SCIENTIFIC ABSTRACT GOLUBTSOVA, R.B. - GOLUBYATNIKOV, G.A.

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• Collection: Scientific Abstracts
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• Sequence Number: 12
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

5(2)
AUTHOR: SOV/2o-124-1-25/69
TITLE: Inventi&ation of the Conditions for the Separation of Cementite
From Iron-Carbon Alloys (Icaledovaniye usloviy izolirovaniya
tsementita iz splavov zhelezo-uglerod)
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 124, lir 1,
PP 91 - 93 (USSR)
ABSTRACT: Institut geokhimii i analiticheskoy khimii AN SSSR (Institute
of Geochemistry and Analytical Chemistry of the AS USSR)
needed pure cementite for analytical purposes. The author
presents the publications on iron carbides (Refs 1,3) and
electrolytes which are used for the precipitation of cementite
(Refs 4-7). She determined the potentials of a cementite-
containing alloy as related to a calomel electrode (Refs 8-1o)
and found that the electrolyte Nr 1, consisting of 5 ml
HCL (1.19) and 5 g citric acid as well as of 1000 ml water
is the most suitable for the said precipitation. The increase
in the amount of citric acid does not influence the yield of
the anode powder nor its chemical composition. It can be seen
Card 1/3 from table 1 that a current density of 0-03 - 0-05 A/cm2

Investigation of the Conditions for the Separation of SOV/2o-124-1-25/69
Cementite From Iron-Carbon Alloys
is most suitable and exerts no effect on the chemical
composi tion of the phase Fe C. Experiments have proved that
the ratio between iron and Krbon in the phase correspond
to the stoichiometric composition of the cementite. At an
increase of the current density up to 0.07 A/CM2 the carbide
phase seems to be partly oxidized. At 0.1 A/am the cerientito
precipitate is decomposed. To detort.,tino the optimitin conditiona
for the separation of Fe,C the reproducibility Of thie"Teaults
under various durations df the experimcnt in the same electro-
lyte was checked (Table 2). Within 1.5 hours the carbide
phase was not decomposed, since in all cases stoichiometric
Fe 3C was separated from the alloys investigated (C 5,
Fe 95;C 2, Fe 98 per cent by weight, produced by P. T. Kolo-
MytzeV). The cementite separation can proceed satisfactorily
without cooling as viell. Finally the details of the procedure
are described. X-ray structure analysis carried out in the
Institute of Gdodhddistry and Analytical Chemihtry, AS USSR confirmed
the existence of a pure cementite (Fig 2, Table at page 78).
There are I figure, 2 tables, and 11 ref-crences, 9 of which
Card 2/3 are Soviet.

Investigation of the Conditions for the Separation of SOV12o-124-1-25169
Cementite From Iron-Carbon Alloys
ASSOCIATION: Institut metaMrgii im. A. A. Baykova Akademii nauk SSSR
(Institute of Metallurgy imeni A. A. Baykov of the Academy
of Sciences I USSR)
PRESENTED; August 8, 1958, by I. P. Bardin, Academician
SUBMITTED: July 29P 1958
Card 3/3

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5/075/60/015/004/021/030/X.X
B02O/BO64
AUTHOR: Golubtsova, R. B
TITLEs Determination of Gamma Quantities of Bor n in Complex Alloys
PERIODICALi Zhurnal analiticheskoy khimiij 1960, Vol. 15, No. 4.
PP. 481 - 486
TEXT: The aim of the present paper was to develop a simple, quick, and
accurate method of determining some of boron in complex alloys on the
basis of Ni, Fe, Co, and Ti, containing also W, Nb, Mo, Cr, Si, and other
elements, from weighed portions of 0.01 - 0-05 9. Alizarin, quinalizarin,
and carminic acid are most frequently used to determine boron photo-
metrically. When comparing reagents such as curcumin, quinalizarin,
chromotrope-2B, carminic acid and arsenazo-2, the two last-mentioned sub-
stances were found to yield the beat results in determining a-quantities
of boron. F. P. Zorkin (Ref. 1) was the first to suggest carminic acid for
the determination of boron. V. A. Kazarinova-Oknina (Ref. 2) used carminic
acid for the quantitative determination of boron in borate ores; in this
connection it is recommended to use a 0-005% carminic acid solution in
Card 1/4

Determination of Gamma Quantities of Boron in S/075/60/015/004/021/030/XX
Complex Alloys B020/BO64
concentrated sulfuric acid (Ref. 3). To clarify the role played by time
in the development of the maximum color intensity of the boron - carminic
acid complex, a spectrophotometric determination of boron was attempted by
measuring the optical density in intervals of 15 minutes. The results con-
firm that Ir of boron can be quantitatively determined with carminic acid
IV VI III
in the presence of not more than 10rof Ti , 5or of mo , 50r of Fe
VI II
75r of T , or 200aof Ni . An attempt was made toward a spectrophoto-
me ric determination of gamma quantities of boron with chromotrope-2B, as
suggested by A. S. Komarovskiy and N. S. Poluektov (Refs. 4-5), and with
the reagent arsenazo-2 synthesized by V. I. Kuznetsov for color tests for
uranium and thorium (Ref. 6). Boron attains its full color intensity with
a 0.01% chromotrope-2B solution in concentrated H 2so4 after 45 minutes,
and remains stable for 24 hours. A color change from violet to light blue
takes place in the presence of boron. 0 07 of B/ml was determined to be
the minimum of boron with chromotrope _2~; The minimum dilution is
1:20,000,000. 1r of B can be determined with a 0 01% chromotrope-2B
IV VI VI
,solution in the presence of a maximum of 5r of Ti , 5r of w .' 553- of MO
Card 2/4

Determination of Gamma quantities of Boron S/075/60/015/004//021/030/;(X
in Complex Alloys B020/BO64
75r1of Ni II , and 100r of Pe The full color intensity of the boron
complex with a 0-005~6 arsenazo-2 solution is attained after 35 minutes; the
color changes from violet to dark blue, and remains stable for 24 hours.
In this case the minimum is O.lavB/ml, and the minimum dilution is IV
1110,000,000. 1 r of B can be determined in the presence of 75r of Ti
VI VI II III
loorof W , loot of'Mb I 125r of Ni , and 125r of Fe " The solutions
of these boron complexes with chromotrope-2B and arsenazo-2 obey the Beer
law. The time of analysis.is approximately 15 minutes. No large amounts of
oxidizing agents are necessary for oxidation. Ammonium persulfate is the
most effective oxidizing agent in determining boron in titanium containing
alloys. After the dissolution of the weighed portion of alloy, the
accompanying elements are separated by N. Chizhevskiyls mercury cathode
method (Ref. 7). For this purpose, the author- suggests a funnel
electrolyzer of glass (Fig. 1) with double walls for water circulation.
Then, boron is separated from Ti and Zr with a lye. The results obtained
confirm the accuracy and reproducibility of the method suggested (Table 1).
Table 2 shows the results for B in Ni, Co, and Fe alloys. After the
separation of titanium with lye and evaporating with H 2SOV B can be
Card 3/4

Determination of Gamma Quantities of Boron S/075/60/015/004/021/030/XX
in Complex Alloys B020/BO64
determined with carminic acid, ohromotrope-2B, or arsenazo-2. At a low
boron content, it is also possible to determine boron by the addition
method (Table 3). The calibration curve for boron determination in
titanium alloys is given in Fig. 2. The cqurse of analysis is described L/
for the determination of boron inqhromeyLckel, c~ail,ljiron and
-VAtitanium alloys. There are 2 figuri's-,3 ti~b-les, and 23 referencest
8 Soviet, 13 US, 1 British, and 1 Austrian.
ASSOCIATION: Institut metallurgii im. A, A~ Baykova AN SSSR; Moskva
(Institute of Metallurgy imeni A. A. Baykov of the AS USSR,
Moscow)
SUBMITTED: May 28, 1959
Card 4/4

GOLUBTSOVA, R.B.
.v-_O_MMMM=wwwwAw
Determination of gamm quantities of boron in complex alloys.
Zhur.anal.khim. 15 no.4:481-486 Jl-Ag 060. (MM, 13:9)
1. A.A.Baikov Institute of Ketallurgy, Academy of Sciences,
U.S.S.R., Moscow.
(Boron--Analysis)

/A 9zoo
*R+W_0 67948
AUTHORSt Golubtsovaj_UL,_Mshkoviob# L, SOY/20-130-1-21/69
TITLEt Investigation of Metallic Compounds FoNmed in the Interaction o:!
a Five-component Solid Nickel Solution .ith Titanium Carbide
PERIODICALt Doklady Akademii nauk SSSR, 19609 Vol 130, Nr 1p pp 79-81 (USSR)
ABSTRACTt In the system mentioned in the titlej the formation of titanium
carbide or a phase on the basis of this carbide is most probablos

ybides may form part of the solid solutions of
Other metallic ca
titanium carbide! If the difference in the lattice 1)eriods is not
1
very greatq the carbides with equal (isoForphic) crystal structim-
always form an uninterrupted series of solid solutions, Carbidea
of the metals of groups IV and V may be soluble with the metall:~c
carbides of group VI to a limited extent only. The authors dis-
solved samples of alloys (melted by LoI. Pryakhina and O*V.
Ozhimkova), after thermal treatment# electrochemically in an
e1qctrolyte (motbod.described in Ref 7).~The experiments showed
that none of tho alloys contained an intermetallic phase. The
carbide phase was isolated in another elbetrolytot 100 al of HC3
(1*19)9 100 g of citric acid, 5 g of suabinic dcidp 1000 ml of
water, current density 0.5 a/om29 cooling with-ir-e (Ref 7). In an
Card 1/3 alloy with 0.1% of TiC9 no separation of excess phases oocurredq,--'

67948
Investigation-of Metallic Compounds Formed in the Sov/~Q-130-1_21/69
Interaction of a Five-component Solid Nickel Solution With Titanium Carbide
Card 2/3
since the composition of this alloy corresponds to a homogeneous
solid solution on nickel basis* The phase analysis of the alloys
with a TiC content of 1-00; 4,00; 8-00% 'showed the presence of
a carbide phase of complex composition iii the alXoys. Table 1
shows the chemical analysis of the carbide powders isolated.
Only traces of nickelg and small quantities of alumint- were
found, This proves that Ni and Al form lies st4~'le carbides than
Tit W and other metals, and are not part'of the titanium-oarbide
hase. Table I shows that titanium prevails in the carbide phase
39- 40%). consequently, the titanium ca:~bide is'the basis of tho
f
carbide phase. The total content of the.parbide-,forming elements
Tit W, No and Or is 52 - 54% expressed in gram,-~atomic percentago,
the content of C being 44 - 46%* Thusp t~e ratio'between the sum
of carbide-forming elements and carbon i~ very ~loae to 1s 1.
The authors assert that a formula of the'carbide'NoO may be
assigned to the carbide precipitateg and this formula may be
expressed as Ti(WvMo,Cr)C. On the basis of the X-ray structural
analysis (made by A.Ya. Snetkov), the carbide phase has a oubica:.,
face-centered lattice of the TiC type. Parameter a - 4.30- 4.32kX.
If the formula of the complex carbide is interpreted to denote

