SCIENTIFIC ABSTRACT GUDOVICH, N.V. - GUDRINIYETSE, E.YA.

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• Collection: Scientific Abstracts
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• Sequence Number: 2
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

On the ;,Iechanism of the Electroreduction cf Lead in SCV"1r'-.2.-,~--7/22
Pyrophosphate Electrolytes
ASSOCIATION: Kiyevskiy politekhnicheskiy institut, Kafedra fizicheskoy i
L I
kolloidnoy 1-himij. (Kiyev Polytechnio Institu"ej Chair of Phy-
sical and Coilaidai,'O'he:Astry)
SUBMITTED: March 19, 1958
Gard 3/3

OVCHPLRP,IIKO, F.D.; GULUVICII, N.V.
Waterproof Crimean bentonite. Bent.glirq Ukr. no-3:23-29
'59. 04IRA 12:12)
1. Institut obahchey I neorgunicheskoy khimii Al USSR.
(Crimes-Bentonite)

5(
3OV/23-1 - 59-5-8/9- 5
AUTHORS- Ovcharenko, F.D., Correspond-.ng Member of the AS UkrSSR,
Blokh, G.A.,.Gudovich, N.V., Lomov, Yu.1.
TITLE- Pyrophyllite, a New Dielectric Filler for Cable Rubber
PERIDDICALt Dopovidi Akademii nauk Ukra-'AnsIkoi RS)R, 1959, Nr 51
PP 489--493 (USSR)
ABSTRACT.- The authors made a study of the physico-chemical properties
of Ukrainian pyrophyllite of the Zbrankov deposits,
Zhitomir region, with the purpose of PDplying it in cable
rubbers as a dielectric filler, instead of chalk and talc
(imported from the Urals). The Zbrankov pyrophyl.1--te wac,
found to consist in its basic mass Of 854, of highly
perse pyrophyllite mineral, about 15% quartz with trac~~3s
of talc. The structural formulas of pyrophyllite and talc
are as follows; pyrophyllite - Al 2 f S1 401010H)2;
talc- 3M90 '4Sio-l' H2 0. The opticall constants of pyr.)phyl
Card 1/3 lite are Ng- 1.600 - 1.594; Np - 1.552-1-555F,

SOV/21-59-5-8/25
Pyrophyllite, a New Dielectric Filler for Cable Rubber
Ng-Np - 0.048-0-039; of talc Vg - 1-575-1-590;
Np - 1.538-1-545; Ng-Np - 0.037-0.045- Chemical composi-
tions of pyrophyllite and talos from the Urals are shown
in table 1. Mixtures of pyrophyllite were substituted
for talc and chalk, as shown in table 3, subjected to
pressed vulcanization at 1450120 for 10-60 minutes. The
analysis of the results of testings showed in table A
indicates that the physical and mechanical properties :~f
the rubber remained unchanged both before and after ageing
(24 hours -long, at 7002 in the air) and did not differ
from serially-produced insulation rubber. Hencet pyrophyl-
lite is a new effective dieleitri(; filler for cable rubber.
It is the most hydrophobic of all agrillaceous minerals,
its heat of moistening is close to zef,-,. the value of
water sorption at P/Ps - I is Os2 nmol/g, the dielectric
constant is 7.7, angle of dielectric losses 9-121,
pH - 6.5. Thermal treatment and grinding may intensify the
Card 2/3 heat of moistening, value of water absorption and

JV/21 9 :2
Pyrophyllite, a New Dielectric Filler for Cable Rubber
dielectric constant. There are 4 tables, 1 micm.Dho~:o,
I graph and A Soviet references.
ASSOCIATION: Institut obshchey i neorganicheskoy khimii AN UkrSSR
i Dnepropetrovskiy khimiko-.tekhnologicheskiy institut
(Institute of General and Inorgani-, Chemistry of the
AS UkrSSR, and the Dnepropetro-sk Chemico-Technologii-,al
Institute)
SUBMITTEDz February 18, 1958
Card 313

83279
3/021/6o/,~oo/t)oi/r)oq/oi_,
o A I 58,402'Y9
AUTHORS.~ Ovcharenko, F.D., Corresponding Member of the AS UkrSSNi Blokh, 11.
A.i Hudovich, H.V.; Yoffe, A.I.
TITLE. ActIvated Diatomite - a New Rubber Fl.lt~r
PERIODICAL~, Dopovidi Akademlyi nauk Ukraylnslkoyl Rrkdyayi;~:koyi Sotsialistychncyi
Respubliky, 1960, No, 1, pp. r-.4 59
TEXT: In his other work (Ref. 2) the first author showed that pyrop4yl-
lite can be used in the manufacture Df rubber cables, yet the strength of rutber
obtairied with its use Is relatively low (60 kg/cm after 30 - 60 min of vulcaniza-
tion at 1450C), wh-1ch calls for a strengthening of such fillers throagh activa-
tion, The authcrs used 'he following a~tlvating age_rts4 I/ &1camon OC-2 (OS-2)~
an activated Crimean diatcmite (a quar~ernary salt of diethylaminc-methylglycolic
et"Iner) that lnc~reases the qtrength criteria bY 50 - 6(% as compared to unactivat-
ed fillers during a short period. fon17 4 - 10 %.In inst,:ad of 30 - (50 min and more)
and accelerat-es the process of vuicanization~ 2) carbazolin, a quarternary salt
of imidazole derlvatlves~ 3) equa"L.Izer A, a preparatica Gf mixed cation-active
and non-ioncgen types, 'The Crimean diatomice consisted of (In SiOP 65-38-
Card 1/2

83279
S102 ! 16'000,0100 1 /0:0/o 13
Activa~ed Diatomite - a New RuLter FtlLer A158/A,~29
CaO '2.00~ M.203 15.43,,~- M90 2-~3., Fe,.30;, 5-822-1 SG~ (K, Na) C1. 0.5. Even
when alcamon 09-2 was introduced or. the rollers into a rubber mixture
filled with natural diatomite, strengthening of the rubber and acceleration of
vuls.anization were observed. Tine lndlcat.,~d positive resul.ts shou1d te expla.lned
as a change in the chemical nature cf the diatomite surface into an organcph*141.lic
surface, and ty the peculiarities of the structure Df natural diatomite, whicn is
-:apable of interactling with tne stz-urture :~f rubber, Tab.'e I 6ncws chemtoo-me-
chanlcal properties of' rubler-- obt,ained with t;he use of pyrophyl-lite and diatom-
ite. Table ~ zhows the percentage cf activating subEtance6 In rubbers at various
regimes of vul~anizatlon. Tab1e 3 give:- the rez-ult-q of the adding all-,amon to
rubber (in .%) under various ?cnd1HLcns of vu--:-anizat.lon, !%hiere are 3 tab'je--- -and
3 Soviet referencee.
ASSOCIAT 10-N. In--' ytu,. zagal'noyl ta neorganichnocyl k-himiy! 0 UkrSSR ta rnzipro-
petrovs1kyy khtirdko-tekhnologicimyy irsfytut. (Institute of General
and inorganic Chemistry of .he AS UkrSSR and ttie Dnepropetrovsk
lnsl~14.U-?e)
SUM---7.r`rFX. Auj~2et --I, lqc~q
C,tr-,�

KUDRA, O.K.; GUDOVICH, N.V.
Cathodic polarization in lead pyrophosphate solutiona.
Zhur.fiz.khim- 34 ao,7:1616-1621 JI 160.
(HIBA 13:7)
1. Kiyevskiy politakhnichaskiy institut.
(Lead pyrophosphate) (Polarization(Jglectricity))

S/110/60/000/009/002/008
E021/E455
AUTHORS: Ovcherenko, F.D., Correspofiding Member AS UkrSSR,
Blokh, G,A., Candidate of Technical Sciences,
Ol'shanskaya, L.A., Engineer and
Gudovich, N.Y,, Candidate of Chemical Sciences
TITLEI~ Pyrophillite - A New Filler for Cable Rubbers
PERIODICAL- Vestnik elektropromyshiennosti, 1960, No,9, PP,5-8 V
TEXT. The pyrophillite found in the Ukraine was studied as a
possible dielectric filler for cable rubber. Physico-chemical
tests showed that it consist9d of 85% finely dispersed
pyrophillite with 15% quartz and a trace of talc: The optical
constants are close to those of talc. Experiments were carried out
on the rubber KC -50 (K5-50) which contains 24,2% talc and 49% chAlk,
It was shown that replacing either or both talc and chalk by
pyrophillite had no effect on the electrical characteristics.
After five days soaking in water they were practically unchanged,
Similar results were obtained when pyrophillite was substituted
for fillers in other rubbers, Experiments were also carried out
Card 1/2

S/1.10/60/000/009/002/oo8
Eo2i/E455
Pyrophillite - A New Filler for Cable Rubbers
on the rubber KS-50 to find the effect on the physico-mechanical
properties of the use of pyrophillite instead of the other filleTs
In particular, the stability after prolonged ageing at 120C was
Lnvestigated, Very similar results were obtained by using
pyrophillite, Thus, using pyrophillite in quantities up to
50 to 60% results in satisfactory properties of the insulating
rubber The presence of rich sources of pyrophillite in the
Ukraine have, therefore, a substantial technical and economic value-
There are 6 tables and 2 Soviet references,
SUBMTTTED. May 5, 1.960
Card 2/2

