SCIENTIFIC ABSTRACT KOZLOV, V.S. - KOZLOV, V.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000825910005-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: July 31, 2000
• Sequence Number: 5
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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MIXH, Takov Moisayevich, kand.ekonom.nauk; KOZIoOT. Vladimir Sergeyevich,
kand.ekonom.naule; GOLIJIBERG. Abram Mikhaylovich, Btarshiy prepo-
davatell; PRIVkUHTSWA, A.G., red.; PTATAKOYA, N.D., takhn.red.
LStatistical atudy of labor productivity in industry; based on
materials of the Odessa Economic Council] Statisticheskoe
izuchenle proizvoditellnosti truda v promyBhlennoBti; po Mats-
rialam predpriiatii Odesskogo sovnarkhoza. Moskva, Gos.stat.
izd-vo, 59. 129 p. (KIRA 13:2)
70deses Province--Productivity accounting)

-1 K940Y, V.S., dotaent; ZAKTAROV, F.M.
Methods for eliminating sterility In cows on a state farm. Vaterinarila
40 no.5:43-44 My '63, (MIRA 1731)
1. Alma,-Atinskiy zooveterinarnyy in3titut (for Kazlov). 2. Glavnyy
vaterinarnyy vrach sovkhoza, "Aksay". Alma-Atinskoy oblasti. (for Zakha-
rov).

DENISOV, L.A.j KOZLOVt V.S.
Determining the magnetization force necessary, for magneto-
graphic control. Stroi. truboprov, 8 no.-9:19-20 'S 163.
(MM 16: 11)
1. Gosudarstvennyy montazhnyy trest Glavsantekhmontazha
Ministerstva stroitellstva SSSR, Minsk.

DOLGUSHEVSKIY, F.G., dote.; JMZIDV,--v_S_,-dots.; PANCHENKO, V.P., as-
sistent; POLUSHIN, P.I., starshiy prepodavatell; POSTNIKOVA,
G.V., kand. ekon. naukj EPJ,IKH, Ya.M., dots.; SHENTSIS, Ye.M.,
red.; ILIIUSEENKOVA, T.P., tekhn. red.
(Statistical study of labor productivity and the uncovering of
its potentials in agriculture]Nekotoi-ye voprosy statistichaskogo
izucheniia i vyiavleniia rezervov proizvoditellnosti truda v sell-
skom khoziaistve. [By]F.G.Dolgushevoki4i i dr. Moskva,, Gosstat-
izdat, 1962. 189 p. (MIRA 16:1)
1. Prepodavateli Cdesskogo kreditno-ekonomicheskogo institute.
(for all except Shentsis, Illyushenkova).
(Odessa Province-Agriculture-Labor productivity)

DOLGUSHEVSKIY, F.G., dots.; GOLIDBERG, A.M., dots.; XOZLOV. V,
dots.; PANCHENKO, V.P., assistent; POLUSHIN, P.I., at.
prepod.; ERLIKH, Ya.M., dots.; TRUKHANOVA, A.N., red.;
ILIYUSHENKOVA, T.P., tekhn. red.
[Problems in economic statistics] Sbornik zadach po ekono-
micheskoi statistike. (By] F.G.Dolgushevskii i dr. Moskva,
Gosstatizdat, 1963. 311 p. (MIRA 16:9)
(Statistics-'-Problems, exercises, etc.)

DENISOV$ L.S., inzh.1-KOZLOV V.S inzh.
01~ecking the quality of welding in the construction of municipal
gad'lines in the White Russian S.S.R. Stroi. trub?provo 8 no.ls
20-21 Ja 163. (MIRA 160)
1. Treat No.24 Goaudarstvannogo montazhnogo treata, Glaveantakhmontaaha
MiniBterstva stroitel'stva SSSR, Minsk.
(White Russia--Gas pipes-Welding)
(Ga=a i i-Industrial, applications)

PAVLOV, I.M.; BELOSE91CH,, V.K.; Prininali uchastiye: WHAKOV, W.V., inzh.;
KO
~ ;4P, V.S., 3Aborant
Investigating the relationBhip between the friotion coefficient and
speed and pressure on a special unit. Trudy Inst.met. no.9:139-146
162. OMU 16:5)
(Friction)

KOZLOV, V.S.
Now 5th series transformer stations of the State Institute for the
Design and Planning of Electric Power Systems. Prom. energ. lF no.7:
14-45 Jl '63. (MIRA 16:9)
1. Kazgiprotsvetmet.
(Electric substations)

KOZLOV, Vasiliy 5ergeyevich; DOfJRONLVSKIY, Ye.D., nauchn. r,~d.
(Black and white electron-beam tubes and externa_1
auxiliary devices] Cherno--belye elektronrio:Luchevye trub-
ki i vneshnie vapomogatellnye ustroistva. Moskva, TSenti
nauchno-issl. in-t patentnol informatsi! i tokhniko-ekon.
1881.J1 1964. 40 P. (1,11U. 18: 1)
.1

-- KOZLOVP V.S. (Minsk)
Increasing the reliability of the MD-11 defectoscope. Stroi.
truboprov. 10 no.2129 F 165, (MIRA 1815)

~-O~z (go ahimkont)
A Atplifted moth6d tf d6termining the maximm power oonsumption of
agrIcultural owitimeiij, triergigtik 13 llo,8:17-18 Ag 165. (141RA AM

DENISOV, T.S.q In'Ais- y ~ -- -, -k-
, ~' -2 -- .
rl-!
c ':, ~:, i .: , r! -. -i. - -;-z r. prr. * zv.
me~hcd o" - r ~ t,,- - 7 1 i r! v ~-; ~.,
1. -L - ~ I -
n,).7:1 -~,-18 E. t65-

KOZLOV, V-Sh., inzh.
Precaot reinforced concrete sectional girdere. Prom. strol. i
inzh. soor. l,no.1:29-32 0 '59. (MIRA 13:12)
1 (GL-dere)

GUTW, G.I., inzh.; KOZIOV, V.Sh.. inzh.-. SYTIJIK, V.I.. inzh.
Open standard crane trestles. Prom.otrol. 38 no.1:25-27
16o. (14IRA 13:5)
(Cranes, derrickop otc.)
(Trestles)

KOZLOV V.Sh.; SVESIINIKOV,, G.V.
Uperimental construction of &baiMing from machine-cast
elements. Prom.stroi. 39 no.805-40 'Ca. (MIRA 14&9)
(Kiev-Precast concrete construction)

LIBrRMAN, A.D., kand.tekhn.nauk; KOZLOV, V-Sh., inz~.; SVESHNIKOV, G.V.,
inzh.
Design and construction of a mechanically assembled building for an
automatic macbine-too3 plant. Prom. stroi. 39 no.10:42-47 0
161. (MIIIA 14: 10)
1. Nauchno-issledovatel.'skiy institut stroitellnykll. konstruktsil
Akademii stroitel'stva i arkbitektury USSR (for liberman).
2. Kiyevskiy Promstroyproyekt (for Koziov). 3. Kiyevskiy sovnar-
khoz Zfor Sveshnikov) '
(Kiev--Precast concrete construction)

-KOZLOV, Vladimir Shalavinh; DYKIiOVICHNYY, Aleksandr Aleksandrovich;
GORCH&R, A.S., red.; BERGER, K.V., red.; YEREMINA, I.A.,
tekhn. red-. I
[Deoign of reinforced-conarete elemental mechanical methodal
Raschet zhelezobetonnykh konstruktaii; mekhanizirovannye me-
tody. Kiev, Goaatroiizdat USSR, 1963. 493 P. (MIRA 16:4)
(Calculating machinea) (Precaat concrete)

DENISOV, L.S.; KOZLOV, V.S.
Possibilities for uoing puloe maGnetization in magaitopaphic
control of city gas mains. Stroi. truboprov. 0, no.5:23-26 Hy
164. (Muk 17:9)
1. Trest No.24 Santaklmontazli, Uin:-)k..

KORSHUNOV, D.A., inzh.; KOZLOV, V.Sh., inzh.
Standard elements for precast monolithAc short shells. Stroi.
kon.qtr. no.20-14 165, (MIRA 18: 32)
1. Nauchno-lssledovatell3kiy institut stroitelinykh konstruktoiy
SSSR, Kiyev (for Korahunov). 2. Kiye7skly Gosudarstvennyy
proyektnyy Institut ro obshchestroiteltnomu i sanitarno-
tekhnicheakomu proyektirovaniyu prim7shlennykh predpriyatiy
Gasstroya SSSR (for Kozlov).

~OZIIOV,.V.Sh., inzh.; SA14OLETOV, M.V., inzh.; KfIAPITONOV, I.G., inzh.;
KORSHUNOV, D.A., kand. tekJm. nauk
Standardization of open c,antry cranes. Prom. strol. 42 no.6:
20-23 165. (MIRA 18:12)
1. Kiyevskiy gosudars-Lvennyy proyektnyy institut po obshchesI.roi-
tellnomu i sanitarno-tekhnicheskomu proyektirovaniyy promyshlennyk1-
predpriyatiy Goss-troya SSSR (for all except Korshunov). 2. Nauchno..
issledovatellskiy institut stroitelInykh konstruktaly Gosstroya SSSR
(for Korshunov).

124-57-1-1077
Translation from: Referativnyy zhurnal, Mekhanika, 1957, Nr 1, p 150 (USSR)
AUTHOR: Kozlov, V. T.
TITLE: Torsion of Compound Beams Made of Rolled Angle Irons
(Krucheniye sostavnykh sterzhney iz prokatnykh ugolkov) -
PERIODICAL: Nauch. zap, Odessk. potitekhn. in-ta, 1956, Vol 9, pp 105-110
ABSTRACT: Bibliographic entry
1, Beams-Stresses-Bibliography
Card 1/1

K r-, Z 1 6-1 / V.-F
AUNORS: Koz1ov, V. T., and Dorogostayskiy, Z. E.
TITLE: Instrument for Determining Transverse Deformation of Rod
Specimens (Pribor dlya opredeleniya poperechnoy deformatsii
sterzhnevykh obraztsov)
PERIODICAL: Zavodskaya Laboratcriya, 1957, Vol. 23, No. 1, pp. 103-104
ABSTRACT: The article describes an instrument proposed by Prof. A. P.
Korobav for determining the transverse deformation where a rod
is either stretched or compressed longitudinally. It is
based on the application of a transmitting, double-knee
lever device clamped on the piece that is being tested.
A dial indicator is included in the circuit of the instru-
ment. A diagram showing the principle of the instrument is
presented. The instrument is of simple construction, port-
able and reliable in its functioning.
ASSOCIATION: Odessa Polytechnical Institute (Odesskiy politekhnicheskiy
institut)
PRESENTED BY:
Card 1/2

Instrument for Determining Transverse
Deformation of Rod Specimens
SUBMITTED:
AVAILAEU:
Card 2/2

--KOZLOV. V.T.,---
Experimental investigation of deformations of noncircular rods
Bubjected t45 free and hindered torsion. Nauch.zap.0d.politekh.inst.14:
C5-95 t59. (MIRA 14:3)
(Elastic rods and wires)

L 43o8o-.66 EWP(k)/EWT(ml//T/EW-?(w)/EWP(-.)/ETI IJP(c') jD/-iW
ACC hIR: AR6014374 (P'A SOURCE CODE: UR/0l37A5/0OO/0ll/D0O5/DOO5
AUTHORS; Kozlov, V. T.;...KY-sochin, V. D. -111-3i
11
TITIE: ImprovemGnt of fatigue properties of wire cable by means of elastic-
plastic elongation
SOURCE: Ref. zh. 14~tallurgiya, Abs. 1ID30
REF SOURCE: Sb. Stalln. kanaty. Vyp. 2. Kiyov, Tekhnika, 1965, 425-427
TOPIC TAGS: wire, wire product.. fatigue strongth,QA0
ABSTRACT: Results of investigations show that elastic-plastic elongation changes
tho character of the distribution of residual tensions. The fatigue properties
of w:L-e cables are notably improved by the proper choice of drawing technology
and elongation stresses. 3 illustrations., 2 tables. L. Kochenova LTransliltion
of abstrac3t
Card 1 qj UDC: 621.771.001.

1 912-0
// =1o
AUTHORS:
TITLE:
66295
ZZ051 lLto3,1136 s/igo/60/002/Ooa/007/017
B004/BO54
Tarasova, Z. N., Kaplunov, M. Ya., Kozlov, V. T.,
Klauzen. N. A., Dogadkin. B. A.
Interaction of Sulfur With Natural Rubber Under the Action
of Ionizing Radiation
PERIODICAL.: Vysokomolekulyarnyye soyedineniya, 1960, Vol. 2, No. 8,
pp. 1201-1206
TEXT: The authors study the problem of production of radiation-resisting
rubbers, the conditions for a common vulcanization of irradiated and
sulfurated rubbers, and the modification of rubbers treated with radiation.
The present paper gives the first informative results of investigation of
the effect of radiation by Covjon rubber in the presence of sulfur. A
considerable sulfur addition occurred at 25 OC, and was accelerated by an
increase in the radiation dose and temperature, Particularly by addition
of hexane chloro ethane. In thermal vulcanizationt the admixture of chloro
derivatives showed no effect on sulfur addition. The presence of sulfur
delays the structuration as compared with rubber without sulfur admixture.
Card 1/3

96295
Interaction of Sulfur With Natural Rubber Under S/190/60/002/008/007/017
the Action of Ionizing Radiation B000054
But structuration increases also here between -800C and +1000C with increas-
ing temperature. Pure rubber showed at 500C a reversion of the structura-
tion process, which was not observed in the presence of sulfur in the tem-
perature range investigated. A study of the infrared spectra in argon of
irradiated rubbers with and without sulfur showed a decrease in intensity
of the 840 cm-1 band due to a reduced degree of nonsaturation. This effect
was more intense in the presence of sulfur. The decrease in intensity of
the 2940 and 1450 cm-1 bands due to a reduced number of CH 2 groups or ring
v
formation was, however, more intense0in the presence of sulfur. An in esti
gation of the sulfur exchange at 120 C in Irradiated rubber tagged wish
radioactive sulfur, carried out by a method described in Ref. 7, showed
that about 40~6 of sulfur is exchangeable. This amount does not depend on
the radiation dose (up to 100 megaroentgens). The high degree of exchange-
ability is ascribed to a formation of polysulfide groups. Sulfurous rub-
bers with addition of hexachloro ethane showed, on irradiation with 20
megaroentgens, maximum values of tensile strength (about 130 kg/cm2) aq
of elongation. When irradiating pure rubber, a maximum (about 100 kg/cm~f)
is only attained at 50-70 megaroentgens. Sulfurous irradiated vulcanizates
showed a faster stress relaxation than irradiated vulcanizates free from
Card 2/3

86295'
Interaction of Sulfur With Natural Rubber Under S/190/60/002/008/007/017
the Action of Ionizing Radiation B004/BO54
sulfur. The authors assume that sulfur addition leads to a more homogeneous
and regular structure since secondary reactions causing chain ramification
are inhibited. There are 7 figures and 7 references: 3 Soviet, 3 US, and
I British.
ASSOCIATION:
Nauchno-issledovatel'skiy institut shinnoy promyshlennosti
(scientific Research Institute of the Tire Industry)
SUBMITTED: March 24, 1960
Card 3/3

S/844/62/000/000/095/129
D204/D307
AUTHORS: Dogadkin, B. A., Tarasova, Z. No, Kaplunov, M. Ya.,.Koz-
lov, V. To, Klauzen, I. A. and Matveyev, V. So
TITLE: The interactions of sulfur with polym6ra under the action
or irradiation
SOURCE: Trudy II Vsesoyuznogo soveshchanly"a po radiatsionnoy khi-!
mii. Ed. by L. So Polak. Mosc'ow, Izd-vo AN SSSR$ 1962,
554-562
TEXT: The interactions of S with natural-rubber, 1,4-cis-polybu-
tadiene, butadiene-styrene and butyl rubber was studied, under ir-
radiation from a Co 60 source. S added bn to natural rubber at.25 - ~/
10000 and to butadiene-styrene rubber and polyethylene at 250C, un-
der argon, in amounts increasing with the dose (0 - 120 Mr), the
rate of addition being faster at higher temperatures. At room tem-
perature the amount of 6 added on is independent of the initial S-
content in the starting mixture (1 - 10% by weight). The addition
Card 1/3 : t-, I

