SCIENTIFIC ABSTRACT GALPERIN, F.M. - GALPERN, G.D.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000614120019-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 19, 2001
• Sequence Number: 19
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

i I

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L 21085
;ACCESSION NRs AP5001982-'
IS
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ferveria,,-notic atoill. D-okl. AN SSM P65 no.~,:1011111-11044.
(\,' T :,!~ !C? . 1 )
D 165. - .. _.-O
1. Sub-mitted i,',IVT 6, 1965.

maim
L 15171-66- EWT(l) IJP(.c)..
SOURCE COEE. UR/0020/65/165/005/1641/1044"
ACC NR: AP6002419
:AUTHOR: Gallperin, F.-M.,
1ORG: none
TITLE: Magnetic moment and field on the nucleus of a paramagnetic atom
!SOURCE: AN SSSR. Doklady, v. 165, no. 5, 1965, 1041-1044
!TOPIC.TAGS:. paramagnetic alloy, nuclear magnetic moment, crystal structure, transi.6'
-7
Ition metal, magnetic field , nucleus
:ABSTRACT: The author shows that the magnetic moment and field(on the nucleus :of ani
iatom are associated with the crystal structure of a paramagnetic material. and that
'this relationship may be used to explain a number o portant phenomena. :The'dis-r
.tances between an atom and its closest neighbor in the crystal structure of transi-I
tion elements in the iron group are compared with tbn ave~rage radii of tbe~ 3d-a'bellg-.,-
iin the atoms. For this purpose,p the author introduces the characteristicinteratom-~
iic distance R:
:R 0,13 [(C/2)1-5,75C+ 51) for C> 8.
JR-0,13 [(C/2)2-4,75C+43j--f0r C < 8,
i:Card l/3----1-.----------- UDC-:.. 5319: ?262

L 15171-66
;ACC NR: AP6002419
where C is t1te electron concentration (the total number of 3d-a'nd 4a-electrons) in
Ian isolated atom. The author introduces the parameters Pa and. for binary unor-
dered paramagnetic alloys:
pa=0,64Zn-i(n-Ra)/A, P==0,64Xn,(rt-.R)IA,
where ni is the number of atomic neighbors; i=1 for closest neighbors; f=2 for next!
f atomic concentration of the:component in the alloy,
Iclosest neighbors; ca is the
IR = C +cbRb. A table is given showing A-moments and the parameter P forl
1 transGion elements in the iron group.' These data show that, for all transition elet
ments except nickel, p 0 W -
- 4)). 1b, mean Visfue fAw Q for all
%tjtdisqI was io.2ftie mitill fm twtft*tltll (rw--
filing I'lle" Vabirli prorlwally of" with lh.-v
lown lby WAltimann. Plit poraffin and
briamirthrri;m K - V - 0.0%*4 and it tur.1m. ftw
6 woniatic Y4 Ilwalbo"I N - ~ - ti.1074. F,w $War&.
mirthylernts Q - K wall hish. if-In. of pristaffle1hylk"Ge
to passiffin-cycLonir mixis. Invurmised Q - K. Repetillft 41
Ihe ell, Imalp within Immut.h,ist"Is ittriks did not chansit the
00 d4writionratia, TtwW&Mtmmnim4lmwtimrft%"ninont$ftI
ffw practirel d6pro4mictry In the aftalysift of prIngrum
fmahmus. In amism rawis thir vishm 0,21401 van he u.M.
F Mpecially rkh in ammatk hydrocubluns
the valise O."MI should be
Z
uwd, anti for paraffin prothiviol (llynthin fraction.) The
valor 0,21PC
It mile's VVV-
-i- 0 4 _4 i i ~O ~*_
16 4)
I a! ,TA t~ -IV"
14-1
181tivi lito ;its
Softio "rim 90 ad@@ a 3 0 1
0 0 0 00 00 0 0 Ow 00 0" lot 0 0 0 0 0 0 0 0
-9 - 0 * ~440 0 * 0 6 0 0 0 0 0090 0 0 0 * 0 0 *
0
see
woo
400
111110111i
!10
too
to 0

,- Ai.1 ) - T-,
~ ; . J .
institut-? of "in-ral Fuels, Acpd. of Sci., USSR (-1943-)
"Applic8tion of the Abbe Refractometer 6nd ".aldnan Coefficient in ll:rdrochrbon
Disp-rsinietry.11 Iz. Ak. Nauk SSSR, Otrlel. Tekh. llauk, No. i_',, 1.944
5R 52059019

10
is J;
~A
00 A
SO 0 1
00 A
00 &
00
goo
*of
004
a
go 01
go '31
go,
J, A I a Y & 0 111 )1
a 1. T IS V
91 ~Iiq P if
0 0 0 0 0 # 0 0 10-9-4-WIF,
NJ) Jim UJI 39141 A**A Q a In 4
ITU. PIATINIM UMII IN AULYTICAL HMOGNATION AS
DXMRWUAT7o# (w MxomB=. Nosey, 1. A. mi
aeltpern, 0.129 I:BuII6. Ac".
which am tabulated and charted, shows that above
catalyst given practically quantitative hydrogismatian
and d*kq4rogs=t.'Iom at bamseme md cyclobexame
respeotively. uster proper conditions. nw forimar
proceeds trais 50' to 150*C-, aM the latter at about
3250C. 4pllcabillty, to unknown mixtures Is "sumd.
B*LoL
:4
.00
.60,
-00
lee
foe
-00
gas
Noe
see
moo
goo
see
A 14 S L A09'IALLUftCAL UTCOIATUOR CLAWPICATWIS 61M Noe
lee
tasamij MAO 0.1':a(
511 two *-io litism 179
A AS
AV 00 11" it I Go 'm a a Ig PC i R a
ON 0. o 0 is a*see 0 0 0 o is 06 0 o 0 0 o 0 0 o 0 0 e 0 0 0 0 0 0:4 WS
00000000000 e 41 0 - ~._ __9 0 .0 _00 0 'g 0
At-

MMUL -M
fee***# -00000000000000 IWOM 00
'A. ~69
1, 4 11 U b m 11 A I, C 4 -1 1-
A 9- L-A-L-L-L 1- L-A- it -bra R I- I. A -V~, X IL-1-AA to Cc .
PD, t

.00

-00

wkSTS OF F'SEFRACrO'-"~' 1;' S,

M G "
'DROCAFTBOS. Gal!,ptr~~. Z. -im~:.ustttiv, I,.
-.
004 Tech.,S ci.). IS49, OC42,,;,n).
Acad. V.3.3.R., Idiv.
I
diiaijasion of the theory on vhich such mathor?~ are fomded. Tile
0* Vlvgter nne. ','iatarman !7:olliod Is oxn-iinof, in detail. and it Is
00 considerod that it is strictly applicable onit, lo tfiri,tj c~f -14 t.
frn-,,ions whose ~enernl type of structure is known, wic: U,-1- an :0 0
*0 arbitrary choice of a "standard" hontolo ous aories of pul,,nerized 11 V-0 0

hydrocqrbons cannot. be justified withnut stirt". e-iontnr~, dix~fi; W
nlthou;;h the s1rape or the curve R-- f ('-*.,) xhorn R is ,he s--. ref.
-ind Y the mol. wt. can, in the case of a s,~rlet or
hydro~erated fractions, Cive infornaptian ft.- to a.#i tv~7a of zoo
structure concerwid.
Petroleum Inart., Acad Sci USSR. P.
1