C, I -I
3/021/61/000/004/012/013
I'S D D213/D303
AUTHORS: Ovcharenko, F.D., Corresponding Member AS UkrSSR,
Blokh, H.A., Hudovych, N.V.p an d Shchychlko, Z-V-
TITLE: Use of activated diatomite for strengthening rubber
PERIODICAL: Akademiya nauk Ukrayinslkoyi RS-R. Dopovidi,'no. 4,
1961, 504 - 507
TEXT: This paper describes the effects of small additionsof ami-
nes on the lensile strength of rubber. The following amines were
i
A: 1) R (Armine-2HT), where R is the residue of margaric
4se 2N"
(C H COOH) or nonadecanoic (C H COOH) acids. This is a white
16 33 18 37
0
waxy substance melting at 53 C and soluble in benzene; 2) PaMICH 2
CH 2CH2 Nil2(Diamine.S), where R is a mixture of residues of Venta-
decanoic (C H COOH) and margaric (C H COOH) acids. This is a
14 29 16 33
yellow waxy substance melting at 29-300C, and soluble in isoamyl
Card 1/4

Use of activated diatomite
alcohol and methanol; 3)
S/021/61/000/004/012/01~
D213/D303
clot-%, CH, CjgH37 CH3 CI
N
C161%.'/ - \CtI, cl#H"/ \C~q?
(Arquade-2HT), a yellow substance melting at 69-700C, and soluble
in benzene and dichloroethane; 4) 0 H CONH -0), a white
17 33 2 (Armide
waxy substance insoluble in water but soluble in organic solventso
melting at'68-690C. The experimental :resUlts are given in Table 2-
A second set of experiments was conducted by mixing the amir~es di-
rectly into the raw rub-ber preparation. The results obtained 8howed
a considerable improvement in the tensile strength of the rubber
and twofold acceleration in reaction time. Comparison of results
shows that the activity of the amines deposited on the diatomite is
less than the activity of the directly admixed amines. The reduced
activity in the case of the activated diatomites can be e:tplained
Card 2/4

3/02 61/000/004/012/013
Use of activated diatomite ... D213 YD3 03
by the elementary structure of the diatomite and the active add*i-
tive. Apparently one of the amino groups of these compounds combi-
nes with the structure of the diatomite, thus reducing the availa-
bility of these groups Lor. the forination. of, an, inopolysulphide com-
plexes which on decomposition produce active sulphur. The greate'r
activity of the directly admixed amines is, therqforet bimply e.%~_
plained by the greater concentration of the active amines which
also help to accelerate the reaction. The action of the amines is
to give the diatomite surface a greater affinity for the rubber.
This tends'to distribute the.diatomite.,better through the mass of
the rubber thus further increasing its strength. There are 3 tua-
bles a~_d 3 Soviet-bloc references.
ASSOCIATION: Instytut zahal1noyi ta neorhanichnoyi khimiyi AN URSR,
Dnipropetrovs'kyy khimiko-tekhno-lohichr-yy instytut
(Institute of General and Inorganic Chemistry, AS
UkrSSR, Dnipropetrovsk Institute of industrial Che-.
mistry)
SUBMITTED: December 26, 1960
Card 3/4

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I . I
GUDOVICH, N.V.; KUKOVSK-EY, Ye,G,; OSIROVSKAYA, A.B.
X-ray study of montmorillonite containing substitution
cations. Rent. min. syr. no.2:36-40 162. (MIRA 16:11)
1. Institut obshchey i neorganicheskoy khimii AN UkrSSR.

~2/000/011/011/013
S/021/
D2 OY?3 07
and Kakovslkyy,
AUTHORC: Kallonov, Ye. M.,,~~dovy Ye.H-
TITLE: The effect of long-chain quaternary ammonium salts on
the porosity of bentonite clays
PERIODICAL; Akademiya nauk UkrayinB'koyi RSR. Dopovidi, no. 11,
1962, 1479-1481
TEXT: The authors studied the possibility of improving the swell
ing characteristics of bentonite clays on firing, to obtain the d
sired porous light-weight product uaed aB.a filler in concrete and
ferroconcrete. Only few natural bentonites develop the required po-
rosity in the absence of any additiveq. Ubing Kurtsevo, Cherkassy
and Gorbak bentonites, it was found that swelling may be induced
during.firing, by replacing the natural inorganic exchange com-
plexes of montmorillonite with tetraalkylammonium cations (the al-
kyl.groups being large). The beneficial action of this treatment
is ascribed to the fact that the quaternary ammonium cations ad-
sorbed on montmorillonite are only partially removed on heating to
Card 1/2

S/021/62/000/011/011/013
The effect of ... D202/D307
400 - 5000C, leaving a layer of 0C which is then.oxidized to C02 as
the temperature rises above 800 C. Owing to the low softening tem-
,perature~of montmorillonite the CO' 'md-y.-then exert a bloating ac-
2 3
tion, giving ris*e to droducts of density as low as 0.22 g/cm . The
required effect may be controlled by selecting the length and.
,structure of the alkyl groups in the organic*cation.
ASSOCIATION: Instytut zahalnoyi ta neorhaftichnoyi khimiyi AN URSR
(institute of General and,-Inorganic Chemistry of.'the
AS UkrSSR)
PRESENTED: by F. D. Oveharenkop Academician
SUBMITTED: January 31, 1962
Card 2/2

GUDOVICH, N.V., kand. khim. nauk; OVCHARENKO, F.D., akademi-k, doktor
- _ . -1 "im. nauk; CHUGAY, 0. D. C Chubai, 0. D. 1; BORISOVA, T.S.
(Borysova, T.S.]; CHORNOUS, D.G. (Chornous, D.H.] ;
ZAKANAVSKAYA, T.I. [Zakamvolka, T.I.]
Effect of the nature of filler surface on rubber strangtheniago
Khim. prm. [Ukr.] no.2:45-48 Ap4o 163. - .(XM 16:8)
1. Institut obshchey i neorganicheakoy khimii AN UkrSSR
(for Gudovich, Oveharenko). 2. Kiyevskiy zavod "Cheryoniy
gumovik" (for Chugay, Borisova, Chornoust Zakanavskaya).

GUDOVIGH, N.V.; OVCHARENKO, F,.D.
Formation of organophilic montmorillonite in ion exchange.
Koll. zhur. 25 no.4;407-411 Jl-Ag t63. (MIRA 17:2)
1. Institut obshchey i organicheskoy khimii AN UkrSSR, Kiyev.

C W _1 R.. . :: :, , ! f r : .- :V . , , ,: .: : ~ \f %, , , ~,, , ;- .:
MiT 0., Ye.A.; KOH, I'J,A, . OV--Hf-', ENKOj ~ . _: ~, 1~ .. .,~ I., .. . . 1. 1 ., -", , .
Activation of ?ac:11n with the cat' or.-Etc ',ive allbst&r~!~ ",I_Ikam,~r
OS-2.1' Kozh.--obuv. prom. 6 no.9;13-16 S 164.
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,UDOVICH, R. A.
Gusovich, R. A.
" On Methods of quantitative Determination of the Protein in Blood
Plasma and Serum." Vtehkt~nt State Medical Int.1 imeni V. 1-"- Molotov.
Tashkent, 1955. (DiR -ertation for the dt.-gree of Can&Lbite in Biological
Sciences)
SOt Knizhaya letopial ITO. 2?, 2 July 1955

V C~T Y ITS', K lyS r f.. T.- q
Sal ti n(,,-cLt, wfj thcd r f i v,,- 1~,, t ~np tle serum Ir
22.319-3114 lt~:.
1. Kafadra bickl7lit.1i (zav. kFif-~drcm
kentskovo gc.,sudarE;tv.?nn,-,gv meJ!ts'nskog-, Anstttuta,

GUDOVICH, R.P.
Subvital Congo red test in children with rheumatic diseases,
Vopr.pediat. 18 no.2:43-46 mr '50. (GLKL 19:3)
1. Of the Propedeutic Clinic for Children's Diseases (Head -
Docent V.N.Golldins) and of tho Yaculty of Pediatrics (Head --
Prof. L.D.Shtsynberg), Voronezh Medical Institute.

I ; : ! I , - ill T? l; ;,. 1, ; *., it 7f: 11,~ I im : F~I ::.
BUGLLY. B.M.; ZHUOV, Ye.V., GIMOVICH. V.A., RODIONOVA, V.K.
71~7_ -~-P_,.,;ev~K.4,00,~
TSNIIKOD-54 carbomide prime coating for transparent wood finishes.
Der.prom. 5 no.5:3-6 My '56. (XLRA 9:8)
1. TSentrallnyy nauchno-issledovatellakty lustitut nekhanicheekay
obrabotki dreveslAy.
(Wood finishing) (Urea)

GUDOVICKU, II.Ye.. inzh.; SAMARIN, I.Ta.. inzb.
Experience in the production of higher
the reduction method. Mael.-zhir.prom.
(Alcohols)
aliphatic alcohols b7
25 no-909-41 159.
(MIRh 12:12)

.UTHORS 6"'-Poldyrev, L. I. (Senior foreman of the large section shop) and
Gudovsa k1kov K.S. (Research Engineer, Central Works Laboratory),
110-3-16/22
TITLE._ Organization of roll char)ging on a 650-mill. (Orgailizatsiya
perevalok na stane 650.)
RIODICA.L. "Metallurg" (Metallurgist), 1957, No.3, PP-31-33. (U.S.S.R.).
STRACT,.' The finishing line of the 650-mill at the Azovstall Works
consists of two three-high stands and one two-high stand arranged
in one, line,, the maximal diameter of the worki% r is being
680 mm. The mill rolls two types of rail, I-sect.Lu_ 6irders,
channels, squares', large angles and other sections. The senior
mill foremano F~.D. Krishtofovich has organized kiis roll -chang ing
team so effectively that the roll-chariging time has been reduced
by 7 minutes. Details of the organization axe given in this
article. Krishtofovich pays great attention to the preliminary
preparation of stands and rolls, the correct positioning of
roll-men and mill ojeratorsp the rational utilization of cranes,,
and maintenance of the sequence of operations. It is considered
C ar 1. that the adoption by other teams of these organizational methods
,would enable mill productivity to be increased by 2
There are two diagrams and one photograph.
SOCIATION., "Azovstall" Works (Zavod "Azovstall").
ILABLE..

