SCIENTIFIC ABSTRACT KOTON, M.M. - KOTORLENKO, L.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000825410012-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 12
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

30292
.5/19 621004100410081019
BI 19Y3138
~~00
AUTHORS; Andreyeva, I. V., Koton, M. M., Kovaleva, K. A.
TITLE: Polymerization of acrolein and its (1,Drivativeo. I. Low-
temperature polyneriz"tion of acrolein and a-m,~thyl acrolein
i iIODICAL: Vysokomolekulyarnyye soyedineniya, 8
"E" v. 4, no. 4, 1962, 52 -532
TEXT: Acroloin (1) and a-methyl acroleino(2) were polymerized in the
pre~;ence of gaseous BP3 between 0 and -80 C in block and in solution
(solvent: Ch 2Cl 2) . The experiments werc made in sealed ampoules, partly
with exclusion of 0 2 and H2 0, partly in the presence of very small amounts
of 1H2O.Results; Polymers obtained in block polymerization with 10-15'/0'
conversion are completely soluble in organic solvents. With a higher
de,~;ree of conversion, the reaction product becomes insoluble in organic
solvents but ooluble in sulfurous acid. The reaction with 15-20'/0'
conversion without H20 takes 15-30 hr at -20 0C, with H20, 3-6 hr.
Card 1/3

S/ i --0/62/'u04/(ju4/Uu8/01 9
Polymerization of acrolein and its ... B119/B158
The molecular wei~;Iit of tho polymer produced in the presence of 1.120 is
lower than in the one produced without water. Maximum conversion
attained at -20 to -40 0C with 1.5 moleO,', BF 3 (with 1) and 2.5 - 3 molec/o'
(-with 2). The block polymers give no aldehyde reaction, they are cyclized:
CH CH 2\ CH /
C IH Ck C;I CH -)olymerization of acrolein in solution
6h /CH CE C-T
~O - 0 / ____ 0 /- ~.'
gives a soluble product with a melting point of 150-17000 and
G-006 - 0-07 in benzene at -600C and 30 /1) conversion, but an insoluble
0
and nonmelting product at -20 C and 301,') conversion. The polymer obtained
from dilute solutions is not cyclized. At -200C the rate of polymerization
decreases in the order acrolein - a-methyl acrolein - a-ethyl acrolein,
There are 4-figures and I table.
Card 2/3

1 s/19o/62/004/004/008/019
17ol.yiiierization of acroloin and its B119/B138
LSSOCIATION: Institut vysokomolekulyarnykh soyedineniy All SSOR
(Inititute of High-moleculur Compoundo AS Uss-R)
IS U ~:,'I T11 !"D '.'arch 10, 1961
Card 3/3
Q 2 0'~
3/190/62/004/006/016/026
B 12 4 //B 13 0
U
AUTHORS: Dokukina, A. F., Yet,
_,orova, Ye. I., Kazennikova, G. V., Ka~
I.T., Kocheshkov, K. A., Smirnova, Z. A., Trtlalay,~va, T. V.
LE:
~S.,Inthesis -an([ polymerization (copolynerization) of fluoron-
substituted styrenes. 1. Copolymerization of fluoran-
,iubstituted styrene3 with vinyl monomers
v. 4, no.
UODICAb: Vy3okomolekulyarnyye soyedineniya, ?
6?3h
TSXT: This paper describes the authors' experiments in the production and
characteriLatiorl of the copolymers of a, 6, 01.-trifluoro styrene with 2,5-
di-methyl styrene and methyl methacrylate; o-, m- and p-methyl-(x, 6,f3' -.
trifluoro styrene with styrene, a, 6-difluoro-(Y-chloro styrene with
styrene, and 2,5-diflIAoro styrene. The emulsion used for copolymerization
consisted of 80 -85 1,17 -,,fater, 2.5 emulsifier (8odium .9tearate ordleate),
and 0-5 persulfate initiator. The monomer mixture, which was added drop-
wise after heating to 80 - 900C, contained azoisobutyric acid dinitrile
(0-5 5) as initiator. Eleven copolymers of the above monomers were ob-
tained. Their compositions and properties are given in Table 2. The heat
Card 1/4

KOTON, 149'el.
flew methods for the synthesis of the the=outable polymeris with cycles
in chain. Analele chWe 17 no.3:98-117 JI-S 162.