A119TALLUMIGOCAL UVISIAtkill CLASUMATION
A 10. 11 0
.
73,
1w 0
I I
I
2
q
I
IF 4
2 2
U D D 1, oil N't Is Run 1101o"Oti ItVA
0 0 0 * 0 0 0 0 41 0 0 0 0 000 0 0 0 0 0 0 0 0 0 0 0 0
0 0
0
1
:
0 0-9 _0 0 0 * 0 ~. * 0 0 0 0 0 0
0 * 0 0 0 0 0 0 0 0 0 G-t a a * 41 0 0

0 0 0 4' 0
--a-" -A, 8, 11 F 0. 1 P-M-4 M ~Mcx 10~114!
'so
746. RING ANALYSIS OF PMMATM PrZODUCTS. Museav, 1. A. and 00
00 riii Gal!porn, G. D. (Sell. Acad. Sci. U.S.S.R., Div. Tisch. Sei., 194,9, Fee
00
t ~ip A crit. discussion of the dietemination of hydrocarbon groups in '001
high-ml. vt produsts. Op. disperson UP and C lines Of H2) 12 tAkme
j ~1 1 :;so
an an Indication of the complete hydrogenation of the materI&I.
so,, Values -'>50.10-4 indicate that, arcimatle hydrocarbons W still be I:
00 a' 7
present. A nomogram is given relating op. ref. to mol. wt (50-700)
for ton hydrocarbon types, curves also roUto an. pt of paraffin-
0 ~0-
narhthens mixtures to nol. wt sp. ref., and 9 content. Zotimation
A Ir
1! of the averRge no. of naphthene rings, tic Ing , and paraffin 2- 1~ roe
1 1.400
chains can be made from a knowledge of and on. pt
of the hydrogenated all and ofthe an. pt pr:Loor to hydrogenati roe
One
The usual value of 0.85 to taken for multiplying the difference is
an. rt before # and after hydrogenation in order to calculate lave
I to o
aromatic rings, although ovidene* has bow obtained that In certain
IYALLUROKAL LJ?WMATbM1 CLASUPICATFOW
t~44
-L' 041 ant I i I CA ~1'
U 0 AT 10 111; Ita AAL %#two "*IV IN 9 a a I f
n
0 0
0 : *0 : : :16'D '00 0 e 0 - 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

A
A 6. D.
Chemiesl Abst.
Vol. VS No. 6
Kar. 25, 1954
General &;d Physf-391 stry
d (11C.-JClopentyleyclebexiLne.
a
n
.0i, and M. M.~ Ku
-09 r ix
-Anncc=ttm*thW*fdetn.tF ed.ofliquidh is
with dilatometric pyenometers. Ds. of heptane, butyl-
benzene, beptamethylnonant, Rnd methy1dicyclopentirl-
cyclohexane were found to change lineady betv"x-n -60*
and +20. EmpWxd equations wm developed to r,% p esi
Oanges in ds. vrith the temp. W. M. sttrubcrx -

Chemical Abstracts
Vol. 48 No. 5
Mar. 10, 1954
Conoral and Physical Chemistry
Tam it of of refraction an
onrature relation d diffritc-
tion. Ilauld hvdrocarbons at lo%v ternperittures, 0. P,
~r~
T--IajL&, L. A. Konovalova' and M. 'AL Ku"k-ON,. U.
1"11. -Nift;'Akad. Narsk
Obrchnov'p method ( C.A. 39. 158,50) was used, baued On the
M`Irr-actiou max. uncl min. tit the boundary of a 11(juid/gla",
I)III(C. fesulting limit the haviference 4 2 limuches Of a
n1outwillonlittie light tay, Otte (it which passcs through the
iquid, and the other through the plate. The its anti dif-
fraction of heplamethylionane, iiii-lhyldicylopetti)-tcyr!olte.rd pie.
and butylbenzerte changed linearly between +21) and -60'.
With a sufficiently Ifigh-tradc nionochrontatur pertnitting
the isolation of a 2-A. spectrunt r-ange, an(] a suffidently
great range of standard glasses. chinges in the is can be
detd. with a high degret, of accuracy in the app. ti~ccl; the
accuracy of the measutunents wa., within :EO.0001. Th,
sp. refraction caled. by the birctitz-Lorcuz formula i,
a function of the temp.. a:itl k lfimr it lower temps.
NA'. 'M. 91embVIC

Chemical Abet.
voi. 48 no. 6
War. 259 IM
Petroleums Lubricantso Wid Asphalt
r A-Z
S
15 vanal~t nit do;sij~ned~y the ~&u
Zelinskii's Ni + A40, catalyst (C.A. 18, 28M) at 100-12D
atm. and 2904009 converts the following aromatic hydro.
carbons into the correWnding hydroaromatic comptle.
&XY1kx4"e, PIMMY444tiecane, i$PkxYUWxaxs, Mellf)i-
cv:p, I 1.2-brurojobeffe. cyclohex ipheRY111"dAme, dio'(10%
=111arnt,
AWire". ' Neither homerization nor closing nor rupture oil
Rhe & and 0-membefed fings In any of the comptis. was In-1
dicated by physicochem. measurements, and In 'particu-
lar by the agreement between expU. and theoretical specific!
refractions of the products. A "enprated LOmstos" cats-'
lyst (C.A. 33, 8MI) was found to hydrogenate selectively
at 100-120 atm. and 2OD-30V all aliphatic d a& U
bonds, without attacking aromatic rings. Ir., 2-h
Its ash " fractions of Yursk kos-cluigyj napistim. W.
255-63~The application of the above method to a petro-
leum fraction, mol. wt. 1954M. and a refractometrici
a-unlys-6 of the products proved the no. of rings to.increase.
y~ffom I to 3. Practkally no hydrocarbons with
~ ~ I- - - - '- -- of tripbenytenethyl)
Y LY b-
we-relound after !1drojenatici, and the mom accurate,
"Pie, and rapid i ractometric analysis Is prefemble to the
Sombustion detn. of C anti H. W. M...Steinber

it ~ oil
1-le'roleum ~,'r.7ctuion. "
oil 'c,, thc
'711 1 C C, Lc-
-u, -,P 2, -'L-n- f. cf
~-'ct--rce o., ",octorate "r nce.-
',Ic-chc-rn,.,. a"Icskva January-Decomber 17~L~'

lp
Were
ul,'1951, AA

aU

od iA -r-
12,
J
'951 x
cdo 1~(N*i Y
method
20
C4
A98)~ ) v
'I
,
,
,
w 'ed
as mm ~ out in w -m*,, witimtt piv w
hesd
Band d
is
.
,
,
speo
f
smiaing w6e dad. d
aM the' -d-. of naphditsift ju4 p4iift

't1
b dehy("-
yl I d
;J
M.wItid

d KsiiU3kfWdhj)d MA,26'. 77) to
trapophle cata
AllJklytkml6 i

y
h-

Its; isup
stl
Pd -with6ut Pedimploo
Pm

th! 1l

ct

i
A5 .:

di
b
m 40
d;~td
s
x
y
bo Ius~ n.
, T
lie tes~16 6f it-
on
,
.;
y
p
ied tht ratid, 41 ~
Ration shov
be .
jj, I tiL
chtc:Wp
cirbost6
:
' H ' - f6jijitid
Como" gaw jut, lvete
6 tents. iJI ue,

W
i
J

J

Y ape n It
ane, lpethylcyclopinfaue~!snd trwis-d Y - i
.
'A comi&rable i1plIntity 0 bydrindead'Was 1) 1e;,
stih
At.
prdent.