67948
Investigation of Metallic Compounds Formed in the BOY/20-130-1-21/69
Interaction of a Five-oomponent Solid Wickel'Solution With Titanium Carbide
the individual carbides TiC, WC, MoC and Cr 4C forming solid
solutions with each other, the (theoretically) required carbon
amount (Table 2). as well as the content of single carbides in.
the anodip, powdurs, can be computed. Thl~s~ the authors proved tha't
only 2 phases participate in the eqlailibrii= of the multiple-
component system of the alloys investigated: the-solid 5-comPoneal
nickel soluti~.nv and the solid solution.of titanium carbide.
The name of I.I. Kornilov was mentioned in the text. There are
3 tables and 7 Soviet references.
ASSOCIATIONs Inatitut metallurgii im. A.A. Baykova Akademii nauk SSSR (Institu-I
of Metallurgy imeni A.A. BMkov of the Academy of Sciences, USSR
PRESENTED& Augast 14, 19599 by I. Po Bardin,) Academician
SUBMITTED: July 209 1959
Card 3/3

544) :30V120 -.1 1;10 - 2 .2o/69
AUTHORS i Gulubti3ova, R. B Nude., L A,
TITLE: Investigation of 14etallir- Compounds iz; 1,11-1ticomponent
Nickel Alloya Contairli.-.k' Niobiu~l
PERIODICALt Doklady Akademii nauk, S=t, 1)6e-, Vol 1 ~50, Nr 2,
PP 318 - 321 (USSR)
ABSTRAM In the present paper, the nio'blum-containing excess phases
in the system r4i-Cr--W-,Mo-Nb-Ti,-Al are investigated with
respect to their composition and structure with different
Ni-amounts in the alloys., The authors' investigEAions showed
that solid solutions were formed on the basis of the com-
pound Ni 17hCast alloys (prepared by L I,, Pryakhina) were
Y 0
investigated after heating them up to '1200 1 keeping them
at this temperature for 200 h. and cooling them in air.
Figure I shows the microstructure of these alloys, Consiler-
Ing the high oxidizability of the anodic precipitate. elec-
trude potentials of NJ.311b and the aolid .1'-solution were
measured in various electrolytes (Fig 2 and the optimum
electrolyte was chosen in this way Table 1 sh,~ws the iso--
Card 113 lation of the Pi 3Nb-phase in various electrolytes at room

lnvsoti~,,ation of Metallic ColapoUrlds it, ',.Ul.'i-,!0MP')IIent I-MV120-150-2-20169
Nickel Alloys Containing Niobium
temperature. By microchemical aaialysis of th-:~ anodic pre-
cipitate from differant electrolytes the 6ame composition
of Ni3Nb near !hn stoichiometric one wa3 F~royed in all
cases. Table .4 presents the reoulto of tl~e influerce of
current density on yield and composition of the 113. 3N-b-phase
The authors assume that the yield of the phase is reduced at
a higher current denuity due to the heating of the eLoctro-
lyte. Oxidative reactionn cau:3ed by -the anion discharge did
nL.t take placeThe shape of the polarization curve (Fig 3)
proves that this prooess cccurs without a drop in the
potential value3l Table 5 shows that at -180 and 00 a me-
tallic phase on Ni3Nb-basis is separated (yield of the phase
16~30%,'Y, On cooling to -6'~ both the Ni3Nb-phaoe and the
solid solution are passivated, This increases the yield of
the phase. The said passivation is evidently due to the
reduced activating effect of the Cl-ions on intense cooling,
On the basis of the above results, tha authors determined the
optimum isolating process for the N '3 Nb-phase, Table 2 and
figure 4 show the results of the intermetallide and the
Card 2/3 X-ray structural analysis by means of the X-ray camera of

t 7 oi; 5
Investigation of Metallic Compounds in Multicoraponent BOV120-130-2-2ol6g
Nickel Alloys Containing Niobiwl
type GFTI-1~ The phase separating from all alloys forms
a solid solution on the basis of the metallic compound Ni3Nb
which has a rhombic crystal lattice. Considering the near
values of atomic radii, it can be assumed that the Ni-atoms
:(1,24 2) can be substituted by Cr-atoms (1.28 R), and the
Nb-atoms (1,47 R) by W-atoms (1,41 R) and Mo-atoms (1-40
Therefore, the authors write down the formula for the com-
pound developing in the alloy as folluwss(Ni 'Cr) (- Nb,W,Mo).
Table 5 shows the distribution of the alloying e~ementB between
the solid ~111 solution and the Ni3Nb-phase on account of the
analysis 4-the anodic precipitate and the electrolyte. The
name of I. I, Korniloy is mentioned in the paper, There are
4 figures, 5 tableii-,and 2 Soviet references,
ASSOCIATION: Institut metallurgii im, A. A, Baykova Akademii nauk SSSR
(institute of Metallurgy imani A, A,, Baykov of the Acad~Ty of
PRESENTEDt
August 14, 1959, by 1. P,, Bardin, Academician
SUBMITTEDi July 20, 1959
Card 3/3

0
S/020/60/134/006/016/031
B016/B067
AUTHORSs Golubtsova, R. B. and Mashkovich, L. A.
- MNAW~
TITLEj Study of the Influence Exerted by the Aging Time on the
Formation and the Composition of the rl-Phass in Alloys
of the System Ki-Cr-W-Al-Ti A
A
PERIODICALt Doklady Akademii nauk SSSR9 1960, Vola 134, No. 6,
pp. 1353-1355
TEXTs According to microstructural analysis (L. I. Pryakhina and
0. V. Ozhimkova, Ref. 1) it was found that the Ni-Cr-W-Al-Ti alloys
consist of two phasesp ioeo, of a T-solid solution and the r'-phase. To
study the composition ard the structure of the phases the authors carried
out a special investigation which was based on an electrolytical
isolation of the excess phases. To isolate the rl.-phase from the alloys,
the authors used an electrolyte consisting of 50 ml HNO 3, 20 ml RCIO4
per 1000 ml vater (Ref. 4). The anodic powders separated were dissolved
in aqua regia with subsequent hydrolytic isolation of tungsten.. Ali Ni,
Card 1/4

Study of the Influence Exerted by the Aging S/02o/60/134/006/016/031
Time on the Pormation and the Composition 13016/BO67
of the tl-Phase in Alloys of the System Ni-Cr-W--Al-,Ti
and Cr were determined In the filtrate. It was found necessary to prove
the possibility of chemically determining gamma amounts of chromium with
diphenyl. carbazide on the background of obviously predominating elements.
On the basiB of the investigations rational -conditions of determining
chromium were developed. Since the high amount of tungsten which is con-
tained in the anodic powders (-,20%) partly carries along titanium in
the precipitation, titanium was determired in a special weighed-in
portion (0.01 g). To fix tungsten 1.70 H 3PO4 were added to the solution.
The results of the chemical analysis are shown in Table 1 . To study the
electrochemical dissolution of the alloys the authors isolated the excess
phass in the electrolyte which they had proposed ear.3111er, (Refs. 5,6)3
35 g citric acid, 5 g (NH 4)2SO49 15 ml HNO 3 per 1000 ml water. Table I
shows the chemioal composition of the phase isolated in. this 4onnection.
As may be seen therefr,,)m the composition of the ;r'-phase remains 'On-
changed if the aging duration is extended f7-im 0 4;~ 109000 h. The ratio
of N1 ic ZAI, Ti. Cr, expressed In atov%, amounts t_- approw-Imat-,,ly
Card 2/4

Study of the Influence Exerted by the Aging .9/020/60/134/006/016/031
Time on the Formation and the Composition B016/B067
of the rl-Phase in Alloys of the System Ni-Cr-W-Al-Tl
This ratio for the phase which was separated in the electrolytet
50 ml ENO3, 20 ml HC 104 per 1000 ml water was closer to 3 than that of
the hase which was separated from the elect~kolYtel 35 g citric acid,
5 g ~NH 4)2S049 15 ml HNO3per 1000 ml water. This shows that the former
electrolyte is better su~.ted for separating the ~'-phase. On the basis of
an X-ray structural analysis (by A. Ya. Snetkov) the TI-phase was ob-
served in all anodio powders with a lattice parameter a - 3-573 U which
forms a solid solution on the basis of Ni3Al. However, no superstructural
lines which are characteristic of pure Ni3AI, were observed. in all
powders obtained from hardened alloys as well as from the 10,000 h old
alloys, weak lines of a phase were proven, whose nature has not yet been
explained. For the purpose of determining the distribution of the elements
over the phases, the authors set %ip a balance of electrolysis products
for a 1000 h old alloy. Furthermore, they calculated the content of
elements in wt% in the solid g-nickel solution in the V-phase. The method
used here made it possible to determine the metalloidli-phase in the
Card 3/4

Study of the Influence Exerted by the Aging B/020/60/134/006/016/03i
Time on the Formation and the Composition B016/bO67
of the e -Phase in Alloys of the System Ni-Cr-W-Al-Ti
5-component Ni alloys investigated. Also the influence exercised by a
long aging time on the composition and the structure of this phase could
be studied. The authors mention a paper by 1. 1. Blok et al (Ref. 3)-
There are 1 table and 6 Soviet references.
ASSOCIATIONs Institut metallurgii im. A. A. 3aykova Akademii nauk SSSR
(Institute of Metallurgy imeni A. A. Bayka-ir of the Academy
of ScienceTq- U5511)
PRESENTEN May 30, 1960, by 1. 1. Chernyayev, Academician
SUBMITTEDt May 17, 1960
Card 4/4

