SCIENTIFIC ABSTRACT KAZARINOVA, M.I. - KAZARNOVSKIY, D.L.

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SCIENTIFIC ABSTRACT
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120-4-4/35 AUTHORS: Gorbachev, Y.M. and Kazarinova, M-I TITLE: 1 1. t if.- Detection of Disii ration Fragments and Charged Particles by Thin Scintillation Films. (Registratsiya oskolkov deleniya i tyazhelykh zaryazhennykh chastits tonkimi stsintillir- ~iyushchijni plenkairii) PERIODICAL: Pribory i Tekhnika Eksperimenta, 195?~Ollo*4, (USSR). pp. - 24 ABSTRACT: The aim of the present work was to design a fast detector of disintegration fragrients based on an application of tbin scintillation films. Tne following scintillators were used: terphenyl anthracene, 2.5 diphenyloxazol in various concen- trations in polystyrene. Tne obtained solution %as transferred by means of a pipette on to a glass surface and was then dried at room,temperature for a number ofhours. After the drying process, the film was easily detachable from the glass. To accelerate the drying pro ss the glAss can be warmed up to 50 - 60 C. A layer of UM ~1 mg/cm---) placed in a beam of thermal neu'jrons was used as the source of disintegration frag- ments. The layer was placed in a vacuura chamber at a distance of 5 cm from the scintillation film. All the measurements were carried out using a photomultiplier collecting 100% of the uardl/2photoelectrons. Pulses from the photomultipler were fed into 24.65 CO, 2'?.6 510 S 0 AUTHORS: Kazarinova, M. I., Zamyatnin, Yu. S.., 3` TITLE: 2.~) and 14,6' mov Nouf:1,c)[1 cvos,~,, seei 1~1?11:3 I.i I ,)4 o 24 1 .:1 j% 1. Pu, .1 ru , and Am~ -1 F1 n E, i A- --13SR PERIODICAL: Allommaya energlya, 1960, voi k~d`, 1,,!1, .-2, ABSTRACT: Following recent. Fission t, e file, Is hy fast, neutrons va rious resea 1 .01 If, I I, ied u es, I I I an empirical relation bel.wf.-Ai 'he rel-1, !,7(-- fissioll cr, f, probabilil-y f = CT c and para lite 4~u r Ne ver 1 he I C S 0 the functional -relation bel.wef.--n V ari rcumber A (for a fixed atomic number Z) was invesli~ated in some detail only for the case of' uranium, and thte !,-la, ex-pt *.ha, f rise, tween f and Z was no, ~~Iear a*.. all quit.e rapidly with increasing Z. TO C103C"' 1 3 aatiell, problem and .o gel.. a more r--elclst~ i'(A) -e1a`1i,.,ns-1~-.-1*P, :,4(", the authops exposed Th", r'u, I'Li- and Card 1/11 2.5 and 14.6 mev Neutron Cross Sec--lons 230 240 Th Pu 224 -1 24! and Am Fission. sc.", PU , , , Letter to the Editor 2."- and 14.6 iTlev neut.rons orig er J i i iL ngv ) Cj ' ' and targets bombardect Uy 11 k,--v Jeu! T h eregistra-icn of even'.ls tcclel- plac-1, '~,y :7~--~ans -,I' a fission chamber wil.h electron 13 p e C01-111CInt. of Th and Am "asz de,ermlred me I- r I ca I ly, and ha '-. o f P~l i n a t a vP i by "Weighing" it In the flux of, '.herrl,a1 -)n S The content of Am241 formed in a la;,er resull.ing frori, its I i i 1~ disin.egration was dF.'.e~rm '.rhe amoun'. )f knc,w'n accumulation time. P Am 24 1isotopes in layers under invest li7a- i~n was de- 1~ermined by countim4 CL -particles e~A,.,ed ~-hose Isotopes. The Fu2L"~ content in the layer was also determined from n~vpber of sporiranec~,S fiSSi-,-113, ' c,,ri f p 2~1 by ccun-ir" CL -par-tcles fr and the amount 0 u 1 41 241 2 Am The PU was ais~' layer Card 2/11 therinal neutron flux, taking 1,021-) 10 .Darn for -,.he 2-5 and 14.6 mev Neutron Cross Sections of' T(P46 Th 230, Pu 240, Pu 241 , and Am 2111 Flasion. SOV/89-8-2-11/30 Letter to the Editor value of the Pu 241 thermal neutron fission cross sec- tion. For Pu 240 and Pu 2111 various methods used agreed within experimental errors. Table 1 contains the results obtained together with the half'-lives used by the authors during calculations. Table 1. The characteristics of layers of Isotopes studied. r -- ----- ---- ----- Icc ....... .. . 1 (3 1 "j t I.,-) 1.2. lo" 1.1i 13,2 111 12" AIII""; SN", 1.011 Am""' L31 Card 3/11 2-5 and 14.6 mev Neutron Croon Sections of Th 230., Pu 240 , PU 241., and Am :~41 Fission. Letter to the Editor Card 4/11 77246 SOV/89-8-2-11/30 The 14.6 mev neutron cross section was determined by absolute methods. Neutron flux was obtained counting ct-particles from T(d, n)He4 reaction, while the background of scattered neutrons was determined per- forming measurements at different places between the chamber and the sources. The 2.5 mev measurements could not be made completely exact, becauSe of the small counting rate. Relative meanurementsutilized twin fission chambers which contained at the same time a material of known fission cross secWn for neutrons of given energy. Crca b section of Th w3~otake 941 relative to that of Th , and those of Pu- , Pu and Am241 relatiNe to the U238 fission cross section. 24l 235 For control purposes Am was compared to U . The 2.5 mev cross sections were also compared to those at 14.6 mev by utilizing the relative fission cross see- tion3 of materials used in the neutron beam monitors: 2.5 and 14.6 mev Neutron Cross Sections of Th 230, PU 240, PU 4l, and Am"41 Fission. Letter to the Editor 77246 SOV/89-8-2-11/30 0.13 and 0.34 barn for Th235 and 0.58 and 1.1 barn for U238 detectors at the respective energies of 2.5 and 14.6 inev. Cross section values are from papers of Hughes and Schwartz (see reference at end of Abstract). All 2.5 mev values agreed on the limit of' errors, and results are given in Table 2. Table 2. 2.5 and 14.6 mev neutron Induced fission cross sec- tions crf of isotopes, barn. xsotopeg I D.r- 6y Datm P"., 0., f.,y --- -- ---- - 'Ire 0, 4 1M I I; -L-0,3 U. 1-5 JAI Al :1 2.1; 1A1 1:2 �0.2 Am'"I 1, I)a 1.0, 1,x. (I] Card /11 rwi. cm C,P%% J.et,p., F-swi c.~ui2 a..Oaanb an rh4L tj 2.5 and 14.6 mev Neutron Cross Sections of 77246 Th230P Pu 240 , Pu 241 , and Am24l Fission. SOV/89-8-2-11/30 Letter to the Editor In Table 2, Reference Z-A is: V. G. Nesterov, G. 14. ~I Smirenkin, Zh . eks 'erim. teor. fiz., 35, 522 (1958); and Reference Z-B73 is: A. N. Protopopov, Yu. A. Selitskly, Atomnaya energlya, 6, Nr 1, 67 (1959). The authors paid spec~jj attention to possible mistakes in the case of Am , where the results disagreed with results of other authors, but they did not find any appreciable error. Evaluation of Results. The 2.5 mev neutron results verify the decrease of the fission cross section and the ratio f with the increase of A (for fixed Z). The explanation of this is connected to the decrease of neutron binding energy, and to the related rise in neutron evaporation probability. From thin standpoint the practically negligible influence of pairing'of the fissionable isotopes on f(A) seems slightly strange, since it affects the binding energy . The authors found also that f is not a single- E lued function of Z2/A since., as seen on Fig. A, VR each element has a particular f-curve. Card 6/h 2.5 and 14.6 mev Neutron Cross Sectiono of Th 230, Pu 240 , Pu 241, arid Am2111 Fission. Letter to the Editor 77246 SOV/89-8-2-11/.~O Fig. "A". Relative proba- M_ _J bility of nuclear fission f versus the parameter 2 Z /A. o, neutron-induced fission; x, photofission 0.4 (points o and x taken fromi _PU --- Yu. S. Zamyatnin, The Physics of Nuclear Fission, Supple- 0,2 ment Nr 1 to the periodical Atomnaya energiya; M. 35 35,S 36 K, S Atomizdat, 1957, p 27, corrected by taking into account newly published fission cross-section data); are data from the present investiga6ion. Dashed line Shows approximate f(z 2/A) relationships for various values of the binding energy. Card 7/11 2.5 and 14.6 v ''_ mev Neutron Cross Sections of* 77 2.'! b Pu 240 Th 230 PU 2111 , and Am 241 Fission. SOV/8()-8-2-11/30 .0 , Letter to the Editor Trying to fit all the curves togetiler jlsjrjg 7" n/A , at n / 2, dependence, It became clear to the authors that fitting curves of different groups of elements would require different exponents of n. To fit Th, Pa, and U, n should be 1.7; to fit U, Np, and Pu, n should be 1.2; to fit Ain 2 It 2with the Pu curve, n = 0.8. The authors note that the weaker dependence of f from Z is apparently connected to the fact that, in addi- tion to the Z 2/A parameter, f is determined also by the probability of neutron evaporation, which again depends on the binding energy of neut ono. 