SCIENTIFIC ABSTRACT KISELEV, A.V. - KISELEV, A.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000722730012-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 96
• Document Creation Date: November 2, 2016
• Document Release Date: June 14, 2000
• Sequence Number: 12
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

47304-65
ACCESSIMI NRr AT5007921 DI
with a packing discharger of 100 kilovolts, and work stopped on the variant with
avorago rl~ngs. Or!lgfnally It was proposed to set up two devices: VEP
Nov energy, and VEP-2 of 2 x 500 Nov energy. The VEP-1 was considered ;Is Omf a2clt!s'lo
model of an accelerator and as,a device for conducting initial experiments at low
'energies.' After the Panofsky report In 1950 on his 'work with colliding electron
eams conducted in his laboratory at Stanfoo, construction coasod on 500:44ev
storage paths and work was continued on the 2 x 130-Mov installation. Instead of,
mork on colliding electron beams with ene.rgies of 500 Nov, work at the-and of 1958
'was conducted with colliding positro -electron beamq and the planning of the-VEPP-2.
!device was begun, whose main elements are a strong-current electron accelerator-and,
1. high-va.uum storage* path of 700 Nev energy. At the present time the VEP-1 and
jVEPP-2 am Installed in Novosibirsk. The VEP-1 is in a state of neglect, but alt
the end of 19611- experiments will be begun with it. Installation of the VEPP-2 has
ibeen completed. -To obtain a marked effect from the application of colliding proton.
ibeams, an accelerator, is ndeded with an energy of at least 10 Gov. Since 'the ordi-~.;
ary accolerato es in a very bulky machine, it was decided to'
n r at such onergi
!bine the idea of 'cc;314d1ng jroton beams with the creation of an iron-lese lm~uUe-,_
accelerator with very laige,fields and a neutralized central busbar.. This Utter
;work of creating such aimabins was reported by the authors at a Mos6ow: conferesson
Card 3/5

73
ACCESSION HR: AT5007921
;J
hold In 1956. The presence of a field with two directions in an IrlDn-ioss accelQrMr-
tor with central busbar permits the acceleration of protons toward opposite cides
in one machine, which makes possible the collision of protons in Fase ofa suitable
race-track. At the present time the Institute is developing a proton device with
a magnetic field of about 200 kilogauss and radius of 2 meters for a particle ene,rgy,
f 12 Ge
0 con--
v in the beam (equivalent energy Is around 30OGev). Tests are being
ducted on models, and an effective method of injection by overcharging of iegative
ions is under study. Also under development am an impulse electric. power. supply
system of 100 million joules capacity and an hf power supply. Since 1958 the
Institutebas been conducti ng theoretical investigations on the 11mita of applicabi
lity of quantum electrodynamice. CV. H. Bayyer, ZhETF, 37, 1490 (1959) 0 and UEN, 78,
619 (1962)3 for the calculation of the radiational corrections to the electrodyna
soatl' s U. H. Dayyer and S. A. Kheyfets, ZhETF 40, 613-715 (1961) and
mic.cross on
Nuclear Physics (in print)], and on other problems of high-energy particle physics..
that are, connected with the preparation of experiments 'on co-ding bpaw lv~ W.
Dayyor, 1. B., Kbriplovich, V. N. Sokolov, and V. S. Synakh, in Zhtr. 1961L The
preeent report takes. up under the mentioned three main headings the falliwiag peritl-~
si. elslitrop-optical C610611;
nent topics t tha-accaler4tor-injection, storage path
twd 4/6

KISELEV A.V.1 YASHIN, Ya.l.
Effect of the structure of silica gels on the gas-chromatographia
separation~of.bydioqarbone. Neftekhimia 4 no-31494-500 My-je 164.
(MIRA IR: 2)
1, Khilmicheskiy fakulltat Moskovskogo gosudarstvannogo universJtets.
im. Lomonosova i Opytno.-konstruktorskoye byuro avtomatiki.

