SCIENTIFIC ABSTRACT GRINBERG, A.A. - GRINBERG, A.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000516830004-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: July 27, 2000
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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GRIMBERG, A. A.
"On the Interaction of the Joining of Divalent Platinum with Iodine," Zhur. Prik.
rMim., 26, No. 11, 1943.
"New Method of Preparation of Monohydroxo-M-rivatives of Tetravalent Platinum,
Dok. A. 14
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GRINBERO, ALEKSANDR ABR"IOVICHO
An Introduetton to the chemiBtry of complex compounda; textbook Monkvn. Goa.
nauchno-takhn. i..d-vo khIm. lit-ry, 19Lr~. 366 p. (51-24310)
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GRINBERGt A. A.
USSR/ChoKistry - Platinus Compounds 8OP/Oct 48
Chemistry - Ammonia
"Acid Properties of Ammonlates and Aminntes of
Tetravalent Platinum," A. A. Grinberg, Kh. I.
G111dengershell, Leningrad Tech Inst Imeni
Lensoret, 14 pp
"It Ak Nauk SSSR, Otdel Min Sank" 'No 5
Introduces nav data vh1ch details acid character-
Istica of ammonia and ethylenediamine molecules in
complex compositions of tetravalent platinum.
Submitted 15 Oct 47.
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Chemistry - solutioas
"The Reaction of an Added Campomeat am the
Solubility of NLterial la a J11z~& So2atlon,"
A. A. GrinbOWS, Yo. P. Zeal^kum.. Chair Imorg
Chsm~ laningrad Chas Pbar Mut wd Chair af
Gen Chow, L*nimgmd Took I=!rt Immul, leasurots
lot Pp
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CoffifixRO& Nbeftomenca (Previasely described br
Wriot) of increase& Golsbi3lty of tMw IM
I Morg"I a salts in 50 aqueom alachol &%w to
/thenistry - Solnbility (Coutd) Avg 48
addition to benzwo. Mime thin pheacamma
Ukes place not only for binary oloctrolytog
but for salts of other types an& also for
OrgLI310 subote=os readily soluble I& vater.
NhOwS that Offect Of additlemal caWament, cas
be generalized: It Is not oomfined to perticaUr
moo of &Icbhol-vater systeam gag, &bog not 2"qq-
in imr"ae& solubilLty. Iffect
should be obserred on any combinations of two
solvents, sod Its sign ('" mes, or dear"no
of solubility) depends an Interrelatim of
ProPe--ties of solute, solvent and additives.
Submitted 18 Apr 47.
29AYM

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0043 qwuw oba for K (how KCI). Vilth an mow
-
to bmind of
vam IlArt 6w 0 1
a 1111 K.
wor
w
* Sw a
wh
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ro
& 6
bmmm a 23A mmew so &Jft " woe
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-
-- 41AL
13AM. HS
13.10W. I^
From ocx-. ow Amb -_ _ i 0
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--
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l o
wamm clavubmats tbr A&M S*Pawnwim W thm bm.
3.723. coke. ~~y at "
No - tt. 14 LO
fmS--l
TW* For Ow $A- - i
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n Ni
b b
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ucit
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tn
tatn ma
I k. MR WA R al SA-- can be dw only tol
,
woe
ad FA Q~ Maud S. 1"brU141--look
comobwo OWY with a contw 31
C=411.1`11 " )30
-S
9%wWI-
Wdk
L w
o
ft
e.
*
r
ds%--wkhg. Tt*mhvomtm.dXhffwm&d5, Bak
--
-- o
11041
- 20
+ a-- + 3 - P X 14*4) - (2 X
as Ow bola of Sif-/Oll- - 2.7 a" IW/W -by I a%
As - mg, and Ow mow & A6 - 53. 3.70) + In + fij - 46.6. " 6626d the 41.19.
to 0w VS* dollev Irm SA-- Wx tbm 1169

it A$*-l&& mOA"WW9*L&fMftVGWftAWAMMlWll I
-fee-
0 ILSpO:I;;l ;;; ;a ita lid iii, aipol T 504 %due melvagme3a 9
9000000000000000100* 000000000*000000
a 0 0 a 0 0 0 0 0 9 0 a- a. 9 -0

CO
14*wown jivelamem peoppook end
kAme, A,- A , Z. Orlovs (Ultmovvit
Torbool. mid. 1. jvi~" PrAW, KUM. 1)
I It. too); 44~ C.A. 06, 474m. -
L"6914= of as drA*, of bivalvat Pt %*.
toothed by litmian of K#11`106. IMI(XIIACIe (ftvtuw*,
(Xviarl's all). PINIfevi'llilp (11M.
It" Oed mr4art's ash). fit- M4 treat- pt(NII, iota, K0111
Ik. KJV$CNh. phif I#, book Is air, %4n, sod in m4 k I
belL viossly (w4n# bmmnw do 6UNNICIP) SrAI Parrolb,
pererkway. It ame hernomAt torerry out flat Iftratirm wish
W-10. 1"0404 Vaosm.mf Ilia 141
00 the pq 0- iltimmind an tow oil I. g"imlitiono. I'm#-
obro KePtalivitrated *Ub mk~ It. c a viw*l filmlim th,
drop ill~ike ~ amem himmeor to rkmw cohar. In
title" 0* am drop cum" a Slemirt.
dw w6kh tbr "emaki cbselpr.
KIM46841vol lbratedo" tknotiff"m with KIM WAR. th.
.am. of It leard is WVNY Am to tow them kW W*=hW1"
Tum, titfttbo
uftkf tbm ewndkbmo W *"rommard to the Complete O'k
cbew to I 6W Cl to 41W Ksrtcl#. It fWartit" Mg.
41' - Fill- + 40'. OrA 42) rfl,'- * It - I'lls"
W" Star albri camp&. WW1
fob the to" of KOM, Mod KA($C.%)#. It was Pomade t.,
fitful* Wftb ON air- wmk- ad to 06" tIW 110`601111 "ms cwf*d
sot 10 KNO or KWX. P"P. to sladviom tho lWolins r4
rt('411*Wh 100% to that F**,OtIAI Mi SIRP 1101111-CON 14
Auffols"" + It M.1 t At W** Im"d to 1"
0.4-11 v. Avild J. Wirt

e-.4
jig.41
Stability of Complies coo ~iww
A A N fil SkAY4. Zhu,. 1'r.kw
Kit. W. Chem.? JJ, a 3IM10). - t
A , Sonoma I jo #4
The It"114184r it, ttmildrit Itornwilva, j.
.1! :"I'luat,4 itw hv,itainl 4-.3mplvj ff#xv, jhr fiv.1tat",
M low Ilw 44 at. ba
(A, lit. 1, 1, N
'Aft 21.M.
1"p Fsw anti 11.111141. af. - 21'smid -2.10 LrAl
. Torace Cl < lit e I < C N IMAd i I.,
Ox4r, wip. I he W4
forctntspIrl"44i'dil.
C-aup"It. in w4n. if Ap > 3 NIJ, (poly of"Ovs. this
-tiferawl thre-N44- can There 1* an equil. 1*1*ei-n undi%.
word clompleite% and their diiiamn. poxxiacts. fly AF -
-NIl"N - -lAObqK the(blvialdc4nist AtOwthreq-
how it 2.2 x fit 1. T1,111 thtrARM if the IIA1111.1 limit
Sept. STOC111- With Aft eqwl. twtoevs andt-uml. Awl th-
-1 &ctr4trtr%) inst %voms. uitfudivittwl
4011Y PIIr6-v fiffres I-Irving On-
(;",Ctwftk. iftmartion 1. VC.,04P .,I, , ,h,
-I-ence 4-1 A (Apid w1jef"ust bwrw tior Central Pat On oh,
coniWes and the free lows. 0 the "4" (4) 111# rate .4 lit,
vichaor reatm I Ptxj - - + X* -knftws im loop or~w
N > I > fir > cl, i... racksagge Is fatt"t in.thgoh
#k"mMfv"4m~-4llv ff"I .141,L- qhj% '. jak~j
thr ptwwwnrn-~ $4 OV4". tl~ .0-P-4 o--
-4 A,i #-%.ItAotjg~ 11-rit \P,f # C\* 1,.L-1 jeto th,
'mitki 11.1w-Iffti 1.1 pe """phtr. N I It.",