OWN

GALIPERN, G. D.
USSR/Chemistry - Catalysts, Petroleum Jan 53
Hydrocarbons
"A Catalyst for Analytical Hydrogenation and De-
hydrogenation," I.,A. Musayev and''G. D. Gal'pern
DAN SSSR, Vol 88, No 1, PP 71, '172
A simple and quick method for preparing a catalyst
for analytical hydrogenation and dehydrogenation by
B. A. Kazanskiy's method (platinized carbon with
iron added) is recommended. A catalyst prepd in
this manner is useful for investigating compn of
hydrocarbon mixts such as straig1it-run gasollnes
and kerosenes, since the transformation of
262T2
cyclohexane end its derivs into hydrocarbons of the 'ben-
zene and napircha-Lene series is accomp.Lishea smoot4y
under it., but hydrogenolysis of pentamethylenes is
negligible.
262T2

GALIPERN, G. D.
USSR/Chwdstry - Petroleum I Aug 53
"Individual Aromatic Fqdrocarbons of the Gasoline Fraction From Petrelsum Occaring
in the Red Colored (1) Stratum of Nebit-Dag". Acad A.V. Topchiyev, 1,A. Musayev,,
M.V. Shishkina, G.D. Galpern, Petroleum Inst,, Acad Sci USSR
BAN SSSR, Vol 91, No 4. Pp OE 869-871.
Investigated the chemical composition of Mebit-Dag petroleum in order to compare it
with that of other Caspian crudes, Found that in the gasoline fraction boiling up
to 175 a la 2a 4 - - trimethylbentene, ethylvenzens,, o-aqlene, and %-xylene comprise
52.8% of the total content of aromatics.
272T7

lPrMl G.D.
TOPCHIM, A.V., akademik; KUSATBV, I.A.;
Investigation in the composition of Nobit-Dag petroleum;
Report 1. Trudy Inst-nefti 4:3-9 '54. (Kim 8:1)
(Nobit-Dag--Potroleun--Analyals)

TOPCHIYEV, A.V., akademik; MUSAYEV. I.A.; SHISHKINA, M.Y.; GALIPERN. G.D.
Investigation in the composition of Nebit-Dag petroleum, Report 2.
Trudy Inst. nefti 4:10-17 154. (MLRA 8.-l)
(Nebit-Bag--Petroleum--Analysis) (Nebit-Dag--Fqdrocarbons)

is
i,j
T ml,
Lill
I zf
ti

9f
DromometrIc I.AftlymIs., 1. investigadon of dograii of utll~
Ifsaturation of In-Alvidual
mr! Ne ti-Ovd. wait
Trudy f-I
YAWRaNdus with olefins
L~* - The re,".175n o I when tbe r eflon takes
AW
plkt-, ill kolli., dt:pcne,:,j not only aft the naturt ~( mlmitllut4d 1
mdivk6 at the tOubbi boinU bot also on the tuitilro of Sol-
Ck vents- The incthod:of culen. oUtinsatu. Stififftted ~Sy Ife-
illney with "correction in subfitifuting'. is not coofitined by
by the K-~ufman method of bromometry of individual!
li~qiroca~bons and witie O-corttg. mapds. the nint. cf Br for;
theorctical reiltifivx!nent.
brundnation Ii (iften near to OL

Of .4mintily- 61 evolved TMr Is dqmidcut upmrs. tile:
ilt
b
nature of %uIrstitti(ed.radleals and does not relate, to them
ftme (it im- ill, 1~11te impnived inethod of goitfilinn for
es and putiried gasolint from CrAck-Ing
IS
p Lrolmini'dbitillat
dm-Tihreili. To OJAa(1.05Y suln. of hydrocartons ill VIC41
about E*al voJq, of a Q.IAV soln. of Dr In MeOH utd, with:
NaBrwaiadded After 20 min. K1 win. was added and the,
liberal ed,1 titmt~d iv ith 0. IN Na-540j. The brominativit of'
alkenes. -eirclemes, a
nd some derivs. ended after 1-40 min-
'Br)ldt ~ - 0.
and d, 0; d(RDr)ldt
1-pbiem~, and furfur5'lideneacetoacreacted with Brmplcfly, In
the bcgbiniug, furdwra maction took plaoi-in whieE-d(Br)/-
di- Ct, it 1113r)Idl: C1, when Cj/Qjjam*8.2aud 3,resp~
The procesa of brotninaflon. of 2,3A1mc1byI_Ia-'
bit tudicue led to the cxprcs.4on . d(Br)/dt'm, vnrl; - i I 113r))
ds - vur.. The rate of brothiriation deemazed; AN first-
nipid process broke off with the ammulation of neg.-Sub-
stitutetl radicals, Thetime effect lvas observed xvith I and
Br, The miction ijf olefins with Br Ivd to:the bitt)1nedifife
"mulb
r mide" (cf. Tishelmoko, C.A. 31,1(Ml) formation
which vais partially tonvertedinto 4ab1c I 0-tiltroilitle -.110
partially into misatc.. monobrontide aiid 1111r. In INIt-Oll
the formatioh of an
solij. the basic prpc~%i is compiluited hy
-mCthDxybroTnidc thTiv. froin mid INIt"Off

1011 evolving equiv. Wli. m. 6.4stl'.,
Mot
Wood
:go Lat degree dirustivrotion uf petsslpju~ produ~
'
~
-P, fidirldual phoholv.. Broi
ometq of attiWfl mixtire
ll *1
hydracorhonk mu&cmtking Case Ults. XHd~ 1,1l-44).-.-ThL-
11tio frwi Ke4chigan petralemn and ii raixt. eX ill(Ii
I oleolsi -xith. low cofitent oralkt1uni nd 3rtolurie by-
Vill"
drotatbotz react PimrAt 4-mantitAtIvely mith 11r. nj-
-s'tdnt,,d to Ihe no. of datible V mkir'j mi'
of Bri
I'M. ."IC svxllim~ 1.11, W irw I a m& Eqmki- a )"I 1W VtL-A 11 iltim
abnornTal1r. i~cnzu"
jilt son Comm.
B MdrY~Mil beapplictl to the quunt,amO
i-,~i ol phinuth,
,
vVithdiff t~imrtttmq. Ill. The deltiminjition of iiii. dt,
Cren
rren of misatumflati of rr ag of pewulmit Nf-
-The brx)mumetry nt ltyd-oocarbolvi iz~ i5claibed lm d,!-
tafll.~ Cyet'te and ;111~,Yelic lly(ImomfIxIas with nne
bond, met 1) Dr in a mol. mtio of 1: t;.~ stytellli hn-A
it3 boatoldig irt tbe r'Aio Im, th-tut one frO. I. urriattl_~hy.~
bons w1ill izuta!~,I dwW: !x3nds mc0o~
t mvr Jus two
.,,I ~ Uwil Aydrm-,r ..... ~s 11th 2 al" - teijlouble wiuls~
~
J'Ji ;~L
o;p- mol. of Dr.

