SCIENTIFIC ABSTRACT KORSH, V.B. - KORSHAK, V.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000824920019-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 14, 2000
• Sequence Number: 19
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

UR/00IS/64 VOIC_ 261-C;29
T.- -c; ic, P. v., navaonvAas, o.lv., reclarova. T. N.
orsh
a ~-n-ir in gtiakrato in
-,f* t,.ilareml a A
mikrn-Ir.~c)-oFil, eT oizt no, 12. 1964, 26-2~
pidcmio.oxii i immunobioll.
ncterial disease, viruzi di;ease, disease incidenco
epiwotic of tulai-emii and Omsk hemorrlhaglt.~ fe-Rr broke out
~a.,'- and of
4-13lrl::51KLy, and Ghaww3xiy kayoi5), and Kurg-&u '~ayoa,
among nuakrntfi MR7 '.trow"'~r. not
I v InBtitut Drorodnoo.-hagcv-ykh infaktaly Mln-Iateratva
n fix :aa 'A t- 1 t e N a -a i a t. Z-y
S-,jBt,'.rr.ML' O3JUn63
tr- R~ SO V' 005
ENIOIL: 00 S" ODDS, is
OTMRi 000

KORM z a Ofiambe
I dft~__
Determining oper~itionsl engineering indicies for antomatia
control in classification bum yards* Vest* TSKII HM 17
no.6:9-14 S 158o (MIRA 11:11)
control)
(Imilroads--Automatic train
(Railroads--Hum yards)

XORSH. V.B., inzh.
Basic operational and technical requirements for small...
car retarders. T6StTSNII JWS 19 n0-5-12-17 160. -
iMM 13:8)
(Rallroads-UM yards)

SADIKOV, F.P.; LROCIEVA, T.F.; KOH ENLENOVp V.K.; PETRUNENKOV, Aja.;
SH-JL.A.&
TIMIKOV, L.B.; ASHI retsensent; REIM, V.Yu.,,
=.nzh
jiph., red.; VORMNIKOVA, Lo lZrad,
F tekba
(Technological eq1tipment of railroad sta~ionsl Tekhnicheakoe
canashchinie stantail. Moskva, Tranesholdorisdat,, 1963,
153 P. (XW 16:6)
(Railroad"tations)
(Railroab-4quipment and supplies)
L e

USSR/ji 0 C PlMLGJC~
nts
"Chemical Weeding of Grain Crops, Ya. Korsh
"Nauka, i Zhiznl"L Vol XVIII, No 9) PP 33)34
Large-scale expa on the agricultural application
t
of 2,4-dichlorophenoxyacetie acid and-2-methyl-4-
chlorophetioxyacetic acid-ve-re conducted in many
parts
Spraying of
of the.UBSRIn.the sumer.of,1950.
fields for ti4 - Ii se of weeding was carried-out
purpO
from plimes. ~Docent I.I.,Gunar and M-Ya. Berez6vskU
:,S~;4 scientists from the Moscow Agr A
Cand Aa
imeni K.A Timi azev who were in charge of this V
ork,
received a Stalln'Priie in 1951 for this work
21M

PUTYATIN. M.D., kandidat tokbalchookikh nauk; WISH, YA.M.. rodaktor;
'ISLMiT$YZVA, P.G.. tokhnichoskly r~dmktdT.`*---4--
[Bzporlonce Is the operation of W-54 diesel tractors] Opyt sksplux-
tatsti disolInykh traktorov VI-54. Kooky&, Ixd-vo *Znanle,* 1953.
.31 P. (NLU 6:12!
(Tractors) (Diesel engines)

xcm 9 Ta., . . - - -
mmew,
A slAh SOWS. 1 4:32-33 A 156. (xw 9--q)
luu,mt, too
I .
e
I
I

,~Jw k
KORM, Ta.
";7,
Streawregulating system. Banks i zbisn' 23 no.6:36 Ja '56.
(WAA 9j9)
(Amm Darya Valley--Irrigation)

loom Y&.m
ftsol produced frm was. I&Wm I xhisal 23 no.11:30 N 156.
- (an 9:n)
(Steel-metialurgy)

KORSH, Ts.
Procious gratno. Zama. oil& 31 w.8:26-29 Ac 156. (NLRA 9: 10)
(Ore drossing)

KORSH, Ya. .
-- Tluurbo 1- 0:9)
~bo 11s. Wn. takh. 2 no,96,46-W S 157. (MM I
(Tubodrille)

AUTHOR: Korsh, Ya. 4-58-4-10/19
TITLE: Oil From Sand (Neft' iz Veska)
P IikI-ODICAL: Znaniye - Silap 1958, Nr 4, pp 26-27 (USSR)
ABSTRACTj The article describes the sandy hill of Kirmak near Baku which
has proved to be so impregnated with raw petroleum that it
can be "cracked" and refined at low cost. There are many more
huch hills in the neighbourhood, and around Sochi, there are
thought to be many others. About 92% of the oil is extracted.
The balance remains in a cokep which burns hotly and leaves a
residue useful for building purposes. Inflammable gas is
produced as a by-product. The article finally estimates that
there are millions of tons of this black gold. There are
2 sketches.
AVAILABLEs Library of Congress
Card 1/1

-~ I'll, -.N ftA I
KORSH, Ta.m.
Wm~~e =jgeTs'iikworta, Hauka I shi7n' 25 no. 6t61-64 Je 158.
(mnu 11:8)
(Sericulture)

..7i iTL
IORSHV Ta
Blast fW.Vjos. ]M%.o tokh. -3 siool:.10-32 is $39. (mm 12:10
(Blast furnaces)

36) SOV/25-59-6-45/49
AUTHOR: Xorshq Ya.,
TITLE: A Migrating Lake
PERIODISAL; Nauka i zhizn', 1959, Nr 6, pp 78-79 (USSR)
ABSTRACT: The Lobnor Lake situated in the Takla-Makan desert (West China),
changed both its geographic position and its chemical compo-
sition. Its water has been found to be sometimes saltyq some-
times potable. Professor E.M. Murzayev, Doctor of Geographic
Sciences, gives the following explanation of the strange fa cts:
The Tarim and Konche-Darya Rivers, feeding the lake, sometimes
change theirdirections and fill other depressions having
other geological contents. In 1930, the lake was 100.1an long,
50 km wide and not more than 5 m deep. New irrigation net-
works will probably dry up the entire lake.
Card 1/1

KORSHAK, F. A. v
Geodesy, Geodeziya, Dorizdat, 1949.
TABCOW, W-13807, 22 SeP 50

FEDOFC-V, N. V.; F. A. KORSHAK.
Geodeziya. (Geodesy) 3- lzd Perer. I Dopol. '4oskva) Dorizdatj 1952.
381 p. Tables,,Diagrs,
"Spisok Literatury"t P. 377ip-(378)
Sot N15
623-1
.F2
1952

STIRPANOV, Nikolay MikoLwavich. professor: K edaktor.
02" r 9
SOIOVNTC16X, A.A., takhmicheskly re. or aolw-A
[Geode I Geodestia. Leningrad, Gidromateorologichaskoe izd-vo, 1954.
341 p1mlicroftla] (MM 813)
(Geodesy)

MOROV, Rikolay Tamillyevich-, XmS2&.!6dor Afannelvevich; CHYABOT, Y.G.,
reclaktor; XOGANO F.L., temic
(Geodesy] GeodestiAi. Isd. 4-oe. perer. Moskva, Nauchno-takha. Lzd-vo
avtotrBnop. lit.-ry. 1956. 403 po (NLU 10:1).
(Geodesy)

KORSHAK Fe-dor Afanu 'yevich; SERZFIANOV, A.Ye., red.
(Ceneral projection with a moving pencil of rays in photo-
grammetry) TSentrallnoe proaktirovanie dvizhushchimsia
puchkom luchei v fotogrammetrii. Makhachkala,, Dagestanskiy
goo* univ., ime VaI,Lenina, 1962. 233 p. (MIRA 18t4)

KOVAL I N.M., nauchnyy sotr., kand. sellkhoz. nauk; GEPIWI, Ya.B.,,
starshiy nauchnyy sotr,; BMUKOV, Yu.Y., starshiy nauchn7y
aotr.; MARTIYANOVA, O.A., starohiy nauchrqy sotr.; SHASHKOV.,
I.G,,, nauchvjy rabotniki KORSHAK, I.T.; BROZHEYT, M.P.;
G.N. - YEFREPI0V-;-N-.1r:-,-re-d*-j' ICIMWATSKIY, S.A.
KUKMCHUK 6 '
tekbn. red.
(Technological cheats for grape cultivation] Tekhnologicheskie
karty po vozdelyvaniiu vinograda. Kiev, Gos.izd-vo sellkhoz.
lit-ry USSR, 1961. 141 P. (MIRA 15:3)
1, Ukrainskiy nauchno-isoledovatel skiy institut vinogradar-
stva, i vinodeliya im. Tairoya (for'Kovall, Germanp Biryukov,
Martlyanova). 2. Zakarpatakaya opytnaya. stantsiya (for
Shashkov). 3. Ministerstvo sellskogo khozyaystva, USSR (for
Korshak, Brozheyt, Kucbarchuk).
(Ukraine--Viticulture)

'-ACC NR:
AUTHOR:
Ano06211 SOURCE CODE: UR/0363/67/003/001/0180/0181
Goryunova, N. A.; Borshchavokiy, A. S.; Venkrbotat YA, Ia.,, Korchak.-VA M.
ORGi Physicotechnical Institute im. A. F. Ioffes, Academy of Sciences, SSSR (Fiziko-
tokhnichoskiy institut Akademii nauk SSSR); Department of Solid State Phy3ica,
Prague Polytechnic Institute (Kafedra fiziki tverdogo telap Prazhakiy politekhni-
cheskiy institut)
TITLE: Growing of CdSnAs2 single crystals
SOURCE: AN SSSR. Izvestiya. Noorganicheskiye materialy, v. 3, no. 1, 196?, 180-181
TO?1C TAGS: cadmium compound, tin compound, arsenide, single crystal growing, zone
melting
ABSTRACTI A single-crystal ingot of the semiconducting compound CdSnAS2 was prep-irodl
by zone melting. The zone temperature was 600OCt and the gradient at the cryst~lli-
Zation fronts 20 deg/cm. After one pass of the zone at a rate of 8 mm/hr, an ingot
was obtained whose first half was a single crystals whose middle portion contained
twins$ and whose and was macrocrysta.11ine and contained cracks. The mechanism of
formation of cracks is explained. The ingot had an n-type conductivity. The elec-
trica.11 conductivity Q* , carrier concentration n = I/eR and Hall-mobility U = Ri j,
--ehere R is the Hall coefficients were measured at 100 and 30010K. It is shown that F
I x 1018 cm7,3 t
the chief imechanism of electron scattering in r~-CdSnA32 with n > a
Card 1/2 UDCt 546.3-i9-48-811-19+,148.55 .0

iiatures is scattering on impurity ions. During zone recrystallization, th
--4:Ues
indicated by the measured mobilities of the charge
separatedp
as
are
The zone malting method is thought to be effective for growing pure COULIZ
single crystals with high electron mobilities. By carrying out the zone molting
repeatedly and using a single crystal seedv the authors obtained CdSnAs2 ingots in
'which individual single crystal grains were UP to 50 = in s ze. The Cd5nA32 single
crystals obtained had an electron concentration from 7 x 1019 to 5 x 1018 cm~3 at,
3001K. Orig. art.*hast I figure and I table.
SUB CODES 20/ SUBM DATEt 2ODac65/ ORIG REFS 004/ OTH REFS 005

KORSHAK, V. V.
Condensation.of methylene chloride with phenols. P. P. Shorygin,, I. P. Losev
and V. V. Korshak. J. Applied Chem. I(U.S.S.R.) 91 1432-6 ( in French 1436)
(1936).- CH2Cl2 was condensed with PhOH in the presence of 2-10 cc, of 25~ VH3
aq. (Catalyst) in a sealed glass tube at 1800 for 1 hr., yielding 3.3 g. of
tar per 4.2 g. of CH2C12 of the compn. C 74.27) H 7.43, and Cl 0%, AcO no.
259, mol. wt. 192.7 Br no. 203, d. 1. 159, initial m. p. 680, relative
viscosity of the 3% a1c. soln. 1-137. NaOH, HCl and the "Kontakt Petrov"
(petroleum sulfonic acids) were also tested as catalysts with neg. results.
The condensation of 71 9. of Ph OH and 42 g. Of CH2Cl2 in a rotatory steel
autoclave at 1800 under pressure up to 45 atm. for 1 hr. in the presence of
80 ce. of 25% NM~011 yielded 50 9- of a dark brown tar (contg. no Cl) of
"bakelite" type, m. 108-200. The tax was polymerized at 1600 in the presence
of 10% of urotropine in 5 min. and in 3 min. with 20% of the latter, and the
product of the polymerization was used in the prepn. of a plastic mass. The-
plastic mass, contg. polymerized tax 50 and wood dust 50%, was pressed at
150-600 at 300 atm. to a board, which had good mech. properties and was
not much affected by acid and water. Condensation Of CH2Cl2 with a technical
cresol under the same condition yielded a light brown tar m. 500. Condensation
of CH2CI2with ures, yielded a light brownish product consisting mainly of
biuret, and in the absence of NH3 a white solid substance consisting of biuret
and cyanuric acid. One literature and 5 patent references. A. A. Podgorny

KORSHAK) V. V.
"Condensation of Mlethyl6ne Chloride vith Phenols, JJ.11 by P. P. ShoMin, I. P.
Losev and V V. Korshak. ~. Applied Chem. (USSR 10, 138-40 (in French 140)
(19371; cf.-C.A. 31, 2181'. - C11 01 condenses with PhOH In the presence of aq.
J~ 2 mol. ratio of PhOli to CH 012 of 1.25. Ini
IM at 1300 on 5 hrs., heating wi a 2
Q be replaced vik by MeMl , Me 11H or Ile N; hence (CI12)6114 is not an inter,,neaate
reaction product of the conaensaiion. P~81H (7-1 g.) heated for 1 hr. at 180P w:O;h
4.2 g. CH C1 rave in t1io presence of M13-- 1102ni aw YIGY"" resp., 5,83, 8a,36$
5.32 and E19 g. of resin.
A. A. Podgorny

