SCIENTIFIC ABSTRACT KOTON, M.M. - KOTON, M.M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000825410010-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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The reactlocts studied wtre thow tA Philit with HCOM
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S'O: Journal of Genemcl C~cmiotry (Zhurnal Obsticie KlAirlJ ) 1946, !Voluno 16, No, 4-5

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IF I V It u Is 4 IS 14 11 It of u H 5 ft I? 111 4 61 0 of a my'v
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00 A 111theorecdom of art-ccutry C-
T. M.
44dirAtilris of hydrombo"
WTr."T6I,. M.1.
Inji", arAl H. G. CKbefl! (1-41"linKtA-1
Ot- At VU(
FVACt At [,-go. With 'litter
t"It dM4 react with CHIS: a It6l.
MI 1, 1,11,111t fill 1111. CM, bo"Itt'l ill ;I -Ilrd till.. ill
N) 3 lim AT" 11 1 11. 1111116I.A., III. UO V.wul it 14 ic-
11MI 'It Ilit
so ZI r .. I.. hut. silive 0.12 9. C.I. mill 11 1.4 K PION, Ill,
[.6ifill-tasc.: 1111,Ilg f CIII.- too
action C"ferifly P(morl
re
it. + 11111140'. and 21'hflxCl. - 21'111191 1- C,I-,
Ij(IAv), mwti trailily with *,let m-1 Vol. licMI-11
1Ig(OAv)a with I lilt Nki it IW* 1 11, Ila- 1 :11 It
fist,, tilt., it. A%1111, aI (I IM or M,( 1-11, the
Mcomlitin., I st.l. 141 V141M I.'-'J It, IIXI,, 0 M.' o;
AtOll.anil 0.07 g. FtOAc. 'rho intv irmli.-ii Willi I
lilt. PhC1f,Cl at 130 1 hr. rv4vv.1 g4wulls 11CI mA
taire 0.21) s. IlsCh. 0.15 It. IIx.CI,. mid to.okl K. llhCll,.
0 IS OAr. floating I S, IlsmAO, %tilt I till. moir at i:w,
A hm 1,-4vr 1.321r. 11111rodn'10.21i g. 111JIM.- Ile.1,11.0's 40 11111
of 116MAO, (I ff~) tillib Olch, C.11,111"
C1114(j" Ona eel, KAVC tile ("U'lallig Inimlill 14
Nniti. in X.); HKIR ().I#;. liftel, 0.2h.1; 111.11T, 11.17.
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Iteadim of ortanomercury campowsaf Nak, -th with 11,0. Efoll, fitio. and benstne, gave I-NJ it. brf-
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ttift M, Nt. Kotoo mel T. M. Zorisa (Lettingrad reacted 0-okfopher", d 0.
td. ritt.). ATW, Cke. (U.S.S.R.) 17. W20- decomp. 12"'. red (ttraitnent with ak. JICJ gave
RtM41m): cf. C.A. 42, 1141C.-Rilft (0-3 a-) a v nitrwherAA); there was aloe formed 1.19
if! and 0.3 g. of a phemA weee It"ted In a setled tube to 130%
t~j OinallP03, does wit ni. Z50'. Yellow Pow- "o0
the Wst. W" treated with atoll, Ilso. or &q. *N&Oil. tjown with sle. IICI. while kxfine
which ab* breaks '06
and th, ra4dus) fig was !Aen up in 111N0; AM dttd. KI siolti. siv" 4.0j-dIh-kIo-9-nitr(j,hC
nol. thm showing
00 The following arnts. of Jig (in %) wm isdAttf! After b4t the proefuct was o
00 readlon of Phalix with vwkui phencis: PhOll IM. pbettol. Shifflar reaction Of Ph-tic with x1-MAt?#*Q0j -00
bMaquiaone 60.63, reuxCinol 73-76. PYv*PM 4-3.41, gave 0vNCJM011)11j1% dwrow, 10-M, Ycllem. and
p G%Iuc, bd r4.24,
0o not 78.03. 3 -naphthol SMA .0-dapht ChNCJ1r(01f)(1[g1'k)s, yeffiew, d,x3 wit M. 240'. Simi, so
P-aminopbenal 10.3, gualacot 0.76; p-, o-, trut m. larly
_p-milrophes.1 save 0,XC,1M011)11j1`A. decomp.
jl~` uitsevhcoof, trialtrcrphenol. p-brorsoplicnal. met Tribro. 179-W .. and 0,NCd1t(01M11gPA)r. yellow, does o, 9
i :~- inopbenal xz%e 04,r~ 11C. When the itactions were melt. Similarly gave the Meftet
00 o! J~ conducted .4imilarly but in 3 cc. H1011, the following 11CPA deriv.. dccump~ 1.1,,1-7 . yellow. HrAiing 3 a.
IV of Hs imc imiated: PhOll (13U') Q. hTdT"in""C ~!:,Ifs 3 it. -brotnap not 3 hri. to 130' gave 0-A5
600') 3.46. (130*) 74.47; resorcinol (130 101' pyro-
49 'tOM, and 2.1
4. m. 145-43,' (front 11.
09 i~i KAM 030) phlorocluciual (Ial') 11; I-Mphthol BF *.It( 11) HZPA)t, dt" not M. 2zol. too
(IM', ; 2
oo a ' 79.W -n2phthol (1*3*1 3m; P-AminoIAeflol which with sk.. I unlIrr c1ravage ul the type given
1130*) SI M'. #-nitrosibencl (130 ) 71.47; fft-nitteephentil above, while Or In K Or 344n. givrs 2.4,64ribromophenot;
(00)*) 4); o-nitropheneA W) 4.88; tristitrophenal hence the product is :!.O-L-4.(phenytin~"Luri)4.bmmo~ 1:` to
(M'l P-bromophenal (130*) 0; trib"RnophenoJ phenol. Similar reaction of 2.4.6-tribrotnoI,hrnol gave
MAJ") 0. cuaijA-1 030*) I.S. When (2-C,*IIj)3Jfg tn. 174-
wA% substituted for Pbsits. the leAtowins r"Wts j% jig) I
were obtained: hyd"u1none (2 brs.) 0, (3 hm) 21.7d; 5' Mmontim.1 Ph,IIx (LI. X.), x.
6; 1- and 3 cc. F1011 heatcd 4 hr%. to l.R)* gayr 1.57 a.
resomincif (2 hn.) 47.&1; pyrogatiol (2 Jim) A4. (011MMPAh. girry. I- n,,t m. in)'; beAtinc 3 hn. Vo
naphthol (3 hts.) 81.4. IFT014" 998 Etoif 0 hr.) gave Iola. idumb4c CX1011"'Injeo'. rhjIg ft.5 C.,f too
) 46.92, (3 W.31, (4 hn.) CAM -in4in3cc 't0lificat, - I
11.04, (2 firs. and 0,5 a. rmwc -13 hn. to 1391
If PbHg (3 a.) -d 3 a. &-niUwhenol ke" 3 hn. at 130* -omp. 131)% and CJI- two
Of (0114MCPA)" fell, 11C,
:tl
th-n 6",1 of benzene by ffisto.. followed by tzestmeni dark ,A. ins(4., infutilile uAid, PWIC
too
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C4115WHIMIPPI. insol.,dws not in. 240'. (I-CoffOs-
11 fit (1 0.) itsil I c, 2.4,S4ribrwiwVhcw4 impt 3 hn. 2t
.1#)' gjkve 0,98 g. Bp,,CJi(OM Mg (74h). itecomp, Mv 1-
" Olin hens, ), which birtaks dnvu "ith ak. JICI ut
yiel'j, appamtly. 1k.c$111,010INCI. in. aml
Coll.. ReWition "nj p~bramophenal pyr BoCsii,-
(Off) (lit MI-orAinst. in".. 14w- nlit in. 240";
"Alit mpllrm4 JtAvv fiiNCjl.wHsU14C.Jl,),. IvAllgr,
I,w~ nm in. :W.
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S4 .WIT Pvdimf. Nt"I. Ino.). kV.SS.K.) -so
so 17. IAI.-S~W,1741(ill RuWaul- 174tic The iv,hmqur
JVW111431 in I'Aft 1, tU1ftAIk%1C9- kX111110C W-J 9-), OW'JOL4
so 01.3 S.). and ak,. (solwat, 3 tv.) (or without &k-.) werv
Altovmf to rract at 130*. Di devivs. wtrv Inost reactivr. .00
0 followt-d by III, Pb. and %. Pbsill and I-C,.14011. 3 8*0
so Jj' Ili: Vh.I1bgavvTA.7Ir` Pb,. Ph.Sngawtll~.Su. With =00
Py"CARC4 JL* The pb~rl~.)f all4l FtUII ItS UlirrIll, ['111111 , S
give 112-42':; Hi In 0.3 hr., WOW',, Ili in I hr.; 40.110s Ih roe
so
s: C-Avc 17.51% Bi in I hr., 49.97, in 2 hrs,, 64.97!7c In Coo
3hn.,and7#()Xvin4hrv. Ph4PbpvvW'pPbin3br%.antI
Ph*Su oc:, Sa it; h hr4. The mg. rv~tkwi jw"lucts werr Kos
C'114 of Mp. 000
or* 0
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ttshittes in acyl Ictiv,. of lit. I'll.
IIKCI mOily virld, Ilig allil Illicit ti,ril it I.."Is ll*11111
I tic rrkctkqls didtf (timn tNmc otilAititil Ily tile jol'"t 44
-
il
%i
l b
l
l
l
ucirt
it
v
A
ng
I I C r it. The ritlits. w"r %-ji
r,
2
60 ir 11,111141 0,3 9 14 I-Afh Ollnt,~Ut With IW -ilbXit
,C
4
040 Wyent for O.&A brio. Phille vields: al lfkl* In Moll.
'
or 1:4)* in twotelle, lictimir, Me.N. 11101MCI (.,t IJX(
I,);
00 .41 1:110 ill w4for, W illt,ml lim pt-lumit m,
00 twul"It. 1111CI.. ~.ml lit. At I:bl, 1-1 411111 Ow
Are Ilit. lligk:l,. \I,-,N. Am[ AM.
l~
il
A:
II
II
N
Ii
d
i
M
Nr
An
I
,j
,
l X
.
,.
t,
g
ll

