SCIENTIFIC ABSTRACT GOLTSOVA, R. - GOLUB, A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000515830005-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 24, 2001
• Sequence Number: 5
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

PRTROTP toAol RIMTIIV, X,Y*.; 5ITSOTA. RA,
Tr4o"storifleattoit of dMethyl pboaphito vith otbylens Col,
Zbiuro ob, khAn. 33 mo.53U85-1498 WI 1b3. (MIRA l6t6f
'(*tbrl phoophites) (Noterifi(tation)
(kowleng 93,yaoi)

ACCESSXOW NR-. AT4034002 9/0000/63/000/000/0170/0174
AUTHOR; Petrov, K. A.j Wifaut'YOV, Z. YG.,*
TrME: phosphorus-containing polymers. X. Synthesis of polyphosphite-based
polyphosphonates
SOURCE: Geterotsepny*ye vy*sokomolskulyarny*ye soyedineniya CHateroebain
macromolecular compounds); abornLk statey. Moscow, Xad-vo "Nauka," 1963,
170-174
TOPIC TAG$: polymerization, pboophorus containing polymer, polyphosphits,
polyphosphonate
ABSTRACT: As a further stop in the authors' polymer studies data are given on
the synthesis of polyalkylalkylensphosphonates, poly-.A -bydroxyalkylalkylens-
phospbonates and poly-&i. -aminoalkylalkylenspboopbonates by the Michaelis
and Becker method using acid polyalkylenephosphites. The following polymers
were prepared, identified and described: polybemylbexamethylanaphosphonate,
poly-.& bydrozybmmylboxametbylonsphospbdta, poly-.4 -dibutylaminobamylhexametbyl
enephospbooste, polydietbylaminomathylbemmekhylenapboaphonate, poly- t -propyl-
aninoisopropylhexomtbylemphospbonate, poly-distbylaminmothyl-p-xylidenepbos-
obonate. nalybutylamin -bia-motbylbwAmethylonaphosphonate, and a copolymer of

lot
ACCBSSXOtf M AT4034Q02
J-dibutyleatinobtaxylbexamethylompboopho"to and di-(hexamethylonapboapbato)
dimulfide. The preparative procedure consists essentially of reacting the
reagents for several hours at 90-13SO; the yield varied from 48 to M for
different individual products, OriX. act. has: 4 chemical equations.
ASSOCXATIOIN.- None
SUMMED: 13Nov62 DATE ACQ: 30Apr64 RNM: 00
SUB CODE: OC MD OF SOV: 009 OTMM: 004
Card 2/2

PM;1T,-V, Nl.FJOrlYFT, E,Ye.i GCLITSOVA, *...G.; MY.
;)u2ynwrr.. PL.-t 11: jynthes-'L ~f
po4imric anKi.cgs of phosphoru3-contaldrg
na. 5:92')-133 I-ty 164. f IE RA
Vpokom.s6tid. b I
17: 6':

GGLITBOTA, TOO*, (Alm*-AW
A"ss"s%%1rk;Wt1ve effectiveness of intravenous, intraiwarterial, and
Intraearotid infusion of blood in acute hemorrhage and shock*
Pateflatol. I Asp. terep, 2 U0,3:44 yq-JG '58 (MIRA 1117)
Is Is katedry patologichookoy fisiologit (tsy$ - seelyshenay
doyatellawaki Prof. O.S. Glossan) latakhokogo seditsiuskogo Instituts.
(atom-TRANSFUS lox)
(MMOMUMN)
(SHOCK)

GOLITSOVAP To G., Cand Med rvi (dies) -- "The comparative effectiveness of
Intreve'nous, iyytr"rterial, and intracerotid transfusion of blood In acute
blood loss mid abook". Alum-Ata, 1959, 1.0 pp (Kazakh State Med Inst), 300
copies (XI,, lie (), ].~X;O, 1213)

OUMw, O,S,.; GCLIMVA, T.G.1 ZIKZMA, A.I.; LONSHCHAKOVA, A.S.
Wjp*-ktm~---~
Wfoot of hMwthemia on the darre1opment of experimental nepbro-
omloinools In ratsb Arkhapate 23 no.4837-42 '61. (MIRA 14:6)
1* Is kaflaby patologicbeskoy fisiologii (71&v. - prof. 0.S.
Mom=) I ,kafedry patologichaskoy anatomi, (tay. -- prof.
P.r. Oobk.*ur) lanakhakogo usditsinOogo inatituta.
(IMWKMKU) (KIRMS-DISRASIS)
(CALCIM H&TABOLISM)

Country TISSR
Caugory 'Urobiolorv. Vicrc~ss Patho7mnic ~'or -su- ard Animals
AL):3. JOU1, tier :%ar iltol.' ";a 2
'),
Author
Institut. t
T It! F~-udy of the Viabilily of kn'thrs,~ d-,ores Fxmsed -to
Or.tF, Pub. : Inform. byul. biml. prou-sti. 1QI)7. No 2.
Ab3tract- : ?h* physical, aultural-morphological, virulent
properties, reactivity and viability of spores of 26
different series of arnLrax vaccines wore attidied tift,
bogin frozen once or twice at -420-440 for three days
with subumquW. thawing at 180. It waa e6tablinhad
teat after freezing tbi physical properties of the
Ouithral vaccines are maittained, but the viability of
the #~vroa Is reduced considerably. The virulence
and reactivity are altored.-Il. v&. Bov*Lrmkava
*T.A., Kokoreva V.B.
Card; 1/1

L 45668-66 BWT(M)/HWP(t)jVa, 14f~SL.ID/WW
ACC N&i 06OWi~---- SOURCE CODE' UR/01941"10647
Qvj
AUMOR: Gglltogn . Ye. I.
WON"*.,
ORG: Power Enalneering.Institute in. Krzhizhanovskly (Energoticheakly inatitut)
I TITLEt Density of lithium, s!~um and L)q~ium up to 1500-16006C
MUM-. Teplofizika vysokikb tomperatur, v. 4, no. 3, 1966, 360-363
TOPIC TAGS:
th4rinacouple, lfthlumi, sodium, platinum, 111 4 metal
Densities of lithium, sodium and potassium were d4ttezuiftq4 up 'to tm
tvi*i. ~of i6adve, Spe"al qVautus md measuring techniques developoCto, ovim,wo
AM "M blab #-bmmicai 6etivi" of 'these, pidlients we djo-
0 7 "8 of 10, to. ;0 -atim. dwo
"_W viiww awlins more ad a son at ptess,
total va& siaturstion Pleasure. Measurement of the ratio of nase to volume Q#
;the samplib at a poisi Aere the temperature variation was very wall was made to Qb-'
:tain a precise demsity-tempersturd relationship. The teiRperature was determined us-
,ing cbrociel-alumel thermocouples below 12000C and by platinum-platinum-rhodim tbirmo
!*ouples; at higher temperatures. The donsity-temperature relationship is linear up to
Above this tpmpersture a strong drop in density occurs, analogous to that of
non-metallic liquids naw the critical temperature. Analytic fame for the experi-
mental data ware deri"d for the linear range. The experisentai *z.~w are t0.3%,
UDC: 669.88t532.14

. . . .. , - -4,~
~ A~ - i6x,4A, - - - - -4~ .. . * .~,-
A- , . .. - , .,! .4~-tjr . . . .
wqw Ale'
I Ilk

VOROBIYKV, Malay KonstantimovIch; "GOLITSSWIDT Vladimir
Avostavlob [deceased); KAR '-Rh hil I
)N?1Wt8M1'Wnw--M2R=Av Vera leonidovna; KRAS144OV,
0
Somstantin Solmonovichl 1XVINSHY, Yu.V., red,
[LaboraUry vork in pbysical chemi.Btry] Pr&ktikum po
fisiohemkoi khimii. Izd.3., perer. i dop. Moskva, Khi-
x1isp 1964. 383 p. (MIRA 18:4)

