SCIENTIFIC ABSTRACT KEYTELGISSER, A.M. - KEYYER, N.P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000721620008-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

DAL', V. I., prof., doktnr telchn.nauk; yolaRKO, O.S., dotsent, kand.tokhn.
nallk;- !4kLy.11OV. 13-M., kand.tekbn.nauk; ALITBRMN, L.So. Nladably
nauchnyy antrudnik; OTTELIGISSSR. A.M., mladRhiy nauchrjy7
aotrudnik
Goals from the western part of the Doi, te Basin an raw materials
for complete processing Into funle and other materials. Ugoll
Ukr. Vol.1 na.5115-17 My 159. (RIRA iptg)
1. Dnepropntrovokly khimiko-tn1chno1ogichoskiy
Dzbershinakago.
Onnets Basin--Coal) (Coke influstry)
institut im. F.S.
(Coal-tar products)

DAL', V.I.; FOMENKO, O.S.; KEYTELIGISSER, A.M.
Studying the coals of Novo-Hookovsk deposit in the Ukraine as
a raw material for chemical industries. Ugoll Ukr. 6 no.2-.20
F 162. (MIRA 15:2)
1. Dnepropetrovskiy khimiko-tekhnologichaskiy institut.
(Dnieper Basin--Coal)
_R

-1WfTIhV=-3Z:Z$ -1. NO-
Dissertation: "Investigation of an Intermediate Product From joal Drozz;ing Plants and the
Developmint of a Flowsneet for Its Dressing." Cand Ilech Scl, :-'oscaw Miring Inst, Moscaw,
1953. Heferativnyy Zhurnal--Khiptiya, Moscow, No 13, Jul 54.
SO: SUM No. 35b, 25 Jan 1955

KEYTELIGISSER, I.N., kand.tekhn.nauk; PIGOROV, G.S.; ZHURAVELI, V.A.;
RYNDAK, S.A.; PROKUDENKO, N.G.
Improvement of the water-pulp handling operations in the coal
preparation section of the Zaporozhlye Coke and Coal Chemicals
Plant.' Koks i khim. no.2:13-15 164. (MIRA 17;4)
1. Ukrainskiy proyaktno-konstruktorskiy i nauchno-issledovatellskiy
institut po obogashcheniyu L briketirovaniyu ugley (for
Keytellgisser, Pigorov, Zhuravell). .2. Zaporozhskly
koksokhimichoskiy zavod (for Prokudenko).
M_

BLAGOV, I,S., inzh.; KMILIGISSER, I#N,, kand. takhn. nauk
Reducing the number of workers employed in coal preparation.
Ugoll Ukr. 2 no.2t23-26 F 158. (MIRA 13:3)
(Coal preparation) (Automatic control)

SHAPIRO, M.D., kandetakhn.nauk; ALITERMAN, L,S,; KEYTELIGISSER, S,R,
Effect of the degree of fineness of crushing on the properties of
the plastic mass of coals and charges. Koks i khim. no.9:10-14
163. (MIRA 16:9)
1. Dnapropetrovskiy khimiko-takhnologichenkiy institut.
(Coke) (Coal preparation)

S/638/61/0()1/000/046/056
B116/B136
AUTHORS: Keytlin, L. G., Starodubtsev, S. V.
TITLE: Variation of absorption bands in the spectrum of dyed
polymethyl methacrylate under the action of gamma rays
SOURCE: Tashkentskaya konferentsiya po mirnomy ispol zovaniyu
atomnoy energii. Tashkent, 1959. Trudy. v. 1. Tashkent,
1961, 279 - 281
TEM According to M, I. Day and Stein (Nature, 16q, 644, 1951), the
color change of dyed polymer during irradiation is due to -fixation of the
dyestuff of electrons (which are separated out during irradiation). This
present paper endeavours to clarify this theory. The color change of thin
polymethyl methacrylate plates was studied under the action of gamma rays
using benzene-azo-alpha-naphthylamine as the dyestuff, To study the effect
of admixtures, both plates without admixtures, and with dichloro ethane
or benzene, were used., They were irradiated in vacuo at a dose rate of
3.5,10 5 r/hr. Under irradiation of the dyed polymethyl methacrylate
Card 1/2

STARODUBTSEV, S.V., akademik; ABLYAYEV, Sh.A.; BAYUZAI-IOV, F.; KEYTLIN, L.G.;
YUSOVA, E.N. I
Studying the molecular transformations in natural gas provoked by a
high-frequency electric discharge. Izv. AN Uz. SSR. Ser. fiz.-Cat.
nauk no. 2:3-11 161. (MIRA 14:5)
1. Fiziko-tekhnichoBkiy institut AN UzSSR. 2. Akademiya nauk IWSR
(for Starodubtsev).
(Gas,, Natural) (Electric discharges through gases)

310 81/62/000/001/066/067
14, 70 Blig/B101
AUTHOR5: Keytlin, L. G., Starodubtoev, S. V.
TITLE-. Change of absorption bands in the spectrum of colored poly-,
methyl methacrylate under 14-he action of d, rays
PERIODICALs Referativnyy zhurnal. Kh1miya, no. -1, 1962, 567, abstract
1R7 (Tr. Tashkentsk. konferentsii po inirn. i3pol'zovaniyu
atomn. energii, 1959- v. I. Tuahkent, AN UzSSR, 1961, 279-
281)
TEXT: The amthors studied the effect of r rays on the aboorption spectrum
of polymethyl methacrylate foils colored with the indicator benzene
azo-4-naphthylamine. The irradiation caused a gradual decrease of the
initial maximum at the wavelength @ - 440 mr and the formation of a new
one at A - 550 mp. The new maximum attains its highest value at n dose of
7
1.7-10 roentgens, and decreases again on a further dose increase to
4.2-107 r. Dichloro ethane admixed to the polymer acceleratee the color
change on irradiation. Banzene has a protecting effeett in the absorption
Card 112
:X,

8/081/62/000/001/066/o67
Change of absorption B119/B101
spectrum obtained on evaporation of polymer+dyestuff solutions in benzene,
the band at 440 @/,,disappears on irradiation, but a now maximum is not
produced. The change of the absorption spectrum of colored polymer on
irradiation reminds of the change of spectrum of an indicator oolution
with addition of acid. In both cases, the color changes owing to an
addition of protons (or electrons) to the dyestuff. EAbstracter's notet
Complete translation.]
Card 212

STARODUBTSEV, S.V.; ABLYAYEV, Sh.A.; KEYTLIII, L.G.
Study of molecular transformations in a natural gas
caused by electrodeless high-frequency discharges.
Izv. AN Uz. SSR. Ser. fiz.-mat. nauk 6 no.5:50-57 162.
(MIRA 15:11)
1. Fiziko- tokhnicheskiy institut AN UzSSR.
(Gas, Natural) (Electric discharges)

0610061016-,
3/166/62/000/0
BIOI/M6,
F.
AUTHORS2 Starodubtsev, S. V., Ablyayev, Sh. A-p Bakhramovo
Ziyatdinovq Sh.0 Keyt1in, L. G,_
TITLEi Study of molecular conversions in natural gas under the
action of elootrodeleas high-frequ*ency discharges. IlIt
Effect of the wattage of high-frequenoy discharges and
gas pressure in the discharge tube on eleotrocraoking
PERIODICALt Akademiya nauk Uzbekskoy SSR. javestiya. Beriya fiziko-
matematicheskikh nauk, no. 6, 1962, 55 - 60
TEXTs To clarify the basic mechanism of electrocrackingy methane was
cracked at various wattages (20 - 18o w),.presoures (20 - 6o mm Hg)p and
contact times v (0-01 - 2-4 see); total cracking and the yields of ethane-j-
ethylene, acetylenep propane, propylene, butylenes, and hydrogen was--deter-
mined. Total 6 'racking increased with wattages the rise was gradual,up to,
-J30 W, -C - 0.05 see, steep between 30 and 100 w, and then gradual again.
The steep section,of__the curve corresponds to the range where a chain
mechaniam.operates. The threshold limit of-the wattage at which the steep
rise sets in decreases with increasing T. The yields of ethane and
Card 1/3
S11661621000100610061016
Study of molecular conversions ... BIOI/B186
ethylene fall with increasing wattage for,-t const, No C 2 H6 or 02H4 is
f-ormed at 140 - 150 w. The yield of acetylene increases with the wattage,
passes a maximum at a certain wattage depending on T, and then falls
steadily. The maximum c 2H2 yield is 11% at 50 w and i . 0.8 see, and 22.5%
at 100 w and i - 0.3 sec. Diacetylene forms at*low wattages. More and.
more liquids are formed with increasing wattage, and diacetylene disappears
due to formation of cyclohydrocarbons. For propane and propyleneg there is
also a maximum at 50 w and -r - 0.4 sec which vanishes at high wattages,
probably being shifted toward very short T. The yield maxima for 0 H and
C H lie in the range where intense decomposition of b 3 a
3 6 H and begins.
Butylenes 2 6 C2H4
-form only at low wattages, they are no longer detectable at 140 w.
The hydrogen yieldg however, rises c0ntinuO@sly with w and is The specific,
energy consumption for a tube 2-5 cm in diameter and for r - 0.3 sea was
w-hr per mole of cracked CH 49 and 280 wohr per mole.of resulting C 2H 2'
The corresponding values for a diameter of 9.1 cm and i - 0.3.sec were 65
and 26o wahr. Increasing pressure has the same effect as increasing wattage
on the cracking and the yield of decomposition products. Experiments with
tubes of different diameters d a
Card 2/3 @owed that totalloracking deppnds linearly-
L

3/166/62/000/006/006/016-.
Study of molocular oonversions.40 310i/B186
on the surfaoe/volume ratio. Total cracking in two tubes of different d
2 2
in proportional to d2/dj, which may be explained by the termination on the,
walls of-the tubes. Furthermore, the yield of the individual products
depends on d, and this requires further investigation. There are 7 fig-.
ures and I table.
ASSOCIATIONs Fiziko-tekhnicheakiy inatitut--AN UzSSR (Physicotechnicdl
Institute AS UzSSR)
ZUBMITTEDi July 13t 1962
Card 3/3
7777
low

STARODUBTSEVI S.V.; ABLYAYEV, Sh.A.; DAKWUNOV, F.; ZIYATDII;OV, Sh.;
Study of molecular transformations in a natural gas caused
by electrodeless high-frequency discharges. Part 2. Effect
of certain physical factors and impurities on electric
cracking. Izv. AN Uz. SSR. Ser. fiz.-mat. nauk 6 no.5:58-65
162. (MIRA 15:11)
1. Fiziko--tekhnichoskiy institut AN UzSSR.
(Cracking process)

STARODUBTSEV., S.V.; ABLYAYST, Sjj@A.; BAKMU14OV.. F.1 KEYTLIN, L.G.;
YUS07AP ZON'
Study of the electroomaking of natural gas W the method of
vibrational spectras Zav; lab. 29 no.6:707-708 1163.
(MMA 3.6t6)
1, Fisiko-tekhnicheskiy inatitut AN UzbSSR.
Gas, Natural-Aboorption'spectra)
'acking proceon)
M

With Krmarcv, S. G. "Prnmeability cf Oil Pmrin.; 5ti-at@t D,--t,?rmin@fd Ly
sp-,!c1fic
P. 17/ in book A ).led Do @nlavi Collection of Articles,, No. eV, Uoscow
4',0--toPt,,--WA 491l@j- =00b7opil"!
111buze exticlets are concerned with the methodology af interpmting the resulta of
seimde " clz@etriml suinmVf. 11--view Via collet-ting properties or
make on Icha basic of data obtained fron re2iatomt4rc end t2te aWlication of obargod
lpaftlcle accelerators In vell logging.