AUTEORS: Gorenshtejn, z-:irric' Candid,7tes
Technical Sciences, P~,gorzhel s'L-.i.7,
-,_Shapiro, Yu.A. , Enr,
1,-ineers
TITLE; An Effective 1-~Icthiod of Rolling Roll Surfc;ces
(Effektivnyy sposob nakatki valkov)
FL,;'RIODICAL: Metallurg, 1958, ITr 8, pp 25 - 2r/ (J.'JO-R~
ABSTRAUT: The roughening of roll surfaces is advantag-
eous in the first fev; days of operatiori L;UU, the author
points out, not all metbodo o1: rouLc,,-hcrii11;, are equally
effective. The 1150 bloominE; mill at thc "Azovstal"'
Works has forged 55 Kh steel rolls which, since 1949,
have had 20-30 mm lonC notches cut on their surface with
pneumatic chisels, a ziE-zag line also being cut in the
first pass (Figure 1). This proved effective only for
the first 2-3 shifts. Mletallisation was tried in various
forms including bead weldinU, but these viere found
unsuitable because of crack extensions and excessive
vibration. After a study of methods used at the imeni
Kirov Ifforks and the Kuznetskiv metallurr~icheskiy kombinat
(Kuznetsk Metallurgical Kombinat), the 'i'
Avostal" Works
Cardl/2 adopted a special system. In this, a toothed cutter up to

Ai.,, Effective ble'Ghod of RolliriL.- Roll Surf3cos
~~ V/ 11 __ C - _~ I - _~Z~ - 10/ 18
100 iam vide with b curvature to Tit tile 1`011 SUrfaCe is
used to form rin-s which are then cut up by a GKhVS-steel
L
roller 50-80 MM %,r ide (Fi-uxe 3), tO Livc a surface
covered in plyramids 2.5 mr., .,ii,--h and 5 x -;~ at the tase.A
c~omplete blooming-mill roll is processeJ by one inan in
three hours. Lead prints taken dail,~ lia-ve stDwn that tbe
pyra-faids wear slo%vly and crazin,, is delayod and orientated
L)
alonr-- pyramidal bases. The method las been adonted for all
L
reducing stands.
There are 3 figures.
ASSOCIATIOD: Zhdanovskiy me-tallurgicheskiy institut (Zhdapov
Metallurgical Institute) and Zavod "Azovstai'"
(nAzovstall" Works)
Card 2/2 1. Rolling mills--Performance 2. Rolling mills--Equipment

Wtiali611091 'kant
Tvinaces Open, Bearth
"Aftonstruotion of 150-Ton Martin Furamoes at the
Mkinsts Metallurgical Pactory.0 S. S. Qudovshohlkow
4..-1. Spirin, Engineers, Uzuets NetaLlurgicaL
0 -bi as 8 pp
wo 8
36~onstruction of 150-ton open hearth furnaces of,
Skinete plant, which Increased their Cap "ity to--Ub
94 350 tons, resulted In & considerable Lnareas4i in
their hourly production rate. Certain modificatISIGS
OW/Zagineering (Cootd) Aug 48
WA to be made In view of now requirements. Coft-'
ilderable Labk'of proportion is observed between Is-
o;roased produotIvIty of furnace and almost unaltti4d
#ilume of chooker brick and slag pockets. Sketcb~wl
show furnaces aul divonsion tables.

GUDOVNHCHIZOVA.. I-J.; LUMM, D-V-
Discussion on general problems of biology in Poland. Bot.thur.
41 no.3:443-449 Kr 156. (nu 9 . 8)
(Poland-Blology)

GUDOVSHCIIIKOVA, I.V.; UHEDEV, D.V.
"Guide to Russian medical literature." Edited by S.Adamso F.B.
Ro,t---. Reviewed by I.V. Gudovshchikova, D.V. Lebedev. Sov.
zdrav.ig no7:88-89 160. (MTRA II-A)
k"i".L.uWHY--MICINE) (AIWIS, S.) -IOGEERS 9, F. B. )

GUWVSKkYA, L. A.
The Second All-Union Conference on the Preparation and Analysis of
High-Purity Elements, held on 24-28 December 1963 at Gorky State Uni-
versity im. N. 1. Lobachevskiy, was sponsored by the Institute of Chemi-
stry of the Gorky State University. the Physicochemical and Technological
Department for Inorganic Materials of the Academy of Sciences USSR, and
the Gorky Section of the All-Union Chemical Society im. D. 1. Mendeleyev,
The opening -address was made by Academician N. M. Zhavoronkov. Some
90 papers were presented. among them the following:
V.- P. Gladyshev, L. A. Gudovsk U a..A. 1. Ivankova, and D. P.-
Synkova. Fluo rim etrici-ind oscillographic pollarography methods for determining Te
and Se, respectively, in high-puritybismudiwith sensitivity of 10 s tolo-6o/..
11 U.47_ IqAo /Vej - 4;F6 -Y 7- 7~

GUDOZI;941K. N.Y.
Modification of terminal panel@ of selective communication linen.
Awtom., tel-em. i aviazI 2 no. 8:35 Ag 158. (MIRA 11:8)
1. Starahiv alektromekhanik Zaporoshakoy distantsii signalizatsit
t svyazi Stalinstoy dorogi.
(Railroads--Telophone--F.quioment and supplies)

GUDNIN, N.N.
Efficient method for extending the receiving lines of off-
shore pumping stations. T-zv. vys. ucheb. zav.~ neft' 4- gaz
A
7 no.9:89-92 164. (NIRA 17M)
1. Azerbaydzhanskiy institut neffti i kh!jd-" im. M. Azirbekova.

GUDM40VIGH V.S.-(Dnepropetrovsk); MSSAKOVSKIY, V.I. (Dnepropetrovsk)
Contact problem for a flexihle ring reinforcing a cyclindrical
shell. Izv.AN SSSR.Otd.tekh.nauk.MskhA manhinontr. no.2:113--
156 Mr-Ap 161. (MIRA 14:4)
(Elaoticity)

CUDR1NIEGE
see also: GUDRINIYETS

GUMMUMO E. (Gu&inieces, E.]; IYEVINISHI A. (Ievins., A.]; VAIL&G, G.
-- - --- G. J; KHErmemG., D. (Kreleberge, D. I
Sulfonation of~-djcstones. Report No.15: BindonemLlfonic acid a4d,
its mIts. Vestia letv ak no.2:Ul-IU 161,
1, Institut kbim4i AN lAtviy*-)y SSR.

GUDRINIECE, E.; IEVIIIS, A.
Academician Gustavo Tanago. Vestis Iatv ak no.3:123-.128 161.

GU;)RINFMTSE,--3.jGudriniece 3.](Riga); IYMNISH, A.[Ievins, A ](Ri
VANAG G. V
anago, G.)(Ri a); STIPNITETSE, Ill. [Stipnisce: H.]rRigs
MAT=p Z. [Mateuse, S. IrRiga)
Sulfonation of /f-g~Uetones. IIII.Salta of 5-phanyloyclobemanedlone-
1. 3-mulfo-2-acid (phenidonsulfo-2-acid. Vestis Latv ak no.8:95-98
160o (Ew 10:9)
1. Almdenlya nauk Lstviyokoy SSR, Institut khimiyi.
(Ketones) (sulfonation) (Phenyleyclohexanedione)
(Phanidons) (Sulfonic acids)

k--v uj R I N I
E~
M AN

-R-A-Ift-h-a --nif fig sal
ch4m. USSR.
xamints on of the salt-3

(m0 an of
2-nimindalle-I 3-di
-t
&
16
h
k
it
l
n I
l
q
e
rot
-ac
o
ll
on
t
t.
ut
diona (1p augg m that 1, In . vo
of Fec-l-N
JI in tho eniol orra (B), A md calone-mi
.orm (A), and A
co 0 Mom)*
'NC -C
CA '-C - ti c If,;-,

'c0 OH
0

'

b
yellow but tlii lik-NotIts of
ke Other" il
.0.
jitlier: tht~h' Tt
want
to
-or 1,
lik

o, I.violet b
givin ,r b via Clrygali, OLn(l. Of
11-lis0i , Cld
tted that both thelogi
d ti
bi
h

ik
ht, i
.
ii milar
a
t, an
ssugge
L~Orm. --S'wc~4 rmtisqcllov~.In aq~soltkm 4re whitain Ill
L& A
.SLA AFTALLmok, LITERATURE CLAS01WIGH
7

CA
inte Structutat ol Z-naltro-1.34ndandicaus and of its "It.,
I" %*,a V41mullill 11, Y". (andrillictle (I-1tviJall State Umv .
14 lgaY J~ ,,rm. Chem. V Y,S R. 19, 1551 -.3( 11049K Ftaxi
tr.m.,Lstion)-Sec CA 44. 1047-1 IS L. M.'
1/41
/ 7,q

