SCIENTIFIC ABSTRACT KISELEV, A.V. - KURCHATOV, I.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000722730011-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 14, 2000
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Adsorption Heats and Entropies of Hexane S/020/61/136/002/025/04
and Benzene Vapors on an Aerosils With B004/BO56
a Surface Modified by Trimethylsilyl Groups
were calculated. With growing modification, g transition from negative to
positive values took place. With.,W.-1/z-mole/m-, C74S/Okon aerosil with 0%
modification amounted to.about -2 ,5 oal/deg.mole for benzene, and about
-0.5 for n-hexanet w .hile the following values were obtained for 100% modi-
fied aerosol:,benzenel about +2,oal/deg..molep n-hexane, about +1 oal/deg.
mole. This indicated a higher mobility of the adsorbed hydrocarbon mole-
=leBon the modified,surface.*.With 100% modification, a non-localized ad-
sorption is assumed. For the initialpart of the adsorption isothermal line,
which is not yet distorted by capillary condensation, T.H.Hill's equation
Ref. 7) therefore.holdB. A combination of the geometric modification
ydrothermal treatment in an autoolave) with chemical modification (reac-
R
tion with trimethylohlorosilane) thus smoothened the surface of silicon
dioxide and led to the formation of a homogeneous layer of trimethylsilyl
groups, on which the adsorption of n-C 6R12 and C6H6 is not localized and
the adsorption heat becomes negative. The authors thank I.V.Drogaleva and
V.P.Marinkova for their assistance. There are 4 figures, 1 table, and 10
references, 7 of which are.Soviet, 2 US, and 1 German.
Card 3/1~

S/020/61/136/004/018/026
B026/Bo6o
AUTHORS: Vasillyeva, V 'S.t Drogaleva, I. V.9 Kiselev, A. V.9
Korolev, A. ~a., and Shcherbakova, K
TITLE: Geometrical And Chemical Modifications of Silica Gel for
Purposes of,.Gas dhromatography
PERIODIOAL.: Doklady Akademii'nauk SSSRp 1961, Vol- 136, No.; 4,
pp. .652-855
TEXT: The present paper deals with the crystalline and the chemical
modifications of S102 0 Silica gel of the type WCK(ShSK) served as the
initial material. Industrial silica.gel was washed -with diluted hydro-
chloric aci ,d.(1:1) for the.purification of iron and other metal ions
(up to the negative react.'-on with ammonium thiocyanate, and with
distilled-water for-the r'arificition of Cl ions (Up to the nega ive
reaction with sllver~:nit.".-ate).; This purified (SI) Silica, gel had An
inhomogeneous surface:arA constituted the initial-material forthe
further.modification ek*, 9
r.eriment'. Por the crystalline modificationy SI
Card .1

Geometrical and Chemical Mo-dIificatiops of 3/020/61/136/004/018/026
Silica Gel for Purposes of Gas'Chromatography B028/BO60
was heated with water in.the,autoolave at 2750C for 19.5 hours. The
resulting product was cr (SG)~ Silica gel. Type crti(SGM) was obtained by
treating SO, with liquid trimethyl chloro silane. The analysis of SGII for
C content showed that 100 A of.the SGM surface contained 1.22~- C' i.e.,
on an average, 2-7 trimethyl.chlo ro silyl groups. This corresponds to a
coating by organosilicon film of an:almost maximum density. Prior to the
adsorption experiments, the samples were heated for a fairly long time
in vacuum adsorbers in small suspended quartz crucibles at 1500C and a
pressure of 1-io-5 mm-Hg. In the range of pressure ratios of p/p. from 0
to 1, isothermal lines were.obtained for the adsorption and the
desorption of benzene'vapor. In the.case of SG the isothermal line
deviates sharply toward the:.lower.right side. With the beginning of the
capillary condensation the hysteresis curve shifts from p/ps - 0.2 for SI
to P/ps - 0 75 for SG. At p/ps = 0 1 1 the benzene adsorption a on SI and
SG equals 2;mole/m2, whereas a. O.;Amole/m2 for SGM. In other words, the
benzene adsorption drops-to the 20th part with the chemical modification
(SGM). Experiments with SGM were conducted jointly with R. S. Petrova,
N. Ya. Smirnov, V. I. Kalmanovskiy, N. Balakhnina, and Ya. I. Yashin.
Card 2/y

r -
U

3z
BELYAKOVA, L.D*; GROMOVp VJ4 KISUNO A.V.; SPITSYN., Vikt-I-p akademik
Adsorption of hexam and benzenexapore on nonradloactivq.azid
radioactive barium sulfate samples. Dokl,AN SSSR 138 noo5sU396-
1142 is: 16101 (MMA .14 16)
1. Institut fixiobeekoy lehimil'AN SSSR i Moskovakiy gosudarstvenWy
universitet im. -MVJA=onozoira*-
(Barium-sulfate)-' (Sulfur--Isotopes) (Adsorption)