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14011101-fatiOSA and l,'I,rcsp. The results were in Wh
CBS" the sattic. the rtmiction products being Cliff. C.11,.
Cliff. CA1, Ph,,
.Y-bitolyl, a,a'-binaphthyl, CCl..
e.
WIX1. and C.11C . The reactim mechanimit is -li-
citoed. Gvrtrude Iterend

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Lab., Organic CheMistrY) 1**adeleylev Thst-
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-00
d to stand at room temp. for
ing. sayt a mist, of 1. PhCH- so*
d diphenyhrialeanitriler (IV).
I the time of reaction to 3
of log.1, log. M&nd Igg. no*
in. complete conversion to IV
Fills &k, KOH rvr dipbenyl-
w. In. 153*. (M c.) witb 2*0
er bath (or 40 hn. gave 30 g. 011111
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kve v woo
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Tn
~ provetl unsaccesdul
.
John Livsk
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CICHICH.OAc -t5 th a And AICI.. the W-111vil .00,
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tram the acid through the diamilde. Adipk acid (140 g.) bo d hen the fto"Wn
d I be d ide as a vv an or
Is heated to IM-200" and tmated with a strwo of Nits- =,.' bid. he Nits
n=. "am -nntam teas stopped and 3011 C.
Still HtO is onadertsed and its amt. is measured; at the tied a AcwO ed with 1.5 it. NH. molybdalt or A)^. Then
the fewtkmj 50-2 cc. 11,0 said. with NM Is obtained. AcO nd ex" AcO "m d6td. and the nitrik distil.
The duration of reaction is 3-4 hrs.; Melorthetodtfoe
becoules Viwoos and the temp. Is raised to 210-2( until decompn. became not kT&ble to the rrlddolt.
d
fl i k-h was then m-amidated and retreated with AcVO as
Nil. is stopped When Olt contents become neall d a
bove. A total of 93s. -Mde Diffile VMS obtained, which
The product is powdered while but, and recryal
1.
t 11,0 -sok, (.1-rol drops of concd. N11401 l we added I an washing with aid. NOIC(h wa,t redif-ld. in ntrus;
d (CIIJACN)t. th 168-9% was obtained in 70, (1
'3 V',thCHO). Yk4d9Oa.(d2%).m.22D-4)A*. Theaw
;it her a.). Some AcNHt was obtainetf from low" (fact Idtir-
liquor Ykkls Almost all tbc unreacted acid. A Series of
j distil. of ti~,e product, it is appamot formed through
TIPts. confirmed that flit above imp. gim The b4best, "iff-141-Ir eschange btilvven ArOll anti CHOACONIfils.
Ykid of the, (ClIrMCON110t. The dieralde (144 g.) and G. hl. go.,olarA
357 9. AcrO (b. 138409) wM treated With 1.6 g. Nifi
It"Ifildfilte It" the mist. hCated to 210'. Spay to 221-
30% for a total of 24-3 hrs., with distio. of ilse MOM and
of I AcO, whkh we collwed &W **bed. Willett the
d6tftte is 370-80 cc., sactioto is opWW sod the rniidual
AcO is disid. at W-W aam. The P-odect Is tlow distd.
lim rww, Its 12D-2201, washed wftb amid. NaUC06 solo.
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0
- 0
N sologi wit Cot cat .111
T 1A no u
1 110
~1. '
0-0 1
AT 00 is It No a 1 1111
o
0 0 0 0
0
0
0 0 0 0
. 0
11041114111
0. : : : : 0 0 a 0 0 0 0 o
*00
1200
Go*
do*
see
woo
woo
see
Woo

--------- ---
is, ; 4
00 0*000000 0*'
o
t
ad ad a 0 0
s
l

A 44 4tA 90111
00 A ;11 -impeoplatli W"A
04fts
0 St 92~~k and YN. A.
frkbft - C4hW&M"-R'.) 14.-312-18
;~"J, Gr*
(11 4)(ffn
sumTV).-AnI111"t (50 WW 98 CC.
g-V
4" fi
I -gaw the .0
throtelical wt. pin was reached; I on dWa. tbeft Wait ob.
0
i
d W
r&
"e
ba 2304
m. M4* R. 11110H) (#icram, ta. I l9-3D* BtOH)):
4
e
The ebm (50 g.) Tru trutisil v*b 1
c
,
CJICIh bested an a swam buts mill MCfewWatim reawd. "Oo
00.4 the solvent was #moved aad ibe mmlihla hic., d. from
WON to ykid Out m.
00 .16 W. Tkh 110 k.) &) cc. Kt0H and 2 if. N&A were see
so' reduXed for 2 Mi. to YWM an alusnat
0,
4
4-m
0
1
iz see
4
00 1 fte-1,44donew, bw 1110-2
, w. 32-3
6
it 0
11
l
):
*
140
b
UP
b

,* so 190% b. 184
is
%
. bw
n
.
,
41-2*; ZaC4 sall
w. 11451 (frons RtOH): Act "jar" t1
1 41110,

so ,
.
x
Moscow Order lAnin
1
62'. The thillaw (111.) in 8 ce. 6 N MCI was (mated
1; 0
004 with 2.6 a. Wax to 10 cc. 11.0 to yield a cryst. 4-p- Chemico-tectinologi- I'L, re &

so,, firm Awe (by treatntent
(10'
cal lust
D
ith
im
IX
009
00 4 .
.
w
.
n
Wam 1160). PhNHCHsCHj0H
was treated Ah k4 In CMCl. to yield a dark o0 Wbirls Mendeleyev.
kil
d
l
d
i
eter
rap
ot e
an stand
y
ng; a freably prepd. sample
mduzed witit N%S in Rt0H also gav!e 4-pluenyl-1.4-thim.
xane
PhNHCH
CH
0H (80
100
) I
C
coo
.
n
o
cc.
o
a.
HC4 was 0
treated wills 30 g. PCI&. the main. W" Washed with water
~
see
andl
ktC% adn., dried and coned. to yield j,#4jp&gjw-
ipeeasiae
1&34* (I
m
K
0)
h
.
tum
to
: T
e am Is obtained
,
t

to 1400 a aUt..of 43.6 S. PhN(CHICHa),
y htfla
g
ties
min
e
and On the basis of the above the reported
prepa. of by Helfrich and ReW
A
C
14
C
2 I
U too
.
.
s arvacoux. 0.
. Kolokpoff
,
1-!-
- too
19. 1 L A ASTALLOWA LAT"TO"
We 0
110"
431111 0A *AT All

t 19illon, two a 0 V I i

A
u I V
"
it 0
a
a
L

0 0 0 0 0
0
T
I
-0 0 * 0 0 0 0 0
O
0 0
0 00 0
I

O i
0 * 0
'
asset
A
6 0 0 46000 600-4 0 0 WO0

so
o:
0
00
go
43
vo
It AT mA.
The
*
0
-00
10
g
a
70 :0
a"
'etics of cm ;;,-
dy Wd" 4s.1
VO
I10
------ c"Ovica"
04
slits" 4M4
1141d wit
cc VA
is ***,a 0
sees
0-10 0:0-A-4

0 40 o6of .0410,10,04 0 16 v U .0
004 0
with
066 #md. K011 and kmWisis dida. 2.0 44111110.
Pw dammen resedeas. 1. lit"Ods of 6664"m- fftl.s;*~'mav 60 0
00 A dm = dibuie AM *101 dian"". be abisioird by Astu. W the sq. w4n. WI I I catn.
:0 S. It. Raftow. A (kg. Ckw- (UAEVWYMMI~'~ with Htp; ilk-as derim., so. 1W 0.4", Adok " " I**
imumv).-Tba pW I of % excess birmamtkybardiamim in sq. X" ghv 84% .00
v 0. lw-l*;
obykmdkmlutl~ "U". Rod - livamit"
*do ww - 71W1
Wide S& I was WA as III* In-2.6 I 00misk, m
oo teadim at tbir latter with with adl* It. Raft"
1008 It was ah"m Ila --- anil V. V. Kaftbak. AW. 9040(Ka&k immimmy).-
witlk beill
teatar% ww the rapWity and Computfum 41 "W M.
b"Ubibm, Aw Om -00
09 1, The :35r,'ied I 111013"LI WWO 0010011 in MO txKk1ft9*tkjN a# 11
diartifetwithadipiewid. Itmaskowtithatitlawagkin goo
so Th. Cteland&V" WWW As WIDOW. 4. ad to hm the " for " hm. at 220-40' in an equal mt. 4d
(312 g. mml 973valm om heatedtare at -h-t Nyknol. cftmA. or pbow). The nor" " 1 -60
0043 Im.1u, umdet 101 Atflk.~ do mist.mo ted p9mtedS in water as well PA by ho"Ing ail tho ARK W*b" 4*0
volvirat, with the forrnml~** of hm-ma. products. 'Iwo
**a wkk wdtr AM the F4, -9" SCMAOWM ova TUI* a*G
00%0 #A&-if *tjW. W.L I z? - ""w). ~ C"1*40*4 1-mr- AM 1voiluds am (*P" of hatbur am too
(Sw Awly If. JINN dwAtkito In it m"Im fir in 11 14 "malk. "At
v lIf. 1.43? "4
.01 '231. deig, factuf IN the lannAtIon 4 ht#h-wA. wadvets 6 1%#
AA cSOIL. goo
wwd logo jotkVMmmvAQ.7j.,(WR dcarvii and complettem of wata 111ouval; the vat Wo (A
reve'sible &L temp. om 2w" with formatka of law-ima. goo
prodwo
In.= 4m. d&JU~01I Is poiind of this =da fmk td WtW hrdm1yv1& - M b9lofto
"IF an 46 1, No, at sweb a ride do NG MORIN comomem *a 60 Ask 91
"go; this teduwal bit 130 at. &Y meoll, ml dw 8 R ltafttw V. V. Kor*a and N. a".
corwom ion at tim, mactime. dw amakil x4e. Is mated vdtk M4711 w'N Aown that IV* p4mm Qf as ON
f 30 L #XA ~-didd. into dd. AICI U404 1 1. ooto# the comommult"an Invortaxt'd Gotbe
WLN&M
to is nhsalu"J: the %4w It its ittvimm, lit
d at W I on-
Hikkift of the palpsaw a (foe
momdI-- *kh me I* w . ,
I ad I
ILA 09TAUURGICAL LITINalml CLAIWKAIM 1610 ac COWAN kloe
with *rmW of low- Pmductit, I'd me ftmvmr!~.
Furtha
slow 111"614- 1 chimp do bimatinc. dbUmetban flow the Grivied 7 v**
It 163aso wit 04V O0 Is P001-mr. XONIAPA
8 At K) U
U
10 -
J." 049 0 0o 0 0 *10 0 *4 0 *vio 0 0 0 0 9 0 0A 0 0

KORSHAK I V. V.
"Studies of poly6ondeneation reactionso II. On the condenoation of hexamethylenediamine
with adipic acid." Rafikov, S. R. and Korshak, V. V. (P. 983)
SO: Jourmal of General Che4s#7 (Zhurnal Obshchei Khimli) 1944 '1 Volwas 24,, no. 9-10,
Lab. High Molecular Compounds Inst. organic Chemistry) AS S86R.

31
T
ML-

1

1
M ILK
I is is ka of
~Kn U it u iia V
a v
" p a a d 41 a 0
A
00 A _j hl; -:

WIT,
..........

00 A unbwjm ad The rw~4=ft
fastlem, U. V. V.
-
-
-
-
47
(Nmvw Chvm.
Te
chi
'
(44. C". (U.S.S.R.) 14, ILW-
5(1%14) SUMMMO: cf. C.A. JiO, 4W'.--lt was
l
in
h
M
t
s
own t
t,
c
i
tixts. Q( MH(i with cyvlolwxyt chlorkle,
The hakagrit bound with At, *4 delit. by hydo,106, coo.
f M
h
52% O
l 19
48
D
14
is %i
p
.
f ow
,
7p Q.
vins. tit JJCJ ajj4l
fill
t
h
ff
f 146

00 it t
e o
f
-swis
filin 11W traclimi of lptnavile hatoisr"
detiv
lit the
didl
f
t h
lid
f
t
h -00
s.
p;v~ocv o
erva
a
a
e o
s
mmi
A
Thuit. with Aillracatmiyst the

it " a ;
1
1 followise roniptis, jpvr The F04 coullin. I" liblell Mow:

1'
ll
414
4l"
Cl 31
441% 110 welb
i
0 0
.1 g
,
.3
.
litic PhCllCl 25.67
~
"
"
M
&
I
00 *
mid 74M%, cyckahexyl
wide
O
M awl TbAl see
xt'.. With AM. calisirst the following
"
111
'li'V
r

0 0 0 were found; flahr MMM 11C1 IVA3% 11111i
p
1
u;
1
1
i aft*

u d MMO- -
79.419
liW 00:74% Old W.W%; ftDr
W
0'
eq (111.67%
aW 33-33
'V.
Tlw rmllm amM the torutation
of min inteftordime complex of the type X(M.U. see
o. M. &;Omupa

1104

-I L A ~9TAkLMKAL L"INAT11*9 ttAlWPICAIM"
,so, sl;Wii 6 ~7:1
q*-J4-j .3'sol am a., its
441111W -it aiall

