SCIENTIFIC ABSTRACT KHARLAMOVA, YE.I. (DONETSK) - KHARLAMPOVICH, G.D.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000721820020-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 67
• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2001
• Sequence Number: 20
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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;=-,-j~1'6028327 SOURCE CON: Uli/0040/GG/C)30/004/0'/Llii/O'/~ij
AUITEOR: Kharlamoval Ye. I. (Donetsk)
0-;,3: nono
-,'ITLE: Reducing the problem concerning the motion'of a heavy solid body containing a
stationary point to a single equation. A new particular solution of this problem
SOU"RCE: Prikladnaya matematika i mckhanika, v. 30, no. 4, 1966, 704-788
TOPIC TAGS; two body problem, gyroscope motion equation, gravitation effect
fors from, tile
The solution of the problem proposed by the author dif thir-
.tccr. C-xistin- solutions in that the center of mass is in the principal plane rather.
n on the principal axis and the integrals in this solution are nonlinear. It is as-,
Gu:,-,cd that one of the special coordinate axes coincides with the principal axis which
makes it possible to reduce the problem to one relatively simple equation. '17he new
pzurticular solution of the problem is obtained on the basis of this equation. The solu-,
.ioa contains eight independent parameters:
a,al.b. ~, ~1, rip &os CLU
of vhich a, al, and b are components of the gyration tensor along special axes; X and
.Al are components of the gyrostatic moment which is constant with respect to the body;
Card 1/2
L 037-39-67
ACC N,1, AP6028327
the modulus of the invariant space vector which indicates the direction of gravi-
ty; Eu is defined by an analytical expression; and au is used to determine the posi-
,tion, of the body in space based on kinematic equations proposed by the author in an
,earlier paper. Orig. art. has: 29 formulas.
SUB CODE: 12,20/
SUBH DATE: 130at65/ ORIG REF: Oll/ OTH REF: 003
Card 2/2

The Rolling of a Ball on an Inclined Plane ~,011140-22-4-11126
the basic equations from the theorem of momentum and from the
theorem of torsional momentum. Under consideration of the
rolling conditions three of the unknowns can be eliminated so
that there'remain three equations for three unknowns. It can
be seen from the general equations that the center of gravity
of the ball moves uniformly accelerated, where this
acceleration depends on the initial orientation of the main
axes of inertia of the ball. The purely formal analogy
existing between the equations of the author and the equations
of Chaplygin can be utilized for a direct transmission of
Chaplygin's results to the motion considered here# To a
geometric iiterpretation given by Chaplygin of the motion of
a rolling ball on a horizontal plane one can give a new
interpretation corresponding to the rolling of a ball with
with an elliptic ellipsoid of inertia on an inclined plane.
The clearness of this interpretation, however, is not very
great.
There are 2 Soviet references.
SUBMITTED: March 20, 1958
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MARTALOV Pr Ya. I., -an,~ Phya-1--tth Sci-(disc) gertain problemB of
A$
dynanicn of a colid body." !'os, 1958. 6 pp ("os Order oi' Lenin and
Order of Inbor Ead Banner Str~te U i,-.i -.V. Lomonoaov), 120 conies
KL, 30-5 8, 12 2)

XHARIAMOYA, Ye. 1.
Motion of a solid body around a fixed point in a central Newtonian
field of forces. Izv. Sib. otd. AN SSSR no.6:7-17 '59.
(MIRA 12:12)
I.Institut gidrodinamiki Sibirokogo otdalaniva AN SSSR.
(Mechanics)

KHARI-AM07A Ya.l.
Uew solution to thu problfnn o! r-tion In a fjold of
force of a body having caviti6s ti2ltA witt, ltquij, PrAl. IN
SSSR 157 no.3,-549.-550 J! '64,, 17:7)
1
1. Novosihirskly gc,-qudarstvcnnyv --Lrifv-~-:-,2.t.-~-t.
wid.-ml.k.= P.Ya. Knchinoy,

L 00276-66 EWT(d) IJP(C)I.
ACCMSION NRs AP5021306 UR/004065/029/004/0 iirUii
AU-IROFII KhexIamovar Yee I* (Novosibirsk)
TITLEs Solutions of problem on' mation of a body having a fixed point
SOURCEs Prikladnaya matematika i mekhanika# Y. 29, no* 49 19659 T33-737
TOPIC TAGS iA 4 If 4
ABSTRAM The author considers
A-dP
j-
where Olte2qe~ in a unit vector from the fixed point to the body's center, and r
is the produc of the body's weight with the distance between the center of mas3
and the point of support. These equatiuaa govern the motion of a solid body with
a fixed point in a homogeneous gravitational field. The autitor finds certain
particular solutions of these equations under certain conditions on the mass
di3tribution and initial conditions* She also finds five solutions of a related
aystem which have as limiting cases known particular solutions or generalizations
of these partiwalar solutions. Orig. art. hast 29 formulas*
ASSOCIATIONs none
,Card 1/2
Mw-

~L 00276-66
ACCEssioN 14R: AP5021306 SUB CODEt Itz MA
RIM 00
SUBMITTEDs 23gar65
140 REP SOVI 007 omints 005
tj
Card

SOV/79-29-6-45/72
50) V. G-, KharlamOvat Ye, N*
AUTHORSt Vasil'Yevi licylate Marked With
Thermal Decarboxylation of Methyl Acetyl Sa atsetilealitailatat
TITLE$ C14 (Termich?lkoye dekarboksilirovaniye metil
mechennogo C )
FERIojaCkLi Zhurnal obahchey khimii, 1959, V01 29, Nr 6,
pp 1973 - 1982 (IUSSR) carboxylic acids has been in-
The decarboxYlation reaction Of the ions a number of
LBSTRACTs stigated in detail- R. R. Br,*n (Ref 1) ment place over the for-
ve ctions take
proofs for the fact that these rea
mation of the anion or the dipolar ion;
RC02H HCO2 R- + CO 2
RCODH eRCO 2 -~ RH + Co2 (2)
I,+ + RCO- --)o HR + C02 (3)
2 n in undissociated form is the
ple of a decOmPOsitiO al decarboxylatiOn
The only exam naya kiBlota) .The therm same stabi-
meoitOl acid (mezitoY ~Omplicated. Both bonds show the
of the asters is more C the basis of thisoreti-
Card 1/3 lity with respect to their cleavabilitY- On
With C?4
Therma Decarboxylation of NethYl Acetyl Salicylate Marked BOV/79-29-6-45/72
cal considerations the authors used a method described already
earlier for the investigation of the kinetics and the mechanism
of tha decarboxylation of methyl acetyl salicylate (-A.M.C.) with
the C14 marked in the acetate group (scheme (6) and (7)) 1. e.
at 280, 300 and 3200. The application of the iactope made poseible
a separate determination of the rates of the simultaneous develop-
ment of carbon dioxide from both carboxXI groups of this compound.
The separation of Co 2 from the methyl carboxyl group takes place
autocatalytically. The initial noncatalytic reaction takes place
with the activation energy 44 Cal/kol. The autocatalytic stage
occurs with the activatidn energy 38 Cal/Mol between AMC and the
product of the first reaction. The curves computed on the basis
of these conditions correspond to th~, experiment. A chain-, radioal-,
and ionic mechanism is not possible. The separation of &0 2 from
the acetoxy group takes place in two stagess at the beginning
acetic anhydride forms from 2 molecules AMC which in the second
stage decomposes into Co and acetone. This reaction is inhibited
bytthe decomposition proiucts of jjAC. The difference of the acti-
Card 2X3 va ion energy of the two reactions (_1.8 Cal./kol) was computed