0 urul lit, whlIQ (11hC110111C Ochk Wilclill" 1,1101,1110.
0
Nfr&S. and Ift (at I:Pl* ia FIOID. 11101h ill R1011
00 130* jivvl 1111,M)CI. %fill I'll'Phelf At 110'. while 1111""r
thicip not rrAcI cvrn at 1.10'. (IA*,,II,1,IIi at Fit), lit
Floll givro Njr,.N. V10111. olod 1110"
"11114. Philli 1111.1er tile 411114, L-olpfili'llis 'l-milf v..m
t Ittetcly. yi,hittilt tietli'lle 'Alta Illell. G. M. K~
10000041111*04111010,
10 a
00
0
00
0*
0 4i
00
00
00
-00
'00
oo~
00 00
A I L I I L it,'- It 11110.1t.1 (t kill;%
0 so
410
'00
0 tl it A. -0
:0 It it n ti cc r, to v IWO W 1. it i
o*o::*1ooooooooo6oo*ooo 00 06 00000000000*0 64018
0
1 0 iloO00090004406600
go 0000000000000000AA

UM/Chendstry - Trimethylaydne, Chlorhyfi.. My, 4.8
drate
Chemistry - Organic Compounds, Metallo,
"The Reaction Caused by the Chlorhydrate of
TrimethylAynine on Metallo-Organic Compounds," M. X
Katon, Leningrad State Pediatrics Med Inst, Chair
of Gen Chem, 4 3/4 PP
"Zhur Obahch Mie Vol XTIII (LM), No 5
41methylamine ohlorbydrate (1) readily decomposes
into trimethylxunine and hydrogen chloride (3:1)
In the presence of metano-organic compounds. The
3:1 evolved subsequent%v replaces aryl radicals by
chl(wine in mercury, lead and blemuth organic
8/49T67
DSSR/Chemiatxy - Tr1methylazine, chlorhy- may 48
drate (Contd)
acimpounds (at 100 1500). In the presence of 1,
Mercurous chloride at room temperature readily
decomposes into mercuric chloride and metallic
mercury.. The reactions of I vith'idetallo-&ganic
ccmpounda are distinct from'the reactions - 6:t -
hydrochloric acid vith these compounds. Submitted
20 May 1947.
8/49T67

k6t&, V. IA.
~f. Y. Voton' and A. A. tollshakova, The reacticn of dirhenyl mercury with phenols.
IV. P. 1290.
Diphenyl mercury on heating with various phenols at 1000 decomposes with precipitation
of metallic mercury. The decomposition rate depends on the nature of the substitutes,
their amount and mutual disposition in the benzene ring of phenol.
Leningrad State Pediatric Medical Inst.
Chair of General Cherdstry
June 2, 1947.
SO: Journal of General Chemistry (LWR) 18. (80) No. 7 (1948).

KOTON, M.M.
22981 Reaktaii difenilrtuti a'aromaticheBkimi alldegidami i katonaml.
Zhurnal obehahey khimii, 1949, Vyp. 6, C. 3137-40.
OSt LETOPIS' NO. 31P 1949

C'Of/
/-.f
Reoctions of metalla~ Ic compounds with pheuols.
M. K TO
I.- V.. 1'. ~ I-kvina. ind F. S. FRxiiisW
A
, A
J. Cen. CAt-. W.$,SR.) 19.
. J.A(,:~ M14111)(Fnali h tfAIII1.16010. -.';re C.A, 44,
1$311f. 11 1. V

C_/~
The catalytic acid-free asteitication of bmxyl alcohol.
N Koton and S. St. Labuzov (LemingrAd SAMC PCIII.d.
i i. I
): J. G.. CU.. (U.S.S.R) 19. No. 9, al-194j)
949)(English transLation).-Ste C.A. 44. f
F -1. V.

611
1.614
It tractions of o- and p-ditalylinercury with phe-1%
1. Nt. N1 K,-t.m aml I A. VIN-111,11. Oxilluji.&A lo.o.
, ','I 011-11"t .1. (;em. CA,". I .:S N X. 11), %,.,. I I ,
\
.0,7.7, C.. L 44, 310'-
1". 1. (..

c4to,
/9
Reaction of diethylMorcury with 116noll. V~ NT. M.
Kut(ml IlAllilljrA StAle 11m. P"fl4t. M"1.). 1. Gem.'
Ckom. 1U.S.S.R.) 19, 'Al63-7(194Q)(Pnglkh trAmWkW).
Reutim of diamylm4rcwy with phenols. Ill. ibid.
C.A. 44, 1043i. I:. J. C.

\20detwit, of diallbylMoncur with lifinifoll. V. m. m.
Zkkf 11MA-Arl Klim.
J( 1041ll 1. 1. 1. 4J, 17 if Pg. 42. 1 ik4h. lit I Is react.
phrn,A,. Ni6ling CAI.Alul HillgArolldefrivs.; -ith
Irsurcin"I vir ditilelt,111414A dirfiv.
It, I tic t Irm (%,,is tl,,i A1,017 %fill Inctra-AA
4 11
- I Ill It . pirl.1 I'% the 6.1111till-111.1ml fileth'.1
C .4 24 , Al".%SAw"I VOtstit"t. INS01".1
b-Ii'd ",tit All A IJ1141 tit. kit i g 1 411 lite VAjhIjjA Iihtl)4,jz
Ill N-AltAl WIT% 'Ili M-1 CAW, 1p4Ml4r the tuht i
1.110111"311"
II Ill; dcri%, lit, it Lp, lia%C I A"
1,~
[C-11ir "Ille'l 'Allb 1.1,0 K:Ivr 11 12 x I- tilt
it 1-11, 1 wll F I A 1,
lit\ I ,it, it. Ilk 1 m 3 111,
I lilt .111.1 it I K. I-II.L. illwl I 1%,t. 1.T.1 bd
t pit!!, -1 -AY m 'tw"Illp, 141,; :1 hl'. 11
1.0 A Ile .*, I.." I Ill J11.1 11 11 it M the 'JINIve left%
w -tit fit A Ili, It lim, jaw tilt ttv.4tillcm
,4 the Itmi lit) 1 t4lll O'N' 1; , In
1 49 2ldr-,mjm- it Ili,- de. w1n. yiddixt ll~tk~i X.
fj11((*jj,j?,(( m. IKV; Lk FrActlun run at 130, K-ave
,,oldy he It, pmlucl 1111 g,), gaire IOW74,
t.m., lirld Im ('rx. delivs. at Ito,' w 1.341". P-Ilr-
C111,011 in :1 lit,. at 1:41 ' g4vt 3.10' 1 fig ;&ntl Ale. c%tn.
give Filig(VtoOl/l/ir, lit. 112A 111.1N J.); at 1:41'.
.fill,. Ftoll. fljvrrA,11MIy1,hk%I 14.W; Ilgalld
tile 'llpuvt. 11triv. ill if- :1 lar.. at lZill' jf,tvc
Its And tr-imcni I-[ the residue with F9011.
Arn SAVt 111"111 Ill" L.mr ,Ill.) OA K. L"111C.
fit 116 7 . :1 hl~ m 1:W m 3 ud. V14111
Kj%%: !9AI", Ile '11.1 th'. 0.,%. .1,11.
(M In ;I lit, 11 1.;., gt~v I'', jig .."A .4 .1...Iv rV,tg
ill lit IA K. i whieh v,-uld imt k- vurilw,l kit
011CC.11'(f 1/1 Ift, :1 fit,. .11 1.41' 111 :1 fill, 1.1011 K1%,
I!, V, Illf.m.1 dir tl.,Vr.lrfll
A Fill" g v, .1 %V fl; h, 1, 'Idm- A 1, 1 -4,141lig " ith
1-ttill . ~tg -~h CAI. 1- -1 g 1 111,4 '11
~10 $I% ilia 1111140
"till ale. IICI , i's I III, It I.W :1 ml. V1011 ,r~
IttIlAitlell 1",2"; flit "I K "I th"
Ililt.01,Nq), m ,I lit, a Ijil 41vt. ISI~V, 1, If
I-Idur. dill .ill 11. 111(1111 ImIk."Ied itill.,
1.1 1. g-, Is -.11.1 1wi 1,c 1,1111
1-1 I'm tit, ,
I.mirl Kj%V I IA. 11111. m (,it F1,11g. .1114 list It 'Ithellof
itimill jig Reaction of dulmy1mlificury with
phenols. V1, M M kwwi I k,d -. I I A I I, .'It I
mcm All"MIC141 ..Ill light, I;.%, "PI11,11,1C. 1., 1-11 6
'I I' I II-IM9 t'llit Ill ill ~" -1 K - "I
lit -.0"1 1111- gm file lig I'll%, limillo.
tit ;t lit, m I ;It . 1-41-,d bV Iteatittoll with
FtIAl .110 cll,tll~ if Ole It' .011, fr"In C.11. g-4w -I IN X.
.1 lit. 111, 19 . S
"IllitUTIV. ,
C.11,011 ga.l. 'I 1Z. 1; .1 Wit'I" In,
%%dt 1"', It', ltg Rv.will"It, %%Ol Vit.
pVrj,,gjIj,,I, litt".11,1111.
1-mmA. "It-I 1101-111itum, g.v,
fir Old %J1.1u, 11111mrilialdr pr-ltjrts~
C. M K-,IIj-tI