S AV 00 JS Th
-jr -ff-'T-T AN I t I ad 0 0 9 1 it g oals I% T-M,
U st a 't it 49 K a a 10
0 0 411-9 0
0 see

off"
60
00 T:
00
00
0
00
00
lot
000
1*0
1;:69
1. 4*0
goo
11109
Igoe
M-SLA
411
0 it Poo folio% IND91
I'mygow""Nommi romocuo", V. "Otfutiftation ot
do P I V. A. Zmny.-stimt 4it.1
V. - U.R.S.S.. chiste 1. i.
4#K".-t'Wymkfoaf. WnW. by beating
her (1) alul Juli* siviiii
N't 23(l-250*- Tht FWWt Is dkuWYW in m*A,
-.1 cd1mcd, amil dried, -g. par.
bY 111tj one
0 -L 0.01 N 11cl am a6O o.(J I 'v
NuOll kw 2 Jws. mW the escem orCearat 6 bACk-titr3ted.
Tbc tual. wt. is givest by M - 2W,(M/a + b. whime a an'l
b am the loop. titers in "a. S. of PrArAmide. M vaoir,&
"m -M to 20,0110 dtP"k rik.
%9f ON the Poepoptions d I iml
1,11miscil, temp., jind that of beating. Valtmut.1tubuinc.1
by wift'li'llf NCAPAvnmts 61v sWiLLr. Wicts LK - 1,
favoinal NHs gre" Predoommisate owing to derArboxyLit.
ej.C.A,40,4".
B. A.
INITALLMIC&L WINAT11111 CLAISOPKATION
forodso "it 4". off
' if F q- -Y I ; F Am A 1 9 ad D a 0 1 1 A 0 3 9 1
U IN At 10 111; Of to0 if of I ZIA
0 a 0 4 0 0 0 0 9 0 0 0 0 0 a 0 41 a 0 a I
In
Mal: 0060000000 ve 41
00 *000 goo 9 0 0 * 0 0
011111- ~F

L M_P_Q~_
of
09
00 A
te-Wilds Of P1011111111116ft-
7- (Insc. Orig. c1
ar& Sci. U.A.S.S.. (
00 (in Rwisk. a]
V1. A44olyetls_ and
V. V. Kimshak and V. A.
a 41 a a ape
!-00
-00
0
.00

00 Jw, 4M', 4OW-Wheii
claw WAIM1. of heated for 4 b
24u, *90

o ro. at
with wift web 480dj* (I OrIftwic(Uhtiveyarebruken
lachlob'
1
Th
) .00

d s
s
.
e mot. wt. of
the 1611411 P-daft Is An a" , I On tk" to the amt
of "so

r .
Mid Md- Wbeve I h mod. Ow wducts havv tmdnal .00
COA VON
~W% but on bw beset lew Co. and the

!==.
61
M
If 11 I

4 P.
V
s used
tiew-, fil WWly hydrocarbon. In alch
10M
Wcorrect wah" for 11W mol
t

so , w
.
_
.
pwtigima Sim srcffmt (amintd.
Wthsd"tennkWNII
r
T1

s 0
94 -
ouPs
.C
l

w Va"Il
s, IN" Mar valutv for the 11;~- wt.
IKvAUft The Nils grualee are United fly H bouds.

Also: 1~h:LM,NaUk'
Iz. Ak. r*,Uk SSSIts Otcleli
,
.
'
use

ILA of M CLASWICAIM
Alm see'
use
%**ago .11 aftv got a ~wv is 4~
'K, 'a ; At IN
AV 00 411i ; C
. or we I N* 1 04 9 0 IS 1 9.0 1 a 4 3 v-11

" 0
o
0

0
00 0
0
0 0 0 0 0 0 0 000 0
0.00 0 * 0 0 0 0 111 00 00,000
f
*
0 a 0 -0 0' ev 0 0 We *_0 4.41
0 0-0 e 090 We G, 0 &_*~W* We'O's

V.
.1 Poi v Polyirbailb6il biber. W
a V. A. tin. GRom.
in
J 47-M 1040j~llngtish. su nutry
A. 37 IMI.-The polymerizaUon of butylvinZi ether
was Stu ed between ann ov In tue presence of
varlouR catalysts, Ear'Lls most vlgorous~ BFJ ightly
less vigorous FcMM.T`vtgor6us anti capabje or inost re-
p"Aticible 'A16 "" gave colored products. The
presence nfVOUTNJ;TW~I~R iftect on the polymerization,
The polymersTME viscaus and very sticky fluids, Sol. In
;Wnd In benzene, insol. lit RtOll anti in water suid
113r. hs-WeWor-wls- up to a56u-V&)00 (max. size ob-
i tained With SuCla at 30*) which polymer was isolated by!
i (metional PPIR. M the crude mist. 0xidatinn by IIN0j
gave butyrIc and oxallc acids, this showing the 5TRIMIre
1, PoTy-mer as of a 1-0 1 1. Hydrolysis by acids led
only !M Wit. UMIrsis 13Y alltall, especially ale.'
MON ave noticeable arnts. of polyvinyl ate. (no de-,
v qa-up
I or elds given), Heating 0 fm polymer Ith 1. 1
roixt. Y.AcOH and Ar' 0
An the firvience of NalIC01
gave a FroMMI-which 4 iiiin"I but 28% Till Itr9lips, and
thus was a Mixed ce ate-bidyl ether_ ol"VOTY-vinyl ale.,
gin.
Y, 'et Y ready soly. In
16 Ronit
Lab. High Molecular cmapounds, Inst. Organic Chemistry, AS SSSR-

of IWAM O"WOWM660 at
&,W,, am &W6011" saw
anj S. it. KAI,6;)v ppilljol. Rewl, U-id. 66-
OAAA. IM, 411, WIT; Mi. Abs., IW, 1114
fit).. flulyawhits from *&IAc and setwic ai4,
wit% Ithyfroo... lettalwhylow-, hexitrucillylele.,
awl tlavanwAyletic-d6uArms and with btnuidme
havo b"ft examined. P"a"If. with the hightt
molvivl,it weight were ubtabW with hcumethvicne.
diamine, Thai a kisThs xmw CUMPWR climinAtiou'd
water, giviag rise MgW *gm of re2ction, The
initial "fdi&IW#w ratio Atte"W"" the nw*cu6f
wCot of the pwducl, AW is isvq tionai
to the excem of acid prescal. Fr":*.- =f-td with
the IUAYIIIcr rawwo latrohn of Inchrealar wc~hl.
A prolotlard nwlWn Itm &Mi Nor lemill in in.
rtcOK41 awk, ukr Wgio It exce" of Iscid IT pr0ekt.
ThIce-.1illic"44)"ll, Ustoluble. wusible IWWUCII skit
fointed by heatiog Ow ptlyaw in air. lmwAM)- owing
to ctoms-linking. ISM.N22 ,14

0 0-6 ise 0-04 wo-
"i I- It , tis 1 14 it 't it a n a x 1% is I? it h ~ 16 Ik v u u is m v a 0 0 44 41 u ta a
A L is L 1. A J-9-L A o r t 10, a IX IV it j st, I S 1 9 -1 0 #--a
-and Madkow. S. F.:
KorsbcbA. V_y
.;I 111XII.m.do-111'r C.411I.Altid.. list
Arail. Ski. U.S.S.R. 19111). 1.-:j
list.
00
00
00 -v is see
oea =00
a"
00.1
woo
::00
ow f 90)
10
00
:
OW
00
00:9 0
A 1 0S L A SITAILLUIRMAL LIMAIL11119 (LiMPKA100" NO*
ams, its
*0
u A' AA I 14M.
I a Ild 0 a 0 1 ff N 9 a a '1 *0
pt Ka Its ocuff "M dft -
6.0 go 0 0 o 0 0 : : : : :10 0 9 **$1,
0 0 0 0 9 O'S, & 0 0 0 e 0 0 0 * 0 0 0 0 0 a 111 0 111 0 0 0 0 0 0 0 0 * 0 0 ~

see,
0 00 0 0 0 0 a 0 9 0 0 0 0
0- o- 4111111110-1,411- got 0 0 0 0 0 of 0-0-0-0-0-
AW -
FF- r-
L rL--1 L 4, 1, ft r %i jq~, ~.~j v Vif I I- I AA 0 (L M It,4 I J 0 1 6, ig- A I, AL A~ a
*0 A&
A* L
of M. Smile I"CWM of
99
cr.
wt. 1116,151; of 1117) hydrubiW Gmnkef a "00
.64"ll"gort slid .4rh-N-b MA - n, 111311) by hat ale.
I and lu-~%Mrllivlf to Uslishav b 110. The ?Wy. -00
viiserl Ak-. wA, three diallynd god jut"W 1WWM the
I-tr-clerr pw 76 sk, unit#. =of. wt. Of
11411 410. see
wait K%1 (MMY of q. own) th" Miligning
OL&I too Airlifleg"t Chaim Ociapip" 1,*' ~6;- 111.
It Cos
wa,
ley rrwvt*tim by Ae;%O-AcOIj in tl~ pggearnce
0
"AnfWtbt"Nni*ICIyK"yUk4~V%!njktfj I miguith's
go land*' uw of eacited P01YAntel air., wbkb was then
.&AI" 6u;-ghly by ak. and HiPt howeriow, Pvt fool
Alki CMpkte
aretYlool" after I hr. at 701; the Product
wall Puriffild by goWn. In hentrelp motif vvqpgn.
:"it*. Oll 9.) Ill ml. 3111'. 'Inyl
N4I]Il W4,6 14,
NO Jorge..
WINI. fil a 14111110 whilh. letter we-
.4"'Utillikul -1 loll"'ant w&Qdum it& water still dryW# over
1.0(4. govall alitained In the fornee of a benjaitt6b jeMid. j"W.
in water, only livoruiag on in water. The wetted
mstwW- After &k'--EtO
Simmilmorly in"4. acetate. wt" vateirly swum in JIM "NMI
orit. Its Ager me. I% 113. i.r. verry clear ito
t
mwtnallx4yviflylntttate. by
1.0 101re 11.V411 gws only (C(h,l) by
whilov aniftelow
:KI-4' lfoh-wd;; -%4()If gave lotelco, craird"ll" tift Ill.
It I itinicturr of the n,winAl pWyvinyl nit-. god
b to
X (A C.) ughled to 1W) I. phthalic anbledi kk j Vinyl!
AcOlf and 0.3 ml. canol. 114%0~. heated hr. to join'.
I
end poufrd inits culd viniter gave 7 g. pot
irvillyl S
r"itittOr .46il. Artiloiet at 7W. .4, IV "If. of
1 1" 4
Q64
see
zoo
I see
Alt FIC&TICA
% .%tA .4YALLL,4eKA LITUNATUNI CL
.4ill Maglig- &to
W le- a -a I to 0 a
3 9 71
u Rk n
[fit It (4
000000000 0 00 40
0 elligoof 0 21M a
60600 0 0 e 0 0 0 * 0
0 00000 0 0
0 00

T. v.
.roducts of addition of Mercuric aitrate to acetylgne, V. V. Korshak and
V. A. Zarivatina. Bull. acad. soi, U.R.S.S., Glasse sci. chi-if- 1946, 111-14
(in Pussian).--
C2H2 was passed into a 25% soln. Of Hg(N03)2 in 2% H1103; the ppt. was 'Washed
after rapid filtration by 21, HNO3, H20, ale., and Et20- It is a heavy White
solid, 02HNOZ, - H92, which inflames on heating and Z;ives CH13 with Iodine in Kl;
it absorbs Br from its soln. in CC1 or H-O (2 moles and 6 *-063, re3p.). Heatijin,
1 g. in 20 mi. AcOll gives an anhydr 1.5-269, in AcOH),
Jlde, C4H202Hg (mol. wt. 249
t~. 2
which opts. from th-~ reaction soln. and decomp. above 240'. If C2112 is passed,-.,-4j
into lb 9- HS(N03)2 in AeOH -contg.- a little AG20 the pptd. product is C2H214.
adds Br and gives "13 with iodide, i.e. is a deriv. of AcK. CICH: CHHgC1 (1g..1
(from G2H2 and HgC12 in 15% HCL) Was 3haken ia 25% aq. Hg("03)2; sOln. and
simultaneous pptn. take place; the product is C2HNOIHg2, identical with that
described above. On the 'oasis of the observations, the following 3tructures are
believed to be correct: 02H2N2O7Hg2 is (03"4102C11CHO, -while 0211110092 is
Hg.O.CF:C11gNO1. G. 1-1. Kosolapoff