SOV/1 37-58-11-22369
Translation from: Refe.rativnyy zhurnal. Metallurgiya. 1958, Nr 11, p 75 (USSR)
AUTHORS: Kirillov, B. S,Garenshteyn, M. M. , Tkachenko, V. K. , Goltvenko.,-A.1.1,.
TITLE: An Investigation of Dynamic Processes in the Live Train of an 1170
Blooming Mill Under More Severe Conditions of Rolling (Issledovaniye
dinamicheskikh protsessov v rabochey linii blyuminga 1170 pri
trihestochennorn rezhime prokatki)
PERIODICAL: Izv. vyssh. uchebn. zavedeniy. Chernaya metallurgiyu, 1958,
Nr 1, pp lZ8-137
ABSTRACT: An investigation is made of dynamic processes in the live train of
a bloomii%g mill (B) by comparing regimes for rolling 6.9-t steel
ingots in 13 and 11 passes. The results serve as reference material
for dynamic stress analyses relating the more intensive B rolling
operations. The analytical and experimental investigations include
derivation of the magnitudes of the static, motive, and dynamic
moments at different phases of the passage of the metal (Me) through
the rolls. The static and motive moments in the period of Me contact
display a linear change and may be deemed constant when a steady-
Card 1/2 state process is in progress. The dynamic moments are investigated

SOV/1 37-58-11-22369
An Investigation of Dynamic Processes in the Live Train (cont. )
by means of the equation for the moment of the elastic forces of the spindle induced
by the inertia of the flywheel masses in the live train of the mill during the contact
phase and the steady rollin& process. The effect of the law governing the increase
in and the value of the moment of resistance during contact upon change in the
dynamics of the process is demonstrated. Dynamic phenomena are virtually equal
upon rolling in 13 and in I I passes. The fluctuations in the torque moments
induced by the elasticity of the system do not exceed 3%o of the static load.
V. 1.
Card 2/2

GOMSHOM, IK.K*, kav4.t*khn.a&uk; KIRILUW* B.S., kand.takhn.nauk;
TrACHIM. T.K., insh.; Q.Ojg3jMp A.I., irsh.; POGORMILISMY,
V.I., inzho.; IMRAIWS, P.D., --rj-isF.--,TJMC Z.A., insh.:
FIZICLUM, V.A., insh.
Betablishing the moot satisfactory conditions for rolling on
b1ooming mills with increased load on the main driving motor.
IzV* vy** uohmbo save; chern. "to no.3:91-101 Mr 158.
(XM 11:5)
14hdanovskiy setalIvrgicheskLy institut i savod wAsovetal'".
(Rolling mills-XMectric dLriving)

3/l)7/6CA=/0C9/'005/029
A006/A001
Tranalation frorml Rerarativrw 2hurnalo Me-al:urgiya. 196c~ 9. T. io'-)~
# '20243
AUTHORS: K1.1,1110V4 B.6., Gorenshteyn, M.M., Goll:venkc, A.:, lkachenkvc. V K
TITLE: Woulatlon of the Multi-Purpose Spindle of a Polling Mill
- 11
PERIODICAL: 8b. nauchn. tre Zhdanovsk. metallurg, In..t.. 1960, No. 5~, pT. 372-
381
TMU - A comparison is made of the existing vrethds fcr r-alcuiating mul.,,-,
purpcse spindles of a rolling mill. The magnitudes :;f error when using cre or
the other method ivere rei,ealed. As a result. of 11,e _0-.idy '_-~ was estatliah-_d :hEL-.
t-he discrepancy betweon the theoret-Ical caicullati~ins , --f a f.-rk al.1 ex.
perimental data is explained by the inaccurate a::-_,-an*.-'.ng f-. te -wlls~lng stress.
Aj, Tselikov recommends to use the method of the strength of materials applied tz
the Siven caaoi when calculating bore rc.lls. When zal_-allating the b-,q'ies zf a roil
new coeff�,~ienta are introduced which can be ILSI.~i as % ba.~is of aprroximate cal-
~culaticns. K.U.
Tranal tor's note- This Is th- full translatLon of th.- original Rjzs!ar abstract,
Card IN

z
_Z
S/137/62/000/002/060/14,4
A006/A101
AUTHOW 3: Kmptistin&, M. I., Kuzema, 1. D., SavchenRo, A. M., Shiryayev, V. I.,
Goltvenko, A. I., Grishina, Ye. N.
TUTLF,-: A rapid mtbthod of calculating the efficiency of three-high sheet
rolling rills
PERIODICAL: Referativrin, zhurnal, Metallurgiya, no. 2, 19~')2, 18, abstract 2D86
("Sb,nauchn. tr. Zhdanovsk. metallurg. in-t", 1960, no. 6, 186 - 198)
TFXT: Calculatlon data were checked by the oscillographic timing of a mill
operation for all the br:Lgades when rolling the main conventional sheet types of
the mill assortments. A method was developed for calculating the efficiency of
three-hig;h mills on the Nisis of i3ai analysis of reduction ccnditions, and force
and power indicos of rolling. The theoretical calcii1ation of the efficiency of
sheet rolling m,111s im given. The problem is discussi-d how to check, the mill
amount of work.
rAN,itractPrIs note: Conplete translation]
L
N. Yudtn,-
Card 1/1

ROMANOT, D., h:swA.t*kta.n&uk; 90
_:k FITSA, K., inzb.
Using piliso with pedestals formed by blasting in sagging loose
*oil*. Stvoloi arkbit. 8 no,6S31-32 Je '60.
(KBA 13 16)
(YAlporoublye-Filing (Civil engineering))

BIVCEWG, I., inzb,; GOLTVXO EsoltroianytAia, X.], insh.;
BMAIROV, HO x LI-12~
E lb xWen 0 M. , insh. I SHAM=, T., izzh.
T r. K. , I
IM* of themal cutters for working granites. Radmt.i konstr.
4 xio.601-53 " 162. (MnA 1502
(Mrsoutting-Equipment and supplies)

lash. I MLWKO, V.0. I Insh.
R**f insulator made of local raw materials. Stroi.mat. 7 no.WS-29
7 161. (MM 24:3)
(BDofing) (Insulation(Heat))

3(8) PHASE I BOOK EXPLOITATION SOV/2268
Glavnaya geofizicheskays observatoriya
Voprosy fkziki atmosfery (Rrobl*ms in Physics of the Atmosphere) Leningrad,
Gidrometeoizdat, 1959. 74 p. (Seriest Itst Trudy, vyp. 82) Errata
slip inserted. 1,250 cooles printed.
Sponsoring Agencyt Glaynoye upravleniye gidrometeorologicheskoy sluzhby pri
Sovete Ministrov SSSR.
Ed. (Title page)s N. S. Shishkin, Doctor of Physical and Mathematical
Scienceal Ed. (Inside book)i T. V. Ushakoval Tech. Ed.: M. I. Braynina.
PURPOSEs This is,sus of the Observatory's Transactions is intended for students
aba, Witbore - 0:rf'WYb0tptW;1*eteorology as vell as for professionals :in the
field.
COVERAGE: This collection of articles is mainly concerned with the results
of investigations on the physics of the atmosphere carried out in 1956-57
at the OW, Division for the Physics of Free Atmosphere. The authors
discuss the dwvelopment (formation) and disintogratton of convective clouds
Card 1/3

Problems in Physics (Cont.)
SOV/2268
and the relationship between the cloud structure and aircraft icing. A
now method of affecting supercooled clouds is described. One article
is devoted to an analysis of the frontal structure of anticyclones.
References accompany each article.
TABLE OF 0014TENTSs
Shishkin, N. S. Growth and Disintegration ,Uispersion7 of convective Clouds
During lion-stable Stratification of this Atmosphere 3
Vasillchenkop I. V, Computation of the Characteristics of Convective
Cloud Flow 22
Zavarina, It. V. Phase Structure of Clouds and Aircraft Icing 26
The article analyzes the results of observations mad* at Shossaynaya
near Leningrad and at Arkhangol'sk for the purpose of establishing the
effect of matec"lo'gical conditions on aircraft icing. The probability
of icing as a functLon of cloud forms is presented in several graphs.
Card 2/3

Problems in Physics, (Cont.)
SOV/2268
Golf
-~YAkp-v, H. F., and P. N. Krasikov. Investigation of the Effect
of Magne11UHV7Ant1monid& on tht Formation of Ice Particles in
Supercooled Water Fog 36
Krasikov, P. N., and G. A. Chikirova. Effect of Ammonium Chloride
Admixture on the Stability of Water Fogs 41
Pr-.renchuk, 0. p. Frontal Structure of Anticyclones 45
Sal'man, Ye. M. Methods of Rader Exploration of Cumulus Clouds 68
AVAILABLEt Library of Congress
Card 3/3 MM/lsb
10-9-59

