SCIENTIFIC ABSTRACT KHORKHOTA, A.YA. - KHORLIN, A.YA.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000722310001-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 18, 2001
• Sequence Number: 1
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

@610630MRSM
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BARRARICH, A.I., kandidat biologicheskikh nauk, laureat Stalinskoy premii,
redaktor; KHORKHOTA, A.Ya., kandidat tokhnicheskikh nault, redaktor-,
OVRUTSKAYA', !'.-,-@4@-'GARSWIOV. A.. takhnicheakiy rodak-tor
[Iandscape jardening for cities and towns] Ozelenienie naselennykh
most. Pod obshchei red. A.I.Barbaricha i A.IA.Khorkhota, Kiev, 1952.
742 p. (MLRA 9:8)
1. Akademiya arkhitaktury URSR, Kiyev, Inatitut gradostroltellstva.
(landsape gardeniag)

S/07 61/031/009/001/012
D215YD306
AUTHORS: Petrov, K.A., Nifantlyev@ E.Yeog and Khorkhoyanu, L.V-
TITLE: Peresterification of esters of dialkyl-phdsphinious
acids with glycerine derivatives
PERIODICAL: Zhurnal obshchey khimii, v. 31, no. 9, 1961,
2889 - 2894
TEXT: In the present work the authors studied peresterification of
dialkyl- and diarylphosphinious acids with glycerine derivatives _
containing one free hydroxyl group for use in insect repellant com7
pounds. The reaction of 1,2-diphenylideneglycerine with 1,2-iso-
propylideneglycerine was studied. The compounds were found to
react readily with simpler esterst methylethyl-, dipropyl- and di-
phenylphosphinious acid. "X@Tycerine derivatives with free secondary
hydroxyls such as 1,3-benzjlideneglycerine reacted less readily,
but still gave good yields of the corresponding phosphinites. The
phosphinitez of the glycerine series provice novel compounds which
Card 1/6

,9/07 61/031/009/001/012
T-tresterification of esters ... D215YD3o6
are either liquids or crystalline solids having unpleasant odours.
They oxidize easily in air but remain stable in an inert gas at-
mosphere; their chemical properties are similar to those of simp-
ler dialkyl- and diarylphosphinious acids and in oxidizing medium
and in the presence of sulphur convert to the corresponding phos-
phonates and thiophosphonates. The synthesized phosphinites react
according to Arbuzov?s reaction forming phosphine oxides and cor-
responding halogen derivatives. The peresterification and alkyla-
tion of phosphinites may be used in preparing some halogen deriva-
tives from polyatomic alcohols if the former are difficult to pro-
duce. In thL presenL veork tne authors also investigated this reac-
T,ion in order to.produce more complex halogen derivatives of the
polyatomic alcohols@ The propyl dipropylphosphinilte and ethyl di-
phenylphosphinite necessary for this reaction were prepared by
reacting Menshutkin acid chlorides with organomagnesium compounds
at -700C ROPCl @ + R I Mgl@*,---@ ROPR I (i)
2@ 2
Card 2/6

S/079/61/031/009/001/012
Peresterification of esters D215/D306
R C2H59C3 H7'
R' C3H79 C6H 50
The first of the esters obLained has been unknown so far, and the
second used to be prepared by more complex methods. The peresteri-
fication reaction was conducted by heating equimolecular quantities
of the phosphinite and the glycerine derivative in a dry nitrogen
stream with a small piece of sodium, distilling the required quan-
tity of alcohol and finally vacuum distilling the residue. Time,
temperature, yields and constants of the compounds obtained are
given in tabulated form. In further experiments the propyl ester
of dipropylphosphinious acid was oxidized with nitrogen oxides at
-100C until a permanent green coloration was obtained. Vacuum dis-
tillation of the solution yielded the propyl ester if dipropylphos-
phinic acid with high purity; b.pt,, 103-1040C/l mm Hg,
n2o _ 1.4418, d 20 _. 0.95439 and having an empirical formula
D 4
Card 3/6

S/079/61/031/009/001/0j'2
Peresterification of esters D215/D306
C9H21 02 P. The ester is colorless, odorless, insoluble in water,
and soluble in ether, benzene, carbon tetrachloride and petroleum
ether. Similarly oxidations of lp2-isopropylidene glycerine ester
and the 1,3-benzylideneglycerine ester of dipropylphosphinious
acid were car-ried out to yield respectively esters of dipropyl-
phosphinic acid, C 12H250 4P, b.pt. 143-1440/0.2 mm,
10
nZ - 1.4530, d 20 1.0376 and C H 0 P b@pl. 117-118'/10-4 mm
D 4 - 16 21 4
n20 _ 1.5190. Both esters are insoluble in water and petroleum
D
ether and soluble in alcohol, acetone, benzene, chloroform and
carbon tetrachloride. Addition of sulphur to both propyl- and 1,2-
.Lsopropylideneglyceri-rie esters of dipropylphosphinious acid was
conducted by heating the esters with thoroughly dry sulphur at
140-1420C (exothermic reaction). The corresponding sulphur deriva-
tives have b-pts. 81-.820C/0-5 mm and 141-140OC/1 mm respectively,
unpleasant odors, and are both insoluble in water and soluble in
Card 4/6

S/07 61/031/009/001/012
Peresterification of esters ... D215YD306
common organic solvents. Propyl-, 1,2-isopropylideneglycerine- and
the lJ-benzylideneglycerine esters of dipropylphosphinious acid
undergo the Arbuzov rearrangement with methyl iodide to yield re-
spectively dipropy1methylphospine oxide, b@pt- 91-930C/l mm, m-pt.
39-39-50C, the above oxide and 2,2-dimethyl-4-iodomethyldioxoleu-
1,3. b@pt. 81-830C/9 mm. n 20 _ 1.5038, and the oxide as before and
D
2--phenyl-5-iodo-dioxan b.pt. 117-120 0C/9 mmq n 20 - 1.4983. The pre-
D
paration of propyl ester of dipropylphosphinious acid and the ethyl
ester of diphenylphosphinious acid was carried out by reacting the
corresponaing alkyl (propyl or ethyl) dichlorophosphite, pyridine,
alcohol and propyl- or phenylmagnesium bromide respectively in
ether at -650C. Distillation of the reaction mixture yields in the
first case the propyl ester of dipropylphosphinious acid b.pt. 70-
710C/7 mm, n 20 __ 1.44309 d 20 _ 0,,8473 B-TR 54.b4; MR
C 4 found calculated
54-949 which is a mobile iiquid with unpleasant smell which igni-
Card 5/6

S/.07 9/61/ 031/009/001/0, 2
Peresterificat-ion of esters D215/D306
tes in air and which is insoluble in water but soliible in common
organic solvents; in the second case the ethyl ester of diphenyl-
phosphinious acid b.pt. 127-1280 C/I mm, n20 _. 1.5910. There are 1
D
table and 8 references& 4 Soviet-bloc and 4 non-Soviet-bloc@ The
references to 'the English-language publications read as follows;
U.S. Patent 2,588,407,- E. Baer, H.L. Fischer, J. Am. Chem. Soc,
70, 609, 10148? C.N. Smith, D. Burnettq J. Econ. Entomol. 42, 434.
1949; T.H. Bevan, T. Malkin, D.B. Smith, J. Chem. Soc. 1955, 1383@
SUBMITTED., September 5. 1960
Card 6/6

Pr@'rl"Jv, K.A.; NIFAINTIYIN, E.Yt!.;jl%')RFJIOYANU, L.V.; i,fiuSl!xJv, i_l.
RepsterificAiin of esters of dialkyl- and dinrylp@osphinic acid.s.
Zhu r. -)I@. Wirt. 31 n,,-).q:)OkS'7_3V-90 5 '61. (MIRA 14: Q)
(Phosphinic acid) (Estprification)

03382
/5' 8150 S/i gc)16210041002101 3/021
//. 9 9 B 11 O/B 101
// ;2 _Q ?
AUTHORSt Petrov, K. A., Nifantlyev, E, Ye., Khorkhoyanu, L. V.,
Merkulova, M. I, Voblikov, V. F.
TITLE: Phosphorus-containing polymers. III. Application of the
Arbuzov reaction for polymerizing ethylene alkyl phosphites
PER1(#ICAL3 Vyeokomolekulyarnyye soyedineniya, v. 4, no. 2, 1962, 246-249
TEM The method by A. Ye. Arbuzov et al. (Izv. AN SSSR, Otd. khim. n.,
1950, 357) can be used for producing polyphosphonates from cyclic
phosphinites. In the present study, polyphosphonates were similarly
synthesized on the basis of ethylene alkyl phosphites (I). Alcohol was
aC.ded dropwise to 126.5 9 of ethylene chlorophosphite, 300 ml of ether,
and 152 g of triethylamine; the mixture was left standing, filtered off,
heated for 30 min, and (I) was obtained by double distillation. Cyclic
phosphites contain an alkoxy group besides the cyclic cater group.
Polyphoophonates are formed under catalytic action of methyl iodide on
ethylene alkyl phosphite during 3 hk heating at 1300C in Ar atmosphere:
Card 0

")3 @1.1
3/1901621004/002101311021
Phosphorus-containing polymers ... B110/B101
C11.0
011. \Pon
GH,O
II.
>P- Oil @__! C113-13-OGII'CIIV
GII'O 0
OR OR
C11, - It OC112CIIJ - ocilpy
111 11
0 0
The structure of polyethylene heptyl phosphite was proven as follows;
0
13
PC_j n CI + nCIC711ts
OCH,CH2 - P
n CI
The degree of polymerization depends on the CH31 amount, the reaction
time and temperature. Optimum was: (1) small CH31 amount; (2)-j20 - 30
hr, the reaction time depending on the molecular weight of the monomer,
Card 2/3

333b2
S/19C/)62/004/002/013/021
Phosphorus-containing polymera... B110/3101
the reaction temperature, and the CH I.concentration; (3)-j16O - 2000C,
depending on the molecular weight (hexyl and isooctyl compounds.:
160 - 1700c; nonyl and decyl compoundss 2000C). The polymers are viscous,
colorless, and odorless liquids soluble in organics. Some of them are
highly thermostable (polydecyl ethylene phosphite enduresj2000C for
20 - 30 hr). Utilization as plasticizer or admixture to lubricants is
possible.
C112-0
\P-On
)PCI+IIOR='. -0
CH'- 0 CH3
was also synthesized. There are 2 tables and 5 references: 4 Soviet and
1 non-Soviet. The reference to the English-language publication readsas
follows: A. K. Sherrill, J. Amer. Cher. Soc., 52, 1985, 1930.
SUBI.,1ITTED: February 9, 1961
Card 3/3