mrmj 14. it.
'The renction of diamylraercury vith ph(,,nolg. VI.17
Koton, M. 1-1. (p. 734)
'10: J,-)urnn2 of Gen-rnl Chemtst (7hurnal O'bahchet Khtmii) 1949, Vol. 19, No. 4

C1031
... 11 -
The reaction aromatic mercury compounds with di-L,,
methylanifine hrarochlafide. M. St. Kc*x% aml V. F
M.Arlyllo'.% (1'~..iltgrml St.11C In'ti. -1. A;-
Chew. V-5.S.R. 19. trvi,latinn)
Sf-r CA. 44, 2A34-
F. 1. C,

I 111meircury with AromAtic, aide do@
and kelms. Rolm T. it - tot, it ~14
MAW Khm. (;7C`lrM Client.) 19, 11.17 40,11I41.1s
"hilli W..'s g.) nd 0-3 g. j his, it
150' in a strAled tube gave 0.15 It. J1AjjCCjj, 01ilk'11(l
yellow, in. 81-3' ifilum lvttf. ether); thi4 richl- VhIIK6
or% ilunding in a %trICO-FtOR ultil. of Itcl; 0"; Ilic I,
alui(nmett in the syriftsis.
6 hr%.. much tar furtm, its WCHAS 12.70, fig. AmmO40
hr. reaction with Acph Caw 0.11.1 K. lit
W5 6* iff"111 U1011-F40), whirl' JI-- give- 1-1111KCI I-1111
.Lie. 110; 1.06170 lig is formcil in the synthcAss. I'lillig
(0.7 g.) and 0.241. PhCll:CIJBj altrr3 hr%. at I.1A)I g.lve
0.35 C. PAjjfCjj.Cjj:CjjHS, 11. &S jN~* (jr,)m
which behaves as ticienbcd abo%c; no [IF wai dettvtol
PWILCIIAc in a hr%. gave 0.3 g. 1111(c
in. 85-7* Ortan JEW). and L-Mc. 11g: extension tod hr,.
g-Avi:6.7%lig. PhjCO, PhO.Nte, Caff.. Ntr,Co, atilt flu,yr-
tnone failed to reut even in 9 hrs. Cimxim,jidek vdt vid
fatfistyltilftra,iludome gave tan and and IIAII
111 re.p., In 3 hm.. or 44.13 mind lit 0 his. PA
i.-C11, in d lirs. gave 5.3% flit. CyclahexafiOllf K IV,
R
41..%31'~ lig In 3 hr%. and 22.5`~ in fS hm G. %I - K.

CR
ReActim d dromlatic dertrativin; of mercury with di.
mothylanfte hytimclilovide. St. M. Kotlnt ~ot.l V. 1:
%1AftYUOVA. Zk*r. (1~14941 Kill". (I. Otti. Chull.) 19.
1141-3(lwg). --fleating 0.5 S. 117,11f ith it--^) K Nil,
NPh.liC1 in ampuli 3-4 hrs. to 1311 yickl% a tiell Jv~
(probilitily an analog of CrystAl 1,11olct), C4116. 0-11; lit.
4,%-M7. lic,Cl.. and 48-127,~; liff(lig0t) " 6%otAtvl 4,
l(gS); a 0-hr. run at M-11" ca%~ 4-1l; Ifir, :tlv~ fig-,
Anti 29.57c US * '; (Cosilt)JIlt Silititatif tAVv ill J hlf,. It
IMI: 0% Itil, 25.71t, lit ". 72.411 Ili *. oid C,.[(.; at
t5n xxue 9.7% lfg*, W~ lit * " 3114 1'.'; UK wltv III,-
Wiled. SmilAr hcating ith llqCl, Al- S.%ve the VvIlvi
dyv, without loctuAtion of fig orligicli'llula salt, (Ctll't-
lit'.) KAYO _#, -80`~ lit, llsOll, and sovic M III,-
vitilritlyr. Thv re4ction h ItClIvVeil to proceed Via Ih NtIell.
of the Antinc-IlCl, with the [ICI C10.1ving R,Iljg into Hit
anti 111C], anti the latter mActins with hic,N11h to VIO'l
the dye in all oxidation-miuction tcactitm, C.. M. K

Reaction of mattillaftstnic compounds with phentils,
M..Sj. Kotint, H. P. Mo4vinA. and F. S~ Florin,kil.
(jXcri.Chetrt.) 19, 1075
lit-atins Ph.Sn. Phl-b, or PblJi with phenol, eAu-, th,
lo" of .11 Ph UOUPS of the nittallocrig. 'ul~tjncr with
fogination of C41fe and the pbeno4w.; of the currr,jx,mhnX
nirt.a%. nr anAIOSY With the Te3CtiOn of Mg. ACIIIN IA
I.Ant"I out (Clicept (oc I't.dCrivS.). Heating IIA C. 1110ii
* 10.3 C. P4NN'Cjl,0ll 1-3 ht%. to 75 list * crv- C.11.
.:"Ilan Urdrige. infuAble. in.A01, MAW (#).):I WIN C 1; 1 hr.
1 IIIVV* (b JAY-k-1) hr'. giv-
' . &XI
VJI'(O )Not . 1,0.and I hr.at lU0*Xivr.Ihr,njn-,
while 3 hr%. gives GIMOMSO'.840,; Irr.itinent of .111
iniih cold ate. HCI gave p-nitruithenol. Ifeating (u, it.
llh,Bi and 0.2 a. pi-McC~11,011 gAve C.H. 411d WIN C. in-
,til. yellow 3 lir-. -it 1-10' with
2.4.0-ClIcIllcOll Similarly CJVt inVA. Yellow I t7#(*4J/t-
tb,bi- In It hr%. at 150' 0.4 g. Ph.Sn anti 0.4 jt~ P-til).
CIU4.SOI ZAVC WAS 4. in"01.
%hilt p-McCJ14011 CAvc 0.08 a, MeC611.(PII.Sx(P_ijjtP,
.ind in a 0.21-C.Cipt.. 2.4.G-CJ,CJlOll give.1410" whit L
on hydruly%iji gAvr W(W) g. Sn(h. At VW lot 3 9 lit,.
11-:1 a. Ph.Ph anti 0.3 q. p-lftWjf,*NO, give O'=1 0.215 it.
yt~tlow insol.
.NfCCJI,Olf t4YC U-1 I. Yellow irml.
11,0; 2.4A)-CtCJl.OlI jp~ Pbel,. C'. M* K -

Catalytic nonacid esterification of benzyl alcohol
M. M. KutunaliadS. M. "- buzov. ZAigr.OhtA,h,I Khm.
OX-in. Chem.) 19. 1713-14(1919).- Va'-r, ,( I'llcll,-
t41 at 15 nit. Ar. ut ='." ill a Sirram of 0 11 1 IlrA o%,~
Cu-Zn catalyst (cf. C.A. 31. 13:All) tave. hum :PI iifl~
1111C11,011.2v fill. (ofidtli'lle. CI)IIIK. lAj.W,:, 1111)11.3 %V4
H&W1,11h, MA18% Bill. und 0.4111-0 PliNle; ill ail air
wesm Ilicile figurrs arc 11.41), 45.05. ali-I
esp.; I'liC111011 ultine g;ivv 1.7d. IOAS. allil
,:1K;,. rc.,p.. -hfl~ 1:1 I'liC11,011-1-1011 jen- 1.12';
A
111011, U% FIODS, -Q'/0 aldehy&4, all,] 0~, Nfellb,
G. M. Kosolarwfl

