SCIENTIFIC ABSTRACT KASATKINA, O.I. - KASATOCHKIN, V.I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000721010008-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 13, 2000
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

From the output slit of the monochromator,.the light falls on the input of a photo-
multiplier.' The output signals from the pbotomultiplier are fed through a balanced;-~~';:-.
d-c amplifier to a K4-51 optical recorder. The monochromator in this Instrument is
modified by replacing the wavelength drum with a rotating conchoidal cam. In a sin.
gle revolution, this cam moves-a lever which rotates the prism so that the entire
spectrum of the oxygen-cesium cathode passes through the output slit of the mono-
cbromator in 16 seconds. The prism Is reset to its original position in 1 second.
The cam is rotated by an MS-160 motor through a gear reducer. Wavelength markers
are superimposed on the spectrogram for analysis of the spectral recordings. The
upper passband limit of the system is more than five times the upper frequency nec-1
essary for reproducing a signal with small distortions. On the other hand, tbe timi
constant of the system is great enough to eliminate the need for a focusing
in front of the monochromator slit. Thus there is no angular error of measurement
and the angular brightness distributionof the reference specimen (baryte paper) caJ
be studied directly. Measurement errors under actual operating conditi;ns do not
exceed 1.5-2%. Orig. art. hasi, 6 figures._
ASSOCIATION: Glavnaya~ geofizicheskaya observatoriya. (Main Geophysical Observato
d
SUB CODE*.
SUBMITTED: 00 ENCL: 01
OTHER-. 000*
NO REF SOV: 002
-Card 213,

L 3885-66
4AXESSION NR:.:,-AT5025232 ENCLOSURE:

A Con 'fiser
de
4,& V.,v if Lamp,-

v Ph
279 Doul~le Monochromator
1200

-7 Eff -

X
f
t Stora
e cell
g
er
f
c
mpl
Fig. 1. Schematic diagram of the installation

L 1~,~T(1)/FCC IJP (c)
ACC NR: ',T16014562 SOURCE CODE: -u.R/0169/65/000/011P-034/130."4
1V ?
AUTHIORS: Kasatkina, 0. L; Shifrin, K. S. R
TITM: On the problem of the indicatrix of light scattering by a system of sphericJ
particles
SOURCE: Ref. zh. Geofizika, Abs. 11B250
RZ-F SURCE: Tr. G1. geofiz. observ., vyp. 170, 1965, 105-114
TOPIC TAGS: light scattering, atmospheric cloud, fog, light diffraction, light
interference, geometric optics I
ABSTIVICT: The problem of the possibility of ontaining indicatrices of light scatter_~
ing in systems of si;nerical particles--7articularly in clouds and fo-s--is examined.
The eydstincr data necessary for calculatinj these indicatrices are evaluated. Cal-
culations by the authors of indicatricos of light scattering by an individual parti-
cle with m = 1.335 for values of 9 equal to 59, 60, and 61 are given. The calcula-
tions were made by the formulas of goometric optics, taking into account diffraction
and interference in the range of scattering angles from zero to 250 every 0.50. It
is concluded that the data necessary for calculation of the indicatrices of light
scattering -in systems of particles can be obtained only exm.erimentally. Authors'
abstract 2Translation of abstract7
SUB CODE: 04~ 20
Card 1/11;L~411'1 UDC: 551.521,3

SOV/32-25-1-19/51
AUTHORS: Rabovskiy, G. V., Yegorova, T. N., Kasatkina, 0. P.
TITLE: Rapid Method of Determining Sulfur Dioxide in Hydrogen Fluoride
(Bystryy metod opredelen--ya dvuokisi eery vo ftoristom
vodorode)
PERIODICAL: Zavodskaya Laboratoriya, 1959, Vol 25, Nr 1 pp 36-38 (USSR)
ABSTRACT: As the iodometric method does not allow an accurate measure-
ment of SO2 in gaseous HP, a determination in a bicarbonate
medium is proposed in the present case. By the reaction of HF
with the bicarbonate an equal Volume of CO 2 is formed and in a
reaction of one SO molewith iodine in a bicarbonate med-ium,
2
four mulci, CO2are formed. The CO 2 volume can be determined with.
SUffiC4ent accuracy and so can the content of SO 2. It is as-
sumed that the errors caused by a dissolut-ion Of C02 in the bi-
carbonata solution are rather small under the conditions given.
Experiments in an absorption vessel (Fig) (with stirrer and
Hg seal) were carried out to confirm this. The experimental
Card 112 results obtained (Table 1) showed that the above mentioned

SOV/32-25-1--19/51
Rapi'd Method of Determining Sulfur Dioxide L
Hydrogen Fluoride
error does relatively not expeed +3%. An anal sis step aswell
as the results obtained therefrom-(Tables 2,3~ are mentioned.
The method allows deterM4 nations of O.M,' by weight of SO 2 and
more, with an analysis taking frl- and the
relative error is rrient4.cned to i~-
There are 1 figure and tab.Iese
Card 2/2

L 2670-66 RE (I)IM (m)IFOCIEiVA~h). GS/0TV
Oc-EssioR NR:-'-* AT50j943 UR/0000/65/000/000/0293/0306
AUTHOR: Dmitriyeva, G. V.; Kasatkina-, V. I.
44''I'S
TITLE: Aerosynoptic conditions for the appearance on the earth's surface of aribas
of increased coticentrations of stratospheric radioactive products
SOURCE; Na.uchn.aya korit-erentsiya po yadernoy meteorolozii. Obninsk, 1964* Radio-
-otopy v atmos zovaniye v meteorologii (Radioact v
aktivnyy tere I ik i
isotopes in the atmosphere and their use in meteorology); doklady konf~!rentsii.'
Moscow, Atomizdat, 1.965, 293-306
TOPIC TAGS: nuclear meteorolo y, radioactive pollution, radioactive Kallou
ABSTRACT: This paper describes the methods used by the authors 'to identify the
characteristics of various synoptic situations present in the surface boundary
layer of the atmosphere over regions which have exhibited especially high radio-
activity after thermonuclear explosions, and to identify the mechanisms by which
radioactive air passes from thd stratosphere into the surface boundary layer. The
data used in these studies were collected from approximately 50 stations in the
United States during the IGY. Orig. art. hast 8 figures and 2 tables. [ER]
Card 1/1j

I-qard

CHOLAKOV, Iordan, dots, inzh. khim.; KASATKINA, Volia
Some problems in the prospective steel production in
Bulgaria, and the problem of its raw material base. Tekhnika
Bulg 13 no. 3s4-7,11 164.
1. Member of the Board of Editors, "Tekhnika" (for Cholakov).

I -
KASATKINA, Yblena
Oar TeVieW Of technological developments. Tekh-mol. 29 no.5826
161. (MIRA '34t 5)
(Technological innovations)

K&SATKINA-TITOVA, V.V., assistant
Blood transfusion into the bons marrow in obstetrics and gynecology.
Akush. i gig. 33 no.2:24-27 Kr-A- 156. (MLRA 9:7)
P
1. Iz kafedr7 akusherstva i ginekologii (zav.-doteent N.T.Rayevskaya)
Tashkentskogo institute, usoverahenstvovaniya vrachoy.
(BLOOD TRLNSYUSION, in various dis.
gyn. die. & labor)
(LABOR
blood transfusion is)
(GTNIIGOLOGICAL DISUSIS
game)

USSRIfIbman and Animal Physiology- (Normal and Pathological) . T
Blood Circulation, Blood Preasurc. Hypertension.
Abs Jour : Ref Zhur Biol., No 4, 1959, 17497
Aut'.-or : Kasatkina-Titova, V.V.
Title Ovarial -Menstrual Function in ItyportenGive Patients.
Orig Pub Med. zh. Uzbekistaiia, 1957, 1,10 1, 36-33
Abstract No abstract.
Card 1/1
48 -

r KASATKINAq Yelena
. 29 no,2:26 161.
Review of new developments. Tekh-mol (MM 14:3)
1. Korrespondent zburnala "Tekhnika molodezhi-n
(Technological innovations)

KASATKIRAq Yelena
our review of new developments. Tekh.mol. 29 no.3:39 161.
ONIIRA 14:3)
1. Korrespondent zhurnala "Tokhnika molodezlii.11
(Technological innovations)

KASATKINA, Yelena
Our review-of technological developments. Tekh.mol. 29
no.10:39 161. (MIRA 14:10)
1. Korrespondent zhurnals. nTekhni a molodezhi".
(Technology)

V, V.A. RODIONOV, s.ye.; KOSTINA. S-I-; -Y-~SAIII"A-
PASKHALIS, T.K.; SIVO
soft butadiene-nitrile rubbers. Kauch.i rezo 19
Preparation of (14IRA 13:10)
no.9:1-4 S 160.
1. Yaroelavskiy zavod sinteticheskogo kauchuka.
(Rubbers, Syntbatic)
A

ARONOVICH, Kh.A.; KASATKINA, Y.e.1.1 SEMENOV, V.D.
Attachment for-a fractionation column. Zav.:Lab. 30 no.12.,1520 164.
(MIRA 180.)
I.Iftroslavskiy zavod sinteticheskogo kauchaka.

