SCIENTIFIC ABSTRACT ISACHENKOV, Y. - ISAGULYESIA, V.
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Collection:
Document Number (FOIA) /ESDN (CREST):
CIA-RDP86-00513R000618810008-9
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RIF
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S
Document Page Count:
100
Document Creation Date:
November 2, 2016
Document Release Date:
July 12, 2001
Sequence Number:
8
Case Number:
Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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WTI! -1111~~11 ------
ISACHENK07,Y-F. I., PIKWOVNIKOV, R. V.
Deformations (Mechanics)
"'Effect of the speed of deformation on the process of stam-ping parts from steel sheet.',
Vest. mash. 32 no. 5, 1952.
9. 'Monthly List of Russian Accessions. Library of Congress, October 19536 Unclassified.
2
ISAGINNKOV~ Yeygeniy jvenoyt,,U, ksncl.tekhn.nauk; SVMWV. H.I.j kand.tekhn.
--04-WW", -r 64 i'j hi- 2'4'f &NOVSKlY, V.P., dots&, kand.tekhn*rAUk'
reda~t*or; KAPT IISKIY, Ye.F., redaktor izd-ve; SOKOLOVA, L.T.,
teldin.red.
Ellew extrusion methods] Novye sposoby shtampovki-vytiazhki. Pod
obshchei red. V.P.Romnovskogo. Moskva, Gos.nsuchno-tekbn.izd-'wo
mehinostrolt.lit-rY. 1955. 50 P. (Bibliotechts shtampovshchits,
no.4) (Xxtrusion process) (MIRA 11:2)
AUiHOR: solozonov, M. SOV/24-58-4-36/39
TITIZ: Application of Technological IA.,briicants and Special
Coatings During Shaping of Metals by Applying Pressure
(Primeneni,ye tekhnologicheskikh smazok i s etsiallnvkh
pokrytiy pri obrabotke metallov davleniyeZ
Conference at tne Institute for Mechanical Engineering
of the Ac.Sc. USSR (Soveshchaniye v Institute mashino-
vedeniya Akademii nauk SSSR)
PERIODICAL: Izvestiya Akademii Kauk SSSR, Otdeleniye Tekhnicheskikh
Nauk, 1958, Nr 4, P 153 (USSR)
ABSTRACT: The conference was held in December, 195?. The following
papers were read: "General Relations and the Mechanism of
Operation of Lubricants During Shaping of Metals by
Applying Pressure" by V.I. Likhtman, S.Ya. Veyler
(Institut fizicheskoy khimii AN SSSR - Institute of
Physical Chemistry of the Ac.Se.USSR); "Applicat lon of
Principles of the Hydrodynamic Theory to the Proce'ss of
Cold Stamping" by Te.I. Isachenkov (NIAT); "New Stamping
Ltibricants for Deep__a_n_UPirtre-al&i,1y for Very Deep
Drawing of Components made of Sheet Steel" by M.A.
Silltsova (Gorlkovskiy avtozavod - Gorlkiy Automobile
Works); "Lubricants for Stamping Sheet of Steel and of
Cardl/4 Various Alloysn by Yu.P. Davydov (VIAM);
SOV/24-58-4-36/39
Ap~lication of Technological Lubricants and Special Coatings
During Shaping of Metals by Applying Pressure
Conference at the Institutefor Nechanicial Engineering of t .he
Ac.Se.USSR
'New Lubricants for Wire Drawing" by A.G. Smirnova
(TsNIICbNR1FBT); "In7estigation of Technological .
Lubricants Applied for Hot Stamping of Metal Components*
by S.A. Dovnar (Minskiy Politekhnicheskiy institut im.
I.V. Stalina - Minsk Polytechnical Institute imeni -
I.V. Stalin); "Investigation and Testing of Certain,
Technological Lubricants and Methods of Applying these
on the Dies of Pressos During Hot Stamping of Aluminium
Alloysn by B.M. Shor (TaNIITfWh); "Lubricants Used.in
Shaping of Metal by Pressure" by Ye-B. 7.huravskiy
(Aviatsionnyy zavod - Aviation Works). The data
given in the individual papers show the increasing use
of liquid, paste and solid technological lubricants
and special coatings in highly efficient-processes:of
shaping metals by applying pressure in the production
of complicated components from various heavy and light
non-ferrous alloys. The undertakings of the chemical
Card2/4 and the oil industries have so far not organised the
SOV/24-58-4-36/39
Application of Technological Lubricants and Special Coatings
During,Shaping of Metals by Applying Pressure
Conference at the Institute for Mechanical Engineering of the
Ac.Sc.USSR
production of the appropriate lubricants and the
instrument industry does not produce instruments for
determining the main parameters of these lubricants.
So far, investigations by individual institutes of the
Ac.8e.USSR on technological lubricants have not been
carried out on a sufficiently large scale and have not
been adequately cc--ordinated. The same ~applies to
other institutes.
S. Ya. Veyler (Institut fizicheskoy khimii AN SSSR -
Institute of Physical Chemistry of the Ac.Sc.SSSR)t
reported on work in the field of lubricants for cold
stamping. Since the result of this work is little known,
it was proposed to devote to it a specially convened:
extended semins at the Institute of Mechanical Engineering
of the Ac.8c.USSR.
Co-ordination was urged of the research work in the use
of lubricants for shaping of metals by pressure and this
Car d3/4
SOV/24-58-4-36/39
A~plfcation of Technological Lubricants and Special Coatings
During Shaping of Metals by Applying Pressure
Conference at the Institute for Mechanical Engineering of the
Ac.Sc.USSR
task should be undertaken by the Laboratoriya obrabotki
metallov davleniyem Instituta mashinovedeniya AN SSSR
(Laboratory for Shaping of Metals by Pressure of the
Institute of Mechanical Engineering of the Ac.Sc.USSR).
The importance was pointed out of putting onto the
market instruments for determining the main parameters.
of lubricants and also of automatic'equipment for coating
dies with technological lubricants. It is necessary to
work out standard specifications for technological .
lubricants and also recipes and methods of analysisof
such lubricants and to increase the manufacture by the
industry of standard technological lubricants. At
regular intervals, symposia should be published on
technological lubricants and special coatings used in
the shaping of metals by applying pressure.
Card 4/4
25(1,5) PHASE I BOOK EXPLOITATION SOV/2294
Moscow. Dom nauchno-tekhnicheskoy propagandy Imeni FeE. Dzerzhinskogo
Novoye v tekhnologil vysokoproizvoditellnoy listovoy shtampovki;
sbornik trudov konferentsii (New JF~eatur'es In the Methods of
High-productivity Sheet Metal Stampingj Collection of Confer-
ence Transactions) Moscow, MashgIz. 1959* 228 p. 8,000
copies printed*
Sponsoring Agency3 Obahohestvo po rapprostraneniyu politicheskikh i
'nauchnykh znan:Ly RSFSR9
Resp. Ed,: V,Te Meshcherin, Doctor of Technical Sciences, Professor;
Eds*: V9D* Golovlev, Candidate of Technical Sciences, Docent, and
Ye#Ne Lanskoy, Candidate of Technical Sciences, Docent; Ed, of
Publishing Houses GoNo Sokolev; Teche Bd*i B*I* Model';
Managing Ed* for Literature on Heavy Machine Building (Mashgiz):
S.'ra. Golovin, Engineer.
PURPOSE: This collection of papers is intended for engineers and
tedhnialans in sheet metal stampinge It may also be useful to
card 1A
New Features (Cont.~) . SOV/2294
students of vuzes and tekhnikumse
COVERAGE: This collection deals with the design and features of
some current problems in sheet metal stamping& Also discussed
are processing methods still in the experimental stage. Several
articles deal with the mechanization and automation of stamping
processes and describe recently developed methods, such as
explosion forming, the use of automatic rotary transfer lines,
and press blocking with the use of radioactive is,ot 'opes. No
personalities are mentioned* References follow several of
the articles.