8/679/162/032/011/009/012
D204/_D307
AUTHORS: Petrov, K.A. , Nifantlyev, E.Ye. , aT1d Y1horkhoy_qriu,__jU!_Y,
TITLE: Phosphorylation of glycerine and its derivatives by
alcoholysis of the amides of lialkylphosphinous acids,
A new method of directed replacement or a hydroxyl by
a cyano group
PERIODICAL: Zhurnal obshchey kh-imii, V. 32, no. 11, 19620
3720 - 3723
TEXT: Interactions of the diethylamide of dipropylphosphinous
acid (I) with 1,2-iSO-Dropylideneglycerine (II)p 1f3-benzylideneCly-
cerine (III) and glycerine were studied, in continuation of earlier
work (ZhOKh, 31, 2889, 1961), 1 and II, and I and III interacted
readily at 120-1250C to yield respectively the dipropylphosphini-
.Les of 1,2-iso-propylideneglyceri"ne and 1,3-benzyiideneglycerine
(IV and V), in almost quantitative yields. Glycerine reacted analo-
gously, at 135-1400C, in 60 % yield, -to give the corresponding trie-
dipropylphosphinite (VI). C 3H7OP (OC3H7)2 reacted readily with bu-
Card 112

S/U7 62/032/011/009/012
Phosphorylation t--,.11 glycerine and D204YD307
tyl thiocyanate, at 0 0C' under an inert atmosphere; when the exo-
theriiiie. reaction was over the mixture was heated at 100-1100C for
1 hr., and was then distilled to give BiiSF(O)(Pr).,. Cyanodesoxy-
1,2-iso-propylidene lycerine (VII) was prepared from IV and benzyl
thiocyanate, in 45 1i; yield, by an analogous reaction. VII was con-
verted into iso-propylidene-2-desoxytetrose by mixing it into
SnCl /ether/HC1, stirring for 1 hr. at the b.p. of the ether evapo-
2
rating the latter off,-addinf; water and neutralizing the mixture
and heating for 5 hrs. at 500C. Iso-propylidene-';,4-desoxy-4-amino-
erythrite was obtained by adding VII to ethereal LiAlH 4 evaporating
the ether off, adding an equivalent amount of THP and heating for
96 hrs. on a water-bath.
SUBMITTED: December 14, 1961
Card 2/2

MsTROV, K.A.; NIFAIWYEV, E.Ye.; IKHOIWIOYANU, L.V.
Phosphorylation of glycerol and its derivatives by
alcoholysis of dialkyl phosphinic amides. Now method
of a directed substitution of a cyano group for hydroxfl.
Zhur.ob.khim. 32 no.11:3720-3,'23 N 62. (MITM 15:11)
(Glycerol) --,w-=O*"Vw*iq(fboiiphory:Lation)
. t
(Phospinic amide)

S/190/63/005/003/009/024
B101/B186
AUIPHORS# Petrov,- K. As.,, Hifant 1yev,: E.. Ye., &horkh2ya u, L. V.,
Voblikov, V. F.
TITLEi' Phosphorylated polysaoobarides. II., Phoaphorylation of
cellulose by-alooholysis of amides-of the acids of three-
valent phosphorus
:@-.:PERIODICAM- Vysokomolekulyarnyye soyedineniya# v- 5p no. 3P 19639 348-352
)::,,.TEXT i In a previous pape
r (M.obehoh. I.-himii, 31, 2377, 1961) the authora',
described the reaetiont Cell-OH + R N-- P,1' 4 Cell-O-Pc + R NH. In the
2 2
...present paper.. a.- study was made of this new-method of phosphorylating
cellulose by-alcoholyeis of phosphorous acid amides ouch a diethyl phoo-
phorus acid diethylamide, pthylphosphorous acid tetraethylamide and*phos-
!::,:-.phorous acid hexaethyltriamide in order to develop fireprooft antiseptic
insecticidal cellulose. Since 1heprocesa of eaterifioation of cellu-
.:lose depends to a great:extent on how the sample is-prepared the followi
cellulose types were subjected to,ph6sp@'orylationi viscose fiber# washed,
with methanol 'and dried
specially prop@red cotton collulosel cellulose
143

0
/190/63/005/0 3/009/024
phory lat ad polyeacoharides ... 101/B186
B
ipitated -from- tr:ietkylbenzylaamonium hydroxide; and pyridine-enolo
repreo sed
;i@!;;; :i; cellulose. The degree of phosphorylation.increased with increasing tempera-
(80 - 1200G)e 'Gelluloses. with a pho p :.i, 4 _'@-
Ll sphorue content up to 17-09
300 were obtained. -These optimum values were obtained with pyridine
oellulos e reprepipitated'from triethylbenzylammonium h5droxide. With di.
and triamides -insoluble:compounds:arose,containing about 3 - 3.5% nitr ge
0
that cross -linking.is assumed. With monoamides, cellulose phosphinites
':q..'.i:::'were formed, soluble in methanol.. The phosphinites with 5 - 7% P were
Y!
,,!~;~:i.,~,,..,,extinguished'aga.in Yhen the flame was-removed, the esters with a-still
;i'!"Ti@i@zi!higher P@ contenVdid: not burn but only.carbonized. The cellulose esters
th'e trivalenV,'hospho'rus acids are highly reactive. With dry oxygen
,rj: "..:i wlp
i!:@::liN:'; --qua ntite tiv6 oxidation: to @ 'hosphates sets in4
Sulfur adds-with formation
p
the'oellulo:se-.-:thio-phosphates hitherto unknowni
0C H 00 H
00, 2
5
1-0-P -.5
:!i::Cell-O-P + S*_+ Cal e. The cellulose phosphites react with
U\
O-Cell
07-Cell
S
:;!!Ili sulphenechlolifes The,ioellulose-phosp4inites are alkylated by alkyl
j@4
At
H C
@02'5 05
i:@ halid;4p,j Cell.. 4 0 QH Ql 1-RI +
P Celluloas
@ @:'] . V 101,12, H/ -P�?P6R5'
0 H Z2-
@L-Z 5-
Oar&j
T;'@

;/Igo 24
/63/005/003/009/0
Phoaphorylate,d~polyeacoharid6s, BIOI/B186
:Ihalides arise wh1oh -can -be used:as the initial substanoes for the synthesli i
r'of desoxy-9 oyano-I amino-,, apd@other oellulose derivatiyes. There are
'3 tables.
.
SIMMITTEDs
Must
A
e 0;'1961

-V4

Can
7"
7,-
_q

PETROV, K.A.; NIFANT'iEV, E.Ye.; KHORKHO-YAlIU -.,11 L.IVq SHCHERBA, I.G@
I - , --w -
Phosphites and phosphinitem of triols and their derivatives. Zhur.ob.
khim. 34 no.l17O-77 Ja 164. (MIRA 17:3)

JPETROV, K.A.; NIFANTIYEV, E.Ya.; UORKFOY-AJVJ, L.V,; GOLITSOVA R.G.
Phospharus-containing polyipers. Part 8: Syntlies-is and some
properties of polyarylone phosphites and phosphinites.
Vysokom. soed. 5 no.12.,1790,..1804 D t63. (MIRA 17:1)

PETROV, K.A@; BAKY.)VA , 1"'.A. ; FH(II%Fc,;YLNV , 1 V. ; SIINOGEYKINA .; "IrlDlEA , T.V.
Properties of pho3phinlc acid arJ@yarldes. Part 1: 4'.!onoairkyllaryl)
phosphonates. 7hur. ob. Min. 35 no-4:?23-728 lip 165.
(MI,V, 18.5)

PETROV, K.A.; BAKSOVA, R,A.;._KjPWOYA.N'J, L.V.
Properties of phosphinic acid anhydrides. Part 3: Reactions
of anhydrides of phosphinic acids with olefiii oxides. Zhur.
ob. khim. 35 no.4:732-737 Ap 165.
(@JJ.IZA IS- 5)
@.- 1'7iL-,@@, - @, ."i: - --.-I-- -
,@@ .

L 16ooo-66 MVP(J)/ZWTW
ACC NR: AT6004037 SOURCE CODE: UR/0000/65/000/0001031010313
AUTHOR: Yam K A..- Baksova R. A.: Khorkhoyanu L V Rebus, 1. F. o&3
ORG: None
TITLE: Properties of phosphonic anhydrides. Part 2: Synthesis and properties
of ethylenediphosphonic anhydrid
SOURCE: AN SSSR. Otdeleniye obahchey i tekhnicheskoy khimii. Problemy
beskogo eza ro ms in organic synthesis). Moscow, Izd-vo Nauka,
organic
1965) 310-313
TOPIC TAGS: organic phosphorus compound, alcohol, phenol
ABSTRACT: The article presents data on the.synthesis of ethylenediphosphonic an-,
hydride and an a study of its reaction with mono-Ifydric and dihydric alcohols and
phenols. The anhydride was obtained in almost quantitative yield in two ways:
(1) controlled hydrolysis of ethylenediphosphonyl tetrachloride in chloroform with.
prolonged heating
nC12(0)PCH2CH2P(O)CI2 + 2nH20 ---.)p n(O2PCH2CH2P02) + 4n HC1
and (2) reaction of thetetrachloride with tetraethyl ethylenediphosphonate taken
in equimolar amounts:
L94Kd--IL2
7777777777W7V

L 16ooo-66
ACC NR: AT6004037
nCl2PCH2CH2PCI2.+ n(C2H50)2PCH2CH2P(OC2H5)2 -)@2n(02FC112CH2P02) + 4n HCl+4nCHZ-CHj-'-
0
0 '0
nediphoophonic anhydride is apparently a polymer with the formula
and consists of a vitreous hygroscopic ma as
CH2CH2' insoluble in all organic solvents. It reacts
P P
0 n readily with alcohols, glycols, and phe9fle.
0 0 Acid esters of ethylenediphosphonic ac were
-obta ne in good yields from reactioiTs of the
anfi isooctyl, and see-octyl alcohol and p-nitrophenol at 8
ydride with ethyl, 0-
120C. Reaction of the anhydride with 1,3-propanediol and 1,6-hexanediol produced
the heretofore unknown polyphosphonates
0 0
x
-0 (CH2) -0-P-CH2CH9-P-0 (CU2) x
n
OH
3 6
07-,/-,- SIM DATE- lmii"t Wo- i003 OTH
SUB CODE. REP: 002,:
:t
-U
LV
v
c4rii 1/2-

PONOMAREVY A.A.; SKVORTSOV, I.M.; KHORKIN, A.A.
1-Azabicycles. Part 1: Hydrc3tymethylation of compounds of the
1,2-dihydrodipyrrole series, Zhur. ob. khim. .33 no.8:2687-
2690 Ag 163. (MIRA 16:11)
1. Saratovskiy goaudarstvennyy universitet imeni N.G. Chernyshev-
skogo.