GUDFtT-N1y:--,rSE, E. 'Cu. In Latvian
GUDRINIYETSE, E. Yu. -- OGrowing Substances with Condensed Nuclei.*
Latvian State U, 1952. In Latvian (Dissertation for the Degree of Candidate of Cherdcal
Sciences)
SO: Izvesti-va Ak, Njjuk Latyiysko-y SS . No. 9, Sept.. 1955
- --T-11-1-1 -------n
"i -,,. ~ I 11~ 11 , 1: ! '! 1 1!1

GOO
C\
hemistry - Analytical chemistx7
Card 1/1 0 Pub. 145 - 3110
AV%bWs I Ievinsh, A. F., and-Crudrinetse, E. YU*
Time Determination of K' sodium tetraphenyl borat,6
POrlaftea Zhur. anal, khim. 9/5., 2-70-274,9 Sep-Oct 1954
Abstmo A new method of volumetric determination of;K., with the aid., of
sodium tetraphenyl-'borate, is described. The K is separatedby
a surplus of titrated sodium tetraphenyl borate solution (accord,
ing to the Ruedorf and Zannier method)p andthe aurplus of the
reagent is determined not by titration witha silver nitrate
,solution but with an amonium chloride solution. Results obtained
by the new volumetrio determination methods are tabulated.
Fight references: 5-Germaji; J-LBA ahd 2-LWR (192.5-1953),
Tables.
Institution State University, Riga,, Latv~SSR
Sutmit.ted July 159 1954

.-A
;f Chloromethylatlon of 2-mathyluohthalevie. G VIOUZ
and R. Cudriniect. Ixall" Azad, V0111
-1000 Russlan).-(2-
1034, ~ MO' No. ROL 103
M di 1'.1-naphthyl)methyl thkwkk (1). m. 821, "w prepd.
1. 4 ykW by licatigg 2-methyinaphthalent with Pam-
r: M sebydc, UsP04. and Mw& HCl at 86-90* for 3-4
hrs I te m, W. N-1(2-P-tethyl-i-naphthyl~netllyll-
p1cm
pipaldine (11), ell oil prqA. briuceing under
p1perldino. ' The plants of
codling awn. I Tm=
1110.- The pyridluluin AWda
in. lGs* In
0011),*Wupt id,b
of 1, M. 130 y~slodng a mixt. ol
soW. of I In Rt&O with div yrIdlat- imldy... 'V_j(S-
Methyl Amlicitanikk, m, pi~Opd.. by
boiling IL soli. of with Ar Re. was sol,'in-
j04 W.C11"It Of
ELOH and i Atm. but Im In
I*Ith' JMWI" L" HN
t
W
bath for (3-me Y14"m htbyl)lfttlc
rield im Occod
seedlies, in. M40': by
refluit ag I a of th roulft.
(2-metb J- with: 0%. with tbe
WtL to, in. I
In. I
1-ca lith I)m"tam
t (IV), I W" "by,
th~ tmmating toduct with
20-M waster
Ms. gydralypi-saftV with KaOH gave z 2-Meth 1-
S$ ~ IMt Wb_
naphthA)RO
stitutin of b.,
216-20,s by wi
AMMW
5
"'0

-~ i 7m mfff"M;
I i.":; I , F ~-,
I I I I I :. ~ , ~~Fui~qr~ 'I'

II I At 11- 111 iI i I
U U AN I
USSR/Cheml stry
Card 1/1
Authors Oudrinietee, E. Yu.;.and Vanag, G. Ya.
Title Reaction of certain alcohols with 2-nitroindandione-1, 3.
Periodical Zhur. (Yb. Rhim, 24, FA. 4.- 725 - 729, April :L954
Abstract During the heatiM of nitrolndandione witha large surplue.,or tappropyl'
or primzry isobutyl 'alcohol takes place the oplitting of the,~: f ivsramber-.
ed nitroindandione ring and a corresponding aster of omega-n,itroaceto-
phanone-o-carboxylix acid is formed. Heating of.nitroindandione;with a
large surplus of Isopropyl or benzyl alcohol.or acenaphthenol leads to
oxidation of these alcohols into aldehyde or ketone and nitroindardione
reduces to nitrosoindandione. Five references; 3USSR since 1939;
1 German since 1888; 1 Ragli.sh.1933. Table.
latvian State University
Submitted August 31, 1953

XSM/Chemistry - Synthesis.mothods
'Card, 1/1 Pub. 1.51 - 31/37
Authors i Gudrinietss,'E.; -Heylinds and Vanag, G.
Title t Nitrodimedons and. sow, of its derivatives
Periodical Zhur. ob. khim.. OR 3.063-18661# Oct W4
4betract t A nel wim thod. f or the d6rivition vf, hiti6dirAedofis ihrou*h. nitration of dimedone
With. t~mib nitt" ic, acid preseiiteC, .-Ce'rtain nitiodimd6ne silts with!inor-
ganic -and organic -bases, Well -solVbli in water ~ and aloohol, are described.
The dei:Lvation of chloro- and bromo-derivitives of nitrodimedons is explained.,
The.prejAration of iaonosemidarbazons and monophenylhydrazone of nitrodimadone
is describedd Eight referlences: '7-USSR and 1-USA (1907-1953).
Institution The.Latvian State University
Submittid Xv 7, 19W

q w

ib~of, titr I'; (I
On &

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:
m 44 PSI?
i
P
oj
of i
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tee
1
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,
28
UOK A601
C f

).~,
- ;
(
i
1
91 ml-
3A ene! rl~.I Ili

I:. Tht
dj
,
with piptshifne at
rootii ttuip~I tl~onl
It in.
ygrumpic, It pierate, ra.
01

dry- ljyrp atr;-

7
4" .4 jq~
wiff,
th
v 4:1 Itil; it Eli If; imilt i h,tlkll k ~,641.,
It(
,
p iji:
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g
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.
No 7
P~l
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it

J I y C- TS E
- 715
(oi- A. 10,00, i, 1;~
aullaos with P041u, F ; I _; 1.
R. oudrinlece (State
4 atvla).. Mut, At"
1
- '
d
simines Iti I% AcO R solm, lit.
?
dOns,: r4n& jjW run 2.
o
f&.~thywaine tit If few tubutAsIlWe, *mht6cyo&-
lift aim,
i cmiAttv in TInj th

sic,
pvts; to: Q
-..Wuswot c I
k dout Tm
(B(C,H4),j -WA.' kit F
geiNT *Th AI, ond lit Oid filtemi.,

t~
t,h
f-fdn
1
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1
f
fi~i
t
ys,
dual
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"
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it) A

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e
re
s
, t
o
Ig
anal
rJ515-best cgftit
,
i
w
.
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y

77
tV
T-CROrametbYlation of 14,V.~
m and
Vanags (Lattviam State Uni~.; Wg7i
%37757F.-Wskad
Ail Y,
Reiting with stkrWk 4.5 hic a mixto-A 30-6 v with
rat nualdehyde, 130 Mt. AcOIL~ 10.8 ~ml. Mt,% or
a-
0 Jlw"Ild
HPg,, and 80 itill 'mued. ITO at WV'~ 101.
UE Wived by diln. witli HtO pv~ 83.0%j Cr6de
-ju. 280'(darkiens'at 262-7; front
Alefit . Treati lh.CrOs it jAve ointhr*qu1mp%je,'-. )VIlm
f
i%
thracen,
much tar im formed4rom which aornt a
I I be
m
g it cred along with 14.71/'0 W(clilproulcilIA)
dedv. -For btst results the abovt n&t. must, be finnittrwt
j
146 WE bath whickhad btcn prOteated t -6, Red
080 - Refluxto
_W'kh'"ceSa WpMd4io W-30-mln, 01v 04.0 9,10
t
m; 2049 (Ito t 11-
eating I with PhNIft at 1009 2~brs..%Itu v
ly
in. gOS fro 11k,
T
so _!~4aexaf acids,* replitd on'diln
it A i
Z

R

A44 0.4
h

bell
trdm 2 1
oilro
a1so: fort
1,144m
AcOll,
decoinp,
cyplohr
ills
,yclohe)
i n,1500

fafed o3
4 i-Brm
arm#Q
of tbe s
gave EL
gave 4
treated
PlgHINJ
gave 1,1

Ing Simi
135* (m
mccoill

gave.

kjW

yo Ir.. I
-cot I
~
4 4y
*
5:11334
'IV
114 49V 4
*140 -OXI
0ft, tmm,
011
.
4anediWis ~ (U) -~ witil OUT vl:. fi, -
4121- In*: tht~- e Ile. r
o
11
U!
oq
-610644114 M-1 1_41 IIXI
Ch
~~
1
it OAN N60H 1 o4ve U.; aa4 a,

YvAth ~PhN Ti In G
jj
Wilt. &Wlad we
'
1
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1179~
s,,* 1444, which' jift-Hao
ve
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tq feat
lix.,066-
I.
ir *7" Ch
M"
a -tit,
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ITV
~~_h b
"DmIA"IN6 t i wi 1:
4c. m. lar.' Mixing C414a br,
the "470 oeilo. of U pvt the toth W,
Co.
?hllffi tive 89
h
V
is PJ 41
Vi. m. QJ
4,2JTcjr,1Vfii~ mki. in. 119-1" ii~
cloff,104" m.* 143 0, N.OH ca"k s
whii amd 10,911~0t)*Uqws ppt~io

- ;' - I ~,; 7:i.;[., -!;' ;. -, t: .1 - I ,, . . I i i. I ,
q . .. . .

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RUH] MM
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favols a diit~ jf~Kcl k 4v

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j
Similar UL41folo
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j,.(jj(Me gaVj Ufi6 y
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J1.