as
PHASZ I BWK MCPLOITATION si*,/6246
Soveshchanlye po tseolitsm. lot, leningred, 1961.
-too olity; poluchonlye, imeledovanlye I primenonlys
SIntetichookiye U.:7
(Synthetic Zoolites: Production, Investigation,and Use). 111ow
cow, Zzd-va AN SSSR, 2962. 286 p. (Series: Uns Dokladj)
Errats, slip inserted* 25W coples'prInted.
Sponsoring Agencyt Akad widya nauk SM. Otdolonlys khimlaheskikh
~nauk. KomIslywoo tooolltax.
Rasp.- Edo. t X.. M./DubinIn, Acadeodclan and V. V. Sorpinsklyo. Dootor
of Chm~cal-Solonoos;_ 2d. s To. 0. Zhukovskayaj Tech. W.s 4. P.
Golub",
PURPOSS: This book is Intended for scientists w4 engineers engaged
In the production of synthetic soolites (molecular sloves),%and
for chadets In, orale
Card 1/0

3ynthetio Zoollt*s on 46
S (C t. Y
MAO
Kolltsov, N. V., I. P. OgloblJLna,, andN Torochoshnikov. i -
Begoperation of ZoOlltes In Cks str~sm-
203
G. V. Astor, ova Yee is 01yonko# N.
1.
Lulova, and A.0T.' Slopnova., Nothods o~;Iant and Quallty
Control or Fln1shed Products DUrIng Nan turo'of.Zeo)lto
&'Typb-AGx*rbont~ 212
Tuf
APPLICATION OF ZRDLITW

5/065/62/000/008/ooi/003
E075/S135
AUTHORS: Aristov,I~B G Kiselev, A.V., Mirskiy, Ya.V.,
_
_
_
nU_Ve_T~
a
Pavlova, L:F::
ova,
TITLE: Adsorption from vapours and from solutions on
molecular sieves
PERIODICAL: Khimiya i tekhnologiya.topliv i masel, no.8, 1962,,
7-12
TEXT;- Results are given of.the investigation of adsovptlon of
vapours Of H20., N2, Kr,.n-hexane, benzene and isooctane, and also
adsorption from liquid solutions of n-hexane,-benzene on porous
crystals of zeolites of theAA and 5A type. The adsorp'l-ion
isotherms of vapours of H20,:N2, Kr and n-hexane 'on the sieve 5A
rise zteeply at,first and.rapidly-reach the s .aturation, stage.
The adsorption of benzene and isooctane remains very small. The
adsorption isotherm of n-hexane from solution in benzene was
measured on the 5A.sieve. of the pores with n-hexane
begins at practically negligible concentrations-of n-hexane, and
subsequently only some additional packing of adsorbed molecules
takes place. The maximum value for-the full packing is reached at.. ...
Card 1/2

44
Adsorption from vapours~and from s/o.65/62/000/008/001/003.
E075/E135
the equilibrium'concentration,of n-hexane of about 0.2, this va-lue
being similar-to that pertaining to the adsorption of n-hexane
from vapour. The quantity of adsorbed molecules in one pore in
the 5A sieve crystals isinot great and is 2.6-2.7 for n-hexane.
Molecular sieve 5A adsorbs-Kr at -196 OC,only on the external
surface of the grains. I Nitrogen at -196'OC penetrates-markedly
into the pores of the*sieve 4A, but the speed of adsorption is
very.small and equilibrium is therefore not obtained.
There are 4 figures and 1 table.-
ASSOCIATION:.Institut fizicheskoy kh1mii; MGU im. M.V.Lomonosova;
GrozNIX
(Institute of Physical Chemistry; MGU imeni
M.V. Lomonozov; GrOZNII)
Card 2/2

KISELL7. A.V.; FAVLOVA, L.F.
Effect of surface chemistry on theadsorption, the energy, and the
beat of the adsorption of~benzene from solutions in hexane. flefte-
khimiia 2 no.6:861-876 14-D 162. (HIM 17:10)
1. Institut fizicheakoy khimii M SSSR i Khimicheskiy falculltet
Moskovskogo gosudarstvemiogo universitata im. Lomonosova.