TABLE OF CONTENTS:
Preface 3
Meshcherin, V*To,[Doator of Technical Sciences, Professor,
Stankoinstrumental"hyy institut, Moskva (Moscow Machine Tool
and Instrument Institute]. Basic Manufacturing Problems of
the Hear Future .5
,. 1. IX -4i
Card 2/9
New Features (Cont.)
SOV/2294
The author discusses labor productivity, shapes of work-
pieces, the materials used, stamping operations and techni-
que, production lines, working speed, and the correct meaning
of basic operational times
Pikhtovnikov, R.V. [Doctor of Technical Sciences, Professor,
Khar,kovskiy aviatsionnyy institut(Kharlkov Aircraft Institute)].
Use of an Explosive Wave for Drawing and Forming Medium and
Large Parts in Small-scale Production 22
The author discusses experimental fabrication of shallow
dish-type parts of an explosive wave caused by gunpowder,
gasoline, or natural gas.
Koshkin, L.N. [Candidate of Technical Sciences]. New
Possitilities in the Development of Sheet Metal Stamping
in Connection With the Use of Automatic Rotary Transfer
Machines 31
Mechanical and hydraulic rotary transfer machines are
described. The flexibility of these machines allows
facility of control, inclusion of chemical and heat treat-
ment in the process, and smooth transition into fully auto-
niatic lines.
Card 3/9
New Features (Cont.)
SOV/2294
Freydlin, A.Ya- (Candidate of Technical Sciences,
Gorlkovskiy avtozavad (Gor,kiy Motor Vehicle Plant)].
Problem of Increasing the Number of Strokes on Presses 2~9
The influence of the speed of deformation on properties
of.metals is mentioned, and the effect of the working
speed on the behavior of metals during cutting and forming
operations is discussed. Information on the characteristics
and design of different types of presses Is presented.
_L~ ~~, (Candidate of Technical Sciences].
Bages-for Zelection of Lubricahts for High-productivity
Sheet Metal Forming 67
The influence of friction forces on the course of the
forming process is explained. Distribution of stresses
and, its relation to lubrication is described. The use of
hydrodynamic (wedge film] lubrication is discussed;
formulas for forces and stresses in the drawing process
are derived; and the effect of temperature increases on
the viscosity of lubricants is treated.
Card 4A
New Features (Cont.)
SOV/2294
Gorbunov, M.N. (Candidate of Technical ~5ciences, Docent,
Aviatsionno-tekhnologicheskiy institut, Moskva~-(Novcow
Aviation Technology Institute)]. $ignificance of Local
Heating of Blanks In Ipereasing the Productivity of Sheet
Metal Stamping
Distribution of stresses and temperatures during local
hea:ting in the deformed zone of tabular workpieces is
analyzed. Formulasare presented.
Solovtzov, S.S. (Engineer, Zavod imeni Sema3hkoMoBkva
(Moscow Plant imani Semashko)). Significance of Tubular
Blanks and Local Preheating in Reducing Main-hours in
Forming Operations 106
-Advantages of using tubular blanks in making thin-
walled shell-type parts by reducing and bulging
operations are discussed. Local preheating for bulging
is accomplished by heating the punch*, -Special features
and the Effl-ciency of this method are also discussed.
Mikhalenko, F.F., [Candidate of Technical Sciences, Docent,
Card 5/9
New Features (Cont.)
SOV/2294
Politekhnicheskiy institut, g. Gor,kiy (Gor'kiy Poly-
technical Institute)). Special Features of Blanking With
an Increased Numbt~r of Strokes 131
The author describes research done on this nrocess in
the cold-stamping department'of the "Trud" plant and
the laboratory of the Department of Machinery - and Metal
Forming, GPI imeni A.A* Zhdanov. A.A. Samoylov, depart-
ment head, and N.S. Gilevich, process engineer, took part
in the investigations made at the "Trud" Plant, and
K.V. Semenov, Candidate of Technical Sciences, parti-
cipated in the work done at GPI. The article describes
changes in punch and die dimensions and clearances in
relation to changes in the number df-stroke's'per minute
and-the number of parts cut out. dptimum clearances,
nd.nimum resistances, bunching forces and energy consumpL
fion at various working speeds are discussed.
Card 6/9
New Features (Cont.)
SOV/2294
Artes, A.E. [Engineer, Moscow Machine Tool and Instrument
Institute]. Press Blocking With the Use of Radioactive
Isotopes 148
The article presents information an the use of beta-
radiation to stop presses in processes where two or 'more
blanks are being fed, and on the principle of operation
and the description of a beta-ray electronic relay-
Suggestions for placing the emitter and receiver are
given, and safety measures are discussed.
Artem'yev, S.I. lEngineer, Goikiy Motor Vehicle Plant).
New Features in the Automation of Sheet Motal Stamping at
the GoAiy Motor Vehicle Plant 160
The article discusses devices for automatic removal of
formed parts from the press, devices for automatic feed-
ing of sheet metal into the die, and devices for complete
automation of the forming process.
Card 7/9
New Features (Cont4) SOV/2294
Nikblayev,-V.V., And-%'-V-* Sore-kin (Avtozavdd ivii6ni
OW 'Vehl
Likhacheva,:MoskvA '(M66~,~-,-:Ikotb*w *I-w-Plant imoni'Likha-
chev Experience of 'the Motor Vehicle Plant imeni
Likhachev ''with High-prodilict~iVity'~Progres4ive''Di6l: Sets. 169
Compound,, coinbinat:L6n:,,Ahd- progressive die~sets with
rectilinear and eircuilar'f6edink-'m~otion,of'blanks, are
described. Mechanization of feeding and removal of
.stamped parts-an&-ickap:tArei discussed-.'*
Filina, - I. S. Erkginee~-k, - Z a-vod "Krasnaya Zairya ",'Leningrad
(1~~iugrad: PRed' Sunrise` Plant,) Transfer Machine f or
Mixing Contact Springs 199
Arrangenient-and-6peration, of imiversal:transfei.
machine:for making springs for-flat'relays iiAesctibed.
Reductibnsin costs, time, tnd.-man-hours are iftown.-
Card 8/9
PHASE I BOOK EXPWITATION sov/4961
kkademiya nank SSSR. Institut mashinovedeniya
Tekhnologicheskiy s=zki dlya obrabotki metallov davleniyem (Industrial Lubri-
cants Used in Pressworldng of Metals) Moscow, ftshgiz, 1960. 96 P. 5POOO
copies printed.
Sponsoring Agency: Institut duhinovedeniya Akadezii nauk SSSR.
Ed.: A. V. Korolev, Candidate of Technical Sciences; Ed. of Pablishing House:
G. N. Soboleva; Tech. Ed.: L. P. Gordeyeva; Managing Ed. for Literature on
Heavy Machine Building: S. Ya. Golovin., Engineer.
PURPOSE: This collection of articles is intended for scientific and technical
pers6nrkl., production engineers.. and students in schools of higher technical
education and teklinila
COVM=e. The book contains articles analyzing the researchon industrial
lubricants used in pressworking of metals conducted by various institutes and
plant laboratories. It is stated that these lubricants improve the metal-
forming process and increase the wear resistance of tools (dies), thereby
Industrial imbricants Used (Cont.) SOV/4961
increasing the quantity and quality of production. Also included are papers
discussed at an All-Union convention on industrial lubricants held under the
auspices of the Komissiya po tekhnologii mashinostroyeniya Inscituta mashino-
vedenlya. AN SWR (Commission for Machine -Building Processes of the Institute
of Science of Machines, AS USSR). No personalities are mentioned. References
accompany some articles and are all Soviet.