3
~7 65t`_,_ PC
7
UP 0
AW4/06~4/
21MI Grw_-~ ~toi~aphio determination of tho absolute values of the i-etainablo
volumes and heats of adsoMtion of hydrocarbons on aiii i~l of various structuros
SQUIXR: Neftekhimi,
ya, v. 4, no. 1964, 634-640
TOPIC TAC-S: gas chromatography, hydrocarbon, silica, temperature, physical chsomiztry
Abstract-. The influence-of 'the geometrical structure of silica gels on the
differential heats of adaorption and absolute values of the retai.nable
volures Qf certain Gt.7j;jn_ hydpaza*rbons, (methane,jethane, ethyleneq propane,
11propyLene, butafteltl,pet'ita-ne' ftexane-, hepta-reoctal ne,,) nona ne cane)
was investigated. -17he heats of ad9orption of the CI-Clo hf(lrocarbons on
--au geLa of Vatlous por,
il L osities were
obtainet- at.Na erawrgsi-Xn~-, rt---~ ner--eii- d
ea
A
IkAi~iie or.
0'-= CK-_, 4"t .(I um, er-6 ~c 17
All~ acreas, -n&--n
__pored 's U ica gela. When
t A
or
expanded-,,' limi
e pomits were a- linear dependence oE the differentLal
1:hesta oE adsorption on the number of carbon atoms in the molecule waa astab-
lished. The difference in the heats of adsorption of oaturated and unsaturated
hydrocarbons with the same number of carbon atoms, characterizing the influ-
Card 1/2
. . . . . . . . . . . . . . . . . . . .

:,ence of "he specific interactions of tbe- pL-electron bons with the hydroryl
grc~spv of Chi! ail L& get surf ake', was found to be prattically Lndependent
of itit geometrical structure. The absolute (related Lo un!L surface) values
~,Cr L-! vetsinable volunes were'obtained for normal hydrocarbons. "The author's
t-tislak -fu. S. Nikitin for his a_Uotment of wide-pore silica gels, and A. V. Dl-fakhlova
an~ !e. ]~e_~vi_taki;f for their partjcipatlon la the oxperim
ental work. Orig.
a.:. t , hai5 4 'jiip-la -in-& 2 tables.
Corti

EI;T JVT RIM
ACC&I33-ION MR: AP5023218 UR/0190/64/CO6/011/1.962/190h
JI
AJJ TMEt Kiseley-2_ A. V.; EltekDvj_yuo A. 'Ell takovp Yu. A.) "7
'TTTLEt Naaromolecular eieves for awauating the conformation of macrowleculas
Vyeokozolekalararwa~~:o'aye~dinaniyap v* 6. no. 11, 1964� 1,962-1~~
TOPIC TAGSt macrom..')1e4=1a, vole=UL- sieve., adzorption, silicas silica.- gel., za 31t-
4 Sorptlaft behiv 6r- a i1orane
MTRACTi E'attut solutions of! polydimethyls
(L-alecular weight approximately 350,000) in n-hexane was studied on uniformly
Porotis adsorbentalitth different pore dimensions (macromolecuar sievea):
Llica ~- aerosil, wide-pored silica gel S-41, a ws3he~' irdjn~rial
silica gel ShSK, granulated aluminum oxde. and ~,C-Ietell zeoie 13X,
narrow-pored zeolite 13X and the sli.ghtly wider pored aluminum oxide
vevy little polydimethyls'.1oxane and only on the outer surface of the
11a:-_~,-:es; the wide-pored silica gels exhibited great adsorption, in spite of
lower specifte surfaces; adsorption of polydimethylaLloxane on the silica gels
and nonporous serosil was proportional to the value of t~.e surface, and the
valuej Der unit surface of the adsorbent practically coincided, The diameter
Card ;L/2

L 64543-65
ACCESSIOM UR: AP5023218
of the polydimethy'lsiloxane molecules calculated from t~a adsorption data
~'comprised approximately 100 A, coinciding with the value of 105 to 440 A,
calculated on the basis of the Flory-Fox theory and geometrical concepts. The
auzhor8 propose thaL in dilute n-hexane solutions, the 11neer macromolecules
~:-,-h 10,00-0 A) interact weakly with the !3ollvert mt lec-.~Ies and are
rather Aenqe balla, the diameter of whl.cn conyr~ a pOXLMnLeIy
A, Lz-iey inote that In the fLeld of the adsorbent, tne po*,yuimetnyIsLioxsne
macrmolecules might assume other conformations (ellipsoid), in view of which.
the dimensions determined by the adsorption method may be too low.
~.irig. axt. has: 6 fornnlas,, 1 table.
ASSOCIATTON: Institu~ fisicheakoy khimii 94 SSSR (Institute of Physical Chemistry
AN SSS~RA
amrrTED- o6jan64 ENCL: 00 SUB CODE: OC, W
I MR REF BOVt 002 GTHMt 002 JPRS

ISIRIKYAN, A.A.~ USHAKOVA, Ye.V.
Chemical modirication. of the rutile pigment surface by hexanol
and dimethyldichlorosilane. Koll.zhur. 26 no-l'-45-50 Ja-F
164. (MIRA 17:4)
1. Moskovskiy universit6t, khimicheskiy fakulltet.