"Relationship EQtwr.-2n Relative Resistivity, Por,@3ity, PerL;,?abIlity@P-!:,I,-'
Specif'.c Surface."
P. 1,?k in book Applied Ovopbysics, Collection of Articles, Xo. 19 Moscow,
Gostoptakbiz&t. 195F,---7-d53pp.
The artieles are devotea to a discussion of methods of Interpreting various
tnma cT electrical logo, sathods of determining the porosity, permability,, azA
spftific surface ebaru4tooristice of vater becxin6 rocksp " wtboda of determining
the pbysical properties ce sidements and the tharactariatice of vario-is pb7uical
jua--=tera. A description of piezoelectrie Vressure recorders used in relamic
exploration ia alao gIven.

z I
Relationship betireen the relative resistance and the porosity,
specific ourfacet eLnd the permeability of rooke. Prikl. geofiz,*
no,19:3.86-194 158. (KEM 1114)
(Petrology) (Iogging (Prospecting))

KORAROV. S.G.; KOZINA, Z.K.; SKOBLIKOVA, G.I.; GUZANOVA, I.G.
Determining porosity by spontaneous polarization curves. Frikl.
geofiz. no.25:192-215 160. (MIU 13:6)
(Illectric prospecting)

EYVIT-311) A.V.
In the cr)lrl Slor-@Lgfj 4:'
51-52 JI-Ag 165* la-))
1. RIZhjkly kholodlllnl@ ll;).2 rnya-moy !!@ollvchncy
fxomyshLanno.-All Sovc.W

GEDOY&Nj P.I.; KOLESNICBEINK0. G.D.; KEYM, A.P.
.......
Examination of the protein fractions of the blood serum
skin diseases by paper electrophoresis. Vest.derm. i ven.
no.9:29-34162. (Mhk 16:7)
(BLOCD PROTEINS) (SKIN--DISEASES)
(PAM LUCTROPHORESIS)

i-IQ
1-11'lreLrt-r, O.Ion of n I on 1,, s i rrp o f %'i, 7 rm r 1 .11:1
i
t ted j.@ r - i

.*L-:- - . - I , '--- -
i
Z-@- @

" 'T" c / / c ;@@-
MLESNIKOVA, T.V.; KEMR, B.R.
Softening of water with ammonium z9olite. Gidroliz. i lesokhim.prop.
11 no.8:24-25 ' 58. (KIRA 11:12)
1. Krasnodarskiy gidrolisny7 zavod (for Kolennikova.). 2. Byurn
voanochiatki Orgenergobuma, (for Keyyer).
(Feea-water purification)

AYVAZC.V, B. V.; @TTYEIR. N. F.; ITLM'Arl, 1'. B.
Leningrad
Laboratory of Hydrocarbon Reactions, Institute of Chemical Physics, Academy of
Sciences USSR, (-1940.).
"Examination of the Conrlitions of Combustion of Gaseous Mixtures." Part M. "The
Effect of Acetyl Hydrogen Peroxide on the Cold-Fltune O-ddation of Acetaldehyde.11
Zhur. Fiz. Kbim., Vol. 14, No. 12, 1940.
Fi

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viog Of =n=ty. The adsorption
=b" to that of FrimadfiCls; the
fli4tributlas p follows cloatir the espossential MIR-
I Wn 0 a Mrs -40. is Is the beat of adsorp(ioss am a
is the coel. of 1- 34. 0. Moore

Keier, 11. F., @nl RoginsAy, 3.Z., The kin-Alcz of elleoorpption of -Asoz-bA
hyi-,o-@--.n. F. 897
Contin-Ann- th,@ -.19tailed chec'.'Inz o'L' thp, concla3ion.-) of th-@ ol"'Atistical theor-j,
the authors decilod t@) study the kinetics of ie3orptlon for several sy3t--@ms, the first
of ,ms hyel.-ogc-n on n ctive charcoal f ram sug-ar. Ti.@is study showed that th-,-
surface of charco.-il f rom sugar is hlt!hly heterogeneous in the ac @ ivat-,on energy of
hy(h,ogen 3nd theref@):a the ba3ic conclusions of the statistical 'Ahe.)ry are
applicable.
SO: Journ3l of sinysical Chenistry, (-33,A) 23, 1"'o. 8, (19';9)
aS 5,04,

4;;11 1 1! T
A
so
:0
j il:
I T 11tezillitt boo ItS
W to M V It
On
1,;r.1 rhmearch Comwil ad Canada
Txz Kv(xTrs or DPMPTM Of ACTtVAT9D AD-
SMIMP NYDWAGGNN: Im". trum Mr. "?.
qw NVIrmakifi-
1940. !,Ly j Ift". by 11"her
ROUL 1"0. up, mr-124)
The folworlipm "bJects arm dift"oodt des"Ption lautmrms
w"41ftwivi am carbon, Ootaroift kbwkg, tempersivre to.
Wims. tm rolatim betwom d"wiptim rate SM ourfsco
coverap. Uw offoct of Imittial preheating, aad a dammotmi
ISMOVIC awthod for Immilgatimig Worogwoolly of activated
P 0 81 0 0 AN
so
i
Q
Isee
ago
*41141
8
ow, Got j'T
I& IS 4v -c &4 r-W-Z I -and a 0 4 1 1wr w -6 -1--70
co 1, ;41911 If MIRWR Jim wil
0 0 0 4 a 0 a 4 0 * 0 0 0 0 0 0 0 0 0
e 0 411 9 411 0 p 0 * 0 0 0
boo
t*e
too

oo A
P
00, t
go, 41
. 4
06
so
04
go
ve
0 410 0 00 0A 04to 4
840-18106 &4,AA
a is 3 it a it v a v a ql 4 di
A.3 OF.-All-C41.1- 1`0
4404 A IlWy el Nets op"Ity 0 AeU" l4dic" by
the Ddton*W hwispia IWA4 Pan L Acti"
Surtu" id Aftwul Nkbd lad w 11114 Odft. P. P.
Kohr Lid L L Itticladl ft A" Neat
With tM am Ol the aulbars O-dftf"Md isotopic meow'.
AM& NWA IL W.49%06M), out wwg
lab"" W-.@ -%wrZ MOUNW, a stuft fte as&
al the -rbc- ad cabbu"ur son @*npite of Waiting
rAtkol and ad also eddL IN bliff'Spnom CMIWWr of Uw
w c" of bmb* 1 11 1 il" Pd aw it Was sho that
dram by "W" smoserials "a "vew by tw bets op Ity
of tholt owbew of*
ago 411181 (me" All
r ad 0 is it I w P I a 3 1 v
Ilb u 0 AV to u A it 100"
0 0 0 0 0 * 0 41 0 0 0 0 0
go so 00000,00,0 a.. 0000 0
As . 0 *00 a 00 0000000
0 0 0 0 LID 0 0 ill 0 0 a 0 0 o-,Q-G 0 001 0
0
.00
106
.00
0*4
*00
000
400
2*0
fee
C3411 a
100,
SO 0
We 0
am*
too

got
0 0 0
14 1 a
a
4
so
it
00 3
00
0 41
0 0 0 0 111
so***
0 0 11 13 U
3647 Applisraliun, sit trArvir Atom- Ito the Study W the
Iltictwiturm tit AdmirScusl And C41tallibiA. W. P.
KTIV-1 IJ%Iwkhi Khtim 19. 59-11111950tilft ft;@"Mftl.
A urvvy if Impirr., un Ad.)rIvitun Arid CAtAly.116 919MIs the
"ry liultur 14a, pArl Ihe methowl plAya
1. lhor- I .... jigAtic.u, 1. 1114- held -11 Alt-Flill"ll JAC110111PILM.
",och W-Ork hA^ I'VC" shul" IPY NUARtAll J'AdUKIWIMPIR. Ithlopin
A1.1 bl% ruiltitsurAlur- n1whest the r1tworhAnimm tit the ad,stsfistion
fruits lulittureh. AM Ilw role JdAyrJ Its
ths"r lllswrwsr@ fir the ImMsurphiqn, (Z. Anorg. U. ailippm.
Che".. 143, 971l9251. thid. 166, 311jIV27). liltml,;@r I At. Z.
phy,lk. Christ. 165A, 41309331, Art& 1-hpicorlilm. U. It. 8. 3.
1 .1
It. 41511939!1. 111"N.J. fur the trivirminAllun 4 Alittululp
WAIW- % tit the fulflACr Area% 44 CrYhIAIIIhV -PIPMkilta U"r
Improved tV Khloptn vt At 4Zh.r. Via. Kbins. 13. 1145j193911,
.1111C the PCCUIlArIlle., in the lichavior ol jdas-Cliptlipirt Iso.
therm% rre Inv"ligairil fir Frun%kin et at mull. mead. act.
vw-w
Illit libkMI61t 110441
.00
.100
11111010
0
coo
coo
see
see
:30
11, R. S., CIAN" XCL chirst., 7731 11136@1, K0b0lWT el At i2hur.
Fit, Khkni 15. 357tI941)), Vni'k-ht,in libisl 21, 163,194711.
rd lbgt-kil (Ad-lpois- aW C,1411,t, s.,, Fl-
SitffAcr., 1,1 AcAdi,my of 1.4,ww- 1' 4 1.4 it , 1044
lkn ltw-un)), The IAIIVI 1,01111% Ate Ith-te It IVNI dtfrCtIv
connotted ssith the problem tit the befirruiettrity M the -1
fare tit the Asil-OrkWilt, Whith %A% Al%li -%111116@1 III Silkill" It 41
Milli. ACAJ -VI V. It- '1 4- CIAlls' @Vl Chl"I . 1101101411,
Itutio.kill I ArIA Phy Irs% hl tl@ It -4 S 11, 1,190446il, ml
Krivr el At jZhoi. I it. Khm, 23. o9lq 1941111 1,, th, . riss.
dr.cribing the u- uI FAJI-ClklIC I-Iopl. lu li'@ Itlisly of the
tAlalv@i,. the ruAltstliv d the -,,rk% turnliustett Are AsuirrIcAts
6.1 ltrill,h Alli, it she ll-ws ..I
hl% vollitnifAtor% I%vr AIxivel t-lustirtl the Influrnire t4 ttwl
Alillussitifel IM the AVIIVIIV ul A CAtAlYli AM the iturkhAl-i -is,
of the lootopic rictungto 111.11. 4CAJ @Cl. U. 14.8 3- ('41 "
sict. chim. 5. 60111940)).
fmA 5-61,
$SO-ILA bn&tLW4KAL CLAMICA"M
U 9 AV .0 9A
000 9 0 0 111 111 04 0 *,*1* 0 0 0 0 00 0 0 4111,0 0 0
000 *1*.$ 0 0 0 9 0 Ill 0 46 49 0 .0 0 9-flk 0 .40 0 0 .0 111 6 so 0 00
S@ s

