SCIENTIFIC ABSTRACT KRAYNDLER, A. - KRAYNIY, A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000826320004-6
• Release Decision: RIF
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• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

KPAYNDLER, A., akad.; KRIGELO, Ye.; STOYMA, I.
(Epilepay in children] Detakaia epilepsiia. Ruchareat,
Izd-vo Aka6. Humynakoi Narodnoi Respubliki, 1963. 269 p.
(MIRA 16-12)
(EPI1 EPSY) (CHILDREN--DISEASES)

"AMR0, Ts-. 9vardii mayor.
. .1
Illuminating pilot balloon. VOen-v8st. 36 no-5:68-70 My 156.
(Balloons. Captive) Cclectric lighting) (KLBA 9.8)

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.- I - '-m 11 . - . . . I
1 11 . ; s TI , ,
-~-
KRAYNER, N. P.
"P. A. Kropotkin, a Glacialist and Goomorphologist.11
Min Mucation IISFSR, Leningrad State Pedagogic Tnst, Leningrad, 1955.
(Dissertation for the Degree of Candidate in Geographical Sciences)
SO: 1-1-955, 16 Feb 56

xm MR. m.r.
Russian glacialistag forerunners of
no.10:151-159 '58.
(Glacial epoch)
-A-KroPotkln. Geog.sbor.
(MIRA 12:1)

t. MTIMI -17I.P, --- -.,-
P.A. Kropotkin on the formation of river vn1lays. Izv.VGes,KOog,
ob-va 92 no.5t436-441 S-0 '6o. (MIRA 13:8)
(Kropotkin, Petr Alekseevich, 1842-1921)
(Vall.eys)

MAYTIR-, N.P. (Yarosluvll)
N.A. Sevortsov as glaciologist. Vop.iat.est. i tekdi. no.11:
91-95 161. OUR,'. 14: 11)
(Glaciology)
(Severtnov, Nidolai Alekseevich, 1827-1885)

KRAYNER, N.P.
Lomonosov and Russian studies of karst. Do;-I. na nauch. konf. 1
no.4:101-107 162. (MIRA 16:8)
(Lomonosov, Mikhail Vasillevich, 1711-1765) (Karst)

---- --- ----
fka, Vgkk 'S,~.S!fflQIfqk5MrSA, jCjh~Q "d Z- YA KRAINEX
I-Phenylquinaldfni CC.
Um fu" ben prCrurcd by
diocnYfamine hydrochlotidc
t ftent greAt with Par4dchvdd J. di
Ulu ! Wi(b Nfaisium cbf --- GX"C SofutiOn and
Jj cys
airke d' fonnijon, ,. af-at~ The cOMpaUd undc,,. the,
r din
yf c Ii bit I. hen 12- 9: condcniatica with ethyl OfthOrarmato In
flin Y* f ,
'k 2 2
-Acci pctchrdlitte,
avf)~,, iodida
0 inc AfAct
A.I.A.

PILYUGIN. G.T.; KRATNER, Z.Ta.
- " -;--i~
Cyanine dyes. I. quino-, quinoido- and quinothiacarbocyanines. Zhur. Obahchey
Khim. 2). 634-43 153. (HLRA 6:5)
(CA 47 no.20,10385 153)
1. Chernovitay State Univ.

(L
her, uinildis
!~CLnlne d a; V1. on-nim T UZ
rafie ~-s
og5j, n
J. Gen Chem. M.
CL It
Anslatjoa).-cke C.A.
Ln
(

USSR/ Organic Chemistry Synthetic organic chemistry E-2
Abs Jour Referat Zhur - Kh1miya, Wo 4j 1957, 11746
Author Pilyugin G.T., UaPqr_Z.Ya__..
Title investiFations or cyanin Dyestuffs VI. N-m-Nitrophenyl quinaldinium
Perchlorate and Its Conversions
Orig Pub Zh. obshch. khimii, 1955, 25, No 12, 2271-22'f4
Abstract On condensation of m-nitrodiphenylamine with paraldehyde there has been
synthesized the perchlorate of N-(m-nitrophenyl)-quinaldinium (I). A
proof of the structure of I is provided by the posotion of the maximum
of absorption of the derived therefrom carbocyanin, which is close to
the absorption maximum of the analogous dyestuff having a phenyl radi-
cal at the N-atom. Condensattonrof I with orthoformic ester, methyl
iodide~f 2- A-acetanilidovinyl-3,3-dimethylindolenin, ethyl iodide
of 2-,j -acetanilidovinyl benzothiazole or ethyl iodide of quinoline,
there have been prepared symmetrical and unsymmetrical cyanin dyes.
In a sealed tube are heated 4 g m-nitrodiphenylamine, 4 ml paraldehyde,
2 ml concentrated HC1 and 6 ml of dioxane, for 25 minutes at 100P; af-
ter treating with ether, by dissolution in alcohol and addition of an
Card 1/2

