SCIENTIFIC ABSTRACT KESSLER, A. - KESSLER, YU.M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000721610014-9
• Release Decision: RIF
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• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Sequence Number: 14
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

KESSLER, A.; MARIAM, E.; PAULINY-TOTHOVA, V.
The diffusion coefflciert of zinc in NaCl crystals. Chekhosl
fiz zhurnal 14 no.1:34-43 164.
1. Institute of Physics, Slovak AcaderW of Sciences,
Bratislava.

KESSLER, Arnost, Mr. CSc.
Thermal resistances in multidimensional heat flow in electric
machines. El tech cas 15 no. .4:205-212 164.
1. Institute of Physics, Slovak Academy of Sciences, Bratislava,
Dubravska cesta.

@@SSLER, Arnost,- MIARIANI, Emil
On the electric conductivity and dielectric Ions of "pure"
artificially grown and natural NaCl crystals. Mat .1"yz can
SAV 14 no.4:317-323 164.
1. Institute of Physics of the Slovak Academy of Sciences,
Bratislava, Dubravska ceata.

Mg
A3

_sL E: R, M
Czechoslovakia/Phyoical Chemistry -- Crystala@ B-5
Abst Journal: Referat Zhur - ni iya. Vo 19, 1956, 60869
Author: KesslerY F. M.,' Vecerikova, V.
Institution; None
Title: Roentgenographic Staly of the Process of Thermal Processing of
Petroleum Coke
Original
Periodical: Studium kalcinace smolneho a petrolejoveho koksu pomoci
X -1-rsku, Paliva, 1954, 34, No 6, 154-162; Czech
f;ations, chemical ele-
Abstracti Performed were roentgenographic investi
mental and technical analyses, and meaburements of electric re-
sistance of 2 samples of coke from pitch (I and II), petroleum
coke (III) and semicoke from pitch JV) before and after th@b`al
processing at 1,3000-1,3800 in retorts of Glover-West type.
X-ra:k diffraction patterns were obtained by the powder method
with Cu-Kocradiation. For determination of radii of diffused
interference lines of the patterns use was made of previously
Card :L/:.4
Cz,echoslovakia/Phyaical ChoEanis"xy Crystals, B-5
Abst Journal: Referat Zhur - Khimiye., No 19, 1956, 60869
Abstract: described prociedure (Referat Zhur - Khlniya, .1.955, 8209). Struc-
ture of all samples of coke is 2-dimensionalL graphite planes are
irregularly oriented, Powder patterns of samples differ in in-
tensity and width of lines. Thermal processing results in de-
creased diffilzion of lines, especially line (004). From width of
lines of powder patterns it was determined that dimEmsions of coke
&-anules are increased after processing. Authors consider an index
of calcined coke a content H - 0-15% regardless of the initial
content (- 0-3-0.5% for I and II, and 4% for III). With decrease
in H content after themal processing the electric resistance drops
considerably. The authors consider that in the technologistl
calc ation processit is appropriate to utilize specimens of
cokelhe production temperature of which did not exceed 7000 so
that the H-content be of not less than 0.5%. There was noted a
correlation between granule dimensions of initial and calcined
samples and their contents of water, volatiles and ash.-
Card 2/2

KWSLERq F.; vECERIKOVAp V.
"study of Graphitization of Resin and Petroleum Coke by Means of X Rays"#
P. 188@ (FALIVAp Vol, 34, No. 71 JAY 1954P Praha# Czechoslovakia) I
SO% Monthly List of East European Accessions# (EUL), LC, Vol. 3, No. 12,
Dec. 1954, Uncl.