%a

i~

AP%O=
TT
ma X,
VIA to
wo - a OVI& bo:
09 in tbair &=27"S0
help in mdifylng
j4 roxcu2m @ad I gJAPM4
wm~tdws3d tow,
M6 Tdr ZOMODOOTA;
AWOC=Cffs
absoWry. yaetdty
(MOOG"
my OjAd63
000
onum
oil
otm
WIN

ACCESSIM NR: AP403TI77
CHs
CIIISICHCHCO~ - 'CSl
C:FfICH--CHt: 0,SICHI
xmc~a- a~ICHCI
CHS
IThe laboratory procedure is described. The extent of substitution of surface
1hydroxyl groups by organic radicals was found at less than 50% (C determination by.i
~Iwet combustion)* The material obtained was pressed into tablets for*iafrared.
inspection. The spectra were obtained and it was concluded that ranini free
surface hydroxyl groupw participated in the modification reactionj the functional
!I ester and chlorine-contalnin groups surface radicals axe hydrogen-bonded to the
1 imemaining surface hydroxyls;.and the most heat-iosistant radicals were those vith
~i'ester and chlorine-containing groups., allyl was less heat resistant. At the law
exper;Jmental density of the modifying layerp the remaining hydroxyl groups determ
imined essentially the adsorptive properties of the modIfIed aeroallso Treatment.
vith deuterium and metbylation of. the latter's surface revealed avaLlability Of
pazn of the surface hydrovIs for n-11 molecules and another part for large mole
culesp such as dietJWI other* For gw chromatograAW denAer. layers should be
ic
3 ... .....

ACCESSION NR:' AP4043126. .'s/o,09/64/026/0~4/9~~
AUTHORS: Kiselev, A, V El, I t'e'o Boga'heva, Yee, Ke
u c
TITLE:- Effect of the'nature of the filler--surface on:the. adsorpti6n:"_.1
of polymers. Adsorption of polyneopentylphthalate~.
SOURCE: Kolloidny*y zh"4ftal, v.~26, no.- 4V 1964~ 458~-464,
'.TOPIC TAGS: adsorpt.iorii- polymer ads~orption'.filler surface property:'
adsorption kinetics, adsorption equilibrium, adsorption mechafiism'i,.,-1
hydrox'lated silica gel
porous silica~gell nonporous..silica gel y
dehydroxylated.silic~ gell,triniethylsila'ted silica gel,' alumina
ABSTRACT: The kinetic's-and*equilibrium-6t adsorption of *polyneo
Pentylphthalate (PNPP ,- M - 2000) .fromn-heptane solutions at ~20C
on adsorbents having diff erent - chemic'al nbLture and _' orosities were.-.
P.
determined: on finely porous silica gel ShSM r ''d
(mean pore diamete
404), very,wide porous~ silica gel, S 41'(d ~' 750A, sp.. surfaci 'are&
S * 41 m2/Vn) I nonporo'us-,-Ailica gel (s.- 170.m2/gm) with hydroxT-.
latedp partially dehydroiylAted.afid 700A trimethylsilated surface,', 7.1.
a - 250 m, 2/
I porous alumina,(d --! 8QA9-_ rutile (s M gm), and,~.--,-.-
[oxidized and graphitized:parbon blacks'.~, Vi~3cosity measurements, 0
f