CA
16 of bit W
MV,m coal-
. =4=17A ' =TM*
pp,kha, d.. (I. A 41"1 Cb"n
IV) ificiffinsc of a iri's &di.
:toups lot IPt*.ch1cl1,(Vmwh,,,r of HIN111)
Stomp. *~.% 4.1.4 1111"1 V noral -At" q
.10% .4ol 0411,14"A ill ofit., tififil.vortlow pill : firlsiflol -fib
"If.oll .".I beAt"l V., "it lons.. tuta,l loto .1 fine while
Pro?. of cnmpn. vrrv n,jr 1.) 'I'liNilds)(5041s, ill) bill
with an admist. of -no. c1. it i4 '1t-4vrll toy careful
X-401l..'rid thc.11tv 14 ppf,l, with
F"o"I
the filtrate. tl(CCS% 1:01itll IICI White Of
(IM the im,quencr CA "ACIWIT111 i%
+ X141,411A0o, f- - 11 +. IMN11,Ct; 2 11 +
2%,4011 f- Sjso~ + :Hiro;
11"If 4f' 411AC1, - 4%ASOj +
ff"t(VII.I.S11,10, +
110 Ill The initi'l I ter the Actions it(
cl, -, -An -4 jillf'O': m-11OW *fill JIM -or toy the
A,it,'Is tit fire HIN11, ..) sn .1. lobs -4 11,11WIl. sivins
'Pf,.f0f. Afl,l theft. folob Of on the prellvat'v W 11c). I
Ali th. too olive -vothe- otio-m, fit do-Onic K41,10. to
All .611 1'1%11, ~411 1114~ it" ficonAlb,"t
I whwh cAll 11, Wentifloni fly the poill
11404. Film this vAn , jrplifmJ with control. 11.*Ak. A
ifill-an of c1, yellopir I 111"cl, I f which cAft be
clonverted Inov Illy theAction ,( 4- Vll.. and
then into Ill A-f,,fvr. Thsometti(xigivrslornewhAtliort.
ter y1chk with tc4lect Ill the oultAt KilliClo, About life, of
the thcory. S. Tholl

GIRETRI"My A. A.
" Oxidation -Reduction Potentials Of CoInPlex Platinun Arvoniates and AmInates",
Zhur. Prik. 10AM., 22, No- 5, 1949-

lase - belle "d St
imanww aslinobm"ic astift A. A. Ct 4-.Obl %. h
I -JV
kato (Ac-Ad NI-e. a IkAo &4.-
t). t4a, V".1 30. :4414141wdW Ilk,
Ilk 1"111"%l
NII.C.11A,11 1,11 1131M 11,111."41.4
#",1 14-4 #-1 14f.. 1 1. 1 Afg-I 4.1t ."I A . If. I II,,I h 411
A Alr.on .-I CA%. 1. A "ills I.(
mul she rv4lsr I I'll yty. lhrk~ I
Via- .1%1 I,v ALAI. Whuh 1611.1- ."low the W U.
I. oil% of slowl wroh NII.ClIxIMI dove .IV
-%11.C.11.41 1,11 P'l r111 #,- looks kith CS. % It.,,
Ifk- ...14,% wish Ow 1~- - .1 ..% Ilk- I.. Ilk
.I. .-StAdUSAIMM 6%3 110411"A I" ~'110 101', Its, --Is-
:1"fif-ICS C"11111" C(%. I" "Mtf*1l 1-- 0.- ~it AM
mil4titm %bortras tbs. twhAvww I-$ Or owth" mo ipw
f-14 40r"14"" femetwidt. with thAt III 11W If.r .. ml
MIXIMIL't 1,11. 11W 1"04 r"MI'S. % .116VII, fg.or" lIv- It-
lohlrb VV.4vV. t'434.1 ..I.-
,,, 16.1

GRI11MM, A. A.
"Introduction to the Chemistry of Complex Compounds," by A. A. Grinberg,
published by State Sckentific-Technical Publishers of Chemical Literature,
LeninCrad-NDscow, 1951
B-76030

0'-~
I%-
'469, rttowms of thr 4shilitt of Cmfropirt I omi"'Wes.l.
4amf #4 Carbaffer arowlitim., , If - ' %
orml 1. V N114,14Au Witowl ~%
14111, 1), %tsPol I
A jiml 0 if. Im. I&SI o'kh it t$ I

0 tam.
alk", Rci N I
Noorl. Xhim., AWNsmi 3
Tresitnt"t of Kiptcl, with AdMillme ds.lptf NII$Mt)r
Chl. Tho ottucture ;Trie4 by Kurnakov i thlburce
action, and by tolmat
14411t Pt Nit I (PtC141.
Cif*Nlfs Nits
By
Niff cl
NHO Pt (N]
I
In bteVill and then treating with HCI. W*r-jPt(CH.Nl(0r-
Chl was tyradmed - The structure at Ibis valt was roved
by the formation of a colorless soln. its thiourea and y the
formatim of
Cf(sNltt I'l Nit lptcl4j.
0 1Nllj CIIINIIJ
1. R. 11thrm"

bw "90464"r WA 60 ebb" ad
OC*Lrtd Omm! K. ". Vatstmir.
she. Invmf. .4= okki, KA4.0- vob
TT*" 101kiewif to voreplelt kOM41k" is that-
fall-ly by the t.,,.tkm of 160
smi-I by tow issm,"fity toost, IC Of the
utter ON gt tuallv Otprfvm tow differ.
Mobility T1:7*c"w-ph?x km anif of the o.",
=1anna=110: - I'mm A tbw DO bm- eftle Involving
4 cwmoklg ion I)AA,I-- fmos U## +
I All - (WO - IVO + U, - 1.,) 4- 40k. -
Wtaft WS &%it 14 1 mg, limp em lid - sit mldn. all It ) find W A,
i-1*141 b*m* at"
r"P.. to thir Sisw~ U". La ismil 14 am Obs, to of by.
11611A.1"mad W01011.1,%
the beat of OvGC- W 1110-P A04 of hydr4jkM .1
nse witi, t- jug coast. tar rrortkm 1
of am Ore. and
The mi-l-lif two Appeog, clio'l, All . .1
If's - 1 11 +
x a or, - 3,j) + V (evinst'). This
lilts th* rvialkin twlwwn lbq g ehsr*egwWjes at the temi.
C-0
links lotmakin. -rhis fewhi, is
.1414 lot I ( wrlifinj lift
IC- es"I lCON,10.11% Isi(vilalil...
in kation to
1000 With Aft iwtfas strwimrs W The outer r
:Zm" 4*11.
but 4111h got ch4t" &W I
this Itails to the C.Neinsloo
that The at4loililvdif nm"14vst* INC1011's"i I"W" h4l go"" 1"
11111 P90011 41MI.Ift"AW4 IFOM IOP 10 ift-tiONS to tbf $"P1 Of
111411 ""441-1k %V'%CCM V09 iOftt With 144WPJO MAIC1391 the
comples stabditi, maht to.ift-te,ise with flul"'Ang M M.
to the roups, il me bm" is lwvuwnimntjv Wftk-. wok pv*-
dtlUd".110y VnW%IMj b0ftliag, Rko"if of the Nit gWkki
bigo"I form liankrulArly -t,W t-14vtro As a result of
the 2 s"tocisialk l"49m. the best of forguation of sAsesais
on ples iqms intbim a ambromp our pan t1gramb a M-1-;
Ou"Ilviel are. fiff (04 pit (,MON U sic"Ill.-
: tot alions
AS IN. AN IM licul Im-A
L licAl !umthi. Tbgr sm-sr is lomml
Zn ". C.1 311. Ht 1,11
for the frew-wit"lly v -Sv AJW - R r is K of for"Wim of
COMPINS 10110 ift Aq. DOIN. The nk" imicod this ir~
valwal rkwAcirr of the Immut. the == I the
Crease of the Outmilty (40t) .1 the em tiles ims from top to
bo(tom; this Is Illostraft4l hr coo Pulmon of AF Im comPlitit
ming the
cklocWto. firopnOn. soil gothl". The lAtter $IN
washeil dia"r 0( a F frout Cu to AN or Imm IS to Its. -
socl list cWoRks the least markM. In Wfirs of irwaimbrig
iom tonmd by ""tral io" with list Name cls"wir. but with
differ"I milff-electron shell strwium. The vomwi*% OU-

GRDMM, A.A.; , A.I.; SR"INUMANOVA, G*A*
Isomery of Alultrodibromplatostos. Isv.AN SMIL Otdkhianauk no.6:
971 X-D 153. (MLEA 6:12)
1. Madlyevyy Institut, In. T.O.Shloploa Akademli nomk SM I Tekhnolo-
gichemkiy Institut In, Issingradskogo soveta. (Flat inan compounds)

(MIJORRO A A
;zg;=;;4~7
Nochanism of formation of potassium chloroplatinits from thechloroplatinits.
Zhur. Priklad. Rhin. 26, 224-3 153. (MM 6-.3)'
(CA 4? no.21:11061 153)
1. Lensovet Technol. lost., Loninaad,

GRINB3RG, A.A.; 319MIOVA. L.Jr.
Derivation of palladium &cetylacetonate. Zhur.prikl.khim. 26 no.9:8-80-882
A.g 13 3. (My-aA 6: 8 )
1. Leningradskty teklinologicheakiy in3titut im. Lensovetu. 2. Lenincrp-dakly
tekhnolo#,,icheskiy institut Im. Molotov&. (ftlladium organic compounds)