USdI Organic Chemistry - Synthetic organic chemistry E-2
Abs Jour Referat Zhur - Khimiya, No 4, 1957, 11746
aqueous solution of K-perchlorate, I is separated; MP 2300 (from
aqueous alcohol). 0.37 g 1, 0-3 M17ethYl orthoformate and 3 ml pyri-
dine are boiled for 50 minutes, and by treatment with ether and abso-
lute alcohol there is obtained the perchlorate of bis-(I-m-nitrophenyl-
quinoline-2)-trimethyneyanin, with a yield of 42%, MP > 3000 (from al-
cohol) , '~ 613 m_,AA. By boiling for 55 minutes a mixture of 0.23
g methyl ioRh of 2- acetanilidovinYI-3,3-dimethylindolenin, 0.21
g I and 4 mi pyridine,'there is obtained the perchlorate of (1-m-nitro-
phenyl-quinoline-2)-(1,3,3-trizaethylindolenin-2)-trimethincyanin, yield
41%, MP 170-2201(decomposition, from alcohol.). By heating for 35 minu-
tes 0.23 g ethyl iodide of 2-1:!;) -acetanilidovinyl benzothiazole, 0.21
g I and 3 ml pyridine, there was obtained the perchlorate of (1-m-nitro-
phenylquinoline-2)-(3-ethyl benzothiazole-2)-trimethyncyarLih, yield 57%,
MP 228-2290 (decomposition). Heated for 50 minutes were 0.18 g 1, 0.14
g quinoline ethyl iodide and 4 ml alcoholic alkali; allowed to sl~and
for 16 hours and sepatate thereafter the perchlorate of (1-m-nitrophe-
nylquinoline-2)-(l-ethylquinoline-4)-wnomethyncyanin, yield 42%, MP
218-2200 (decomposition). Comminication V, see RZhKhim, 1956, 68353.
Card 2/2

BABIRMO. A.S.; %~MATNM, Z.Ta.
Hicrocrystalloscopic detection of the ferricyanide ion by means of
4*hydrooyquinaldinium chloroethylate. lzv.vya.ucheb.zav.; khim.i
khim tekh. 3 no.1:62-65 160. (MIRA 13:6)
1. Kafedra analiticheskoy khimii Kharlkovskogo politekhnicheskogo
instituta imeni M. Lenina.
(Forricranidea) Nainaldinium compounds)

CW,~;L)UIRGY b.M.; KRAYNES, L.Ya.; LOIIJKIIA, V.K.; GORYACHEV, N.I.,
inzh., nauchn. red.
(Assembling steel structures] Montazh stallnykii komtrukt9li.
Loningradp Goontroiizdat, 1963. 311 P. (MLtA 17:4)

BJ YINS. L.Ya., insh.
- I
Annembling precast reinforced concrete elements, Blul, tekh. inform.
4 no,3:12-15 Mr 158. (MIRA 11:3)
(leningrad-Precast concrete conetrnation)
OniMing machinery)

KRATNES, L.Ta inzh.; MYSHEV, V.P., inzh., MITROFANOV, Ye.N., kand. tekhn.
New methods for combined aaaembltng of prnstreened reinforced
concrete construction elements. Riul. tokh. Inform. po atroi.
5 no.5:14-17 M7 '59. (MIRA 12:8)
(Precast concrete construction)

KRATNEY.A.
Increase efforts to overcome industrially-caused interference.
Radio no.10:39 0155. (KW 9;1)
1. Kazakhakaya SSR Kurdayskiy rayon.
(Radio--Interference)

YAROVOY, L.V., dotsent; RUDNEV,M.M.; SHAIAX4AY124KO, V.A.; KABAKOVA, L.V.;
BENINSal, S.M.; ~PWNKV, L.G.
Clinical and epidemiological characterlatics of an outbreak of
Q fever in children. Pediatriia 42 no.5:73-76 My'63
1. Iz kliniki infektsAonnych bolnzn*y (zav. - dotsept L.V.
Yarovoy) Stavropollskogo meditsinskogo instituta, Stavropol'-
skogo protivochumnogo instituta i otdela osobo opasn-ych in-
fektsiy saniturno-epidemiologicheskoy atantaii Checheno-Ingush-
skoy ASSR.

Soviet-Durmesa trade and economic relation [with Xnglish summary
p. 41J. Vnash.torg. 27 no.3:7-12 '57. (MLRA 10:5)
(Burma--Foreign economic relations--Russia)
(Rusaia--yoreign economic relations--Burma)

KUYNXV. S. 1.
1. Cntnlase In unhemolyzed hUMAn blaod. Von.med.khim. 3:244-252 '51.
(MIRA 11:4)
1. Knfedra biokhimii Kubanakogo meditainskogo inatitutn, KrnanodAr.
(CATALASR) (BLOOD--ANALYSIS AND CHEMISTRY)

.M' fMPM5
USSR/Hematology FD-2438
Card 1/1 Pub 17-21/21
Author Kraynev, S.
Title Method for the rapid determination of blood catalase
Periodical Byul. eksp. biol. i med 39, 77-79, Jan 1955
Abstract The author describes a new method of rapid determination of blood
catalase. He shows ou a diagram and describes in detail the manner
inwhich the catalase activity of non-hemolyzed blood, hemolyzed
blood, and the over-all activity can be calculated, No references.
Graphs and diagrams illustrate the article.
Institution: Chair of Biochemistry (Head, Prof N. P. Pyatnitskiy), Kubansk Medi-
cal Institute (Director, Prof F. K. Chekhlatyy), Krasnodar
Submitted May 13, 1954

cytes
P by estdi.,4 acii,;ity a j4tcAL S. 1. kndrucv (KuLA11 Mcd.
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is Ivul'o,ol: '-10 mX-I'Afters of It ii JiM. by
of 21"a lzlf~~ 4;;4MW t,.~ c-'!0i (4 !!,-Axts rwitc. 'T'AL:1 w1m;.
k~s If U.8, 410.7, 04, 0,55, 0 5,,0 (VI. auff Lt.~ To t'lle
2
r At-l !1kc c,-1, I - -11 L N4 C.,
(CAct tk (111) kith till.. of 0~511;
RA irl OAGY vh'), .11 k, jlT;. A (p 117.0). Afta u Pe t (it'.
ju. VIC soht; i slcaesi 30 ttieu 5 till, of love, Ills(). 14
t(tmtttd with 4AN KWA. '01 difrtrctce ia We na, 'if
mi. of Klftto, into, mcd foc duation of t~wh scan. and Ehe
bUnk =10plicd by W c4u--czcrixc% I upre4zi-ed in of