NUM", H.8w; MUU3v A.S., s.x.
GKIdatlon (W n-butane In the gaseous phase under pressure. gas. pros.
no.1006-4.3 0 158. (KIM llsll)
(IMtam) (Ozidation)

ACCEMON NIL: AT4033630 8/0000/63/000/000/0007/0017
AM014 FuMPA, X. S. (00aWr of ObOM1061 Ww") I TAVIN, V. V. I V1WSrM4kk%
bt. V.; Golltya"Val N. A.
TITLE: Uquid pbaso oxidation of cyclohexane by atmospheric air at high temperatures
SOURCE: Poluproduldy*dlya sinteza poliamidov (Intermediates for PDlyaMide "U-
tboals). Moscow, Gooldilmizdat, 190, 7-17
TOPIC TAGS: cyclacmane, cyclobexanol, cycloheranone, cyclohexane --vidation.
liquid phase oxidation, cyclobexane air oxidation, high temperature cyclohexane
oxidation, cyclobex=e oxidation Wnetics
ABSTRACT: Tbe Idiietics of the liquid phase air oxidation of cyclohexane were studied
In the absence of catalysts at temperatures of 160, 170 and 180C and pressures of 20.
35 and 50 at3m. It was established that high temperature oxidation is of practical in-
terest when the reactiom lasts lose than one bour. The ratio of cyclohexanol to cyclo-i
heoumone, resulting from the o;ddation of cyclohexane, increases the temperature rises.
The specifla activation energy of the reaction was 3. 5 to 5. 6 kcal/mol at pressures 6f
20 to 50 atm. 03ddo0olL at ** India" temperatures ocic~urs in the diffusi(m area, L e.
cam 1/2

ACCEMON HR. AT4033630
the rate of oxidallon Is not governed by the rate at which the reacUon proceeds, but is
dibterroAned by the rat* of oxygen absorption in the cyclchwme. "The analyses were
cozried out by L G. SolovIyova, by a method &YvelopW In the analytical. laboratory of
GIAP. It Orig. art. bu: 9 piq" and 2 tables.
ASSOCIATIONt None'
DATE AOQ- 06APrG4 ENCU 00
SLTSM=ED: 120U113
BUD CODE: OR NO REP SOVI 016 OTHER: 007
2/2
cam

LIFFS$ V.V.; IA;UXrSEVA, L.K.; GOLITYATEVA, N.A-.; FURMAX, M.S.
Analyzing the composition of acids forming during the liquid-
phase cx~dation of cyclohexane by air oxygen. Khim. prom.
40 no.9A56"71 S 164. (MIRA 1711l)

,GOL#rZWN, T.Klh.. insh.
Constructing hydraulic atructiwas without building cofferdams.
Uet.i shal.-bet. no.l.-23-27 JS 160. ()aPJ- 13:5)
(Hydroelectric power stations)
(Piling (Civil engin"ring))

GOUI, M.
-11,
"Principles of experimental psychology." Vop. psikhol. 10
no.2s177-180 Mr-AP 164o (MM 17t9)

BALAMqcU, 10,; 11,11CII, I.; PUFAN, C.; POPH.XI), I.. ' .0LU, M.; (;AZiNG'.-I'
A.; CCJNSTAIJT11;t,~-V:, P.
Contributis.vis to the study, of I.Ye world of the young generation.
Rov pathologie 11 no.10-21 165.
1. Miair of Psycholoa of -.he University c;f -Ucnare&-,. Sub-
mitted August U, 1964.

"f MW
MDar t Pyrethrum, A.
Prepar, t1on f om V. T.
-Miliss-kogo
Ya. m*idti~p and G. 1 5 rnfFtrua
kkn-Sa Mg--
US-2 e I - a DA&-=tQMM'tsevticheshM Instituta
1955, V*1 To VIP, 123-132 :ftom ftjer~ti= Zhurnal--Khimiya, No 4,
Feb 57 Abstract go 1240h by A. Grapov)
"Describes extraction of oleoresin (1) from dry flowers of Dalmati"'.;
sles. with abhyd us dichloroethane (11) by boiling and at room temp-
ure. dalcium tlorltle (III), placed in a stream of boiling (1), de- :1,
Uses the activity of (1). Copper sulfate (CS) and Tikha-Askan clev
*
Incredne the ilctlylty of (1). An insecticidal dust is also fox
'Ocre""
T
(U). Ireathoput with isoWl alcohol or methanol (IV) in the pre
E~(C4S)Itqld to a 4ecrease in: the activity- of (1); and (rv) in the pre::*-,
AnA
fte,,,Fe lightened with basic

,'I, J:rui,: ;Jivx-Diol., Yo 27, 1~58, 930,23 -
'It*r!c~r Goltib, P.CX-xL.-l' YLZhI.-3v:-'-' D.
Ti-, 1L of I.-Lion yolul~ I -' 's
Oi**iG 1"Wo: Za cm,s. 1958, AT, 17c 1, 73-,1,2.
-b ss i; r--. c t 02 i,,i 14 yuanL: p-'-cs ~ms b'w- th,
I.roc -:ctliod frai thc d--y of -.hcir b--'r-~'-h tn the %C,.;
of !~ rickitli. Up to t*,,; ar)~! n-- ' 6 dayr th;.~ -ilz; did
i.A xmct to a lowrlir of UW tcnpcra~'-uru 3: th---
frui Z-, + I do~,Tuu. to 3 1
y , r
nd..Ilt-S L, ~l r
L.Urc f,~:'Ll. 1.6 71ic 02 t"
L/2

KONOPLYOTSEN, A.A. ; SEVENOV, S.M.; GOWBI , A.G.; JUIU~TWYEW, S.S.
'.Hog.1ona.lization of the northern slope of the Trans-Ili Alatau
and the alluvisl Ili Depression adjacent to it according to
the character:gstice of the regime of ground waters. Trudy
no.10:139-151 164.
(MIRA 17: 10)
1. '1sescTu=yy nauelmo-issledovatellskiy institut gidrogeologii
i inEhememoy geologii.

QOW,4~ r&.,;.4 VORMSKIT. le.l.; IjYAM. A.Ye., spetered.; TIAMA INA. G.Be,
"r64 -. YARN. B*M.. tekhn. red.
[Adyawnd qoratlat "thodu for wrappiug meblues] Peredovys
metody rAo%:r us sa"Ay"dushchM mashitakh, Moskva, Pishohm-
pramUdat, 1956. 29 P. (Wapping vachines) WU 110)

GOLUB, A. 1.
S~wlwordzatdon of hAding in yeadto TSitologiia 3 no-4:481-484
A-Aig 161, (RIR& 1418)
1. Otdol biafiWd Imtituta b:L*Iogii Urallskogo filiaU AN SWR,
Svwdlav k
MAST) (OZLL DIVISION (BIOLOGY))
(TIWERATURE.PHYSIOLOOICAL EFFEGT)

HDRI. P~,Lwj GQ~tW. A . OMMMSEWN.P.M.; LOMOVSKIT, D.P.
A*tomati*#Uy, eantrolled sicip leadors. Opeupory 25 no.10:448-452
160. (Hnk 13:10)
L Milcitoveldy clolowita" kowaluat (for Motik). 2. Ukrenergocherset
(for Golub'. Grateershtern, lobkovakiy).
CIIAOMIte) (loading and unloading)
(Antos&tto oontrol)

GPOLUBI p A.X.; ZAYISIV, A.I.
botrurnent fbr precis* =mu=e=mnt,,oJ' machine-shaft speeds.
h-lbarostrosaie no.12t27 D 161. (MIM 14:12)
(Tachometer)

UM&V, A,X,, kmbdL,4tmkhnra*j OOLUBI A.I. GOIMMIR, A.A.
H~&amlio romoval of oUt hrtu nechoploal self-cleaning filters.
Rnmrg, i *1014trotekhe FrCoo rweli6lp-64 0629 (HIRA 15:6)
1. Ma-enoo.-Soobsruet. (Air filters)

4NOTKOV, A.M.; BMZREV, V.S.1 TMOVSKIY# A.Ye.; BUTENKO, V.A.; GOLUB, A.I.;
DUDAVSKIY, I.Ye.; KOIXSNIX, X.I.; SOKOLOV, I.N.; MASLOV,
Increasin$ the stability of arches and walls of large-capacity
steel-smelting electric furnaces at the "Dneproopetsatal" Plant.
Stall 23 no.3t222-224 Mr 163. (MIRA 16:5)
14 7Avod "Neprospetestall", Zaporoshakiy savod ogneuporov i
Proymktny7 institut i inspektaiya po slushbe i kachestvu
opouporov, (Electric furuaces-Design and construction)
(7APproshlys-Iron and steel plants)