New metho I In slablo AAW"
f t And ;C%.tltclf 1z""'t
ales 0 in .d ". tA1:r;1rk- Z.1-1
C III its : 1hur. Mffl"T-t)
1111110111.1 AIIII lvrh,tlst otlitir
aft C.tAv 1K.
foriiii nf cisitimit, I III III a III Co C%IIIIPIV~Ct 4.
,Jctd. by tuca"Sotan -lilts-01-111C4.1pl), III vVilkh the 3IIIIII'miate
I. mi-mi %vith is I.-Irge exer.4 of lit. reSO, -hi. an-l Naoll
tolded. The swilti. it (licit dkt,L 15 fidit, izabs a kwavii, %,q.
,,I If3SO# 5111FI. *rhe omjj+--x it to I,,, co
mol the lif,cralvi Nil, I,. almir6c.1 by lit, .1,41, tl%e v~ck,% .4
ohich 14 rmally titrated. ji~ W.

iv
U S S R
titm of bividentjLau~ blialsial
T on W4 ftoco of one an-
0 Cf. Crinkm and
. S4=F
j%k*_l 3( "U,
$*,1(47-MI9MXEuxI. trauslathm).
'WWW'W"titratt" telt-
tiometticully with KMnOt. Two Ocoatinuft," w1p.0 ob-
saved an the poundomettic cum caffespocWtal to tile
transition Pe** -Fes 4, *vA It$" - 444. Part of I he Pt
teaction W accounted for In the Fe tmasitioo and the rcit'
In the It Imphinn. 7`he arnt. In each cate is dctd. by the'
c*", of ilia Pi In th~ solii. beial t1traW. R. 1_1~

A &
structure (A 11IM111,11)'Cl'i (1) H
Jensen. CA. 31. .7711,11: G., R. ond Tr,,il,kil,.,. CA 43.
t4172g) war etaind. I will prrl-l. by Ifir arti-a .1 aq
KPNCI, on Mr. Ilh,P with heating and it 1:2 iatAaf rmito -f
reactant%; 1.5 X. Phill in 1". all. hot FtOl I tv,ii trentvl with
a hot spin. of 1.2 U. KINCIO in 12' lld. IIjO and tile milt.
was shaken fitrther Y) futti. to ln%iirr coinpiclion of reartion.
-TNe ppt wtq w-ash&I with lud 140. fiat 1`1011, wid Ft").
giving 7,5 yield r,f The purr 1, Inwl. in mil, *nlvrati, dr-
Mop. 30879. 1 (4) 3 r) in I I "I "it It 20 Stil, IIP wai tteate.1
with little exreii of (CIIINIII)i And hCAtCd Alld 41131(to lot
a tons titue leading to Stailwil solit The soln. w,14 filleted.
cooled. and Glided ((; a filtered cotlc,l, at, 0aill, of n 3 f.
Kim).. yielding a pink ript., which wai filterM "Iff: this
antaillilrd to OA g. (95%) 11,011h.11)"allptel') (11).
Titus the trartion utilizes equirriolar amounts of the re,
-actants still Olt initial I "lust have the Cis Confilruration.
The reaction with K2PtCie thus can he fortnufated al:
fPt(Ph.K,wICI, 4- X.PtCl' - 2KCI -4- 11. It was rferi-
ou'lly Shown that tur Show- a tmne tr.. effect. the same
being true of phosphites. In the present letirl, PhsP at-)
shows a strong trans effect. Thui It treated rith colic, I
NO and heated. dissolves slowly and the pink ppt~ Is 'be.3
replaced by a while ppt. while file soln. ricquirel the color
v PtCl.--. The dried ppt., in. 305% Is 1. Such ready
cleavage of the diarnine eye e can be expNined only by a
strong trans efrect of the fillip group. G. NL Kolol2poq

GRINB1W,A.iL (Leningrad); BABATIVA, A.V.(Moscow); YATSIMIRS11Y. K.B.
11-Ovoanovo): GORIMIS, V.I. (Moscow); BOLIT, G.B. (Moscow), FIAI-
OV. Ta.A. (Kiyev); TALSHIN, M,M. (Moscow); KEMY, B.M. (Moscow);
GIRLIMAN, A.D. (Moscow); FMROV, I.A. (Moscow); MMIMM. Ye.A.
(Leningrad), VOLIKUSHTZYN. N.Y. (Leningrad); ZHDANOY. G.S. (Moscow);
PTrISYN, B.T. (Leningrad); ABLOV. A.Y. (Kishinev); VOLUTAIN, L.M.
(Dnepr ope tr ovsk ), TWITSIATA. A.D. (Kazan'); 1OWCF1KO, N.A. (Moscow);
BARATSTA, A.T.; TRONIT, T.G. (Moscow); RUBINSHTSYN. A.M.(Moscow)
CHIRSTATIT, GRIIIBIW. A.A.; TANAKATIV, I.T.
Arplanation, of the tranneffect. Isy.Sekt.plat.1 blag.mot. no.28:
56-126 154. (MLRA 7:9)
(Compounds. Complex) (Platinum)

.,4020 AEC-Ir-2435014.2) 6). J45-52))
INVESTIGATION OF THE STRUCIVIAE 1) REACTIONS
or COMPLEX COMPPUN&S BY THE METIKTD-617
LABELED ATOlk". -A. A. P. 145 - SA oMt-- .4" (--
FEILEXUAIr Till; QF Tfir USSR
M,rffil Pf'Af*rV(lf. (IRM 0 A'U).%IFV PMEH(:y JULY
-5. 1955. SESSION or THE DIVI$ION OF CHE
SCIENCE. (Tranciallon). Itp.
This paper w2a originally abstracted [rain The Russian
&Ad Appeared In kut-lear Science Abstracts as NSA 9-7714.

V 7714
VMUCTURKA"RZAMMDLOU-pl,v.srnLfpnlyNDO.
&A.Ortoborij.
Boostij of the Academy of Science@ of
on the Peaceful Use of Atomic I[Der*y. July
1"0. Moscow, Ptiblishing House of the Academy of
Sciences of the U.B.S.R., 1965. 378p. (Is Russian)
A short review of the works lb this field to given, Ma)or
attention is paid to the excbanp wA substitution reactloul.
The following conclusions werv, madat The application of
tracem makes It possible to verify Lod establish the &torso-
chemical conceptions of coordittellon chemistry In a now
manner. The onme toothad permits a more profouad in-
sight Into the mechanism of different reactions of complex
compoundat the processes of exchaw and substitution to
the inner coordinattas aphers may proceed in different ways.
TUG Isotope exchange IPtarill- under the cooditt tuilled
proceeds via acpic-lon species. The possibility =Pota- V
tion at such a mechanlow over [PtX,12- compound& with other
11gands roquires experimental proof is each coast the life-
Ume of %b@ matal-11pod boW may differ widely for various
stable complenel &W Uw exchange, rate of coordinated
ligands ;p not natessArtly determined by the thermodynamic
stability of ths, complex in Me scan of ionic dissociation.
FI

~p
"Athul" of 01 's
L -*a I
~W A W M'' I". i we
"t,"d, Ab". N4.k SZ.5.1t.
53, &U-43,Work on the
mechaulm of - Is reviewed, and
the remalts a no. of papm
aft sumusarlud. The botooe-extrAmu vviodti-In c*m-
ples kno must be f&vunRFW-F*dm that bdp in reaching
'he complex4on d1mo. equU. and by ficturs that reduce
the mutual nTuWm of particles that enter into exchange.
W. M- _qj"nber
VAA

092J,
11 X
1; cout ot]
A
M A all WRI-7; c1. C.A.
;
;'m JU
50, 10404f.-Isotopic exchange of 13t In KjjPtHf#j an4 Kr
(PtBr.l was studied in aq. wAns. Deperiddmce. (if tbc ex-
(Ch.an ondainen
te P!a
iin.ition wrr* dvid. Activatim entrgy for
Jim
theexchingewit c-3ld.tobe4-10kml.firiPtllril--aud-
- 17 kcal. for t'11tBrjJ--. The excliange turchaniuits i&re
different for 2 i,~ns; in tile cmte of [PtDrl - - It (x-curs
through Vic. lnferlmli~lry aquo Ions, whereas for lptBrd!--it
defivid.4 Oil wti'hfioli mILIC60ti equil. ' Tile rm;lul (plitai'l(A
show Omit tile r'Lle 0 t-'Chavge Ill not dttd. by the r(ability
4:01p1q. "I tile vr)npjex

77-1
AID P - 1572
Subject USSR/Chemistry
Card 1/1 Pub. 152 - 2/21
Authors _Grinberg, A.A., Kozlova, L. I., Nikollskaya, L. Ye.,
-6-fid Shagi-sultanova, 0. A.
Title Exchange reactions in platinum complexes
Periodical Zhur. prikl. khim., 28, no-1, 7-11, 1955
Abstract Experimental measurements of the rates of exchange re-
actions showed that the exchange rate of iodine in
K2 1Pt161 is higher than that of chlorine in
K2 [PtCl A method for the preparation of
K2 [Pt(N82)jBr~ 3 is given. One table, 2 references
(Russian: 92 -51)
Institution: None
Submitted Je 26, 1953

.Tnk aj6d
.. =4*1=1le01)!-WA ~-Ad 'Itibe, . V4. A.
Kati (Len-"et -_r-,rmmvmlr-- [writ. selderd
T
8-kheta, Aldal., bil. ObskM i Neo
'ok S.S.S,R. No. 29,37-44(10M).-C.,
,Kki-. ad Na It
lin.W.;cA
M (O.;'C.) added too.5 g. of Kil'tC14 In 10 ml. w 2'1r'
slid heated for 46 min. an a %team bath. gave sity"-whit.
Pt dighatiumte (1) cryitali. To toblain a ptue product. the
vol. of the w9n. must be kept emist. during thacTystn. A,
test with ethylenediamine c"Alisuird that I cooisMs pre-:
domini-intly 4 trans form. Rmethat in coned. )ICI with,
Olimm-4 iihowed that rAnue U the ek fiwsu w.vt piccatt.
Plulissurn diaslotut'ste (11) was ptepd. 10,21M Ovid by a
similar method. At a conen. (4 2.5 X 10-4 molt-4/1, the
clec. cond. td I va-i 80 olun-1 cm.1 and of 11 UND.2 ofim 'I
rill., '171)h ngt'... well Willi tile arreptcd crxildlll.~11,-Il
A. 11.