'If one takes into account that for a given Z /A and the oanic, pairing, an Increase In Z Is connected to a decrease of binding energy (see Table 3) and, consequently, with an increase of evaporation probability, it becomes understandable why one observes reduced relative f.ts:31on Card 8/11 probability of Isotopes of elements with larger Z. 2.5 and 111.6 mov ?Ieutron 230 P40 24 1 Th Pu Pu Letter to the Editor Table 3. cro.,j.,~ "sectiolij ol, and Ain-; Fi3aion. /10 Neutron binding eneegy in riuclei versus Z for fixed Z 2 A, ill inev. Card 9/11 Th"-" 7.1) 1,;j!33 "7 IN 1 7 21 t 5M It follows that by observing nuclei which have equal values of F one can exclude the effect of neutron 'B evaporation and obtain an f(Z /A depending on the fission process only (see Fig. fl. The 14.6 mev 2. 5 ai Id mev N'~:utron CrDss See! lon:3 230, Pu 240 , Piz 22 11 241 Th and Am Fission. Lette.- to the Editor --j-4! SOV,4~ 9 - 3 - 2 - I arid S. K. Sokolova supplied the Isotopes arid pre- parud the layers; 1, As Tinhehcnko and G. M Kukavadze performed the mass-spectrometric ;nalysis; Yu. A. Vasillyev and E. I. Sirot-In performed measure- ments on the accelerating tube; and M. S. Shvetsov, Yu. A. Barashkov, and E. D. Beregovenkc) helped "alu., mea.3' 'wements. There is I figure; 3 tableo, and 8 ref'- erences, 3 Soviet, 1 U.K., 11 U.S. The U.K. and U.S. references are: J. Huizenga, Phys. Rev., 109., 148~ (1958); D. Hughes, R. Schwartz, Neutron Cross See! ioriL:, New York, BNL (1958); D. Hall, T. Markin, J. Ino!F,. and Nucl. Chem., 4, 137 (1957); R. Leachman, Report Nr 24067, presented by U.S.A. at the Second United Na4 T--~ Int-ernational Conference fov the Peaceful Uses of Aicm~"c Energ%Peneva 1958~; M. Studier, J. Huizenet-a.. Phys. Rev., , 545 (1954 SUBMITTED: August 8, 1959 Card 11/11 -L 30954-66 EPF(n)_~/4)VA(h)/EWT(j. 4QVT(m)jETG(m)_6/&P(t) 1JP(d "liNI D ' G ACC NRz AP6013489 SOURCE CODE: UR/0120/66/000/002/0037/0040 AUTHOR: Degtyarev, Yu. G.; Kazarinova, M. I.; Protopopov, V. N. 41-C ORG: none lb TITLE: Fast neutron spectrometer using Si surface-barrier detectors and LOP SOURCE~( Pribory i tekhnika eksperimenta, no. 2, 19661 37-40 TOPIC TAGS: spectrometer, neutron spectrometry, neutron bombardment ABSTRACT: A semicondt On. An spectrometer has been developed whose sensing 40 eutT element is a thin film\of L16F sabdwiched between two layers of n-Si. Neutron bom- bardment of the film yields the splitting reaction Li6 + n - T + a + Q, in which the combined energies of the triton T and the.a-particle equal the neutron kinetic energy plus the reaction energy Q. A section of the sensor is shown in Fig. 1. Allowing for the loss caused by the g6ld foil, the authors used a figure of Q - 4.6 Mev for thermal neutrons and 4.7 Mev for those above 3 Mev energies. The preamplified pulses from each counter are si ed, giving an output of about % + Q, and this out- put is connected via an expander to the spectrum analyzer; with t e expander, any desired portion of the energy spectrum can be observed. Amplitude spectra of tritons, a-particles, and neutrons were obtained for bombarding energies up to 3.2 Mev. De- %1 Card 1/2 2 -1 ACC NRi AP6013489 Fig. 1*Detector construction I -- Ni dase; 2 -- epoxy filler; 3 gold foil; 4 -- L16F layer; 5 - n-Si; 6 outputs to preampe. - tected pulse amplitudes v9 neutron energies over the test range showed a linear relationship. The spectrometer design is recommended as being reliable and stable. Orig. art has: 5 figuress . [SH) SUB CODE: 20/ SUBM DAM 19Har65/ ORIG REF: 003/ OTH REF: 001/ ATD PRESS 4? 2- 41 Card 2/2 KAZARINOVAp N. F. KAZARINOVAO N. F. "The Chemistry of 9-oxy-, 9-orinoaryl Derivatives of Acridine." Min Higher Education USSR. Ural Polytechnic Institute imni S. M. Kirov. Sverdlovsk, 1956. (Disset-tation for Degree of Candidate in Chomical Science) So: Kni?hnapi Iatopial, No. 17, 1956. 'R1K'"0T'K0 F 24(7) 3 L'Yov. Wavermyt.t ?X'U I BOOX ZXFLOZTATZON 3OV1,1365 Kate x r1aly MO okul nfm Cc no -Pkt,-o ron 3P9ctr;.cCv,,y% (?841~re or th '"Pil- t. 1. 110, pr -To L-vo Vol. I t &I akogo Wv * loth Aal.t?njon Intel T t Qcu1&r 3p*ct Its, plyo a 1957. 499 roloopy) Additlonal ';~;? lbl'Vk, P-.4,opo)ooples 3POnsorin, A,*., *P*ktrOmkpjj PA. I j 79 AkA4* rdltorlai Boa* Aser a L et", A- SUR KOIL1.1'. '0 r4' "'*Qh Ed B 3 -s 34rarquk, T.V., labolins' - " Doctor are 0 3.. Aoad* I f&Y, I.L. Doe, - h~* I (R**P- U., D. -Or of p4hya1j,.4jr4a.XathtmAtlcaj Sol 004"d), K=k%`2t. V.A. &4t ralt,4U. V al or or phyal &them&tl"_ C4WIdat, or CADd4datq 0Al and MaM LL Sciences. "WIdato or pph7aloal ;;~ or Teola.al S Ofttloal sotinces. X&theZAt'oja S C-*nC*4 Raysidy. 3.M.. vamIdAte or plvs-*'u ahd MathomAtl GIOU0*51 ii 1 11 10A . Cal rsal 1010yokly. L.K. C&I'Al Xa-,"Atilml clence yo., Oat: Of thralaid *noes" Millyenol'uk V 3. Card 1130 and MR-meet, Gal I'a and "Subn'"A" IsAo*4. Babughkin, A.B. -A V Infrared 30 . . AW L A Am Surf Pect"st'Pla 3,,,, r - - C0 ReactIon, of , 0 the Ad,*rptlo. On AI__ O.U44 "`yl an~ PkttWl Alcohol@ 161 &Idorov# "r. study or 04 F'rous ler by Mean@ Of IftfArj Ab,or;tloa Speatra BelenIkLy. L.Z., X. y. jL, Photo"trl~ Stud, 4atro' 31d0rov T A ITO the jn~; -0 AM M-M. 3obol~v Z,,tople f 3,,,,tgV*" 3P*Otrum Of 90;i0 Aeld, AMShiltst 'a ShAYnker. Yu. M. 3P*Gtrg and Tautomerles or lists-GY6110 Aaing. AQYI&t*d "Ostovskly. 1. y4. Igo 40stragooolo sju~*,,* Shenker and 183 Cam 12/30 POSTOTSKIY, I*Ta.; SHHYXMt Tu.T.; WARINOTA N.Y* S~mctroscoplo analysis of 9-oxyarylacridines. Fis. abor. no.3t 183-184 157. (KLU 1118) I' Voaooyuzry7 nauolmo-iseledovatellskl~v khImiko-farmtnevtidhskiy institut im. S. Ordshonikifte i UmIlekly politekhnichaskly insti- tut im. S.M. Xirova. (Aoridine--S;*ctra) AUTHORS: Kazarinova, N. F., Postovsk-iy, I. Ya. TITIE: On the Tautomery of Acridine Compounds (K ta-a- il~-7~d--r-~-y~-'. 5c-ys- dineniy). On the Structure of 9 - I-- Oxyphenyl) - an(I 9 dine (0 stroyenii 9 - 'z nov). 47- - o~xxif en~-,I) 1 9 PERIODICAL: Zhurnal Obshche-y Khimii, 1957, Vol. 27, Nr 12, pp. ABSTRACT: The subject of tho D.-esent publicaticn is tl- ~r L. - 0 r'-Y structure of 9 - ~,'- - OVphenyl) - and 9 xyc'~ t-~ Disregarding the piesence of phanolrests ii, tlviy --vct~ not '~cIv.Y.e in alkalies. Both compounds are difficullt- t.rj :irzi drochloric acid and in organic a---icts and have a hLip'li k**) 340), different from 9-phenylacridine, which, ilicugh wiVi,,i!, hy- droxile group., melts already at 181~O and can e;~;1--'s melted in concentrated hydrochloric acid and o-rg~,ni- A! rEg~-Zds their characteristics both compounds remird ui c-' formulae). Based on the zomparison witll co-npcur-.& whi-cr, V-, ~z;'-W' have a phenol- and quino-d structure, the e-a"hQrL3 dines have oxystructure but not oxc- or The sun",-:'s Card 1/2 assume that the cause of tha weak phenc.l- AT,.,;- alk&lin- On the Tautomery of Acridine Compounds. 9 21 On the Struebux,% of 9 OjWphe- nyl) - and 9 of these compounds is the pcesence Df the st-ong intern-'-~- gen compounds. The new2,v syr-thetize-1 N-meth'..,)-9. dine is of unstable chara4,,terp There are 2' figures, I tablej and 8 referen-~-.-,, 3- ASSOCIATIOM Ural Polytechnic IrL-iti+.utq (Uraj7a~jy SUBMITTED: November 14) 1956. AVAILABLE: Library of Congress. 1. Acridines Isomerism Card 2/2 XURRATOV, D.L; XAZARINOU, N*F. 1- (2-thiedlazolylaze) -2-naphthel (?,,- =70), a new acid-bass indicator. Izv, Sib. otd. AN SSSR no.