SCIENTIFIC ABSTRACT KAZANSKIY, V.B. - KAZANSKIY, V.I.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000721320008-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 13, 2000
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

AUTHORS: Kazanskiy, V.]R. , Docent, J?;
]4.1. Engin. r
TITLE: he 25th Anniversary of the Fo-~Lnd Ing of ORGRES (K
dnya osnovaniya ORGRES)
PIMODIC11: Elektriohestvo, 1958, Nr 5, pp~ 88-89 (USSR)
ABSTRACT: In May 1958 it will be 25 yeman- sinre the State
Trust for ih& or--
ganization and rationalization of ~.-gioaai electric power
plar,,.-A
and networks (ORGRES) of the 11in.'stry' for Electric Power
Plant~, hazz
been founded. The 'basic ta3k to be performea by ORMES isi to
render
technical aid to plants in patting into operation and
int-rod-,icing
new equipments for power engineering ir. order to increase the
safe-
ty and economy of these plant-3. ORGRES has Sr-a+ -Ixperience
-,,n thi.3
field and worked out numeroxLs schemes and const-,uctions, The
mea3-
ures recomended are published by ORGRES as w--ll as by the
llini,3try
for Electric Power Statiom. In the cou--se of 211; years more
than
200 electric power statiow wer&3 able to start operating
-,,.--th `-,he
aid of ORGRES. The most important aovL'_,~-vement during
N-e..ent yeanz
was starting operation of the Kuybyshev hydraulir, pover
staticr.
ORGRES developed a number of mea3urlirg dev3ces, pu'tl4_5hea
instruc-
Card 1/ 2 tions for electrical equipment, ar,3 mrri~,d out work
in

The 25th Anniversary of the Founding of ORGRES lo5_5p
with safety measures to be un3ertaken in conrr-~ctior vrith the
alato-
Mation of systems. Also a n=ber of rt~contnendation_.3 for the
tion of losses in networks, securing the necessary voltage, Azz-~d
for the economical distribution of act~-;e- and rea.-tive loads
weer-~
elaborateaby ORGPMS. Such probletwR a.,~ the rztduction of
,,taff:-,. 'Ji
substations and changing over to operation without- the necassi'y
of a permanent control of the steering pai~el are solved. On thl
Khotlkov test stand the staff is trained for bu-~lding- and
assem~-I'y
work in connection with the 00 W long-diatance linez. The work
carried out by ORGRES is coordinate] rrith that perltomei "by thp
Institutes (VEI, MUN, NIIPT, VNIIE). ORGRES det,-~ALoj)-?d
for which achievement M.Ivankin, V.Ye.KAzam;kJy, G.P.MinIn &n3
N.P.Lapshov were awarded the Stalin Prizt. Among the new
teiem~-ter_~,
the type T40-53 deserves to be mentioned? which ,Yaz; Jeve'ope3 cn
the basis of T40-3. At present ar apparatus for wx~-c~ma:tlc
quency- and power control developt-d ac:cording to tb-:~ ORGRYS
rnetho-5
is being tested in the Ural power engineering systei.,_- and in
the
electric power stations of the Belonuenergo,
AVAILABLE: Library of Congress
Card 2/2 1. Electric power prod uc t ion-- Organ! za tJ~ or,-.-
UfM 2. Power
plants--Development 3. Electrical networks--Development
S/109/62/007/001/024/027
D266/D301
z
~. ~ //D
AUTHORS: Kazanskiyp V.B., and Stepinp L.D.
TITLE: Calculating the dielectric constant from measurements
performed on an axially placed sample in a cylindrical
H01n. resonator
PERIODICAL: Radjotekhnika i elektronika, v. '19 no. 19 19629
173 - 175
TEXT: The dielectric constant E and the loss tangent tan 8 Of li-
quid dielec*~rics can be obtained from measurements in a
cylindrIcal
HOln resonator a8 explained in a previous paper of the authors and
V.Y,. Tkach (Ref. 1: Radiotekhnika i elektronika, 1960, no. 12,
2009
The dielectric constant is expressed there in the following form
2 + k 2 (1)
2 + k 2
0
Card 1/2

BORESICOV, G.K.; DZISIKOY V.A.; YNRnIYANOVA, V.M~;
PECHERSKAYA1, YU.I.;
WANSLUI-3-Rio_
Catalytic activity and-erlectron paramagnetic
spectra of
molybdenum oxide catalysts for the polymerization
of eth
,Tlene,
Dokl. AN SSSR 150 n0.082"2 JO 163. (MIRA 16~6)
1. Institut kataliza Sibirskogo otdolenlya 0 SSM i
Institut
khtmicheakoy fiziki AN SSSR. 2.
Chlen-korrespondent AN SSSR
(for Boreskov).
(Molybdenum catalysts-Spectra)
(Polymerization)

KAZA!ISXIY, V.B.; 14ARCIIENKOp A.I.; STEPIN, L.D.
Circuit for measuring the dielectric constants of
substances In the
3-cm. wavelength band. Prib. i tekh. eksp. 8
no.itio'-'.O~j
163. (Mi R
L Radiofisichaskiy fnkulltet Kharlkovskago
gosudarstvennogo
universiteta.
(Electric measurements) (Dielectric constant)
R

-- - - ~, -~ ~~A - _-- -
.t- - - - ~ -1 1 ...- 1-t~-
~ - - ----
-1 .1 - -
, ;: k-; , - , ~.-
. I .

AUTHORS:
-
Kazanskiy, V. B., Voyevodskiy, V. V. 20-4-29/51
---------------------
TITLE;
-
Note on the Ole of Hydrogen Atoms in the Catalytic

Oxydation
of Hydrogen on Palladium (o roli atomov vodcroda

v reaktaii
kataliticheskogo okisleniya vodoroda na palladii).
PERIODICAL:
Doklady AR SSSR, 1957, Vol. 116, Nr 4, pp. 633-655 (USSR)
ABSTRACT:
Wagner (Vagner) and Hauffe (Khauffe) (reference 2)

investigated the mechanism of the catalytic oxydation of

hydrogen on metallic palladium by comparing the

stationary
concentration of hydrogen atoms at the surface

of the
catalyeator with the concentration corresponding to

equilibrium. On this occasion the authors established, that

a
chain-like mechanism of this reaction is possible. The

authors
of this paper examined the final conclusions by

Wagner
(Vagner) and Hauffe (Khauffe) by an independent

method, using
a different experimental procedure. According

to modern
conceptions a dissociation of the hydrogen

molecules at the
surface of the metal takes place in the

adsorption and
dissolution of hydrogen in metallic palladium,

resulting in
the formation of adsorbed atoms. The solution
Card 1/3

Note on the R81e of Hydrogen Atoms in the Catalytic
20-4-29/51
Oxydation of Hydrogen on Palladium
and diffusion of hydrogen within the metal apparently
takes place in the form of ions. The authors compared
the stationary concentration of the hydrogen atoms on the
surface of the palladium with the concentration corresponding
to equilibrium with the help of a diffusion process in a
vacuum circulation apparatus. A capillary tube consisting
of palladium served as a catalysator. The numerical data of
the experimental arrangement are given here, and the occurse
of the experiments is explained. The results from some of
the experiments of the authors are compiled In a table.
According to these data the stationary concentration of
the hydrogen atoms in the reaction zone is considerably
smaller than the concentration corresponding to equilibrium.
For the purpose of a more precise investigation of the
mechanism of the reaction, the authors computed the deviation
of the stationary coneentration of the hydrogen atoms at
the surface of the catalyeator fro m the equilibrium
concentra-
tion with the assumption of a radical mechanism. The data
computed in this way were then compared with the experiment.
Card 2/3 Oxygen does not modify the mechanism of this
reaction. The

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3/68i/6o/00G/021A)06/fj18
A 6 -~? 0 A005/A001
Translation from: Referativnyy zhurnal, Khimiya, 1960, No. 2 1,
p. 5G, ;7' 939TI
AUTHOR,3: Kazanskiy, V. B, Voyevodakly, V. V.
TITLE: On the Problem of the Possibility of Chain Mechanisms at
the
Catalysis on Metals. An Investigation of the Mechanism of Some
Catalytic Reactions on Metallic Palladium.
PERIODICAL: Probl. kinetiki i kataliza, 1960, Vol. 10, pp.
398-403
TEXT: The mechanism is studied of three catalytic reactions on
nnetallic
Pd at 150 - 3000C: the hydrogen exchange with deuterium, the
oxidat.Lon
the hydrogenation of C,41!,. The reaatian mechanism is radical
in all trio three
cases.
Summary of the nut"Ihor,,;
Translator's note: This is the full translation of the original
Russian Ibstract.
Card 1/1