Far c6 M%
1 C T- 12 lcrv u
r
SL"03 rl-

oi@

Y Polaroc-.1phic determInation of wollybdenum in or-
'ujiri
"sigu Am. .4
--J, 1-IG-W(1955) (Hugh4h sunintarli-A 11.,
polar.,:-raphic, mcfll@id wa% worktd out whkh serves " 16f;
utvs contg. rruAlytillenita (1). (or critceritratri and for an
orc@ which cuistain only true" of Mo. ni: samples 3,re dis-
"AwA ill 11NO'. (licit rclicatedly brought to dr-5-ness with
IICI to remove SiCh. then treated with NfI,,OH to remove
re(OfIlls and A4011).. The Ali. is then brought to pff
5.0 with 14 M AcOl 1, and t1to 1wilarogratu, k obUined 3Acr
rti@uvlng RU Olt, under N, protection, In the pmvice of
ethylenediarninearetic acid. AcOlf, and AcONII4 at Pill
al),iut 4.6. The nicthod mn also be used to det. Bi and Cu
c-')Y- sk
u
b.1

C=w= 'OREKOV F. @JAAMA, k-411 1". M,
6 Vi-krul, vu;@i falit, 1955, Nn 3. pp
41=711!" b" I Ap@4 Cf@o (L@od.-n,. 0 11, 1 155
1ka5d)-Experi-t. - -- - --- -- -"t- " "'! . "
the (Guawin, Pr k7l, .- @,j c-1 .,I"
A O, that would adjust the
dT dT
theoretical values of AW and L 2-P contradicts experi-
mental evidence. The authors conclude that in order
to explain experimental deviations of the data on
AW and T 2 from the Debye-Huckel 'Itheory@, it is necessary
to consider the existence of ion-pairs and the changes
in the structure of solutions affected by increasing
concentration. There is 1 table; and 39 references,
5 Soviet, 12 German, 2 Indian, 2 Japanese, 2 Dutch,
I French, I Canadian, 2 U.K., 12 U.S. The 5 most recent
U.K. and U.S. references are; D. G. Miller, J. Phys.
Chem., 60, 1296 (1956); E. GlueckaLlf, Trans. Faraday
Soc., 51, 1235 (1955); J. B. Hasted, S. H. M. El-Sabeh,
Trans. Faraday Soc., 49, 1003 (1953); R. A. Robinson,
R. Stokes, Ann. N. Y. Acad. Sci., 51, 593 (!949);
Card 2/3 J. B. Hasted, D. M. Ritson, C. H. Collie, J. Chem.
cill tile 'Pheory rdl solution- of' 77 C6 1;
A* Coiw' sov/62-59-12-8/43
Strong Elect-rolytes
Phys., 16, 1 (1948).
ASSOCIATION: N. S. Kurnakov institute of General and Inorganic
Chemistry of the Academy of Sciences, USSR (Institut
obshchey 1 -eorganicheskoy khimii imeni N. S_ Kurnakova
Akademii nauk SSSR)
SUBMITTED: April 7, 1958
Card 3/3

4 -,An Al
5 (4)
AUTHORSt
Gorbanev, A. I
Povarovq Yu. hT., Sevostlyanov, E. S.
SOV/20-125-6-30/51
TITLEt
PERIODICAL:
ABSTRACT:
Card 1/4
Some Re6ularities in the Properties of the Solutions of' Strong
Electrolytes (Nekotoryye zakonomernosti avoystv rastvorov
sillnykh elektrolitov)
Doklady Akademii nauk SSSR, 1959, Vol 125, Nr 6,
pp 1281-1284 (USSR)
The authors state that it is possible to explain the
deviation of the properties of electrolytes from the Debye-
Hilckel-law only by taking the specific ion interaction into
account. On the basis of assumptions made in an earlier
paper (Ref 4) the contribution f of ion interaction is given
0
as amounting to ln f. = A7ra3Bc - B@jc (1). [a = r + r_
3 +
the sum of the crystallographic radii of the cation and anion,
B - 6.024- 1020, P, - coefficient taking the solvation energy
of the ion pair into account (Formula 2), c - concentration].
The deviation lg f exp = lg fD - lg fc (f exp =experimentally

Some Regalarities In the Properties of the SOV/20-125-6-30/61
Solutions of Strong Electrolytes
BPjo and b (dipole effect) as well as g (charge interaction)
resulted in no connection in the case of water. On the basis
of data (Ref 7) for formamide the valuOB of B@jc in a
formamido solution were calculated and represented as f(a)
and f(b) (Pig 3). The authors, however, emphasize that this
connection, which now becomes apparent, may be due to a
misapprehension. It happens that the salts for which data
in formamide are available, show a continuous connection
between a, b and g (Fig 4). Thus, the real argument of the
function BP1 c can therefore only be one of the variables
a, b, g. In order to clear this up, it is necessary to
determine the values for salts which do not fit in to the
curve of figure 4. There is no connection between a. b and g
and the deviation from the law of dilution heat. The dilution
heat is influenced in the same manner by the various effects
of ion interaction. In this case the entropy terms of the
equation must not be omitted. There are 4 figures and
Card 3/4 7 references, 4 of which are Soviet.