Thermal Decarboxylation of Methyl Acotyl Salicylate Marked SOV/79-29-6-45/72
With c14
from the ratio of the constants of the initial velocities of &0
and CO 2~ This difference is mainly due to the difference in the 2
degree of conjugation of the two carboxyl groups with the aryl
and methyl group of the molecule AMC ( 2 curve diagrams). Thero are
3 figures and 21 references, 5 of which are Soviet.
ASSOCIATIONs Nauchno-issledovatellskiy fiziko-khimicheskiy institut imeni
L. Ya. Karpova (Scientific Physicochemical Research Institute imeni
L. Ya. Karpov)
SUBMITTEDs April 15, 1956
Card 3/3

81730
B/020/60/133/01/42/070
B000007
019
AUTHORSa V
TITLE4 investigation of the Strength of C-O Bonds by Isotopic
Exchange
PERIODICAL: Doklady Akademii nauk SSSR, 1960~ vol. 133~ No- 19
pp. 152 - 154
TEXTs The authors investigated the relative st'rengths of C-0 bonds in
ethers and asters by means of the exchange of C14. As a relative measure
of strength an exchange yield was selected,,which was attained after a
certain time. The experimental conditions were chosen in such a manner
that the yield did not exceed 20 - 40 %, so that its values approximate-
ly corresponded to the rate constants. Equimolar mixtures, in which one
component was tagged with C14, were heated in ampoules. In the first two
experimental series determination of the radioactivity absorbed by the
non-tagged cemponent was carried out qualitatively by measuring radio-
activity, but in the third, it was carried out quantitatively by
Card 1/3
Investigation of the Strength of
by Isotopic Exchange C-0 Poride
81730
1/010/60/133/01/42/070
B004/BO07
determining the C14
content. In series I reactions of
velltigateA. Neither P-nitrophenol,
P-creeol eth. ethers were in-
vi ether entered into e P--'hlorophenolp P-diethoxybenzene nor
tagged with C14 0 xchange reaction with sulphuric ether
the at 300 C and with the experiment lasting 20 h. Only in
"Be Of phenstole was a slight excha
out with phenGtolej
In series 2 qualita (P-nitrophenol) and CYIQ observed. Experlme~nts carried
acid tive investigations wer -ethanol also showed no reactiola.
e Oa
8, esters, acid anhydrides and ketones (T 1e 1) 'A mixtures of
enter into reaction with acid anh rri,d out
ab - Ketones did not
C H C00C H + C H C14 ydrides, For series 3 the system
6 5 6 5 6 5 OOH was seleotodv and both the exchange of C14
a, also, in parallel 8xperimenta, with C H CO 0 H the exchange of 0
were 'nvestigated. C14 18 18
was combusted to 6 5 18
the pulses Of BaC140 is CO 2 and determined by measuring
determined by means 3' 0 was combusted to C018 and the latter was
measurements were ca Of a 9.% 2
rri2-~' ~303'011 1303)-tYpe mass spectrometer (these
exchange of C14 Out by M. V. Tikhomirov). Tile authors found an
equalling 41.5 %, and of 018
Card 213 equalling 21 A* Therefore,

27906
S/079/61/031/010/006/010
5bloo D243/D304
AUTHORS; Nazarova, L.M., Kharla!pmo
qv e. j., Aleksandrova,
G. Ye., and El't-eY6`v`a, Ye. B.
TITLE: Interaction of benzole with phenyl derivatives of
elements in Group IV of the Periodic Table and of
their molecular composition by methods using tagged
atoms
PERIODICAL: Zhurnal obehchey khimii, v. 31, no. 10, 1961,
3308-3311
TEXT: The report was to fill a gap in literature and investigate
further the 1:1 molecular combination of triphenylmethane and
benzole described previously by AnschlUtz (Ref. 2: Lieb. Ann.,
235, 208 (1886)). The combustion of the molecular compounds and
benzole for activity analysis was effected by the method of moist
oxidation with a Van Slayk-Pollkh mixture, the carbon monoxide
being absorbed by a saturated solution of barium hydrate which
was later filtered, washed and dried. Activity measurements were
Card 1/3
Interaction of benzole ...
279o6
S/079,/61/031/010/006/010
D24-3/D304
taken over five minute periods, alternating with background mea-
surements; At least five readings were taken with each specimen*
Exchan~e experiments with benzole were done in glass ampoules.
3(C6H 5 4 (where ) = Sn, Si, Pb) was placed in a dry ampoule and
benzole added in a molar ratio of 1:15. The ampoule was sealed
under nitrogen and heated at 1500 until complete solution of
3(C6H 5)4* After cooling the ampoule was opened, and excess benzole
removed by a current of nitrogen. The dry remainder was left for
some days in a fume cupboard and then removed to a desiccator for
storage. Conclusions: 1) Tetraphenylsilicon, tetraphenyltin and
tetraphenylead form stable molecula't compounds with benzole which
have a general formula () (C6H 5)4)7 ' C6H69 whilst triphenylme-
thane forms a highlY unstable 1:2 molecular compound with benzole.
2) A method of determining the molecular compositions of these
compounds using tagged C14 atom was suggested. There are 3 tables
and 2 references: 1 Soviet-bloc and 1 non-Sviet-bloc.
Card 2/3

27906
S/07 61/031/010/006/010
Interaction of benzole so. D243YD304
ASSOCIATION: Fiziko-khimicheskiy institut imeni L. Ya. Karpova
(Institute of Physical Chemistry imeni L. Ya.
Karpov)
SUBMITTED: September 24, 1960
Card 3/3

11,1ICHEVA, Z.F.;_.YJIARLAMOVA, Ye.N.;~4LOVOFJIOTOVA, N.A.
Spectr-acopIc study of the complex formed lor natoral rubber
with titanium tetrachloride. Dokl. AN SSSR 164 no.3:581-
583 S 165. (MA 18:9)
1. FIziko-khImicheskiy institut im. L.Ya. Karpova. SuInitted
March 13, 1965.