S/844/, 62/000/000/095/129
The interactions of ... D204/ 307
was promoted by C Cl The presence of 8 hindered the development
2 6' 1
of structurization, which.~-;au, however, promoted by raising the
temperature from -80 to 1609C. Pure natural~ru'bber developed cross-
linking only up to -5L)oCq :above which temperature the process was
reversed; this reversal wqs, not observed in,the presence. of 2cv' S,
i1 (SKS-30AM) bu-
up to 10000. The pre~;ence :.of 1 - 45' S inr
tadiene-styrene rubber led only to a slight reduction in the de-
gree of cross-linking on irradiation. The loss of unsaturation and
_CH 2- groups on irradiAtion was studied (by ir ~;jectroscopy) on
natural rubber both in ~he presence and aboence of 8, and was found
to be greater in the latter case. The ~~ adds on in a form capable
of isotopic exchange with elemental sulfur. Initially 70ri of th&
C~
added sulfur may be exchanged in natural cand butadiene-styrend
rubbers; this value falls with irradiation to a constant 40% at
50 - 120 Mr. Radiational vulcanizates of.natural rubber exhibit in-
creased tensile strength when the polymer contains 2% S, particu-
larly at 10000; in general', the strength increases with the dose
-of irradiation. The best strengths were obtained for a mixture of
Card 2/3

The interactions of ...
S/844/62/000/000/095/129
D204/D307
natural rubber, S, and C 016 The sulfur is believed to interact
with the polymeric radic3le ~formed on irradiation by C-C fission)
to form polysulfides which (a) lower the thermomechanical stabili-
ty, and (b) prevent recombination reactions and reactions of radi-
cale formed with C=C, thus hindering the development of branched
structures. There are 12 figures.
ASSOCIATION: NII shinnoy promyshlennost'i
dustry)
(NII of the Tire In-
--Card 3/3

S/1~0/62/004/0108/01o/o16
B101/B180
AUTHORS: Tarasova, Z. N., Fogellson, IM.
Kashlinskiy, A. I., Kaplunov, M. Ya., Dogadkin, B. A.
TITLE: Ep3~ study of the radiation vulcanization of rubber in the
preeez)ce of sulfur and hexachlor ethane
?F,RIODIC.%L; Vysokomolekuly~arnyye soyedineniyaj v. 4, no. 8, 19621
1204-1209
TEXT: Records 'd epr spectra were used to study the formation of free
radicals during the radiation polymerization of natural rubber (11R) and
mixtures of INR with 2wt.V.' sulfur or iowt.-~ C,Cl,,.
/0 Zrradiation was,
0 6o I .
,!onducted at -196 - +20 C witn cc at a dose of 6 - 11 Mr. Results:
(1) Lon~;-lived radicals with an initial concentration of (1-2-5).101 4mg-
form in UR and its mixtures with S or C Cl at 200C and 6-8'Ar.*
2 6
(2) Radicals of different lives form with irradiation at -11960C. Their
initiL concentrations in NR, NR + C 2C16 and in Nil + S are
Card 1/3

s/19o/62/004'008/010/010'
Bpr study of the radiation ... B101/-180
4
7-9-i-O-*1015mg-1, (11+2).1015 mg- 1, and (2-.6+o.6)-1o1-5 mg-1 , respectively.
(
Inhibitinn,
o?
delocaliza-tion
Tne
effect
S is due to
of an electron-in
0
the S ring. (3) If the NR + C Cl sample irradiated at -1960C is slowly
2 6
brou.-ht to room temperature, structuration occurs near the vitrification
temperature (-70()C). Short-lived radicals disappear and the concentration
of free radicals approaches the room temperature level. (4) Gradual
heatin6 of the NR + S sample yields new short-lived radicals with a
factor of 2.027 + 0-003 which is typical of 3 radicals. The radicals
whose concentration reaches a maximum of approximately
1,
S-1014- -1 00 are formed by reaction between IM and S, the S ring
mg at -50 a
A
.being ruptured. (5) After irradiationtarystalline C 1.1 ahowed an
2 6
--ntensive epr signal, from which it is assumed that various types of
r4didal %ru formed. The form4tion or 401 radicals was confirmed by tho
3 . .
analytical detection of chloroform. (6) Structuration of NR irradiated
at low temperatures is supported by C2Cl 6 and impeded by S which increases
Card 2/3

s11901621004100810101016
Epr,study of the radiation ... B101/B180
the static strength of the radiation vulcanizate. (7) crystalline S
showed only a weak epr signal. There are 5 figures-
ASSOCIAMOIT: ilauchno-issladovatellskiy institut shinncy promyshlennosti
(Scientific Research Institute of the Tire Industry)
SM:ITTED: May 12, 1961
Card 3/3

I

TARASOVA, 2". N.; LWADKIDI, B. A.; LYKIN, A. S.; KAPLUNOV, M. 'ia.; KHGZAK, V. K.,
KOZLOV, V. T.; SOBOLEV, V. S.; EIMZEN, N. A.
"Struktura i nvoystva vLLlkanizatov, POILichennykin karnhim."Lrovannyv. cleystvilem
sery I ion i-ziruyushchikh izluchenly. It
report sdomitted for 35th Intl Cong, Industriai Cloemistri. Warzaw,
Sep 64.
Nauchno-issledovatel'skiy institut shinnoy promyslKlennostl, Moscow.

YANSHIN, A.L., akademik; YAKOVLEV, Yu.Ya. (Moskva); PLOTKIN, S.Ya., kand.beekhn.
nauk (Moskva); GVOZDETSKIY H.A., prof.; NOVIK, I.B. (Moskva);
SVINTSITSKIY, V.N. (Moskva~; KOZLOV, V.V. (Moskva); SULIDI-KONDRATIYEV,
Ye.D. (Moskva); BELOV, S.V. (Lenirlgiaid)'
Books. Priroda 54 no.7:56-57; 71; 104-111 Jl 165.
- (111IR-k 18:7)
1. Moskovskiy gosudarstvennyy universitet in. I.I.V.kmonosova (for
Gvozde tskiy).

KOZLOV, Vadirr, Valentinovich
Legal-medical si,~,nificance of Gunsmith Lubricants concerning
Bullet Wounds (experimental research)
Dis5ertation for candidate of a Medical Science deFree. Chair of Legal
M'edicines (bead, Asst. Prof. I.V. Skopin) Sariltov Medical Lnstitute, 1q57

XOZLOV, V.V. ':/ a".11" Vkbl~~0'~J
V
Significance of the Impregnation of skin nerve fibers with silver
for the diagnosis of intravital, injuries. Bad,-med.ekspert. 3 no.l:
18-21 Ja-* 160. (MIRA 13:5)
1, XELfedra sudebuoy meditsiny (zav, - dotsent I.V. Skopin [deceased))
Saratovskogo meditsinskogo instituta.
(WOUNDS AND IRMISS) (SXIN--INMVATION)

KOZWT, V.V.
We are improving the remote control of deep wells. Neftainik 3 no,4z
26 Ap 158. (MIRA 13:0)
1. Ispolnyayushchi7 obyazannosti nachalinika konstruktorskogo by-t=o
elektromontazhnogo toekha nefteproqrslovogo iTravleniya Starogrosueft'.
(Oil wells) (Remote control)

AFANASIYE;V, FIM.,, inzh.; BORMICH, M.K., Inzh,j DOLGOV, V.A., inzh.;
KOZLOV V.V. inzh,
1knufacture of wire-reinforced concrete articles on the TP-906
unit in Krasnodar* Bet.i zhel.-bet. no.6:254-257 Je 161.
(KIRA 14:7)
(Krasnodar-Prestressed conorete)
BORODICH, M.K., nauchnyy sotrudnik; AFAIMIYEV, P.M., nauchnyy sotrudnik.;
MUCV, V.Y.
Tensioning station of very simple design. Bet. i zhel.-bet.
8 no.61276 Je 162. (~aRA 15:7)
1. Krasnodarskiy filial Nauchno-issledovateliskogo instituta
po stroitellstvu 14inisterstva stroitellstva RSFSR (for Borodich,
Afanaslyov). 2. Glavnyy inzhener zavoda No.3 Krasnodarskogo
sovnarkhoza (for Kozlov).
(Prestressed concrete)

KOZLOV Vasiliy Vasillyevich,- BEDRAK, T.V., red.; DATRIYEVA, Ye.U.,
'-tekhn. red.
(on multinational collective farm] V mnogonatsionallnom
kolkhoze. Ordzhonikidze, Severo-osetinskoe knizhnoe izd-vo
1959. 18 p. (MIRA 16:7~
(Collective farms)

KOZLOV, V.V. (Moskva); snIDI-KONDRATIYEV, Ye.D. (Moskva)
-------
Before the flight into the unknown; collection of papers "flew discoveries
about the moon." Reviewed by V. V. Kozlov, E. D. Sulidi-Kondratley.
Priroda 53 no.4:1.18 164. (MIRA 17:4)

KOZLOVP V.V.0 kand.med.nauk
Unusual transpositions of internal organs in automobile accident
injuries. Sud. - med. ekspert. 6 no-3:51-52 R-S'63.
(MIRA 16%10)
1. Kafedra, kriminalistiki (zav. - dotsent D.P.Rasseykin) Sara-
tovsko o yuridicheskogo instituta.
fTRAFFIC ACCIDENT 11WESTIGATION) (TRAUMATISM)

a Al -30 b IV's 12 U 11 0 is 11 4 1 V a) a ago
It I-V 1~111 - - * . .1 s - 0
A& -01 CC OR U48-1 1 t
lit 4.0 j.D 040100~
A mineral dY" 08 W001 &bar tf!~M MVWOUS MUSPOUGMU& M. A
TO V .KOIWV. J. R&JL PhYS.-C". SOC. WV OIWIJ(RO)).~7U obkt
I" to study the adborptim ol.mincral dyes (1%.0, (1-bero.),pb(oft),
00 ultramarine) on woolen latick which bas been technically washed with soda and amp
sohu. When woolen cloth is pond through an sq. mpention of mine-ai dm the .441
latter settle on the fiber in an even layer. Tht rractim is completed In the cold in 2-10
it
min. The resultant dytingissubstantiallyfutto water. The particularobjrctal the
to study quant. the staseis of adsorption a functions of the coam.. temp..
:g elLp"MUn. as well as adsorption an addified cloth. the effect of eki"rulytm and the
dt-ir" of evvirsibifily ut the P.Dise For the quant. studies. air-dried MyCr(]~ (0.37%
ell lfO) wu employed and a cloth of 11.62% inasturv (ev.). For the qual. studies the
00 E 01 her substances were employed. Adsorption proceeds better In ordinary 11.0 than in =00
111sid. 11#0. 71w pitmiKe a( inherrid salts In ordinary water makes the adsorption
c,,tnpk-te and siv" the dyeing a brighter shade. The adisorptiou isiefra" rapidly with 0
we time at first, but XTadually appruaches a cocist. value; It shows a typk-Al curve. As the
00 j, cimm. hxTrnm-*, the wt. adsorbed incrtam linearly and rapidly at fim up to a cirtain
Point; then further increase abruptly cram and the cum becomes gat. As temp. rim, roe
as u the advarptiou lam-aws but slightly. As cotics, of elemalytes hicreastro, adigirption
first decreaws, then incrvasta, thra again decreases. As the diln. inervean. the WL of
ff adsorbed decream but slowly. =lc washing the cloth retamed 60%
=
dyestuff initially adsorbed. As the " inerraws, the cluantity of acid
adsorbed by the labric ins:rcaxa up to a certain value. whetru" it becomes const- .00
0
The dyed acidified labirk at cam &bows an increase of 13 to 23% in adsorbed wt. of dye 640
0 over non-ar,4dified fabric. However. as quantity ol add adsorbed Increases. the wt. of Ago
dyvstuff adsorbed does not himase -.,M rapidly. D. IL
'A
'00 11:
*11TALLUNGICAL LITERATL49 CLASSWICATION 0
0 J, 'I-so., s I., I o.
0 it I
:E!-
a AT .0 LO At
IT 0 0 * 0
41
0 0 0 0 0 0

Ms-vir-few WT 40
I I I is 11 a) u W is L6 it 14 Is a 11 it a SO is u Sd 13 a v a 44 hi 0
a a it I R .1-4 A A--L JL A-1-AA -N A Do U4 k 1 4 0
Koil;,v and T. 1). XvIrduva. I miliol.,j"Isoik 0
Pro" 3 91 V IMI).
-in The prvi'd of W'.11111K vilmlorwe. III$. N-41 rrAull, w"M
laitirti lily -imill!Ancooi mill-mation d VOI, will, Itaming 41
with fti-cl oil, 1-41-AmOlf and N)I( (Itrit, Inji, f'. 1. .11, filfl), wflrrrl,v a
W3161 prothwt "'tild IV Isolatell only with (ta.-I '111. th" PC-Alict 1--'. pkial wV16111 .641
and entul,l(vul ptuprtilvi, and itt tivring of cotton and "IwAsIly td av%ul fail#" lsrt,-
d
Mrs very le%vl vilrets. Chas. Illanc
00 1'
Af
of
.4$0
00
=0 0
0
S . - s L a .1TALLLWGICAL UTIRAT"t CtSl1fPK#TWN RZ
two.
'A L
03 of er ft 1, 49 4 of if

7e, m"se.
004#60044064000
Oc At 1~ a of 111 V ld 5 a OF 0 a 4111 it 41 a 4W 4
is u la Is. 1_1L, -0 - a #--a-
OV 4q!L-
'm
so
of so
played by the in~lbilitv ,I th' ACid- -It CjI.
C.11. w give u,*h 111.4 luk. .. awl
Aioht%qtkiwqKu11,mw A,W, pt,%Ikh, thiln rite
j:: Msts.1104intliftilto COMP1411 COMP"Adt 61 MMAII11061C Inch, -,-[ 01 AlON1 A11-4 Aml "dr,%jivamowe
j-, . acids of ampilthalme and benzene. N, 14. Vorushusiv Acid, .4 C.Ils MOVt, .4. Nil, woli'l, is. Nqnr doolso.
if -~iz and X-jL-fjoll"v. J. Gets. CAM. W. S. S. R.) S. Arlifi, %urh a, 000
of IAffauffunic scists NA-hit. wonw 0-ititumulfouic wylo (2,1- And 2.4.9.) arml
00 "t C'.11, &nit CJ1. will, 4'1. N11. 1. *Jns. .1 Cat And Ni 1.3- mild m-mull,ka tusrxi;X6
(11) --pk% Sit. runtpOs.
1111* wta. or lit, l"Wlis the A. Cis anti NI malm of thster achis
00 with all. %11&. 11wrt %Vft- Pistil. Isom, tvyst. frictalul- With Ni Al"I Co Aft.%. Wit I.I.Alie'd 11tv insist, Cu cunt1*110. as 0
anunisin cnni-k-% illsOl. ol' newly Invil. ill HP 1-he I'Willatiml '11 untie far tAllo-d trullitio conlidexes wim
Allj t,"111114mi mX. -,ivrut,~ M. Ephraim. C. .1. 14. UM); the mullonic acid. .4 is so highly wusitiv cloill
*17:1. 17, ll12). The %truclurr, of thiew MHOCIrs that the rraction can tic tmA for detertion wisit dertil.
00 CII(N110. R" LL1141 N0,1614 RI, (ri. Chustary, CU 01141 Xi and flillsiffillibilliC OCKIS. M COMPICIL C(Ant9l"k L*
Wmseir. fl 4.). Th" -91"lits' '01 -%(),- and balogess- prej-1. 10%C Onne Nil, at rall trulp. alid all the NIL At see
UlAtittited .,"If,mor At id% to give %uch colill4est cmlpd3- 110'. by mulAtitutinif AroniAtic Aild aliphatk- amiricts
-it '14ritt hw Nil, ill the tractum, therv were olitaitscd litsu. of the
te a is astrilivil to th"If iliefl, lots, character. Fhr go 0
d ability of 1'*2-()l%'C'Jl.4-X*h1I (1) to give mint eAtily ults of the cum~j-odills and millsille, '00
these rmplt.%r.% shown the influeoce of the o-Imissition of five front Cu and M. BY addii, -4 NflCI or so*
the NO. anti 80111 Kwur in the rius. (cf. C. A. 27, 2444)). to a ImAll. of Cis ult of an-(hNC.11,.~XMI or OsNC,Il..
The Illnurrice of Its, mOrtiorg, rudiests L% fistritheir dis- Sooll there were o6tained utyNt., *4. Anti fing" ppits. '06
ly1m C -1
of the V110,80i CuRt 0 - G -Kraut, 114od.
buirk aisopl. Chem. S. 87110. The wimitivirneu of the woo
folkywitif reaction,, i%(tyen ill Isatts of Cis, Ni at Cal I" too
-a parts 11.0. 4 1.2. NC,.IISOs~.Cu(.Vffs), 21flO, sit.
zoo
siss
nt
I d.ICC- W,-11,
I-T
Isla" oil ONT old 41141111
u is Alf As 'd It I I -ss~w I I A OW 0 is 0 1 it 14 0 A I I 1 401111
Ia. eta 1.
'T
0 0 41 see a 00 a so* 00 10 00 0 0 0 0 0 # 0 0 0 0 6 0 0 0, 0