3/074/62/031/002/001/001
B110101
AUTHOR: Koton, M. 1-1.
TITLE: New methods of synthesizing heat-resistant polymers
with rings in the chain
PERIODICAL: USDekhi khimii, v. 31, no. 2, 1962, 153 - 167
TEXT: This is a survey of the progress made during the last two years
in the field of synthesis of new heat-resistant polymers with rings in the
chain, i. e., polymers with benzene rings or heterocyclic links in the
principal chain, A. N. Nesmeyanov, A. A. Vansheydt, V. V. Korshak, Z. V~
Vinogradova, Yu. V. Mitin, and A. V. Topchiyev are mentioned. There are
I table and 47 references; 12 Soviet and 35 non-Soviet. The four most
recent references to English-language publications read as follows: C',
Marvel, Rubb. and Plast age., 42, 87 (1961) and J. Polymer Sci., 50, 511
(1961); W,, Lee, Polytechnic Institute of Brooklyn, Polymer Seminar., 10,
110~ 5 (1960); L, Mulvaney, C. Marvel, J. Polymer. Sci., 50, 541 (1961T, C.
Ab3hire, L. Mulvaney, C. Marvel, Macrom. Chem. 44-46, 58a (1?61) and J.
Org. Chem. , 2i , 95 '1961).
Card 1/2

S/074/62/031/002/001/001
Now methods of synthesizing ... B117/BlOl
ASSOCIATION: In-t vysokomolekulyarnykh soyedineniy AN SSSR (institute
of Iligh-molecular Compounds AS USSR)
Ca--d 2/2

S/07 9/62/032/009/010/011
1048/1242
A,'rT I IRQ" Kobon, M.M. and Florinskiy, F. 3'
T r r r.;-L The a-ynthesis of lead organic metacrylntes
PER I ODIC A L: Zhurnal obahchey Ichimll, v.30-, * no.9, 1062, 3057-3059
TF,XT! The renction3;of (GGH5),3?110J1 and (C6115)2?bO -.-Ath ijobu L,,,r lo
find motacrylic acids viere Studied in detnilo The intoraction of
aniilmolrir amount of (C611r,)-Tb011 and freshly distilled i9obutypic
mirl In an alcoholic sol-~tyo'n -,7ioldod tr Inhanylload mono isobutyrate
(colorlass urystals, M-p. 1138-1900). The Anteraction of 0.026 g-
molOs Of (Cc-115)oPbo and 0.054 g-molos freshly d1stilled Isobutyric
FICIrl in an aque-ous or n1coholic iolutiQn a:t 80-900C ~Ialdcd diphenyl-.
load diloobutyrnte (colorless crystal3, n.p. 201-203 C). The main
prod,.int of the intornetion botwoon one molo of (C PbOll and Ono
~Tlr )3
to f ive moles of motlier7lic acid In an aqueous me ilolz tit GOG Vinn
L7, iphenyllead monomotacrylate (colorless cr'yntals , m.p, 126-1280C
a avallor amount of dlphonylleaO dimotncrylata was also formed. Di-
phnnyllead dimetacrylate orystallizes as a colorless colid which
Cal (I l/
Tho r-,,nthe,
I gis of lead...
S/079/62/032/009/010/011
1048/.12142
e,ooa not rnalt at tomooratlirIos tip to 22.51C; a ylf~ld was also ob-
L-1111ed from 0.03 g-molos of. (C6115)o,?bO and 0*07 g-moloa of frashly-
(11.~jtillod Inntacrylle acid, Iby mixing for 2 hra in 50 inl of wator,
allowing the mixture to stand overnight, washing the procipitnto
with hot waterp drying,, and r aor irs tall Iv Ine,, fron dioxano,
AS-)(MATION., -InstItut vyeakomoleltulyarny1di soyadinonly Akademil
nauk SSbR (Tho Institute of hieh-mclocular weight
compoundso Academy of Soionce.9 US"IM)
S~IBMITTED: septerber 20, 1961
Card 2/2