S/195j6O/OO1/004/005/0--5
B017/B055
AU THO R s: Kaztirlskiy, V. B., Pariyskiy,, G. B.,
Vcyevodskiy. V. V.
TITLE: A Study on the Pzoperties-of Hydrogen Atoms
Adsorbed on
Silica Gel Surfaces by Applying Electron Paramagnetic
Resonance
PERIODICAL: Kinetika i kataliz; 1960, Vol. 1, No. 4, PP-
539-541
'TEXT : R. Livingston, H. Zeldes, E. U. Taylor (Ref. 1)
and N. N. Bubnov,
V, V. Voyevodskiyk L. S. Polyak and Yu. D. Tsvetkov found
that under the
influence of x-radiation at liquid nitrogen temperature
hydrogen atoms,
detectable by the EPR method, are formed from adsorbed
water molecules
or OH groupi on the surfaces of glass and silica gel. The
properties of
the hydrogen atoms adsorbed on the surface of silica gel
were studied
in the present publication. Co6o was used as source of
radiation. The EPR
spectra were taken at liquid nitrogen temperature on a
spectrometer with
a high-frequency magnetic field, The spectra of the
irradiated silica
gel are represented graphically in a figure. The removal
of hydrogen atoms
from the silica gel surface in presence of ethylene was
investigated, and
Card 1/2

A Study on the Properties of Hydrogen Atoms
S/195/60/'001/004/005/015
Adsorbed on Silica Gel Surfaces by Applying B017/8055
Zlectron Paramagnetic Resonance
it was found that the desorption rate of hydrogen atoms in
presence of
ethylene exceeds the desorption rate in vacuum by a factor of
thirty.
Hydrogen atoms adsorbed at -100 to -1500C react with ethylene
and oxyge
There are I figure and 3 references: 2 Soviet and I British.
ASSOCIATION: Institut khimicheskoy fiziki AN SSSR (Institute
of Chemical
Physics of the AS USSR)
SUBMITTED: August 2, 1960
Card 2/2

KAZANSKIY, V.B.; STRUNIN, V.p.
Nature of the temperature maximum of the reaction
rate for the
hydrogenation of ethylene on metals. Kin. i kat. 1
no. 4;553-
.557 N-D 160. (MMA 13:12)
1. Institut khimichookoy fiziki AN SSSR.
(Stbyleae) (4drogenation)

20422
S/lo9/6o/oo5/ol2/o2o/o35
E192/E382
AUTHORS: Tkach, V.K., Stepin, L.D. and Kazanskiy, V.B.
TITLE: Resonator Method of Measxtrin,- the Permittivity and
Loss Tangent of Liquid Dielectrics
F
U
-RIODICAL: Radiotekhnika i elektronika, 1960, Vol. 5,
No. 12, pp. 2009 - 2014
TLXT-. The resonator method provides means of accurate
measurement of the permittivity and losses in dielectrics at
micromaves. However, the measured sample is usually in the
form of-a disc and the method cannot be easily employed for
measuring the permittivity and losses in liquids. It is
proposed, therefore, that the measured sample be cylindrical
and situated in the centre of the resonator parallel to its
axis. For the purpose of the derivation of the formulae for
the measurement, it is assumed that the resonator contains
Waves Of the type H Oln The solution of the ~Jaxwell equations
for thi., region occupied by the dielectric (0 < r b where
b is -the r-adius of the sample) is given by
Card 1/7

20422
s/iog/60/005/012/020/033
E192/E382
Resonator Method of Measuring the Permittivity and Loss Tangent
of l,iqtiid Dielectrics
H,A '.. - CJO (kr) itin
iO GJI (kr) cos Ps
E.j i'O Cj, (kr) sin
-W
where: 2
2 2
k -2
The fields in the regi
on occupied by the air (b < r a where
a is the internal radius of the resonator) are expressed by:
Card 2/7

20h 22
S/109/60/005/012/020/035
E192/E362
Resoniitor Nethod of Measuring the Permittivity and Loss Tangent
of JiquJ"Ld Dielectrics
where:
2
2 W 2
k = - - 0 (2).
0 2
c
In these expressions, W is the angular frequency,
c is the velocity of propagation,
P = 2W/% BA is the propagation constant,
XBA is the wnvelength in the resonator.
The unknown k can be determined from the boundary
coadition at r b and r a These conditions lead
to the following expression:
Cnr.d 3/7

2LI422
s/iog/60/005/012/020/035
E192/E382
Resonator Ne"thoe of Measuring the Permittivity and Loss Tangent
0 f. Liquid Dielectrics
J, (kon) Ye (kob)
kb Jo (kb) k0b jo itat) 7. -(k-..l 70;-(kT) (3)
JI (kb) J, (kob)- I (k0a) V, (k9b)
The quantity kb- can be evaluated from Eq. (3). A special
table is given for this purpose. The tangent of the loss
aligle tg 6 is approximately expressed by:
t 0
(7)
WP,( 0
Card 4/7

S1 J 0 9/60/005/012/020/035
Elg%/E362
Re.,3unator Method of Measuring the Permittivity and Loss
Tangent of Liquid Dielectrics
where W is the energy stored in the region b < r
WA is the energy stored in the region 0 -\ r b
Q i,9 the quality factor of the resonator with the sample,,
Qo is the quality factor of tile resonator without. the
sample.
The final theoretical expression for tile loss tangent is
in
tile fox-III:
tg6~ kv as J02 (kb) F1 (joil)
k;ze- IT -70i~ T, -(k6)- Q
The method proposed above was investigated
experimentally.'!
The resonator used in the experiments was made of brass and
had an internal diameter 2a 5.908 cm and a length of
Card 517

20LN
s/io9/6o/oo5/oi2/020/035
E192/E382
Resonator Method of Measuring the Permittivity and Loss
Tangent of Liquid Dielectrics
14.9 cm. The resonator operated in the it Oil *mode and its
quality factor was 3790; the position of the plunger in the
resonator could be varied by means of a micrometer screw and
could be determined u-ith an error of + 0.002 mm. The resonant
frequency of the system could be accuiPately measured by means
of a cavity wavemeter. The permittivity and the loss
tangent of the sample were based on the determination of the
resonant wavelength and the magnitude of the quality factors
of the resonator itself and the resonator with the sample.
Sonic solid and liquid dielectri~s were investigated
(organic glass, obonite, ethyl alcohol, benzole acetone"and
distilled water). The measured values are indicated in a
table. Froin this it is seen that the results are in good
agreement with the data available from literature. The method
Card 6/7

2002
S/109/60/005/012/020/035
E192/E382
Rs~:;onator Method of Measuring the Permittivity and Loss Tangent
of Liquid Dielectrics
permits xhu measurement of' permittivity with an average square
error of not inore than 3% and that of the loss tangent with
an err~>r uf not more than 9%. There are 2 figures,2tables
and 9 referencest 8 Soviet and 1 non-Soviet.
suBmirm). January 16, 196o
Card 7/7

AUTHORSz
Kazanskiy, V. B., Veqherskaj&,,~ S/076J60/034/02/039/044

B010/BO07
TITLEi
Paramagnetic Electron Resonance in Irradiated
Aluminum Oxide
PERIODICAL:
Zhurnal fizioheskoy khimii, 1960, Vol
34, Nr 21 P 477 (USSR)

0
60
d1
ABSTRACTi
At -196
C gamma aluminum oxide was irradiate
gavnyna rays
with C0

in a vacuum and investigated according to the method of
paramagnetic

electron resonance. A complicated signal with a
g-factor of about

2 was observed ) which did not change also after
a prolonged
a
'
g
4pi

S
storage at -196
tor
.
age for some hours at room temperature led

to a change in the
signal, in which case the intensity of the left

line (gzr2)
decreased considerably, whereas the right line remained

unchanged
(Fig b). Here intensity decreased by about 10 times its

amount.
This decrease of the signal and observations made by TpLylor

and
Kohn (Ref 1) are explained by the fact that the signal is in

correlation with the centers of aluminum 3xide, which are
responsible

4'or increased catalytic activity.
.i.SSOCIATION:
t~kademiya nauk SSSR Inatitut khimicheskoy fiziki Moskva (Academy
of

Sciences of the USSR, Institute of Chemical Physics, MoscoWT -
Card 1/2

Paramagnetic Electron Resonance in Irradiated
S/076/60/034/02/039/044
Aluminum Oltide BOIO/BO07 ~V
SUBMITTED. July 31, 1959
Card 2/2
Uo
5-.1190
AUTHORS:
TITLE:
PERIODICAL:
OIT 110)
jtog 1114 12A7
Mishchenko, Yu. A., Boreskov, G. K., Kazanskiy, V. B.
Pariyakiy, G. B.
Effect of ionizing radiation on the catalytic and magnetic
properties of titanium dioxide
Kinetika i kataliz, v. 2, no. 21 1961, 296
21769
S/195/61/002/002/004/304
B101/B208
TEXT: Several papers published in the course of the last years
studied the
possibility of changing the catalytic properties of solids under
the influ-
ence of high-energy radiation. Kohn and Taylor (Refs. 1, 2)
observed a
considerable effect of gamma and neutron radiations on the
catalytic proper-
ties of A120 3 and of catalysts on S102 basis (Ref. 3) in the
isotopic H - D
exchange. It was the purpose of the present study to investigate
the effect
of gamma radiation on catalytic and magnetic properties of TiO 2'
The cataly-
tic properties were studied by H - D exchangel the magnetic
properties by
electron paramagnetic resonance. The TiO 2 samples consisted of
anatase with
specific surface of the order 130 m 2Ig. T102 was heated to 5000C
for several
Card 1/3