YtW V ATNITSUT, Nikolay Petrovich; OVSHIUSKIY, H.U.,
~
t-! ~rOdUJA fkt6r! ~IHUC~HIUX Vlo YU.96, takhaichankty redaktor
t
[Practical work In organic chemistry] ?raktikum po orgenicheskot
khtmii. Moskva, Goseltd-vo modelit-ry, 1957. 93 P. (MLRA 10-10)
Whomistry, Organic-laboratory isanuals)

IRIYMI S.I.
Iffect of certain alcohols on the catnlaoe activity of hemolyzed
human blood [with summary in Inglish]. Vap.med.khim. 4 no.4:262-265
J1-1g 158. (HIRA 12:2)
1. Chair of Biochemistry of the Kuban Medical Institute, Krasnodar.
(ALOCHOIS, effects,
on catalase in hemolyzed blood (Rua))
(MOLYSIS,
catalame in hemolyzed blood, off. of alcohols (Ras))
(CATALASH, in blood,
hemolysed blood, off. of alcohols (Rue))

PYATNITSKIY, N.P.; O"ELYI)KOVA, M.N.
Catalase activity and osmotic reoistance of orythrocytes in preserved
human blood. PrOd. gemat. I perol. krovi 5 r-0- 509-44 My 160.
WIRA 14: 1)
(ERYTIntOCYTES) (CATAIASE) (BLOOD-COLL-ECTION AND PUZERVATION)

'___ KRAMEV 1 6 0 LI
Determining the catalase activity of h.emolyzed blood in I-second
and 15-second periods of reaction with hydrogen peroxide. TAb.
delo 8 no.2:13-18 F 162. (HIRk 15.2)
1. Kafedra biokhAmii (zav. - prof. N.P.Pyatnitakiy) KubELnskogo
meditsinskog instituta.
ZGATALASE) (HYWMEN Ft;4XIDI~)
(HJI40LYSIS AND MMOLYSIM)

KRAVEV, S.I.
Catalase activity of the blood in various gasseous media. Biokhimiia
27 no.4:589-594 Jl-Ag 162. (MIRA 15-11)
1. Chnir of Biochemistry, Kuban Medical Institute, Krasnodar.
(CATALASE) (BLOOD, GASES IN)

PYATNITSKIY, Nikolay Petrovich;
KRAVIE Y
lym h
_Y, Serge
N*,__N.D.', red,#. YEZHOVA, L.L., takhn. red.
(Laboratory manual on organic chemistry] Praktikum po
organieheskoi khimli. Izd,2,, parer, MOBkTa, Vysahaia
shkola, 1962. 173 p. (MIRA 16:7)
(Chemistry, Organic-Laboratory manuals)

X.q A Y,;.i- v Y- I
ITr,di Cicti V,-~-a 1,-,r o, ~-, R-1 Y' 1 rs, d A,,, j .- t , ~%, -;k. t,~ -- , nat." :r. :~ r
rEAt.lbis.3 ac-*~IVA,v ~1'~ q '- t f~ r':~ 7 i - ~ I C f, i, 3T, w I ' h '-. "'I ~ N' " ~, ,, 'r -,. . , d cl c
L,'? t. d P- I o rp.~ . L3 ! ~ j~o- : ,,, , -
, , I., 164 . t If -,. P"'. ?-t2)
~, Kllf#,(irii ' ~jj -, .,+ I ~ t., y~ , ~- I. - I I- ~!.~ . yw~ -i 1 t fl'c: v 1
!~tutanakcgc re i i , i ,i r,i, Y, ~ ,, 4ci 'A n F t I -, ~ t *. i ;. ' -, I (t i8 I ~( ~ , ~' " I

I , ; J : 7 v ; , , I - 1 1 h, G. E.
~ .1 , , .: -~. i ! i, V ;, S , 1 , o Kill AV
w I
i ' ' of the a~~ticn nf hydrogen sulfidn bathfi. Vop. kur. , ftzlotor.
I ,-h. fiz. k,111t. 29 n-3.4,,297-3i):j JI-Ag 164. -RA 18:9)
,t (M:
1. Fafodr& lblokhimil (zo-7. .- prof. N.P.PTatnltskly) hubanokogo
nio, j! initituta, I(ramodar.

KiWIM, YO.D.
Trannnortation of moles. Pr1roda III no.7:116-117 Jl '53. (HLRA 6:6 )
1. Ukrainskoye otdeleniye Voesoyuznogo nauchno-inaledovatel'skogo inetituta
okhotovedeniya. (Nolen (Animals))

--KELAUAY, Te.D. LKrainiev, IE.D.j
j%colimatization of molos in tho, Vnlilto-Anadoll Forest. Hat.pro
okhoro,pryrona Ukr, rio.2:92-93 160. (Mm 13:8)
(Ollinka District-Holes) (Forest fauna)