KOTON M.M.- ELORINSKIY, F~S.
Synthesis of organolead methacr-
ylates. Zhur.~t.Mim. 32
no.9:30`~7-3059 3 162. 15:9)
1. Institut vysokomolekalyarnyl.,h soyedinerny 1,111 Sssq.
(Lead organic compounds) (IMethacryli-ct aatAd)

tui~. CorrespondinG Member, AS USSR, Andreyeva, I. V.
an~ Getmancia;k, Yu. P.
7- e i n
m-;.::icn polyr-.iorization of
-j fv.:Lrious redox sy3tems
10 DI A L; Ak;t--A-..ri~-a nauk SS5R. Doklady, v. 1-4, nc.. "';f i C,,-, 10
'T
aicroloin -;,ras polymorized in various rcdex in thi.,
of a nc-a type of emulsifier, aqueous polyacrclelin SUIfite. Thj
a stable emulsion, and polyrierization takes place in the
the emulsi4ier. Polymerization is carried out in ton times the. arlount 0"
,ter -.-fith Ll-.dit4cn of twice the amount of a , `~ aque'
" P ous emulsifier, sill
related to the monomer us,-,*d. The most suitable redox sy3tem for this f;CC-j)CI
.A3 potassium, pt~rsulfate and silver nitrate which give3 hiLh polymer
of maximum rniol~;cular weit,ht. All a-mothyl-acrolein polymers ob",lined
cuntain 6-5-110 1`o' al,iehydic groups, while for polyacrolein prepared in th!~,
samu- red"ox S. Stems this firure is 20-70 This i's due to the methl.,I
in the side chain ctf 'the a-methyl. acrolein molecule, which p:evurits the
~a, d 1

5/0 ',0/62/1eI,,j/005/C 1 "/0 1 7
Emulsion .,,Aymerizat~:on of. . . 1312 4/B I 5C~
cycling of the aldehydic groups, -;;hich occurs-, in the acrolpin The
U
U I
I~mers obtained are 3oluble in wridine, their intrinsic v4scol~ity 1,
ri di ne rang es f rom 0. 1 and 0.,131 and molecular v-eit.-Iitt, deter2iinA rcr~
the coefficient of proeres3ive diffusion and the intrinsic viscooity,
70,000 and 195,000. The white powders obtained could bo mo)l~,erl ~.t
COC and 75 t:t to iii-
_,ht yeilow Plates with a softenint., point, Iht1!,-,VF"r.j, I
,~Ilki ' 1 "0 r- V. Y EA i n a nd S . I. K I en i n a r(,~ t I 1, 01? e d 1'0 r Ill C 11 -- 1: ri n.- t hL
i n dl '~' n, 'he di;-usion coefficient, aiW for Pai ~;,,; la t, i n;- Ihe
1-acular weights of the polymers obtained. There are 4' tabl,.!s. III
i sh-lan,~uqLe f - r-ence i s
E. Gilbert, J. Donleavy, J. A:-...
7 9
ASKCI~TION: institut vysokomolekulyarn~kh ooyedineniy
(In-titute of High-molo-cular Compoutids of ti,,ti Ac-idcr:,-~ uf'
2cieuccs U.;3R)
3U!3:-;ITTZD: )-Iarch 2,',, 19062
Gard 2/2

&TOH,~M.M.; PJQiEYE-VA,,I.V.; ANDHEYEV, P.P.; DAIIILOV, L.G.; RWOZINA, E.M.
Reaction4 pf an aqueous w lution of polyacrolein with inorganic
salts. D-olk,.AN SSSR 146 no.3:60f-610 S 162. (MM 15-10)
1. Institut vysokomolelmlyarnykh soyedinsaiy AN SSSR.- 2, Chlen!.-
korrespondent AN LSSR (for Koton).
(Acrolein) (Salts) (Macromolecular compounds)

KOTON, M.N.; FLORINSKIY, F.S.
Synthesis of polymerizing organothallium compounds.
Dokl. AN SSSR 11+6 no.4!820-821 0 162. (MIRA 15:U)
1. Institut vysokomolekulyarnykh soyedineniy AN SSSR.
2. Chlen-korrespondent AN SSSR (for Koton).
(Thallium organic compounds)

SLEPTSOVA, O.M.; GROBOVA, K.I.; KOTON, M.M.
Synthesis of unsatlirated esters of hydroxwnic acids. Zhur. ob.
khim. 33 no.8:2-568-2570 Ag 163. (MIRA 161l1)

- KOTON, M.M.; LAVRENTIYEVA, Ye.M.
Sergei Nikolaevich Ushakov; on his 70th birthdwj. Zhur. prikl.
khim. 36 no.12:2561-2564 D163. (HIRA 17:2)

KOTON, M.M.; DOKUKINAj L*F.
Polymerization capacity of tin-containing monomers. Dokl.
AN SSSR 152 no.6:135? 0 163. (MIRA 16:11)
1. Institut vysokomolekulyarnykh soyedineniy AN SSSR.
2. Chlen-korrespondent AN SSSR (for Koton).