Some Regularities in the Properties of the SOV/20-125-6-30/61
Solutions of Strong Electrolytes
ASSOCIATIONt Institut elektrokhimii Akademii nauk SSSR (Institute for
Eleotroohemistxy of the Academy of Sciences, USSR)
PRESENTED: January 14, 1959, by A. N. Frumkin, Academician
SUBMITTED: December 26, 1958
Gard 4/4

AUTHOR S Gjorbanev, A. I. Kcss@@er, Yik. m.
TITLE,. Brief Cornmunicat.Lon-c. c n c e r n i n
Effec?l- on :he Structure c` Waler,
-a -a 1,o n o
PERIODICAL lzveotiya Akauemli nauk SSSR.
nauk, 1960, Nr 2, up I40-AILi mI!--, S S R
ABSTRACC P It was shr.,wn by a serles r)C 1--cansformatic-r-is
,@-hat the mel-@no-i for calculal-ing effect on ihe
sl@ructure cf water, prcoooed ty 1. 11. Ml-khay1ci and
Yu. P. Syrnilcov ,Ves@ri, Leningr- i;niv- Nr '@.,D, Serlya
flzlki I khlmli, %,yp. 21,
Elnj 1wor-es*,Irg fr@,,rl tJie 1A ai I aT nu- auan,@-i-
[e-mail] L, 12 exprc--sse,:; c r r ec fne,:- is I
Scvlet reference.
ASSOC'AT"N: Ins' 1@ute of Acaj-ry i," 3@-lerlces USS,@
Akai,.lemil r,-juv S)33p`@
SUBMiTTEDT un@- 23, -11959 a r d I

SINYAKOV,, Yu.I.; GORBUM, A.I.; POVAROV, lu.M.; KESSIZRp Tu*M.
Den3ity of H-mathylformamide. Izv. AN SSSR. Otd.khim.nauk
no.8:1514-1515 Ag 161. (MIRA 14: 8)
1. Inatitut elaktrokhimii AN SSSR.
(Forma.mide)

34824
8/020/62/142/005/015/022
S7 0 B110/B101
AUTHORSs Alpatova, N. M., Gorbanev, A. 1,, Ke-.9sler, Yu. M., and
Lozhkina, L. G.
TITLE. Physicochemical study of complexes between alkyl (aryl)
chlorosilanes and halides of tetrasubstituted ammonium
PERIODICALt Akademiya nauk SSSR. Doklady, v. 142, no 5, 1962, 10'15-1076
TEXT: The authors studied the complex formation between CH 3Sicl 3 (1),
(CH3)3Sici (II), C 6H5Sicl 3 (111), Sicl4 (IV) with NaCl (a), NaF (b), KF
(c), CsCl (d), CsF (e), NH 4 Cl (f), (CH3)4NCl (g), (C 2H04 NBr (h),
(C H
4 9)4 NCl (i), (C4H9)4 NBr (k), (C4H9)4 NI (1), ethyl pyridine bromide (M)
by chemical analysis (for hydrolyzable Cl, and argentometrically), con-
ductivity measurement, and visual observation of the dissolution. The
synthesis was conducted in Ar atmosphere at 35 - 400C during 3 - 12 hr.
depending on the dispersity of the salt. 1, 11, 111, IV reacted with e,
h, i, k, 1. With halides of teturasubstituted ammonium salts, complexes
Card 1/4