Reattion ofo- and p-ditolylinertury with pbstiols~ VIT.
M. M.- Koton anti 1. A. Chmov (Uningrad St.1le
Ited4t. Inst.). Zhur. obskA4 KUM. (J. Gen. chem.)
9. 21t4-8. 1919). cf. C.J. 44, lWi.-fo-.%fcCaffjtlfg
0 and ;hc&-i~Axnrr (U) rmct with phentAs ~najOVxj3jy
~
o 1`11311 ; e mictiom proc-ml 11"Ambly via the radirAl
turch.inimn anti Api-ir to tic grocral for kilts camNs.
At OW the billo4ing ',; yiekis of US vrm J~Uint%l un
liciling Lqual wts, of plicnots with I tv 11, Frip'; P.Ylo-
h,
tAll,il 91.49, 71.71; hydroijuinnne 71YAl. NI.Wi; 1.110.
C,Jir 88-1. 49.11; ri~orcino! 77.6. :111.31); PhOlf M1.9,
L
15,72; &-(I1rCjI,0lI. e- and P-110C.H.011, anti 2.4,i1.
11r.("r. W.W.11.011 Jll WIVI its yietri Any Its. The
C41111111CMUY d1riVS. ObtAin"I in the rcActi'mis wcrc:
toin 11 sind 0-110clif'No'. p-A1eL*'11'11gc.11'(01f)Xo'-
(1,1), tu. 21-11)-V, which yieltis %IcCglIjIgCI with ~ltr.
IICI; 11 and P-IIQC,li,.NOj sifniLLrly [Ave p-.Vn'.11,-
in =0' ((ruftt Ftoll), Ai
%vil 41 YcHow. (foes mit
lit VW In-A lit If and
Vidding ~1'4-
c*,li'altille./hiolo1jr, In. lW14te;
tIC611#011 Oil liflitnin4tiOn in Klir vot:. It and 2,4.11-
11r.Cjf'0II pvc (S hr'.. VA)') P-Afectil.114C.11(011) lip"
ju~ IK%-7* Omit PRO10. If mi-I 214111- (0) N) ~cj (,()I I
XAVC (3 hirs., Ilf") Yellow
,lecom.p. 14.14' (from C411,); I and P. I0C.1I..1;0i gavr
insol.. inhiqible; I ami
p-BrC.11,011 pvv pink
Infulible Solid; tand 2,11.11401NOX411,011 C.Avr
11c(V1(01WS00,. lifowu, decomp. 13-W% 1 and
I V 1C'II'N(hrlvc 1111mittle
Y'llow WAid; I anti fevircinal it.iyu into,ible (-
Aft Ko.'Ut.~tf

Reactloos at Matillodrilitak comp"Ads with thkokendic
M. It., Kolun, L. 1'. Nto%kvia.. And F. S. Mcuitkil (Phys -
Trvh. lust.. AcAd. Sci.. Leninpaill. Zhur. Kkins.
(). Gen. Clicin.) 20. LIMI-Si, 19-10); cf. C.A. 44. 63W.-
c4ting 0.4 C, PhIIK and 0 3 S. PbSIl a has. at 17304 gave
I 'Mr~o fig, ~LHIIC Calif. Mid WASh. M. N-60', SLA WCU as
IV %. (PhSlalij, fit. p-SICC41I.Sil similarly gave
11,; flat. .'11W Call,, 411.1 o a a. (f,-, NW1.1;Y/t. 11). Uhq-
,i((C-1 Call.). Ille lid .11, 1 111:11juile 'tAble aml only
owly deca'alp. into R.Sll aud IIjtU*,,jj I-qj.jS witli
Cl. licating 0A g. PhJli with 0-3 C. J'h1;II 1 11 has, At
'l,'10* gJVV g. yelloW (IAM11h, 41,WS at in. '-'.At';
MCCOJI.Sli gave 0.-"' g. red. dron"p.
"-&)*. PhXb (U~j A.) JIM it.:$ X, 111t.101 heAttil 6 his. At
and 3-d his. at IN)' gave *)me Call* 41110 0.211 It,
(11S~Pb, 3rcHow, in. 191"% and 0.12 K. (Phs~; P.
%tcC#If.SJl gave 0.25 S. at. 2V.1-31.
Ph.1ki (0.15 s.) and 0.3 x~ MR gave in 6 his. at M' some
1-9'. wfictse anAlysit indicaivi a mW. tit
ciyatals, m. Z.
(PhSh.5"011 with (11S).5a; p-.VeCJ1,S11 similArly gave
U~21 111- (A-M#G11.VhS4(0/1)1. m`edl". Hi- MOM
Iit,O). Thut. Ph frtyn Its. Ph. SH, And Bi compds. reacts
with 811 of thinithenol". brims lxazrn~ And thi"I'llenolAirs
of the niviAls, The f~activity (jecrustriff ot'ler) is Ili, Its.
Ph. Sit. C.. M. K(.AoLipoff

1-1. KOTON

r
.0.
4
01~v
-i 1-mi-AW41 C~?
p '
IJ750,,
it, 11W. M-21r16-2104)
Memufat kin of ithenols may Ite eff"ct'd by ,,mpm m I. of I 1w I qk~
14,11,1 And Alpo, 11,,%% rv;Uliiy, lft;OAtt, New
'040""' are
cu
-
(a-2) ulth I -g
(MICH ),jig
t
K
l
S-) givel
ig 11114
t2 hr.. 7
sutrA:tjrib,-n:rnr J0.1e) g.), tit It. 9.5-j7' (Act-mps.-I by fit 1 1:1011
to p-NOl-C.1111-011. in'll. 112 - 114", io,d mp. lo';
11W). With I : 3 2-and I
p-C&HIlle-01-1. I'lillig micti. mwc ripidly t1i in %vith
an(I.P-C'tI'.N1e4;lI alld mi tit kite

163'114 mm.. APO 2.86, mho 1-6317 Pit., b. U2'118 mrn,,
1-87. tit 1-67M, With-Br. h-rc4pis of I kt Us", &VIOR I I hr.
C. an unidentilictl ur,_.jturttLtI gas, and a Inixture.
Into tiva fractions , V1, b.p. 67-93*. and VH, b.0.
itiva test for CtI:C - with
" VL wbico
i
vcs a pos
g
NH Is treatcojO Witfr Br a~d (ractionated, yieldi..,g Sia"
SID 1. hp~ 7"2* (lit.. 80' d" 179 and I : 2-dib""jo-
01y"Almia~' C'I(Cj'I3r'4;j (ViII), bp: Mot., 210--213-1
-
rl 2
ith
N
73S
OH VUt
marm., d
a
-. an tmatment w
aq.
.1, tip 1-5458
*
-
3l 2
L4 1-5432
i
CHB
i
CHH
3
VII
b
-
.
ves
ves
r
. "
r.
p. I 11-1 t4
.
g
. d
C
4
a
d to be a mixtu
e of U
od
t
id
14
6
b
uc
ere
7-1
Pr
5
. cons
.p.
r
(M.
an4 2-boromovinyltn0loicrAlan, ; treatment of tK with Dr affords
a mixtUre of M with Its I : 2 g.t3omer. which with exccu of
NROH gives on distilLation e3 Of flA111C--hAlG9C11atCd
(UI with
t
inolft
t
l
N
w
tmen
aco
qu
em). IV (chmutc(lied as
y
q
* d
~115
hr
i
es ITU
SiC1
I
l
A
,
.
v
vL%
. g
r.
M&
4 and IV: p~ru
ysk
9
alittlo Vt. and unidentified a ysis ~f Ix
at 630-660' during 8 hr. gives i ment with

t
' ." interactiom
Brt,&1emUmreCH1C-SiCI give: SICIa~d Sli I., t
1

at CHBT:CE I at mi--.affords what is -
If$ and S53
41 aU7 n8 or
C1ASi b.p. 76--80*1
C
considmd to bo bremaethyieyltricAkrorila"A
.
%
11 diam., isM 114~40. it. C. FORD.
% _
_7
7

.)p
k I ~
i A lao ^&- k 'Xt n4"A - ~ / o
7 7
, 164dions of mct&llo&g&Wc ownpounds W" thiophenol 4
x0ton, F. 1'. NI'mkVit". And F. S. Flolillsl,~:.
, Y-.&Ckm. U.S.S.R. 20. lr4n4-
"tion),-19" C.A. 43. WAU. It. L. M