Lu U,
USSR/ChOnical Te,:kmology - ChomIcal Products and Their Application. Treatment of
Solid Mlneral Fuels, 1-12
A~st Journal: Ftefe3mt 2anLr - KhImlya, No 19, 1956, 62536
Author: Gartman, DI. V., Golub J, A. 1.
Inatitution: Noine
Title: Catalytic QKidation of Phenanthreme and of' Anthracene Fractions.
Conmunication 1
Original
FerickIlcal: Zb. prikl. khimii, 1955, 28, No 5, 507-515
Abstract: Phmnaxithrene (1) and anthracene fractions were oxidized for the
purpome o:V producing phthalic anhydride (32). The catalyst vas
fusecl vanadium pentoxide. Optimal operating conditions vere de-
temWed by vapor phone oxidation of pure naphthalene. At IV600,
curitact %Um -2 seconds and ratio of air to vaporized substance
-1,5 I./g rield of acidic products recomputed as II was 91% or 70
of theory. On oxidation of pure I optimal temperature 44,B-"90,
air to I ratio (1/g) 20:1, contact time 4-6 seconds. Yield of
Ca:rd 1/2

UMB/Chamical Tectmolo" - Chemical Products and Their Application. Treatment of
Solid IUZWal FWls, 1-12
Abet JDurnall Reif erat 2aiur - KbImiyas -110 .19, - 1W, 62536
Abstract: acifte products recompa ed as 11, 69.8-71.9%. Acidic products
consist on the average of 86% n and 14% maleic anhydride (3:11).
Ott axidati** of redistilled, washed anthmeene fraction, boiling
ranse 310'.3450, yield of acidic products an the basis of I is
3-32-22% of vkdch 78-90% is II amd the remainder III. In addition
tbera are obtained 62.7% anthraquinone on the basis of theoretically
calculated anount of anthracene present in the fraction. By boiling
w-Ith 5% al)MI1 and sublimation an anthraquinone MP 2860 is obtained
which doeo not depress the malting point of pure synthetic anthra-
quinove and has identical other characteristics with the latter.
Yield of "idic products an catalytic oxidation of unwashed first
Whracwie fraction is 287-51$ of the theoretically calculated on
the -~Iisis of the phanantbremej 188.14% of these are 11 and the re-
maindc- Irl. Mn addition there is obtained a 42.54% yield of antbra-
qidnomv an the basis of the antbracene. Large yield of acidic
priduc's cm oxidation of antbracene fractions, exceeding greatly
their yield from pure I confirms the propostion concerning the ad-
viwtvges of corqposite utilization of a number of compounds in mix-
tur-4.vj for the purpose of obtaining the same product.
Caril 2/2

go / C~ , -IZ- -
GOMI, H.V.1 GOYA% A.I.
Catalytic oxidation of basic POIYOYclic *OmPOUnds Of coal tar and
some of its fractions. Zhur.prikl.khim. 29 no.8tl256-1265 Ag 156.
(min 10:10)
1.Voutoch3*7 asuchno-iseledovatellskiy-uglekhimichooki3r institut.
(Oxidation) (Coal tar) (Phthalto anWdride)

AUTHOR: 69-59-7-13/27
TITLE: Catalytic Vapour Phase Oxidation of I'llaphthalene and
Haphth!i,lene Fraction (Kata lit iche szkoye parofaznoye
olrisleniye naftalina i naftalinovoy fraktsi-J)
PERIODICU: Koks i Milmiya, 1958, Nr ?, pp 44-4? (USSR)
ABSTRACT: As tho catalytic oxidation of pressed naphthalene and
naphtbalene fraction waj not tested on Soviet works,
while the former process has been successfully operated
for mmay years abroad and the latter process for a few
years in Sweden? an experimental oxidation of pressed
na.T.,hthalene usiaG Soviet catalyst (used for the
oxidation of crystalline iiaphthalene) i,.ras carried out.
The -'-'-oz-k was considered as a preli~ainary staCe for the
industrial experiments on the oxidation of naphthalene
fraction. The results obtained indicated that no
difficulties in oxidation of pressed naphthalene should
arise. The yield obtained was ?6% of phthalic and 5% of
maleic anhydride (of the -theoretical). For furth-er
investl~~ations of the oxidation of various individual
compounds and technical products derived from tar, a
lar-er- ilot plant was desi6ned of a throughput of 8 k8/day
Card 1/2 (Pie'~'urX Crystalline and pressed naphthal,-~ne and

Catalytic Va-pour Phase Oxidation of Haphth--:Iene and Naphthalene
Fraction
naphthalene fraotion rare successfully oxidised on this
plaat viLh. a ?0% viold of technical anhydride, i.e. -i;ith
a yield about 10% lower than on indu trial 1~jits (the
rel.oulLs obtained are assembled in thLs' tr-ble~-
Therc are 1 table. I figure and 7 reference-c~, 6 of which
are Soviet, 1 German.
ASSOCIATION: VUKh]21
-I. Napkithalenes-Oxida t Ion 2. Catalysis--Appli,2ations
Card 2/2

--arl. teklin. m,,ilz;
JISCI, Of vlrlall~,
no.
u.

ro)WBI t All:..t -lin2li.
Mechwiization of the horizontal turn of a trans book. Mashino-
stramie no.6e99-IOO N-D 164 (MIFU 18,--Z)

GMUB. A.K.
Origination of chamistrr as a science. Ukr.khlm.shur. 20 no.3:325-
334 154. (KLVA 7: 8)
1. Xljr6vskl)t go"arstvenW univerattat im. T.G.Shavehanko.
(Chemistry-Sistory)

IV41
USSR/ Imorganic Cbemistry. Complex Compounds C.
Abe Jour : fieferat 2hur - Xhiziya, No 4, 11"
Author : Golub A.M.
Title :~~OC*ZaWical Study of Complex Silver Thio-yamt-s
Orig Pub : Zh. obahch. khimil, 1956, 26, No 7, 1.837-1848
Abstract : Potettiomtrically and by the method of solubility in aqueous and anhy-
drous solvents has been ascertained the predominant for=tion within the
regidn of medium and highs CW ebneentrations of the complex ( ~i_
hav"g the diss6cilltion constant 2.86 . 10 11 at 200, 3.56 . 1!ffo
400 and 5-36 . lo-!? at 6&, and a heat of formationnJ 25.5 kcal at 20-600.
Equilibrium constant has been calculated for the reaction AgCRS(s,4ij) +
n CM = Ag(=),nu_- in vater and acetone solutions (nPAn value ()", 1 5 and
the solubility ra-oluct of Ag= in aqueous solutions (4.14 . 10-12- ), it
is shown that in acetone solution, in contradistinction to an aqueous,
there Is formed Ag(CSB)i. 'A molecular compound XCW.Ag0S.3(CHj)gC0 has
been isolated. The conclusion is reached that complex-formatio2i exerci-
ses greater Influence on mLgaitude of eqL*dlibrium electrode potential than
nature of savant.
G_
USSR/ i4a 44istry, Thermadynamics, TherTiochomistry, PI-6
EquLlibriuras, PhYs-Mm' Anal-is) PhASO-TrAnSitions.
AbB Jour : Pkf Zhur - Khizdya) Uo 7, 1957, 22331.
Luthor : A. ?,. Go1iib, 0. H. Kilimnik.
Tnst : 17 --- 11

c---( c, i, L' 1~ , R, m -
(W.XM,, A,li.', Blum. 0.-0.
41':w "
It"stleating the thtooranate complexes of cadmium. Report No,j;
Vnv. neore.'Wo. 2 no.M2723-2733 D 157. (NM Ila)
II Itlyevelki:r ComWaristvennyy univernitst Ia. T.0. Sheychenlro I labo-
nutoroa imargaulaheskoy klilill.
(Cadmium thiocyanate)

6-7-t) ~-Vb) A.M ~
-0019 ",",[HolUb, A.M.]
Devs1optMMt Of chwistrY Of solutions. Nauk.xap.4ivaln. 16
uo.15'.13-29 '57. WRA nal)
(Solution (Chemistry))
I
ff
11 11/I -.