TAME OF CONTEWS:
_-jeoghtnkov, e. 1. Application of Principles of the Hydrodynamic
Lubrication Theory to Stamping Processes 3
Korolevp A. V. On the Problem of Testing Industrial Lubricants Used
in Cold Stamping of Sheet Steel 15
Davydor.. Yu. P. Friction and Lubrication in Stamping Sheet Steel and
Alloys 24
S/137/6 1/000/tO b"PA43,:
Translation from: Beferativnyy zhurnal, Metallurgiya,1961 No-1,
P* 11,;#.1b155
AUTHOR: Isachenkov, Ye.I.
...................
TTTIE: The Application of Principles of.the-Hydrodynamical Theoryof Lub-
rication to Cold Press-Forming Processes
PERIODICAL: V sb.: "Tekhnol. smazki dlya obrabotki metallov davleniyem,, Mos-
cow, Mashgiz, 1960, pp. 3 14
TEXT: The author discusses factors influencing the meciianical*efteict -of
lubricants, intensifiers and extensifiers of external friction Experiments AM
described an Investigating the influence of viscosity on the lubricating effect of
greases at high contact pressures. Increasing viscosity first reduces thaztress
during extrusion and, after having attained optimum reduction, increases again
the stress. Optimum viscosity of the lubricant decreases with a higher extrusion
speed and depends on the pressure between the blank and the extrusion rib of the
die. When evaluating the lubricant, thermostability must be taken into account
Card 1/2
PHASE I BOOK EXPLOITATION SOV / 6161
Isachenkov, Yevgeniy Ivanovich
Shtampovka detaley iz nerzhaveyushchey stali (Stamping of Stainless SteelIParts).
Moscow, Mashgiz, 1962. 53 p. (Bibliotechka shtampovshchika, vyp. 9).
Errata slip inserted. 9, 000 copies printed.
Ed. (Title page): V. P. Romanovskiy, Candidate of Technical Sciences; Ed. -
V. Ye. Nedorezov, Candidate of Technical Sciences; Ed. of Publishing
House: G. N. Kurepina; Tech. Ed.: A. A. Bardina; Managing Ed. for
Literature on Machine -Building Technology (Mashgiz): Leningrad Depart-
ment, Mashgiz-, Ye. P. Naumov, Engineer.
PURPOSE: This booklet is intended for engineering personnel of stamping shops
and industrial planning institutes.
COVERAGE: Technological fundamentals of stamping parts from stainless steel
sheets are discussed, and various types of dies and special devices are
described. No personalities are mentioned.
Card 1/3
Stamping of Stainless Steel Parts
There are-8.referenceil: 7 Soviet,, and I English.
TABLE OF CONTENTS:
Ch. 1. Basic Information on Stainless Steel
1. Classification and physico-mechanical properties
of stainless steel
2. Specifications for stainless steels used for cold stamping
Ch. H. Blanking of Stainless Steel Sheets
Ch. III. Forming of Stainless Steel Parts
3. Bending with metal dies '
4. Bending and forming with rubber die
5. Forming with metal dies
6. Forming of the sheet hlank with rubber, hydraulic,
or gas punch and a rigid die
Card 2/3
SOV/6161
3
3
8
11
13
16
16
27
Stamping of Stainless Steel Parts SO V / 6161
7. Forming from three-dimensional preforms with elastic,
hydraulic, or gas punch
8. Forming with elastic or hydraulic die and a rigid
punch with flange clamping
Ch. IV. Prospects for improving the Process of Cold-St-amping
Stainless Steel in Machine Building
Bibliography
AVAILABLE: Library of Congress
SUBJECT: Metals and Metallurgy
37
46
51
55
DV/wb/mas
Card 313 2-5-63 ,
PHASE I BOOK EXPLOITATION SOV/6300.
Isachenkov, Ye. 1.
Shtampovka rezinoy i zhidkost'yu (Rubber and Liquid~ Die Forming)- Moscvv,
Mashgiz, 1962. 327 p. Errata slip inserted. 6200 copies printed.
Reviewer: V. T. Meshcherin, Doctor of Technical Sciences, Professor
Ed. of Publishing House: Yu. L. Markiz; Tech. Ed.: G. V. Smirnova;
Managing Ed. for Literature on Hot-Working of Metals: S. Ya. Golovin.
Candidate of Technical Sciences.
PURPOSE: This book is intended for engineering personnel of machine-build-
ing plants and scientific research institutes. It may also be useful to stu-
dents at schools of higher technical education.
COVERAGE: The book reviews the basic -principles and engineering prospects
of rubber and liquid die forming processes, used in machine building fo r-
M~ -a,i -las
ng~par-is-,fro-m nefirsheet'.' t also e:~vlaihs the P Inciples of,
sifyink sheet-parts and the various productions processes.~ No personali-;
ties are mentioned. There are 64 references. 42 Soviet, 20 English, ana,
German
J
-ig o d titboi m' -BlOVE38"
F orniii C radiallly-o-corru. a im
AS
t ilbe and flie.rubbor Under t~eii s Ii.,
punch e c ondit.1 n P compr .;i*e
u to'Ahe frictio n X bre es ,, ~c,~nm , approx Iihat ei, I!
r . eaveiv,
x;0S s c~) fthe tub e material.. irl
o:zc 0 04 1 :tile, yi old* st iis~ malres~ th%6:,,
pr o c esa particlila':~ly owjj~gl~to jt~s simpli-li Lnd -hljh~',~
lalitY of t, surfv,,-~e:
% 1 6 ~inished,product odd
q
of~ work-ha'rdening b
degree sur hae- aybr'-'Winiiii~-.xe uc 16W"
r.46-~~,qacektedlby, t 6,
thoAul;ia tpiA46h
L -~vall thic ess
nereazes x-ri increasing-`~t
wall --tii!6kness
-~I~idreasing-vxscqs.
LtYl of
~:-Inereaslng ---speed,-
v. process. --th'O i1Pr,,qijsttre: pereasp
th s.
; onta,~t,~~:4,6tv
pun ci h,6rj6:*-
I -:anaT~'tho;- d T
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L 23054-66 EW,T(d)/E4T(m)/EWP(w)/..7NP(C)/EWP(V)/T/E',VP(i~)/t'iYP(k)/EWP(h)/E;IVP(I)~/
ACC NR: A?5028993 ETC(m)-6 ~jD/ItW/Dj - sOURCS CODE: UR/0182/65/000/009/000:t/qOO8
AUTHOR: IsacheBMx,,Aea.,j Mishunin, V.-~ A.
ORG: none
C
TITLE: Prospects for intensifying the processes.of '014 prii~sing
191
SGUr,,CE-. Kuzuechno-shtampovachn ye 55 1.~8
ibizvodstvoi noo 9.
'C MIM cold'forging, .metal predsin Ig lubri tj extrusiba p~asti it terial
can C YF =A
re e rc
deforma. tion
metallurgic a a h
~ABSTMM Despite its great promise the cold-pressing (extr6ii0n)1* proceal S41:1 is
employed on an ade4uate.'scale,inMachine building, Wixticularry, fabrica-!
o4 parts from high-strength nonfWrrous and ferrous alloys~ Thii~problem can be
resolved, by accomplishing the followXag'tasks- 1. i Davelopmen't'.of a' h~drodynami !Au~-
Iricating-regime and the eltminationlof the considerable ener' ~, lqsaes~ due, to jil%ing.
u 9 1 .1 1.-
'Th,e hydrodynamic theory of frictidnMakespossible a sufficiently complete.desdrLption
of the basic. patterns of the effects accompanying various condition oficold f 0*8 as 4
!2. uniform propagation throughout the blank of the conditions~ 'of flowage arisiq in
ithe surface,layer of the blank during foraing; this.is aecampllshe4~b~ compreigirig
the blank so that the hydrostatic pressure in the zones of freie-floF~age.of the, lml.t_:~
erial.would be c. ensurate with the deformation resistance ot the viaterial of the
Card -112 UDC::621.983.1
ISACi0NKOV, YE. K.; PIKHTOVNIKOV, R. V.
