SCIENTIFIC ABSTRACT GRATSIANSKAYA. L.V. - GRATSIANSKIY, N.N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000516610006-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: July 27, 2000
• Sequence Number: 6
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

"-ACC NR% AP60007133 SOURCE CODE: UR/0240/6-5/0091009/0114/0114
V.
Ravinskayat F. S.;,Gratgiqn
q);A
!AUTHOR:
,.y
ORG: City Sanitation Epidemic .Station (Gorodskaya sanopidstautsiya);
Sanitation Epidemic Station of Lenin Rayon, Leningrad (sanepidstantsiya
Leninskogo rayona)
TITLE: Working health conditions and incidence of disease of textile
mill workers
SOURCE: Gigiyena i sanitariTRI no. go -1965# 114
TOPIC TAGS: industrial medicine, textile industry
ABSTRACT: The authors studied three,groupa of workers at a textile'
mill to-determine the effects of unfavorable working conditions on
disease inoidenoee The first group of workers was exposed to excessive
dust; the second group was exposed to an Insignifioant amount of dust.,
a moderate amount of noisep increased a1r humidityp and ph-ysical strain
(carrying loads of 8 to 12 kg); ando the third group was exposed to
high room temperature and intensive noise, In each group there were
more than 100 personst mostly women, with no significant differences
in age or length of emplo7mento The authors found the highest
incidence of disease with the highest loss of working days in ',he third
Card 1/2 UDC: 613.6:677,022

L 11141-66
ACC NR, AP60007
oup, This group had the highest number of angina cases and acute'
F
iseases of the respiratory passages and lungsj, and this is attributed
to high room temperature, A high incidence of hypertonic diseases and
neuroses was also found and is attributed to intensive noise, The
first'group had the highest incidence of respiratory organ chronic
diseases and skin diseases, and this is attributed to the excessive
dust. The-authors compared the data for the textile workers with data
for garment workers in sewing plants where most of the unfavorable
working conditions are absent and the workers are predominantly women,
For the textile mill workers,, the incidence of heart disease was 3
times higher,, the incidence of ulcers was 6 time higher, and the
incidence of pleuritiss bronchial# and hypertonic diseases was 2 times
higher. The authors conclude that unfavorable working conditions
increase the overall incidence of disease and certain nosolQgical
forms,, and have made specific recommendations for improving conditions
at the textile mill. Orig* art* has:, nones
SUB CODE: 06/ SUBM DATE: 00/ ORIG MW: 000/ OTH REP: 000

GRATSIAWSKAYA, U.14.
Visibility of slepals on the ecreen of cathode-ray tubes. Nauch.
do),,I.vys.sbkoly; radiotekb.i elektron. no.4:189-,-Oo 158.
OtIRA 12:6)
1. Kafedra eloktronnykh priborov Moskovskogo onergetichnskogo
institute.
(Cathode ray tubes)

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GRA,TSLWSKAYA. 14. M.
Storage characteristics of cascade screens and calculation
of the visibility of the signal. lzv.vyB.uchob.zav.;
radiofiz. 2 no.5:759-765 159. (MIRA 13:5)
1. Hoskovskly onergetichesicly ipstitut.
(Television--Picture tubes) (Radio direction finders)

S/ 19 021000/002/04010906
D2 01 YD3' 01
,tUTHOR; GraTsianskaya, M. r-1-
TITLE: Investigating the signal visibility on CRT's with
0
brightness intensity markers
?ERIODICAL: Re'Lerativnyy zhurnal, Avtomatika i radioelektronika,
no. 2, 19062, abstract 2-3-87K (Tr. Mock. energ. in-ta,
1961, no. 34, 280-294)
TEXT: Experimental and calculated curves of visibility (V) of a
signal are given for type jO,/jrj(1ZLM) CRT's with different screen
characteristics. The agreement between experimental and calculated
visibility curves proves the correctness of the equation relat,~ng
the CRT screen chiracturistic, having brightness intensity markers
with the values determining the signal V at the screen. The most
suitable means of increasing the signal V is increasing the slope
of the CRT modulation characteristic. The arrangement used for mea-
;3urements simulated a circular scan CRT, operating with brightness
modulation. A detailed description of the measurement procedure is
given. /-Abstracter's note: Complete translation-_7
Card 1/1

S/194Z61/000/011/042/070
D256/D302
AUTHORS:
TITLE:
PERIODICiE:
Gratsianskaya, I.I.M. and i3oylco, V.A.
Some problems in the application of photo-multiplier
tubes (of Soviet-manufacture)
Referativnyy zhurnal. Avtor..iatika i radioelektronika,
no. 11, 1.961, 26, abstract 11 G177 (Tr. Mosk. energ.
in-ta, 1961, no. 34, 295-306)
TEXT: Results are presented of i-vestigating the photo-
multiplier tubes: IaY -19 (FEU-19), ~ZOZ( -32 (FEU-32) and ~-_V -34
(FEU-34) used for brightness control on the screen of an electron-
beam tube. A non-linear potential divilcr was chosen in order to
reduce non-linear distortions at large -.ttput currents of the photo-
multiplier, resulting in a better linearity of -the light character-
istic at high current and comparing favorably with figures obtained
when the recommended voltages were used. From the performed investi-
gations methods were found for improving the photo-multiplier stabil-
Card 1/2
V

Some problems in the application...
6/194-/61/000/011/042/070
)256/D302
it by reducing the effect of the tub(-, .. -, ue .2 refercnces.
27Abstracter"s note: Complete trans Iati'O ,
Card 2/2

GRATSIADISKAYA, N. N.; LISTOVA, N. M.
It pri uchastii- 0. A. GAIESKOY) (SSSSSR). Voprosy tipolo'g-JI-i tradlitsionnogr,
zhilishcha Tsentral'noy i Yugo-Vostochnoy Evropy."
report submitted for 7th Intl Cong, Anthropological & Ethnological Sciences,
Moscow, 3-10 Aug 64.

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Op&kW Mk4whissilan arA CoAkital of Cestreal 4
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(In Russian.) A. S. Sarin and
Astroal r4hijiArskoi Fixiki
Physics), V. 18, Oct. 1948,
nd**
p. 132&1331.
Shows that, in sensitized photographic film, the
coefficitnt of cantr"t In the region of sensitization
:jD '3 may be larger than, equal to, or less than in the 10

0 reirion of natural light sensitivity. Presents esuIR-14
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USSR/Chemistry - Photographic
"The Influence'of the Concentration of Bromine Ions
amd Hydr6xkl'Io.ns on the Photographic Properties'of
an Emul6ion," A. V.' Borin, Z. 1. Gratsi kays, and
R. A* Podchishchalova
Zhur Prik M2im, Vol 26, No 7, PP 708-720) 19s,3
Raising the conan of KBr above the equiv prevents
hazilormation during chemical development. The
centeis tbat hre formed during phys ripening par-
ticipate in the formation of photographic properties
,of thi. emulsion. A, ebange in the cone of Br and OR
271T23
.iouq at the start of chem, development has a sign-
ifi6aht 'effect an the contrast coef. As the concn
of tb6'above Ions increases, the contrast coef
grows. Raising the concn of Br ions at the start
of ahem development improves the sensitizing ef-
fect,of dyestuff in the emulsi6n. Observed the
disappearance of the desensitizing action of H-ions
on the light-sensitive layer that is optically sen-
sitized with disubstituted thiocarbocyanine dyes.
2=23

1. "The, 'Err~ct ,r
of Cntic-.1 Sen~!;i'tizat1m) ~f P-otcrrn-
1~'in CiAturn Lr~tdnir:-d Ir-t , f
Lenin.rmd, 19561. (Di-.inerfation rn-
,~'at.e in Tnchnlc~-l Sclence~
t!,c- L-oconn
' Ic
%"Iipc: n
M-f, Dof-ree of uland-4-
So: '~nizhmya Letorlist, blo. 10, 1956.