Cv- P- I u B s ?,G-) 4. A -
USSR/ChemlBtry - Synthesis
Card 1/1 Pub. 22 25/49
Authors 1 Grinberg, A. A., Memb. Correspos Acad. of Sc., USSR, and Gilldengerabell, Kh.
"V. -11 .1 . WMNMW
Title sThe mechanism of the new systhesis of hexamines of tetravalent Pt
Periodical IDok- AN SSM 10113, 491-493, Mar 21, 1955
Abstract IIn explaining the mechansim of the new method of synthasiiing hexammines
of tetravalent Pt the authors point out that the Intra-complex bound
othylamine molecules in the Ptl C12 012 compound become sponified into
ammonia which remains in bond IhIthe Pt and ethyl alcohol which remains
In the solution. Lxperiments showed that only the intraspherally bound
ethylamine is subject to sponification and not the othylamine which
was aeparated from the complex as result of substitution reaction. The
process of conversion of othylamine into ethyl alcohol is described.
One USSR reference (1949)-
Institution s The Lensoviet Technological Institute, Leningrad
Submitted i October 15, 1954

USSRI Chemistry - Reaction ptocenses
Card 1/1 Pub. 22 - 21A7
Authors I-Grinberg, A. A., Memb. Corresp., Acad. of So., USSR; Nikollskaya, L. Ye.;
and Snag1EMMvaj G. A.
Title I The mcchan1sm of displacement reaction In the Internal sphere of complex
compounds
FOrlOdIC&I I Dok. AN SSSR'101/6i 1059-1060~ Apr. 21, 1955
Abstraot I A new effect is described which, as it appears, offers definite proof in
favor of a reaction mechanism utilizing the intermediate reaction between
the complex ion and the solvent as a basis. The new effect is explained
as the rate of isotopic exchange in relation to the increase in complex
solution, L e., the rate of exchange depends upon the time interval which
expired from the moment the aqueous solution of the complex was prepared
and the realization of the exchange with various addenda including the
marked atom. In other words., the exchange occurs through intermediate for-
mation of aque-ions. Four references: 3 USSR and 1 1JSA (1939-1954).
Inatitution : .....
Submitted December 1, 1954

gill"
Is, itg

lip:
;,pi

,% jitt'j"ta'I lt, wu.
pall hl: C, I
()!!I. IT, w- 4rWxKwti,k- tir.1-1il

!A-Od

cwl,144 I ;Ill-
11 till" ("run. 11: ("nordinallon V~i"kim
.0- fL,1,11 Vk kx-t+%1

Inne complex compounds.
t I o
zc I . "44 ~7Y4 19.
12173f.-Attempts were m4de to substitute PO,--- for
S04-- In the Itexamadne (Pt(NHAjCUW p1tim. de-
wribc4 (a the preceding cot=unkmion, bmuse of the
-dlffl"IfY IQ OiroinMing 604-- AS B4W4- HOWe0f, the
subititutlan of Nil, + (NlI,hlIPO, for Nils + (NlIt)a)t
In the eviler %3rnthcsls Iran D'%Nlfj)4CljPj pTWUced
jPt(NIfv)&CIjC4 insteM of the hcx-,jmmi;-ie, gaid no Iveigh-
able amt. of any solid sut"tanre was tt-covered whonmart-
Ing vVith jPt(clljNIljj4C1vjC1t. On adda. of 1411, or NaOll
to the solu. obtainct with the first anmille, jPt(,',4Ifj)j-
NII.CIICIo was obtained. The results tinphasirc the
effttts ul the outer lou on substitution rtactions in the cation
Inner sphere, *M show that diffemt sutultution products
can lie obtained undcr the influence of different auter-sphere
anions.

GRINBERG, A.A.; BXLOUSOV, Te.A.
lxchangm reactiona In complex Iridium compounds. Dokl.
AN SSSR Ill no.1:599-600 N 156. (MLRA 10:2)
1. Chl,.~n-karrespondent Akademit nauk SSSR. (for Grinberg).
Orldium compounds) (Compounds, Complex)

(14!f
tt~

GRINHM. A.A.; PTITSYN, B.T.; TAKSM, Ye.N.
WEEMOMMUM
Physical and chemical properties of the aqueous solutions of complex
uranyl oxalates. Trudy Radiev.inst.AN SSSR 7:74-86 156. (KLHA 10:5)
(Uranyl oxalates)

or
U1
of itte (if
c UW~ and c
A
the ticuloyla"tunate c(mmiltim 10 b-tipmp awd CC4t-
11.) th-, 1(41-1-is- SW-~atar is prcj;otcd for uninyl bci---
royhechi%atf.
0,
agtce -mth it tral."
form of thc ura~lvi i:folift, IlwAvii, 1, G 'NILlu)k

761
I- -A
ii.-;unidm liiitacarhil~yf -A.- A*
-1~411;tl V
~1~4 --Tho ff,~ 4nd 1~ t" 1~
prCIA. I;v the jtd,r n.~d
2W71), hut !~Y'Ithco;h "f -4w.
.. malty H lilts),,tibit. mt,h -!ord. pr,,britAy 6" x in i
"ij:.' V)t;lo cl)firhmons caa h, drawu abotit tfit -aruc-
ture fit the 7th jwtkA (A thc psiodir tahte. j4:jt!tjj(Ijjtj C;f
at. riol.'EU-103 ebould cwoupy Itin ~.arnc n1alive IxAtbmi ro
the Lntli:,iiid,~i, anti clt!nirnta 0 at. 104-1118 th-.04
Eccupy (lie mi;t,! rdafiv~ I.,iiOunu as Ocricrits 72 .10.
C- M 'L~
PAIT

T
~'Frj?;Wi Ali
7. 17-1fK1656). MZ~11
if qu;AdIVRIent ulankmi oxAtilp til :6- oxi, 'r,
h) ej
ns n I a-" tit LI I L'
OV) 1.1, ~~ RA ~ .
1- -11 -4!F V2.4' , t1l~j
Fil IWA)olil 4- W;X14 f- w('110 tI;.o
411V Upt-ah) 41ML, tfi;a a(vt moitc 6ow brat a 111A. 0 1i ikmr
forl-.1 the hvX-Illydr,41e. lliL tKtAlydr4te "Al Ow i".1 VAL
Zia tile (A Ow ell vol wre ob.."041"'A In ~11
at'aloj"outl fxlawlrr~ CA, * rr-kcts wo4 f"11"icrAM to
yield ppt%. of mid cac"O'. 1f:tr'twtf,! GImfVptl-
y
bitity studi#.-4 of tf(C41,), wd K, [lt. (tn'A CA d IL-
I
Jnflk-mc- 2 lInp-m[A I,-,;I
pcctfuln of IIA4 111:1 V~OIJ 'OW-O, P:43
(4,15.6 111$, wvI the oaulpht %.1t S!,ow's pmdatoinatr chvLa~ t,:-
of No kindinO.
v

R,
MO' Probkm'of the IntctMuerc*
of croups in th; inner
SFIWO of 9%titxA K
T usnel am reum a we kaw
a
A.
nd Zh;Q
ols V. 1. 806 ~ W"a
Laboratory proof of we theory of tratv-influence, cona&ntjm
Of cb-Influenw. problenur of hometry. Vwhmb of subdfttim
Rroceues in homtric dMrodlawnes, Table. 3 nE

GRINBERGJ A. A.
"Investication of the Structure and Transformations of Complex Corpounds
by the Tracer Atom Method," a report presented at the USSR Conference on Application
of Tracer Atom Methods in Chemistry of Complex Compounds, Kiev, 5-8 October 1955,
Zhur. Neorgan. Khim., 1, No.2. 1956
Above conference was described in wi article by Z. A. SPEK.