PHASE I BOOK EXPLOITATION M11/5994
Akademlyn nauk Ukratnakoy 03". Institut matallokernmIki I
spatalalInykh splavov. Seninar po zharootoykim miferIalam.
KiycLv, 1960.
Trudy Seminars. po zharontoykim ic)-21 apriNlyn l9bo g.
Byulleten' no. 6s Minichenkiye svoyatva t motody analiza tug-
oplavkUdi'soyadlnonly (Trannacttc~in of the Seminar on Ilent-
Resistant 11aterialri or th,3 Inaitul,j or rcwder flotallurpr~v and
3peclal Alloys or the Acnd'~My or ;;~'Icnaes of the U!wainlan
SSR. Held 19-21 April, 1550. Villetin no. 6: Chenical Pro-
perties and Methods or Refrnctory Compound tnalysts). Kiyev,
Izd-vo AN UkrSSR, 1961. 124 p. 1500 copies printed.
Sponsoring Agency: Akademlya nauk Ulcrainakoy SSR. Inatitut
metallokeramiki I apetsialInykh aplavov.
Editorial Boards 1. N. Frantsevichl G. V. Samoonov, Resp. Ed.;
I. M. Fedorchenkop V. N. Yeremenko, V. V. Grigorlyeva, and
T. N. Nazarchukj Tech. Ed.t A. A. Matveychuk.
Card 1/5

T~ansactions of, thm Semirinr (Gont~)
SO-1/5994
PURPOSE: Thin collection:of art1clc:a Is lintcndod for chcmin.'s,
engineers, workera at scientific research Institutes and plant
laboratories, senior attident3. and anpiranto at chv~nlcal and
metallurgical achooln of h1fhor ksd%teatlon.
COVERAGE: Articles of the collection present the renultv of
studies of the chemical properties of refractory compoinds
(carbides, boridee, nitrides, pho,3phorldes, 3111cIdes), re-.
fraotory and rare metals, and th~,Ir alloyn, and Bome original
methods of analyzing theno materials, Witeh are now b,~ing
utilized In the new fields of enginee ring. No peraonalities
are mentioned. Each article is accompanied by references,
mostly Sovie".
TABLE OF COUTENTSt
Foreword 3
Sameonov, 0. V. Refractory Compounds, Their Properties, Pro-
Card 2/15

Transactions of toe Seminar (Cont.) SOV/5994
o bts6val-R- B-,~ and'.L.'.A. Mashkovich. Study of Metallic
compoun 0 #o4-m:4 th'
a Interaction of a Multicomponent Nickel-
Base Solid Solution With Titanium Carbidd l('9
Shcherbakov, V. G., and N. P. Anikeyeva. Spectral Analysis of
High-Purity Tungsten and Molybdenum 134
Kotlyar, Ye. Ye., and T. N. Nazarchuk. Analysis of High-Tin
Titantum-Tin Alloys 111.11
Modylevskaya, K. D. Simple Method of Analyzing Titanium-Tin
Alloys 1,9!4
Recommendations of the Seminar 1"!6
AVAILABLE.- Library of Congress
SUBJECT: Metals and Metallurgy
Card 5/5 DV/ - /I t
wrc~
-
(/2 12
OX

35055
3/700/61/000/006/014/018
D267/D304
AUTHORS: Golubtsova, R. B. and Mashkovich, L. A~
--azMaN~
TITLE: Investigating metallic compounds forming as a result of
reactions between multi-component nickel (solid) solu-
tions with titanium carbide
SOURCE: Akademiya nauk Ukrainskoy SSR. Inutitut metallokeyamiki
i spetsiallnykh splavov. Seminar po zharoEtoykim materi-
alam. Kiyev, 1960. Trudy no. 6: Khmicheskiye svoyclt-va
J_ metody analiza tugoplavkikh soyedineniy. Kiyev, Izd-
vo AN UkrSSR, 1961, 109-113
TEXT: The authors investigated the excess phases formed in t3ye.,
tems where 5--component and a-component solid solutions of nit:kel
reacted with TiC. The most probable in such a system is the for-
mation of TiC or a phase bauec. on TiC, whereas other carbide3 of
metals can enter into solid solutions of TiC. The alloy specLmens
were hardened at 12000C for 115 hours and cooled in uuter. Be-
sides Ni.. the alloys contained Ti, C, W. Mo, Or, Al (scme also Nb),
Card 11/3

3/70 61/000/006/01,1,/018
Investigating metallic compounds ... 1)267%3~4
but -no intermetallic phases. The carbide phase was se arated in
an electrolyte consiet.ing of 100 ml H01 (sp. gr. 1.M, 100 1a ci-
tric acid, 5 g succinic acid and 1000 ml water; the electrolyte
was r;ooled with ice and the current density was 0.1 A/cM2. No ex-
cess phases could be separated from alloys containing 0.1% Tic,
whereas a carbide phase of complex composition was present in al-
loye containing 1.0, 4.0 and 8.V,. TiC. The anodic residues ob-
,ained were washed, dried and subjected to chemical. and X-ray ana-
IyFiT. It was found that the carbide powders contained almost no
N! whereas the Ti content was 39 -- 40~, that of Ti., 'J., Mo and
Cr 52 ~x, 54%, and the C content .-- 44 - 461p~'. Thus, the carbide re-
o7-due seems to have the composition MeC. The carbide phase has a
-ubic fa,.e-centered lattice of the TiC type (a = 4.30 - 4,3e kX"".
The resizIlts of chemical analysis of carbide powders separat(,d from
the alloys of the system Ni - TiC show that the increase of the
proportion of TiC in original alloys (while the Nb content reraninz
--onstant) ia associated with that of Ti content in carbide 1)c-,.,vder-S
~~nd th ~3 de.--rease of Nb content. The amounts of other compcnentq.
r

S/700/61/000/006/014/018
Investigating metallic compounds ... D267/D304
U
including C, vary very lit1le, the total metal/carbon ratio boing
cloee to 1:1. It may be, therefore, assumed that the separate(I T-_C
,.s substantially a solid solution of the carbidea of Nb, Mo. Al and
Cr in TiC. The carbide residue can be envisaged as con3isting of
TiC, NbC, VIC, Mo2C and Cr 23 C69 which form mutual solid solutione.
There are 7 tables and 11 references: 10 Soviet-bloc and 1 non-so-
viet-bloc.
ASSOCIATION: Institut metallurgii AN SSSR im. A. A. Baykova (in-
stitute of Metallurgy im. A, A. Baykov, AS USSR'
Card 3/3

ODLUBTSOVAI R.B.1 MASMVICH..'L.A.
Study of the metallic compounds formed during the interaction
of multicomponent nickel solutions with titanium carbide. Biul.
Inst. metaloker. i spets. splav. AN URSR no.6:109-2.13 161.
(MMA 15:;!)
1, Institut metallurgii AN SSSR imeni A.A.Daykova.
(Titanium carbide)(Nickel alloys)

AUTHORt Golubteova, R.B.
21496 S/020/61/137/004/020/031
B103/B208
TITLEs Study of the nature of a chemical compouzd in the systom
Ti - Si
PERIODICALs Doklady Akademii nauk SSSRp v. 137, no- 4, 1961, 859 - 861
TEXTs The author studied the metallic compound in titanium alloys with a
s4mall (0.25 - 7-5 wI.% Si) silicon content (pregared and supplied by Te.
No Pylayeva)o The alloys were annealed at 1000 G for 24 hrp and at 5000C
for 500 hrt and then quenched in water. The compound studied was electro-
lytically deposited in insoluble state on the anode. Since the interme-
tallic phase Ti Si 3 at a Si content of 0o25 - 2.0% could not be deposited
in any electrolyte known so farg the author developed a new electrol:rtet
15 ml H2SO4 (1984)p 3 g ascorbic acid (or salicylic acid)p and 1000 :n1
methanol (Refe 59 author's certificate no, 133237P 1960). The phase
Ti5Si3 is a titanium silioide of exactly stoichiometric composition
Card 1/2

Study of the nature of ...
S/02 61/137/004/020/031
B103YB208
Ti a Si - 2-85% or 1o68 atom%. This was confirmed by microchemical and
X-ray analyses (the latter was performed by M.A. Volkova). The substance
deposited on the anode was scraped off, rinsed with water during centri-
fuging, and then with alcohol; finally, it was dried in the hydrogea
stream on the oil bath. The optimum current density for composition and
yield of Ti5Si 3was between 0.03 and 0.05 a/cM2. The sample is conside-
2
rably heated at 0.1 a/cm , There are I figure, 3 tables and 5 references&
3 Soviet-bloc and 2 non-Soviet-bloc. The reference to the English language
publication reads as follows& M. Hanson, H.D. Kessler, D.J. McPhersoa,
Trans. Ame Soc. Metalop AAt 518 (1952).
ASSOCIATIONt Institut metallurgii im. A.A. Baykova Akademii nauk SSSR
(Institute of Metallurgy imeni A.A. Baykov of the Academy
of Sciences USSR)
PRESENTED& October 27t 1960 by I.I. Chernyayev, Academician
SUBMITTEDs May 18, 196o
Card 2/2

5/020/61/137/003/017/D30
B103/B208
AUTHOR: Golubtsova, R. B.
TITLE: Composition and structure of the titanium - chromium
compound
PERIODICAL: Doklady Akademii nauk SSSR, v. 137, no. 3, 1961, 593-596
TEXT: Considering the wide application of titanium and its alloys, the
author studied titanium - chromium alloys (from 1.0 to 80 wt~o' Cr) which
contain a chemical compound as one of the phases. The available publica-
tions disagree on whether the formula of this compound corresponds to
TiCr2 or Ti 2Cr 3* In order to solve this problem, the author used her
previous methods of anodic dissolution of alloys, in which the chemical
compound is isolated and studied as an insoluble component (Ref. 11.
R. B. Golubtsova, author's certificate no. 120,925 of April 28, 1959;
Ref. 12; DAN, 106, no. 05j 1011, 1956; Ref. 13: DAN, 111, no. 4, 824,
1956; Ref. 14: DAN, L18, no. 1, 1958; Ref. 15: DAN, 124, no. 1, 1959;
Ref. 16: DAN, 130, no. 2, 318, 1960). The alloys were prepared by
Card 1/4

