SCIENTIFIC ABSTRACT KRISHTAL, L.I. - KRISHTAL, M.A.

Document Type: 
Document Number (FOIA) /ESDN (CREST): 
CIA-RDP86-00513R000826510015-3
Release Decision: 
RIF
Original Classification: 
S
Document Page Count: 
100
Document Creation Date: 
November 2, 2016
Sequence Number: 
15
Case Number: 
Publication Date: 
December 31, 1967
Content Type: 
SCIENTIFIC ABSTRACT
File: 
AttachmentSize
PDF icon CIA-RDP86-00513R000826510015-3.pdf3.98 MB
Body: 
TRUBIKMV, H.C., kmd. ekenom. nauk; FlSY'-,HM.Vl, kand. ekoncm. nauk; KREYNZ, A.V.7 kand. 6k'7'T;')m. nwak., 1.91*1 red* (itincilPco f,~r the emtAj.'a'ne7,.t of r:illrcad rreight rates In n.-.,clalLit irbi,?igament). ?i-Intsipy postroentiA zheleznodo,-Pozbnykh gruzco,v-ykh tarlfu7 -T rol.l~nlisti:,bel;kcm. khrzististve. Moskva, Transport, 46 p. ixnyl naucbno-iseledoystell- skil Institul. zbeleznod.-.rnzt:rrE- trinsporta, Trudy, no.278), (MIRA 17r) VINOGRADOV, A.N.; LIVSHIN, G.L.; OLHAZTSOVA, R.I.; TULUPOV, L.P.; Prinimali uchastiye: RAZORENUVA, L.K... inzh.; J)-UBINKINA, L.I., inzh.; PODGORNYKH, A.L., inzh.; IAVRENTIYEV, N.V,s retsenzentj MINAKOV, A.D., retsenzent; NESTEROV, Ye.P., retsenzentj STEFANOV, N.Ya.j reteenzent; USHAKCFV, P.S.j retsenzent; L.I., red.; KHITROVA, N.A., tekhn. red. (Calculating machines in accountings planning and administra- tion in railroad transportation) Vychisliteltnaia takhnika v uchate, planirovanii i upravlenii na zheleznodorozhnom, trans- porte. (By] A.N.Vinogradov i dr. Moskva, Tranazheldorizdats 1963. 407 P. (MIRA 17:2) BERLYA14D, A.U., otv. za vyprusk; KRISHTALIj LI.j, red.; VOROTNIKOVAO L.F.p tekhn. rW-. [Collection of materials on traffic safety; excerpts from orders and instructions issued by the Ministry of Railroad Transportation on traffic safety] Sbornik materialov po bei,opasnosti dvizheniia; vyderzhki iz prikazov i ukazanii Ministeretva putei soobshchenlia po bazopaanosti dvizheniia. Izd.2. Moskva, Trang2heldorizdat, 1963. 206 p. (MIRA 17:2) 1. Russia (1923- U,S,S.R,) Upravleniye glavnogo revizora po bezopasnosti. dvizhenlya. 2, Starshiy pomoshchnik glavnogo re- vizora po bezopasnosti dvizheniya Ministerstva putey soobshche- niya SSSR (for Berlyand). FErROV, Vaevolod Ivanovichp kand. tekhn. nauk; alSHTALI, L.I.p red. - I --, [Transportation and economic ties of 'the U.S.S.R.J Transportno- ekonomicho8kie Bviazi V>SRI abornik atatel. Moskvaq TranBportg 1965. 170 p. 18:4) 1. Moscow. Institut kompleksrqkh transportrVkh problem. ZAKHAMKO, Nikolay Nikolayevicbj 1111411, Ley Mendeleyevichl KRISJUAL' , L.I.,, red. [Ways to increase labor productivity in rallroad transportation] Puti povyshenila proizvoditellnosti truda-Y khozielotye dvizhenlia. Mookvaj Transport# .1964. 151 Pe (MIRA 17:12) L -__ 1:CjN'01,'AIa',V, Sorgey Alekvan,tr~jvichj j4dSH-T~iL.' V I.. t. y -(;d. (Long-term planning of suburban passorwer trantport&- tionj in the eactiun and on the railroad an a whole) Ferspakti,moo planirovanle prigorodnykh perevozok pas- sazbirov; na. otdelenii i zheleznoi doroga. MomWit, Transport, 1964. 34 p, (Miftill IIli) VLADIMIROV, V.A.1 KRISHTALI, L.I., red. [Original statistical accounting on rallroada) Per- vichzWi statiaticheskil, uchet na zheleznykh dorogakh. Moskvap Izd-vo *Transport," 1964. 57 p. (MIRA 170) I'1Z'Cj"AkEV, Scrgny Aleki3aMrovich; MISHTALI, L.1., red. (Loi4l-turm planning of suWiL,,;n puisonger transportation; on railroad lines and sectious) PerspektivnoO Flnnirova- niu 1)rifrorodnykh perevazok passazhirov; rui otdolanii i zho- leznoi doroge. 14oskva, "Transport," 1964. 34 1). (MBU 17:F) 01:AiTALf, L.1s, rod. [Establishing -the norms for industrJal supylion of materialB and Bpare parts in locomotive and car deFots; methodological manual) Normirovanie proizvodstvennykh zapasov materialov i zapasnykii chastei v lokamotiviWkh i vagor-Mkli depo; metedi- cheskoe posobie. Moakvaj Trawnport, 1964. 29 p. WIFU 17:8) 1. Moscow. Vsesoyuzrrjy nauchno-issledovatellsidy institut zhe- leznodorozImogo -transporta. FETROKANSKIY, B.I.; ZVEREV, N.P., retsenzent; MIZIN, V.I., retsenzentj PEIROV, A.I., retsenzentj Mj=--AL1, L.I., red, (statistical accounting and the work analysis of a railroad branch] Statisticheskii. uchet i analiz raboty otdeleniia do- , rogi. Moskvap Izd-vo "Transport," 1964. 218 p. (MIRA 17:5) IVLnVo, I.V.; PETRUKMIOVSKIY, I.V.',*retsenzent,-j KRIMNUS, G.Kh. Iretsenzent'; NAUMOVI G.I.'reteenzent ORLOVI V.N. .retconzent 1 TUCHKEVICH, T.M. retaetzent USHAKOVpP.S. ,reteenzent ; CHERNUKHAj N.T. retsenzent EDELISHTEYN. P.G. retsenzent,;,PISHTALO, L.I.p red.; VINNICHENKQ,,_N.G., kand. ekon. naukp red.; USMKO, L.A., tekhn.red. (Finance and the financing of railroad transportation]Fi- nansy i finansirovanie zheleznodorozhnogo transporta. Mo- skvas Transzheldorizdntj 1963. 439 p. (HIRA 17s2) PETROKANSKIYO B.I.j ZVEREVp N.P.j, retsenzenti MUM, V.1.0 A reteenzentj PETROV, A.Lp retsenzentj KRISHTAL'I.LsIsp.., red.; MURAVIYEVA, N.D.p takhn.red. ~_ _-_' 'dr (Statistical accounting and the vork analysis of a rail- road division) Statisticheskii uchet i analiz raboty ot- delenlia dorogi. Moskva, Izd-vo "Transport w 1964. 218 p. WRA 17:3) - -- - - - TAOROT - - L-8 - -~-- INSHMO - L. 1. - DKITRIYET. V.A. I a 60 --- --momoom [Pri4olples of railroad statistical Olno sholesnodoroahnoi statiatiki, [Rodakiory Kriebtall. L.I.. Dwitriev, V.2 Koskva# goo, trausp, shol-dors lvd-vo, 1953. 194 p, (KLU ?tl) (pailroado-Statieties) LUGOVOY, P.A., inzh.; TSYPIN, L.G., inzh.; GIBSHW, A.Ye., prof., doktor tekhn. naukv retsenzent; USHAKOV, S.S., doktor tekhn. naukp retsenzent; KA15HTALI,_~J., red.; VOROTNIKOVA, L.F., tekhn. red. (Technical and economic calculations in the reorganiza- tion of railroads) Tekhniko-ekonomicheskie reschety pri re onstruktaii zhelesnykh dorog. Moskva, Trans sheldorisdatt 1963. 246 P. (Nin 16:4) (Railroad engineering) KAPLANI A.B.; NESTEROV, Ye.P., retsenzent; KRISHTALI, L.I., red.; DRDZDOVA, N.D., takhn. red. " - , 1.1-- -, (Cybernetics in railroad transportation) Kibernetika na zheleznodoroshnom transporte. Moakva, Tranazheldor- izdat, 1963. 66 p. (MIRA 16:11) (Railroads--Electmnic equipment) (Railroads-44anagement) TISHCHENKO, And~ey Ignatlyevioh; SAMOKHVALOVp V.A., retnenzenti KRISHTALI, L.I., red,; VDBDTNIKOVA, L.P., tekhn. red. [Technological rodrpnization of traction] Tekhnicheskaia rekonatruktaiia tiagi. Moskva, Tranesheldorizdat, 1963. 131 P. (Locomotives) (Railroads-Menagment) (MIRA 16:7) ISTOMIN, L.I.; SHUBNIKOVp A.K.; POPOVI V.M.; MOLYARCHUX, V.S., reteenzent; PAISHIKOV, V.A., retsenzonti KRISHTALI, L.I.,_ red.; KIIITROV, P.A., tekhn. red. (Unear programm~~'-in the planning of Ihe'&el and electric-power supply for railroad transportation] Linei- nos programmirovanie v planirovanii toplivo- i energoanab- zheniia zheleznodoroahnogo transporta. Moskva, Transshel- dorizdat, 1963. 178 p. (MIRA 16:10) (Lineir programming) (Railroads--Management) MIKHKYEV, A.F., doktor tekhn, nauk, prof., red.; Yj-,.!S.HTAL', L:.'., red. [Banic trends in the develorant of transportation tech- nology in foreign countrlosj Oanovnye napravlenila v ra7,- vitii tekhnlki tranaporta za rubezhom. Moskva, Transport, 1965. 335 p. (MI RA 16: 4) 1. Moscow. Institut koml)leksnykh transportnykh problem. ---- - -- --- --l- Ned of lUkft Do the VqWdubm of P. - nil"itl an $k Met. Inst.). Votmat '~~M ft'llal-l= X171,950. 213-7 -A i Murrov Sefshus A15~1 5#71qz , M ~ 4 - KIRSTUL, M. A. USSR/Ifttals - Cost Lron, Proceises NOT 51 "Concerning Graphitization of White Cast iron," M. A. Kirshtal "Litey Proizvod" No 11, YP 31, 32 Presents exptl evidence of'shlfting of iron atoms In process of decarburization of graphitized cast irons. Results obtained permitted study of effect of Sicontent, on rate of decarburizing, process and' detn or activation enbr& of this proc*bss.' * Considets graphitization as process reverse to decarburizatibn of,graphitized cast iron and explains accelerating effect of silicon on gral-bititation-process6. IRISHTAL. N.A. -------- Thew of graphitization of white Iron and steel. Jo 153. (Iron-Metallurg .y) Lit.proisv. no.6:22-24 (VIA1 6:7) (Steel--Metallurgy) US S R ~v termmatioz *f the alor oaM o ':a (m co' clct=LAL liat:nita %nd in Itmts L17&-W~tllml -A ptx~ 11 ,!