ANDREYEV, German Sergeyevich; KHORIKOV A.1 red.; BARMIN, S.F.,
"'I
nauchn. red.; LEBF.DEV-TSVETKOV, YuJu., re..; MITXFANOV,
I.A., red.; NECHAYEV, M.A., red.; RUSAKOVA, L.Ya., ved.
red.; YASHCHURZHIUSUYA, A.B., tekhn.red.
(Firing-line method on main gas pipes] Vedenle ognevykh ra-
bot na magiatrallnom gazoprovode. Leningrad, Gostoptekhiz-
dat, 1963. 110 P. (MIRA 16:10)
(Gas, Natural--Pipelines)

TIKHOMIROV, Yevgeniy Nikulayevich; 001`@'KOV, AJ., red.; 11k.-MTE,
S.F., red.; I-II7ROFANOV, I.A., red,; NE-ECHAYEEV, 'X.A., red.
OLIVOVSKU, I.,G., nauchr, red.; NEVELISHTEIT, V.I., ved.
red.
[Assembly, adjustment, and operation of devices for the,
electrical protection of pipelines] ",ontazh, naladka i
okopluatatsiia ustroistv elaktrozaslichity maglstraltr@ykh
truboprovodov. Leningrad, Nedra, 1964. 126 p.
(MIRA 17:12)

KOMAR, losif Yakovlevich; KHORIKOV, A.I., red.; MITROFANOV, I.A.2
nauchn. red.; RUSAK@TC,-L.Ya. . ved. red.; YASHCMUMNAMA,
A.B., tekhn. red.
[Operational organization of main gas pipelines] Organiza-
tsii magistrallrqkh gazoprovodov. Leningrad, Gostoptekhiz-
dat, 1963. 109 P. (MA 17:1)
(Gas, Natural-Pipelines)

@'fanttvlvevich;
ROV, Ye V, J
red.; TIKHOMIII
, , - -c
V. A. , . -d.
10"afety technique on main gar rdpelina.,: Tt-!kthnik@ )cz-
opasmosti na ii-,agistrallnom grazopi-ovocle. Leninffrad, lzd-
0 11INed-i 11
v - @ 1 1961". 106 p.

FTIOR11TV, I. A.
Electric Currents
Using an out of order electric motor as an inducti-on reMilator, Torf, prom, 29 no,3, -1952
Monthly Lj2L of Russian Accessions, Library
of Congress) 1--1aY 195" UINCIISSIFIED.

ACC NR: AT700-1001 SOURCE CODE: UR/0000/66/000/000/0?24/'OZZ9
AUTHOR: Sipaylov, G. A.; Ivashin, V. V.;-Khor'kov, X. A.
ORG; Scientific Research Institute of Nuclear Physics, Electronics, and
Automation, Tomsk Polytechnic Institute (Nauchno-issledovatel'skiy institut
yadernoy fiziki, elektroniki i avtomatiki pri TPI)
TITLE: Shock generator as an energy source and storage
SOURCE: Mezhvuzovskaya konferentsiya po elcktronnym uskoritelyam. 5th,
Tomsk, 1964. Elektronnyye uskoriteli (Electron accelerators); trudy konferentsii.
Moscow, Atomizdat, 1966, 224-229
TOPIC TAGS: shock generator, electric generator
ABSTRACT: Various methods of storing energy - in capacitors, inductors,
electromagnetic machines, batteries - are briefly reviewed and their applicability
is discussed (R. Curruthers, Proc. IEE, A-io6, no. 2, 166, 1959). The authors'
scheme of arcless circuit breaking of a shock electromagnetic generator (see
Card I /Z

ACC NR: AT7004001
Abstract AT6004000) is hold capable of solving the main problem of using these
generators when the stored energy is over 100 j. Design formulas that connect
the required load energy with-the Arnold machine constant, electromagnetic energy
and kinetic energy per unit of rotor volume, and a utilization factor are deduced.
Numerical examples show that impulses up to 20 Mj for a duration up to 0.04 sec
are feasible. The shock electromagnetic generator operating jointly with a
capacitor bank promises still @igher usable energies. Orig. art. has: 8.formulas
and Z table a.
SUB GODE: 09 SUBM DATE: 06Mar66 ORIG REF: 006 OTH REF: 002
Card 2/?.

L 46778-66 EVOY k I)
ACC NRt AR6014546 SFO~ic-c6O-D-E-:---UR-/--01-9-6/6510-00/01
AUTHOR: Sipaylovp 0. A.; Khorlkov,,_K. A.
13
TITLE: Selecting stator winding of an !r 115/
SOURCE: Ref. zh. Elektrotekhnika i energetika, Abs. 111303
REF SOURCE: Izv. Tomskogo politekhn.in-ta, v. 132, 1965, 181-189
TOPIC TAGS: impuls e current generator, electric generator
ABSTRACT: The results are reported of a theoretical and experimental computer
("Minsk-111) study of the selection of stator winding and number of slots of a
single-phase impulse-current generator intended for producing powerful magnetic
fields. Calculations of several versions indicate that a single-phase, single layer
winding that-fills 2/3 or 5/6 of the total number of slots Is optimal.In the latter
case, the increased amount of copper is offset by an increased generator energy,
with the same distortion of eaf curve shape. The number of stator slots was
determined from the estimated values of impulse power for different slot
configurations in a stator D21 n 7 ml and D % 2 m. The optimal number of slots
lies within 46--60 V. Lyashenko [Translatton of abstract]
SUB CODE: 09

ACC NRe AR6026539 SOURCE CODE: UR/0372./66/000/004/0053/(;053
AUTHOR: Loos, A. V.; liborlkovs K. A,,;_S1paylov, G."A;
TITLE: Mathematical model of combined operation of a surge'gonerator and a capacitor
battery
SOURCEi Ref. zh. KiberneUka. Abs. 4G373
REP SOURCE: Izv. Tomskogo politekhn. In-ta, no. 138, 1965, 124-133
TOPIC TAGS: electronic simulator, generator, capacitor, current density MDN-1
electronic simulator
ABSTRACT: A mathematical model of a scheme of combined operation of a surge generator
and a capacitor battery with Inductive load Is presented. The effect of individual circuit para-
meters on the pattern of the transient process was investjgated with the aid of an MBN-1
electronic simulator, and the resulting findings are presented with respect to such parameters
as: effect of the resistance of stator windings and load on the intensity of the load current;
effect of the natural frequency of the circuit, original charge of the capacitor battery, generator
load and disconnection of the generator and load on the magnitude of the energy transmitted to
gard-, 1/2 UDC: 62-506:681.142:001

I
I I I . . . . . . . I

S6uRcE;_CO_Dr,,: uR/0196/66 000 004/1018 1018
AUTHOR f Sipaylov, G. A.; Khorl kov, K. A.
ORG: none
TITLE : Selection of the size of air gap in a load shock generator
SOURCE: Ref. zh. Elektrotekhnika i energetika, Abs. 41120
REF SOURCE: lzv. Tomskogo politekhn. in-ta, no. 138, 1965, 272-279
TOPIC TAGS: generator, emf, shock load generator
ABSTRACT: A connection is e3tablished between the degree of permissible distor-
tion in the emf curve of the stator winding and the relative size of tile opening of the
stator slots.. This connection makes it possible to determine the size of the gap
when designing shock load generators. [DW]
SUB CODE: 091
Card

It-40WI-66 EWTO
ACC NRo AR6014543 SOURCE CODE: UR/0196/65/000/011/1021/IO22
AUTHORS. Sipaylov, G. A.; Khorlkov,, K. A.
TITLE: Specific energy of an impulso-excited oscillator IIJ51 J5
SOURCE: Ref. zh. Elektrotekhnika I energetika, Abe. 11D27
REF SOURCE: Izv. Tqwkogo politekhn. in-ta,, 1965? 132,, 20-25
TOPIC TAW : pulse oscillator,, kinetic energy
ABSTRACT: The dependence of the specific kinetic energy (per umit rotor volme) an
the rotor diameter D. for a slugle-phase synchronous Impulse pover oscillator (tar-
bogenerator type) is obtained in the fam
&T=4&1*.(,2!jo@10/cM3
where D is in metoers and p in the xamber of pole pairs. Bibliography of 16 Oita-
p
tiow . frranalation of abstrao-t7
SUB CODE: 09
cm iA 127z-

KHM I KOV, L. K.
i
l
h
l
t
Ph
onle
e
r
o
onep
c deter rnlhith@ or zinc to
blood. S.I..
'
-
A. Bitovt. anti . K, tawr,k
-C L)r
1,13itsev, 7

trictric method for thr. dctu. of Zil in as. little ax 0.2 mi. of
kbtmt, which tak" 2-2.5 firs. to coinpicte, is based u a
the miction which readily takes; place betircen Zri and dr.
fit the firtmeller of SCN- in arl'i
rcp@. of chinride:

sn ve 5 g. antipyrin
le In a Hinall Vol. IfjO;.adkI 1-2 lilt. IICI
(tL LIP) ni@tj 1-2 till. Cil.,010. . ll,!at o%@er %vater bath for
;30-40 inin. and ettol. A cryst. - tanss will lonn which'
'

ru,
I
I I be rerrystil. front Itio. Thnnitighly dry In a dotlc-
*
po

r. Prellu
. of the reagent. I' , iolve 1-@ -N
52 g. NTfSC
in 93 till. 'Inuhh- distd. 11,0; now add with const,
*

Chemical Ab3 L, %lifting I ull. 27.
tllc. still. of

8 No
3 filter through 1kiper previnusly washed Mee with double
.
Vol. 4 distd.jL0. The mmiltant is a clear soln. of the reageni.
Feb. 10, 1954 The procedure: Place 0.2 till. of the blood, into a quartz

ical ChemistrY
i
Bi
l Kic)(Ifthl flask, ndd I till. coned, JfrSOj, tuld perhydrol as
camlyzer nud di
est ai mual
Wn
h i
P
t
dkh
i
h
c
.-
g
o .
n
n n
s
t
w
t
g
doubly (listd. Iflo. Rvap. to dryness'belm@ 460* and re-
tuove till traces of SO.. To the dry residue tuld 0.3 nil. N
MI. 9.7 mif7doubly distd. 11:0 itud 0.03-0.05 C. ascorbic
acid orO.0g.of hydroquinone. Shake well and pa." through
filter rper (previntuily washed as above) Into a tro tube.L
Take ) In of the filtrate and addict it 0 nil. of file Zn reagtot.;
mix, anti alloer to stand for 15 min. for max. development.

of turbidity. 7A
-ro point on the neplielometer 6 established
as follows: Take 9.7 till. doubly rlL%td. Jfj0, add to tWs'
0.3 nil. N IICI, 0.03-0:05 g. ascorbic acid or 0.2 Z. hydro-:
4ttinone and wait for soln. to clear, Divide into 2 equsd;
I
rts and add to each 9 nd. of the Zn reagent, inix, let stand:
Va
h
f
i

or 15 ra
en c3tabli.
n., t
-%h the nephOottictrIc zero point.
Now add to one of the tubus the soln, ptepti. f:)r testing an&
make nephelametric rdiding. A nomographtc curve of'
standarrivatuesispreentef. Use either qtwrtz or Pt dishes
B.S. Levine
A-@

1 , - , , ;@ ,
Vo I q t 11 P, i ri h I L, i t o rs c I' me .a'- :3 . NT,-vika 1 iv. n:-,.-4.
604:0 S ' c,@4 .
I I
1. Corre.,ipondotnt, or the A,nlem- of Pt@dnj!.,%j E @ 1.
-1 @t. -lences, @)f
the H; S. F, , it,

5
hhORIKOV 11
--.-
Algorithm for the static calculation surface-typs air
coolers. Toploonergetika 11 no.3:48--53 Mr 164. (MIRA 17-6)
1. Gosudaratvemiy-y vaegoymnyy tsantrallnyy nmwhnC>--.
isnladovatal 1.9 lily imstItut koiTq)lvksnoy tivtovvatizatALI.