PHASE I BOOK EXPLOITATION SOV/4226
Riga. Universitat;
Uchenyye zapiski, t. 14 Khimicheskiy fakulltet, 4 (Scientific Notes, Vol 14,
Chemistry Faculty, 4) Riga, 1957. 251 P. 550 copies printed.
Eds. (Title page): A.F. Iyevin'sh, Professor, Doctor of Chemistry9l L.K. Lapin',
Member of the Academy of Sciences Latviyskaya SSR, Professor, Doctor of
Chemistry; G.Ya. Vanag, Professor, Doctor of Chemistry; Tech. Ed..- A. Peterson.
PURPOSE: This book is intended for inorganic chemists and scientists in the ceramics
industries.
COVERAGE: Th-9 book contains 22 articles on organic chemical synthesis and analysiE
and the phvaicochemical properties and compositions of ceramic and refractory
materials. No personalities are mentioned. Figures, tables, and references
accompany the articles.
TABLE OF CONTENTS:
1. Iyevin'sh, A.F., E.Yu. Gu4rlpi etse, Yu.A. Bankovskiy, Ya.A. Tsirul. Reecttm-re
"TZMe Syl-j~, 5-cyclohexanedione Trioxime 3
of Divalent Iron
Card 1/4

Scientific Notes (Cont.) SOV/4226
2. Yanson, E., A. Iyevin'sh, and E. Gudriniyetse. The Use of Sodium
Tatraphenylboron in Quantitative Analysis 9
3. Groakaufmanis, A., A. Vei8s, and U. Alksnis. The Luminescence of
Alumin- Oxide Hydrate 17
4. Balodis, Yu.R. Resistance of the Boundary Layer, Electrode Potential.,
and the Corrosion of Aluminum in Aluminum Sulfate Solutions 25
5. Vanag, G.Ya. Lignin as a Reagent for Qualitative Determination of
Aromatic Nitro Compounds 35
6. Vanag, G.Ya., and A.K. Aren. The Interaction of 2-Bromo-2-phenyl-1,
3-indandione With Primary Amines
7. Rowdan, I.A. On the Predicted Mechanism of the Alkylation of Naphthalene
and Diphenyl. With Alcohols Using a BF3 Catalyst 49
8. Grirshtayn, V., E. Kalninya, and G. Villere. Study of Usninic Acid and Its
Derivatives 63
Card 2/4

Scientific Notes (Cont.) SOV/4226
9. Grinshteyn, V., and Z. Leymane. The Concentration of Phytotoxins of
Prunus Padus and Their Influence on Ferments 79
10. WArlivan, V.P., and P.N. Odintsov. The Problem of Prelininary Hydrolysis
["Pre-twdralysis"I With Wati5r and Acid Before Cooking Cellulose in the
Sulphate Process 89
11. Eiduks,, J. Properties of Typical Clays of the Latvian SSR 99
12. Eyduk, Yu. Ya. Properties of Gypsum Calcined at Low Temperatures 123
13. Froydenfelld, E. Zh. The Use of Lignophosphogypsum for the Production
of Binding Substances 155
14. Freydanfel'd,, E. Zh. The Production of Caustic Dolomite 161
15. lyesalniyetse, A.A., and Yu.Ya. Eyduk. Properties of Some Opaque,
Easy Melting, Non-Lead and Non-Boron Glazes for Structural Ceramics 167
16. Freydenfelld, E. Zh.j and U.Ya. Sedmalis. The Possibility of Using
Mengame C~sn-Hesrth slW for the Production of Binding Substances 173
Card 3/4

Scientific Notes (Cont.) SOV/4226
17. Eyduk, Yu.Ya. Retarders of the Setting Period of Gypsum Calcined
at Low Temperatures 179
18. Maksimova, O.S. The Interaction of a Fireclay Refractory With a
Fluorine-Containing Glass Batch 195
19. Freydenfelld, E. Zh., and A.A. Apsitis. Physicochemical Properties
of Compositions of the S)rstem CaO-Bn0-TiO2 201
v
20. Ozoli9s, J., and J. Eiduks. The Role of Magnesium Oxide in the Pro-
duction of Silicate Brick From Dolomitic Lime 211
21. Eyduk, Yu.Ya., P.G. Pauksh, and O.S. Maksimova. The Influence of Some
Technical Factors on the Properties of Enamel Coatings on Cast Iron 221
22. Eyduk, Yu.Ya., V.G. Reyne, L.A. Skuya. The Physicochemical Properties
of Easy Melting Faience Glazea 225
AVAILABLE: Library of Congress
Card 4/4 JA/rn/.sfm
9/29/60

gq BUM

nd,
1 967
al d A Were, gnu on&

en U
ih-"
sAt.
Ar4d

OUDRUTIETSE, E.; JJJYJAJJD, 0. ; VANAG, G.
- '~ll
Om*p?a"d"o"n*n1ltu~m; derivatives of ~-dlketones- Part 1:
dimedon with iodozobenzene. Zhur.ob.khimo 27
0 '57.
The reaction of
no.10:2737-2740
(MIRA 11:4)
I.Latviyakiy gosudarstvemqy universitat.
(Cyclohexnedione) (Benzene)

AUTHORS: Gudriniy,--tse. E. Yu-
-vilug'g, G, Ya.
TITLE: u-,d it3
(2-Yitro- 5-feux trsikloe-ek!.andion -1. 1
proizvodnyye).

PERIODICAL. V -3092,
Zhurnal Obohchey Kli-i-,r..", I QI L ur pp. 3087
(USSR)
kBSTRACT, In cotine-,tion with thu i!7L tkie field
of the nitroderival -1 ires of cy-~]-jc -the I examined
1-pheny1cyclohexandicn .. 1;3 whii-n -,.-i i-., resembles

. I - j.
5, 5- dime thylcy,- loll,2 xar.,j i o1, of
thi6 itaxandicr. N,-,s lutherto u:tir~v,.-vtn. ~lhpxandicjn
1,7, -Le produl-ed by Cal, deni~ct tio."I af vi~:h
malinic aoid re3idua-.3. The uutho~-3 method
described -.in publications ")j redv.~,ing r., of
cox~denset-ion from 7 h, u L, -- :3t L' ~h -,,roduct
Octa-ined in p,` di,4
r ec ry stal Z~-d. Me ~iJ. ~. ratia u:
pattern u,3ed in the ~f
The aqueru5 5oiut--on of tbe
Card 1/2 sy,-,!~~haxandi.),% ha:-, tz,-".d r-splaces

2-Nitro 5-Phenylcyclohexandion - 1 and 2.1 Li
Derivativeg
the carbonic acid frem tl~e oarbonates, hydr.-jt~en
sulfide from sulfides. 2hereforc- the. salt forriation ea-slly
takes place. SomQ si~jts of
orCanlc case3 ware uroduc,~~t, 'rlju~ 0i.%: of
5--phenylcyclohexandion -!,)- won improved and ~-,-nixro
5-plienyl--yclohexandion -1,1, hitherto not de,,crilbed irl.
publicatiors %va3 obta:nerl, The followitq: der-ivet--res zl'
thia compound viere alz3o prcduced. :.nl ~-, w%zn and
ore,anic bases; 2-halcren -2-nitr4z, -'~ - paen.,; icy,:
-1,3; mono semi cart.,o zone, the monioxim and the hydroj,en chloride
salt of 2-am'nz) - r-phen,
1 6. j1CY01GheX~Lnd--Loi - 1, 3.
There are i table. and 19 referenf~c~,3, L.1 of which are Sla-ric.
ASSOCIATION: Latvian Statp University (Latv1y9kiy gosudar-3tvennyy
univpraitet),
SUBMITTED: October 31; lg.,.)b
AVAILABLE: Libraxy of Conf;res3
Card 2/2 1. 2-Nitro-5 phony! eye lohexsn dlon 3--Derivatives

so V/1 56 - '.--j e-4-334/49
AUTHORS: Gudriniyetse, E. Yu., 1yevin'sh, A. F., Vanag, G. Ya.
TITLE: The Sulfurization of Cyclic P-Diketone-, *,With Sulfuric Acid in
J. -aiklicheskikh
the Presence of Acetic Anhydride (Su-, ~fl:mrma:.Iye t
P-diketonov sernoy kislotoy v prisutstvii uksusnago angidrida)
PERIODICAL: Nauchnyye doklady vysshey shkoly. Khimlya i khim-icheskaya
tekhnologiya, 1958, Nr 4, pp IN6-750 (USSR
ABSTRACT: The following cyclic P-diketones were sulfurized with 98'%0
sulfuric acid in the presence of acetic anhydride: 5,5-dimethyl
cyclohexanedione -1 3; 5-phenyl cyclohexaneu _ione ~', 3; indan-
dione-1,3; 2-phenyl indandione-1,3; perinaphth-indandione and
bindon. The sulfurized P-diketones were separated in form of
sodium or potassium salts. The mechanism of the sulfurization
with sulfuric acid in the presence of acetic acid probably
proceeds according to intramolecular rearrangements. At first
a dark-red colored product is formed. After 5-15 minutes a
white deposit (III) precipitates.
Card '11/2

SOV'/116-~8-4-34/49
i
The Sulfurizaticn of Cyc;1ir; P-Diketones With Sulfuric Acid in the Presence
of Aoetic Anhydride
?o3
CO C14 + 2 SO, 4o-,
C H 311. G H CH --lop-C H '__'Co_'C (so
6 4 Co 2 6 4-co-' 2 6 4'-,C0,-/ 3H)2
P
so3
IV
There are 1 table and 12 references, ;4 of which are Soviet.
ASSOCIATION: Kafedra organicheskoy khimii Latviyakogo gosudarstvennogo
universilleta im. Petra Stuchki (Chair of Organic Chemistry
at the Latvii=State University im-ari. Petr Stuchkft)
SUBMITTED: April 28, 1958
Card 2/2