21769
s/195/6i/002/002/004/004
Effect of B101/B208
hours at 10`5 mm Rg prior to irradiation. The samples thus
treated exhibited
no marked cettalytic properties at OOC. They were now
irradiated with gamma
rays of Co6o in vacuo at the temperature of liquid nitrogen
with 120 r/sec,.
The integral, dose was about 1-7.1o7 r. The irradiated
samples showed high
catalytic activity at the temperature of liquid nitrogen.
The catalytic
activity was increased by at least 3-4 orders of magnitude.
Heating of the
irradiated samples to OOC considerably decreased the
catalytic activity.
The constant of the reaction rate at OOC I hr after thawing
was by about two
orders of magnitudes smaller,than at the temperature of
liquid nitrogen.
The T102 samples heated in vacuo at 5000C showed no signal
when the epr
spectrum was taken. At the temperature of liquid nitrogen,
the samples
irradiated gave a signal with well-resolved hyperfine
structure, total width
400 oersteds, g factor approximately 2. The signal does not
change if the
sample is stared at the temperature of liquid nitrogen.
Short heating to
room temperature reduced intensity and changed the shape of
the signal.
When the samples were kept for 1 hr at room temperature the
signal became
stable. This parallelism in the changes of catalytic
activity and epr signal
was also cbservable in silica gel (Refs. 3-5) and A1203
(Refs. 2, 6),. It
Card 2/3
i J,

1,=M-nay, V. B. ) PARlYSFM) GO B4j VOMODSM, VlUdiGlaV
V-
"Radiation induced surface reactions in silicagel."
repoit 'to be submitted for the Faraday Society,
General Discussion
on Radiation Effects in Inorganic Solids,
Gif-sur-Yvette (Seine-et-olse),
France, 11-12 Apr 1961.
Inst. or Chemical Physics, Acad. Sci. USSRp Moscow.

MISHCHENIO, Yu. A.; BORLISKOV, 'PARIYSKIY, G.B.
Effect of Ionizing radiation on the cataly-tic and magnetic properties
of titanium dioxide. Kin. i kat. 2 no.2:296 Mr-Ap 161.
(MIRA 14:6)
Is Fiziko-khimleheskiy institut imeni, L. Ya. Karpova.
(Titanium.oxide) (Gamma rays
A

S/195/61/002/003/008/009
E071/E412
AUTHORS. Kazanakiy, Y.B., Pecherskaya, Yu.I.,
TITLE: An investigation of aluminachrome satalysts by the
method of electron paramagnetic resonanze
PERIODICAL: Kinetika i kataliz, v,2, no,3, 1961, 454 46i
TEXT. Sin-re the formation of chromium of an intermediate
valen-,y
in chromium catalysts may be useful in explaining the nature of
their catalytic activity, the authors investigated the
pro--ess of
decomposition of chromic anhydride on alumina by the ~~blflFz)
(EPR)
method. Specimens of catalysts were prepared by shaking
y alumina (apecific surface area about 180 m2/g) with aqueous
solutions of chromic acid of various concentrations. After
filtering, the alumina was ignited in a stream of air at 350
e' C or
at 500% fo.r 8 hours. The reduction of the catalyst was done
in a
stream of dry hydrogen at 360 or 500*C for 5 hours, After which
it was cooled to 30 to 50*C in nitrogen. The content of
chromium
in the specimens (which varied from 0.2 to 11.4%) was done by
chemical analysis. The EPR spectra were taken with an EPR-2
spectrometer operating at 9400 millimegacycles (X - 3,2 :m)
with a
variation of the magnetic field from 0 to 8000 oerated.
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S/l95/61/oO2/0O3/oo8/ooq
An investigmtion of aluminachrome E071/E412
Occasionally an instrument with X 21.8 cm and Hp n 500 oersted
was used. The intensity of the signals observed wass dtlsi-mined
by comparison with the spectrum of a monocrystal Of CuC12'21120.
The EPR spectra of the specimens,containing up to 9,,21'0 ~f Cr
anzi
ignited in air at 350, contained only one resonance lint
44 oersted wide with g-factor = 1,97, At a highe:
content this line is observed on a background of a wide
rei!onan~e
absorption line, After reduction in hydrogen at 350-C thf~
intensity of the wide line (characterizing micro:rybtal-s of
reduced Cr203) increases and the intensIty of thi narrow lina
decrea3ea but it is still present at a rliromium content Df
from 0.4 to 2.5%. On redu--tion at 500'C.. the narrow line
disappears from the spectra of' all spe--imens,. If a a:
redu--ed
catalyst is heated in air at 3001'C~ the narrow line
The influence of oxygen on the narrow EPR line was ae-e--m,-nad
a*.
room temperature and at - 196%~ At room tempr.-a:u--.- wl-'r
increasing oxygen pressure, the amplitude cf the sign--
and its width increases.' whereupon the -hang,-- -,5~ Oil
prolonged retention of the spe--imens in aii, rt n i r 7 c- * &
-- -a - b-', t
decrease in the intens1ty of- the narrow 1,.n~ w b -A,~ r ,~
drh 1
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S/195/61/002/003/Oo8/oog
An investigation of aluminachrome ... E071/E412
is apparently due to the oxidation of all chromium to the six-
valent state. At -1960C, a decrease in the intensity of the
narrow line without an increase in its width was observed. The
influence of temperature was studied'within a range of -196 to
300%. The width of the line is independent of temperature but
its intensity obeys the Curie-Weiss law with the value of the
'Weiss constant 4 = 25*K. The results obtained indicated that
the phase giving the narrow line in the-EPR spectra of
aluminochrome
catalysts is bound to the surface of the carrier and that its
thickness does not exceed a few atomic layers. A comparison of
the SPR spectra at various frequencies indicated that the width
of
the line and its g-factor remain constant, thus chromium ions,
responsible for the narrow line do not possess a fine structure,
i.e. the line corresponds to Cr~+ ions. The above conclusion is
in line with other results obtained in this work, e.g. the
disappearance of the line for catalysts reduced at 5000C can be
explained by the reduction of all chromium to the trivalent
state.
The narrow line was never observed by the authors in the EPR
spectra
of various chromium oxides without carriers. For chromium
Card 3/5

S/195/61/002/003/008/009
An investigation of aluminachrome ... 9071/9412
catalysts in which aluminosilicates or silicagel were used as
carriers, the narrow EPR line is asymmetrical. The above
indicates the strong influence of the carrier. In general
compounds of pentavalent chromium are unstable and the existence
of Cr5+ ions in chromium oxide catalysts on carriers is
apparently related to the stabilizing effect of the crystal
lattice of the base. Acknowledgments are expressed to
N.Ya.Buben for measurements. A.Y.Topchiyev, V.A.Krentsell,
R.Michail, P.Corlateanu and A.Ionesco are mentioned for their
contributions in this field. There are 6 figures, 1 table and
17 references: 10 Soviet-bloc, 1 Russian translation from
non-Soviet
authors and 6 non-Soviet-bloc. The four references to English
language publications read as follows:
Ref.4: R.Michail, P.Corlateanu, A.Ionesco, J,Chim.Phys., v.56,
568, 1959; Ref-5: J.Matzunaga, Bull. Chem. Soc. Japan, v,31,
745, 1958; Ref.11: D.E.O'Reilly, D.S.MacIver, Symposium on
technique on study of catalysis mechanism, Boston, April 5-10,
1959;
Ref.16: P.W.Anderson, P.R,Welss, Rev. Mod. Phys., v.25, 269,
1953.
Card 4/5

KAZAWKIY~V.B.; PARIYSKIY, G.B.
Electronic paramagnetic resonance spectn= of ethyl radict-.2z
adsorbod on a silica gel surface. Kin.i kat. 2 no.-':50'7-508
Jl-
Ag 161. (1,LlhA 14:10)
1. Institut khimicheskoy fiziki AN SSSH.
(Radicals (Chomistry)-Spectra)

KAZANSKIY. V.B.: Yh'ZJ1KOVA, Z.I.; LYUBARSKIY, A.G.;
VOY-EVODSK1Y, V.V.;
!OFFEJ, I.I.
Electron paramagnetic resonance study of the structure of
vanadium-molybdenum oxide catalysts. Kin.i kat. 2
no.6;862-866
N-D 161. (MIRA 14:12)
1. Institut khimicheskoy fiziki AN SSSR i Inatitut
organicheakikh
poluproduktov i krasiteley imeni, K.Ye. Voroshilova.
(Catalysts--Spectra)