KHOLOKOVI P.; TATARNIKOW, G.
Economic work performed on a volunteer basis. Den. i kred.
20 no.4:61-68 Ap 162. (@URA 1514)
1. Upravlyay-ushchiy Tatarskoy respitbliVanskoy kontoroy Gosbanka
(for Khor1kov). 2. Upravlyay-uslichiy Khakasskoy oblastnoy
kontoroy Gosbanka (for Tatarnikov).
(Banks and banking) (Industrial management)

KHORIKOV, V.
Speed sports model. Voon.snan. 34 no.12:32-33 D '58.
(MIRL 12:2)
(Hydroplane boats-Modela)

I : -,- @@ -- - -@ @ - -- ; 1-

__@@OWKOV, V.G.
Party and state control in the chemical industry. Khim. prom.
40 no.11:801-804 N 164 (MIRA 18:2)

GOROBETS, Te.G.; XHORIKOV, V.L.
URing television units in mines of the Irivoy Rog Basin. Biul.tekh.-
ekon.inform. no.10:3-4 160* (MIRA 13:10)
(trivoy Rog Basin-Industrial television)

KHORIKOV. To.I.
.. -..' -' " -1-1.1- ... V--.-
Xnglish walnut in the school garden. Ist.v shkole no-5-.74-77 S-0 153.
(KLR& 6:8)
1. Institut fiziologii rasteniy imeni X.A.Timiryazeva Akademii nauk SM.
(Walnut)

REORINOV, Ye. I.
"Variation in the Leolo[ical-Physiological Con(Aitlon:--, of t:-,e Walnut
(Ju,cdans re(-,ia' Mirinc- AccILTatization in 44vscow." Cand idol -Sci, Inst of
U j C,
Plant Physiology imeni F- A. Tiiniryazevj Acad Sci US:;R. 13 Dec 54)
Survey of Scientific snd TecludeRl Dissertation3 Defended at 'U,&;R
HigLer Educational Institutions (12)
SO:
0
StUd. No. 556, 24 Jwi 55

OZOL, A.M. (Ozols, A.); KHORIKOV, le.l.i-KULITIASOV, M.V., red.; DY@MSKAYA, 0.,
red.; DKIS, R.@ t@@ * r*d.
[Walnut, its introduction and acclimatization) Gretskii orekh, ego
introduktsiia i akklimatizatsiia. Pod red, M.V.Kulltiasova. Riga,
Izd-vo Alcad. nauk Latviiskoi SSR, 1958@ 302 p. (MIRA 14:10)
(Walnut) (Plant introduction) (Acclimatization (Plants))

A.L., umidemiko OVCHAzmV,
ririuk, red.: ",ENKEP ro@d.;
y,r(-,f., red.; PROFC@@"Y-EV, A.A., t.rcif., red.; 1.G.,
k.and. -.--ellkhoz. nauk, red.; SEDLMKO, iJI., red.; GMSFEL',
K.P., red.; KIIORIKOV, Ye.I.p red.
[151ological LAsos of incrensing Of, i,pmI`A;y
neds; materIals of a scientific session helli November
26-30, 1963 in Moscowl iliologicheokle omovy povysheniia
kschesL,ja sen-dan sell okokhozIaistveimykh riwt,eyill, mnLe-
rialy na-aclincii ssssii, sostoiavsheisla A-310 nc--iabria
v 140s@ve. Mloskva@ Nauka, 1964. 278 p.
1. Akademiya nauk SSSR. hist.itui,

POLEVOY, V.V., otv. red.; KHOR'KOV,,.Xp.l.,w rod.
[Plant growth regulatort; and nucloic acid rrotaboIJj-m]
heguliatory rosta raotenli I nukleinovyi obmun. Mo-
skva, Nauka, 1965. 209 P. (MIRA 19:1)
1. Akadem]qa nauk SSSR. Sibii-Aoyo otdolonive. Vostochm-
Sibirokiy biologichoskiy institut.

A I C I
-L L
:0 3
Igoe
CIO 0
re a
00
11400
4
t. SL -tVALLURCKAL WERATURIF CLASSIMATI ft
an,
S; A,v 43 It
"00 jr6c Hit wit F9 (I IT 11 ag
Aaiom*tj, RaPid Makinig I
Firporad'.. 8 A Krrmetit and it hi
KII)T@gV11, Indusirjal poij-j., ( V.V S R
'Ist. 1947. v. 2.13.
Electrical circult for stweditig tip fit,,
0131pulation of Plectrodrs during Me
llu-timou of electric furrinces.
"
In.
I I a w w I ff
AR
110 If 1 9.
000
141
bee
ties
we

DEVYATOV, B.N.; KHORIKOVA, GI.S.
Analysip of the dynamic characteristics of counterlow-t)pe
Industrial processes taking into account change in the speed
of the mediap Trudy Inst. avtom. I elaktrometr. SO AN SSSR
no.8:80-92 164. (MIRA 17:11)

I
DEVYATOV, B.N.; GIMLISHEYN, F.Ya.; XRORIKOVA@-G.-S.._
Using distributed control for creating high-quality control systems
for technological processes of heat and mass transfer. Izv. SO
AN SSSR no.2 Ser. tekh. nauk no.lt60-77 163. (MIRA 16:8)
1. Institut avtowtiki i elektrometrii Sibirskogo otdoleniya
AN SSSJI, Novosibirsk.
(Heat-Transmission) (Mass transfer)
(Automatic control)

S/200/61/000/008/001/004
SAO D218/D306
AUTHORS, Devyatov, B.N.p and Khor1kova, G.S.
TITLE: Inertia and regulation of counterflow heat exchangers with
variable-speed heat carriers
PERIODICALz Akademiya nauk SSSR. Izvestiya, Sibirskoye otdeleniye, no.8,
1961, 36 - 43
TEXT- In previous papers the first of the present authors and Yu.N.
Kornev (Ref I-, Ti-. Tri-ta avtomatiki i elektrometrii, SO, AN SSSR, no, 2,196S)
and S,V, Lapshin (Ref 2! Tr, In-ta avtomatiki i elektrometrii, SO, AN SSSR,
no 2, 1960) discussed the transfer functions for heat exchangers of the "
tube in tube" type and discussed their inertia and regulation u.ider steady-
state conditions, It was assumed that the velocity of the heat carriers was
constant, In reality, the velocity is a random function of time and hence a
steady-state theory cannot be used. These and other considerations necessi-
tate the study of the dynamic properties of such heat exchangers, The set of
equations which describes nonateady state processes in a counterflow heat
exchanger is of the form Eq. (1)
Card 1/10

inartia and regulation of ... D21 6YI)306
u
9
3t _x 1 (U2 U1
aul)
(U
at '2 a x 2 1 2
where U and U is the temperature of the two moving media in the heat exch-
1
anger respecxi@ely, w 1 and W are the linear velocities, and X 1,76', are
coefficients desc'ribing the Keat exchange between the two media. Sifice the
velocity is an arbitrary function of time, these equations have variable co-
efficients and their general solution is difficult to obtain. The tranofer
fuxif,-tionn for the problem may be found in two ways. Firstly, one can deter-
mine the solution for a step-change in the velocity, and secondly, one can
obtain an approximate representation of Eq. (1) by a. nonhomogeneous system
with constant coefficients. The present authors show that the first method
does not lead to the required transfer function but leads to a rather in-
':[e-mail] formula whioh is a nonlinear function of the velocity change, It
I-S, therefore, concluded that it is of doubtful value for practical purposes,
A. simpler, and linear, transfer function can be obtained by the second of
3120 61/000/008/001/004
"ir-d 2/ 10

27729
S/200/61/000/008/001/004
Inertia and regulation of ... D218/D306
the above two methods. When the steady-state conditions are disturbed, i.e.
when there is a change in the velocity, Eq. (1) assumes the form -Eq. (6)-
(111(' + a fit) + (w, + A WO 0 (U10 +it, (U'. + A".,)
ot Ox
.- (1110 + A it,)],
(117f) + (W2 + A w.) () (Uaj) +U2 = X2 10iJO +
ox
(U20 + A UO 11 (6)
where u 10 and U2 0 are the steady-state values of the temperature of the first
and second media at t=O The equations representing the steady-state condi-
tions are of the form -iq. M_
DU10 + w I . X, (U20 U
)q
'at -0 x JO
u
20 -
w 2
)0
2 (U
0 U
(7)
bt b x 1
20
Card 3/10

27729 1
S/200/61/000/008/001/004
Inertia and regulation of ... D218 D3o6
where -10 u20 Subtracting Eq. (7) from Eq. (6) one obtains
t a t
the following two equations:
Du 1 + W, au 1 +Awl (t) !u 10 +A WI(t) ,ou 1 -Z (U U
1 2 1),
dt x d x x
U2 - w @u "U20 -A, W M Ou U
2 -.a w (t) 2 U
jat 2 @Tx 2 3x 2 x @2 1 U 12 @3u 2,
Assuming thatz@w(t) are small and neglecting,8w,(t) 7-
x and 4 w2 (t) .-3 x
one obtains the following differential equations with constant coefficients-
Eq. (8)-
u
+ W U W, (t)
1 = X 1 (U2 1 x
t @x
u2
t2 - w 2 U1 - U2)+ '@X w2(t)
o x
-i t x
Card 4/10

Inertia and regulation of ...
27729
S/20 61/000/008/001/004
D218YT)306
This set of equations will hold only in the case of small perturbations. The
solution may be found with the aid of the operator method subject to the fo-
llowing boundary conditions;-
U, (X1, 0) - 0, U2 (XII 0) = 0,
U, (0,t) = .1(t), U. 2 (11+') 2(t)'
The final transfer function is then found to be Eq. (9)
+
W., + @,) I
a2 (9)
K,, K..C a-+)" 01 - CL2 + X1 P_-I + 21 + )2 al
pT,+a,+X, p,,,+aj+ 12
where R11 01, + 1@
(xI + p+ el, - (k2 + P -'I + 01) el-
a2 7-
WS W,
Card 5/10