GOLUI, A.R. CHOI*b, A.X.1; TSIT=nTA, T.I. [TSybgw7Us,, T.I.]
Plarcurv xtodanine complexes. JF&nk.sap.kjv.un. 16 no.15-'101-107
15?- (KrRA 11:3a)
(Xoroury organic coupounds) (Abodanine) (Complex compounds)
A
f

C-1 L t i f 3 , Ai J "')
APINOA: Golub, it, 14. and Saacy,Lonko, V. F.. 73-1-4/26
TITLO 2or=tion of the Simplest
Zbiocyanate Complexes of Lead. !.
,J,oziplexes. (RodanidnyysKompleksy Svintza. I. Obrazovaniye
Prosteyshilch Kompleksov.)
PAiiIODIOAL-. Ulaainskiy MiizicheskiZ? ~*hurnal, 1957, Vol.23, No.1,
pp - 17 - 21 (USSIZ).
AB8TiiAO"2,- ':.Ihiocy~wate compounds reseiable halides in a~_,,-.y ways, but
can be iawstibated only with difficl'ilty, in "';.'aich ~~anse
the7 differ from lead halide comulexe_-. 2h!~ simoler
th1oc:ja=-Lte complexes quoted in litcru-~uie incluae Pb(CirS),,,
Pb(OS)GI axd Pb((;NS)Br (viz. (1),: Herty, ~,. IL., alli C_
Bog6o, il. R; J. Am. Ohem. Soc. 18Q?, Vol. 10, 820.) It can
be that com
plex 6roups consistin- of thiocyanate ions
and lead ions musb be fomed in the ru Zio 1:1, 2:1, etc. as
was shova by Golub,, A, U. (Naukovi, Zapittkci KD'-,', Llilr&.
Z,binAkj No.6, Vol.70,V55). Invesil-igations were carried
out In tba systems Pb -, V"NS- -H 0 E=eriments were car-
ried out now in limits of cone en~r~tions of CITS-ions from
0.00548 to C;.1161-mol potentiometrically and spectrophoto-
uletricall~r..' The exi . _~ie complex 6roups Pb(CIIS),
and PWIWS)~,- was =11,8111MOW-' llaeasurino the optical
~~kj 1). '.~Jjf$ 1 2Z~aa,]. Pb(OUS) ';zoups wore
cerd. 1/2 2

Thiocyanate Gomplexas of IAaLd.I: Foruation of the SimpleR- 1-4/26
GDaplexes.
revealed by potentiometrie measurement; these exist in
rvgioas of low concentrations. Dissociation constants
of these complexes were calculated and are tabulated in
table I# The heat efftot of reactions during the formation
of tho complexes VbCNS at temperalZures between 20 - 40' 0.
ave evaluated and tabulBted (at 40"' C)(table 2.) At
higher temperatures (40 0) t4e PbQNS* complex prevailed.
Higher temperatures (up to 60 C) cause disintegration.
Tbere are 2 tables, 3 sTaPhs, 5 references, 3 of which are
Slavic,
SUBMITTEDs Apelr#" 300 1956.
ASSOCIATIM: XUw State University, imeni T. G. Shevchenko.
(Kiyevskiy Gosudarst-veanjyUniversitet im. T.G. Shevchenko.)
AVAIL&BLW-. Ltbr=7 of Congress
Card 2/2

.jw -und.khI=IcbzWkh nauk; DMIMK,
ey V
OOLUB Andr 4,1~r
akovISTIOb LDW07k, S.IA]; PILIPXM, A.T., red.
[Rar* and dispersed elements and their importance in the national
eeonovO Rtakient I rovoliani elousitty ta ikb snachennts. v narodnomu
hospodaretvi. Ryiv, 1956. 43 p. (Toyaryetvo dlia, poshyrepula poli-
tychlWkb I naukMkh suan' Ukrainalkol RSR. Ser. 4. no.10).
(Chemical elements) (MRA 12t2)

ATJ THOR: Gol:ub~ A. M. S07/156-58-4-18/'49
TITLE: ThO Formation of Selenocyanate Complexes of Silver With
Higher Coordination Number in the Solution (Obrazovaniye
s1?3enotsiana,tnykh kompleksov serebra vysshey koordinatBii v
rastvore)
PERIODICAL: Namchnyye doklady vysshey shkoly. Khimiya i khimicheskaya
t*khnologiya, 1958, Nr 41 pp 685-689 (USSR)
ABSTRACT: B.T the potentiometric method the formation of the seleno-
cyanate complex of silver in aqueous 80luiions within the range
of medium concentrations (0.3-1.5 mol/l KCNSe) was investi- 2
gated. Under such conditions mainly the complex [Ag(CNSe)
is formed. In mixed aqueous acetone solutions (6-7 mol/1
acetone) the complex [Ag(CNSe)4]3- is easily formed. Salts in
crystalline state with the following anions were produced:
EAf,(CNSeQ_, [Ag(CNSe) 3j 2- and [Ag(Me)4~3_. New salts of

Card 1.12 the silver selenocyanate complex were iso ated with potassium:
KAF, (ClrSe)21 KAg 2(CHSe)39 K2Ag(CNSe )3' K,Ag(CN3e )4 . The 3alt

SOV/156-58-4-18/49
The Formation of'Selenvoyanate Complexes of Silver With Higher Coordination
Number In the Sol-atlon
KAK~(Cxse) is decomposed on heating without melting. On heatJng
3
is converted
above 40000 the compound KA92(CNSe)3
KAe(C3Se)2 . The salt K3j`g (CNSe )4 was isolated in slow crystal-
lia&tion in the vacuum exsiceator on P205 in the form of color-
lems cz7stalse This salt can also be produced from acetone
solutions by miring AgCNSe and KCNSe at a ratio of 1:3. It was
zonfirmed thal. in working with solvents more active than water
the coordination number of the complexes increases.
There are 4 figures and 6 references, 5 of which are Soviet.
LBSOCIATI011 - Kafedra noorganicheakoy khimii Kiyevskogo gosudarstvennogo
univarsiteta im. T. 0. Shevehonko (Chair of Inorganic Chemistry
at the KJ.yev State University imeni T. G. Shevchenko)
SUBMITTED: lfarch 10, 1958
Card 2/2

5(2)
AUTHORs Golub, A. X. SOV/153-58-6-3/22
TITLE: On Nomenclature in Inorganic Chemistry (0 nomenklature v
neorgthnicheskoy khimii)
PERIODICALs Izvestiya vysshikh uchebnykh zaveden-Jy. Khimiya i
khimicheskaya tekhnologiya, 1958, Nr 65 pp 14-19 (USSR)
ABSTRACT: The prDblem mentioned in the title is among the most burning
once in theoretical. chemistrv. Major reforms In the field of
chemistry have always been accompanied by a new classification
of sabstances and by a change in tLe bases of nomenclature. As
chenistry is an international scienre, 144 is only natural that
its language should not be removed from the science itself"
and that it should not lose contact with the principles that
have been established thert!in with regard to definitions. Ir- the
drawing up of a national noman~llature care must te taken to
avoid isolationism. The achievements cf international science
must not be pushed aside in so important a matter as is that of
nomenclature. At the same time, however, the national nomenclatre
aliso has to take account of the pe -uliarities of the national
language. It is necessary that the term for any given substance
Card 1/3 should readily illustrate both "he composition and the naturr-

On. Nozenclaturs in Inorganic Chemistry SOV/153-58-6-3/22
of the substance concerned. The Russian nomenclature in
inorganic chemistry, as it is used today, in many respects
falls short of these requirements. Whereas, in the thirties
efforts were being made (Ref 2) to adjust the Russian nomenclatum
to the international one, there has of late been an increasing
tendency to revert to 19th century Russian nomenclature, which,
in fact, is nothing but a slightly modified German system.
However, international nomenclature is not entirely flawless
either (Refs 4-6, 17). In the paper under consideration the
author restricts himself to a treatment of the acids, salts,
and complex compounds, as the other substances have beer, dealt
with an a previous occasion (Ref 6). The rest of the paper is
subdivided as folloves acids and saltst terminology of the
acid-, basic-, and thio-saltsl com;lex and molecular compounds;
terminology of compounds with a complex anion, compounds with a
complex cation, molecular compounds with an unusual element
valaricy, and finally double salts and double complexes.
Numerous examples of obscure or confusing terms are quoted in
respect of all the categories enumerated, and in many cases
improvements are sugFested. There are 22 references, 16 of
Caxd 2/3 which are Soviet.