~/Theexcan OC-1 AC.MC!l9N&ndd1!n K,PdXtype torn pou n ds
A. A Gl~
L B lk. skaya. and N. V. Kist-
tub~
Kkint. 1, 220-1~!VM).-The Cl-(-i"
and exchalip's wtre
studied by radioactive tmc,--r technique with C110 and Br" t
In 5.5 X 10-OSI solm. exchange wu3 cvni-
itt case of the Dr silt, and was sommilat
blower 'or the Ct valt. Tfibrapid ratoof txch.~oge (its corn-
pared vvith that of Pt complexes) Is thir to the rapid hydrq1-
ysh of tho Pd salts, ratlitt than to dilfcteuccs in disvxn.
consts. A contributing factor may also lie In the tendency
of I'd +* to bond with figands fit addii. to the oft".9 rcquired
A. 1. 114 Ix

1~
I . . . . . . ~dl . 1. - -
.. j I- I . . . : , - - . -. - I ~t7 I 11-1
-~t ,, - .
-. - I , r, ;, -." ; .

-7,

C,;-~Mdj Of we strength of bases of the (11t(NHOSI~ L AN
Whe fifAbulty 01
4
tione %nd the strength Of the base thia).1-
1
,
~
o
VH),. A._ A. f ghag aud A.
_Qj
4wrl. 190J.-Because of ydrulyds"

C1

t(th1O t dourea) haq an acid reaction In'
hl
10
t
IC
J~
(th
~
this Poln.
soln. end the I can be used to dot. the strength,
'
staudIn
n
61 th
o
b
U
f~t(thl
(11)
)
1(Gil)
n
e
an
o
.
aq.
g a
4
,
p
;
toln, of I becomes more acid "Ing to tht displaccrnent of
the thiourea Iftpin the complex by Oil -. Ucznheprapd.,~
b
a
- sn't. of bw to R 0.001 M soln.
I ad:1,1L
0 Ift p Y
lalsald roeltublivourea
The bw" can be 0"ted
j
I
.
with OAN JICI. The thration Curves give the following
vahzes for the diswo. coustg.: K, o- 10" - 10-4- K,
10-0
.

e IR, , I 6V R C~ A. 0 ,
Category: USSR/AnaLlytical Chemistry - General Questions. G-1
Abs Jour: Referat Zhur-Khimiya, No 9, 1957, 3o924
Author : Grinberg A.A., Dobroborskays A. I.
Inst :'WK 'given
Title Volumetric Determination of Iron, Platimun and Iridium in the
Presence of One Another
Orig Pub: Zh. ne-orpa. khimii, 1956, 1, No lo, 236o-2367
Abstract: For the analysis of the system Fe'P* f-PtCl,,tpland Z-IrCl,
1 _7j
r-e(SO ;I- was used as the oxidizing agent. The sw*le of
KJL -7 (0-05 to 0.015 g) w" dissolved in 2D-25 ml water,
and to this solution vere added 10 ml of approximately 0.1 N
solution of Mohr' a salt, 20 ml of 25$ 4W,~. and 10 ml H3PO.,.
(specific gravity 1-5). The resulting solution was titrated,
at, 18-200, with a solution of Ce(SO,,O).1, in the presence of 4-5
drops of a solution of diphenylamine, until the color of the
solution cbanged to bluish-violet. It vas found that the pre-
sence of K, /-i'tCl #_7&nd replacement of H
~SOl by HCl do not
Card 1/3 -8-

Category: USSR/Analytical Chemistry - General Questions. G-1
Abs Jour: Referat Zhur-lhimiya, No 9, 1957~ 30924
affect the results of titration of Fe-,"'vith a solution of Ce
(SO ) - On potentiometric titration the end point of titration
of lel'AA#-is sharp; oxidation of f`PtClJP1-begins after comple-
tion of the oxidation of Fe-24 Presence of HjPO4 or of MJAPOv
in the solution does not intej~fere- For the determination .of
CIrCl(,_73- the titration is carried out in sulfuric acid solu-
tion (about 15$ 11450~0; CIrCl(_P-does not interfere. To deter-
mine the sit- Pt; + Ir in the presence of Fe the samples of KA
Ptcl/ IrCl,j were dissolved in about 2D ml
z , _7and (NH,,), [
water with addition of 20 m! kSO,,,,:. (2 N); solution of NHtFe
(S0,t),A.12H.,,O was combined with a solution of OuCl, the mixture
was added to the heated solution under study, aliquot portions
were taken after 2D hours, in one portion the Fe,"'O'content was
determined by titration with a solution of Ce(SO,~).~,in the pre-
sence of H.)JWf, H3PO~_ and diphenylanine, while in the other por-
tion the sum of Pt + Ir was determined by potentiometric titra-
tion with a solution of KMnOY.. It was found that on oxidation
Card 2/3 -9-

category; USSR/Analy-tical Chemistry - General Questions. G-1
Abs Jour: Referat Zhur-Xhimiyap No 91 1957Y 30924
of K,,C~tcl~j with a solution of Ce(SO ).;,. as veil as with a
solution of KMaO,& there is f ormed Kz Ncl", (OR).j. and that
in solutions of the latter there takes place the equilibrium:
2
f--C3,4(OH)Aj7 -> Kaf-ptClj + 2K.,Z7PtC1.j 00,7.
FVL PT, OCZ'-
Card : 3/3 -10-

~---J-,Jtcs ef UI%;.Al"!!
Ju 1.~

Groups in Complex
I- Oo 16 uc': Chemistry,

m cait Wkiiiubt 81, frcm ctra;Io-
IIAjmIIIIII:=;ft-Zr7". = b~ ~.jtlikh, 4 1 A.
ull
MT
eivin)4beDre" sapond. with Alk. molmi. 71be wc,*cr Liqu of
js first V-auod tbr=gh a 11 fum t( I cenig. djv~nyl-
i;~t to exL vitarwa bit. The axid soin. is mli-airc-i
and pw. P4 thimigh a Na fartu of Iteta-U. 2.6"'0 divi"Y"l-cm,
tL -1444~

LACiaetits of t4o reaction of jM41GAL2 k2t"
h1olo Al jajt!~!~d witb Koss Gal
P., ~111 0. kilu" Fi ~'q'
2 hu r. Ne
rate C117y'-Oreacti"111 of NII) %-Ath
Was lltudivd %ith fres'llt, 1"-tpd. al
aged smajil,:!i (lmtf~,re mixin& wi;h INIT, th-o
tained at 25* fc,r 135--U) min.). Ill all O.e rcxz!i%i:i
Changtj its character vvilil fllli'.. F r fre-dily prqvl.
'thenpr is chameteritcd b3~ a 6.w in tht ratio
~( ~ac C51
Coe ring tilt first 31) will. 'I'llem tile, J-rcc-iii. un-l~!Kpic" :I
r4gill"Caut rate of in"Cale. TIK of th.k sccnil k
characluilcil by tile COO. 21.0 10-1. An allalug~ju:;
phewmijenou %Tasobr;mrc-.d for the fic~hly pccpd. Koss 5.1.1t.

GRIMMO, A.A.; KUKUSHKIN, Yu.N.
Kinetics of the hydrolysis of certain complex coal'Dounds of bivAlent
platinum. Shur. neorg. khtm. 2 lo:2360-2167 0 157. (NIRA 11:1)
(Platinum compounds) (Hydrolysis)

GRjJ~M--A--A-.,-.-B=A1OVA, S.S.
Phenomena of thiourea exchmngs in CO1WlQX COMDOUftdG of bivnlent
platinum. Zhur. neorg. khtm. 2 10:216B-217C) 0 151. (MIRA 11:1)
(Platinum coamounds) (Urea)

A
-Fir
%Allghtly sWuble compounds of qwidrl-ralcitt u
_k, A_
with the maj G! ronfalift.
_3
iit 1; t;xkcn ft, Uf t, r
dutcd to (ht quArisAlcilt furm by wftj;-.A1:tr Ir r--id J'An.
-4- it reclu"Icni waw carTirtl out in Or
t .1 the OxAldtc ppt'L The reactkin earcd out in
111NO, of Onal c(mcn. 111, In the prvsl "' ji.,~- 4 HA'Il'i, 10""I CI-
mm of tht(wetkal vout uung (,vr vacli rn.,1 ronp.-
lift. plu, 7-10r"; excess. With thii
tallied no tuote U than detd. by t le ;,AY A 0~-
Uud,!1r ,iiinifAr r,;nJi6tm U wtu Ai4i vpul

L.-USleMnAttOrs 01 WtMftn In cu!i!plet
Gridber 4 1 X.
C,T, 49, T!ic. for th,.-
n
I V tevfAl~ly
n
, 0 to
Oi V
Complex KUUI,04 Which "I Can lir
IttAt" diStil - Well it' O'C' in
plexes which du not If pf tbl~
141(1 oftly tan bt jetd. 7-.- 1"1 i tiltil Ow twal
by llutucts, (usalkwil I'!