ACCESSION NR: AP4043129
the solutions showed the low molecular weight PNPP'molecules were
mainly adsorbed in the beginning.and these were then gradually
displaced by larger macromolecules. The finely porous silica geld.
and the rutile practically did.not adsorb the polymer..' Adsorption
-the ae' sils, rutile
equilibrium was attained within 2 days with ro
and wide porous silica gel-,.but alumina and finely porous silica
gel required;several days. -Comparison of-the'adsorption of PNPP
per unit surface area of adsorbent showed very close values for the
hydroxylated surface of wide porous silica gel and adrosil$ and 1
considerable divergence from those values by mod.4iied silica surface
rutile and carbon blacks. Comparison-of the adsorption of PNPP
and polyneopentyl3u.ccinide (PNPSj Ml- 4400) on glassi 'aerosil and".
wide porous'silica gel also indicates the similarity of the ac;sorp.;-'
tion mechanism and the closeness- of the' properties of th.e adsorbents.1
The solvent significantly, affected the adsorption of the polyesters
The total weight of.PNPP, PNPS.or of polydimethylsiloxane ?DMS
iadsorbed per unit-surface of silica is close and the relative amoun
t
of PNPP and PDMS adsorbed is approximaVelf"prourtional to the rela-
tive diameter of the maoromolocules--16A cir P PP and
_7A for PDMS.
Card
__2/3

'
,AP
CESSION NR
0
12
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AC
4
43
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rThwauth6rs thank ltu
N
eA*. ikitihA, for ~Aupplying
.
and S. V. -Yakubovi h for: -sup
c plyiiig
plyriqooerkty~phthalateew

'd
rt has:
a
6 figures an 2 ~
ta

les
.
.

'ASSIIGIATIOII':"Ingtitut~'fltidh6,,k
o~~-khl:mli--*AN SSSR;Moskva
(Inetitute,pf P*sIcil- Chewist~ -AN SSSR)

SUBMITTEDt Munb3~` ENZIN

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SUB:'CODE#o,.Go
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AFSHINSkAYA, N.V.; DAVYDOV, V,Ya.; ZHURAVIEV, L.T.; KERTOYZ, Dzheffri 10
[Curthoys, Geoffrey],- KISELEV. A.V.; KUZRETSOV, B.V.; NIKITIN,
Yu.S.; RYBINA, V.V.'
Effedt of hydrothermal treatment in an autoclave on the structure
and adoorptive,properties of silica gel. Koll. zhur. 26 no-5:
529-537 S-0 164. (KTRA 17: 10)
1. Moskovskiy universitet, khimichaskiy fakulltet i Institut
fizicheskoy khimii AN SSSR.

MISELEV A V - Y021PV, G.A.,, MG.M.1 V.I.
Eloctron pa,.~tupapiotic resonance spectra of graphitized carbon
blacko. Koil. zlivir. 26 no.5t651-653 8-0 164.
(MIRA 17-10)
1. Moukavskiy universitet imeni Lomomsova,, khirrlicheskiy faku:ltet.

BEZUS, A.G.; DREVING, V.P.; KISE A.V
Energy of adsorption od ethane and ethylene on surfaces of
varying nature. Part 1. Zhur. fiz. khim. 38 no.1:59-67
Ja'64. (MIRA 17:2)
q
1. Moskovskiy gosudarstvennyy universitet, khimicheskiy fakulltet.
-; MS.
gp,

MOM
AKSH1NSKAYA, N.V.; KISELEV, A.V.; NIKITIN, YU.S,
Geometric modification of the skeleton of xerogels. Part 3.
Zhur. fiz. Mime 38 no.23488490 F 164. (141P-A 17: 8)
1. Moskovskiy gosudarstvennyy universitat imeni Lomonrsova,
khimicheskiy fakulltat.

BIIBI, R.A.; KIS&EVp A.V., KOVALEVA, N.V.; TiZoN, R.F.S.; KHOIYtS, Dzh.M.
Adsorption and state of C02,,SF6, and IIH3 on a graphitt9d
carbon surface. Zhur. fiz. khim. 38 no.j:708-718 Mr '64.
1. Khimicheskoye otdeleniye Amk-hertskogo kolledzha, SSU, i
Gruppa khimii poverkhnosti InstitiitaJizLches.Xoy WWU AN SSSR.

BEzust A*O.; VVING# VOP.; KISE1zV'_A.V. (Moscow)
~N.
i0kerfergy of ethane and ethylene on ourfaces of
T nature.--Par~ 2. Zhur. fiz. khim. 38 no.'4s947-
964e, (MIRA 176)
1. Moskovskiy gosudarstvennyy universitet kisepi M.V. Losonosova,
Khimicheskiy fakulltet,
14
M N.- M
~ rm
MR. RIM