Sheet Metal 'Work
Effee't of the 8pped of deformation on the process of stamping parts from steel sheet,
Vest. mash., 32, No. 5, 1952.
9. Monthly List of Russian Accessions, Library of Congress, October 1996. Unclassified.
2
,"~-JgGLKI,y i..,,Qpza).
,.,Aj~
Using slide rules in computation lessons. Hat. v shkole ne.6:54-61
N~--D '58. (KM 11:12)
(Slide rule)
ISACHKIN, B.Ya. (Penza)
Solving quadratic equations with the slide rule. Pat. v shkole
no.3:61-63 Mr-Js '59. (NIRA 12:9)
(Iquations, quadratic) (Slide rule)
KOUTOROVICH, P.G.; KUPLUTOV, V.A. (Sverdlovsk); GUTMAN, A.Ya. (Moskva);
DEYNEGA, A.V. (Kiyev); ISACHEIN, B.Ya. (Penza); IIETRDNINA, N.G.
(Tambov); P0140MAREV, -SERYANOV, D.P. (Xormunl-
Shevchenkovskly, Gherkaoskaya obl.);-KOLIEDV. A.1F. (Kalinin);
SHM, Ya.A. (Moskva); IVANOV, M.I. (,Tula)
Discussion of the now mathematics curricula. Vat. v sbkole noj:
4-20 N7-Je 159. (MIRA 12:9)
(Mathematics)
ISACRIM, B.Ya. (Penza)
lessons on calculation with the aid of the slide rule In the
10th grade* 11at. v shkole no.5:35-41 5-0 159. (MPA 33:2)
(Slide rtae)
3:SAC-HKIN,-B.Ya. (Penza); MALININ, V.V. (Loningrad)l BOGDANOV, I.M.1
SWOVSWAP F.V.,, obahchostyenMy metodint; ASMMV, K. (Baku)
ties In grades 9 to 11 of eveniM
*'aft 'roo =~smcahools of general education, Mat, v
(stagg'sredr)"Le
shkole no.3:57-59 MY-Je 163, (MM 16:7)
1. Inspektor po shkolam rabochey solodeshi Nalininskogo r1yons.
MOskv7 (for Bogdanov).
(yethematice-Study and teaching)
BUSITA; V.T.; POP, 0.; VASIMSCU, I.; TOPGIU, Vl.; POPIAN, R.; CUCURUZ, L.;
ALEXAMMOU, R.; ZAGSON, I.; SON, G.; GRAVGVSCHI, V.; ZIMMMI. L;
FITARAU, A.
Clinical study of levtoopirosis. Stud. cercet. inframicrob 101, IUL~W.
8 no.2:259-280 i957.
1. Comminicare presentata la Institutul do inframicrobiolokis, &I
Aca4emiei R.P.IL in sedinta, din 5 marts 1956,
(LVTOBPIRMIS
pathol. & epidemiol. of.L. pomona. 1% canicols & Other,
leptospiral infect. in Ruwania, case reports & rqvivw),
TOSADNOV, P. P.
Fishing Implements and Appliances
Drop hamner with head for driving in seine stakes. Ryb. khoz., 28, No. 6p la""2.
9. lonthly List of Russian Accessions, Library of Congress, 950. Un'claissifted.
1, ISAD07, P. M.
2. USSR (6oo),
4. Iron - Analysis
76 Opxlitativo detection of iron in ores and minerals by menne of trituraticn. Ymch.
biul Lon un. No. 30 1952.
9. Monthl List of Russian Accessions, Library of Congress, April 1953,.Lincl.
SO V/118-58-1, 2-50/17
AUTHORS: Glotov, V.V., Lysenko, M.A., Parshina, Sokolova, N.A.,
Isads~~a _Z.A.9 Engineers
TI"LEt The Economical Effectiveness of a Centralized Electric.Power
Supply for Lumbering Sites (Ekonomidheskaya effektiv-aost-1
tsentralizovannogo elektrosnabzheniya na. lesozagotovsakh)
PERIODICAL: Mekhanizatsiya trudoyemkikh i tyazhelykh rabotj 1958,, Nr 12,
pp 29 - 35 (USSR)
ABSTRACT: The article deals in detail with the calculation of the
operational expenses at lumbering sites,,using electrio
power instead of oil driven engines. The research leads to
the conclusion that under definite conditions, the'electri-
fication of the lumbering industry proves to be economically
more efficient as compared with the.utilization of oil-fuel-
led mechanisms. There are 7 tables, and 1 graph.
Card 1/1
GULMOT. R.G.; U7XO, G.I.; ZOTOT, A.M.;
Tu.A.; SRXrXM, A.Ta.; TSLWINUO M.P.; UWJMWO. I.L., red.;
BAKMYAROW, A.. takhn.red.
Dashkaut: concise reference back] Tasbkont; kratkil,sprayfichnit.
lsd.2*o dop. 246*80, GosAnd-va lVabskskoll M, 1958. 1" p.
(MW 131:
(Tashkent-%Ittobooks)
BOIADZIUWA, M.; MILEV, M.; ISM, Iv.
Experience with the preparation of complexes in the form of dry
extracts and tablets. 11. Naueb. tr. vissh. med. inst. Sofia 39 no.'.5:
133-138 '60.
1. Predstavena ot prof. T. Trandaftlov, rukovoditel na Natedrata p9:
tokbnologiia na lekarstvenits foral i galenovi:preparati.
(TABLETS) (PHARMACY)
BOIADZHIEVA, M.; MILEV, M.; ISAEV, Iv.
Experience with the prep"tion of complexes in the form of liquid
extracts, dry concentrates and tablets. I. Nauch. tr. vissh. med.
inst. Sofia 39 no,5:139-143 160,
1. Bredstavena ot prof. T. Trandafilov, rukovoditel na Katedrata po
tokbnologiia na lakaretvenite formi i galenovi preparati.
(HU'RKACY) (TABIETS)
Iv.; BOIADZHIEVJI, M.
Production of galenic and neo-galenic preparations and experience
with the isolation of active substances from Leonurus cardiam, Nauch.
tr. vissh. med. inst. Sofia 39 no.5:145-152 260.
1. Predetavena ot prof. T. Trandafilov, rukovoditel na Natedrata 06
tekhnolagiia na lekarstvanite formi i galenovi preparati.
(PLANTS NEDICINIAL)
ISAEV, Iv.; BOIADZHIEVA, M.; MILEV, M.
Production of tablets of Leonurus cardiaca alone and in
combination with nealeovasan, phanylurea and other drugs.
Nauch. tr. viveh. mod. inst. Sofia 41 no.4:33-37 '62.
1. Pradstavena ot prof. d-r T. Trandafilov.
ANTICONVULSARTS) (ANTiHrFERTENsivE:AGF.NTS)
%PNOTICS AND SEDATIVES) (PLUITS, KEDICINAL)
FASKOV, D.; ZHELIAZKOV, D.; ISAEV,_Iv.,- BOIADZHIEVA, M.; MILEV, M.
Production and pharmacological analyain of a purified Digitalis
ambigua eardfac preparation. Nauch. tr. viesh. mod. inst.
Sofia 41 no.4:39-50 162.
1. Predstavens. ot prof. P. Nikolov.
(DIGITALIS GLYCOSIDES)
ISAEVA, M.