3/020/62/142/005/015/022
Physicochemical study of complexes ... B110/B101
are formed if the alkyl radical is long enough. Their ability to form
complexes increases with decreasing anion radius. In I and II, which
behave similarly, i dissolves with formation of two layers, The one has
anarganosilicon compound: salt ratio of 3:1 (viscous. at room temperabze
supercooled, colorless, or yellow liquids), the other a ratio of " 4011
(movable, organic compound with some dissolved salt), Dissolution of k
is analogous, I yielded no complexes, only slight ye:low coloring, and a
slight increase in conductivity of the organosilicon compound, IV behaves
like I and II but forms poorly fusible complexes. i and k dissolve in III
without layer formation to give a yellow solution with high temperature
coefficient of solubility. The solubility of i in III is much highrr
than in I and II, the conductivity x = 2.7'10-'4 for III:i = 5.4 : 1
(unsaturated solution); X = 7.4@10_5 for III:k = 45 t 1 (saturated solu-
tion). In the system II-i the layer composition does practically not de-
pend on time and temperature. This Is confirmed by equal conductivities
of the isolated complex and the com@lex together with the second layer.
Tne behavior of [ (CH 3)3'3iCI13(C4H9 4NC' to solvents provts a strong-ir
bond of the one molecule than that of the other two, Si was not separated
Card 2/4

S/020/62/142/005/015/022
Physicochemical study of complexes BI'C)/'B-,O--
off during, eleztrolyols of thFj nyntP:Tn T@
@j I I I f-1 1 1-0, Olnl 'it"
cJ i anil V in I tit 1) 0-21 4.
10 a/di,,, Low-rpsistance, p-ty-.e silicon
was dissolved in the systems I-i; II-i. and the solution of i in III, In
'he [(rH 3 )3SiC'13(C4H9)4 NCI complex and' its benzene solutions (I mole of
2
complex : 10 moles of benzene) at D a ' 4 a/dm ,silicon diG2olves with
almost 100 % current yield (referred to Si 4+). Complex formation, layer
formation, extraction of two (CH 3) 3SiCl molecules by aliphatic solvents,
the dependence of the complex formation on anion radii and cation dimen-
sions, the anodic behavior during electrolysis are similar to the behavior
of analogous Al compounds, the cathodic behavior during electrolysis is
different, There are 3 tables and 10 references: Soviet and non-
Soviet.
ASSOCIATION: Ins1itut elektrokhimii Akademii nauk SSSR (Institute of
Electrochemistry of the Academy of Sciences USSR)
PRESENTED: October 7, 1961, by A, Ti. @,rumkin, hcadt@mician
Card 3/4
r7l

S/020/62/142/005/'015/022
Physicochemical study of complexes B11O/BI0!
SUB,'ITTED: October 2, 1961
Card 4/@j

GORDANEV, A.I.; KESSLER. Yu.M#; KRYLOV, V.V.
Effect of the structure of strong electrolyte solutions on thermo-
dynamic properties. Zhur.strukt.khim. 2 no.3:260-267 My-Je 161
(MIRA 15:1@
1. Institut elektrokhimii AN SSSR.
(Electrolyte solutions) (Vemistry, Physical and theoretical)

POVMV,, U.N.; GORBANIV, A.Ipj XMIAR, TU,,M,; SMNOVA,_ I.V.
Activity coefficients of cesium chloride in N-methy1formanids.
Dokl, AN SSM 142 no, 5:1128-lM 7 .162, (KMA 1512)
lo Institut alektrokbi-ii AN SM. iredstarleno akadsmikom
AJXrumkirqaio
Cesium chloride)
Formpaide) .
Antivity coefficients)
i

KESSLRR, Yu LIFIlaTIN) N. P.1 NUCHINSKR, Ye. M.
!T!@@
Solubility in the ayotem water - oulfuric acid - p-chloro-
benzenesulfonic acid. Zhur. ob. khim. 32 no.12,3871-3876
D 162. (MIPA 16: 1)
(Banzoneoulfonic acid) (Sulfuric acid)
(Solubility)

-KESSLERL Yu!,14-i POVAROV, Yu.K.; GORWEV, A.T.
Problem of the aalting-out effect* Zhurestruktokhimo 4 noolsloo-
102 Ja--T 163, (MTRA l6v2)
1. Institut elektrokhimii AN SSSR.
(Salting-out)

SEUSTIYANOV.,.E.S.; GO.RBANEV,, A.I.; [e-mail]-(Moscow')
Apparatus for measuring electric conductivity. Zhur. fiz.
khim. 36 no.33644@645 Mr 162. (MIRA 1718)
1. Institut elektrokhimii AN SSSR.