RODE, T.V.; KAZANSKIYw V.B.; PECHERSKAYA, Yu.I. (Moscow)
Electron magnetic resonance study, of chromium oxidea.
Zhur.fiz.-
khim. 35 no.10:2370-2375 0 '61. (MIRA 14:11)
1. Akademiya nauk SSR, Institut obshchey i
neorganicbeskoy khimii
imeni N.S*Kurnakova.
(Chromium oxide--Spectra)

PECHERSKAYA, Yu.I.: KAZANSKIY, V.B VOYEVOD.-AI!Y, V.V.
Electron paramagnetic resonance studies of the thermal
activation
of chromium gel. KinA kat. 3 no-1:111-113 '62. (MIRA
15-3)
1. Institut khimicheqkoy fitiki AN SSSR.
(Chromium) (Catalysis)

S/051/62/013/001/005/019
E039/E42o
AUTHORS: Kazanakiy,_.Y,,-B,.,,,.Pariyakiy, G.B., Burshteyn, A.I.
TITLE: Study of the properties or hydrogen atoms formed
during y-irradiation of silica gel, using the electron
paramagnetic resonance method
PERIODICAL: Optika i spektroskopiya, v.13, no.1, 1962, 83-89
TEXT: - Measurements are made of the spin-lattice relaxation
time Tj of atoms of hydrogen, formed by y-irradiation of silica
gel, from its surface hydroxyl groups or molecules of adsorbed
water o-. --'*zs jurface. Th.e silica gel was prepared by th.,~
action
of sulphuric acid on a solution of sodium silicate. Acid was
added until pH = 0; the precipitate was then separated, washed
and dried for 4 hours at'500*C. This produced a gel with a
surface of 300 + 25 m2/g. Before exposure, the gel was heated
for 10 hours at 400 to 5000C at a pressure of 1o-5 mm Hg in a
glass ampule and then sealed o f under vacuum.. Irradiat:Lon*was
perform9d at -1960C using a Co9O source (dose -10 Megarad).
Electron paramagnetic resonance measurements were then made at
-196*C and compared with results obtained'for the case where part
Card 1/2

Study of the properties....
S/051/62/013/001/005/019
E039/E420
of the hydrogen of the surface hydroxyl groups was replac'ed
with
deuterium and the effect of radiation defects observed. The
dependence of the ratio of the amplitude of the signal for
hydrogen atoms; to the amplitude of the signal for diphenyl-
picryl-hydrazyl with microwave power was also investigated.
It is shown that the curve for-hydrogen-in a vacuum falls well
below the curve for the case of hydrogen in the presence of
adsorbed oxygen. The spin latti e relaxation time Tj for
hydrogen in a vacuum is about 10-~ see. Atoms of hydrogen are
stabilized on the surface of the gel in spaces in the crystal
lattice which are of sufficient size.. There are 5 figures.
SUBMITTED: June 2, 1961
Card 2/2

KAUNSKU,- V.B.; FAMSKIY, G.B.; 13URSHTEYN, A.I.
VaIM, the electron paramagnetic reaons e method in
studying the
Im-opertiev of bydrogen atoms formed by )r-irradiation
of silica
gel. Opt.i spektr. 13 no.lt83-89 Jl 162. (MIRA 15:7)
(Paramagnetic resonance and relaxation) (Silica)
(Hydrogen)

8/844/62/000/000/113/129
D207/D307
AUTHOIW: KrUMT113kiy, V. B., Pariakiy, G. B. and Voyevodskiy,
V. V.
TITLE: An EPR study of the properties of hydrogen atoms and of
defects formed on the irradiation of silica gel
$OURCE: Trudy 11 Ysesoyamogo.soveshchaniya po radiatsionnoy
khi-
mii. '--d. by 1j. 6. Polak. Moscow, Izd-vo AN 63*.~R'9 1962,
656-659
TEXT: Silica gel was investigated because of its special
adoorp-
tion and catalytic properties. The gel had a s,iecific
surface area
of 200 M2/g and contained leas than 0.1 't Fe and Al
impurities. It
was irradiated with Go b0 d" rays, in vabuum, at -196 0C and
at room
temperature, urith doses of 5 - 10 negarads. After
irradiation at
-1960C the Bi'R spectrum (recorded at the same temperature)
indi-
cated the preuence of radiation dofucts and free hydrogen
aton.0,
the latter being for.:ied by radiolysis of the-surface OH
roups;
the H-atom concentration increased with the temperature ?200 -
5000C) to which the gel %--,as heated before irradiation. On
vacuum
Card 1/~
ARM

KAZANSKIY, V.D.: STFPIN, L.D.
Concerning the methodology for calculating the
dielectric constants
of substances measured by a method involving the use of
a cylindri-
cal Holn resonator with axial arrangement of the
samples. Radiotekh.
i elektron. 7 no-1-173-375 Ja 162. (K.Rh 15-.1)
1. Khar'kovskiy gosudarstvennyy universitet im.
A.M.Gor'kogo,
kafedra radiospektroskopii.
(Dielectrics)

KALAISM PARITSKIY, G.R.
"ESR stuftes of the reactivity and structure of
free radicals stablized
on solid FairNces.."
Report submitted to the Sixth Intl. Symp. on Free
Radic913,
Cambridge, England 2-5 July 1963

L 19b21-65 Pc-h/.
k -
-v /z,7'
SOUR.CiP: 'Ref. 2~i. Klumlya, Abs. 9B570
Cord 1/2

L 19h2l-65
ACCESSION NIR: AR4048175
to the H atoms. A ddi tion Of 02 and C2H41 increased the rate of
recombinand on of T-T
Thus. at -151". e T-atp of T-ecom7l-n-afl-on In the presence of
C,)H~ vvil--,
0: 7
ril q,iriltiny t
irt- -rnpo-n-
SUB CODE: GC, :3P
Card 2"
ENCL: 00

KAZANSKIY, V.D.- PECHnMKAYAP YU.I.
1, 0
Changes in electron paramagmetic resonance spectra of
chromiar-alumino silicate catalysts for ethylene
polymeriSktion
induced by reaction components. Kin.i kat. 4 no.2:244-251
Mr-Ap 163.
(~au 16*5)
lo Institut khimich3skoy fiziki AN SSSR.
(Chromium
catalyats---Spectra)(Polymerization)(Aluminosilicates)

PARIYSKIYp 0,B.1 ZHIDOWROV, G.M.; KAZANSKIY, V.B.
-'-
Spectrum of electron paramagnetic resonance of a methyl
radical
adsorbed on the silica gal surface. Zhur.strukt.khim. 4
no.31
364-367 Yy-Js 163. (MIRA 16%6)
1, Iristitut khimicheskoy fitiki AN SSSR.
(Methyl group-Speotra)

h5354
5/181/63/005/002/043/051
t1 B102/B186
AUTHORSt Ir a Pariyakiy, G. B. , Aleksandrov, I. V., and
_~.Ltzaiq ki
Zhidomirov. G. M.
TITLE% Investigation of the interaction of free radicals with the
:9urface of a solid (silica gel) by the ep.rspectra
PERIODICALs
*Fizika tverdogo telaq v. 59 not 2, 1963, 649 - 659
TEXTt The authors give a detailed analysis of the o.p.r. spectra,of
atomic
hydrogen, methyl, ethyl and polymer radicals adsorbed on several
types of
silica gele (specific surfaces 290, 300, and 700 m2/g). The studies
were
made in order to obtain information on the nature and the geometry
of
binding and the motions in the deorbed state. The e.p.r. spectra
were
taken at A - 3.2 cm and a hf modulation frequeficy of 1 Mo. The
e~pu spec-
trum of adsorbed hydrogen is characterized by a hyperfine a litting
constmt
of A - 1411+0-1 Me (for free hydrogen it is Ao . 1420-40 Mc5 and a
great
asymmetry of the components. On the basis of the present authors'
earlier
re8ults (Kin-atika i kataliz 1, no. 4, 539, 1960) the hyperfine
splitting
Card 1/3

8/181/63/005/002/043/051
Investigation oJ.' the ... B102/Ble6
constants A anti A for E and H411E) are calculateds
A A.. A A -. ~7
spy '0 (4a)
A
so a3 (4b)
Nt!- 15.5Xj A. (I - 15.5XI;
3 a3 (4c~
a2E/e. The anisotropy of hyperfine splitting is obtained as
A A, 47 pA, 141 AoX'.
- = g -j-=_
1 .160 (5)1 z1JE and perpendicular to the sugface. The
i,anisotropy of the g-factor,6g 91, -Ig-L , is very weak (, 10- ) and
not
to be observed in experiment. ;he p0 arization energy of the hydrogen
atom in the E field was obtained as PA kcal/mole. The apr. spectrum of
deuterium atoma adsorbed on SiO 2is consiaerably narrower and is
symmetri.-
cal, with smaller amplitudes of the side coWponents. The e.p...e~
spectrum
of the methyl :radicals was measured at -196 C1 it consists of tour
hyper-:
fine structural lines with a distance of 23.1+0.1 oe and with an
amplitude,
ratio of 1 1 8.5 1 13 1 2.r,. instead of 1 1371 3 1 1. This can be ex-
Card ?/3