............
0 'trio-
it 14 1 1& N N, it 12 o W 0 t. I; As low 41 fill "ImBe
'it If 6
A _L_ 0 L-A 0 a A I I A-A I
I., 4p it 0 (X t%4 0. V
:~ _41 -1.", 1
0-sult J
A lot -so
polys"ll"641104 194CUMS, Val. '44
- % gmuhs 1. 0.77 ski OV,. (I..U at 1611. 11 Um at *00
of adlpk ad d on pulywailoquilan with 130%, 0,111 111 M1,~'whI0,1281 100`,~~Cuvbm 1. Twoes-
andme. V.V_Kmsh&k&n4V.V.Go1ubev. ReMocild. Pi,,,MM Of the action of exce" I ulay be given: (1) the
Ad. U.N.S.S.. CkA.14 Ad. CUM. IM. I"(10 RUNIPA).
lijktion through alternate CoUrA,ng of
cI.C.A.40,+W6,4I,IGI7g;42 150s.-Excenotildiple I and 11
41~!: exid (1) in the condensation witellexamthylenedismAne until the lenninal gTolliv, WT both of tm I and reaction
(U)StatbtopolyantlAksottowtndamA.wt. Attemid," ends (this. howvvvr d,1,. nots,,txknt 'r int~rarthvn (
formuld 11 - (125m/b 1- 140, where At is The av. ",W. Wt the wyantme With h. ami (2) .01,11 Int"S'l; .. ... mr. hy
of the IMMILWts L the wt. % of exce" 1. was derl'v~ti Suralts of arld.14%iN, Wilk b Iviltis to chAnt -t-hits and de.
400 1; flout cookkrations in the pmvkmn paper. TUatedut Ctraw of 1kv. 111.4. wt. G Nt Kt-OA1.4 .040
00-0 used was itmit of Radkov "I X. (C.A. M, ON').
90 products were examd. fur Mol. wt. (by vlKvWty In emol)
ana no. of end S"m amlidind to a previlift paper Also: Iz- Ad. Nauk SSSR, Mel -fie
00 !RW fullowind results (StYrn In the 400
40(drT ot, -1 ), cavvx* I mud m4d. wt. by wild groupo, by VI- Rhim- NaUk
11 Cooly, wild by The above lorillyiel Wilm oMdh*d: 0.5. Zo 0
00 35,tW.23.023, above foruntia,15"' I =A@. 19M
see
22.740; 2. IK.ISI,, 14,970. 11.446,
Will 15. 4", 4139. IGU; 30. 3160. 2683'3'.~M"-MR NON; Inst. 0t Organic Chem., AS USSR.
_M, =. 100, 2170, 2M. 372. The rmdb am &W 44
given paphic-ally. The diverawe betweem Ciale-d. and
obeav-d I". wts. 6 not Cauard by Immanplew nwtkm 1400
t and rmat!w c',rined by ibe ummited partim of 1, wMrh Igoe
uppets I equ I + 11 - polyantilic. by splAkedoo of
+
a low. faluxula, using is lu a polit of I which mers the ft- go*
action. a - =.6W/(JW-I4d)N, wbcsv a h ow total
We 0
munt. of I used. the values of a wvm found to be: 0.77 at
6~0..SL A AsTALLURr1r.&L LIfIENOURIE (CAISIFKATICII
tL AV a 5,
IN 0 x 9 It a it It I
0 0 0 0 0 0 0 0 0 0 0 4
00 00 o 0o 0 004 00 a 4
KW K I
0
0
A S 0 FW 0 1 w ft
0
0
Igoe

mom
00 goal 000006 6 soo.elboolboosoo
g 0
00000000000410000*0 90000000000000*00
ILI 10 It 0
0
,, ?U34 36 Is V 18 It 40 At Q 43 44 A %I Cm
At 0 -4 CPU a I TINT"If. A., 't y U T,
Is, -.0 _L, I -V9;----
0
0
ImLlistal )op *.a 40, tw.,Ivs
10 ~ft
Oft
0 04
o::
0 ft
0
0o
oov
^00
00= 00
oft 00
00= A
00
*Oa 12.04,
00. jp 00
046
066. 00
00. 1 .03uajajaj 00
jalmil pilly'. I ji!
of. p "11jActid -pqvAild pm 1*uimp ',%' 4 00
pulu tldax~ ju q"sm -am* pit# -qvl #irv"jwjr11X
Go. -t) 10 Awal- Wtqv 699wril 00
.1 'S "D PUN 31=11UPAl'
.4 'A 00
0 IN"
2262
.3a. 1114#14344 COT 11,111113wed 00
471$ q 00
or VTF T--v T- a T-A R I R_ 9-
a It ir 1 6, 4~ i 4 4 # 4 of f
0 00 0 11-0 00 0 0
9 gos, 00 go 010
00
14, . "m

00
0
:
0
00
*0
60 4
00 A
00
ooz
0*
000
3
00 1
OOAM

If

LOAM-- too ~u6
-
7

1
8
= 0
4
0

4
0
Iock" Mitu Mcdo. M. Re".
:
0
0
to am afore wft*
vwyj too .00

Mowdem). J. Gen.
0. (MBAR.) 1 3064-11=04 Rw4kn); cl.
--C
4W3l
40
34
AK4
Ali, 006
.
o
, wen
1.
"

.l
mh
w
g
k =;C%; 0.0
w
b
df
m
I St.- Ph(
acted CJIw Aw a tolly I . W& %b.178-80%
Z
Atod
400
N-M . iuW a owl mt. of mtwW. b. 21640%,
A wee not foevestlAnted. so gyrown wee towed In the
loalt- 1twooopperea thettiseedwrionedtoood- 400
a with COS. bw swair
t
l
i
h Cj
* "had a pdymw; the ktter
ti
f
k
l
M k
oo
w
t
took s
4a
M
k
d SM
A now
on o
oot w
a
ft
d with 43
t
Kb
c
were
e
ra
g.
i
e& 1.) a
CU. Us Am misift.); a oko ovolutim of H&
plom "d lbe Edo. weis bated to 60-70* wwaml
so
nun awts
of
to yw
~lftw dw Una decou
.
..
p
t
o
(U and #j
*
b
i
-2
li
o I. M
(frM B
t
w* abulseed lo 72% YW km 4 t. U vA 3 g.
qt W70% AcH poosed *o of CJ14 =4
Q
10 - I L A _!f.L4WMC" UICOATAMOr CIANIPWAYMN bee
Me
1*3440 oto qwv a", 4SALS14111 MASI an 4MV All
I - I - 7 An A I a w 0 0 9 1 IF a I a a 4 0 1
U 0 AV IS X, S a x a a a k ;&As 1 %4,-
0 00 000 0 040 000 0 * 0. 0 0 00 9969 00 *see 0 0 9 10 0 9 0,0 0 0 W-40 a
0 0 0000100 0 0 Wo a 0 60--o-so 0 -0_A- 0-0-,* 41-0 *-o 0 0606609606 000/
I -
i=

KQRSHAK, 1. PA 52T2
1~',

a' -

: . OV Mid Abu ape 414214
I J
"
A~ L 1
It 0 A I
";ffTTTTrm
9 V
X 0.

A
:
l _
-
,
,
JL__ A __ t- -.1 --a __L_ "
. , c , 2
__I -.
o

Polywaden"llon reactlons. ~-V-4-kovAuk, S. It
l
-
(I
II
Ch
M
i -00
t
-
I",.
rg.
n9
-,
ikov, wid V. A. lailiYal
Ral
'I'm Phrif-him. :1, WWI;...
6
o
1
4 -00
. -Hrifitit 4
14
1
. Itid:J
vilKI1.11); 0. C.A. 40, it u
J flu- locilymmkic frism lievAtist-thylvarilLimia,
astil ailipic scid, 4 flu- uk-chanimn 44 the ImilytotulvoiNitit"a
ft,acti-mi, 411.1 of acidolly.'k and amiludy.11.11 IiitlyAmid".
A. FIriwlicr

see
so
of so*

'0e1
see
C.- LLMICAL LIT11114111011 CLAUPKA111"
Blow 111,141,111F. 9.&:T.M-_2w
oNv an 2110. ve
as ow all
IL a ~v lo a L t a 04 a v I N a I a 4-
'1* 0 0 0 0 0 0 0 o 0 e 0 0 0 0 4 0 0 0 ~ 0 0 0 0 0 * 0 o 0 0.0
0 0 0 06000609060
000040000000000:2

TW
-Wo-W-0111foo Goose

0 'Oil 0a
0,8-t,0 o 4
o
-
06609
00o
0
6
0
~
'
0
111116 gia. 0 0 0 4, 0
l
iijjl On its) "View" slivo W
L; A l
I
T
a r O-00
'
,
41. ;j-VJ*$

0*0 044 Its APP FOCOM-44 ~iq
Misduntim of the ftedol.

=fmisards of bearins sad lelowri with Womilartat
11sin for all suins. vnis 32 1. Tlai~ ot-4. %to of Allthro kit
f
k 00
iz, V. Kursha
. N. N. Lcbnkv. sad IL D. _
Fetlowev, (Alendeleev, Visitors. Tech. laist.. Momew). ibis "u. If.p. narthod) found were 41#4 AM 4111.5 Illat-o.
k
6
di *00
Mt
al M-
), in
t:1605 only it snall tkilti: ill Afts'suell.
J. G,.. Ch... 17. M-01(1947)(ln Itawkw) go.
ls~ phj,(e at
essintilar
Whendrylittr6 4,"
u
U
A
00
004 .
.
& V.A. 41. 2711se.-JUdgirs t
'be "'k' mMtM y Ail;r
I
st
W
1. Ph&k
th
mu
jb
t y
T
I
1 ;1
4 -4
ies
e
Y
.
c
t
ft
.
.
l
1
i11W lool. st(Mcitiqut, Soluss, q tks In betruilisso or PhMis which hats 3
14-338
tor
f II
f
h
I Al
h

00 ns, o
.
a
I In
owirvirs, t
. i
.
e
41" w.1 4~ooiaill ossify drd"ists "W"pth. bat "it an Is
ily couspli" Is 44144inni wilhout life O&W 44 A.1-lell 11111 [lot
75 7
0414 rilifil, itt the lylw Al.lirs + aCtIll 0.3 Al
WO1104. a flat ex
,
s
1
ert
@ of
ll
slur
lit lit VhNI
th
s
testir
i
os
e
ir
Q.
p
I
Nahiftril sulestaitil fly Ito the kit-luntil aide. Wben such
71t;
attlin
Is iscitnewhat dillcirtat: 2
lit t
W 1 A
1
.
,
o
.
a ouln. iti treal swith 1111r. Ito ever. proloslitil cbsn#n -00
9 Olt l"Ilt, it-alling 11) a Viallilex WI)kh on". all us oil. chww Indivillual variations were maidecable sold arc aL%vontw
-f
b
ro

,3 or
y partial Isydrulyishisif AllIts.
ttrized fly ritorswund. anti having the covolin. Allike :
0.
j complex is *&shelf with dry PhAle
it. lir/Al ratio " e
00 .
1
Ar..118r; the uster-all system is bat coasideted an 9W =00

*00 proaches15:1. The isitailarmisplex tacAtned by ticd.

f Alti
l
i
l
i
h l
;200
ictitcoe w
n
t
if
r %" mussewhAt lc~
rs
!j~ similar to that given above. Allirs was twild. by The trictil. o
d
b
di
00a sts
k and
d not witfuland washing without wine kwis it
w1jorral Hr ost.ssi shoying% with Ur being added toal&YVI
' Zoo

OOU .* I.WLIS-1.61411 and with water
of glas3 wool underlying a thick sim" of Al shavings cuts- r; the complex W ot
i
b
b
l
=00
ves
erisene ant
(arry
y-pioducts. Compirstes joregid.
a Uk fitted with a ~tllilituatiojj tube and re- g
in
(s4ned
I
00-4 .
MVrr. I he flAsk ill lwatol coiscurrearly with the Of W,klit.; in suoist bentenc have the cousins. AlsIJrG.6l,:.If# whdc
I
is zoo
the larikluct IS third. 1131 110441C41 IfUto the revirivw. AICI, -thaw m4* with dry Mir are Alill(s.K.1 I..11 lit. Licill.
was insult simMuly, using Cl and Al; Ilse distu. twit wait Of flit MW. Of. CfYML(qkWiy in liclurils, save 141-144 see
provided with a sleeve-sleaW ml lorr civArW the suNins- for the tolsocrur ctariplrx and W017 Its the benzene LMU-
1! 1 --sit Front the disin. tube. Wh hallilm were obtained in Reaction
aat the complexm wish AcCl gavir ths: (oib,"Ing comfort.
briter than tW!, purity. Mlsi,- tit AllArs In bt%Ltcttc a is
high ast 0% 1" coswis. am modify 181911C and, after jsrJJUVsiI of flit JJX CV19VL41.' llflttelle CtillipleX. X1.48 lool. ':~ fillf 1 ;too

J ti. and IM-62 mol. % IICI. toluelle coulplit-ii, 81,07-141.1
a miltiall sont - of I he C41Y roollstrik. call lite litured Inde 0
M
It
l H
l
I.- OU-I
s stil
i
AI 111.4. ~~ IlCI, olikh stup. i
I This (OHOWing COMIS. 'Arfl! tIC141. for SUCIS solits" mol. %
'
"!P.
AQ2; PMUthefUnUtIlAtilMS: 2IAI,l1r#.l1C.Il..IlIk) I- lAcCl-
AIB,. tit' 0 OW mV. LVAI. 0-irkt, I--
-SCJI
+ 4PhAc + 411tAlli
Uilli
WAY
cf)
41
UW
;
0
t
1(A1-
4
+
t;
17.19%, IAW.
.
,
13.
% D-97
.
'
S
211(i
11111
I(
I
CI

oo
r
rlw- upil. ivfldc-
crX
k + H
+ 3A1
) +
c.0 + Aliks.
I
j*L1.
LIMI, IBM;
I
XI. I ..
61,1611.1,06K&L W13101411 CLASSIFICATION Vr

Joao 410, 0611 004 4T. skills Ca 4V 'l:
'
'
U 5 Al 10 11
; C, a 1, so Or X a or it X if PA A S 0 rid a 00 Al I Is of 0 .9 0 3 Is
i I; Will 45 It
1 ff"A ~i
W
~
.
0 Z 0 0 * eo 0e 0 o f wes 46 0offiltilciii so o 0 o * o 6060 dl see a * 61
0 96 0 00 0111114111141111 0010-46 0 40,4111F 0 0-111110 -0 -0 0-00*0 a 0 we e 009 6991

*Olt I I It? f ?I I I I I III T, I I U111T M--
1-4-1 -.U.
,A
00
Ll
411 rFic I
f +
-lie
lue
~ -a
00
di u A U-U 91
El I-Ij +
Ka J� 0
flv!~ A 1 -5 +
to S
-1 lq .
u lu MTN ec--4 0 0
I.- j9u t2 d
C6 Vt,- 4.6
004 t'14 , . t
V'j 6 .113,91 - 9 . -~-&. -r -2
Aplid -:. j I - .. $1
.8j(
A4.! SOU u- (j
mag C3 U +
uu
LITIENATURE CLAISIFICATION
go., V~
ilTil
- ----------
S v fw 0 4
wilt wooo -j -vu o a 0
0 00 Sg 0 0 0 0
a U AV
-00
I
'00
#s0
coo
too
coo
ale 0
Woo
Us*