1-~. 13 .2 0 0
Mranslation from: Referativnyy zhurnal.
L
68266
SOV/81-59-10-34855
Kh1miya, 1959, Nr- 10, Pp 171-172 (USSR)
AUTHOR-'- Ludriniece, E., Lielbriedis, I.
TTTLE, The.Sulfonation of Aromatic and Hydroaromati)f Compounds by Dioxanesulfo-
trioxide. Il. The SuLfonation of Tetralln
PERIODICAL- Uch. zap. Latv. un-t, 1958, Vol 22, PP 115-117 (Latvian)
AEOTRACT. 4,2 g of tetralin are added to 7.2 g dioxanesulfotrioxide In 15 ml of di-
chloroethane, after the end of the reaction the solvent is eliminated, the
residue is treated with NaCl solution and the Na-salt of the tetralinsul-
fonic-2 acid (I acid) is obtained, yield 77.4%; S-benzylthiuronic salt of
I, m.p. 1600C. 5 9 of the Na-sall. of I are heated for 30 min with 15 9
5'
M.P. 54 - 580C; from 11 by the action of concentrated Nflj~OH the amide of I
Is obtained, m.p. 130OC; by heating (water bath, 30 min) Il with aniline
the anilide of I is obtained, m.P. 153 - 1540c; by treating II with piperl-
dine the piperidide of I is obtained, m.p. 108 - 1091C.; from Il and phenyl-
hydrazine the j3heny1hydrazidelof I Ic obt-a-Ined, m,p, 160 - 1620C (decom-
po-=ez). The preceding communication see RZrOhim, 1958, 46736.
L.Ya.
it is treated with ice, 1.1 g of acid chloride of' .1 (11.) are obtained,
PCI

L ( T')
AUTHORS i Giidriniyetae, E. Yu. Vanag, G. Ya,
TIT-LE. Investigations in the Field of Cyclic Arylazo-F-Diketona6
(Issledovaniya v oblasti tsiklicheskikh arilazo- diketonov)
I.'I'he Condensation of Indandione-1,3 With Diazo Lmpoand3
(I. Kondensatsiya indandiona-1,3 s diazosoyedineniyami)
PERIODICAL: Zhurnal Obshchey Kjjimii, 1958, Vol. 28, 11r 1, pp,~~8-62(USSR)
ABSTRACT: I. the present experiments the authors connected indandione-
-1,3 with different diazotized amines an(] their derivatives.
The reaction takes place most rapidly in an al1zalino, uomo-
what, more slowly in a neutral and mostslowly in an acid me--
dium. But the final products are most purely obtained in an
acid medium. The conversion of indandione with diaz,~~ salts
in an acid medium is unknown, on the contrary it is pointed
out in publications that cyclic diketones only react in this
manner in an alkaline medium. The products of the conversion
of indandione with diazo compounds - arylazoindandiones - are
Card 1/3 crystalline compounds and difficult to dissolve in ordinary

Investii-ations in the Field of Cyclic
tion of Indandione-1,3 With Diazo ComDounds
T n :3 -
solvents, especially in glacial acetic acid, diox-ane and
acetone. The table enumerates the products of the reaction
of indandione with diazotized aromatic amines. 2-phenylazo-
indanione-1,3 was more thoroughly investigated. It is pos.
sible that the name of this compound does not correspcnd
to its strtutrep as, accordina 'too published datLL, it- pos.-
sesses the structure of phenylliydrazone. The authors for the
present are of the opinion that phenylazoindarthone exists
in two tautomeric forms (formulae I and II) which are in
equilibrium. Accordinj to conditions the hydxazo- or the
azo-form (I and II) reactS. In favor af formula II speaks
the solubility of phenylindandione in alk-ali, under the for-
mation of essolates which re-form the unchanged phenylaze--
indandione (II) on acidification. Thus the most favorable
conditions for the synthesis of 2-phenylazoindandione-1,3
have been determined and a number of other 2-arylazoindand-
ione-1,3 were synthesized. Some derivatives of phenylazo~
indandione-1,3 viere produced, too: p-broL-.op~ienyla--oi-ndand'~cne,
p--nitrophenylazoindandione, p-sulfophenylazoindandione. the
Card 2/3 monoxyn of phenylazoindandione~,. phenylhydrazone and the azine
701-1-13/63
Investigations in the Field of Cyclic Arylaz O-P-Dike tones. I. The Ccndensa.-
tion of Indandione-1,3 With Diazo Compounds
of phenylazoindandione. There are 1 table, and 12 references,
5 of which are Slavic.
ASSOCIATION: Latvian State University
(Latviys1dy Cosudarstvonnyy universitet)
SUBMITTED: December 24, 1956
AVAILABLE: Library of Congress
Card 3/3 1. Chemistry 2. Cyclio compounda-Chemioal reactions

AUCHORS: Gudriniyetse, E. Yu. Iyevin'3h, A. F. , Van,-.-_, G. Yn.
TITLEs The Sulfonation of P-Diketones Vlith Dioxnne-Sulfotriox.Lde
(Sul Ifirovaniye -diketonov dioksan - 3ullfotriok_~;idom)
II. indandione-1 ,~-Sulfonic Acid-2 and Its Salts (II. Indan-
dion-1,3-sul'fonovaya-2 kislota i yeye soli)
PERIODICAL: Zhurnal Obshchn- 11.'~,-4i_19jk5, Vol.'23, Ur 1,111P.95-100)(USSR)
ABSTRACT: In the preceding paper it was shown that indandione-1 3 is
easily sulfonated with dioxane-sulfotrioxide (= D - so ) on
which occasion indanione-1,3-sulfonic acid-2 is Produc~d.
In -oublications it is maintained that the nulfonation pro-
cee~s over the enole form (see fcrmula M), on -which occa-
sion the addition product is then formed, which finally in
the hydrolysis yields the sulfonic acid in our case (see
the process of reaction). It was, however, not possible to
isolate the intermediate product (II). On addition of the
indandione to the solution of D - 130 a reaction iramediate
ly takes place, the dissolved substa.Le warms up (cooling.;
Card 1/3 with water!) and after 2 - 3 MinUtC3 indandion~--1.3-3ulfo-

7
The Sulfonation of P-Diketones With Dioxane-Sulfotrioride. 11. Iniandione-
-1,3-Sulfonic Acid-2 and Its Salts
nic acid-2 (III) is rrecipitLted. The solution of this preci-
pitate in water does not show any reaction to the sulfate-
-ion from which follows that the assuined inter-mediate pro-
duct (II) does not fonti. It seems that thia reaction takes
place im.3ediately with the 17drogen of the active raothyl
;,-xoup of indandione-1,3 that in other words the indandione
joins the sulfuric-anhydride molecule under the formation
of indandione-1,3-3ulfonic acid-2 (III). In the case of an
exces:-, of D - SO and at elevated te-r,oratures indandione-
-1,3-distilfonic Lid-2,2 (IV) is produced %,hich is isolated
as a sodium salt. The crystallized indandionsulfonic acid
(III) could not be recrystallized. - 1"hus it was proved that
the indandionoulfonic acid in contrast tG 2-nitroinda;idione
is easily converted to the enole-form Und that eith-ir :.nly
one sulfo group or the sulfo -roup to~;ether with the enole
,-,roup Xticipate in its salification. The cobalt-, nickel-
and manganese-salts of indandionsulfonic acid form complex
compounds with pyridine. There are 6 references, 9 of aiiich
Card 2/3 are Slavic.

T,)- 1 -20/65
The Sulfonation of P-Diketones With Dioxane-Sulfotri-oxide. II. Indardione-
1,3-Sulfonic Acid-2 and Its Salts
ASSOCIATIONt Latvian State University
(Latviyakiy gosudarstvennyy universitet)
SUBMITTEDt December 24, 1956
AVAILABLE: Library of Congress
Card 3/3 i. Chemlatry 2. suironea

79-28-5-14/69
AUTHORS: Neyland, 0. Ya., Vanag, G. Ya., Gudriniyetse, E. Yu.
TITLE: Iodonium Derivatives of P-Diketones (Yot1oniyJYje''proizvodnyye
P-diketonov) II. Thernal Decomposition of the Phenyl.dimedonyl-
iodonium (II. Termicheskoye razlozheniye fenildimedonilyodona)
PERIODICAL: Zhurnal Obshchey Khimii, 1958, Vol. 28, Ur 5,
pp. 1201 - 1205 (USSR)
ABSTRACT: Earlier (Reference 1),the authors had shown that the dimedo-
nium (5,5-dimethylcyclohexandion-1,3) reacts very easily with
iodosobenzene with the formation of an iodonium compound -
-phenyldimedonyliodonium (formula II). The recrystallized and
dried product is very stable at usual temperature, contrary
to the non-purified one. But also the purified product M)
decomposes on boiling in aqueous solutions. From the decompo-
iodized benzene and the phenyether of iodo-
sition products
'
dimedon (III) could be separated, the composition of which is
proved by cleavage with acids in phenol and conversion into
Card 1/3 the phenyl ether of dimedoae(IV)~ This ether is easily cleft

79-28-5-14/69
Iodonium Derivatives of P--Diketones. II. Thermal Decomposition of the Phenyl-
dimedonyliodonium
into phenol and dimedone by acids. The decomposition of
phenyldimedonyliodoniu-a is illustrated by schenie 1. Depending
on the place of the break of the C-J binding,the phenylether
of iododimedone iodized benzene arn obtained. The invectiga-
tion on the decompositionof phenyl. dimedonyliodonium shows
clearly that this compound iiu:; the structure of iodonium salts.
The phenyl etherr.')f dimedone have hitherto not been described-
Thus in the thermal decompositionof Dhenyl "I 1.7.1edonyliodonium
a new compound f-jrms, namelythe pheny, etneof iododimedone,
besides,still-iodized benzene and an oily product of unknown
structure. In the reductiog, of phenyl ether of the iododimedone
a new product, the phenyle ier of dimedone was obtained., In
the case of direct phenylation of dimedone -.,ith dip?jertyl iodonium
bromide new products resulted: the phenyl ether of dimedone,
the phenyl dimedone -. the diphenyl dimedone and the phenyl ether
of phenyldimedone. There are 8 references, 2 of %hich are
Card 2/3 Soviet.