First step toward inventiveness. Nauka i 'Uekh x mladezh 13
no.12:8-9 D 161.
i
I -
I
ISA13ALIY3VA, H.H,
wa 6AA"~'~Ai i,.,
-m
ftnicillin for treating progressive paralysis. Trudy Inst.kraev.pat.
AN ZosakhoSSR 1:123-132 152. (MIRA 20:2)
OUICILLU) (PARALYSIS) I .
-U-07221n67
ArC-M-,-W?6026502 SOURCE CODE: YU/0002/66/000/004/0209/021ii,
-'?e
AUTHOR- Inagulianc, V. I. (Academician; Professor); Desukki, A.
ORG: Moscow Institute for Oil and Gasoline Cheii-stry. Moscow (Moskovski institut
za naftu i petrokiEMUT-
TITLE: PolymerizatiAof certain unsaturated hydrocarbons in presence of cation
exchange resins
SOURCE: Kemija u industriji, no. 4, 1966, 209-213
TOPIC TAGS: ion exchange resin, hydrocarbon, unsaturated hydrocarbon, polymerization,
catalytic polymerization, polyisobutylene
I
ABSTRACT: The article is a translation of a lecture given in September of 1965 which
dealt with the polymerization of tertiary unsaturated hydrocarbons in presence of
cation exchange KU-2 resins. The polymerization of Lsobytylenceliand isoamylene yields
generally unsaturated dimers and trimers, whereas the polpnerizition of OL-methystyrene
and its homologues yields mostly saturated dimers with some unsaturated trimers. '
Optimum conditions for polymerization are given, and it is shown that a-methylstyrene
and its homologues show differing tendencies toward polymerization. The pol~meriza-
tion of p,a-dimethylstyrene, p-ethyl-a-methylstyrene, and p-isopropyl-a-methylstyrene
in presence of cation exchangers has been studied for the first time as was the
Card 1/2 UDC: 661,715.3,095,264
L 07227-67
NR: AP6026502
copolymerization reaction of a-methylenstyrenelith isobutylene and isoamylenes.
Compounds were identified by infrared and-ultraviolet rays. Orig. art. has: 7 tables
and 2 figures.
SUB CODE: 07/ SUBM-DATE: none
/CQ!Grd 2
MI
~~m
POFG. N.F. ;-- 1 JAG111,011,1. I.
Using metal s!ipporls in ,io-f't grovsi. Ndu~h. KNIUI n0.143153-
162 164. (MIRA 18t./,) '
m
YERSHOV, V.Z. (lErshov, V.Z.); ISAGULOVA, O.Z .. [14#iulava, O.Z.]
Jurasi3ic sediments overlying the coal-bearing layer of the Lvov-
Volyn' Carboniferous and "terials on their stage. Visnyk
Llviv.un. Ser.geol no.l:';l-24 t62. (MM,16:-,7)
4vov-Volyn Basin--Geology, Stratigraphic)
ISAGULOVA, Te.Z.
Hystrichospheridia in Jurassic deposits of the Lvov-Volynt Coal
Basin. -Dokl, AN.SSSR 148 no.5:1.156-n5a r 163. (KU~A 16:3)
1. LIvovskij gosudarstvonnyy universitet in. Ivana Franko.
Predsta#leno akademikom V.N.Sukachevya
(Lvov-Volynt BasM441sobotany)
ISIIGUILOV~-'- Yfj.Z.
Palynological characteristics of Middle Jurassic sediments
in the southwestern margin of the Russian Platiorm and
Carpathian piedmont fault. Vest. LIvov. un. Ser. geol. no.2:
36-40 164. OrIRA 19: 1)
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"puttinis (it.. r,.i. 37, 2w) ; e.m., faw the aystent with
-
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ISAGIILYAHTS~ G. V., KEYER, N. P., FLDTTCK. B. V.
Ethanes
Preparation of acetylene and ethane tagged by radiocarbon C 14. Dokl. AN SSSR 85F
No. 5, 1952.
Radioactive acetylene was prepd from barium carbide C.Tft C14. and
Water. Radioactive etbane was prapd from the tagged acetylene by nesias of hydm-
genation over a Ili catalyst at room t4mp. Submitted by Acad A. N. Frum 12 Jurt 52.
239TI3
9. Monthly List of Russian Accessions, Library of Congress, December 1114
Utclassifiedo
IL8 - - 1-1-U! i TI Z- I, G . 'Vt. and 1ID7U;ON, B. V.
Ethane Tagged 5b. ~o Obshch, Xhimii.
"Preparatiop af'Ac~et,lene and "E 4th
Izd-vp Ail 1% ---t., Vol 2, pp 1566-11,69, 1953
,Veveloped a laboratory method for the preparation of acetylene tagged
with CJ-4. Method consists of heating radioactive barium carbonate with
magnesium to prodice radioactive barium carbide. The barium carbide then yields
radioactive acetylene when treated wiht water, and the acetylene can be hydrogenated
over a nickel catalyst to give radioactive ethane. (RZhKhim, No 22, 1954)
Sum. No. 681, 7 Get 55
IS.~ GULU-ETIPS G. V. ; KEMR and KTITI~21MY, B. 11.
Preparetion of Acetylene and Ethane Tagged with Rndio,':ictive Cvrbon C14-p
Pac,e 1566, Sbornik st~-,,tey po obshchey khindi (Collection of Papers on
General Chend-stry), Vol II, Moscow-Leningrad, 1953, paZes 1680-1686.
Inst of Physical Chenistry, Acad Sci USSR
ISAGULYANTS, G. V. --11- Aue, -53-
USSR/Chemistry - Isotopes
"The Preparation of Caproic Acid TaUed with Radioactive C14 In the Carboxyl Group,:"
G.V. Isagulyants, Ye.,4- Pndreyev, and N.A. Ko-solapova
DAN SSSR, Vol 91. No 5. PP 11*-1124
Using the Grignard reaction prepd caproic acid having C14 in the ca"oxyl group. Reacted
amyl-N&bromide wit)i C1402 prepd from B&C140 3- Yield of caproic acid was 91% of
theoretical. Presented 'by Acad A.N. Frumkin 13 Jun 53.
~266TS
ISA6-ULYANTS,
PHASE I BOOK EXPLOITATION .1181
Akademiya, nauk SSSR. Inbtitut fiziche6ko khimii
Problemy kinetiki kkatalizaalt).Ix.- tzotopy v katalize-(Proble43
of Kinetics and Catalydis. I'd q.- isotopes in Catalysis) Nos'c'ols'
lzd.;-vo AN SSSR, 195T.. ~442,P- 3,500 copies printed.
Edse RoginskiyS'Z.., Ifinoigradovi,, O.M Keyer, N.P. and Yanovskiy,
M.I., Corresponding Members, USSR Academy of Sciences; Ed. of
Publishing House: Va.s.seroerg, V.E.
PURPOSE% This book Is for specisAistsiinterested In the theoretical
and_pzntctical problems of the a Ipplication of Isotopes in catalysis.
COVERAGE: This collection of articles forms volume 9 of "The Problems
of Kinetics and CatAlybis.*!- Most of the.:papers were reeented~at the
f. p
Conference on Isotopes.in Catalysis which took place in Moscow.. March
31 - April 5, 1956-. Scientists from the Academy of Sciences of
Card 1/34
3.
Problems of Kinetics and Catalysis (Cont.) 1181
of the USSR, the Ukrainian Academy of Sciences, institutes of' the
chemical and petroleum industries, and several vuzes took nart.
Scientists from the six people's republics China, 0DR,
Poland, Czechoslovakia, Hungary and Rumania also participaied.
Thia conference was the first of its sort not only in the Soviet
Union, but internationally. Several articles which could not be
included in the program of the conference are given iin the text.
Each article has figures, tables, and a bibliography.