** *Soto 0 00 0 0 0 0 0 a
- 3 of
11, Sol TIND f ex
fe. 41
" a 0 a l#PO
004
m7m~
- -
"#Fit$ AS* pakwfor-ef woo*

0* t "um Go a" bdow Wish 6mm. Kordwk and
-
r
Wb
Cb
A47f
M
dd
K
M
4*-
ite
orw
.
-. S. take
m
m
ow (
.
C9110). A Go. CWN. A111-1=643-4(19472n
dboomm th
III III the d AK% Iiwt st*Akd with amaly4s of
h
l
HC
Hl
rain
Md t
e
l:
tbeHXevdv . Istlacema
-
HCI&md?4
15
utou
25
06=d
gil
vwa
"3:1
.
.
w
g.
;
iP
o
,%
~
I
d I
ith AlCl
W
Hl
W
090 w
.
III "III
-
N
s
.%.
I"ll
WhW HCI in ben -
sJ& tOllf/
ACI
im 34
17%
-
.
e
,
g
I
. no. d AlOrt In bowne, followd
um with w I
p" a ps T&Ol mol.% It Hr and
by bmft
a
l go

o.,

n wwo bmwne
'law
a

ge
goo
wwanslywdia4
.
b
f ti
I h
ith N
Cl
d
d
w
) g

r.
I
m
-
81vwa
(ta
m,
; w
4
W ee
AWL! o
tin kam fit INL% 110 0.8
TJOl~Nm
rC=fl
HCI
d
1
t
76
d
V
d
l "so
m
8
o
.
m
.
r
m
W,
w" the
k
&
veIiit4A wAl.% HCIwW 95.5 tnol.% see
th
ki
i
4
lbbb
b
ll
0
r-
uc
s
m.
im
icalu
w
wiInum Xse
o
rmoiow we vwy dmillw. G. M. Kambped f
*Is zed

A 5 a - I L A 21 TALLUOKCAL LITIROM CLAUVOCATM C-;Z goo
-tl
SIV-41410
RUM NNOW
-4
110
0 a
r
l tog
10
9
9 1
.06
9
4
1/ ll
0i
0
981121 GIC ON# Lot
U 9 AW 00 11 ' q ' I I a rm 0 is 0 1 v N 0 As 4 3 0

0 0 0 0 So 0 40 0000400664 Gee a 0 0 0 0 0 0 0 0 0 0 a Is 6 411
a 046 0 0 0 0 0 0 0 0

mu

ow-- MO
ffilff ml ME

L-j 00 of AS
cillif -040
OSA Is? Awp 1%0 4"#NL
feactmi &W 0410041111111 Get
I to Th.
F ThO f4lolictlan of 1.2-ilkillmin'11111,14P with bmusnoll.
AT
V. I'Artsbak, 0. N Kid,
V. Is ,A-l
s itself A, V.
tloill)iir F *4
.1-4, Ito, $0, ire
Ow (VII.C11, 11)
anti Collo W file P-11ty of A10. IL.Ivr hircts %ttulk A %imilm KNO111 1% obtAill'.1
Mitts. Uf tNt.; of. Colt -d. 1--- -4
fill's 1w, wt,V heated 4.5 firti, at ith stiff. AcONa. U) g. jjv., anif 3 S. I (cf. Utz, CA. lit
a 85* with varying %all%. u( AM. (11.4, 13.5 and 6. 00
7 it.). in McOll. licated S mist.
The yield of difillenyleth4ne (11) Creaml i~ thew cawq an the 11.0, ratis antl etellut. ift -a- give, after Ji'mltv'ftg -00
from -Mlolo ill to M1.0"t.. where"'I tho, yield nt the midue In lip. %ri,lifyi"j, gtul ptilt. llw off with prior.
the Avinfork, mithict with (he -00
so AIVI.. vtlorr, i$-111 (IV). ill. IV Is .11.) oblAilled fly
When tlw tims. kif AICI, t,,,l ,,, held beliting ml the Il'o 11-1th I hr., muttle detivii. of I (cf. oo
mut. but ill . ..... IV vatic; of Coll. to I Wall Visor" (13.5. DUp(Mt. C.A. 22,3M) Alld 4 Slight eXCM (A
e 0 0.7. .3.35. 1.114, 1.11). 1).m. 31k, 0-017). file yfeld'i 0( U Pall4l hydr(tritation of I In ste, with R
Ancy ~ tip ,ves
were r"Is. AAA.M.3. 37m, 12m, 4), it, anti wtmrmq the WT ISO,*
Baclitclills. in.
anti. oi imayint-t intw4u4i. 'rhet-rim"k-IM141%WtWhilloo
theyieldoillw4mov", "'19 110*181. Its V411" 1. Nfrol AdAftl Its It, it, I ill rg) C. i-A.I. dry lit 0 1 ofIV" lip Alh,,"myl -
lbor" j 1. l4eirchli -hopla-liellp k V 1, its. I V (2 0 1.
: And ICI(Ill. lit tit t.tlWf r%lsli, llW
e*J Volls-%14- ptlynt
z4u,t. were .11 r1h. ihot cAlvd. oint. tit 44) g. 101, Aroll.
Own lit JLjVr It'. vj,.Jtj,~ (40, ill C 11 ) till) Imill. give. after py"tri. With
eel' 0-412441-14, lbetited a few min. Ito the
go " i licitm it W" 01111. 111,11-4 11.0 Rod mt3mill. hims Mr.. it 111ftid,41itir (VD, roe
lorlivilbill of lemplith"ji, deld,
'kit 'he I'lly"I't w-11 in. 211 2*. V (I ~) 2A re. ArOll,aml mit rlter" 44 Nill.
CON)INHOIL-I 1 '11) awl AviiNa. bvmM t hr, ..it Ow
cli.ell, 110 tutill. olive 4 IVIII), too. Int"
which Will nol rm&-t 11111hrr Willi Vit. V with 1611" Nt
abolitalis I mol. It to give 14 ctrittlid, (M. lit. 1323'. IX
r,ent.10A and j,,,, (1,,. with 8% aq. permaticAnUe 1 vc% 'IlsOll and ris-1,3-
cyciopentancilkAtblMyliC Atilt. In. 11W (C(. C.A. 41,
main' "Na' ode- "Alm- FrOmir 1140117s NO-O.-A mixt. of 2 11. Vill, milli IX).
f g. lisciclis (I) And M g. Hitch Sol". ("Id. in the 2430t. fix the stirtictum of V. V
cat anti arldit" with 6 few droll, 1101is) ,led ... al R, L. May wee
it". on 'be "it) ')'it" gim "It URCUstallimble oil Which.
I after exin. with HIP and asitalion of this matill. with Cu.
(OAe) giv" A FIM111 Plot. of the ON Mk of 0* 0401
I ftwm
IL Of Ali Ohl's 11) Orl"ll im-lilifify IS mitt. of I
Jiforqu- W(Oll):01116 till) (V6 Anti train) dild I'll. I tak. SO. i Im V
G
AA tev
0 0 0 to to a Is adsig flow ttegmen 1 14
to re o o to o 0 0 0 o a 0,0 Or 0 0 9 a 0 0 a 0 0 0 0 a 0 0 0 o 0 o
&'s & a 0 a 0 0 a a * 0 * * 0 0 0 a * 0 41111 0 0 0 0 t. 0 t 0 0 0 0 0 0

KORS'AAK, V. V.
?A UT72

KORSHAKJ, V. V.,,
PA 58T4

and LMEDEvi
"C
omplex (;OmPounds of Alk
1947 %y1 Halide and Aluj...
Ibid: 57P Ifo. 9, .1947. Halide, Dok- Ajq, 57, No. 3p

u It u a k It Is 0 in 41 Q -1 it re
0
4JO A A -L-,b F r a So I _j_AL__'X P_A_ .-C-# -1 1 o I- I
t.t. ..0 "C#.%
06.4 towpeun& M. The PeAp j
of V. L'rkgij.Mk and V. A.
7nanjolina.
194,11. 412-19; cf. C.A.41, rM."T"Polyaneld"
iVees
onerr lorelool. toy el"itlentatloin of few and
I't
tl~l adipic schl, The
chiametrie tati of ditattline And 11clot- 1110141 1% It"- wt- 14
00 I5,2M by it delo The
2nd ftnmiilr (11). oUldt with S" ""'t- Of nallf"C &ci'l- '00
hold wt. 14 ") by T let n. atilt We) by elett-poettv
al'.1volis. 'A reltial parlsof I *not U bait a mol. wt
: fly the fact that IrStudAtiter (Owtit 1-trollivs) frievtont- roe
"IV") by 111101): 1#1111 A1411P by
g: tionation of a 21, cre-Ail loln. Ill the inild. by SA1110, 01 call Occur at tilt -41- tittle t. Tile Illutt
MrOlf produced 2 fractions. The Ist tractioa. ewe- son]. enixt, repirrsenisa tr:oultant tit list ltmillus rructi,lo,i
q detn. atilt l1ructitonalin" 14 I-olvalnMrs'1-1 $I'll llftvuarily prtwti-d
fing to 1. had 44 neol. wit'. ref 14.411) by
17MM11 low end-potolt analyqi%. The 2o,1 firuction, ctiorre. in a tit met &.liver ard toy the- 121"1. to 1. -4 tbp 1.4vilirr towl'.
5 1 N I I I rtcl by the 11.1111w 4 11"...10 ar-mil-ut Ou
almondirls I., It. 1,4.1 'S owl. to I. "N I liv to little. and ',7:Ul its M1141mit' i: =go
Njill "ify I
by ro.1 st,"it. Amatwir 1.4yam6lo, (till. 0., ol.d- 1. 0
IRA& (title% SO Ih-4001411011C 1.111- 44 trd.'11411110. load A 111.4 obotorovs-.1 %%tile h0l.. ad.."
tat. of 111. VA.A. (I .... I tile lollitl%ic 4. Tile LA',. ~t%. -Iv. 1't "00
A114 CTVWI U.10.44411 Ill ,it (NdiOnAtell Willi NICOII (tilt) A (tile- K. 1.1villpf.... i:;400
tioneet fanxitill in nuil, wt. loom "Ill to 21,2%). A 1-1j. roe
an�Utr (IV) tuadr Willi riorr'. olitemil'o, hall a mool. wt. of
Tile 2.61"C"Oll Mille. it(
IV all ItACtillhAll"t with Met)II live., it frictions rAngitilt
is I=. wt. from Z4111 to 10.1011111. 310. wt. distribution
orum% slumil III to tit mostly in the Ifi,t)(0-2D.000 multr.
6 of much loiner mal. wt., while
IV .11=1 o:;A`:t` I - 0
luol. wit. range without any jtro-
too
jLlt~'-_SLA 11111ALL111164CAL Lilt CJAJSW"
9 Dee
Ila. $1.1. 1
,4" .44.1
Ono smlv~') -AP a.. goot roe
4,1111113011
U &V 00 ItI
a go tv tv 19 wit "Itflu 14941111 Itultilin I ae 0
00 411 0 0 0 000 0 0 0 4111 0 0 0 a 0, 0 0 0 0 & 9 Is 0 0 0 0 ig 0
0 0 0 0 0 is 9140 0000 0 0 0 0 oi~-
T

MWdhemistry - Jxaes,, Poly
Chemistry - Distillation
14/lug 49
Mudies in the Field of High-Weaular 4ampounds,* V. V. Norshak, V. A. Zanyatina,
Inst Org Chem, Acs* Sei USSR, 7* pp
*Is Ak Hauk SSSR,, Otdol nim Nauk� No 1,
DencrIbes fractioning of polywddes from solutions in cresol bF precipitation vith
methyl aloolol. Constructs distriWon curve. Establishes that polywddes are
fairly uniform products 'containing only ma3.1 quantities of low-mlecular
fractions andj, therefore, the man value of the moleculaz~K: determined by
viscosity of solutions,, represents the basic constituent of'the'po do fairly
accurately. This uniformity, evIdently, dlstln&ishss the polyamides from high-
molecular substances obtained by polywrization*. Submitted -20,~;Nov 1946.
?A 8/49T15

KORSHAK, V. V.
ussR/chemistry - Condensation, Chemical Nov/Dec Lb
Chemistry - Molecular Weights, Determination
"Research in the Field of High Iblecular Compounds: XVII, Distribution of
Polyesters According to 1-blecular Weight.,." S. R. Rafikiv, V. V. Korshak, 0. N.
Chelnokovaj Inst Org Chem, Acad Sci USSR, 10 pp
"Iz Ak Nauk SSSRj Otdel Khim Nauk" No 6 P 6,0-65-1
Investigated reaction of poylcondensation in adivic acid with glycols, Separated
polyesters obtained into fractions, and determined their molecular weight by chemical
and viscosimatkic methods. Data obtained was used for consideration of the reaction
mechanism of linear polycondensation. Submitted 19 Jul 47-
PA 33/49 T23

KojjSjAK, V. A.

oGetilar
4r
lycondeneation of 2 With -jhAG't=.
V. K#MbA
n Iri; Q
V em, cc 111
Ict IrMCM. (U 5 S R IT lug-
T tI0U4E;R,fiHd 61,C1) In t AICII
b
was shown to be affected
y voriat I
h
I4
f
o
0
i I I
: d t: oints.
I
h I
rm
ltents,
o
t
o comp
X
4t '
4% ct
r"
(polycondetimflon product) by? Cr 0 to ext ~ 141tai reaelle-5 1.118
when the idol. Wt. of the
file ilixivo ratill
acid, Indicating that life polymer ade o f P I nuclei ,
.
; t,P!jlix1. Whoit the polyriter (.1-7 g.) ViAA
Prrxitwt oivor
joined by CHIClis links In para positiow, Coto (26-1 g~)
4-o
and 50
CI)
e tre
ted with 07
(C11
7
Am ~
wiltA 7-18 lim. with W cc. il,O, IM W. IlrSOj, and 40 C. 1
I
.
i wer
a
.
g.
g.
s
,
4.5 lars. on asteam bath; the yield of the polymer dropped K'cr-01' mlly (Creplithalle acid wits isolated. This alm.
with sm-Wer adits. of AICI, (from 31.7 11. to 15 1.) but Its IWOMM Nylli"ll the polymer W-'" oiddlasid.
nature was not changed; It wits still a homogeneous ISUL.44
I
C
H
2
i
AIC1
l
I
d
h
d C
l1
h
il ~t' lie it it i nat Imi of t he Iii-wi, polymer 6 readil explainctilly
thc fact. that with the ptopriftion,4 used all t1to Cilia reiwO
,
so
na
ser
es t
d
s.
n
e
3 an
, were
e
a
a
const. (anits. not given) while the (CHICI)2 was varied to form the polymer and the I-Alter is then able to condense -
fro425g. toW0g- (inol. ratio to C41-10 from 13.15to0.07); further with the dichloride through reaction in the ortlia
;is the amt. of the dichloridc Increases, thr amt. of (I'll- posit ion, lea, ling to3-ditneiisioiialmoLs.byc!rnssllitkiug.
'
CHI)t drops and reaches zero fit mol. ratios below I ithe Kosolapoll
reaction time had to lie reduced from -1.6 firs. to t-2.5 mrs.
itt these runs because ofexcessive foaming); theitint.ofthe
polymer, however, constantly rL-xs, from 6.2 C. to 3W g.
Only when the ratio of Cilia to the dichloride drops lower
than 1.1 does the polymer change Its propertkes; it be-
comes insol. In CsHp :The mol. wt. o! the polymer (b
viscosity In benztne) remains In the 12(*-13W range fmtrl