GIDZMAK~O.S.; KASATKINOVA,A.P.
Some theoretical and clinical problems in blood replacement.
Bratiol. lek. listy 2 no*9:536-541 1163.
1. Katedra patofyziologie Kazasskeho lekarskeho institutu v Alma
Ate, Kaz,.., SSR.; veducit prof. O.S,Glozmany Dr.Sc.
Rw-

MATOCHKIN A.V., gornyy inzh.
Experience in diamond drilling of blast holes abroad. Gor. Zhur.
t
no.4:33-37 Ap 160. (MMA 34.- 6)
1. Moskovskiy gornyy institut.
(Boring)

KASATOCHK'BI. AnatolJy Yasil!yv~- LYUBIMOV, E.G.,, otv. red. izd-
va; OVSF-YENKO, V.G., tekhn. red.; BOLDYREVA, Z.A., tekhn.
red.
(Diamond drilling of biaEl+, bolas) A:Lmaznoe burenie vzry-v-
nykh skvazhin. Moskva; Gosgortekhizdat, 1962 67 p
iMIRA ji-.7)
(Boring)

KUTTJ20V, B*N,, kand.telclm.nauk; KASARCHIMI V. ~ irizh.; IMIELVICH, D.AN,
inzh..T()IILIZ I I U.G. I in,-h~--
Dust coll*eM-W-.~jdmr!nC borinC with the c1cwli-C of loore. lioloo
with co,., roo-oct air. !3c-.op.truOa v prom. 5 no.ll:"3-24 "I.
(17M, 14:11)
1. lafodra burvzryvnTl-h r,-i-)c,t 1,oolzovs%o-o -ornorro instituta.
(Mine duutu-St"'ety mcaa4ea~

SHISHOVA, O.A.; OGURTSOVA, L.A.; KASATOCHKIN) V.I.
Kinetics of the absorption of amino acid in the intestines. Fiziol.
zhur. 47 no.51630-637 14Y 161, OURA 140)
1. From th6 Laboratory of Higher Nervous Activity Institu'te of
Nutrition and the Department of Physical and Colloidal Chemistry,
I.M.Sechenov Medical Institute, Moscow.
(INTESTINES) (AMINO ACIDS)

-IV
set
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of thermal denaturation of protein under
=VMM Tongur and V, 1, Ks,at%hkiV% Mrwow
Irlharm. Inst.). 'Dokladv 74. &M-6
69,50J.-Cr"t. human blood albumin (Ice) in lihmphatr
buffer at pit 6 was heated In rubber w% in it high-pr"sure
Rutaclavtlhr. Controls weir run in the same app, without
pressure. With pressure of I(xw)-71M aim. at 200, 7O.P.
and 78.4', the following was found: at prmiure% above IMO
atm. the equil. shifts toward natural protein (measured by
tuibidity of soins.); at pressures above "I atm. the pro-
lein Is denatured by pressure and turbidity rapidly rlm4.
Initial pressure nettled for denaturation riscs with increased
lemp. (results given graphically). The caled. equil. concn%.
nf denatured protein, calcd. as a function of pressure.
~
Vgrmf well with expd. data. The following values for
aF, aff, anti AS. for the reaction were caled.: at 2003-K,
andlOO(latin. lMkca1./moJe,24.OM. and 76.3 kcal./mole/
degree. r"p.; at 2fM atm. anti M.A*K. -1111. :.104.
and 73.0. resp.; at 25M atm. anti 343.5*K. -457. 240W.
and 71.2. resp. G. M. Kosolapoff

Arvication Of X-
Zj ~fto the Oudy of milk produas.
,kfm %1-,.. Pts,trul
,".I Invif Akad, V~1611-8'.T.T-M ' .14, Fis 13. ""1. 1
, IMi I Altl~ "0 Clkilt Ilk the 4*-hY%IlAtC 64M CIT%tff.
Iwk)w W )* awl the ji-anhytl6lc form crystAllising Abure
W.P. Sinav the t-tritsi. stul the Qzv- ot the oyotali Irtrt-
I'do 0 thC 411A111Y .11 11101k. q46111t. JVUS. Id .- A11.1
.1-Lwt~ is hoal-tmis awl c~tn 1. 4-1,Nbi"l 1-y vrosy Anskly,i,
fit I,. abo shom that a Ample of powil. milk ccullaim4l j~j%
10- and 712% a4mm. Nwil. and depritini milk md vocs-

TONGUR, V.S.; KASA OCHKIN, V.I.
Wfect of high pressures on therml denaturation of proteins. Kh1m. L riz.-
Khim. Vyookomolskul. Soedinenly. Doklady 7-oy Konf. Vysokomolekul- Soedineniyam,
152, 124-30. (MIRA 5:7)
(CA 47 no.22:12438 153)
a
Ar~ -

!7, -Protc~a-iige;iiiWo-n-undcr prenaisro. The kitietics and
11~-the od num of th rocew., S. rongur ard V. 1.
Sci. U.S.S.R,Wscow). 1,7i2 ~,-
BiAhimikm:j A
Mi nall,,_
jov, Agd.Wauk S,S,S. R. 2, lGG-71J(19ryt)-A new method'
was &velopcd for die rcgenexation of licnatuted ptoteins
iiith the aid of high pres~qurr. Oil tile basis of the general
concept of heat dt-matiliation as a structural disorganization
of the protein mal. reAulting in an increased inclar vol., It
was assumed that pres,ure would prevent heat denaturation
and revert the process to that of re4eneration of tile protein I
mol. Under Audy were cryst. c~,g .and hwa X3
trwli, conalbLinin, -t-globulin, ctyst. chymotry7sin, and.
ha.-ulfti- '17te meff;ods of stuay Lt:ed were similar to thoic
dendhed t)y Tonjur (C.A. 4-1, I-16f). Preliminary expts.
(CA. 47, 6-1,M) Mill egg alhMnitl verifitif ille correctness
of die theoretical aslumption, and indicated that tile: non-
Cryst. fractiolis were pritalitily tile ones that regenerated
tinder premnire. However, such protein heatcd at 62* for
8 min. an(f subjecturl to pies;ure (if !ON atin. for 20 firs.
resultetl in it reguierated prutein that, in the properties
studled, differed from hoth the native and the denatu-rd
protein, probably owing to the oxidation of certain active'
groups during ~ e process of &naturation. High pressure
in the presence of redUCIng substances such as glumse and
aheorbic acid In N~atd. 5oln. causes the denatured prot6ni
to gn into soln. Denaturid ovalbimnin thus regenerated
difftr!i froni the original native and the denatu"d proteins.
Home If-globidin was similarly ikudivd with aiuch the -,ame
Malts, Cryst. human Stnim filbuin, in O.SN phosphate
, In
buffer at 011 6.0 was h "~ted or 13 nim. and flien
suhj~xted to a prnstite P of *Matm, for '.0 lirs. Tile re--
generated protcin was practically irlentieal xvith the initial
riLtive protein. Partial ri:gcnt:r;ifi-; ti-denatured
scrurn albtimincanbeaccomplish~l~ 1.111irs.
L

7

mific antnttrlrnn~ri;litin prinKrtici (A ~ucli
,Axum pr,,t.iins remain uniffectul, Griart-ally Ott dt, ;,T: M
rogenirration thal: denatured saurn protein mml~g~-
ftvidt large.11, on P-nitij couditions and FrArticularly nn the
pli of Me invilum, No pre-.sure regewration in a plioi-
Nhntv.Ajuff(--l 'Olu. could he efkcted with 4cmm allIU111114-
i
t d
iff
e-
efe'li
nts ta a, d
Enatured by 111tht of tural this Po
naturin.- rm,hunistrl. lltat-dtnattlr~i ay%t. allyinottyli-An
at" tk~ teg-Imitecl to a considmIlle deglitr try rtcs-~Ure in
d
h
ti spoatwimus it,
ta w%
a pff~fiel maditim mum rnpidly t
V
i itistilin in 1jt
de
Ii
w
l
t
d
-
,,.
t
oos.
um
m
it
Mmation con
1411101 (to Prp"tnt lortneatou of r1btilq) "m lit
by- iticycaiie& lim-ure, but its ih5ulhi pMcitirs reanain
UmverAbly lost. A Witf: theoretk-al gentlMijI.RtiOU JS.P;--
sentedl Ar, a~ result of nurzterous apts. 'Vith Iffmute4 QU

tMO, 2W. and 3" atm., It as concluded that the
rate of regeneration of serum albumin cza be satisfac-
Melly expressed by % reaction-rate equation of the Ist
orCz- Since --the - rate--of serviti-alburain -denaturation
--unintal.
can be presented by an eq=tian of the Ist arderi, the znech-
anisin of the process of scrum elbumin denataration Is of it
type. provided that scine possible intexction be,
twetn the protein and HjO Is not considered. If the mol.
of protein in safts. is conceived as a globular entity, then the
process of denaturation and regeneration must proceed In
each Individual glabule Independently. The comparatively
small vahte of heat of activation iodicAteit that few %'cak
bonds In the denatured globulin are being broken during
activAtin. The pas. and smRil value of activatlon entropy
likewise indicates that in saint parts of the macrumol. there
ruay occur link rotAtIons, Throughout the clipti. tile LIC-
fivation heat rentaincil practkolly const. and Indclmiadent
of tile ju,44urc Thils. tile balic factor that (lotit, tile III-
-crease in tile rate of regeneration tinder prcs,~urc Is tile
change in the activation entropy with change of P. Rc~
suits of calm. of equil. catists. and thcrinodynainic vallies
for dificrent temps. and 10000 42W, and 3OW atm. of P
for deriatured serum proteins are tabulated. The effect
of denaturation and of (lie reduction lit the conen. of the
native protein with the incr&Ase In P can be explained
on the basis of equil. between the native and denatured
forms of protein. as per equatiau K - ( C~ - C)l C, where
Co is total protein coucti., and C is equil. conen. of the ni-
tiveprotein. The shift in the dcriaturation equil. under the
Influence of p in the direction of native protein is explained
by it e incrinir In the Molar "I. ol tile ptotcha din ing the
denamratian procevi. F40. coacns. tit regcnetatcd pro-
tein In rel3tion to pressure were obtainctl by the following
cquatlan-log Kt - to& K, -(A V12.3RTXP- - P,). where
A V is the mean value of the ptoteux vol. conversion during4
the pressure interval Pt to P, The calcd. approx. values
of the equil. coast., of the free energy. and of the entropy
-sure and 20* Indicate that
of denaturation under atm. pre,
the equil. form of protehil utid(,.r itannal Conditions is that (it
-denatured. protein-- a. S.
pa- ~tr` M

KASATOCHUN, V. I.
with R. A. Dulitskaya "Examined kinetics and thermo(3,ynamics of renaturation
under pressure"
report presented at the loth AU-Vnlcn Coar. on Hlgbly tblecuLxr compourda,
B Active PblYMSr scow., 11-13 JUna 1958- (Vest. Ak
Nwk am* 1958., NO. 9,0 PP- Ul-31-13) '

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I mkixti~t,'%uhlimcd W,
the dbvrrsiw of A- clectlaw jvthwity 40,14K) W.) .00
f W W 14 "S
zil xj,,es vWua for the launud ptA-tw ~, It
f JtW4 c '90
-jv.&ndof#-O t Ckviran InIcl Cft=
the cirptals. Tbcw.='= ri,h thaw of Rupp
(C. A. 26, 3723, M32)' and id Spfautl (C. 1. 27, IWO
00 If It Is smumed that & monuMstall of thr*c authtwi
were cavend by is Wer of antwiclitrd
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47Aurmd RzkAgskoy NAimij (j. pAW. CAem.). IkU. S. (m). lixr) _ ICIIS
00
Itumelan.) The divrerskutafriectrunam mFovitsf)f 40-4011 v. h&A I"notud"
The vitluv.v( the intentAl
potrutcat (if tungatim. delorinhw4l by dipplaveluctil 4 maxima, im IP-5 V.
l I
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epentlent of tim spowl of the clectrons. All the indsirna
can Im
divkW Into two grou
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with internal
t
tisl
M5
i
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en
a
ant
,
po
p
0 v., respectively.
'11w existence of these groupm Is the rrAtilt of eloctrunit, interfm-utv either in
the crystal or at its ste
cxi surfa
e
Th
diff
ti
1
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c
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e
on o
werv"i in th, 4,11m.n.
pp
mients of Itupp anti 8proull occurml twt *I the A-an fa-1 .,f the ingle