79-28-5-14/69
Iodonium Derivatives of P-Diketones. II. Thermal Decomposition of the
Phenyldimedonyliodonium
ASSOCIATION: Latviyskiy .-osudarstvennyy universitet (Latvian State Uni-
versity)
SUBMITTED: April 15, 1957
Card 3/3

GURINJIFTs'p- j6 [Gudriniecep E.] (Riga); IYEVIN'SH, A. CIevins,A.) (Riga);
VANAG, G. LVanaga,G.] (Riga); XURGAN, D.
Research in the field of cyclic arylazo-,4-diketones. IV. Metallic
complexes of phenylazodinedons. Vestis Latv ak no.9:101-105 259.
(ERAI 9:10)
1. Akademiya nauk Latviyakoy SSR, Institut khimii.
(Aryl groups) (Ketones) (Dimenthyleyelohexanedione)
(Metals) (Phenyl group) (Azo compounds)
(Complex compounds) (Nickel) (Cobalt)
(Copper) (311ver)

~ (3)
AUTHORS: Gudriniyetse, E. Yu.~ Iyevin'sh, A. F., SOV/79-29-3-44/61
TITLE; Sulfonation )f P-Diketonee (Sullfirovaniye P-diketonov)-
IV- 5,5-Dimethyloyclohexanedione-1,3-sulfo-2-acid and Its Salts
W. r-,,5-Dimetiltsiklogeksandion.-1,3-sullfo-2-kislota i yeye
soli)
PERIODICAL: Zhurnal obahchey khimiiv 1959, Vol 29, Hr 3, PP 959-963 (USSR)
ABSTRACT: Th, sulfonation X P-diketones with dioxane sulfotrioxide
(Refs 1,2) takes place easily, an well as with 98 H2so 4 in
the presence of acetic anhydride (Refs 3.4). In the viork under
review the authors continued thi, sulfonation and their
attention was specially attracted by the salts of the above
acid (dimedon sulfo acid). Besides the acid, two series of
its salts were synthesized, with an equivalent of the metal M
and with two equivalents (II)
Card 1/3

Sulfonation ~f P-Diketones~ IV- 595-Dimethylcyclo-
hexanedione-10-sulfo-2-acid and Its Salts
CH CH
H2 CH2
Oc CO
QC
HSO 3Me
(I)
SOV/79-29-3-44/61
CH 3,, 1111CH3
H2 C El2
0C OMe
)so-
so 3Me
(II)
The acid is obtained in crystalline form. Dimedon is formed by
heating with hydrochloric acid,. Ammonium-, sodium-~ magnesium-9
calcium-, strontium-, barium-, nickel-, and cobalt salts9 with
an equivalent of the metal, were obtained by saturation of
the aqueous solution of dimedon sulfo acid with the correspon-
ding chloride. All metal salts, with the exception of nickel-
and cobalt salt, are obtainable in crystals and are soluble
in water. The aqueous solution of the salts with an equivalent
of the metal has an acid reaction. The dissolved dimedon sulfo
Card 2/3 acid yields sulfo salts with organic bases (e.g. with aniline,

Sulfonation if P-Diketones. IV. 5~,5-Dimethylcyclo- SOV/79-29--3-44/61
hexanedione-1,3-sulfo-2-acid and Its Salts
pyridine,and quinoline). With the same ease it forms salts of
the enol form (H). These salts are obtained by neutralizin,-, the
aqueous solution of the sulfo acid with carbonates or hydroxid-
es until the weakly acid or neutral reaction. The salts of
alkaline and alkaline-earth metals, as well as those of copper,
zinc, and manganese, have an alkaline or neutral reaction in
aqueous solutions, depending on the properties of the cation,
The ammonium salt of the enol form could not be obtained. As
is the case with other sulfo acids, the reaction of the
dimedon sulfo acid with 3-benzylthiouronium chloride leads
to the benzy1thiouronium. salt (III). There are 41 table and
5 referencesq 3 of which are Soviet.
ASSOCIATION: Latviyskiy gosudarstvennyy univeroitet (Latvian State Universi-
ty)
SUBMITTED- January 16, 1958
Card 3/3

50) 14. (-()~J/7~-29-6-2 6/72
AUTHORS: Gadriniyetse, B.0 Vanag, G., Strakov, A., Neyland, 0.
TITLE: 3ulfonation of tl -Diketones (Sullfirovaniye ~ -dikc-tonov).
VI. Derivatives of Indandione-1,3-!-~ulfonic-2-.-icid (VI.Proiz-
vodnyye indandion-1,3-3ullfo-2-kisloty)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 6,
PP 1893 - 1897 (US5R)
.kBST--UCT: There are no data available in publications regarding the
derivatives of the keto group of the talfonic. acids ol the
ketones and aldehydes (Ref 1). Although the dioxi;ae of the
indandione-1,3-sulfonic-2-acid obtained from its dipotassium
salt and hydroxylamine hydrochloride in the presence of K 2CO3
was described (Ref 2), the authors were not able to attain
the same results, neither with the disodiura nor with the di-
potassium salt of this acid. On addition of alcohol the initial
product, and not the dioxime de9cribed, precipitated.
Card 1/3

Sulfonation of P-Diketones. VI. Derivatives of Indandione- SOV/79-29-6-26/72
1,3-sulfonic-2-acid r.---OMe
C
[ISO3Me C so3M e so3M e
WO
NOR NH
M (II) (III)
The experimentt3 under review indicated that the oxime (I) is
readily forL:ied on boiling of the sodium salt of the indandione-
1,3-sulfonic-2-acid in glacial acetic with hydroxylamine-hydro-
chloride, even without anhydrous sodium acetate. It is hardly
soluble in water and is tranaformed by bromination to give the
2,2-dibromo-indandione-1,3. The oxygen of the keto group of
the sodium salt of the acid mentioned is substituted by the
imino group with compound (II) being formed in the Me-NH 4* When
treating compound (II) with the alcoholic solution of :iodium
hydroxide or sodium ethjlate compound (IV) (Me-Na) was formed,
the bipolar structure of which was conifirmed by the ultraviolet
Card 2/3 absorption spectra. A number of derivatives of the indandione-
1,3-sulfonic-2-acid was thus synthesized (the oxime, senicarba-

Sulfonation of ~-Diketones. VI. Derivatives of '-()V/79-29--06-26'72
Indandione-.1,3-sulfonic-2-acid
zone, imine and phenyl-imine in the form of the sodium, ammonium
or aniline salts). Bromination of the sodium salt of the oxime
of the above-mentioned acid and of the ammonium salt of the
imine of the same acid (V) yielded 2,2-dibromo-iridandione-1,3.
Phosphorus pentachloride forms with the sodiual salt of the acid
the 2-chloro-indandione-1,3-sulfonic-2-acid-chloride. Its bro-
mination results in 2-chloro--2-bromo-itidandione-1,3.')Vhen
boiling the salfo-chloride with alcohols SO 2 develops, which is
transformed into 2,2-dichloro-indandione-1,3. There are I figure
and 11 references, 6 of which are Soviet.
ASSOCIATION: Latviyskiy gosudarstvennyv universitet (Latvian State Univer-,lity)
SUBMITTED: May 19, 1958
Card 3/3

S-. -36 10 66419
AUTHORS: Oudrinijstseq Vanag, G. Ya., SOY/20-128-6-23/63
Academician, AS LatvSSR, Sakhar, L. Yu.
TITLE: Condensation of the Sodium Salt of Ethyl Eaters of Indandione-
193-carboxylic-2-acid With Diazotized Nitroanilines
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 126, Nr 6, pp 1182 - 1184
(USSR)
ABSTRACT: There are no publication data on the interaction of indandione-
1,3-derivatives with aryl-azo compounds. If the interaction re-
action of the latter with eaters of cyclohexanone-carboxylic
acids is carried out in a neutral or weakly acid medium, cyclane-
dion-aryl hydrazones are formed (Refs 10-12). In a strongly al-
kaline medium, the'ring is disrupted# and aryl hydrazones of
keto-dicarboxylic acids are formed (Refs 12-16). The authors in-
vestigated the products of the condensation reaction of the o-,
m-, and p-nitroanilinee mentioned in the title with the sodium
salt also mentioned there. Apparently, the reaction proceeds
with a displacement of the reaction center (Ref 18), not accord-
ing to Dimroth's mechanism (Refs 19,20). The'aryl-azo coupounde
M obtained by the authors are yellowp insoluble in water, but
Card 1/3 well soluble in methanol, ethanol, acetone, ether, glacial _K