*_076 W
a
0 011111, v

-
fo 0
ft
4 L. L I -A., -9 j. l, L 0 A
h 1. U A I T I L~ As 0 tt it i

so,
so
,
Casub"M W "Ossak
SdA.
W*
..r Lehedvv. and K. V. liorisova. zA1W.
XAiW
: 0. Gen. Chem.) It, M-MIM).-S
41k
metflum under iselkw of Q (
of K
OCI
.
W
&
b kwdlutoalk
0 li
eratiort of frev N. the Interme"fe, deffluipa.
d 112SO4. Ilv
C
Pro
" (mono- and dichlarmullantle acids) have
MY the same result
short Die in the suln. The dmompa. In alk. medium way
b 'in 3 days
02 m
e retweserited by; 2NaOSO~NCI,-N*0S%NCI-NCISQ,
1
0 ,
of I the
Wn
.
40111 Ns + VaW), + XUCI. When dilmination Is .
rapUlly clouds
dorie In acid win. the reaction does not appamfly stop at pCgiliol, 0( yel
00 The dich3oro stage Ilut proemls to trkbkco scid; he Allempt
litter immediately demuposes Into NCh and
To 20 Ir. CISvWi was grisdually Wiled W 1. (NIIS)ICID
th cadint and stirrins; after 2 Isrs. at 7#5 or 0.78 hr.

:

a

. the man was paw into ice-water in Siva 76 It. o4oo*
t
.94n.oft.
en
.
l.
low
s

To,60g.coaW.14*904WAS
added 15 C. (Nifg).CO with Cooling oW stird". followed
by 110 g. 43% oleum. The inixt. was beefed to 100-51.cooled,
am list resullins ivswi (1) (83%) MW liftered o11 aw
7ji washed with little water; it m. LO~a _~Wtler).
Addlu. of N&OCI to sq. win. of I
hanalling and lib.,W. .1 N; d. ~~nmWG;Cll 1.
A WITAiLUPWAL LJISNAILSE CLASPOKAt"
.10 a.. off
,U ts AV 00
0 it p a it tog Its 994 Itaft Igst
00 0 00 00 so 0 0 4' W1
-0-0-0-
t
4 0 1

----- -- 1-00
;-go

00
oduct
In both =ft%thC2Ud1 Pt
00 pruduc"
an Insumcient aml. of NA
'go
In it quant. expt. t ff. sulfamic acid pit. .90
N (79.65%). Wber: C1 is papsW Wo sq.
soln. becomies want and Colorfast, thro are 0
and turns yellow with Simultaneous de.
oily NCI,, which constantly Itheratft a
to Wate the intermediate products, 099
M. KO*Aapod

nee
Ise,

lee
No 0

-Z, W_
Id., ... ...
a* C.- Ill
.0 a 3 0
0690100 goo * 0 0 0 0 CO 0 0 0 0 o1

UUMI/Chemi stry Friedel-Crart1w1te"tion' Aug 4~5~
Chemistry Vinylidene acgpoundg
"Prieriel-Craft's ]Raaoti=: VII, Beaction of Vinyl-
1dene Chloride With Benzene," V. v. jqorsbgLk, K. 10
SWAPlavskaya, Moscow Or& of Lenin, Chemicotech Inat
imeni D. 1. Wnclaleyev, 4j pp
Zhur Obshch Thimli" Vol XVIII (=), No 8
P"viously established pronounced difference in tnm
of reaction of olefinio part of =lecule in vinyl
chloride or acetate on one hand,, and- vinyl butyl'
other in presence of aluminun chloride on the other
band. Disubstituted ethylenes now investigated on
1qAqT12
USSR/Chemdetry Friedel-Craft's Reaction Aug 4E
(C ontd)
emmple of vinylidens chloride, It reacted with
benzene in ratio 1:8 Lin Weeenes' of 12-200% al=i -
chloride, and yielded 35% theoretical 1,1-di-:,,
atylethylene an& 45% theoretical of its d1mer,
ph
lj3Lp3-triPhenYl-3-methYlhYdrindene- Limitation Of
poljymerization to &imer is explained by sterio
hindrance. SubmItted, 7.1ftr 47.
19POT12

V. V.
"CRS
V. V. Korshak and N. N. Lebedev, On the mechanism of the Friedel-Krafts reaction.
VIII. On the structure of complex compownds of alwinwm lizilides with alkyl halides.
1766.
The absorotion of ultra-violet rtiys by solutions of aluminwn, bror:lide in et;,Iy1
bromide was investigEted and it was found thLt tl-.is solution absorbs better than
the pure solvent. The content of various hydrogen halides in f~.,ases evolved during
the Friedel-Kxafts reaction were also investiyated. (This article hi;s a bibliocraphy
of 43 entries.)
The Mendeleev Moscow Chemico Technological Inst., Holder of the Lenin Order
October 15, 1947
SO: Journal of General Chemistry (USSR) 289 (80) No. 10 (1948):

so's
00 A
z
00
414 19
go rr
if% I I
set
tID
ood
44
0
All (I
06
OSMAMLIMM
Sol
000004,
Is 0'
0 0 * * so 0 00 00 00 0 00 0 00 cot 00 00 00 *0 ~0000 00 108
TOO: 19io ee * o 0- ~6~00 -o0 0 0 ~~Owo ma*~*-Wot 00 ~itl ~ ~0*-'109 ~ I I

"Degree of Polydispersion of Polyamides)" Dok. AN SSSR, Nova Ser., 59, No. 5,
1948.
.:ZF- --M-~ - I
ve~ I
- ~p
- H~' Wx
!~Ii ~xl
I'M I ilw
N,
bi w Imp-M m -

GOWTA, O.P.. IYANOT.T.I., KORSHAK,V.T.. doktor khimichookikh nail .
redaktor; SHffCRJM, (T.-N. -.'IS cheskly redaktor.
[Molecular wight of cellulose] 0 molskultarnom vese teelliu-
losy. Moskva, Isd-vo Akad, zeuk SSSR, 1949. 114 p. (MLRA 8:8)
(Cellulose)

Mini 704fiiffk~fct_ fr -
eno t pn rf1mAprt9
Me
an

Akd'd. Nauk, S_~ S.R 194Q. 22 J~t. -Ilic
ratio "t starfinic "W[crials is conqidered in pnerat ft"'i
spe-jile caqcj of poty cundetwitivil reactions (Mm a kinctic
viewpoint, In whicir (i Is shown that the exetis of either cam-
p(Ment leatt% to a sll trp dectilic of tile iv - Mol. -ft. of .be
poiyeandensation IM Kht-d, The data irc ta-ken fmn tirlitm
putilicattatm, largely Gf the authan. 14 rtferrnm.
114 Ko'n la- t-1

K4. W~ q

-11-ci
G. 11. Chelnokmra, S. R. Rafikov and V. V. Korsha
"From the Field of Macromolecular Cormounds, l9th Report.: The DeterrLnation
of the Mean Molecular Weight of Po2yesters from the Mridgroi~ps." Reports of
the AcadenV of Sciences, USSR, Department of Cherulcal Sciences, 1949, 205-3.1,
A-pril; Institutue for Organic Chemistry of the AcaderV of Sciences j USSR.
:3S'.'L,-ACT AVAIIL~12LE
A
T
D-50054

-7-
USM/Chemistry -: Molecular: Weight Jan/Yeb 49
Calculation of Ave=.
Chemistry - Polymers, Kolecular Weights of
*Study in the Field of Compounds of High Molecular
'Weight: 2VIII, Average Kolecular'Weights of
Polymer Homologues," S. R' Refilcoy, V. T Korshak, 4-3
to
'G. X. Chelnokoval Inat Or; Chem, Aced Sci USSR, 6 pp
'11z Ak Naak ME, Otdel Khim, lauk" No 1
49
Considers Influence the degree of jolydispersion
in compounds of high molecular weight has on
average molecular weight, which In determined by
various chemical and physicochealoal methods.
2TA

UM/Chaidetry - Molecular Weights Jan/yeb 491:
f A
e
C
ti
l
l
(C
tdi
a
on o
v
on
a
cu
rap
Tatroduces cothod of theoretical determination of
average molecular veight.~ correctness of which Is
...
I
0
.
confirmed by larestlipUng synthetic uUtures of.
polyesters. Introduce@ concept of a coefficient
PqWispersion'# by which the product my be do-
teralned. Shows gr_eWc method of expressing the
a*efficient of polydispersion. Considers possibility 43
of using this method to evaluate the, machanisa of
reaction. Submitted ~O Nor 47.

2TAM2
- -P C1%

XORSF,a, V. V. FA 56[49T18
CheldBtX7 Polymerization'
"HIO-Molequi~r Compourds.. xx., Effoot of the Number
and Nature 6f.the Substitutes M the Polymerization
Capaoity ok BlibstitutetEthyler'W's)" V. V. Korebak,
Inat of Org Chem, Acacl Sci. MR.. pp
"1z Ak Fauk SSSRJP 'Otdol. Kh1m Nauk" No 3
Shows tbat'.sizeand.n=ber of substitutes determine
the stage of~& screening effect, by which these
substitutes Influence polymerization capacitya
Suggests a diagram exp3alrilng~ the. diierization of
i, 1-dipher~vuthyiene. Submittea. 2o s4p 48.
56/49nL

Atting, th- coliz, itlan.,of
-f0 ':..,to
si-

USM/aNnistry - High-Holecialar Sep/Oct - kq
Compounds
Polymerization
"Field of Higb-Molecular Compounds: EXTI. Effect
of the, Polarity of Substituents on the Polymeriza-
tion, Ability of Substituted Etb~,16nes," V. V.
Korshak, Inst of Org. Chem, Acad Sci Usm, 542 Pp
"Ts.Ak Nauk SSSR, 9tdel KhIx xa%W No 5
~'Experlments showed. that polymerization capacity Of .
stabstituted etbylenei.'is: increased as a result of
polarization of the double bond under influence of
.the, substituent and that polymerization tendency of
I , -- -.149T16
UM/Chemista7 - High-Molecular Sep/Oct 49
Compounds (Contd)
monosubstituted etbylenes is connected. *ith polarity
of substitutents. Establishes conn ction between
dipole moments of vinyl compounds and their ten
to polywrize,.and explains regular str=ture of
1?olyvi:6yl derivatives as-result of polarization
effect of substituents. Intr6duction of' polar
substituents attached to'carbon of a carbonyl group
decreasei tendency of compound to polymerize. Shows
po3jfmerization tenden of c
CY yclic aminex and ethers
,to, be dependent on polarity of bonds of beteroatan.
Submitted 20 Nov 4T.
~4

38013. KORSHAK, V. V., FIE-YUM, R. KII., AIM UBACHNIK, 1. 1.
AM)YEMIK ALYEEKSAIIDR NIKOLAY-EVICH NM-.%IYFYAIIOV 4N31-11K K 50-LIMTEU SO D,
ROZHDYl',N1--rZ7 IVY-ESTIYA AKA-T). NAUK SSSR, OTD-NIYE ]GIR11. IIIJAUK, 1949,
NO. 6, S. 562-66 S Portr.

e -A W;-, -4,
L9U~
14~
A2
Zr, U 6r` ''t a, -Beuzebe'""I'
VM
-j~~j3keiya- -A !Ao `Aad;e*3*V&
.%3hbV.'Ixwn Dl* 1. ~n
I
mg
i~aotion iu 'the prooaxwe ot,
ii"ii `AU-Ado" jlo~i of
polTnw ar xo4n
0 are
77- -777..
qtitliteA f
cbe r at t,-,,
p
NO!`

t
Z,

AA:

va
S. Wikov, V. V. and G. IT. Chelnokova
"Tnvostigat-4ons ix. -Bile Field of Yli~hrrolecu~lar Cormotmds. 25t','1 rePort: The
Mechanism of the Reaction of Idnea--,, Po2ycondensetion." Jounial of Gencral
Cher-m-stri, 2.0, (81) 2109-17, Have.,;ber 1949. lnstijtl~klc for Orzanic Chcm,~xtnj
o-f the AcaderV of Sciences, USSR.
ARSTILkCT AVAILABIL
D-5005LP

hk 2:.~~-,149!1-7
UUM/CbeidatX7 w X160-000 Jan 49
Chemistry Esterification
,'The Problem of Reaction Kivetics in rolyeateri-
~floatlonlll S. R. PaMov) V. V Irorshak- 4 pp
"Dok Ak Nauk SSSR" Vol IXW, No 2
Investigatee'reaction kinetics of polyeaterl-
.fication for the case of Interaction of adipic
acid vith decamthyleneglycol and.ethyloneglycol.
Conoludes that reaction peed.of polyesterifica-
-.,tlon vill dependInot uponobain's length, but
upon
concentration of free groups capable of re-
Action., Submitted 7 Oct 48.
Arm :~25/49W

_m4swo vt.--v,
USSR/Chemistry - Asidesj, Formatiou
Chomistr.r-- Hydrolywis
Jau 49
"The Kinetics of Amid Formation and Hydrolysis'00 G. N. Chelnokova, S. R. Rafikovt
V. V. Korshak, 3-,pp
NDok Ak Nauk SSSR*. Vol LXIV, No
Kinotic study of the reaction of'sebscie acid vith hexamethylenedismine under vary1mg
conditions (tempmture and catalysis3e, Submitted 8 Oct 48
PA 27/49T7

Fab 45
MSS/ChemLs~Ty -,XoleculgLr Woi*Lts
Variations Of
Chemistry Cellulose, Hydrolysis of
*Variations in the Molecular Weight of Compounds
With a HighAolecular Weight In theL Process of
Chemical Destruction," V. V. XDrshak, last Org Chm,
Acad Sol USSR.$ 4 pp
wDok.Ak Nauk SSM" Vol LX1V, No 4
Attempts to make Freudenberg and Lahn's theory
applicable.to the first stages of the destructire
prooess. This- theory stems from. representations
infinitely long chains of the parent substance,
27/49T12
UM/Chemistry Molecular Weights, Feb 49
Varlationi of (Coatd)
and vas successfully applied in the case of complet
deitruction of cellulose as'e. result of hydrolysis.
Satmitted 9 Sep 48.