-rystal. but at the IAyvr of unurientod suicru-cryatals %hich tvvered the ZOO
muf~w~~( the ainglo crystal.-N. A. 00
4.11A A afTALLUROKAL L11911AU11111 CLASSIMATION
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so It
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amumptionx made. The theory it applied, with matimfiewry nvults. ui
00 J
cal.-ulmite irmlitiv of file lattive ronstwits, heatA of foiblimatilm, ;%fill wfil- 60
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0 4 01
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AA 1. 6- AL X JP: 01 A-A- X k- j L 4
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Structuls of mixed (load) chiornotes,
00
and V. 1. Ka-utochkina. (kg. Chem. Ind. 111~ S. S. It.)
ail 3 GiA 41-(I1kM'-M'C. A. 27. 1W.-Mixtil Plausents
t
b
h
onA
e$
cas
iltisiused by eli-Wis. al PIK) vinti alk. cwt
sit 10% AWII twoved it) be supailm in latuctule ulu-
ocissity and in makin; *pit in (be loudness resulting
ML11. of the itipctlicntit, Tile
at ltwcu
tu
b
.
,
y xcp. pp
ji-ray pattans aftcl a cevtokd the pttirsave of a 2-phaw
system, Amnsisting Chielly of tIW triple mat of MCCO041.
0 SO, with au &Ill. mah adate aud soinje free elk. ixith
1
the tDoao-
i
us
IW,.4C&.W. leta
sulfate. PbrLs".I Iwo
00 clinic systent of pure I`bCx(h.PbSkh'accompassied by a
h
-
Go
e
"iclst contractiots of the lattice, ami rellesishh-s it its t -
0 r"rucluxe WW prup"titv muce that] file Iriple %dts dr-
Ce 0
rivvI (torn IWA) &04 Srso'. In file furnialiml
Old
38AW
pQ
O
PbC as
4
f
4,
q
of
the Djulloclitsic I4ttkC Of FbCrO4.PbSO# is r&IIKUIIY
gee
The prewisce of excess ". stalts of alk.
raids mclaIq duting the ppin. of mixed chmmatel
ltud alk
0 ,
-tTcvt, the crylltal habitats withip4t cbun&g the stl:wture
All "( tile cry*t. latittv, Thr ncledl* &W rint-like ccyit.
l
tr
ppts. air better pigments for points tball tile Crultu
M
j
~ryvt. pila*n1subtstillrd by ppt$. in the (A Nact.

oo
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Russ
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.,
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y
j
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ainst Kammovshl'it
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g
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oxide fom
00
for"11114 111:0:0, with 6Inol." Or. Arv advall,
E. It. of
AWAN it c.. 'I"
u a A. -is:
0019, ov#4 I(A wig K a
00
40
ET
I I a rw a w 14 1 1 1 v
v, I, An
0 0 0 0 0 a 0

to to If It I is of R a 0 a Is u -SG fr-w
A sit &No ;App "plot oo D ".plal
X-ny in a ad tho alrumis pt"mium
00 Kasatuvilkin anti V. K"lov. J.
Ckew.
00 cf. C. ~. 30~ WKP; M. 441-.--
tkvnwtrk evaluation of pavider ding
00 it) i he viethod of I)tbyr-Schefter =06.1=1 v-dCu K.
0 mdiiLtkm and in&xing according tu the ulcthtid of Ifull-
Dawry (cf. C. A. 16.17W) shawrilahexagunodrionenavy
:0 cell with t~r tiiintitsiom a - S. '0 A. and c - 6.72 A.
06 ond indwilng 4 muh. KOI. The stitictuft
10 the C&CI type. The Opw group 11, J)"'A' Thr VIP-
ordinsirs of the 4 9 attions air: 0 0 11, 11 'is I j. ',, , ',1 11,
V, 0 91, and thow of the 80 atoms: 1/14141 A, 1) t; . I -
U. 0 0 0. Vi V, V, - v Od 1.11 im
00 til the higher K pcioxide is ftittued by K i,,n% wimb
nly Chargril iml tif (h ~ I I is "Inslar
04 allermle with sit
00 j to a defamed K tattice. 'rhe diuaiwr tNiw,-cn ait, o
atodis td the Inns al the itiol. amounts la d. 1 -1'8 A.
00 M. G. Ihmne
J~
u a AV to AS',
l* 0 3 T ITA M A I I am 0 Ill IF I w IN 0 a
Cp tr it a at a a K off a it of No A I !at 04
* 0 0 * 0 * 40 g 0 0 4 4
to 0 0 0 00 : o 0; 'm of
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00
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see
lose
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00
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'
iihimhako y awl
"Odmitim d kdm &Ydds of &M by Alwalm N. A.
L^K tochhkin ("L Akad. Nawk 8.8B.N. (Compt. remid. Arad. Nei.
X. 14). 277-278 (in Runian); armi Compt. rrad. (IA4Wy)
Acuis.8ii.U.R.S.8.. 938,[N.H.bSk(4),tT7 (in FrAg6h)).-Bram which hema
biva gmisaii in am dLrvvtion only sim an elivmm-diffmction oliagrapt which
buticatesainimtt~ompkteorkatatimotanumbt-ruftlwcn-oWm Whrrithe
phot%mph hi taken wM the incident bram Mlirmlicular to tim difvvtion d
the wmtcbtv. the aids slong which crystels Lm orientmi is the I 1101 dirrction.
No such effect Is obiverved In the unidirectional
bmio
of
l
a
c
n
ean copper,
iron, or ".-N. A.

00

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00 t Elecuoule diffmaian in the sut(aco layers of fmial

Fngh,h).--X.mv f1chyr redec-
tim mts. an cinrry-pol~Q Mn~lerl I Cr-%ln..Ni-
in ruh eae ul 1.1th n. and -I-
steel MWAsed tb
w~
plim" (fristicrim d anstenitc). hut [lie
showed only the a-phasc, 'A*ithlitiLN%,x.tayt%pt-t.showeiI
both 41-Mad #'Ph&w%- but elect foat'Kratni (in] y I he- phac.
th
li
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o not %
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case the e
rctforingrains
e
thow phtwi which we unstable at low t4-fnp,;. X-ray-,t
penetrate too deeply to show changes in the surface layr"
due to various treatments, but rk-efronic difTraction np-
parrntly shows the condition tif themuf2ce w1wre, Ott- 1111-

1
Mable ham,% have been dicintegrate,f by intene dr(or.
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: A Fm I 1, 11- 2.441 A.. I
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31WA, twng (othe .1oldt'ril), Io tile KC
r,,W. ihat thrditstieft. epot(gy 14 too - -;i.rj r.v. And file
firl'it-41 Oftillity .4 fl~ - ALI V.V, The fiftfurfats. is"%-
with the forollaill-11 mill ofrl."Illp", of Iworol0h.,
so ill which tile (IS 111gli, tilkr,% INkIt. tx~ well si the oxidalk"l.
40 -3 mill"Itofs p"wfWrI;" of perlotold". C111 Ill, 41VA-01"41 fly I%

: m-W r1reirnie -a-heoviv ill file tvaivv .( the fi,aclimi.
ge
0 At f1w,, ii qajor,lf rhem, ija~txvjf-ai owir 3-rImfi"I sr~-
0 flooltr INWHI 14 V6111fillrd Ill the IN On.4. owing to 1hpaddil, 14

so :1
A pvtrullitir of the
the rkrlfn" 0( the O"I.Istwe.
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oM which
fi
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ly
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l
td
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. Imn
Iltowt filoriber Illietartitim into the ~nnllw; vtMAhle o( 1110
A&A fvi~ k-10-01-R. 'Me troutsfOxi i% Aftwipankil bir
tile IIIIIISIrC4,11 the lumd. Tostiv%mutf,tor
i
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tact. o
fill. bors"S01,11 64 phloth)MI", Slad othel prih
"I ik-li--n -1 hyd,-,K~0--. too.. It 6 nrcr.,uY to taittodry
'he decampfl. of the 1wroxhic gorup All.1 the rCWr_ pf-
U." ed rutdivoth and atomic itr)II4.
m'
NH
f
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Chemical Technology), COOOPI
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Wertis and rolation suit Ccillatit
I Ane iliff,ftlive; flat
00 1." tfsA At the Symincity via,lit ax Pth and the
k,nrutiurv ivil dimenvilivo, (in A3 at: it It
041D V)AN't -

1-il-arrO ill an Anier"A value ill I.XIA. hi.0, should
file Vnl.. floollateli -IT11014TV:

C C
-C
0o 'o w
1,47, A.. lo o - 1.45 A,. I., tit
0,, aliplimic Wind) - I.&I A.. 1, P (It" the Im-tit,"ic
11,-0 - 1.41 A-and wheit, Iv. v - :1 0A. istlirstual-t
hosuicir lietween the C alonia ill ailiucent uslavvicill. mids.
lilting the c axiii. The valrr~. angle in the peroxide group
kralvd.a*113"15'. In the latticv the 4ekingsted tuotz..
%%jilt Ifitir perinide groups ill close vinitact, fmin an auncd.
111~ tit, IAIO Ill (he