~tn tA coefft Fc-~ tf~ rhis fzl,tlt~i - be .,.ei q vil, ~,l -lt-o, T'L,: f lhe 110u- -11 J vqM t~v, Ual tucthod at Qjttr -~J~ .1 1 . I : . .": ! : :.. -- " f 1 - a , ,- F g1rhilec"Idtaks, and the C cemlent was ticid a: 4.0~. Thc 6 4 CM(rut was vmtw betwe" I and 5%. 5hecto 1003 mm. thick Were cast continuouxik, CPA wem heid at - In pwr It The digusioe L~*h. a( C was dnd bv 0tv ~rlm- tty wfth which &Q auitenitic ed4e wj" famied The cunrcs thnw that sharp drnln in the diffusim mtc ~e at I uld 4% ca;` Mewurewat (d t1cc. PC,(-cntws 4 tht tflo~% *VdpjeArmoo Ims Uspd (CIC Omt . to a 0.01 ill rwtpn I(.SO.s(u;vkdtw-fmim.. mpfoat I and t% Ca. Itsprcars that Co (cwm* a ItATT at, "ling with kicaltrC4 electmn tgtmdt, SWIM the C diffti4w procru takcs pLacv m aul- (Cr4ce, PmAoW moo a$ the C* k perwAt to this phtee. a" VAlf ocue /T f- M/ Engineering - Technical physics -Coxd 1/1- j-Pub.-22 - 19/49 Authow i Krishtal, H. A. TMA I Fast graphitization of white cast-irons having a higher content of chromium Perlodleal I Dok. AN SSSR 98/4, 583-584, Oct. 1, 1954 Abatnwt A method which helps to speed-up the graphitization of white cast-iron (caat-iron with a high % of chromium) is described. Five references (1945-1953). Graph. Institution Arkhangelsk Foreit Institute Presented byiAcademician G* V. Kurdyumov, April 24, 1954 ULSII/ :,.nFj1r,eerinF. - lechnoloa Card 1/1 Pub. 22 - 26/0 Authors I Krishtal, M.A. Title I The.nature of a process affecting the speed of cAst Iron graphMtALion Periodical I Dok. AN.SSSR 99/6, 983-986, Dec 21, 1954 Abstract I Experiments, intended to determine the nature of a process which reduces the speed of cant iron graphitization, are described. There are two con- cepts with regard to the speed of cast iron graphitization: one is based on the idea of carbon diffusion and of iron self-diffusion. The other is based on the idea of the speed of the removal of iron atoms from the cast iron as the graphite content uvrows. The expariments were conducted to de- termine which process is the more acceptable. Twelve USSR referencei (19.0-195J). Graphs. Institution: 1he Archangels% Forevt,Technical Institute Pregented by: Academician sk.N. 'k,erenin, Aupst 6, 1954 KRISHTAL, 1-1. A. Krishtal, H. A. -- Me Effect of Alloying Elements on the Kinetics and Mechanism of Graphitization of White Cast Iron." Min Higher Mucation USSR. Moscow Order of Labor Red Banner Inst of Steel imeni I. V. Stalin. Moscow, 1955. (Disseration For the Degree of Doctor in Teelmical Sciences). So: Knizhnaya Letopis', No. 11, 1956, Pp 103-114 ., .:I- -- ":*T11 . - 1 1-4- -, - i-,P ~r . KRISHTAL.M.A. The graphitization theory. Idt.proixy. no.9:30-31 5155. (Cast iron--Metallurgy) (KLRA 8:12) metheid for deurmWal, the cotfficfert of sell dirusioa ut trol ba a.1107a4 austenits. 14, A. Kriexzl~ Zhu? r#AA 'I Figi 2.5, , I '~Ccked ""bacro If cc ~ Wo! A tioli- tak-~ii place hy tneans of h.711 ".,N prr---13E in a arytial trial bc filled wlt.~ &n ~djrfatmc tC1V =--sing it 19 mo-m for onc interat. sprice. A dL4:A#L,,!!1-nf ,f t ho!, (oz R enmLdtrable dittmixct do- u, t ,-c-- r -uf;nC itio,,tnitnt of an atom A (J a rt ~f one hitetat. vtweschic-s the itt-It. Yhrtr Is Ito 11"d for an atom to travizf frrn the t,Yrf4i:,! Intn 1he ~.~y oi nietall lor Mline inte.triml Attnt:i of Fe diFuso In th!s timinct, as cao tic gecn In cra gilt i tiratifm I,oles must truvel to graphite inclusions to lxrinit C atx-.-.s to join the latter. Diff4sion promr-S have (tic VLICX-ity thi,, 40!ci travial, an4 the decatirbufrization resetints off 0-5-miu, .1 varthilic imn in Ift, was "%cd foc it& d-cotonmration. kito'- ari-ig the thirknesti of noisicnitic layer firce fmn emplitte a, a iwnrficrn of timi, gives this Velocity Sprcinl~-~Cnnte 41-14~ C xpd 0.6, 0 9, 1.2% Si and thogc i;h tfl~e ~me C and 1. 2.5, and M7, Ki wen decarbudreti at giving the " e( sell diffusion of Iran. Atll)20'theiflffusionvel~~i- "Cfthc Si &!Tties Screg.1 X 10-0. 1.05 x 10-, an4 1.8-4 x 10-", while M incremsed it to 2.32, 9-Z3, and 14.0 X 10-. This diflusion veloicity Is a!mut 4 orders of ma&mittld eoW tabu , 'T ttu" t,vkt of pore (tom. D!1U%i= dAtii. am is . J. D. GAL-..m IRA,; ? R-0 Ell OWN, AUTHOR: Krishtal, M.A., Eng. 129 - 8 -5/16 TITLE: Influence of preliminary hardening on the diffusion speed of carbon in the austenite. (Vliyaniye predvaritellnoy zakalki na skorost' diffuzii ugleroda v austenite). FMIODICAL:"Metallovedeniye i Obrabotka Metallov"(Metallurgy and Metal Treatment), 1957, No-8, Pp.20-21 (U.S.S.R.) ABSTRACT: During heat treatment steel components may be subjected to repeated hardening and, therefore, it is of interest to study the influence of hardening on the speed of diffusion of carbon in the austenite. This was done by means of a metallographic method based on studying the speed of decarburisation of white iron described in earlier papers of the author (3,4). As test specimens the authors used 0.5 mm thick white iron plates containing 0.4% Cr and about 4% C; the material was produced by "liquid rolling" of melts smelted from commercially pure iron. The specimens were decarburised in a hydrogen stream at 850 C during one-and-a- half hours and as a result of this an 0.120 mm thick austenite layer was obtained with a carbon concentration approaching zero at the surface. The results are summarised in a table and a graph which gives the influence of the umber of hardening operations on the value of the coefficient Card 1~12 Influence of preliminary hardening on the diffusion speed of carbon in the austenite. (Cont.) 129 - 8 - 5/16 of diffusion of carbon in the austenite. It ~:an be seen from this figure that-with increasing number of hardening operat- ions the diffusion of carbon in the austenite decreases. there are two figures, 1 table and 5 references, 4 of which Are Slavic. ASSOCIATION: Tulsk Mechanical Institute (Tullsk.iy Mekhanicheskiy Institut). AVATLA LE: Card 2/2 AUTHOR: Krishtal M A SOY/163-58-1-37/53 TITLE: On the Mechanism of the Diffusions in Volume Centered Iron (0 mekhanizme diffuzii v obl'yemnotseritrirovannom zheleze) PERIODICAL: Nauchnyye doklady vyashey shkoly. Metallurgiya, 1958, Nr 11 pp 201-205 (USSR) ABSTRACT: Iron and many iron alloys have volume centered lattices and therefore are of great importance in the explanation of the mechanism of the diffusion in a- and 6-iron. To explain the pore formation in volume centered iron samples were annealed at temperatures where 8-Fe occurs. All samples investigated by metallographic analyses and micro- photographs prove that none of the samples was without 'Pores. In microphotographs pores of uniform shape are present. The presence of pores in iron is proved by the diffusion of iron and tantalum in volume centered iron alloys. The shape of pores occurring most frequently is pentagonal. By means of the microphotographs the depth of the penetration of the tantalum atoms into iron was determined. The mean magnitude of thin penetration is 0,256 mm. Card 1/2 The magnitude of the diffusion coefficients of tantalum in iron SOV/163-58-1-37/53 On the Mechanism of the Diffusions in Volume Centered Iron 2 may be oalculated by the following formula: D !