OO.-.OKHOVSXIy, yu.N.; GRATSIANSKAYA Z I
- 9_044!,- -
Research on the optical sensitizing of photographic emulsions.
Part 7: Influence of the color-forming components of color
development on the process of optical sensitizing. Zhur.nauchn.i
prikl.fot.i kin. 2 no.6:421-431 N-D '57. (MIRA 10:12)
1. Laningradakiy institut kinoinzhenerov.
(Golor photography) (Photographic sensitometry)

GRATSIAIISKAYA, Z.I.; SIDOMIKOV-4, P.T.
Effect of light diffusion in the top layer of a multilayer film
on the resolving power of the underlaying layer. Usp. nauch.
fot. 8:29-34 162. (MA 17:7)

MW M
104
S/058/6YOO0/0OY053/
A062/A101
"AUTHORS: Barro, M. I., Gorokhovskiy, Yu. N., Gratsianskaya, Z.
Pruss, P Kh.
Dependence of the resolving power of multilayer color films on the
disposition sequence of the layers,
PIMIODICAL: Refei~ativnyy zhurnal, Fizika, no. 3, 1963, ~8, abstract 315594
("Uspekhi nauchn..foto9r.11, 1962, v. 8, 21 - 28)
resolvometric balancing of three
TEM, Aconcept is i:ntro.auced for a
elementary images in the final positive color image. Requirements are form..
lated for the structure of a pair-of multilayer films forming OL set, in which
the resulting image can attain the highest resolution. A study was made on the
resolvometric properties of.7 sets of multilayer films with different sequ
enc6s 0
of disposition of the.layerspandit is shown that fulfillment of the presented.
balanc-
demands brin,is about effectively a higher resolution and a-resolvometric
ing of the set.,'The'resoltving and distinguishing powers of two negative multi-7,,,l
layer materials and the positive images obtained from them are compared. It is.11W
Card 1/2
-A

BARRO, M.I.; GOROXHOVSKIY, Yu.M.; GRATSIANSKAYA, Z.I.; PRU&S, F.Kh.
Dependence of the resolving power of mu.1tilayer color films
on the sequential arrangement of the lay6rs. Usp. nauch. fot. 8-.
21-28 362. (MIRA 17.-7)

GRATSIANSKIY, A.A.,
i_' ~~ fm ~j_ - - .. 1 1,
rorm of schizophrenia resistant to aminasine therapy (with sumary
in Frenchle Zhur.nevr. I psMa 59 no.2:172-176 159. (KMA 12:4)
1. Kafedra paikhtatrii (save - prof* AV. Susihnevskiy) TSentrall-
nogo inatituta usovershenstvovantys vrachey, Moskva
(CIMMMOKUUM, there uses
schizophrenia, relsist. forms (Rua))
(SCHIZO.OHMIA, there
chlorpromazins, resist. forms (Ruls))

CRATSIANSKIY, A. N.
IfYugoslavia (Physicogeographical Characteristics)."
Q
Thesis for degree of Cand. Geographical Sci. Sub
20 Jun 50, Moscow Order of Lenin State U imeni
M. V. Lomonosov
Sumaary 71, 4 Sep 52, Dissertations Presented
Lo_r Degrees in Science AIA Engineering in Moscow
1_n_12LO. From Vecherny&v;a Moskva, Jan-Dee 1950.

-L-A J"
tsufy 6
621.01
CIViTSIANSKIY3. AUDREY NIKOLAYEVICII G72
Priroda Yugoslavii (Yugoslavia Nature) Moskva, Geografigz, 1955.
241 p. illus., maps, tables.

s107316~V028100910051011
A057/A122-6
AUTHORS: Vdovenko, I. D., Gratsianskiy, I. N.
TITLE; Corrosion resistance of indium, tin, and indium-tin alloys in the
presence of surface-active substances
PERIODICAL: Ukrainskiy Miimicheskiy zhurnal, v. 28, no. 9, 1962, 1069 - 1072
TZKT: At the Institut obshchey i neorgani'cheskoy khimii AN USSR (Insti-
tute of General and Inorganic Chemistry AS UkrSSR) corrosion properties of in-
dium, tin, and their alloys were studied at room temperature in 60% H,,AOjj in the
presence of the surface-active substances heptyl-octylamine, decyl-dodecylamine
mixtures, or octadecylarnine at various concentrations (0.094 and 0.265 g/1). Al:
loys of the following composition were studied -(in at%): 99.0, 97.0, 87.5, 75. 0
62.5, 50.0, 37.5, 20.0, 3.0,'1.0. The tests were carried out with disc shaped
samples 80 - 100pthick, measuring during 12 days the stationary potential, and
the corrosion rate was determined gravimetrically. The electrode potentials
shifted towards negative values after the addition of the amines, apparently due
to the formation of an inhibiting film which arfects the cathodic processes. The
Card 1/2

GAT51 A115K I Y, I. H. PTIOOLEW; ('#' THt: T~icoiiy Am) r,ir CULAI I ON ~r ALTUINAT I N-'.;-
(:tJ,InCt,T MrA'J(JQltl,-, ELEMENTS." '5tu 6 Juti r~2, VO~vr.,,%w oF ~(:I;m
If-IT141 V. M. MOLOTOV (Ut',tCr4TATIrN FOrt THE DECOCE: ()F' CA;iC)((,,.-E tit Trcimict-~. S7cfrl4(:clj
"'f); VrcjjrntiAYA Mlo~;itvA, JAHUAPY-OCCCML~ril

GRLTSIA19SKIY, I.N., kand.takhn. nank.
Aotlve RO dIfferentlator, Trmdy 01 no.13t32-41 153. (Irm 11W
1' Mookovskly onargetlohookly instItut Imeni r*X, Nolotoval, Ufe&a
elektropriborostroyonlys.
(Caloul&ting =whines)

SOVI 112-57-6-1?890
Translation from: Referativnyy zhurnal. Elektrotekhnika, 1957, Nr 6, p 177 (USSR)
AUTHOR.: Gratsianakiy, I. ?j.
m_'hffa'-e-_for D
TITLE: Fundament lF esigning Block Circuits of Computer
Amplifiers (Onnovnyye formuly rascheta blok-skhem reshayushchikh usiliteley)
PERIODICAL.: Tr. Mosk. Energ. in-ta, 1956, Nr 18, pp 297-309
ABSTRACT: A general block circuit is presented, as well as a table of specific
block circuits of computer amplifiers that can perform scale conversion,
inversion, differentiation, summation, and combined differentiation or integra-
tion with simultaneous summation. Design formulae are presented for the
transmission factor, input and output impedances of a scale amplifier operating
with a negative feedback, a differentia'tor, an integrator, and an adder;
sinusoidal waveshape of the input voltage is assumed. An angular -error
formula is also given for the integrating and differentiating amplifiers -
Amplifier errors due to DC amplifier zero-point drift are indicated. A proce-
dure for designing differentiator and integrator components is suggested.
Card 1 /Z

SOV/112-57-6-12890
Fundamental Formulae for Designing Block Circuits of Computer Amplifiers
Some hints are given on the selection and calculation of components of a
negative feedback amplifier. A block circuit is described of an amplifier that
has a low zero-point drift secured by an additional amplifier with a vibropack,
and a method is offered for calculating the amplification factor and the zero-
point drift voltage for a low-drift amplifier. 4 illustrations, 2 tables.
Bibliography: 7 items.
1. M. V.
Card 2/2

A
GRATSINjUIT, I.N.
Modulation transi4tters used In controlling cathode ray tubes.
Ism. takh. no.2:74-77 Nr-Ap 157, (KM 10:6)
(Cathode ray tubes) (Blectronic measurements)