&4~97 '58. (MIRA 11:10) 1.Urallskly filial AN SSSR. (Indicators and test papers) (Naphthol) 5(2),5(3) AUTHORS: Kazarinova, N. F., Vasillyeva, 11. L. SOV/75-13-6-412/21 TITLEt Photo et 'o D termination of Germanium With 9- 1p-(N-Di'metnyl Amino) - Pheiiyl-2,3,7-Trihydroxy-6-Fl.uorone (Potometricheskoye opredeleniye germaniya s 9- lp- (N-Zime tilaminol -fenil-2,3,7-trioksi-6-fluoroncm) PERIODICAL: Zhurnal analiticheskoy khimiij 19589 Vol 13, Nr 6, I)P (177-681 (USSR) ABSTRACT: Among the known organic reagents on germanium, good experience has been made with 9-phenyl-2,'~,7-trihydroxy-6-flti,,)rone (Ref 1). By adding traces of germanium to the solution of this reagent in dilute hydrochloric acid, the color of the solution changes from yellow to orange and a raspberry-red procipitation takes place. The formation of this precipitate is an obstacle for the photometric determination of germanium and must be prevented by stabilizers (Refs 2, 3). It is therefore more advisable tc~ alter the properties of the reagent by introducin,3 other substituents, maintaining the sensitivity and specificity of phenyl fluorone and yielding soluble compounds with germanium. Card 1/4 For this purpose, the authors synthesized Photometric Determination of Germanium With sov/7r-1:,-6-12/-',1 9-[p-(N-Dimethyl Amino)) - Phenyl-2,3,7-Trihydrox;y-6-Fluorone-' 9-[p-(N-dimethyl amino)] - pheM~1-2,3,7-trihydrox~,-6-fluorone by condensation of p-N-dimethyl amino benzaldehyde, with hydroquinone triacetate in the presence of concentrated sulfuric acid. This synthesis is accurately described in the work (in a yield of 52%). The resulting reagent is a red fine crystalline powder playing to green and having a melting point of >3000. It is unsoluble in water as well as in the majority of organic solvents. It easily dissolves in lyes, in mineral acids when heated or in the presence of alcohol. A method was worked out for the photometric determination of germanium vrith this new reagent (briefly called DAFF). DAFF forms salts with acids and is stable in dilute acids. In concentrated hydrochloric acid a yellow precipitation separates, caused by the formation of a weakly soluble oxonium salt. The stabil-ity of the acid solutions increases with temperature in consequence of the increasing solubility of the oxonium salt. In the presence of germanium the color of the hydrochloric solution of DAFF changes from yellow to orange, in which connection a maximum of color intensity occurs only by adding a great excess Card 2/4 of reagent. The solutions of the- germanium compounds with DAFF Photometric Determination of Germanium With SOV/75-13-6-12/21 9-[p-(N-Dimethyl Amino)] - Plie'nyl-2,3,7-Trihyd'rox'y-6-Fluorone are stable in dilute hydrochloric acid (1 n) up to a content of 1.2jrGe02 per ml. They raprasc-nt highly disperse colloids and follow the Lambert - Beor's law up to quantities of 1 tGe02 per ml. An increase in acid concentration causes a decrease in optical density of the solutions. With decreasing temperature the optical density of the solutions increases considerably; these changes caused by temperature fluctuation are, however, wholly reversible. At constant temperature, coloring remains stable for a few hours, the maxim-am intensity being reached after 0.5 - 1.5 hours. The measurement of the optical densities was carried out by :~ M-4! photocolorimeter with green light filter. The sensitivity of determination amounts to 0.05t e02 in I ml Of the experimental solution. G As and Bi cause no disturbance. Sb (III), Sn (IV), and Mo (VI) react with DAFF in much the same way as germanium; the sensitivity of the reagent to these elements is, however, considerably lower than to germanium. Detailed working instructions for the determination are mentioned in the paper. Card 3/4 Photometric Determination of Germanium With SOV/75-1,7-6-12/21 9-(p-(N-Dimethyl Amino)] - I'lionyl-2,.5t7-Trihydroxy-6-Fluorone The authors thank I. Ya. Postovskiy for his valuable suggestions and advice. There are 3 figures and 4 references, 1 of which is Soviet. ASSOCIATION: Institut khimii Urallskogo filiala AN SSSR, Sverdlovsk (Institute of Chemistry of the Ural Branch of the Academy of Sciences, USSR, Sverdlovsk) SUBMITTED: June 29, 1957 Card 4/4 EAZARINOVA, N.F.; L&TOSH, Y*I.; POSTOVSKIY, I.Ta. InvestigatIM the complexons of amino acid derivatives. Izv.Sib. otd.AN SSSR no.2t60-70 160. (MIRA 13:6) 1. Ural'sIdy filial AN SSSR. (Complexons) (Amino acids) 1-57 1? 9 0 0 8oo63 S/02 60/132/01/37/064 B011YB126 AUTHORS: Poetovskiy, I. Ya , Kazarinova, N. F., Afanaslyeva, G. B., Latosh, TITLEs New Esters of Dithiocarbamic Acidel PERIODICAM Doklady Akademii nauk SSSR, 196o, Vol. 132, No. 1, pp. 141-144 TEXT: In the publications data on the protective effect of antiradon (AET, ~-aminoethyl isothiuronium bromide (I)) against ionizing radiation 'have appeared (Refs. 1, 2). Thus, the authors tried to synthesize compounds with a similar structure, namely, 8-aminoethyl dithiocarbamates (II). They have produced new carbamates with a non-substituted amino group (IV, V, V-0. They are formed by the reaction of ~-chloroethylamine with sodium salts of the relevant dithiocar- bamic acids (sodium diethyl dithiocarbamate, -tatramethylene dithiocapbamate, and pentamethylene ditbiocarbamate). The reaction producte were obtained as easily crystallizable hydrochlorides (Table 1). By using the known reaction between amines and quinones, the authors have synthesized now derivatives of benzo- and naphthoquinone (VII-XIV) (see scheme). These types of compound have recently become recognized as physiologically active, and as new synthetic drugs, amongst Card 1/2 W~ MoO New Esters of Dithiocarbamic Acids S/020/60/132,101/37/064 BO11/B126 other things as antibacterial and antigrawth mediums. The benzoquinone derivatives (VII-IX) and the naphthoquinone derivatives (X-XIV) contain A-aminoethyl- dithiocarbamate residues, and easily form on the interaction of free amines Vt' (IV, V, VI) with quinones in an ethereal solution. They are red,readily crystallizing, not easily soluble substances (Table 2). There are 3 tables and 8 references, 1 of which is Soviet. ASSOCIATIONi Institut khimii Ural'skogo filials. Akademii nauk SSSR (Institute of Chemistry of the Ural Branch of the Academy of Sciences, USSR) PRESENTEDt January 17, 1960, by B. A. Kazanskly, Academician SUBMITTEDs December 21, 1959 Card 2/2 KAZARINOVAP N.F.; PODGORNAYA, I,V. Chemistry of complexono. Report No.lt Derivatives of iminodiacetic acids. Trudy Inst,khim. UFAN SSSR no.W03-110 160. (MIRA 1616) (Complexons) (Acetic acid) r-, I- ~ POSTOVSKIY I.Ya.; KAURINOVA. N.F.; AFAKASIYEVAp G.B.; IATOSH, N.I. -.Aminoethyl diethyldithiocarbamate. Zhur. VKHO 5 no.1:3-13 160. (MIPA 14:4) 1. Urall.skiy filial AN SSSRj lutitut kl'-4mii. (Carbamic acid) SHEYNKMAN, A.K.; KAZARINOVA, N.F.; UBIN) Ye.P. N-acylpyridinium salts as pyridilic agents in Fridel-Grafts reactions* Zhur*MiO 7 no,1:112-113 162. NIRA 15:3) l..Donetskoys otdeleniye instituta, organicheskoy khimii AN SSSR. (P#7idinium compounds) (Priedel-Crafts reactions) KOLOK)YTSEV, L.R.; KAZARINCIVA, N.F.; 0SONYA, N.I.; SHEYNKMAN, A.K. Antibacterial action of some N-substituted py-ridine derivatives. Report No.l. HAkrobiol.zhur. 24 no.3:23-28 162. (MIRA 15t8) 1. Donetskoye otdeleniye Instituta organicheskoy khimii AN UkrSSR. (PYRIDINE) (BACTERIA, EFFECT OF DRUGS UN) KAURINOVA R.F.; BABI14, Ye.P.; SOLO&O, K.A.; KOTELMTS, M.I.; A.A.; SHEYNDWI, A.K. PreparatiWi of 4-ethylpyridine. Zhur.prikl-WP, 36 no.3: 649-654 MV 163. (MIRA 16:5) (Pyridine) SHEYNKMAN, A.K.; RUDENKO, N.Z.; KAZARINUVAv N.F,; LYSENKO, V.B. Structure of quaternary salts of 4-(p-dimethylaminophenyl)- and 4-(p-dimethylaminosiqryl)pyridines. 2hur.ob.kbim- 33 no.61l964- 1969 A 163, (MIIU 16:7) 1. Donetakoye otdolemiye Inatituta organichaakoy khimii At UkrSSR i Donetskiy gosudartitvennyy neditsinakiy institut. (Pyridinium compounda) KOST, A. N.; SHEYMCMANp Ae K.; LAZARINOVA, N. F. Interaction of acetylpyridinium salts with dialkyl anilines. Zhur. ob. Khim. 34 no.6t2O44-2049 Je 164. (MIRA 17:7) 1. Donetskoyt otdaleniye Instituta organicheskoy khimii AN UKrSSR i Moskovskiy gosudarst,irennyy universitet imeni. Lomonosova. V.A.; KAZARINOVA R.P. Temporary disability in skin diseases. Vest. derm. i ven. 38 no.3:71-72 Mr 164. (MIRA 18:4) 1. Ullyanovskiy oblastnoy kozhno-venerologicheskiy dispanser (glavnyy vrach V.A.Konnov). ,_KAZ~R~NOVA,_V.,_ kand.arkhitektury; FEDOROV, M., kand.arkhitektury Composition; basic categories and regiLlarities. Tekh.est. 2 no.l2s2-7 D 165. (MIRA 19:1) 1. Vaesoyuzny)r nauchno-isoledovatellakly in8titut tekhnicheskoy eatetiki Gosudarstvannogo komiteta Soveta Ministrov SSSR. 7 Al GRXBOV, I.V., inshener; VYAM Aand.tekhn.nauk, red.; SKYORTSOVI, --Fm I.P., red. iZdat el'stTa; STIPANOVA, X.S., tekhn.red. [Methods of transporting large reinforced concrete panels by geans of trucks] Sposoby pereT4)zki krupnorasmarnykh zhelezobetonnykh detalei avtomobilIny, transportom. Pod.red.V.M.Kazarinove. MoskTa. Gos.izd-TO lit-ry po stroitJ arkhit., 1957. 34 p. (MIRA 10:12) (Motor trucks) (Concrete blocks--Transportation) DROBTSHUA, D.V., rod.; CHIZHOV. A.A., voduehchiy red.: GHN='YEVk,-I.M.,, tekhn.red. [Geology and oil potential of the Vast Siberian Plain.] Geologlia i neftenost' Zapadno-Siblrukoi nizoannouti. Leningrad, Gos.nauchno- tekhn.izd-vo neft. i gorno-toplIvnoi lit-ry. Leningradekoe otd-nie. 1958. 