The b"QM&i" 41 ON ndeft W "MbAldly all - -
DabladyAba,Ndliks.91.
S,A, 72, 1071-CIDAM.--The libudes of Adw
POIN of
Coils gas by '140 veriol. by thv"noo. of Kim Ill am
kundtir not ryv" lit I nim, lit, grul subocclowt 411981411114 1
in inuad at air frjwr@"W'6 fly the eciiiatin f 0
.41110. where q sim. adautlovil to cv. $.T.P. twi(1.75S.
NiO, initiAl CJf, jw@ww 240 into. fig. I - the& to
Win.
441 is dow1w wif I life lwrfrctly llwar. with the
slopes =tgpwkb tiolat temp. 4-19.6.nWl. The
of I I tioto" selivatle" ity d
MICU, A.11 a Iffet, FIF #via wrim =Mv*
101APKed" 47 .4 - Wor WS)SA MW on a all, VIM
the expit, data of tin was cd sibrorptiou of Wis. at
-19.61. l/n - 03M. log A - 0,113, a - 6 X 10',
agel at 0% U@M' 03W. ww 6 X 10-6. Fmon the gut of
the blisetli: curves abric the fir Ift I co6relbute. at cool.
f, the magnitude log ft - -(kot At, - We Arj)11010r.
- (vast IN RIPOW(w dibutbutiom Is 1,00
to a .5.481 bncvj firom lot If - loc A + log a + (1/0)
kv to. thit cortst. it - 0.44 X 10 -6 cc./d.
wilm 11) wO.44 X 1()-*-A
with ibesdaixp- get. wt, tivill'Jig. NW,
and a in call./Mbals. - to term ol the tknt i sit prop"altill
wisawl", a t 91MU*o FEUIJOX3 A - 2.3
itr Q I that With PwNews ww- 4 la-
Mill" to kzktw IQ tM dmdbvTt" lwt@rqwa by
at an wwfit x <
mow 0(s)WImt, tbAw t-w-we
with I from Arfheniku'rvistim. Tbkqu&nt.
sporinent is stron evi-1--ce for the swUn4ortzrogrucity
thowity, am Api"t attempts st interpretation an the
buls of republve interactions lortween adowbed mols.
N. Thou

F,
71WO of 4WeienWid-41@r @fimaj ciinjers Ln the-hi'dr-ogent.
Chemical Abst. - 11,A4. q1tkL4. I. Invi
zguffEoclu -OMManc"a 0-1 nMkel with the aid of the 'dT.Ur a
190tople method. N. P. KeTer-%-hull. Arad. Scj. U.S.S.R.,
Vol. 48 No. 9 Div- Ckem. SCi._T;37,_T?M(EngI. tra"AtIon).-Set
MaY 10, 1954 CA. 46, 1
H. IL-L
General and Physical q*I'itrY
J.

114
Rojo= 40iff deralt'a gantries
notim so an == is I III
* I - III tk;
of im"al wift the aid W Ili* quilroustiaii w.
N. P-KrIfe (Inal Phys. Chvi" Avwl tk+
U@S 8 k.. 1%lo`A-jw1,' WiU AW, Ningh S S S. R , 01444
Kk,-. Nook IM. 616-:0--0 1 Dewlition and c%Wytk,
reoselk"If ill @jjlj on NI were luvrofigatord by folJolmimu; the
Coll, bv portions, one of which was 1ASIrd with foulloorlive,
CII: the degairlsed flas or the satorm refortka lwoduMs we"
andifyor-I 1W C11 bv faditawtivity lueastore"Wato, The Ni
catufrat. made by leaching of a 60% M-Al allay. had of SO
sul,fave ourest of 16 * I sq. M./g. (by bdkWptkM W Cfig?.
It was oulginomord at MW, reduced In lie at the stime it,
and film tmixawif at ArIP under 10-4 min, ItS. %.
catAlyst did oust admob %@oll# or Cliff. but did viagorb Cliff
In sivittkunt Anti%. even at rotom temp. Only jwt of #be
Cdl, mid-Awd'al "men 1 ollont be dearlmed as such. On
1, a -
a IM)kl ratAly about Joe Coil. &too sidsoortmed it
rvvembly. whervots, on a catalyst preliminarily drW In a
trevorn of No. The fractim of Irreversibly adsorbed Coll,
of only about 10%; the totall modeforption is also much lan on
the dry catalyst. even though the Pp. surface areas "I the
tivoigi and th,, -Iry catalyst are appornit. flit same. Ov, dr-
vwpii." at 16,11 W Cjlj xdKorbed mi ruoin lernp. Cit. and
9.00.4.1 T
co)". - z V
If# am found, shirri with Cliff. which on got "Vord in the
rutullmollbeadforlohm. AIWO*,abnuI3O%vm(thrWfj
Idwirtw4l at fral"I Ift"p, was dv%vIwA "acha"ifelf; G"I
14%ai the CO the %%lifinal V,III 4;,IwAmt w0l...fout the
tialgogre 44 Of, V.11. was 41ft-affifti, it- C and fig (41 I,W" I
PcWtifin, of C.) If were U41S4.11W.1,11 0,@Xvl -alw4ulivelv;
A III I"orth-M. I M7 ml./g_ of FvIlinary, and & 1hod puriloon,
After '.'min, rvacuotionto
M -4 Mitt, fit, tile lvmjl@ 'A&, rak-d to W. with A vat-unst
tjn(frt theme couditinno, Was 16r. -
'Jjj of the Coll, W.44 tlfcoth"I, the 04 dmpgw otto V7%
nonradioactive Cliff, I.e the &As desurbed ravot vv"-
whellin sly fructo the portimi wistwbed first. 11 11, is mod-
mitted at rogial temp. to Cliff advarbed at that temp.,
C414 91111 Cliff appear In OIC 911A Ph&V; 0*114111t4111114114
Ltalasill"I t0cwtv hydrootruallon. The rrivulkider bring simply
witiltul"I *ffluout vr4rikul, With excess Fit. the
lwvdiwt 6 Coll. (KI JX1%j; the anit. M CH6 incerrommook witik
Slit"equeutly 1141tutt"I I%Wtions of Its. Illrott"C"atiols of
adjoeford Coils with fit ga. takes 14"v at ruotu trvmp@;
for 2110% the jr.",I~bed with fig contAinq no Cliff at C.114.
(3)(krolinsforyC411,
(2.81 mi.) was modoorbed M-1. two 0 M a. catalyst (COVOISP
46%). and then 1 .21 nil. tagged Coil, (cintermigit 2^). (M The
(411, obtained by admission of fit. 43% Came lentil the Ist.
v,nd 67% how the LOnd portim; this portion of Its had
hydmanated 4A% of the mfd@iorb,-d Coll. With Its ad-
tuittvil at I&P. the rus wsA all Wf,. 04% of the tagged pror-

to.m adsoorbed 2mi. At hisher truips.. without Ito. tht SO
Jr-clerd vrAs Clio + lit. w1b Clio Pt"WOU112NOLU39 lit Ifd)`-
2W*. am) the If# vonicnt inctraQng vrith temp.. the Clio
dejwwtvd at *It?' t"n- .1-m.t eutirety frout the Celle ad-
.6b'd beef. V"'M Ow-ev reoult.. 3 Itituls 4A active centers -
aleinferretf: witris from which Cells lodewwbed ftvqrsibl
tvutcn of hydroffettation, and centers cA detvmVn. of wit.,
14) with Cii, witorbed at town temp. In 3 cofte"tive
porlions, 0.12K mi tAgged. 1. 142 mi. ordinary, and 0.619
nd. tA1jVj CJI'. evacuation at roswu tevap. for 170 minj
resulted in the desorption of 1.6% of the 3rd and 2.4% of '
The 2nd jourtiots; further prokonsed evacustion gave no
withilsatrooontew
2,9170 of the C.Ho was hyeltornated in M min.. of wb N
:9%, was Iturn the 3rd and M% from the 2nd portion.
Ahow ItoP. the Clio obtained cante mainly from do 2nd
.foext,rd t-wtion; the C" cuutcat in the C114 fS foever. the
hogberiottertritip, 'I be C 114 obtained at rAJO0 was Completely.
menradimmyr. Up to &xj* no nwm than Wr. 9( the
toul Cello coubt be tefmvvd In all Uw forms combined.
firteru the. facts it k concluded that hydraffemition takes
place At active c"Ottft c%JrTw'P'wWWS to Q-48% miurfs@v
COV-9r. at high- cowmV4 Coll, is adsorbed reverfleir.
and is not susceptible 14) hydrolmnatioa, wiser"W .1 1. ,
cowntiles. at the otoot o"j" @jrro. the Coll. is cracked to
CH4 or eircomixf. to carbide &M He. 04 a CaWIM dried
lit Noff the C,11, undergoing hydroeenatioge was msisly th&j
front tit 2nd adsorbed portion. corresiewAing, an the dry -
catalYst. to 12-16% surface coverap. with an activation
enerV of 16-16 Itcul./wole. (3) 'Altereas in The CqHj
rewersibly deowbed at rotun temp. the Ist adsorbed portion
Predominates. the fractiewt of the 2W ponion Increases with
fix"MiAng temp. of the dosorption; at 5()-Ioo- it c,,,tft,t,,
about (10%, Lh%OrPtim does not befria at the fewer active
centen vrith the mai. activation energy ". but at more
active centers. carrespolujing to a loven covetser, on,
PO"sible I'vilrewntati'm of the dependrom of the activation
4,1191'
Xy of ticsUrption, F", on F@&' is a curve with a tnin,
Tof left or the m.n. tie- the r.ngr of irreve"ibir. and to
its r'EU the rante or Fvv11`eJb11- adumpli-on. This tepee.
AMMUOM'"nacrount her the abo%robeervAlkom.
.N. 11M