1 9 is
09
00
0o
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00
00 1
0v
00
00
00
of
es
a 11 v 31 bi a 1611 mod 411 42430MAO
Ito .1.
D=coatrol of P-aaphthol product[ois at th4
Latim
&IoX and A. A. Chff-
Frult" woo V..P
kankil. Amilix0hrasockx4yis jImm.4.
A setwral mtthotl of anslysb k dm-ribed. C. H.
:31
4 U w is 16 v a 0 a
6m 4!~
-40
-00
moo
Zoo
roe
r.* 0
go 0
Cloo
go 0
t:94
Us 0
"to ILA AITAI,L(O CICAL UtTRATLOR CLAIIWKAYIGP Do 0
77--
Aid., 11.1411 .34. goo
felava &l, Q.T 4*1 SlAill OK a., is.
A . . I I , ; I A 0
U n IT so to a 19 it OP K 9 a I " a ig it r, I I.. Pill so 040 willwilmsa
0 0 0 4 6, 0 0 0 :1$ 0 a 0 0 0 0 0 0 0 0 0 0 0 0 0 o
04'es
,TOO::::: :100*0,00 000004004-09 000069 0 ego 06 0000000900e

4000*00*40000 off#*: . a- VIA-
m o00 0 0 0 0 e 0 0 0 0 0 0
03 11 A Is b Ina WX A M U U M n b V j6 P. Ar Q 63 41 to
1. &A. 0 p a 0 1 f .211 A I AA a k I a A I I
4 .-1**
Lj&.(&d b"k dy" with beteraWY -P-ds
(ragW1444). V-V-AAkMV- AXWX0kFdJ0CA"aYu "row'
S, )H0-92(1935) 19M, 1. '21443.
S~' Top" diwuwgd Wu& Lb"c"mPt' szeUmn"i'lle prel"t. of I"
0 ail dyn (rum cumpigs pho%pholungstic, phMplumn(Avimlic
mukatuagsik WW6 of Row" auLnul.. tests W the
siped bxh in thr
famnem to light of tbt plgrswnts so tA)t i .00
pugr farin and an caniers. (At gets, tle.93.. kmAin), snd
00 11
-magions at to I twif uW.. W. A. Mmor -0 0
90 z
00
00
00 coo
00
--0 0
00 r; 40 0
0 18=2 ::Zoo
00 f
00
0
00 A 0
es to 0
00
L* 0
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Of Wo
- - ------------ -It
04
u #A I I a W a 0 -1
v P I- a 04 It is K 0 of c[ it It of suo A I ~14
oo::Sooooooooooooooooooo0400000000000:
4Y : : : : : .: 0 0 Ogg a 0 0 0 006 go * 0i0 Ogg 0 09 oe 0 0 0 0 0 0 0 0 0 OA

A
00 a ,~
qq a
e 4
0 4t
:
004
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00 13
4.6 0 470 6 IF* -06-0 6-0
oo**oooo**ooo
UNSIX hVIN0041 one
WhOW OF DYI UALYSISo lo AN"7818 OF qUINOHOID
DUS BY TIM TITANNU XXTUV9 V* 19"ov (j . Appl.
93 TIC13 or
OWS4 Rule,# 1935j, 8. 1416-141'1~
TL2 (So4)3 solutions ch" tMir titvo by 0.00=4 N per
dsqs th* oxidised solutions can be periodically ro-
generated tW adding Zme Tbe d3va are best titrated in
201 120-stoil contalrAnt lot' or N& I tartrato AM
approx. IS of 4yes the resvits tend to be high, by;~.
2.5~* Titration with.CrOU lin place of U013 does -flot
Sive Satisfactory resullso swift to the indefinite mid
point and to the slootwas of the reastion with certain
dyes. (Ple-vioUts surudness, rhodamines)i the most
reudily red,joad are oxasins and thissirs dyes. R. T.
lee
.00
0*0
-00
-00
.00
40041
nool
VA 6
see
see
8,4001
400
So 0
we
165 Us
All-ILA
r--r J-w
e
a a:&
41410400,00000000000000
0 A-0- 0-41 0 0 0 0 0 0 0 0 0 0 0 le 0 0

0~9 0 * 0 0 0 0 0 * 0 0 0 0 0 6 004 * 0 - s- 6 0 0 606600006 0 0 0 0 *
0** 0 0 0 0 0 00 0 0 0 so 00, 4. 000 0 41 0 0 0 0 0 0 0 0 0
03 1 0 111 to 11 1) m16 U
" " " a " "
V
C
*
,
,
0

--
-
-L--L--L-AA *,.C
0
'

as
S. V.
W
W

-
00 sof Scal details f(w the utp. (4
;m
, -90
py'VIu it with HCI p in. of Mn(OH)s by NaOfl and
ax t of the Mot Of with Cis oto live 1110~ of hisks
ox pown we 1. M. Lcocester
itoed

06
1~
3
60
1
~
90 =0 9
--.0 0
so =o

of
-0
:
c:00
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00 r0 0
96
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06
cz, t:O

00 '0
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I
wn IRA
K .
A
4"
0o0040000000-000
o
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o
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0
0 gio 0 0 0 0 0 0 0 0 0 0 9 q 0 4 1 0 0 0 0 0 0 0 0 0

off* g
?900000 0 000000
Alt

00 A via Mal"

1-00
^0

Oec W A 0
.00
bo .00
O
'
w
j
ids
k
i." (a)

000
mod Ismans awo zoo
dya DWI*
2 rVin, by we4W &W ppL. but
.000
1

im Im is Ma cam of b~iAo dye&
I
O
PP .
r 000
OOW L IMLO(al "b"odwapies"dwoomi.
I
I
I
, a T
on coo
Ap whi" Is dtmUd
O
t
II
by
WW
0(60h AM
A
IL
1J6 rAL Of it" r4iMW$*4TOmL
n
%%
i f
*
w
wt W
s
!=
of 11-ft AAd
r6
d
m
s
L
ft
, x6o
Al Wuua*m No*

I in OA gh)ft
:to*
t i
~ The
a II
T
.
610.2LA &I .
a
A
TtL

IM It 4". -dat *A ~ftr It.
0 ar so AS

T A' a ad a 0 a I If of 9 dB a 3 a
I pop a K
~

4
1
Is 16 I
161
0
0 0
4
0 0 0 0 * 0 a 0
00 a see 4 0 0 0 W 0-0-0--0-O 0 0 0 * 0 0 00 61

900000 0 0 a * 4 a 0 0 : 0 0 411: 0
0 0 '0 ~0660
I I I ]a 11 if is m is m )its "Alin 83911110)1?0 wit Uss m 1% m u 0 H LI 'I
A a A L J. m U"
J"(, Jw;

Stable preparation% of diato cormliounds.
lium. bl,?RW. sqfl. .91. IWI',. Ali, -k-111's, ilf '4111%
air fival"I woll lulcl-

th"i" mill if" of F
d S'.
r
A
0
I'll's k;
1h
e
~

.
00
.

fie.,
L A *,I -t,o Wfwto( c% awri(wit.
too
is
if If It '.4 ~.4.) 'I o14
0 0 0 a Ole 0 0 0 f 0 0 0 0 0 0 0 0 0 4 0
*--* 0 0-0 0-9 40 0 * 000 0 0 0 40 0 o 4 4 g 0 0 0 0 0 0 0 0

w Ir 14 0 0 6*00 __o* so ova W~e
x It a IS w Is
A, I-11.1 IIJ 1. a. is a is v XT 36 it
00 #A 1 -&-
4
00 rr~ too ANCI st! "q -00
PROCISIOS five P660191111 moth
~ VIL Us roduction of 1,641-
'
00 pitionaphthaMs. N. N. Vowtuht., .,.I V. V, KadoV.
i
j -
J. (;ex. Chow. (V. S. S. k.) 7. 73"21 IWO); 0. C. ii
30, MW~ -Cam. 1,15-C"(2400t; k1l was fromed Gain Shc
%O
.
jirjusmee (U) by dimolving it in W parts of 100% H,
,
and filtering
at W-90% thm roofing the solm. to IS 30
fStso 11. TU fitteste was pmvd into vx" orwer, mW
the pitt., after wasthing to twu" reacticto and drvnjr~
00 c l. In. lm 70'. A cm-
was reffymd. from Calls, sivind
watI effmited by
112% from In. 215'
m
Iet
se
of 1
*a ot .
.
,
c
m.
.
p
a rapid cooling of the enrichtc! I in AcvO. IA-Ctoll,-
jP41f;)j, nt, tirrulted in 77% yield when HvS. to-
orso coudoct"I
f d
till
k
i
h
stream o
a wea
s,
grthcr w
t
rr
into ID g, I in RX) g. I'hNHs lot 1(0,1' for 2,-A firs., (of-
lowed by diatc. ad of the I'liNH, and crymig. frotto ILA)
The jame reaction at W multed In the furmation of
c*9
timphthaleme-pai-dibuinc, III, 110, yield, 0.621 x. frout A g.
Of Chas. Hham-
cI*#

00
j
no 0
.
AIR-ILA WALLURGOCAL U1644f"I CLAS111FKATION
oz-
fig.,

U BAY POAS" 1
1
ZA
0
i#

' 1
L Im a a I
I m 111 0 AS
"
a or Ir N X a x a x a It 41
,
a a
a
a
0 0 0 a # a 0 0 0 0 9 0 0
0
[4
.
00 00 a* a 009 0 00 a 0 0

a S 4 t A bd it U Ij M 11, 1.
o
is, Al,nj,
.A I
f
1%
d
ii
w
hi
m
I
0
0 t
1
00 al *
0 o
0 IT
:
of

IP UIF aa Al a is A 20 A, 1. V UIN Vm0 A. .1 V N, A, go
I Z kA go CC DD a A -2.

Coolly, 0
I(XIIS81, ..D -II(Vtor'll -400
-00

oa
Ditto totizatloo 0i amiymo$ in the
WW I DIM -00

*,Me of vale:i
r an "Its. V--.V,-KQLIQX J Gr*.
tin.
1 p- I of the benzene rld C.14, " k", which are umally
Wt to dimatize. can be diszeltited qtrkkfy and n"r-
B
i
h K
I
W
f
i
t
a
y w
n (be prelmence o
n neutral or
SnC],
h -09
d volfts. Whtn this "It Is, present. every I-aminin-2-
iroxy4-cyanomplithalene, whkh century he dfarmiml
let ord;Tyary cooditions, reacts without difficulty. The
bilitlyof thediazotized moln. is Iftcrealyrd by the prm,
Wh
S
C
HM
i
en excess
a
h.
s prmnt rmrpling reac.
h
rm with diazoalum salts often give tars and by-producti.
lit wAn. contains SySCII, suchside reactiyrn are entirely
Ifirr-misvil and very pure prcAu,-t% tire Mitained frenn the 0
lillng. Smlts(d bivalent My anel Fi- &Ivy thow this tx,. 0
rW. If. %I
my W
zoo
00
00
A AD S t 62ITALLUV(,KAL LiTERAT01 CLASSIFICATION
00 1101. ~1- ill.
7,.
ono sm ma Ica a tt it Of 'w n All I -f IN 6
g
0 0 0 0 0 0 0 0 0 * 0 0 0 000 0 a 0 0:0 0 * G. 0 0go go 0 0 0 0 q 0 1

NNW! 6 4 4 0 a * 0 0-4 0 a * 0
Of
t 0, of ow got oil oil ON 'PU a It v a m a b v m 0 it a a w 420
r 7v1xv
A- L-A- a it i I v ~ Y, L-L-I-L- M A QL U44 A-4 A-B
tit 140. "Via$
.14 .*cf$.1qt -4.
UIV-stualtive mitre comptinds N~
Ole, (J,- /"./ -1 . h -N 11 1 4.
a in-vi'm pubim-dwitt, .1411 11-4,tl-l Aml
d"K.Usmuts Lilt l"dw
Ell
to 0
04
coo
00
of I
of
'goo
X00
two 0
PiTALLURGICAL LITCRAILMIll CLAWFICATION 92-- jc* 0
100
1. SQ4., 0- dal
IV 10 Is rp J. 1 0 Od 0 &Fps
it
u n it v4 4n
~00*001000000,,;;Of 0* 00000004joe 0 0 0 00 of 00 000
S
TION Ou 60*6,6 *as a a a 00 0 000000 00 016 0 q6*OOO6oOOOO:::::1