273 p. (Leningrad. Yseaoluznyl neftianol nauebw-lasladovatel'- skil goologorazvedocbryi institut. Trud7, no.114) (HIRA 12:6) (West Siberian I'Lain-Petroleum goology) KUZIETSOVA, N.P.; KAZARINOVA, V.P. Geopbysical prospeoting In studying regional geologloal struoture of the West Siberian Ple6in. Geol. nefti 2 no.4:11-16 Ap 158. (KIBA 3.lt5) 1. Novooibirekly-geofixiohealdy treat. (West Siberian Plain-Proapeoting-Geophysical methods) WCC-NK AP5022639 ml/oo8g/65/019/002/0179/0100 AMR: Gromov. D. F.; ygrma Ia. Solodyankin,' M. A. TITIZ: Angular andenergy distribution of Mmma radiation on the surface of a iolume souroe 17 SOURCE: Atomnaya energiya, Y. 19, no. 2, 11165, 179-180 TOPIC TAGS: nuclear reactor, gamma radiation, nuclear physics apparatus ABSTRACT: Many layers of material are usually placed in nuclear reac- tors between the reactive core itself and the outside surface of the shield. Thereforep various attenuntion processes must be taken into account In calculations of biological shielding. The authors Investi- gated the angular and energy d1 Istribution of garuna radiation on the out- 'he results of their research are given side surface of the reactor. fl ' I for two cases. In one case, the reactor vessel wns protected in water b y a boron shield while in the other case no boron shielding was rovided, The Monte Carlo method vras used for calculations by means of -20 electronic computing machinee It was assumed, that the gamma rays are generated at the initial einergy levels of 29 31 49 59 6 and 7 Mev6 Mi 539-122!539-121.73:5391121.64 JL/ A Z -C WR -s A-'P- 5-- -0- 2-- -2- 6 3-- -9 0 The greatest statistical error after 12000 tests was less thnn 25% for angular and 20% for energy distributions, The distributions applied to two above mentionod cases and seven energy lavels were illustrated by two sets of histogramat The attenuation of 7 Mev gainma. radiations in lead shields was also analyzed, The results of this analysis expressed in dose rates were tabulated and graphically illustrated. ASSOCIATION: None SUMaTTED: 2omar65 ENCL! 00 SUB 00DIR: NP NO REP SM 000 OTHER: 000 04 Uil *to f "T a *0 A 04 00 00 Vi k 00,3 Aa-4 A I-m-- I LAM FAIAVE41M LMRAIAOI CWWCATON otbaw .&F for -4--T v I I U a Air q3. Is 09 -0 pt iitwts all . fV m am J--L ^00 .00 see :go too dreg see see "go t drul ee two,, it 1933. OW Is.-t WAC so - 4 0 00 -00 0 * .00 00 of 00 .00 Ao WIN ..... .I.VAlh .,W.. i 6 15 I v t' Mm * a q * 0 0 6 0 0 6 0 0 0 a 0 0 1111 0 0 0 0 0 0 0 a a All a '11 a J- 9 -JL TEAL AMC a 1 -1 A .. _00 lot' ..0 .10V 00 0 0 OBOCI **A t;4F 0 0 411 00 c .00 00 a .00 90 S. N kommv and Fertiluffs (h1cmule), 1J'--*W1M(19M1)--PQr the detu. .1 P in spatit, of it And 809 (106 Pmmv ot Cl and col"did 04 3 so An lkod is kdt&W providing a lisp all h 10% 140% in 149% will. b iotmduccd in the abompti,in noo train. For sts"liples Colors. Also on. mailer two IMM A.-e inWW-d: - with A&W4 the Miter Wills a said. motil. 00 too SQs VIA yield of P POIL&W nwthud. is 0 low. , de 1. F is~ 0 For . =tm 0v., C.6 or the riample dumild 1W drkd ia - -~t 11006. it may Adoo a Ail x lie driod in the ove but the temp. abould tall tscmd Nil. '00 0- WE 1. S. boo go - ------- -- woo woo silott AM iml kit all t 0 0 4 0 0 00,11 AV 41 0 0 0 0 0 0 0 0 0 0 00 0 so 0,0 0 00 0 06 0 a Goo ** o 0 00 " v a a 11 a H 14 4 A IL I A 4 1 4 - .. - , - 0110clOff ams, ""Walk 1" cc in I in so" I - .1 %V i i -Mfiepe 1 ad . 60"Webs "$-- i bd* 44 vtm Am sto Qsd I It l of M i i . 100 t NO b 0* 't j , ~ih ra to 3 y do mew 00 ip oh d&d Cos", tlrVAr., by ~& Of Nix O"Jer imbAblo 61tiods Ica moo 0 . ,* a6 As V Nit AL N X m" o . . , ~ ' W." cr, dick. d, P- T. ases sit V: 11 t goo 1; 4- u I X'41;111 ;spi 0 0 *9009:0000*0000* 0 0 0 0 0 0 a ar w w 00 0 0 " a ft v a 0 a 4 v 0 m one "Wi age Coo coo 300 goo goo Ago 1 too 9-8- too 6AA& w 0 0 1 1 v IN 9 A a 2 9 T 00*0600*000*0*0000 00 000 00 **so 9*0 09 ! 000000000000000 000 R q 000000 I I 0 al A A A 6 Orsimilliflu Is It It IN It IN j a 6 X .1 j- v -I., I -#A 0 Q( 0 tf It' I. It- 11 P- 4) U a to 00 A . 60 k Us 4don0matim of PA by tko eltmts msftsc % - 0 . Katarifitivi-OkMins %tA A. 0. flilimmiva. Zdwdvblv-i 2 00 -W.- Chow. Zovily. 1940,11,3 - 09 , orate methoct according to p"xvdum of osT JsqovFvd that in tbr pircocnce of dis"Yed We I be mult* tilt. 00 V lained wne tcKi bigh. 'Alva the SiOl was cirm"I Ity rt. -00 prated irvapn. with HCI nxymt value. f's Py, ).,Arfv ub. .0 0 00 go taitied 400 00 :;so 00 00 -- : ,l 00 W K O 00 so 4 L 10 AiTi U 0110, o p 11 11 80, S* 00 40 '01 00 10, OU 009 TO 0:0:6 00100000000000060-0 I"! roo zoo NO 0 tloo age 0 000000::A 0 IRS 0 1 :ftu x - , . a - - - ~r . V it 'W 1 111" 21 a' ISA MIS A A, V. a- a A T lit 4~.OJA,4~ ChOINI kna to vittaultog. A. A. filkilitus. raftsfift" Lish. im mW N sanittle ,I viviantle will, at a 1-9 -Tt v s. "a. 8% #4o Place Iti-A) "a. .4 the Cleat awn. a cyUmleir vquA;;;4- witst, a lintel, capillary faluiel. am A Itutiorn valve. add 111- 10 ml. of 10% 110, a few dn4m sit II Kl H l all I g. icth. %pe It; mclitylem blue "a. stKI mithON.Wki bg. NII.V aml I x X*C,tk through tbefuncirl. Osithir 11w Fr- wilhil I A to udis. in tin Intience W match, 11. Kalilmll a 00 616. ILA LIVIN.IVVI Ct&SlWKAIIV. It' s~7 - e; A -1-0 A A 0A it I CM 0 0 a 1 9 ro to 40 lp 0 0 0 0 0 0 0 0 -09 - zoo aof A zoo 00 Q 0 ",p Iroo -j a v 0 1 0 0 * 0 0 00 so 090000 0 a 11 U 1 0 o o 0 L If 3 U a 1, v 0 V JU M X It V S P 6 I a L P jt a A A 3 1 AA 0 M SEP ZUK b t 01 Q 43 a 4 -- _ _ _ - - . - 1 , A j ploclists ..b VeMpilts w I .00 - The mic 911146act of plosphocites. A. Keitsf- f J 11 140), Sfi. 144. F#VJ&hW� 1410V AriiQf111 901' ? f l lil Ki t 146 14 M IM N A - l r . t . m. i o. , . k.) , IM, No. 1, 40.--Br trMtft P"bmilvb with 110 + HP tbe4r orx~ mbstame im cc,x . qumthati%it~ itim tbr~ tnqd. ppt. The org. mbstame wai atudy" 1,y thr P"lKxl drVOMed for anslyzbW pmt. coah MW ~hal~ The contratsolbliumens. humit"a. rtwalwcnifland C g0# of C wmf* In bituawn 81.4-59.4, In huittic scid. 00%) 71.0 and in residual cost 77.3-43.1%. The ftinitnis (if 0013 H wit, mp.: &MI-SiC, 3.W8.2N and 4.18 4.71- OOU Humic &M prrilowninales In The orp. submanve of thr young" johopphoritra (Altirmbinskian) and rr-hinal ~wl 00 001 predommates in the ors. substance I-( the viorr Alivictil ' l s1i) phmpiporites. Podol IA; t ALLWSK&L LIVIIIA1160111 CLAISWIC08084 b U a AT 00 it, 0 0 a 0 0 *1* 0 0 0 0 0 0 0 0 0 0 0 0 900 000000000000000 .800 zoo 0 !wool 1101voisdac is# 0 Ole 0 e 0 0 0 0 0 0 0 0 0 0 0 0 0 _;_79t*7 o o * o o o s o s o a o Oi 0 0 0 0 0 0 0 4 0 ~Wfflwmw *0 A AIL III as 06944 1 is 1.141 OAJ .all III the finely grouall sample + IW2(v) Il. of Cial'arwiams .1. CAC(N with Wallets tradumadly add bit fill. &" di4tU by gradually rallaing: the ittap. to 00 tbil, trials. until Ills hax di,attt ovart conijOrf the dilatilliate In W. IV II0.1wil. laortioust mull M (itratim can lit itaide lot Portion, separately. * 4 of two inotbods, (1) To thr distillate sold I lindirstar (0.05".y. ads. of Na alisaarialaullmatl 0 the win. i% 140k. Then I with N Koff onto %1% 10011 will Intirmu" IICI (11124 N drirnm 41alut ch&nj" frout n41 to rrilow (jill SA) add w lom drop of MI (11.(*41 S I and tiff white himAground with TWNW, until the I *0 9 from yrflow to pink. (2) To the (fi%tWAte in red) and 0 4r indicator (0.03170 Wa. of alitar ad". until The Indicator turns Violets then ow NaXOi soln. In tarrem. Illvap. the spin, 1i i Drutarmalials with Ima 0.03 N I(CI until (be inall, to Yellow. Smartie ad. 0.4 N ArOll StA 21trult with ().S N Tb(NO.). lot AcOll to a tiaright pip It tv#11 t LITINAlialtif C&&jWKA,Ma IV OF W 0 A R 0 4 Q v all Cad - ' A Kamilli- -11- 0.5 W. Keep 00 Ir. t-41"I -06 11111ste '40rh b- ari'ller i' i a 96 . n a, l S .00 ) and fliarmile lid MI MI, of 400 i4e Until the Allet that 11C.&K.41fl-I d %0 Lalor changes add 1.0 ad. C 1 N %*,C.(h 0o 11-2 Mi. of -00 30,-*f ud., se stop chitnt" e Im"Walliattly COO r militating. MO O j too lee* Oi 94- too too so Is AV so AS *Iasi, 40 a.. U N Ogg w I Is 111 Aft A I it 0 0 0 0 00 009 000 am* to 106"0000 0*0 0 0 000 $q;q Ipsw WWW-6 0 . o&*o#oo#foq**o4v~ is ;; A 0 a x a a is 4; 41 14 to 4s 1! A a a A a - M A 'Ir P-t,lftjj#m~_ , - _ , ~ I I .- 01,11MM AND PAPOP#011#1 1,# 0 lest NV "of ;~i Coloftistris: dittertakaUm 6( bOt" to borsto ores "J*r j lot field wedIU-11, V - A lAih, 14. 243-50949), uIrlder rents% twilh M-Alfl ml. tA 40's 0 N 410 1; 0 4 Y I NIX).; all er emblic, fill rr Its I n 4 I'll). VVAUlllC`tTiC &A Alid Wk1h thr ft-01111C With C-10111 OA ,31 110SA Dil, 11) lilt) fill, lilt%. All'I ill. 1 1111 4 tilt milli. 