GRATSIANSKIY. Igorl.Nikolayevich, kand. tekhn.nauk, dots.;
teAn. nauk, red.
[Electronic measuring devices; abstract of lectures] Elek-
tronnye izmeritelInye pribory; konspekt lektsii. Moskva
Moak. energ. in-t. Pt-3- 1960. 143 P. (MIRA 16:7~
(Electronic measurements)

BTXOV, Mikhail Alek9androvioh;-QRLT!~IAXS-jY Igorl Nikolayevich; 11FIR,
X
Kiih-iji-o-4-na;
LEVIN, Mark
Ise'ak losifovich; KUTYASHOVA, Yelens
Iosifovich; POTECT, Vladimir Tikhonovich; STRUAT-OV, Ivan
Aleksayevich; TALITSKIT, Aleksandr Vasillyevich; UARCHINKO.
Roman Romenovich; SHUMILOVSKIY, Nikolay Ilikolayevich; KASATKIN,
A.B.. red.; VORONIN, X.P., takhn.red.
[Course on electric measurements] Kura alaktrichaskikh Ismerenil.
Pod red. V.T.Prytkove i A.V.Talitskogo. Moskva, Gos.energ.lzd-vo.
Pt.l. 1960. 479 p. Pt.2. 196o. 430 P. (KIRA 13:10)
(Electric measurements)

S/115/60/000/02/015/031
D002/003
AUTHOR: Gratsianskiy, I.N.

TITLE: A Small-Size Galvanometric Amplifier/-on Semi-Conductive
Devices V
PERIODICAL: Izmeritellnaya tekhnika, 1960, Nr 2, pp 26-29 (USSR)
ABSTRACT: The galvanometeric amplifiers, "GU11 are used as
attachments for increasing the sensitivity of mea-
suring devices, for instance, of vibrational oscillo-
graphs. The general theory of am lJfiers J%'GU") has
already been treated previously /RRJ-Ief:1-3 R.R.
Kharchenko ~_Ref 4_7 discussed the interc-6upling pro-
blem of "GU". The present article contains a descrip-
tion of a "GU" model consisting of miniature units
shown in a block diagram (Figure 1): The miniature
"GB" galvanometer, designed by Ye.S. Borisevich
Z-Ref 5_7, a sulphur-lead photoresistance of special
design of the VEI imeni V.I. Lenina (VEI imeni V.I.
Card 1/2 Lenin), and a d.c. amplifier on transistors. The

S/115/60/000/02/015/031
D002/003
A Small-Size Galvanometric Amplifier on Semi-Conductive Devices
design and performance of the unit are explained. The
family of amplitude characteristics (Figure 4), and
the amplitude-frequency characteristics (Figure 5),
are shown in graphs. The amplitude characteristics
are linear with an error not exceeding 1%. It is
concluded that it is possible to construct multi-
channel miniature galvanometric amplifiers on semi-
conductive devices. Engineer L.M. Sukhorukova took
part in the experimental work. There are 5 diagrams,
2 tables, 4 graphs, and 6 Soviet references.
Card 2/2

or, /A d-A
GRAT-STAN TY, f . ". , k Gra 0tual
G 1101% Li L'I
Dissertation: *Measures Against Continuous Chips
Cand Tech Sci, Moscow Order of Lenin Aviation Inst
(Vechernyaya Moskva, Moscow,, 11 Jun 54)
in Cutting Steel on High-Speed Lathes.0
imeni Sergo Ordzhonikidze,, 22 Jun 54.
SO: SUM 318, 23 Dee 1954

GRATSIANSKIY. L.N., Imud.tekhn.nauk
Direction of the movement of chips in free turning of steel.
Izv. vys.uchob.zav.; mashiiwotr. no.8:110-114 16o.
(MIRA 13:9)
1. Moskovski7 aviatsionnyy institut.
(Turning)

GRA6TSIANSKIT, L.N.
Using chip-vringling devicea. Rashinostrottell no-10:30 160.
(MIRA 13:10)
(Metal cutting)

3/145/60/000/008/013/014/XX
D211/D304
AUTHOR: Gratsianakiye L.N., Candidate of Technical Sciences
TITLE: The direction of shaving flow during the free turning
of steels
PERIODICAL: Izvestiya vyeshikh uchebnykh zavedeniy. Mashinostroye-:
niye, no, 8t 1960t 110 - 114
TEXT: The article deals with the characteristics of shaving forma-
tion of steels 45 and 18)(FIBA (18KhNVA). Cylindrical and tubular
specimens were turned on a 1616 type lathe using tools with a T15
K6 (T15K6) hard alloy tip* The cutting speed was 125 m/min and the, 20
feed was 0.21 ram per revolution. The angle between the cutting edge
and the track left by the shaving on the front surface of the cutt-
ing tool, covered by chalk paste was measured. The removed ribbons
of shavings were annealedp unwound and flattened and the radius of:~
The plane coil obtained was measured. To study shaving formation
under various conditions a series Of 4 experiments were carried outi~
The author concludes that with tools having the angles 900 andi"
Oard 1/2

5/60/000/008/013/01
The direction of shaving flow D211/D304
00 LAbstractor's note: cp and Inot defined] the shaving moves
at a right angle to the cutting edge. If P = 900 and /1./ 0 the
shaving moves at an angle w = 900 � ). with respect to the cutting
edge. If (p / 900 and ~,/ 00 the shaving has not the form of a
straight ribbon but that of the surface of truncated cone. There
are 6 figures and 3 Soviet-bloc references.
ASSOCIATION: Moskovskiy aviatsioxinyy institut (Moscow Institute
of Aviation)
SUBMITTEDt March 13F 1959
41X~C I
S11 4
Card 2/2

GRATSIANSM, M.
"Fundamental principles of planning the aprons of low pressure dams."
Dissertation for Candidate of Technical Sciences, AU-IiLicnn Sci. Res. Inst. of
Water supply, Sewerage) Hydroengineering Caastruc'i.-)n and Engineering Hydrogeology."
(VODGEO)
Subject: Hydroengineering building and construction.
Gidrotekhnicheakoye, stroitellstvo, 12, 1946.

GRATSIANSKIT, X.N* kandliat tokhnichemkikh nauk, doteent.
-- I - - I *np-- R 04
-,
V, _-.- Y
Characteristics of Investigating and designing low pressure damm
under conditions where the river bottoms are inundated** Sbor.
trud.NISI no,9:41-55 855 0 (KLRA 10s3)
(name)

OrIRA1__S:rANSIClYj'M-N-
1, K K* Wave action an OV0.1flaw daffit tin
Russion), Gidrotskb. Strait. 24, 7, 31-3% 1935.
hicasurements were made on a 1150 scale model of the Kuy-
bitschev dam for the influence of traveling waves upstream.of the
dam. The shape and velocity of these wAyesArd Ittgued to be corr
scant, the transport over the dam& is shown to change only.by the
change of water level upstream, the Iiw is not chansed.,
It the wave amplitude is of cim same order At the. water hoisht I
she dam, the transport, over the dam f0f rising wav - is
SteAtly different irdm that for falling wave. .-Semi-empirical for.
mulas are given (from experiments) for transport in pre.scace.of
~,Waves (dimensionless by transport without iraves) exprcsgl;d in
warer-wave height u stream of the dam, neglecting kinetic energy.
p
Mean coefficient of transport checks.well 16ith experi'ments. ~ From'
the transport, w4rer height downstream of the'dam can be calcu-
laced by Bernoulli's law and the momentum eq"ioa.
It is recommended to take aciount of the e4tc'%3 of these wind-
gencrated waves upstrearn and to compute them with model experi-
ments in the consgruction of new dams.
R.~ Timman, Holland