r
P, 108
z
PSI*
6.
A3.
51-IMUM jjj
In 2
j..
A- I
z Zo
3.J
13.2ilp
I A 1 11 1

alse"Rien as %be *-Shod* of 30IP53-54-3-30130
zVoSligasiag the cauji" recus,43.4a Is 301%,%&"a
tow"SiGodLes, as 4SvQ;0,d,4 1S7 the 24ands"VLOM, "beat to or
b30 gala&. Be 4490 point*& to the aeofs-Ity of 81*4084
Was ki'lettee of Ike process "d a 4LM"SL%4L1.0
60"864sats" of the *trometa, of %as Polymers. 4. a. 2"ke
P"a"d an% Ike% %be atuar of the pol"We air"Sure, a"
mosemouT. 1. r. Komar* meationad in BI~ lecture the% the
raWW W&A*Ir 67PFU 111171hal'250114A SIP- "468`44-4 20 U-
geb=O *0481004, + Santa s~baz$. to Set obsoL..d &a .11 a&-..
as toluvLad ealeastals so" W% I& %b- disauasloa. T. 1.
talmashow. &~ W. Ulow. 1. S. Runtsfis. 1. r. Ussmuw.~ a"
IL a. yetaLmArobts. A. R. Be". ske& diesumond Is US lastur.
W%ho" at Voterawne %a& Diaosolatios, cosateat of the
Camping 04100#0 Is 201%910"- tbD &.14 FrIM4pl-- Of 40%oroLLL.4
MW LastabIlIty OsastanSo. S. P-&oow' tloo-..4 In al.
Imetwe "Cialoulatics Nothade of law 1"I&WIty con.aSeAte at
us camplea campausts Asee"LAd to upwriaeasal "%a- ".
Pe"Abulues ar "Las the k~z Osavulatlea *ask"& of the
Luslablistr os"t"ts far W&r7LOUS gash* of the adopt" forms,
u*a I& solution. It onversI. sesaaami-&r sompioase ,* rors.,t
%6e 4loplaosdong Both" by &bm" 4^4 3"loador (Damalesed ar
A. a. Bolts) asn"t be rdedumse".4 far &be G"calauea or
460 ISO&MIUSY "ease&%. rho Isaluser dlecum." %be 416.
salustes amaneds or the pexrodaidas proposed bj, J,yon-10.
Amd". Ne"MIL. Aketake". X4"11*1 and other "Share. Th.
6ameteate sale-Islet In Sol* way are sat very "curst.. It
a" Proved that gas mesa" of S."Ba'av. opproximatic" a"
Imma to Wrong do"Iftate" " to %a# hoolval jl"foe". Sonlad
Stadia to no Wates, twopsleatd. TBS. Book probable ..4"
of as OSGLS&l eamassats ed~ be obt.Lo.4 bf the Both" of
"a least studroe. D. W. plitaya. To. 1. ?"star MA L. 1.
flawedeve "Sarthed the dozormimation "%hod* at %be
swasublitts senateass of the OX&I.S. saxpl.846 of aloblum.
Waftles, 4" 1"A rush " be"& 0. the to-OGS14.11" at %be
04"Ilbrlum 4LOPI&Soeoat of to. *~pl.x fo,vatlea b, szlvar
1400. V. 1. 34l*sb"o,&. 1. T. Us".44. " 0. S.
bald & Is'* of So. Use faster In th-6-TV-641C.-
it*& or the Complex vormatlaa,-. is Ihs 4A.C.S.1" a& %be
lootardo A. A. GrIaborg aaat&a." that d- to the @I"
816"t Of the squIllbri. %a. &*tb"o 419040-4 of
e4j
cost 7/16 :
to% 8114010d to* 1"1441ILtY S.&SX0438 (I&IISAIMAI &M4 041S~t
66"Les.0) *ao, art.. sat be -pley.d. A. 1. Able. total"
"I %be oneseaLty at AOILMIMC d1T#4l -Shot* of pro.tmd the
Galote"o at Lat.rw"141. foroSo to . .%Op-.100 damping fare..
11046 9- 1- TGSG&44tMlJY 410.4L.104 that 44. la.t.biliti,
es"46410 of Steel: 414"al.%zae sooll.aws a- be 4.49.1.9.d
t"a abormoobeale" 4.%~ L. P. ".4--sek. A. a. Galva
0110416 *%hot* %BOB Part IS %I. t&601,01" on %a.
A. It. same rat"8244 I& %be Beat door.ra.*.
to.
OW"Oll? at OMPIOX OMPO"do & lost- In -%Lob .-I
.::
ea,18"611" methods of %b- last.bLitsj, dometast. Shoals I.
44*Sm*dw4 bJP ShO ONMOIS Of "%"I a&&@6- TUO O&OUld 61&rLfJF
to vUeb 41-orgencle, of %to of %be ,... %",, d,t.
to"&$ S4&ft*As Of .14a"ILAd %A. xp#rt&GAtaI data 4" lead.
5. P. 14~' stressed that $a the of %b

Laos-61116S 4-mot"So all ek"14.1 .4.111bete .6"14
:. tax..
&&SO asso"t %k&$ "~A.r adopted the a-lies formallea V"*..*
&a the "last", GersaWly %sm, b4dro1j.1o of Sao
**steel 104 a" the addend" . In too 1.4t.r. by,
a" A
r. 168.1ja of In* 0961,10..
tend GPG .'
a Usu-04 too I *-*TLx&%L.a at %a* steaslisy coasteat.
q

~# .11 as Ist..49 wallizaar. owl U-ji Ottsmaj sort O-S
V'rTmTeTax. .1 apt-tj evil"91.120 -us jo Rao*w* oil VVIAeldes,
so sm"'Mies" q& an 40 valeavoon 041 11 time
0*6% Way 0 In *1 pea Ass%-Wtol 'I 'A *A.1199VIOS *ff '& '.0141
I =I 2"'. VI s.roldwee Ams"Iss, "I "I is
Z"%e .1% *1 a-dolval #AT1Gq0tv-J jo a-% ago wralf-z SIR at
P"9111011 ADWTT3 *A *oo..oP*jd voTj.zVA`B sit So well,"ove
I"" 1.1toos .43 $a *^%&"Is qs 1pavTo S oprommas 04*1801
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AUTHOR: Grinberg, A. A. 'je-1-36/0
TITLE: on the Importance of Complex Compounds for Radi,c~6.rltstry (0 zrachenli
kompleksnykh soyedinenty radiokhimii).
PERIODICkL: Zhurnal Foorganicheskoy Kh1mli, 1958, Vol. 3, Nr 1, PP. 125-1,03 (USSR)-
ABSTRACTI. The article deals with the abovementioned qtiestions only in general otit"Une,
the use of complex compounds for the obtaining of preparations of a high
specific activity and for the separation of isotopes was not taken into
account.
The first part deals with the state of radio-elements in the solution. Be-
sides other examples, the difference of uranium. and thorlwr_~salatu and
the separation of the thorium-isatope UX from uranitim is given.
The next chapter deals with coprecipitation and complex-formation. Copren
cipitation develops by adsorption or incorporation lnt,~ tho crystal latti-
ce# A lower limiting concentration below which the radio-eltiment is not
built in, exists frequently, but not always, fcr "abnorralln formation of
mixed crystals.
In the third part the author deals with the formation of coaplexes and
processes of extraction. The rules governing the extraction are derived
Card 1/2 and some recent extraction solvents are enwmerate,l.

On the Importance of Complex Compounds for Radiochemistry. 7.?.Z-36/4-3
In the last chapterp dealing with chromatographi and forrat-ton of ccmpl~-.A
xes-, the author limits himself to a disc-ljBsLon of de!icrption. A ti~cble of
the constants of stability of various alkaline.-i!arti~-,:(,mi-Ietes is reprow
due.-ed from the work of Martell.Calvin (Kellvia):
Chemistry of the Metal Chelate Compounds;
There are I table, and 3o references, 21 of which are Slavic.
SUBMITTED! August 2, 1957.
AVAILABLE46 Library of Congresso
Card 2/2

AUTHCHS: Grinberg) As A., Fetrzhak, G. I.) lnvtey,~vj L. T.
71'-1-37/13
TITLE'o Studies in the Choodstry of Uranimb- and Thorim-Oxalates
(Isoledovaniya po khimii okoalatov urana i toriya).
PERIODICAL*. Zhurnal Neorganicheskoy Khimii, 1958, Vol. 3, Nr 1, pp. 204-211
(USSR).
ABSTRAM After a brief survey of literature the authors find that according to
referenee-61-the formulae of uranium oxalate (IV) and its derivates
sho%ld- be 'do
biedo Since these conceptions were not in mutual accor-
-dance with the theory of coordination and since they were not based
on any physico-chemical data, the authors charged themselves with
supplying this necessity.
Complex uranium oxalates. A salt (UC2002 .2K 2C20405P20 was produced.
Barium salt, as well as new representatives of this series Of COM-
pound&o. leadw, cadmim-, and calcium-salta were isolated by doixble-
exchange-reactions. The two latter representatives of tho uranium-
Maderivates are ftbnormal" red-violet colored. The molecular conduc-
tivity of the water solutions of the potassium saltn was Investigated
Card 1/4 for proving the coordination-structure of the oxalates of uranitin