4""S
I low 00.11tv
r0%. ou i-llall go Gm- tit
u AT go 4 1 ;-T-W-Ir' #A L I I N 0
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006906*9600904 o0 o *go o0
if it m " Ad It Zf J3 34 dl JS 17 211 P At $1 U U
PC it it it " is I is I.
A a -L -11 11 _ jL_ J. L -1. a , 14" r 0 1 1 V V ~j _A. -t- I AA $f CC 9P
so
X
x
. Y investigation of the CfYttallizAtion of Vulmiled then IllaxiolA IRI r 30' f 21, and 6S. 2-. F"P.) I lit- 30
So rubber on stretchinq. If. V. Lukii, jua idimrvatifinq lva'l I" flit- that. its 8,11111, 140
YJ .' Ft.
J. IWA. PA . 16. I;Ixl- St INIMin Ru%slan).. I'milr%xive frmilfillt In 1,
-Tile tottlit-I Of Fivid j C.A ~ 33, '21Q291, KLW) w-as %116-11 vollioll of ety'lo., mullAtivr drmttletim accoinNilying
so a ft? det. fly tlcbytFgtjfn alicruphotitfoctry tile petrental" vuloAttiratimi tAkt, plact. The itwtva~c 4 1, at Ill 111411~ i~.Oo
"f cryst. phal'c C ill I %,niftles Of niblVr vulcanized at 143* in tile prmnce of acxvlrrjIlv4 i~ ciplailirl Ity tile 'h~vlcr
06 fur v&rYifli( lc"Kth, Of tin't r (in miti-3, aftcr sttetchimig. r and coff"ponifingly lc%,er accumulation of OXHAtion
00 a, a funclitni Ill P, Ilimir tmuplt~ d-lV) were prejol., products; on the other Imind, the nb~rvvd rever.41 of
(roill IVA tllixt "t '11)AL
-if .13VTI rubber ]DO, S 7, zilo tile -tress from r ful upwarill, ill-licall, incirctrd I
00 ~JVA IV lit- d '_1. % 4C
*1 i ilit"I't Mild Wit It I lit' Adlill, Of HICIV-111110- title it, ,uch an accumulafloo. The f I thm the
Z Iwild.1thist'lic 0:1. thliffellylontalliditle 10.378, alid a thfulain 4 r I't-Volt-I flit- Illikii. is tile it rr marke'l live 1^4 tile
screleratut OA-11. J"P. The "41111PICA Witte offetched %irrichilix I, IiII1141 V011 ~l r"Ife'l.wdillit lit, it-AV in virrP.
.4
cxcvi
Ill hich could bc Ntletchcl olliv IuVCfWfv related I., N~ Thoit
go after r 60 ruin., attil IV, which was Ftrctchcd Wi7r, ordy roo
up to , 3, and i*,M~; after 1, 3 Illill. I-'Aclj Of the: 4 samples
00 Showed 9 11111%. f III a C"1114in 1. io,-rMJjIjgly Affortef it zoo
00 the IVIICV 1. 111. 11. IV; Ilk' Illight Ill tile flats. iticrea::r', roe
in tile Older 1. 111, it it .~J' 71. '.j" ; ): f-W a give)) millpir,
60 if ifictc-ascs. with flit- dr9mr Ill %trutchius, but the positimi
& 4 the max. remained uncliang"I for a given %afriple:
jjt"n V fell to Fri., at , "Aaml IW Illin. for MX1% slivichinxiintl
"P. stIclixth . al'alu'l , 114,1
AmAii. Wil 41PInit Ihr.~jnr r " eur~" 4 e (1111). Ail. antl .4) 'zoo
Illill. (Air 1. 111, aild 11, 1", p,). curves kill zoo
4unt, bir a givert strain, with I tit, to
, 4i) loin afti-r which they flevirawil with further in- NO*
~4! crease in w. Curve ttf the ultimAte cloogation e of I And
Ill )fall min4mi (at 11), e 12"; atiol I, I.%. r 141-, fe,. 10.
aloe
LITIM.IM CLASUPK471014
tic.,
r Ah A 8 o' 2 Kno
U it, it at Kja afte
IV it tv IF K n it a ft ft
0 0
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b ,~a=to we
rubber' It. A. Dmmlkln, KLm-ca.
and A. Stuicuova (hl-kiiv. 1-
Zk
layst. AW. , " S". Fit. 12, oto--m
(I%W).-Messurements were made with it Ifilm spectroul-
eirr kit the relthin 15-11.3 14. The mviver wt* it Ili Ag
thennopite. The lubber Wall il%VMt19AlCd 4S 3 fibli 45 -."A)
i, Shick cast on *,iler. Thr alronjillon .1wisum of Na
buraditur lubbef 111141wil it Wall licaf 3.15. valkwil by CII
vibralkiru. a baud near d.1 m by C:C vibialuum. a Imil-I
clear 0.0 A attributed to the deforruation of the inethylon:
Foup, and 2 handii at to.", 5 )A anti 11.0 11, causcil by de.
willations of the grimp -C:C 1- Polylliefs (1)
I
-01101:011011,01,C)IX)ICII. -) aj -CII.-
k'II(CII;CIf.)CII,CII(CII; ell,) I Vint Iw .11116(ir't.
"' Ise M-Mill PrOciummim The fillos werfirmi'llso-i ill lilt
at 142-3' for S. 10. W. 30, 40. anA (k) ndo. ILtn'l. V..f.
restiondinx to the Oil And the CO group aprW.1r; alti
Imilds to vibralimm tit - C ( t C - t14 5
).I. Ottyltoll act. pit lilt thoulde bou'll All.1 lite aplic.11.411AV
tit new poulli liectolt"Ill (.A lilt Ouittge tit lite 1,1,4w4 fle-( ill
N't

Ing i~ the f(~rm o( the aDmarphous ring- but mther -fmufzt&,-
ng Tbig pTnbll)ly repm-i'raq vart, af
"6d
-fn
A-

c#KIAI
ond 01
3445.
rubw
Itkub. 674.
(-f. shi-
thi. Ilow
2s. 4M. A
"I'lWATI.

0 0 0 0 0 0 0
b
a C
A .
-
:.*a
*a
as
00 c
00, a
0 A
13267, X-R.y Study of the cry.1.11Itian 'A' Vuleard"d
Rubl-r During mortching
it- V
I
K
hL
a

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.
.
amAtx
in and 11. V.
Litkin. BuIpbrr Chemistry and Irechistd-w. _
s

11. ITranslated fnmu Aurr I I alch" "i
" r
Fftikl (jutarnalofTechnical v. 19jan
IN9, It. VIA)
.3
Pri-scm;s detailt-d stiody of the crystall&ation vurve-s of vulcam-
\,aitrz in relation to lbe elongation )f villvallized olijtarcs. l

00 zil
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00
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An x-ray investigation of the cryttalillation of rukattised
rubber on stretching. 11. V. 1. KA,itmkkilt itni It. V.
liakin. lkair. 1*,kk. Piz, 19, 7d Kit 19411) ~ cf. C.A. 4 1,
-W-17J.-An unukRA Rlo~l. whiattiv prrvitmil puittkit4liatil
and Conti. no tilk-r,. vulcanized it I VII for lengths ol,
time , froul 0 ill 10 titin., and strriched NNI'7,. fix, fractian
of fill- cry%t. phi-w i1ccravases regularly, from 70 1
.ith inm-ing , N-cuu- of destructivc ox6lition. Within
the sAme limil~. I he anal. wt. (by vicosity of dit. soins.)
(Alk from 711,10N1 to 1.1.w V.011). ind the carp. mt-Antrrd
untler I ka.imet. call. ill IM" ill NO Jiro., rites from IN) to
4.'W)%, 'rh, 1cmile ttirvisbith I, MIN ImearIv frann IS it) Ill
kg./sq. call. With nnoler,1 slicri t IM) + *i i2l, Zito 05),
all"ric acm (2i t1w%
weply to a m... w(hin the lot 41, mill., then falls off-
slightly antl renuins ennst. with further increasing r.
The curw of e has a sitnitir skilic, ricept (hilt ar (alk oft
slightly with latrac r- This Litter c(Trer is even more pro.
nounced with ~natik-l %laevt with site ~snw Iwarrvaltatirs of
'I
S, ZnO, and %traric j61, but wiih thittrain MA541 of
dipbeny1flutniiiiiw (0.71%) instead of tnercaptlaticovithi-
Iliok. In sualikird sheet with the Litter, but with 7 instead
of 2% S. the nixt. f is alluirper. and its fall with further pro-
klaird r sofflaw"Iml more marked. The Cictor rtsponsible
for the decrt-am- of / is evidently tile fornution of 8 toritigi-s
which rriluve The tinkility of the mob, and lhu4 count cl
ef"a
crystn.; with a low S content of 2%. tile provess of op.,viii
network formation is pimetic-Ally completed ast the optimum.
Anil has fit) fin'th, r rfit-CA On 11101V 1111110"gai'd T. The anh. v
sciturnt (.ill 4 I-ds fand # i, Mtrif,niv.1 to tfw 14,4ficixing
Oction of the jo,ilutil. 4 rou. T~ Tin, ts i,arn,
out by the calm rvvil (Al of fit,- imultiltiv 4 Lwicttir with t
ptolongtil I R yquid tit, opt iintlin in mi %I i. %it h '~"` S Thi%
Is n'A so with 7`-C S. whtrr prokuwIt r f, Milts tn'TU;hr in
lillus, Owing to contintud growth of I'M*--
ctrasinic irm,
Addn. all 3)% pla.,ticiter lmwrsfal A: -If eUM-Mili-
jr r ling , MO
tion; jjjJ)ujyj phih.slitt. Kk~ a strou
thin anatut. The mi,il, M11901 0 i, .," itim-4iing fit'Ic-
flon all ~ over the wholr range of vuk'alliLatit)". hilt. for R
live it milit., eaell f is --kil. "Ith 2 VAn' , of 0. onv cv-
IV, - ad
Imindhis 10 tile t.j. the other f., Ill,, 2n'l tilli,it
flat. vnit-allil.1ti4wil timiti,nif tlw optintinn) Tid, iollwAt i
.ditlefrol u.,low of the 011-119111 in IIN- _" phi., Yth,
mt. of bound S InCrrai.s with tinir at it" intlial '1310 , 14
Ila, %11jcanj,,atj,~n. flat tile oL,.rL,j Ntill tvilllill, plk%tiv .%,
long its tile %1%itial network IL,% rmt %limill throlighotit it,
whola-urtsi. Titi,nt-ky-im)utitfilrih,~f.-,'tttLtt-in-Litiwty
gor"ll ctmjjV it% ImAntil S -An 1~- jeconilutnit-d by a n1tti%reltr
liargrehAugeo1r.
baryond the opiiir-nia, Is gmvirrated by the d. 4 the PjtLAl
of, twolk~ %lore com ktrly crystil. i.-ulcinizate-i li.tvr a
gnAter at. owing to t e gn-ater flat. Of Chihli. Ilo-,Tr
high tensile sirrngth may still be prrsent. v%vn thl,ugh
calystats utty hAvc disapprami almost cotnPk-tclY; it, that
let.1, by oriented c1mim. lollibiticall of TY,,tn
"A"'. Iis t'
by bound S Is that? to Ill,- noticoincidence of the C S 14nd
distance land tile Lattice perM of cryst. ru')ber. Son-
m tile crystjjji=laiity t3y nceupying pointi,
bridatr S lowar
whieh tlu-rwiw miolit hi%T fornkit Imtt of Itw crystal.
N. Thon