140 215 t"L with Ck OJO!'(7. ImAll. oil Vvillille 14A Ill vmlA, I-lei. Mix. It( stAnd I lir., and ctutipirr -$ih lilt col"T 14 Welt VAill MAIIIIA111%. Isr. K~1,81.10 00 zoo 440 bee, lose ji st;t use 4 v life 0 00 6, or it 01 W el is is as #A A 'm 4 :Tag ? cc 4, 1, 0 0 0 00000,016 1 9 010 0 4, 4, %0 000 O's, go illito *of go 0 00 0 0 0 0000 0:0 0 '69 00 0 00 A. Cana On- Dissertation: "Photocolorimetrie Methods for Chemical Analysis of Natural Phosphates and Boron-Containirg Ores." 20110150 Sci Inst for Fertilizers and InsectofungicideB, XJnIstry of Chemical Inchistry USSR. so VeCheryaya M,Oskva %9.urn 71 Vin rT and vres contaWrix bitron. 21 (n), fill ol Nigan,11 (a fit it-0, 5ofilti"ll :it 1.14 It ii t1trat(d -1,1th EDTA ;Llbodium Salt) (11~ Ith miltvXiLIC al indi- ,xt~,r, to give tho cc-nuat of Ca. Anothr, I-Itic'm is titrateil, mith Etiothrome blAck T a, indici,tar, I. give file stink M ('a alld Vill: NIC Is ollt;lm-I I.). Pot, tbn duterminatiou of Ca and Mr in bgritte otirs, the nrt is rxwict~d with ncl, .n, 25 to ~a int -of the rolticn containing I to :Iijing Ca and IiII; =v trvated kith Aq IM to ppt *tlie mv4Uioxi,Ics. anti file solution is Zlt~rpd. 'Thi% solution ils tval,orated to a mfitabte vulame and Ca and Mg are detcrinined as dtscriN-d alwr. For the dotetillination of Ca and JAV, In the prestiict- of phospIliale. e.g.. in apatite, Ca Is dejertinkled hi%t by decumposing 0-6 g of apalite with 10 ini of 110 if 4 1), Itiltiting to '230 nil. taking a 50-m1 aliquot JK)rUnn And Wing 0 it 2.5 rm? cif 0- 1 N 1; 1 soluiirm, 10 tu 20 per cent . I% add,,-d to ttvv a 1,11 Of 12 (Ultiveffal tildivatorl, and tbell 0".' to 0.- j; of 3a, -ator. The ex(m, )f I is d,trt. in t, tin (,d bIr t! a lwl larl'o-1 *%' Cacti. Und" i1". the Cacti[,_%6lUtfo.n.__ --he result is c4lcxllawd ti-ci. The tota. ! Ca and Mg is determined by vidding 25 nk, uf 0-1 N :1 to .10 In[ of the acid extrazt. adding I D ml of a buff,ir Solution lprejwcd 1)), 07g of .11 ter, f-dding 570 I'll tit tr, jwr c cot ~~tj tion ai,d d-luting to I lal 0 . mid 9 it, 10 droIA ,f Vrik~Jlx,mw black T I'lle 4;!,, tion is (Illuttil to IM IDI unit c-im(olly tift-atvd tith 0.1 s A1,;,.;0, Und,r the _nm conditi'lliN. V.', n1l of 1 sohl lion mr! fitratcd Nvith the Mpot 1, sollition , 4, Is. ,kit I it !,arm Abs Jour: Ref Zhur-Biol., NO 12, 1958, Author Kazark11ij_2a-Y--_ .-t- inst of-gTv-en. ing of Karakul Title on Breading Idork in the Roar Sheeps, Orig Pub: Khodzhagii qishloqi Todzhikiston, S. kho Tadzhikistanal 1957, No 7, 10-12. Abstract: No abstract. Card 1/1 39 Concerning the Structure of an Intermetallic Zr Compound. Brief Communication SUBMITTED: Card 2/2 77122 SOV/70-4-6-23/31 J. Inst. Metals, 86, 504, 1957-1958. July 21, 1959 `;06 D2 25 /'D j 0 5 A ("j, ;.alkliia, N.I., and Yuz,~-,rncosklly, 3.1.7 In j s~nthesls ol" cyanuric a,-Ld' f.-o! 1, 1 'J'L ~',!.-arnal prikladnoy khimii, v. 34, no. 7, 1961, 1563 - 1587 D, in technical literature do not give the reaction me- I 12 1.4 the thermal treatment of urea nitrate under atmospheric ,_nd the present work deals with these aspects. With an of 0,01 gr., 3 gr. of urea nitrate in a glass test tube hea*-d in an oil thermostats to the required temperature and J_i tlir_ required time. After this the test tube was taken out, ~_';_'Ied and the contents weighed. Ammonium cyanate was determined the portions of the product by potentiometric titrntion. The of the separation method for determining ammeline and consisted of the alkaline extraction of samples of the 1/5 22h36 5/08 61/034/007/011/016 The eynthesis of cyanuric D223YD305 product followed by the spectrophotometric analysis of ammeline and ami;iclide (Ref. 27: N.I. Malkina, A.I. Finkel'shteyny ZhFKh 32, 5P 981, 1958). For better clarification of the procesep the sepa- rate products were expressed as the yield on the initial urea ni- i-rate via carbon mass balance. To study the kinetics of formation, cjmvirio acid was produced at temperature intervals of 132-15000 azil for corresponding experimental times of 15, 30, 60, 120, 180 n,inutss. In order to increase the yield of cyanuric acid and also to '*ree it from side products a series of experiments were carried 011t, the results of which are given in the following table: T,-.-ble. Cyanuric acid and oxyamino products (ammeline and ammelide) in the melt. ],~-6end: 1 - content (% on initial urea nitrate); 2 - before HN03 treatment; 3 - after HN03 treatment; 4 cyanuric acid; 5 - amme- I -Lina and ammelide; 6 - cyanuric acid; 7 ammeline and ammelide. Card 2/5 224 6 The synthesis of cyanuric 8/080/61/03.4 007/011/016 D223/D'405 Table.(cont'd) Cogspmanve xuanypovol xxono7m N ~O:VxImXXOuPOR~3OAxUX (m mu 0 X5& X &X348nxAs) 2 unaNG (D cwwpmmm ,wxo=og 0 AD 00 R6 PA WOTWAO . P="I"M Epuir"0300 RumnWra a WE"to'. L.1" 45.0 14.21 64.0 0 45.7 131 63.3 0 46.6 MCI 64.0 0 45.6 141 04.1 0 46.0 MO. 64.8 0 44.8 MCI 63.0 0 45j) t4l 64.6 0 44.2 13.0 00.2 0 Card 3/5 22436 S/080/61/034/007/011/016 The synthesis of cyanuric D223/D305 1 table and 27 references: 8 Soviet-bloc and 19 non-Soviet-bloc. The 4 most recent references to the Englit3h-language publications read as follows: H. Iidaj J. Chem-Soc.v Japanp Ind. Chem. Sect.9 54P 775v 1951; Ch. A., 47Y 1953; H. Iidap K. Vamakawap J. Chem. Soc. Japan, Ind. Chem. Sect., 57, 587, 1954; Ch. A.P 499 6609, 1955; Z. Voshida, R. Oda, J. Chem. Soc. Japan, Ind. Chem. Sect., 56t 92t 1953; Ch. A. 49t 4679, 1955; H. Kinoshita, Rev. Phys. Chem. Japan, 25, 34, 1955; Ch. A., 50# 7114, 1956. ASSOCIATION: Gorlkovskiy politekhnicheskiy institut imeni A.A. Zhdanova (Gor1ky Polytechnic Institute imeni A.A. Zhdanov) SUBMITTED: May 4, 1960 Card 5/5 KAZARNOV3KAYA, B. E. ~ Dissertation: "Shifting Water Pressure Corditions Inst imeni Academician 1. Cand. Tech. Sci. ; 1 of the Water-Petroleum Contact of a Field." Moscow Order of M. Gubkin, 3 Jun 47. and Flooding of Cil Vell,13 Under Up. Tabor Red Danner Petro2eizz SO: Vechernvaya Mcskva, Jun, 1947 (P~roject #17836) K11 ZL1 _117 _'~'KAYAI 1. 7. ;/'. t? f MM/Oll Wells YAr 194T' Petroleum - Well drilling "Movement of Water-oil Interface and Water Incroachment Into Wells Under Hydrostatic Heat," B. F. Kazarnovekaya, 4 pp TR Acad Sci" Vol LVP No 8 Consideration of an oil reservoir of great length with a plane oll-bearing stratum, slightly Inclined to the horizon, and wells drilled at right angles to it. P. -, 8T57 KAZAMOVSKAYA, D. B. Kazarmovskaya, D. B. -- "The Equilibriwa of the Reaction of Methanal Synthesis from Carbon Monoxide and Hydrogen at Elevated Pressure." Moscow State U imeni M. V. Lomonosov. moscow, 1956. (Disseration For the DeTee of Candidate in Chemical Sciences). So: Knizhnaya Letopis', lio. 11, 19,56, pp 103-114 KA7A.RNOVSKIY, U.S., karA.khtm.nauk-, SIDOROV, I.P., kand.tekhn.nauk; ,,-Ek7,ARNDV . kand.khim.nauk Equilibrium of horogenevue gas reactions at high pressure. Trudy GIAP no.7:21-25 '57. (MIRA 12t9) (Phaeov rule and equilibrium) (Onnes) SIDOROVO I.P.L-KALAMOVSKAYAp D.B.j ANDREICHEV, F.P. Recirculation flow method for studying the kinetics of hetero- geneous catalytic reactions at high pressures. Kin.i kat. 3 no.4:523-526 Jl-Ag '62. (?URA 15t8) 1. Gosudarstvannyy nauchno-issledovatellskiy institut azotnoy promyshlennosti. (catalysis) KAZLIMOVSKIY, Ya.S.; KAZARNOWSKAYA., D.B.; SIDal ov, I. P. SquilibrIum of homogerjeouo gas mix" reactions at high pressure, Khim.prom, no,10.-747-750' 0 162. (MIRA 15:12) (Gases) (Chemical equilibriun) K"ARNOVSKATA, D. B.; SIDOROTp I. P.; KAZARNOVSI=, Ya. S. Peteruination of the compressibility of methanol, carbon monoxide-bydrogen and carbon monoxide-bydrogen--notbanol mixtures at high temperal-mros and pressures& Eximo prom, no.3:205-~32 Mr 163, (KM 16:4) (methanol) (carbon monoxide) (Hydrogen) (Compressibility) 2 t3i f.t)T-11~j prit r,,) r mf~ 4.,j air, C, e KAZARNOVSKIY, U.S.; KAZARNOVSKAYA, D.B.; SIDCROV, I.P. Equilibrium of the reaction of methanol synthesis from carbon monoxide and hydrogen at high pressure. Xhim. prom. no.6: 426-433 Je 16). (MM 16s8) (Wthanol) (Carbon monoxide) (Hydrogen) KAZARNOVSKIY, Ya. S.; MAHAYLOVA, S. Aq_!