-, where x 4-r denotes the depth of penetration and i the duration of the treatment of the sample at 14500C. -8 The diffusion coefficient has the order of magnitude of 10 - '0 -9 cm 2/sec. I There are 5 figures, 1 table, and 6 references, 4 of which are Soviet. ASSOCIATION: Tul'skiy mekhanicheskiy institut (Tula Mechanical Instit,ite) SUBMITTED: October 1, 1957 Card 2/2 '00"'t/ AUTHORt Krishtalp II.A., Candidate of Technical Sciences 128-58-5-10/16 TITLE: Calculating the Limiting Factor of the Graphitization Process (K raschdtu limitiruyushchego faktora protsessa grafitizataii) PERIODICAL3 Liteynoys Proizvodstvot 1958p Br 5t pp 22-24 (USSR) ABSTRACTs The author lists the different points of view on the factors limiting the aphitization process in malleable cast iron - Ilef. 1 - 1 and analyzes the formulas suggested by different f authors for determining the diameter of the growing graphite inclusions as a function of time, for determining the activa- tion energy, eto. He comes to the conclusion that the speed of the initial graphitization process in Fo-C-Si alloys is controlled by the speed of the vacancies in austenite toward the growing graphite inclusions. He points out, however, that this conclusion can only be accepted as yet for the case of Fe-C-Si alloys of studied concentrations. In other cast irons, and particularly in alloyed cast irons, the graphitization process can be controlled also - as was already indicated - by the speed of the plastic flow of mold, by the diffusion of Card 1/2 carbon, and by the solution of carbides. Calculating the Limiting Factor of the Graphitization Process 128-58-5-10/16 There are 13 referenceep 9 of which are Soviet and 4 Engllohs AVAILABLEt library of Congress Card 2/2 :;0V- 128 - _z 8 - AUTHORS: Kr' Y,A., Candidate of Technical S~;ienses, Fcm~nykh, .:t.9 ~tl of Technical Sciences, Rikman, E-P ,P., Cqndida , Engineer TITLE: Peculiarities of Magnesium Distribution During Annealing of Magnesium-Treated Malleable Iron (n3obennosti. rasprede- leniya magniya pri otzhige PERIODICALt Liteynoye proizvodstvo, 1958, Nr 8, pp 10-11 tUSSR) ABSTRACT: The effect of magnesium on the formation of spheroidal gra- phite has been studied since the discovery of magnesium iron ZR-ef,1-17. The purpose was to study the behaviour of man- ganese in the process of annealing, e,g. the redistribution of magneaium between the metal and the graphite. The study was carried out on specimens of iron of different composi- tion and with the use of a device fcr localized spectrum analysis (described and il2us-.rated b * a diagram), It was stated that silicon, solved in MeVil, tie3 iragne3ium, and hence an increased silioon content in iron entails an 'Ln- creased solubility of the manganese therein. The bond be- tween the atoms of silicon and magnesium impedes the trans- fer of magnesium from the matrix (austenite) into the gra- Card 1/2 phite during the process of annealing. In low-silicon iron, Peculiarities of Magnesium Distribution During Annealing of lliagnosium- Treated Malleable Iron the magnesium atoms in the matrix are only weakly bound, and migrate into the graphits even at comparatively low temperatures. There are 2 graphs, 1. diagram, and 7 refer- ences, 5 of which Are Soviet, 1 Engl,--Qh 9-ni I German.. I. iron alloys--Heat treatyrint .2. effects Card 212 vo Ila jv- fill vial 'Veil IN 411 If %a . I . I. i ,ua " a "Pi 18 (7) AUTHORS t Krishtal, MO Golovint S. A, SOV/163-59-2-30/48 TITLE: The Relative Fading of Torsional Oscillations in the Thermally Treated Steels 50A and VA (otnocitellnoya zatukhaniye krutillnykh kolebaniy v termicheoki obrabotannykh etalyakh 50A i U7A) PERIODICAL3 Nauchnyye doklady vysshey shkoly. Metallurgiya, 1959, Nr 2, pp 173-175 (USSR) ABSTRACT: The authors investigate the internal microplastic friction in the hardened and drawn stools mentioned in the title in order to clarify the connection between metal structure and internal friction in carbon steels. Products of these sorts of steel (springs) are exposed to rapidly changing loads. The composition of the two steel types is indicated in a table. The internal microplastic friction was determined by the fading of the free torsional oscillations which were recorded by a special apparatus with tensometrio recording of the vibrogram. The results for the two steel types are represented in figures 1 and 2. They show the dependence of the torsional oscillations on the voltage applied to the periphery of the sample. rigures Card 1/2 3 and 4 show the influence of various drawing temperatures. The Relative Fading of Torsional Osoillations*in the SOT/163-59-2-30/48 Thermally Treated Steels 50A and 17A At drawing temperatures between 450 and 5500p a considerable reduction of fading occurs. It in explained by-& splintering of the blacks of the cL-phase in drawing, as was also ascertained in the investigations by K. F. Starodubov and A. A. Sazon6va (footnote on p 174) . The fading of the oscillations In hardened steel drawn'at a low temperature is mainly influenced by the austenits, component whereas at drawing temperatures above 3000 the ferrite structure becomes decisive. There are 4 figureep I table, an& 2-3oviet references* ASSOCIATION# Tal'skiy mokhaniobaskiy Institut (Tula institute of mechanics) Card. 2/2 18(3) ^f)V /12~?-50-7-14/25 AUTHOR: Frishtall M.N., Candidate of TechnicP1 "ciences TITIE; - -------------- ~Teutralizing Chromium -in ','allepble Tron IIERIODICAL: Titeynoye Proizvodstvo, 1017c, ?Tr 7 74-7c (TTC?7T)N ABSTRACT: ~s is rell lrnovm chromium even in small nmoiintq blocks the process of grnphite formation. I~cience is occupied with Vie acceleration of this process and the author himself has already written several ar- ticles on the influence of cobalt, bismuth, etc. on the formation of new groupings of etors. V-erefore, the author has done experiments to neutralize the chromium during the production of cast iron in order to allow the formation of ErRp,hite. I.- a basic mate- rial cpst iron with a contents of chromilin of 0,251"t has been used. An exactly measured amount of antimony Ob) has been admixed to have an exact kno,.~:leige of - IT the proportion of the atoms (!T ). Tjje results ,b cr Card 1/2 of the research on the formation of graphite are lis- ~O 3 11/12~-59-7-14/25 Neutralizing Chromium in !Iallenble Tron ted in one table. The formntion of frrap',lite appeprs ap a function of the conten"s of antimony. The pro- ces3 of grnphite formation lasts 6 to 7 times lonlyer in case antimony has not been nVed. The foundry ex- periments and the analysis had I~een made t'7e ag- sistance of P.A. Tyzlov. The experiments 'have shoi,.m that the most. favorable proportion of IT sb or is equal to a ratio of 2 : 3. T!,ere are I"' d'La,-,rrms, 77 microphotographe and 11 ",oviet references Card 2/2 9,5-ig 0 AUTHOR: Krishtal, M. A. 2C.-'e'--5-37144 TITLE: Estimation of the Vacancy Conoentration in Gamma-Iron the Internal Friction Method (Otsonka kontsentratsii vakanaiy v gamma-zheleze metodom vnutrennego treniya.) PERIODICAL: Fizika metallov i metallovedonlye, Vol 7, Nr 3, pp (USSR) ABSTRACT: Slightly Abridged Translation. Cara 1/1~ by IVN 469-470 The peaks of Internal frietion Rt low temperatures-in interstitial bod"entred cubic solid solutions are associated with diffusion redistribution of the dissolved atoms under the action of applied forces (Ref.1). Carbon atoms dissolved in alpha-iron are In the octahedral pores of the lattice and create distortions which change the tetragonal aymmetry. In the absence of stress the distortion axes are evenly dia- tributed between the three dixeotions 1001, 010: and fOOlj. The force applied along one of' thos'e directions leads to such a redistribution of atoms that the axes of tetragonal distortions lie along the line of action of the force, since stresses are partly removed, The change of Estimation of the Vacano-y Concentration in Gamma-Iron by the Internal Friction Method deformation lags behind the it-angq In stress, which leads to internal friction. The atoms of oarbon in the vacancies do not lead to tetrahedral citst;ortiona and oan give internal friction peaks only if their conaentration is great. if the carbon concentration J.3 iOW, peaks are absent. Therefore it appeared probable that a super-saturation of iron with vacancies would lead to a lowering of internal friction peaks. A calculation of the co ncentratlon of -the carbon which bLad gone to the vacancies will enable ths Vaoancy concentration in the specimen to be estimated. The number of vscancie.,% in metala Increases with rise in temperature. An Investigation was oarried out with wire specimens of Armco iron, 0.5 mm diameter and 320 mm long, which had been quenched frem 1250 and 13700C (i.e. from the .gamma-region). Heating was sarried *ut in quartz ampoules of-rall diameter which hadbeen evac~uated to a pressuro of 10 mm Hg. Quenching was r;aLrried cut together with the Card 2/jr, ampoule in cold water. The motol (,ontained 0.013;~ 0, 0.02% 11n, 0.008% P, 0.023;1:4~ S aud traces of Si. 41 .0 7 ? 