It
IL I a I It L
is' Air,
00
Ali
- I
o*
Eve
004
of j
04111
00 'a
00 g
oo 8
&44 :J
jW
ti
WA0111:!
g~lj t I
1.1111:111-missiti" nitro tompomile. till. met*-N*M-
tbmceo~MODOGWI*nlc acids. N. Varmbitov at",
64i'l ChOm- t'~ '4' " 71
27, 2440*, Tho Iterm. of tell-thris-
1107); .4 4a1 use
:=;1~9 vic 11) hy t thosit of Ithintillst seat
,Jfohvts~ -I;
1% A 18, ZMI 11091~lklt Stac"t'd St"" 'he
I., kept at lit-1h, durinq allet6m. I maussigg be
by .1icialition of ttw tritrossimbrimiceme. all" Only
milirsterLmulne I. formed. Treatment Of I with 'let and
11100, give, a dit-h4whir which Is ovidisird by C10; in
inven, - Title shingsk that I ItAll tile mein.
ell,
mws:.-Ilsm of I with Zn And Rt~W% give" 1114
smine. When #h1t 14 dintaillnirl "d heal rd
.,orripiustriftiF t ajfn,,. 11. IM-91, willielt Is hy-
wish Poct. If Si- a -
topontleranol-l-sulforsk-mcid, That.
itrolyted bY NaOll
~mcrne-I-4uIf(jniC em. Itts, Ne. Ca. Cu.
fit', Im. M, As and feelic "allm
aulgonle " Ill) mritt RIM10
me Nimmanthraeftil-2
Ivy The grapthod of ff. anif %f-
.1muled during 11% PrtPll. tim ion of anthracene.d-sulfanyl s
It cannot lie forrsiti. by ill
As, Inv and ferrovii; %All* air (le-
chlorldi It- Cis- lie.,,
't-tilsed Whru I lio~t it$ light. it rilt'"i" a dar-Ir
in,. 11
while ,ajer the mine condilk
&%m.lLA
&A IS At 40 11
0
1 0 0 0 0 0
ST44000000
11TALL11116KAL L171RATM CLASSWICATION
Vis
D It stall MAINIC Man Ital
o n
0 0 0 a 0 0 0 0 r0 0
0e000040900900906
..*1@ 0 sa
4 _IL__4.
aA
The action of 110t an Witter solutions
at m ddo and an their eWor on w" and
lb". lot-lik4- sap. o( l-"it""-nsph1ha=gfM
m-id 41) in ail toin. am autswaimavocauv redn.vit liv light
Viiiiatkne,itmIS,
i0ossins. than in "Is. The Ifit itall 1. entire imilvir
lb" 11W Na -411 ot free I. The flainge twvmr- lietrer
wbft The mill 6 dritualittil an wool then Oil -0k nr cation.
T1h*s=e:(tnk1anh hassillm thrieution. and h"" it
goes N, or M atm. - The I jLk%,mer iq inner
tivethlirr in flight than ivi 1.2- or 1.7-Itimem In res"111.
comptIm. in whi'll Mh and N)jIf are etmw%t (I ruch Oliver
are The nawo 'I'milltr Whril the %uhiliftwelit are In the
quitiogrnie i I,', ond 1,7.) the je,61 I, it-" %russ.
Iive than whets thity ate in the rimi-quitiogrinic (1.0i anti
10pusilk"m Amont I fie dinlirmilpheityl tikulfidev and
d
nitrodinaplighyl dirul6de-i anti the nlinkentenisti4ifortir
acids the o4"tm% are the mint wit-ith-r. but none we
as arfl%-r at 1. When P41wr qKmkf%l In fileati faill"I. end
t*%ptw,l to light It rin
hwil,wilh dil. NatCrt0t *Qm, the
colum err wt N-livr I ail I r4ur H,0 k isted. Tl;e %411%
of the. tvipi-natilithelene cvv"ipdq. desverewitise Al"r rmul.
[I.
moke
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800
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ago
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woo
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16
0 0 o 0 0 o 0 q 0 0 0 0 0 0
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I of It U Is Is 4
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61 6.t to Sokol
to .00.
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::9 NK
$.a -A- I A
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06 3
0 Um prodaft of dw cdou at
snuonic add. N. it, twv and V. V. Koatuv. 1.
6*0. CAew. M. S. S. R.) 7, 1610~13(1037);* eh C. A. 31,
M4tIt-t-%'hcn I -CoalG( NEMS(hif P.4fk.. are tril-,l
1-1 'unlight, it dayeppl. omirs d-iwn, 11 it probably I-
dillino-H (it -nitro- I -tutplithylsulluoyl) -2-ti4phtlwl, t4l
IlkuXb It'May bc an Isomer conig. another of( gionp all.l.
anNOinsteadolaNOsmp. When the Mit %alt ,I tit,
wame acid Is extiosed to sunlight for 33 his., tire dark pp
whichremsholiprolably lbecyvfic M;xidt 42-hydrmt
1,1'-azonaphihakite-8,8'-di$Wanic acid. Ifthoexritnut,
lasts 1.0~1.5 yrs., a dark, in-A. polymffic rnoduct is ol.
tained. H. NI. Leimtti

zq
AS&-ILA drtTALLURrKAL LitairaTLAIR CLASIAPKATIGO
Too., 90.01~
'PC..
0-09 flitSIM.9
it , V--j-r_T__rw__ a ad 0 Or 0 '1 Of 0 3
U 19 to III;
. It it "a
f, to 0 9 It
0 0 0 0 0 0 C 0 gi 0 0 0 0 0 0 0
0 0 6 0 0 0 a 0 0 0 01 4
sorill,
a**
7 1*0
soill
see
,00
.04111,

*:o * 0 0 0 0 0 0 0 0 0 0 0 6 4, 0 0 0
)o 0 0 0 * 0 0 0 * 0 0 0 0 0 6 4 0 40 9 0 00 0 0 0 0 0 0 0 0 0 0 0
S 6 1 1 4 Zo 11 u It Al is IS it 4 1 TI u a m J$ At 11 a h a It 11 13 m a At I? a 10 A; At a 41 a CC 0
.1 V 9 A J-1 .,V JAUL-A-1-1 #A Is M PMP U 6 f..$ A A Ii t)
1-0
09
F,
00 1-00
00 2 Analysis *I dyes. V. Analysis of Illsolultle iuo dyes .00
a&4 colair lacqum. V. V. Kozlov and A. V. 14manov,
00 A skaya. J. Applied CUW. -(11: S. S. k.) to. cm %I
Go F b M)(1937); c(. C. 4. it, ~=4,. oxxis. -00
A =Lwm am amlywd hv the UnIlwerhi tue-thoul
(Off. lik3&MOK111)) of by the (latictihinskaya mrohmi
if 1~!l -00
(c. A. To suslyrr intmol. out ilyr t,*K. pig.
Incull) 0.1 $- Was di$NAVVd Ift 25 cr, 44 11,FA). (d. 1.J44 t by
heed waW bath for 30 On. The tmiting "I.
i was Wwalth 400 cc. of water and, after all air in tim. coo
fiask was clisplaced by CCt,. was Itreted with 44) 70 cc.
ofSnCJvfpr45mIn.to2hrs.uutd therewa%atilwpchang,
Of COW whik lKsting on a Wding vlairr ljclh. The o %-
CC1111 Of the reducing M=t was back-litrated in the UUMI
OC z *0
uuLu-. TiCh and TV80,11a can he used as the ruilucing
ts Ingeld of SaCts, but the rumilts are lem. wcurpit, 25*0
0 4
with S"ClI. Mats are NFWYAII in the valne way,
sincgthcolidonnul inteffrewith 16&tudyl,. "k00
w0
A. A, INOVwIly Igoe
Tj
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voo
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SIVALLURCICAL LIURATUAll CLAISIFICATION C-zrr
- -- * Ila.. Sa.01,
x1lift-i-iii~4JI.- ~77: too
Mallt) it a-- O-C lllkljl~ll aliTli UFO- 11i
U 35 At 10 411; tt 1, 1; AAA INOWD ".1mims'a v OWL-
PT KW I's
a 0 :10 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0 0 !1* 0 0 0 0 0 * 0 o 0 4 0 0 0 0 0 0 0
4 le~
p : : : : 0 A 0 0 0 0 a 9 0 0 0 0 0 * 0 0 0 0 0 0 0 0 0 * 0 0 0 N 0 0 a * 0 0

0000*0000000*00040 ~ V00 pro w go 0 0 00000000 0
's
its is if 41 111 0 0
O'S'l I its s to tolititil'! 16111,11
ir
0 a _x I f.-T A
* Ill T (w voqta~
0 v Cie,Iis~ .0 014, Pill f #I
00
00
o-Antlinquizoamitanyl chIM4#. V V Killh.V AIM
IL G. Fionsiva. fill.%. ati~ :11, PAS Awhi- .9
quitione is ttrA(cif With ChWiriAll (mlicip't'll its flit- A 0
tit sulflit" of itictatli,d the first and tilt, m,,,tid Ki.,up ,( Ow
j peritlilic q9twi. rx of sails tit $-Alit hrailitintirtirmillotitt, see
strill m Its malltmil. =00
00 is CID 0
66 j
*9 041110
too
-.0
00
AITALLURGICAL LITINATtilif CLASSWKATM" It 1--- 0
--- ---------
.&I CNI cog gills, &I
i ; " ;i "t I I I T.-I ... V171- -
n at I W A I a 0
u lot AT 10 -4 ww a I I xx T I ir 0; old:
0 0 Ste 0 0 0 0 0 0 0 Ole 0 0 0 a 0 0 0 0 0 0 0 0 0 0
0 0 0 Ole 9 o 0 0 0 0 0 0 0 0 * 4 0 Ole 4 0 a a 0 0 0 0 q 0 0 0 0 0

0 0 0 0 0 0 0 0 0 * a 0 0 0 0 0 0 0 0 *10
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4 * 0 4 0 0 0 a 0 0 0
Ij I a 1 4 P 0 4 N 1, 11 11 M Ib 16 11 4 OP a'11 V a 14 a JS V 8 P 6 33 L' U 36 a b V a 0 41 Q LI M 4
A
:0
T k t
A

94 Lacquer pigments. N. V. Vqw-uht-, Jr.. 00
SumnovAava and A. T. rroshchenko. Ruv%.
?ttatvh 31, 19M. Azo dy,-i ,btaint4l bY miPling 00
-4 P-hyd%P'Iv't4j'hC"yI with &%J.- 4,41,14N. firr o# "it 1,00
fur kith 1.1"tIAIC -UCh &A Al-
"WIT11116 ItImI7
-00
IIA
,
00 a
f0 -00
00 j NO*
06 .3':~ :10 0
00
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*0 so*

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oir
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!100
1
1g00
&ITINAIIAR UOO
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go it n 41 og Q n I
* 0 0 0 a a 0 0 0 0 0 0 0 # 0 0:0 0 0 0 0 0 0 0 0 0 4 0 0 0 0 Z
0 0 0 0 0:0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Ole 0 0 0 0 * 0 * * 0 0 * 0 0 0 0 0 1~~

Ve
0
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00

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09 a As* dy**. V. V. K,utl.v. RU-. M.M. )%dy
* -00
.00
0 Mg
1
Nuall anIto:Ut
i.J6iA Ilk-tals that All be o%WU%-d
hi
0 a ithrr stage, C. S., AIIIIIIIIJ114, fV110111 to IlLaUKAIRMS
0 .00
*411s, air added to diato *An%. tsefutc empling with the

0 Imial conlj~nctsts.
:

00
0 3

-00

'O'b
goo
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ICAL tlygeATUR9 CLASIMPKATION
all.
slow VIWIII two 141431 ~v oil 0
Igmailo sit 0" (369 10
J 4 a
'T, 0 0 0 0 r 0 0 a 0 a 0 a 00000 0
-0 0 0 0 0 : 9 0 0 00 4 4 0 0 00 0
0 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0 0 0 Ole 0 0 0 0 0 0 0 4 0 6 0 9 4 0 A

0:0
w 1:1 0 We W0,676"We 4,910 0 0 0 0
- -1wr d as 4
LLLLL U-1 --11.11'lill--~
0e4 -00
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000 -00
00-4 -00
0*4 p c-, .00
soc 0
00 a
0
00 ~00
004Z 000
fee -40
ooz
0* 0
sea
Tfig-c6i~FL of d." mArgaw is detftvdwd coWd.
nifteivaly. Nut of aw hae"kaft
Iola
got
40*
cat
~74
tic"" *lWask..
SOA466 Nit Owv 411 on 40,I
00
A I a
u 40 10 0 ir is ii 4 2
0 460000000*00*0090 o0000000#41000000
see*
00000000000000000*000o 090960C06#640 of

00000000*0090000 0 *w,
01.61, ~0161- 00.1 ~04--"
0l 0 00 1.4 0 0 0 0 000
0 m No Cc W U A. I "I 1., 01-*1 Ul
1. V -U~w -A
00
00
00
00 I-so
so 1-00
00 .0
*0
90 km. lestbarm, ate-
pe 0
U-- KIM. 1hmmlics 31; JWp' Tho dyq"
effecird with 1.3. 1.7, 1,8-, and(cw)* 2."ihrtwxy.
0 -3 -Vhih&kiws w th~, mixt r4 0
01 1 j.4_C,j4(Njj.)"
00 e. lho Fwrwtwel4 all olillitinj coo
99 go *
0 0 00
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S L a METALLWMICAL LITIRATUNE CLAISWKA?"
'3460 .4s q%V 044
3 4
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09*0000000000
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let 1 *4 T 00 **1* 00000101
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00
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&&%n C"thm- oft, V. V, K to
u
u . 7=
. - KIM. Ike. St. UNW. 'DIV V,. '00
talned by oxictittion of a mixt. of 2.6- or 2.7-dibydr my.
naphilaskme atW 0-tihenyknedismine, c. x.. with 11sot.
go
me 0
""Do
C00
.91ALt VROIC~L Uttit 41441 CLAH 0KAMN r.
Zia". si"WaLl.
aftv del
M--
&V go is It M 14 166 0 it a I v
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41 0 * a 6 0 0 0 0 V 0 0
0_40 0 0- 0 0- 0 0- 0 0- 0 0 0 0

of
0 0 0 0 0 4 0 0 0 0 0 0 000, tP o o 0 a 0 o a o 6 o o o 0 a 096
I AS Ij " 1 11 i"OH11 USA us asu astrieSlade 46 dii~v 0
A I C _11"J rXIT is I I A I v a 8 1 A
: W I I mail 11-9-11
A W. AV -00
09 1 gain* derive. 1.00
Light-ovaisitivis nitro compounds, V
lives of with o- and "viblibluents can.
sallser. N,N.Voajhiit,%v 1-00
60 st I IL U, J. Gets. Ckirm, W. S. R.) 9. 6121 bi likil)j;
.00
cf. C. A. 32. 49W.-O-Nitircs-0-ruiplithybunine (1) is
to. by n1irriiiici .4 amt-d-naphitsd6le. Wht,n
-A%, to the 14v,.
00 =gms The va"irm issith I
"" .,# II'S(X. it At,.-
ill), in. 119.5*. It IICI is owil inot-All ill ll*S). in lilts
ttvictiurs, ilic product ii atid.
:Ile its. *3",.1*. U is nictiltrattly lialst-tirnutivir. Nittaltim"
00 givr. a likisif ~ .4 the Ll- and 4 111tio .00
0 0 drilvis These our [WAS ftlkl, by JW%%l%ind lilt 11110. its Go*
it% K611, ddig.. ridilinx lite pla. toils v I'hNA 1, Qlhl Im-
00,1 iikq in a stfranicA dry IICL Urkh-r ills- 1.4. : S:1110,
09. trittamplithylatittide L4 tiljlahw4~ Ity cite Gattefirtisifut tv-
"Clims this lim orld. ill.
"I "'go:
132.111" which it ulkli" by 116(h its ths. Clirl"Ixill,fitia is
0411 -iflionis: SAM. Both thrse ackla are weakly witAitivv to See
light. dd k/ IS tMrSld. IIT I lie
00 91 Sunditteyrt reartkin fitsit 1'z 0
richl. It is a hyjtivscvpk- yellow lx,wd" whiter Its. I-e !50
!zip
NI.
00
A
A."'-W YN.&I COW UAS44 %AMJ.
CA
All. $1, It LIAGK LITEIAIL411 CLAWOKA11010
.'r". . As
is er TV.
U vt AV M3 "jo 0 tv 1. a Is if ill a 11 M it a n I a so 11 43 a 3 1 V
0 1101 a 0 0 0 0 0 0 0 4 0 0 0 0 0 0 0 0 0 0 0