Brud"M In tbe Chemistry of Urazdam- 4M
Thorium-Ozalates.
78-16-37/43
salts. Respective measurements prove that the potassium salt Is a
5.ion,electroly-te which decaya according to the scheme:
K4/U (C204)4) 44K + /U (C204)4/4-' Previous test. results - which
were precisely determined meanydille - together with data from lite-
rature for other 5*ionmelectrolytes are shown in table 1. Since the
pH of the potassium salt solutions hardly deviates frcm the pH of
the water (figure 1) at the beginning, the authors, taking account
of the conductivity concluded that the coordination number of ura-
nium in potassium salt is e ual to 6, Probable equations of the in-
teraction of the & (C 204)7- -ion with water are set up and the
further dissociation of the aquo-ions is explained. The pF conses
quently decreases in the course of time. The constants of stability
of the afore-mentioned Ions are evaluated (according to reference 12)
and a value of the order 1o-4 Is obtained by potentiometric titration
with HC1. The known salt U2(C2O4)2'K2C204' 8H20 precipitate3 with
this titration (after adding I mol HC1). The production of mixed salts
was achievedwith cerium and lanthanium. (according to reference 13).
Card 2/4 There are metastable phases which gradually decay in the solution

StuUm In WO MooloW of UrvAm- and Thoriuw4bAlatss 78-1-37/0
and enrich the deposit with rare eartha. For clarifying the charac-
ter of linkage in the complex oxalates of uraril imi, the magnetic pro-
pertiei of some salts were investigated and absorpticn cwrves of the
potassium salt were plotted. It results fr~,m table 2 that in all ca-
ses the magnetic moment depends on 2 unpaired olectrons. Furthor It
was proved that the violet barium salt, just as the green tetravalent
onep contains uranium. The curves in figure 2 show the absorption of
the potassium salt in the visible (luminous) region of the spectrum.
Its solutions have a maximum absorption in 3 ranges: with the wave-
length of 49o,oo56o,,o and 659.*5 miA- The tetravalent state of uranium
as part of the oomplex ion does not greatly differ from other known
derivatives of the tetravalent uranium. These data - in view of the
magnetic properties - allow to state that the two unpaired electrons
of uranium (IV) are not included in the formation of the co-valent
bonds,
Comparison of the properties of U(C 2002 .6H20 and Th(C,)O 4)2'6F20'
The authors elaborated 2 new methods of producticn for the oxalate
of tetravalent uranium: 1) based upon an electrolytis reduction of
Card 3/4 UO2(C20 4) in presence of a surplus of ox&'-tc acid. 2) by the action

StudUs In the ChenleW of Uroudams and
Thorium4)xalates.
7t~-'-137/43
of rongalite on uranyl salts in an acid solution in presence of
necessary surplus of oxalic acid. The molecular conductivity and
the pff of the U(C 204)2 .6H20 reaulting from the Lit method, the water
solubility (comparing for Th(C 204)2'6H20) and th" soLability in ac-
queous solutions of various acids were investigated and a potentiome-
tric titration with permanganate in a H 2Sovjnilieu was carried out.
2 potential differences occur with the titration (figure 3); a)
with the oxidation of UI'Vin UVI, b) at the end of the oxidation of
the oxalate-Voups. It was found that U(C20 02 .6H 20 and Th(C 2002-
6H20 behave quite different in water solutions. The rrinch greater
of the acidity of uranium salt, compared with thorinm salt was cons
firmed by the action of gaseous pyridine on the two hexahydrates. The
acid properties of uranium salt are finally confirmed by a much less
solubility in diluted acids than in water. The differenc-i in the p-
perties, of acidity between the derivates of V(17',- and Th(IV) can be
explained by the relation of the ioncadii.
There are h figuress 2 tables,, and 1.9 rt--~arenceti, -,f v0ilch are Slavic.
SUBMITTED. April 29, 1957-
AVAIIABLE. Library of Congrcs-i.
Card 4/4

&

AUTEORS.- Q,~inbel~Cj_L11ji. L Gil I dengershol ]"i. T.
t -- --
TITLE: II.011 tile Effect of Arli Outer nphem Ujx)r,
t Nature of Substitution Within the Inner Sphere of Complex
Compounds 0". Ov
v.,erj1mc-y sfery na kharalktur ey
ofe.-a kompleknnykh soyedineniy)
213RIODICAL Zhurrictl Xhimii, TA jir
pp 1162 - 1165 OSSIZ)
A IEST R A CT The interaction between the iso-loric dij.~ii:~ of t -,;-avalent
platintim and ammonia in the presence of
ion.s vias inv sti"ated. The results shovied t i,
2- 3-
Dence of 30 and PO different pro~!:!ctc wov,,- oil Upon
4 4
tho action of ammonia uponlolt M11 ) C1
' 3
5
2
a.,Anc in ti,.e preoe-ce of SO 4 . I!. I.:-
Card 1 /2 -~, 0
3- chloropentanizic for -.s. By of t..(:~~o t,,::
4

7,
I1.0n the Ef.!*(-,(-t of Anioi.:; t:w Outer Sphere Upon the Nature
of Substitution Within the Inner Sphere of Complex Compounds
SUBMITTED:
AVAILABLE:
C,, rd 2/2
2-
it io wovotl t, ~lt t'ii~, anial"l; SO, rl;4(1 I'Ll
reaction into t.,.c Inner sphere. CrO42- also t.'.c
same ef'cct upon the above--icritioned at:r-.onia-cis or-tv,:,Z;
L Pt Ml 3)5 c11 3+ zysten. Proin the obtained rc~lultL.,it
aeon thLt in t'I,.e presence of SO 4- ions and U1r0,-:,-). -- t
substitution procenn vithin t1-,c inner sphere
-of ou.
v~ nd. The lant chl--)rine atom ic displuce(i
The rL''UltD ShOVied V-at the anions within t`.o outer sphere
of co.-.j)1cx can ctlizsc -, ccrt.~in in '.:.e
anions of t e inner sphere of zi co%iplex.T'~,cre ~.~c &
r~!ferencon,j o. -whici. fro ;,oviet.
'.IIY 16 ), 19 57
Library of Con,-r,:=
1. Complex coMTov11k1.:---%1b:MtUtl.on v(-actj(,n7--"

AUTHORS: GrinberK, A. A., kukushkin, Yu. 11. 78-3-6-61/3C)
TITLE: On the Production of Co3sa Salt (K vopros.: 0 poluchenii
soli kossa)
PERIODICAL: Zhurnal Neorganicheskoy Khimii, 1958, Vol. j, Nr 61,
pp. 1312-1314 (USSR)
ABSTRACT: Kinetic investigations of the reaction of K 2 F-PtC141
PtNH Cl with ammonia were performed. The smaller
and X 1 11 3
yield of K PtNH 3 Cl 33 due to the direct action of ammonia
on K 2 Epte'41 was discussed- 46 % of the Cossa salt which
can be produced thenretically were obtained by the
Lebedinsk4r- eaxwi~k alumd.
It was found that the greatest yield of Cossa salt in the
calculated equivalent amount can be obtained in the boiling
Peyrone salt - ois CPt(NH 3) Cl j with KC1 and acetic acid.
There are 8 references, 6 oi Xch are Soviet.
SUBMITTED: October 27, 1957
AVAILABLE: Library of Congress
Card 1/1 1. Chemistry 2. Salt--Production

AUTHORS: Grinberg, A. A., Inlkova,Ye. N. 78-3-6-7/30
TITLE: On the Mechan"m of the Synthesis of Hexamine Platinum-(IV)
(K voprosu o mekhanizme sinteza geksammins, chetTreekhvalentney
platiny)
PERIODICAL: Zhurnal Neorganicheskoy Khimii, 1958, Vol- 3, Mr 6,
pp. 1315-1325 (USSR)
ABSTRACT: It was found that in the synthesis of hexamine platinum-OV)
a reduction
of platinum-(IV) occurs in platinum-(II) if
[Ptzt4C121 HSO 4)21 NH4OH and (KH4)SO4 are used as initial
(
components.
Experiments were carried out for the explanation of the
action of various oxidizing and reducing agents on the
hexamine reactions. On this occasion it was found that in the
presence of potassium permanganate, manganese sulfate and
H202 in the reaction medium hexamine formation does not take
place. Howevert the yield of hexamine is 60 - 90% in the
presenoe of chlorine as oxidizing agent in the reaction
medium. This reaction is of special interest for the
explanation of the mechanism of formation of platinum hexamines.
Card 1/2 The mechanism consists in repeated oxidation and reduction

Oii the MechZMiBM Of the Synthesis of Hexamine Platinum-(IV) 78-3-6-7/30
of platinum. Instead of gaseous chlorine a frshly prepared
solution of' NaOCI can be used as oxidizing agent.
Also the action of the quantity of the ammonia introduced
into the solution was investigated and it was foun4 that at
higher concentration of ammonia in the solution favorable
conditions for the production of platinum hexamine exis*t.
The yield of hexamine is increased by the introduction of
small quantities of cobalt-(II)-salts into the reaction
mixture.
There are 9 tables and 12 references, 10 of which are Soviet.
SUBMITTED: October 26, 1957
AVAILABLE: Library of Congress
1. Hexamine platinum--Synthesis
Card 2/2