SOV/124-58-10-11170
Trar:31ation from: Referativnyy zhurnal, Mekhanika.. 1958, Nr 10, p 66 (USSR)
AUTHOR.~: Gratsianskiv, M, N. , Kulygin, )3. A.
TITLE: Wave Action on Overflow Dams of Practicdl Shape (Deystviye 1foln
na vodoslivriyye plotiny prakticheskogo proftlya)
PERIODICAL: Sb. Tr. Mosk. inzh. -stroit., in-J, 1957, Nr 20, pp 149-168
ABSTRACT: The influence of waviness in the head-water basin on the water-
discharge rate through the spillway is described according to experi-
mental inVesti8ations carried out under variable head conditions and
&fferent spillway flow into the tail-water basin, It is shown that
maximum wave pressure upon the spillway gate obtains when the
orifice is fully closed, viz. , when the gate is lowered completely.
Under these conditions the wave pressure can surpass by 50 or
more percent the pressure existing under calm-surface conditions.
To prevent icing of the gate in winter due to waves spilling over the
gate it is recommended that the top of the gate and the height of
areas that should not be flooded be raised above the calm-surface
level by a height equal to the surn of the wave height, the reach of
Card 1/2 the waves, and the rise of the mean wave line. Spillway discharge

Wav(~ Action on Overflow Dams of Practical Shape
SOV/124-58-10-11170
per second under wavy conditions can exceed the maximum calculated discharge by
as much as 605o. Even under minimum gate opening the waves penetrate into the
tail-water basin and impair considerably the energy dissipation of the flow and the
conditions for the approach and mooring of ships. To minimize the wave pressure
on the gates and the waviness in the tail-water basin, specially designed energy
dissipators are recommended, such as pneumatic, solid, and ribbed visor (surface-
skimming) types.
B. A - Pyshkin
Card 2/Z

GRATSIAZISKIY,, Mikhail Nikolayevich? dots.p kand. tokhn.nauk;
]klZkMmTlmySKrr,--yu-~-iy--V:[~dimirovicho dots.., kand. tekbn. nauk;
IZOTOVP B.S.0 dots., retoenzent; SUROV, I.Ye., inzh., retem-
zent; BONDARIp F.I., inzh,, reteenzenti SAMSMOVA, X.T.,, rad,j
VORONINA, R.K., tekbn. red.
[Hydrology and bydraulic structurso) GidzologUA i gidrotokhni-
cheskie sooruzheniia. Moskva, Goo. izd-vw,wV~sshaia W*Ola
1961. 351 P. 15:31
1. Kafedra gorodskogo stroitelletva i khozyayatva Leningrad-
skogo inzhenerno-stroitellnogo instituts. (for Izotov).
(Hydraulic engineering)

GRATSIAIISKIY, M.N., kand. tekhn. Dauk;- KOSTOMAHOV, V.M., kand. tekhn.
-------imUk,---A-ak,',SAIID;ZOVSKIY, Yu.V., kand. tekhn. nauk; KARAGODDI,
V.L., Inzh.j YWAGODIIII A.L., inzh.; ANUFAIYEV, V.Yo., kand.
tekhn. nauk; KURUYUI%,(AI, M.D., inzh.; DZHUNKOVSKIY, N.N.,
doktor tekhn. nauk, prof.; ABIUMOV, S.K., kand. tekhn. nauk;
KEDROV, V.S., kand. tekhn. nauk; GIB,%IILkN, Ye.Ye., prof... red.;
YEGOROV, P.A., inzh., red.; VARGABOVA, A.N., red. izd-va;
LELYUKEIN, A.A., tekhn. red.
[Vanual for the design., construction and operation of urgan
roads, bridges and hydrotechnical structures) Spravochnik po
proektirovaniiu, stroitellstvu i ekspluatatsii gorodskikh do-
rog, mostov i gidrotekhnicheskikh sooruzhenii. Red. kol. Ii.E.
Gibshan, NX'.Dzhunkovskii,, PeA.Egorov. Moskva, Izd-vo M-va
IR. . [Hydrotechnical structures) Gidro-
komnun.khoz. RSF, Vol.2
tekhnicheskie sooruzheniia. Red. toma: II.N.Dzhunkovskii,
M.D.Kurdiumov. 1961. 706 p. (MIRA 15:3)
(Hydraulics) (Hydraulic engineering)

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GRATSIAMIY, N.N.; K&LYUZMU, P.P.
Ilectrodeposition of copper, tin, and lead soluticus of complex
compounds. Ukr*khin.zhur.l9 no.4:377-385 '53. (KLBA 8:2)
1. Institut obshchev i neorganicheakoy khimii Akademii nauk
us=,
(Electroplating) (Compounds, Complex)

tau. VC1,

for 49

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observed, w1dell contradicts titcTAttimmul th~dey (Z. artorg.
The corrmiionlimits In
1%_9404,60111 - is Qbie&~(t With ii 50 at. typ lit tnt the COfftj-
sion diagrala. pr~'bdttuhfy through a MO.-
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rrosion resiAzince Ilinit is ob-
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arp lpfIrgticto. W. M.

GRATSIANSKIT. V.V.; KALYUZHUAYA, P.P.
Studios on the corrosion resistance of metal solid solutions.
Part 4- The system BI-Sb. Zhur.fIsAhim. 31 no.4:88?-892 Ap '57.
(MLIRA 10-7)
1. Akadentys nauk USSR. Institut obsbahey I neargenlebeekoy Wall.
(Solutions. Solid) (Disunth-satisow alloys)

AUTHOR: Gratsianskiy, N.N., Yalyuzhnaya, P.P. 76-11-12135
TITLE: The Investigation of the Corrosion Resistance of Solid Solutions
of Metals (Isoledovaniye korroxionnoy toykasti tverdykh rastvorov
metallov) VI. The Ag-Cd System (VI. Si:tema Ag-Cd)
PERIODICAL*. Zhurnal Fizicheskoy Khindi, 1957. V01. 31, Nr 11, pp. 2458-2463
(USSR)
ABSTRACT: This is a continuation of previous works by the same author LRef.1
Here the corr ion resistance of Ag-Cd-alloys was investigated by 11
the method of determining losses of weight in a 5% HCl solution and
in a 3% NaC1 solution at room temerature. The potentials of
corroding alloys were measured. By the method of measuring the micro-
strength the thickness of the loosened alloy surface layer before
and after corrosion was determined. In the 5% H01 solution and In
the 3%NaCl solution a considerable decrease of weight losses VMS
found within the domain of 40 At.% silver in Ag-ca alloys. This in-
dicates the formation of corrosion-resistance limit, probably at the
cost of the forming of an anti-corrosion surface layer of particles
of the constant Ag2ca 3-compound. The potential amounts of the cor-
Card 1/2 roding alloys, which were measured during corrosion investigations

AUTH6RS: Gratsianskiy, H. N., Bogachevaj N. A. 76-32-4-24/43
TITLE: Investigation of the Resistance to Corrosion of Solid
Metallic Solutions (Issledovaniye korrozionnoy stoykosti
tverdykh rastvorov metallov)The In- Pb System (Sistema
In - Pb)
PERIODICAL: Zhurnal Fizicheskoy KJlimiit 19589 Vol- 329 Nr ij,
PP- 875 - 681 (USSR)
ABSTRACT: Determinations of the resistance to corrosion in solutions
of 3% NaCl , 5% HC1 and 1% H2so4 were carried out at 2ooC,
as well as in 1% citric acid solutions at 16, 2o, 3o and 50 C,
the composition of the surface layer having been investigated.
The experimental results in 1% H 2SO correspond to those of a
previous work, while in 1% citric alid the displacement of the
limit of the resistance to corrosion takes a regular course
with the increase of the content of the more resistant component
indium; this is explained by the formation of an anticorrosive
surface layer. The examination in 3% NaCl and 51A HC1 solutions
showed that the velocity of dissolution in the latter is
Card 1/3 essentially greater, and that a limit of the resistance to