On Nomenclature in Inorganic Chemistry SOV/153-58-6-3/22
ASSOCIATIONs Kiyevskiy gosudarstvennyy universitat imeni T. G. Shevchenko,
Kafedra neorganicheakey khimii (Kiyev State University
imeni T. G. Shevchenko, Ch&ir of Inorganic Chemistry)
S'U DR I T TED iSeptember 17, 1957
Card 3/3

AUTHORSt _GoiP-h4_&t_A. Ivancbenkc, G.
TITLEt 1. Investigation of the Zinc-Tbiocyanate Complex in a Solution
I (I. Izucbeniye rodanidnykh komplekeov tainka v rastvore)
PZRIODICAM Zhurnal Ileorganicheakoy Khimii, 1956, Vol-3, Nr 2, p:1.333-338
(USSR)
A,-STRACTs A suitable method for the production of Zn(CNS) was worked
out and imvestigations of its property were performed. Zinc-
thLoayanate has the following compositions Zn - 36,01 1%,
CNS - 63,99 ~*. Zinc-thiooyanate is easily soluble in water
and the aolubility increases with increasing temperature. In
benzene and dioxane it is insoluble. In acetone and absolute
alcohol it in littlf soluble (0,8 mol/1). In a temperattwe
interval of 210-225uC Zn(CNS)2 melts with the beginning of
doootaposItion. By thedeterminition of the electric conducti-
vity of the mixture KCNS-Zn(CNB)2 in alcoholic eolutions the
assumption is expressed that the complex K[Zn(CNS)j is pre-
Card 1/2 sent here. The investigations i+queous solutions flake a

78-2-13/43
Investigation of the Zinc-Thiocyanate Complex in a Solution
negative course, as the zino-thiocyanate complex is unstable.
Por investigationscf the system KCHS-Zn(CNS) in acetone so-
lutions ison'ola in itia4 solutions of 0,2 mol/l were used.
The complex K Zn(CNS)A is determined in an acetone solu-
tion by the dirzerminat n of electric conductivity. The ooin-
plex-solutiona were also investigated by potentiometric meth-
ods. Asindicator-electrode the authors used zinc-amalgam
opposite a saturated calomel-electrode. The results in
aqueous soluttons, showed the prosInce of the folIowing com-
ploxess ZnCNSr, Zn(CNS) Zn(CNS) - and Zn(C S) - The dis-
sociation constants of ih'ese four complexes as iell* as the
thermal effect in the formation of the Zn(CNS)2- complex in
the solution, which amounts to 5,7 cal, were also determined.
There are 3 figures, 5 tables, and 15 references 7 of which
are Slavlo.
SUIVITTEDs December 30, 1956
AVAILABLEs Library of Congress
Card 2/2

GOUM, A-M- 010401IT-4,.M.M. kaind.ktdm.nauk: KRAMARMT, N.A.
Solonlum. Wauka I shyttia 8 w.10:13-15 '5R. (MIRA 13-4)
(selenium)

~ rX., , , ' '
GOLUB,,,~
1,~ ,
%wainkan teradnology mad nosenclatmv in inorganic chemistry.
Ulm% kh1u. shur. 24 no.1:118-129 158. (MIRA 11:4)
I.Kiyovskly peudarstvennyy univervitet In. T.G. Shevohenko.
(Ukrains-Chattistrr, Inorganic--Terminology)

AUTHOR: Golub, A* 11. SOVI 20-12o-6-25/59
TITLE: The Influence of the SolVent on the Coordination Interaction
and the 7ffect of the "Negative Complex Formation"
(Vliyunlyo raotvoritelya na koordinatsionnoye vzaimodoystviye
I effokt "otrituattflInogo kompleksoobrav.,ovan-yall)
PERIODICAL: Poklady Akademii nauk SS3R, 1958, Vol, 12a, Nr 6# pr*1255-1258
euo i; I
ABSTRAC?i As it was proved earlier (Ref 1) the character of the complex*
f=nution In the presence of medium cincentrations of sol-
vente such us ulcohol# acetone, and dioxans remains unchanged
in aqueous systems as well no in pure aqueous solutions.
Higher concentrations, however, may considerably reduce the
rattetion of corplex formation (Ref 2). In order to explain
this latter influence the authors studied the system
~'d2+ _ CH _ H 0 dioxane potentiometricallyg Before investi-
Ratinr the a0lations it was found that cadmium nitrate and
cadrium perchlorate are Pasily soluble in dioxane. Therefore,
It could be expcct-~d that ordmium ions form complexes with
Card 1/3 dioxane In the presence of ruter. This, however, will probably

:3-al 2o-12o-6-25/59
,The Intl4onoe of, the '.11olvelit on the Coordination Interaction and the ---'ffect
of the PornAtion"
not,41sturb the determination of the composition of cadmium
thlocyanato~oomplexes. On Tablm I the values of the die-
a" 'lation of the complezea Lae given which dominate in a
Meltaln. rnngo of concentration of the complex former. As can
be:,~~Sleon from Table 1 and Pig I the complex Cd(CNS)- appears
alkeady at 2~,5 mols of dioxano# i.e.lmore easily thn, in
atiiiisops solutions Yoreover, a complicated complex Cd(CHS)
iLo',bboerved'in-a mixed solution with 2~5 mols of dioxane.4
Ift;Ithe case of sti'll higher di9xans concentrations (Tables
2,3)~aloo the complex Cd(CM;)'4_ was observed. Thus, the
introduction of dioxane extendg# so to speck, the possibili-
ties 6f the coordination of cadmium. ist first sight this
WOXIU~be co0radiatory to the formation of molecular com-
pcru'~ft~di of diozan* and cadmium salts. In order to find a de-
finile solution:of this problem the author aiso carried out
pot0hitionetric measurements in the system Cd t- H 0 - Dy
11 2
(whaxie-Dy denotes dioxeme)b The results are given on Table 4.
InatesA of the expeoted. reduction of tne values of the elec-
trode potentials a slight increkse, could be noticed. From
Card 2/3 this follows that no complex groups of cadmium with dioxane

Oum , Andrev. lub, A.K.j,tMM=o, N.I. kand.kUm.
.: S# We P*D.j red#; BALTASNA, b.Te. (Baliasna,
re
:PGd.: MALAo 0.0., tokhu.red.
[Methods of classification and terminology in inorganic chemistry)
*ptomatylm i larminaloglia v neorganichaii khImil. Xylv Tyd-vo
rqivalkobo %mly., 1959. 147 p. (kRA 13:1)
(Chemistry, Inorganiu-Nowncisture)

GOLUBI. AA [Holubo A.H.)
laveist4jAion of metal perchlorates, Viarqk Xyiv.un.noo2&S*r-fizt&,
kid%4 nool:105-107 159. (KU 14ta)
(Perahlorstes)

SA'N'0/000/004/002/008
A166/A129
AVTHOR: Golub, A. M.
TIME: iestlgation into metal perchlorates. The preparation of anhydrous
perchlorates of heavy metals
PERIODICAL: Referatii7,,yy zhurnal. Kh1mIya, 1960, no. 4, 109, abstract 12877.
(Visnyk Kyyivstk. un-tu, 1959, no. 2, ser. fiz. ta khimiyi, no. 1,
105 - IVI)
MT: For theoretical consideratior-s a new metbod of obtaining anhydrous
per~,,hloretes (and nitrates) of heavy metals by the introduetion of non-aqueous'
solvents containing oxygen donor atoms (dioxane, acetone) iz proposed. The hypo-
tbesis Is adranced that medium bismuth perchlorate could be extracted from a
mixed water-diozane or water-acetone solution. The conclusion is that the per-
chloralves (aiW nitrates) of beavy metals form molecular compounds with dioxane.
Author's summary
[Abstracter!s note: CorTlete translation]
Card 1/1