ACCESSION 14R; AP 034593 S/0076/64/038/004/1044/lo47
AunfoAi Abiam6v., V. N.; Kiselev, A. V.; Ly*gin, V. I.
TITLE:,~ Infrared study of the adsorption of phenol, apiline and nitrobeinzene on
Acrosil and zeolite.
.SOURCE-: Zhurndl fizicheskoy khimiij, V- 38, noo' 4, 1964,, lo44-1o47
TOPIC TAGS:-.Jfifrared spectroscopy, adsorption'
phenol, aniline, nitrobenzenep
~:Aerosil, zeolite, molecular spectra
ABSTRACT: In this work a study was made of the change of the infrared ape Ictrum
of the;hydro>W1 groups on the stirface of Aeros .il, durinG the r-Isorption of phenol)
aniline and nitrobenzene, as well as the IR.spectra of these molecules themselves
upon t.1je adsorption on Aerouil-and zeolite., 'Tis. I Ghows the spectrun 6f Aeroaill)
evacuated at 400 C and the spectra after adsorption of phenol, aniline ~Lna nitro-
benzene under saturated vapor pressure.of these compounds at 25 C. N6'to the
overlal? of abs6r 0 e ass
,ption.bands f th ~ ociated,.surface and intraglobular,hydroxyl
group
q'of Aerosil 'and phenol it is difficult to establish accurately the magnitude
ishift otthe groups of Aero
of them,
oil with respect to the absorption band of free
Card
AA..

ACCESSION NR: AP11034593
hydroxy~l groups!perturbed by adsorption of phenol hydroxyl. The magnitude of
-eAhan 350 cm-1. During ad .sorption
ishift during adsorption of phenol is not mor
of aniline theband lies aroung 3200 cm-1 andAhe shift is - 550 cm-'- turing'
adsorption of nitrobenzene the band 'of perturbed free hydroxyl groups on the
i~sutfacq of Aero i1 is completely masked, Therefore, one can only say that the
Lshift ~s much less during adsof,?tion of nitrobenzene than during adsorption of
;'Pheno4pnd
aniline ( r-150 cm The:changes:of IR spectra of the adsorbed
molecules themselves are also shown in Fig. l.' The greatest changes are~observed
!:in the,yibratiokial frequency of OR in the phefi8l and NH in the aniline. ~In the
case of nitrobei~'zene no significant ch.~nses arle' observed. Changes of molecular
spectra during the adsorption on zeolite are gieater-than during the adsorption on
Aerosil. Orig.,iart. has: 1 table an& 2 figures..
ASSOCLATION: Mdskovskiy gosudarstvennyy univiirsitet im. Mj V. Lomonosovap
Khimiche'skiy fa~ulltat (Moscow State universit;~ im. M. V. Lomonosovi Chemistry
DepartzIi~nt)
SuRaTTED; 05NOv63 ENGL: 01
Card
24/4

KISEIEV A,V.; POSHRUS, D.P. [Pcskus, D.F.'; AM-MMMICHT. ,,!.Y.--
La statistical calculation of the thermodynamic propertles
Molecu' r
of inerb gases adsorbed on graphite. Zbur, fiz, Wm. 38 no.6:
1514-1522 Je '64i.~ (R2M 18:3)
1. Institut fizich~skoy khimii AN S-SSR j. histitut ldiimil -I Zhimi-
Cheskoy tekhnololali AkademU nauk UtLwskoy SSR.

DZHIGIT, MIKOS, K.N.; MTTIK, G.G.
Heat of adsorption of water vapors on zeolite of the Na-faujasite
type. Zhur. fiz. khim,- 38 no.7:1791-1796 il 164.
(MRA 18:3)
1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova, Idiimi-
cheskiy fakulltet.

4~
L ~~_6~ KwT(K)/VF(c)/&W(j)/T p0_4/?r-4 B3D/98D/AM/AKC(b)/KSD(gq)/
ACCESSION NR: AP4044446 S/0079/9410391008/204712054
/AUTHOR: Dm*dov, V. Ya.: ZhurRvlev, L. T. Kiselev, A. V.
at
TITLE, id.14 f
a of surface hydrox~Vgroup's 0
aemall and their reactionts with ahlorbilane3 tj
647 40
7
4L
W& 1; W #YRF -Va 0 ~ W__ 9 OR M PLl
QFT,~~. _4u _ft-
ABSTRAM, -F*rVw-_zqt4d-,.L f-tha, ii of the hydro3WIs: on- ihii~ -a u-ifice of
y propert es
rare 4pecix--
Inethad.1"LlLuge rmfntition d eL:Mean concwnfm,~-
trcucopic- j!j~ fitive clete,
tj0,j OV6 OH Inups Ott lia ,..SudoLce of si!Lca the deuterim axch=p method with v -in
AM
1 ca. no - ~Y_l --spad r
rb e
rx
a LiF prisno in the AGqO,-~ 2206.=27 -region. Aerosil wag pressed into pellets
c_,dI 3
141. 1 IN
W