-/-a
C
11, Vill. M....
,,. ;O=wn -Xt.
In ck,qq. K
20. L'171-x I C.A. 45"M
11. L. W:

t#1
Ram of weawsy" M4. 114JL.~ 9"t'" at"I P.
"vinskil(Acad. sd~ U.N.S'N.. tr~wjrwtil-- 746F. I *SA4
Kbsw. 0. Gorss. Chem.) 21. IS#I -3(1100 , - Ilse jwqm, "i
lotiewing eam al md4wt*k stiW is moxt"I; thv low"
r-tart ov powpd. by tfvwt estefdMOMI of (be fhv a6d.
while Most &4*r emu Bu a: 0
P:,by tranwaktificatiou
of Me ="bacryuct (sk. ra and 40 givrn): Ei.
mn
p
b. 0.9116; Pr b. 33-4*. O.IAM; iis-Pp, h, X-A%
OJwfi(P Be. b. 20-41)j. 0M49: iso-Ro, b. 36-7', Olcjoi:
sm-Aw. b. 3.", 1, oArA4; Am, N 34-7'. 049T.41; ii-- ow th.
49-61*. 0-M711; W-Aft. b. 43-S*. 011441.-; Cjf... b. M.-
RAIN;
UJI"l;
cou th M-A', OW41, sploAterv?. N 0-70% OW, I.
J`10% b.*W. I Mri; diaw,ow ejww. I% aw. voivp
Polyson obtskwd wfth coccii up 1'. His. ith OA-. 1404 1.
--stall" 401 Owe. as T.A' stod :,14 ht. dl looff'. arre 64%%v
-&b. Pa. in SfisCO And C.If, Pplr~- .4 Cott* U11t,
t'... .". we" tLitio sAI4. sol. 'k, AIMnr. f1w rNt" -4 the
,Sc. WAS tMly pArtly M4. in Mg. "%Vatc Ifich"
tcM K%vt tiquw p,4yrnvm(thr Cattd ConteftemamdY
TbecTT&'vI&c1KOcsftf Comm
M.A. xt.-y 1.4y%vwr. as did Ow I" Cott. -An Me ftte"
1911 WC, c"49AY"Mist in rmuhi- -kb rhcwcu~ sit well
i" Wit, V1. M. K4-kPag

CP
It p Nivina &Ad F H. F=444n=
mi. 1"tfo-fl' 140# f4thibef Kits*: (j
I !#" k1wf" ISO, 1043 Tt twit I It"Rqostalk"s "Multhl tof I
jok) S, nil ith M S, lit And 1 4. Fr, 6Akmrd by.3 hc.~ at
100', VAvc 11717, b. whicb, converted to
RUgUr otmi trr*1rd with Acil dV' p-PW1.01-
(011)Me, th. W4 d'; this ~m deg= (~.4 by
ovoi AAA at ao)-441)' at 119 uto.. or Wo uvil by
with KIM). and hydfuquisone) gave 111)"
too 3"' d'* I.MW; d4romodc m. 73V-"--F-Cdjf1:m-;
(W .);with A3 g. Cov" in CCI. 3 days at room temp. gAve
p.. bw 70'. -hkk (40 g.).
b=ftd0M4"VaMbdth-3dQ with 32.6 g. C1114CO.M., it
846"11. comcd. acid Altered r
Are
1W. PYIMIW, Mitt M Ud.
60% #*"i4odmit acid. M. 17241. tk; (34, 6.) i;;ted 3
bra. with 3.4 g. CuSO, and 65 S. quimcIf witb slow dista.
at 2W-M*, pve 43a o-j(mmost rew, t:20~M~Idj* 1.11M.
0-CICA a gave
02.
3(11~- Iwhich save #a
1AV=; skaikuly W" prW. 7--,
Nj~-2* d:* I o" Uhrwime. ve a
m. W7' it ~iogjwmsc
"M. m. " .46 8 , which pvc ~d.B p9m. After-
RAtiVely, 10 6. p-WJIAC hftt an stftm bRth 0 hm
will$ .110 ML iso-PrOll And IN' nil. utd. AKOCIlMell, In
0 11 Ott h 11,tn 4 tf~ XICTCo I A% r -_'6 5-
"Ichybok-n V'r#
:e(AA41J,#ftd. IN 144 5" ~~kjmd fat
AlAh 417"AF; U. I-V '1- 1 -'Rool .11~
* ;~ W. b.
d.. (mm w6r#medmaAmw od. in. :12 14' DW,
inglons 111INIC3nihm with.Wig AoCl aW 130 6
/11cls, Inxitims into t"It 1110, Iteutratizing with Altah,
bring, ImAlissig the jn,i. I hr, with cunot. IWO, ftrutraliu
f~,
Ing, I,tV4'IIA16tg. the ?"klual Pb\*Il,. Anti W-tts. the CC41W
with Hilo I-Air In#. n2. IM d* (fifou
11A)), wthk-h. dwolixedju HIS" an44mied *it% Ak M1W
o( KI, hittinv, Anti pumd Cu in 110 0- 48
PAWsomr, rn. ms 6'. yielIting with AXOCIIMet~ 73% 0~-
wdo*xyi)mdAyh&,bix4, m. 39-40', whkb m tiebytkatim
with KIISO, in the ptv--entt of hytkN indne Pit 411r,
p-iodoslyrm. in. 43 -V (from MtOlil, W K.

tat.
Im
th-vt
11M
mv
tv
pts. wc9T
.elf. w" t,
40* of the dMv.
t 6 1 Cal

USSR/chemistry - catalysis Nov 51
"Reviev of B. K. Dolgov's 'Catalyais in Organic
Chemistry,"' M. M. Koton
"Zhur Prik Khim" Vol XXIV, No 11, pp 1222-1224
Koton calls book valuable material for students
of catalysis and lot comprehensive USSR vork in
field but disapproves Dolgov's occasional depend-
dnce on reasonance theory. Introduction covers
development of catalysis in 'USSR. Ten chapters
treat catalytic principles, adsorption theory,
and different types of catalysis (oxidation, de-
hydrogenation, cracking, polymerization, etc.).
204TU
USSR/Chemistry - Catalysis (Contd) Nov 51
Sp subjects include A. N. Bakh's peroxide theory,
N. N. Semenov's tb,-zory of chain mechanisms, and
development of synthesis of liquid fuels, methanol,
and laigher alca ---.a laboratory investigation to
industrial pra' ion. Book published by Gookhi-
mizdat, Leningrad/Koscow, 1949, 560 PP (text for
higher chem technological education).
204T13.
C>
~4

USSR/Chem.1stry - Styrene Derivatives; 4iar 52
Plastics
"Synthesis and Study of the Polymerization Capacity
of Styrene Derivatives Substituted With Halogen in
the Nucleus-Synthesis Dichloro-Substituted Sty-
M. M. Koton, 1. N. Samsonova, F. S. Florin-
skiy, Leningrad Phys-Tech Inst, Acad Sci USSR
"Zhur Obsh h Xhim" i;i XXII, No 3, pp 489-491
Developed general method for producing 2,5-di-
I
chlorostyrene, and 3,4-dichlorostyrene. The process
with p-, m-, or 3-clichlorobenzene, reap.,
which is treated with anhydrous al=innm chloride
1.209T4T
USSR/Chemistry - Styrene Derivatives; Mar 52
Plastics (Contd)
andL acetyl. chloride, to yield dAchloioacetcphenone.
This is treated with isopropyl alc ~nd alAPIM41 .al-
coholate'to yield dichlorophenylmethy:L~ '.inol.
The latter, vhen dehydrated over.A120,2 at reduced
pressure and elevated t6mp, gives the-"final product.

KTON, M.M.
USSR/Chemistry - Organometallic Compounds Apr 52
"Reaction of Organometallic Compounds With Thiosali-
cylic Acid and Thiophenol," M. M. Koton, Leningrad
Phys-Tech Inst, Acad Sci USSR
"Zhurn Obshch KhIm" Vol XXII, No 4, PP 643-647
Aromatic derivs of mercury, lead, tin, and bismuth
react with thiosalicylic acid to form hydrocarbons
and metal compds of the general formula Mex(SC6WAo
Mercury-organic compdo of the general formula4iBgHal
react with thiosalicylic acid to form Hg(SC6H4COOH)2,
RH, HHal, and H H 12. With thiophenol they form
'~ a
Hg(SC6H5)2, RH I g, and(C6458)2'
224T43
Moskvina, E. P., Florinskil, F. S. - "Polymerization of halo
derivatives of stvrene (substituted in the nucleus). II. Polynerization of
dichlorosty-rene." (p. 789)
SO: Journal of Goni_,rql Chemistry. (Zhiirnn! Obsticheii _hjmjj), 22,2Lot__5_

of Ad e -f mg~itl-
tu,
T%riili; Menir, ~mdte
C~F.vcal Abst.
U.S.S.R. 2Z, 851-3(19j7). (U~-ng-F-t-rajj ation)-sce CA. 47,
'/,A, No. 5 ------ H.,
195A.