K-AZANSKIY, V.B.; STEPIN, L.B.; TKACHY V,.K*
Use cf a new variant of the resonntcr metL(A for mepsuring
die::.catric constants for the study rf h4uh molecular woight
ccmpowids. Biofizika 8 no.1g112-116 163. (MIRA 17:8)
1. Kh&r1kovskiy gosudarstvennyy universitet imerti (,or1koeo.
U562
S/020/63/148/001/021/032
B144/B186
AUTHORS: N'ladimirova, V. I., Zhabrovaj G. M., Kadenatsi, B.
M-j
J,azanskiy, V. B., Pariyakiy, G. B.
TITLE- Joint action of radiation and oxi 'de catalysts on the
dehydrogenation of oyclohexane
a
1963, i01-1W
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 148, no. 11
TEXT: The radiation effect on catalytic systems is studied in
the
dehydrogenation of cyclohexane activated by S102 , A 12039
MgO, ZrO 2' ZnO,
or NiO. After a vacuum pretreatment of the catalyst at 400 0C,
c lo-
hexane vapors were led over it. The determinations concerned:
1fthe
catalytic properties after irradiation with 0.6 Mev electrons
at room
6 9 '2) the
temperature, dose 2.4-10 rad/sec, energy absorption 1 - 10 rad;
paramagn~etio properties after gamma irradiation with Co90* at
- 1960c,
dose 3200 mou, energy absorption 5-10 6 _ 1-108 rad. 1) A
low-temperature
dehydrogenation of cyclohexanone took place. Good results were
obtained
Card 1/3

M kw, ~ ~
q
~-~j
"C ~~M
F R.-N
_R
9/020/63/148/001/021/032
joint action of radiation and B144/B186
their different electron properties. In dielectrics and poor oeml-
he radiation-induced ionization is stronger, since the
conductors t
d holes formed are longer trapped and the paramagnetic
electrons an
centers are resistant at low temperatures, while they vanish so
rapidly in ZnO and NiO that.no e.p.r. signals could be recorded, There
are 2 figures and I table.
ASSOCIATION: Institut khimicheskoy fiziki-Akademii nauk SSSR
(Institute.,
of Chemical Physics of the Academy of Sciences USSR)
PRESENTED: jd~lj 30, 1962, by V. N. Kondrat.lyev,. Academician
.SUBMITTED; July 19, 1962
Card 3/3
19-4ACTOUR" -th*n the Amplitudo or.the
v Xou Gates
narrow" or initthl a Aei- aft-,or--20-mm-tbS-ilipftl-otmot-be
observed.---'.
A
Inflwncos of tbe czygen on the elgrAl are invertible.,The paper was
presented-by
IAcademician V. N.~Kondratlyev on 3 April 1963.
Itable. Orig. arl~. has,t_ 2 fi,-,zes and
Card
7
77
e"'771
'g
~j ~,Mf
41 p

%P-41MKII) V. B.; PAjtiySKjy
I-- -- ) G. B.
"The e.s-r. study of free radicals adsorbed on
catalysts."
rePOrt submitteil to 3rd Intl COng On Catalysis)
Amsterdam) 20-25 Jul 64.
Inst of Chemical. physics, AS USSR, Moscow.

_t~06 - YL
r
-49 _WVt) '/r_PF(C)/VJP(J) ~' Pc-4/Pr_Is/Pa-4 DTAAP MM
1 , 11 1 1?14014768F, _k/0?0~/64/0~)411005/07il/0767
A !T&'- 1!~R iZhabrova, G. N., Xazant2kiy, V.B. jVIadImIr2yg_,_7,I.
Kadenat-.11,1; ili Par! v90 V,
T_,L: Radiaticn catalysir, in the conversion Uf 5Yc_Iohe7tnc`\
SOURCE: Nefrekhimiya, v. 4, no. 5, 1964, 753-762
TOPIC TAGS: cyclohe-.xane, radiation catalysis, dehydrogenation,
catalytic dehydro-
Sena-tion
ABSTRACT Tha joint effect of ionizing radiation (Y - rays from Cn601
and of
I '; I nq 1A' a t o T FOn' A I
ca t -.-i I y4--th different -:~Icctrical propertics, 9iicha I -;
ali-nninum. silicnt,:!), s emico-ndue toys having low conductivity
fto,
conductors havin:,, high conductivity (ZnO, MO) and somne-netair (7%
Pt on
was invcscigated wiLh respect to dehydrogenation anti othior
re,i,_tionz; Z~f cyci,
bexane in the nd3c,rbed layer at terperatures from 20 to -196C, For
ccrin-pa zts-n,
L.-te catalytic activity of non-irradiated samples was also stud',ed.
Cyclobexane
aimi benzene were used as adsorbent3, and EPR spectra were recoided.
The sample
wirl~ the adsorbed cycrohexane was irradiated at tho teLVerature of
liquid nitro-
ga~7k the dose varying from I x 10? to 1 % 108 raA. 'Me selectivity
of thc~
inva4tigated aolld compounds in the radiation-excited catalytic
pr,,)cess was es-
Coed

L 15296-65'
ACC_SSILCI~ NI: A114047688 .5,
h t h _erma
IiDd a ~j k a-redt-c I catalytic process and hcrinogenecus
_3,Jiolysis. -if highest radiation- induced catalytic activity was
lc-unu 2v",
~,xldes cf ti-P insulator type, which are hardly effective at
filil in --'e
I-Sull caalyLic proci,,-~s even at high Lemperaturez- 'In Ote;u,
aDpeararce of poramagnetic centers and adsorbed C H7 radicals was
e9tablishea.
-:he semicondtjct,~rs and -metals (IiiO, Znd,-- Ni)__~7hicp ayi~
active
catalytic procesis had a low radiation-induced catalytic activity,
N,~ appearAnce
02. paramagnetic centers and adsorbed radicals was found. The
relationship
and t e -0 erage 'a." .- 5.0
.~-betweniM the- rAdiafton-chem1cai-;-yiia16 af lqdxog", h c v th-
' 2
surface wit1h Usorbed cyclohexane was establisbed and it was found
that tiie
,nitial -arts of surface adsorption were the most
radiation-active. It was alSo
L-stablished that there is a strong relationship between the
electricoi propei-t~_ef,
,f and thLir abillity to transmit the energy of iontzing radiat
ion. Th~q is
Ui Ceh,d 0 e~natlon a-d
oih~r leaf L luau i y,
711e icrLaLtOn Of Positive C6H6 ons during radiolysis of
oLn_-en,_, au-
_3%ows tiie possible donor adsorption ef cyclic fly'! lmczi. cv,wS
C,
G i :i I-. U21COCC5 ~ L:il!j 15 additionai evidence for the
zarchanism of
C a t ii'i 6 . "7rt authors thank R, Kh. Burshte)rD for providing
the sample ti- _N1
caLaIYSI~, and A. N. PonomareVa and G. L. Karpova for carrying out
the masn-
,_c~r

rqNf" ~"f
- - - --- ------- ----- ---
L 15296-65
A1,4041688
,q IjR -
ACCESS-10-
2 tables -
spectrometric awilysIs.ff Orig. art. Ias: 5 figures and
SSSR (Institute Of Chemical
ASSOCIATION" khInicheskoy fiziul M
physics, SSSR) SUB CODE:
IMCL: 00
121;0-v63
SU&jITTED
OTHEEt. 008
NO RE-F SOV-. 007
Card 3/3

L 15P96-65
ACCESSION NR; AP4047688
spectrometric analysis." Orig. art. has: 5 f1gures and 2 tables.
ASSOCIATION: Institut khimicheskoy fiziki 91 SSSR (In,;titute of
Chemical
Physics, AN SSSR)
SUBMITTED: 12Nov63 ENCL: 00 SUB CODE; OC
NO REF SOV: 007 OMER: 008
Card 3/3

BORESKOV, G.K.; BUKANAYEVA, F.M.; D17131RO, V.A.; V.B.;
FECH~RSXAYA,
YlI.T.
Electron paramagnetic spectra of depos3ted chromium
oxide catalysts
used for ethylene polymerization,and the nature of their
activity.
Kin. i kat. 5 no.3:434-440 Itr-Jo 164. (MIRA 17%11)
1. Institut kataliza Sibirskogo otdelenlya AN SSSR i
Institut khimi-
cheskoy fiziki AN SSSR.