TABLE OF
CONTENTS: From the editor 3
Roginskiy, S.Z* Isotopes-in Catalysis 5
PART I. CATALYTIC REACTIONS OF HYDROGEN
Voyevodakly, V.V.. Mechanism of the Homogeneous and
Heterogeneous Homolytic Deuterium Rxchange
Card 2/36
Problems of Kinetics and Catalysis (Cont.) 1181
Balandin, A.A., Neyman, M.B.., Bogdanova, 0 K.,,_jLaj;ulyants,, G.V.,
Shcheglovaj A.P., Popov, Ye, I. Tagged-at;m Study o-r-T"-
Dehydrogenation of Butane - Butylene Mixtures
Avdeyenko, M.A., Boreskov, G.K., Slinlko, M.G. Catalytic
Activity of Metals in Relation to the Homomolecular Isotopic
Exchange of Hydrogen
Golovina, O.A. Rogirniiy, S.Z.,, .5akharov, M.M... Eydus,. Ya.T.,
v ains in the
Dokukina
., Ye. S. Stu y of the Role of Plane Ch
Synthesis of Hydrocarbons from CO and H2
Tverdovskiy, I.P., Tupitsyn, I.F. Study of the Nickel-Boride
Catalyst
'Discussion:
R#Xha-Burshteyn
G.K. Bdiseskov
Card 3/24
45
61
76
84
91
'.92
~ t - F ;~ I - - 'r"
..4- ~ --- , - .
IJAGUIIYAMI~;' U. V., G. "'T'A=", it. i.-.'- - -.1 .-. _. 1?~ z
ItApplication of radio-carbon in investiCating the mechanism of
consecutive reactions of butane-butylene-divinyl," a paper submitted at
the International Conference on Pedioisotopes in Scientific research,
Paris, 9-20 Sep 57.
BALANDIN, A.A.; XBTMAH, H.B.; BOGDANOU. O.K.; ISAGULTARTS, G.V*_L'_.__
SHCOGLOVA. A.P.; POPOV, Te.l.
Process of carbon dioxide formation-As obtalving divinyl from
butane-butylens mixtures. lsv.AN SSSR.Otd.khIm.sauk.no.3:270-278
Nr '57. (MM 10:5)
1.1netitut organicheskoy khlmli im. N.D. ZellaskDgo Akadsidl-vaWc
SSSR I Institut khtmicheskoy fisiki Akademll nauk SSSR-
(Girbou dioxide) MUM) (ftlAyleno)
A G, Z7 V/
BAIANDINO A.A.; NITW, H.B.; BOOMNOVA. 0.K.;
A,P,; POPOTO
Dehydrogenation of butane - butylens mIxtures
Probl. kln. I kat. 9w45-60 157.
69hydrogenation)
ISAGULYANTS. G.V.; SHCMLOVA,,
usivg taMd atoms.
(xm nol
(Butane)
laAG',ULW-i$o G.T.
Distmesion. Probl. k1n. i kat. 9:215-216 157. (KIRIL 11:3)
(Dehyftogenation) (Datane) (Ratylons)
BAIANDINJ. A. A., XB B0GKj1_NOVAY 0. K., ISAGULYANTS. G. V., mynu, Yu. V-, and POPOV, Ye.
(Inst. of Organic Chem. AS USSR.)
"Investigation of the Mechrism of Successive Reactions Butane-Butylene-M-vlnyl
by Using Radioactive Carbon C1 fl P. 52.
isotopes and Radiation In Chmistry, Collection or -japers of
2nd All-Union Sci. Tech. Cour. on Use of Radioactive and Stable Isotopes find
Radiation in National BconopW and.Scieuce., Moscow, lad-vo AN SM,190, 3iftp.
Tble volume publiskied the reports of the Chadetry Sectlan of tbi
2nd jW Sci Tech Coof on Use of Radioactive and Stable Isotopes and Radlatlon
in Science and the National ZcmcnW, sponsored by Aced Sci UBSR and Main
Admin for Utilization of Atomic ikergy under Council of NInlisters UMM
Hoscow 4-12 Apr 1957.
/ 5-,q 6 &~ 4 VAA.) -/:S- J~;, ~/,
AUTHORS: Balandin, A. A., Bogdanova, 0. K., 62-1--J/29
Neyman, 1,1. B.) Popov, Ye. I.
TITLE: The Application of Radioactive Carbon in the Comparison
Between the Dehydrogenation Velocities of Butane and Butylene
(Primenaniya radiouglaroda dlya sravneniya skorostay
degidrogenizatsii butana i butilena).
PERIODICAL: Izve~!tiya AN SSSR Weleniye Khimichealcikh N.auk, 1958, :Nr 1,
pp~, 18-23 (USSR)
ABSTRACT: The investigation (with the application of C14) was carried
out by means of a special catalyst under conditions especi-
ally favorable for the obtaining of divinyl. Since it,turned
out that divinyl can be formed from butylene and that:butane
cannot be transfo=ed into divinyl, it was.cancluded that the,
reaction (d-ivinyl from butane) passes only through the-st agi'
of the formation an~i dosorption of butylene. Therefo.re the
desorption of butylene cannot be a final stage of the;entire
reaction. The authors report on the carrying out of the 'in-
vestiCation: The correlation between the dohydrogenition
velocity of butane and butylene in divinyl at the chr-onium
catalyst was found by means of computLtiona,-corrasponding
Card 1/2 to the experimental data obtained already before. It was
The Apl,lication of Radioactive Carbon in th(., ConpiLrisor- 62-1-4/29
Between the Dehydroganation Velocities of Butane and Butylene
shown that the ratio of the velocities of the dehydroaen-
ation. of butane in butylone and of butane in divinyl is for
both catalysts of the same order and corresponds to the
.,riLtio 20:1. In the experiments with chromium catalysts the
irolocity ratio in the formation of divinyl from butane I ~
corresponded to 1:1000 and in the experiments with an alumo-
chromium catalyst to 1:25, Furthermore it was confirmod-that
the formation of divinyl from butane takes place over the.
stage,of the formation of butylene. It was shown that the-
constants (in the denominator of the kinetic equation of de-
hydrogenation) represent aduorption~o'oeffioionts. There are
6 fioure 4 tables, and 5 references, 4 of which are Slavic.
ASSOCIATION: Institute of Organic Chemistry imeni N.- D.. Zelinskiy AS USSR
(Inatitut vf6anicheskoy khimii imeni N. D. Zelinskogo
Aka'demii nauk- SSSR).
SUBMITTED: January 4, 1957
2. Butylene-Dehydrogenation
(;a:;-d 2/2 -3.','~Cifbon- isotopes '(Radi6active)-Applications 4. Chromim
Catalyst-Applications
6- V
AUTHOIRS: /3alandin, 1k. A., Isagulyants, G. V., Popov, Ye, 1.,62-2-18/28
Derbentsev, 'Cu. L., Vino:~radov, S. L.
TITLE- The Application of Radioactive Carbon for the Invectigation
of the Dehydration Mechanism of Ethyl Alcohol Over Aluminum
Oxide (Primeneniye radiougleroda dlya.issledovaniya mek.han-
izma degidratsii etilovogo spirta nad oki3lyu alyuminiya).
PERIODICAL: Izvestiya AN SSSR Otdelerdye Xhimicheskikh Nau1c, 1958, Nr 2,
pp. 233-235 (USSR).