KISEIEV, A.V.,- KOVALEVA, N.V.; MOPINA, V.V.
Adsorption of cyclohexane, benzene, toluene, and napinthalene -from
n-beptane solutions on oxidized carbon blacks and carbons treated at
high temperatures. Zhurifiz.'-khim. 38 no.8:2095-2098 Ag 164.
(MIRA 18:1)
1. Institat fizicheskoy kbirnli AN SSSR.

V. (Moscow)
ARISTOV, B.G.; KJTS~L~7,,
Efftct of the dehydroxylation of silica surfaae on the heats of adbor~-:
tion of nitrogen and argon vapors. Zhur.fiz.L~Ir. 38 no.-S-1984-198c)'
Ag 164. (MIHA 18 ;.1)
1hatitut fizicheskoy khimli VI SSSR 1 Khimicheskiy fakulftet
M:~skovakogo gosudarstvennogo uni-versueta. imen-L M.V.Lomonosova.

AVGULI, 11,;,; KISELEV, A,V.j- LYGINA, I.A. (Moseo,t"'!
Standaxd tharm-odynamiz. character is-ticz, ef i.:,-3orptlon -.-,i a homogeneous
surface and the activity coefficiarits of adsorbaLe in the adsorption
layer. Zhur.fiz.ldi" '-38 no.8:2055-2058 Ag 164.
(14M !8:1)
'St"U'It, fizicheskoy khimil AN SS-SR.

(Moscow); K(r/,LOII, A.A. (Moscow)
BEREZIL S
14 G, I. (Moscow); KI !~ ,
Calorimeter for measuriang heat capacities of disperse bodies and
adsorption systems from 120 to ';OOIK. Zhur.fiz.kbjm. Ilb nQ-.8-,2I06-
2110 Ag 164. (MIRA 18:1)
I. Institut fizicheskoy khmit AN SSSR.

KISELEV. A.V.I-NIKITIN, Yu.S.; SAVINOVA, N.K.; SAVINIOV, I.M.; YASHIN, Ya.I.
Use of macroporcus silica gels for gas chromatographic analysis
at high temperatures. Zhur. fiz. khim. 38 no.9t2328-2330 S 164.
(MIRA M12)
1. Moskovskiy gosudaratvennyy universitet imeni Lomonosovap
khimicheskiy fakulltata.

KISKLEV, A.V.; LYGIN, V.I.; TITOVA, T.I.
Specific adsorption of ammonia on silica and zoolite studied by
infrared spectroscog. Zhur.fiz.khim. 38 no.11t2730-21733 11 164.
(MIRA 18:2)
lo Moskovskiy gosudaretvannyy universitet imeni Lomonosova.,
khimicheskiy fakulltlat,

ACCESSION NR., AP5002570
4
AUTROR klibli~~ A.
0. A." W., --1w.~";.-
hydro4lated-sUict~ourfade~s~,~.- at --FA 6 void *ith'q~WtidiV
ave me e es
1/3.
card

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96
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I. 238~6--651-
ACCE=ON NR-. APNOM70.-,
khimii AN OM (P
-0 %for

MG ) V.P.;-KISEIIEV, A.1% (MOSCOW)
Isotherms and heats of adsorption of riethare on graphitized
carbon black. Zhur. fiz. khim. 38 no.12:2924-2930 D 164.
(MIRA- 18:2)
1. Kbimilcheskiy fakulltet Moskovskogo gosudarsLvennogo uni-
versiteta imeni M.V. Lomonosova.