111 0 4 0 0 o c a 0 0
443 Cc 't
I ki it 1: 14 it is It p :1 u A30A XvxJ0 lot) JIM Jon by Sjov it wood,**
"Pil", 00
pacc#9111 AW 01CO10141, .Lot r-
naphthylamint mad its Irsaidormation into an suo dyo.
9;_ Vomilmov and V_X. Kuduv, J. Grpo. Chem. 00
S. R. 1 9. .1 - - --
K. U(110W 31. 5.ilml
A mWit6m ot nh -w 61.4).
m ns
11-111,4 lit.111 alt.. m NIUM l1w:.61"I
alk. u4n. Kivv, a dop
lift,wit-1.12.1,
(Ill, ii ppid. WW1 40A. Th.. IV'.. Illwlitnhh- ;I, ml =00
00 .3 !.1111111valm, Klvr, % 1110-n-mt -it, Ill -md,
00, fwm.mud
N;1.011 o, mwi-r-fidly ill-plall w 111w, of .1114 1 ago
1611OR10111f, J1141 Of 9- Athl
f john Lival coo
so a ago
so SOO
s!00 see
41*111. 00
04, .j
tie o
"'o
A S a S L A Of TAWAG)CAL Lilft#7601 CLASSIFICA110 1 1 t3vo
so sic Ito., 10.", l1re*
-Z T
2;'
-"L- An- -i-
a AV 10 is
0 IV so 0 a ew 0 10 0 1 v IN 5 a a
0g of a it If It 91 it It K kW n I : 14
0 gio 0 0 0 *go* 4

so*@ *00 *00 000 4 00 600699066* so
a It ;to 11 v F1 m I's lot v w a 4 61 A; Al apo
I v I - i r
I A k AA a u II I
.00
ChowAstry of naphlbalone derivativec f ReActiOll A)
Joe anic acids with alkali chlorates -00
of paphtweammewaff
so and D. 6. Talybov. J. Gto - C". I I'. S~
S R -M -WO10)).-The mrtion of I
RCI whb KCI(h m the luviting trllnk~. I%vf ch-4-11v -00
1.6-C OC14 and Smuc I.S, I.X- Aml '.!-
40
C,4H a uudcr thew 411ndillow, x"%, 0.411 AV% -.IL,
Clifw The mactions mV act1mvp1mini bv lum.11 .%i. .04
Tf the di-Cl mmpdI. to
datik;~ - -00
Of nme,m.,106-70. ; .
lakr. plzr~ at low f temps.. fm fW). Chad. 111,4",
00 j
00
00.1 300
Noe
91 :2.", ::$so
RL*41ACtl 'r
LAI. ("I U~It IIktUMAAA;W C"~ 9d.. 1%4J'
, AT '1 .1 .
A%- % I z : I I
we*
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a--4 a I IF 04 1
0 00000 0 0 0 0 0 0 0 4 090 0*0000 00 0 0 0 0
0 0 0 * 0 0*00000~1roo:::*9* 0 9;4 0 a 0 e 41 # 0 0 0 0 0 0 4 a 0 go 0,

-000000600
:Zile 0 0 0 0 00 0 0 0 0 0 0 4 *0*0000090 00000
I j a 1 4 1 a0 4 as 11 It w Is 4 it a It j0 HT a311 V'x "loll 161111 us me mostalou"aace
A -a "9-
I., "as i
P&OCISSIS AstO POCIstial-11
Oil cApadtj col wj~nk p4p-ont-a and
%*-%',K41Alcov;al%1A. Simanco"kaya.
dw 1039.*N-ci. 10. :111) 42; skkim~ Risferal. boor. 1040.
No, it, 119, cf. C. A, $4, 36M.-C-mipervallarar slots moo-
pte-writ 4111 tkir ml empAcity 4wf "volli, orol. joloolivelitt Aild
varlifth" ii,arol ht the lx4yrsophl, indmitar. Fsaar -0 0
letit. ail tod rairwity (hr mrth,%l't,( bsamig a, SwArtli'l 1"
111"'ar.4 A110.4 th-Ses. umearch 11too .4
w w
VAMill'141 4111il Pioclalttll~; it lit MOM I'Sliki. .11asViltille ILMI
sanail Slimat ttt,r(mltjcibk- arratillat.
ZOO
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1:311110
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so
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10 us AV so 11 T I', 41"t
1 1: g a 0 11 : : ON a '01 ; g' : 9~
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--Of
Sit 000 d6fiVativ*s as oxidation dyes for fuM.
=
Am
And D. S. ZhUk_ 1. APP(W (. - (U. S.
V2 V
.0
IMI-12(in French. 1313)(1030).-The ability
A 0
halcurs to dye fun dc"cases in the
of the dihydroiyrA&Pht
mdre 1,2-. 1.4-, 1.6", 1,7-, 1,3-, 2.(1-. 2.7,. Ifi-. IA- zoo
y1jprocedutcladescribedindclail. coo
1,4-Naphthyletiedfamims and 1.2- and 1.4-amin-Ph-
lbols, also were stud[W. Richer colors are obtained with
6
these diarninci, than with those of the benicne series, too

urnbiuations ul these dyes in fur dyeing art stmi dixuucd.
c
Nhydrozynaphthalents can he combimA with other oxi-
Iatkm dyes of lbt usphthakist series as well as of the
betmene scrin, The fastum of the dye an the fur* is not
infetlix, and in wxnc instances It LL supetioc. to that ub- It
l
isined from licantic "Ys. 22 referroces. A. A. D. ose
le 0

'00
'09

-i go it I t i~ 'At flow* go v1srm9aq3#.,x
0 000 q *1 0 0 m 0 e a 0 0 0 0 9 6 0 0 S'o 0 0 0 0
0 0 0 4s 0 0 a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9 0 a

O
o 0 0 0 & 0
MP
f
N '
jolt lin lots ismassal UU
a F F d old
60 A '.r.
*0 1 PSOCISMAS AMC ..A the cleavage of the lIctert"lly " and the foruistwork of
I Nato compounds. The-Istasoctlooic d d1iiii Coom. corresponding phrools. Thus, the derivs. of *-(NNC4H#-
00 j 1
Note wltl~ complex hotel polly acids. Xr,,L?, Kodo, and Nil, and ol-anisidine gare resp 4417a #-C~.NCX4011 and
ru
. Arkill IV M% Conflict
so Ge". CArria. (U. S. S. R.) 10, CM -06
09 OW). cf.pl-. A-j31, 85171.-Pteviously It was shown etiodlounines with heteropolly adds and certain dy" as-
(Rum. put. 51.808. C. A. 33, QMI) that Monistic di- rfrood fmm them. V. V. Koziov. D. N. Arkhlpuy and
09 Azoniurn suits tract with betero" adds ound their salts A. V. SArnaraivskays. Ibid. 697-77N.-The isomeric
as0i free front F to form water-husol. Coulplex dL-ml CJLfNH.) reset in IICI IkAn. with heteropoly acids to
01111 11 polls.
ljj~ Addill. data show that the scheme of the closest. reaction give splitingly Vol. complex salts of the type: jC.H.-
A with pho%phontulybdic acid (1) (&M with bosphot [C4IIl(Nff1)IjS-jIIlP1,WA)IjI
on (NI10118-111
acid is: 3 j .14,X + I-Moto - JArN,jlgP(b'foA nic and IC4II4(NIIl)ejj.II.S4(W,00~. The complex -who, -1-
ivrd foro~tn .. a I t-i-nrt.. raft -lift NaN(S in IlCl
9 + 3 fix. Silicottimptic at-id tract, with 4 11
Z AtN.X. Ube "nuplex diarn or"otnp&., derived from i-o- .4". To of" 'j lbor tvt-~
I in" it'
0! k- it rividlinra, tolulditirs and ardsidinors. are inxil: And Iff.NC.-
In coulnum Ms. sulwnts and are =1. in cold amtin, dd If NaN(% is used in excess of I
eC0. --row morodiazo products bcconw
0 itlycitiol and ILI70 NaQH and in hot ca4N and m tnol.. the yellow or paile
I'licy show greater stabili ty than the common diontelcompils. dilcolored by partial decompti. Analytical aw, extod.
'31 to the action of elevated temps. (""). .evidence showed that only I Nil. vuup In "IUNII.1,
Prolonced
V ::i Stomlle (over I yew) and shock by blow. They burn in a Is diazatiied. Thus, the drcurrini. of the diato products
! free narne without a flash. Then "us. (freshly prrpool. Willi Wiling dil. IlpS04 and the treatment to( the drvtonipri.
1 or third) react in an sq. m%pornsiclin with azu components irs.idue with LN)"'o NaOil jpvr no reulorcinal anti hydro-
i;. togivr dyrzol the manic color and tinctorial strength as the ~nnonc, r"p.. but the corresponding m- and p-IIINC#11.-
L-Punding simple diazonium salts. Cu and Its salts 1, Identified as di-lit derivs. In ully. and stability
catalyze the decoinfou. of the complex diam toolupois. with these itionodinin eximpo1q. air Rilinitoor too the curriales duali MOCO

00

.
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I-94

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-00

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age

300

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if

nIpoll. dcft-l ibell in Pat I I I AlMVr. Wile" coupled a it h no
W-,..
A:
I I A tl1LL1,kQkAj LITtItAltollf rtA%jltKAljC*
TS AT 00 111; n :0 It op 04 N
2-C.ol IrOl 1. 1 hey Ilive lilt t it oil lit town &sit dvort o it gi kxI
Nat)II he !ago
se dye.
f.14tiless. %%Illrll treated With N
are decontiod.: + ~060
PiNaOlf - 3 ll,NC4114NICI61froll + alfro + NAIPOI +
NaiNliAh (d. C. .4. 31. ROW). o-C4II4(NII,)e rVACt11
slu) with hett-m4tilly itridg. but the resulting cryst. ewnplex
Vodioi foorill Willi IIN(h Monte o."llpkol C.11111"ll. Ill.-lipal's,
of timpling reartitm with ara "mulwincins, anti ~Wbly ts
Ides of the ly
too, 1C.H.N.I.M.M
siv" Analvoils rmitktin*. C. U.
C.
;o
AA I S 10 a 0 1 11' 14 1 Ah
if of it K I to

0* 0 07
10 0. 0. a v u jd a 36 u a P 4 41 a a &AS
A
00
A
POOCISS116
-4 1# Soriat. it. 'i -don of a salt of
Wd'I'Uto a "It of I-nsphthyl-
If. V. Agistow, A. 1. Itaryshev and M. F. F-61614Y."' J.
Gr*. Owoo. (U. !1, S, R.) 10. ?A4-1Xk1(1WO1. O-L C. .1.
31. 71731.-Tbe translotutatkm o1 the No %sit (1) of 1,4-
ILNCIJ (U) into the No ult (III) W
2,01M.) an heating with %Wd or CJI, in the ptes.
ewe of Sk proceeds vk the No sot (v) u( I-ftphthyl- -*G
Suffatak NW (VI). slace 2"All amis. of 1-naphthylaraine
from VI can be detected in the reaction mist. and V yields -00
0, IU on ::'%onOdntQkv)t 1. as moneously stated by Beritcu. see
J: hdm m (C. A. 33, 13(W) for the cme-
spondLug N14 salt. The K, AfS and Ba salts of It tcact =00
in an analogous manner as 1. and the X and NIL salts of r0 0
V1 react like V. 11 is not rearranged an heating. The 00
yield of M 6 particularly high (73.77%) when 1 is boil,,l
IN
ith QUitIOUTIC. Gertrude B~xcnd too
002 U09
400
rkeOCOW UUAU.r't4-
rh.,~
A I a I L A Of ULtVP.GK4 LOP.P&TIVE CLASSWK411016
lorm, a a
u U AV ;0 UTf A 19 09 U tt It K KW
*to o 0 o o a 0 0 0 0 0 o 6 1 0 0 01
:_OIL.*~ O.AJ19-0-A ke a q a o a o 0 0 o : : 0 a SIA

10 0 0 0 o o to q o a *.6 41 If 4" Fi,
a
'
a is 4 is V is of 0 a a i'll a, 517 if
111 It APO it 4:4) rio
, 1
1
,
N
, !t 0
MIT 1 1
r". 4'2o
A
00 A B . " . . . or " . . " a a I It 6 V
1
1
.
1
b
__!l' -A^* - _'-. -. 0
*#a 1,1101:11011 Alai 0,1104,11MIt Dr.

00 The MUnWorat series. 1. Tblatithromor-.1 sulfamok
00
shor"Iyaka". J. (;Va. C is"o. C. S. S. R.) 10. fit'- -M
-00
60 a Cell. still AtClj give 744 A% lidantfurne

0i Which it "Xidued by CI(4 lot orI46at 110A, to givr 93'e,
thiAnthircite disullum oil, tit. 321'. rills is very incirt
0
t toward Plillonatins &sorcil-, and only When brat"I lot I
hill. at 140' with a large curols of 012% OICUM in a scalcd
I
tubc does it give "A`4 Ili a moplei"Ifomoo: 41fid, isolated as the
Z 1. K mh (11). No othri coonjxl%~ can be obtained. The
f'
two 0
, Nil.. %Is. Nil. K. Ca. 114. /it. Al. Fr, )'It still AS -wit,
00 131
I 1, 1
Ati, Jewlilit'd. 11i'llm It it Iriluml low 5 lit-. Willi 111.1. .00
00.3. A( Iftil, ill file litclenvor 44 a Hill, Ill 10'. it Ill.,-, ,I Ifte

*0
irildir kill), drN.o%j.-. IUV, When Ill il
k1f.
in a walord to1w. it givrot a vvty
o
I
J
ll
i
Nil
l
1

00
ll! volfr
'
oil J.F
ll""
. sl%v t
Mollie grit
and
. too
'jaoj4#. Ill. 17n". whro 11 in Rf'ound Willi 14:4 and agne
04F a
1v
-
11twis and livalrd Ila .5 tits. at 110" 1 78% of a 000
00 z
Culinal will$
id
"I. 12W. which f.
by oxidiling Willi
the cow 1. prepod
P
00 j.
IlOAc. tr~iun of 11 with NaOll gives PhOll,
CV01 I.
feiroudnol and p-110C.U.S6411, Thrmor facts Voter! thAt
'Allicination of I occuts in 1114? j1-1001ifiUll. I M. L.

A ; ifllilll
to 0 0
too#
A 1 6 - 1 1. A -1 fILLUJIGICIL 1.118001149 CLA111FICATION cc-
58 too
smicaj all 049 cog AP)MIC"t
~11:1' . - - - . ___ -ei"i,
211-n09" I" "
0 .9 1 14 L 9 1 old 0 a a I w st s a 4-3 4 V
aill
it
: : : : 0 0 0
N 00 0 * 0 0 0 0 0 0 * 0 . : : '0 1

dm** **,O*o 0 Olo **Go
4
00
00
0:0,4 0, is 00 *0 ol 0
0 0 0 0 o 0 0* 0 0
0 0 0 0
w1Mw,,YTL",A IWO It 12 11 All atiomp*411000 41~0
A-A
PROCISM11 &"a P110011 tilts
Dim grpo#M. IV. Us Wuncs of p*bydrw
ed
n th
d1awdutle
of
mes
0-
i4
o
e
s
auddlawbe. V. V, Kailloy and fl. 1. Stepamir.
jl!rx. CkM. (U. S. 8-,R-.t1O.-T5I0-23(l940); cf. pfc-

00
vdln lotr.-Thtinflut=ofaddn.o(glyccrol,niannifol.
,
xlurwe. nialtow, latc-nale and
(CIIA
d=
raffulose ou izAtion Of IN-C&IIAN110i (1)
wrA Investigated. Tbe ykM of biowlistso clatupd. famed
Was found to incrtax with the itilmloing vilA. -1 110
gmps In the will. of the added substacim. It &Lw in.
creased with tht rovicn. of the added sub%tfinCT In boll).
It "s altit found that the addith"i iJ sly(vtol inct tawd tilt, age
lited of the stso-coupling wcactim. %% rUrvint. 114 table.
and 17 Wertifirvs %-.v given, jahlro J, Hi-fitill
Zo 0
MA,
fig*
..e -Makw- l-, zioi il
-V. a - i-, i- -11
V,
U n AT PO r T A a
ip to ft ty it ~11` $9 Olt xx 0119t.
:*:iooo 0 0 04111, 00 00 0 00

KOZLOV, V. V.; ARKRIPOV, B. N.; SIMANOVSKAYA, A. V.
"Investigations in the Field of Diazo Compound--III. On the Complex Diazo Compounds
of Phenylene Diamenes With Heteropoly Acids and some Pigments From Them". Zhur.
Obahch.aim. 10 No. 8, 1940. Lnb. of Dyestuffs, Mo6cow Chemico-Technol. Inst. imeni
Mendeleyev. Received 13 Oct- 1939.
Report U-1627, 11 Jen. 52

9 w4
~Waj ,
00 A
60
009
son
004
so&
00
ova
00.2
so
OOM ii
0
so Mil ii!
4,
0*000*060000000
a Is 4 a 9 a 0 0 al 4 a 411
Way
4144w: /d
g certain nuirdants and in -'-t-.
with 05~i=dnym The colors were clatividembly
Inure Its Ilion these of ordinary dyes of the bentrate
wics, The IA-, 2.0-. varld 2.74movacra can InteSSUY the
vol-w in a mixt. with other oxidizing drgs. Dihydr*XY-
n4ilithAam caa be used (at the synthesis of vathWlle
IMMIS In payfftephy. . W. R. He"ll
Chem. Ab., V01- 38, March 10, 1944.
&ITALLU46KAL LfftRA1k1d1 CLASWKAtCO
440 aw 684 filial cave I filial Oftv All
Ig AV 00 Ail; 0 a 0 1 1 , - f r- I S a ew 0 N v I W IN 9 3
ang man -.1y"AlA
00000 logos a go 00 & 0.000000 :190 * *000 see 0000000.90
.00
.00
1104140
2 -0
ago
0*0
go*
000
so*
400
#so
4040
boo

ti is of NTT
WAS old*
.. I i Y1
so

00 A
wo wim X. kwb~Wg Y-
ja -00

90 V.
'I
;
A
W
:
di
y -00
ater
v.
.
u
p. O
t$
-
d. C-1. A
it "m AMIM

"1120*6 , with uddike. ul
b
-day"
=fo
!
~
i~ -00

so WWAWOAA
t lk
l.-- YkkU
W*
%Mtj kk
= -00

*-8

o
act,
to tb Ii!
of
.00
...
mtbF to the (H-011 -pd.. t
at Zk)+P* lovisal the Imestiesults. Thembotsel- 0
u rwisdat amill l1kd WM hydrimulAt" "it
Und" 4hd aban cuu-
AO
a J
3
F
J4(S(h11)
it W
U
g
.
j~Wj
chtkmu cauM be aL., to fog of R"bthmt~W- age

0*-0 clad.