27729
S/200/61/000/008/001/004
Inertia and regulation of ... D21a D306
and C is the temperature difference between the first and second media at the
output of the apparatus in steady-state conditions.The above transfer func-
tion is convenient both for studying the dynamic properties of heat exchan-
gers and also in practical calculations concerned with control problems. A
consideration of the transfer functiora obtained in this way shows that when
there is a change in the velocity and the steady-state conditions are thus
upset, the transient process at the output begins instantaneously, i.e. them
is no delay, which is consistent with the physical interpretation of the pro-
blem. It follows that the operation of the heat exchanger may be better con-
trolled by adjusting the velocity of one of the media rather than by adjust-
ing the temperature. In practice, it is convenient to define the inertia of
the heat exchanger. The inertia is numerically equal to the area between the
transient process curve and the straight line corresponding to the new steady
state conditions, i.e.
I M FM U, (01 dt
Card 6/ 10

Inertia and regulation of ...
27729
S/20Y61/000/008/001/004
D216 D3C6
where m is temperature in the new steady-state conditions. The inertia can
also te expreeeed in tei-me ot the t=ansfex- funalion Rof 1.)f
I lim [1 nK, , ]' ,
P40 (10)
A further uq-ful quantity is the dimensionless inertia which may be defined
by
S = zi I+ 'r2
Since the transient process in this case occurs immediately, i.e. there is
no delay, the inertia is also a measure of the regulation. Using the linear
transfer function given by Eq. (9), it is found that the inertia is given by
- Eq. (11) - (C4I-N 2 2 ok Ck.,
2 (OX 1 -M2) - -2 - 3 + e (3 +d,1 -(A2)
S - S
1 +qP2
(0(1 _C@12)2[0(1 ((X1 -':X2) U2 (1 - e0@ 2 -r3k1
Card 7/10

27729
S120 61/000/008/001/004
Inertia and regulation of D216YD306
(S
N
C@
Pi C)(
1
2
2 1 2
2
2 e 4 2
2
U 1(cjj _(@2 cf\2
where
+
@@ 2
1 - e 2
and S1 is the inertia when the temperature of the first medium is disturbed,
an gi@.ren by
S1 - CA 1 cy. 2
2 -rX 1 2 -Oki
tj__ (JI 2(1 e 2(1 e
2(CK e C@2
2 1 -()(2
+
Card 8/10

27729
S/20()/61/000/006/001/004
Inertia and regulation of ... D218/006
The above formula gives the inertia of the transient process in the heat ex-
changer as a function of its parameters D(, , C& 2 , and Vi . Fig. 2 shows the
curves od equal inertia. This figure is convenient in the selection of the
optimum control conditions. However, the values of the parameters which co-
rrespond to the optimum control conditions do not always ensure that the ap-
paratus will work satisfactorily in other respects. Fig. 3 shows typical
plots of curves of equal inertia for given values of'C**. Other figures re-
produced may be used to determine the inertia for any values of0( 11(@(V`C
In this way, the authors obtain a set of graphs which describe the changelin
the inertia as a function of the parameters of the heat exchangers. These
may be used to select the optimum parameters for control purposes. There are
8 figures and 3 Soviet-bloc references.
ASSOCIATION: Institut avtomatiki i elektrometrii Sibirskogo otdeleniya AN
SSSR, Vovosibirsk (Institute of Automation and Electrometry
of the Sibirian Branch AS SSSR, Novosibirsk)
SUBMITTED: February 7, 1961
Card 9/10

KHORIKOVA, N. N.
KHORIKOVA2 N. N.: "The rate of restoration of nucleoproteides included in
varloua fractions of brain protein". Leningrad, 1955. Leningrad Order
of Lenin State U i*eni A, A. Zhdanov. (Dissertations for the degree of
Candidate of Biologics4 Sciences.)
SO: Knizhmya Letopis t No. 50 10 December 1955. Moscow.

2 V01.10/10 Pt@y. ,ocna-.. Oct 57
R:qA Se-C.
43 0 4. KHORKOVA N. N.- Dept. of Biochern. , State Univ. , Leningrad. * R a t e of
phosp-Fo-rus incorporation into nucleic ac;ds of various
protein fractions of brain tissue (Russian text) BI0KHl-
MIJA 1956, 21/6 (709-714) Graphs I Tables 4
Proteins were extracted from the brain successively with distilled H20, 1 .11 NaCl
and I N NaOH. The 4th fraction was the residue; RNA and DNA were extracted
from the proteins of these 4 fractions. The rate of P incorporation into (INA of
the aqueous fraction was 5 times as great as into RNA of the salt fraction. and
that In the DNA of the aqueoua fraction was several times greater. Itenewal of
RNA phosphorus of these fractions was several times greater than of DNA phos-
phorus. Renewal of nucleic acid P of the alkaline protein fraction and of the resi-
due proteins was so small that it could not be detected by the methods used. The -
rate of P incorporation into nuclear RNA was greater than in cytoplasmic RNA,
and that into the R14A of nucleus, and cytoplasm higher than into DNA.
I.. Ufe(trs bi*HUH LeninUadskogo goeudarstvennogo universitete
Iment A.A.Zhdanova.

IV,-IOC W6,4,4, L". 6--.
MDGILEVSKIY, Ye.M.; KHORIEDVA, O.G.,; MIGER, G.G.
-*,,,I-- -
Desulfurizing viscose fiber with.solutions of surface-active
substances. Tekst. prom. 18 no..11:9-12 N '58. \ (MIRA 11:12)
(Rayon) ADesulfuration) (Surface active agents)

YOGILEVSKIY, Ye.M-;_MQ94@Ap.
VAp O.G.; KMNSKIY, R.V.
9 1 -5- ,
Produotion of viecous milk by the cottinuotw method.
Xhim. volok. no.2t53-59 '59, (MIRA 12:9)
I.Vaesoyusmy nauchno-ionledovatellskiy institut lskunstvennogo
volokna.
(Ravou)

5.14CO
77279
sov/63-4-6-13/37
AUTHORS: Mogilevskiy, Ye, m. (Candidate of Technical Sciences),
Kupinskiy, R. V ., Kh.orIkova, 0. G.
TITLE: Machinery for the Continuous Process of Viscose Rayon
Production
PERIODICAL: Khimicheskaya nauka I promyshlennost', 1959, Vol It, Nr 6,
pp 770-776 (USSR)
ABSTRACT: This is a review of literature and industrial data con-
cerning the construction and use of machinery for con-
tinuous process of viscose rayon production. The authors
stated that in the USSR viscose cord is produced only by
the continuous process on machines designed at the All-
Union Scientific Research Institute of Synthetic Fiber5
and produced by the Machine Works imeni Karl Marx
(S. A. Tairov, A. B.'Chic&hiani, Equipment of the
Synthetic Fibres Factories, Gizlegprom, 1955, P 349).
The factory equipment of German companies "Bemberg" and
Card 1/2 "1. G. Farbenindustrie" and U.S. "Industrial Ray. Corp."

Machinery for the Continuous Proce3S 77279
of Viscose Rayon Production 5011/,6 -6 - 13/37
are described. Schematic drawings and descriptions
of the following machines are given: "Nelson,"
"Maurer," "Textima" (designed and produced in Eact
Germany), and others. There are 22 references, 2 U.S.
3 U.K., 3 German, 14 Soviet. The U.S. and U.K. refer-
ences are: S. W. Barkor, R. Albeston, J. Text. Inst.,
39, Nr 1, 3 (19118); ibid. , 39, Hr 1, It (1948); Br-ttish
Patent 1M95, 1907; Olive, Chem. Metall. Eng., 45,
168 (1938); Ray. Synthetic Text., Nr 6, 39 '(1950).
Card 2/2

3/'185/60/000/003/015/016/XX
B004/BO67
AUTHORS: Mogilevskiy, Ye. M., Pinger, G. G,, and Khorlkova, 0. G.
TITLE: Distribution of Elongation Deformations In Viscose Pibers
PERIODICAL: Khimicheskiye volokna, 1960, No. 3i PP. 41-43
TEXT: The authors attempted to find out whether the viscose fibers
produced by discontinuous centrifuging in the form of cakes differ from the
viscose fibers produced In a continuous process. The experimental data con-
cerning breaking length, elongation, and bending test are given in Tables
1, 2- Table 1. Physicomechanical characteristic values of rayon in the
layers of the cake
Layers of the cake Yarn breakin g length,km elongation, Number of
number dry wet dry wet double bend
I ings
ore
bef outside
7.26
2 14.2
12.8
7
13. 1059
shrinkage center 7-18 25.6 14.0 13,1
1 14.6 1087
inside 1 7.18 1 24.9 1 13.1 13.7 15.2 -
1 1213
Card 1/3

Distribution of Elongation Deformations 3/183/60/000/003/015/016/XX
in Viscose Fibers B004/BO67
Layers of the cake Yarn breaking length,kir elongation,77 '14umber of dou

after number dry we t dry wet b 1 e b a ndings
shrinkage outside
center
inside 7.15
7-05
7.15
I- 24.0
24-3
21.8
I 12,,3
12.0
11.2
- 13.1
13.7
14@2
I 13.9
14.7
15.6 1192
1028
178,11
_j
Table 2. Physicomechanical characteristic values of the fiber produced
in continuous processes
Fiber Yarn breakin g lengt km elon etion, Number Type of
number dry wet dry wet of dou- drying
ble bend- rollers
_ _7
_
- ings
before 7. 4 T 6.7@
2
13.4 8.7
14@6
1258 Two cy-
shrinkage linders
7.24 26.6 12.9 9.7 15.2 !615 Cone and
cylinder
7.34 27.4 13.2 10.2 15.3 1693 Two coneE
after
shrinkage 7.0) 24.8 12.2 13.6 15-2 1466 Two cy-
linders
Card 2/3

Distribution of Elongation Deformations S/183/60/000/003/015/016/XX
in Viscose Fibers B004/BO67
The values of the fiber obtained by the centrifuging method are differert
withIn the cake, and lower than in tho fibQ.P Dtt6duced In a cont!ALiQvp
P-qqquav 'Furlliermor@, the revor@fble and irreversible deformation iere
determined In the case of elongation. Elongation up to 40% of the breaking
elongation is fully reversible . With stronger elongation, the irreversible
deformation increases linearly. Here, the fiber produced in a continuous
process showed lower values of irreversible deformation. There are 5 figures,
2 tables, and 6 Soviet references.
ASSOCIATION: VNIIV (All-Union Scientific Research Institute of Synthetic
Fiber'0
Card 3/3

