriess of the
distilled beryllium (99.98%) decreased to 130 kg/mm2 for monocrystals
and the hardness of the cast metal was 100 Hb - a decrease by a
factor of 1.5 to 2. The low plasticity of the beryllium is
explained by the considerable quantities of carbon and oxygen still
present. There are 5 figures, 1 table and 16 references%
8 Soviet and 8 English.
Card 2/3

85043
5/126/6o/010/004/012/023
E021/E4o6
Refining Beryllium by Vacuum Distillation
ASSOCIATION: Fiziko-tekhnicheskiy institut AN USSR
(Physics and Engineering Institute, AS UkrSSR)
SUBMITTED: April 12, 196o
Card 3/3

S/032/60/026/05/47/063
00 B010/B0O8
AUTHORS% Amonenko, V. M., Kru#j-lykh, A. A., PaYlov,_V, S.,
Tikhinskiy, G. ?i
TITLEt Manufacture of a BLrz.-.-lium Foiiy~
PERIODICALs Zavodskaya laboratori3:a, 1960, Vol, 26, No. 5, pp. 625-620
TEXTi Beryllium foils of a thickne;is of 20-300 AA are used for the
manufacture of X-ray counter tube wIndows. With the existing methoda
for the manufacture of such foils there is the difficulty of obtaining
foils which are sufficiently plastin at room temperature. A method
according to which 'beryllium is depisited by vaporization on a polished
molybdenum lamella in vacuum (appro:-. 10-6 mm Hg) is described. The
beryllium is deposited by vaporizat:,on on the preheated molybdenum
lamella from a BeO-.cruoible at 1300--15500C in vacuum and then treated
thermally (in vacuum). The dependenie of the plasticity of the finished
beryllium foil on its thickness (Fil,. 1), on the temperature of
condensation (Fig. 2) and the lengti- of the thermal aftertreatment
(Fig. 3) was investigated. Vacuum tight and nlastic foils are obtained
Card 1/2

Manufacture of a Beryllium ?oil S1032
,/60/026/05/47/06.3
BO1O/BOO8
if the molybdenum underlayer has 50-1000C at the beginning of the
deposition by vaporization, and the temperature is thereafter quickly
increased. It was determined that the grain of the foil gets coarser
with the increase of the temperature and prolongation of the duration
of the beryllium condensation. A corresponding duration is to be applied
for each temperature of the thermal aftertreatmant. It is recommended
to aftertreat thermally for 6 and 3 hours at 700 and 6000C. Foils of a
thickness of 40-70,oA. are vacuum tight, if the underlayer was not heated
above 3000C~ There are 3 figures and 2 references, 1 of which is Soviet.
Card 2/2