Molecular structure and properties of rubber. V. 1.
Kx%atochkin ant! It V, Lukin. Doklady Akad. Samili
M-50949) -fit smaked-shr" tubber,
vuleattlad Nk.t (staukrit 4~44 fix,. ino 3. stmeic sew :_ "
N 7, (1.3). Atut vulcant"d NO
MKI, 5, 2, 2. 0-0). the intensity ot theamorphous ring in x.
ruy diffraction was const . over a wide rasice of extension,
notwithstanding the steady Increase fit Intensity of the
spLq& comftponding loan increase In the snit. 4 the cryst.
plutse up to (V)%. "is constancy of the intensity 4 the
amorphous ring on stretching Is Interpreted iv. ^n lkidiest-
tion that the crystals we not fornied from the "liquitt"
purl of the amorphous rubber, but from WhAt I% termed its
.. ga%eous" part, presunlitit to consist of free fragments of
trint. chains. The considerAble change in the if. of rutilper
on crystri. Is In mccord with this hira. The "gamtu."
part o( the amorphous rubber, which should scatter x-
ruys assips,ticts. the elastic propertivs of rubber. Com.
purism of the Intensities of the amorphous ri 43 1
of different clasticitles, plasticiml and .Plk-IXI
smoked sheet. and a highly elastic truk-unizate NK.31 -
fiPtrength 163 kC./sq. cm., telative elongation WM)%, crerp
under 20 kir./sq. cm. in 50 brit., 5re), as a function of the
thickness (up to 1.0 mm,), showed the highest Intensities
for low-etasticity and hith-plasticity plasticited smolrett
sheet, lowest Intensities for the vtry highly elastic NK-31.
and Intermediate value% for the unplastkitt:41 tmoked -sheet.
N. Thon

-&-ray
MOW Ell,'-,_

- - - - - - - - - -

Fulbber -Abs -~7
-77--L -4664-.---U-i-iy.-Irmstigation--ot--the- ~ aCML
cryatal M ation- I carAzed.-
I
-1 -
-
-
- -.
-

V01. 31 ..T
KASA e
1
B
V
I
HMdnd
rubber on streticidmg. IV TM -.r Unlr
-1160w6
ChemsIffid
kh
Pi
0
2;
1
19n=
MT
.
Zhur Te
o 0
'
.,
95
z ,
l
1,
,
r
Nw;. 1953 , 1950, 28p 565. The number of crystals vas
rf. this- journal
Vul-c-anised
determ-4-nect as a function of the period of vuleanisation for
Natural- smoked shee4- rubber stretched 400% without and with carbonllmk
Rubb
as filler, using varying proportions of carbon black, sulplu=,
stlparie acid, zinc oxide, IST, and thiuram. Without earbcn black,
cryatnIllsation beGan to bo apparent after 10 min.j GrowinG rapidly
at first,, slowing dodnl rembing a 60% maxim. arter Wmin*p
rer-nining constant to 220 min., and falling to zero at 3100 min.
Usilncf 30% car-bon black, maximum was reaftd,very coon after the
beeirming of vulcanisation, fell alirhtly within 20 min., and then
reached a cmatant value of 6eo. This checks with the 'relationship
betweqn the content of rubber crystals wd the contant of bound
sulT3h,-,-. Carbon black reduced t4ho modulus of elasticity. Without
black, tension atrength increased but little with the amomit of

The elongation of the X-ray spots irdicates that, carboa
makes the oriantatioii.of the crystals less definite. ';iith
black,.thiuram makes the rubber crystals more no.,irly r~~rfect,
explanation -of 'this effect b:! adsorption of the 1-ub-..-,'
to the carbon particle stwfaci) being corif izn?d by 4:'.-a t",
carbon causes crystallisation of the rubber even In the lli.~)~,-_~n~.I_ 01.
S,
mAcanising a"
- ynts, aid also by the difference b~)tween
orientation- and the - diroWocn tn' them
stretched rubber. The ovientat'L._,n of the nols. In tl-i C
of elongation, coopled with restricted rotaticn ~.iie to
creates an effe(~t of single-dUmension-0.
crystals are likely to be formcd at th,.~ siirfFcob of

K A SkY W ve I.
125. Xt-qAY SIUDY OF MMIC ACIDS (OF COJkLj
Kukiiarcnkoz:q. A., ZoloLarevskaya, -&_Yu.~ 57r.-,,MTHN.IOTOLL~ i
7"I'lauk SS-R (Tcep
Dol-1:*y aad Sci.
Vol. 74, 775-778: abstr's in Chem. Abstr., 1 Q 5 2 )Vol. -1 2
1228). Htunic. acids. are aromatic hydroV carbojzylic acid-_; h ig h
molecular w6ight. Changes in their molecular stractu-E,
the --radu41 coxification were studLed by X - ray exxmil T)
peaLs and soft coals or different localities, and
0
dized coal (with ratios C:H from 13.2 to 26.8). Th- iater--'erences
'd
are increasingly distinct and sharper with aivancing degroe nC
c0 alif ication and, molecular rearrangement. The hum1c acid ivor.1
co-
il shows thrce maxima which corresNnd to a double
carboi, lattice siiular to that in graphitc. With pyor,,res 3ive
coalification the ordered lattice of the aromatic nuclei- 6f dle
hirriLc acid increases: the dilsordered part appears peripho-ralt owing
to the groups of the molecules. Nic cl,7"i,-es of the ratio C.,!~
as an indicator for increasing conde-.-,-~ation of aromatic ni-,clei.
parallel these diffraction phenomena. 'the. calculated mmrlbo~ of
.3 the nuc cus varies beUwcen 1 and 10 or nore: the proFrCsS3_Ve
~inp
coalifl-cation corresponds to their condensation to increasinp;jy (over)
---------------
21P UP= 1D no
in ChfM. A
OUS X-
-Itqat-d -'-c--
L
P~
rO R! OR
P NON,
NO

KASATCOHM-P V. r.
UM/ruels - Coal, Structure Sep 51
"Certain Problems of Studying the Fine Structure of
Coals," V. I. Kasatochkin
"Iz Ak Nauk SSSR, Otdel Tekh Nauk" No 9,
PP 1321-1334
Presents results of studying fine structure of
coals and their components by X-ray and electron-
microscope methods. Discusses X-ray diffrs~ction
in coals, mol structure of antbracite, metamorphism
Of coals and-their petrographicicomponents, sapro-
pelites and carbonaceous~:substances of combustible
shales, humic acids, and thermal processiAg of
coals, Submitted 21 Apr 51.
205T33

,A
."The X-ray Analysis of the Molecular Structure
Rubber it. 1. 'Kasatocbkin, B. V. lulkimp
SC., Res Inst of Tire Ind
"Iz Ak Nauk SSSR, S6r Fiz" Vol XV wo 2 jF
PV~209-217
Authors lectured on scattering of X-rays in
ai~orphoua caoutchouc, variations in m~)I struc-
ture of caoutchouc under fatigue and vear,
cr~stn of filler vulcanizers of, rubber, and
mol orientati6n of filler vulcanizers of eyn-
thetic rutber. The folloving participated in
LC 187T95
WSR/Physic.a X-ray Analysic, Rubber Mar/Apr.51~
'Contd)
discussiona 'after the lecture: Z. G. Pinsker,
1.:._Kasatocbkin, V. I. Kitaygorodskiy.', N.''S.-
Koitetskaya, V..L. ftrpov~ V. I.1 Danilov.
lecture read at 3d All;.Union. Confei-ence on,
Use of X-rays in Study*of Materials beld 1~~
24 Jun
50 in Leningrad.
187T
95;

It It Is w 11 IS If It If 4
9 1 ~ 7 : I . wt . . w w - - w - -
a m is )i v a )q lid 11 11 It Id a is If w 10 a] at a a 60

AIS LLJ~ 0
tin J_ V V 7- A., AA 90U 114t 0
A

.1 q
2
.
:0 1.1269' APpli,.tl.n of Jnf,.,,,d Abiorplion
-Spirctra t
to 2 .
-Studir-I of 16 0xiditti., of Soclium-fluladiene Rubwr
IS

a .
,
DOR.-Iditin. B. Kmatoclikin, N. Uluzen. and A
_
_
Sudruo,j R
b

: .
-
'
u
b- Ch-AV
'iiu7
T'fc7';01u9V, Sr. 24
July-
5e
i
IMI
591
0 .
.
.
-
.
p
, p
00 1t -~96. (Tranilated from DAIddy Abidemil Nauk SSSR (Rrport~
so el of (lit- Avademy of &,lences of the USSR). Physit A Sprjt~
v
12

o a

- .
,
.
fin. u4s, P. ISIM120.1
so Prevnits a ijualitaliSe and lindled quanilwite unaly%vs tit thow
krolips whit: I originate during oxidation and also in euminatimi
09 j I)f tht. "troctures which determine the vhangv% tit She ph~sival

00 v and divinical prtq)4-rti" in thr reaction of rtiblwr with inott'i. Ida
oitygen.
00
06
041 id
'00 V

too j

is 0111

ASA. A tz
&FIALL01GICAL LITENAT411t CLASSIFICATION

A
- u SS AS

it cit
r;K 911 1, ,,
ntt -Vlzl
14
v4a n I z1A An 1 S A r"
I
0 0 0 0 0 6 o 0
004000000600000100