30 SOV/12E-7-3-37AA Estimation of the Vacancy Concentration In Gamma-lron by the Internal Friction Method It was assumed that the vacancies formed on heating are filled by0carbon atoms. Speeimena were soaked at 1250 and 1370 G for 40 minutes each. There will be insufficient time for the vacancies forming in quenching during the Y ---> Of transformatUn to be filled by oarbon atoms, as it takes only about one second. It appears probable that the vacancies formed at a high temperature will be "marked" by carbon atoms. The results of Internal friction measurement with a totsion. pendulum at an oscillation frequency of 1.35 cycles per second are shown in Fig.l. The curve for unquenohed Armoo iron of the same composition, taken from the work of Fao-tsuy Yunt et alia (Ref.2), is also shown. The internal friction peaks become lower as the quenching temperature is increased. In the table on p 470 results of treatment of experimental data regarding the exposure of carbon in solution and that Cald 31j~ having gone into the vacancies, are ahown on the basis of data Estimation of the Vaoaney Concentration in Gamma-Iron by the Internal Friction Method by Plmo-tnlui * Y~n et alli (Ref.2) and Dijkst-ra et alii (Ref.3). The vacancy conoentrations obtained are comparable with data by Lazarev et alii (Ref.4) in which it la shown that other face-centred cubic metals, e.g. gold and platinum, at the melting temperature have 0.1 at.% vaeanoies. There is 1 figure, 1 table and 4 references, of which 3 are Soviet and 1 English. ASSOCIATION: Tullskiy mekhanicheskiT Institut "T_-_1'% Mechanical Institute) SUBMITTED: February 28, 1958 Card 4/4 sov/126-7-4-11/26 AUTHOR: Krishtal.... TITLE: On the Volume and Grain Boundary Diffusion PERIODICAL: Fizika metallov i metallovedeniye, 1959, Vol 7, Nr PP 565-571 (USSR) ABSTRACTt After discussing the fact that the relative importance of the part played by the volume and grain-boundary diffusion often depends on the thermal history of the metal or alloy under consideration and that, according to some workers (Ref 6-8) the ratio between the coefficients of the volume and grain-boundary diffusion is often of the order of 10 to 1o5, the author points out that in some published papers the values of the calculated diffusion coefficients are regarded as referring to one or the other type of diffusion without first evaluating the coefficient of the grain-boundary diffusion and without sufficient experimental evidence. Thus, a subjective factor is introduced in deciding whether the diffusion process is of the volume, grain-boundary or mixed type, the more so that in most cases the diffusion coefficients are calculated from one and the same Card 1/6 formula (Equation 1). The object of the work reported On the Volume and Grain Boundary Diffusion SOV/126-7-4-11/26 in the present paper was to calculate the diffusion parameters Q and A from experimental data using 11 quations derived for the case of volume diffusion alone, compare the obtained results with the values of Q and A calculated with the aid of Eq (1) and use the obtained data for evaluating the part played of the two types of diffusion in various processes. Experimental data on the coefficients of self-diffusion in silver and iron, and coefficients of diffusion in iron quoted by various workers (Ref 3. 8-11), were used in these calculations carried out with the aid of the Dushman-Langmuir equation D = 62 Q.,-Q/RT (2) Nh where 6 - interatomic distance; N - Avogardo number; h - Planck constant; Q - activation energy of diffusioni R - gas constant; T - absolute temperature. Eq (2) was selected since it is in good agreement with the experimental data on self-diffusion in tin, gold and copl)er (Ref 13). The pro-exponentinl term of this Card 2/6 equation contains well-known magnitudes (6, N, h) which SOV/126-7-4-11/26 On the Volume and Grain Boundary Diffusion does not always apply to other formulae describing the connection between diffusion parameters (Ref 14,15). The value of 6 was taken to be equal to the shorter interatomic distance (2.883 A for silver, 2-521 for iron). Table 1 gives the experimental data on the self-diffusion in silver (first 3 lines) and iron (the next 3 lines) and on diffusion of chromium in iron (last 2 lines), represented in the form of parameters Q (kcal/g-atom) and A (cm2/sec) of Eq (1). (Column 4 gives the reference, column 5 the type of diffusion according to the original source: volume, mixed, grain boundary, volume, volume, grain boundary, volume, volume, mixed). The calculations of the value of activation energy from Eq (2) were carried out by the section method (Ref 16). Fig In and b show the examples of the results on these calculations for volume self-diffusion in silver and mixed self-diffusion in silver, respectively. The values of the coefficients of diffusion and self- diffusion and the values of Q and A calculated from Eq (2), are given in Tables 2, 3, 4 and 5. The values of Card 3/6 the diffusion coefficients D (cm2/sec) and parameters Q On the Volume and Grain Boundary Diffusion SOV/126-7-4-ii/26 and A calculated from Eq (2) for self-diffusion in silver are given in Table 2, the three sets of data referring to volume, grain boundary and mixed diffusion. The same data for self-diffusion in iron are given in Table 3 for the cases of volume and grain boundary diffusion. Table 4 given the values of D, A and Q for self-diffusion in silver for the case of volume diffusion only but calculated from data quoted in Ref 9 and Ref 10. The same data for volume and mixed diffusion of chromium in iron are given in Table 5, Fig 2 shows the temperature dependence of the values of Q calculated from Eq (2) for: 1 - volume 2 - mixed; 3 - grain boundary diffusion in silver; 4 5.7 - volume aelf-diffusion in iron according to data tublished in Ref 8, 9 and 111 6 - grain boundary diffus.4,on in iron; 8,9 - volume and mixed diffusion of chromium in iron. The values of Q at 3000C obtained by extrapolation of curves in Fig 2 are given in Table 6 (column 3) together with values of Q calculated from Eq (1) (column 2); column 1 of this table gives the character of diffusion (self-diffusion Card 4/6 in silver, self-diffusion in iron and diffusion of On the Volume and Grain Boundary Diffusion SOV/126-7-4-11/26 chromium in iron)l column 4 gives the source of the experimental data; column 6 gives the type of diffusion: volume, mixed, grain boundary, volume, volume, grain boundary, volume, volume, mixed. Several conclusions can be drawn from the results obtained by the present author; (1) When Equations (1) and (2) are used for calculating the parameter A, comparable values are obtained in the case of volume Belf-diffusion only. (2) In the case of volume diffusion, the values of activation energy calculated from Eq (2) decrease with rising temperature. (3) There is a linear relationship between the temperature and the values of activation energy calculated from Eq (2). (4) Extrapolation of activation energy curves determined ifith the aid of Eq (2) gives the values of Q at 300*K comparable with those obtained from Eq (1) in the case of volume diffusion and self-diffusion only. Extrapolation of these curves below 300*K shown that in the case of grain-boundary and mixed diffusion in iron and grain- boundary self-diffusion in silver. there are temperatures Card 5/6 at which both values of Q coincide. The results of SOV/126-7-4-11/26 .On the Volume and Grain Boundary Diffusion calculations of these valuen are given ill 'ruble 7 ulldor tile following 110adingst number of tile curve ill Fig 2; equation of the curve; character of diffusion (self-diffusion in silver, self-diffusion in ironS diffusion of chromium in iron); the temperature ( K) at which 02 = Ql; type of diffusion (grain-boundary, grain-boundary, mixed). (5) Calculated values of A and corresponding most closely to those characteristic of the volume diffusion were obtained from experimental data due to Gruzin (Ref 9) and Birchanall and Diehl (Ref 11). There are 2 figures, 7 tables and 16 references, 11 of which are Soviet, 4 English and 1 German. ASSOCIATION:Tullskiy mekhanicheskiy institut (Tula Mechanical Institute) SUBMIT-TED: November 20, 1957 Card 6/6 SOV/126-8-2-20/26 AUTHORS: Krishtal, M.A. and Golovin, S.A. TITLE: Nature of Intornal Friction in Hardened and Tempered Steel PERIODICAL: Fizika metallov i metallovedeniyo, 1959, Vol 8, Nr 2, pp 294 - 301 (USSR) ABSTRACT: Many hardoned and tempered steel parts work under loads of varLable sign at high temperatures and the nature of relaxation effects is thus