KISELEV, A.V.; MULMIUVA, Ye.V.; SHCIM, RBAKOVA, K. D.
Ghromatograpbic determination of the hert of the adsorption of
lower hydrocarbons on -5A zeolites. Neftekhimiia 2 no.6-.87'7-884
11-D 62. (NIRA 17: 10)

IT-Zla~;~ a
gal-MOTS ~-:MwWdl

S/069/62/024/OOZ/003/008
B110/B144
AUTHORSi Drogalev-:-., 1-.,V., Kiselev, A. V., Korolev, A. Ya., El tekovt'
Yu.
TITLE: Productionand properties of ethylene j3lycol aerosil
PERIODICAL: Kolloidnyy,zhurnal, v. 214,.ho. 2, 1962,-152 -.158 4~1
TEXT: The surface of aerosil-was modified with ethylene Mlycol to reduce
the adsorption energy and pres'erve the hydrophilic character and aelective-
action of functional groups. Etherification of silanolgroups with ethylene
'glycol -Si-OH + H0C2R4 OR _Si_O_C 244 OR + U20 causes coating of the
aerosil surface with.ethylene glycoxy groups, one hydroxyl group of which.is,
located at the end. First the increase in the degree of modification is
comparatively fuht as the time of ethylene glycol action increases then it
slows down. The number of *~-CR -CR - groups grafted onto the unit surface
2 2
2
varies between-2.and 6' 1`001 - -W-hen one hydroxyl group reacts with one
,per
diol molecule,' the substitution aegree of OR groups isi
Card 1/

'0'9
'j 6 2 /324 10C,2100 3/001
Production and properties of ethylene..., r 1 V
-1 ~_/B144
OR Only-2/3 of the 0 .H
on -OC 2H4OR -OR2-OR 2 >/C~-CH,-CH 219'
groups located on the surface of hydrated silica were substituted. The
adsorption isotherms of substituted aerosils showed that the adsorption
of nitrogen, n-hexane) and argon vapors was riot affected but that of
benzene and methanol vapors rapidly reduced. This reduction is due to
chemical changes of the surface and their effect on adsorption since the
sDecific surface o-r ~,erosil is hardly changed by etherification. In a dense
monolayer, the area per molecule is '06 811 /aM11, where aM is the capacity
2
of the monolayer, a N is the specific surface. Substitution of ethomy for
2
silanol groups causes decrease in a for methanol and benzene. With nitro-
m
gen andmethanol the equilibrium. constant decreases with increasing substitu-
tion degree. Grafting may be;applied to diol substitution: (1) to one or
two OH groups; (2) to -Si-O-Si- bridges, and (3) to bridges and OR groups.
Mlore complex compounds' Ay forlm. on the surface since ethylene glycol forms
polymer chains in the,presence of oxide catalysts. This causes a composite.
mosaic structure of the modlfied.layer. Screening of 3ilica wibh ethylene
Card 2/4

S10691621024100210031008
B110/B144
Production and properties of ethylene...
glycol groups improves diapernion anddisaggregation of' aerosil particles
owing to a decrease in their i nter.
action. Disa6gregation ia important for.
the introduction of modified aeroSil as filler into polyur,~thanes. The
gluing strengths of modified.an,l initial quartz hardly differ. The hydroxyl 7.
groups of the quartz surfnce reect vigorously with the isocyanate groups of
the glue. The adhesive r-~-xer in to be preserved, and wetting and complete
disaggregation of fille-, particles in the polymer are to be reached by
.!chemical modification _7~ aimed regulation of surface properties of highly
disperse fillers. Scri-.-aiJnjk of the silica surface by a dense layer of un-,
polar, chemiually inert groups-reduces adsorption and adhesion. Modification
with dimethyl.dichloro silane tYus forms a thick, continuous polyTethyl
siloxane layer eliminati g the polar glue-quartz adhesion. There are 2
n
figures, 4 tables, and 16 references.
::ASSOCIATION-.: Institut fizicheskoy khimii AN SSSR Gruppa khimii poverkhnosti-'
(Institute of Physical ChemistryAS USSR, Group of Surface
Qhsmistry~ Xoskovskiy universitet Im. M. V. Lomonosova
Laboratoriya adsorbtsii Khimicheskiy fakull tet ~Imoecov x3ninm-0130",
Imeni M. V. Lomonosor, Adsorption Laboratory, Chemical Divisim).
Card 3/4

'
I/Oio'
j/o~)9/62/024/005/00
.
B107 F186
Aristov, B, G.* Daiiydi
AUTHORS: ov -Y. Ta., Drogaleva, I. T"0
Karnaukhov~; A* P.; Kiselev, A.,V., Korolev- A. Ta. i Poiyakov,~-' .
A. L. ,
TITLE: The modification of
bighly. dispersed silica aeroeil by
hydrothermal treatment
"J
PERIODICAL: Kolloidnyy,zhurnal* v. 24, no- 5, 1962, 513 521 _
TEXT:, The influence of temperature and duration:of hydrothermal trea,tment, _',,._,
on the aerosille specific surfacearea and power to adsorb nitrogen is-
systematically studied, and some samples mere examined by electron
microscope. The original material was industrial aerosil prepared bY
-high-temperature hydrol as well as the material Bk -I (YY- I
Y"s of S'C14
prepared by..burning off silicor-organic compounds. The hydrothermal
0
treatment was'accomplished at',120 410 C in periods ranging between,4
0
and 132 hrq after which the,eamples were dried at 150 C and their
adsorption of nitrogen at'its boiling point was measured. From this the
..specific surface area was-calcialated by the BET method. Results in
Card 1,1.d
Ur