S/020/61/137/003/017/030
Composition and structure of the B103/B208
T. S. Chernova by fusing the components in the are furnace, annealed at
12oo-6oo0c for 4-600 hr, and dissolved anodically. The author developej
a new electrolyte (A): 5 ml HC1 0.19)", 3 g succinic acid, and
1000 ml methanol, which need not be cooled either before or during
electrolysis. The anode was placed in a bag of tracing cloth. The
composition of electrolyte A was determined by measuring the anodic
potential relative to a saturated calomel electrode with the aid of the
compensation method (Fig. 3). Electrolytes 1-111 (1: 3 ml concentratel
H2so 40 3 g ascorbic acid; II: H 2s04 like 1, 3 g succinic acid;
111: 5 ml HCl (1-19), 3 g salicylic acid, I-III in 1000 ml methanol)
were used as standard solutions. The author concludes from Fig. 3 that
the potential is stabilized at once and remains stable. Electrolyte A
shows a high selectivity, as anodic powder containing pure TiCr 2 (alloy3
with 20% and 65% Cr) was not dissolved in it at 210C, not even after 24 hr.
Experiments in electrolytes I-III gave satisfactory and well reproducib:-e
results. The chromium-to-titanium ratio corresponded in all experiment:3
to the theoretical one in TiCr 2, and was 2.0 (atom-%) or 2.17 (wt%).
Card 2/4

sy'020J61/137/003/i)17/030
composition and atruoture of the B103/B208
2
The author determined 0-03-0.1 a/cm to be the optimum anodic curreit
densityy at which TiCr of stoichiometrio composition is formed as the
2
insoluble component on the anode. Material from the Ti - Cr alloys Was
obtained'from the electrolyte A (1000 ml) by electrolysis for 1-5 hr.
After the end of dissolution, the anodic deposit was scraped off,,washed
three times with distilled water during centrifuging# and two times with
0
alcohol during decantation, then dried in,the oil bath at 160.C in,,Ihe
hydrogen stream. Both microchemical and X-ray analysis confirmed.the
content in the TiCr phasei The latter analysis was performed at ihe
2
TsNIITTifash (Central Scientific Research Institute of Technology and
Machinery). A paper by N. I. Blok is mentioned. There are 4'figures,
3 tables, and 17 references: 12 Soviet-bloc and 5 non-Soviet-bloev
The reference to the English-language publication reads as follows.,'
Ref. 8: C. Cuff et al. J. Metals, 4, 848 (1952).
Card 3/4

U
B)1020/6-1/137/003/)17/030
composition and structure of the ... B103/B208
ASSOCIATION: Institut metallurgii im. A. A. Baykova Akademii nauk SSSR
(Institute of Metallurgy imeni A. A. Baykov of the A,,.adomy
of Sciences USSR)
PRESENTED: October 27, 1960, by I. I. Chernyayev, Academician.
SUBMITTED: September 30p 1960
4-
Legend to Fig~ 3: Values of electrode
potentials of the alloy Ti- Or
(70~ Or) in various electrolytes.
I) in A, 'II) in II, III) in I, IV) in
111. Abscissae: min, ordinates:
emf in gy.
8 AU IN&W
Card-4/4 ......

S/59 62/000/007/014/040
D244%307
AUTHOR:
TITLE: Composition of metallic compounds forming in the alloys
of binary systems titanium-chromium and titanium-silicon
SOURCE: Akademiya nauk SSSR. Institut metallurgii. Titan i-yego
splavy. no. 7, Moscow, 1962. Metallokhimiya i novyye
splavy, 110-113
TEXT: To obtain the composition of compounds forming in the alloys
of Ti-Cr and Ti-Si systems, the method of anodic dissolution of
the alloys was used, the compounds being deposited on the anode.*
The powdery deposits were examined by microchemical and X-ray me-
thods. The electrolyte for the isolation of TiCr wbs composed of
3 g succinic acid, 5 ml 1.19 N HC1 and 1000 ml M~OH. Theanodic
current density admissible for the alloy containing 20% Cr was be-
tween 0.03 - 0.1 A/cm2. To isolate Ti 5Si3 the electrolyte was --om-
-Posed of 10 ml 1.84 NH2SO 4, 3 g ascorbic acid and 1000 ml MeOH. The
CbLrd 1/2

S/59 62/000/007/014/040
Composition of metallic ... D244YD307
electrolysis time was 1.~ hr and the optimum current density be.-
tween 0.03 and 0.05 A/cm4. Exchange of ascorbic acid for sulpho--
salicylic acid permits the quantitative isolation of Ti 5Si 3' The
electrolytes used had the advantage of not having to be cooled I,e-
fore or during the electrolysis. Purther work continues on the iso-
lation of metallic compounds forming in the multicomponent Ti al-
loys. There are 3 tables.
Card 2/2

34476
S/02 621142100410131022
1.2 S-0 Bi 06YB1 10
AUTHORS: A and Nude, L. A.
TITLE: Study of isolation conditions of the metallic compound 11' IJ
forming in multicomponent nickel alloys 3
PERIODICAL: Akademiya. nauk SSSR. Doklady, v. 142, no. 4, 1062,824 - 8;'7
TEXT: Metallic compounds which can be isolated in the electrolytic dis-
solution of alloys of the system Ni-Cr-W-Mo-Al-Nb-Ti were studied. Chemical
composition and conditions of heat-treatment of the alloys studied are given
in Table 1. Five electrolytes used by different authors (Ref. 1: R. B.
Golubtsova, L. A. Mashkovich, DAN, 106, no. 6 (1956); Ref. 2: N. F.
Lashko, A. F. Likina et al., Sborn, tr. Tsentr, nauchno-issl, inst.
tekhnologii i mashinostroyeniya, kn. 59, 1953; Ref. 3: N~ I. Blok, A. I.
Glazova et al., Zav. lab., ~, 901 (1954)) for isolating the 11-phase fron
nickel-base alloys were tested on the alloy no. 1 in order to find con-
ditions for the electrolytic dissolution of these alloys. These electro-
lytes had the -following composition: 1 1 CH 3011, 35 9 citric acid,
Card 116

S/020/62/142/'004/013/022
Study of isolation conditions... Blo6 B110
5 g (NH4)2SO4' 15 M1 HN03 (1.4); 1 1 H20, 35 g citric acid, 5 (TIR 4)2s) 49
15 ml HNO 3 (1-4); 1 1 H20, 10 g ammonium citrate, 100 g CuSO 4 10 ml R.", 04
(1-64); 1 1 H 20, 10 g ammonium citrate, 20 g CuSO V 5 ml H 2 so 4 (1-84);
1 1 H 20, 9 g citric acid, 9 g (NH 4)2 so 4' Chemical and X-ray structural
analysis of the powder that separates anodically in the electrolysis in
these electrolytes showed that it is in all cases a solid solution on -Ch.?
basis of the chemical compound N'3A1 in a quantity of ^.,,l 1 . 5% of the alloy
anodically dissolved. The electrolyte with methanol proved to be the be;3t
one, since no hydrolytic precipitation of niobic and tungstic acid takes place
therein. The anodic dissolution of the alloys studied takes place in ~h:.s
electrolyte at anode potentials of +1.35 to +i.5 v. Under -,hese conditions,
also the phase Ni 3Al is precipitated quantitatively. The sclid solution on
the basis Ni 3Al contains also other dissolved elements, Niobium-contaln:.ng
allcys were anodically dissolved in an electrolyte provided for t-hle isola.
tion of Ni 3Nb in order to find out whether other pha3es (e- g. Ni 3Nb) ar(.
present besides Ni 3Al,. In this case, the alloys di,_-sol,!ed at low anode
Card 2/6

S/020/62/142/004/0-i.3/022
Study of isolation conditions .. B106/B,110
potentials (^.- +0-35 v) and no powder was separated anodically~ Hence it
can be concluded that only the compound Ni 3A1 which is not precipitated in
the electrolyte provided for the isolation of Ni 3Nb4 is formed. In ordei
to determine the amount of the phase Ni 3A1 in the alloys investigated an,
the distribution of alloying elements among the r-solid solution and the
Vi3Al phase, the alloys were anodically dissolved in the mentioned metha-,o'-
containing electrolyte and the powder anodically separated was analyzed
chemically. The distribution of alloying elements among the phases was
calculated from the results (Table 4). r-sulid solution + Ni,Al phase in VIK
the table corresponds to the composition of the alloy, the phase Ni 3Al
the composition of the powder precipitated anodically, relative to the
weight of the alloy dissolved during the experiment (anode). The compos~-
tion of the r-solid solution was calculated from the difference of elemei4-
contents in 1he alloy and in the powder precipitated anodically. This
study proved the reliability of the chosen optimum conditions for isolating
the compound Ni Al from multicomponent nickel-base alloys with contents Df
Card 3/6 3

5 0 2 0 /6 2-/ ; 4 2 /0 0 4 /0 J , jT0 2-
Study of isolation conditions... B106/B!!'O
Cr, W, Mo, Al, Nb, and Ti. Moreover, It was found that 'the metallic cor-
pound Ni 3Al is one of the phases of which the alloys studied are compose],
L. I. Pryakhina studied the mentioned alloys in order to establi.9h tne
phase diagram, R. N, Rogova, Yu,. G- Sorokina, V. A. Smirnova-, and SS. A.
Yuganova. are mentioned. There are 3 figures, 4 tables, and Soviet
references.
A'130,"IATION; Institut metallurgii im:, A. A, Baykova Akademii na~-,k SSSE
(Institute of Metallurgy imeni A. A. Baykc-., of the Acad-~m,'j of
Sciences USSR). Tsentrallnyy nauchno-issledovatellskiy
institut tekhnologii I mashinostroyeniva Oen~ral Scientific
Research Institute of Technology and MacInine Bu-.-Id-~ngi
PRESENTED: September 16, 1961, by I, I~ Chernysqev.- Academ-,cian
SUB'-7ITTED: Septembol-
Card 4/6

S/02 62/142/004/013/022
Study of isolation conditions ... B106YB110
Table 1. Legendt (I) tiumber of alloy; (II) conditions of heat treatmenti
(III) content of elements, by weight; (IV) degrees centigrade; M hours;
(vi) residue.