AcO!;ssiou iiR: AF4307900 S/0190/63/005/012A8l7/1618
AUTHORS: Adrova, N. A.;,.~oton M. N.; h-lages,, V. As
TITLE: Synthesis of organometallic polymers with tin atoms in the basic chain.
30=1;: Vy*sokomole~-.ulyarnMe soyedineniya, v. 5, no. 12, 1963, 1817-1818
-.01--31C TAGS: polymer, organo.-aetallic polymer, organotin polymer, organotin,
co-13ound synthesis, tin.dihydrodibutyl-, polymer structure, polymar property.
methacrylic acid, tin. dihydrodiphenyl-, ethylene aycol.methacrylic acid diester
A351DIAICT: A now tin-organic polymer hao boon synthesized from the reaction of
R2SrIH2 with dimethacrylato etkylene, glycol and with dimethacrylate hydroquinone.
The structuresof the compound&re represented by
-cil,cll(-00-/Z--,\)-OCOCIICIIsn-
CHIMIC00CHICIF30COCIIC11"I ri-
where !l C,1-19; C,H&- C113
Card 1/2

Acc-F-owiazi NR; AP4007980
The reac4ions were carried out in 'toluene, with and without initiators uhder
atmospheric nitrogen, increasing the temperature gradually from 80 to 100-120C.
The molecular weights were determined using the cryoscopic, technique in benzol.
Orig. art. has: 3 formulas and 1 table.
ASSOCIPuTION; Institut vy*sokomolekulyarny*kli soyedinaniy AN SSSR (Institute of
Hiah-11,1olecular-J-1eight Conmounds AN SSSTZ)
0
&JB',,IITTM: 26Apr62 DATE ACQ: 2OJan64 ENCL: 00
SUB CODE; CHj, M NO REF SOVt 001 OTHER: 000
Card 2/2

'ACCESSION KR: AT4033978 8/0000/631000/000/0009/0010
AUT11ORi Adroval No A,j It. Ke
TITLE: Preparation of polymers containing phenylene groups and tin, antimony
and phosphorus atoms in'the principal chain
SOURCE: Geterotsepny*ye vy*sokomolakulyarny*ye soyedineniya (Heterochain
macromolecular compounds); abornik statey. Moscow, led-vo "Nauka," 1963, 9-10
TAGS: polymerination, polymer, phenylene group, tin, antimany, phos*phorus,
metallic polymer
ABSTRACT: New metallic polymers: (l)-poly-p-plianylenediphanyletannine, (2) poly-p-
phenylenetriphenylatibine, and (3) poly-p-phenylenaphenylphosphine, have been
prepared by polycondensation resulting from the interaction of dLlithiumphanylene
and organometallic dLeblorides by the scheme
A.
in which Me to 8n, 8b or P. and R to 005* 'The a-butyllithium for the reaction
Card 1/2

ACCESSION NR: AT4020708 S/0000/63/000/000/0195/Oi97
AUTHOR: Koton, M. M.; Adrova, N. A.; Khomenkova, K. K.
TITLE: Polymerization of some derivatives of p-vinylbenzoic acid
SOURCE: Karbotsepny*ye vy*sokomolekulyarny*ye soyedineniya (Carbon-chain macro-
molecular compounds); sbornik statey. Moscow, lzd-vo AN SSSR, 1963, 195-197
TOPIC TAGS: polymerization, vin~lbenzoic*acid, vinylbenzoate, vinylbenzamide,
polymer physical property, poiyvinylbenzoate, dilatometry, azodiisobutyronitrile,
butyl peroxide, block polymerization
ABSTRACT: Using a dilatometric method, the authors compared the block and liquid-
phase polymerization rate5 of p-vinylbenzoic acid, Its methyl and amyl esters,
p-vinylbenzamide and its N-methyl, N,N-dimethyl and N-amyl derivatives, using
0.2 mol.% tert.-butyl peroxide or azodiisobutyronitrile as the initiators, respec-
tively, at 120-180C. Some of the physical properties (thermal stability, solu-
bility, weight loss during heating) of the polymers obtained were also studied.
The polymerization rate*of the derivatives of p-vin'ylbenzoic acid decreased in
the following order: acid>amides > esters. it was found that the polymerized
amides of p-vinylbenzoic acid have a higher softening point and a higher thermal
sbabl/lity than the corresponding polymerized esters. Orig. art. has; I figure
Car
ACCESSION NR-. AT4020708
and I table.
ASSOCIATION: Institut vy*sokomolekulyarny*kh soyedineniy AN*SSSR (institute
of Macromolecu'ar Compounds, AN SSSR)
SUBMITTED: I8Jun62
SUB CODE: OC
Card 2/2
DATE ACQ: 20Mar64 ENCL: 00'
NO REF SOV; 002 OTHER: 004