Ore
0
z , a
'00
400
rife

USATSOM11 V. I.
Wo FM STRUCTURB "I (19vasto Akado Nouk SSSR# Otdol,,
lakh# Nauk (Bulle Aamde Soie U,69349g, Beat* Tedie Saiv), Saptq lp6l. 1521-1534).
Rosults ome &.Ivan of (1) X-Cay oxamination of brOM and bitumincus aaals,
anthra(Ato, schwigito amd gpaphitesp (2) Xorwj and cloatron rdaroscope w=V14nation
of the patrogmphio oonatituanto of coals, antl (3) X-M axwAnation of aMnSes
In molecular and jutemolecular struoture ol~ (mIs duriag tharmel traatm~ntu A
isug;pstlcu Is vade Cor quantitativ-3 eutlwtlon of tba 4agreo or graphitlisation,
J=odiate cource olipping

in "WOM
- -
K*M"Gt14~3C"hkWin "andden. Lukin. 1Wy All". Nawk
VT. 81-4095D.-Tht previously given (C.A. 44,
TJO) Interpretation of th* structurs 04 amorphous rubbo
am ainwiling of 0 Dqu if Ptirl, giving a Iflifthr"es
loss. of the Witted Io=1y U x-ray* " it Nwitiet of the
smitering anglit (due to nest-range order), wsd it dMordeted
gas.(ype part, 6 further corroborated - - of
the amttiring intensity curves W1
th the temp. With ;&;g
temp. (2). so. Is)*), the "Nx. bftvmes I fiatter,
And The Intensity Ire the range of actuall watt 6461"
Intmors. The ctityra iota very strously rtmin t of
NWI's (Phyt. Now. 42. X*9 1043)) curves for ths X-ray
1wattcring InteiLzity of litto at diffevvist it= with e
nutz.disappearingtoutpicteirat210% Ilse sclat
intensity I - 1, + it. whem the becripts f oW i to
so 1C
-gaseous" and the "Nuid" Part , is
1. - PNJI. whae F - structure of
by OAgk Unks of the tual. clialm (dctd. by in
the radiation coherently WAtterW by the atoms at the same
chain Unit). X, - no. of links constitudug the "SIMMUS"
C.iond aP - (I +cost 20)12, where 0 - scattering *ask.
'. 1, 1, of the -liquid" part. detd. by Intatweace
I of the radiatu htiet dy scattered by Unks us neighboring
chains. as given by Debye's theory of scattering is liquids.
Is to Wfifff
OF/J?)dP, whert It' - ProbAbilitY of litishituring dispositim
of links P - mean d., Y
TheaA' and 4FFW#' - rum
of - spicicai ben .1 thkknem dr t a distance r Imm a
given link. In the case of ctmnlaelc divAdef. I,. _ 1.
and I - P-VP, wheff! N - total no. of finkc For high 0.
the IniWal tend& to gem, I I trudi in the i4tx)vr V41ur for
a cant irly disordercd %=-- StAte. Foe *1"411 0,
the integral tend& to ulkity. 1, . L). am(, I m 1g. The
coexistence of the "gas" and the -tiquid" phases in an
oafms7hous polymer is due to the ddrwLdty of close packing
Unki neighboring mol. chains. The Lune cause
andedlei; the Incomplete crystn. of polynwrs. an evidenceel
by x-m7s. IN. Thou
0

2
,
fn Uia rate gtru-,tuze of fmfi cwj in razicaus

t
47.
Till CMCglaCt ld ill.LL. lie
iUcr=4:R- in t"It !1.,,.--,","s f t;" A 4:1)
of a --cries d Doar,.s t.ir 1-si, Gi de.
J
-
c~ophla lztd"t~ Ih.,m.lh of tnA -I-'
a2etamotpUsm. Howavi:r, tmlikc gruph'tc. in t~nti~ramite
-and lesserc"3 the ht-X2gull3l PIR,13r C atom littic" forq-i
do not lineup gJ~Lrlly- It ~C,-
cla,led that tmd,-r tli, .tral --jizzi~- i

y 2Ua Y? ~7~ Vltt'% !--and
scpd.-front coal in varimul incTatnuililik stagCS-S"OVi
that vitra-la vaderg;3cq over-all structure &.wTK%!3
t .(Ml
typkal of ewl chwing carbonizaau. Fisain, mrimnacd b
th- WAY St29CS of MCNMIOTVI'kl~'. Cutlt--UtU Solne One.-I'Ll-
tica in P.--cks a Parallel c;lrb--n !a I t-'-es. 'fhe of
Vom Coal to C~bOnj~tjPn :,~~ JC tj,C Pa7e~..~,'*LiLG the
fonn 4 the structur[j~ Tlmn,~n,- lwmg r%~ e-v -d
eventually to -- ilr-oirt, - "n-ly
lten.~ .~d m-t rhia,!O, al i.11111~

V J. 0
(32
fay lnves~lgatlon nt the "Morph2ur 610;e of rubber V.
ngatzlIL- nud II._Yf_LUkju, i Fj--KftM.--
toiekw?--s- -,i K.,,f. Ify ok~-
ll&rkul. Sordin'lli)-a" 11952, 242-5; ef. C., 1. 47, 1
The tunorphous scattering of rltbl,~r i--Ille to 2 types of dis-
order, one usually found in gxqc%, the other ill liquid:i,
Gases show qcattering curve5 which bicrease strongly to-
Ilards low angles, while liquids show a diffuse ring which
depends oil the av. me]. distance_,;. Xfea~urctncnt of the
amorphous scattering of rubber as a function of tCmp.sho%v5
a strong increase of the "ga,.~Cous- Lytle of scattering with.
temp. Curves of scittering at 20, 80, and 120* are given
and compared with the scattering of diethyl ether (Nnil.
C.A. 27, 1819). Prolonged treatment of rubber tit high
temps. (20 lirs. nt: 100*) causes an increase of 15-207f ill
"liquid" scattering. This is expected, since strong oxida-
tion. takes p!ace all([ leads tostronger interchain inter-action.
It. D. Noether

KASATOCHKIN. V.I.
-1111.
Molecular etructure and properties of b3rd coal. Doklady A:vjd. Nwik
S.S.S.R. 86, 759-62 152, oaaa 5;n)
(CA 47 no.191lO195 153)

or fill-,~d(nial grtmilp-s. Ti~- stlruaurv cif -the
paipw-In it Me gtnxtu:-,il ~L,-

!_'*,~-_,,'_T1'!(s1!FTT,T) V.T.
".rialysis, Vold;,-ulmr
~tethr)~, )f Petr-rminlng the 0r0erir!;.:1. in Polymers"
lukin, Inst of 9"inerals, Acad Sci Us,I-R
V.I. Kasatochkin and P.V. T
2, pp '19-2'3
IZ f~k
Vol 17,
1'ethod' Oil OUL't of intenzitv c," raxira a.-.d of
con'tinuous bacf-?ro!~,n,,~ o--:' Scattered X-rays. Results oC t~,!rt!~ o-P
anci rubber are tabulated. ~-,ece_iveO 17 -'-e b 5 3 -
262T96

--jsi CS r,-,
-!--tjon o*" Co a in A n t i; ra t, e (7
'IFIectrono,,raphic
-aya, runrl
V. T. Kasato"-hlkin, Y"I. Z,Aotorevsk
.".CEC" Sci U
.-erzis,
T Z Ser 7:iz, Vol 17, 1.1o 2, pp 2/~'-20
-k 1. 3
77'
Stul~ie(~. c,-)-mr:,)nents by Interfere-.ce .-,,%t4-e--.-ns. -un(.
)f (!if*1,1.--!-t--*'--)n an(I L~.bnej,.cEj n
CO&IS Mich, as fusain, -an-,- Vjtr~_4 11; and in s cot
"eceived 17 7eb 53,
2621'100

Chemical Abstracts
No. 5
Vol- 48
~inr. 10, 1954
Fuels and Carbonization Products
cban res in coal on hear-treatment. V
~KaF-alocbkiv`and L. L. Razurnova."Dokladv Akad. Nalik
by' heating arg,
~corupfl% is chararteired by lonnation and tile growth of
i(he Oat hexagolial lattices of C. atolus Similar to tile atomic
i'llouOlaYer ill a graphite crystal. Part of t tie C as well as 11,
~0, N, an(I in thebubitanceare elimi-
inate(I as volatile matter. Fortantion and grosvith of the
C lattices call be obst-rved according to the origin and tile
:incr~sing sharpne%i of the interference bands oil the x-ray
photograph--; of tile proOncts carbonized. Tile rn:)I. lattices
under the influence of the vector fi.ld orient themselves
parallel one to the other. Interorientation of the C lattices,
occurring simultaneously with their growth, is shown by the
interference bandq (MI) as vrell as by the change of their
sharpness on the x-ray photograplo. RvIrtion between
temp. and C latticcs iq Faratollow

SHISHOOV, N.A. XAS Maiwil IVA fessor; doktor khimichaskikh nank,
otvetstv(i--,,7Te-di~k-tor-, p L.L., redaktor; 2MTAKOVAq T.A.,
tekhnicheskiy redaktor
[Problems pertaining to the 'structure of silica glass3 Voprosy
struktur7 eilikatnykh stakol. Moskva, Izd-vo Akademli nauk SSSR,
1954. 191 P. (MLRA 80)
(Glass)

0
Ac
tn~
UWRI Chomiatrv - Physical chemistr7
Card 1/1 Pub-.43 50/62
Authors I Kasatochkin.,V.,- I.j Shostakovskiy, M. F.; Zillberbrand, 0. 1.; and
Kochkin, V..A.
Title 41 About hydrogen bonds in.ailanols.
Periodiedl t Izv. AN SSSHR Ser. fiz. 18/6$ 7216428,, Nov-Dee 1954
Abstract I The infrared absorption spectra of trimethylcarbinol and five different
silanols. (CH )ISiOHO CAS'OHi C. z (C H ) SiOH and
a~(C H )SiOH
C6H, (C2H;)2S'QA were ~nves iiated in a r ge 0~ wavesle;gVof from 2 - 4
to (ieterffiine the nature of molecular association of silanola and the effect
of the Si-atom on the hydroxyl group. It was established, among othersi
that the chem. properties of silanols, particular2,v their amphoteric pro-
perties, are due to the strengthening of the O-H bond and strong reaetion
between the oxygen and hydrogen of the neighboring molecules which takes
place as result of increased polarity of the O-H bond. Graphs.
institution Acad. of So., USSR, Institute of Combustible KineralB
Submitted s