S/06~/62/024/005/001/010
The modification of highly dispersed.... B107 M6.
~Table 1 show that,the a r-face diminishes with increasing
pecific su
temperature and duration of hydrothermal treatment. Electron microsclope
exposures shoved that this is due to,coarBening of the particles. If
the absolute amount of adsorption is plotted against ph
8 (where p 8 is the
saturation vapor ressure of the.nitrogen)'a-very reproducible isotherm
obtained*.(Table 2~. Within the range p/p 0.015 -.0-3 this can be
a cp/p
M 8
represented by the BET.equation: a - ith
0 -p/P 13 )[1+ (C-1 )P/pjw
2
a 10.25 AM01/m., C 164. 1A, the.range p/P 0.2 0.8-Ahe iB.otherml
,formulated
noes see belo
'Jonf orms to Halsay- and Hill (reiere w). As.' b
Pierce- 2.75 (cc/10 )2-75
(reference see-below this::redds ~(Oi/a' .25
m
1.30/log(P/P -It is pointed out.that this isotherm makes it possible
to determine the'specific surface area of a nonporous or large-pore
silica with hydrated surface area from a single experimentally fixed-
point, according to the eqdation a - a/ a m2/g (a being the adsorption
in t1mol/g and athe value-of-the iaothe )/p 'There are
rm for the same I
Card 2/#

S/069j62/024/005/00i/010
The modification of,highly dispersed... -B107/B186
6 figures and 2 tabiesi The
most-important English-lan~uage 'references
.
are: 0. D. 11aleayj Ghem Phys., 16, 931t 19481 T. L. Hill, J. dhem.
. Pierce:1 J.. Phys.-Chem.,
.PhyB., 17, 590~ iq6t; c
63p 1076, 19591 64P
.
.
1184, 1960.
ASSOCIATION: Moskovikiy universitett Khimicheskiy 'fakulitet
(Moscov
J. ,
University', Divisi
on' of,Chemiqtry)
.
19'61
SUBMITTED: Septembir 9,
1
'2
Table 1. Specific surface area* (w /g) of, aerbsil 'in 0ependenov on
temperature and duration of hydrothermal treatment in an autoolave. The
specific surface area of the initial aero
dil was 187 M2/9-
,
Legend: 1. Temperature in 0C; 2. Muration. of treatment in hr; 3. Specific
:surface area in m2/g.
Table 2. Absolute amount of nitrogen gas adsorbed, at its boiling~poinij
on hydrated samples of nonporous..amorphous.siliabL., The surface area
covered'by a molecule of nitrogen corresponding to a monolayer of ('3
)
m
'R'andlhe~ degree of filli a/a wherefr6m
..thickness is put-at*16 2. ng'
M
'card 3 -------

BIOIjBi8O
AUTHORSI Aristov, B. G., Babkin, I. Yu., Kiselev, A. V.
TITILE i Adsorption and. heat of adsorption of vapors on alkoxylated
silica
PERIODICALz Kolloidnyy zhurnal, 24, no..6t 1962, 643 647
TEXTs 'Aerosil-gels dontaining groups of 11 4, or 8 C atoms on their sur-
face were obtained by treating aerosil with absolute methanol at 3000CP or
with n-butanol or n-octanol at.,2800C and by- subsequent evacuation- The
specific surface of the-aerosile.remained uncbanged. When --acuum terated
f-the-bu- -3500C
i. the modified layer o toxylated specimen was stable upAo,
Modification of the surface lowered -theN adiorptive capacity at -1950C
2
and the adsorption heat of S*0 -.CH OR, and GH At low degrees of ad-
2 6 6
sorption, the surface showed marked energeticinhomogeneity, particularly
the methoxylated one. The adsorption isotherms of H 0, CH OR, and C H
2 3. 6 6'
became 'convex. Adsorption~decreases as the length of the modifying radical
'increasest C H being adsoibed 'more strongly thon CH OR. This Is attributed
6 6 3
Card 1/2