~5(2)
'OTHORS. 4olubi, A. M--., Pomeranta, G. 13, .31008-4-4-11/44
MLE. Complex Silrer Selenocyanates (Komplekanyye selenotsianaty
serobra)
PERIODICAL: Zhurnal neorganicheakoy khimii, 1959 Vol 4, Nr 4, pp ?69t-774
(LISSR)
ABSTRACT: The potentiometric method was used to investigate the condi-
t1oms needed for pneparing complex silver selenocyanates in
aqueous and acetone-water solutions at 200~ The complexes
A.g(CItSeI2'_ and kg(CNSe)3- were determined. The dissociation
13 4
conatants of these compounds at 200 were determined:
Ag K - 1.61.10-14 (in aqueous solution) and 2.6,10-15
3 3 .15
(in acetone-water solution)- Ag(CNSe)4 . K - 1.57,10
(in acetone.-water solution). At higher concentrations of the
complex.-former KCISe in aoetone.-water solution the --tomplex
ioxt Ag(CNSe)3,, forma, The solubility of krMe in the
4
Card 1/2 prosence of KCNSe ions in aqueous and alcoholic solution was

CDMP10X Silver Selehooyanates SOV/78-A-4-11/44
inventigated, Cryatals form after some time in saturated
solutionti of silver selenocyanate in the preaence of potassium
selezwyanate,, Fine cryatals precipitate from acetone-water
solutions with an excess of potassiura selenocyanate Analyses
of' these crystals indicated the composition KA '92 (CNSe) 3' The
salt. I's stable in the air, is diffioultly soluble in water,
but easily soluble In aqueous &olutions of sodium thioaulfate
and potassiam se~'ez,oeyamate Three tables summarize the
rosults of the potentiumetric measurementa at a) constant
silver concentration, t.) constant concentration of seleno-
cya.vate ion. and c) constant acetone concentration. There are
4 figures, 3 tables and 8 references, 5 of which are Soviet.
ASSOCIATION% Kiyovskiy gosudaretvannyy universitet im, T G Shevcheako
Kafedra neorganicheakoy khimii (Kiyev State University Imeni
T,~ G. She'vchenk.:, Chair of Inorganic Chemistry)
SUMMITTED: Julas 10. 1957
Card 2/2

5(4) SOV/78-4-6-22/44
AME[ORS: Golub, A. M., Kosmatyy, Yu. V.
TITLE: The Potentiometric Investigation of Lead Selenium Cyanates
(Potontaionetrichaskoye isaledovaniye selenoteianatov svintea)
PERIODICAL: Zhurnal neorganicheakoy khimii, 1959, Vol 4, Nr 6, PP 1347-1351
(US'9R)
ABSTRACT: The Itad selenium cyanate complexes were investigated in aqueous
and mixed solutions. The potentiometric method was used for
the determination of the stability and composition of these
complexes. The composition of the complex is not changed in
aqueous solution in the case of constant and changing ionic
concentration of the solution. The complex has the composition
Pb (CTSO)4-
6 . The dissociation constant, the complex formation
react on, and the thermal effect of this complex war detected
0
at 20 and 30 - The dependence of the log LPb(C.qSe)xi
----T-
&04
on the log 1CNSe-j in the aqueous solution is given in fig-
ixrs 1. The influence of the solvent on the formation of the
Card 1/2 lead selenium cyanate complexes was investigated and the results

SOV/78-4-6-22/44
The Potentiometric rnvestigation of Lead Selenium Cyanates
of the mixed solutions are given in the tables 2 and 3- It
vas foi3nd that the stability of the complex is increased by
the adiltion of acetone. The Increase of the acetone concen-
tration, complioates the composi ion of the complex. It is poa-
nible that the complex Pb(Ma)~ - is formed by a higher
8
acetone cono e tration. The dependence of the
loo., [Pb(CFSe)xon in the mixed aqueous-acetone
, In 2+j log ICrIse 0
solution was investigated at 20 and given in figure 2. There
axe 2 figures, 3 tables, and 7 referenoes, 5 of i0ich are Soviet.
ASSOCIATION: Kiyevsl~iy gosudareivennyy universitet Im. T. G. Shevehenko
(Kiyev State University imeni T. G. Shevchenko). Kafedra no-
organichookoy khimii (Chair of Inorganic Chemistry)
SUBMITTED: Ptirch 25, 1358
Card 2/2

50) BOV/78-4-6-23/44
A UT HOR S Golub, ft. Iff., Kilimnik, G. M.
TITLE: On the Problem of the Coloration of the Copper Thiocyanate
Complex in Solution (K voproau ol okranke rodanidnykh
kompleksoy medi v rastvors)
PERIODICAL: Zhurnal neorgamicheskoy khimli, 1959, Vol 4, Nr 6, PP 1352-1356
(Ussit)
ABSTRACT: Spectrophotometric investigations were carried out in aqueous
and alcoholic KCSS-CuCNS-eolutions, aqueous Cu(C10 4)-solution,
alcoholic solution of N(093),j CuCl-LiCl and Cu(CNS),-KCNS
in acetone medium. The results are given in the figures 1 and
2. It was found that the rod color in recently produced
Cu (0N$)2_XCNS_s0lut'on 'a equal to that of a longer stored
CuCTIS-KCNS acatone solution. The alcoholic Cu(CNS), solution
has a yellow coltr. The compound Cu(CNS), is decomposed by
the addition of acetone under the separation of monovalent
copper thiocyanate. It is assumed that the coordination atruc-
ture of the thiocyanato ion and the copper ion in the acetone
Card 1/2 solution is changed and that a donor-acceptor interaction

SOV/78-4-6-23/44
On the Problem of the Coloration of the Copper Thiocyanate Complex in
Solution
takes place between the central atom and the acetone molecules.
A colorlean crystalline salt of the composition K 2Cu(CNS)3
was isolated from an acetone solution (Fig 3). The crystals
nre easily solved in acetone, the salt decomposes in water.
The crystals decompoag only.partly in alcohol. The cry W.
0- a 3-
melt by heating at 55 165 , and decompone at 220 230
under proftetion. of gaseous substanocs. There are 3 figures
and 8 references, 4 of which are Soviet.
ASSOCIATION: Kiyevskly gosudarstvennyy universitet im. T. G. Shevohenko
(Xiyov State 'University imeni T. G. Shavchenko).
Kafedra np-vganicheskoy khimii (Chair of Inorganic Chemistry)
SUBMITTED: March 26, 1958
Card 2/2

5(2) SOV/78-4-7-17/44
LUTSORI. Golub, A. N.'
TITLE- Investigation of the Selenocyanate Complexes of Lead by the
Solu'billty Method (Inucheniye selenotsianatnykh kompleksov
evinton. metodom rastvorimosti)
PIRIODIGAL: Zhurnal nmorganicheakoy khimii, 1959, Yol 4, Hr 7,
PIP 1511-1581 (USSR)
AB$TRACT: On the basis of one of the author's earlier papers (Ref 1) the
following rule was deduced for iodide-, thiocyanate- and seleno-
+ nUA--2K
XeA
, where MeA
is a
cyanate Complexes: X"
k
a
k+n
k
diffioultly soluble salts KA and KnXeAk+n two easily soluble
salt-it. In stable complexes n has a low value (1 or 1/2), in
non-stable complexes its h4heat value indicates high co-
ordination numbers# On the basis of these rules it was assumed
that in the system Pb(CNS9)2 - ICNSe, aqueous solutions, in
which Pb-complaxes show little stability, must contain
IIb(CXS9)4-_joAsj whereas in acetone solutions, in which the com-
6
Card 1/2 plexos axe more stable, Pb(ase) 3-ions muct be found to occur*

SOV/78-4-7-17/44
juvestigati= of Jbe Selanooyanate, Completes of Lead by the Solubility Method
Experimenta2 results (table 1 and figure 1 acetone solutions,
tOl a 2 and --figur* ~2- aqueQue solutions) confirm this expeotaticn
and Ous aloo the rmle,set upe.Inventigation of the properties
of A" P~ was carried out in col-
laborati*z with Yu. To. Kosaatyy. If complex solutions are storod
over longer period&, shiny black films are formed on the glass
wallop which are said to be due to photolysis. It prair possible
to oiyefal2lze the salt KPb(me) 3 from the acetone solution,
and the salt ir4Fb(CNSe)6 from a va-ter-acetoue solution. The
micraphotographs of the two salts are given by figvre 3. There
are 3 figures, 2 tables, and 5 Soviet references,
ASSDCIATION: liyovskiy gosudaretvennyy universitet im. T. Go Shevchenkot
KafedroL neorganicheakoy khimii (Kiyev State University imeni
T. Go Shevahenko, Chair of inorganii Chemistry)
SUBZITTED: March 25, 1958
Card 2/2