impartial. A pronounced internal-friction peak has been observed (I.N. Chernikov Refs019 2) for hardened and tempered carbon stools at 200 C, the peak height depending on the carbon content and tempering temperature. The authors describe their work with type V-1 high-carbon steel, widely used for springs. Two compositions (Table 1) were used: 0,71, 0,92% C; 0.47, 0.24% Mn; 0.34-0.26170' Si, respectively, with 0,02910 S, 0903% P, traces of Cr, under 0.11,19' Cu and no Ni nor Ti. Tent pieces were 0.8 mm in diameter, 320 mm long. Vacuum annealing at 1 000 0 C for two hours 0was carried out Cardl/4 before hardening; hardening was from 800 C. Tempering SOV/12~4-2-20/26 Nature of Internal Friction in Hardened and empered Steel was effected for one hour at temperatures of 100, 200, 250, 350, 450, 500 and 700 0C. Internal friction was measured on a type RKF-MIS-1 vacuum torsional installation at frequencies of 1-33 and 2.08 c.p.s. Internal friction as functions of temperature for various tempering temperatures is given in Figures I and 2 for the 0.71 and RZ 92% C specimens. The peaks lie between 220 - 260 Acreasing inxalue with rising tempering tempera- ture and with falling carbon content (as shown by the data in Table 2, derived from the authors' and published (Ref 1) data and in Figure 3). The temperature of the peak rises linearly with increased carbon content (Figure 4). In Figure 5, the internal-friction peak values are shown to be related linearly both to total carbon percentage and to percentage of residual austenite (obtained from the work of A.P. Gulyayev - Ref 4). The authors have calculated values of the diffusion coefficient and activation energy corresponding to the positions of internal-friction peaks. For activation-energy determi- Card2/4 'nations additional internal-friction measurements were sov/.i26-8-2-20,/26 Nature of Internal Friction in Hardened and Tempered Steel carried out at 2.08 coposo Figures 6 and '7 show internal friction plotted against temperature for the 0.71 and 0.927/0 C steels, respectively, hardened from 800 C. Curves I and 2 in Figure 6 (.orrespond to frequencies of 1-33 and 1.81 c.pos. and to frequencies of 1-33 and 2.08 in Figure 7, a second pair of ~.,urvte in the latter corresponding to steel tempered at 250 *"-. Tables 5. 4, and 6 show diffusion-coefficient values for carbon in the 0.92- and 0.73N-C carbou steels, respectively; Tables 5 and 6, based on published (Ref 1) data, give the values for steels with 0.58 and 0.46% C, respectively. The results agree with published (Ref 8) indications that the rate of diffusion of carbon is lciss in austenite subjected to hardening than in austenite not so treated. Diffusion-coefficient values measured by the internal- friction method for hardened steel tempered a'. low tempera- tures agree with those found metallographically in austehite obtained from the hardened state. As a further Card3/4 SOV/126-8-2-2o/26 Nature of Internal Friction in Hardened and Tempered Steel check the internal friction o6 0.92% C steel subjected to double hardening from 800 C was determined, showing a displacement of the internal-fription peak towards higher temporatures (Figure 8 - Curve 2 compared with Curve 1). Professor B.N. Finkel'shteyn, Yu#V. Piguzov, L.F. Usova and I.N. Chernikova helped in internal-friction measurements. There are 8 figures, 7 tables and 10 references, of which 8 are Soviet, 1 English and 1 international. ASSOCIATION: Tul'skiy mekhanicheskiy institut (Tula Mechanical Institute) SUBMITTED: February 28, 1958 Card 4/4 SOV/126-8-2-21/26 AUTHORS: Krishtal, M.A. and Golovin, S.A. TITLZ~ Contribution on the Nature of Relativo Damping of Oscillation in Hardened and Low-tempered Carbon Steel PERIODICAL: Fizika metallov i motallovedeniye, 1959, Vol 8, Nr 2, PP 302 -- 308 JUSSR) ABSTRACT: The authors' previous (Refs 1, 2) measurements of m1cro-plastic Internal friction in heat-treated type 50A and U`7A steels and of internal-friction relaxation in U7A and-UgA steels showed the great effect of residual austenite in hardened emd low-tempered specimens on the damping capacity of the rteel. Their Iresent investigation, aimed at further examination or this postulate, was carried out with 50A and U7A &teels (widely used for machine parts tubjected to vibration in service) of the following reopective percenta a composition; 0*49, 0-70 C: 0.34, 0.23 Mn; 0. 59, 0.18 51; 0.024, 0.021 S; 0.019, 0.026 P; 0.19, traces Cr. An apparatus (Figure 1) was provided with tensometric Cardl/3 recording of vibration patteins and with a furnace SOV/126-8-2-21/26 Contribution on the Nature of Relative Damping of Oscillation in Hardened and Low-tempered Carbon Steel enablino the 7-mm,0diameter test pieces to operate at up to 36o C with 10 intervalS in a protective atmospbero. Before hardening (from 800 C for U7A and from 860 uC for 50A steel) specimens were annealed for one hour; hardening was followed by tempering for one hour at different temperatures. Tte effect of repeated-stressing treatment on relative damping for the two steels is shown in Figures 2 and 3. In the higher-carbon steel repeated- stress treatment gave reduced relative damping at higher stresses. The treatment did not increase hardness. Holding In liquid nitrogen was found to reduc8 relative damping for tempering temperatures up to 200 C (Figures 4 and 5 show this property as a "function of stress for various heat-treatment histories for the two steels). Repeated hardening also reduced relative damping (Curve 2 compared with Curve I in Figure 6). A maximum of relative damping was found for U7A steel at about 290 OC in tests with continuous heating (Figure 7). The authors used their Card2/3 own and published (Ref 1) data to calculate the carbon SOV/126-8-2-21/26 Contribution on the Nature of Relative Damping of Oscillation in Hardened and Low-tempered Carbon Steel diffusion coefficientt diffusional relaxation in austenits evidently playa some part. Their results indicate that residual austenite has a considerable influence on the damping properties of the hardened and low-tempered steels investigated (Figure 8 shows relative damping at various atrossas plotted against time of tampering at 200 0C for U7A steel). There are 8 figures, I table and 9 references, 7 of which are Soviet and 2 English. ASSOCIATION: Tullskiy makhanichookiy institut (Tula Mechanical Institute) SUBI,aTTED: August 22, 1958 Card 3/3 KRISHTAL, M.A., kaTA. tekhn. nauk, dote.; FVMIlr=l I.P., kand, telchn. nauk, dot$@; MEW, V.F., kand. takhn. nauk, 4ote,; TSETTLIN, A*Y&,, insh, Characteristics of the surface structure of decarburized malleable Iron castings and their machinability. Trudy TMI no.11:66-77 159- (nft 12:12) (Cast trarr-Heat tr6atment) (Metal outting) i '~RT'h7A4_j "i. L., Lir. Sci - llloifl.~."'~!~;'j in 1 -L, , ~-'- , 1") - - ov f~ -1 1, s t 1. tu to ~ m I . '. .-11.il n) (I. ~--, I)o ;.Os . ,, lgr-o, 51 pl) ("os.,;o.; Stec '7 101,7 1 14 64 via A ail M11 ts A VVI . . mg o V. 9 ;lit I! a jj a 1.44 o" I A 9 1 R R 40 Of ~j R gi led 44 1. X 4!01 d.1 .!Z 4 06 I;. j HMO: si4 Ali ell 9. 