XOT011" M. M.
USSIR/Chemistry - Mrcury Organic Jul 52
Compounds
"The Reaction Capacity of Dimethy1mercury," M. M.
Koton, leningrad Phya-Tech Inst, Acad Sci USSR
"Zhur Obahch Khim" Vol 22, 110 7, PI) 1136-1139
In the reaction with phlenol3, di~ethylmercury
forms principally monomercury comrds of the
formula CH3HgC6H3(OH)R. Upon- interaction with
org acids, dimethy1mercury forms compds of the
eeneral formula RCOORgCH3'
22r
L35

KOTON,I, M. M.
USSR/Chemistry - Mercury organic Jul 52
Compounds
"The Reactions of Diphenyliwrcury With Esters,"
M.'M. Koton, T. M. Kiseloya, Leningrad Phys-
Tech Insti-Acad Sci USSR.
"Zhur Obahch XhIm" Vol 22, No 7, PP 1139, l140
Studied the reactions of diphenylmercury with
esters. At 1500, diphenylmercury reacted with
esters to form corresponding derivs of the gen-
eral formula RCOOH9C6H5- Besides the latter,
formation-of metallic mercury took place in
several cases.
229T36

Aoton,
, 's?/Chcrustry - T-lastics
1-3 .. I
"I Jan 53
"The ~,f~Litiunslnip Between Stinucture an,! Alullity to Polymut-l-e in Vin,--l Dci,iv-itivon of
I-oton ~irid T, 1-1. ~'.iseleva, Lenin-rad Phy:,icotcch Inst, *(-,-d 5ci J5_1't
.1 . 1; 1 u H
Dan "101- ~3"Sl 1'0 3, pp IYS~-4,66
2-vinylrviphtlialene, and
vin.~,ldec,~~,Y--Ironaph~~h,ilf,-ne were prep-d and the process of their polyn-eriiation studied.
I"- u I i ~l -
,4,. the b-isis of 'hese compls, it w:s demonstrated tl-.at by inrr,,-;Sin,,; the no of double
'bnnds in t'nc ~Iie no of conjugates is increased. 'I'his 1-ids to a :--reriter redisluri-
OuLion of the electron --;tm ,-Aiich enables tLc double bond in thr virnyl croup to omen up,
.nancim~ -.;, n. y 'cad V. Tozc",4 yov :;ov 52
ius cm polmcrization. Presented
265 T9

*, 1- - -. . ..I I . - . I I . .. .- . . . . . . ... - I . .1 . .
. - -- I . " .
. -- - . .. - . . .. - . - i * . I I .

VAYMUMM, B.K.; IONY, M-M-
Mormlixation of Pourierle series as applied in the calculation of
~alsatron density. IDok.1.AN SM 93 no.5:821-823 D '53- (MM 6:12)
1. Laningradskly f1siko-takhnichaskiy institut Akademii nauk SSSR.
Predstavleno akadenikon AJI.Yesmayanovyms
(Crystallography) (Yourierls series)

Chemical Abst.
vol. 48 No. 8
Apr. 25j 1954
Synthetic Resins and Plastics
f a-Ida
11 Acas,
qt"
"'Al"y Akad. Nauk x 93
PhCal.C11:01s polymerization " S~Udicd at 100, 110,~
and 1250; at these temps. the compd. polymerim sig-
nificantly more rapidly than doc3 PhCH:CHt (rtsults
shown graphkally ; the rate diffemnee is about 3W% and
the wCer !s V high mol. wt. The mom ready ry-
7'.
Meti.,at Is cxplained by lower activation energy ( 7.75
C41-/mOtc)rctatlyttOltYmne(M.24). G-MACOSOIADOff
Chemkd behAvlor of Lvillig1jiS. Jeannine CourdaeA.
rsduiltie P&Jdjudi ". . NO. b. 2" 1 iW.-
Fkimmayy of data, much of which trus appmmd in otber
publications or trade catalogs. on the restitance of this
methyl metbacrylate polymer to varlotts chemical re2genti.
W.H.Gwor

for

777`7

COO/2' t: _b
Pu --WIT),

Authors and, Bes

v
-Radiial, .lim- i Wit at,6'
-of styrene iui4l tipt d by the-vv~d, M
method
'Parlodic&I g Zhitr -fi wjn~''~z
ZI.
Dee, 1954 ,

Abstratet t
A Stu4,6 -at inir tbat
polpetizatj6 V-maans of marked atoms'shoiM&
berizoil j*~&-dicompoqes ~ during the pol7marization of a Ui.
byren
.i+
-H COO,~z:radicalsi a majority f vihich:attaches Welfto
mass., orming 0 0
ir4d-ad~ the' -
C00-
id
di
l
e
ra
ca
s. are cons
t9n
o f -
basid
1oxi Wti
olomerJza
f
f
a
Th
e
chai
s
tfo
i
Ol
.
a
o
-p
s~
e a
m
n
_
r
n
ym
p
during.styr. ei.pd '06S
n in, the presence of benwyl poicd'ade
''
' ' bj, encounter of . twoo growing chains o iins . chain
.takas,,j3*
'
And benzoate vaacal-bitt not
,by the transfer of. cbains,,jtwas, es
.
l . !tabw
-
~i
lished
0-~bonzoate radicals attaching themoOlVes"to''
t1~e__-~*1jmer,-d6psnds'.:upon. the conditions of,polymeiiiatioile iicre2sa*
in temperature and-IM -Concentration of -the Insic benzogl -pero4da( is

ollows ~.y._a re untioh e-
Irt the radival groups in the polymoric pol.
d b

::
:cule and.an in -00 he s ences
in t ga eous phase Se4en refer
~
3
3 WSR and 4~
Usk (1942-195
). Tables; graph,*, illustrati6n.

PC m
'Cero If I u c 6)
e
--71' Metj
the Presence of be
au RtI W of Lab 020
ed atom
-- " ml
Ein,
:e C'I , -01 b, re3tM
this h,,i,4' j1hd; i~ I-T~ . ~kr_
fave(phC140) PCI edlizoij, , entnfph.
19"" labeled H n 3-415~
hi 9 Yield.
Polylerizat"Ort eh "I u.sed r - zCl which, u-1,
The sn,id mj)"atO.7-21 or
C, 1, 10 Concl? find at Zo'.'" Of phcll
in mot " -Ppti. f* I IM.
J.7.J labeled 13- vrt f rOM benz.n' b . and 140.
-
of th -0 'm 19-4M to )
6, d FI-111 13
d,,o,,' , r-137"., n to be pregent PC ~ to
P- With er propo,,,,n ., the r mot.
C()~- this p.pow., Y .... I'le
2E!L.SDlk
st coit, rkes With
G. N~. K.

I- . : . . .. . t* . , ..
. - ... 1 , . .

KOTON, M.N. (Leningrad)
Progress In the preparation of now polpers. Usp.khim.24 40-7:
901-930 '550 (MAL 9: 2)
polymerization)
(Polymers
and

.. I....I -Mmmm~~~

Rat.-

;Ph
of

I - , . I . - . . . . .- - . I - . . -

XOTON, M.M.; XISMVA, T.R.; RESSONOV, M.I.
Study of the radical polymerization of styrene by means of tracerse
Zhursfiz.khim.28 no-12t2l37-2141 D 155. (MLRA 8:5)
1. MmAemiya nauk SSSR. Inatitut v7sokomolekalyarnykh so7edineniy
Leningrad.
(Polymers and polymerization) (Styrene) (carbon-Isotopes)

IOTON, M.M., MARTYNOVA, V.F.
Reactions of symmetrical aromatic compounds of mercur7 vith
phenols. I2v.AN SSSR Otd.khim.nalak 86 rio.6:1063-1070 KT.155o
(ML-RA 9: 4)
l.Inatitut v7ookomelekul7arnykh soyedinaniy Akademii nauk
SSSR.
(Hercur7 organic compounds) (Phenols)

RUMAITIA/Physics of High - Molecular Substances D-9
Abs Jour : Referat Zhur - Fizika, No 5Y 1957Y 11539
Author : Koton, M.M.
Inst
Title Accomplishments in the Region of Production of New
Polymers.
Orig Pub An. Rom.-Sor. Ser. Chim., 1956, 10, No 3, 84-111
Abstract Translation from the journal Uspekhi khimii (see Referat
Zhur Fizika, 1956, 16533)-
Card 1/1

'.)I)z1, ~) -~I
t ~ -T "_ -r-I
DOKUINA, A.F.; KOTONO M.M.; MINETIVA, O.K.; PARIBOK, V.A.
Synthesis of chloro- and brome-substitutod methyletyrenas. Zhur.ob.
khim. 26 no.6:1651-1653 Je 156. (MIR& 11:1)
1.Leningradski7 politekhnicheakiy institut.
(Chemistry, Organic-Symthesis) (Sty-rene)

Kul-m, M 1`1 -
SUBJECT USSR / PHYSICS CARD 1 / 2 PA - 1273
AUTHOR KOTO"j
TITLE or, the Properties of Scintillating Plastics.
PERIODICAL burn. techn. fig, 26, faac. 8, 1741-1743 (1956)
Publ. 8 / 19 56 reviewed 9 / 1956
In literature the question concerning the influence exercised by the chemical
character of plastics used for the production of scintillation counters has
hardly been examined. Therefore, a number of polymers of different chemical
character was examined and the scintillating properties of the plastics obtained
were studied. It was shown that, on the occasion of the introduction of spe-
cially purified anthracenes into styrol and its derivates, into ether of
methacryl acid, into the derivates of naphtalene, etc., as well as on the
occasion of a following polymerization and in the presence of benzoil, plastics
of different scintillating activity which is closely connected with the
chemical structure of the initial product were obtained. The highest degree of
activity was found in the case of those plastic samples which were obtained
on the basis of pure polystyrol or with additions of naphtalene derivates.
This shows what an important part is played by the aromatic benzol rings to-
gether with the system of the hereto connected bonds in photoluminescence
processes. With an increase of the percentage of aromatic compounds scintil-
lation activity is increased.
Tests have shown that, for the production of scintillating plastics with