The problem of the above-mentioned de]Wdration mechanism.has
long been discussed in publications. Various authors.assume
that the formation of ethylene takes place over thesta6e, of
the formation of the diethyl ether. Others, however, think
that ethylene and ethers form as a result of 2 independent
parallel reactions. For the purpose of solving this problem
the authors performed the dehydration of ethylone alcohol. with
addition of diethyl ether. See formulae (2),(3),(4). A:3 the
final result of the performed reactions showed, alcohol,
ether and ethylene possess a spicific radioactivity (see
figure 1). The authors determined: the dehydration velocity
Card 1/2 of ethyl alcohol and ether in ethalene as well as the ,-ommon
The Application of Rad-ioactive Carbon for the Investigation 62-2-18/28
of the Dehydration Mecbanism of Ethyl Alcohol Over Aluminum Oxide.
conversion of alcohol and ether over alumintun oxide at
3000 C. they found that ethylene forms in two differett ways:
directly from alcohol, and over ether. There are 2 figures,
1 table, and 8 references, 6 of which are Slavic.
ASSOCIATION: Institute for Organic Chemistry All USSR imeni N.D. Zelinskiy.
(Institut organicheskoy khimii imeni N.D. Zelinskogo kkademii
nauk SSSR).
SUBMLITTED: September 21, 1957
AVAILABLE; Library of Congress
1. Carbon Isotopes (Radioactive)-Applications 2, Ethawl-
D61Wdration 3. Aluninm oxide-Applicatiom
Card 2/2
,50)
AUTHORS: Balandin, A. A., Isagulyants, G. V. SOV162-58-11-5/26
.TITLEt Dehydrogenation of Soma Hydroaromatic Hydrocarbons on
Chromium Catalyst (Degidrogenizatsiya nekotorykh
gidroaromaticheskikh uglevodorodov nad khromovym
ketalizatorom)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheakikh nauk,
1958, Nr 11, pp 1303-1309 (USSR)
ABSTRACT: In the present paper the authors especially tried to establish
equal conditions of reaction for various hydrocarbons. For
this reason the data determined may be compared qualitatively
as well as quantitatively with each other. The authors applied
the running-thru method. The general scheme of the appairatus
corresponded to a similar scheme described in referen ce 1. The
catalyst was produced according to the method described in
reference 4. Its activity was constant and was controlled
after dehydrogenation of cyclohexane.,Dehydrogenation of
cyclohexane, Dekalin, methyl cyclohexanel 1,3-dimethyl cyclo-
hexane, Tetralin, 2-methyl-5,6,7,8-te:tr&hydro naphthalene:was
investigated on the chromium catalyst. The 4 compounds
Card 1/3 mentioned last were investigated for the first time. The
Dehydragenation of Some Hydroaromatic Hydrocarbons SO lr//~-'52-58- 11 -5/26
on a Chromium Catalyst
activation energies of cyclohexane, methyl cyclohexane,
1;3-dimethyl cyclohexane, Tetralin, and methyl Tetraltr,
were determined on the chromium oxide. The.hydrocarbone
similar in structure - cyclohexane, methyl. cyclohexante,
dimethyl cyclohexane, and Dekalin - are characterized ty
similar constants of the Arrhenius equation which, however,
do not agree. The occurrence of methyl groups in the cyclo-
hexane ring slightly reduces these constants. At high
temperatures this leads to a considerable difference in
dehydrogenation velocity. Tetralin and methyl Tetralin can
be dehydrogenated at a greater number of active places than
cyclohexane and its homologs. Dehydrogenation is in this
case characterized by greater constants of the Arrhenius
equation. For the dehydrogenation of all hydrocarbons
mentioned the factors of the exponential functions are
logarithmically dependent on the activation energy. The
distribution constant is the same in all cases. There are
7 figures, 10 tables, and 5 references, 3 of which are Soviet.
Card 2/3
.Dehydrogenation of Some Hydroaromatic Hydrocarbons SOV/62-58-11-5/26
on a Chromium Catalyst
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D.
Zelinskiy of the Academy of SciencesUSSR)
SUBMITTED: May 14P 1957
s/.cal/62/000/001/007)'067
B156/B101
AUTHORS: Minachev, Kh. M. Isagulyants, G. V., Kondratlyev, D. A.
TITLE: Investigation of the poisoning of a platinum catalyst, in
reforming conditions, by thiophene containing the radio-
active isotope S35
PERIODICALt Referativnly zhurnal. Khimiya, no. 1, 1962, 75-74, abatraci
1B540 (Sb. "Khimiya seraorgan. soyedineniy, soderzhashchikhoya
v neft-akii i nefteproduktakh, v. 4". M., Gostot)tekhizdikt,
1961, 160-165)
TEXT: The general laws for the poisoning of platinized Al 20 3 conta.infjng
%6' Pt by thiophene labeled with radioactive sulfur, when dehydrogenat'"ng
cyclohexane in a floa system at an H 2 pressure of 20 atm and a temperature
of 4500C, are studied. Radiochemical analysis enabled the sulfur content of
the catalyst to be determined, this varying between 0.063 and 0.14~* according
to the concentration of thiophene in the initial mixture. The activity of
Card 1/2
B/081/62/000/001/007/'067
Investigation of the poisoning ... B156/B101
the cptalyst decreases linearly as its sulfur content is increased. The
process of regeneration of the catalyst is accompanied by the removal of
sulfur from it, but full activity is restored when the catalyst still
contains -40',- of the sulfur which it contained before regeneration begans
[Abstracter's note: Complete translation.]
Card 2/2
33491
S/195/61/002/005/016/o27
S71190 E030/Ei8.5
AUTHORS& Isagulyants, G.V.l__and Balandint A.A.
TITLE: The use of radiocarbon (C14) in studying the mechawism:
of parallel-consecutive catalytic processes
PERIODICAL: Kinetika i kataliz, v.2, no-5, 1961, 737-;740
TEXT: The use of radiocarbon is proposed to determine the
stages and proces s of forming products in parallel-c6neecutive
reactions, the general scheme of which is represented bys
W
A
W
W\2 C 3
where A is the initial product, B and C the products formed
during the process. Three'typical cases aris*t for &'reaction
rate W2 0, C is formed consecutively from A with*B an inter-
mediate; for W3 f-se 0, B and C are formed from A in parallel but
Card 1/ 5
33491
The use of radiocarbon (C14) S/195/61/002/005/Oi6/o27,
E030/EI85
independent of each other; and when all the rates are
commensurable, C is a product of a consecutive-parallel reaction.
The formulae for the rates Vi aret
dp C2 d, C-L
Wl
dz (a Ta
C3(dy/d-t) + (y - a)(dC3/dT) dC3.
W3 W2 _(F7 W3;
where mo p, y are the OL specific activities and Cl, C2'j C? th-a
concentrations of A, B, Cl respectively-, T is,the contac tim-S.
The authors were able to observe the above discussed.cases in,
many processes by adding to the initial product A a small
quantity of B or C marked with C-14 and determining the changes,
in concentration and specific radioactivity in relation to ~
contact time. one of these processes was that of thA decompo-
sition of ethyl alcohol investigated by the authors together with
Ye.l. Popov and Yu.I. Derbentsev (Ref.3s Izv. AN SSSR, otd.khim.
n., 1958, 233). The decomposition was carried out in the
Card 2/ 5
33491
The use of radiocarbon (C14) s/iq5/6i/oo2/oo5/oi6/027
E030/EI85
temperature range 275 - 400 OC with aluminium oxide as catalyst.
It occurs in two directionss into ethylene and Into ethyl ether.
At the lower temperatures, decomposition into ethylene was much
slower than the dehydration reaction (reversible) into ethyl
ether. An the temperature rose, the decompositi6n rate.of ethyl
alcohol into ethylene rose until at 400 OC it b4came comparable
with that of the ether reaction. Thus, the concentrations of
both alcohol and ether show maxima. As the temperature rises.the'
ether maximum is produced not only by the direct alcohol-ethylene
reaction, but also by decomposition of the ether to ethylene.
At 400 OC where there is 100% conversion to ethylene, 80% of the
ethylene is produced from the alcohol and 20% from the ether.