0 0 0 0 0 0 9-4 so 94 0 0 0 * 0 'e'.

t 0 0
WU
'0 -1--ji A-A-
to

_
A 1~
_O fM Oll"It

dio

00
00-t
402
Oe 0
O'j
0OR "Wmakwulw-WIDIAt CAMPMS&. XXIV. (1).
C- old 111--twe of t3wn Grmth in ralyrON&S.

' 0-1- R-d- XXV1. (1). Omw prmiWly of She
now
00 ad cbmkw DwiSawatf.4 at Hwmwrm.
-000
IW-W#Wk COMPOWN& (fit filmishim) V. V. Nt"ItAk.
Izoediflior AWeriN N&A SSNR (Hulklin III flit- Avail-
I
f S
f goo
colly o
c4cricm o
Situ W
N"). Sedhicl lot Chemical 4114
lk*mcis, Jan.-Feb. IWW. p. 47-M. PwO
VIM article prtsents mirld dixymn resolis of Investf.
mation of Igpic-st types of a1mve mdlonz. fit tile 'row
.1ficivot of
odic She rWAmn of rhange of ax
'
nit
l
i
ti
l
la
i
h
f
I
t
on lux ino
.
n
a
ecu
r we
po
t o
f
y
t pu
g
)
nien durin !?f
clIcnaml disinleffullon h st ell. Ex.
-1
perlonentall data at* tabulated and chaned
24 rt

.
.

Ail a. S L A 11117441,1,41161CAL LITNiAlLOC C"SWICATION
i
1111411M "NAM.
t
0
0,
41111t 4WIF All
411 ; a, rr g, 41 17rT%U AA I 1 11 IM a it IIw~m0a 4

: 6
.0
*'*z
06940041110
*0*06
OOOOO
*
0 604
004*01 '
1
'
.
.
000000
::

All 41'l,
A A A w 14 4 or At-*-a oil
_JL_JL_A_A_.L_A
top
v
046
Go"Qf"% 01
pe"Clists &M

go=

Odd Kbiic NisAt, RM. p.51 5;
111011, 41. 165. lit 146 tllktlla~al ~lkl,lv
W lite l1tKIA416st hiji-jowlet-sUl
.'llnialm-ws file wilth.)

whaall of dirgIA-Ima JAVIILS 441,14NI. Ile ill-)

I
w.l. 1C.1114 4.1 tleglit,('06oll the
Itialwo-mAktulat l"'ItWil. dic Alleted qu A K(ratrg
3siA

C-n!

S
age
see
woo
-Jaw
too
4 ;ww I j Irb a A to Iwo a
AV As
. : 6 Ole 0 0 000,19 0 0 in 0 0 0 0 O.e 4
0
0000;090000ced 0 0 WOO 0 0 0 0-0 0 0-0 0 0 0 0 0 * 0 0 0 0 614 4

mochambuataolprwdoi.crattateactim, x 90-ch-
GRIM Of Ow C1111101YINIS Welkin of Aluminum chloride, V,
V. Konha-MMA N. N. Lebedev (hiendclecir Chetil.-Tecli.
OICUIP). ZANY. 001AICAPF Xhim. (J. Gen.'
Chem.) 20. 3001-700M); cf. C.A. 44. 3470&.-7'hc
catalytic: action of AlCla and rckstell Friedel-Crefill reac.
tion Cotalysts is explained by theyresenre of a powerful
111 0 1" the C&Wyst, especially when the twinned mot.
AV'. is conskinkild. which is given the higbly dipolar
0
AICI#.A?CI4 structure. and Inducei sirring 14"filAtil"I ill
kite rearlant mois. This k 1whevrd 10 I-C the imINXIAIII
the WUAI All'011116tiC-t"'al" ca"YWI 1'Y thr tuctal
of this I The atim If OF"Etto is 5'm'tu-
tiou between pos. 0 ond ties- 11
Was due to dixi-'Z G. M. Kobotapoll
allow.

H4ft-makifiths, v bt compounds. XXVI. Poillymird-
too"* yli*dWlomwmwwpnword"oi 1.2-diffoodoelmne,
k! Job -1
V. V. tor4mle. X. K. Saniplovskayn, And N. M. I
Zkor. MkIld Gen. Chorm.) 20. :Xv'0-401N'A' 1:
4-1. C.A. 46.7217s., 43.1513t.-C.11, pasm) raphily throllith
ton absuWkin trs)n cuall. .100 g. lWhie with 1.14 fill. ?A)"'
Ittoli and Irrafflostetl with a 1010-or. bull? was vadually,
trandarvilled late (Wilh. yellow mordles, which, after
washing with aq. K I and drying, in. 7V' (yielif ZP-W 11. 1.
(CRiDs (140 If.) and 40 g. N&011 In U1 I nil. litiLoll heated
' flatestra bath pore 10.412 1. gas ciontg. 877170 Ctif4, far, ated
Cliff. CdW W.kif -f 11.6 9. (ClItih with 40 m1-
0.8"1 KI in WOW Naloso 0.5111. (rkl%) C.U... Its F101VO."'.
is oblidned: in KIM save 19,7-46.27,.. Show
off 179 tord, 3 S MONA in KIM fit 0.0 jr~ (Cliff,,
save 14.6 1. jasconts. 111.6% Cliff, and
It. M* It if the faller (0.7 S.) with LA Jill. 0.1 '16,
JA at Initiated time) CAUWd P1311Y11117firIttilin fit I
L sol. In risrolol stiff tivitillowd. ifs (CiI,CI 4
itArk corumbly M
or (CI(s][10s. Resting IN) X. (01114rh with 1311 N. R(M.
2W ml. 160. and NAI nd. Molf to W-5, (finally to -$0 "' I
pvrd3%Cff3;CI1Rr,b.Id1. This let staff.[ 7-1(1
jdaYs with 0.002 B. HzA. gave 2-2.5 a. solid polymer-, after
12 namthe a 10WV. ykM in fiblainedl the er.is a coffor.
Ito crumbly solid. decorrip. 120 , Wflyrr(Cifillf). 21.
'PhCl 1, cold ditizane 0.05, hot dimiane 0.4. (Cificill ".15,
PhCI1qCI 0.2. Sthr 0.3%. jxxxty wil. in C.S; anti PhSO1.
Itlad. Its H1011'IRtO (if hievoco. l"ling 3 a. .polymer
With 10 g. 9019 in .174 ml. ditoxatift lot loop. g;&vc2K. Ity-
dfollyds product coliffill. 6.3% Or. The cuttloor of the pmor
pill torfiralloom of C1111XIII is the litorr.1tion 14 Wine.
WhAlactsus an Inbiltilow. food preventivefo, wich as fine AK
off lil?$. weft juirfleffive. 4.. Nt' Kowbix.11

1116-milliscular voitl& camposommide XXV111. Aelitsia of,
hYdricoolid acid an sithyleflool at Cal "d Ills immilyeak", V. lo',
A NvWva i1rad, S-I, hloilowl.
Wri. Kholsol, 'Vostak low.
,11.11 .144, 72M.-Hoilius 10 4. (CIIiOII)s with
.1. 1 j:1 25-7") frave 0.5 1. from, khruilfwd as Cilia i
le rV'kh I liquid gave
MISAIJ still. It( plainly
%table (C I I I I )I, ill - x V; till lit I was liclorvicil (Cf. 611111 mooll
lkwitisch. C.A. 3, 1711). llcimv, lite froadiou ljtxxvvds by_
funnAlion of JCIllDI volikis decamp. Into I and Calls, and
floor Marl delli. 1.614 with xlycol. Attempted um of the
Invitiod for file detil. tit F10,1ruollmo fiors Imillat ilia tiolyelle"
opt glycol with dii-mboxylic a .lit -.till Lilly lailord anti pvto
risalior moseL;.. V"frottly. thr Imilr"ters were hydrolorisrol
fly 111, farlosillog jC111,I), which thra doconifid. as allarvor.
XXIX. Polyloydraccosses. V. V. Kanihak and H. A.
N.%*HCs1i.), (1) with dit-arbanyl COMINIS. gave jsoooofj~xowors.
A closer study tit the reaction with Act showed that excess-
,,I the toolto,jr limi-ml till- isiol. wt. of the resulihis lVal "it .
11,11swiltir 1114.0 1.) ill L~l .11111 Mr, I ICI anti IIN, till It I'(
Ills). t"jk,l it) *) 411". for IrWwnys U) 1. k,., followed 1)'Y
23 till, cooled. lICI dikl. unh 23 nil. 11,0, cuolell Ill -10', 1
"not Jumtiotcd rapidly toy 70 not. wl;'~ 'NAN(so (the fillip.
ollay low 1.0 12'1 grov...1 m-.411Y ..b$ , olli'lls. .4 till,
.11dolildt.. Milli. fit 1'.NI 0 Sit'l, fil All list 1111 46-
1.1111V okifillor I of-stre a 1'.8k I Ual 111111, 11 1"I Ill I. Whkh
ttm toluplutr'l fly J hil. m1'1 mr.1111 1XIIII; 411hi. "till 11,11,
locating. will coaling gave 1110 Wt, which fornis I
ilar vvry tradily. Ah.-tilatiorr ro-ohirlitt"! the 'Romimor
iMolls. 11 1.) a ".11"d "I'I' 'tit' 'I'll' of M) SL S;A,%;A h;
thin. with olnell list), heallialf. Irraillivill With ZISLAvOll.
fillialitin, c-N,hild, alul a-hin #if IICI. clove 4?1"~ 1110 iilit,
YellOW-IT11 Mllkl Wilkit A-ViUld floor bor ttvrystd. Alth,migh I
(Vatknoirs with aldthydes in various solvents, the following
was the twat prorrolute: I a. Cf [.Act and 2.14 a. I In 1.11 till.
AcOl I Mitred ' litc till it %train loath anti dild. javo, to IS x.
Most'. solid, 'Is. 3MA11% moll. vot, It-mm-opi, lit 1-11.)XV8.
floy vi-,isaly) .502%). 1,, shisiLisly gave low jodyk
IsItasomo,
Ill ullat"I"I yiVW. "llepw 111411. wt. fits doolli4lir) 1.611forst ("a"
:MV to 1-145 when the anti. of Act w4s raised train 0% ex-
cem to 50' ~ excess over theory: the product (lid not melt.
P-Calli(CHO)t. fn. 124)4' 0:%,ftoin p-Cilh(COLI), by
heating with fill in xyletir in t a train of 11 at Mll% the
chloride, tit. `o, -11'. it. LVA 41:1*. %%ill% ablAill"I Ill Wt,!; vir6l
~1( braling [hr atrill with Mli-INNJ, 0 lit*.. followed by 12
I Its. sidnifillig). Will, I Jim, gave is how vield of p,4yAWjr#jjltxooj
md, wt, Oll lik'sLine)

CA
Now cl UpAst Yconclausation to4ction (tans
'IT Itatim, V, V. Kutruwk skild kole'ttililiv (AvmI.
S. . Mud. Vauk S.S.S.K. 70.
,12A 7(1"11 ; 1* C*A,,11.34M*-IIMinlI (PhOlil, -ill,
A10, In a 'IrY Cil, 1.110PAM it) 14111" Atilt 1411* utsist (:.I(.
"ohokm xnvt. aftel "3411olf ovill illow. ist-14
Oil, mur"40 litairti4l. She lo't Illri"K
r1hyl." Le. 11I)IJAIrsitlY it filleat IN4111", "ill,
unit* and M chaill U1111111AIllms-; 11M
01.11 1.11 Inito. With 161CO11 Irt"n C#114 ;J1111 Ilml .1 111411. 'A I
4XIN'41, 4Mi whm sms.tv as 11101' twAM01 12m) if m-fr o
111l'. It* it 6141im "W) cr mizir Save let rphl ImIsem-1.1 ~
Tho Illoxhirl Iscatell Willi 1311101 C.H. 'Imills the Ir'I'lim,
nis,fcrgtw*

-------- ____
IUNOV, V.I., doktor tekhnicheakikh nauk; X9UJA",.j,,_,._Aoktor khWche-
skikh nauk. otvatstveunn rodaktor; KOROBITSYNA __T.K. redaktor
izdatelletva; KISELITA,A.A., tekhnicheskiy reds~tor 0
Nscrionolecules] Molskuly-giganty. Koskya, Izd-vo Akademil nauk..
sssR, 1951. 116 p. (" 9: 11)
(High molecular weight-compounds)