The SubmicrosciopL, ~tructnra,)f coal V. 1. Kasatojiffa,
$hlyapnikuv, =a L. 13-
A 14. liauk 3,S.S.P. 96, &17-e(.1064); cl, C.A. 47,1
119374.-Thi structure of coal was itudieA widi an. clectrom
i Inicrosrope. It vias oblerved that In photographs of tht rcp--~
Jim of natural Cate them Ware tr2cti of bubbles of different t
sizes, vibereas the (a bubbta for coal wgre of miNnu alte,
This Feet could be tataprelt(d frolu the point of view af the.
equality of the rates of repl3cement of. vs bubbles aud yield;
of Ps by diffusion through Oe co--l in the slow proces3 of ras
formation dudng metamorphLan. Thus, the stzt~3 of the
fiiiiiial6i wext detit. atla of the,rates of diffusi= aud,
-by the r
pa'fermation andi thereftnt-, deptMcd an the-ii,%fute-of the'
Le rate of gas fann,
eval end on factors dttg. C ation. Often'
It was found that that wtse fine, Individual particli's,
huiag 0 the replica. It fii possible that they actually are'
soot particles ar-d that their , , is connected with fires
occuning during the early bZ---1-nf formation ca the coal

rASAPOMMN, V.I.; SHOSTAMVSKIY, M.F.; ZILIHIMERAND, 0.1.; EDCHKIN, D.A.
-
Hydrogen I .intage in silanols. Zbur.fls*khljm9 29 no.4:730-733 Ap 155.
OWU 8:8)
1. Akademlya nauk SM, Institat orgmdchaskojr Wait.
(Silanol)

of Is ressareg oa the molecular structure d
Ah's effect
Ifiramlaous A L. !Wumova. V. 1. Kasaroch;dn
and M. P.-Volatovich. Dokkdy A key,
103,1033~4 IM).,~-X-my invcstigaWs of caml subitetWt
torn Te to prusures of 20.000 L-9.1sq, em. showed
thA the Unidifted(914i C(XUPrCSShIn Cfutles It rC0fiCAt(Atl0`I
at the at. C lattice, with a preferrM dLit'ib ti t of 0 Ir
normals in, (lie difixtim of the active pte-Im
ctusion was drawn that the vitrified =is2
coal of medium vn~tamorplsic st-iges N catkverted ta a liquid-
flaw Systeux Und" tuessure, $4111&r to it% state when licatcd,
The commion to the liquid state 6 contweted with the
destruction of skle chains, which explaimo the mse of rota-
tion 9f the LAttice the formation of uniAArupy undu
W. IM. SterijbIA&A

V,
USSR / Physical Chemistry. Crystals. B-5
-Abs Jzur : Ref Zhur - Khimiya, No B. 195T, 25998
Author : V.I. Kasatochkin, 0.1. Zillberbrand
Title : Roentge'fiogra~hy'and Infrared Spectroscapy in Application to
Stuctr of Structure of Humus Substances.
Orig Pub : Pochvovedeniye, 1956, No 5, 80 - 85
Abstract : Theairves of absorption in the infrared spectrum range in wave
length intervals of 2.8 to 3-9, 5.7 to 6.8 and 7.8 to 11.31&
are given for humic acids of bl,-7r-k earth and stronay podzol
soil, fulvoacids from the same soils, and humic acids from
the culture of Aspergillus 'Niger. The bonds were
detected; 0-H and C-H in aromatic groups (C-H bonds were ab-
sent in fulvo-acids of strongly podzol soil), C-11 in CH groups,
a weak intensity band of C-H in CH3 groups., C-J) in carboxyl
groups, and conjugate double bonds G=C. The intensity ratio
of the bands C=O and C=C is characteristic of various samples.
Card 1/2

USSR Physical Chemistry. Crystals. B-5
Abs Jour : Ref Zhur - Khimiya., No 8, 1957., 25998
Abstract : There is in the spectra of humic acids of the strongly pod-
zol soil and of both the samples of fulvoacids a band of 6.�,k
referred to aromatic groups with lateral alifatic substitutes.
In the cases of humic acids from Aspergillus Niger, a band
of 8.04,L is observed; this band is characteristic of o#gen
containing aromatic compounds, in which the 0 atom is direc-
tly connected with the C atom of the aromatic nucleus (Bre-
ger J.A., Fuel, 1951, 30) 204 - 208). These results do not
contradict the known data of x-ray studies of the molecular
structure of humic acids and similar carbonized substances.
Card 2/2

15-57-5-6649
Translation from: Referativnyy zhurnal, Geologiya, 1957, Nr 5,
Pp 137-138 (USSR)
AUTHOR: Kasatochkin, V. I.
TITLE: X-Ray and Electron-Microscopic Examination of Coal
at Various Degrees of Metamorphism (Rentgenografi-
cheskoye i elektronnomikroskopicheskoye issledovaniye
kamennykh ugley raznykh stadiy metamorfizma)
PERIODICAL: Tr~ Labor. geol. uglya. AN 333R, 1956, Nr 6, PP 150-
155
ABSTRACT: X-ray examination of petrographic coal components has
shown that the development of carbon in metamorphism
occurs in the form of flat lattices or a two-
dimensional crystalline lattice. The dimensions and
form of the lattice may be determined from the X-ray.
Metamorphism of the vitrainized substance contributes
Card 1/3 most to the development of the crystalline lattice;

15-57-5-6649
X-Ray and Electron-Microscopic Examination of Coal (Cont.)
the fusain changes little in form. The crystalline lattice develops
somewhat more slowly in the structured elements than in the vitrain-
ized substance. The process of carbonization of the substance may
be characterized as a two-dimensional crystallization; the final
stage of the latter is the formation of the anthracite structure.
The transition to the three-dimensional lattice of graphite occurs
abruptly. Formation of two-dimensional crystals is characteristic
only for caustic bioliths of the humus series; the beginning of the
formation of the nuclei of the crystalline lattice must be considered
the beginning of carbonization. X-ray structural analysis of ori-
ented specimens has shown that two-dimensional crystalline lattices
are located along the plane of stratification. When coal dust is
subjected to high pressure, the crystalline lattices of two-
dimensional crystals take up a specific orientation after several
minutes. The anisotropy which develops differs in various coals.
Coal magnified 50 000 times under electron microscope appears as a
spong mass with small round pores. Orientation of the two-
Car ~/3

Ii T 0
Category: USSR / Physical Chemistry - Crystals B-5
Abs Jour: Referat Zhur-Nximiya,, No 9,, 1957, 29789
Author Kasatochkin V. I.) Fazumova L. L.
Inst A_a~5"ciences USSR
Title X-Fay Analysis of Molecular Structure of Coal and Coke
Orig Pub: Izv. AN SSSR. Ser. fiz.., 1956, 20, No 7, 751-754
Abstract: On the basis of the concepts of macromolecul" structure of carbo-
naceous matter of coal and coke, the interference function of x-ray
scattering is expressed depending upon probability of orderly packing
of W network of the C atoms which constitute the scattering units.
Widening of the 002 interference band on the roentgenogram, taken
as index of inter-reticular orderliness, is determined by magnitude
of W, dimension of coherent volumes. The r'/-j efLuves of
coke, obtained as a result of integral wuUysis of intensity curves,
are interpreted as the result of superposition of 4~-D r,5- 4 _?
functions of the different structural forms of C in coke -- of car-
bon networks and chains. fte difference in 4 -, r curves
Card 1/2 -57-
------------------ --------------------- ----_---_---------------I--------------------------------- ----------
%J%N%Z. , - ; - ;i:~i -58-

KAUTOCHKIN, V.I.; YUROVSKIY, A,Z,; SHUBNIMV, A,K.
To P.F.Andreev's review of the book of S.M.Grigorley wFormation
processes aM properties of mineral fuels.P Zhur,,priklekhim*29
ito.2:315-317 :r 156. (MM 9:6)
(Coal) (Petrole=) (Grigorlev, S.MJ (Andreav, P.Tj

1e -

~': F,
I : :

'
PRIK 00T
K0,
pun I swx amorTniox say/n.,s,5

LIvoy. UnIveraytat

Materlaly X Vaoscyuznogo nov*ahchanlya po opelctroakopil. t. Is
molekulyarnaya speottroonpiya (Papers of the loth All-Vaign
Confamnca on Speotr,3nccp7. Vol. It Molecular Spectroscopy)
jL'Vov) 1zd-v* Ltvoyakogo urdT-ta, 1957. 499 p. 4.000 copies
printed. (Seriess Itas nzychayy sbi mk, vyp~ 3/8/)
Additional Sponsoring Agency: Akadealys. nauk SSSR. Xosda3lya po
ape
ktroakopil. FA.t Oazor, S.L.1 Tech. *i.j Saranyuk, T.V.j
Editorial Board4 Lwvlstarg, O.S., Aaada=dian (Reap. Ed., Daddagod),
Reporent, B.S., Doctor of Physical and Kathematleal Sciences,
Paballnskiy, I.L., Doctor of Physical and Mathematical Sciences,
V.A., Doctor of Physical and Mathematical Sciences#
V.O., Candidate of Tsobnloal Sciences, RAyakiy, S.M..
K=
f Physical and Mathematical Sciences, Xlimovskiy, L.K..
Candidate of Physical and M&f.-Atezatical Sciences, Miliyanchuk, V.3.,
Candidate of Ph7sloal &--4 Whematical Sciences and Glauborman,
A. Ys., Candidate of Physical " ftthazatical Manage.
Card 1/30

Busay, P.M. SpeatrophOtonotriG Study of the YAahwdsm
am xinetion of the interaction of Congentrated
Sulfurio Acid With Diphanrl Amineffi And With Scale
Of its Derivatives 945
Tqaroj* H,B, Infrared Emission Spectra or certain
72AM. And Coubustlor~xon~ Products 252
guanstsova Hq?. Sow Speatmi Studies in the field
of the Alatory or Goooheadstry W in the Gonatio

Classification or Bitumens 255

'
Ultberbrand, 0.1., and V. use of
~
Challoal.
-
M%rrared Speatrozoop, the study

Structure of Shale xerogGI2 257
Xseat V.I., o.I. M,berbrwid. and A.A. Shubla.
spestra, of organie Mineral