Ullit
41
:".11

u
o 1
V L

-1,W;: r i n b e-rv_
r: i n e t i c i n v c.-. t o r, *, L; f ,; om f,, "' om p i,~ x T, r 0,J rj j :5 o f j v i 11 n t
r Latinum (Kin-3ticheskt ijol _-iovani -t r. K I) t 1-:,
tn,
lotizal fifflucnc~_ u:' '_o~)rjlnatvn vli.vinii
k.;~ 1, !,hurnal niorgnnL(.hjrkry khimji, 1J58, 701. 3, :;r A,
!)p. !U10-1817 (USA)
A 3 ;T R.A C7 The kin-~tics of the int%-raction of ammonia *ith
(i t ( ati 3 )3 CI]CI ane K[PtIPvClj, on as the Kinetics of the
inter-action Of Dyridine with K ] and
21PtCl,J' "I:?"yCl
i"[Pta'! C1 I were investigaten. 11, was shown 'hat in the com-
' 3 3
pounds X LlItcl I KEPtIllf cQ, trnns-[Pt,kNfl. 01 ] anj
2 41 3 , 5 2 2
LPt(IIH ) Cl] the velocity of internction of' the complexes
3 3
with NH - ani OF- groups increa3e5 from K to trans-
3 2LPtc,
Lpt(N',( Cl 1, and then iecreases to [:-to~,) Cl)Cl. This
Card 1/2 2 2
-7

Kinetic Investigations of Some Complex Compound3 srV/78-5-8-16/49
of Bivalent Platinum. On the Mutual Influence of Coordination Groups
dependence of the velocity of interaction is based on the
cis-effect of the !;H 5- molecules on the coordination group
Cl-Pt 2+_ Cl.
Based on the comparative investigations of the velocity of
1.
interaction of pyridine in K ~1,, i K[PtPyCl it Wns
2CPt j an, ~1
found that also pyriiiine can exert a cis-effect. Tho cis-
effect of pyridine in the system investigated is greater than
the cis-effect of ammonia.
There are 4 figures, I table, and 17 references, 11 of which
are Soviet.
SU 3.V ITT*-" D: December 12, 1957
Card

6
AUTHORS: Grinberg, A. A., Shaeisu'4.
-artova, G. A. SOV/78-3-10-1 1/55
TIT LE The Question of Geo-metrical isomerism of Dinitro-Dibromo
Platinum Compounds 'K voprosu o geometricheskoy izomerii di-
nitrodibrctaoyletoatav~
PERIODICAL: Zhurnal neorganicheskoy khimii, 1958, '101 3, Nr 10, pp 2289-2294
(USSR)
ABSTRACT: The compound K2[Pt (110 2)2 11r2wan produced by Interaction of
K with H3r. This com.Dcund is enric*-ed with cis-
2 [Ft(!T02'1j
isomers. Lemon-colored preparations are produced in the inter-
action of K [PtBr4] 11011) . The preparation produced
2 and K2~t(A ~ 4]
y interaction of K 2 1P t ("102and 13r, has an orange color. The
yellow and orange fo of KI t(NO Br differ not only in
rm 2)2 21
color, but alzo ill solubility ill 96'1V ethyl alcohol, in electric
conductivity and in the plll-value3 of thc.-ir diluted aqueous
solutions. The solubility of the yt~llcw -c-dification is 0,138 g1
100 ml in 96~io' alcohol, that off the orar.,E:e Modifica"Icn is
Card 112 0,179 9/100 ml (at 2500-
_~7'

S C -1 /7 e -.", - 11 () - 11 /,`~ 5
'Ahc, question of GeoMetrical Isomerism of Dinitro-Dibromo Platinum Compounds
The aqueous solution of the yellow modification has a pH-value
of 5,10, that of the orange modification has an initial pH-
value of 4,65, and one of 3,017 after three hours. Various products
are obtained in the interaction o' the yellow and the orange
modification with ammonia. Dinit:.o-diamm1no platinum compounds
are produced in the interaction of' ammonia with the yellow
modification, and cis-dinitro-diamino platinum compounds are
obtained from the interaction of ammonin with the orange modi-
fication. There are 6 references, 6 of which are Soviet.
SUBMITTED: July 17, 1957
Card 2/2
U

T,,G *11, S rlrinLerg, A. A., Shikheleva, L. V. 12/2
- - - ---------------------------
TITLE: The Oxidation of Complex Titanium Oxalatvs in t,;e Poterntio-
I
metric Titrntion (Okislitellnoye potentsiometricheskoye
titrovaniye ko-nplekanykh oksalatov titana)
PERIODICAL: Zhurnal neorganicheskoy khinii, 1958, Vol 3, Nr 11,
pp 2491 - 2495 (USSR)
ABSTPACT: The oxidation of the co-mpounds K 2CT'o (C20.11)213' 2H20,
KLTi(C 204)21. 2 H2 0 and fPt(NH3) 4jfYiO(C2014)21' 21120 Was
itivestigated. The method of the synt'neris of the above
mentioned compounds was giver. The potentionetric titration
of these compounds with K Mn 0 4 was carried out at 35-700C
and a potentiometric titration ctirve was plotted. Thie
clirve of K2[T'O(C204)21 .2H20 was investi~.,ated in dependence
on the acidity of the solution; it showed a jump -..hich
corresponds to the oxidation of the oxalnte group. The
potentiometric titr.-.tion curve of the compound
Card 1/3 K,~Ti(c20 4)23 .2H20 has two jumps. The oxidation of the

T.-,'e Oxidation of Complex Titanium Oxriiates in tlic- SW/78-3-1 1-12127,
Potentio.metric Titration
compound K,)fTiO(C,)O ),I. 2H 0 proceeda to the
1~ ~ 4 2
following scheme:
FTi0(C 0 ~ 4X1TnO, +16F SO Ulnso t5TiOSO #20.C0 +
5
K2 . 2 4)21 1 2 4' 4 4 2
7K2 so 4+16H2O.The first st.,.,ve of t'~e ox4dation of
K[Ti(c 2 10ij)2I - 2H20 is tile folloviing:
5K[Ti(c 0 X1In0 ~4H SO +H 0 .0a Minso. t')H iTio(C 0 +
2 4)21# 4 2 4 2 1 2L 2 4)21
+ 3K SO . The gross-reaction of the oxidation of
2 4 ~o
[Pt(NH 3 )43 LTiO(C204)21 . 2H20 at 55 C proceeds according
to the followint; schene:
5 CP t ( "I H3)4)[TiO(C204)3 ~6 P21r. 04 o9H2so 4~ 6,:nSO4
f5LPt(NH 3)4 (OH )2)SO4 +20.C0 2t5TiOSO4+3K 2so4+141H2 0. The
results show that no separation of the titrated oxalate
groups takes place in the complex oxalate compounds of
the trivalent and tetravalent titarium. A gradt;al oxidation
Card 2/3 of the oxalate groups was found only in the complex

'A"he OxidatIon of Complex Titanium Oxalatee in the 11- 1212
Potentio.,:,,etric Titration
compounds with platinum. There are 3 fit,~,ures and 10
references, 8 of which are Soviet.
S17B!JITTED: JulY 18, 1957
Card 3/ 3

AUTHOR: qr~ 50'1/78-3-12-1/36

TITLE: Filipp Mikhaylovich Filinov (Obituary Notice)(Filipp Mikhay-
lovich Filinov (Nekrolog))
PERIODICAL: Zhurnal neorganicheakoy khimii, 1958, Vol 3, Nr 12,
pp 2593-2596 (USSR)
ABSTRACT: The well-known Soviet inorganic chemist F. M. Filinov died on
November 10, 1956. Since 1932 Filinov had worked in the field
of inorganic chemistry and especially in regard to the chemis-
try of the complex compounds. His first investigations in this
direction were those on the dihydroxy platinates and on the
isomeric salts rt(NH 3)4) ~"14' (OH)2] and Ept(NH3)4'(OH)21
EP tC141. This second compound was synthesized for the first
time by Filinov. His dissertation in 1939 dealt with the
migration processes in complex compounds of platinum. In 1939-
1941 Filinov worked with A. A. Grinberg in investigating the
transformations in complex compounds by using radioactive
isotopes. F. M. Filinov was also active in developing analytic
techniques for the noble metals using radioactive indicators*
Card 112 In regard to biochemical problems, he worked out in great

SOV/7e-3-12-1/36
Filipp Mikhaylovich Filinov (Obituary Notice)
detail means of investigating hemoglobin using radioactive
isotopes. Filinov was especially active in the Leningrad
Technological Institute, Chair for the Chemistry of the Rare
and Radioactive Elements. F. K. Filinov becafte professo.r.in 1956.
There are 11 Soviet references.
Card 2/2

GHINBERG, A.A.- PRTRZHkK, G.I.; IIIKOLISKATA, L.Te.; PTITSYN. B.V.; FILINOV,
YIONO [~aceasedl
Now means of preparing tetravalent uranium derivatives. Trudy
Radiev.inst.AH SSSR. 8:166-169 158. Oup-A 12:2)
(uranium compounds)