GOLIDSHTEIN, I.P.; KESSM. Tu.M.; POVAROV, ru.M.; GORBAME7, A.I.
Dipole moment of N-mthylformamido. Zhur.strukt.khim, 4 no,3t
445-446 )@r-Je 163. (MIRA 16:6)
1. Inntitut elaktrokhinii AN SSM.
(Formamide-Dipole momen@B)

GOLIDSHTEYN, I.P.; ALPATOVAv N.M.; KESS R -Yu.-M.; GURIYANOVA, Ye.N.;
GORBANEV, A.I. 9 -t-
Interaction of hydrogen chloride, tetra-u-butyl ammonium chloride
with trimethylahloroollame In benxene solutions. Izv. AN S&9R.
Ser.khim. to.9tl683-1685 S 163. (KIRA 160)
1. Institut alektrokhimii AN SSSR.
(Ammonium compounds) (Silane) (Hydrochloric acid)

POVAROV, Yu.M.; KAZARINOV, V.Ye.; KESSIER, Yu.M.; GORBANEV, A.I.
Solubility of AgOl in solutions of NaCl and CeC1 in
N-mathylformamide and in formamide, Zhur.neorg.khim. 9 no.4:
1008-1010 Ap 164. (MIRA 17s4)
1. Inatitut elektrokhWi AN SSSR.

POVAROV, Yu.M,; KESSLER, Yu.M.; GORBANEV, A.I.; SAFONOVA, I.V.
Thermodynamic properties of solutions of strong electrolytes in
solvents having high dielectric constants. Dokl. AN SSSR 155
no.6tl4ll-1414 Ap 164. (MIRA 1714)
1. Institut elektrokhimii AN SSSR. Predstavleno akademikom
A.N.Frumkinym.

KESSLER, Yu.M.; ALPATOVA, N.M.; OSIFOV, O.R,
Electrochemical and physicochemical prcperties of aluminum compounds
in nonaqueous solutions. U3p.khim. 33 no..7:261-295 Mr '64.
(MIRA 17:4)
1. InsU'zut elektrokhimil AN SSSR.

AlThTLOVA, N.M.; Yli.M.
................,
narpounds of silicon. 2:rar.strl;kt.khim. 5 no, 2@-
332-353 lAx-Ap '64. (WRA 17:6)
1, Innti'llit elektrokhirii AN SSSR.

ALPATOVA, N.M.; USSLER, Yu.M.; GORBANEV, A.I.
Interaction of hydrogen chloride with halides of quaternary
ammonium salts. Izv. AN SSSR. Ser. kh1m. no.8tl369-1372 Ag 164.
(MIRA J?tg)
1. Institut elektrokhimii AN SSSR.

POVAROVF YU.M,@ KESSLER, Yu.M.; GORBANEV, A.I.
Thermodynamic properties of strong electrolyte solutions in
solvents with dielectric constants. Izv. AN SSSR. Ser. khim.
.no.10:1895-1896 0 164. (KMA 17:12)
1. Inctitut elsktrokhimli AN SSSR.
o7r,

FAIZIEVAy LeYes; U.@SWj lu*M,.j POVAR07j, Yu9M,
Activity coefficients of sodium and cesium chlorides In a
mixture, of formamide with ace'=Ide at 250 C, Elaktrokhimiia
1 vo,7t822--827 ji 165, (MIRA 18 tio)
le Institut elektrukhimii AN SSSR*

ALFATCVA, 11-44,@@SLER,, Yu.M.; G(IREAW-V,, A.I.
Anodic behavior of siltoon In some notyiquecua oolutl.,.-ons.
F,lf-kLr,okh!-ndta 1. no.7:8"-850 J-L 165. (M--MA IWO)
1. InaLltut t)lektrolddmdi AN SSSR.

POVAROV.9 N.M., Yu.M. -, GORBOEV, A. 1.
Trvt),,aodynamic praperttim of utrong alsetrolyte solutions in solventis
with high dielectric constanta. Rl.aktrokhimila 1 no.10:117/,-1181 0
165. (MIRA 18:10)
1. Insti-tut olektroknimil Ali SSSR.
U 3,