USSR/Chemistry - Activated Carbon 11 Apr 52
"Investigation of the Kinetics of Activated Ad-
sorption of Oxygen and Hydrogen on Carbons Con-
taining Different Inorganic Admixtures," N. P.
Keyer, N. M. Man1ko, Inst of Phys Chem, Acad Sci
USSR
"Dok Ak Nauk SSSR" Vol LXXXIII, No 5, pp 713-716
Activated birch charcoal was treated with WaF in
ENOI, thus lowering the ash content from 3$ to
0.4@. One % of K, Ca,' Fe, Ni, Ag, or Pt was then
introduced into the carbon and the adsorption of
02 amd H2 measured. The data obtained show that
USSR/Chemistry - Activated Carbon 1.1 Apr 52
(Contd)
the reaulting carbons strongly differ with respect
to adsorption, that some additives reduce while
others strongly increase adsorption; that the ad-
sor,ition of O@? and % is not affected by additives
in the same manner. The results were correlated
on the basis of S. Z. Roginskiy's theory of proc-
essts taking place on inhomogenous surfaces, and
the'conclusion reached that presence of additives
on the surface of carbon increases the deg of its
inhomogeneity. The relationships pertaining to the
formation of an active surface which have been
disclosed m;zt have a bearing on the action-of
catalyst promoters, modifiers, and poisons.
21arg

KEYYER., N. P. PA 239TI3
USSR/Chexistry - Isotopes Aug 52
"Preparation of Acetylene and Ethane Tagged With
Radioactive C114"' N. P. Keyyer, B. V. Klimenok
and 0. V. Isagulyantfi, Inst of Phys Chem, Acad
Sci USSR
"DAN SSSR" Vol 85, No 5, pp 1029-1031
Radioactive 14etylene was prepd from barium car-
bide contg C and water. Radioactive ethane Vag
prepd from the tagged acetylene by means of hydro
genation over a Ni catalyst at room temp. Sub-
mitted by Acad A. N. Frum 12 Jun 52.
239rl3

A-VIER, 11. P.
Nickel
Elucidation of the role of vatious adsorption centers in the reaction of hydrogenation
of acetylene on metallic nickel. Part 2. Kinetics of hydrogenation and activated
adsorption of acetylene on a nickel catalyst. Izv. AN SSSR Otd. khim. nauk. no. 1,
1953. @D. @ey -.5_,
Monthly List of Russian Acceslions, Library of Congressy June 1953. Unclassified.
0

I -)K, B. V., and ISAOULY;1ITS, G. V.
-IEEMER, N. P., LLP-711L
"Pron.-ir.,tion of Acetyl-ne and Eth;ze TaEred With OIL', " 3b, Zzt@-tey -jo @tsh@h,
lzd-vo AN 555P, X. -L., Vol 2, PP 1566-1569, 1953
Develged a laboratory method for the pre.nration of acetylene taF
E.ed with Cj, . Method con6ists of heatinf: radioactive barium c;@rlonvte
with r,srne,-,ium to T)roduce ritdionctive b,,rium carbide. 'he bilrium ear-
bide then yields radiwictive acetylene when tre- ted with wat(-r, tne the
acetylene cenbe- hydrcrennted over a nick:el c,-tLl.,,st to give rediotictive
ethrine. (KhMiim, No 22, 19.54)
sun'- 14- 681, 7 @)ct 55

.-AF701577 TREASURE ISIAND BOOK REVIEW AID 833 - S
MYER, N. P. (Institute of Physical Chemistry, AeadeAy of Sciences, USSR)
'---i3MZDDVANIYE: AJKTIVNOY FOVERMOSTI NEKOTORYKH POLUPROVODNIKOV IZOTOFNYMI
METODAMI (Study of the active surface of some semiconductors by isotopic
methods). in Froblemy IdnetdJd L kataliza (Problems of Maetics and Cat4iysis)p
vol. 8. Izdatelstvo, Akademii Nauk SSSRI 1955. Section ly: Nature of tho
active surface. P. 224-232.
Attempts were made to develops a theory of adsorption covering all deviations
from Iangmuir's theory. The concept of the nonuniformity surface led to the
development of the theory of processes taking place on nonuniform surfacep
(S. Z. Roginskiy, Ya. B. Zelldovich, 0. M. Todos, M. I. Temkin, Taylor).
Except for the uniformity of surface, the theory retained all other point4p of
the langmuir theory. Another concept ascribed the deviations from the IajRg-
muir theory to the inteMction of adsorbed molecules (M. L Temkinp N. I.
Kabozev, Roberts). The latest development was F. F. Vollkenshteynts assump-
tioa that the number of adsorption centers changes with the change in tem@-
perature and that two types of bonds may be formed on the same adsorption
center: mono-and di-electron bonds. Several catalysts were studied with the
aid of the differential isotopic method and Oe data compiled in Table l'
(p. 226).
1/2

AF701597 TREASURE ISLAND BOOK REVIEW AID 839 - S
KEYER, N. P. (Institute of Physical Chemi3try, Academy of' Sciences,
DISKUSSIYA (DIscussion). In Problemy kinetiki i kataliza
(Problems of Kinetics and U-5talysis), vol. 8. Izdatellstvo
Akademli Nauk SSSR, 1955. Section IV: Nature of the active
surface, p. 238-239.
Reply to S. Z. Roginskiy (p. 237-"'38). The kinetic anomalies
can be explained only by electronic processes which are as-
sociated with adsorption or by repelling forces between the
adsorbed molecules of ethyl alcohol. The experimental data
obtained in studying the chemisorption of ethyl alcohol on
zinc oxide lead to the conclusion that anomalies are caused
by electronic processes. The processes were discussed by
F. F. Vollkenshteyn. Since the calculations are essentially
quantum-mechanical in nature, they were applied to sim lified
and schematlzed models. One reference (Russian) (1949@.
U@ @RjKinetics---Combustion- Explosions. Topochemistry. Catalysis. B-9
Abs Jour ; Ref Zhur - Khimiya, No 8, 1957, 26234
Author :N. Keyer
In8t :Xc' @emy of Sciences of USSR.
Title :All-Union Conference on Application of isotopes in Catalysis
Orig Pub : IzY. AN SSSR, Otd. khim. n., 1956, No 10, 1279-1284
Abstract No abstract
Card 1/1

-Atearcli;e A Arm-mlArf @wmR61141k6ii: catmidg'. In
Kcstigatiwi (I:" llk'Ct Of ill III Ni
Taffice upor th", at-.4.0c aftil Y N 11 1,414 r, S.
c
metals in tw blvainit sl@llv kMt;-. Zn). 13(livalcill ;tte (1 :1,
A@), Mitt friV11,1111, tA:LtV "Cl , 111) ill Ni( I 'Ill fhc@
cutalyst activity in Me I I an I CO Vvere I ill
preViijill 44, 4.1. @ 1,14C
\4'io U,' tar'; 1,-Aid @@.,An:i. %rttlt Mgt). I-ij 1, :v!,i Cr,(-) d !i
tht.. tViZ"t@-Y, with T,f*.4) @- 1--e,C, wvr,@ p(clul tf,
d..Mrlpn. of the of ;ilc Irlixts. X-ray 4WJYOF@
sh'aww thgZ1,44 6@aO atW MLO wem forn cd witil
Nios an-1 (lie UI(ke NNO W"tl illcrt @,;Cd by
klzo a-let by 1.1@ii @1!e, Wt3
soidied untftr it-.tt;:- c-.jr@rfgi !n@ i!i-! -t 'M !@illFt@,

KITYXR, H.P.
Affect of the interaction between acerlene molecules adsotbed on
nikeelous oxide on the characteristics of adsorption. Dokl. AN
SSSR Ill no.6tl274-1277 D 1569 (MLRA 10:3)
1. Predstayleno akademikom A.N. Fr umkinyin.
(Adoorption) (Nickel oxidee) Acetkient)
77

VINOGRADOV, 0. M. , FOMM, 11. P. , ROGINSUY, S. Z.
"Study of the Mechanism of DIvInyl Synthesis by the Method of S. V. lxbedev
With the Use of Radioactive Carbon."
XEYYERp N. P. (without co-autbore), "TAotopio Data on Active Surfaces of Catalptee."
9. @rA Cata:L.-i-rila, "-:CV, IM-ro
Ig-, I
3P.

TINOGRADOVA, O,H@; XJTJR# H.P.;ROGINSIClYp S,Z,
Using O.V. labodevals method and radioactive carbon in the study of
the noohnnium of divinyl oynthesig.. Probl. kin. i kat. 9:175-186 157.
Ontadiene) (Catalysis) (Carbon--Isotope) (MIRA 11:3)

XIM, H.P.
F 0 ATM_P@__
Active
i kat.
mirfaces of catalysts according to isotope data, Probl, kin,
9r283-293 157. (Mnu 1123)
(CatalYats) (Radioactive tracers)

AUTHORSs ___ Keyer, X.P., Roginakiy, S.Z. and Sazonova, I.S.
TITLEi Investigation of Catalytic Properties of Solid
Solutions containing Bickel Oxide (Issiedovaniye-
kataliticheskikh avoystv tverdykh rastvorov na
oanove zakisi mikelya)
PERIODICALt Izvestiya Akademii Kauk SSSR, V91. XX11 #2, pp 183-
191, 1957, USSR I Seriya fizicheskaya
ABSTRAM The Connection of electric conductivity with the kind
of admixture is simple in some systems and when this
is the case, conductivity can be regulated within,a
wide range.
The Institute of Physical Chemistry carried out a
series of investigations with the oxidation of carbon
monoxide on nickel oxide as a catalyzer. This
investigation deals with catalytic properties of
various solid solutions with nickel oxide, which differ
Card 1/4 by their electronic characteristics. Oxides of one-,
two- and three-valence metals were dissolved in NiOl
TITLE: Investigation of CatalYtic Properties Of Solid
Solutions containing Nickel oxide (Issledovaniye
kataliticheakikh s-royntv tverdykh rastvorov na
oonove zakisi nikelya)
and the correlation between the elec and catalytic
properties of the catalyzer was studied. Nickel
oxide and its solid solutions were obtained by
roasting nickel carbonate or its mixtur8s with other
salts for 2 hrs at a temperature of 900 C-
The change in electronic structure of solid solutions
containing nickel oxide was concluded from the changes
in sp.ecific else conductivity. nVen Li2 0 was dissolved
in the nickel oxide, coaductiVitY increased as a result
of thq decrease in activation energy of this process.
The relation between temperature and conductivity in
solid solutions containing nickel oxide with various
ratios of lithium oxide is shown in Graph 1. The
energy of conductivity activation varies linearly aith
the logarithnof lithium concentration (Graph 2).
Catalytic activity with reapoct to reaction of GO
Card 2/4 oxidation was studied in a vacuum.