Substances 261
Card IT/30

AIJRAMOV, S!K-., kand.tokb'n.nnuk; AVERSHIII, S.G., prof., doktor tekhn.nauk;
AMMOSOV. I.Z., do)-tor get)l.-min.nauk; A)IDRIY3VSKIY, V.D., inzh.;
ANTROPOV. A.N., InTIL.; AFAIIASIYEEV, B.1., Inzho; B72EGHAII, Ya.V.,
inzh.; BLOUU. Ye.Ye.. irith.; BOGAGULTA, Ye.U.. inzh.; BUKRINSKIY.Y.A..
kand.tekhn.nauk; VASILI)C;W, P.V., doktor geol.-min.nauk; VIHOGRADOVI,
B.G., inzh.; GOLUBET, S.A., iilzh.; GORDIYEIIKO, P.D., inzh.; GUSEV, N.A.,
kand.tekhn.nauk; DORO13(0. 1.V., kand.geol.-min.nauk; KALMIXOV, G.S..
khtm.nauk; KOROLEV, I.V., Inzh.,
inzh.; AM
KOSTLIVTSEV. A.A., inzh.; YJUiTKOVSKIY, L.Y., lnzhA; WSHRIINNIKOV, G.P.,
prof 0 doktor geol.-min.muk; IMIKUIIOV, L.A., inzh.; LEVIT, D.Te., Insh't;
LISITSA, I.G., )mnd.toklai.nauk; WSHIIIKOV, V.A., inzh.,- HATVB'YEV, A.K.,
dote., kand.geol.-ml.n.navk; HFJWISHVILI, G.Ye.. 12nh.; MIRONOV, X.V.,
inzh.; MOLCHAMOV. I.1., iznh..- 110140VA, S.N., starshiy nauchnyy sotmdaik;
]WIPHLOV, V.Ye., irah., PAVLOV. F.F., doktor tekhn.rLauk; PANMOV, P.M.,
doktor geol.-mln.nark; POPOV, V.S., inzh.; PYATLIN, M.P., kand.tekha.
nauk; RASHKOVSM, Ya.U., inzh.; ROHANOV, V.A., prof., doktor tekhn.
nauk; RYZHOV. P.A., prof., dok-tor tekhn.nauk; SELYATITSKIY, G.A.. inxh.;
SPERANSKIY, M.A., inzli.; TERENTlYLY, Ye.V., inzh.; TITOV, X.G.,doktor
kbim.nauk; GOXAREV, I.F., inzh.; TROYANSKIY, S-V.. prof.i doktor geol.-
min.nauk; FIMOROV, B.D., dote., kand.tekhn.nsuk;FED0R0V" V.S., insh.
[deceased]; KHCHENrOVSKIY. A.S.. prof., doktor geole-minonauk; TROYAMOV-
SKIY, S.Y.. otvetatvetiDyy red.; TERFIGORLY, A.M., red.; KRIKUHCV. L.A.,
red.; KUZIMTSOV, I.A., red.; MIRONCY, K.V., red.; AVERSHIN, S.G., red.;
BURTSEV. M.P., red.; VASILIYIY. P.V., red.; MOLCHANOV, I.Is, red*;
RYZHOV, P.A., red.; BALANDIN. V.V., inzb., red.; BLOICH, I.M., land.
tekhn.nauk, red.; BUICRIIISKIY, V.A., kancl.telehn.na-uki red.; VOLKOV, K.Yu.,
lnzh., red.; VCRCiB'YFV. A.A., lnzh., red.; ZVONAREV, K.A., prof. doktor
tekhn.nauk. red. ICnntinimil nn nqr4- etmv-ti)
F """ 7 P77Z 7

ABRAHOV, (continued) C& rd 2.
ZDANOVICH, V.G.,.prof.,r-oktor takhn.nauk,red.; IVAITOV, G.A., doktor
geole-minanaukp red.; YJOWAYET. N.M., red.; KOROTKOV, G.V., kand.geol.-
min.nauk. redo; KOROTKOV, N.Y., kand.tekhn.neuk. red.; KAKKAVEYEV. A.A..
doktor geolo-min.nauk, red.; OMELICIWKO, A.U.,kand.tekhu.nauk,red.;
SENDERZON, E.H.,kand.geo!.-min.nauko red.; USHAKOV, I.N.. dote., Imiad.
tekhn.nauk, redo; YABIA)YOV, V.S., kandogeol.-mintnauk,red.; XOROLNVA,
T.I., red.igd-va; ""LKINA, redoizd-va; FROZOROVSKAYA, F.L,,
tekhn.red.; NADEINSKAYA, A.A., tekhn.red.
[Mining; an encyclopedia frindbook] Gornoe delo; entsiklopedicheskii
apravochniko Glav. red. A.M.Terpirorev. Moskva, Gooonauchno-tokha.
izd-vo lit-ry po ugollnoi procTshl. Vol.2. [Geology of coal deposits
and BurveyAng] Geologite ugolInykh mestor-ozbdenii i marksheiderskee
delo, Redkolegiia tomo S.V.Troianskly, 1957. 646 p. (MIRA 11:5)
1. Chlen-korreB ondent All SSEM (for Kerave5ev)
Mal geolot7-Dictionaries
m

Use of infrared spectroscopy in studying the chemical structure
of kerogen In shale, Flis, obor, W.3;257-261 157, (HIU 11:8)
1,',Iustitut goryuchikh iskopayevVI& AN SSSR.
(reroden-Speatra) (Chemical structure)

68-6-'//19
AUTHOR: Zamoluyev, V.K., Candidate of Technical Sciences, and
Kasatochkin, V.I._, Doctor of Chemical Sciences.
TITLE: Changes.-of the Coefficient of Temperature Conductivity of
Coals during Isothermal Decomposition. (Izmeneiye koeff-
itdyerita temperaturoprovodnosti kamennykh ugley pri izo-
termicheskom razlozhenii)
PERIODICAL: Koks i Khimiyaj lqc~
17, Ao.6, pp. 21 - 23 (USSR)
ABSTRACT: A study of temperature conductivity of Donets coals of
the A, K and VIC types at various stages of isothermgl decom-
position at various temperatures (400, 500 and ?00 C) was
carried out. Vitrile component of the above coals separated
in heavy liquids (properties Table 1) was taken for the inve-
stigation. The experimental results are given in Table 2 and
a-diagram. It is concluded that changes in-the coefficient
of temperature conductivity depend on the type of coal, temp-
eratiire and time of decomposition under isothermal conditions.
For coal types K and 11C, a sharp decrease of the coefficient
is observed during the transition of coal into the plastic
state. Time of the transition of various coals into the
plastic state is different; therefore, there is a possibility
of increasing the coefficient of temperature conductivity of
Oard 1/2coal blends by a suitable choice of their componentse

68-6-?/19
Changes of the Coefficient of Temperature Conductivity of
Coals during Isothermal Decomposition.
.- There are 2 tables, 1 figure and I/ Slavic references.
ASSOCIATION: Institute of Mineral Fuels of the Academy of Sciences
of the USSR. (Institut Goryuchikh Uskopgemykh AN SSSR)
AVAILABLB: Library of Congress
Uard 2/2

USSR /Soil Science. Biology of Soils
-Abe Jour : Ref, Zhur - Bioloeiya, No 17, 1958, No. 774oo
Author : lapina, N. K. - Mtn LtQ2hgAL_yj_j..__,
Inst :Institute of Fuel Reserves AS USSR
Title :Ion Exchange and the Structure of Humic Acids
Orig Pub :Poohvovedeniye, 1957, No 91 28-32
Abstract ;Investigation of the IE absorption spectra of humic acids
and hmiatos of Na, Ca and Ba that vere separated from
different coals confirmed the molecular mechanism of im
exchange in the alkaline solutions of humates. AllmUne,
humates are genuine molecular solutions which oonsist
of individual aromatic lattices with lateral. radicals which
carry cart*Vlic groups In ion forme With the formation
of Ba- or Ca-humates, an erobange reaction with Na or H
takes p1we; the formation is possible of complexes of two
and more molecules of humic acids connected through a cation:
Card 1/2
24
7, ;7,
R

A)l
. -- 1 24-11-31/31
AUTHORS: Zamoluyev, V. K. and Kasatochkin, V.I. (Moscow)
TITLE: Coefficient of temperature coau'ctivity~of hard coal at
various stages of isothermal decomposition. (Koeffitsiyent
temperaturoprovodnosti kamennykh ugley na raznykh
stadi-yakh izotermicheskogo razlozheniya).
PERIODICAL: Izvestiya Akademii Nauk SSSR, Otdeleniye TekbWch skilrb
Nauk, 1957, No.11, pp. 199-200 (USSR)
ABSTRACT: Results are described of the study of changes in the
coefficient of temperature conductivity of five grades of
Donets coal, the data of which are given in a Tablel as
a function of the degree of isothermal decomposition at
various temperatures. The tests ware carried out with
coal after decomposition in heavy liquids. The isothermal
decomposition of the coal was effected in a quartz
tubular furnace inside a stream of purified nitrogen
at the temperatures 400, 500 and 700uC. After various
heating times in the furnace, the coefficient of 0
temperature conductivity was determined at 20 to 40 C
according to the method of the regular thermal regime
proposed by G. M. Kondratev and the author of this paper
and perfected for investigating relatively small samples
Card 1/2(Refs.112), The results are given in the form of a

h-fi 6-AT-C, -C i6
AUTHORs KASATOCHKIN,V.1., SMKjKA,Z.S. 20-6-36159
TITLEs The iia"I-Ve~compoaition.Kinetics and Structure Transformations of
Fossil Coals. (Kinetika termicheskogo razlozheniya i strukturnyye
prevrashcheniya iskopayemykh ugley, Russian)
PERIODICAL: Doklady Akademii Nauk SSSR, 1957, Vol 113, Nr 6, pp 1314-1317
O.S.S.R.)
ABSTRLCTr The thermal decomposition of fossil coals shows a series of character-
istic features which can be brought into connexion with the chemical
structure of their organic subst&nce. The coal substance combines
in its structure a relatively inactive core (carbon nets) with a
reactive, peripherio part (lateral radical).-By this the usually
observed two stages-of the-primary and secondary decompositionj
which differ considerably from each other, can be explained. In the
case of the fire't, which develops comparatively quickly at a low
temperature, the main mass of the volatile substances is separated
chiefly by the destruction of the lateral radical. Chemical modi-
fications of the core of the structure begin at a'later stage of the
secondary decomposition. Thus, the carbon nets of the initial coal
substance remain in the solid product (coke). They form centers
of a bidimensional carbon crystallization in the process of carbon-
ization of the organic coal substance. Structural transformations
Card 1/3 of the coal substance were investigated by means of radiographic
Card 2/5
e_m_p_GTatur6_*__
depends on the metamorphism stage of the coal and on t
The observed rapid rise of activation energy in dependence on 6
for low decomposition temperatures might be assumed to be con-
neotted with the selectivity Of the process of the primary destruc-
tion of the coal substance. A radiographic investigation of the
structural transformations of the coal substance during thermal
decomposition was carried out in a series of solid residues n of
coke coal which originated from the aforementioned experime ts
The observed changes are connected with the primary decomposition
of the lateral radical and elimination of structural units. The
obtained mobility they enaeavor, on the occasion of trans~-
ition to the liquid-flowing state, to reach a position parallel
to each other under the influence of the molecular field of forces.
The infrared absorption spectra of the solid residues characterize
essential modifications in the atomic groupings of the coal sub-
stance. The regular modifications of the position and of the
intensity of the absorption strips according to the grade of de-
composition indicate a relatively lower thermal stability of the
aromatic simple ethers compared to the aliphatic and cyclical
simple ethers. (3 illustrations, 4 Slavic references)
ASSOCIATION:
PRESENTED BYs
SUBMITTEDt
AVAILABLEz
Card 3/3
Institute for Combustible
Science of the U.S.S.R.
V.A.KARGIN, Member of the
21-11-1950'
Library of Congress
Fossil SUbBtances of the Academy of
Academy

i) s nT CC N )