76-32-4-24/43
Investigation of the Resistance to Corrosion of Solid Metallic Solutions,~
The In Pb System
corrosion is present at 6o atom% Pb, while in the case of the
first mentioned a slight loss of weight was observed,. The
potential measurements showed that after some time a constant
value is achieved with the alloys rich in lead having values simi-
lar to those of lead and those with indium being similar to
those of the indium potential. In 5% HCl at a content of about
5o atom% Pb a jump of the curve composition vs. potential was
observed just as well as in 1~ citric acid at a content of from
50 - 7o atoelfu Pb. According to a method elaborated by M. B.
Neyman and A. Ya. Shinyayev (Reference 2) determinations of the
surface layers were carried out and it was observed that their
composition prior to corrosion corresponds to that of the
alloy which consist of lead atoms from the corrosively less
resistant to the limit of corrosion resistance; in alloys of
less than 75 atom% lead the formation of the limit of corrosion
resistance is explained by the formation of a surface layer of
a solid solution of In-Pb at 2:3. During corrosion indium enters
Card 2/3 solution in spite of the low resistance of lead., The resistant

76-32-4-24/43
Investigation of the Resistance to Corrosion of Solid Metallic Solutions.
The In - Pb System
surface layers showed the same composition to a depth of
3P, the non resistant to a depth of 59, the latter having
been considerably loosened to a depth of 6g on the action
of 5~ HC1 - the first mentioned were not. There are 7 figures,
2 tables and 2 references, 2 of which are Soviet.
ASSOCIATION: Akademiya naukftrSSR~nstitut obahchey i neorganicheskoy khimii
Kiyev (KiyevInstitute for General and Inorganic Chemistry.,
AS Ukrainian SSR)
SUBMITTED: November 12, 1956
AVAILABLE: Library of Congress
Card 3/3 1. Indium-lead systems--Corrosion

AUTHORS: Crp.141-siwanskiy, N. It. K-.1yuzhnaya, P. F. 76-32-5-12/47
TITLE: Inveat ion of Corrosion Resistance of Solid Metallic
Solutions (Isnlodovaniyekorro~,ionnoy sto-konti tvcr(lykh rait-
a
vorov metallov) The System ML; - Cd (Sistana 11c - Cd)
PERIODICAL: Zhurnal fiziches-koy khiriiii, 1-956, Vol. 32, Nr 5,
PP. 1038 - 1o42 (USSR)
ABSTRACT: In continuation of already carried out experiments two types
of structures are investigated in this paper; after annealing
at convbrsion temperatures of solid solutions into chemical
compounds (I), after annealing on conditions excluding the

.L
formation of chemical compounds (II), with the function of
the corrosion resistance li.-,iit of the M& - Cd system on the
a&:ressive medium, as well as the cozipocition and thickness
of the surface layer at the boundary alloy-corrosive medium
of the parts prior to and after the occurrence of the corrosion
resistance boundary being investi,-,,zited in the present case.
Alloys of different cadmium content, as well as pure metals
were investigatedp with a 0,1 n sulfuric acid solution and a 5%
sodium sulfate solution being used. It was observed that alloys
Card 1/3 richer in magmesium dissolve more quickly in both solutions,

Investio-ation of Corrosion Resistance of Solid Me- 76-32-5-12/47
-tallic Colutions. The SZfstem Mg - Cd
with a covering layer of corrosion products difficult to
solve being formed in the sodium sulfate solution, which fact
makes difficult a judgement on the limit of corrosion resistance.
The potential measurements of the corroding alloys showed
an equal change with the composition, with the potential sta-
bilizing more quickly in the alloys (I) in both solutions, which
is explained by a regroupine of the atoms in the alloys (II).
The polarographic analyses of the solutions prior to and
after corrosion, after the dissolution of the thin surface
layer of the alloys showed that prior to the corrosion the
composition of the surface layer corresponds to that of the
alloy, while-after the corrosion the limit of the corrosion
resistance is formed by the formation of a layer of cadmium
atonis on the surface in 0,1 n sulfuric acids, and in 5% sodium
sulfate solutions corrosion products form which are difficult
to solve. The investieations of the loosening and thicluiess of
the surface layer showed that after the corrosion the loosening
in alloys rich in cadmium amounts to 1,54 while this value
Card 2/3 is twice as great in alloys rich in magnesium. There are 3

.InvestiCation of Corrosion Resistance of Solid Me- 76-32-5-12/47
tallic Solutions. Tne System ATj - CD
figures, 2 tables and 2 references, 2 of which are Soviet..
ASSOCIATION: Akademiya nauk USSR Institut obahchey i neorganicheskoy
khimii,Kiyev ( Kiyev Institute for General and Inorganic
I
Chemistry, AS Ukrainian SSR)
SUMMITTED: November 3o, 1956
1. Corrosion resistant alloys--Analysis 2. Cadmium-
magnesium systems--Corrosion 3. Cadmium-magnesium systems--
Surface properties 4. Polarographic. analysis--Applications
Card 3/3

5'(4),18(7)
.gUTHORS.
SGV/76-33 -39/45
Gratsianskiy, N, N. Ryabov, A. K. -2
TITLE: Surface Phenomena in the Corrosion of Solid Solutions of
Metals (Poverkhnostnyye yavleniya pri korrozii tverdykh rastvo-rV.,
metallov). System Cd - Hg (Sistema Cd - Hg)
PERIODICAL; Zhurnal fi4zicheskoy khiMi47 1959, Vol 33, Nr 2, PP 487-491
(USSR)
ABSTFUXT: Diffusion processes which take place or, -the surface layers -
at the boundary between solid metal solutions and the corrosion
medium can lead to the formation of a corrosion-resistant layer
as well as an intensification of the destruction by corrosion
of the alloy (Ref 1). In the case that the surface-active
component is a corrosion-resistant element a passivation of the
surface and a partial inhibition of the dissolution process
take place. In order to take into consideration the effect
of the surface-active component the surface tension(I must be
determined in its dependence upon the composition. The value
for 6 is best determined at the boundary between the melted
metal and its metal vapor. In the work reported here the
Card 1/3 determinations were carried out on the system' Cd-Hg at a

Surface Phenomena in the Corrosion of Solid SOV/76-33-2-39/45
Solutions of Metals. System Cd - Hg
temperature 300 above the melting points of the metals and
above the flow temperature of the alloy and at the phase
boundary (with metal vapor). The following compositions were
investigated (given in weight ~6): pure Hg, Cd - 1. Vio, Cd- 5-0'i-,
Cd - 25-0%, Cd - 40-0P', Cd - 49'5%, Cd - 60.V1., Cd - 75-W.,
and pure Cd. The vacuum apparatus (Fig 1) with which the
6-measurement was carried out is similar to the gravitation
apparatus according to P. P. Pugachevich (Ref 2). The value
obtained for 6 was calculated using the equation of Kontor,
which was completed by B. 1. Bering and No L, Fokrovskiy
(Ref 3), and a value of 467 erg/cm 2 was found for Hg at -100C
and 586 erg/cm2 for Cd at 3500C. While in alloys rich in
cadmium an increase in the mercury content from 0 to 30 atom%
changes only inconsiderably the value for 6 (of 586-587 erg/cm2
the alloys rich in mercury showed an increase of the b value
from 487 to 558 erg/CM2 with an increase in the cadmium oontffitft~jn
0 to 55 atom%. The point of transition from the Ot to the /3
Card 2/3 phase, which occurs with a mercury content of 35 atom%, was at