!--~P min. Ifulnulug's of phem)) rmrt more hipidly. : r)i-
cr-,11 mrld.rc~xmhlo) malbiat'. with 3 moN. C4 llr during,20
c-cr-,vl, 1,2,4~, ami 1.2,txyletjuj?i with TIMS,Offlr;:~
-naphilsol wid 1.3,4-xyl-iml with I mol. ordure la 0%.
.11 o1th phimols W%, Ur beemnes

GALIPM, G.D.
Bromometric analysis. Report 2: Investigation of the dmgree of-an-
saturation of petrol4mm prodmets and individual phonols. Trudy Inst.
nefti 4:131-140 '54. OUA 8: 1 )
(Brosometry) (Phenols) (Petrolous products-Analysis)

GALI PFM,._.G,D.
Bromometric analysis. Report 3. Method of determining the
degree of unsaturation in petroleum products. Trudy Inst.
nefti 4:141-150 154. (N1" 8:1)
(Bromometry) (Petroleum products--Analysis)

TOPCHIYEV,A.V.; MUSAYEV,I.A.; GALIPM,G.D.; o"HISHKIRA,M.Y.
Analysis of the composition of fiebit-Dag petroleum. Trudy Inst.
nefti no.6:3-11 t55- (KLRA 8:12)
(Nebit-Dag--Petroleum--Analysin)

6 L")O
USSR/Chemical Technology Chemical Products and Their Application. Treatment of
Natural Gases and Petroleum. Motor Fuels. Lubricants,
1-13
Abst Journals Referat Zhur - Khimiya., No 19, 1956, 62581
Author: Mironov, S. I.,.Gallpern, G. D., Kolbanovskiy, Yu. A.
Institution: None
Title: On Temperatures of Formation and Conversion of Petroleum
Original
Periodical: Dokl. AN SSSRJI 1955, 103, No 4, 667-668
Abstract: On the basis of data concerning hydrocarbon composition have been
calculated equilibrium temperatures of 32 varieties of petroleum, on
the basis of which was calculated the mean temperature for these
petroleum varieties which is -1700. Calculation of temperatures was
done according to approximate formulas for the systems cyclohexajae-
methylcyclopentane, metbyl cyclohexane-ethyl cyclopentane; n-hexane-2
and 3-methyl pentanes, 2,2- and 2,3-dimetbyl butanesl n-heptane-2,2-,
2,4- and 2,3-dimethyl pentanes, 2- and 3-methyl hexanes, 3,3-dimethyl
Card 1/1 pentane, 2,2,3-trimethyl butane, 2-ethyl pentane.

USSR/Chemical Technology - Chemical Products and Their Application. Treatment of
Natural Gases and Petroleum. Motor Fuels. Lubricants.,
1-13
Abst Journal: Referat Zhur - Xhimiya, No 19, 1956, 62605
Author: Topchiyev, A. V., Gallpern, G. D., Musayev, I. A., KiBlingkiy, A. N.,
Shishkdna, M. V.
Institution: None
Title: Individual Paraffinic and Naphthenic Hydrocarbons of the Gasoline
Fraction of Nebitdag Petroleum
Original
Periodical: Dokl. AN SSSRY 1955, 103, No 6, 1035-1038
Abstract: The gasbline fraction of Nebitdag petroleum after removal of aromatic
hydrocarbons by chromatography on silicagel, was divided by distilla-
tion into 43 narrow fractions. The first 11 fractions were used di-
rectly for spectral investigations, while the other were also sub-
jected to spectral investigation after analytical debydrogenation
over platinized charcoal with iron, and in part after dearomatization
Card 1/2

I~SR/Chemical Technology - Chemical Products and Their Application. Treatment of
Natural Gases and Petroleum. Motor Fuels. Lubricants,
1-13
Abst Journali Referat Zhur - Khimiya,, No 19., 1956, 62605
Abstract: of the obtained catalysts. The analyses showed that Nebitdag gaso-
line recovered up to 1500 contains about 140 Individual hydrocarbons.
Approximately 50% of its composition consists of 15 hydrocarbons.
In maximal concentration are present: among the paraffinic, 2-methyl
butane (4-50%)P- n-hexane (3-31%); n-pentane (2.69%); n-heptane (2.26%)
and 2-methyl pentane (2.10%); of the cyclopentanic, methyl cyclopen-
tane (5.03%); CiB-1,3-dimethyl cyclopentane (2.16%) and trans-l.,2-
dimethyl cyclopentane; of cyclohexanic, methyl cyclohexane (10.49%);
cyclohexane (4-97% ); 1,1,3-trimethyl cyclohexane (2.41%); ethyl
cyclohexane (2.25%) and cis-1,3-dimethyl cyclohexane (2.a2%). ft was
found that on dehydrogenation conversion of 1,1-dimethyl cyclohexane
with cleavage of the methyl group as CH4 reaches 5% in the case of
the 118-1190 fraction. Analogous conversion of 1,1,3-trimethyl cyclo-
hexane yields traces of m-xylene. In the 96-1010 fraction is observed
a conversion of about 5% of cis-1,2-dimethyl cyclopentane to the
trans-form. In the 86-880 and 128-1360 fractions is observed a slight
hydrogenolysis of cyclopentanes (up to 5%).
Card 2/2

USSR/Chemical Technology - Chemical Products and Their Application. Treatment of
Natural Gases and Petroleum. Motor Fuels. Lubricants,,
1-13
AbBt Journal: Referat Zhur - Khimiya, No 19, 1956, 626o6
Author: Topchiyev, A. V., Musayev, 1. A., Kielinskiy, A. N., Gallpern, G. D.
Institution: None
Title: Individual Aromatic and Hexahydroaromatic Hydrocarbons of the GaBO-
line Fraction of the Romashkinsk Petroleum
Original
Periodical: Doki. AN SSSR, 1955, 104, No 1, 93-95
Abstract: On study of the composition of the gasoline fraction (50-1750) of
the petroleum from the Romashkinsk deposit by the combined method of
Kazanskiy and LandBberg (Izv. AN SSSR,, OKhN), No 21 195-11 100) it was
found that it contains 5.46% aromatic (toluene, pseudo-cumene and
m-xylene, etc., a total of 15 hydrocarbons) and 8% hexahydroaromatic
hydrocarbons (methyl cyclohexane, ethyl cyclohexane, 1,3-dimethyl
cyclohexane, cyclohexane and other, a total of 20 hydrocarbons).
Card 1/1

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VON ImAlk HMN4MALSI *I: ;a [ROO
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IN
KARAULOVA. Yn.R.; GALIPEMI, G.D.
Oxidation" of--. sulflfi hydrogen peroxide. KhIm.i tekh.topl.no.9;
39-44 S f56. Owl 9:10)
l.Institut nefti Akndemli nauk SSSR.
(Sulphides) (Hydrogen neroxide)

Tiavnilliki, I !l ~W,

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GALIPKRN, G.D.
Sexual variation In som* pine species. Biul. Glav. bot. @ad&
no.24:58-63 '56. (NLRA 9:11)
1. Inatitut neftl Akademli nauk SSSR.
(Pine) (Plants. Sax in)

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24(7) 3 PHASE I BOOK EXPLOITATION WN/1365
L'Yov. Unlversyt4t
vlateridaY X V5saoyuznzgr3 11370shchIni7A PO spektroakopil. t. It
MolaWyarmays. spektNO-piya, (Papers or the 10th All-Unlan
Conference on Spectr3scop7. Vol. 1, Miscular Spectroscopy)
(L-vovl lid-vo Wvcvskoso WT-ta, 195T. 499 p. 4 000 copies
printed. (Series: Itss PlzychM7 abi Mk, vyp. 5A?)
Additional Sponsoring Agenc-7; Akademlyn nauk 3SSR. Koulaslys pO
spektroskopil. FA..- lazer, S.L.j Tech. Ed.i Sararquk, T.V.;
Editorial Boardt LwAsterg, O.S.. Academician (Rasp. Ed., Deceased),
Neporent, B.S., Doctor or Physical and Mathematical Sciences,
Fabelinskly, I.L., Do-3-or or Physical and MathemaLtical Sciences,
Ya%rika3t. V.A., Doctor of Pnyaioal and Mathematical Sciences.
Koraltsuls, V.4. Candidate or Toohalcal Sciences, Rayakiy, S.M..
Candidate or Phykoal AM Mathematical Solana*&, Klimovskly, L.K.,
Candidate or Phiratcal. e:nd gathematical Sainc4s, KilLyanchuk ,V.S.,
Candidate of Pbjeloal and MatherAtlcal Sciences and 01sub*ruang
S
A. Ye., Candidate of Physical ad Mathematical
aionae,.
Card 1/30