8/069/62/024/006/001/009
Adsorption and heat of.,46 BIOI/B180
to the increasing contribution of the entropy term in the equation for the
adsorption equilibrium C 6H6 molecules adsorbed on layer of long radica.1s
are less mobile than in the liquid state, while methanol molecules are
firmest on a methoxy layer. -As the imperfootions.of the modified aerosil
surface are completely covered by water even at a small p/p ratio, adsorp-
tion will be very low---at a high p/p ratio. There are 4 figures and
I table.
ASSOCIATIONS.M68kovskiy universitetp.Xhimiaheakiy fakulltetj Laborstoriy&
adsorbtaii i gazovoy khromatografii (Moscow Uni-rersity,
Division.of Chemistry,.Laboratory of Adsorption and Gas
Chromatography)
SUBMITTEDs September-4# 1962..'.
L--.qar.d _212,

ISTRIKYANp A.A.; KISFUVOAGY.
Absolute adoorption:,isotherms for nitrogen.. benzene~ and
n-hmane vapors andAhe heats of adsorption of benzene and
n-hexans on graphitized carbon blacks. Pai-t 1. Zhur. fiz.
kbim. 36 no.6-.1164-1172 Je262 (MIRA 17Z-7)
1. Moskovskiy gosudarstvennyy imiversitet imeni L=cnosova
i Thstitut fizicheskoy khimil P14 SSSR.

~- ~~~La dz~~~
I-. - -

BEPEZIN,
G.I.;.ESELEVp V.; SIFRDOBOV,,, MoV.
Continuously heated adiabatic differential calorimeter with
continuous adsorbate feed for measuring the heat of adsorption
(.i, small solid surfaces. Zhur. fiz. khim. )6 no.9-.2091-2095
S 162. (MIRA 17g6)
1. Ingtitub fizicheskoy khimii AN SSSR.

S/076/62/036/011/010/02.1
B101/3160
AUTHORS: Babkin, 1. Yu., and Kisslev,~A. V. (Moscow)
TITLE: Adsorption and he&% of adsGrpties of various Vapor@ 44 a
trimethylsiliLte&.aerozil surface
PERIODICAL: Zhdrnal fizicheskoy.k.hinii, v- 36,.no. 11, 1962,.2448-2456
I'M vapors were~-6arbbn-.-t4trithlOvidet-nothmol and water, on the
M The
a tridymite. sil-46ve'ret jr1th a layer of grafted trimethyl
surface of aero
silyl g:zoupa which greatly-ieduced.,ihe--adgorption. The adsorptfon of,
nonpolar C01 is not affected.-by dsfects'1n the trimethyl ailyl layer,
but that of Lthanol.and waterloccurefirst In these placed with formation
of H bonds.- The modifying--lay*r reduces the 'selectivity of the aerooll
surface wl'th regard to large.non-polor molecules such as C 06' C 6R14" and
Ccl 9making their heats of adsoration lcwor thaa.those of condensation@
4
The variation in the entropy curve (?IS- Wshowe that hydrocarbon
molecules adsorbed on the surface have greater mobility than in the liquid,
whereas the methanol and water molecules are localized in the layer
Card 1/3

S/076/62/036/011/010/021
Adsorption and heat ofadsotAioa. B101'/B180
defects, particularly in the first stage of adsorption. Tridymite goverod-I
with trimethyl,silyl groip3has-lower adsorptivity than graphitized carbon
,black for nonpolar molecules,,The.-adsorption of CH 30H on modified tridymite,
however, is at first hiE;her than-on graphitized carbon black, because H bonds
are formed with the hydroryl groups of the layer defects. . In the whole
range investigated water is adsorbed,on tridysite more strongly than an
carbon black. There are.9 figures and I table.
ASSOCIATION: Moskovskiy gosudArstvonnyy univorsitat im-..M. V. Lomonosovat
Khimicheski
ly,fakulltot ~(Veesow State University imeni
M. V. Lomonosov, -Chemical Division).
SUBIZITTED: JulY 7,, 1561
Fi~- 7. Change in adsorption~ entropy on tdaet~ylsilatsd aerosil for
C H C H OH'
;.14) KjGj 5) 09
(1 ccl 4; 6 6; (3) 6 14 3
Card 2/3

ARISTOV,, ;B. G.; DAVYDOV, V. Ya.; KARNAUKHOV, A. P.; K~S~Vj A,.~V.
Corptwcular-theary of the structure of adeorbents. Part 5:
Adsorption of imitrogen and carbon tetracroride
vapors on
model ade.orbents obtained by compression-of aeroaila. Zhur. fis.
khim. 36 no.3.2-.2757-2763 D 162. (MIM 16; 1)
I.- Moiskmkiy gomidaks.tvennyy universitet imeni Lomon.oBova i
Inetitut fisic,heskorkhWi AN SSSR.
(Adsorbents) (Nitrogen) (Carbon tetrachloride)