BELYAKOVA, L.D.; KISELEV, A.V.; KOVALEVA, N.V.
Gas chromatographic determination of hydrogen bonding energy
in adsorption layers. Dokl. AN SSSR 157 no.3:646-649 J1 164.
(MIRA 170)
1. Institut fizicheskoy khimii AN SSSR. Predstavleno akademikon
A.N. Frumkinym.

lite, benzene
'fractiong 0-0. 1) -by
J
f; anes ~-and- '.Taoul~ex
at thiophefie mo!~:~ f-' _dti
Aisplaces-u- e "frofii,_
11 pt#46~
Iloted.thall desulfurizakion of liquid
40.
t'-' Udde'11.1 ~X-_zcolit6::
Rtf~res i -
ICL ~~wr:Lgures.
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ACCESSION NR: AP500608.+ 5/0204/65i005/0011014110148
AUTHOR: Kiselev, A. V.Z Chirnenkova, Yu. L.; Yashin, Yn. 1.
,-ME: Use of granulated zeoRtes tnolecular sieves) for the gas chromatograilc!
sep.ration of gases an4 hydrocarbons
t
SGURCE: Neftekhimiva,~'V..-.5,!-qp~j, .1965" 141448
TiDPIC TAGS: gas chromatography, granulated realite, molecular sieve, hydrocarbon!.!
9~!Daration, helium purffication, air fra--tionation
~r
t" B 1-7 z RA Cr-r :Experimental results are pres-2nted for the eFffc;enc-,, of granulated or
Pelieted zeolites "A, 10kh and l3kh in tic gas chromatographic Zeparation of hel.
nitrogen, orygen and Cl-C3 and higher aliphatic hydrocarbo-~q, and for the
of carrier velocityj tenipera~ure and grairi sizz- ~r-. st-;ir zeolites
~rrjm the Gor'kovskaya opyr-naya baza Vsesoyuznogo nauchno-issledovatel'skogo in-
L
stituta po pererabotka uefti (Gor'ki experiment station (if the All-uni.or petrol-
processing scientific research institute) an6 Linde ;,eollltes were deh,--"Irated
aC 450-600C h~f~~r~C~elr -vaillatlo- -I- -ollifirl The nPight
'4"';qlent theoretical plates for the separat-inn i~ o:r-.,zPr- nitrogen anr~
'ne E.nar.e was shown to decrease with grain sLze aid optLma, value5 were measured at

L 331M-~65-`--~
ACCESSION NR: AP5006084'
lineat carrier gas velocities of 2.5-7 cw/sec. Temperature did not significart1l.
affect the separatiort of-hydrocarbans- Type 13kh zeoliLa is rec-eaded for
of C1_C3 hydrocarbons at MC bqt it doeg not give well-defined peaks
hydrocarbons. The temp,-ratiirp -.Ii~rogen-~ydro-
caraion. aeparattona and Lhe various eltac:a oi zc,~iiLc wjifii
C i- .. _4
of C2 3 hydrocarbon pa! rs ciadi-ilie Utd'aehieve satisfactory separation, of auchll;-,
"Me aut'hors thank B. A. Upkind for supplying the studied zeolites
end L-V. Y~_ I
nkhLova for her az~istanc~e im the expertmental atudies." Orig. art.
has: 3 tables,. 5 figurep and 2 formulas.
;7:
"so a a OU 6dw
em
m1ttee)
ENUL- 00 SUR 00DEt GGw, UP
NO REF SM- 010
030
Card 2/Z

EV
XMIZVO LYGINAj I*A.
Potential energY of NOt Aro Xr, Xe, and GH4 orystal lattloaso lave
AN SUR, Ser. khim. no.7d.1434.151 165s (MIRA 18M
1, Institut ftsiaheskoy khiaii AN SSSR.

ARISTOV, B.G.; KISELEV, A.V.
Absolute values of nitrogen and argon vapor a0sorption on
hydroiylated and dehydroxylated nonporous and wide-porous
silica surfaces. Koll.zhur. 27 no.3:299-306 My-Je 165.
()URA 18:12)
1. Institut fizicheskoy khimii AN SSSR i Moskovskiy
gosudarstvennyy universitet, khimicheskiy fakul'tette
Submitted Jan- 4., 1964.

-UR/0069/651027/003103U/0325'
541 i 101
Kiwlev, A. V.,, Korolev, A. Ya.-,,I.Xgini,

H_ "0.
~NH2 rVOIJ S~-.are
A
~qn W. _____.Z,p
"d;% b6nds on
Ck - and CH- up.s.;-'The,.. ----t obbla
3,gro. linodified'film qurfa~m~
-hyaheating-A x -304RC-~- -has: _1--,table.~and-
destroyed a.~. aciiixi.. tbLr:
J_