~Z~RNOVSKAYA, D. B. Influence of pressure on the tberwal effect of the synthesis of methanol from carbon oxide tind hydrogen. Khim prom no. 3: 183-187 Kr '64. (MIRA 17:5) XATARNOVSKrr, V.D., inzh.,- FAZARNOTSIATA, Z.A-, insh. Washing salty soils for road construction* Trudy KADI no,22: 170-175 '58- (MIRA 12r4) (Soil physics) (Road construction) PKAZAR SKM- ~NO They have been teachers from the very beginning. lUn.nat. no.1:13-15 Ja 160. (MM 13:5) (TUNSPIANATION or OR.GKMj TISSUES, RTC.) AZER111KOV, V.; ARLAZOROV, M.; ARSKIY) F.; BAKM~IOVp S.; BELOUSOV, I.; BILENKIN.. D.; VAIELI, I.; VLADDIIROV, L.; GUSHCHEV, S.; YELAGIN, V.; YERESHKO, F.; ZHURBINA, S.; KAZAHNOVSKAYA, G.; KALIN11", Yu.; KELER, V.; KONOVALOV, B.; LE:3EDEV, L.; PODGORODNIKOV, M.; RADIKOVIC11) I.; REPIN) L.; WOLYAN, G.; TITARENKO, V.; TOPILINA, It.; FEDCHENKO, V.; EYDELII~',All, N.; WT) A.; NAWOVp F.; YAKOVLEV, N.; MIKHAYLOV, K., nauchn. red.; LIVANOV, A., red. [Little stories about tho great cosmos] Malon'kie rasskaq o bol'shom Kosmose. lzd.2., Moskva, Molodtda gvardiia, 1964. 368 p. (MIRA 18:4) IL 04311-67- EWT(m)/EWP(t)/ET1 JJP(C) M-~NB ACC NRa AP6018265 W SOURCE CODE: UR/0133/66/000/002/0171/0173 AUTFORS: Fomin, V. V. (Candidate of technical sciences); Kazarnovskaya, I, I, (EngineeO ORG: none TITLE: Resistance of martensite and martensite-forrite type stools to hydro-erosion SOURCE: Stall, no. 2, 19660 171-173 TOPIC TAGS: alloy steel, - ine equipment, sea water corrosion ABSTRACT: kho resistance of 10 different martensite and martensite-forrite types of steel tJ hydro-erosion was studied. The study was carried out with the aid of a magnetostriction vibrator as described by 1. N. Bogachov and R. L Mints (Kavitatsionnoye razrushoniye zholezouglerodistykh splavov,, Mashgiz, 1959). The rate of motion of the specimen was approximately 60 m/soc and the diameter was 8 =0 Several specimens were tested under natural conditions in sea water. The influence of annealing temperature on the flow impact resistance of the different stools was determined. Microstructure photographs of the apecinens are presented. The experi- mental results are omvmrized in graphs and tables (sea Fig. 1). It was found that the martonsite and martensite-forrite type stools acquire a higi.141!' resistance I~F hydro- erosion as a result of quenching and annealing. Stools ;YJLIODl OKhl6N4D4T,I-hnd 30Kh14G6T soess high resistance to hydro-orosion and action of sea water. It is Card 1/2 UDC: 620.193.16:669. 15-194:669.26 L 04311-67 ACC,NR: AP6018265 Fig. I Destruction curves for steel 18=4VA obtained in hydro- erosion experiments: (a) annealed state,* b) quenched and annealed state. a L LI ~ 0 0 12 .'Time from beg ning of experiments, hours recommended that stools 4KU3. 20Khl3 fgg.8~ and KhlOS2M be used in the construc. tion of parts designed to operate under conditions of intensive cavitation. orig. art, has; 1 table and 5 graphs, SUB CODE: 3-1,O/SUBM DATE: none/ ORIG REF: oo5 Stainless Steel ACC NRt AP6004175 SOURCE CODE: UA/0096/66/000/002/0083/0086 Dissert'aDt); AUTITOR: ?0minj V.V.' (Candidate of technical Belences, "azarnovskaya, Iol. (Engineer) I ORG: Murmansk Marine High School (H=anskoe Vysshe morekhodnoe uchilishcrie) TITLE: Resistance of high strength stainless ste'els~to the shook- cyclic action of a water Se ~ /i SOURCE: Teploenergetika, no. 2, 1966, 83-86 ,TOPIC TAGS: wear resistant alloy, high strength steel, stainless steel, mechanical shock resistance ABSTRACT: In the experimental work, the res1stance to failure was de- termined in a ~et-shock unit In fresh water, at a rotation velocity of the samples of about 80 meters/sea and a diameter of the exit open 6 zzle of 8 mm,(,' The foll iing type iteel w4e tested- of the X. X BT(~1918119T; 1257,hl4Gl - _lY.h4lND,k OKhlMy__4D2T)"N~414q6T, 'Olhl6~ D4 9 2, %J A te. __I1_ ,lKh16314AT~k2OKh16G14H3AFAand Kh25N5M ble sts the mec propertia n the resi ce to $f the steels investiGated under the conditions of the experli-ents.-10was found that the highest wear resistance.under the experimental conditions was exhibited by tha ,'Ca-rd -17"2- UDO: 669.15--44:620-193-16 ACC NRs AP6004175 dispersion-hardened austenitic ste'9~s lXh16G14AT and 201K'hl6Gl41T3AF, additionally alloyed with gitrogenV~nd the dispersion hardened steel OKhl6N4D4T. A high resistance to jet-shock wear was attained by quenching from 11600C with subsequent aging at 70000 for 10 hours. The steels investigated are atainlass and have sufficient corrosion IV resistance In fresh and salt water. Orig. art. has: 4 figures ahd 3.55-1 tables. SUB CODE: l1/ SUBM DATE: 00/ ORIG REP: 002/ SOV REF: 000/ OTH REP. 000 lift 2/2 D'i A 004 000 00*000000 0*6 0 0 Ilo******* E-K VIVIF-A 9U Ad A it 9 X 0 0 41 19 0 All lla~q LLLM-jk-JM-x - A- I , . Pavia$ T 00 00 The Allowstastic scwU Ali Im#k" of the cald- C-- bids trpe. IX)V Intl. J Phy., Chrn- 20. IM11, in '60 t F&tj," C,4d ill till, I&ItkV its diffin" 4111,1111 F&S Cue.. KOO. II&(h. fe-I 11 NI:1 177 7 - . , . "I", milli eo got mand 972.5 ki.-cal.jutok, see 00 j 00,01 :100 eel Site SLA 411ALLVIROKAL LFTIBATL41 CLASSIFICATION itim. lill'aliv. son*" .0 1 salami .10 a.. Gal AV 00 -jiT". 8 . W I I I I I . p -T It a ; I * 0 0 It 0 0 *1* a 0 0 0 0 0 0 0 0 * 0 0 : a zot too too I I I pw a a 9 1 IF a 9 aw a 3 1 V 0 0 0 0 0 q 9 0 0 a 0 4 a 0 0 oAff I- i- _- 1_._i . A Host of was" gunkm ese" 614 Waited aWly of Ow sow %Amlo. 0. P. MkWskil. L- J. "-" t. A. M*jp&m*r'y%u. and 1. A. Kami- -*.W - a. xwpwfnr.4:brm. lost.. Mowvwi. lwwl Aw. SMA S.M. . ". TWISOW.-The bmt of ". of the asomkis K% (pmpd. the action a( Os on dry KOH sod cift, witli liquid NJ7. in Till. HA0j. 16 4&4.) - KJ% (&q.) + IW + W+Mimuy to (ST.) AS.. %Cal./nu*; new, with the aid of kwwo lbermorlmus. dats, The cmlcd. t of tonnaticis of KO~ from the elements is #12.1 - 11.0 kml./mok. For The down". 2K0, - 21M, + 0,. Am' - -11.6. AS* - W em AP. - -21 1 bml.:. Mole. FarThe rameflaus iu;4,7d-I'n*tbv lwrp:of Ko~. the mecbAu6m XW + OX - X" + Olt Is exchulewl by the tkfmAyftmk Ws, caW. to All' is 13.4. IV n -32 Ar. m 111M, sow possible nwekx*Kn involv" The ;4;=te FICUSwely Koli-(h + Ch - KOs + 0~+1101. The kt;Wof KOmbduganslogoutto that d KI... te"Usawal of the X.F. type with a - IIJ194. c - MUS A.. Use lattiot is calcd. to 149 kcul.; brmv. the clecu 8"Y w"IeT 4 0". rated. to 67 bml.. Eg. 3 thum the election aftity of Of. IN. Than Had ad iwoMWi of 1. Xammovska 'a1"1 1. A. Xammy -ICUS776T.' Moscow). Aw. "22-8(1061).- hftt of lartuallass AN of (XW + (h 6 CAWI. d *tqd.SJ=.cfK(h dd-16806 4:m alilu%. . aaarimuica0y betwva 21 sad 23*. CAw- refliam am Mao& our uw of KA (2.43%1. Koll "I) im mm KOV. 67A ~6 (111"NOL obtAined In SaW Wmant with tbev"al GT.5kW-1uwk 311mmum by F.-.W (C.A. 8, 2319) Jtk ft_T& d ---- vmiw eculpti. m Boadan I - p I ~ - 1~,i - ~ -) li-- , I., ~, _ ~ . ~.'i --I--." KAZARNOVSKAYA,, L.I., kand. khim. muk. .,:, 1 Catal,vats for the oxidation of hydrocarbons in a krypton concen- trate. Kislorod 10 no.3:25 157. (MLRA 10:11) (Catalystv ) Otvdrocarbong) A e AUTHM: Xuarnovskays., L.I., Dykhuo, N.M., Nsrinskiy, G.B. 32-11-W60 TITM A Device for the Analysis of Oxygen-Nitrogen-Argon Mixtures (Usta- uovka dlya arAlisa. unsay kinlorod-axot-argon) PMODIMI Zavodskava Laborstoriya, 1957, Vol. 23, Nr 11 , pp. 1387-13M (USSR) ABSTRAOTt In order to be able to carry out the walysU mentioned aooumtely, a devioe is moommended, which in based upon the principle of the ab- sorption of oxygen by copper and of mLtrogen by calcium with inter- mediate measurements of the pressure of the remaining gas. The content of argon and nitrogen can in this o&se be attained with an aooumqy of up to 0.02-0.05% at a occoentmtion of < 5%. Though beyond that analysis up to a content of 80% is possible, accuravy is then reduced. The following are the basic parts of such a device: A burette with a oapillar,y &rot a U-shaped glass tube with copper and calcium; the burette k of 30 ml oontent) oonsists of some cylindrical reservoirs with oapillaries between them. The glass tubes are sealed by mercury with a -anom ter tube. The burette in in a glass vessel, which is filled with water and is provided with a thermometer. Gas pressure is here measured aooording to the mercury oolumn, for which purpose a Card 1/2 vessel in provided in which mercury ia able to rise under pressure. A Derioa for the Analysis of Oxygen-Nitrogen-Argon Mixtures 32-ii-W6o It is provided with two faucets: one leading to the air, the other to the pro-vaouum. pumps Absorption of oxygen is carried out in a Jens, glass tube by meww of granulated copper. Absorption of the ni- trogen was brought about in a quartz tube which is filled with calcium shavings. The gu mixture is oonveyed by means of a mercury pump. The process of amlyeia is deaaribea and examples of oomputa- tions carried out are given. There is i figure. ASSOOIATICK: AUAhtlft Scientific Research Institute for the Building of Oxygen Machines (Vaesoy4nyy nauchno-isaledovatel'skiy institut kislorodnogo muhinostroyaniya) AVAIMLIt Libmr7 of Congress card 2/2 AUTHORS: DiVman, V.V., Candidate of Technical Sciences, 67-0-3-7/18 Kazarnovskayat Lel. j Candidate of Chemical. Sciences TITLE.