Condensation of the Sodium Salt of Ethyl Eaters of
Indandione-193-carboxylic-2-acid With Diazotized
Nitroanilines
66419
SOY/20-128-6-23/63
acetic acidg and dioxane. On heating an alcoholic solution, the
corresponding 2-(nitrophenyl)-hydrazone-indandiones-193 (II, see
Diagram) are formed. (II) were also obtained In an alkaline
medium (pH- 8-9). The ethyl eater of the 2-(p-nitrophenyl)-azo-
indandione-l,,3-carboxylic-2-acid (Ia) crystallizes from diluted
ethanol with I molecule of water, and yields a monoxims. On
boiling the alcoholic solution, 2-(P-nitrophenyl)-hydrazone-in-
dandione-193 (II) is formed. The ethyl eater of the acid (Ia)
dissolves in alkalis while the color turns into red. At the same
time, the indandione ring is hydrolytically split, and the sodium
salt of the ethyl ester of the p-nitrophenyl hydrazone of o-car-
boxy-benzoyl-glyoxalic acid is formed. On acidification of the
solution, this acid (III) is also separated in the form of a
yellow precipitation. The red disodium salt (IV) of the acid (III)
was isolated by heating the azo eater (Ia) with sodium ethylate
in ethanol. Besides, the well water-soluble salts of the acid
(III) were produced: monoammonium-, di-diethylamine-, and di-
piperidine salts. The acid (III) is resistant to hydrolysis, and
Card 2/3 splits off the ethoxyl group only after boiling in an acetic,/

66419
Condensation of the Sodium Salt of Ethyl Eaters of BOV/20-128-6-23/63
Indandiono-1,3-carboxylic.2-acid With Diazotized
Nitroamilines
sulphuric-acid mixture for 5 hours. Here, the p-nitrophanyl
hydrazons of the o-carboxyphenyl glyoxal (T) in formed. Thus,
the authors succeeded for the first time in producing derivatives
of cyclic 0-diketones. There are 20 references, 5 of which are
Soviet.
ASSOCIATION: Rizhakiy politekhnicheakiy institut (Riga Polytechnic Institute)
SUBMITTED: June 29, 1959 tr-
Card 3/3

-GUDRINIYETSE, E._Yu., Doc Chem Sci -- (diss) "Nitration, sulfonation,
and azo-coupling of -diketones." Rigs, 1960. 26 pp; (Riga Polytech-
nic Inst); 400 copies ' i - not giveni list of authors' works at
end of text (37 entries ; (KL, 32-60, 145)

-GUM1141FLE's E.; VANAG, G. [Vanags,G.1; TIRE, E.
Research in the field of cyclic arylazo-,*.-diketones. VIII. Condensa-
tion of 5-phenyleyclohexanedione-1.3 (phenidone) and 4-carbethoxy-
5-phenyleyclohexanedione-1,3(4-carbothoxyphenidone) with diazotized
aromatic amines. Vestis Latv ak no.2-.87-94 060. (EEAI 10:1)
(Pbenyleyclohexanedione)
(Phenidone) (Ethoxycarbanyl group)
(Aromtic compounds) (Cyclic compounds)
(Aryl groups) (Amines) (Ketones)

GUDRII,q a); MIN'SH, A. (Riga); VANAG,G. [Vanaga,G.j (Riea);
NATELIS, L. [Nakele,L.] (Riga); KREILE, L.
Research in the field of cyclic ar7lazo-A - diketones. V. Metal
complexes of 2-phenylazoindendiones-1,3. Vestis Latv ak no.10:
107-113 '59. (EULI 9:10)
1. Akademiya nauk Latviyakoy SSR, Institut organicheskogo sinteza.
(Aryl groups) (Xetones) (Metals)
(Cyclic compounds) (Phenylazoindzndione)
(Complex conpounds)

GUDRINIETSE, E. [Oudriniece,E.] (Riga); VANAG, G. [Vanags,G.] (Riga)
Research in the field of cyclic arylazo- VI. Reaction of
.06 -diketones -
aryldiazo compounds with 2-banzyldimedon. Vestis Latv ak no.U;73-78
*59. (EEAI 9:11)
1. Akademiya. nauk Latviyakay SSR, Institut. argnicheskogo sinteza.
(Aryl groups) (Ketones) (Ato compounds)
(Benzy1dinethyleyclohezariedione)
(Diazo compounds) (Cyclic compounds)

AUTHORS: Gudriniyetse, EVA Tanag, G S/153/60/003/01/031/056
Grantag Z.- B011/3005
TITLEs
PERIODICALt
Interaction between Sulfuryl Chloride and Beta Diketones
Ixveatiya vyeahikh uchabnykh zavodeniy Xhimiya i khimicheakaya
tekhnologiya, 1960s Vol 3p Nr I* Vp il;-121 (USSR)
TEXT: The authors proved that sulfuryl chloride is a good chlorination reagent
for cyclic 4.-diketones4 Ethers dioxanes CC14, 1,2-dichloro $Uses chloroform, and
benzene were used as solvents. The highest yields in dichl:ro-A-diketones were ob-
tained in dioxane at a ratio ofA-diketone s sulfuryl chloride - I 1 2-5. The re-
action was carried out at different temperatures between 0 and 800. At higher
temperatures, the reaction proceeds faster,.but only 2,2-dichlorodiketones-1,3 (I)
are formed. Without a solvent, the reaction proceeds very vigorously, and the
product becomes resinous. Application of ultraviolet light (quartz lamp) and
anhydrous aluminum chloride did not lead to the formation of sulfochlorideo. The
compounds produced are: 2,2-diabloroindandione-1,3, 2,2-dichlorodingdoftet? 2,2-
dichloro-5-phonyloyclohexonedions-1,3, and 2,2-dichloroperinaphthindanHone. The
table (p 120) shown the reaction temperatures, solvents, yields, and the calcu-
lated and measured melting points of the products obtained. There are I table
Card 1/2

3/079 60/030/05/29/074
BOONO 16
AUTHORS: Iyevingsh, A. F., Apinitis, s. X., Oudriniyetee, 1. YU
Tanag, (A. I&.
TITLE: Sulfonation of P-Dikvtones~ VII. Crystallographic and X-Ray
Analyses of Alkali Metal aWd Ammonium Salts of Indandione(1,3)-
-2-oulfanic Acidl
PERIODICAL: Zhurnal obahchey khimii, 1960, Vol. 30, No. 5, PP- 1541-1547
TEXT: The authors of the present paper investigated the crystals of the
lithium-, sodium-, potassium-9 ammonium- and rubidium salts of
indandiono(193)-2-oulfonic acid. To obtain suitable crystals for the
crystallographic investigation, these salts were recrystallized from
aqueous ethanol. The experimental conditions are given. The mono- and
dihydrato of the nodiun salt of indandione(1,3)-2-oultonic acid wore
studied while the remaining 4 alkali salts occurred in anhydrous state.
Crystal class, axial ratio, volume of the unit cell, and number of
molecules in the unit cell were determined for each of these 6 salts.
4 tables give the spherical ooordinat*s of the individual lattice planes
Card 1/2

Sulfonation of P-Diketones. VIL Crystallographic S/OT9/60/030/05/29/074
and I-Ray Analyses of Alkali Metal and Ammonium B005/BO16
Salts of Indandione(1,3)-2-oulfonic Acid
for the 6 salts investigated. One table shows the parameters of the unit
cells of potassium-, ammonium-, and rubidium salt, 2 further table 15 present
the identity periods for the 3 lattice planes [110], [101], and[0111 for
the dihydrate of the sodium salt, and for the potassium salt of
indandione(1,3)-2-oulfonic acid. 4 schemes show the crystals inveatigated!::~/
in the oblique and top view. The authors further investigated the
solubilities of the alkali salts of indandione(193)-2-oulfonic acid in
water and alcohol at 200. The results are compiled in a table. The
solubility of the salt decreases with increasing radius of the cation.
There are 4 figures, 8 tables, and 2 Soviet references,
ASSOCIATION: Rizhakiy olitekhnicheskiy institut (Riga Polytechnic
InstituteT
SUBMITTED: may 11, 1959
Card 2/2

-'GUMIRIETSE, B.YLJVANkG, G.; HLUALIKE, L.
Sulfonation of &diketones. Part 10: Sulfonation of dimedoxi.
Zhur.ob.k.him- 30 no.6:1904-1911 Js 160.
(MIRA 134.6)
1. Rishakiy politekbalcheakly Institut.
(Cyclohexanedione) (Sulforstion)

GUDRINITICTSZ, &JO-VAN&G, G.; KA2KAL'ICR. L.
Sulfonation of A-diketones. Part ll*. Derivatives of 2-,dimedon-
oulfonle acid. Zhur.ob.khim- 30 no-7:2379-2387 J1 160.
(RDA 13:7)
1. Rishakiy politekhnichaskiv institut.
(Cyclohemnesulfouic acid-Spectra)
(Cyclohexanedione-Spectra)

I! I,! j:j
UIBFctr,E.) (Riga); IIEV NISH,A.[Iev-ins,A. ](Riga);
ga,G.](Riga); BRUNERE,V.(Riga); BANKOVSKIT#Yu.
[Bankovskia,M(Riga)
,;d1ketonem. II. Indandione-1,3-dioulfo-2,2-acid
Sulfonation oft
and its malts. In Russian. Vestis Latv ak no-3:1o3-1% 160.
(EM 10:7)
1, Akademiya nauk latylynkoy SSR, Inatitut khinii.
(Ketones) (Sulfonation) (Indandimilfonic acid)