Oord&dZ0, D.S. k&arw~nicity of the Potential
311
Curve of 4 Hydrogen Molecule
W"&kav, M1 N S.S. Njrontqva, Ye. 3. FokrovWWA. at &I.
row Composition of
uatural-
St
d
3t
j ;C
u
c
r
g
y o
icarosens rraoti*" by Keane of the Absorption Spectra
321
In tbf Near UAtraviclat Region
Jaganseav A.T, Strunturel-grouP k1slysis or Saturated
Petroleum Products by Means 1.f Wrs"d Absorption
Spectra. Dateratnat-'01% Of CH3-groups. Allphatio
and Long Chains, (CHk- 32T
CH2-groups

A.N. Xts'jin~U,
Q%j!2!rn -y, I.A. *Aam"'r, at al.
n7UW*f the Composition of Banxiuo-ilgroia ftentLons
by Means of Combined DispsraloA Spectra 329
4ka-pern Q.v. M.N. Nusakov, 70. S. Pokmakaya. as 41.
Absorption Spectra of 8010 tetra*=
Aromatic Hydrocarbons In the soar Mtravlojet and Wre-
M4 Rosso" 334
CW4 21,4o

GALIPMN, G.D.; KISLINSKIY, A,N,; MUSAMffs I*A.; TOPCB:EYMVg AoV*; SHISMYA,
0 .
R&mn spectrm atudy of gasoline-ligroine fraetions. Fiz, sbor,
no,3:329-333 157 (mm 11:8)
(Qa;ollrA--9pectr&) (Ligrolue-Spootra)

GALIPERN, -G.P.; SHISHKIITA, M.V.; SHCHETSKO, M.I.
A,-' -,
Light naphthene and paraffin h7drocarbons in ordinary Surakhany
petroleum. Trud7 inst..nefti. 10:59-73 '57. (miRA 11:4)
(Surakhany rojion-Petroleum)
(Paraffins)i (Naphthene)

TOPCHIYEV, A.V.; 1SKIIAKOV. W.Kh.; MUSAYAV, I.A.; GALIPERN, G.D.
Chromtographic separation of benzene produced by thermal cracking.
Khim. i takh. topl. i masel no.11:26-33 N 157. (Kim 11:1)
1. Institut nefti AN SSSR.
(Usollne-Analyals) (Chromatographic analysi3)

AUTHORS: Volynskiy., N. P., Gallpern, G. D. and Chudakova, I. K.
TI7LE: Quantitative Detection of Haloids in Organic Compounds by the
Method of Double Combustion (Kolichestvennoye opredeleniye galoidov
v organicheskikh soyedineniyakh metodom dvoynogo sozhzheniya)
PERIODICAL: Zavodskaya Laboratoriya., 1957, Vol. 23,, No. 1 pp. 27-29 (U.S.S.R.)
ABSTRACTs In these experiments the method of double combustion was used to detect
sulfur in organic compounds. By this method vapors of the substance
to be analyzed and products of its pyrolysis are conducted into a
flare produced by some suitable solvent. The products of the combustion
are absorbed by a suitable device, which quantitatively binds the
elements to be detected. This combustion produced hydrogen haloid or
free haolid., and nitrogen as N02,, NH2, N(R3),, etc. Some description
is given of the method of detecting chlorine and bromine. Sketches
are presented of the equipment for quantitatively detecting haolids
in organic substances by this method; besides quartz beakers., capillary
tubes, burners,, etc. The results of the detection of chlorine and
bromine are given in tables. There is 1 Slavic reference.
tft"E*^-
s-

AUTHORS: Karaulova, Ye. N., Moylanova, D. Sh., 79-11-27/56
Gallpern, G. D.
TITLE: On the Thermal Isomerization of Allylarylsulfides
(0 termicheskoy izomerizatsii allilarilsullfidov).
PERIODICAL: Zhurnal Obshchey Khimii, 1957, Vol. 27, Nr 11, Pp. 3034-3040
(USSR)
ABSTRACT: According to Claisen the characteristic property of the
allylaryl-esters is the so-called regrouping, the ability
of isomerizing into o-allylphenols on heatin,-. It was
attempted to apply the thermal isomerization to the sulfur-
analogues of these esters, to allylphenylsulfide and o-
and p-allyltolylsulfide. In contrast to the results obtained
by Hurds and GreenbTards it was found that on heating
(boiling) of allylphenylsulfide without solvents no
allylthiophenol is to be obtained, but only propenylphenyl-
sulfide which, if heated, yields concentration products. The
structure of the product obtained in the thermal
isomerization of allylpheriylsulfide was detormined by
hydroe,enation over nickel. Thus this isomarization with
Card 1/2 subsequent formation of allylthioplionols (Claisenian

On the Tliermal Isomerization of Allylarylsulfides 79-11-27/56
regroupine), like in the analOLOUS oxygen compounds, has no
effect. In thermal isomerization the qllylzxrylsulf ides are
converted to the correspondinE propenylarylsulfides. At
first they obtained allyl-o-tolylsulfide, allyl-o-tolyl-
sulfone, propenyl-o- and p-tolylsulfides, propenyl-o-
tolylsulfone, cis- and trans-propenylphenylaulfones. Allyl-
phenylsulfide and propenylphenylsulfide are split up by the
solution of mercuric chloride in alcohol, on which occasion
mercuric chloride of thiophenol forms.
There are I figure, and 12 references, 2 of which are
Slavic.
ASSOCIATION: Petroleum Institute AS USSR (Institut nefti Akademii nauk
SSSR).
SUBMITTED: December 10t 1956
AVAILABLE: Library of Congress
Card 2/2 1. Allylarysulfides - Isomerism

AUTHORs KARAULOYA,Ye.N., MEYLANOVAID.Sh. 20-'6-26159 ---
GALIPERN,G.D.
TiTLEt '-U-n-=-19RVr9-1e&rre,ngenment in the 1111laryloulphide Series.
(0 peregruppirovke Klayzena v ryadu allilarilaullfidov, Russian)
PERIODICALs Doklady Akademii Nauk SSSR, 1957, Vol 113, Nr 6, pp 1280 - 1282
(U.S.S.R.)
LBSTRLCT: This rearrangement is an isomerization which, according to the
opinion of some scientists, is characteristic not only of the
allylarylethers but also of their analOgYB. In contrast to Hard
and Gr6engurd the authors found that in the case of boiling of
allylphenylsulphide without solvent practically no allylthiophenol
is formed, but an isomerization of the former in propenylphetyl-
sulphide occurs. It is identical with the product insulated by
Tarbell and Me Call which they obtained by the action of sodium
alcoholate in an alcoholic solution on allylphenylaulphide. When
standing or warming propenylphenylsulphide forms condensation
products. The thermal isomerization of the allylarylaulphides
develops according to the scheme:
to
ArS - CH 2CH - CH2 LrSCH - CHCH 3; (Ar - C6H 51 O-C 6H4CH3
and n-C6H4CH 3)
Furhtermore, the single reactions with yields and experimental
Card 112

2o-6-26/59
On KLEISEN's Rearrangement in the Allylaryleulphide Series,
ASSOCIATIONt
PRESENTED BY:
SUB14ITTED: '
AVAILABLE:
conditions are described in detail. A colored reaction with
sulphuric acid is characteristic of the here investigated
propen.ylarylsulphides; A red coloring results, which quickly changes
into brown. In contrast to this, allylarylsulphides, after addition
of concentrated 11 2so 41 turn only faint yellow. The obtained results
allow the conclusion that KLEISEN's rearrangement does not take
place in the case of the allylarylthioethers, in contrast to
corresponding oxygen-compounds. Allylarylthioethers isomerize
in the case of heating in corresponding propenylarylsulphides.
(1 Slavic reference).
Petroleum Institute of the Academy of Science of the U.S.S.R.
A.V.Topchiyev, Member of the Academy
24-12-1956
Library of Congress
Card 2/2