.. . - . .- . . . . .. .. - -.- - . I . . ..., - . . . L . I .
w - . . . %. - 1. . . - I . r - . . I

. .- - :s --
- .~ ll~ I -
7 - . -

Y, C, A ~ V11 I Vf%~ V-1.
1"'CrTC11", 1M. M. IDEK and MITI111 Yu. V.
It Tht-- Santhesis of Polymers .Ath Cycles In 'kho Chain,"
T1 T 11: : Gencral ZMecting of the Departurent. for Chcmdcal
Sciences of the ATI USSSR Held in May 30-31 and
june 2.3, 1957.
FFIRIODICALT: Izvestiya AN SSSR, Otdel, Khim. Nauk, 1957, lir 11,
pp. 1416-1419 (USSR)

I . , i ..- . , ") I
by 2apcr prescited
;,,)-,tiO;-. of
Lt:-, '~-Jae ~th Cw7ess on thc Clncmistr,~-- and Flnyoics of Ilir-*;-, Fiy7,ers, 2C Jar-2 -!,'C!b
57,
D--~
~ 1 395

KOTON, M. M., Institute of Mocromoleculor Compounds, AS UOSR, Leningrad
"On the Polymerization of Vinyl Derivatives in the Aromatic and
Heterocyclic Scrics," a paper submitted at the International Symposium
on 1.1,acroLrolecular Cliemistry, 9L-15 Sep 1957, Prague.
1/1' - M, 1,2?, 0
f I
,I UTHOP~':): Adrova U
o -o Pano-,r, Yu.:-..
TITT.-
U- ',tic
-Scintillitors for lccorJin- of
Lo-
-ctive. Emissions (Lj-L.L--,tiVr,)7e
U --U -L1-rz-'Usi,XM~W -,!3 4U- a o s y
'U' -47
A 3 -3 TPL 1-1'2 VLi-r-: .)U"
bccn
It ha - '7
s cOn 50,01 n- chat the
i 0 1-10 "-ii 11 ~: -?la: ;tic Sci, !-
CL OjYS'-.jrrcnC arc
ci 0 C. 0 11
.3n-:
I
2~L -t,DrT),jcj-jyl + 11 'j.
2.
1 - 2'~
-U~I-f-,hcnji + 0.0,) 0.05'' ~3124) Zl-
U
-k-Oc bra phonyllbutadione.
tO2.Alonyl + C1.02) -b0 4- 2-(5----i,c-jyj-
o-7:azo1yj)-bonzcnc.
j-
L U
rd 1/2 0 c i,,aj jUc O-L of Plos"ic sc-'ntillator, ba d
. U -L u

KOTOII~', M.".
AMOVA, N.A.; KOTON, M.M.; FLORINSKIT, F.S.
Preparation of 2. 5-dipheny-loxazole and study of Its scintillation
efficiency in plastics. Irv.AN SSSR-Otd.khim.nauk no-3:385-386 Mr
'57. (MLRA 10:5)
LInstitut, vysokomolokulyarnvkh soyedineni3r Akademii nauk SSSR.
(Oxazole) (Plastic materials) (Scintillation counters)

KOTON. M.M. (Leningrad)
~: ~., I
Organic unsaturated compounds with elements and the polymers of
these compounds. Usp,khtm. 26 no.10:1125-1140 0 '57. (MIRA 10:10)
(Unsaturated compounds) (Poly-mars)

-AUTHORS: Koton, M. M.; Sokolova, T. A.; and Chetyrkina, G. M. 476
TITLE: Synthesis of N-Substituted Methacrylamides. Part 1. Carboxy-
and Carbalkoxy-plenylmethacrylamides (Sintez N-zameshchennykh
metakrilamidov. I. Karboksi- i karbalkoksifenilmetakrilamidy)
PERIODICAL: Zhurnal Obshchey Khimii, 1957, Vol. 27, No. 1, pp. 185-189
(U.S.S.R.)
ABSTRACT: Carboxy- and carbalkoxyphenylmethacrylamides are polymerizable
monomers. In order to synthesize substituted amides of methacrYlic
acid, the authors began with their acid chlorides and following
in the Patai (2) steps utilized equimolecular mounts of acid
chloride and aromatic amine. It was discovered that the reaction
in this case does not reach the end because a part of the amine
is consumed for salt formation togetYer with the hydrogen chloride
forming during the reaction. For this reason the authors choose
the Bryant, Mitchel (5) method (used in the derivation of p-
bromphenylmethacrylamide) which consists in the reaction of moles
of amine per 1 mole methacrylic acid chloride. The basic amines
for carboxyphenylmethacrylamides were obtained by esterification
of o-, m- and p-aminobenzoic acids by heating the latter with
Card 1/2 methyl, ethyl, or butyl alcohol saturated with -dry hydrogen chloride.
476
Synthesis of N-Substituted Methacrylamides
The basic aminobenzoic acids and their esters have low basicity
and their salts are therefore easily hydrolizable.
The obtained N-substituted methacrylamides were analyzed for their
carbon, hydrogen and nitrogen contents by unploying the micro-
combustion method. The analysis results and the properties of the
obtained amides are described in the table; the melting points are
corrected in every instance.
One table. There are 10 references, of which 2 are Slavic.
41
ASSOCIATION: Academy of Sciences USSR, Institute of High Molecular Compounds
(Institut Vysokomolekulyarnykh Soyedineniy Akademii Nauk SSSR)
PRESENTED BY:
SUBMITTM: February 17, 1956
AVAILABLE:
Card 2/2

-io
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ZAMA10v, N.P.; KOTON, K.R.
Synthesis and polymerization of mathoxy-substituted (in the ring)
styrenes. Part 2: Synthesis and pq~ymerizatibn of dimethoxyetyrenes.
Zbur, ob, khive 27 no,,6:2142-2145 Ag t-57. (MLEA 10t9)
1. Instit-at vysokomlekmlvarnykh soyedineniy Akademii na-ak SSSR.
(reratrole) (Styrene)

KOTON. K-K-; SOKOWYA, ?.A..- SAVI7SKATA,, X.N,; KISKMA, .T.j(.
.
3: N-alkylacryl-
Synthesis of N-substituted mathacrylamides. Fhrt
and N-alkylmethaerylamides. Zhur. ob. khim. 27 no.8:2239-2243 Ag
157, (HIBA 10:9)
1. Institut vysokomolokulyarnykh soyedineniy Akademli nauk 333a.
(Mathacrylamide)

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721 2LE: ThC SyntIlLO-4i c4' 2-Vir._-l,, iJ.14.ic

PLHIODICAL:
1 1 2 7 2 7
Zhurnal Obslicl..u" KIii-iii,

AD-'TRAC2: Al thou -h 2-V4 wllpyri klinc ii ~:nowi, fov !t lor.
tiufactor'7 uynthc3i~'; per-li t tc 13 Lo
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2-vinylpuinolina ij _~."-o for h)r, L -u it
w".0 0..'1~ v,~ry rcccritl'. VIL:t -t !~".Od i'o!'. t"~ oL' th-1:3 Com-
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cati.,co an insufficient p1tritir of ~1. )no:iars, of a
_h de roe of purity %;Qrc ncceqJ_-:-y lloi: t:w cf the
jolymeiization procco.,: oZ 1,1~1 iii o line , so
thnt appro2riate clian--eo in Vi,_ of t1io of the Se

cu.,,:ounds had to be -.i,,d( O'int: .-Io 9".", t'1: Ii~ed from
L
Oe- -picoline c:nd froll C:Ilinal-
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Cie j L; o 2-Vin* -1;,l ridine 'm6 of 2-1fj r, -L-juinoli nc
'al i,lprwf~;d tL-t1jcjd fov Vli,. L:~inC;cji, of '2-,rir.,, 'L:, r,-" iru :!n t; -')-vin.,,l-
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1. 2-Vinylpyridine-Synthesis 2. 2-Vinylquinoline-Synthesis
C--Lrd 12/2

)KO-70
AUTHOR KOTON M 9 SURNINAO.K.
TT,TLE ion of 2-vWipyridine
(Polimerizatalya 2-vinilpiridina 1
ARIODICAL Doklady Akademii Nauk SSSRO1957tvol
Received 7/1957
20-5-33/67
And 2-virylquinoline.
2 -vinilkhinolina -Russian)
113,Nr 5 pp io65-1o65(U.S.S.R.)
Reviewed 8/1957
ABSTRACT In spite of the fact that in the course of recent years vinyl
derivatives have been widely in use, their polyomerization and
co-polymerization has been but little investigated. Both substan-
ces have a very similar structure, but the second was very little
used, probably because the polymerization and the polymer proper-
ties were not sufficiently well known. The study of the polymeri-
zation of vinyl derivatives of pyridine is theoretically interest-
ing because it makes it possible to estimate the influence exer-
cised by the heteroatom in the rings of the vinylpolymers upon
their behavior in the polymerization and co-polymerization pro-
ceases. It was possible to study also the influence exercised by
the molecular complication of the heterocyclical monomer upon the-
se processes by introducing a second benzol ring. Por this purpo-'
se the authors synthetized the monomers of 2-vinylpiridine and 2-
vinylquinoline by the interaction of picoline with quinaldine with
paraform, which was followed by the dehydration ofthe obtaind car-
binoles. The physical properties of the monomers are shown by tab-
le 1. In order to study the polarizability of both substances the
Card 1/2 kinetics of this process was investigated in the block by the di-