M149A W

06p, TKU

t COAtP3K8HRe.1AeMeRTO3. Set.%
-Nb- 1--T1
C' I W I MO I

1

t 1M. 100 nacj(~) 4,33 0.60 6,00 3,029 WT.
2 t2OO*-100 qav 3,86 3,00 - 9,50 6,00 3,00 OCT V
3
4 12000-200 qacCjZ")
1200*-200 vaqv 6,87
8,47 1,59 - 9 '56
- - 3143 6,10
2 41 2.90
1,12 ocT
ocT
5 U000-200 4sed) 3.46 - -3 '85 9 , 65 5:50 2,72 oacT
Card 5/6

S/020/6-2/142/004/013/022
5LAdi of isolation conditions ... Blo6/BIIO
Tab,le 4 . Distribution of elements among r- Oolid solution and the Ni i1 r1la-e.
T,egend: (I) Number' of alloy; (II)tases of the studied(alloys (Iil~ con-
t..,,,nt of elementG, 0/~o by weight; (I ~-aolid solution; V) phase; (VI)sum;
the nickel content of the alloy wasIcalculated by completion to 10CI~-
COCTSODWIAVIO $tau ICCAtAYOMMI ( V Coikepmatime sileme"Too, Pec. %
UD CrIASSON NI* Cr W MO Nb. TI Al a
T
f-TaieP5-DA pacnop 43S NIjAI 76t90 9, 60 6,09 3,02 - - 4,33 100,o0 v
s3a NIgAl P; 8160 0.55 1,25 0,27 - - t,30 11,97
T
I-TsepAufi pamop 68.36 9.05 4,84 2,75 - - 3,03 88.03
T
,r-TtsepAwft pamop$410 NIvAl
~O 74,64 9,50 6,00 3,W 3,00 .- 3,89 100.00
a3a NIxAI 19.62 0,87 1,44 0,23 1.52 - 2,01 26.59
T
I-TBepAO PSCMOP 55,02 8,63 4,SS 2,77 1,48 0,1)5 73,41
p ~.~MtAl 72,98 9,56 R, 10 2,00 t,59 - 6,87 IW,00
~Tuequg pacTBoPT
I-`
(OM IOAI 37,30 2,50 1,60 1,04 1,56 - 5,57 49,57
T-Tsep,lun PRCM &5,68 7, OCY 4,50 1.86 0,03 - 1 30 50,43
R 94,57 3,43 2.41 1,12 - - 8,147 IW,00
T-TBePAMA PSCTISOP fPQktNjsAI
(Da3a N13AI 13,87 0,50 0,51 0,25 - - 2,t2 17,25
I-Tae PaCTBO 70,70 2,W J,ilo 0,87 - - 6 35 82 75
1 Toe P"' PaMOP NIAI 74,82 9,65 5,50 2,72 - 3.85 3146 00:00
P, I I
-9 3 a PNA IU34A 1 18&-) 30 W 1 01, 0 83 0 39 - 2,60 3,46 38,%.
ITBe 44 22 r'.1 I V ii: 3:1 1 - I , 25 0,0 M,10
V P"11A PaCTBOIM
I r,16

GQL=SOVA, R.B,
Now electrolyte for the isolation of the Ki Mb metal compound
from nickel alloys containing niobium. 423ur Inst.met. no,10s
2:L,r.-216 162. (HM 15:8)
(Electrolytes) (Intemetallic compounds)

- - I
. - r - I

~A&_NR,- AP-5628913 50MC9 CODE: UR/0020/65/165/003/0559/0561
AUTHOR: Golubtsova, R. B, 'r
ORG: Institute of Metallurg Im. A. A. Baykov (Institut metallurgil)
TITLE: Selective isolation of the metallic compounds N13LI nd Nij!~i from multi-
component nickel alloys
0'5f V1
SOURCE: AN SSSR.' Daklady, v. 165, no. 3, 1965, 559-561
TOPIC TAGS: nickel alloy, aluminum compound, nickel compound, electrodeposition
ABSTRACT: The study was made an a two-phase ternary alloy containing 75 wt. %
Ni3Ti and 25 wt. % N13Al, and on a multicomponent nickel alloy having a three-phase
structure and the cemponition (in wt. %) Ni3Ti 52.5, Ni3Al 17.5, y4 30 ( (4 being
a nickel solid solution containit,g Cr 10, W 6, and No 3%). To find the electrolytes
for the selective isolation of the phases, the electrochemical behavior of these
alloys was investigated in various electrolytes by recording anodic polarization tnd
potential-time curves. The optimum value of the current density at which the dep)GL-
tion was performed was 0.1 A/cm2. Microchemical analyses of the depcsiLs were
carried out. It was fourd that the selective isolation of the two metallic com-
pounds N13Ti and Ni Al can be achieved in electrolytes of the following compositLim:
(1) 20 ml UC104 (5R), 50 ml HU03 (1.40), 1000 ml CR3OH; (2) 35 g citric acid, 5 1;
(NH4)2SO4, 15 ml HN03 (1.40), 1000 ml CH30H. Presented by Academician 1. 1.
Chernyayev. Orig. art, has: 2 figures and 3 tables.

6---.--- -- -- - .--I- - . - - -- ----- -I -- -.- I -
--7:7777
I L 13065-6 - I - - - - - -- - - - . 11 - - .-- , - -.- - - ~ - --- . ---- --- ---
ACC NRs AP5028913
SUB CCDE: 11 / SUM DATE: O3Feb65 / ORIG REF: Oll )7

-----------
L 21728-66 L74T(m)/EWF(t) IJP(c) JD/'JG
;IACC HR: AP6008060 SOURCE CODE: UR/0032/66/032/002/0150/015:L
1AUTHOR: Golubtsova, a, S. M.
Savvateyev
MG: Institute of Metallurgy im. A.-A. Baykov (Institut metallurgii) 41
!TITLE: Spectrophortometric determination of chromium- in anodic powders
SOURCE: Zavodskaya laboratoriya, v. 32, no. 2, 1966, 150-151
TOPIC TAGS: chrcmium, spectrophotometric analysis, powder alloy, electrolysis,
light absorption
A13STRACT: The,authors attempt to define conditions for chemical determAnation a
gram quantities of c6romium in anodic powders produced by electrolytic isolation of
iinterm.etallic and carbide phases from chrcme-nickel alloys. The proposed spectro-
!photometric method is based on the reaction of oxidation of diphenyl carbazide by
1hexavalent chromium in an acid medium. Curves for the light absorption of dipheiiyl'---
'carbazide ccmbined with chromium and for the pure reagent show that the reagent As
icolorless and has no effect an wavelength selection. It is found that one Vg of Cri
an be detected in the presence of 30 ug of N1, 90 mg of Al, 120 pg of W, 270 vg of!_-
UDC: 543.7

L 21728-66
ACC NR: AP6008060
Ho and 375 Ug of Ti. The effect of iron is easily eliminated by using ascorbic acid.
The best medium is a 3% (by volume) solution of sulfuric acid. The dye is unstablej
in 10 and 25% acid. The reaction conforms to the Lambert absorption lav. The ana!
lytic procedure is described in detail. Orig. art. has: 2 figures.
SUB CODE: 07in SUB14 DATE: GO/ ORIG REF: 001/ OTH REr: =i
-7
A0
4x4 2t2 _j

t "'
-_ .- 3 t-" - 66
L
ACC Nk,' AP6019833
SOURCE CODE: UR/0370/66/000/001/0136/0138
AUTHOR: Golubtsova, R. B. (Moscow)
7
ORG; none
TITLE: Selective separation of metallic compounds from multicomponent throe-phase alloys
SOURCE: AN SSSR. Izvestiya. Aletally, no. 1, 1966, 136-138
TOPIC TAGS: chemical separation, electrolyte, metal compound, nickel base alloy,
niobium compound, aluminum compound, anodization
ADSTRACT: 'flio article deals with the conditions for theanodic isolation of metallic com-
poimds from two mul4component alloys having a three-phase structure. Xho phase composition
of alloy 1 (15.5 1 1-
1% NV; 6. 257o Alo, 1. 077o Cr, 0. 67% W, 5. 72% Al, Ni base) was 45% INI, Nb, 45~
-fid Ni solution treated with 107o Cr, 6,7o W and 3% M.o), while the ;hase
Ni Al and 10% y4 (so
composition of alloy 2 (12.607o Nb, 1.467o Mo, 5. 5)117o Cr, 1. 38% Al, Ni base) was 33.7.,1% N1 Nb
3
111. 25~,() Ni IM and 55% )-A. The electrolytic behavior of these alloys was investigated ir. Lhe
3
presence of such electrolytes as: 1) 50 cc 57% HCIO
41 10 cc HCI (1. 19), 35 g of citric acid,
1000 cc CH 3011; 2) 50 cc I-IN03 (140), 20 cc 57% TIC104, 1000 cc C11.011; 3) 50 cc HC1011, 35 g 9f
1/4 UDC: 669. 017.15 ---

I ACC NR: AP6019833
citric acid, 1000 cc C11 011. Ilie activizing effect of the chlorine ion is demonstrated 31ter
I-ICI is added to clectro?Yte 3, which strongly displaces Uie potential to Uic left; 0iis rosults
hi curves (Fig. 1) characteristic of an alloy in an activo state (cuxTo. 1). Thus, dio pha so Nt N4
ril !F
i,,a/c al I
J f
t,ve al 94 Etv
Fig. 1. Curves of anodic polarization of alloys
I (a) and 2 (b) plotted in the p:-esenco
of various electrolytes (numej!als on
curves represent ordinal numbers of
electrolytes)
may be selectively isolated in electrolyte 1 despite the presence of another phase, Ni,Al, in the
alloy. The selective isolation of two metallic compounds -- the phases Ni 3NIb and NI3'U -- is
due to thp. considerable potential difference of the investigated alloys, which arises in electro-
2/4

L 44312-66
I_A_CC NR
- AP6019833
lytes I and 2 (Fig. 1). For anodic isolation of the phase Ni3Nb the alloy must exist Jn an active
state, which is evidently associated with the nature of this phase, while the anodic -3olarization
of the phase Ni3Al should occur in the presence of a marked polari7ztion passivating the
surface of the alloy (to this end it is eepedlent to use the highly effective passivatois repre-
sented by the anions NO 31 and CIO41 which are part of electrolyte 2). The potential-:ime
curves plotted for alloy 2 (Fig. 2) show that Its dissolution occurs in the presence (if a fixed
E, A
14 __12
f
f1v inin
Fig. 2, Variation of potential in time during the anodic
dissolution of alloy 2 in electrolytes I and 2
(numerals on curves)
Card 3/4

ACC NRz AP6019833
potential which rapidly sets in. The experiments with alloy 1 at current densities 0. 05 and
0. 1 a/ci-n2 resulted in the anodic isolation of the compound Ni Nb with a rhoinbic crystal lat-
tice. Radiographic and microchatnical analyses showed that the aiiodic dissolution of allo)s I
mid 2 resultod in the Isolation of the phase Ni.,Nb with a rhonibic lattice except for one case
'alloy 1, 1 = 0. 15 a/cm2, electrolyte 2) WIr re the anodic residue Nvas found to be a cubic face-
-centered lattice representing a Ni3Al-base solid solution In which the phase NI3Nb is dissolv
The motallic compounds thus isolaU can be used to harden varlous alloys. Orig. art. has:
2 figures, I table.
SUB CODE: 11, 07, 44POP/ SUBM DATE: 13Dcc64/ ORIG REF: 010/
4