USSR/Physical Chemistry - Kinetics, Combustion, Explosions, B-9
Topochemistry, Catalysis.
Abs Jour : Referat Zhur - Rhimiya, N,:, 1, 1958, 513
Author : O.M. Vinogradova, N.P. Keyer, S.Z. RoGinskiy.
Inst : Academy of Sciences of USSR
Title ! Study of Mechanism of Divinyl Synthesis by Method of S.V.
Lebedev with Application of Radioacti.ve Carbon.
Orig Pub : Dokl. AN SSSR, 1957, 112, no 6, 1075-1078
Abstract : The distribution of C14 in products of the @atalytic syn-
thesis according th Lebedev (at the addition of tagzed mo-
lecules of ethanol, acetaldehide and crotonaldehide)
shows that the forma-iion of divinyl from ethyl alcohol
proceeds mainly throuji the condensation of acetaldehide
into crotonaldehide, which, in presence of excessive ethna-
nol, transforms into crotyl alcohol in the result of the
Card 1/2
USSR/Physical Chemistry - Kinetics, combuztjon, p. los
Topochemistry, Catalysis. @'p Ions, B-9
Abs jour Ref Zhur - Xhimiya, No 1., 1958, 513
redistribution of hydro,@_en. The dehydration of crotyl al-
cohol leads to the formation of divinyl. Divinyl is uot
forming
,, at the ethanol reaEtion in the layer. A very ra-
pid isotope exchanC
,e Of Cl@ takes place between ethanol.
and acetaidehide on the catalyst, which is a resul'u- of the
intermolecular redistribution of hydroGen. The authors
confirmed the fundamental order of stages Of the Gorin-
Kacan scheme.
Card 2/2

T\ LL
so v/3o - 58- 7 - 34/49
AUTHOR: Krylov, 0. V., Candidate of Chemical Sciences
TITLE. Physics -,tnd Physical Chemistry of Catalysis (Fizika i fiziko-
-Knimiya kataliza) Transactions of the All-Union Conferenca
(Vaesoyuznaya konferentsiya)
PERIODICAL- Vestnik Akademii nauk SSSR, 1958, Nr 7, pp. 119 - 122 (USSR)
ABSTRACT: This conference convened in Moscow between March 20 th and
March 23 rd. It was called by the Department of Chemical
Sciences and the Institute of Physical Chemistry of the AS
USSR (Otdeleniye khimicheskikh nauk i Institut fizicheskoy
khimii Akademii nauk SSS4It was attended by more than 600
persons from different towns of the Soviet Union as well as
from countries of the people's democracies. Nearly 100 re-
ports were submitted, 76 of which were given to the parti-
cipants for discussion. The remainder was read. The follow-
ing reports were heard:
1) S. Z. Roginskiy, (Inatituteof Physical Chemistry,.,AS USSR),
spoke about the selective methods concerning semiconductor
Card 1/15 catalysis.
@T

Physics and Physical Chemistry of Catalysis. SOV/ 30-58-7-34/49
Transactions of the All-Union Conference
2) V. V. Boldyrev, Tomsk University, used electron repre-
sentations for the explanation of the course of topo-
chemical reactions.
3) 14. F. Keyyer, (Institute cf Physical Chemistry)AS USSR),
7i d electron representations for the clarification of
the characteristics of heterogeneity of the active sur-
face of 8emicoriductor contacts.
4) F. F. Vollkerishteyn, V. B. Sandomirskiy --nd Sh. M. Fogan,
(Institute of Physisal Chemistry,AS USSR), investigated
the influence of exposure as well as of an external elec-
tric field on the absorptive power of a semiconductor.
51) A. N. Terenin spoke about the investigation of the struc-
ture and the behavior of surface formations in the case
of adsorption and catalysis.
V. F. Kiselev (Moscow University), dealt with problems
concerning the elementary act ofaitalysis,
7) G. K. Boreskov, Physical-Chemical In8titute imeni L. Ya.
Karpov (Fiziko-khimicheakiy institut im. L. Ya@ Karpova),
reported on the dependence of the catalytic activ-ity of
metals on their position in the periodic system of ele-
Card 5 ments.

Fhyaiue and @1,qsical Chemi8try of Catalysis. SOV/ 30-58-7-34/49
Transactions of the All-Union Conference
8) "'. ,,, Bon--h-Bruyevich and V. B. Glasko, (Moscow University)q
reported on the results of the adsorption computation of
metals.
9) A. Ao Balandin, Institure of Crganic Chemistry AS USSR
(Inatitut organicheskoy khimii Akademii nauk SSSR), re-
ported on new data concerning the Ale played by structure
factors in heterogeneous catalysis.
10) V. V. Voyevodskiy disproved his (and 11. N. Semenov's) hypo-
thesis of the existence of surface lattices and a hetero-
geneous catalysis.
11) Ya. T. Eydus and N. 1. Yershov, (Institute Of Organic
Chemistry AS USSR), 0. A. Golovina, M. M. Sakharova) S. Z.
@")arid Ye. S. Dokukina, (Institute of Physical
Roginsk 3
Chemistry)AS UiSR), proved the existence of polymerization
lattices in heterogeneous-catalytic processes of hydro-
carbon synthesic.
12) U. N. Tikhomirov, Po N, Bubnov and V. V. Voyevodskiy,
(In9titute of Chemical Physics)AS 111'10R)y reported on the
application of the method of paramagnetic resonance of
Card 3/5 eleotrons for the purpose of investigating the interaction
'9

Physics and Physical Chemistry of Catalysis. SOV/ 3C-58-7-34/49
Transactions of the All-Union Conference
of molecular oxygen with the free carbon valencese
13) Ya. K. Syrkin, (Inititute of General and Inorganic Chemistry
AS USSR@ (Inotitut obshchey i neorEatiicheskcy khimii
Akalemi;. nauk ,::Sq), reported on problems concerning the
molecular mechanism in catalysis.
'14) F. V. Topchi-yev, Yoscow University, gave a survey on the
data concerning cii-talytic activity of aluminum silicates.
15) L. 1. Piguz,,va and 11. A. Faliko, All-Union Sclentific Re-
search Institute of Mineral Oil Indu3try (Vsescy-uznyy
nauchno-issledc-ratel,skiy ingtitut neftyanOy promyshlennosti)
reported on problems concerning characteristics of active
acid centers in cracking and in catalytic reactions with
alumillinn silicates.
16) N. M. 'C'hirkov, 'nstitute of Chemical Physics,AS USSR,
proved the proton character of the mechanism of homogeneous
acid catalysis.
1'[) 0. V. Yrylov, TLrjq,.itute of C11omical j,jjysica,AS VISE, spoke
about the linterogeneous catalysis of acids.
18) G. M. Zhabrova, V. I. Vladic-ircra and Ve. I. Yegorov,
Institute of Physical Cheaiotry,AS U'SH, spoke about the
sorption of ions in the production of a zinc oxidA cata.-
Card 4/5 lyst.
:71777777=@

fhy@ii -s and I@hysical Ohr-mJstry of Cntalysis. SOV/ 30-58-7-34/49
Trensactions of the All-Union Conference
19) 0. M. Poltorak, Moscow University, reported on problems
concerning the genpei3 of catalysts.
Card 5/5

AUTHORS: Keyyor N P Chizhikova, G. I. SOV/2o-120-4-39/67
TITLE: The Chemical Adsorption and Catalytic Oxidation of CO on ZnO
and Its Solid Solutions, Which Differ With Respect to Their
Electric Conductivity (Khimicheskaya adsorbtsiya I kataliti-
cheskoye okisleniye 00 na ZnO I yeye tverdykh rastvorakh, ot-
liohayushchikheya po svoyey elektroprovodnosti)
PERIODICAL: Doklady Akademii nauk SSSR, 1958, Vol. 12o, Nr 4,
PP. 830 - 833 (USSR)
ABSTRACT: The authors investigated zinc oxide and its solid solutions
with lithium oxide and gallium oxide parallel to their cata-
lytic activity and to the chemical adsorption of the reaction
components. The production of zinc oxide and of the solid
solutions Is described In short. The dissolution of lithium
oxide decreases the specific surface considerably. The cata-
lytic reaction was investigated in a vacuum device under static
conditions at a pressure dnot mom than 2 torr. CO oxidizes with
a measurable velocity only at temperatures above 2500. The
kinetics of oxidation in the case of all s&mples corresponds
Card 1/4 with the first order. The dissolution of lithium oxide, in the

The Chemical Adsorption and Catalytic Oxidation of CO on SOV/2o-120-4-39/67
ZnO and Its Solid Solutions, Which Differ With Respect to Their Electric
Conductivity
case of concentrations of up to 0,5 atom per cent Li exercises
only little Influence on the constant of the velocity; in the
case of a further increasing percentage of lithium oxide, the
constant of velocity decreases considerably and can then be
measured only at higher temperatures. The activation energy and
the constant before the exponent in the expression for the
velocity constant increase according to the law E-E 0 +Ilgk0
The dissolution of gallium somewhat decreases the activation
energy of the oxidation of CO. The adsorption of oxygen de-
creases the electric conductivity of all samples and this
speakftora,
disso ution of lithium oxide accelerates the adsorption of
oxygen considerably; this is a consequence of the decrease of
the activation energy of adsorption. At room temperature CO is
very quickly adsorbed by-ZnO. This velocity of adsorption de-
creases with increasing temperature and at 2000 It becomes
insignificantly low. The adsorption of CO at room temperature
Card 2/4 does not change electric conductivity, but at 340 0 conductivity
iecrease of the concentration of free electrons. The