MOGILEVSKIY, Ye.K.; :MCR!XOU,-QQ,.-. FINGER, G.G.; PRUVODITELEVA.,
A.D.; KUZOMIMA, G.P..; HIEUTLEIZO, P.P.; TUMAYAN. S.A.
Continu-is process for producing viscose rayon and for its
flnishirL4. Xhim. volok. no. 6:25-27 160. (MMA 13*-12)
1. Vsesoyuznyynauchno-losledovatellskiv institut iskusstvennogo
volokna (for Mogilevskiy, Ihorlkova, Finger). 2. Vsesoyuznyy
nauchno-issledovatel'skiy Institut trikotazhnoy promqshlennosti
(for Predvoditeleva. Kazlmina). 3. TSentrallnyy nauohao-iseledo-
va tell skiy. Idetitut shelks (for Mikhayienko. Tumayan).
(Rayon)

CA
nyy raw hf.c- 5 t@

KHORLIKOVA. L.Ya.
Production of glass for mcport in Czechoslovakia. StekA ker.
20 no.2t4l-,42 F 163. (KMA l6s2)
(Czechoslovakia--Glass manufacture)

7
-i@tsa lit I. Y1 c III @-4,4 i.,)* j@i3 I-Sil .
Il. Reactions of
e. in& alcr tun. f
KoLlic kov qnd@L Yu KI folyinsethylinatuntsk, It, IIW-3% d. I.MT7. ill,* 1.,1576; (fit-.
-korilw-Gioscow/1 11
liv fir. Schd Khios. 2 Shakell with coned, IfOr 3-1 days.: -1 ht-atml to 30 -111' is(
KSCRI. '3 -I'c acid. it). 11C -I'
anti 7-1 3-chloromethyllsoxnzole (1).7 lwt. lot cil-r- (front 11-0). Thk relluxed with Ilcl tind C41f, with,
dibl. and ulsill4ig trave 711"S i.:ex -Ole. In. a?.etjtropic removal of 1110 gave Aqj-isOxu@1s1y1)prqpig)m;c,
52-3' (I'ttim 1)
ell'. Olltx). land IZOAc Ili A,@t gavvdier
3 I'm, rk-flklix )is, "NARV I tmatvd -kj. rtXII 45 min. ut 70-80" Iraw.
'd. 1.11,122, til," L-1570. To it hot "In. of KC N Ill aq @ 1, j() I i ifi-11tylawit ..... . ;,', diuwazole It.- 60-G.W. d. 0.(17,811
@Ivas addell I and, aftcr tilt: ittitittity Vi,.j@.tutu;:tV;tV1iatt t1le 1. hl@)4., pwfu.,@. m. XI -al.5 I with coltO. N11,011, @.ktd.
voistintionsly wit". NI h I lars. pvc -13.5t"O
Mixt. tepw, r"luxt-11 1,5 br-;. )-idding Ms,'(, i-epintum-1hylisa.v- . - i. 1 3,;
A,,", e
mole, It, .1ri* 81. il@, 1.1781. d;" L-1720, which --it Aa 4 In. fir-
ilCl 'wit. -kvump. lsl@ I mi-wd with ulotfopisw ill
iolislific", m. 15 l1pfwjpi,q at ro.111 tump: 3 day.-i lit
culked. lICI gav'i'S6% issoxin-4-3,tedic udd,@ ill.' Cl let, fulut, a 'I'Vintill, 14)(1 -lit', wiliell k(m,
cill'). Itt-Aittg (Ilii witt% powd. ell
1"', 11s "crill. ImIx", ul"', 1.4%315. The Orn, chem. V.S.S.R. 25, 1159 63( 195:, @1 Fligi,
'wil
the ;tcid witli Cil in flaillolille. I tnalAttion). G. NL K. 4.,
C I I (C( 1@ I
- . ill I(W.111.
(;.5 fir. m6111 f;J 1-.301 .1
I; Al'i
I's @t -10 rit", I11r.;ll ",4 (its' mul If..', l1r.0 110" tlu@
mixt.

-KHO&k4M:- A-:4
@w till
Oi4 N@
z a P -':'4 -
......... ..
Nvu-
Me
.m,fj-
r
ilia,
- - - -- -----

ti i_I
USSR/Organic Chemistry. Synthetic Organic Chemistry. E-2
Abs Jour Ref Zhur - Khimiya, No. 8, 1957, 26699.
Author Kochetkov, N.K@, Zhorlin. A.Ya.,
Gottikh, B.P.; Nesm'6_y@anov, A-.N.
Inst Academy of Sciences of USSA.
Title Synthesis of Alkanyl-,d-chlorovinylketones.
Orig Pub : Izv. AN SSSR, Otd, Ichim. n., 1956, rio. 9,
1053 - 1058.
Abstract : The following methods of synthesis of alkenyl-
.6 -chlorovinylketones (ACVK) were developed:
the method of direct condensation of acetylene
(I) with chloroanhydrides (CA) of oc,,d-unsatura-
ted acids in presence of AlC13, and the method
of condensation of I with CA 6 c(- orB-chloro-
replaced acids in presence of AIC13 with follow-
ing dehydrochlorination of the produced CC-
Card 1/6
------------ --.1--, .................I....... ...... --------------------- ----------

USSR/Organ-4c Chemistry. Synthetic Organic Chemistry. E-2
Abs Jour Ref Zhur - Khimiya , No. 81, 19577 26699.
(or B) -chloroalkyl-,6,-.chlorovinyllcet one. Ex-
periments with CA of 0,-, or _/9-bromoreplaced
acids did not succeed. It is shown that ACVK-
react with ,d-naphthol (II) in presence of
FeClj producing ferrochlorides of 20-alkenyl-
naphthopyrilium. 88 g of CA of butyric acid,
119 9 Of S02C12 and 1 9 of 12 are heated (146'
to 50 hours at 90 to 1100)9 distilled.@,the
fraction of the boiling point 115 to 1500 is
collected, shaken with mercury, distilled
using a column still (10 to 15 theoretical
lates); the yield of CA or CC-butyric acid
I) is 60.3%, boiling point 129 to 1320/
M
756 mm' n20D - 1,1+475, dj+17 - 1.2360. CA of
cara 2/6
USSR/Organic Chemistry. Synthetic Organic Chemistry. E-2
Abs Jour Ref Zhur - Khimiyal No' Bi 1957@ 26699.
isovaleric acid,%16? 9 Of S02C12 and.1 goof 12@0/
the yield was 5 , boiling point 145 5 t 146 "
749 mm. I is conducted into a solution of 81 g
of CA of 6 -chloropropionic acid M in 150
mlit of CCD+ (6 hours) and 85 g of AlCl is
introduced (2 hours), at 10 to 150), po@red
out on ice, CHC1 is extracted with 63 g of
a mixture of vin@l-,A-chlorovinylketone (VI)
and B -chloroethyl-.,d -,chlorovinylketone (VII)
treated with 65 g of C6H5N(C2HI)2 (VIII) at
about 200 and 1 hour at about 000 diluted with
ether, filtered, waqhed with 5% H2AO+' the
yield of VI is 31.5%, boiling point L@A to )+9.501
14 mm, n20D zl-4938, d4 20 =L,127LF. 57 g of a
Card 3/6
.......... ...........................

USSR/OrganicgChomistry. Synthetic Organic Chemistry. E-2
Abs Jour Ref Zhur.- Khimlya, No. 8, 1957, 26699.
mixture of propenyl-.9 -ahlorovinylketons
(IV) and cC-ehloropro yl-,4 -ohlorovinylkotone ,
boiling point 81 to 960/15 = was received.-
analogously,of.81 g of III anA 85 g of AM 3
in 200 mlit of CCI
.4 by conducting 1 (7 to 8
hours at 15 to 20 3- aftor the treatment with
51 g of VIII this yield of XI was 47.3%,
boiling goint @O to 720/ 10 mm, melting point
38 to 39 . A fraction of the boiling.point
of 78 to 920/10 mm was received in the amount
of 30 g from 60 g of IV and 60 g of AlCl
in 150 mlit of dichloroet1heuie (X) by conhet-
ing 1 (7 hour3 at 15 to 2'00); it was treated
with 32,5 9 of,VIII ield of isobutenyl-.A -
chlorovinylketonO UIT was 32.7%@ boiling point
76 to 790/11 mm. 11.3 9 of AlC13 is added to
Card 4/6

USSR/Organic Chemistry - Synthetic Organic Chemistry, E-2
Abst Journal: Referat Zhur - Khimiya, No 1, 1957, 848
Author: Kochetkov,, N. K., Khorlin, A. Ya., and Karpeyskiy, M. Ya.
Institution; None
Title: Direct Synthesis of Aryl-y&chlorovi-nylketones
Original
Periodical: Zh. obshch. khimii, 1956, Vol 26, No 2, 595-598
Abstract; A conienient method is described for the synthesis of aryl76-chloro-
vinylketon6s ArCOCH : CHC1 (I), where Ar can be C , n-CH3CA
Zsic,T (b), n-ClC61I4 (c),, o-BrCQ% (d)., n-NO@2C6H4 fel 2TTr. Note: n-
apparently is equivalent to p:/-, by the direct reaction of ArCOCI
with C2H2 in the presence of AlC1 and ethylene chloride. To a solu-
tion of 100 gms C61'5COC1 in 100 ml ebtylene chloride cooled to zero
degrees, 95 gms of anhydrous AlC13 are added with cooling and constant
mixing ttemperature 100); next, C2112 is passed through the mixture
with vigorous stirring for 6-7 hours at 40-500; the reaction mixture
is then poured over ice, and the organic layer separated and dried
Card 1/2
ether).
Card 2/2

z T

lc@ 16# K
UC I dAhL izy.,,@ p#,
A
of

Qjc,,jnJI Et8ji ;Z.
dravi
,
*
@

wed b 7
Na In UtOHj follo 13r 15
CHICO& was Wid 411
g
"
thece *a$
S. S-A c G44109 Of I and h1ter 17 hra. at@ 601
-11b
taInrA 73A% M 2@aUlObkY441j:
'
P
M
et
wh;ch giv-S Sk
bt., -144-6% -sj
1.4803i
-@hlorob
of
bcpv&@cnc xvith CHt(C(hEt)j and NP@Ju HtPH 78 70,
di-Pi
148.5-9,5*, M. M-20" Whoso
ation,
W ovir Pd
e
f #1
1h i
11id
o
n
rog
p
1
B191 'in MR pve the said., andtai. Id
* i4ith ibove;
dC=Ibed Opectmen, Rv=tlor 2.3 g.
t
5
2111t
-
-e
ep
Na, and 12.11 g@ 2-bcnxoyW-c ne
JOE

material up
In Cius Save in 20 hra. at 60', and rcmovA q
ON 12W*,-&dark=sldue(I31G.).WI1kl I Withaq
' `
I
`k'
I'VI
s
I
-
i,
dj,-K
KOI1 I br-gave 2-benzoYlUbw
M.O
AZ
e free
ivx-4-ylawknafs, which with dil. TICI PY4
_
'
dt:
d1stillate
'00* gavt a
dtcomp. 135-7*. Heating III to 2
''