- The Prevention of theCarrying-Off of Lye From Decarbonizers (Preduprezhdeniya unosa shchelochi im dekarbonizatorov) PMUODICAL: Kislorod, 1958, fj Nr 3, PP. 35-36 (USSR) ABSTRACT: In high-pressure o_xyglen apparatus the purification of air from carbon dioxide is in the USSR carried out with lye (Yrith a caustic soda content of 9.5-10%). It happens on this occasion that the lye is carried into the apparatus by the draft of air if an excessive quantity of foam foms on the lye. It is said that this forming of foam, which exercises a detrimental effect and usmilly disturbs the operation of the apparatus, cannot be explainea by the quality of or by t4e manner in which the lye is prepared, and therefore investigations were carried out in this direction. Four samples of caustic mixtures were investigated: 1.) Used (impure) samples; 2.) Pure samples; -1.) Such as were taken from the upper part of the carbonizex, 4. 5 Such taken from the lower Tart of the carbon- izer. The results obtained showed in a convincing manner that the Card 1/2 carrying away of the lye from the deoarbonizer into the apparatus 25(6),5(2) Kazarnovsk2y V/67-59-2-5/18 AUTHORS: _a, L. I., Candidate of so -Mi'mical sciences,-Dykhno, N. M., Candidate of Chemical Sciences TITLE: Catalytic Combustion of Small Quantities of Methane in Oxygen (Kataliticheskoye szhiganiye malykh kolichestv metana v kislorode) PERIODICAL: Kislorod, 1959,,.Nr 2, pp 28-33 (USSR) ABSTRACT: Small quantities of hydrocarbons are always contained in the first krypton concentrate (during the extraction of krypton from air and liquid oxygen). They were removed on various catalysts by combustion at 0000. Due to its low degree of oxidizability, methane forms the main part of these hydro- carbons. Only a few papers have hitherto been published con- cerning the process of catalytic combustion of methane in oxygen. In this article the efficiency of various catalystg was investigated and the catalysts were selected according tc whieh are best suited for the combustion of small impurities of oxygen resulting from methane and other hydrocarbons. The authors Investigated cupric oxide, active aluminum oxide Card 1/3 platinum catalysts, copper-chromium catalystst and Catalytic Combustion of Small Quantities of Methane SOV/67-59-2-5/18 in Oxygen manganese ores activated by silver. OxyCen with an impurity_ of 0.02-0.4 % methane was uced for the investigation. The diagram of the plant used for investigating the catalysts is contained in figure 1. First, the gas was purified from carbon dioxide and then passed throuCh the reaction vessel, which was heated in a crucible furnace. The gas consumption was indicated by a rheometer. A small portion of the gas which had flowed through the reaction. vesoel was passed through caustic soda in order to determine the quantity of methane burnt on the catalyst. The other portion is led over a glowing platinum coil, where the rest of methane is burnt. The CO 2 content of the gas flowinG out here is determined by the titrimetric method. The degree of combustion of methane was measured in dependence of temperature and the gas volume which had passed through. (FiGs 293; Table 1). Further, the authors investigated the catalytic activity of manganese ores activated by silver, i.e. dependent on their siliver content and grain size. It resulted from all investigations Card 2/3 that manganese ores with and with no silver content are -Catalytic Combustion of Small--quantitien of Methane SOV/67-59-2-5/18 in Oxygen the most favorable catalysts. A change in the silver content affects the catalytic activity only to a small extent. Methane is completely burnt on manganese ore as soon as a temperature of 3600, a content of 0-10-0-15 % methane in oxyeen and a weight rate of flow of up to 560 11h has been attained. At 4000 the rate may be increased to 750 1/h. It resulted from investigations performed in the krypton plant of the Shchekinskiy gazovyy zavod (Shchekino Gas Works) with the assistance of A. A. Mokin, head of the oxygen plant, and A. P. Podchufarov, head of the krypton plantl that, by use of a furnace with catalysts filled with manganese ore or manganese ore activated by silver hydrocarbon, impurities of the krypton concentrate are burnt already at 4600 (compared with '(800 in the case of alumina catalysts) with- out deteriorating the degree of methane combustion. There are 6 figures, 3 tables, and 6 Soviet references. Card 3/3 3/064/61/000/001/007/0111 B132JB218 AUTHORS: Kazarnovskava, L, I., Dykhno, N. M, Vagin, Ye. V. TITLEs Burning of methane in mixtures with inert gases PER10DICALt Khimicheskaya promyshlennost', no. 1, 1961, 29-32 TEXTt The authors have developed an industrial method of purifying inert gases obtained in the production of orypton from methane. Several catalysts were used to oxidize methane quantitativelys manganese ores from Nikopoll and Chiatura, nickel catalysts, and aotivated cupric oxide. The initial mixtures contained nitrogen and methane, and some of themalso small amounts of oxygen. Also other carbon hydroxides were burned under the oxidation conditions for methane. The experimental unit used for this purpose is schematically shown in Fig. 1. The catalyst was introduced into stainless steel tube (1) and heated in electric furnace (2). The necessary CH 4 /N2 ratio was brought about by rheometers (3) and (4), and then the mixture was conveyed to mixing vessel (5). In column (6), the mixture was purified from CO 2 admixtures by means of solid NaOH, and then passed into tube (1). A Card 1/7 S/064/61/000/001/007/011 Burning of methane in mixtures... B132/B218 special procedure was applied when the CH 4 content waB less than 1~. In this case, part of the gas current was diluted with 0 2 up to a ratio 10:1; this was done in mixing vessel (10) by means of rheometers (a) and (9). Then, the gas was purified from CO 2' CH4 was burned on a platinum coil, and then the CO2 evolved was determined titrimetically. When the CH 4 concentration was above 1-2%, the gas analyzer BTH(VTI) was used. The catalysts were reactivated by N2_02 mixtures, reactivation being determined from the dif- ference in oxygen content in front of and behind the catalyst layer. As manganese ore is not regenerable, it cannot be used as a catalyst. A nickel catalyst loses its activity if the gas mixture contains C02 or high con- centrations of CH 4* At methane concentrations below 5A, it may easily be used. At a temperature of 500 OC, a volume rate of 65 hr- 1, and an initial CH4 content 0f-4-5", the residual methane concentration was less than 0-5-0-TA /0 for 10 hr . The use of activated cupric oxide yielded the best results. Card 2/7 S/06Y61/000/001/00 7/011 Burning of methane in mixtures ... B132 B218 This catalyst was produced by the method of M. A. Shpolyanskiy (Ref. 3, Zav. lab. 19, no. 10, 1166 (1953)). It was composed of a 990 mixture of GuO and Fe203 (BOA) and kaolin (20A). The experiments were made at 6600C and at a volume rate of 65 hr - 1 with binary N2 at a CH4 content of 4-5ci*', and with ternary N2 (82~'o) at a CH4content of 11~ (02 amounting to 7%). With one catalyst, 15 cycles of methane burning and catalyst reactivation were carried out. The residual CH 4 concentration did not exceed 0-5% before seven to nine hr . After this time, the utilization coefficient of CuO was about 25~'. The 0 above experiments were made in a pilot plant schematically shoun in Fig. 4. At a CH4 content of 9.1j.', the residual CH4concentration could be maintained for three and a half hr at 0.24'a if a temperature of 7500C and a volume rate of 70 hr:-l were used (Fig- 5)- When the volume rate of 70 hr - 1 was reduced to 35 hr -11 the residual CH 4 concentration dropped below 0-075',0'. At initial concentrations of methane of 2.3A and 9.1~46 the residual concentrations were Card 3/7 S/064/61/000/001/007/011 Burning of mezhune in mixtures ... B132/B218 0.1-0.2%. A residual concentration of O,5A was attined after 13 hr at an initial concentration of 2-3%, and after 7 to 8 hr at an initial concentra- tion of 9.1%. Then the initial concentration was 0-35~~Op the residual methane concentrationdid not exceed 0,0031,4 during 5 hr . The authors re- commend the following experimental conditions as being most favorablet 1 temperature: 700OC; volume rate: 70 hr - , Activated cupric oxide is the best catalyst since it warrants a maximum efficiency in burning of methane and can be easily regenerated, As P. LIvova and Ye. N, Razheva took part in experiments with the pilot plant. There are 7 figures and 5 Soviet-bloc references. Card 4/7 Z /06#61/000/001/007/011 Burning of methane ini XixiUil' 09 '-B132/B218 Fig. 1 1 Scheme of 10 laboratory unit tor bmnin g of methane Legendt I ) steel tube; 2) electric N, lurnace 1 3)~ 4) 9) rheometers; 6 and 11) columns with NaOH I 1 7) water tap; 12) platinum..,.. coil; '13 to gas andlyzer rM Card 5/-7 (h 3106416110001001100qlOil Burning of methane in m xturese'.. B132/B218 Fig. 4s Scheme,lof the-, pilot.,. - ~ ~)vq plant; Legends 1 JMdI 8).' valves; 2) and I I ,rotamete reI 3) CH container; rhbo-. 