0'. Mw &w =.pnxhwt w. L7444
do*,, M. . d'*Or"O de"p. 0. with
too
g
~

001 ?bNVQ tin pwduct yWd# -P ws-4u"- 40muff- goo
0
6. Lt. KOW11puff

X*d

woo
11*0
00
A t ONT q"
94
w

14
w)
t
*$'0 1 Olt 4NO 426
* -~-4 4
I - F -

t AV 00 All; ; AM
I fm a a I I IN 04 11 A 4 3 1 V
v is, Or At n A x It K a a It

0 * go e 0 0 00 0-0 **A*** **a* goes 009

*11`1 lei lieu 1:11 a It 0 41 W IS M a a It a IT 0 to a As a ape
IF d It I If
to K,IL,-j I- d- 2-1-6
00 A A- -00
o*P i 0 a VIC I S
14, 11tianthrous series. U.
ill dtoulfoost. 2-HydroxythlitAthrmodWisifeav. V.V.Koi-
a Wit anti N. I,.*akhov4Aya (Moscow Clicin. Te-M-N4.T.-
-Prem. Chose. I I Hk-2D(JM)(in Ruslan);
et. C.A. 35, 4100.-N3 2-thLitathrenesulfunate 3.10-di-
At
NjOlf. 0.M g. %'4%*(h. anti 20 -60
th,c C~O tewti-i "t4y be psittiAlly c0d, with EtO. CIICISI i
%vh-ne fituit the vallitial reaction mist . but. due to its
great ~~Jy. ill wiver. the mother liquors still tire the Above- I**
inentionel ilye. It was poqiitxlc to lsobte only 23-M70 .00
Z-hydiaxylbiaouArtive 5.10-disulfitim (U), m. 160' (dr-
go -E sp: con pit.) (from EtOll), in a state of comparative punty; 41440
it xMill a brown color with FcChp a btack ppt. with NH.- 00
Ax'No,, a white ppt. with Cacil, and a Yellow ppt. with A
ljr wlter. 11 wa3 acttylated only with difficulty on be-jl-
0 ing to M* with Ac4O in the presence a( a little 11,SO,; coo
(1) Ac deriv. tn. above 30)' (front F'tOlf); treatment with
1
It its AcOll Save a dib-rowde. CojjsO.SHrj, in. 150.5* 0
vc. witcr were livalvi In in jutocLive 5 lirs. to 19U'. ifroinAcOllorPtOll). T'licatono-Oll conapd.z=7 also ',I-**
the mist. 4cii,lifivi to Congo red with 11C], evapd. to be obtained in 17% yield by conducting the aut"vv
aryne", and ext.l. with UtOlf to give 0.5 g. I.Jt4iky- reaction with 1.27 C. Na sullonAte, 2 C. N&OH, and 20 2.1,00
~j!
droxWhijaArems 5,10-disuffoxe, a Alce -yellow man, tn. cc. water5lus.at M-90% with isolation of the product by z0 9
197 di-,Vs sail. yellow needles (from dil. HIM); Pb =it, HIM citn. of the evapd., acidified reactlim mist.
Alto
yellow gt*in% (Irml HIM 1); tbeK. C4,,;.'*, Cot Nit and M. Kowupoff
IL.'x jalb arc reatfily tiol. in water and 111011. The Ag oft see
IMMOrly ". In Witter. Tho above expi. was Micated.
ing 2 j. Na Nill and 2 g. CaO In 2) cc. water U hirs. ac age
U, t:*
IM) 11" .. ('Zwed by "ifimtion With 11CI to Coope red;
it ji the "a. ~ thtu coadenied withl P-Ditrisantline In
:41 ;' % ?C
4.%L4 WALtIONGKAL LIVIERATU01 CLASIVICATION I rZoo
IM
lot
0 U a AT 10
W tit It q, it K It X is 41tte, tftUon ,,AAA A S 41two '14 larilloa 0 3
i .00
V41 0 0 0 41 0 Si 0 0 0 0 0 000 see* oe 0 0iA

*,0 0-0 0 0 0 11) ,C4
1**. 000 0 0 0 0 0 0
I OIJ 4. 1 4
A h I
004 no
P-JI AND 01CO11114% ~01, 1
go - ......
Tke naph"ette series. XI, Reartatipmeat of the
no)(st of I-seAllool-4-sultook acid Into the salts of I
6 Xplik"-2-nifectic add. V-V~ and ?,I. A:
11tatwC (Mainjim, Chem'
:6 J. Von, C". (11.8-4-R.) '16.
am ozoll. Cf. C-1 - JO, 27441. - The rea"Angriftelif c4 salts of
1-114phthol,l-mmunic " Into the salto ot I-Asphthol-2-
so 4u)ftmk- iscid was fttudkd In reopect to the c1lect Ld trisill.
00 wid Ouse, the restills, were mnptrtrl)r min"out Iti thoac
00 tet-atird eviller (Voroahttov, ef s), V.A. 33, 4:17.0) Its
comorvitom, with the forination of saltsof 1-naphthyllamine.
004 2-stalloode acid. The r"Wrancense"t apilarently J*txVcdx
00,3 throtigh the ittlersurcliste fornsatim of a I-itaphthol sulfate
esict; the reaction I!& clortijiletely Inhibited by CaCj. Tbc_
'%,, with ittax. duratifitl 0(
000 felop, range h-Aled was JW-2
f] his. in a typical exist., 3.23 g. IN& I-olophthol-f-sul-
90.3 14mante ami 21) It. mand we" heated to VW 3 bn. to give
I.ttaphth,44- and 63.47, Na 1-nmph1h,A.2-.uJf-
-Late. The the productik was effevit4l thiotish the
0e K smIU; saltin4out with KCI pptd. ottly the K I-na fithut.
2-Sulfanatt, the 44so.mrr retuaining Its u4n. G. boil. K.
A j L a atfALLUR4KAL L111441401 CLASPOKA1101#
IF
0 1, p to o`I W, I it to m a to it 49 a I III
0 0 o * 9 0
W
a 0,04 0
An A Is 0 ad a 01 W Me n I m a 4 9 W
0 0 & 0 0 0
-Zoo
0
00
-0 is
-00
000
ago
COO
coo
too
99*0
44
400

rdp-- 0 --

I t 1 4 to if Is if 11 M JA Is is 9 At to a of 41 Ollw 4 led
-A-A- b t, P Q A 1 -1 _u ~c W-ju., J- 1 9 - .-t-

CA v 111-1 A
4
4
t
V
V
K
h
-
,4
t
,
Dane.
.
raqu
I-IlydFosyant
-Xf,-
-
I-Amho
,
1917
:IiP
68
MO
S
R
U
S
r .
.
.
r.
.
,
.
,
.
I;g,wov
4.
,
'ill ilmor'lliflulk. arl.1 I% actol u1""1 by Ile I'llrdil. 11",A). ill
'
1-99
so . ll,.Wll
Z0111
-,Qo

so
0o
to
as
0
00 zoo
00
00
0 0

ho 0

1.90
floe

I'K 9~1 tj
it "I
0 0, 0 0 e wla 0 0 0 0 0 0 o, 0 * 0 0 1
0 0 0 0 0 e 0 0 6 0 0 0 0 0 0 0 0 o 0 0 0 so 0 *go 0 0 0 0,40
0 0 0 0 0 0 * 0 0 lo 9 e 0 IS * 49 0 0 0 **(

KOZLOV, V. V-
PA 15T46
TY902AChemistry - Anthraquinone Feb 1947
Chemistry - Sulfonic acid
"Investigation of the Anthraquinone Series: 1., The
Study of 1.,4-Anthraquinone Disulfonir, Acid," V. V.
Kozlov) 10 pp
it Zhur Obshch Khim" Vol XVII, No 2
Synthesis of the subject acid, and studies of its
salts with metals and amines.
15T46

KCZLkiv, V. V.
PA i5TO
I
IU13M/Chamistry - Anthraquinone Feb lq'7
Chemistry - Sulfonic acid
"Investigation of the Anthraquinone Series: 2,1.
Chloro-4-Anthraquinone Sulfonic Acid," V. V. Kozlov,
5 pp
"Zhur CYbahch Yhi?n" Vol XVII, No 2
Subject acid obtained by action of chlorine on 1,4-
anthraquinone clioulfonic acid (see above) during
its evolution.
3-5T47

a- I I I Ask
O= ina~
M
4
4

0 But". TV.

l.

ell

of, "Itwitaw
= . Vk'V.xGW"WWK-I'KL4kl1-VW .so "Cl,1101,41
)".'Wit, Tech. Init. J.41 F.
~
d I he
i
h
h
00.4 Ahq. I,
S.R.) 17, 302-01(1047). cd-
it
41I
T
f
h
1
It
i stuAw an
raqu
(KI nt
a V " to ou"1011YOrate
In"afts
ranging front MVV
t
C
so., .-
reattwat o
ant
rmane (
) w
t
of
,
higher couch. "is to significant amts. of ox t . .
4
showed that at -U4)" oil to 21)':(' AlIthlAtillillOSIC I% -1blAill-
00 C wta, principality anthraquisione and d1hyd laut je~
TZ able, while at 70" this ti". to M'16; at hill' igililKwit
a
l milli% an olklation of I under thm Mulition, are stints. of C am funnni will lhk4 Is the limitills; trolls. fur
it, -Ole of tile
CulkstivIr
cti
ims
e
ti
d
lli
l
b
I
ee AIM In corves, showing the effect of tcrop. find of the .
t
(
ve al
a
a
i
on r
r
i
.
9
courts., and knit. of 11,s0, tmril. it 1A M..'sunittl that Ithr 4kV The ititht el.
reactivity it( 1, no smittloation (Akm Isl ~
'
0: 014latlaso t*krz 3 lislelwildent cossirlin *Idcb least, r"p" to
dressin.
cWtil
is
uilloile
and &JIls
elff
w
mlil
4111hra
r lle Isw '4
Iftlive alklAtive M(st, (it 11,14 1. i4 tO W.". I
His" ok-unt IUA-hr, r"tril4m) siv" imitir rrssuti% ill dult
00 u
u
ir
ous t
v
,
y
,
q
throw. Pure I wa% pstro. front ant brallubustut by rittkic. o4lailon 6 the stilly strat'li-s, oh C 1-mousis 1wisix
lion with At dust at 30-10" It% 1140
140 In 1147
yield omcwhat inore lisrusiousivol, (0, Orion Wid, 1.1 C list -
90 4-
a
(ortimit, in. M-40"), followed by purification, which is tuition even at.2t)'. Whets Its licated tirls,
m thwrrtmd (or
um ifr
t
f 10%
h
l
*0 43 Initially the most dilfictilt operation, by cmtn. from -%fclr
4 "
hi
di
144
CO
h i
l
i
ld
hil
1
2 o
o
e
ng ismill. o
wit
Increas
mooloullonation to a 5-fold most.) the sunt, Of utWh4n&"1
sol) -
mme
ate
e
s
c
. in -
e
more
. w
. w
y y
crystals. give the pure Droduct. M. fat-a". I (I g.) wait I rapictly drops from HUq- to 61)1,'0; wiIh2?I)`~.r%rrxvoIruuA
'
00,3 added Vnisdually to 15.cc. JIT504.11[sO with tirdng at 300 ,~ 01CUM CX-
,sit 100' 50% of the I is carbotoral, white 4 60
'
and kW 2.6 hn.; at ter posurinf; Into 75-11 1 cc. Ifso, the gives 40% 1, 3S 5% dihydrulUti(hione, and
cen at OG-70
13.5% anthraquitione. Addo. Of 1011311 AIIII.S. Of Ni[,Vth
crude prosittisrt **A Wiclul Olfe wwlstd thollo4hly with 'Or NJI96044sties rotcAu-cibesulloIL-ttioilfvActiolI totAke
wattere and driell t NJ*; yjVI,I 0.147 S.; ritylills. froth Mer- , Plactit, tat sonsewhat rftfucrt the client of the oxi'Wissa, at
N114VOI of At du%t sitoln (he oxidatiw;u almoTt
00-70*
11 CO Pee IK4 g. I asid 1).45 g- mixt, of aojhrkqsAj,,,4. .
coospktdy. Attila. of SIC], IL&s a simiLor effects only 10%
ALAL. hYdrodixothrow, its. The wi.n. of the prwlucts
n clo-c Of mixts
tvnt
of C wi,, dow dilsydrofiallithroce being formed undtir conditious which
.
g.
by tits. with C'114' an'llyzing the ext. arcording; to the normally yieM 20,17. anthr4quinow. HgSO, promotes
idccrea~l! of
t anits
i
ifi
i
b
method given In Part Ill, anti Sept. it 1"103 ivincipalcons.
is by extu. with cil, (witich lesivet; tehind the bulk .
can
on
y s
gn
tbt oxidation react
urift"ed1by,50%). Na'SO. promotes the formation &4
=dilAydro,fialithrour),essapo.of the t.
anticryurt. dilsydrodiandirosse but hindtTs tile formation of antliza-
*
,
(Ma Mc%CO (which vitra"t incM at 1); when the t. mdlifi~ the eilect~ of
itchisone. Raising the temp. to 100
w
tile ukilit
~ initiall
exid
ont
in
d much 1
with ki~~ AH Addidvell. G- Sf - KfWAADOff
.
c
a
e
w
.
,
y
NlcrCO. Air-1,lowing of I x. I in 15 cc. 95.61,'o HsSOm
12 JIM. at 20' jave ahtsM a quint. yickl of tilbysiraWan.
a throw, in. 1130 . When I C. I in 10 cc. 95.6% lf'SO4 was
kept at IOV 2.05 he%- in A %WW Stream Of COr, there WAIX
milli, lac "V Lt,
obtained 0.:.,
0. 14 S.'Othit, OjEkjajtDgk
U 0 AT $0 . I ~ 0 9 1 1 V is S 413
it It IF OF #4 IF zt IF 1 1 An L N 0 v R)l
IT 0
T*16 004 4111t0 0 & 40 0 0 0 0 o 0 00 0 4111, 0 00 00 0 0 a 0 0 0 a 0 0 0 0 a
"41110
*00
-06
'00
Aloo
Zoe
I;o o
000
Ice 0
Oleo
40
00
18309
No 0
0
UOO
kee