,/V-0
20-2-21160
AUTHORS,- Adrova, N. A. `--Koton, 11. 11. , Panov, Yu. If. , Florinskiyt
F. S.
TITLE: The Scintillation Activity of Carbocyclic and Heterocyclic
Compounds as Related to Their Chemical Structure (0 svyazi
mezhdu khimicheskim stroyeniyem karbo- i geterotsiklicheskikh
soyedineniy i ikh stsintillyatsionnoy aktivnostlyu)
PERIODICALt Doklady Akademii Nauk SSSR, 1957, Vol- 114, Nr 2, PP-311-313
(USSR)
ABSTRAM The paper under review investigates the relationship between
the chemical structure of the carbocyclic and heterocyclic
compounds and their scintillating activity.
In addition to the known inorganic 'phosphors', also the
organic tphosphors' are at present being widely used as
crystalline, liquid, or synthetic scintillators. Among the
organic compounds, fluorescence will be found in the majority
of the aromatic hydrocarbons and also in a considerable
number of heterocyclic compounds, the molecules of which
Card 1/4 contain ring-shaped structures and conjugated double bonds.
20-2-21160
The Scintillation Activity of Carbocyclic and Heterocyclic Compounds as Re-
lated to Their Chemical Structure
An investigation of the relationship between their structure
and their scintillating activity can be of help in the
construction of scintillators with highest luminescent pro-
perties. The authors of the paper under review conducted the
investigation of the above-mentioned activity of the substi-
tuted anthracenesp polyphenyls, aryl derivatives of the dienes
and of a sequence (60) of heterocyclic compounds by intro-
ducing them into the polystyrol plastic. They were introduced
into styrol monomer in quantities corresponding to their
highest effectiN;eness. In presence of 0,2 % benzoyl peroxide
and under gradually increasing temperature (80 to 120 degrees
centigrade) they were polymerized until transparent cylindri-
cal hard blocks were obtained. These blocks were exam-Lned
with reapect to their scintillating effectiveness by means
of a device that permitted to establish the relative ampli-
tude value by the output of the photoelectronic multiplier.
The results obtained suggest a dependence between the chemical
structure of the blocks and their scintillating effectivaness.
It may be concluded from Chart Nr 1, contained in the paper
under review, that the 1,4-di-(2-(5-phenyloxazolyl)-benzene,
Card 2/4 the quaterphenyl and the 9,10-diphonylanthracene, i.e. hydro-

20-2-21160
The Scintillation Activity of CarbocYclic and Heterocyclic Compounds as Re-
lated to Their Chemical Structure
of cycles is increased to 4, the activity rises from 9 % to
31 %. If substituents are introduced into the benzene ring,
then both the chemical nature and also the isomerism affect
the scintillating activityl this was observed by the authors
of the paper under review in 9-substituted anthracene. Here
this activity also increases at the transition from the methyl
radical to the butyl radical. The paper under review gives
diagrams of the chemical structure for all comrounds mention-
ed. There are 4 references, 2 of which .--
ASSOCIATION: Institut for High lifolecular Compoundo, AS USSR
(Insitut vysokomolekulyarnykh soyedineniy Akademii nauk SSSR)
PRESENTED! December 12, 1956, by A. N. Terenin, Academician
SUBMITTEDi November 0, 1956
AVAILABLE: Library of Congress
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(Instituluu of ~~acru:rolecullar Ccmpoun-ds, Acad. jri. 1036R, LeninGrad.)
"Poly-erization of Arcmatic and llet-~,~cycllc' Vinyl comi-31-uldj"?
paDcr sij'o:njtt----d at, Sojia,l HigIl pol',- ' u
mers, Intl.
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AUTHOR: Koton, M.M., Professor 26-58-7-2/48
TITLE: Polymers (Polimery)
PERIODICAL: Priroda, 1958, Nr 7, pp 7-15 (USSR)
ABSTRACT: The polymers bring into close contact the two leading scien-
ces of our time - chemistry and Dhysics. They aro also
closely linked with practice and production. In addition,
they open innumerable ways to new materials with unusual
properties and, by use of new methods, changes in the already
known polymers. In May 1958, the Plenum of the Soviet CP's
Central Committee pointed out the importance of research
and progress in the field of polymers. The industry re-
quires cheap materials with a high chemical resistance at
temperatures of 300 to r.OOoC. If in polyethylene all hydrogen
atoms are replaced by fluorine, the polymer becomes soft
only at temperatures over 300OC- Ion exchanger resins,-are,
being more widely U3ed, especially in the field of -a ti*io'!
ties. In the laboratory of Profpssors A.A. Vanshtept
A.A. Vasillyev and N.N. Kuznetso*~~-_pf the Ivtitute of High-
Molecular Compounds of the AS USSR, synthesized special ion
exchanger resins, based on the theory of chromatography and
Card 1/5 ion exchange worked out by Professor S.Ye.Bresler and G.V.

Polymers
26-58-7-2/48
Sameonov, the first extremely pure antibiotics, ouch as
streptomycin, albomycin, biomycin, terramycin and others
were first obtained. This opened the road to the production
of new antibiotics and other complicated drugs. Polymer
substances cLa also be used to replace blood conserves. In
the Leningradskiy institut polimerizatsionnykh plastmass
(The Leningrad Institute of Polymerized Plastics), a "block"-
copolymer resistant to impact was devised which -gill be
mass-produced in the Leningradskiy Okhtinskiy khimkombinat
(Leningrad Okhta Chemical Combine). In the Moskovskiy fizi-
ko-khimicheskiy institut imeni L.Ya- Karpova (Moscow Physi-
co-Chemical Institute imeni L.Ya- Karpov), under the direc-
tion of Academician S.S. Medvedev . investigations have been
carried out using model systems with marked atoms for an
improved study of the ramifications of polymer chains and
the mechanism of polymerization reactions. The theory of
the process of the so-called reactions of the polyconden-
sations is being worked out in the Institut elementoorgani-
cheskikh soyedineniy AN SSR (Institute of Elemento-Organic
Compounds of the AS USSR) in the laboratory of Correspondent-
Member V.V. Korshak. He also worked out a polycondensation
Card 2/5 material called polyethylene terephthalate that is obtained

Polymers
26-58-7-2/48
from glycol and terephthalic acid called "lavsan", which is
a base for strong fibers and mechanically resistant trans-
parent material that can be exposed to all kinds of twisting.
In the same institute, new synthetic fibers called "enant",
"pelargon" and "undekan" were devised by Academician A.N.
Neameyanov and the Correappnding Member R.Kh. Freydlina.
Products from these fibers exceed the quality of kapron and
are more economical to produce. Polycondensation products
of phenols and derivatives of carbonic acids, the so-called
"polycarbonates", have a great future. Resins of this type
are - under the name of I'leksan" - suitable for varnishes,
films and fibers, known by their extraordinary resistance
to high temperatures, ultraviolet radiation, and the effects
of boiling water, acids and salts. In the last 10 to 15
years, increasing attention was devoted to polymers where
the main chain of the macromolecule does not consist of
carbon atoms but of alternating silicon and oxygen atoms.
In naturelsuch substances, e.g. quartz and rock crystal,
are known by their solidity and resistance to high tempe-
ratures. They are also brittle. 'Corresponding Member K.k.
Andrianov has worked out such polymeric substances, removing
Card 3/5 the brittleness by the addition of supplementary carbon-

Polymers 26-58-7-2/48
containing groups to the remaining free valences of the
silicon. This method permits the production of a vast array
of caoutchoucs, oils and hard covers suitable for tempera-
tures ranging from -550 and less to +3000C. This will be
important in the electrical and radiotechnical fields. The
same compounds have been used in the Inatitut khimii sili-
katov AN SSSR (Institute of the Chemistry of Silicates of
AS USSR) by Professor B.N. Dolgov and senior scientific As-
sistant M.G. Voronkov to make paper, material, various di-
electrics and entire buildings impervious to water. The In-
stitute of High-M61ecular Compounds has also obtained new
highly heat-resistant materials from polymers containing
various metals in the polymeric chain. In addition to
common links, coordinated links were also obtained that ex-
panded the possibilities of a synthesis of new DOlymers with
special properties. Low-temperature (_800C) poiymerization
in the presence of a little-studied catalyzer, gasous tri-
fluoric boron, yielded an isoprene which did not have common
rubber qualities but became a hard transparent polymer with
Card 4/5 a softening temperature of over 300"C.