X#tOH and cyclopouLadlene, and e resIdue in
distg,
VMO juve "clAyl-3-earbdbox" Simi
@ IRk, '
t
19 eydo tjk-@@
lar treatment of the 2-112 analot o
l
r 'c,: m, A-o*
-and
-38% 6-Phdny1-j4arbc1hvxycO
dleq6

6.5*. Sl
dail.2,21 .
ow distu. of UtOll from 10 1,
hept-311malonatc and 1.0 9, N Y_
R-R@ 2-adetylbic
r
i (a 30-ML RtOH-
:,Imtll a f reely-flovviug,powdtr was Pvc on aq.
f th
t
E
0
d4
oti O
e SQ.
treatment and exta. wItIV
4
A k
,
'
1;1
myer 2.88, g. Ouri
the total:
159.5-60* (from Met
#aPhtkdkne, m. ' IMF yleld'
ilar treat- j
e
Si
id
ki
th
7k;
Qj
f
s was
e res
u
m
,
ter,wor
a
ng Op

:

A,
uu@nV of the 2-proploryl anal g 9.
0 9qvf
135

KIIORLI14, A. Ya., Cand Cheri Sci -- (dis. the
"Invostigation
I series WO B@,cyclo-U.2-2)hoptanA." Nos, 1957. 9 pp (Mos State
Univ im M. V. Lomonosov@ Ghomisti-j Faculty), 100 copies (KL,
47-57, 86)

1) @ i@l i- / A.` ;), //,;) @ 452
q
AUT`F1dHS: K
imkO'J9 V, T., @horld, A. YA; Mikhalov, V. A. i Skoldinov, A, P";
Kochetkov, N. K.
TITLE: Beta-Aminovinyl Ketones. Part 7. Reaction of Beta-chlorovinyl
Ketones with Tertiary Amines (Beta-aminovinilketony. M.
Vzaimodeystviye beta-khlorvinilketonov s tretichnymi aminami)
PERIODICAJ,: Zhurnal Obshchey Khimii, 1957, Vol. 27, No. 1, pp. 62-65 (U.S.S.R.)
ABSTRACT- The reaction of beta-chlorovinyl ketones with tertiary amines was
investigatea for the purpose of obtaining quaternary ammonium
salts containing the ketovinyl radical. Beta-chlorovinyl ketones,
when subjected to numerous reactions, are capable of exchanging
their highly mobile chlorine atom into other groupings thereby
forming beta-substituted alkylvinyl ketones. The reacLion was
found to be so smooth that it has been recommended for the separa-
tion of beta-chlorovinyl ketones without their preliminary purifi-
cation-'directly from the reaction mixture. The same smooth reaction
was observed also in the case of pyridine (a similar experiment
with methyl-beta-chlorovinyl ketone and pyridine was carried out
by A. Ya. Yakubovich and Ye. N. Merkulova (6). Very interesting
results were obtained during the hydrolysis of one of the obtained
Card 1/2 salts - triethyl-(beta-benzoylvinyl)-ammonium chloride - when
Card 2/2

79-2-38/58
AjJTHCR S: Kochetkov, N. K.; Khomutova, Ye. D.; Karpeyokiy, M. Ya.: Khorlin, A. Ya.
TTTIE- Study of Isoxazole.' Part 3. Synthesis of Aryli@oxazoles (Issledovaniye
v ryadu izoksazola. III. Sintei arilizoksazolov)
PERTODICALi Zhurnal Obahchey Khimii, 1957, vol 27, No 2, pp. 452-457 (U..S.S.R.)
ABSTRACT: It is shown that eryl-beta-chlorovinyl ketones react with hydrochloride
hydroxylamine under the ver- same conditions as their aliphatic analogues.
When both components are heated In methanol, they produce high yields of
arylisoxazoles. The reaction of alkyl-beta-chlorovinyl-ketones with
hydroxylamine yields a mixture of alpha- and gamma-isoiz6rs (5-*ahd 3-
substituted isox-azoles) with 50 - 60% of the alpha-form. The reaction
with phenyl-beta-chlorovinyl ketone produces a mixture of alphe- and gama-
phanyllsoxazoles in approximately equal amounts. The alpha-isomer content
in the phanylisoxazole was 62-67%. Phenyl-beta-chlorovinyl ketones with
substitutes in the aromatic ring react smoothly with hydroxylamine,
giving high yields of arylisoxazoles. It is shown that the ratio of the
alpha- and gamma-substituted isaxazoles formed during the reaction'of
Card 1/2 beta-substituted vinyl ketones RCOCH . CHI with hydroxylamine depends

Study of Isoxazole. Part 3 79-2-38/58
upon the nature of the substitute X. When the substitute X z NR2, the
reaction yields a practically pure alpha-substituted isomer.
Experiments also showed that alkyl-beta-dialkvlaminovinyl ketones during
reaction with hydroxylamine gave high yields of alkylisoxazoles and the
reaction in this case tends exclusively toward the formation-of alpha-
Isomers.
There are 13 references, of which 6 are Slavic..
ASSOCIATIOU: Moscow State University and Institute of Pharmacology end Chemiotherapy
of the USSR Academy of Medical Sciences
PRESR, TTED BY
SUBMTTTED: Febrniary 20, 1956
AVAILABLE: Library of Congress
G,-rd 2/2

of eye 0
k-4
Kh @Iand 0 State mv.
-36.6 2-amyl Ilorn c .2

-
hvtue@
it
to 160
MI
It 3 his
UhN
$CPO
,
.
-
.
.
.
d adding SN HCJ ve
jzoneg-tite filtrate an
.Of neutild ruterkth with utlo; oil %V by addit. or.100j-a@
iath cy in glojl.2.2@heprane
Al). b, 10"0, xV 1.4 dZI 0.9 5
17 3%@ .1Ldre1yWcydoj1.1 -Ojhipl-2-enc, b, 0-1HVj nU
'
'
:: Pic - jajt@ M,
X formed',
at
Ial@-21; *dhWW Mniliir
io
e
t
coud
nsat
ot
:
-
!
Wc gave 62
2-wwp&mryl
44no,'bi 11T 10 -i il? IA812,dw picfCle. ni. MAI;
'
@'n
0- 'Si
'143
dkfi:
l
it
5
2
43
A
-
-4
-
lo
tu
tn
ur
y was prtpd.
(
70
yry,
'
@
iL
4W8 Z07172
a
l
36

sm
vn@
1
u
y was
;
"J.21h0tans, M.
ftnd@ s g. CH

-3 MM hiat@d In 25 inl.'EtOff and 0A j. Ni Id lirs. at'.
":
1@
I
i

- 2-acelyj-
o di-JU
5
dUd.
vith !W"d AddlW, gave 40
,
xl? 1.4720 (cf,@
"
*
u in@fr*kcnAiydrawxo, tn@, 1W. z I inetbin-
24
'I. dide 'dwc
QHt)# Slittually
v
e
r
Itipn0cal
t
4
wl
G. K2MI

ARUNDARUK, A.P.; BUDOVSKIY, B.I.; GOTTIKH. B.P.; KARPEYSKIY, M.Ya.
KUDRYASHOV, L.I.; SKOLDINOV, A.P.; SMIRNOVA, N.V.; KHORLIN,. A.Ta...
KOCHETKOV, U.K.
Dihydrosarcomycin and related compounds. Part.10- Zhur.ob.khim.
27 no.5:1312-1318 MY '57. (KLRk 10:8)
1.1natitut farmakologii I khImioterapii Akademii meditainskikh
nauk SSSR.
(Antibiotics)

7@-12-2/43
AUMOR: Kochetkov, N. K... Miorlin., A. YrA.
TITLE: Derivatives of
-p-Lenes una S @
geptana). III. 2-AV1bJcyc1rL1,_- nm of Their
Reactions (2-Atsilb_JtsJ,klo(l,2,2 gepteny-2 i nekot-oryye ikh reel@tsii)
PERIODICAL: Zhurnal obshchey khirail, 1957, Vol 27, ur 12, pp 3182 - 3189.(USSR)
ABSTRACT: Reaction of 5 g. P-MeC6H4OC-HCC11CL with 5@3 g. cyclopentadiene over-,
night in petrolem ether gave 75% 2-(p-toliiyl)-3-chlorobir-,yelo[l,*2,2]-
hept-5-ene., m. 91.5 - 20 (EtOA..*.'). SAmilexly vere obtained: 80r,j '
2-(P-chlorobenzri.yl)-3--chl.orobloycl-,[1,2,2)hept.-5-ene (I), m. 94.5 - 5*;
76% 2-.(p-riitrobenzayl)-.3-chlrrobicycl-o(1,2.92]beFt-5-ene; m. 147 - 8'
(AcOH). Hydrogenation of I over Pd gave 2-(p--ch1orcbenzoYl)'bicyclo-
(1,2,2]heptane, m. 109 - 9,5- (E@t-QH'; auch bydrogenations proceed
more rapidly in MeSO than in ktoil or Ft2O,, Heating 40 g. 2-acetyl-
3-chlorc)bicyclo['~,2.2]h,~:ptane in 06116 with 100 al. Et N and a little
hydroquinone 20 - 5 brs. at reflux gave a precipitate 3of Et, N-HC1
and a filtrate which yielded 50% 2--a~-etylbic-yolo[1,2,21-hea_l-ene
(11), b,_h 62 - 60, -b 76, -, 8', n2) 1.4992, d2o 1,0102 (a lacrimator),
5
Card 113

Derivatives of Bicyclo, (Cont)
.7
vhose 2,4-dinitropherry-lbyirazoniz has m. 1.530 f abE, max. 369 M [1). Similarly
2-propi.onyl-3-chlort,.lbic.,velo [1', 2-9 eptane giLve 77.4% 2.-propionylbicyclo(l.,2,21
hept-2-ene (III), b2 5@_ CO.. U@ 1.4990, cQ 0.996 '5; (2,4-dinitrophenylhydra,-
zeme with m. 145.5 .- 60., abs, * may.. 365) - 70 m p ) . Sinilarly prepared from the
`1@chloro derivative was 74.2% 2-bt):t-,yrlylbi.1-yelo(I.,2,2].Ilept-2--eri,-,, b3 82 - 4%
1.4915, d2O o.9861 tit. 12k) - .3001'abs. mx@
D
3 9 .- 70 mtO. Similar treatment of 2-bep-z,)Yl-3-,,-.Iilor-obi,-yelo[l,,2,,2]hept'%Ue with
Ett N and treatment of -the prr,.dul_;u vith dilizted H2S04 gave 46,5%
L 2-eae 80 2
2Znzoy1bjcyciOrj,2..2]hep+-2 5-5.8 m4) (-'-t-20; the
max..
mother liquor gave 20% of apparently a d1wr of the abo,,re, m. 130 - 1*,.vhich
has no double bond. Reaction of II with NaCH(C02'@'",2 in 6 hrs. at 51o - 6(P gave
1m
after aq, treatment 78.6% di-Et 2-acetylbicyclo(1,2 2]hept--3-Y alonate, b2
157 - 6oo, n2O 1.4720 (2,4-d-initropheny1hydrazone, m, 13Q - 10). 111 refluxed
6 hrs. with R2NH gave 74.1% 2-propionyl-3-dietiVlaminob4Lcyclo[1,2)2]heptane,
b3 89 - 90*, n2O 1.48055 d2O 0.9440; HO salt. m. 141.5.- 2.5*; methiodide, m.
D I ji.
143 - 4'. H drogenation of -TV over B-11 gave 2-benzoylbicvclo(l,,2,2]heptan,,y b 10
_@O
155 - 8oo., n 1.5540 (2,4-dinitrophenylhydrazone, m. 155 - 60),. PhCOCH.-CH2
D
Card 2/3