:: *
U U 14 U if to
4
ubwoo "riots. V. ms-Salfaisic adol of an-

OOA
.0
i, raw V, XorJoy Mendeleev Chem. Tech. Inst.,
M ). ' ,
DKMW Liles. Ckonoo, (U.SS,R,) 17, 747-U(1947)
(in Ru"ian); cf. C.A. 4Z, 561g-Anthront (1) with
Itrual
okum or MR0,11 gives ws-axiArants4sook
I
a).
V g.) In 2) cc. Acoll, treated otw 13-30 mist.
'
at with 3 g. 007e ofeurn, heated 6 hn. at IOD
.
oes l"red Into 7&-Ino cc. HsO, and filtered. gave 0.5 C. U"
vroduct com
osed of 80% anthra
and M%
uitione
p
i
,
q
Mited dihydroanthrone, anthrone, and C. Concn. of
09 the filtrate to &.8 cc. gave 0.15 g. (lack product (11),
which was purified by charoaf In hot sq. HtOlf; It forms l
minute jorisms. which have no m.p. and which bydrWyw j
e9 tws heating the aq, soln.; I (I g.) and 10 g. C1190,11f

00 lot-Ated 3 bit. at IM " and treated as above gave UA5 jr.
crude insol. product, which on brief boiling with IftO
04
0 gave 0.46 g, Insol. solid mitt. similar to that described
show, whike concro. of the sq. solot. gave 0.3 g. Buffonic
h
h
d
h
h

It at abishIr
t
Plenf)cal wit
wit
okam. C
antes
W-150*
S
7 h
i
ll
d t
I
f
f
i
f
i
in
is. or
oo
e
o
rnm
rom
t
me
emp.
,
chingr The result, higher temp. merely Unno Ing the
amdativr reactions. The sulfonk arid on boiling 4 his.
with water gave U.90. and 1. Its well as trac" of anthra-

'j,
0 1
4
A
1
-quinone and bianthrone. The sulfonie " (ormt; the

:
~ [Alawing salts: N4 64hydratc), yellow needles (from rill.
1
4i 131,011) which Juse 211,0 on stowage ever Ifs'Wh: di-Nor,
yrilt,w-torren 14-11" Mm" all. P1011): CO irtilawIlre"
'
nrefle% (hom 11%0), difficulily
-4. in W4 11,0; Afg

a smAir,
lf'~" Pb. plAt", Ulmnal Insol. III
11P, 14011, i1c Amil, 11W 4flol 0144 ASSigneti 1111P 31111117~

-71t 7 F4
T 01,
-V-" --- 11 - -P-
U sor or
a it or at at K 4 or x it cc It It it W
~UM
o,,dyds,
0 00 0 :*0010 IN W
a 0 ;1*
0*009*0* 009
9 if A j6 V 2 30 4 40 a a a *k 0
- -coot 111

4P

of uu.&4tWoO,,Voak on the beals 011 eltmen'sory
Anthr""O'se -00
M, 's
sis P-bIc'*- and ev"It'lloo Zi
al
d
b
=
r
Y
in
y
outol biant
dustuc 11011011r3j'. change Uf the YT'kw
go 00
"Ime
,
to-
CO&M of the mor N*as4ll tot ,,ter has an o-quinnooid
the
Latt tow, indicates that
1 . t-ff
G. %I
across the a 0 0
gtrcwture
a**

Coo

Is 0

7 -co- I
-
L'~;V
l 10 *
W a W I I It 14 5 41 4 2 1
if 1 1 Iq 0
114-
A

0 14 4, Jj
00 A,
000
00 A
00-
0* C
0611
0o
0
:0
0*
00.3
OOV
:a
00
04POOOTOO
I I
4 it
0 00600000009000
a Is 9 a 6 0 At a a 0
tt M-M
krdwatiminonit Swiss. V1. ictwe 4 dAwomwmk
add on anthraquiume. V. V. "&v IMUWM Chrm-
Tft*nol. Inst.). J. Ap*arMir. (US.&R-) 20. Srt-
ucncr
-980947)(in Ru%%L4n); cf. C.. 1. 42, 1231f.-Tbe Intl
of exce" CISUM. time. alml troull, Oil the rmtkwt of
CM)%II with anthmijuirione (1) w-AL Intcalgatiml. The
reaction p"Krr4ls in it complex manner and at 1.15* yirldi the
-%ulbi (U). 2-chlexosalluetyl (111),
following defivs. of 1: 2
2-chkwo (IV), dichlorn IV). br1rox7 derivs. plus anthra-
cene derivs.. w1ducts of Cl and IICI to 1. as well as un-
changed 1. The yield of M as the chkl pmduct
can be obtained in 3 brs. at 135* with jo moks CIS%ll or
with 18 moles CISO'll and I mote 0070 olcum or WWI
sulfate. Sullonstion In the presence of fig doft not lead
to I -sutfo derivs.; almost all the I Ig sublimes in the form
of IIICI,. Srpn. of I and 1111 is best done by ligroin, but
fractional crysto. of these substances Is not very salis-
any
factory: hence. in view of the rather low content of Itc-
ondary lwodycts. the analysis of the mixb. was best done
by sublimation of resicluji I (temp. is not given); M is
esid. by difictruce. 1 (tn.8 g.) was added over 04 hr.
at to= temp. to 11.7 At. CLSOall, &IW which the mixt.
was heated 3 hys. at IW-3'; after cooling and Pouting on
let, the inixt. was m ly boiled. filtered at 80'. and the
filtrute stul Aq. wasrigs were heated to the b-p- and
treated with.10 ml. tl)% Xa,80.; the salted out Na Salt of
H Me") is filterrd off in 15 bts. and rect"d. from IM).
Z
At*.SL41 -tIAL~Lllk.AL LIRSAV641 CLAWPICA110M
conv"wxl.,( this to the a deeiv. $IVTSSfv
1, M. 24-6-,
thus showing that the primary product if. 'rho ppe.
("Minell ffl-111 the naiginal resctim Edit. asul Ilet) UUWIV
m. *U--8* and M Sublimation gives I (M.8-
0; crystn.
from solvents (unqwctfird) Permits 603111110111 of 5" 1
. - U.
111- Will' (from ligroin); no ember products stem ISO-
fated. The use of excess Ci&)Jf gave addni, prorlocts,
summarized Wallows:
Na salt of 11, 2U.2% Ul. 1.5% IV, 2..5% V, 1.5,; brlrmv
firriv. of 1. 2.0% hydroxy detirs' of qulfiwnihraquinont~
ivl),3.5~tanthracrizedttin.,un(ill.151 adductsoiCito
1. (2)12mok-sCISOJJ: 40.0,2.6,39-6.2-3.3-5.2Ati.o.
5.6. and 0.21'. frsp.; (3) 19 moles CLSOJI: I I.S. 0.0, U-5.
4.01 7.5 6-0, 1.5. 2-0. Arid (1-155. r"p.; (4) .0)
moh~
asmil 80.0'i. tram. 7.0. 9.0, 2.5. 2.5, -
Mle V referred to represents be mist. obtabird on trt-&t'
inent of the motlu-r liquor, after wpn. of 11. with byl
1~-
chlorite. it is aplarrotly a mixt. ul the 2.jj- and .1
known. IV was estd. by Cl nalysi. of the th....k;;
washed ppt. after ice treatment and by fractional
c!yxin.
(it the sublimate from AcOli. 11 as by adsorptixi ot
AIA from PhMe "n. The as we
VI wen detected by the mkw
change of the mother liquor an neutralization by
the mother liquor with hypochkxitrs at III), gAvv a crude
hydroxy chloro deriv., m. 2.%-M'. while crystn. from
AcOll gave COLOVOlfh, m. 2D4'; although the stnw-
ture Of these COM-f-li- Was nOt ftlablilb9d. the cotot
change to red an twulralizatino Indk-Ates a 2-011 deriv.
Crude III on bettling in sto 111410CIAVI! With little gave Kj-,
-41114111
-4110
.00
1-00
.00
-06
moo
=00
1;0 0
;, C*0
ro 0
4,1111111
Z;O 0
1940
300
moo
C200

Tb*uWottationo(2.J'-dinaphthyltutione. V.V.kq,iIus
-0 1111. S. TuIlv-.tn%k.4yu ~ Mrodclivv luxt..
;-J, .044. Nauk S S N.H. $10, '-"1:; sit 11474% Client. 7rodr.
lo4g. 11, _n". is. rhr W fla, Action of on
air rItirnirly Iliffivoll I., millonalt' illulty nor-
m4l runditionst- The avid onist Ili- 4nird, lilid nird Ili Urge
r%cm. Ile min. roncit. mquired is, litudoce slow %ulf(init.
linti tit 100' %hrit Itself in an e%r"% equal Iii M times the
thrtwrtit-ul aint. "a% A like rilsrr~ of Wr; livid
,ullonatni the xtillmir m I.`- L1.1)" is ithin oil hour. A SO!' is
vii"- of lite (oth-J. on innaostallana t Ion)
slid not produce stull-mallon tit ', Inv. even at l(W. Nn bet-
ter resilill were I,bt;4jn,,J bY Irratiox lite bulfolne In JfOAc
with 20 Wce nicnin it br, at 15'. The adifts, of I0% NRr
So. Well. oil the ~Ilrotl. . the traction some-
,' II,It HICAUW --f Ills no I, III lite 2 naphthalene an.
Oc-1, the J Ow its-itt 1" 404". I's file
'Hitibaritultril pt,wincl I, vIr,v xbxhs. R~liwi Issisduct,
lepts(Int are' 0- f7.2_IItNSCa,If.h
(If!, last tellil".
lAw,url the fissimown,4 I and 111; at A1.1111 IVW the 6,11111-
tioat of III was already thitht, while at I&V the munii-I
product wim 11. The ill comr.14. were tint brominAted 1,v
while the mons; comild. took up 2 Bt
atoms. All 3 sulfouir j4-id4 %hoierd weralz surface activity
(ensulsifying porrerl, Alkali hiflimi. rJ the dioutfametand-
yiekirtl di-1111 ilerivIs. whwh couhl br useif as new aso d.~
romposlesh. fixpll,: 3--(i r. (2-Coll,VS(h, in. 11W, Wd%
heated with 30 times the theoretical amt. of conril. INS is,
the PtodIII-1 Jklini'd intill I(W)-*-Xlfl rr~ Water. filtered Oft; the
tanchangesl ultone witshril tint, the itasibef liquor tind %&Sh
Water liCtItIldift1l 'A ith IIACOs. atIll the filtrate from the Ittit
cmird. Ms. It's firit. the" the- ILI 'All of
1. 1110 1,111r.lit. was rVAINI. to thyllem Just ritid. will) W."',
ale. Th.- rt'idur was 81111'.1 Islar 1; It w4s obtAlled front
The Alc-~ Vxt. lirrivm. ill U lite Ila %dt with jlSAJI, yieLIC41
fnv 1. a,( it hy1r.-K-,,jAs: nza-. tit. 64'. The its ult with
VC4 ~i Ili,. A[ IM' vi,,hIiii lite dirblurille.
-nocti"(1-us C.U.. xvicur. and IIIIAO, tit. =', :llls7~ hi
drolyled ill 6 lirs. by bralling wilb W.I" ,1 ]IN)'. "sulpittrIT
hydrnlyged by aq. IIOAc and aq- ak-.. fnerned esters with
anbyd. "~ Missif,,ndmade, ptatirkto Innis MrANO
MeOll. ru~ 21W; di-miloffaxilid,. ptattlects f",nt PhXf I/

C.116, its. 'rig'. 'no Ila $aft. CSIfoO.SIiA,AjI,0 vlv.W~
front wairr an mimbedrons, C.11ol)"Ba-0140 111,111 "Ale,
as ilmod.,brilrons. C.11,043,11a.711,13 front I'll. ak' l-1
~Imfrtpla; P& oak. plairict. Imot 11~0)e;
1
1OAr. in-A. let water aml 14011. Cu imill, greenlidi or"Ib.,
Ca nit. thin ureslin; Pr ' ' '. Ni * I '. a ','It. pl..t,
trip; till salt. granular, insol. tit water; Na. K. Mll. tit,
alld fig milit. readily pol. in water; axilime salt. C01ir
"A W
. AXNtIsPh)*,4IIP0, medIrs from water, In- 17..*,,
bloffiilfimol Jab,
Imm W., In 2W. NOVA. *,I It. M.'WAP144.
IAN frtint L L&I )WAr. tit. C110. vrov .4. In 0,11. .4trill,
and 143% ty'd"roly" by floating *till notti 6 loo A III) ''
still otherwise anAkWou., ill the aichlothle of 1; dijullem-
W940, Allt CIV*tAI4 ffllnl NIWII, to INX% ill%olr ill VdWt,
Vill.. %virne, mild C14-o"14, A-ITS-m.; dijulfe"d a dow,, ope
lips foAo MrOlI.C.11a,
*-,)14c umiles from Ilk.;
nic.: btausdiw Sak. obtaint.1 as Jill ody fraillor. 'I be %.1l,
14 other metals and of triany andn" were very all. it, Ila'---
I~Vl. with the a& gult of Ill gave the salf,,syl 4hl,,,d,.
11milro (fill" C.1101. tit. Ifill 7* and froto this Ifir
xmpAIAwhxi,, in. Ill . and 1.6-du him omaphl4olt pit, Ill. III*,

o
0 4
0
0
00 C
0o 4
0o
*0 of
x
-3
Poo
0
Anthraquitiono series. Vil. Suppression ON the Cat- f
alytic effect of ntatcury in the sulfitattlort of an"al-

nano. V. V. KoLlov. /Ato'. V&S44401 KAIM. tj. CWn.
evolved on sofit. of llxt*l,. III, I~Alfftotl t~ JIJJ(*J
J. ! -60
Chem.) It. RuWatt); d. C.A. 42
d
;i ,
ll&)s + Sk), ~ IIjS,). + 2 SAIIIIICI, 'I*llr ext"t of the
ation
72wk, anti follitaing abstr.-Ill victor of The eluci reverse reuction, is insulficient to cnuirv wtcquAte removid
the nature of lite %wil-known anlicVktalYtic effect Of N2CI- of Jig by sublimatiota tit IJCCIl. I,ht,,, 4,1&1. (d 111IC4

CWntVfAcq1llg lite j_%IlIIon.1tjl11 effect of lilt atill thus .
husilluch As it is colivrri"I Into has the %ante
'
_1111141111
Ivermitting of atithraquitione (11 to
vioro-
-
ll
the bo
h
t H
id
i
i :141ft"MAWIF "AlAlYlk elTmA A- other lilt ctuillw1ok. This
r
a
c lo
le pfrW114
irvt1l
ll f
fullu"Ic.'r
s,
h
l
d
i
i
t "C" IS Cry" "Wrly 4 "o"(101-Wint M4 IMIIV 61 NACI bill al%l
r so
n
e
different Jig comildt. tit sullottat
on, an
t
y. by other antiraiAly.ts. Thus, in The sjjllowl~on
W :bM C
Oltum. virre investifilited, In the rilowsulfonatiou of I .
I In 160 g. 40% olcutti, with 2 it. lIgO
3
5 btl At 136'

in the prescnccul cotiiderable mints. tit flit, 1160 OrJINSO..
h .
,
ih, ajntq. of Of- anti of a~adfotlic aci4is were, ;jIh n ~i~ a
y the un.
-4 fix (culctf. its ligO) bound
(
-
s
m
h
4
1
r
! '
I
in NACI 45 an.) 551!. *jih I C; NJCI, fix? 'not ()q; 'ith-
, coo
3 It); of Ito; wt., 17% in the casir of MOO..
in
(
1
u
T
u
c
1
u
l
With Jig, IIlj0.,.r IfflSO., trams of flit begin tuatIlwar If' hlxCl". Ilk, .,,,I i
91 Allot 97,; oait~
I PT; with 1% CACI, h
2"'
'"
PO
l
r
"
I
i
l 7 too
Z
lc mut. of the Ill (us 1100)
the sulfunAted pftXIUCt when 0
1
f 1
II
C
I
Z l-
a
.
w
' 2
,
l
, PCI.- Of -110 11
; '. with 1. 2.
A , ,
nd V!,, Nalit, I) isn.1 fix), IA..i Anti X1,3. M'f. Allot ms:!
0
-
,6 (rewive to the wt. o
).
6 about 4
4.
s
%.
I1
h
h
d
i ~
KCN li,-v4 a weak anti~4talytjc ell"t. thu%. witll:l;lnd rja,,,
e n-
owever, II
er
1
v.;
also directs lite sulfunatiun to t KCN. 46 Quit 54. .54.2 still 47.8%. NaSo.. -,,I
tki
to 5% 111[ch, the unreacted I bindi only up to 0.75%
-
C
1l
b1
f th
l
il
f Il
o ,
Va p b, e no R"tiC3tAIVtjV VaeCt at all. The foffi)Willg
i
e
-
era
or amt. o
e
; it con
its wt. o
g
s
sublimeoi, anti conticeLsors on the walls. At 1330. the Wy.
' facts are quot"I as evidem, that tile atill,mat"k 8,,,
consi4to in supplying IICJ for the ~cjjou So
+ IICI -
v olrism is very slight And no CV Ions ire
of JfgCI# in 3.61,~
'
'
" ,
SWIClo which convert% the hulk tit the fig or fig conllxI