Surface Phenomena in the Corrosion of Solid SOV/76-33-2-39/45
Solutions of Metals. System Cd - Hg
2
6 . 618 erg/cm . Since mercury in the Cd - Hg system is both
a surface-active component and an element which causes resistance
to corrosion (Ref 3) a pa8sivation film forms quickly in this
case. There are 3 figures, I table, and 3 Soviet references.
ASSOCIATION: Institut obshchey i neorganicheskoy khimii)Kiyev (Institute
of General and Inorganic Chemistry, Kiyev)
SUBMITTEDs August 8, 1957
Card 3/3

5(4)9 18(7) SOV/76-33-3-27/41
AUTHORS: Gratsianskiy, N. N., Bogacheva, N. A.
TITLE: A Study of the Corrosion Resistance of Solid Metallic Solutions
by th~ blethod of Radiotracers. The System In-Pb (Issledovaniya
korrozionnoy stoykosti tverdykh rastvorov metallov metodom
radioaktivnykh izotopov. Sistema In-Pb)
PERIODICAL: Zhurnal fizicheskoy khimii, 1959, Vol 33, Xr 3,
pp 677 - 682 (USSR)
ABSTRACT: In the case of a successive removal of thin layers of a metal
(or alloy) the method of radiotracers permits the determina-
tion of the action of a corrosive medium and the variation
of the surface layer according to the individual parts
(Refs 3-10). By this method the alluys I Pb -24-01 At,~'49
In - 75 At"". and Nr2 Pb - 55.21 AtIply 'In 44-79 At~_-, were in-
vestigated here using In114 and by means of the unit of the
B type designed for measuring radioactivity. The depth of
micropores was measured by "pressing" a RbxCl solution (in
alcohol) "into the sample" at 125 atmospheres absolute pressure.
11,t sulphuric acid solution vervod as a corrosion liquid, which
Card 1/3 acted in the sample for ton minutes, one hour, six hours, ete

A Study of the Corrosion Resistance of Solid Itiletallic SOV/76-33-3-27/41
Solutions by the Mothod of Radiotracers. The System In-Pb
at room temperature. The depth of the micropores of pure
indium. amounted to 3,Kapproximately before corrosion and
up to 7~L, after corrosion, in the case of Pb it was about
2tv before corrosion and 4 afterwards, in the case of
nonresistant In-Pb alloys itwas about 1 before corrosion
L surfaces made by
and about 2f5~afterwards. Images of samp
means of an electron microscope (Fig 1) that the porosity
of the In-Pb surface and of the nonresistant alloy It I
increases considerably after corrosion and remains almost
unchanged in the case of Pb and the resistant alloy Nr2. If
corrosion acts for six days, only In from the In-Pb solutions
enters reaction and the surface is enriched vrith Pb. After
twelve days a surface layer 2,~K thick is therefore produced
from Pb, the In content increases up to a depth of 12p,
and a composition according to that of the alloy is found
above that point. The formation of the surface layer depends
on the composition, the rate of dissolution of the unstable
component, as wall as on the rate of atomic rearrangement
in the alloy. There are 3 figures and 15 references, 10
Card 2/3 of which are Soviet.

A Study of the Corrosion Resistance of Solid Metallic SOV/76-33-3-27/41
Solutions by the Method of Radiotracers. The System In-Pb
ASSOCIATION: Institut obshchey i neorganicheskoy khimii, Kiyev (Institute
of General and Organic Chemistry, Kiyev)
SUBMITTED: August 20, 1957
Card 3/3

5W, 18(7) SO'1/76-33-5-7/33
AUTHORS: Gratsi mxp"N." I-, Kalyuzhnaya, P. P. (Kiyev)
TITLEi Investigation of the Corrosion Resistance of Solid Solutions
of Metals by the Method of Radioactive Isotopes (Issledovaniye
korrozionnoy stoykosti tverdykh rastvorov nietallov metodom
radioaktivnykh izotopov).II. The System Mg-Cd (II. Sistema
Mg-Cd)
PERIODICAL: Zhurnal fizicheskoy khimii, 1959, Vol 33, Nr 5,
PP 997 - 1001 (USSR)
ABSTRACT: A previous paper (Ref 1) dealt with the problem mentioned in
the title in connection with indium-lead alloys. This paper
reports on the results of investigations of two Mg-Cd alloys,
namely alloy 1 (26.6 atm~p/ mg, 73 -'/ Cd) and alloy 2
(74.5 05atnt"'
atmj. Mg, 2 -5 atm% Cd). Cd was added while the alloys
were melted. Rb8z was used in determining the depths of the
micropores. The method of this determination is described
in reference 1. The following observations were made with
regard to the distribution of WC1 in the surface pores of
the me-tals Mg, Cd, and the '.Ig-.Cd alloys; with Cd and Mg, Rb-*Cl
Card 1/3 had penetrated to a depth of 11,u before the corrosion, with

Investigation of the Corrosion Resistance of Solid SOV/76-33-5-7/33
Solutions of Metals by the Method of Radioactive Isotopes. II. The System
Mg-Cd
Cd to a depth of 3p and with Mg) of 5 after the corrosion.
With alloy 1 RbACI penetrated to 1 ~e'fore the corrosion;
the penetration depth remained unlan ged after corrosion.
With alloy 2 Rb4*Cl penetrated to 2 before corrosion, and to
4~1 after corrosion. The isotope exchange between Cd, Mg-Cd
a oys, and Cd ions in solution was investigated by means of
the isotope Cd115. The alloys were exposed to a jet of
CdSO4 solution with pff - 1.38 for 10 minutes. Then tin metal
layers were taken-off of the samples by means of anodic disso-
lution at high current intensity, and the isotope quantity
dissolved was measured by radiometry. Upon treatment with
CdSO4 solution isotope exchange with dissolved ions occurred
on the surface only. No considerable change of the radioacti-
vity of lower layers could be obser%red. The corrosion was
carried out by means of 0.1 normal sulfuric acid. Pigures 1
and 2 show the results of the radiometric investigation of
Card 2/3 alloy I and alloy 2 before arid after corrosion. Before corrosion

Investigation of the Corrosion Resistance of Solid SOV/76-33-5-7/33
Solutions of Metals by the ".1lethod of Radioactive Isotopes. II. The System
Mg-Cd
the cadmium is equally distributed in the crystal lattice
of the alloy; increased Cd content is present to 1N depth
onlylit is probably adsorbed on the surface of the micropores.
After corrosion, the surface composition of the two alloys
has changed. The first sector (depth: about 1t4, ) consists
of Cd atoms which remained on the surface, or' of Cd which
was partially displaced from the solution by Mg ions. At,a
depth of from 3 - 10~ the Cd content is incroased, probably
because of diffusion from the surface; the lower layers are
unchanged. The unstable alloy 2 has a looser surface; the
looseness increases in the course of corrosion leaving eithir
a loose crystal skeleton or causing the atoms to lose the
connection and dissolve. There are 2 figures and 13 refer-
ences, 11 of which are Soviet.
ASSOCIATION: Institut obshchey i neorganicheskoy khimii Kiyev (Institute
of General and Inorganic Chemistry Kiyov)
SUBMITTED: August 26, 1957
Card 3/3

5 (4)

AUTHORS: 3 3 / A A
Gratsianskiy, N. N., ~yabov, A. K.