TOKER, N.I.; ABEND, L.K.; KRAYNEU, E.P.
Pborsicochemical investigation of asbestos from varimis
deposits. Nauche trucbr VNIIasbest n0-3:62-103 162.
(MIRA 16:11)

ii"". r - -- ~- -1 1 __ 11 -_ -
&M "pt
/0408/0408
ACCESSION NRI AR4015698 S/0081163/000/023
SOURCE: RZh. Khimiya, Abe# 23H247
AUTHOR: Toker, No I.; Abend, L. K.; Kraynevap F16 Ps
TITLE: Physico-chemical Investigation of asbestos of various origins
CITED SOURCE: Nauchn. tr. Voodo no-it in-t asbast. prota-sti, vy*p', 3, 1962,
62-103
TOPIC TAGS: asbestos
ABSTRACT: Results are presented of analyses of asbestos fiber of various origins
by the physico-chemical laboratory of the NIlAsbast (Asbestos Institute). The re-~
aults obtained can serve as reference material for certain physico-chemical con- j
stants for asbestos, and also facilitate the identification of the asbestos fiber
during the study of nev sources of asbestos. The methods of toontgeno-chomical
and thermal analysie are &lao described. H. So
DATE ACQs 09jan64 SUB COD33 MT- ENCL I W
Card 111

YELISEMA, A.M'., prof.; KRAYNEVA, I.I.
Intravenous drip administration of cardiac- in
cardiovascular insufficiency. Sov.med. 28 11 165.
1, W"dra feik-tilltookoy ternrli (,'.av. - prof. A.11-!.Yoltneveva)
lqanovskogo meditsinskogo in8t.ltuta (rektor - dotspnt Ya.M.
Romanov) na baze oblastnoy klinici-eskay bollni ',rj (gla-rnr
v-rach - zaaluzhennyy v-rach RSFSR A.A.Gheyda), F. Ivano-10.

GULfA'f-V, A.P.; UVaTEVAI Z."I"
Stool tempering in a clamping device, lzr. rys. ucheb. zav.;
chern, met, no.2.121; U3 160. ('ILIIVL 15:5)
1. Moskervskiy -,r,,-cberniy mashinostroitel'nyy institut.
(Steel-11cat treatment)
(Tomper.mg-Z-quipment wid supplies)

USSR/Physics - Piezoelectricity I July 53
"Piezoelectric Propertie,. of Solid Sclutions BaT'03 -
PbZrOP" G. A. Smolenskiy, A. 1. Agranovskaya
and V. V. Kraynik, Instlof Silicate Chemistry,
Acad Sci USSR
DAN SSSR, Vol 91, No 1, PP 55-58
Detd temp dependence of dielec permeability of
various compds and attempt to explain this de-
pendence. Results are presented In tables. In-
debted to Profs Yu. V. Morchevskly and F. N.
Smelova. Presented by Acad I. V. Grebenshchikov
(deceased), 3 Jun 52.
266T96*

SUBJEM USSR/Luminescence 118-3-19/26
AUTHORi Kraynik N.N.
TITLEt Investigation of Antiferroelectric Properties of Some Solid
Solutions Containing Lead Zirconate (Isaledovaniye antiseg-
netoelektricheskikh avoystv nekotorykh tverdykh rastvorov,
soderzhaahchikh tairkonat evintea)
PERIODICAL: Izvestiya, Akademii Nauk SSSR, Seriya fizicheskaya, 1957,Vol 21,
#3, pp 411-422 (USSR)
ABSTRACT: The author undertook an attempt to explain qualitatively the
changes of relative stability of ferroelectric and anti-
ferroelectric states in solid solutions containing lead zir-
conate and small amounts of another component. This expla-
nation is based on the consideration of electrostatical energy
of the crystallic latticel only changes of the ionic polari-
zability of central ions were taken into account.
The following samples were synthesizedt PbZrO 3 - CaZrO,,
PbZrO 3 - PbCeO 30 PbZrO 3 -CaZrO,, PbZrO 3 - .1/gZrO,, PbZrO3
Card PbThO,, and PbZrO 3 - ZnZrOV and their properties, such as

48-3-19/2b
TITLEs Investigation of Antiferroelectric Properties of Some Solid
Solutions Containing Lead Zirconate (Isoledoyaniye antiseg-
netoelektricheskikh avoyaty nekotorykh tyerdykh rastvorov,
oderxhashchikh tairkonat evintea)
:
emperature-dependenc* of dielectric permittivityq tg and
elative dilatationg and polarization dependence on
electric field intensities were studied.
On the basis of X-ray studies and special measurements, it
was concluded that solid solutions are not formed in the
following systems% PbZrO 3 - PbThO 30 PbZrO 3 - ZnZrO3and
PbZrO3 CdZrO 3 (synthesized by using preliminary calcinated
PbZrO3 Solid solutions are formed in the systems
PbZrO3 MgZrO 3 and PbZrO 3 - CdZrO3(aynthenized directly out
of oxides and carbonates) at very small contents of MgZrO 3
and CdZrO3 respectively.
In the system of PbZrO 3 - CaZrO 39 with the content of CaZrO
not exceeding 8 % (molecular), in the system of PbZrO 3 -
Card PbCeO3 and in the system of PbZrO 3 - CdZrO3 (synthesized

48-3-19/26
TITLEs Investigation of Antiferroslectric Properties of Some Solid
Solutions Containing Lead Zirconate (Iseledovaniye antisegne-
toelectricheskikh avoystv nekotorykh Vrerdykh rastvorov,
sodershashchikh tairkonat evintsa)
directly out of corresponding oxides and carbonates), two
phase transitions are observedt a low-temperature transition
which corresponds to the transition from an antiferroelectric
phase into an intermediate non-polar phase, and a high-tempera-
ture transition which corresponds to the transition into a
paraelectric state. The spontaneous negative striction of
volume corresponds to both of these phase transitions.
The third high-temperature phase transition was detected in
the system of PbZrO 3 -CaZrO 3' This transition occurs appa-
rently from a paraelectric state into another also para-
electric state.
In the system of PbZrO 3 -CaZrO 30 the spontaneous striction
of volume, which corresponds to a transition from the antifer-
roelectric phase into an intermediate non-polar phase, changes
the sign from negative to positive with the increase of
CaZrO3 concentration.
Card 3/4