AUTHORS Topchiyev, A.B., Aoademic.ian 20-4-3o/6o
Musayev, I.A., Gallpern, G.D.
TITLE The Chemical Composition of Gasolines 6btained by
Thermal and Catalytic Cracking.
(0 khimicheskon sostave benzinov termicheskogo i
katalitioheakogo krekinga.)
PERIODICAL Doklady Akademii Nauk SSSR, 1957, Vol- 115, Nr 4,
PP. 740-743 (USSR)
ABSTRACT The knowledge of the unsaturated and other hydrocarbon
groups which form part of the cracking products is very
important. At present the problem of the influence of the
raw material on the structure of the above-mentioned pro-
ducts is not clear enough. The solution of this problem
will make it possible to ooze closer to a rational
selection of raw materials as well as to produce mineral
oil products of prescribed quality. Furthermore a number
of possibilities for the chemical synthesis of mineral
oil will be created. The systematic investigation of the
cracking products, however, meets with specific
difficulties. A survey of the methods hitherto proposed
CARD 1/5 by other authors is given; special reference is made

20-4-30/60
The Chemical Composition of Gasoline Obtained by Thermal and Catalytic
Cracking.
to the combined treatment of sulfuric acid by hydro-
and dehydrogenating catalysis and the selective hydration.
The present work employed the combined method. It
contains: 1) the sulfurio-acid method for determining the
total content of unsaturated and aromatic compounds,
2) determination of the per cent content of unsaturated
hydrocarbons in fractions according to the iodine number
and the molecular weight.
3) selective hydration of the unsaturated hydrocarbons
at 80 at.excess pressure and 280-3000C,
4) dehydrogenation catalysis for the purpose of determin-
ing the nature of eyolanes (the unsaturated and the
saturated ones),
5) the method of aniline points for the purpose of
determining the group composition of the fractions which
do not contain any unsaturated ones. Pressure distillates
of the thermal and catalytic cracking of paraffin oil
from Groanyy were taken as test objects. Gasoline from
thermal cracking. kfter drying in a weak nitrogen flow
it was fractionated and separated into standard
CARD 2/5 fractions. Table 1 shows the yields and characteristis

20-4-3o/6o
The Chemical Composition of Gasoline obtained by Thermal and Catalytic
Cracking.
fractions. The fractions were divided into two parts;
one part was investigated by the sulfurio-acid method,
the other one was first selectively hydrated (over
a copper catalyst). After sulphidization and distillation
of the polymers the paraffin oil residue was thoroughly
dehydrated on a platinum-iron catalyst. Table 2 gives
the final results of the various hydrocarbon groups in
this gasoline. Gasoline from catalytic cracking.
Table 3 gives the characteristic of the initial
fraotions which were investigated in the same manner
as above. For the 6-menber naphthenes a detailed
chemical group composition of gasoline from catalytic
cracking (60-2000C) was determined. The final results
are shown in table 4. By means of the combined method
the precise group composition of gaeolines from both
types of cracking were investigated. It was proved
that for the fractions 60-2000C of the thermal cracking
gasoline a high content (44,7~) of unsaturated hydro-
CARD 3/5 carbons is characteristic. The acyolio ones were

20-4-3,o/6o
The Chemical Composition of Gasoline Obtained by Thermal and Catalytic
Cracking.
predominant (24,2%). The concentration of the unsaturated
ones: oyolohozenes (7,2%) and cyclopentene (11,9 %) was
marked. The comparatively high content of paraffins
(28,8 %) in all fractions was close to that of the
acyclic unsaturated compounds. An analogous analysis
of the catalytic cracking gasoline showed that the
smallest content of unsaturated hydrocarbons (almost
the same percentage of the acyclic ones and those with
one 5-member cycle) is characteristic for the fractions
60-2000C. The 6-member unsaturated cyclic compounds were
almost-completely absent (0,8%). The content of paraf-
finio hydrocarbons considerably surpasses that of
olefins; the oontent of aromatic hydrocarbons rapidly
increases with increasing temperature of extraction and
reaches 60% for the fraction 150-2000C. The diene-
hydrocarbons with a conjugate bond are absent in both
gasoline groups.
There are 4 tables and 13 Slavic references.
CARD 4/5

20-4-3o/6o
The Chemical Composition of Gasoline Obtained by Thermal and Catalytic
Cracking.
ASSOCIATION: Petroleum Institute AN USSR
(Institut nefti Akadenii nauk SSSR)
SUBKITTED: JUlY 9, 1956.
AVAILABLE: Library of Congress.
CARD 5/5

LEVENSON, Viktor Emanuilovlich; KUZIENTSOVA, Nina Pavlovna; MAKS114DVA,
Seraftma Nikolayevna-*,-6AIrIf=,-G.D.,-doktor khin.nauk, OtTereds;
KOTLTAREVSKATA, P.S.,red.lsd-va; MINA, Yu.T., takhn.red.
[Some problems In the geochemical history of bituminous minerals
of the Volga Valley in Kuybyshev Province] Nakotarys problawr
geokbimichookot istnril bituninos?Wkh iskopasarkh guibyshevskogo
Povolzhlta. Moskva, Izd-vo Akad.nauk SSSR, 1958. 62 p, (KIRA 11:12)
(KxWbyshav Province--Bituminous materials)

LEVENSON, Viktor Emanuilovich; KMNETSOVA, Nina Pavlovna; MAXSINDVA,
Serafima Nikolayevna: GALIPERN.,G.D.. doktor khim.nauk, otv.red.;
KOTLYARN SKAYA,P.S., ~W(f. ": isd v'a';'TftINA, Tu.V., tekhn.red.
[Introduction to the general study of bitumen of the Ural Mountain
and Volga regions and results of the study of bitumen of Saratov
Province] Vvedenie v obahchee issledovante bituninologit Uralo-
Povolzhlia I resulltaty bituninologichoskogo lzucheniis Saratovskoi
oblasti. Moskva, Izd-vo Akad.nauk SSSR, 1958. 153 P. (MIRA 11:12)
(Ural Mountain region--Bitumen) (Volga Valley--Bitumen)

5(3)) 11(4) MASE i DXX MY11,01TA-2.7,"N /22-a
Akademiya neak SSSR. Institut nefti
Trudy., t. 3.2 (Trazzaetions of the Petroleum Institute, MU. Acndmw of
Sciences, Vol 12) Moscow, Izd-vo MY( SSSR, 1958. 395 P. Errata slip
inserted, 1.,700 copies printed.
Ed.t S. R. Sergiyanko, Profegsorj Ed. of Publishing House: K, G,
Miyesseror; Tech, Ed,,: Ve V, Golubevao
MkPOM The book is intended for scientists., engineers, and technicians
in the petrolew industry.
COV4RAMt .This colleation of articles describes the results of studies on
the che&stry and technology of petrolemm and gas conducted in the
laboratories of the Petroleum Institute., Academy of Sciences, USSR., in
1956 and 195T. A new section "Petrochemical Synthesis and Technology
of Petrolew" has been included in the coUeation of articles. A list
Of investigations published by the assodiates of the Thatitute in 1956
and 195T and a list of dissertations for the Doctor's and Candidate's
degrees presented in 1956 and 1957 at OPen sessions of the Academic
Coweil of the Petroleun Institutej, Academy of Sciences, USSR, are given.
Card