1i " a"', I 11 a I Val V3 6 4:8 I bV " ]I, ~ 1 1, is Niff - 'k SW 111 -.1- H 1 is Ells 3 0 Ji- IA 31 AUTHORSt Krishtal and Titenskiy, E. G. S/12 60/0UU/009/001/003 A161 YA133 TITLE: Modified malleable cast iron with hi&h chrome content PERIODICAL: Liteynoye pitizvodotvol no. 9, 1960, 33-35 TEXT: As it is known, chrome is the strongest inhibitor of the gra- phitization process in malleable cast iron, and its usually permissible maxi- mum content is O.Or/.. more chrome is getting into cast iron with high-alloy steel scrap, and ways must be foun4 to neutralize its effect. This is pos- sible by the addition of silicon and aluminum [Sobolev, B. F. - Ref. 2: go- difitsirovaniye i isakustvennoye stareniye kovkogo chuguna (Modification and artificial aging of malleable cast iron), Mashgiz, 1956], or by'the addition. of manganese. But the greatestattention is paid now to the addition of an- timony (Krishtal, M. A. - Ref- 3t DAN SSSR, v. 99, no- 4, 1954; Livshits, B. G. - Ref. 4t DAN SSSR, v. 93, No. 6, 1953; Krishtal, U. A. - Ref. 5t Li- teynoye proizvodatvo, no. 8, 1959). This article presents data obtained in an investigation with additions of antimony and-boron, and combinations of boron with bismuth, and boron with antimony. Boron was added in the form of Card 1/5 S/128/60/000/009/001/003 Modified malleable cast iron with... A161/A133 ferrosiliconboral and ferrobcron in amounts of 0.003 - O.Q10% of the weight of iron. Antimony and bismuth were used in metallic form. The Gorlkovskiy avtozavod (GorIkiy Automobile Plant) has started to utilize cast iron modi- fied with boron and bismuth, but the mechanism of the effect of these addi- tives on the graphitization is not yet clear and further experiments are nec- essary. Four alloy groups were studied (the compositions are given in the table). The results prove that the graphitization time is shortest at a weight per cent ratio of antimony and chrome of 3t2, which corresponds to the formation of atomic segregation's of the Sb2Cr3 type. Annealing for 36 hours as illustrated in diagram (Fig, 1) resulted in malleable cast iron with gra- nular pearlite metal Fig. 2,a ; no primary carbides formed with a chrome content of up to 0.2%~ The mechanical properties of metal modified by Sb alone are given in curves (Fig. 3): hardness and strength increasing with a rising Cr-content, the plastioity decreases; at 0.10,'o Or the elongation is 5%, at 0 2% Cr it is-2.6%; the ultimat4 strength and hardness incresse'to 50 kg/mm, and HB235; the machinability remains good de spite high hardness. Contrary to 3b only, additions of B and Bi resulted in 5 - 8% eutectic car- bides even at a low Cr-content (0.06%) and meohanical properties as in Figure 4. The residual carbides did not affect the machinability because of the en- Card 2/5 -!1 on/ 0 /0 C A 0fc- C, I /C0' 3 malleable ca:;. ixuii A1131/A133 voloping graphite, and at UP to 0.10~,~ th4, cloneation did not drop below the strength reached 40 - 42 ko/mm2, and hardneso HB157- An increase in the chrome content over 0.101,11, resulted in some decrease of the impact strength. 'This modification method yielded forritic high-chrome iron with low hardness and hiCh elongation. Iron modified with boron only had a sufficiently hi;;h Craphitization capacity. Bismuth is a very inconvenient additive - it.burns with copious fumes separation. Antimony is a chemical equivalent of bismuth, and it has the samechilling effect and dissolves well in iron, whil3t liquid iron and bismuth do not mix at all. The plasticity of iron modified with 3 and Sb remains high with up to 0.2j'a' Cr,')and tho elonGation is about 7rfi; the str~!ngth and hardness are increasing with a risinG Cr-content. The higher hardness is due to the presence of a small quantity of pearlite (Sb prevents graphitization in the second stage). The machinability is not affected by residual pearlite. In general, the machinability of iron modified with borcn and antimony, or with boron ard bismuth is practically eame. Antimony (like bismuth) gives an isotropic iron structure. Modification with antimony is not accompanied with any fumes separation. 3oron alone may be used for thin- walled castings (5 - 15 mm), for no graphite separation takes place durinu crystallization. The optimum boron addition for 15 mm wall castings is Card 3/5 S11201601000100910011003 Modified malleable cast iron with... A161/A133 0.003 - 0.005$. The impact atrength of iron modified with boron only drops abruptly with An Inorwing ihromo content# which appoore to be duo to ani. eatropy but it does hot affeat the dhor madhatiaid PrOpettidd. The tiadhin- ability of boron-modified iron did not differ from the usual in malleable iron or in iron modified with other additives. There are 6 figures and 8 Soviet-bloc references* Ic 700 WO sea 0. 17 Figure It The annealing grapht temperature'in OC and time in houre (to 37 hours). Card 4/5 M,odified malleable caEit iron "161IA133 q yry U L. a C 51 Ain S P Cr At Sb I MO ov.. 2,72-2,62 1,14-1.27 0.&)-0,55 0.126-0.1= 0,074 0,70-0.20 0,015-0,C"0 0,12-0,3D 11 1t- MO 11 w 1 = 8 rc.vTo- 2,W-2,15 1.16-1.?2 0,53-0,58 0,22-0,143 0^2 0.01-0,16 0.013-0,c-0 - 0.003-0005 0.01 III MOA1OOp"W.POB2"- out 6apow . . . 2,61-1.72 1.12-1.23 0,41-0,53 0.0-0,143 0." O.CS-0,14 0,015-0,0M - 0.0C3-0.01 - IV M nut 69p9w K I.P-2.79 1.10-1.30 0.49-0.81 0.120-0,135 0.072 0,01-0,20 0,015-0..20 O.WS-O.Ml O.W3-0.fts - Table: I Iron modified with Sb; II with B and Bi; III - with B only; IV - with B and Sb. ~1~ chemical composition.in 1744; 2 addition of modifier in-%. Card 5/5 s/i26/6o/oo9/O2/033/O33 AUTHOR: Krishtal, M.A* Elll/E335 I------------ TITLE: Special Features of the Influence of S-ilicon-on the \:,Diffusion of Carbon in Austen�te,'i PERIODICAL: Fizika metallov i metallovedeniye, 1960, Vol 9, Nr pp 317 - 319 (USSR) ABSTRACT: The author notes that the results of his metallographic investigation of the influence of silicon on the kinetics of carbon diffusion in iron-carbon alloys'](Ref 3) differ from those of others (Refs 11 2); this has led to confusion (Ref 4). He has now added precision to his previous results and extended his measurements to higher temperatures. Using his previous method (Ref 3) he has studied diffusion durin 6 annealing at 860, 880, 920, 950, 1 000, 1 050 and 1 100 Ce The data in Table 1 show that at 1 100 dog an increase in the silicon content reduces the diffusion coefficients at 1 000 and 1 050 OC it has little effect and at 950 C and below it increases diffu,!~~$ Card 1/2 S/126/6o/oog/02/033/033 ,P j5~jl, E 3 3 5 Special Features of the Influence o icon on the Diffusion of Carbon in Austenite There are 2 tables and 8 references, 6 of which are Soviet and 2 English. ASSOCIATION: Tul'skiy mekhanicheskiy institut (Tula Meohanical Institute). SUBMITTED: December 3, 1959 40, Card 2/2 )STO S/i26/6o/oo9/O5/oo6/o25 AUTHOR: Krishial, M.A. Elll/E335 TITLE: Diffusion of Several Elements from One Source in Iron and its Alloys PERIODICAL: Fizika metallov I metallovedenlye, 196o, Vol 9, Nr 5, pp 680 - 688 (USSR) ABSTRACT: The object of this work was to develop the method for investigating the diffusion of several elements from a single source and make a qualitative evaluation of the influence of some alloying elements. The localized spectrum- analysis method of I.L. Mirkin and E.P. Rikman ( Ref 1) was used, giving a diameter for the working part of the sparked area as low as 0.05 mm, or the spark operates between the section and an edge up to 0.1 mm thick. The source was electrolytic iron alloyed with 0.0120% C, 0.0231,10' P, 0.01410' S and 2.5110 each of Cr, Mn, Si, Mo and Ti. Diffusion was studied into iron and also into binary alloys with 5 at Of Cr, Si, Co and V. Figure I shows distribution of chromium"Ailicon andvKanadium with depth in diffusion layers of specimens made up of iron-silicon, iron-chromitun Cardl/3 and iron-vanadium alloys and electrolytic iron. The LK 0527 S/126/0009/05/006/025 Diffusion of Several Elements from Onllellg&M in Iron and its Alloys ordinates in this and all other figures in the paper show tho difference between the degrees of darkening of the analytical pair of spectrum linen. Figure 2 shows distri- butions of chromium, silicon and vanadium in a single ferrito grain for diffusion from the multi-component source. Figure 3 shows distributions of titanium, manganese, silicon, chromium and molybdenum diffusing from the complex alloy (lefthand figures in abscissae) into ironi the corresponding curves for diffusion into the binary iron-chromium alloy are shown in Figure 4, into the binary iron-silicon alloy in Figure 5, into the binary iron- vanadium alloy in Figure 6 (which includes a curve for vanadium) and into the binary iron-cobalt alloy in Figure 7. Figure 8 gives the titanium-distribution curves for diffusion into all the binary alloys and iron; Figures 9, 10 and 11 give the corresponding curves for manganese, chromium and silicon. From these figures the influence of each alloying element on the diffusion -of each element can be estimated: the author gives values on this influence. The work showed Card2/3 that the rate of diffusion increases in the following order: 2 CS 2.7 S/l26/6o/oo9/05/oo6/025 Diffusion of Several Elements from 0111140M in Iron and its Alloys titanium~ manganesk';,~ chromium, silicon and molybdenum~4 All the alloying elements of the binary alloys reduce the diffusion rate, this effect being the more marked the slower the diffusion rate of the diffusing element in iron. Cobalt had the greatest effect on diffusion, which the author attributes to its pronounced effect in reducing isothermal austenite decomposition in the presence of other elements. Professor I.L. Mirkin assisted in discussion of results and E.P. Rikman and N.I. Peshkova in the experimentaf work. re are 11 figures and 4 Soviet references. ASSOCIATION: Tullskly mekhanIcheskiy institut (Tula Mechanical'it/ Institute) SUBMITTED: October 16, 1959 Card 3/3 KRISHTAL. M.A.1 RIMWP E.P, - Distribution of elements in a complex iron-base alloy. Piz. met. i metalloved. 