48-3-ig/26
TITLEt Investigation of Antiferroelectric Pronerties of Some Solid
Solutions Containing Lead Zirconate (Iseledovaniye antiseg-
netoelectricheskikh avoystv nekotorykh tverdykh rastvorov,
soderzhashchikh tairkonat svintaa)
The article contains 9 figures and 1 table. The bibliography
lists 18 references, of which 5 are Slavic (Russian and I
Hungarian.
INSTITUTION: Institute of Semiconductors of the USSR Academy of Sciences
PRESENTED M
SUBMITTEDi No date indicated
AVAILABLEt At the Library of Congress.
Card 4/4

240)
AUTHOR: Kraynik, "If. N. S0';/46-22-12-21/33
TITLE: Anti,-Pi&,,-.ocloctric and Piezoelectric Properties of Some
Solid Solutions on the Basis of Sodium Niobate (Antisegneto- i
sognetoelektricheski.ye svoystva nakotorykh tverdykh rastvorov
na osnove niobata, natriya)
PERIODICAL: Izveatiya kkademii nauk SSSR. Seriya fizicheskaya, 1958,
Vol 22, Nr 12, PI) 1492-1496 (USSR)
ABSTRACT: In the present paper the following systems of solid
solutions were synthesized and their dielectric properties
- CaNb
were investigated: NaNbO
- LiNbO
0
9 NaNbO
2
2
6
3
3
3
NaNbO 3-, CaTiOY The samples of these solid solutions were
prepared according to the usual ceramic method from previously
synthesized single components. On the strength of the study
on solid solutions on tho NaNbO
- ba8is it may be concluded
3
that those solid solutions can be divided into 2 groups
depending- on their dielectric properties. Solid
- solutions
NaNbO3 +Y-NbO 3-P Pb11b 20 6-2 CdNb 206- and LiNbO
3
Card 1/., belong to the first group. With an increase of the content

A
Anti-Piezoelectric and Piezoelectric Properties of P,-2,;-1 2-21133
Some Solid Solutions on the Basis of Sodium r1iobato
of the second iomponent, piezoelectric pseudo-tetra;,onal
and ortho-rhombic phases are formed in them. Solid
NaNbO 3+NaTaO 3-P CaNb206- and CaTiO 3- solutions belong to the
second group. With a higher content of the second component
a new, apparently ferri-electric phase is formed in them.
However, it cannot be unequivocally determined according to
geometrical factors whether solid solutions belong to the one
or the other group. In solid NaNbO 3 +Pbllb2 06_' CdNb206- and
KNbO 3- solutiona the electron polarizability of the corner
ion increases with a higher content of the second component.
If it is assumed that the increase i-n the covalence degree
of the catIon -anion bond can increase:the dipolar moment in
sclid NaNbO 3-~-PbNb206-1 CdNb206-and LiNbO 3'_ solutions, an increase
of the dipolar moment (as compared to the central dipolar
moment) at the expense of the corner and oxygen ions as well as
in consequencs of the increase of the covalence degree of the
bond between the cornor ion and oxygen is to be expected. The
Card 2/3 formation of the piezoelectric component of the ion displacement

Anti-Piezoelectric and Piezoelectric Properties of SOV/,18-22-12-21/33
Some Solid Solutions on the Basis of Sodium Niobate
in the low-temperature phase of the solid NaHbO3+NaTaO 3-'
CaNb206- and CaTiO 3' solutions remaifia - urowx~10~inad ao,far~-2healt1w
thanks G. A. Smolenskiy for the interest displayed and
A, 1. Agranovskaya for ae3istance given in preparing the
samples. There are 4 figures and 10 references, 4 of which
are Soviet.
ASSOCIATION: Institut poluprovodnikov Akademii nauk SSSR ( Institute of
Semi-Conductors, Academy of Sciences, USSR)
Card 3/3

5-1 3 16 [5
AUTHORt Kraynik, N. U.
TITLEt Phase Transitions in Cortain Solid Solutions With Lead
'Zirconate (Fazovyye perekhody v nekotoryl:h tverdykh ra3t-
vorakh)qoaer,_,haohcMMi tdrkonat :jv~nt,,itt)
FERIODICAL3 "hurnal TekhnicheoVoy Fi~;iki , 1' 56, Vol - 2ti , ':r 5-5 35
(USSR)
ABSTRACTs "Llhe ;tuthors here produced of the follovring gyatems on
the basis of lead zilrconate in a synthetic way and investi..
,gated the temperature dependence of the dielectric constant,
of tg S , the relative extension and thle dependence of the
polarization on the electric field stren:~th of the samples.
1) In PbZrO 5" Pbllb206- and PbZrO 3- PbTa.06systems a. a con-
tent of PbNb,06 leso than and of PbTIL20 leis than 2 1%,
solid excharic'e.-solutions with a jubtracti0h Lattice form.
2) In solid PbZrO "Pbllb 0 and PbZrO PbTa 0, sclations a
3 2 6 3" 2 0
Card 1/4 Rochelle-.salt electric intermediate phase develops. In solid