ACCESSION NR: AT,1020710
iand that the rinr formation is not complete. On heating polyphonylmethacrylamido at 320C
in a vacuum for 2 hours, a soluble polymer with rings in the chaJn was obtained in a yield
of 56. 0%. The properties of all the methacrylamides investigated are reported before and
after deamination, and the perimental conditions for deamination and polymerization are
described. "T. A. Vorotilova also took part in the work." Orig. art. has; 3 tables.
ASSOCIATION: Institut vy*sokomolekulyarny*kh soyedineniy AN SSSR (Institute of Macro-
molecular Compounds, AN SSSR)
SUBMITTED: 02JulG2 DATE ACQ- 20MarG4 ENCL: 00
SUB CODE: 0C NO REF SOV: 005 OTHER: 000
Card
2/2-

,ACCESSION NR: AT4034068 8/0000/63/000/000/0236/0239
AUTHOR: Dyachenko, T. D.; Glukhov,'N. A.; Koton, M. M. ; Sazanov, Yu. N.
TITLE: Synthesis and polymerization of cc, d.1-bia-chloromoUkyl-p-propiolactono
SOURCE: Geterotaepny*ye vy*sokomolekulyarny*ya soyedineniya (Heterochain maoro-
molecular compounds); abornik statey. Moscow, Izd-vo "Nauka, 11 1963, 236-239
TOPIC TAGS: lactone, lactone synthesis, proptolactone, lactone polymerization,
pentaerythritol
ABSTRACT: The authors accomplished the synthesis of the lactone from pentacrythritol
which was successively converted to pentaerythritol trjohlorohydrin by the action of
chlorothionyl, and then to trichlorapivalic acid by the action of nitric acid. Pyrolysis of
leqd trichloropivalate yields the lactone.directly:
C115011 cilia UNO CHtU
HOCH& 0111011-42201bill1c - J- cilsoll-obillac C0011-4.
6,011
CHICA
H&C, L
~_Coo~_ Pb-=dC-~ C-o+pbal
C aid 1/3 Alact
ACCESSION NR: AT4034008
In the procedurey Igo g of pentaerythritol trichlorohydrin were treated with an excess of
concentrated nitric acid for 30 hra until the complete removal of nitrogen oxides. The mix-
ture was then cooled down to room temperature and the crystals of trichloropivalic acid were
washed with ice water, dried and recrystallized from n-hexalle. The acid melted at 109-
110 C, and the yield was 60-65% of the theoretical. C-, 11- and Cl-analyses and M-determin-
ation agreed with the theoretical yalues. The acid was dissolved In ethyl alcohol and reacted
with an equimolar amount of lead acetate. The precipitate of lead trichloropivalate was
dried in a vacuum over P20 The melting point was 180 C, the yield - 65-70% and the
analysis and molecular weiX were in agreement with the theoretical. The pyrolysis of the
lead salt was carried out on an oil bath at'150-160 C and lo-3-lo-4 mm, vacuum in a special-
ly devised flask preventing the over-heating of the product. Special care was taken to keep
the salt absolutely dry. Ile lactone obtained melted at 35 C, had a yield of 66-78%, a mol.
weight of 168. 11, and the C-, H-, and Cl-content was in agreement with the theoretical. The
thermal polymerization of the lactone was also invOstWated between 40 and 120 C and the 0
actone was stable at up to 250 C.' Orig.
destruction at3OO C. The latter. showed that the
art. has: 6 figures.
Card 2/3

A-CCESSIQN NR: AT4034008
ASSOCIATION: Institut vy*sokomolckulyarny*kh soyedinealy AN 6WR (Institute of High-
M olecular Compounds, AN WSR)
SUBIMUTEM 14Mar63 DATE ACQ: 30Apr64 ENCLi 00
SUB CODE: OC NO REP BOV: 001 MHER: 094
Card 3/3