L 33067-66
At-u- NH& Al 24159 5WRCE CODE: UR/0020/65/164/003/0581/0583
'-?
AUTHOR: Illicheva, Z. F.; Kharlamova, Ye. N. Slovokhotova, N. A.
ORG: Physical Chemistry Institute im. L. Ya. Karpov (Fiziko-khimicheskiy institut)
C,
TITLE: Spectroscopic investigations of a complex1of natural rubbexJ'-'141th titaniLm
tetrachloride
SOURCE: All SSSR. Dokladyo v. 164, no. :3, 1965, 581-583
TOPIC TAGS: i3poctroacopy, natural rubbor, titanium compoundp cyclization, apoctro-
photometer, ir spectrum, chloride
ABSTRACT: It is known that under the effect of titnnitum tetrachloride cycli-
tntion of rubbers taken place. The present study van undertaken to elucidate the,
nature of the Intermediate products In this process. Natural rubber (HR) was
used for the investigations, treated vith boiling acetone for 24 hours, and then
reprecipitated with methanol from a benzene solution. For measurement of
infrared spectra a XR film 0.004 cm thick vas prepared from benzene solution in
the center of a KBr disc. After careful drying of the film under high vacuum..
several drops of T'C14 were deposited on It. The brigbt-orange product then
'formed van covered vith a second KBr disco after which its Infrared spectrum was.;
immediately measured on a UR-10 epectrophotoneters All the operations with TIC14'
.and the filling of cuvottes were carried out in a hermetic chamber in dry
argon.. Infrared.spectra of the MR ~ TiClh system differed substantially rrom
Card 1/2

L 33067-66
ACC NR: AP6024159
~tbe ope'ctra of the original rubber and re TIC14. In the system, a new intense
,bond oppeared in the region of 1530 cd- at the some time, the 1665 cm-1 ab-
,sorption bandp corresponding to the valency oscillations of the M bond In the
original HR disappeared. Evidently, 9 135 cm-1 shift of this band into the longai
wave region occurredp along with an Increase in its Intensity.
An intense absorption band with a maximum in the 445 millinicron region vau
~observed in the electronic spectrum of the system RR ~ TiC14; a band in this
:region woo also observed In the electronic spectrum of the ir-complexes of
idiphenylethylene and its dimer vith SnC14. These facts indicate that In the re-
taction of ZiR with TIC14, a it -complex is Initially produced. Evidently, due to
:the formation of this complex disappearance of the 3040 cm-1 band of the valency
cocillations of the CH bond In the -C=CH- group Is observedp along with a shift
6H3
!in the 640 cm7l absorption band of the deformational oscUlatior. of this bond in
Lth. 820 - 810 ca-l.region.1' This paper was presented by Academician V. A. Kargin
on 1j Mar" _1965- Orig. art. has: 3 figures. [JPRS]
SUB CODE: 11,07-J,20/ SUBM DATE: 20F665. / ORIG MF: 002 / OTH REF: 005
..J
Card 2/2 A -

SENIKIN, T.M.; KRARLAMDVA9. Z.14.!A inzh.
.Improvement in railroad yard operatton on the basis of using advanced
labor methods. Zhel, dor. transp. 40 no*12:63-65 D '58. Wn 12:3)
1.11achallnik stantaii Nadezhdinak.-Sortirovochnyy (for Son'kin).
2.Otdeleniye stantaii Hadezhdinak-Sortirovochnyy (for Kharlamova).
(Railroads-Tards)

16 (1), 10 (2)
AT2!1OR: Kharla=va, Ye. I.
-----------
TITLE: A Special Caoa of tho
slu,chay inteGriruyemo3ti
lie 71-~-l 1/r.1
PERIODICAL: Do'r:lady Akademii ntatk SSSR, 1911, Vc,] 1,11~. Nr
(USSR)
ABSTRACT: Fur the p--.~rposa of m-ttin,- up thv of of
heavy) solid body ro--ml an. Jr.,mobilo (if b.,ly h~iL;
c,avittes ,,.,hirh aro filled wLth an .*,Jeal
It ir, sufficijnt to th,~ cocffici~,-Pts k:f
-,oz the doublu ki-.ql.,tic of the holy ar-1 the
If at thL, mom--~nt at ,,,hirh tl,.e a-.7t ti-on -,'.c th- "i-
quia wLs not in motion, It io 1y 8,af-taloi~
of tha axes Oxyz ril~--411-y with thc- (in
the origin of coortinates is at 0,r.- +I),,
to write down this quadz-ati-, form as foll--.w~,: A-- -2?,'-
2. tor of the ty f,
Cr Here (.P,q,r) denote the vcc f
the body. The quantities A,B,C in the casn of t!---
-r1llod with a liqi,.-~d natisfy tho in?l,,i,.,1'4,,y 13.
Card 1/2 c-Xpression ie writt-~m dcvm f,-)-- the kinutic ~f V-0 1~~Ijjd

A Sr~ecial Case of the Euler-Poisson Equation SOV/20-12r,-5-1 1161
for the case of an ellipsoidal cavity, aft--r which the herefron
resulting expressions for A,B,C are writton drwn. if the conte.::
of mass of the body does not coinnido with the point,
the motion of the system defined above is deacribed by t~e a.llor-
Po.4s3cn equations: A d" + (C-B)qr Adl)
dt
B !L+ (A-C)rp C dr + (B-C)pcL= Q(y,,T-xcT')
dt dt
d - dy'
rr - q.3" I,- _ j -,=
I Pr -rri If
Here Q denoteo the iveiGht of the -,iven mecjhanical syotem, and
(X o9yo 1z0) - its center of the unit vector in
the direction of them gravitational force. Several solutions of
these equations are known. The author further m,3nti,:)ns U parti-
cular solution of this equation, but tho for-mulao !7annot be wxlt-
ten do-an here because they are tc,--, -)11.iminnus. Thcra- arg I S,-r.Let
references.
PRESENTED: December 15, 1958, by T. I. Artrb-~Ii~vsi-.Jy,
SUBMITTED: July 9, 19513
Card 2/2

,
Yast rotation of a solid body around a stationary point with the
oxintance of it northolotiomic bond. Vnnt. 14,jmk. tin. Smr. mat. %ekh,
astron., fiz., khim. 12 no. 6:25-34 157. (MIILA 11:10)
(Mechanics)

KHARLA14P ID I, G. P.
Hormonal method of stimulating birth of twins in beef cattln.
Zhivotnovodatvo 21 nc..6:56-58 Je 159. (MIRA 12:8)
(Hormones, Box) (Beef--Cattle breeding)
(Birth, Wltiple)