The Chemical Adsorption and Catalytic Oxidation of CO SOV/2o-120-4-39/67
on ZnO and Its Solid Solutions, Which Differ With Respect to Their Electric
Conductivity
increases. The dissolution of 0,5 to 1,25 atom per cent com-
pletely suppresses the adscrption of CO at room temperature and
at higher temperatures. The strong influence of the dissolution
of lithium oxide,upon the catalytic-properties Is connected
with the alteration of the active surface. The adsorption of
oxygen considerably influences the state that marks the velocity
of oxydation. There are 3 figures, 3 tables, and 6 references,
2 of which are Soviet.
PRESENTED: February 19, 1958, by A.N.Frumkin, Member, Academy of Sciences,
USSR
SUBMITTED: February 18, 1958
Card 3/4

hEnIER, N.P., Doe uhem Sci -- (diss) "Study of the 104"*4
wid nature of the non-homogeneituy of an active surface in
chemosoltion and catalysis." Vos, 22 p (Inst of
Physi.cal Chemistry of Acad Sci USSR) 1@0 coides (KL, @1@9 123)
16

6%
5-W
AUTHORS:
TITLE:
pERIODICAL:
ABSTRACT:
Card 1/3
Kutsevaq L* soV/62-59-g-6/4C
Keyyor, P-9
the Chemisorption of Gases 0"
investigation of Solid Solutions With Lithium OX4de'
Axide and Its adsorPtHii gazov ra ZaRisi
(I.siodovaniya khimicheskoy '14-iya)
i yeyo tvardykh rastvorakh 9 okislom I @ kikh
izvestiya Akademii nauk- SSSR. otaeleniye khimiches
1959, Nr 5,.Pp 797 - 005 (USSR)
r no data have been given in publications 0
so fa, of two substances
ductors consisting of solid solutions nickel and lithi*,-,.--
different electronic properties, as.are ity of nlc!@Ql
mentioned in the title. The ele,-t-rical-conduct'.V
ied within a idO range by a varied Tlant4@--'-
oxide can be var n of a met,al oxide, having different val2n,;'@@
tive introductio o its lattice (Tab 1). Thusq in the present vcelc,
than nickelp int ases 02, coo Co C H was investi-
the chemisorption of the g 21 2 2
ith lith4u,-1 oxide
gated on nickel oxide and its solid solutions w
at various Hi:Li ratios as well as on ternary nickel oxide,
lithium oxide, iron oxide systems. The solution of lithium olide
in nickel oxide reduces the specific surface of the latter from
Investigation of the Chemisorption Of Cases on
Nickel - , . Oxide and Its Solid Solutions S07/62-59-5-6/4o
With Lithium oxide
I m 2/g in Nio to 0-3 m2/6 in Rio + 8 at % Li. The adsorption
was measured in a vacuum unit on account of falling pressure,
The chemisorption of the various gases was investigated at
various temperature ranges. The investigations Showed that the
solid solution considerably influences the adsorption of the
various gases by retarding the adsorption of CO (Fig 3) and
acetylene (Fig 4) and accelerating that of the gases 02 (Figs
1,2) and CO 2- The conductivity of the adsorbents is increased
by the adsorption of 0 2 and CO 2 (Fig 6) and decreased by the
adsorption of CO and acetylene (Fig 7). This depends on whether
the Cases are electron acceptors or donors, respectively. The
Li 20 solution increases the activation energy of the adsorp-
tion in the beginning (FiC 5) and reduces it in the further
course of adsorption. The DrOCeSS ia r--@versed in the case of
iron oxide, i.e. the solution of admixtures chanCes the type
of kinetic dependence of the adsoxpticn. It is found that thla
Card 2/3 chanae cannot be explained by the chanCe of the le7el C'f thP

lnvestigation of the Chemisorption of Gases on
Nickel Oxide and Its Solid Solutiona
With Lithium Oxide
SOV/62-59--r-6/40
chemical potential. The active contact surface of NiO and lti@
solid solutions is inhomooeneous (Table) xs osn be seen f Z-o=
isotope investigations" The adsorption mechanism is descr-41pa
as follows: The active adsorption centers of the gases wit.-.
ceptor electrons, eago oxygen I are formed by electrons or, "-
acceptor centers of admixtures. The N13+ oations which ar.:? in-
dependent of admixtures proved themselves to be active ads-.rp.
tion centers of the electron donor gases (CO and acetylene).
Moreover, it is pointed out that the investiGation of the ad-
sorption properties of solid solutions with known structure
and of the electron pr6perties permits a thorough study.of th-
rules of chemisorption and its physical and chemical natur_a,
There are 7 figures, 2 tables, and 15 references, .0 of wy@i@h
are Soviet. I .
ASSOCIATION: Institut fizicheskoy khimii Akademii nauk SSSR (Institute of
Physical Chemistry of the Academy of Sciences@ USSR)
SUBITITTED: July 23, 1957
Card 3/3

AtTHOR% Keyyer, IT. P. SO'1/76-33-2-40/45
TITLE: An Investigation of the Nat-.;-re of the Deviations of the
Regularities of Chemical Ad3orption From the Langmuir Type
Using Isotopic Methods (Issledovani'ye prirody otkloneniy
zakonomernostey khimicheskoy adso@btsii ot lengmyurovskikh
pri pomoshchi izotopnykh metodov). I. A Study of the Adsorption
of Ethanol on ZnO (I. Issledovaniye adsorbtsii etilovogo
spirta na ZnO)
PERIODCIAL: Zhurnal fizicheskoy khimii, 1,059, Vol 33, Nr 2, PP 492-499
(USSR)
ABSTRACT: ZnO is a dehydrogenation catalyst for alcohols, and as it had
been observed (Refs 1, 2) that the adsorption of ethanol. and
methanol upon ZnO deviates from the Langmuir adsorption a
study of this system wae undertaken. Ethanol tagged with
radioactive C14 was used. Before each experiment the gas was
extracted from ZnQ at 5000(;ar-d after each experiment it was
regenerated with an oxygen treatment. The radioactive carbon
content in the combustion gases was measured by measuring the
Card 1/3 radioactivity with a counter (Raf 7) aft er conduction through
n
4. y4l@ M4.
-KIUIIZ@ In,

An Investigation of the Nature of the Devi-Lations of the 5OV/76-33-2-40/45
Regularities of Chemical Adsorption From the Langmuir Type
Using Isotopic Methods. I. A Study of the Adsorption of
Ethanol on ZnO
potash. The specific surface of ZnO, determined by the
BET-method, was found to be '12 � 1 m2/g. Since the rate of
desorption of ethanol at room temperature does not decrease
proportional to the degree of packing of the surface (P4_g
the catalyst must be heated to drive off theethanol.
Investigations on the hetorogeneity of the active catalyst
surface were carried out using the differential isotopic
method (Ref 5) and it was found that at RT the heterogeneity
of the surface exerts nc on the ethanol adsorption.
Experiments to study the exchange tetween the adsorbed ethanol
and that in the gas phase showed that at room temperature
there exists a "weak" bond (apparently a hydrogen bcnd between
the 011 group of the al,.,ohol and the oxygen ion of the ZnO)
between the adsorbed ethanol and the surface. This "weak"
bond becomes a "strong" bond (depending on the temperature),
which varies from place to rlace because of the heterogeneity
Card 2/3 of the surface. The high rate of adsorption of ethanol is

An Investigation of the
Regularities of Chemical
Using Isotopic blethods.
Ethanol on ZnO
7'- a
Nature of the Deviations of the S07110 32-2-40/41
Adoorption From the Largmuir Type
I. A Study of the AdsorPtior. of
explained in terms of a small actl4vation energy of adsorption.
The variation in desorption of the "weakly" bourd alcohol
(deviation from the Langmuir type) in t),e case of a variation
in the degree of packing of the surface is explained by the
strength of repulsion between the adsorbed molecules (with
oriented dipoles). The deviations from the "strong" binding
is attributed to the total effe@.,t of the heterogeneity of the
surface and the interactio-i of th6 rep-ils-lon between. the
molecules. Measurements on the electrolytic properties carried
out by G. I. Chizhiko-;,a showed that there is no electron transfw
in the"weak" bond, while an electron is transferred from the
alcohol to the ZnO in thtj formation. of the "strong" bond.
There are 2 figures, 2 tables,and 1i Soviet references.
ASSOCIATION; Akademiya nauk SSSR,Institut fizicheskoy kh4-=ii krosk-,ra
(Academy of Sciences USSR Institite of PhYsical themi s try, Moscow)
SUBMITTEDs July 12, 1957
Card 3/3

S/062/60/000/03/01/007
B008/BOO6
AUTHOR: Keyer, N. P.
TITLE: Catalytic Activity1of Solid Solutions of Zinc Oxide and
Nickel Oxide
PERIODICAL: Izvestiya Akademii nauk S3SR. Otdeleniye khimicheskikh
nauk, 1960v No. 3, PP- 389-397
TEXT: The interrelationship between.the laws of chemical adsorption and
the initial electrical conductivity of nickel oxide and zinc oxide was
investigated experimentally. Laws governing the adsorption of gases were
studied. The latter can be divided into electron acceptors and electron
donors according to their effects on conductivity. On adsorption of the
latter, and electron is transferred from the adsorbate to the catalyst,
while on adsorption of the former type of gasp the reverse occurs. The
adsorbate thus.becomes positively or negatively charged, respectively.
The adsorptive properties of the contact are considerably modified by
solution of mono- and tri-valent metallic oxides, which also affect the
Card 1/4
_j

Catalytic Activity of Solid Solutions of s/o6 60/000/03/01/00-1
Zinc Oxide and Nickel Oxide B008YE006
6-conductivities of NiO and ZnO. 0-conductivity of the NiO changes
inversely to that of ZnO. The solution of lithium oxide in NiO and ZnO
increases the initial adsorption of the acceptor-gas oxygen. The initial
adsorption rate of oxygen as a function of the lithium concentration
according to Refs. 16 and 17 is illustrated in Fig@ 1. On the adsorption
of donor gases, to which acetylene and CO belongg solution of L12O in
NiO and ZnO has the inverse effect. Solution of trivalent metal oxides,
such as Fe203P in NiO strongly reduces the adsorption rate of oxygen
and slightly that of Co. Solution of Ga2D in ZnO has no effect on
oxygen adsorption,. At the same time, no direct relationship has been
found between the activity of the contact and the conductivity. By
transference of an electron to the acceptor level, an excess negative
charge having the size of an electron is formed besides the lithium
cation. This disturbs the periodic potential. It is assumed that the
change in chemical adsorption is connected with the fact that cations
at lattice points having anomalous charges affect the statistics of
active centers on the surface. The oxidation of CO, decomposition of
N20, decomposition of N20 on NiO and ZnO, and the exchange of hydrogen
Card 2/4