Transactions of the Petroleum Institute.. USSR (Cont.) B(;V/2=
Th*re are 349 references: 199 Soviet, 3-12 English, 29 German, 6 rrfmah,
and 3 Jspenese.
TAM OF CONTMM:
From the Editor
Is HYMOCAFMN COWMITION OF THE GASOLM-KERoSIlVE pBTRrjLM FRACiTI-ON
Topchiyev, A. V., 1. A. Masayev, and 0. D. 0 Chemical Composition
of Gas,olines ObtaJned by Thermal and Catalytic Cracking
Topcl;iyev,, A. V., E. Kh. Iskhakova, I. A. Musayev, and G. D. O&I'pern.
Chromatographic Separation of Thermally Cracked GaBol-ine----~- 19
E. Eh. Iskhakovs, F. V. Korenevskaya, I. A. Musayev, and V. V. Sbehekin.
Change in the Activity of Silica Gel in the Chrometogmphic Separation
of Hydrocarbons 35
P-Wlpe~~-p M. M. Kus-qkov, Ye. S. Pokrovakaya, and N. A. Shimanko.
Study of the Absorption Spectra of Some Cyclohexyl and Oyflopentyl Benzene
Derivatives in the Near Ultraviolet Region 38
Card 2/,0,-.11'

SOV/81-59-7-24797
Translation from: Referativnyy zhurnal. Khimiya, 1959, Nr 7, p 462 (USSR)
AUTHOR: Gal'pern--CL.D.
TITLE- Physico-Chemical Characteristics and Composition of Petroleum
Products
PERIODICAL: V sb.: Sostav I svoystva vysokomolek-Lil. chasti riefti. Moscow,
AS USSR, 1958, PP 36 - 44
ABSTRACT: A short review of the literature. It Is noted that for the
investigation of the group composition of standard light
fractions (6o - 95, 95 - 122, 122 - 1500C) the best characterls",ics
until the present time are the critical point of' dissolution in
aniline and the refractive indices. In the case of investigating
the structural group composition (SGC) of oil fractions the
methods of Waterman's school have found the widest spread. Not
one of the SGC methods proposed yields reliable results without
preliminary separation of the raw material into the aromatic and
naphthene-paraffin fractions, There are 36 references,,
Card 1/1 A. Ravikovich

AUTHORS: Petrov, Al. A., Ser---Jyenko, S. R., Tse6ilina, A. L.,
Teterina, M. P., Kislinskiy, A. IT., Gall-ern, G. D.
TITLE: Iz:)merization of Saturated Hydrocarbons (Isomerizatsiya
ne.syshchennyk1i uglevodorodov). Communication 1: Isoneric
Q
Conversions of Alkanes With C 6 - Ca Str!!CtUre (Soobshchani-e
1:Izomernyye prevrashclieniya alkanov sostava C 6 - C6)
PERIODICAL: Izvestiya Akademii Nauk SS3P,,Otdeleniyp- Khimzicheskirkh Nouk,
1953, Nr 4, pp. 437 - 445 (USSR)
ABSTRACT; Diring the last years in a number of works it was pointed
out thut saturated hydrOCILrbons are subject to a remarkable
isomerization ( References 1-4) under hydroc-en pressure
in the presence of catalysts (alumosilicates). This hetero-
ge-nous isomerinL~tion reaction of saturated hydrocarbons
found already industrial use at largest extent. Thou-rrh thcre
is -reat attention paid to the preparation of catalysts
there are, however, relatively few works dealin- with the
Card 1/3 investicztion of the reaction of individual hydrocarbons

62-58-4-8/32
Izomerization of Saturated Hydrocarbons. Communication 1: I30neric
Conversions of Alkanes With C 6 - C8 Structure
(on the same conditions). Only the works by Chiapetta and
Khanter (Reference 4) are an exception here. As the -in-
vesti,-ation of isomeric conversions of the individual
hydrocarbons of different structure is of greatest interest
the authors decided to carry out a systematic investi,:;ation
of the isomerization reaction of the alkanes with a C 6- C8
structure. The exT)eriment was carried out accordinj to tILe
flowino system on special conditions ~~nd all ex-eriments
of the isomerization of the individnal hydrocarbons were
performed at lo atmospheres excess pressure.
The obtained experimental data were compared with the
calculated thermodynamic values.
A new mechanism of isomeric conversions of saturated hydro-
carbons in the presence of polyfunctional catalysts was
sitCgested. According to this mechanism the first sta-e of
Card 2/3 reaction leads to the formation of olefines. Also a Creat

62-58-4-8/32
I-lomerization of Sattzrated Hydrocarbons. Comrnunicz~.tion I : Isomeric
Conversions of Alkanen With C 6 - C8 Structure
nunber of new data were determined which offer new ideas
as to the binding connection, the structure and the
reactivity of hydrocarbons.There are it tables, and 17
refcrences, 11 of which are Soviet.
ASSOCIATION: Inatitilt nofti Akadenii naul: SSSR, .(Petroleum Institute,
ASUSSR)
SUBMITTED: November 19, 1956
AVAILABLE: Libi-ary of Con-ress
1. Hydrecarbons--Saturated-Ismorisatim 2. Alkanes
C C ~~-Isopp4e COWTersims
6 8--
Card 3/3

AUTHORS: Petrov, Al. A., Sergiyenko, S. R.,, SOV/62-58-6-13//77
Tsedilina, A. L., Kislinskiy, A. If., Gallpern, G, D1.1.1-1-1.1,
TITLE: The Iaomerization of Saturated Hydroc'arbons (Itomerizatsiya
nasyshchennykh uglevodorodov) Communication 3, The Isomeric
Transformation of Cyclanes (SoobshcheniYe 3. Izomernyye prevra-
shcheniya tsiklanov)
PERIODICAL: Izvestiya Akademii nauk SSSR, Otdeleniya khimicheskikh nauk,
1958, Nr 6, pp. 730 - 738 (USSR)
ABSTRACT: In various earlier papers the isomeric transformations of
alkanes are discussed, which develop in the presence of poly-
functional catalysts under hydrogen pressure (Refs 1,2). The
main purpose of this paper is the investigation of the rules
governing the isomerization of hydrocarbons and of the connection
between structure on the one hand and kinetic and ther:-,iodyna-mic
parameters on the other. The catalytic isomerization of the
cycloparaffin hydrocarbons C - C in the presence of a poly-
functional catalyst under hygro,rQ pressure was carried out.
Furthermore, it was found that the isomerization products of
the cycloparaffins C and C 9 correspond with respect to their
Card 1/2 composition to the thzrmodynamic values obtained by calculation.

The Isomerization of Saturated B~ydrocarbona. SOV162-r-8-6-13137
Communication 3. The Isomeric Transformation of Cyclanas
A mechanism for the isomerization of cycloparaffins was
suggested, according to which the formation of iinsaturated
hydrocarbons fiGures as the first sta..:,
.,e of reaction, Furthermore
the influence exercised by presoure and temperature upon the
direction of the reactions of cycloparaffins in the presence of
a polyfunctional catalyst was shown~ There are 5 tables and 17
references, 0 of which are Soviet.
ASSOCIATION: Institut nefti .1kademii nauk SSSR Ntroleum Institute AS USSR)
SUBMITTED: November 19, 1956
1. Hydrocarbons--Isomerism 2. Cata2,ysts___PerforM1Rce 3. P_nesaure
-Chemical effects 4. Temperature--Ghemical effects
Card 2/2

GAL I MIN, G. D.
Abnormal fruiting in the Japanese red pine. Biul.Glav.bot.
Sada no-32:112-115 '58. (MMA 120)
-11 lo Institut neftekhImicheeko 0 sinteza AN SSSR*
:.! t: (Adler--Pine) fAbnormalities (Plants))