9 no.5:790-792 My 160, (MIRA 14t4) 1. Tul'skiT mekhanicheekly institut. (Iron alloyow-Metallography) 3/126/6o/oiLO/02/015/020 ER~K AUTHORSt Piguzov, Yu.V Krishtal, NN Golovin, S.A. TITLE, The Nature of t;o Maximum of Internal Friction in Steel After Thermal Treatment -116 PERIODICAL: Fizika metallov i metallovedeniye, 1960, Vol. 10, No. 2, pp 285 - 290 TEXT: Experiments were carried out on three steels - U7A, U9A and U12A - the compositions of which are given in Table 1. Measurements of internal friction were taken on a mlaxator at a frequency of 1 cps. Results for two steels are given in Fig. 1, where the internal friction is plotted against tempera- ture. The curves contain the usual maxima at 200 0C. The curves with the higher peaks are for the steel with the greater amount of carbon. The absolute values of the peaks are given in Table 2. Working in the cold leads to a decrease in the value of the peak corresponding to the decrease in the retained quantity of austenite. Fig. 2 shows the internal friction - temperature curves for U9A steel after quenching from sub-critical temperatures (720 0C and 670 OC). A low maximum is obtained at 200 OC, much less than that after quenching from the austenitic condition. Thus, the 200 OC peak can be explained by two phenomena taking Card 1/3 S/126/60/010/02/015/020 2021/9333 The Nature of the Maximum of Internal Friction in Steel After Thermal Treatment place simultaneously: diffusion of carbon atoms in the retained austenite6'and migration of carbon atoms to the dialocdtion regions forming on account of the martensitic transformation and thermal stresses. Further experiments were carried out on armco iron containing 0.019% carbon after 250,; and 75% deforzation. Fig- 3 shows the curvaCs obtained. Deformation of 25% leads tootwo peaks at 40 and 200 0 75% deformation gives one Teak at 20 'C. The disappearance of the first peak can be explained by migration of carbon atoms in the alpha-iron to more energetic positions - in dislocations. The peak at 200 0C is much lower than for quenched steels because of the smaller amount of austenite. There are 2 tables, 3 figures and 10 references: 2 German$ 2 English and 6 Soviet, Card 2/3 S/126/60/010/02/015/020 E22j/ The Nature of the Maximum of n WN Friction in Steel After Thermal Treatment ASSOCIATIONS: Tullskiy mekhanicheakiy inatitut (Tulsk Mechanical Institute Moskovskiy institut stali im. I.V. Stalina Moscow Institute of Steel im. I.V. Stalin SUBMITTED: Penruary 18, 1960 Card 313 85965 24 1700 S/126/60/010/005/013/030 Elll/E452 AUTHOR. Krishtal, M.A. TITLE: Concentration of Vacancies in Iron-Chromium Alloys PERIODICAL:Fizika metallov i metallovedeniye, 1960, Vol.10, No.5, PP-720-726 TEXT. The author criticizes evaluation (Ref.1,2) of vacancy concentration from measurement of electrical resistivity of quenched specimens: the temperature vs vacancy concentration relation could be distorted by polymorphic changes. He recommends measurement of resistivity during heating to high temperatures and describes his work on this. he wire specimen was held (Fig.1) at a pressure of the order of 10-3 mm Hg in a quartz U-tube in a furnace at up to 1400"Ci the ends of the tube were outside the furnace and the specimen ends passed out through rubber bungs and were connected to a type MOA -49 (MOD-49) bridge. The range of compositions W covered was 0.013 to 0.040 C, traces and 0.02 Mn, traces - 0.011 Si, o.oo8 to 0.030 P. 0.010 to 0.023 S, 0 to 5.72 Cr. Resistivity was found to increase linearly with chromium content (Fig.2). Fig.3 shows, for the 5-72% Cr alloy, resistance as a function of Card 1/3 85965 S/126/6o/olO/005/013/030 Elll/E452 Concentration of Vacancies in Iron-Chromium Alloys temperature: above 11400C the experimental points deviate from the atraight line. Table 2 gives resistance changes and temperatures for the various alloys: linear relations were obtained between the logarithm of resistance change and reciprocal of absolute temperaturo (Fig.4), the corresponding activation energies for vacancy formation increasing from 93800 cal/g atom for Armco-iron to 31200 for the 5.72% Cr alloy. Vacancy concentrations calculated from these results for Armco iron and each of the alloys are given in Table 3. They were checked by the internal friction method already described by the author (Ref.6): the internal friction peak at 40% in determined for specimens with and without vacancies, the concentration being found from the difference. Vacancies were created by heating in vacuum to 1050 - 13700C and quenching. Results for the 0.85% Cr alloy are shown in Fig-5 as plots of internal friction against temperature for various quenching temperatures. Table 4 like Table 3, shows that vacancy concentration rises regularly with higher heating temperature and lower chromium content. Table 4 also gives carbon concentration in Card 2/3 S/126/6ow/005/013/030 E111/E452 Concentration.of Vacancieb in Iron-Chromium A11oyB the solution and in the vacancies. Extrapolation suggests that at the melting point, vacancy concentration is about 0.1 at.%. There are 5 figures, 4 tables and 7 references: 5 Soviet and 2 Non.-Soviet. ASSOCIATION: Tullskiy mekhanicheskiy institut (Tula Mechanical Institute) SUBMITTED;; March 29, 1960 Card 3/3 8/123/61/000/011/020/034 A0041AI01 AUTHORSt Krlshtal,_M.-A.1 PomWkh, I. P.1 Lyzlov, B. A. 'TITU: Properties, structure and maohinability of malleable cast iron with chromium and antimony for fittings PERIODICALi Referativnyy zhurnal, Mashinostrayoniye, no. 11, 1961, 3, abstriot 11018 (qSb. tr. Tul'sk. maknan. In-ta", 1960, no. 15, 20-26) 'TECTs An increase In the chromium content of the metal, when alloyed steel gets into-the charge, causes a considerable prolongation of the annealing cycle and also tool breakage during the working of-fittings an a result of insufficient annealing in the first stage. Investigaticna showed that a Cr-content of 0.15% in neutralized by the addi-tien of 0.23% Sb to the cast Iron. S&at iron contain- Ing ?.56% C, 1.5% Si, 0.15% Cr, 0.23% Sb6 Lfter heating to 960 C for 3 hours holding of 15 hours, cooling down to 720 C for 2 hours and holding at this temperature for 10 hours, had the structure of pearlits malleable cast Iron of the Kq-54-5 (KCh-54-5) grade. Tests of the machinability showed that in the time interval between the sharpening of the taps 5-6 times more fittings from malleable cast iron alloyed with chromium and antimony (HB 170-200) could be Card 1/2 S/123/61/000/011/020/034 Properties, structure and maohineability ... A004/A101 machined than those of ordinary non-alloyed cast Iron. There are 3 figures. L. Tumanova [Abstracter's notat Complete translAtion] Card 2/2 S/137/62/oco/oWoWi63 Af6O/AIOI A1111TORSt Mirkin, 14'L-1 Irishtal, M. A. TITLEf The thermal mobility of atoms In alloys PFR[ODICAL: Reforativnyy zhurnal, Metallurgiya, no. 6, 1962, 7, abstract 6143 (In oollectiont "Iasled. novykh zharoproohn. splavov dlya energe- tiki". Moscow, Mashgiz, 1961, 5 - 33) TEXTi Review. Discussed are the meohanisms of diffusion: the diffusion of the pair exchange, along the vacancies, along the interstices, and the annular diffusion., The results of work carried out on the determination of concentration of vacancies by the methods of measuring tbe electric resistance of alloys and of the internal friction are presentedi The effect of the volumetric factor on the diffusion of elements dissolved by the principle of interstitial atoms-is considered.. As regards the diffusion of H, N, C;-ard-B, a linear dependence of the energy of