BOYKO, Dmitriy Fedorovich; Geor&jy..Pavl'ovJch; SOBACHIK, A.P.0
spetered.; GORNIK, M.1r., red,; PXCHENKIII, I.Y., tekhn.red.
[Introduce the SZhK preparation more widely] Shire vnedriett
preparat SZhK. Moakvv, 1960. 11 p. (MIRA 13:11)
1. Moscow. Vystavka dostizheniy nBrodnogo khozyaystva SSSR.
Pavillon *Gvtsevodetvo.0
(Hormones) (Stock and stockbreeding)

L 33226-66 EW?(m)/EWP(J)/F,~P(t)/ETI IjF(c) JDABIRY1
ACC NRt AP6024589 SOURCE CODE: UR/0314A6/000/003/000( 5
AUTHOR: Kharlampiyev, I. G. (Engineer); Kuwy-ukov, A. N. (Engineer)
ORG: none
TITLE: Intercrystalline corrosion of pipeline parts in urea production
SOURCE: Khimicheskoye i neftyanoye mashinostroyeniye, no. 3, 1966, 45-46
TOPIC TAGS: corrosion, pipeline, urea
ABSTMCT: *Observation of the condition of high-pressuro pipelines in uroa
.production at the Lisichansk Chemical Combine have shown that intensified
1corrosion of individual pFaio can occur in t o uroa molt line the molten
ullca. entering the pipelines from the synthesis coliunn at a t perature of
2000 C and t* pressure of 200 k&/cm2. To conqwfct the examin Ono, a T-Joint
.was removed from the pipolinej made of the alLpol Khl7Nl3M3T1l'and acoupling
(Dy = 80 mm)p made of the steel OKhl7NIL6M3T,\ In use for about four years was'
ai-~o removed. No traco of corrosion was 2[itocted in the couplingp and ito
j
Innor 3urface was smooth and glistening. The inner surface of the T-Joint
,io-qover lookod as if it had been sprinkled with miAal powderp which could-be
removed from the surface o.nly with difficulty. Crig. art. has: 2 figures and
1 table. [JPRS.- 35,7281
SUB CODE: 13 / SUBM DATEt none
Card 1/1 "~2L) UDC: 620.193.4.#621-643.4

SOV / 137- 58- 12-252 12
Translation from: Referativnyy zhurnal. Metallurgiya, 11):;8, N- 121, p 167 (USSR)
AUTHOR: Kha rlarnpi vev, 1. G -
TITLE- Distribution of Manganes(- Among ?he Phases of Low-carbon Steek
Which Exhibit Differcrit Susceplibilov to Cold Bi-ttleness (Raspre-
delenwe margantsa mezhdu fazami maiouplerodisivkh staley,
imeyushchil,ch razlICIIIII-IYU sk!onnost k ~hladtiolonikosti)
PERIODICAL- Tr. Vast. -Sib. fit. AN SSSR, 1q;;7, Nr 6, pp 41-46
1
ABSTRACT: A study was made of Ihe relat onsbip between Mr. content in the carbide
phase and the critical brittleness terriperature bv determining ak I rt!-
silience! in the temperature range of +20 to -60aC and by the chemi-
ca) analysis of carbide precipilates separated from specimens of
industrial smelting of St 3, St 4: and St 20 sleels which had been an-
nealed, normalized, and quenched wiTli tompering at terriperatures
ranging between 300 and 720c). ',I ,vas vtilabhshed 1hat the Mn content
in the carbides increases w 'th an increase of the tempering tempera-
ture,with subsequent decrease in the criticil brittleness temperature.
T. F.
Card 1/1

it it It to is to a a Po is it, to 0

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00 4! courboxylic, oriols 1.0, lobtrattto Nom. 1witfitad arid *jj,.,
7.1%, was bytiveltrosted at an initial prritoutv of im aim. 00
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11110da 20-60MM,in 11sorpresorrievol MrA-h + AJA + NJ

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3% Phniols, vbkb art easily removed with cattoic. ii~
mmor-futri yki& wwa alfrotiat kleni"I for all The ragalyrit
,
lbutigh vim. w(garouts tiaclsing was obotorvied for the tats.
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pberocols sod "M parallins before hydrovius-
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active phessal-roducing catalysts afte pfo% + AIA and
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0
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a
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, after the "00
rwwv&l of pbetiols and bafti, had do 0.7974, 1 no.

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0~~' K MUSP't i~t

G.D.
Dissertation: "Multipurpose Use of Higher Phenols of Coal Tar." Card Tech Soil
Ural Polytechnic Inst, Sverdlovsk, 1953.
T (Referativnyv Zhurnal, Khtmiya, Mosco-4,
No. 16, ,~,g 54)
SO: SITMI 393, 28 k'eb 1955

GOTTRAN, M.Y.; KHARIAMPOVICH, G.D.
Ghemicid utilisntion of coal tar. Koka i khlm.no.8:47-50 156.
(MLRA 10a)
1. Umllskiy politekhichaskiv institut imeni S.H. Kirov&.
,(Coml tar)

H 1~
GOFTMAN, N.V.; RAUKAS, M-14-; MLARLARPOVICH, G.D.
Means for improving the technology of naphthalene production-
Koko i khIm. no.4:45-47 157. (KMA 101-5)
1. Urallskir politekhnIch6skiy institut in. S.M. Kirov&.
(Kaphthalons)
po t/1 C
ff
USSR/Chemical. Technology - Chemical Products and Their
Application. IndustrIal organic Synthesis
Abs Jour Ref Zhur - Khimiya, No 1, 1958, 2157
Author Goftman, M.V., Kharlampovich, G.D..--
Inst
Title Study of Antioxidant Properties of Higher Phenois.
Orig -%b Zh- prikl. khim-Li, 1957, 30, No 3, 439-446
Abstract A study was made of the antioxidant action of higher phe-
nols. Alpha-naphthol (I) and beta-naphthol (II) were
used as comparison standards. Paraffin was subjected to
oxidation. The objects of study were: phenoll o-cresol,
phenol-cresol fraction, xylenol fraction, polyalkylphenol
fraction, 1. 11, waste products of the recovery of I or
II, methyl naphthols, dimethyl naphthols, p-phenyl 5henol,
methyl phenyl phenols, heavy phenols (boiling above 33,00)
in an amount of 0-05-0-1%. The content of peroxides was
determined. The study was based upon the well-known
Card 1/3 ()J?,IJ sg Pei'
concerning this question vere arriVed at in the present
Card 2,13