GERASIMOV, Yakov Ivanovich;-prof!p; DREVING, Vladimir Petrovich;
YEREMIN, Yevgeniy Nikolayevich; KISELEV, Andrey--
trov h, PANCHENKOV,
k#zO~ch; LEBEDEV, Vladimir7p~' - -
VI j~
Georgiy Mitrofanovie.h; SHLYGIN., Aleksandr Ivanovich;
NIKOLISKIY, B.P., prof., retsenzent; SHUSHUNOV, V.A.,, prof.,
retsenzent; LURIYEP*GJe'... red.; SHPAK, Ye.G., tekhn. red.
[course in physical chemistry] Kurs fizicheskoi khimii. [By]
~IA.I.Gerasimov i dr. Moskva, Goskhimizdat, 1963. VoLL 624 pe
(MIRA 17:1)
1. 6len-korrespondent AN SSSR (for Gerasimov, Nikollskiy).
2. Kafedra phizicheskoy khimii Leningradskogo gosudarstvennogo_
universiteta'(for Nikollskiy, Shushunov).

- ~N', ~, 29M R'NUMISP i
n, W--`,~E "' - M., .1
M IN
~; -, =,III- - ~ - - YIN&,- ZV-,;R " ~R ~,V~~~
'.. , -1 EPSON- -11-1
! I
1 1

V069/63/025/001/06/006J
B1 01 /B1 86
AUTHOR~; 'Dzhigh 0. M. I Kiselev, A. V. , Muttik, G ~G.
--------------
ad orption by zeolitee. Differential -hea
TITLE: NECture of S t
adsorption of diethyl ether vapor and a-pentane vapgr on--..;;
'porou
4--drystals
'PERIODICAL. r
Ko'll oidriyy zhurnal v. 25, no- 1 -
1963t 34,42
TEXT; The adsorption Viroperti4ds of moleculeo*having:.similar geometrid but
different'electronic a rudtu'jre'
t s~were', tudied. For this..ptkrpose-.diet
;_4
ether and n-pentane adsorbed'on porous zeolite. crystals of
-2. 5i( 0
(O-97Na2O*Al20 9 6' 1 ) and:1 OX (O-31Na o-o.66.CaO-Al 42-95SiO were
2. 2 3
3 2
used. 'The results-were, compar6d:-with those obt iaimid earlier (zh. f ki-
khimiii 36,*919, 1962)-f6r-zeolite 5A which also contained C.L"+ ions
channelways, however, were nariowerthanthooe of 1OX. Results:, In 13i,
the adsorption heat Qa- of ether.was.approximately'U*44 higher than
f
B ~p
'Was almost constant as the amou
pentane,.. Q., nV a
(mm6leB/g) of adsoibed
Card 1/3
-F-

S/069/63/025/061/6011068'
Nature of adsorption by, i BIOI/B186
-a wa s-, arger an -Q owing to electrostitid
substanoe'increas6d, and th
aP
ino e'
interaction between ether-Idivoleis ancl Na ions of zeolite..
ap
with'a and p sed a maximum:o;iing an J",
as to interactibn~among pent e mole',,
which were more densely- pack6d--.'bn, the zoolite surface. The curve. Q.;
a-of 10X first dropped, for ether as well as pentane owing to inhomo*-
0 -~by Ca
-.of the electrostati ~field-:,f 'reed and Hat' ions~ In.:contres ~to
14 1 increased with-ap.-but i, -o_.'- (kca
aE . qaP less Inten6ively than 1W 13X'
i ris given for the degrees of :population 0 0.1 and 0.'5 f o*r ether' on
and,22.0; on I OXi, 22 `3_.~axid 20.2; on I 'I,and 21.0; for
25 6
.3x: 21
54 14- '6
pentane on 2, ahd4l 5 on iox.. 13 5 and 13-0; on 13X: -1
14-0. Adsorption on-zeblites-iiith,high adsqrption-_ehergy.affect's't
molecular packing of, the -adsorb' tes Thus th-
a the ratio a
E/a P of 6
1612'in'
concentrations of adsorbed nd entane at p/P -0.51 is~
p
1.18 in 1OX, and -1 .19.in 1 3X,- wh-ei-r-eihs c'/c of_-the.Aiq'uids is4only 1'A
P
E
1~,'table T e'- uage-:
There are 4-figure's-and h most imiortant Engliah-lang
'11. Ial
references are: R. 11. 'Barrer 7S. Wasilewski, Trans. Faraday Soce P 57s;
L.Card 2/3