activation on the atomic diameter of the element was detected in ol-Fe, In the case of diffusion along the Interstices, the valence of dissolved ,~~Iewents has a secondary importance. The diffusion of elements dissolved in -;,ar,d 1/2 S/137/62/00()/006/09Z/163 The thermal mobility of atomn in alloys A160/AI01 Fe-94,J NI-by the-principle of substitution is discussed in detail. The results of work on the investigation of simultaneous diffusion of several elements from on,:~ source are given. The effect of the structure on diffusion is investigated. tilrfaoe dAffuzion and the dependence of diffusion on crystallographic orienta- tI-_,n are disrussed. There are 49 references. I. Leftonov J'Arstracterlz note; Complete translation] Card ~?12 30454 11 OD 114 64 S/126/61/012/003/009/021 Jr.193/Z135 AUTHORSt -Krishtal, M.As-, and Mokrov, A.P. TITLE% work hardening of surface layers formed by diffusion of -nolybdenum into iron and its alloys PERIODICAL: Fizika metallov i metallovedeniye, vol.12, no.3, 1961, 389-394 TEXT: One of the shortcomings of the diffusion method of surface-hardening of metal components is that they produce diffusion layers whose hardness and strength decrease with the distance from the surface. Means of attaining uniform-mechanical properties across such diffusion layers are required, and a possible method for achieving uniformity in the mechanical properties in described In the present paper. The method proposed is based on the fact that (a) the variation of hardness is ass6ciated with the gradient of the alloying element concentration across the thickness of the diffusion layer; and (b) the rate of work-hardening of ferrite decreaseis with increasing content of alloying additions. Consequently, a diffusion layer subjected to plastic deformation should work-harden most in its softest part Card l/A V 3045h Work hardening of surface layers S/126/61/012/003/009/021 E193/EI35 and least in the hardest region with the maximum concentration of the alloying additions. To verify this proposition a series of diffusion experiments were carried out. Diffusion couples were formed by a mo2ybdenum foil (0-04-0-05 mm thick) sandwiched between strips of iron or one of the five types of iron-base alloys, containing up to 5 at.% Co, Si, Cr, W, and V. Good contact at the diffusion interface was ensured by spot-welding the components in hydrogen, after which they were subjected to a vacuum diffusion treatment for 10 hours at 1250 OC. Each diffusion couple was sectioned, and microhardness, H,,l measurements were taken across the thickness of the diffusion layer at regular intervals. Each type of the specimen was then compressed to 10, 20, 30 and 40% reduction in thicknoss, after which the micro- hardness measurements were again carried out, the degree of localised deformation c, S. in the diffusion layer being deter- mined from the decrease in the distance between the original microhardness tester indentations. From these data the so-called specific microhardness &HII/c (where 6HV& is the increase in H~j due to deformation c) was determined which gave the measure Card 2/ "~/ Work hardening of surface layers S/126/61/012/003/009/021 E193/EI35 of work-hardenability of a particular region of the diffusion layer. The results are reproduced graphically, those obtained for the 5 at.% Co-Fe alloy being shown in Fig-3 where H,, (kg/MM2, left- hand scale), LHp/c, and c (%, extreme right-hand scale) are plotted against the distance (mm) from the surface of the diffusion layer formed by diffusion of molybdenum. Circles and squares denote Hp before and after 40% total deformation, respectively; the variation of localised deformation c in a specimen deformed to 10% reduction in thickness is denoted by white triangles, black triangles relating to specific microhardness (AHIA/c) of specimens deformed to 40% reduction in thickness. Analysis of these and other results showed that hardness of the diffusion layers studied varied across their thickness in accordance with the variation of the molybdenuts content. The effect of plastic deformation (compression) on the variation of H$Ll C, and t4 HO/C across the thickness of a diffusion layer was also dependent on the molybdenum content, the regions of low Mo content being preferentially work hardened. This proved the possibility of using plastic deformation to attain grantor uniformity of mechanical Card 3/_.!~/ 30454 Work hardening of surface layers S/126/61/012/003/009/021 E193/E135 properties across surface diffusion layers. The beneficial effect of plastic deformation wa3 most pronounced in the diffusion layers formed by molybdenum in the Fe-Si, and least noticeable in the Fe-V alloys. There are 7 figures and 12 references: 4 Soviet-bloc, 4 Russian translations of foreign language articles, and 4 non-Soviet-bloc* The English language references read an followei Ref.2: C. Austin. Trans. ASM, 1943, Vol-31, 321. Ref.4: C. Austin, L. Luite. R. Lindsay. Trans. ASM, 1945, Vol.35, 446. Ref-5: C. Lacey, M. Gensamer. Trans. ASM, 1944, Vol.32, 88. ASSOCIATION: Tullskiy mekhanicheskiy institut (Tula Mechanical Institute) SUBMITTED: December 19, 1960 Card 40,/_ 32660 S/126/61/012/005/022/028 19 11511 EO4O/E435 AUTHORS: Krishtal, M.A., Baranova, V.I. TITLE: Internal friction and electrical resistivity of ferro- .chromium alloys PERIODICAL: Fizika metallov i metallovedeniye, v.12, no.5, 1961, 768-771 TEXT: Due to the ease of formation of chromium carbides, the mobility of the carbon atoms in solid solutions of ferro-chromium alloys can be appreciably affected and with it the mechanical properties of the metal. The problem was examined by determining the kinetics of carbides dissolution in chromium-containing solid solutions during their heating prior to quenching. For this purpose, measurements were made of the internal friction and electrical resistivity of wire-shaped specimens 0.7 mm in diameter and 160 mm long. The specimens were completely annealed by holding for 2 to 3 hours at 10500C and quenched in water from 720 to 12000C. Before quenching, the specimens were heated in vacuo for 10 to 40 minutes, depending on the Cr content. Internal fri~ction -was measured by the torsional pendulum method in Card 1/3 32W) S/126/61/012/005/022/028 Internal frittion and electrical ... Z040/E435 vacuum relaxator apparatus. Annealed specimens containing chromium carbides were found to have no internal friction maximum on the temperature curve. However, specimens quenched from 800*C gave internal friction maxima corresponding to 30 to 40 and 170"C. The actual value of the internal friction peak risen with increasing temperature of quenching, reaches its maximum for the quenching temperature of 1050'2C andthen drops. The height of both internal friction maxima was found-to be dependent on the chromium content in the alloy. The specific resistivity of the specimens diminishes with increasing quenching temperatures (up to 1100*0 and passes through a minimum at 1050'C but it increases if the specimens are quenched from temperatures exceeding about 11100"C, It is conpluded that an increase of the quenching temperature leads to progressively higher carbon contents of the solid solution because of the rising solubility of chromium carbides. The concentration of carbon at points of its introduction into the solid solution rises up to a temperature of 1050*"C,, while further heating above this temperature leadis to the formation of vacancies which tend to be occupied by carbon atoms shifting from the points Card 2/ 3 32660 S/126/61/012/005/022/028 Internal friction and electrical EO4O/E435 of their original introduction. The lower temperature internal friction maximum (30 to 4000 is believed to be connected with carbon migration in the stress field around the iron atoms. The high temperature internal friction maximum (170*0 is thought to be connected with the migration of carbon atoms in the solid solution around the chromium atoms and, perhaps, with their migration to positions surrounded by iron atoms. There are 4 figures and 5 Soviet-bloc references, ASSOCIATION: Tullskiy mekhanichesiciy institut (Tula Mechanics Institute) SUBMITTED: March 20, 1961 (initially) May 8, 1961 (after rovision) Card 3/3