Ifigh-Illolliscular-witiol Compounds. XXXV, Role Of
Al"llsollyals In pollygoerificathiss. V. V. Km%L111. Ind V
Virsoitraduva Wall. Sci. U-S-'v7K--.AtW"W) I-vest.
Atad. Ask S.S.S.M., visiel. Kkim. Vamk 1051, 11.1-9; ft.
C.A. 43, 7=k-'nse Itinelies of the silcisholysj!t of lit
'Imirate M by cetyl ak-. (111, CvIfmC(,1,Fj + C1,1111011 - -
C014.420!C141fla + HIM. ilk inveitilt.tird it~ a Illotlet ,f tile
Ovilhillytit. 'kiliv reaction :i'mutled to accolullany thilyuml
dvil"tioll alld. Illong "ith olvidoljr~l% 111.1 "fer evelung'.. I'l
brimak tile powth of the Mycandens.Wimi rhalu Thv
I Ilowed by e-tills. (it the 1-1011
,:ingress (if tile reaction WAS fol
wined with Ill() anti its oxidation %ith K,Cr,O, to AcOll
With equinsul. aints.offand Uatillconcd. Ji.SO#(I%n( tile
iii, of ll)ima Catalyst. flie--nd-order rate consm at 1=1. IM.
,m) 183, were: for The forward friartion, I)AIll, o'siml. A1141
1.31[k), atilt for Ilse Imck reactitio, 1.315, 1 3XV), 41111 O.&M K.'
far.; the r
.7111i1. mists. - 2JM. 1.1410. and 0193. Willi
C1.16.0N, 193and250%
#hc 2hid-order r4fe cominew., fur the fwn-Ard reaction. are
-)A-N and OAMS, and &W it* Imck traction, 0,427 unit
br.: the equo. consts.. .1. 114P and 11 U41, Without
at 2AW. flit t Coll d %.!
11.11019); vquil. mi-I. 3ANI. ActivAtioll Ctlrrxiv-. in the
temp. range% aff-I fits-IM" with
for the forward reictimi. 1011) 1571. and t:A,
for the Nick reaction, -1139, rg;, atilt -10,3.,0) CAL:
%ith CiolluONa. in tile scroll. range lKi-I.-Ar, forwara
27,011, lmckrtwtkm -1175cul. With Ml'.thv~
,olivrrokill mitalt:4 01.67o, with ci.11"O.Va. at '21.501.
los.l$%; wit buill Catalyst, at -2150', M.3%, AlcoUrNi,lim-
:Iotshlrdly $)Jay% It 11(milexiisible role ill tile I'MyconliMatiall
if glycols Willi dicitillittylic delds. N. Thon

- - - - ----
V. V. Korshak and S. Vo Vinogradovaq High molecular compounda. 36. The importance
of acidolysis in the reaction of polyesterification. P. 179.
Inst. of Organic Chem.
Acad. of Sci.,, USSR.
March 20, 19500
SO: Bulletin of the Acad. of Sciencess Izvestia, (USSR) Section on Chemical Sciences,,
No. 2. (March-April 1951).

-1nv1L R40 40 OW 0 "at" be! a Mm In
tm . 4 r V-V~"A1'-*"d '-4- V-
'I- ' 1 -0 - "gC Aead. 14-1 If 1414H,
Vint lovit (ifto.
1. 1.9. AU' W,1. Khm
.V.l&,k 1951. M11-8, cf. CA. 45. 1075C.-Thm rate of the
Ntearatr) + AvOC,.It.
(crtyll - (111fac(W1411" f- AcORto was itivrootigAtnt toy
ritin III AcUfft "ith 140. With ctininvil ainfor. ut the
""trrs. And with 11.140. (1% u(the wt. of the bt"rate) A,
-; citalymot, Ow amts. #A ALiM fartned wvrr: at 121'.
lit 1. -1. 4, 0 Ws.. 18.3. 21,2. M.4, 30.7%. at lt*%4-9*. in
1. 2, 3. 4. 5, 6 hm, 21.7. W.9. 32.4. 40.0. 48 7 48 77, - -
at III A", In 1, 2A 4, 5 Ism. WA, 41.0, 51 A, riilh, 51 -5~r' .
At 21W', In 1. 2 hm.. 32.1.38 2%; after 2 hrs. at 2M)". Ific
tv"Utfun Iftlat. undrewcut dect"Illin. Withi"It VAIMYNI,
At IK;-4*. In 1. 3. 3, 6 hroo., it. 10.3. 13.4, 13AII, at "Wt*
in 1, .1 ,3 4 0 ht% 4 7 11-5. 13.8, 14.0, i-itt~
4AU11 (R4tIW t4tl~'teardfch its araidivit. ut IM3.
I.. In 3. 4. 3 hfc. 7.0. 11).4. 13.0, 1&7,23.3%. T1w
"Iltil. C-Aw. K, and thor fair Coolants. 8. and k$ of the A.-
it Aid And tbL tMickward rVaccitta, calvd. fitieft thew dala. air:
itith " a CNWYM#. at 1831. N - O.Or. ki 0.2M.
k, - O.:MS: at 11111". JAW, 0.273. 0,330; at 122 3.1u).
0),=, 0,90', WIIhOUt VAIUIySt. at 250'. -0.6m, u,m),
at IK11 41 (NO 0,0511, 2.0W. The activaticirt cn-
~fjimsj.r thett"arti total bAckward rructitins. with HIM. lit
Ifte rouse IM-183". 130V And - 14125 cal.irta)k;
14) And -W: 122 -184". 1111 and - 1410; vittutut caulysit,
IKI-:YAI', W5 and -1030 val,luatte, Ebter exchange Te.
At 14mis play it tmak rule inp,4y"icrideAticou proccon.
N. Thnn

,~ f
,
,O_
/1717 Li.

I
: 4
j
I
-1
,e.
(L9
,~j
.1~4

84"malmolar "mapeak, XL. we me.
Ismst. Wd. Auli S.S.S.R.,
~ak 19111,M-6; Cj, 46 of Colts with CKCII.har accordint to am
CHA lift.,
chain Or6" Of JKNIVMM Y a "destructive" mami.1 am Vatsitnink" (C-4,33,3101111) pre but QiMmot ,
Pronounced In mubstameet MO mal. we. Awmamitte ths. the reaction tun as outlined above gave "it, bo IM-Al
Necessity lar I took of such a substance I'll ho of a Warto-Fittift Ndctkm with 13A 1. NA duot ISO with
W the pollraw It Is ("Any Mo that b AU4131.4 1. PhOr cove 23
0.01:t:Wj~ ~;U4, -pi 1 .49 4050"ed an
CHIC111011h M 6.) treated at 00 th 3m,jr.
strueuve" mmiTrw &xats. to 0.0010 mcle of this ON Par,, Then let stand overolshf. Per "%
per MOLI o(M) PW Conte. 10 units. and only 0.03 m* per how. h. 190-40. Wurta-Fittle reaction of this with
took at 0 tilt polymser. The location of the cleavage 4 PhDr gave MW4% I "i0mythisne, m. 51-2'. b.-4 123-
1n respect to the t". *C of the resulting frarmnis Is dW t" dkrO derim (0.11 oak) vreft.
CM-4 briefly; cleft'ram new the Mal. crater PFWUM 2 55' (crude). The i
"mall fraipments relatively 7ftobta"I", to further cleavaer. ke" I0 min. at 1300. then [ruled with I ii. MCI~ sad sub-
wb&- a ckav*xc near a chain end produces I IvP f I *t*d to a streant of pun N the YWAtfle bydtamboa# bAW -
irner.. collerletl ove. a bAr. expti. period. P14018. rwilme,
whome fismimability Is newly thAt of the Initial = MCIIA, MCHACIII, (ACUSCHOL A" IA-wt"m--
XU- Almholysla ad pollosom. V. V. Korsbak and S. V. undergo the tMistylallom rew.
viamwedova. lki4 756-M.-In the alcabolysix of poly. t . I leld Mg. resp.: 6. 1. 8.5, I.S. I.G. and 7.2 it. CJf*:
wbacaw by cvtyl adc. at IW* the dr4m or 0. 0, 12, 7.6. I.8. and 11.7 x. jklartins material; 6.73, 7.0.
chain ad"i" is directly plopm lonal to the CIWAU. C4 C*tyl 7.0. 5.1. 2.2. mad 13ilri, [furor polyfaer (wA.): and 2.33,
sk. The lompr chains an cleaved first (cf. promflas 0.1, 0.3. 0. and 0 1. Irmusional pogyratt. Tim vaection
Because otreveMbIlityal tbervactim. not all the
Is visuallsed as taking place at artba am pm PoOdaus of
M111 &k. is utilized, XLU. Trammar7latism mada d the arormatic dogs with fm~tlm of the cinved supbAtk
a. 0. & Kolesmikor mad V. V. Kardink
P. 1. CU&Wv ClsensAtchmol. ltt$t,, MOKOW) 441.1 The I&A substance pvt 6.6 C. tetrmhydrmftph~-
!RW polar f. (PbCHs), 6
L
.61-70.-Mdo. of 100 C. ftCllCl to 40D tal., CA The Pal
Cir
r.
if
'r
Is
A&I 4 M" at redsm ethyl, wkik Ph)j yields jrphruY=WWYZ
Cre "WhiCH
shown by oxida6m. G. M. KOWINVON
40 A1.11M yields " pr bm. to 130
C,
.C
pj (P Cit.).. N-6
I 11114i~. 71-2 (f. MOM, I-Cndts reaction

_:~.Xjr
'OrPAIX '__ V 0- Vc
USSR/Chemistry High-Molecular Compounds
Nov/De c !11
ItHigh-Molecular Compounds. IXIJI. Rearylation of Diarylalkylenes," G. S. Kolesnikov,
V. V. Korshak., Inst Org Chem, Acad Sci USSR, Moscow Chimicotechnol Inst imerd
D. I. Mendeleyev
"Iz Ak Nauk SSSR, Otdel Khim. Nauk" -No.6y PP 761-770
Polycondensation of 1,2-diphenylethane in the presmce of AICI~ into polyphenyleneethyl,
as described previously by the authors, is based on a rearylation (benzene is
liberated). In this instance, established that dipherVlmethane., 1,1-diphet*lethana,
1,3-diphenylpropahe (I) lj4-diphenylbutane (II)) and 1)2-di-(beta-tetralyl)-ethane
also undergo rearylation. Found that with I and II, there is cyclic condensation under
formation of hydeindene and tetralin inaddition to polycondensation. With II,
cyclization predominates. In the reary3ation of 10-diphenylpro-,;ane, polypherVlenepropyl
is formed.
PA 197T12

C*MP"n4N 41 blo MW~Cwdr w0fillit. XXX. Synthesis
of G. S. Kole'llikov. V. V.
KwAink. and 1. 11. Krukovilaya (1). 1. hirtideletv
brit., Moscow% Aar. ObAkel Kirin). (j, Grit.
Chent.) 21.31IT-40IJ IRAI); cf. VA. 45. M-01.
( INI a.) to '.lit) a, NaOll, 41111 tul, JIM. alul 4111 lid. 1`1011
'it Out 70* it Irral"I with 110 X. CIICI,; 111" lite li'l
"dor dryclop.. the Hitill on and 1"Itt t-do-A "...I
,tvidilied with 1110. extil. With FIAW YO.I. " .2%,
J-waphAiWk)*. b-I 185-7'. in. 7*-I*P' (ftion littffl I
This (16 g.) lit added to SU tril, 2% KOII at the b.p. ind
treated with III S. Mem, Over " min. with the tilixt,
kept alk. at all times; filtration after coolf . lit W"'
etude, to. P44 intinn"In'.1411to:
I hille,:tarting nuAteriAl may lie recovered front the soln.
Me In turt (4 X.) wid"I to %tC%Iltt (froin lit R. Mell its
L1.5 itil. HIA) atid 15 tril. dry Wit and heuird 30-40 Inin.
vicl& after the usual tretatment 8U.670 (,~-Mdhoxy-l-
x4pklkvI)mrthy?,ra?bix,,I. m. 724' (from Utto. then from
I-eir. ether). Dehydration by heating with air open ILine
lit the I)re%cncd of KIIS04 and a little hydro,juinotte virlds
1, tidsly of softening
,.Ixnjt I 10-a". with polymeffiration oage, 414. Dehydration
under reduced pressure (20 mni.) Sives a siroilar polyiner.
~oftcikinll at 104". its. 1541. IICIICC. tile UOUP does
riot stefivAlly hinder the activity of tire vinyl gratip.
0. 'it. N."AIIA1.111

- KC'iRSHAK, V - V. - - -- -
"Chemistry of Highly Molecular Compounds," Kommunint., No. 62, 16 March 1951,
Yerevan.
Lab. of Organic Chemistry of the Academy of Sciences of USSR.
Abstract - Report go. 112887

19411); tf. CA, 44, 41VAti-Titwnwei 'Ilf Phr
Cil Mime. Phat'Cli'm. Pb(ClIalli'll. Phicll!)Xh.
jtd l~"-bWtetnbydn)-2-it2phthyl)tihane with AICIs yitl,
16. . the comspmding elementary ammitic
~
bon, mid a polyawvk twoduct (linear or incll~ trid-11-
sionji). The insol, tridimensional polynwr* iplvAr to Yr-
be ortho t-tti-ms of Ph
rings in a linew polymer. (PI&CIII), Y"I.. as I.Ayintfic
pr(Auct, polypbrnylvarfithyl (C.A. 42. Z.174,), lwovell by
osklatkiis to CIIIAC(hI16- Tht. poly"Iff freAn Ph.
s of as thimo
(CIIAPh cous r.,
bY cliddatim to P-QUICWth and P-C.114CH.CW14.
long with this linear product there is inifiration of rinit
=flon mid chaNendsax Indan was atio i4olated. With
Ph(CHs)^ the cyclintion is tIrtdOttlitlAtIt alld OR' t1l.lin
litoduct is tefrehydroosphthalefte 411d C41I.: else rral-11,111
leing rrv"Me, 5.9-8.4% yielth o( llh(CII,)41'h air Ml-
tilineff from tetrallydronaphthalcue anti AlCI,. The iw-;.-
Silbfir mode oif fonnation tA O,Ifklitnetfiyi-fi,iNiihycfri).in-
thruccur from PbCIINft and of unthract-or from fllj,Clfr
lit the liftstace of AlCle may be: rtuction of'21 inoli. of the
4111noatle cmild., yielding o- land p-con-leimition ditistr%:
file ti-Im"Cir felAilycYclif" with elffillmAtion of C4114. %hitt:
the Im-Iminver mity be Win"lited Into the ~ivjmrr to i air y
tile cycliAution reaction to high yirtdik. U. NI - W.