;, -i ~ - , -- - -: ~ , - , ,, I - - , -. I
_i -7.r ,-t -, , - - i - , - I I - I I -
I GoJTMa, M.V.;-.=ARLUMICH,..G.D.
New technological arrangement for th6 processing of tar. T~rudy
Ural. politakh. Inst, noo'59:-5-13 157. (xiR& ntO
(Tar) (Distillation)

j, ,)-P -~ I.) v,i - " I , ., ;- , 'C", -
I )r2 ~ I ~, "~
. .; KHARLuMVICH, G.D.
GI -
0
Studying higher phencle from coal tar. Trud7 Ural. politekh, Inst,
no;59tl4-36 1570 (Tar acids-Analysis) (KIBA UtO

)(,T,; KIFARUMPOTI
SepAmt JM pure *4 -naphtb.olp t~ -naphtbal, p-phanylphenol md
4urenol out of phemols from coal tar. Trucly Ural. Politekh. inst,
n
'59 07
o. -" '57- (Tar aoids) (MIR& l114)

WRUMVICH, G.D., referent
a) (from wDas Gas- uud
Coke chemical plant in DurgaPur (Indi
Wasserfach," 98 no.47 1957. (MIRA 11:6)
l.Urallskiy politakhnicheakiy institut im. S.M. Kirovs.
(Durgapur, India--Coke industry)

A , . *i 6'. b",
L
AUTHORS: Goftman, M.V.,and Kharlampovich, G.D. 68-1-15/22
TITLE: Modern Trends in the Utilization of Naphthalene (Sovremennye
tendentsii v ispolIzovanii naftalina)
PERIODICAL: Koks i Khimiya, 1958, No.1, PP- 53 - 56 (USSR)
ABSTRACT: This is a survey of literature (mainly Western) on the
utilization of naphthalene for the production of phthalic
anhydride and other chemicals. Methods and raw waterialo used
for the production of phthalic anhydride are briefly outlined.
It is considered that under present trends of increasing demand.
for naphthalene, the production of phthalic anhydride from
naphthalene fraction would be the most economical.
It is stated in the editorial note that the expediency of
erecting phthalic anhydride plants on coke oven works requires
further confirmation. There are 2 tables and 11 references,
4 of which are Slavic.
ASSOCIATION: Urals Polytechnical Institute im. S.M. Kirov.
(Urallskiy politekhnicheskiy institut im. S.M. Kirova)
AVAILABLE: Library of Congress
Card 1/1

KHAIUA.MVICH, G~Do, referent.
I%w British by-product coke plant (from "Coke and Gas," 19 no*216
1957). Reviewed by G,D, Kharlampovich, Koko i khim. no.It6l_62 158.
(MM 11#2)
1. Urallskiy politakhnichookiy inotitut.
(Great Britain--Coke induatry)

AUTHOR: - Kharlwapovfc~i, Gr, D, 6:;- ~8 - 7 -14/27
TITLE On tha c1loice of th'-, Moot Economictil
Methods of Purifizarion of Col-le ov-r Ga:7 fro:.-,
Sulphide (K voprosu o vyber-3 naiboicyc- el"ono:uielinyhI,
nietodov ochistki kok~ovogo 6azla ot oerovodoroda)
PBRIODICAL: Koks i Khimiya, 19r1`11", Ili, ~, pp 4IS-51 (USSR)
ABSTRACT Ou tho basio" of a comp,,:trif;o-1 of the -.o,,As of clen~ld_nc,
M3 - I
1000 of col o ovr..n F,,-, by tlii,~ WIMAO PO'_~I~ 11 Rrid
arsenical methods,Tabla 1, and. am.iicniacol ir,-Ithcd~
Table 4, under operating; cond-4-11-lionS of the !daL-eyavj0!L
arid Zaporozhya Coke Ov~an Worlcc-,5 da':a c7n si:ailar coi;ts
iia West Germa_-(y and -.hz! Costa of _--ulphur and 3ulphijric
acid in various cour:~-rie~!, tl-ie a2d tecluiio-A
advanta.,es of -the ove L~nn~ cle--nin, systoms rre
diccussed. lt 1-3 concl,,Acd tha-i-l vacuc-car~,_onate
nor arsenical of _,as cleanini~ liave deciding
advanta co and I.-_Iie c%o_*-_- or. loc-1 conlitiorks.
From -'-.he poiat of v-'L--,%, of i~nd
o f
operation thO to '112.
not u-,ed
ot/her riv"thuel-, t, wl i-,
Card 1/2 in Ruz~_]_u tll_~ f_;UiA101'

68-5/8-7-14/27
1, )f
on tho Problc:~i of the h of
Purif ication of Col-,P- Oven Gas f
trials of thj-,- iiiettiod S-I'lould "bo out in ordi~r to
obtain zhe nE~ce2s~.ry dl~-ta aria, L ~ie eI o L inC
project:~ olf of plants
roviev.cd in order tc, the--,, ,j t*a~~---
method.
There arc 4. tables, mid ~-) r.-!fc-ren,~cs. cji' are
Soviet, 5 Goviian., I Er.LLIJ-~,
ASSOCIATTON: Ural' skiy poliral'.~h-nichecki- y --' i-;,-! L i t. U. t
(Ural PolytechnicLl
1. Coal gas--F~:.rificatinn -2. Hyd-ro.ry:.~n sulfide .... Separatio-n
3. Coal gas--..Ccf-,ts
Card 2/2

SOV/68-.58-12-12/25
AUTHORS: Khariampc~vIch,,q.D.., and Ogneval A.K.
TITLEt An Improvement in the Technology of Processing Coal Tar
Phenols (Usovershenstvovaniye tekhnologii pererabotk.J.
kamennougollnykh fenolov)
PERIODICAL: Koks i Khimiya, 1958, Nr 12, pp 41-1+5 (USSR)
ABSTRACTS The composition of residues left after the distillation
of phenols fvom Eastern coking works was investigated.
The residues were redistilled under vacuo (5-10mm) U.) to
a temperature of 1800C (equivalent to 305--3100C unde.r
normal prossure). The composition of distillate was
further investigated by rectification (Tables 1-3). rho
composition of raw phenols and those obtained from the
residues was compared (Table 4). It was found that:
1) coal tar phenols~ particularly higher phenols undergo
considerable ohanges during heating, namely the yield of
phenolic pitch increases while the content of lower
nhen-Dis decreases and their composition changes* 2) The
composition of phanols and primarily the presence of
phenolic pitch, i a components boiling above 3050C, has,
Card 1/3 a deciding influence on the decomposition of phanols.
3) The degree of decompos.-ition depends more on the

SOV/68-58..12-12/25
An Improvement in the Teichnology of Processing Coal Tar Phenols
duration of hetating than on the temperaturo (within a
range of 170-2300C, Table 5). 4) A considerable amount
of valuable high boiling phenols, primarily naphthols,
were found in the residues, Thus if the phenolic pitch
can be separated before the distillation of phenols and
the duration of their heating decreased, then the y1eld
of the residues could be also decreased and in addition
the residues would contain a higher proportion of
naphthols and their homologues, For the above reasons
flash evaporation of aqueous raw phen3ls with a short
heating time was tested (Tables 6,7). It was found that
by heating to 190-2000 (100--150mm hg) a complete separation
of phenols can be obtained and due to a short heating tirae
(10-40 Min) the degree of transformation of phenols Is low.
Card '2/3