Catalytic Activity of Solid Solutions of s/o6 60/000/03/01/007
Zinc Oxide and Nickel Oxide B008YB006
and deuterium were investigated. The depenAence of the logarithm of the
rate constant versus the reciprocal absolute temperature for CO oxidation
on NiO, according to I. S. Sazonova is givcn in Fig. 2. In Fig. 3, the
decomposition rate of nitrous oxide on NiO and its solid solutions is
plotted as a function of the molar content of lithium oxide and In203
according to Ref. 5. The decomposition rate of nitrogen oxide on
ZnO and its solid solutions as a function of the lithium oxide- and
Ga203 concentrations in mole %, according to Ref- 3, i@ shown in Fig. 4.
The changes in the factor s 0 Keand 03 with the decomposition rate of
N20 on NiO according to t he t cry by K. Hauffe and E. G. Schlosser are
illustrated in Fig. 5. The investigations carried out in the present
paper reveal that the catalytic activity of solid solutions of NiO and
ZnO is determined by the effect of U20, Ga2031 Fe203 , etc, on chemical
adsorption. The following persons are mentioned: S. Z. Roginskiy,
P. P. Vollkenshteyn, L. I. Kutseva, and G. I.Chlizhikova. There are 5
figures and 21 references, 7 of which are Soviet.
Card 3/4

Catalytic Activity of Solid Solutions of S/062/60/000/03/01/007
Zinc Oxide and Nickel Oxide B008/BO06
ASSOCIATION: Institut fizicheskoy khimii Akademii nauk SSSR (Institute
of Physical Chemistry of the Academy of Sciences
_LSSR)
SUBMITTED: July 19, 1958
Card 4/4
XNYTSR, N.P.
Nature of the change in the activation heat and activation
energy of adsorption, accompanying an increase in the filling
of a surfaces Kin. i imt. 1 no.103-93 VV-Je 160.
(KIRA 13:8)
1. InatitUt fitiChORICOY khiMii XMd6Sti nauk SM.
(Adsorption) (Sembaonductors). (Catal7sts)

KRYTXR, N.-P
Effect of the electronic structure of nickel oxide on ox7gen
exchange. Kin.i kat. I no.2:221-228 JI-Ig 160. (MIRA 1);8)
1. Inetitut fizichookoy khimli AN SSSR.
(Nickel oxide) (Oxygen--Isotopes)

Nature of the heterogeneity of the active surface of semiconductor
contacts. Probl.-kin. i kat. lOt73.-76 160. (MIRA 140)
1. Institut fizicheskoy khimli AN SSSR,
(Semiconductors) (Catalysts)

CHIZHIKOVA, G.I.; KEYYERI N.P.
Mechanisms of'the chemical adsorption and@catalysis on solid
solutions Of zini oxide. Frobl@ kin. i kat. 10:77-81 160.
(MIRA 14:5)
1, Institut fizicheskoy Icbimii AN SSSR.
(Zinc oxide) (Lithium oxide) (Carbon monoxide)

KTJTSEU, L.N.; KEYYER, N.PS
Chemical adborption of gases on nicirelous oxide and its solid solutions.
Probl, kin.ki kat. 10:82-86 160. (MIRL 14:5)
1. Institut, fizicheskoy-Ichimil AN SESSR.
(Nickel oxide) (Adsorption)

81870
S/02 60/133/02/46/o6a
Ils-4906) BO04YBo64
@57 / / CY 0
AUTHORS: KhuaA_YuZpey, Keyer,_N._j, Rq_jLinskiY, S. Z.,
Corresponding fe--MFe-rf8- E,SSR
TITLE: Investigation of the Catalytic Decompesifionl of Hydrazine
on Nickel Sulfide and on .Its Solid So-rutions
PERIODICAL: Doklady Akademii nauk SB.";R, 1960, Vol. 133, No. 2,
pp. 413 - 416
TEXT: While the relationship between '@he electrical properties ani the
catalytic and adsorption properties of metallic oxides has been in-
vestigated in many previous papers (Refs. 1-3) no such papers exist
as regards metallic sulfides. In their investigations the authors used
NiS in order to study the effect of*various additions of non-bivalent
metal sulfides (Li 23, in2 83) and to compare them with the behavior of
NiO (with addition& of Li .0 and In 203). The nickel sulfide was obtain-
qd from NiCo 3 (i.e. NiCO 3' + Li2C-039 NiCo3+ In(NO 3)3) by passing
Card 1/4

81870
Investigation of the Catalytic Decomponition of BIO?OV6011331021461068
Hydrazine on Nickel Sulfide and on Its Solid B004/BO64
Solutions
through H2S at 4500C. The X-ray analysis made by M. Ya. Kushnerev showed
that NIS waa obtained as P-form with a hexagonal crystal structure. The
specific surface was determined with the equilibrium isotherm of the ad-
sorption of krypton at -.1950C according to Brunauer, Emmet, and Teller.
The tablets formed from the NiS powder at 4000 atm had a resistance of
1.2 ohm.cm which increased in the range of 78-5730K in accordance with a
rise in temperature. It can therefore be said that within this sphere
NiS possesses metallic conductivity. A measurement of the thermo-emf
ahowed that NiS is a semiconductor of i;he n--type. The decomposition of
hydrazine occurs at 1 torr in accordance with the reaction equation
3N H -> N 4- ANH In nickel oxide it is accelerAted by adding Li 0, 11V
2 4 .2 3* 2
while it is retarded by adding In.0 3 (Pig. 1). In the experiments with
NIS palladium was used in order to chec;k whether hydrogen was liberated.
Since this was not the case the rsactic,n proceeded aoe,,ording to the
above equation. The kinetics of the reftotion was investigated by mea-
suring the nasoent nitrogen. Fig. 2 shows the kinetic isotherms of the
Card 2/4

81870
Investigation of the Catalytic Decomposition of 8/020/60/133/o2/46/o6a
Hydrazine on Nickel Sulfide and on Its Solid B004/BO64
Solutions
d--.--.omposition of N2H4at 60, 75, and 1000C in the z@oordinates
log(-AP ), log t. Fig, 3 shows the dependonce of the composition of t
N9H4 0
and PN2H4. The speed of the reaction inoreanes from 60-150 C and do..
oreases after 150 OC. The assumption that this is due to a poisoning of
NiS by NH3 was proved by pro-treating NiS thoNH3@ NE; retards the reac-
tion. Fig. 4 shows the isotherms of the re:citi n a 7 OC and with addi.-
tions of 0.2 - 1.0 at% of Li or 0.2 - 1.0 at% of In to NiS. Furthermor6,
the dependence of the speed of the reaction on th9se additions is shown.
In the case of an addition of 0.2 at@ of Li the maximum rate was observed
which is the same as the maximum rate of dependence of the work function
on L! or In addition as measured by E. Kh. Yenikeyev. In general the ef-
fect of these additions on NiS is leas than on NiO. i further obaerva-
tion of the authors is that only a single preparation was investigated
with 0.2 at% of Li so that the conformity of the result with that obtain-
ed by Yenikeyev may well be a matter of coinoidenee. There are 4 fig-
urea and 5 referenoes: 4 Soviet and 2 German,
Card 3/4

81870
Investigation of the Catalytic Decomposition of 5/020/60/133/02/46/068
Hydrazine on Nickel Sulfide and on Its Solid B004/BO64
Solutions
ASSOCIATION: Institut fizicheskoy khimii Akademii nauk SSSR
(Institute of Physical Chemistry of the AcadeU of
Sciences, USSR)
SUBMITTED: April 7, 1960
Card 4/4
3/020/60/133/03/11/013
B004 B056
AUTHORSs Khuan Yu-mey, Keyer, N. P., Roginskiy, S. Z., Corresponding
Member A9MR
I S With Admixtures
TITLEi Chemical Adsorption on Pure NiS and on Ni
FERIODICALi Doklady Akademii nauk SSSR, 1960, Vol. 133, No- 3,
pp. 641 - 644
TEXT: The authors investigated the chemical adsorption of oxygen and
acetylene on pure NiS and on NiS with admixtures of Li2 S (0.2, 0-5, and
1.0 at% Li) and In 2S3 (0.2, 0.5, and 1.0 at% In). The production of pure
NiS and of NiS with admixtures has been described in an earlier paper.
The adsorption was carried out in a vacuum apparatus, and the pressure
drop of the gas introduced was measured. The adsorption of 02 occurred at
25 - 650C. It exerted no influence on electrical conductivity. Fig. la
shows the kinetic isothermaillines of oxygen adsorption on pure NiS.
They obey equation (I)s q . Atl/n. The values of k and 1/n increase with
Card 1/3 k1

31090
S/195/61/oO2/00/005/008
Z111/9585
AUTHORS: Keyyer, N.P., Boreskov% G.K., Rode, V.V.t
Torentlyev, A.P. and Rukhadze, Ye.G.
TITLE., Catalytic activity of organic semiconductors.
1. Polychelates
PERIODICALt Kinetika i kataliz, v.2, no.4, 1961, 509-518
TEM The authors investigiitod various classes of organic
polymers in order to establish the catalytic capacity of organic
semiconductors and the relationship between their electrical - .
conductivity and catalytic activity. The present work deals with
polychelates of a given structure whose electrical conductivity
varies by more than ten orders, depending on chemical composition.
As regards chemical composition and structure the polychelates'
were of two typez:'I) the sulphur atoms constitute the electron
donor and, together with the metal., form the chelate group, which
in connected with the radical by the =N-C group
Card 1/4
Catalytic activity of ... 31
SX095/61/002/004/005/008
Elll/E585
\M \C-Nfl- R,-Nff-C.-' \M.@/15 \C-Nii-
-'N11C1S\M< S \C_
\S/ IS/
2) monovalent copper fO'rmfi two coordination linear bonds
-5-CU-5- evolving into areticular structure
-NII-C=S-Cu-.i-t,-Nn-i(-NH-C=S-Cu-
S S
Cu
-S-C-Nf1-R-N1I1-C-S--Cj,-S-c
The organic radicals of tile poj@chelates were
Rl-(Clfj,-; R,-(Clf.
Card 2/4 R4-
r/

S/195/62/003/003/001/002
E075/E436.
AUTHORS: Kcyyer, N.P,., Astaflyev, T.V.
TITLE: Catalytic activity of organic polymers
11. Catalytic properties of the polymer prepared by
dehydrochlorination of polyvinylidenechloride
PERIODICAL: Kinetika i kata@iz, v.3, no.3, 1962, 364-365
TEXT: Catalytic properties of (CH2CC12)n were investigated in
the reactions of decomposition of formic acid, isopropylalcohol,
decomposition of hydrazine and oxidation of CO. Formic acid
begins to decompose on the freshly prepared catalyst at 2400C and
the reaction proceeds towards dehydrogenation, the hydrogen being
Absorbed by the cataly3t. Tho docomposition of isopropylalcohol
proceeds similarly with the removal of H and begins at 155*C.
The catalyst prevented the oxidation of CO under 1 to 2 mm Hg
pressure up to 2500C. The decomposition of-N2H4 proceeded
according to the following equations
1) N2H4 N2 + 2H2
2) 3N2H4 ---4 4NH3 + N2
Card 1/2