'061
510021
/01
405MA126~--_-_-~..
l_J
0
4":: 14 V
Z _-zed tAni leatof -adsorption of benzene-
andm.
a-- SoolitIS-;VO: 13 X (13KhY
~T
A**~ ~Kolldidny~~y-_
'MaOD144AI
129
5
3
dl Z6C. beingne-And n4himnci
ra
vapo qn
J`,;:;l3Mi -zeolite -:64stals' hid
*ere amw or me rically.,.: The lll~a d . dso
sure st
t
ea s"are- app 4ly- ce'da.-I dorresp*onding.heats of 6
SLvt~ole: . ondensmtion~'
ene~-Td. by-,"about:3:k~ hi r than
ghe
~"`:~vmt` of n-44juini.- iittU--j 'Was, Obser-44_1~ the,
S -heat of adsorption of b
of!_-.'adsorpt oni- 0.
o saryatlon- was -
t
~980 Id ild afid iim~ldlt4dl
in teracti0ii;0k:-', non-pol4i~-
MA~daib liii6_wAdi6ipticftldoe of f6
,ii,zed soot surfAO'd,`--.Dlscuss]JL~ of
066 SAble"; -6mrilta the bditieno and
Aiei., t
"Vitles 0 IN
ze tAO thd d~Wokd A
F aofi
; 02 T v

12.",- 19,62

11

"

.5/0
63/037/001/027/029' .
J
_
Isotherms and heats,of a ds or' pt ijon-. . B10
186
Q , (th~e'differ6ntial heat of adsorption)~ 200
versus a ,at C-were plotted' thi
a
were kept in o at
1P0 C.for,25 30 h~s. Results: The curves
vaou
.
4XR ly era us and q ve re the same for the;two silicag,,-and
a a-..r .sus.- 0 a
IT, 2
agree with the curve obtained earlier for1KC(-2 (ksi-2) silica gel. The

same.was observed,for, an C H The is 6therms' and the deD*endence of
'CH Ok d~
3
.,,-on.. the degree of. --were. found. not. to depend.oh the type. and-
a -
.diapersity. of -a~: silica;, with .-h dpaied':~urface., The adsorption of CCI was A
4
eas -ured n s h hydrated surfa'e and on'silica dehyd n vacuo

o rated i
X ilica w it
2

at.8000C~(i 100 M ~Re~ult;':: The ~tdso ;Dt ad
r
ion.and
the heat of,
.
2

sorption ot nonpolar 001 are "l t depend on the degree of surface
ow and do.no
4
-..
hydration. There are 4 figures.
ASSOCIATION t'..Moskovskiyl gosuderstvennyy unive 'Sitet'' im. M. V. Lomonosoval
r
Khimicheskiy fa
kulltet (Moscow State University imeni
,
9.. V.- Lomonosov, ft~emical Division)
SUBMITTED. April-. 10, 19.62
_7 Card 272
a --- -----

'da~ ~;Ib
L oU 1 at 16fi .-I- of ~'~.'thd '~:'total eridrgy afid entropy, of
-W
-,,Oocupa ion 0- -41f, them -surface as based:. w'a.~
endrgy~-of - t1ii berizene molecule ~-~Adeotbqd-'~'-

"St at I'st io,

3/076

-o' n"
-:ca:ou ~a 6' tot
B101/b2l
'
00
I kT) (kr I hvi~; -1) if
7
7

2
A" (W/hv.) f(p) do

V
0)

7,~, W
U - nV 00
kj 2 'kT
1~yr4r 2aei
~
'a
~
7
and,- T 6' r- -c" 1 - a- -s- sd, -c a-3
rd

.,exp

two
-R In Oi
kn iv) da:
0

-~b6nzeiie 'at* 0 K,
.heat 6f

---v'
the'indic
.O
e k)j
-
-0.
1~63~bed" bonzene,;,at 9 3~ K, ~
j
~
. the calculation-yie
L

- f~ , - - - , ., - i .:
-,: . - - - p~ ,-., -.: ,

AKSHINSKAYA, N.V.; KISELEEV~, A. KITIN) YUSSO
- ~-xi
Geometric modification of a skeleton of xerogels,, Part 2.
Zhur, fiz. khim, 37 no,4:927-928 Ap 163. (MIRA 170)
1, Moskovskiy gosudarstvennyy universitet imeni M.V. LomonoLova*

, * I/ :
. -1 ~ ~ ~2 z
-.., or ~,. ~ ~ .