79-12-2/0
Derivatives of Bicyclo (Cont)
and cyclopentadiene readily gave 804p 2-benzoylbicyclo[!,,2.,2]hept-5-ene,, b7
135 .. 69, n20 1.5660; hydrogenation over Pd gave the saturated analogue. There
D
are 7 references, 5 of which are Soviet, 1 German, and 1 English.
ASSOCIATION: Nauchno-issledovatel'skiy Inatitut farmakolog 4 chilnot api
Ji k ar i
(Scientific Research Institute of Pharmacology ;j1d Chemotherapy)
SUMITTED: Nov. 12, 1950"
AVAIIABLE: Library of Congress
Card 3/3 1. Cycloheptanes--Derivatives 2. Cycloheptanes--Chemical
reactions

c 1-1 i" tov
L.h t i- on
71.0n
V,',O
I'llorlill, A. ya.
In the --oxnzol Series o
tlic, lvnthe.,iis o-' the
izoks@:znlovll
nu rna olb,,@ he n ey kh im B -Iol.. pL
of the moqt z3imric c, -P -, han t h-is, 0 f0 y-z
reaction of O-chlorovinvlketonoz ,-.ith hvdroKylamfn,@,
w a 7-01 izefl tly
Koclict'k.ov @I:d M.s cull,.bonutors @ef@-
@it j.o, hoviever, accompanied b.-.: two cQrnj,-@tln.:@ -r
@he Varmation of t-rro i@Gmtric zncl 5-substituted ii!ryxaznl@
i.och@--nkov f urt'ler !3ho-.-.,ed ("'ef that the P-dialkyli:%miric,.. in@,
I-Aones with hydrcx,.r-,,.,mi-ne- to form practicallY puro-.
;:._--tt,b3tlitut@d I.Sox-,z that the
ol!@ . and
retlct!3 under tl-r-- formation of @-chlororlietnyl
. I L
It,'OXIM01. Thi-S f.,)CL tnrovon that in tht:l car,ti th--@
,-ttnck o" hydroxylaminf! t,!I-e-3 rjL@co at the cabonyl r.--oll?)
.-Crding tL41-he schera,- merc@io,;--td, To e-pla.-n ths vroblemi t,-
t@u thei q
-s Inve- tigutod Une roaction of o-chlorethyl-e-chlcrc-

J,
u i iin the Tf-,oxj!!7o1 ','erius. 1,11, Cm th., '.yntht-sir- ol the
k@,t@)np -,,iith hydro>:,yl,@Aminc. It turned nut that the syn -
JI r
of -chtoreth 'vi-O-chlorovinyl ketone, as well np@ thnt
Q Lhe 0-chloreth hicrovinylketorie already known, do-,3
riot; Tfif''A with any difficulttes (according to the method men-
tioncd in ref-@rerx,@ A). lit the condensation of the 0-1-chlor-
-eith hydroxylbatine the !-'-chlor-
vv-,ke obtzAne 1 4n good Irield "v.-ithout awi forma-
Lion of denoT!its) in ir;@ tr;!atment with sodium nlcohoLate ac-
cording to Claisen (Ref 5). This indicates a
@-fjub'stiti.ited i.'@Om"r:
C,'H C'U'Li'001f @CH,@ L+N1,f')OH ----> 1-H3CIICI -
ylketones .4sith
.n the rcactions o" --he
',I-v-'rox,viarninc, beside@ the oxazole also small amounts of
-ub:itituted iinomer:-@ are formed. The synthesis of thp
3--alkylisoxrizols by the :Lediiction of the correrpondlnE,
chloralkylisoxazols with zinc dust -aan elabora-ted. There ar.
9 references, 6 rill which are
/@7
v

AUTHO'?S: Kh Or 1 Chizhov, 0. S., 3 Ov//79 -28 -12 - 41 /41

(_ f:
)c
K
K '.etkov, 11. K.
TITLE: Derivr-tives of Bic@rclo (1,2,2' Heptane (Proizvodnyye bitsiklo
(1,2;'2)geptana) IV. Some Amines and Amino Alcohols of the
Bicyclo (1,2,2) Heptane Series (IV. Nekotor;ye aminy i amino-
spirty ryada bitsiklo (1,2,2)
geptana)
PERIODICAL: Zhurnal obshchey khinii, 19503, Vol 28, Nr 12,
n 33,15 - 3351 NMI)
A BS"N' ACT: The arnine3 of bic'7clo (1,2,2) heptane series owing to the
physiological activity of some of their most important
compounds are attractin6 the attention of scientists (Refs 1,2).
The authors had recently described the synthesis of some
amino ketones of this series (Ref 3), namely, the synthesis
of some derivatives of 2-acyl-3-dialkyl aminobicyclo (1,2,2)
heptane. To continue the investiSdtion of the physiological
activity of the amines of' the bicyclo heptane series some amino
aiconols and anines of this ser.Les were synthesized, which
were then pharj-,jaColo_-riCjlly inve@lti-ated in the form of
their hydrochlorides, and iodine alkylates. It was inter-
Card 1/3 e3tine, to irivestigate in which way the physiological activity,

Derivatives of Bicyclo (1,2,2) fleptane. IV. Some Amines SOV/79-28-12-41/41
and -I
emino Alcohols of the Dicyclo (1,2,2) Heptane Series
especially. the h.,potensive effect might change in compounds
.1,'ith the amino group in position 3 and with che same carbon
skeleton as that to be found in bicyclo (1,2,2) heptane,
if in the position 3 an oxy-alkyl or just one alkyl group
Ticre eubstituted for the acyl radical. To arrange the trans-
form,ition of the amino ketones of the bicyclo heptane
!3ericu into the correspondinF, a,-7iirio alcohols their reduction
with aluminum-lithium hydride (LiAlH 4) was carried out
(Schewe 1). This reduction takes place very easily. The
,yields of the corresponding PLmino alcohols (I), (II), and
(III) unk'novin before wet-e almost quantitative. Thus 2,1-oxy-
alkyl-'-dialkyl aninobicyclo (1,2,2) heptane was synthesized
by reduction of-2--acyl-3--dialkyl bicyclo (1,2,2) heptane
with LiAlH 4' 2-alkyl-3-di--lkyl amino bicyclo (1,2,2) heptanes
were obt:%ined in two ways: 1) By treating 2-acyl-3-dialkyl
amino bicyclo (1,2,2) heptane with phosphorous pentachloride,
by further reduction of the intermediate products with
zinc dust, and by hydrot-,enation. 2) By treating 2,11-oxy-
Card 2/3 all~yl-3-ditlkyl--a.,ninobicyclo (1, 40,2) heptane with thionyl

Derivatives of Bicyclo (1,2,2)Heptane. IV. Some Amanes SOV/79-28-12-41/41
and Amino Alcohols of the Bicyclo (1,2,2) Heptane Series
chloride and with sulsequent hydrogenation. The problem
of the dependence of phy.-iiological activity on the structure
of the ajnino derivatives of bicyclo (1,2,2) heptane is
discussed. There are 4 references, 2 of which are Soviet.
ASSOCI.I.TIOTT: Institut farmakologii i khimioterapii Akade!,'Iii meditsinskikh
nauk SSSR ( Institute of Pharmacology and Chemotherapy of
the ,licademy of Medical Scienceq,USSR)
SUBNIIT'@"ED: September 30, 1957
Card 3/3

SOV/710-2Q-1-17/74
AUTHORS: Kochetkov, N. K., Khorlin, A. Ya., Lopatina, K. I.
TITLE: Derivatives of Bicyclo-(1,2,2)-Heptane (Proizvodnyye bitsiklo
1,2,2) geptana) V. 3-Amino Isocamphane and Related Compounds
V. 3-Aminoizokarafan i rodstlvenny@-e soyedireniya)
@
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 1, PP 75-81 (USSR)
ABSTRACT: The authors worked out in detail the synthesis of the product
3-methyl-amino isocamphane which was recently found to be
highly active (Ref 1) in order to obtain new knowledge con-
cerning the relation between the structu-re of the ganglion-
blocking and hypotensive properties of a series of amino
derivatives of bicyclo-(1,2,2)-hoptane (Ref 3). For this pur-
pose they synthesized several other N-substituted 3-amino iso-
a@ampha@HAa_ Only brief de5criptAgnq of the s@,nthesis of 3-methyl-
amino �socampharie by readtion of camphane rivh poi5ovo-as
hydrocyanic acid have hitherto been published. Ag found in
this connection the described reaction takes place in two
directions at +50 (Scheme 1). At -20 up to -150 it proceeds
in one direction (Scheme 2) in which case the yield in 3-form-
Card 1 amide i3ocampbane amounted to mo@e than 70%. In order to avoid

SOV/7 9-29-1 -17/74
Derivatives of Bicyclo-(1,2,2)-Heptane. V. 3-Amino Isocar.-hane and Related
lompounds
the highly-poisonous hydrocyanic acid new methods of synthesis
of the acyl derivatives of 3-amino isocamphane were investi-
gated according to Ritter,'a"tove mentioned (Refs 5, 6).
According to Wagner it was possible to substitute hydrocyanic
acid by aceto- and benzonitrile at low temperatures of up to
-500- In the condensation of camphene with dichloro- and tri-
chloro-acetonitrile in the presence of concentrated sulfuric
acid it was possible for the authors to obtLin already at 00
the compounds (III, R=CHC! 2) arid (III, R--CC13) which lead in
the reaction to the compound (III), with R=CH 3 (Scheme 3); in
this case the regrouping according to Wagner was not necessary.
The acyl derivatives (I,III,IV) of 3-amino camphane were used
as initial products for the synthesis of secondary amine3 of
this series. The yields of the compounds thus obtained M,
(VI),and (VII) were very high. The results of the physiological
investigations of the above compounds together with 3-amino
isocamphane are mentioned in the table which shows the
dependence of the ganglion-blocking effect of the structure in
the series of amino derivatives of isocamphane. There are
Card 2/@_ 1 table and 8 references, 2 of which are Soviet.