KISELEV. A.V,; NIKITIN, Yu.S.; PETROVA, R.S.; FAM NGOK TEHAN'
Study of magnesium oxide surface by adsorption and gas chromato-
graphy methods. Koll.zhur..27 no.3.,368-373 MY-Je '65.
(MIRA 18:12)
1, Moskovokiy universitet imeni Lomonosovav khimicheskiy fakull-
tet. Submitted Oct. 292 1963.

magma
KISELRV,- A.V.,-. SHIKALOVA, I.V.
Adsorption of large-size, molecules from solutions on carriers,,
,fillerep and pigmentie Part 1: Adsorption of squalene and equalane
on-aerosils and carbon blacks*. Xoll. zhur. 27 no.3s374-378 Hy-Je-
165* (MIRA 18:12)
L-Institut fiziahaskoy khimii AN SSSRp Moskva. Submitted Jan. 291,
1964.

-BOGAGMAP Ye.K.; KBELF) A.V.; F.LITEXCV, Yu.A.
Effect of the graphitizing of channel black on the adsorption of
-polystyrene, Kello,zhur*. 27 noo5:65&-W S-0 165. (KM 18:10)
1, Institut fizicheskoy khim:Li AN SSSR, Moskva*.

ISIRIKM,, A.A.; KISEIEV., A V.; USHAKOVA) Ye.V,
Adoorption of water gnotbanolp .-hoxaney band- bewiene-vapors on, pigment
ratile-modified.by-diethyldichlorosiUne..Xoll.--zhur. 27 uo.5:690-
696 5-0 %5. (MIRA.18alO)
1. Moskovskiy vniveraitet imeni Lomonosova, khimicheskly fakulltet.

BOMMIEVAy To.K.- XXSELEV A.V.; EWTEKOV. ru.A.
-ion of polyter solutiona
44 fa4e' obamistry.,qffoot on, Lhe advo7pi,
on tillers and pigments. Par'* 5t Adoorptilat of polystyrene 1-;f
t4tani=. dioxide. Xoll.-2bur. 27 no.C-P7~.'J-796 N-D 165.
(KRA ILW2)
1, Inatitut Michesko Mhimii 0 K-S&r Moakv-A. Subvetllled
~uv 18P 1964,

KISEISVO A V. 0VALFWA, N.V.; PETRMA, R.S.
A~sarption properties of acetylene black. Koll.
m,.6.-822-82-7 N-0 165.
1, institut fizioheskoy kh--'-!rdi AN SSSR i hbimicheskIly
Mosklovskogo universiteta imsni M.V. Loriononva.
October 14, 1964.
zhur. 27
(1411FA 18912)
fak-ull-tat
Sulcmitted

VA

ABRAMOT, Y.N.j KISELEV, A.V.,; LYGIN, V.I.- (Moskva)
.Vibrational spectra and dtate of*water molecules adsorbed on
synthetic seolites. Zhur. fiz. khim. 39 no. 12123-128 Ta--165
(MIM 19 rl)
1. Moskovski-y gosudarstvaninyy universitet imeni M.T. L=onosova,
khimicheskiy fakulftet. Sabmitted May 19p 1964.

,KISELEV, A.V.; POSHKUS, D.P. (Poskus, D.1
Theoretical calculation of the potential function avid the thermo-
dynamic properties of symmetrical diatomic molecules adsorbed on
graphite. Adsorption of H2 and D2- Zhur. fiz. khim. 39 no.2098-
402, F 165. WIRA 18:4)
I T-444....& C-01-D 4 T--4.44...~ 1,1-4-4- 4

AUTHOR'i
TITLE: Hydroxyl group concentration on silica surfaces
SOURCE- - 21nit6dr-1 19--- no-i :2 1965, 453455
TOPIC TAGS: hydroxyl group concentration, Aerosil, silica gel., surface adsorption,
deuterium exchange
d7
:t e:authors measure q con emr.,
I ABSTRACT: U-sing .'th~,: -deuteftixu~_exdharige ttethoh
trationv'rjk-j- of hydrox~i_grou_pi on t6 surfac'e of silica as a function of the
temperature of vacuum processing4 These data for Aerosil and silica gel were
compared with data reported by J.-J. Fripiat et al. (J. Phys. Chem., 66, 800,
1962; J. Uytterhoeven, J. J. Fripiat, H. Skeex, Bt-11. Soc. chim. France, 1964) who
j,
dif 'Mte results, show that-' for,--- 6--gi-Ven.
vacuum processing temperature,-1 theo4 ()jj values for all the samples are approxi-
mately equal, and that the decreases in o