4 con'ta'ot furnaoej-.:,,-.,, meter;,&; 6) water separatorl 7) colu~m for the removal of CO I 2 9) ejectcLrl 10) regulating,:..... cohtaot galvanometer of-typo-,, I; mpwnP-64 (MRShohft~-54) a) 50 hydrogen, b)c) to type XTA . (KhTDK) analyzer. 1''Card 6~7 ~UALLLI'.Lu_ ILEH 1 1-11"' 4,)7 U _LL~A A i Burning of methane in mixtures ... Legend to Fig- 5: Time dependence of the residual concentra on of methane during burning with activated CuO at various temDeratures. Initital mixture'9.1~!, CH4in IN 2; - -1 volume rate: 70 hr x) time, hr; Y) residual con- centration of CH /Q. 4 S/064/61/000/0011/007/01 1 3132/3-71a Card 7/7 I P. "S 2 5/061/62/000/010/058/085 B168/BI80 AUTHORSt Kazarnovskaya, L. I., Kraft, D. P. TITLEi Determination of concentration and 8olubili of mineral oils in liquid oxygen PERIODICALt Referativnyy zhurnal. Rhimiya, no * 10, 19t 401, abstract 1OK92 (Tr. Vaes. n.-i. in-ta kislorodn. mao inostr., no* 2,. 1959, 149-158) TEXTs A visual fluorescent method is described for determining the concentration of oils in liquid oxygen. The oil remaining after evaporating a sample of oxygen is dissolved in dichlorethane, the luminescence of the solution in UV light is compared with that of standard samples. The results agree satisfactorily with determinations by weight. The solubility of lubricating oils in liquid oxygen was found to.be ---0.002 mg/l. VAbatracter's notei Complete tranelation.'~ Card 1/1 -----WAFIiOVSKAYA,,L.I.,, kand. khirrichaskikh nauk; DYKHNO, N.M., kand. k.himicbeskik.h nauk Removal of carbon dioxIda and watsr vapor from krypton concen- trates by absorption on synthetic zeclites. Trudy VIIIIKI,'.!ASII no.9:170-179 165. (MIRA 18:6) Av C, v 5 Doxadlhik ov~ctlile. V. G. Put,illf) 4ud .1-1. A. 7*rl,;Iy A421 I- - 1~ Di ~=4i~ "CA. and V Ix;iul on the 0:1 ?I~t vagicj between 0.5 P.-A The I,r.k i; a ~,uqd:,Irar viah ubrui valional,., 1, ~bly- 5rvcll rt~.rr-~O , amlittrefit%ale liWe 4- C--;, Of 017 b)tlll-IV~ fl rth--~l lh~ ,LrA enly I slfolll~ly oxjdl~"', w,tb thr f,mm,.ntj-:3n of uA1,49 from. pimf.n h unit aria!, jib %r d,.Wc tq,,,d SHT.Y.AXOV# E.N.; SHROIT, I.G,j GUZv Ye.V*; UZARNOVSKAYAp M.L. Primary intestinal form of anthrax. Zdravookhrananie 4 no. 1:58- 59 Ja-F 161, (MIRA 14:2) lo Iz Moldavskogo instituta epidemiologii, mikrobiologii i gigiyeny (direktor - N.N. YezhovL4 Kishinovskogo maditsinakogo instituta (direktor - N.A. Notemitsanu). (ANTHRAY.) BSRKHW. D.L., o sent (Leningrad); ITSKINA, R.S. (Leningrad); KAZARNOVSKAYA 0 S. (Leningrad); P&RKHMOVA. A.I. (Leningrad); RMD'j?r 9 ningrad). Treatment of tuberculous maningitis in adults. Klin.med. 31 no.12:31-36 D 153. (MLRA 7:1) 1. It tubarkuleznogo otdoloniya bollnitey im. Kuybyshava. (Tuberculosis) (Straptomycin) (Meningitis) 3 35 8 7 S/204/6i/001/005/005/008 h2d 0 E075/E484 AUTHORS: Bobkov, S.S., Kazarnovskay~kR.Sh.. TITLE. Some problems concerning oxidation of ethylene PERIODICAL: Neftekhimiya, v.1, no-5, 1961, 661-668 TEXT: The paper gives results of an investigation into the oxidation kinetics of explosion-safe mixtures of ethylene with oxygen and nitrogen. The concentration of oxygen was below the upper limit of flammability, i.e. below 13%. The experiments were conducted in a flow-circulating apparatus. Ethylene was mixed with nitrogen and fed into the circulating system. Oxygen was added immediately before the gases entered the contacting zone. The catalyst (5 nil of AgO with surface area of 0.3 m2/g) was placed in a glass tubular reactor (I.D. 22 nun) heated electrically. The VK oxidation temperature was varied from 200 to 2400C. It was shown that no diffusion effects existed at these temperatures. For the mixtures containing more than 33% of ethylene the velocity constant for the formation of ethylene oxide increases more than 100-fold. Energies of activation calculated for the formation of ethylene oxide and carbon dioxide and water were 14.3 and 21.4 kcal/mole Card 1/4 4 33587 S/204/61/001/005/005/008 Some problems concerning E075/E484 respectively. All products of the oxidation form directly from ethylene between 1.90 and 230'C. Formation Of C02 from ethylene oxide is predominant above 230*C. By changing the concentration of ethylene in the mixture it was shown that the reaction order for the complete and incomplete oxidation of ethylene is zero in the temperature range 200 to 240"C. Reaction of the second order is observed for the reactions C,!H4 + 0 = C2H40 and C2114 -t- 302 = 2C02 + 2H20- As the reaction velocity depends both on the content of oxygen and ethylene in the reaction mixture for the above reactions, it is impossible to increase the selectivity of the process by changing the composition of the mixture of reactants. Introduction Of C02 into the reaction mixture does not increase the oxidation selectivity. Concentration of ethylene oxide has the most marked retarding effect on the velocity of' its formation from ethylene, but has no such effect on the formation Of C02 and H20. Thus the removal of ethylene oxide from the reaction mixture greatly increases the selectivity of the process. The retarding action of ethylene oxide, or its oxidation products, results from its irreversible adsorption on ethylene oxide. This effect is especially visible if the catalyst is Card 2/4 33587 S/2o4/6i/00l/005/005/oo8 Some problems concerning E075/E484 heated before the reaction at 200 to 2500C in the atmosphere of oxygen. It was shown that a part of the adsorbed ethylene oxide can be desorbed from the contact surface in an unchanged state. Apparently the deactivation process in this case is due to adsorption of ethylene oxide on silver. The following empirical equations give the dependence of velocities Wl and W2 of the complete and incomplete oxidation of ethylene respectively: klC2 W 02 (6) CC2H40 + kICC02 k2c2 W 02 (7) ;C C02 3358 S/294/61/001/005/005/008 Some problems concerning ... E075/E484 M.I.Temkin, N.V.Kullkova, A.I.Kurilenko and M.Ya.Rubanik are mentioned in connection with their contributions in this field. There are 4 figures, 4 tables and 5 references: 3 Soviet-bloc and 2 non-Soviet-bloc. The two references to English language publications read as follows: Ref.3: Shen Wu-wan. Ind. Eng. Chem. v.45, 1953, 234; Ref-5: A.Orzechowski, K.E.McCormack. Canad. J. Chem., V-32, 1954, 388. SUBMITTED: MaY 3, 1961 Card 4/4 KAZA VSKIY, A.N., inzh. Preventive maintenance of painted Burfaces. Trud7 TSNII MPS no.208sI59-110 161, (HIM 14: 5) (Railroads-Care-,Maintenance and repair) XAZARNOVSLIY, D.L. Creative initiative at the ITR Dmitrov Wt goods factory. Leg.prom. 14 ro.2:14-17 F 054. (HLRA 7:5) 1. Glavnyy inshener fabriki. (Dmitrov--Knit goods industry) (Knit goods industry--Dmitrov) UZLRNOVSXIT, D.L. Improving the preparation of yarn for knitting. Leg.prom. 16 no.5:51-52 My 156. O= 9:8) 1. Glanvyy inslasner DmitrOTOkoy trikotazhnoy fabriki. (Dmitrov-Milt goods industry) KAZARNOVSKIT, D.L. New system of repairing tachnological equipment. Laq;,prome 18 no.9:9-10 S 158. R& 11:10) 1. Glavnyy inshoner DmItrovskoy parchatochnny fabriki. (Knitting machines--Maintenance and repair) e lb I oles 6 f03 ~06 OT 011A 01 10.0 ere ON vei, V 0q S) . OGP7~ '160 WW nvo evor olq,~%Jl- Vp