..~ACCESSIOIN NR: AP401900B s/0062/64/ooO/002/0331/0334
JkUTHORS: Zhenevskaya, X.G.; Sheremeteva, T.V.; Koton, M.M.,
TITLE: Synthesis and polymerization of p-butyl- and p-butyrophenyl
methacrylates. Communication 3. Concerning ester structures and
their tendency to polymerize
SOURCE: AN SSSR. Izv, Seriya khimicheskaya, no.2,1964, 331-334
r
T0j?IC TAGS: parabutyl methacrylat:~ polymerization, polymerizattion,
parabytyrophenyl methaorylate polymerization, ester structure, metha-
:crylate phenylmethacrylic ester , substituted pheny1methacrylic ester
.ABSTRACT: The purpose of this Investigation is to find how the poly-
:,merization rate of the above esters Is affected by the structure of
.;the substituent. The dete3~mination of the polymerization rate of
;-substituted phenylmethaorylic esters was made for the following mouo-
mers: p-normal, prisoRrimary, p-tertiarybutylphenylmethaerylates and
'~p-normal, p-isoprimark butyrophenylmethaorylates. Polymerization itas
carried out at 800 In the.presence of benzoyl peroxide (0.3%) and in a
nitrogen atmospheire bhoause oxygen:inhibits polymerization. It was
Cord 1/2

KOTON I M.
Invasion of polymers. Tekh. I vooruzh. no.3:72-75 Rr 164.
(MM 17: 8)
1. Ghlon-korrespondent AN SSSR.

VOLKOVA, A.I.,- KOT0112 M.M.
Effect of the chovdcal stru2ture of upsaturated
their ability to polymerize. Part 2: Substituted
and methacrylutes. Vysokom. soed 6 no.3,480-483
1. Instifut vysokomoIeku-Iyarnykh soyedinan!,.y AN
esters on
acrylates
MIr'64.
(MM 17'5)
SSSR.

!ACCESSION NRt AP4043189 S/0190164/0061008/1496/1497
AUTHOR: Koto!~jj~,A,.; Kiseleva, T. H.; Arkhipova, 1. b.
TITLEs Synthesis of metal-containing polymers by reaction in a
,poly(mothacrylic acid) chain
I
ISOURCEi Vy*aokomolekulyarny*ye soyedineniya, v. 6, no. 8, 1964. 1496-i-
11497
.,TOPIC TAGS: metal containing polymer, metal containing polymer syn-
Ithesis, poly(tri-n-butyltin methacrylite), poly(triphenyltin methac-
irylate) , poly (diphenylan timany methacrylate) , poly( triphanyllead
methacrylate) - poly (phenyimercury methacrylate) , thermostable polylue-Ir.
.ABSTRACTi Thermally stable organometallic copolymers which ara
soluble in organic solvents were synthesized by reacting poly(motha-
crylic acid).with alkyl- or aryl-metal hydroxides. The copolymers
:were synthesized in alcohol soluti.nn. -at 7.OC as. followat
CHl
Ott% + 11OH"R i
Card
113

iftw, Y.
MRS
9-0 - .7-5--l
WNia-
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TOMOTACSR Q W,
3M
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aw,
WS 5W
;j,
aWA-VIOU
~ i, - - 90
W-h wim
VIM-
7-M Oft-
ow-as
Mffe,
MI
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Y
AW-Kop

ACCESSION NR: AP4042082 S/0079/64/014/006/1757/1758
AUTHOR: Koton, M. M.; Dokukina, L. F.
TITLE: The synthesis of unsaturated tin organic compounds
SOURCE: Zhurnal obahchey khimii, Y. 34s no. 6, 1964, 1757-1758
TOPIC TAGS: synthesis, copolymer,.polymerization, organic solvent, tin organic7
monomer, stanniferous monomer, vinyl compound, metal organic compound
ABSTRACT: The authors inve'stigated amethod for developing a synthesis f6r the
polymerization of unsaturated metal organic compounds by first obtaining:
n-vinylbiphenyltriphenyltin (I), and n-vinylphenyltricyclohexiitin (11). Tin
organic monomers (I and II), colorless crystals, are quite soluble in organic
solvents; they polymerize, easily, in bulk as well as in solution and product
copolymers with other vinyl compounds. The processes of synthesis are described
for both I and 11. The authors express gratitude to J. M. Kiselov for his valuable
advice and assistance.
ASSOCIATION: Institut vy*sokomolekulyarny*kh soyedineniy, akademii nauk SSSR
(Institute of high Molecular Compounds, Academy of Sciences)SSSR).
1/2
ACCESSION NR: AP4042082-----------
SUBkTTED: 20Kay63
.,SUB CODE: OG NO-REP SOV! 003
C,,d k_?/2
ENCL: 00
OTHER: 003