57-28.-,;'--16/33
Phase Tranoitions in Certain Sofld Soluti on,,j W, tb Le;Ld Zir(:()rj"Ltc
11- -
PbZrO 3-11 PbSnO solutions a nonpolar, apparently antiseig-
ne tte-.elec trig, interviediate phase, analo,,,ou3 to the inter-
mediate phase in solid PbZrO JrZrO -solutions., f,)_-ms.
3) In solid PbZrO 3-11 PbSnO:; and Pb2rO -, SrZrO solutions
the third and the third afid fourth phah tranhtion,respec-
tively, were determined. On an increase in concentration of
the second component these are displaced into the domain of
higher temperatures. The nature -.)f these transitions can
either be explained by the fornation of new antiseignette-
-electric phases or by the as3umption that these transitions
are transitions between the different paraelectric phases.
4) In the temperature dependence of tj S in samples of
solid PbZrO _PbNb 0 6.. and PbZrO -11'bTa 0 solutions two maxi.-
2 1~w-t)' 2,6m
ma are observed immediately be 'e "e perature of the
transitions from the antiseignette-e1cctric into the seic-
nette-electric and from the rjeiGnette-electric into the para-
electic phase. 5) In the temperature dependence of tg of
the samples of solid PbZrO 3-"PbSnO "-, and PbZrO3-SrZrO
solutions two "jumps were observed im:::ediately below ilia
temperature of the first and the second phase transition.
6) On the basis of the neutronographic and radiographic in.
Card 2/4 veatigation of PbZrO 3 (Referunc-e 16) the concludon is drawn

57-281-3-16/33
Phase Transitions in Certain Solid Solutions With Lead Zirconate
that in PbZrO at room temperature two different systems of
partially homhpolar linkages between the lead and oxygen
ions exists. The followin- values of the sbortest distances
between the lead and oxy,gen ions correspcrid to the first
system of the linka,geu'2 58, 2,58., 2,53 X, In the second
systemi 2,59, 2,50, 2,26 i. 7) The asou%iption ii expressed
that the occurrence of twu near but different systems of
partially homeopolar linkages between the lead and oxyLren
ions in PbZrO is one of the causes for the 3mull 0gradient
of the free ehrgiea in different phasefi near 230 C.
8) It is asjumed that in apite of the important part played
by the nature of the linkages between the iors the mutual
orientation of the dipole moments in the antiseir-nette-elec-
tric substances as well as in -,he aeii-nette-electric substan-
ces is first of all determined by the forces of the electro-
static interaction. 9) In connect.-on with that the attempt
is made qualitatively to explain the modification of the re-
lative stability of the spignette--electric and antiseignette-
Card 3/4 -electric phases also in solid PbZrO 3- PbN'b206-; PbZrO 3-

57-291-3-16/33
Pha3e Transitions in Certain Solid Solutions With Le'arl Zirconate
,-PbTa'O6.. an(] l1bZrO from the point of
view Of the electrohatic e?er6y of the ory,,ital lattice.
The results of the work were diacuosed with G. A, Smolenskiy,
Profesoor. There are 11 fi~;ures, iind 21 reforenceo, S of
which are Soviet.
ASSOCIATION; Inst4tut paluprovodnikov All SSSR
', Leningrad
(Leningrad Institute for Semiconductor3 AS )USSR)
SUBMITTED: Jul., 25, 1957
1. Lead zirconate compourds--Phase studies 2. Lead zirconate
compounds--.Dielectric properties "'. Dielectric p-ropertles
f actors 4. LRad z~--conatf-, co,-,rpo-,~_-~' s---lo ix,' zat ion
5. Polar--, -ittion--Flectrical factors
Card 4/4

AUTHOR: Kraynik, N. 11.
57_28-3--17/33
TITLEi Phase Transitions in Solid ~;L)Iut-lons of Calcium Hafnate in
Lead Hafnate (Fazovyye perekhody v tverdykh rastvorakh Saf-
nata kaftsiya v gafnate svintua)
PERIODICAL: Zhurnal Takhnicheakoy Fiziki, 1958, Vc,1.28, Nr 3, PP-536-5-138
( TTgqv )
ABSTRACT: In Reference 1, it wau reported an the anomalous properties
nzi-jples of the
of lead hafnate. 1) Here polycryatal 14 rn
PbHfO - WIN -,system with a CaHfO -content of 0, 5, 10 and
15 moLr ~ were produced in a EqntLtic way. The temperature
dependence of the dielectric constants P_ and of tg j were
investigated. It was found that in these solid solutions be-.
side the 2 phase tranalti.ons(observed in purc PbHf0 ) bet-
ween two different anti seignette. elec tric itates an~ the
antiseignette-electric and paraseiGnette.-,ele.-tric state a
third and fourth phase transiticn also exists. It is shown
Card 1/3 that the temperaturomof the first and sacoi-4 transition de-

57-28-3--17/33
Phase Transitions in Solid Solution3 of Calcium Hafria-te in Lead 7afnate
H
crease w1th the increase it-, CalffO -content in the solution.
whereas the temperatures of the t1rd and fourth transition
increase. .. It ic shown that below the temperatures of the
first and second transition -iaxi:la Of ta J' are observed.
lit the temperaturtncorr(.,31)oild-i~it; ":,, thL third and fourth
phase transition no anomalic-o in the temperature dependence
of t6:, LT were observed. The temperature dependence of
tg 6 in Ca..", samples is analogous to that of the solid
Pb(Zr 0 Sn )0 '-solution (Referenze 4). On the basis of
the dideoMic gemurements and acc'ordin- to the analogy
with the PbZrO ..CaZrO "system it can be concluded that in
the interval o? the c9ncentrations investigated here (from
0 to 15 molar ~) in the PbHfO - Callfo "system solid solu-
tions are formed. - The nature of the hird and fourth
phase transition can either be explained by the development
of new antiseiUnette--electric phases or by the formation
of paraelectris, pha3es with a structure of the perovskite..
I type distorted at the expense of thQ small calc' um-ion-di-
1:1C ":~ I -~',_' Cal!fO possesses, as is ,,;ell known, a distorted
struct4r~- :' th~ perovskite type with orth-orhombic 5yr,,.metr:f
(Referenoe 5). There are 4 fiat'req and " referen~~es., 3 of
Card 2/3 which are Soviet.