AUTHORS: Gailpe~n, G. D., Bezingpr, N. N. SOV1/75-1.]1--- 19124
- - -- ---------
TITLE: Determinati-z)n of Primary, Secondary, and Tertiary Coexisting
Amino Groups (Opred;-leniye per,;ichnykh, vtorichnykh i tretich-
nykh amin ~Igrupp pri sovmestnom. ikh priwatstvii)
PERIODICAL: Zhurnal analitioheskoy khimii, 1958, Vol 13, Nr 5, pp 603-607
(USSR)
ABSTRACT: There are several references on the sepa_~ate determination of
primary, secondary, and tertiary amines 'Refs 1-5). One of these
methods (Refs 47 5) is based on the ac_-dimetr.-1,:: titration. At
first, tl~e total content of amino groups in the mixture is
determined. Then,, the primary amino groups are bound by salicyl-
aldehyde, fo:."m4rg Sohiffls-ba5esp and the sum of the unchanged
secondary and t-ertliary amino groups is determined by titration.
In the third samr19 of the original mixture the pr1mary and
seco.-dary am'-no gr.-ups arp a~,etylated by means of acetic an-
-itrated ac1dimetrical-
hy,1ride and the te-rtiary amin-, groups are 1,
I
1j. The main diffi.2uity of this method iq the determination of
the and point, because the a'lcchols used as solvents (iqo-
pr,,~pylaloohol and ethylene glycol) are very Yreak acids. There-
Card 1/4 fore the intensity of tho 'bases is in th,?ski oclvqnts somerhat

SOV/7~ - 13-5 -1,0/24
Determination of P.-inazy, Se,,cndary, and Tert4_ary Coexisting AM-fr.,- Gzoups
higher thar, in aqueous solution. In alc~Dholi:; solution3 only
au,ih bases can te titrated the ionizati,_)n constant of which
J 8
is no'. below 10-" - 10- , In subsequent papers (Refs 6-8) for
"he ac-idimetris titration of amines glacial acetic acid has been
_,le to titrate
suggested as solvent. In this mediura it 4S p()S---r
precisely am�nes wi-ch icnization constant's tip to 10-11 - 10-12.
In the titration with glacial acetic aoid, however, the Schiff's-
bases are co-titrated since they are in glacial acetic acid
bases of the same intensity as.the secondary and tertiary
amknes. The authors of the present paper used as solvent for the
amines glacial acetio acid. The primary amino groups were quanti-
,~atively blocked by phthalic -anhydride. Thusp the corresponding
Phthalimides are formet! which show the same behaviour as neutral
compounds In contrast with the Schiffts bases. The intensity
and accuracy of the subsequent potentiomet=ic titration of the
secondary and te::.-tia=y amino groups with HC104-is not at all
.-educed by this process. The potential jump in the endp.oint is
nearly as large as in an acetic acid solution of amines in
Card 2/4 absence of phthal_fmides. The tertiary aminea are quantitatively
L~

C()V/75-13-5-19/24
Determination of Primary, Secopdary, and Tertiiarjv Coexisting Amino Gro-aps
dete::-mined after acetylation of the primary and secondary amino
groups with --cetio anhydride by pote-tiometric titration With
HCIO4. The method under rev--ow Tias applied for the quantitative
determination of primary amino groups in several aliphatic and
aromatic amines and i-!1 3-aminopyridine and 3-amino-quinoline;
the results of these determinations are given. The error does as
a rule not exceed 0,1%, if the nitrogen content is > 10~. Amino
groups in position 2 and 4 in pyridine-, quinoli-ne- and thiazole
derivatives react reither Yrit-h phthelic anhydride nor with
acetic anhydride and car, t-e--efore not 'be determined by the
described method; the same applies to 2-aminothiazole. Details
are given. for carrying out the elaborated riethod of determination.
There are I figure, 2 tables, and 10 references, 2 of which are
Soviet.
ASSOCIATION: institut nefti kkademi-i nauk SSSR, Moskva (Petrci-eum Institute
AS USSR)MUSCOW)
Card 3'

TOPCHIYEV. A.V.; MUSAYN, I.A.; IMIWOTA, H.Kh.; KISLINSKIT, A.N.; GALI,P
G.D. .
Chemical composition of thermally cracked gasoline. Report no.3:
ftudy of individual aromatic and saturated cyclic hydrocarbons's
Dokl9 AN Aserb. SSR. 14 no,'4-.291-298 158, (KLIU 11t5)
(Cracking process)

SOV/7--27- 10-1/4
AUTHORS: Topchiyev, A. V., Kazanskiy, B. A., Musayev, 1. A., Gallpern,
G. D., Kusakov, It. M., Plate, A. F. (Moscow)
TITLE: Investigation of the Composition of the Light Fractions of
Soviet Ci-ades' ", (Issi-edovan-iye sostava. legkikh fraktsiy
sovetskikh neftey)
PERIODICAL: Uspekhi khimii, 1958, Vol 27, Nr 10, PP 1177-1197 (USSR)
ABSTRACT: This paper gives a chronological report on the fundamental
publications on the investigation of the composition of the
light fractions of the Soviet mineral oils which have hithez~to
been made. In this connection special attention is payed to
those publications which are edited by N. D. Zelinskiy, his
collaborators and students (Refs 1-50). As may be seen from the
present paper the current investigations of the mineral oil
fractions until the years 1937, 1939 were carried o-ut mainly in
connection with a chemical characterization of the light benzoin
and benzene ligroin fractions of mineral oil. Orly in the 1940's
methods were elaborated for the intensification of the individual
investigation. of the light fractions of the Soviet mineral oils.
Card 1/1' At the beginning of this paper reports are made on the first

SOV17 'If -27 -1 " - 1 /4
Irfvestigation of the Composition of the Light Fractions of Sov-'Let
CTudes
work carried out in 1881-83 (Bellshteyn and Kurbatcv). The
diverse research institutes of mineralogy which have been
established are chronologically mentioned (e. g..: 1924: the first
central (Gosudarstvennvy Issledovatellskiy neftyancy Instit--`)
State Research InstJtuie of Petroleum in Moscow)i 19--,:: In-
stitut goryuchikh AN SSSR (Institute of CoM'r-
iskopayemykh ~ L, tustible
Minerals AS USSR), diverse chemo-technical labora tor4a- of the
GINI (State Research Institute of Petroleum) as rell as diverse
research institutes in the Republics of the Uhion: Azerbaydzhanskaya
SSR, Vzbeka"ya SSR, "Turicmeliskaya SSR, and others. After World
War II methods of group analysis on a higher level Nvere
elaborated for the investigation of the -petroleum naphtha
fractions (with a further differentiation of the hydrocexbon sub-
groups). It was necessary to investigate in detail the compositlon
of the hydrocarbons of the light mineral oil fractions becwase
of the rapid development of air plane and automobile motor
construction in the USSR. Due to this fact the demands concerning
the quality of the motor fuel as well as of the crude oil changtid
Especially in 1955 intensive investigations of the individual
composition of the hydrocarbons of gasoline produced by crackirt-
Card 2/3 were carried out by using the chromatographic di-stribution of

SCVj/7, 1--2-74 -10 -1/
Investigation of the Composition of the Light Fractions of
Soviet Crudes
adsorption, the catalytic analytic hydrogenation and dehydrc-
genation as well as spectrum analysis by means of combined
dispersion of light (Refs 108-160). In conclusion the authors
are of the opinion that mere geological and geochemical factors
are not sufficient for the production of experimentally founded
theories on 'the formation and the change of petroleum under
the conditions of migration. A great number of important data
are necessary for the solution of the problem of the formation
of petroleump . namely the fiature, the concentration and the
composition of the hydrocarbon components (or the non-hydro-
carbon components); i. e., of'the organosulfuric, nitrogen and
oxygen compounds which belonO to the composition of petrole-
um. , There are 160 references, 160 of w~~ich are Soviet.
Card 3/3