KC-LICN, MI.M.
-;table polyr,,3r3 Of high stren,,-th. ilrtr~.,4ri 1,J : i -, . ~' . 1 ; ,
- -i, ~
0-forul 1,-,o)
1. Inilt-Wit. nly iIJI,
~:!~D~r-korrcspvntlrnt AN S'SNP.

KOTONY M.M.; DOYIIKINA, A.F.; YFGORCVA, Ye.I.
Kinetics of homogeneous and heteroveneous polymerization of
Oe ~ -fluo-zo-substituted styrenes. Dokl. AN SSSR 155 no.1-139-140
i~! 164. NIRA 17:4)
1. Institut vysokcmolekulyarnykh soyedinoniy AN SSSIR. 2. Chlen-
korrespondent AN SSSR (for Koton).

KOTONY M.M.; ANDREYEVA , I.V.; GEIMANCHUK, Yu.P.
Polymerization of meta-acrolein with anion catalysts. Dokl. AN
SSSR 155 no. 4:836-838 Ap 164. (MIRA 17;5)
1. Institut vysokomolekulyarnykh soyedineniy AN SSSR. 2. Chlen-
korrespondent AN SSSR (for Koton).

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ADROVA, N.A.; PROKHOROVA', L.K.; KOTON, M.,M.
Production of polymers with dibenzoborimidazoline links in
the main chain. Dokl. AN SSSR 158 no.1:130-13e'_ S-0 164
(IMIRA 17:8)
1. Tristitut VY30,11-0molekillyarny'kh AN SSSR. 2. Ghlcm
.7
korrt,spondent AX SSSR (for Koton).

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KOTON 0 M.M. ; KI OTLIEVA, T.11,1. ; ARKH IFOVA, !, L.
Synthes"s cf imtal-contaln-Ing polymers by reacticns lxn r.Clynethacr-jlic
acid chains. *,,~rsokcm. coed. 6 no.8:21,~~6-14197 Au- 164.
(NMIRA 17:20)
1. litistitut vysokoinolakulyarnykh ,,oypd-'Lnen-..y AN SSSR.

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KOTON) M.M.
Syntliesla of new fiber-foraing po2ymars. Vest.. AN 65SR 34 no.901-
74 S 164. (MIRA 17:10)
I.Inatitut vysokomolekulyarny-kh soyedineni-y AN SSS~. nha-err-korrea-
pondnnt AN SSSR.

j -III ! s~ i I -I t! I o f 41 e I d of T.no z'~~Tl tlt'~:: .. -, Of I I%""' "nos 1) f, poi V-
.`Lait. no.~'- il-I) 1 (4 !' f,', i RA _18:1.)

KOTO.N) M.M-.; KOCHESFIKOV, K.A.; GORSHKOVA, I.A.; DOKUKINA, A.F.; PA1NOV, Ye.M.
CopolymerJzation O-Gp"t -halo-su'nstituted p-divinylbenzenes with
styrene. Dokl. AN SbbLt 158 no.51-`-UO-LU.2 0 164.
(MIRA 17:10)
1. Institute vysokomolekulyarnykli soyedineniy AN SSSR, Leningradskiy
politekhnicheskiy institut im, M,I,Kalinina i Fiziko--khimichezkiy
Institut. im. L.Ya.Karpova. 2. Chle ny-kcrre s pond on ty AN SSSR (for Kotonp
K-Ochoshkov).

KOTON-, M.M.; ARDRENWA, I-V.; TURBIIIA, A.I.; SOYAVSKIY, V.G.
Polymerization of o-hydroxypnenyl vinyl ketones. Dokl. P11 SSSR
159 no.3:602-604 N 764 (MIRA 18:1)
1. Institut vysokomolekulyarnykh soyedineniy All SSSR. 2. Chlen
korrospondent AN SSSR (for Koton).