KEYYER, N.P.; BORESKOV, G.K.; RUBTSOVA, L.F.; RUKHADZE, Ye.G.
Catalytic activity of organic pclymers. Part 3: Some regularities
of catalytic activity on the chelate polyOrrs of various chemical
composition and structure. KinA kat. 3 no.5:680-690 S-0 162.
OURK 16:1)
1. Institut kataliza Sibirskogo otdoleniya AN SSSR VMoskovskiy
gosudarstvennyy universitet imeni Lomonosova.
(Chelates) (patalysis)

KEYYERP N.P.; TROITSKAYA, M.G.; RUKHADZE, Ye.G.
Catalytic activity of organic polymers. Part 4: Catalytic
activity of chelate polymers in the reaction of hydrogen peroxide
decomposition. Kin.i kat. 3 no.5:691-697 S-0 162. (KRA 16a)
1. Institut katal-iza Sibirskogo otdeleniya AN S3SR i Moskovakiy
gosudarstvennyy universitet tmeni Gomonosova.
(Chelates) (Catalysis) (Hydrogen peroxide)
SAXNOVA, I.S.; KHOKHLOV#, T.P.; SUSHENTSEVA, G.M.; KEYYER N P.
Catalytic properties of titaniup dicocide and its solid solutions.
Kin.i kat. 3 no.5051-760 &-0 162. (MIRA 16:1)
1. Institut kataliza Sibirskogo otdoleniya AN SSSR.
(Titanium oxide) (Solutions, Solid)
(Catalysis)

3 `@_S L 1 L
5/020/62/144/005/011/017
B120130
_9 .2 0 19' #;
AU ril"OH3: Borenkov, G. K, p Corresponding Mombor, AS VSSR, K;,jy1,r, 11. P.
RiOntoovit, L. F., and Rukhadzu, Yf,. G.
Citul tic @rcperties of che-14ite (intrac@_=Zliex' @o!@-=ers
-2 0 D11. CAL nauk 5 5 SR. Dckladi, v. I
Tile article covers studies of the effect of the following: on the
catalytic zictivity of chelate polyners the decomposition pf hydrazine, the
netnl component, the chemical com!iosition of the atoms of the admixtures in
the chelate center, and the organic portion of the polymer in the main or
side-chains. Structures and compositions of the polyiners are given in
Table 1. Hydrazine decomposition is sensitive to the elictron state of the
contact, and takes place in two ways:
112H4 H2 + 2H 2 (1)
31;2H 4 OH 3 + 112 (2)
Tho saloctivity of a pol)mer catalyst can be assessed frqm the 'Way in 'Which
its structure and chemical composition affect the direction of hydrazime
Card
7-j,f02O 62./14Z./C,05!G11/017
properties of...
lecom-,)o3ition. Tile Jecomposition of ioor,ropyl alco'hol ani formic acid by
dehydrogenation wau als, ctulied. No oxidation of CO took place On the
studied until 20000. Table 2 gives exge@rimental data on the
slecific decom:)osition rate of hydrazine at 108 C in the presence of various'
Pol.,rchelates. The follo--ving decreasing order %a.,7. found for the catalytic
activity of polychelates of copper with chelate centers of-different
cam--ositiona ; CU01113) ___Cu(S1S) > Cu(u,o) >Cu(0,0). The catalytic activity
of chelate poly-erc is twice as high as that of
inorganic copper
ae@miconluctori. The same %as found for the polychelatec of nickel
investigated. Fig. 3 shows the deDendence of the selectivity of't"-.e
co3per polychelates on their cheLiical comiosition anJ structure. It is
co-ncluded that the catalytic activity and selectivity of a polychelate
6e ,)erds on: 1) the m6tal entering into the polychelate; 2) the nature of,
z-.-1:_-.4xtures entering into the chelate center; and 3) to a considerable de"gree,
the organic part of the polymer, There iu thus an analogy between the
rules governing the catalytic properties of these polymers and that of
fernents. There are 5 figures and 2 tables. The English-language reference
is: L. Leslie, Orgel, An Introduction to Transition-Metal Chemistry.
Ligand-Field Theory,.London, 1960.
Mar.-' 210 --?

5/020/62/144/005/011/017
Catalytic propertion of ... B124/@136
A 530C I AT ION, Institut kataliza Sibirskoeo otdeleniya Akqdemii nauk SSSR
Novosibirsk (Inntitute of Catalysis of theSiberian
Je)artment of the Academy of Sciences USSR-,' Novosibirsk).
:,Ioukovskiy gosudarstvennyy univeraitet it. -11. V. Lomonosova
1.7() .3 C a y, State University imeni M. V.Lomonoftov)
December 8, 1961
Table 1. Study of chelate polymers.
Legend: (,,) polymer; (B) Organic compound on the basis of which the
polychelate wan isolated; (D) Chelate center; (x) Composition of
polychelate; (F) Sodium bia-di-thiocarbamate; (G) a-titioalkylpyridine
amidodiphenyl; 'j 2bRubianic acid; M PolY-(4,41 bis)-a-thio-2t6-lutidine
amidodiphonyl; N 5,51-methylene-bis-eali,cylaldehyde; (NO 3bDiacetyl
Tesoreinol; (P) 4b Dinitrosoresorcinol.
Card 3/0

AKOPIOILNOV, F.G.; VAYIL,3!l'F_','YN, I!.; L.". ; I
Ye. G.
X-ray ab2orpticn K-npectra of col-,!jcr in come cutalvticalily active
clielate (inner-comFlex) polyiners. Kin. i kat. 5 nc.4:61-6-(23 il-
Ag. 6j,,. (Mlli', 17:11)
1. Institut kataliza Sibirskogo otdelenlya AN SSSR I Institut
neorganicheskoy k-himii Siblirskogo ctudelenlya AN @S_SSR.

I fl, -f, v
1. roi f, r: L*.".

KFHEIII, '4"'MAYLOVA, I,J,*; SAZONI(VA, i.,".
C,I-emacal adsorption of poes on UUinlum diodde, und IU3 volid
m-)Iutions having different electric prop-rti@@s. Kin.1 k:.,,. 5
n@--6:108i,@1094 N-D 164. (,kf'@Rk -LR-.3)
I
110ln:@Utut kataliza Sibirskogo oWeloniya AN S";SR,

E;. ,vF(C)/Evi?M/T P c - r
AIL7CESSION NR- T54061 4 S/0020; 64 @ 1 005. 110,59/1061
K. i Kevver N P.
I !, 1 i
--(Gorr
___R -mponding tem Wt`
1TT,8: Study of the EPH spectea of (,u(III
1 OPP@: 1-11GS: chernical structure, ejortron pararnafrn-i- e, chelate
comp]4@x, copper -.ilnha thiopicolinandidr- ro,nf-Or-@
"I : It iq of great importance to invFstivnio 0-
,rionorym,ric links of rhelate polyrner,;. Thiq
r@ of thr ',;PR spectra of (':III!
;fate and in s,)@ @f 'his 7nrllplex, vdiidi
'inalol, of dielate rxilynlt@vs, I i s, "Ahown In 1. This Complex
i:; oh!_.-Iined as a brown crystalline prc-,ci[ it.,Of@ 1@y re -,i irlci
, -he I' P R
,,vi'Lh cuprv- acetate in a methanolic MPUIUM. I spectrum (if Cull-TPA is
',,gure 2, It is concluded on the basis of this kvm-k O-t (-ull-TPA is a

6 3 1 -
ACCESSION NR: AP111001514
coplanar complex in which the Cu-N bond and the Cu-S borid -are predomLnantly
covalent. Orlig, art. has- 3 figures
ASSOCIATION: Institut kataliza Sibirskogo otdeleniya Akadeniiii 1--auk SSSR
(Institute of Catalysis of the Siberian Braw-+ f,f fl@o V
I E-Li: GIAug64
N"11 REF SOV: 007
CNCL: 02 SUB CODE: CC, UP
OITIT-TIFP 0111-1
Card 2/4

fig
-thiopicolinanili(i,.

MR: AP5001514
Uu-TT TPA

V
...................
Para
-a gn
(313orpti on
P@'Qleratf?a in th,.,
oxygen on nalle. Kin. 1 6 ro.j:pgO-jpj
18: 6)

SAZONUVA. I.S.1 KETYERp No?,
Work function of an electron of titanium dioxide and its solid
solutiono in the prooese of chamisorption and catalysis, XIn,I
kat. 6 no.3t449-456 My4e-165,. (MIM 164 10)
1. Inatitut kataliza Sibirskogo otdoleniya AN SSSR,

MIKIRYLOVA, I.L.; ',AZGji(',-VA, I."'.; KI"HER, N.P.
OAidation of carix)n monoxin@,- tn tiUijjh),n (1-4 0.7 i
solutiorw with tungsten and iron oxldrs. Kir.,. 104-
709 JI-Ag 165.
1. Irwtitut kataliza Sibirokog,) otdclentya AN'
KLTfER, N.P.; MAMAYEVA, Ye.K.; ALIKINA, G.M.j TYULENEVA, L.I.; AFANASIYEVA, S.M.
Catalytic properties of chelato polymers based on quinaldine
bin-thloamidess Kin.i kat. 6 no.5t849-853 S-0 165.
(MI RA 18: 11)
1. Institut kataliza Sibirskogo otdeleniya AN SSSR.

AJIJ5013059
JC/E 5,/007 /005 /0847 /085
C!
P. Soy@odinerli7u, 7, no, !Y65, 847-853
TOPIC TAOS. MY spectrum, cholatFj, i2nIvrP.-
D ill-Ostigation is ar. f

0 O-A
where R tv
R2, RIL, and R axe differen-t p
2 LiPhatic and aromatic radicals. The
results are su=--a-rizad in
2. is Pound Uiat
,%IXIwU%Op anu nejx activity is found to be addi-
The effect of Polymerization on the X-ray 'ine sti-ictLre of ths CC-rtr-al
Ar'm ana'Logous to thO effect of increased chainL-branchimg in Lhe m-ono"-er.
@iL- -V-

"R
art has 1 10 graPlis and 2 illumtratj@@,,,S.
7.
(In-alti

AP5013059
El"CLOSUREt Ol
f07
Fig. I
Comparl3on of the fire structure abnorption spectra o- the K
x-ays of copper for challate =01ECUIC8 DO -7 T-,?
@r-eren;. radicals R and R
1
I - TI