L 38966-6 J,,',1,7' (11!'j/T/n1r MAT.-T lip(c) -'rV, fo~
ACC NRt AP6013373 SOURCE CODE1 UR/0370/66/000/002/3174/0176
AUTHOR: Golubtsova, R. B. (Moscow)
ORG: none
V1
TITLE: Separation of the Intermetallic phase N13AI from the alloy Ni-Cr-J.1
SOURCE: AN SSSR. Izvestlya. Metally, no. 2, 1966, 174-176
TOPIC TAGS: nickel alloy, aluminum containing alloy, chromium containing alloy,
electrolytic deposition
ABSTRACT: Tha~scparatlon of the compound N13AI (an portent strengthening Inter-
metallic phased n modern heat resistant nickel alloyi from the alloy Ni-Cr-Al
(NI base, 10.00 wt.% Al, 16.07. Cr) was studied In several electrolytes. Anodic
polarization curves showed that the most suitable electrolyt~ejsfor the electrolytic
deposition of Ni3A1 are those containing nitric acid; this was confirmed b.7 potential
vs. time curves. Measurement of theelectrode potentials showed their Valuas to be
close and to range from 0.95 to 1.2 V. The high values of the electrode P)tentials
in these electrolytes Insure the substantial degree of passivation of the nickel
alloy required during its anodic dissolution for the separation of the int-Brmetallic.
compound from the solid solution. Anodic dissolution experiments confirmed the
possibility of isolating the N13AI phase from the alloy in all the chosen olectro-
lytes. In view of the closeness of the atomic radii of nickel (1.24 A) and chromium
2- ..' .. ".- - - I- ., ... 6--1 - UJ?C1 669.017.13

ACC NRs AP6013373
(1.23 X)s It is postulated that the nickel atoms can be partially replaced by
chromium atoms in the Ni3A1 phase. Orig. art. hast 2 figures and 2 tables.
SUB CODE: ll/ SUEM DATE: 2lDec64/ ORIG REF: 004
Card 2/2

GOLUBTSOV$ L.A.; GOLUA=Ur-&--F~TERLETSKIY~ 0.1.; KARNAusHENKo, S.G.;
SREBNXYX-tL.D.
Antifog light filters for automobile headlights. Stek. I ker.
19 no.8tl9-20 Ag 162. (MIRA 150)
(Light filters) (Motor vehicles--Ughting)

1. GOLUBTSOVA, V. A.
2. USSR (600)
4. Electric Insulators and Insulatiom
7. Problems of electric insulation in the works of Russian scientists. Elektrichestvo
no. 12, 1952.
9. Monthly ListkDf Russian Accessions,, Library of Congress, March 1953. Unclassified.

UOLUBZOVA, V. A.
"lliermal Splitting of Polyisobutylone", I(eports of the Academy of Sciences, USSII, 1,1.
701-703, June M2.
ABSTUCI AVAILABLE'
U-500ii,l

GOLUBTSOVA V. A 11 Feb 52
USSR/Chemistry Insulating Compound Oils
"The Action of an Electric Field on Petroleum Oils and Their Mixture With
Hydrocarbon Polymers," V.A. Golubtsova, All-Union Elea Enging Inst im V.::. Lenin
DAN SSSR, Vol 889 No 5. pp 821-824
Studied the effect of an electric field on petroleum oil (bright stock) azid its
mixts with polyisobutylene and 12ol at gradient of 7 kvlm and freq of 50 cps
(const temp, of 30 ) in an atm of H. Gaseous products are separated and tk.e degree.
of unsatu of the oil is slightly increased. Mixts of petroleum hydrocarbcns with
rosin oil and mixts of petroleum hydrocarbons with hydrocarbon pol erB d
. ym am
rosin oil absorb H (decrease in iodine number). Established that the absorption
of H is connected with the hydrogenation of unsatd cmpds of the rosin oil
(abietic acid). Presented by Aced A. V. Topchiyev 13 Dee 52.
Source #264T23

GOLUBTSOVA, V.A.; ANWAVOT, I.A,
Tetroleum-base oils and hydrocarbon polymers as dielectrics. Zle):triche-
stvo 153, No'.it 31-6, (MU IA 6: 2)
(]NA 56 no.6700016A53)

1. GOLUBTSOVA, Docent V. A.
2. U33i" (6oo)
4. Shilling, P. L.
7. Electric insulation in P. L. Shilling's and' B.S. Yakobils writings.
Elektrichestvo, No. 4, 1953.
9. Monthl List of Russian Accessions, Library of Congress,
April -1953,
Uncl.

'd 7' o V fi
L
Subject USSR/Electriaity AID P - 1218
Card 1/1 Pub. 27 - 13/34
Authors : Kand. of Tech. Sci., and Volkov, V. A.,
Title : Mica in electrical engineering (History of Electrical
Engineering)
Periodical : Elektrichestvo, 12, 65-69, D 1954
Abstract : The authors give a historical sketch of the developmont
of the use of mica for insulating purposes. They pro-
sent a comparative table of the main insulating materials,
and describe some of the characteristic properties of mica.
They also give a review of production of insulating mia-
terials employing mica in the USSR. Two diagrams, 4 tables,
18 references (15 Russian, 1898-1951; 3 non-Russian, 1929,
19061 1944).
Institution : None
Submitted : No date

Name: GOLUBTSOVA, Valeriya Alekseyevna
Dissertation: History of and prospects for the
development of electrical insulating
/;j materials for electrical machiner-,
apparatus, wires and cables
Degree: Doe Tech Sci
Affiliation: Inst of History of Natural Science,
and 11~ Acad Sel USSR
t ') r, - T I ~01 t
Defense Date, Place: 30 Dee 55, Council of Moscow Order
of Lenin Power Engineering Inst imeni
Molotov
Certification Date: 26 may 56
Source: BMVO 4/57

LIVIT, Grigoriy Osipovich, inzhener; BRLIKM. L.D..doktor tekhnicheakikh
nauk, redaktor; GIAZUNOT, A.A.,doktor tekhnichookikh nauk, redaktor-,
Q2I,U2T9QIAo--V_~A,,kandidat tokhnicheakikh nauk. redaktor; ZOU)TAREY.
T.L.,a-oR-6r-40'&nicheskikh nauk. relaktor; IZRASH. S.V..
doktor tekhnichaskikh nauk, redaktor; KIRILLIN, Y.A.,rodaktor;
KWIMERATOV, I.Ya.,doktor tekhaichedkikh nauk, redaktor; PETROY,
G.H.,doktor tekhnicheskikh nauk, redaktor; SIROTINSKIY,~L.I.,
doktor tokhnichaskikh nauk. redaktor; SOLOTIYBT, I.I.,profeasor,
redaktor; STTRIKOVICH, M.A.,redaktor; SHNNYBM. Ya.A..Imndidat
takhnichaskikh nauk, redaktor; SHQHIGLYAYIV,A.V.,redaktor; AIM.
I.Y.,redaktor; FRADKIN, A.M.,takhnicheskiy redaktor
[Outline history of power engineering in the U.S.S.R.] Ocherki
po tatorit, energeticheskol tekhniki SSSR. Red. komisslia L.-D.
Belikind i dr. Moskva, Gba. energ. izd-vo. No. 3. [Power
congresses and conferences3 Inergetlaheskiy slezdy i
konferentiii. 1956. 98 p. (MLRA 10:4)
1. Moscow; Mookovskty energeticheakiy institut. 2.Chlen-korresponderit
AN SSSR.(for Kirillin, Styrikovich; Shcheglyayev)
(Power engineeriag-Congresses)

-99LUBTSOVA, I.A.; CHILIKIN, M.G.; KARG=VA, T.Kb.; MSSHKOV, V-V-;
DROZDOV, N.G.; PMZKALIN, M.A.; SMIRMV, V.A.
Professor V.S. Pantiushin.' Ilektricbestvo no.7:93 J1156. (MMA 9:1.0)
(Pantluabin, Vasilli Sargeavicb, 1906-)
4

It B
CHILrIN, M.G.; WHKOV, L.I.; VIUrKOV, V.A.;
ZOLOTAREV, TeL.; XCUBMUROV, I.Ya.; SHMEERG, Ya.A.; V&SRLGVSrrf, O.N.
Professor L.D.Ballkind. Blektrieliestvo no-8:93-94 Ag 156. (KLILA 9:13)
(Ballkind, Lev DRvidevich, 1896-)

[3,rf) y/j lqj, E r, s F-
ylq
ypyna; TARSYMV, B.H., red.;
'Q,0~0~SOY,4', jSlariMAlgt~Se XXDVEDEV, L.Ya.,
t e1rhn * red.
[Histor7 and prospects for the development of electric insulation
materials] Istoriie i'perspektivr rasvitiia elektroisoliatsionnykh
Materialov. Moskva, Gos.awrg,izd-vo, 1957. 76 p. 9 graphs
(KERA 11*2)
Odlectric insulators and insulation)

BADYLIUS. I.S.. doktor takhnichaskikh nauk; BELINSKIY, S.Ya., kandidat
takhaichookikh nauk;'GINXEL'YARB. M.L., kandidat tekhnichaskikh
nauk; KAIA-FATI, D.D., kan'didat takhnichaskikh nauk: UMTSELLI, L.I.,
professor; KOVALIV, A.P., doktor tekhnichookikh nauk: XONMEUTOT,
I.YA., doktor tekhnicheskikh nauk; IAVROY, Y.N., doktor takhniche-
skikh nauk; IMIDXV, P.D.. doktor takhnichaskikh nauk; IMITSKIY.
V.V., doktor tekhnichookikh nauk [deceased]; PXTUKHOV, B.S.. doictor
takhnichaskikh ~auk; SATANOVSKIY. A.Ya., kandidat takhnichookikh naukj
SEMENINKO, N.A.,doktor takhnichaskikh nauk; SMALINITSKIY, S.G..
kandidat takhnibheskikft nauk; SOKOLOV, Ts.Ys., doktor tekhnicheskikh
nauk; CHISTYAXOV. SJ., kendidat takhnichaskikh nauk; SHCHIGLYAYEV.
A.V.; BBLIKIND, L.D., doktor tsk~nicheskikh nauk, redaktor; GLAZUNOV,
A.A., doktor takhnichaskikh nauk, redektor; GOLUBTA_QLTA,_.j.A., doktor
takhrii. cheBkIkh nauk, redakt or; ZOLMAREV, . T. L. , d6k-t-o-r-i-e-k-Enicheskikh
nauk. redektor; IZBASH. S.Y...doktor tekhnichaskikh nauk, redaktor;
KIRILLIN. V.A., redaktor; MARGULOVA, T.Kh.. doktor takhnicbeakikh
nauk, redaktor-, HESHKOV, V.V., doktor tsihnicheakikh nauk, rectaktor;
PMOV, G.N.,.doktor tekhnichaskikh nauk, redaktor; SIROTINSKIT, L.I..
doktor takhniches'kikh nauk, radaktor; STYRIKOVICH. X.A.. redaktor;
SHNEYBIMG, Ys.A., kandidat takhnichookikh nauk, radaktor; MATYEYXV,
G.A., doktor te *khnicheskikh nauk. redaktor; M&DVIDIV, L.Ys.,
tekhnicheskiy redaktor
[Hiotory of power engineering in
Istortia energetichaskoy tekhniki
Goo.energ.izd-vo.
the U.S.S.R.; In three volumes]
SSSR; v trekh tomakh. Moskva,
(continued on next card)