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t 8 74-6 EWP(J)/EWA(c)/EWT(126/T R14
ACC Ms AP5025957 -SOURGE UR/01qO/65/0o7/oio/i6q3/1697
AUTHOR: Ivanovq~ .30; Gavryucbenkove L. P.; Xoton,, M. M.
Zia
4 7
~ORG, Instituts'of Macromolecular Comgounds,AN SSSRqynstitut
V7s;kcmo1eku1yarnykb soyedinen AHMSSR)
.TITLE: Syntbasis of pbly-alpha-alkylglypy1dehydr lanines~ Report
No. 1.
SOURCE: Vysokomoleku7arn'YYe soyedinaniya, v, 7. no. 10 1965;
1693-1697
-TOPIC TAGS: alanines-polymerp polymerization, biochemistry
ABSTRACT*. The syntbesis of carbon,obsin polymers with peptide and,
'perboxyl groups in the~side chains loof Interest in the study of
biologically active compoundee; Pol-y,!.alpba-alkylgl-yeyldehydroalanines
were.synthesized by reaoting,alpbs~-ohloroaootyldabydroalanlne with
aminea which leads to substitutio .nWfAhe halogen by the amine'residus-
and simultaneous Volymerizati6m . olymerization.meebanism Im to ~
be discussed. -elsewbere* ~ h-e-151lowIng, oompounds, unknown in the litere,
ature, were synthesized and:obaracterized-by elemental analysis and
IR spectra: pol7-alpha-alkylglyayldehydroalanines, wbere the term
Card /2
~UDC: 6-78.675

M__
L 8874-66
ACC NR
'AP5025957
tialkyl" included the methylj, ethyl# n-butyl, n-hexyl,, dibutyl,,
n-ethanol, amInoetbyl,..Phenyl.'and anino..radicals, Astudy of the
thermal dec2mositiop?kinet ion' these compounds
start to compose at 150vGo Orige arto bas: 2 figures, 2 tables
and 2 equationse
SUB CODE: OC/ SUBM,DATE-.- 03Nov64/ ORIG REF: 003/ OTH REP: 004
L~qrd 2/2 A~A

L U526-M W(M')fEW0(j)fi RW
__~CC: kRo' AP6001858 SOURCE GODE: UR/0190/6 039 2 7
5 7 012
AUTHORS-. Koton M M Andre~Levai 1. V.; Getmanchuk,_Yu P.; r ava. L. Ya.-.
-6 ~'-Ko
Pokrovskio 11 Filatova, V. A,
e tsov, A. I.;
ORO: Institute of High4folecular F210ers AN �A&jInstitut vysokomolakulyarnykh
soyedineniy AN SSSR)
ture of methac
TITLE: Struc rolein polymers, obtained in tho presence of anionic
catalysts. 3rd report iii the rpFiei~'Polymerization of Acrolein and Its Derivatives
SOURCE: Vysokomelokulyarnyye soyedineniyaj V. 7. no. 12, 1965, 2039-2047
TOPIC TAOSt polymerizations polymer structure, reaction mechanism, qatalyst/~ Nipp .0n
Bunko infrared spectrophotomater.DS 301--GNM 3 nuclear magnetic resonance spectrometer
ABSTRACT: The structure of polymerslobtained from methacrolein and C< -ethylacrolein
in the presence of sodium naphthalena~ and I sodium trityl using the method described -
by M. M. Koton, 1. V. Andreyevas and Yu. P. Getmanchuk (Dokl. AN SSSRs 155s 836, 1964)
was investigated. -The structure analysis was perrormied by chemical means-. oxime
formations-hydrog enation, oxidation with perbenzoic acids ozonization, as well as by
physical m6anst infrared spectra)* using Nippon-Bunko spectrophotometer DS-3011 and
NMR spectras using instrument. GHM-36. It was established that the rate of conversion
of methacrolein and the structure of the obtained polymer are both functions of
polymerization temperatures as illustrated in Fig. 1e: Mechanism of the polymerization
Card 1/3 uDc: 678.o1.-53+678-144

At OC and abovep the termination step occurs main~Ly along the Ionic path* Thia
mechanism explains the formation of -the predominantly cyclic structures consisting
of condensed tatrahydropyrane rings at temperatuips below OC. Orig. art. has t 3
tables, 6 figuresp 4 formulaso and 3 equations#
SUB COD& llp-*-b7/ SUBM DATEs OlDec6h/ ORIG REF: 0051 OTH REF1 014
Card 3/3 0