AUNIOR Borv-,sko,7 KazmBk-IY, V. B,, KIabCb(-'TIY-Cl Y u. A.
a Ca V7
StIM
:2;a.
SOURCE; AN GWR. Daklady4, v. 157, no. 2, 1964, 384-3d7
T
7OPTC TAGS: WmV-n, dauterim, allica gel, electron parp-mnopetir,
spectrophotmetry isotc~pe exchzinge, lrre,reruilcle
h')-im,gar ill, PY
ADSTRAOr: The pui,j~oso of thID vork vm tc ntudy th~a aatur'e )r F
irradiat-Be si-Uca gE~~ 1,y -TtIca2, act"s Pjad by
their r-, Ir 1-n I rii I ul ~,,)r k7 ki-Al.a

ACC9SSICN NP: AP40422og
Lh
equizolar cc-itent of e rli-xtuze at 7-fr- K arid 0-7
OMPO G i
r,"a wi! '--a f-
If yp A rv
-Z "I t JL.
ej 2 el ",.e
accampaal-I'd by d! isnclwjr~r) MR!
LZ ti
cent-e rt f ~U:i tY
fac!
I rT-- ~3 M:L-, -p I Z, C~ oj, acrec".il 0-1- c

L 6716-6 5
Accwmcm NR; AA-D422og
centers. Orig* arbe bas: 2 tables and 3 figures.
In tUt-e
Institut Mdmicheakoy Miki AXademii nauk SWR ( BU of
Cal Physical Aandewy of Sciences SSSR),Institut kataliza
R ~Df 7-77-
SUDUTM- 2%lar6:4 F.4 C L
gUB O=: UP, cc no fw say: Do6
Card
3/5
~yj

L 6716-65
ACMIC" NRI AA,042209
Nil
v
xtv
OpUza slifttm of SiUca gel before (1) WA aitar (b)'&Uawtiaz
of bydrogn st rNm ta*emture.
n.,A Vt; ,

L 6716-65
Ar,C&WICV WRI Pl*a2l?09

.50,)xpL
0
ENCILCISUM-P!
Fig. 2. MM oeotr% of irraUated slitca gal -'Oefore (a) wd
after (b) ~ ~Ay,.
A

A:
1-4 7 ,
A1--C'i:1:z~9M,N NR- AP;)07041 s/oi2oj'6-s/()Oo/ooi.,'012-3/0127
AUTHOR: ~i,-V. B.; Stepin, L._Dz; qgrin~~_L-.
L),Aflt ior z-~ ii;uriiimz thL, dieiIE-,c fric conHiant Aand diel,-( tric
-Ion
SOURCE: Pr6u-ory t toviuijk~i ek.Lpe rimenta, no. 1, j9f)~, 123-1?'7
TOPIC TAGS: dielectric constant, 'dielectric loss, 10 cm band. dielertr--
1%,BSTRACT: The instrumena is b-.ised on the 1-~,,,-resonator n-lethod of
,zneasuxernent. The tz k3t liquid in _i glans Lir quarztz tube in piziced
alcrL:
:1:cis. Vari.L.ion o-1 the natural frri3ucncv and 0-facior of f h e. r- T:
-vea a
iner-m-an :3LY -.9 a basi s f0 T e St I r1-- Rt. 1 t-. 2 iF
wale7: acplon-p- nitrn))Tonzann mt~rhvl
7
v a 7 i for 7
mat -ubiiahed b- Western YeBearchers. ~.Vrlg. ar-.
5 fi urea and I table.
0-
-:Card 112
mbe -a I
5
Z
AP

;.ACCF-SMON NR.- AP1007041
ASSOCIATION: Khar'llcovskly unlversitet (10mr'kov UrAve-raityl
suB.mi,r,rED-- mianif A- ENCL: 1A SUB (:7(."DE7 P,-
NO REF 50Y: 006 OTHER: 001

eT, y
It are-ice of aloe trn, psirpim-g.-i! -I e a rna
lur-'n; the
loq-T-emiew.ure ads--nrl,-jm of VArlirlus ph3tg ru
WI -EdL."Od t
Toorut. 181-''i86 ~IY-7~! 16"-,
%KRA aFc9)

PLPCIMRSKAYA, Yu.I.; KAZANSKIY, V.B.
Relation between the catalytic activity of chromium oxide
catalysts
and the valence state of chromium, Kin. i kat. 6
no.2:357-360 Mr-
Ap 165. (MIRA 180)
1. Institut khimicheskoy fiziki AN SSSR.

Atrj~SANDROV. 1.-Vj KAZANSKIT, V.B.; MIKHFYKIN, I.D.
E.---~i*on parnmiagnatic resonance studies of the structurn of q-tive
canV3;:,s of chromium o;Lida catalyst..s for athylena polymerization.
Kin.1 kat. 6 no,3'Z439-41,7 MY-Je 165.
(MTRA 18t10)
L 1wititut kbimiehaskoy fiziki AN SSSR.

PARI-YSE17, G.B.,~ Yu,*A.; KAZAN--
Na~ur~ of r;~!llutlov- ourfrice defo.-tr Ir. irradistt~~,J
s'lica ge2.
i'ar t, I ~ Me,-!han Lsm (, Inydrogen udgoryt r~n. I n. I
kat, .6-15-633
j -'( - -A e, If) 5 .
i Inni lt,,it khlrl horki v I A, I

PECHERSKAYA, Yu.I,j KAZANSKIY, V.B.
InhibitEon machanism of ethylene polymerization on
chromium oxide
catalysts. Dokl. AN SSSR 162 no.5slIOl-1104 Je t65.
(MRA 18:7)
1. Institut khimicheskoy fiziki AN SSSR. Submitted
December 3, 1964.

Sou~_
N)
ACC NRt Cp ODE: LqVO181/66/oo8/o1l/3418/342O;
AMWOR: Kazanskiy, V. B.; Korolyuk, A. P.
ORG: Institute of Radiophysics and Electronics, AN UkrSSR, Kharkoy
(Institut radio-;
fiziki i elcktroniki AN UkrSSR)
TITLE: Giant quantun, oscillations of the absorption coefficient
of ultrasound in
antimony
SOURCE: Fizika tverdogo tela, Y. 8, no. 11, 1W, 3418-3420
TOPIC TAGS: ultrasound absorption, antimony, quantum oscillation,
electron inter-
action, phonon interac-tion
ABSTRACT: In view of t he increased interest in the
characteristics and the Fermi
surface of semimetals,,*the authors measured the amplitudes and
periods of giant
quantum oscillations in antimony using 3~0-Mft ultrasound at 1.8K,
in magnetic fields
up to 110 k0e. The wignetic field man produced by discharging a
capacitor bank
through a liquid-hydragen cooled solenoid. The duration of the
magnetic field pulse
from maximum'to 50 kOei was 0.25 see. The oscillations were
recorded with an oscillo-I
scope. The sample was cut from a single crystal in the form of a
disc 7 mm, in dia- !,
meter and 2.5 m thick. The wave vector of the sound was
perpendicular to the sur-'
face of the sample and parallel to the binary axis. The
experimental values of the
periods of the giant quantum oscillatioxis were found to be in
agreement with a theo-
retical formula derived by one of the authors earlier (Kort-1-yuk,
ZhETF v. 51, 697,
1966). The measured amplitudes are used to calculate the energy of
the electron-
ACC NRt AP6037030
phonon interaction, which is found to decrease from 7.2 to 6.0 ev
at 0 and 30'
respectively) and then increase to 6,3 ev at 36% The anisotropy of
the electron-
phonon interaction energy is found to be small in the plane of the
binary axis. The
absolute value.of the energy of the electron-phonon interactioli
in antimony is thus
found to be close to Its value in good metalsi in spite of the icw
carrier density.
orig. art. hast 2 f:Llpmes) 2 formulasl and 1 table.
SUB CODE: 20/ SUB11 DATE: 02JUn66/
P2
MM W
011IG REF'- 003/ OTH PXF.' 003

YEZIIKOVA, Z.T.; JOFFE, 7.T
.1 -.; KAZANSKIY, V.B.; KRYLOVA, A.V.; LYUBARSKIY,
A.G.; KRGOLIS,
Aa~~*ivity, etracture and the ejer*ric properties ol'
mixed
vanadium catal7ets. Kin. i kat. 5 no,5t861-867 S-0,
164.
(KMA 17: 12)
1. Nauctinc-issledovatellskly institut organicheskikh
poluprovod-
nikol, kra9ft'..e'ley i Inst,!tut khimicheBkoy flziki
AN SWR.