9 BADYLIXIS, I.S.---(continued) Card 2.
Vol. 1, CHeat engineering] Tsplotekhniks. Avtorekit kollektiv tons
BadylIkes i dr. Red. -soot. toma I.IA.Xonfedaratov. 1957. 479 P.
(MIRA 10:8)
1. Chlon-korrespondent Akademli asuk SSBR (for Shchoglyayev,
Kirillin, Styrikovich). 2. Moscov. Moskovskiy energetichookAy
institut
(Beat engineering-History)

ALIIXSAHDROY. A.G., dots; ARONOVICH. I.B., insh.; BABIKOY. H.A., doktor
tekhn.nauk; BATUBOV, S-V., kand.telchn.nauk; BELIKIND, L.D., doktor
tekhn.nauk; VEHIKOV, V.A.. doktor tekhn.nauk; VESELOVSKIT, O.N.,
kand.tekhn.nouk; GOLOVAH, A.T., dohor tekhn.nauki;YGOL1MT6OVA.. V.A.,
doktor tekhn.nauk; GEWIAM. L.K., inzh. -, GRUDINSK . G., pr6e.,
GUSHV, S.A., inzh.; DHOKHOVSKAYA. L.F., kand.tekhn.nauk; DROZDOV,
N.G., doktor tekhn.nauk; IVANOV. A.?., doktor tekhn.nauk [deceased],,
KAGANOY, I.L., doktor takhn.nauk; KBIM12. L.L., inzh.; KOCH14NOVA, A.L.
kand.tokha.nauk.; IARIONOV, A.N.; HINOV. D.K., doktor tekhn.nauk;
10;TUSHIL, A.Y., doktor takhn.nauk: HIKULIN, N.V., kand.tekhn.nouk;
NIL-9MM,. R.A., prof.; PANTYUSHIN, V.S., prof.; PASYNKOV, V.V.,
doktor tekha.nauk; PITROV. G.N., dok-tor tekhn.nauk; POLIVANOV. K.M..
doktor tekhn.nouk; PRIVEZHItTSXV, V.A., dol.-tor tekhn.nauk; RADUNSKIY,
IJ.D., lnzh.; R~M, V.T., doktor takhn.nauk; SVINGHAIZKIY, A.D.,
doktor tekhn.nauk: SOWVIYZV. 1.I., doktor tekhn.nauk; STUPELI F.A.
kand.tekhn.nauk; TALITSKIY, A.Y., prof.; TXMNIKOV, F-Ye., kand.takhn.
nauk; YLTOROV. L.I., inzh.; YEDOSEYEV, A.M., doktor tekhn.nauk;
KHOLYAVSKIY, G.B., inzh.; GEEGINT, Yu.S., doktor tekhn.asuk; SHNXY-
BMG, Ya.A., kand.takhn.nauk; SHUMILOVSKIY, doktor tekhn.nauk;
ANTIK, I.B., red.; KOVEMV, L.Ya., takhn.red.
[The history of power engineering in the U.S.S.R. in three volumes]
Istoriia energoticheskoi t ekhniki 880 v trekh tomakh. Moakva, Goo.
energ. izd-vo.
(Continued on next card)

AIRKSANDROV, A.G.--(continued) Card 2.
Vol.2. (Illectric engineering] Slektrotekhniks. Avtorskit kollektiv
toma:.Alakeendrov i dr. 1957. 727 p. (MIRA 11:2)
1. Maccow. Moskovskiy anergeticheskiy in5titut. 2. Chlen-korrespon-
dent AN SSSR (for Iarionov)
(Alectric angineering)

DITMAR, Andrey Borisovich; GOWBTSOV-k Ye.S., kand. ist. nauk,
nauchMy red.; SRD~~~akademik ;
red.; PROKHODTSEVAp S.7a., red.; &ULIGA, L.K., mladsiuy red.;
XOSBEIEVAp S.M., tekhn. red.
(From Scythia to Elephantine; Herodotus' life and travels) Ot
skifii do Elefantirqj zhizn' i puteshestviia Gerodota. Moskvaj,
Geografgii., 1961. 85 P. (KRA 15:6)
1. Chlen-korrespondent Akaderjii pedagogicheskikh nauk (for
SolOvIyev). (Herodotus, c-484 - /+25 B.C.)

5(2) SOV/79-29-5-1/75
AUTHORS: Morachavskiy, Yu. V., Tserkowlitakayat I. A., Golubtsova, Z. G.
TITLE: Precipitation of Palladium With Dimethyl Glyoxime in the Presonce
of Ferric Oxide Salts (Osazhdeniye palladiya dimetilglioksimon
v prisutstvii eoley okisi zheleza)
PERIODICAL: Zhurnal obahchey khimii, 1959, Vol 29, Nr 5,
PP 1405 - 1408 (USSR)
ABSTRACT: In the present paper the authors investigated the influence ol!
iron upon the precipitation of palladium from hydrochloricq sul-
furic, nitric and chloric, acid solutions of different concentra-
tion. It was first determined how far the acid concentration nay
be varied without deoroasiag the yield in palladium. The expe:.-i-
ments indicated that the precipitation of palladium with dimel;hyl
glyoxime is still almost complete in 1.5 normal chloric acidt
nitric acid and hydrochloric acid solutions. In sulfuric acid
solution a 100A precipitation of palladium etill takes place
from the 2-n solution. The increase 'in acidity of the solution
influences the yield in palladium most in chloric acid and least
in sulfuric acid solutions. The results obtained in the precipita-
Card 1/2 tion of palladium with dimethyl glyonime in the presence of

Precipitation of Palladium With Dimethyl Glyoxime in the SOV/79-29-5-1/7,5
Presence of Ferric Oxide Salts
FeCl3 in hydrochloric acid medium are summarized in table 1.
Table 2 presents the results of the precipitation in the presonce
of Fe 2(SO4)3 in Gulfuric acid mediu;m, table 3 the results in -.he
presence of Fe(NO 3)3 in nitric acid medium and table 4 the re..
suits in the precence of trivalQnt iron in chloric acid mediwa.
The results obtained permit the assumption that there is an
interaction between dimethyl glyoxime, iron (III) and palladilun
in acid solutions in which connection a complex compound is
formed. The nature of this compound is not yet clarified. At
present the authors are carrying ont the spectroscopic invest:."ga-
tion of the system palladiunt-iron-dimethyl glyoxime. There aro
4 tables and 2 references, I of which is Soviet.
ASSOCIATION: Leningradskiy gosudarstvennyy universitet (Leningrad State Un!.-
versity)
SUBMITTED: April 22, 1958
Card 2/2

S/075/60/015/004/019/030/XX
B02O/B064
AUTHORSs Morachevskiy, Yu. V., Lebedeva, L. I., and Golubtsova, Z. G.
TITLE: Spectrophotometric Study of the Interaction Between the Ions
of Trivalent Iron and Dimethyl Glyoxime
PERIODICAL: Zhurnal analiticheskoy khimii, 1960, Vol. 15, No. 4,
Pp. 472 - 475
TEM L. A. Chugayev (Ref. i) was the first to investigate the metal -
dioximate complexes-IThe reaction of trivalent iron with dimethyl glyoxime
has hitherio not be n fully clarified. Some researchers (Refs. 1,3,4)
assume that the salts of trivalent iron do not react with dimethyl V
glyoxime. In contrast to this, it is known (Refs. 5,6) that the presence
of dimethyl glyoxime (Dm) in the solution prevents the precipitation of
iron hydroxide even at high pH, a transparent orange-colored solution being
formed whose color is stable in time; in the authors' opinion this is due
to the formation of a stable iron - dimethylglyoxime complex. A.M.Gurvich
(Ref. 6) found that the ratio FeiDm is equal to 1:1 in weakly acid
solution. The authors proved in Ref. 7 that Fe+3 complicates the
Card 1/4

Spectrophotometric Study of the Interaction S/075/60/015/004/019/030/XX
Between the Ions of Trivalent Iron and B020/BO64
Dimethyl Glyoxime
quantitative precipitation of palladium with dimethyl glyoxime, sometimes
preventing it at all. Experiments showed that iron reacts with a dimethyl
glyoxime excess in acid solutionj the reaction rate is, however, very low
at pH!z,3, which is due to the low degree of dissociation of dimethyl
glyoxime. At a pH of 2.5 - 3, equilibrium is established after about one
day, i.e., at a dimethyl glyoxime concentration of an order of
10-3 g.mole/1 and at an iron concentration of 10-4 g.atom/l; for this
reason, this range of concentration was chosen for the investigation.
Trivalent iron reacts with dimethyl glyoxime both in acid (pH -3) and
alkaline solutions under the formation of a complex ion.. The composition
of the dimethyl glyoxime - Fe 3+ complexes was examined with the spectro-
photometer C~-4 (SF-4.), the hydrogen ion concentration in the acid range
potentiometrically with a glass electrode and titrimetrically in the basic
range. The composition of the complex was determined by the method of
isomolar series and by logarithmic determination of the limit, Fig.1 shows
the experimental results at three wave lengths for series with a concen-
tration of 4,17-10-3 g.mole/l. The curves diverging from additivity show a
Card 2/4

Spectrophotometric Study of the Iriteraction 8/075/60/015/004/019/030/XX
Between the Iono of Trivalont Iron and DitnothylB0201BO64
Glyoxime
maximum at a ratio of the components of 10. The same result was obtained
by logarithmic determination of the limit for dimethyl glyoxime and
Fe3+ salt excess. Fig. 2 lists the data obtained. The lack of a distinct
maximum (Fig. 1) in the present case is no proof of a poor stability of the
complex formed in this range. The composition of the complex in the alka-
line region was investigated by logarithmic'determination of the limit and
found to be FetH2Dm - 1:1 (Fig. 3). At pH - 3, the solution mainly contains
Fe(OH) 2+ ions, which indicates that the complex formation proceeds
according to the equation Pe(OH )2+ + H2Dm-FeOH(HDm)+ 4. e. The authors
made an attempt to calculate the instability constant of the complex using
the relations derived by V. N. Tolmachev (Ref. 8); which, together with the
dissociation constants and optical densities are given in a table. The
12
calculated instability constant K FeOH (HDM)+ equals 2.16-10' .There are
3 figures, 1 table, and 8 references: 7 Soviet and 1 US~
Card 3/4