TITLE: Surface Phenomena in the Corrosion of Solid Metal Solutions
(Poverkhnostnyye yavleniya pri korrozii tverdykh rastvorov
metallov). The System In - Pb (Sistema In - Pb)
PERIODICAL: Zhurnal fizicheskoy khimii, 1959, Vol 33, Nr 6,
pp 1253-1255 (USSR)
ABSTRACT: In continuation of a previous paper (Ref 1) wherein the
surface tension 6 of the system Cd - Ug was determined, the
present paper reports on the measurement of the value cr of
the solid solution In - Pb as depending on the composition of
the alloy. It further deals with the problem, which of the two
components is the surface active factor at the boundary with
a corrosion medium, and what kind of influence it exerts on
the corrosion resistance of the alloy surface layer.
Measurements of a were made in a vaeuum apparatus at temperatuxes
30-500 over the melting point of the alloy and of the specific
weight r in a special vessel (Ref 1). The values for c and
with different alloy compositions are given in a table. The
value :-for pure In at 18ro C amounts to 592 erg/cm 2 and for
Card 1/2

Surface Phenomena in the Corrosion of Solid Metal ISOV/716-33-6-13/44
Solutions. The System In Pb
2
Pb at 3620 455 erg/om . It was observed that crin the case 2
of a content of 40-100 at~t Pb changes but little ' 164-475 mdom
a marked change is observed with 30 atl,,f, Pb, tht, transition
point of the p,.- to the j~~phaee in the phase transformation
diagram. From a content below 5 at-16' Pb d-rises up to the
value for pure In. In the surface layer of the system in - Pb,
at the boundary with a corrosion modium (ottric acid), In is
the surface-inaotive componen'.. The diffusion of the surface-
active Pb to the boundary allay - corrosion madium effects
the formation of an anticorrosive lead layer or -f the
In-Pb alloy. There are I figure, 1 table, and 4 Soviet
refarences.
ASSOCIATION: Akademiya nauk USSRInstitut obshchey i neorganicheskoy
khimii Kiyev (Academy of Sciences of the UkrSSR, Institute
of General and Inorganic Chemistryg Kiyev)
SUBMITTED: October 26, 1957
Card 2/2

8751o
15,S2 S/073/60/026/001/008/021
.>09> B004/BO54
AUTHORS: j;_;g~tsians ~i ~11..,and Kalyuzhnaya, P. F.
TITLE: Study of Corrosion Resistance of Sol:*,d Metal Solutions of
the System Fe - Cr
PERIODICAL: Ukrainskiy khimicheskiy zhurnal, 960, Vol. 26, No. 1,
pp. 53-57
TEXT- The authors attempted to find the cause of the format-Jon of
corrosion-resisting regions in 30lid alloys of the components Fe and
Cr, both of which are subject to corrosion. They investigated the follow
ing components: No. 1, Armoo iron; No,2, chromium with Fe traces;
No-3, 47-34 atom% Fe, 52-52 at% Cr; No-4, 79-71 at% Fe, 20.1 at% Cr; and
No.5, 86.1 at% Fe, 13.60 at% Cr. Corrosion was conducted in 5% HC1,
5% H2so 41 5% Na2so4 solutionand 3% NaCl solution at 200C for '180 hours,
and the loss in weight of the specimens due to corrcsion was determined:
Table !, corrosion losses, g/m2,h
Card 1/3

87510
Study of Corrosion Resistance of Solid Metal S/073/60/026/001/008/021
Solutions of the System Fe - Cr B004/BO54
No. of specimen 5% H so 5% HU 5% Na so 3% NaC1
2 4 2 4
3 0.0 127~O 0~0 0.0
4 10.7 8.2 0.008 0105
5 3,74 8.91 0.012 0.05
The stability of sample No. 3 in H2 s04 was confirmed by measuring the
potential. A potential jump occurs at a chromium content of about 50%
(Fig. 1). A 3-4 p thick layer of the corroded specimens was electrolytical-
ly dissolved, analyzed, and Its composition compared with the solution
obtained by corrosion. In 5~ HC1, the components dissolve a" the ratio at
which they are present in the alloy. In 5% H 2s0 4' a corresion-resisting
layer is formed on the surface of the ailoy, which corresponds to the
or phase whose basis is the FeCr compound. The thickness of this layer is
1p . N. N. Kurnakov, N. I. Korenev, 1. 1. Kornilov, and V. S. Mikheyer"
are mentioned.There are 2 figures, 3 tables, and 5 refGrences: 4 Scviet
and 1 German.
Card 2/3