_1
J.h",
v olcuin, one detects cqWv. units. of,
detectable; in .
into nollioIjAcd IJSCJ,, thus ensuring The removal of fig
N

Jig** and of CI-. but. on cooling, 111W4 Crrtmill"M In-
.
frM the reaction illixt. through sublimation. Pre- o 0

C
1
t
stead of llgCll. Con~rqurntly. In oleum. I M
's
#4
f
limingry boiling 'it Prior - onitfoilattion
L t
with HCJ too
1
oo
1
i
1
compd. Into IISS04.+ 211CI; in strong okum, .
boo
A 14 1 A al IALL to06Kill. L 1111 AIUNI CL A tWKAVIU 0 9 8 14 41;
old., 411.411 WOO

Q_ ON IF &;*WfW*;: 1 ::1141341 9 9
r 0 At a Of AM Z
0 Is I ; WI
~111- trip 0
0 0 0 000000 e 0 0 0 & 0 0 0
090000*900000 0 0000*000*00-000000*00o

0 0 0
ooo
0
oooooolooo
::::::::Oo Soo
$00000 :
0*0
000
00
so
so
00
suffonation to 0; while with equiv. amts. Cie Hgs(),
and Naa in cotled. HM~. preliminarily heated to 100-
110'. the product Is a; with a mixt. of lIgCh or lilso, 0
ith 2 CqWv2. of N&CI In 25% oleum. bewiftl as before.
; 00
I
-sutfoole ac4d Is obtained. II;CIs alone In 211% olcum,
preliminarily heated, gives a. but with an addn. of 1%
80
liCl it
Ives onl
S
bli
0
i
f H 00
a
.
u
mat
on o
g
gClt brXins
y
ottlyafters time lag of about 30 min., itscribed to formation
00
1
.01 the complex 80,HCI.HgClg. The rutchanism of the 00
anticatalytic effect of NaC1 con thus be sumnsarit"I In the 010
scheme: 3 NaCl + 3 11.90, - 3 NaIIS0. + 3 IICI;
3 IIC1 + 3 5% - 3 SCOICI; 1100. + 2 S(MfCI -
00
"It" + II.So. + 2 M: 1-11C), + S%IICI - IICC6.S0V-
-
N 90
11
1
irclaxAllcl - SOXCI + HgCI, (sublimes); the
global readies: Is 3 MACI + 2 H*SO. + S0s + If&). -
3 Nalm + Its" + MIMI. 11W effect of KCN is
.explained in a similar wap b6 formation U the equally
noulonlred but less stable s( Nh- N. Thon
00
go
00
*0
00

0 0 a 0 0 0 0 0 0 0 * a 0 0 0 Ole
0 0 0 0 0 0 0 0 0 a * 0 Olo 0
0 0 0 0 0 0 0

CA
0S.U.ni, .,ids V It
K!Clly~,Jf OA."At'11,:=.'l 4701%, 111 -tech. M, slilrl-
Inst., 26ftmicow). Pokkidy Akad. S4.k S.S.S.R. S7,
P17-70011,47); Chrm. Zemir. (RtiViUn bine FA.) 1043, 11,
Imill-1; cf. C.A. U.NIN Omluryw dAtA ill the lita.,
Ittiv, I-alakraq X14-4. mid (1) :Alt IN, hirdli-lys"ll
mitladquitiour ill) I,v lmV, III t1w
Ill bAli*. Thc ficill of lt~ Sa -Al 11C.It'll bolt SO.,.
11,410, luldvir aliont, A 11h)-jNI, fol Ii h"
tit XK" 11. 1 ydro)Ysiii of the tm,I,r t--m
Ill 161101.1". 11"itv%er, II.-Millit till, A. I'l
.tilt %%,Itrr At ;ilwr
/"I Ii llf~~ K.4%v MIV it' , 11 1
%A ht-Itt'l it- NO t, Ml-. %lith vIt"Id 14N 01 1~
it, tw1clitt'll [[j; m1t. tlw hOwl"., ..I if,, I
.1IlItWfIIIV lillt Of I--- ~Alli .1111 111. ~!
leould lia-hydrulyr.-d withh:", 11"SA).Al 1111i
;11 all 01.11 V.-wl or oith '181. act'l
:41 yidd ill H. iNK; , Tip- I, %,-fv 't"wh
,vicrat-I fly the 14-111V A 119, itith .1 119 MK- 01MI-1
tl~ms (kit Itird. I wAtc4l "ith "At.1 At 1,41 ithl I
(IIII. tit ltoi% Ow tv.Illlml liquid
Wil-Is ifiL 11,141, , ,
%Ij_q U,i.l, ill,- irl"I'l of Ill 'Ir.rea-d 114
Willi Im oil grmill. V%ull 01,11 if..- ~At- A Ill,
16-1 kNA. K. Nit., Ill C.-I illft %k_l, tit, sidd ill Ill A."
It ki'llid N. Illl-- d I., -w. if .'.' , JJ,s4 I, "'th
the NA ..It t,f I ,ml h-lillit it :. 0 'i.11 I... I-' I, I".
I(rittills I %tit it 'Aaw, lit lhu ptv- lit, .4
l1w 7jej,f ,11 ut; 18 111 It I 1,"A 0. U-1 -tl~ It
%ij. obtaill"d, i% IN-li J.z anth'aqwq 1) .)'Noit" 'o. ~'l
%%AOIC.11441 Willi 11,S41,111 lit' p1r,,two 4 fix -ifl,,poly lit,-
I allmit, i,id %,-it, .- - 41"1 it. J, .,,I,i w"
It'irlmd. %V c., NLxt,

KOZLOV) V. V.
USS/Chends-try - Antbraqulnona Apr 48
Chemistry - Anthronet Ybrourization of
"Studies In the Field of the Anthraquinone Series,"
V. V, Kozlov, IAb of Ibres, Moscow Chemlootech Inst
Imeni D. 1. Ylendeleyev, 10 pp
'Zhur Obshoh Xhle Vol XVIII (L=)., No 4
PA 8/49751
Describes mercurization of anthrone. using mercury
acetate and sulfate. Products are dthydrodian-
throne, anthraquinone) blanthrone, and mercury
organic ccupounds. Submitted 13 Feb 1947.

00
a
at
00
*a
00
00
009
*0 .3
as
00 3
00,
00
0.0 Id.0 0 11111" goo so a as goo**
AlliLl- 00006000000:::!*
T, _rl
*'100
Tt'o 0
O'NOCE ISO IA.0 0-~112141 M~l7ll' I
.-a*
0 !-*a
sturfrig. VIU. Merestrattillia -01 am- If
Zhur. ObsAwW Mar. (J. Gen. C
Chem.) 18, 707-M(IM);, c(. C.A. 42,12W. and pre. ~66
ceding abstf.-Anthrone (0.58 a.) still 0 Raw ligo
In 30 nil. AcOll a-, rvilulted 4 lits. V-41tered but, 00
Ills 0.27, a. of a black solid, which on treatment with
IINOv tA hrv. at nvom teinp.ww% treed of metallic Ila -00
save 0.2 a. (11.41!;) yellow atuarphous, (Ijoill'(Wit :a
prullably blj(P.10 - d4hydre - 10-rure -0
wilompy. The ma~kir product tw6ted by cv*Un
was 10.10'.bianthrone (U), m 2561 (fnxn AeOll then C
C611a) (0.47 c.). and anud] am*s. of unreacted antiltme.
00
As the reaction time Is Incfft= in 12 her. tire amt. of the
1.4tter drops to 14.4%, the "black prolfuct" locrewws to '0
OM a., anti It inctet6wit it) 0.42 a. 1, Ititurviled with it ills) 0
little "fiRdlin 4q1 "lilt Ivivilell with ittilling with romit. MI 3
1 hm.. SAvr IIKCI, and 1111; 1 (0.2 1.) 1 6 mi. 5% olvilill I fir., a-',S I. It. 1.1 a. anthr-ponone, 0.15 a. Ila, anti roe
treated with CI (lot 45 min. at 1.5 , thrn poiarTil Into fre O.K.5 X. 1; 4 fir, 4 M, tr4cr, 0-07. 0 Od. mp.; adlin. of
water, I.Ivr 0.1 a. la, 131.1$- smoir At du%t in '~e Lilt rx;,t. K.1ve 11 IS. 0.1.
I ;wellali 41A a. Mov"ed lin I Illulle. 0- 00
((fom (111. F1011). Ilthilinx 11) a. anthrotte. tog. 111CO, u
anti 2W nil, AvOll hi'll. 2111411 411111%. of 1,111ILilit, W
CA ithydiule and j,h.,L tile
Ill, which after extri. with ble,C and crystri. were alw i%olAtnt, Uthrour (0.5 1.) In 10 nil. llio...
from AcOll gavro.15 a. midue. does not in. up to 300- IGO treated with 0.5 a. Its %ultAte in to mi. IjpSo#.jIto, "41110
and on reduction by Zn-AcOlf save 10.10'-W-9-anthrol. heated 2 firs. at "". then pourcil Jilt., water, C.1ve
.... -- , Indicating that the original product "us Ila. 0.61 ff. Solid. which after earn, will% ClIC4 X'lvv 0.15 ff. 'age
When a a. antlif one. 5 it. lit(OAc)#. and 2W mi. AcOll Rick frlifilur. Cj.11,,0&S11f (HD. which ii, In.A. fit the i be 0
were fluxed file rniinwins pinijucts werv I %jUtr4I: usual volmh and it,," not int-11; it is probably
11 JuValf; the ClIC4
e%t. save 0.31 a. 1:* 0
m. 11.07, a. mixt. of anthraquinone "ith U, En.
2,"'. and OAS a. anthraquirtrate-imili t in
"we mix ', "
METALLURGICAL LITEA&7441_CLASUPKAIICN 170.4 ". (The.nif it higher truip, (70-lit)") incm1w, tire
-SW
OF
v An &
U IV 00 it 1, a fW 0 M 0 1 W IN 9 its a 3
It 11 0 luo n I
0 a 0 0 a 0 0 a 0 0 0 0 0 0 a a 0 0 0 0 0 0 0 0 a a 0 6 a a 0 0 0 0 0 a 0

00
go
00
410
so
00
so
00
as
*0
00
so
90
difficulty t4 limitations oil III becauxe tif C intonation. 111
idthCrOt in HIS% at M' 1 hr. Save anthrosquillow 185%);
y Into who. of M in U.S06.H.0 at W-00"
gave the same product Kati U; tu catud vri,.h a
,little Sl 0l and ACOII and treated hot with coned. IICI
band K 'A pre mathraquintine sold
III realized with KI in dil. RtOlf In the :Zsenct rof a
Wife slizann nil throne, It. milli a NO H -liv.,
pvrtan a tit
01001. In OWN. stalven 0. whkh on treAtment with H.W),
kws S. but retains Hit. analysis giving r-,tH,Atfg (rW.
wt. in HoSO.. W); it is up "rently Moratival with 1.
Iffillinp O.A 1. 11 "fill 0.5 g. VIOSO. I" MI loll. 111,10o'.
1110 3 firm. at fAV-Gtl* with litining gave 0.2 ff. anthraqui.
"Oni, and 0.3 S. 114; no Its iferiv. was twitlated. IX
Action of satfoomating agents Do
do W somthrone. lbod. SU
t--&-The actiou of sid-
=ing agents on netio-He derivv. of anthrone giv" it
Clitliples traw 40 a result of direct exrhaple of the fig
'rolue (for the 11011f 111111p, 01thialivir redtflons, and oildt
freelit,aA. M-Aritlutiltylill"cury Oullotle (IV) (0.3 1.)
411,12, rid. lls%.11.011"Iml I hr. lot IOU* seat theta poured
into 8 nit. WaICT girr a ppt. cmtg. 0.20 g. Misittal He
.]"IV.: no sulfonic acid IsdetrCtetl in the filtrate; traces
-1 anthrmquincine unit 0A1 It. 11, tit. 284'. are found in the

ppt. The Its detiv. (14 g.) and 5 a. W% toltuou after 3 041
hrm.at~oo* veOllit.13and 0.021. anthrequinowle, while
the all". xtz nw, tratinticia. tiltration. and xcidiek~atinrt 0*

0.33 it. ac*i M (vi, K..
Ran 00
C.A. U 1254f). Monitor holoothis low 3 fire. at 1:1.'6' save
h
V
i 0
. traces of as, atit
ntintsultanic avid. anti
0.04 g.
rilqu
0
0
0.6
'Of. U, so 'Well as tracts of 114 and C. Heiiiing WS g.
V th 6 S. 20% olliturn 3 hr%. at 135' IaIW to yield any. .
00
thing twin an elk. ext. brilkles, 0.03 it. ch1cwtainthru.
IS
0
quincine. in. 202' (cobtatiml by treatment tit the nitrate
with HOCD. the In". Imikin pire MIA 1. anthrloquin,wor 09
anilO.3a.11. IV 0.6j.) *nil bit. OSAMI heAlM3 hroo. I.#
*
0
0
133
few* unrov If and O.W I. V. as well as IM" S.
I .
0
tolanne. be
1gdtr1v.*tU t2o;
all - I hr. at 70*, filtered hot after 0
pdni Wa~irloter, P" on sellindimatim Othe oil. u4n..
filtraflact, and a. V. while HOCIadded to
the filtrate care a true@ of I-chlorilmonthmclitirmone, tn.
'
INLA
; the tolsin ppt. (1.3 if.) on extiv. with CHC4 kit
4.3 a. itimal. residue ciatite. S and Its and camsponding in- 00
comilln. to IV; the CH" ext. gave 0.7 a. U and 0.12 or.
antiumquinone. G. xf. Koft-Ulu'll
00
0 0 0 0 0
o a 0 0 0 0 0 0 0 0 f 0 0 o 0 o 0 0 0 111,

C-4
101
J-A
USW/ChemistrZ - AnthrCaO may
Chemletry - Dyes, Antbraquinane
"Studies of the Pnthraquincne Parie;~YIX," V. V.
rozlov, Iab of Dyes, Moscow Chemicotooh Inst imen:t
D. 1. Mendeleyev, 4 3/4 PP
02b= Obahch Xhim" Vol XVIII (T No 5
Devoted to action of sulfurizing agents an mercury
caMounds of anthrcae. Vith.the meso-mercury com-
p=ds, a coMlex mi3fture is formed as-the result.or
direct replacement of the - cury by a sulfo group.,
*- 9xidiiing oonqensatlon =d similar process. Mie
.aation of oleum (700) on meso-morcury-oulfate or an',
d1bydroquinone-mercury results In the formatiom
8149T6j
USR/ChemIstr7 - Anthrme (Con+A)
gLntbrcn8 M080-thio0arbonate and dibydroantbrone
as basic products. At 1350, the main product is
dibydrodianthrone. When chlorosulfuric acid
(1350) reacts with anthrone-maso-mercury-sulfate,
the main product Is enthrone meso-thiocarbcnate.
Submitted 18 Mar 1947.
MOscov Chemico-tech. inst. im. I). I.
Mendeleyev.
8AW62