Spectrophotometric Study of the Interaction S/075/60/015/004/019/030/XX
Between the Ions of Trivalent Iron and B020/BO64
Dimethyl Glyoxime V
ASSOCIATION: Leningradskiy gosudarstvennyy universitet im. A. A.. Zhdanova
(Leningrad-5-ta-t-e University imeni A. A~ Zhdanov)
SUBMITTED: May 30, 1959
Card 4/4

GOLUBTSOVA, Z. G.
Cand Chem Sci - (diss-1 I'Spectrophotometric study of the system
palladium-dimethylglyoxime-iron(III) in aqueous solutions."
Leningrad, 1961. 14 pp; (Ministry of Higher and Secondary
Specialist Education RSFSRj Leningrad Order of Labor Red Banner
Technology Inst imeni Lensovet); 180 copies; price not given;
(KL, 6-61 sup, 197)

G..0LUBTSOVAY Z.G,; 1EBEDEVA, L.I.; MORACHEVSKI7, Yu.V. [deceased]
Interaction in the system palladium--dimethylglyoxime-trivalent
iron. Zhur.anal.khim. 16 no.2:191-195 Mr-Ap 161. (MIRA 14:5)
1. A. A. Zhdanov Leningrad State University.
(Palladium compounds)
(Glyaxime)
(Iron)

GOMUSHIN, Th. [Holubushin. rj.]g nalachrO7 sotrudnik
"The Constitution of Night Hieroglyphics-* Znan. ta pratsia no-8:12-
13 Ag 160. (MIRA 13:9)
1. Inatitat ekonomiki AN USSR.
. (China-Agrimiltare)

GOLUBUSHIN, YUrly Sergeyeviqh--[Hojubushjn, IU.S.); DANIIZUK, Zinoviy
Z.Z.1; CHUFAICHMKO, V.S., red. izd-va;
ROZE21TREYGI Ye.F., ttkbn. red.
(Socialist countries on the path toward couvamism]SotsWistychni
krainy na shliakhu do kormunizmu. Kyiv, Vyd-vo Akcad. nauk. IMM,
1962 51 P. (MIRA 15--12)
iComarunist countries-Economic corditions)

KIPRIANOV, A.I.; GOLUBUSHINAp G.M.
.. .. ia~
Cyanine dyes from 2-methyl-5,6-dioxybenzothiazole. Ukr. khim.
z.hur. 29 no.11:117.3-1179 163. (MIRA 16:12)
1. Kiyevskiy gosudarstvennyy universitet im. T,G. Shevchenko.

GCLUBUSHKIN, P.N.
Additional contact blocking at the control station of TPSK and
TPS-50-I capron hosiery stabilizing machines. Cbm.takh.opyt.
[W,Pj no.36:39-40 156. (MM 11:11)
(Honiery, Nylon) (Automatic control)

USSR/Physical Chemistry Themodynamics. Thermochemistry. Equilibrium. Fhysico-
chemical Analysis. Phase Transitions, B-8
Abst Journal: Referat Zhur - Mlimiya, No 1) 1957) 372
Authort Golub P M. SO, and Bergman, A. G.
--ftft"ft'
Institution: None
Title: A Ternary Mutual System Composed of Potassium and Calc-_Ium Sulfates
and Chlorides
Original
Periodical: Zh. obshch. khimii, 1956, Vol 26, No 2., 328-338
Abstract: The mutual system K, Ca//Cl, S04 has been studied by the vlsual-
polythermic melting method. It has been establish-ed that the crys-
tallization surface of the system consists of 8 areas which interse.ct
at 7 multiple points and differ considerably from those found earl~.er
(Jaenecke, anorgan. allgem. Chem., 1936, 228, 241). Two transitioij
points (at 676 and 7480) and one transit point (at 6530) were found.
From a comparison of the 2 phase diagrams for the mutual system in
water solution and in the fused state, the conclusion has beep dram
Card 1/2

USSR/Phyeical Chemistry - Thermodynamics. Thermochemistry. Equilibrium. P'Xisico-
chemical Analysis. Phase Transitions, B-8
Abst Journal: Referat Zhur - Xhimiya, No 1. 1957) 372
Abstract: that complex formation in water solution is weakened by the chamical
activity of water.
Card 2/2

GOLUBTATNIKOV. A.I.
Study of forage.plants
no.10:44-46 0 '58.
(Forage
in secondary schools. Politelth.obuch,
(WRA 11:11)
plante-Study and teaching)

GOLUBYATNIKCV, A.N.
Nonlinear spinor functions. Dokl, AN SSSR 165 no.2*.265-267
x 165. (MIRA 18:11)
1. Subn-Itted April 31, 19659

KOBILYATSKIY, V.G., inzh.; GOLUBYATNIKOV. B.G,, inzh,
. - ...... ~ - ~ -1.
Vertically closed conveyor. Hashinostroanio no.6-.40-.41 N-D '63.
(MIRA 16s12)

GOLDBYATNIKOVO B.P.
Feeder block for the 234 molding machine. Mashinostroenis no.4264-
65 J1-Ag 163, (KRA 17s2)

GOLUBYATNIKU. B.F., lnzh.; KOBILYATSKIY., V.G., Jnzh.
Automatic line for producing small. cast-iron castings. Mekh. i
av,tomeproizve 19 noo3:3-! M-,~ 165. (MIRA 1814)

GOLUBYATNIKOV, B.P., inzh.; DoRoNIKO, T.Ya., inzh.
Automatic machine for pressing molds under high specific
pressure conditions. Mashinostroenie no.6:6-0, N-D 165.
(MIRA 18:12)

GOLUBYATNIKOV, D.V.
- . -1.
Upper Paleozoic volcanic apparatus Aydarly (central
Kazakhstan). Trudy VSEGEI 98!117-127 163. (MrRA 17:5)

DOTSIZKO, T.K.; SURCHAKOV, A.V.; BELYAYEVA, A.M.; KOROTOVSKAYA, II.T.;
GOLU13YATNIKOV, F.I.; KOZIDVA, K.F.
Use of now inaecticideo in controlling syranthropie flies
in nonisolated aectors* 14edeparazei param.bol. no.3:355--
359 162. (MIRA 15:9)
1. 1z Ymybyahevskogo naucbno-Usledavatel'skogo inatituta
epidemiologiii, mikrobiologii i gigiyeny (dir. K.P. Vasiltyev)q
Gorodskoy sanitarno-epidemiologichookoy atantaii (glavnyy
v-raeh A.A. Galaktionova, zav. parazitologichoskim otdelom
IT.T. Koroto-okaya) i Gorodskoy dezinfek-tvionnoy stantsii (zav.
H.F. Koz-1ova).
(FLM-EXTEWIFATION) (TISECTICIMS)

AGALIKA. H.S., inzh.; AKUTIN, T.K., Inzh., jUW,SOV, A#H., inzh.,, ARISTOV,
B.S., kand. takhn. nauk,; BELOSTOTSKIY. O.B., inzh.; BEMIN, A.Ye.,Inzh.;
BISSKIY, K.A., inzh,; BLTUMI A.M., inzh.; BRAUN, I.Y., inzh.; BROIISKIT,
I.A.. inzh.; BURHAS, A.I.,inah.; TATHMAN, I.Z., inzh.; TARSfUTSKIT,
I.N.,inzh.; VASILYETA, A.A.,inzh.; VORONIN, S.A.,inzh.; VOYTSEKHOVSKIY,
LjK., inzh.: YM)BLEVSKIY, A.A.,inzh.; GERSHKAN. S.G., inzh.;
GOLUBTATNIKOV. G.A Insh.; GOnIff, M.Th., in?,h.-, GRAJOIANKOV. A.M.., inzh.:
~.;DIDICOVSKIY, I.L., inzh.: DOBROVOLISKIT, N.],.,insh.;
DROZDOV, F.F.,kand. takhn.rauk,; KOZLOVSKIY.A.A.,Jnzh.; KIRILENTO,
Y.G.,inzh.; KOPELTANSKIT. G.D.,kand. tekhn. nauk,-, KORETSKIY, M.M,,inzh.;
KUKHARCHUX, I.N.,inzh.; KUCHER, M.G.,inzh.; MIUMYAK, M.V.,inzh.;
MIRONOV, Y.Y.,inzh.; NOVITSKIY. G.V.,inzh.; PADUN, N.P.,inzh.;
PANKRATIYET, N.B., insh.; PARKHOMENKO, Y.I.,kand. biol. nauk.; PUSKIY,
Ye.A.,inzh.; POILUBNYT. S.A.. inzh.; PORAZHMO, F.F.,insh.; PUZA90Y.
I.G.,inzh.; REDIN, I.P.inzh.-, nZNIK. I.S..kand, tekhn. nquk,;
HOGOVSKIY. L.Y..inzh.-, R=RKAH, A.G.,inzh.; RYBALISKIY, T.I.,inza.;
SADOVNIKOV. I.S.,inzh.; SEVERITANOV. N.S.,kand. tekhn. nauk,; SUSSHKO,
A.T.,inzh.; SIKKIM, A.Kh., inzh.: SURDUTOVICH, IoN.,inzh.; TROPINOV,
V.I.,inzh.; YYJFAR. M.K.,Inzh,: FIALKOVSKIT, A.M.,inzh.; MSHKAN,
H.S.. inzh.; ORMUSHNEV, V.A., insh.; SHNSTOV, B.S., inzh.; SHIINAN,
K.I.. inzh.; SMMYA!PSKIY. A.P..inzh.; SHCHERBAKOV, V.I..inzh.;
STANCHMMO, I.X., otv. red.: LISHIN, G.L.,inzhj,red.: KRAVTBOV,Te.P.,
inzh..red.; GRIGORITET. G.V.,red.- XMINSKIY, D.N.,red.; LHASOVSHY,
I.P.,red.;-LETTMAN, LaZe, rede(daceasedj,; GUREVICH. K.S.,inzh.,red.;
DANILEVSKIY. A.S..inzh.,red.: DEMIN. A.M., inzh.,red.; KAGANOV.
S.I.,inzh.,red.; KAUYMAH. 3.H., kand. takhn. npuk, red.-.LISTDPADOY,
N.P.,ifizh.,red.; MWIIEVIGH, left*, inzh. red-[deceased);
Icontinued on next card)