The dehydrogenation of cyclohexane to cyclohexene and to benzene
is another similar process (Ref.53 Yu.1. Derbentsev,
A.A. Betlanding G.V. Isagulyants, Kinetika i kataliz,. v.2, 741,
1961). A pare consecutive process occurs in the dehydrogenation
of butane-butene mixtures on chromium catalysts. Both the butane
and butenes are converted directly to butadiene, the conversion
rate from butane boing about 3 times faster than from butene.
Card 3/5
33491
The use of radiocarbon (C.14) .... s/.195/61/002/005/016/027
E030/EJL85,
An unexpectedly interesting'syttem is the decomposition of
isopropyl alcohol on a vanadium trioxide catalyst. The catalyst
was obtain*d by passing hydrogen over the trioxide at 4170.
The genoral scheme possible.ins.
H2 ~H20
(113 H60 4 C3H7OH, C H
3-
H2\1. H
C H/I _/ 2
Sy using radioactive propylene (up to 29 000 impu*/mizi on BaCO3.))
and by separating propane, propylenso and the catalysa.te,
and determining their activities, it was shown that propylene
in not converted to isopropyl alcohol at 3150, and that propane
is formed, not from propylene, but from the isopropyl alcohol.
There are I table and 10 references$ 8 Sovlet.-bloc and~2 non-
Soviet-bloc. The English language references read as followal.
Ref.8.- V.J. Komarevsky, J.Amer.Chem.Soc..j V.69, 238,1947.
Card 4/5
3 3L- 9 2
S/195/61/002/005/017/027
E030/El85
AUTHORSs Derbentsev, Yu. I. I Ba landint A. A. , and Isagulydnt s oll~ V.
TITLE. Investigation of the role of cyclohexene in the
heterogeneous catalytic dehydrogenation of
cyclohexane, using radiocarbon
PERIODICAL: Kinetika i kataliz, v.21 no-5, 1961, 741-747
TEXT3 The dehydrogenation of cyclohexane on chromia and
rhenium catalysts has been studied, using C14. Chromia was chosen
as an oxide catalyst, favourable for doublet dehydrogenatio .n.,, and
rhenium as a metallic catalyst suitable for a sextet dehydrogena-
tion, where the conversion rate of cyclohexene by this process..L'S
negligible. The chromium oxide in' 2-4m pellets was obtained from.
ammonium bichromate. Before every experiment the rhenium catalyst.,
prepared by the method previously described (Ref.81 A.A. Balandin,
Ye.I. Karpeyskaya, A.A. Tolstopyatova, Zh. fi.z. khimii, v-33.
2471, 1959) was kept for one hour in hydrogen at 480 OC.
A continuous flow reactor was used, with varying initial
concentrations of cyclahexane (obtained by hydrogenation of benzol),
Card 1/3
33492
Investigation of the role of s/195161/002/005/017/027
E030/E185
benzol,-and marked cyclohelcene (ActivitY 470 pulieA/minute
mg BaC03) obtained from C" marked phenol. The Cat&lysates were
analysed.chromatographically on a 7m long spiral column of
diatomaceous earth, of which the first half was impregnated with
dinonylphthalata, and the second half with dio:;tylsebacatei othi~
outlet from the column was led either to a thermal conductivity
detector or for quantitative analysis to a bubbler with obaryta
water,, in order to obtain ba rium carbonate. The radioacAivity of
targets made from this carbonate was measured with an end window
counter, and samples taken after 15 min. on the chromia
catalyst, benzole was formed by a parallel-consecutive processi-
conversion of cyclohexane into benzole is 1.5 times faster than
the conversion of cyclohexene~~ a considerable part being formed
from adsorbed and desorbed cyclohexone and it is obviously a
doublet.mechanism of dehydrogenation. on the rhenium catalyst,
there is no consecutive process at all and cyelohexane is
converted directly into benzole by a sextet mechanism.. The
differing behaviour on the two types of catalyst is striking-,,
on chromia it is dehydrogenated to benzole, but on rhenium -it is
Card 2/3
ISAGULYANTSp G.V.; BALAUDINO A.A.v akademik; POPOV, Yo-1.
-------
Deteruiination of relativo adsorption coefficients by isotopic
dilution. Dokl. AN SSSR 139 no.1:139-141 JI 161. (MIRA 14:7)
(Adsorption) (Radioactive tracers)
ZAMUffCHZVAI I. I.X--LUGUTAI!T~ ~G. V.; BAIANDIN,, A. A.
IfomtIon of ethane during deeomposition of ethyl alcohol on
titaniiiii dioxide, Isy. AN SM* Otd. khta. nauk no.1:179-180
163. (NMA 16: 1)
1. Institut organicheskoy Wadi in. N. D. Zelinskogo AN SSSR.
Octhane) (]Bttql alcohol)
M~
ISAGULYANTS, G.V.t RYASHAIJISEVA, M.A.; DERBSITSIEV, Yu.I.; hIRIACH7, Kh.?,4.;
MM7=- A.A.
Role of cyclohexene in the dehydrol-ation and isomerization
of cyclohexane under conditions of reforming. Neftekbi-Pa 1,
no.2o.229-235 Vb7-AP'64 (M I P-k 17 18)
1. Institut organicheskoy khimii AN SSSR imeni Zelinskogo.
ISAGULYA~~...~.V.-, BALANDIN, A.A.; POPOV, Ye.I.; DERBENTSEV,. Yu.I. (Moscow)
C14 tracer study of the dehydration mechanism of ethyl alcohol
on aluminum oxide. Zhur. fiz. kbim. 38 no.1:20-27 Ja164.
(MIRA 17:2)
1. Institut organicheskoy khimii imeni N.D. Zelinskogo AN SSSR.
DEREENTSEV, Yu.I.; MARKOVY M.A.; ISAGULYANTS, G.V.; MINACHEV, Kh.M.;
BALANDIN, A.A., akademik; FrInIma-La - e SHGHUKINA, O.K.
Mechanism of cyclohexane dehydrogenation over holmium oxide studied
with the use of radiocarbon C14. Dokl. AN SSSR 155 no.1:128-131
Mr 164. (MIRA 17W
1. Institut organicheskoy khimii Im. N.D.Zelinakogo AN SSSR.
ISAGULYANTS, G.V.; DERBENTSET, Yu.I.; KLABUNOVSKIY., Ye.I.; BALAND111, A.A.
-...... ~,
Mechanism underlying the catalytic dehydration of 2-butanol
on the surface of aluminum oxide. Izv. AN SSSR. Ser. khim.
no.6:985-990 Je 164. (MIRA 17:11)
1. Institut organicheskoy khimii im. N.D. Zelinskogo AN MR.
E
RYASHENTSEVA, M.A.; DERBENTSEV, Yu.I., MINACHEV,
Kh.M.; BALANDIN, A.A.
Mechanism of cyclane isomerization on bifunctional catalysts.
Izv. AN SSSR. Ser. khim. no.8tl555-1556 Ag 164.
(MIRA 17v9)
1. Institut organicheakoy khinii im. N.D. Zelinskogo AN SSSR.
V.S.; GUDKOV7 B.S.; 1~-ACMLYAWII'S,
lknife,-tation of a bifunctional character of 'N'
surfaco In catalytic conviw3ions of e.vc-lohexana,
S'SR. ~ - r, i, - 1
;er. il"I -~A
t Organ,
mm
13,11GITLYANTS, G.V.,- FOIIARWA, Ya.N.; DAI-ANDHII, A.A.,
Dehydrcgenation methanism ot c:yclane:3. Delaydrogenation
of me tlWlc,,yclrhexane or, an califdy~~it. Dokl. AN SISSR
164 no.6.'1307-131.0 0 165. (ViJRA 1.8: 10)
1. Instlitul. orgardeheskoy kleml-,- im. AN SSSR.
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