87510
Study of Corrosion Resistance of Solid Metal S/073/60/026/001/008/021
.Solutions of the System Fe - Cr B004/BO54
ASSOCIATION: Institut obshchey i neorg--nicheskoy khi-mii AN USSR (Institute
of General and Inorganic Chemistry AS UkrSSIR)
SUBMITTED: July 31, 1958
Legend to Fig. 1: a) atom%, b) potential, v; 1: in 5% H so 2: in 5% HCl
2 4
0
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S/073/60/026/002/009/015
B023/BO67
AUTHORSt Gratsianskiy, N. N. and Ryabov, A. K.
TITLE: Study of the Corrosion Resistance of Solid Solutions of
Metals of the Nickel -- Chromium Syst4m
PERIODICAL: Ukrainskiy khimicheskiy zhurnal, 1960, Vol, 26, No. 2,
pp. 201-205
TEXTs The authors attempted to determine the limits of corrosion
resistance of metals of the nickel-chromium system in numerous corroding
solutions, arid to explain the reasons of the strong changes in the cor-
rosion resistance of melts in connection with the changes of the com-
position. Corrosion resistance was studied in the following solutionst
5% HC1, H 2s0 40 Na2so 49 Y. NaCl at 200C during 300 h. In H 2s04, Na 2S04;
and NaCl all melts proved to be corrosion resistant with all relation-
ships of the components. In the 5% HC1 solution the corrosion losses are
rapidly changed with a nickel content of about 10%. With a nickel content
exceeding 106 in 5% HC1 solution an approximately 0.2ft thick corrosion
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Study of the Corrosion Resistance of Solid S/073/60/026/002/009/015
Solutions of bletals of the Nickel - B023/BO67
Chromium System
resistant surface layer of pure nickel is formel. On the phase diagram of
the nickel - chromium system the development of of corrosion
resistance in a 5% HC1 solution corresponds to the transition from th-3
ok-phase to the o(+,r.-phase. Fig. 1 shows the dependenco ~f the corrosion
losses in 5PA HC1 solution on the composition of the melt. Table 1 gives
investigation reaults concerning the losses in weight in % HCI. Table 2
shows the results of the analysis of solutions after corrosion in .5~ HCli
Table 2 corrosion of Ni-Cr alloys in 5% HCl
alloy No. 5 6 7 8 9 10
dissolved Ni traces traces traces 2.8 0.1 0.2
at % Cr 99.92 99-94 99-95 97.2 99.9 99.8
alloy 5 23.0 at% Ni,
6 18.1
7 13,8
8 B-95
9 3-97
-10 1-36
There are 2 figures, 2 tables, ~).nd 2 Sov:-"----t, riferen-,ea.
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Study of the Corrosion Resistance of Solid S/073/60/026/002/009/015
Solutions of Metals of the Nickel - B023 B067
Chromium System
ASSOCIATION: Institut obshchey i neorganichoskoy khimii AN USSR
(Institute of General and Inorganic Chemistry of the
Academy of Sciences UkrSSR)
SUBMITTEDs July 31, 1958
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S/073/60/026/003/003/004
B016/BO54
AUTHORS: Gratsianskiy, N. N., and Kalyuzhnaya, P. F.
TITLE: Investigation of the Resistance-to Corrosion-of Solid
Solutions of Metals of the System Fe Ni Cr
PERIODICAL: Ukrainskiy khimicheskiy zhurnal, 1960, Vol. 26, No. 3,
pp. 324 - 326
TEXT: The authors wanted to find the limit of resistance to corrosion
of alloys of the system Fe - Ni - Cr and also to determine the composi-
tion and thickness of the surface layer of the alloys, which forms due
to corrosion of the solid metal solutions. Alloys with varying content
of the individual components and pure nickel were used. They were ground,
and tempered for 6 h in an argon atmosphere at 11500C. The samples 2, 3,
and 4 were subsequently hardened. Corrosion was gravimetrically examined.
The alloys were exposed to 5% solutions of H 2so 42 HC1, and Na2so 49 as
well as to a 3% NaCl solution at 200C for 200 h. In Na 2so4 and NaCl,
the alloys showed only small losses in weight. The limit of resistance
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Investigation of the Resistance to Corrosion S/073/60/026/003/003/004
of Solid Solutions of Metals of the System B016/BO54
Fe - Ni - Cr
to corrosion cannot be established in these salt solutions within 200 h.
Fig. I shows the results obtained in H 2so4 and HC1. The authors found
that in 5% solutions of these acids the lose in weight due to corrosion
is reduced rapidly in alloy 3 (20-43% of Cr, 9-77% of Ni). A limitation
of the resistance to corrosion was observed in the ternary alloys of
the system Fe - Ni - Cr in a range corresponding to the transition from
the a- to the I-phase. The authors measured, at the same time, the po-
tentials of the corrodible alloys. Fig. 2 shows the stabilized poten-
tials as a function of alloy composition. A sudden jump in the direc-
tion of positive potential values, depending on the alloy compositiong
is observed in the range corresponding to the a-I phase transition,
which again confirms the existence of a limit of resistance to corrosion.
The authors dissolved thin layers in 5% H 2s04 at high current densities
for 1-2 see (Table 1) to determine the surface layer (thickness and com-
position) forming due to the action of the solution on the alloy sur-
face. The results show that the surface layer is slightly enriched with
nickel in the little resistant alloys. This layer remains nearly
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Investigation of the Resistance to Corrosion S/073/60/026/003/003/004
of Solid Solutions of Metals of the System B016/BO54
Fe - Nil - Cr
unchanged in resistant alloys. In the latter case, the ratio of components
corresponds to that in the alloy. The authors analyzed the corrosion
solutions to determine the amounts of components which, during corro-
sion, passed over from the alloy surface into the solutions. Table 2
shows that in nonresistant alloys the ratio Fe Sol : N 'isol is higher than
the ratio Fe:Ni in the alloy. From the resistant alloYs 3, the compo-
nents pass over into the solution in such amounts as correspond to their
content in the alloy. Nicrohardness measurements showed that nearly no
loosening of the surface layer takes place in resistant alloys. The au-
thors therefrom conclude that the limit of resistance to corrosion
originates at a Cr content of 18% and a Ni content.of 8%~ and is ex-
plained by the nature of the y-phase. The cause of the origin of this
limit cannot be explained from the standpoint of the Tamman theory
(Ref. 3). There are 2 figures, 2 tables, and 3 references: 2 Soviet and
1 German.
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Investigation of the Resistance to Corrosion S/07 60/026/003/003/004
of Solid Solutions of Metals of the System Bo16yBO54
Fe - Ni - Cr
ASSOCIATION: Inatitut obahchey i neorganicheskoy khimii AN USSR
(Institute of General and Inorganic ChemistrX of the
Ad UkrSSR)
SUBMITTED: July 31, 1958
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241651
S/076/61/035/006/001/013
~S.~00 B127/B203
AUTHORS: Gratsianskiy, N. N. and Vdovenko, I. D.
TITLE: Formation of lead sulfate films on an In-Pb alloy during
corrosion in sulfuric acid solution
PERIODICAL: Zhurnal fizicheskoy khimii, v. 35, no. 6, 1961, 1208 - 1211
TEXT: The authors describe the treatment of an In-Pb alloy with 1~% Sul-
furic acid. The alloy was obtained from chemically pure lead and indium
fused together in vacuum, the mixing ratio was 55 atom% lead : 45 atom%
indium. A resistant layer was found to form on the alloy surface due to the
deposition of poorly soluble corrosion products in the form of lead sulfate.
The object of the present paper was a study of the formation process of this
layer. The formation of the film was observed with the aid of S35 in sul-
furic acid (H 2S3504). The activity of the film was r,-ieasured with an
rICT-17(MST-17) Geiger counter. It was observed that the layer grew rapidly
at the beginning, but the rate of growth decreased more and more until it
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FUSTOVIT, V.T.; GRATSIANSKIY N.N9.0 kand.tekhn.nauk
Studying the polarization-of electrodes during the electrolytic
forming of Pb.T1 all6ys. Met.i gornorad.prom. no#500-72 SmO
162. (MIRA 26d)
(Lead-thallium alloy"lectrowtaUurgy)
(Polarization (Electricity))

Al, IV
Al
j/185/62/007/010/,011/020
D234/11308
AUTHORS: ,._d-Irat8ians'kyy, H. PI., Vdovenko, 1. D. and Baturynskat
14. L.
TITLE: Formation and structure of corrosion surface layers
in In-Pb and Fe-Ni alloys
PERIODICAL: Ukrayinslkyy fizychnyy zhurnal, v. 7, no. io, 1962,
1118-1123
TEXT: The layers were studied by the x ray method, using charac-
toristic Pe wavelengths 1.9321 Kx and 1.7514 Kx, on both rotating
and fixed samples. Corrosion unstable in In-Pb has a layer of, -
2bSO4 on the surface, a thin layer of.nearly pure Pb below it and
finally a solid, Pb-enriched In-Pb solution. Up to the depth of 2
microns two cubic lattices are observed. Corrosion-stable In-Pb
.possesses similar surface layers. In Fe-Ni alloys lattice parame-
ters do not change and ne% -v lines do not appear.* ;jtable alloys ex-
hibit the Ni lattice and unstable alloys the Pe laitice. Thickness
-and composition of thu lityars were studied in previous dapers by

3/185/62/007/010/011/020-
Formation and structure ... a)234/D-508
the first of the au-uhors et al. There are 2 fi,-,ures and 2 tables.
ASSOCUTION: lnstytut qahalnoyi ta neorhanichnoyi k1himiyi I'LN URSR,
Kyyiv (Ins-'u'itute of General and Inorganic Chemistry
AS Uk-rSSR, 'Kiev)
SUBY11YTED: Diarch 31, 1962
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8/073/62/028/006/002/002
A057/A126
AUTHORS: Vdavenko, 1. D., Gratsianskiy, N. N.
TITLE: The effect of surface-active substances upon the corrosion of indiur4
tin, and 1ndium-tin alloys
PERIODICAL: Ukrainskiy khimicheskiy zhurnal, v. 28, no. 8, 1962, 991.- 995
TEKT: The effect of adding small quantities (0.094 resp. 0.265 g/1) of
mixtures of heptyl and octyl amine, of decyl and dodecyl amine, and of octyl
amine on the corrosion of Indium, tin, and their alloys (50% In, or 20% In) was
investigated In 60% sulfuric acid solutions by the method of cathodic and anodic
polarization curves. These admixtures caused a shift of the cathodic polariza-
tion curves towards negative potentials. The-shift of potentials is explained
by a decrease in the rate of the cathodic reaction, i.e. an increase of thi over-
voltage of the hydrogen ion discharge. This is due to the formation of dense
.adsorbed layers of the surface-active organic compounds on the surface of the
electrode. Corrosion inhibitors with a specific adsorption on the metal surface
show the greatest effect when the potential of the electrochemical reaction is
Card 1P

VDOVENKOI I.D.; GRATSIANSKIYj N.N.
Corrosion resistance of indium, tin,, and indium-tin alloys
in the presence of surface-active agents. Ukr.khim.zhur.
28 no.9:1069-1(Y72 162. (MIRA 15:12)
1. Inatitut obshchey i noorganicheskoy khimii AN UkrSSR.
(Indium-tin alloys-Corrosion)
(Surface-active agents)