Ps-4/
L 18313--Q~',. EPFVEPF(c)/EWr(l)/EWP(q)/W(m)/BDS AFFTG/ABD
-4 'RM/W1
JD/WH/
Pr
ACCESSION Nnt-': AP500,4974: 5/()076/63/b37/6O8/17T
6/iM
AMHORS i IsirilwAint A A, Zie"elevo A v. V,
TITLE: Adsorption'isotherme or-vaDdr ~of nitrogwks-'tenzene, and W-hexane and heat:
of adsorption'of enZenS%1ankN"hexsn&
lacks. 3. Therm -
gSEe~on &ap=zed carbon. 0
t on
dynamic characteristics of a" equilibrie.~.,
Ii. 37
S=6r-w Zhurnallize khin i 1,:noo~8#J96
3 1776-1785-1
..TOPIC TAG,SSL adsorption. isotherm .1 sorp
Mitrogen- benzenep K-hexane heat of ad
tion, graphitized'c'arbon b a"
lao k ~t ad orp.tion equilibri
c propertif -of
VnaMj L ?a . graphit
ABSTRAM f The thermok szeniene and graphite-N-heX=e L
adsorption ~systems are comparede* L Adsorption -isothermsp differential heats and
entropies ofLadsorption. of vapors'of:X-hexane~ and benzene are also acnixpared in
a constant graphite grain. These- prop. erties depend only upon the nature of -the
adisorbate-adeorbent System-and are, -their, physical-schemical characteristicso' L L
They are practically free from,the effect of adsorbent heterogeneity.,, The sharp
,:difference of these ebaracteristicb for X-hexane and benzene is discussedo
L -1
-vapors at 1950,.'-hexanev and benzene at 200
Isotherms of adsorption of nitrogen. N
!.Card- 1A

az

11 :~ZT4~;7112-1- -, . "I'll, VQ ~
-- ;tT71-.- -, - - '. . I I ....
- ... . . . . .-- - ... I TRM~~ li,

IN, ri

ZEDANOV, S.P.; KISNM,- A.V.; LYGIN, V.I.; TITOVA, T.I.
ChanRo of the-Infrared anectrua of zoolites,X durinR their
thermal treatment in vacuo. Dokjo"AN SSSR 150 no.39584-587
MY 163. (MM 16W
1. Mookovskiy goelldarstvannyy univeroitet in.MV. Lomonoo,ova,
i lustitut kbizii silikatov AN SSSR, Predstavlono akademikm
A.N. Frunkimme
(zeolited-Absorption spectra)
t

KISELEV, A. V.
*Gas Chromatographic Study,~of theInfluence.of the Geomtry and Chemistry
of Silica Surfaces on,Their Separating and Adsorption Properties."
Report to be submitted'for.theiSecond International Symposium on Advances

JACCESSION HR: AT5007921 S/0000/64/OOD/000/0274/0287
1AUr11OR: B er, V. N.; Blinpy~Gj A- Bon4arqAko.~N~; Ye
I L
'
Korob --Aironov, Ye Haum v, A. A.. Onuchin. A. P Panasvuk.
Korqk
Sfdorov. V. A.- Siltvestroii
Skrin k
r
A
jlqj~q~ ~ashey, A. ~q. ; Auslender V. L - Kiseley A V; - Kushnirenko.
Te
j.~~-hits A-; R21jonov. S. H.;
IVA~a.qmn%_~L_P.; Veche3lavov, V.
1. Ya.; Budk
iTITLE: Colliding electron-electron, positrcn-electron, and proton-proton beam
SOURCE: International Conference Dubna, 1963. ;4
Trudy. Moscow, Atom zd~i, 1964, 274-267
TOPIC TAGS- hk_vj.LAner Interactiono high enevvy Plasma. particle physics', par-_,.,.,,
ticle beam, iWam
d.particle
cb~rg
ADSTRACTt In the'Ustitute of Nuclear Physics, Siberian Department, Acad~my._of
Sciances,SSSR, programs on biph-onergy particle physics are mainly concerned
work on collidinj'cbe~Vd pirticle The Institute considers it vWUit*b2*-.-'t

47304-65
ACCESSION MR. AT5007921
for its purpose to Install huge accelerators whose construction requires large
resources outlaid and long time. For work on colliding electron-electron, Iposi-
tron-olectron, and proton-proton beams, throe In3tallations are being built, which
are In various stages of readiness. Work on colliding electron beams was con-
ducted at the institute (then a laboratory of the Ins~.tq LA rZY-jr4d
#p_Q tpmic Xnj
I. V. Kurchatov) in the Fall of 1956, after Kerst's report on accelerators with
beaW of the FFAG type. By that time Soviet scientists gad al-
ready acquired some experienco.in obtaining large electron currents,, An pirticular,
the nentioned laboratory had installed and then abandoned a device for the spiral-
ntorage of electrons (G. I..Budker and A. A. Haumov, CERN Symposium, 1, 76 (1456)),
by which, subsequently, circulating currents of th* order of 100 amperes iere ob-
tained. In 1957 two variants of this device were considered at the same time. The
first one consisted of tsto accelerators with spiral storage and subsequent transi-
tion of the particles to synchrotron state in comparatively narrow paths. The
second a,
-is had storage rings with constiint magnetic field and frequent external in
jection because of-the da~nping of the oscillations under the action of radiation.
The fir-at variant was more 6mobersome; the second variant contained an -element not
developed at that time, namely a 100-kilavolt7 commutator of 10 kilo-awbres with
nanosecodd fronto --At the end of 19S79 the.first,positive results were ebtaLned
Card 2/5