SOV/68-58-12-12/25
An Improvement in the Technology of Procossing Coal for Phenols
On the above basis an optimum scheme for serration and
rectification of phenols is proposed (Fig 2 .
There are 2 figures, 6 tables and 6 references, a:.1
Soviet.
ASSOCIATION; Urallskiy politekhnicheskiy institut (Urals Poly-
technical Institute)
Card 3/3

SOV/68-59-5-11/25
AUTHORS: r1ampavJzhG.D., and Kagasov, V.M.
TITLE: Separate Recovery of Ammonia and Pyridine Bases from Coke
Oven Gas (Razdellnoye ulavlivaniye ammiaka i piridiriovyk1i
osnovaniy iz koksovogo gaza)
PERIODICAL: Koks I khimiyal 1959, Nr 57 PP 30-32 (USSR)
ABSTRACT: In order to Increase the recovery of pyridine bases, which
under present practice does not exceed 7019, a separate
recovery of ammonia and pyridine is suggested. To prove
the validity of the suggested method the influence of
ammonia sulphate additions to acid pyridine sulphate, and
to pyridine sulphate on the stability of respective
pyridine sulphates (Figs 1 and 2 respectively) and the
influence of the content of pyridine sulpbate in a
mixture of acid and medium pyridine sulphates (Fig
were investigated. The results obtained Indicated that
acid pyridine sulphate is very stable in aqueous sol.utions7
even solutions containing 200-26o g/litre of pyridine in
the form of acid sulphate do not practically evolve
pyridine at 70-80 OC. The stability of the medium
Card 1/2 sulphate is low. The process of separate recovery -,an be
carried out as followst after the passage of the

sov/68-59-5-11/25
Separate Recovery of Ammonia and Pyridine Bases from Coke Oven Gas
saturator, the purified gas containing only 0.03-0-13
t&3 of ammonia is passed into a small scrubber
4-5 plates) with a circulating solution of acid
pyridine sulphate. Part of the solution is led out
in the neut;,aliser. In this way the amount of solution
passed into the neutraliser decreases 20-25 times, the
amount of steam-ammonia mixture used for the decomposition
of pyridine sulphate decreases 4-5 times and the amount
of solution returning to the saturator from the pyridine
plant decreases 10-15 times. It is stated in the
Card 2/2 editorial note that the proposed scheme -requires
additional studies.
There are 3 figures and 1 table.
ASSOCIATIONS: Ural'skiy politekhnicheskiy institut (Ural
Polytechnical Institute) and Chelyabinskiy metallurgicheskiy
zavod (Chelyabinsk Metallurgical Works)

AUThOR Candidate of Ter~hnical Sciences
T IT Lil, Perspectives and Directions in the Develo-oment of the
Production of Phthalic..Aiihyd ride in the C;king Ind-,ustl-j
P.L,'--,~IODICAL: Koks i khimi~a, 1959, Nr Q,, pp, 36 - 41 (USSR)
ABSTRAICIT:11he above problem is di-s-cussed on the basis of literature
data. It is pointed ouU that -!.-ho production of plithalle
anhydride by oxidation of riapbthalene fraction (instead of
crystalline napthaleno. which i,,; at prez-ant used in the
USSR) will increase Lhe alrailabilit-,, of raw inate3~ial and
docre~,se the cost of the product. BimultLancously, it will
be possible to produce cheaper anh7dride and anthra-
9~.Iinone. From econol-;lic nsiderations 1~1.--14-. -,-Or -th--lic
i ~ s - -oil
anhydride siiould be -oui'Ll.- at larp coldng works (trans-ort,
lari.-p scale plants, cneap steam and [-jas for heutin,~). No
diffiCLIltiCS sliould Tk~ ,,ric-untered in the o--ddl3.tion
of waphthalene fraction and a concentration of the research
organi Sat ions on this probleir, is advocated.
ure are 4 f iLure, 2 4 tables and 20 roference s , of whi;~h
Cald 'L/- 10 are Soviet, 4 EnGlIsh, 2 Japanese. 1 French, 1 German
and 1 Poliksh.
A&,OC-,ATIOI[-. Urallskiy polite khniche ski-y institut (Urals Polytec.h-
I nical, Institute)

5(3)
5GV/aO-'2-4-x6/47
AUTHORS - Kharlampovich, G,D., Goftman, M,V,, Raukas, hl,M. and Huslyanova, N.D.
TITLEt Antiseptic Properties of the Components of Coal Tar (AntiseDticheskllye
svoystva komponentov kamennougollnoy smoly)
PERIODICkL: Zhurnal prikladnoy khimii, 1959, Vol 32, Nr 4, PP 905-909 (USSR)
ABSTRACT: The antiseptic action of individual components of the coal-tar oil have
not been sufficiently studied thus far. Therefore the authors undertook
an investigation of the action of various coal-tar oils and their in-
dividual components, separated from these oils, on wood-destructive
funCi of the Conlophora cerebella and Merulius dome3ticua species. The
results of the experiments are shown in tables and in graphs where fi-
gures of the loss of weight, ascribed to the destructive action of the
fungi, are given. Conclusions drawn by the authors are as follows:
1. Phenols are more effective anticeptic3 than bases and neutral com-
pounds, the effectiveness of the latter two is approximately the same;
2. The alkylation raises the antiseptic activitj of phenola; 3. Naphthols
and their homologs are better anticeptics than phenol deTivativen; 4. The
activity of compounds with a condensed system of benzene rings is higher
Card than that cf compo-ands vith disconnected benzene rings; 5. Compounds

Anti3eptic Properties of the Componento of Coal Tar IS 0 V/.81),,32-4-71,6/47
containine the imino-Grou,-.- are a nutritive medium for the fungi, acce-
'erating their growth. hloreccr;er, it cao establiihed that a definite
~L
maximum of activity erists for all the groups of coal -.ar components,
and the values of The temperatures of these peaks are given. It was
also found out that 4,-,oxicity of impregnating oils did not drop when
phenols ware removed from them, provided that the phenol content was
les'_ 10~; hcwaver, with increasing content of phenols above 10%
the toxicity of coal-ter oils increases. Therefore, coal-tar oils with
phe-nol 3ontent higher than 101/1, are especially effective anticeptics~
There are 3 graphs, 2 tables and 3 references, I of which is Soviet
and 2 American.
ASSOCIATIM Urallskiy politekhnicheskly inst'.tut imeni S.hl.Kirova (U.-al Polytech-
nical. InGtitute imeni S.M.Kirov)
SUBMITTEDt October 4, 1957
Card 212