57-?8-3-17/33
Pbase Transitions in Solid Solutions of Calcium 11afnate in Lead Hafnate
ASSOCIATIONi Institut poluprovodnikov All SSSROLeningrad
(Leninerad Institute for Semiconductor3>AS USSR)
SUBMITTEDs July 27, 1957
1. Calcium hafnate-lead hafnate--Phase studies 2. Cqlcium hafnate
-lead hafnate--Dielectric properties 3. Dielectric properties
--Temperature factors 4. Phase transitions--Ana4sis
Card 3/3

KRAYNIK, N. N., Gand Phys-Math 6ci -- (diss) "Ar-tiseigriettoelectrical
properties of some solids solutions of the perovskite type structure."
LeninFrad, 1960. 15 PP; (Ministry of Higher and Secondary 6pecialist
Education W-'FSR, Leningrad Polytechnic Inf,,t il[L IN- l- ~',alinin); 150 coP-
ies; vrice riot (~iveri; VL, 52-60, 118)

S/18 60/002/01/17/035
B008XB014
0
AUTHORS: KraZnik, N. N.p Agranovskaya, A. I.
TITLE-. Antipiezoelectric and Piezoelectric Properties of Some
Solid Solutions Containing Pb 2MgWO6
PERIODICALs Fizika tverdogo tela, 1960, Val. 2, No, 1, pp. 70-72
TEXT: The authors synthesized samples of PbMg 112W11203and some solid
solutions in the systems PbMg, /2W 1/203_PbT103 and PbMgj/2W1/20 3-
PbMg 1/3 lb 2/3'3 and studied their dielectric properties. The synthesis was
carried out according to the usual ceramic technology, but the final
annealing was perfgrmed in PbO vapors. The X-ray phase analysis of nu-
merous samples of the system PbMg, /2W1/203-PbTiO 3has shown that these
samples have a perovskite structure. There was no sign of a second phase.
Fig. 1 shows the temperature dependence of F_ of a number of solid
solutions of the last-mentioned system, which was measured at 1000 cps.
Samples with less than 1e. of PbTiO,0 which were located in fields of up
Card 1/3 t

Antipiozooler~ric and Piezoelectric Properties S/181/60/002/01/17/035
of Some Solid Solutions Containing Pb 2MgWO6 B000014
to 20 ev/om, showed no hysteresis, whereas hysteresis loops below the
temperature of the E-maximum, were observed in samples having more than
10% of PbTiO 3* These hysteresis loops vanished, however, as soon as the
temperature exceeded this point. Thus, the piezoelectric phase is formed
within the concentration range of - 10% PbTiO 30 the temperatures of the
E-maxima corresponding to the Curie points. When the content of PbTiO 3
is raised up to 10%, the Curio temperature drops considerably (Fig. 2).
When the content of PbTiO 3 is further increased, the Curie temperature
starts rising. It passes through a minimum also in the system
PbMg, /2T'1/2 03_PbMg1/3 Nb 2/303' Samples with less than 2 of PbMg, /3 Nb 2/303
showed no hysteresis loops. Above 20%, there are so-called "double"
hysteresis loops. This confirms the assumption that PbMg, 12W1120 3 is an
antipiezoelectric material. On the strength of the experiments carried
out, it may be classified as an extremely "hard" antipiezoelectric
Card 2/3

Antipiezoelectric and Piezoelectric Properties S/181/60/002/01/17/035
of Some Solid Solutions Containing Pb 2MgWO 6 B008/BO14
material. In spite of the similarity of the structure factors which were
calculated with the aid of ionic radii, the compound PbMg 1/2W1/203 is
an antipiezoeleotric material and PbMg 1 /3Nb 2/303 Is a piezoelectric. The
parameters of the elementary cells of these compounds show great dif-
ferences. The authors thank Professor G. A. Smolenskiy for discussing
the results obtained here. There are 2 figures and 5 references, 4 of
which are Soviet.
ASSOCIATIONt Institut poluprovodnikov AN SSSR, Leningrad (Institute of
Semiconductors, AS USSR, Leningrad)
SUBMITTED: May 11, 1959
Card 3/3

-
Antiesignetto and saignettoelectric properties of NaNb -.PbZrO3
of solid solutions. Fiz. tvar. tela 2 no.4:685-690 Ap ~10.
(MIRA 13:10)
1. Institut poluprovodnikov AN SSSR, Leningrad.
(Sodium niobate--Blectric properties)
(Lead zirconate--Zlectric properties)

K-RAYNX, N.H.
Comparison of Internal fields In some saignattoelectric and anti-
Beignettoelectric structures of the perovskits type. Fiz. tvar.
tela 2 no.5:993-996 My 160. (MIRA13:10)
1. Inetitut poluprovodnikov AN SSSB, Leningrad.
(Crystal lattice)