L 1435;-66- 94T(m)/EFV.(c)/EPF(n)-2/T GOAM
ACCESSION NR: AP502:083 uR/oi95/65/0O6/oo4/o625/o633
541.183.'5"-11.+ 541.15 445
V. Be
;AUTHOR; Pariysk~y,* Mishchenko, Yu.'A.; Kazanskiy,
TITLE: Nature of surftce radiation defec,"-a in irradiated silica
gel. I. Mcabanism
of hydrogen adsorptio)
"k
SOURCE: Kinetilra i kataliz, ve 6) no. 41 1965, 625-633
TOPIC TAGS: radiation defect, silica gel, aluminum impurity,
radiation damage,
hydr-ogen adsorption, color center, acid center
ABSTRACT: The irradiation of silica gelmarkedly affects its
adsorptional and
catalytic properties., since, owing to its highly developed
surface; the proportion
of surface defects In this subutance is particularly, large. Thus,
irradiated
silica gel irreversibly adsorbs hydrogen. The adsorption is
accompanied by the
disappearance of the color centers that had formed as a result of
irradiation. Both;
effects are attributed by Kohn and Taylor (J. Phys. Chem. Y. 63.,
966,,'1959; v. 66, L
1017, 1962; J. of Catalysis Y. 2, 208, 1963; Nature v. 184, 63o,
1959) to the pre- ~
sence of alvminum Impurities in the specimens; they have not,
however, been successL
ful in establishing the nature of the attendant radiation defects
and the mechanisal
of hydrogen aAsorpticn. Therefore, to elucidate these questions,
the present ar-
Card
777-

L 14,35-66
,ACCESSION NR: , AP50200:103
ticle describes their Investigation by adsorptional, optical,
and radiospectro-
1 scopic methods. Three varieties of silica gel, each obtained
by a different methodl
and having a different content of impurities, were
investigated. The first) K-5 I
was obtained by bydro~~rsis of a SiCl4 solution and had a
surface area of TOOt5O I
m2/g. The two other s-pecimens were obtained by adding H2804 to
solutions of sodium;
silicate; the acid was added until a IN acid solution was
obtained, whereupon the
precipitate was carefV1.1y washed to remove the sulfate ion and
dried.for 4 hr at
5000C. The surface aril.,a of both specimens, which were tagged
silica gels I and TIj1
was 300�50 m2/g. The iii ecimens were irradiated with a COPu
7-radiation source
-5 x 10 r). Their absorption spectra in reflected light were
then:-
(doses: i66 to 2
measured with an SF-4 iiipectropbotometer and their EPR
spectra, with an EPR-2 radio-1
spectrometer. It was Xound that ionizing radiation leads to the
formation of free
electrons and vaca]ncie;1i. Part of these electrons may be
trapped by the protons of
the acid centers that had formed as a result of the presence of
aluminum impurity
thus leading to the fo%*mation of hydrogen. At, room
temperature the stabilization
of H atoms does not ocour~ and they may react with hydroxyl
groups) causing de-
hydration of the surface. Following depaAure of the R atom, on
the Al atom there
reniaLris an uncompensated n&gative charge which may be
neutralized when the vacanc7
on the adjacent 0 atom gets stabilized. Thue, the color centers
forming under the
Card 2/3,

L 1435-66
!ACCESSION NR: AP50209813
action of irradiation exid due to the presence of Al impurity in
the 'specimens re-
f present positively charged vacancies stabilized on the oxygen
Atons adjacent to
the atoms of Al impurit3~. These defects are centers of
irreversible adsorption of
hydrogen. "The authors wish to express their sincere gratitude to
G. K. Boresk0FVd,1,-.-,15-
for his interest in thic project and discussion of the findings."-
=rg.-I~x- hhW:
T figures, I table. U61
J ASSOCIATION; 47 Institut thimicheskoy fiziki AN SSGR (Institute
of Chemical Physics,
~~ AA-14 . I
suBmirm: lTFe-b64 ENCL: 00 BUD CODE: S S, lip
HO REF SOV: o06 OTM: 01.4 ATD PRESS:
rd
ca.
I
1k

L 1327-�
EIVT(r.)/E.PF(!O.,'!/'EPF(n)-.r2/Ev/P~(J)/I~LVA(h)A',VA(l)---GG/Rm
-- -
!ACCESSION NR: AP5024005 UR/0020/6 64/002/0361/0364
i 44"a
;AUTHOR: Vladimirova, V.-I.. Zhabrova, G. N.*. Kadenatsi, B. M.~
L(azansk!zt V. B.; I
,PariXskiy, Go
ITITLE-. Radiation-cata Ac conversion of methanol
iSOURCE: AN SSSR. Doklady, vo 164, noo '~,~'AV5 361-364
;TOPIC.TAGS: methanol, g4imm radiation, radiation chemistry,
electron pi
!resonance, free radical, silica gel, alumina, aluminum silicate,
semiconductorg
!heterogeneous catalysis
ABSTRACT: The authors Nid established earlier that during the
combined action of I
ionizing radiation and solids of different electronic properties,
the dielectric-
i
!type oxides SiO2, A1203, and aluminum silicate SiOVA1203, in
which paramagnetic
Icenters and adsorbed radi 18 were detected, displayed the
greatest activity in thf.
~conversion of cyclohexanti n the aftorbed layer, whereas
semiconductors and metalst-_
;which had no paramagnetici enters or radicals, were inactive. In
order to deter-
~mine the scope of these findings, a similar study was made on
tho radiation-cataly-~
:;tic decomposition of methanol in the Wdsorbed layer at 200C,
C060 gamma radiation
being used (dose rate. 4.3 X'10 16- Ov/g - see; ..'adsorbed
radiation doset 8.2 x 10 19 to
-Card

L 1327-66
[ACCESSION NR: APS024005
,7 x.1021 ev/9). it was fotind that as in the case of the
heterogeneous radiolysis of:
cyclohexane, S102, A1203, and S102-A1203 were the most
effective catalysts for
methanol; the radiation-chenical yield and rate of formation of
hydrogen, formal-
dehyde, and ethylene glycol on silica gel were ten times as
high as in the case of
homogeneous radiolysis. The electron spin resonance spectra of
the radicals formed~
~on Si02 and A1203 were recorded. oxides with semiconducting
proparties such as
i
jZnO showed a considerably lesser catalytic activity. The
results confirm the rela-:
~tlonship established earlier between the radiation-catalytic
activity of solids ands
itheir electronic properties. The high radiation-chemical
yields of hydrogang for-
:ualdehyde, and ethylene glycol during decomposition of
methanol on oilica gel, alu-1
1minum oxide, and aluminum silicate are apparently closely
related to the processes
lof transfer of the energy of ionizing radiation absorbed by
theive solids to the
;molecules hasorbed on the surface. Orig. art. has: 1 figure, 1
table. [14):
ASSOCIATION: Inatitut khimicheakoy fiaLki Akademii nauk SSSR
(Institute of Chemi- I
cal Physics, Academy of Sciences,SSM
SUBMITTED: 04Feb65
NO REF GOV:, 005
.Card 2/2--
ENCL.---400
MI IER: o04
SUB CODE:CCGC
ATD PRESS:

KAZANSKIY, V.D.
Improvement of the quality of automobile gasoline in
the petroleum
refinery of the Kuybyshev Economic Council. Neftianik 7
no.6:20-21 Je 162. (MIRA 15:8)
1. Zamestitell direktora Kuybyehavakago
nauahno-insledovatellskogo
instituta, po pererabotke nefti.
(Kuybyshev Province-Gasoline)

KAZANSKIY,V.1.
Some features of breaks In limestone-shale strata.
Trudy Inst.geol.
nauk no.162:109-119 155- (MLRA 8:11)
(Limestone) (Shale)

KAZANSKIY. V.I.
Distributi-on of upper Mesozoic granitoid intrasives and
contours
of ore-bearing areas in the Pacific ore belt.
Geol*rudemestorozh.
no,4:3-18 JI-Ag. 161, (MIRA 14tlO)
1. Vsesoyumiyy nauchno-iselodovatellaldy institut minerallnogo
syrlya, Moskva.
(Far East-Ore deposits)

KaEanskiy, V. I. "The separation of volatiles fron, the ri,,apatic
hezoth," In the cc;l-
lcction: Nauch. ra*l oty studentov gornu-Metallurg. in-tov jNoskvy.
"loscow, lcl,5,
1~6-141i, - BUUoj:: 12 items
SO: U-V-31,Y 29 Oct 53, (Letopis 'Zhurn.~l 111-lykii Statey, NO. 161
lllll~).
Z
5
M;-

KAZANSKIY, V.I.
Primary aourceB of gold In the Lesser Xhingan Mountains.
Geol.
rud.mestorozh. no.2slOe-113 Yx-Ap 062. (MIRA 15:4)
1. Veasoyuznyy nauchno-isoledovateltakiy institut,
minerallnogo
syrlya.
(Khingan Mountains-Gold ores)

KAZA KTY,,V.I..l 'UUHIN,, V.H.
Effect of enclosing rocks on the geology of dislocations
with a break
of contimity. Trudy IGEM no.41:134-140 161. (14M 14:8)
(Geology., Structural)

UUNSKIY, V.I.
Metamorphism of rocks in some fault zones of the Lesser
Khingan Mountains. Geol.rud.mestorozh. no.6:19-32 fl-D 162.
(MIRA 15:12)
1. Inatitu'al geologii rudnykh mestorozhdeniyo petrografii,
mineralogii. i geokhimii AN SSSR.
(Khingan Mountains-Metamorphism (Geology))

KAZANSXTY2 V.I.
Inner structure, of Archean faults in the centrftl
Aldan region.
Geol. rud. meatorozh. 7 no.2t63-79 Mr-Ap 165. (MIRA
18:7)
1. Instit~it goologil rudnykh mestorozhdoniy,
petrografii, mineralogii
i geokhimii AN SSSR, Moskva.