XURUMPOVICH, G.D.; GOPTXAS, X.Y.; RUS'YANOVA, N.D.
New method of recovering ammonia from coke-oven gle. KoksA khim.
no.4:34-39 160. OURL 13:6)
1. Urallskiy politekhinichookiy institut.
(Ammonia) (Coke-oven gas)

XLGASOV, V.M.; KHOLOPTSEV, 1.P.; NWIROVSKIT, M.Kh.; UKUT, Y.G.;
IMARLAMPOVICH, G.D., kand.tekhn.nauk
Separate recovery of ammonia and pyridine bases from coko-cven
gas. Koko i khtm. no.6-32-35 160. (KIM 13 -',?)
1. Chelyabinskiy metallargichaskiy savod (for all except Khar-
lampovich). 2. Urallskiy politakhnicheskiy Institut (forKhar-
lampovich).
(Coke-oven gas) (Ammonia) (Phyridine bases)

KIIARLAMVICH, G.D.,-~ZVZKOT, V.N,, inzh., reteenzent; MIK&310VA, M.A.,
- inzh., nauchnyy red.; KUTMKOU, G.M., tekhn.red.
Doal chemicals as raw mterials for the production cf polymers]
Xhimicheskie produkty koksovenita - syrte dlia proizvodstva poli-
marov. Sverdlovsk, TSentrallnoe biuro tekhn.informatsii, 195q.
24 p. (MIRA 14-.4)
1. Ruesia (1917- R.B.F.S.R.) Sverdlovskiy ekonomichenKy admi-
nietrativnyy rayon. Sovet narodnogo khoryayntva.
(Coke induatry--By-products) (Polyrars)

KIIARLAMPOVICHO G.D.1 AKSENOVA., T.F.
Production of plasticizers substituting for cresyl phosphate, based
on xylenols and high boiling phenols from coal tar. Koks J. khim.
no. 5146-49 161. (MM, 14:4)
1. Ural'skiy politaklinicheskiy institut.
(Plasticizers) (Coal tar) (Tolyl phosphate)

GOFTMAX, H-V- I prof.; KHARLAPPOVICH, G.D.; RUSIYANOVA, N.D.
Ways of utilizing coke-gas ammonia. Zhur. VKHO 5 no.1:38-42 160.
(Ammonia) (Coke-oven gas) (MIRA 14W

S/068/62/000/001/002/002
E071/E435
AUTHORS,, Ruslyanova, N D., Kharlampovich, G.D.,
Belyayeva, G.;,, GE-f-tman,
TITLE. Oxidation of anthracene-phenanthrene fraction with the
production of anthraquinone, phthalic and maleic
qnhydrides
PERIODICAL: Koks i khimiya, no.1, 1962, 47-52
TEXT. The process of oxidation of the above fraction in the air-
vapour phase over a vanadium-potassium-sulphate-silica gel
catalyst (K-26) used in the industrial oxidation of naphthalene V/
was investigated on a laboratory scale. The starting fraction
was obtained by rectification of raw anthracene fraction with a
column equivalent to 25 theoretical plates. The yield of the
fraction was about 50% on raw anthracene. About 80% of
anthracene and 75 to 80% of phenanthrene were concentrated in this
fraction; mean compositiont anthracene 40 to 45%,
phenanthrene - 35 to 40% and carbazole 10 to 15%. The
oxidation of pure anthracene and phenanthrene takes place under the
following identical conditions: temperature 370*C, contact time
2~3 to 2.4 seconds, load on the catalyst 25 to 30 g/litre hr.
Card 1/Ac-

s/o68/62/000/001/002/002
Oxidation of anthracene- E071/E435
Whereupon from anthracene, anthraquinone is obtained with a yield
of 60% and from phenanthrene 54% of phthalic and 13.3% of maleic
anhydrides, On shortening the contact time, the oxidation is
incomplete and among the products of oxidation of phenanthrene
lactone of 2--oxydiphenyl-21 carbonic acid is formed. The
oxidation of anthracene-phenanthrene fraction &-t 3700C and contact
t1me of 2.3 to 2.4 seconds leads to its complete combustion, Only
on shortening the contact time to 2 see was a yield obtained which
was equal to that obtained from pure products at a contact time of
2.4 see, However, there are substantial differences in the
conditions of oxidation of phenanthrene:
J-) the reaction products contained lactone, which on oxidation of
pure phenanthrene appears only at a contact time of I sec;
2) there was a decrease in che combustion of phenanthrene and
the total yield of its oxidation products increased to 90%
(72% acid products and 18% lactone). On shortening the conta,;t
time to 1,36 see, a similar phenomenon was observed for
anthracene, due to a decrease in the degree of complete*
combustion the yield of anthraquinone increases to 81%). On
further shortening of the contact time to 1:06 sec, the yield of
Card

S/068/62/000/001/002/002
Oxidation of anthracene- E071/E435
anthraquinone increased to 84% but simultaneously the yield of
anhydrides decreased, An increase in the load on the catalyst
from 50 to 66 g/litre hr has a positive influence on the process,
Optimum conditions at 370*C were: 1.36 sec contact time and'
66 g/litre hr load on the catalyst. The composition of the
mixture (proportion of anthracene to phenanthrene and'the content
of carbazole) also has a considerable influence on the process
(Table 3). In the experiments the oxidation products -
anthraquinone, lactone and a part of the phthalic anhydride
(about 20%) - were caught in the air condenser, the remaining
products in water. The separation of the reaction products
presented no difficulties. Anthraquinone was purified by washing
with hot water to remove phthalic anhydride, with a 20% alkali to
remove lactone and then sublimated. The pure product had a
melting temperature of 286 to 2870C, The aqueous solution of
phthalic and maleic acids was evaporated in vacuo and
anhydrides redistilled, These can be used as a mixture or
separated on the basis of the difference in their solubility in
water, It is considered that under industrial conditions, the
condensation of the oxidation products should be done in two
Card- 3/.6-.3--