8 645 2
S/181/60/002/011/042/042
(also //47-) B006/BO60
AUTHORSt Smolenskiy, G. A., 1supov, V. A., Agranovskaya, A. T.,
and Krarnik, N. N.
V%a
TITLE. New Ferroelectrics of a Complicated Composition. IV
PERIODICALt Fizika tverdogo tela, 1960, Vol. 2, No, I", pp. 2982-2985
TEXT% This is a report on the discovory of now perovskite-t e Te rro-
electrics, which may be described by the empirical formulas YrBi 0- 5Na 0 5~'03
and [Bi 0-5K0.51 TiO 3' The Curie temps.,rfiturea of these compounds are 3206
and 3600C, respectively. The compounds were prepared by mixing the initial
substances Bi 2059 TiO 2'K2CO 3Y and Ha2CO3 in a stoichlometric ratiol and
by sintering them in the air at 1120 1140 (Bi-11a) arid 10600C (Bi-K) for
an half an hour to twc, hoora.. Tfu? p(arov,.,Aite ntructure of the compoundz
tlius obtained was (,,,j tabl ij tied by X-rays,. The parametero of the elementary
cells of the two ~ompotinds were fotjnd to be a -- 5.88 and 5 94 A,
respectively. In the said compounds, Ittio authors determined E, tans
Card 1/3

86452
New Ferroelectrics of Ft Complicate,l
Composition. IV
S/1 F3 60/002/011/042/042
Wo6XBo6o
the relative longitudinal expanalon 61/1 and the coofficlenf, of linear
oxpaxisionD~ as temperature functIOTIS, Results are shown in Figs. 1 and
2, A study of polarization revealed that aodium bismuth titanate has a
well-shaped almost rectangular hystereois loop, whereas that of potassium
bismuth titanate is far from saturation. The first mentioned compound has
at 1160C a spontaneous polarization of f3.,O/Acrul/cm2 and a coercive force
of 14 kv/cm. It was further estabiishi-,d that also Na Bi,.5]ZrO,
1 1 0~5
and LK 0.5 BiO.9]ZrOj havf; a perov:3k."*tt_~ -type cry;3tallization, There are 2
figures and 16 reforences- 15 Soviet, 1 US, and 2 British.
ASSOCIATION: Institut pr)1uprov,)dtiik0v AN SSSR, Lenin,,;rnd (institute of
Seinicondiic.tors of thv~ AS USSR, Len-ingraki)
SUBMITTED: June 30, 1960
Card 213

86452
5/131/60/002/011/042/0421
LeGend-to FiCs. I and 2: 1) at 500 kc, 2) --1/1, 3) - 4 'tin tit .1 '?,c.
!gl .10
MCI 03
fooo of I?i
0 0-
Card 3/3
M10 230 10
Vo 0 j
a 'ICU :106 100 OGO JOU t.*t
loo ZOO illo 4c0 t.

84995
S/04 60/024/010/004/033
B01 3YBo63
AUTHOR. Kraynik, N.-N.
TITLE: Internal Fields Acting in Some Piezoelectric and Anti-
piezoelectric Model Structures on the Basis of BaTiO
PERIODICAL: Izvestiya Akademii nauk SSSR. Seriya fizicheskaya, 1960,
Vol. 24, No. 10, pp. 11937 - 1190
TEXT: The author calculated the coefficients contained in the formulas
for internal fields in an antipiezoelectric structure (Fig.1) and com-
pared them with the corresponding coefficients of a piezoelectric struc-
ture of the BaTiO3 type. Spontaneous polarization is effected by the
ions in the corners of the unit cell ions A and the oxygen ions 0 111
(Fig.2). The fields acting on the ions B, Oid and 0 11 are equal to zero.
The fields were calculated from the polarizability of the ions and from
the volume of the unit cell by using Kinase's method (Ref-4). The re-
sults of the comparison of the corresponding quantities y,j for
Card 1/4

84995
Internal Fields Acting in Some Piezoelectric S/04 60/024/010/004/033
and Antipiezoelectric Model. Structures on B013YB063
the Basis of BaTiO3
piezoelectric and antipiezoelectric structures are collected in a Table,
a variation of the polarizability of oxygen and of the volume of the
unit cell being taken into account. The Table indicates that the rela-
tive stability of the corresponding antipiezoelectric structure, as com-
pared to the piezoelectric structure, increases with a decrease of the
polarizability of oxygen and with an increase of the volume of the unit
cell. These results are in qualitative agreement with Refs. 1 and 3.
Thus, the comparison of the relative stability of three different anti-
piezoelectric structures with the piezoelectric structure of the BaTiO 3
type, estimated from the magnitude of the internal fields, has shown an
equal dependence of thesethree structures on the polarizability of oxygen
and on the volume of the unit cell. The author believes that the polari-
zability of oxygen is determined, first of all, on the conditions of
ion packing in the octahedron, and depends on the interval B - 0 rather
than on A - 0. Next, the author discusses the problem of the length of
the oxygen radius which was estimated from the interval B - 0. He sup-
poses that the oxygen ions are compressible, whereas the radii of
Card 2/4

84995
Internal Fields Acting in, Some Piezoelectric 8/048/60/024/010/004/033
and Antipiizooleotrio Model Struotures on B013/BO63
the Basis (f BaTiO
3
B-cgtions (to not vary and agree with the tabulrr values. It'may be as-
aumed that~the polarizability of oxygen decreases with a reduction of
the radiualof oxygen ions. It may be seen from a compariaon'between the
internalft lde that the etability of the aptipiezoeloctric state is thus'
increased n comparison to the piezoelectric state. This assumption
might help.to explain the fact that the antipiezoelectric state in crys-,
tale of. th~ perovskite type appears with t