KAZANSKIY, V.I.
Recent, struit-ures of the earth crust; rejuvenation of
platformns
and mineraltzation. Priroda 54 no.9:51-58 S 165.
(MMA 18:6)
1. Inatitut geologii rudnykh mestorozhdeniy, petrografii,
mine-
ralogii i gookhlmii AN SSSR, Monkva.

GO-Ijeral -moeti.ng of tho DolwirLment of' Farth
Sciancess of the Academy
of SclienClos of the U.S.S.R. Geol. rud. mestorozh. 7
no.3:124-125
MY-Je 165. (IMIRA 18:7)

Kn~ann-y, 7. 1. - "lic, nr~--411-rj !"'Ip al,
Oscil-lat 'ruly Astral:h. in-Ln, Vol. L~, .1
SO U-3-,/w?, 12 March ',3, (I-etopin IZI,tL,-.qal

Kazans'11y, V. T.
(I (,Vol op-c lit,", Tr-dy Ast,rn%~i, ---s. '--i.
Vol. IX) 194"', P. ~'2-~3.
SO: 11 -m-ch ~,3, OeLoi,ls IZI-urnal Stnti%V

KAZAIM)KIT, V. T.
0
14
20120 KAZAIISKII2 V. 1. Leclieniye ostrykh peotomksov . V
ab i Voprosy rrudnoy
khirurgii T.P.!A,. s, 1949, S. 31-50.
so: Lvropis Zk~HWAL STATEY9 Irol. 271 Moskva, 1949.

V. i.
35547. Y%.hii,urEiya '-Inukholey Pisbchevoda. V SB: Vopr,. sy
-'~rudnoy Khirurgii..
T. 111. 194") c. 205-08.
Leto---sl Zhurnallnykh itatey, Vol. 48, 1,'oskv--, 1949

KAZANSIIY. V. I.
USSR (6-10)
Me dA Ft s t i num
Certain possibilities in surgery of co-ronary insufficiency;
medinstinal anesthesia.,
Xhirurgiia. no. 1, 1952.
Monthly List of Rassian Accasstins, Library of Congress.
April 1952. UNCLASSIFln.
T

VILOTYSKIT, A. L.: KAZANSKIT, V. I.
USSR (600)
Coronary Arteries - Diseases
Development of collateral cardiac circulation in coronary
disorders. Klin. med.,
30, no. 1, 1952.
Monthly List of Russian Accessions, Library of Congress,
May 1952. UNCLASSIFIF.D.

KAZANSKIT. V. I.
......... WOMM-w-w~?, --
(Cancer; diagnosis and treatment: a popular
scientific sketch]
Rak; profilaktika, diagnoettka i lechenis.
Nauchno-populiarrqi
ocherk. Moskva, Medgis, 1953. 63 P. (MLFA B.-12)
(CANCIM)

PITROV, B.A., professor, predsedatelf; DUBXYKOVSaYA, E.G.'
sekretert; BGAN-
TSEV, N.I., kandidat Teditsinakikh nauk; TFMOVSKIY, S.D.,
profestor;
MILIK-ARUTYUNOV, A.I. kandidat meditainakikh nauk;
PATSIORA, M.D., kan-
didat meditsinskikh nauk; YZLANSKIY, N.N.. professor;
DAMIYE, N.G.; TA-
VONIUS, K.N.; GULYAYEV, A.V., professor; KAZANSKIY, V.I.,
professor;
15ROZDOV, D.Ye., professor; DOROnYEV, V.I.,, H.I..
dotsent.
Minutes of the session of the Surgical Society of Moscow
and Moscow Pro-
vince of September 12, 1952. Khirurgiia no-3:88-92 Hr 153.
(MLRA 6:6)
1. Khirurgichealroyei obnhchestvo Moskvy i Moskovskoy
oblasti.
(Spleen--Surgery)

VISHN-EVSKIY, A.A.' professor, i3redsedatell; CHISTOVA,
M.A., sekretar'; FICS111-
SHEYA. A.A.; KRICIECVSKIY, A.A** kandidut meditsinskikh
nauk; UTESEXT.
S.S., kandidat meditsinskikh nauk; BEGELIMa, A.A.,
kandidat meditsin-
skikh nauk; Y16ANSICIT. N.N.; ZATSEPIN, T.S. professor;
PWTKIN. F.M.,
professor; PjkTSIOILL, M.D.; KAUNSKIT, V.I., -professor-,
TROYAN, I.V.;
F=ROV, I.P.; FIL*rppov, A.V,; UTSSHW, 5-.3.; DOROFZYNV,
V.I.
Minutes of the session of the Surgical Society of Moscow
and Moscow Pro-
vince of September 26. 1952. Khirurgiia no.3:92-95 Mr
153. (MM 6:6)
1. Khirurgichekoye ribahohestvo Moskvy i Moskovskoy
oblasti. 2. Fakulltet-
skaY& 1~hirurgicheskaya klinika
saniturno-gigiyenichenkogo fakuloteta I
Moskovskogo ordena 1enina meditainakogo instituta (for
Krichevski.V).
(Heart--Surgery) (Arteries-Diseases)

PETROV. B.A., professor, predeadatell; DORM~,Y, V.I.,
sekretar" MLYNCH11,
V.A.; KAZANSKI.Y....Y.1., professor; HANiJUV, A.N.s
profesco;; LEVIT, Y.S.,
prof es87r'1:_"__P_ZTROVSK1Y, B.V., professor; PWHiTNIKOVA,
E.*.; SOLOVITEV,
A.Te., professor; MAKHOV, N.I., dot6net; YEWSKIY, N.N.
professor;
PWTKIN, F.M.. professor; VISHNEVSKIY, A.A., professor;
VETCHINKIN, Yu.M.;
GUREVIC11, N:I., professor; OSIPOV. B.K.. professor;
TIKHONOVA, N.A.; BY-
ZHIKH, A.N.I professor; RUDYAVSKIY, B.A.; TERNOVSKIY, S.D.,
professor.
Minutes of the session of the Surgical Society of Moscow and
Moscow Province
of October 10, 1952. Khirurgiia no.4:92-95 Ap 653. (MLRA 6:6)
1. Khirurgicheekoye obshchestvo Moakvy i Mookovskoy Oblast.
(2sophagus--Surgery) (ZsophagUB--Canoer) (Rectum--Diseases)

The Camittee on Stalft Prizos (of the Council of Xinisters
LWM) in the fields of
science and inventions annomees. that the following scientific
vorks, popular scien-
tific books, and textbooks bAime been subuitted for
competition for Stalin Prizes for
the Y*ars 1952 and 1953. (L?A:Net8k"- 011turd, Moscow, No-
22-40, 20 F*b - 3 Apr 19c.4)
FAM Tltle of Work Nominated by
Kazanskiy, V. I. 'Transi aural Resection of Central Clinical
Hospital
A
the Tboracio Portion of the Ministry of Railways USSR
leophague in Cases of
Cancer"
SO: W-30604* 7 JUlY 1954

XLZANSKIY, V.I.
[cancer prevention; contemporary theor7 on malignant
tumors]
'Rak I ego predylireshdonle; sorremennoe uchanie o
zlokaahestvenrqkh
opukholiakh. Moijkva, Hedgiz, 1954. 97 p. (MLRA 8:2)
(Cancer) (Tumors)

rA7A SKIY. Y.I., professor.
Surgical treatment of coronary inWficiency; second report.
Khirurgila no.1:42-A19-J& '54. (XLRA 7:5)
1. Is TSentralluoy klinicheskoy bolluitay Hinisterstva
patey moobahchaniya
(nachallnik - generol-direktor T.N.Zakharchenko).
(Coronary arteries-Disseses)

XAZANSXIY. V.I., profesoor (Hooky&)
I -I"-
Gonsiderations on A.A.Poliantsev's article,
"Dextrolateral surgical
technique in exophagogastric anatomosis." Vest. khir.
74 ito.4:
84-85 Ja '54. On-RA 7:7)
(ESOPHAGUS, surgery,
*excis., approach & prop. of stump in portial & total
surg.)

N15
6U. 2
.K2
Kazanskiy, V I
Cancer and its proph31ac tics (Modern
theor-i of malignant tumours) Moscow, Foreign
Languages Publishing House!, 1955.
95 P.

V. 1,
&=Wri" of pqWm pWWAM at the Un CMSVO" of &WOOMS of the
USE# MD"mt 2D - 2T &R=rY 2935s lWuftd3
Surgical Treatment of Coronary Insufficiency.
V. 1. KAZANSKY
(Cffl*W Publiestim) UwU"Ifl".
WM

KAZANSKIT, V.I.. professor.
Glinical a5pacts of diseases preceding cancer of the
stomach.
ik.Y.Mallnikov. Reviewed bv Y.I.Kazanmkii. Khirurgiia:no
.7291-
94 j1 155. (HLRA 8:12)
(STOMACH-DISROBS) (STOHACH-CANCIM) (HRLINIKOV, A.T.)