S/068/62/000/001/002/002
Oxidation of anthracene- E071/E435
stages; single-stage scrubbing would be difficult due to a high
density of the product pulp (a high concentration of anthraquinone).
The first stage scriibbing should be done in a Venturi scrubber with
a water spray as the cooling medium, It is concluded that the
oxidation of antliracene-phenanthrene fraction containing
approximately equal proportions of anthracene and phenanthrene and
a mininium amount of carbazole would be advantageous on an
industrial scale, There are 5 figures, 5 tables and
4 references.~ 3 Soviet-bloc and 1 non-Soviet-bloc, The reference
to an English language publication reads as follows;
Ref.l! Kinneu, C,R,, Pinkus, I. Ind. Eing, Chem, 1951, 43, no.12,
2880~
ASSOCIATION: Urallskiy politekhnicheskiy institut
(Ural Polytechnical Institute)
Card 4/45 -
Oxidation of anthracene-
Table 3.
S/068/62/000/001/002/002
E071/E435
Is raw material
2. contact time, sec
3. lc)ad*on catalysts 9/litre hr
4. Yield at the theoretical
5. anthraquinone
6. lactone
7. Phthalic anhydride
8o maleic anhydride
9- 55% dnthracene, 35% phenanthrene and 10196 carbazole
10. 45% anthracene, 40% phenanthrens and 15% carbazole.
V
Card

GOFTMAIN, M.V.; KHARLAMPOVICH, G.D.; RAUJKAS, M.M.; RUSIYPIICIVA, N.D.
Ant, septic properties of the products of noal. tar. Trudy Ural.
politekh. inst. no-94t90-102 160. WRA 15t6)
(Coal tar) (Antiseptics)

RUSOUNOVA, N.D.; MELINIKOVA, V.I.; GGRDEMA,, Z.K.;
i uchastiyo: MIROMOV, V.L, laborant; YAKAROVA, Z.A,q
laborant; KUDRYASHMA, 4.1., student; TATARUIN, G.P., student;
SELMKIT# G*Ae, student; ILICHENKO, P.P., student; MMKOVSKIKH,, V.V.p
studentl I M E M 9 X9*I*j student
Studying the nev method of amonia receovery in an experimental
ir4ustrial installation. Koko i khim. no.204-38 162.
(HIRA 15:3)
1. Urall Okiy politakhnicbeekiy institute
(Coke-Oven gas) (Amonia)

RUSIYANOVA, N.D.; KHARLAMPOVICH, G-.-D.; BELYAYZVA, G.F.
Oxidation of the anthracene-phenanthrone fraction
production of anthraquinone, phthalic and imalaic
KinJ kat. 3 no.2t289-291 Mr-Ap 162.
1. Urallskiy politakhnichaskiy in5titut.
(Anthracene) (AnthraquLnone)
(Phthalic anhydride) (Malsic anhfdride)
for the
anhydrides.
(KRA 15:11)

IZVIN, I.S.; IqVJUAWOVICH,, _G...D,...
flew typos of binding material for the brJ.quo-.ting of fuel.
Ugol' 37 no.9:48-52 S 162a (MIRA 15:9)
1. Urallskly politekhnicheakiy institut im. S.M. Kirova.
(Briquets (Fuel))
(Coal tar)

BOAKOV, N.G.; KHARLAMPOVICH, G.D.
Ammonia vapor pressure over aqueous solutions of Ammonium orthophos-
phate. Zhur.prikl.khim. 37 no.1:36-41 JA 164. (KRA 17:2)
1. Ural'skiy politakhnicheskiy institut imeni Kirova.

KHARLAMPOVICHP G.D., kand. tekhn. nauk; KAGASOV, V.M.
Di sc.us.sin.gD.S. ~trenko, O.D. Goritskaia and M.D. Shapiro's
article "Efficie t utilization of ammonia from the tar liquor
in the production of pyridine bases." Koks i khim. no.10:62 "' 3.
(MRA 16til)
1. Urallskiy politekhnicheskiy institut (for Kharlampovich).
2. Karagandinskly metallurgicheskiy zivod (for Kagasov).

KUDRYASHOVA R.I.; KHARLAMPOVICH, G.D.; DEGTYAK-VA, V.F.
.9
Conductometric methol of analysis of solutions of ammonium honphates
and sulfates, Zav,lab. 29 no.12sl/,29-11-30 163# ~MIRA 172 1)
1. Ural'skiy politekhnicesk-iv institut 1. Urallskiy filial Vsesoyuznogo
naUohno-isslacbovatel'okogo kiii-miko-farm..trevtiolieskogo inatitutao

KHARLAMPOVICH, G.D.; KUDRYASHOVA, R,l.
Recovery and separation of,pyridine bases in the produefion of
diammonium phosphate. Koki i khim. nc.2:31-35 164. (MIRA 17:4)
1. Urallskiy politekhniohjdkiy institut.

1) 1 1,~,
gase,i
hydr..jgan sulfAa)
of ain,:~Ww,4 -,r.h-)ph,,)g;pYiatetj. Zhur.prikl.
38 3 165.
(MIRA :18-.a1)
p.
Ure k,y inslt.iL, t, imenj Klrova.

ACC NRI AT7OOhO79 SOURCE CODE: UR/3244/66/ooo/004/0069/0071
AUTHOR: Kharlampovich, G.D.; Golltsova, L.F,
ORG: Urals Polytechnic Institute (Ural'skiy politekhnicheskiy institut)
TITLE: Preparation of stabilizers for plaatics, rynthetic resins, and
petroleum products using methylnaphthalenes'derived from coal tar
SOURCE: Dnepropetrovsk. Khimiko-tekhnologicheakiy inot-Itut.
KhimicheBkaya tekhnologiya, no. 4. 19669 69-Tl
TOPIC TAG-* naphthalene, rubber stabilizer, chemical stabilizer, stabilizer
additive, antioxidant additive
ABSTRACT. 1-methyl-2-naphthol, 1-methyl-4-naphthol, and 1-methyl-8-naphthol were
prepared and their antioxidative properties were studied to determine the
possibility of the use of these coal tar derivatives as readily available
.stabilizers of aviation fuels, lubricants, resins, prlymersq and food
:products. The antioxidative activity of the methyinaphthols along with
;naphthols and flexzone were studied by measuring the induction period
in air oxidation of paraffin at 170 t OAC with an air consumption rate
of 6 ml/g-min. The induction period was determined by iodometriq... _
'Eitration of the peroxides formed. The-results foLa 0.1% concentration of
the additives are given in the table. The induction period decreased

ACC NRi ATT004OT9
Table 1. Induction period of the oxidation of paraffin
with additions of methylraphthols
Induction
Additive period,
min
Without an additivia. 22
6-Naphthol . . . . . . 214
a-Naphthol . . . . . . 520
Flexzone . . . . . . . 802
1-Methyl-2-naphtliol't . 420
1-Methyl-4-naphthol... 796
1-Methyl-8-naphthol. 942
considerably b~tdecreasing the additive concentration to 0.05%. The
.effectiveness of the inhibitor decreased with increasing temperature.
,Thus, the methyl substituted naphthols are more effective as oxidation
than naphthols, and are more active than some patented antioxi-,
dants of the substituted amine type, produced abroad. [PSI
SUB CODE: 07/ SUBM DATE: none/ ORIG REF: 002/ OTH HEF: oo6!
ATD PRESS: 5114
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