GOUB. A.M.; ROXAMM. L.I. -. SAWYLIMEO, V.H.
Liesd zlhodanl4e oo-Pplemes. Part 2: Composition and stability of
Adion, coupluices. Ukrkhiu.sbur. 25 no.1*50-54 159.
(MIRA 12:4)
1* 11yevskly gosudarstvanny universitst in. T.G. Shevebanko,
kafedra neorganicheskoy khtult.
Nad tblocyanate)

MWASOVAp Ullp Sarlpayevm; BOGAMIY, Alo~ni-v VqavolodaTiah;
aty.red.; TUDCLBVA, ft.ioq rud.
.........I
(Obunist" Lu the vorrice of people] Xhimila no alushbe norodno
Kiev, 1960. 31 p. (Obabobeetvo po rasproatransniiu politichaskikh
A. wiuchofth susail Ukroinskol M. Ser.5, no.12)
(KIRA 14:2)
(chemistry)

QCWBO Androy MatTey'Ovich EKOIVb, A.M. k%nd.khim.nauk-. PETRUSMO,
~ Chtrueenko, A.M.). kund.f ilosof.nauk;
BOLOWA. V#P.. kand.khim.nauk. glavuy red.
[B.I.Mandolsev's periodic low in a fundamental law of nature]
PeriodycJmvi sakon D.I.Wendelleieva - fundamental'nyl sakon
pryrody. Kriv, 1960, 56 p. (Toyarystvo dlJ.a poshyrennia
polityebofth I asukovykh xnan' Uicrainalkoi RSR. Ser.5. no.3-4).
(KIRA 13:7)
(Periodic law)

.1 .1. 1
AUTHOR$-. A, X._M~ tostrava, R. A. S/07BJ60/005/03/039/048
6IM
1
-
6
B004/DOO5
TlVLtt Tavestigotion of qomplex ?_or in the System VO 2+ _CXS- -
Solvent
PMODICALs Shuxnal noorganichoskoy kbialig 1960, Vo2 5, Nr 3, pp 726-730
(USSR)
AMTRACT: The, object of the present paper was the determination of more oon-
plioat#4 complexes than the known VO6CN+. At firett the authors
report on the Investigation of the electrical conductivity In the
system VC 24 -CNS- - solvontb Water, and water + 50% of acetone, were
too$ as solvonts. fte conductivity was measured acoording to
Xchlrausoh's mothod. An 10-7 osoillograph was used as null in-
strumento a Sonerotor of typo ZO-10 &a current source. Tigure I
Ohows ttst with increasing Ion concentration the conductivity changes
Monototwuoly. The devistlon from the additlvitgy (diagram A%, Campo-
sItion, fig 2) shave indistinct nazina. which are ascribed to 'the
complexes V0Gb'+ "a VO(SCN)2' These complexes are little stable
so that the Investigation of the conductivity yielded no clear
rosultso Therefore, the system was investigated by an SP-4 spectro-
Card 1/2 photometer in the wave band 326-1000 mp in aqueous solution an well

Investigation of Complsx Porsation in the system S/07SJ60/005/03/039/048
VO 2+ -C15- - Sol"O B004/3005
SUBMITTED:
as In sollitione of water with 25, 50 and 75% of acetone. Figure 3
abowe the absorption curves for VO(CIO 4)2 and VO(Clo 4)2 + N&CNS'
figure 4 the dependence of the optic density on the composition.
The varying course of the two absorption curves suggests a com-
ploz formatlonj In aqueous solution, the complexes VOCNS+ and
VO(=S)2 axe formed. An addition of nonaqueous solvents leads to
a displacoment of -the water sioloculoo from the innyjr sphero, and
to a formation of anion ooapl*xts including VO(CRS)4-. Thor* are
4
4 Upres Azd 5 references, 2 of which are Soviet.
Dsoosber 16, 1958
Card 2/2

"W 4 907
S/078/60/005/05/14/037
i.;? o B004/BO16
AUTHORS: I,. Romanenko,L1, 1. 1P
TITLE: The influence Exercised by the Nature of the Solvent Upon the
FormatioA of Thioo3ranate 6-2~sx!.slOf Vivdl9nt MOrcurY
PERIODICAL: Zharnal meorganioh*skoy khimii, 1960t Vol.- 59 No- 5, PP. 1085-1089
TEXT: The authors made a potentionetric investigation of the thiooyanat* con
plexes of mercurjr vbich form in pure noz-aqueous solvents or at high oonoentr;_
tions Of such solvents in water Acetone and methanol were used as solvents
The equilibrium consiazt1br Hd+ + 11S Hg2,+ was determined. The composition
2 2+
of the complexes resultod, graphically from the diagrams Ig Hg lg.CKS (Fies-1-4).
The *xperimental data am* present,ed as follows: value of X H 2.,I'./[Rg 21 in
92 J
the various solvents (table J)j potentionetric Investigation of the system
Rg 2.& - CXS- R2D - C11 01 (Table 2); system Rg2+ - CRS - - H2 0 - CH3 COCH3 (Table 3);
system He 2+ CWS- - CH OH (Table 4), and system Rg 2+ - CN5 - - Y (Table 5). The
statement made by A. I., Posigun (Ref. 3) that the anion complexes of mercury with
I

6~w 6 9s-j'9
The Influence Exercised bj the Nature of the Solvent S/078/60/--105/05/14/037
Upon the Pornation of %11*47azate Complexes of B004/BO16
Sivalent Mercury
tbiocyaouto ions may pomss*s the coordination number 6, vas confirmed. With in-
creasing concentration oC the non-aqaegue solvent the composition of the anions
becomes,nore complioated'up to Hg(CNS)g- 1 vhoreas In anhydrous solvents simpler
4.
complexon are formad. The IS CNS)6 aomp1mm fore in aqueous solution at KCN$ con-
oentrations of betusen 2! and 3.4 moles/l. The dissociation constants of the com-
pl*xos lgg(Cn)2-,, 1tS(CV3q-, and Rg(CXS)t- in th* various solvents vere calculated.
4
There ate 4 figured, 5 tables, RW 5 references, 4 of vbich are Soviet.
ASSOCIATION: U evskly gosudarstvowkyy universifet in. T. G. Shevchenko
(XY
ROT State University imeni T. Q. Shavahenk
SUBUrMD- September 20, 1958
Card 2/2

S/07 60/OO5/O09/C27f/O40,/-(,X
B017YB058
AUTHORS: Golub, A. 9, and Skopenko.-V V
TITLE: CoEpor Selenocyanates
PITIODICAL: Zhurnal noorganicheakoy khimii, 1,960, Vol 5, No~ 9,
pp. 1973 - 1976
TT-XT: Copper selenacyanate complexeAn acetone solutions were
investigated by spectrophotometric and solubility determinations,
V-iff dependence of the solubility of copper (I) ihloride on the con-
csntration of K^VNS* in acetone was ascertained. and the results are
graphically represented in Fig. 1. The equilibrium constant of the
complex KCU(CNSO)CI" was calculated as being 0 24 Spectrophotometric
examination of copper seleLocyanate complexes in acetone solutions
shows that tile following complexes may appear in the solution:
0-
CACI(CNse)-, Cu(CNSM) 2-~ Cu(CNSe) 3 and Ci(CNSe),, The compounds
KCu(CNSe)C1 and CuMe were isolated and their properties investigated.
Card 1/2

Copper Salencayanfuten S/0718/60/00~,/009/027/040AX
BO-VBO58
The compound KCu(C11Sw)Cl is a colorless. f-Inely crystalline p,-wder
which lecompones very easily in water &n-1 alcohol The copper
solenceyana.Le CuCN$o in practically unsoluble .n water, acetone, or
alcohol, ani stable in a dry state at normal temporatures This
compound do-.omposem when heated., Copper aslenocyanate is easily
soluble in WISe solutions under the formation of complexes, The
solubility proluct; of CuCNS9 at 20C~C amount3 to 1 82 10-10 The
authors mention papers by Vr- F. Toropov, Yu V, Karyakin, and
I I. AngrelDT. Thare are 2 figures, 1 table. and 8 Soviet references.
ASSOCIATION: Kiyerakiy gosudaretvannyy universitat Im T G Shevchenko
Kafedra neorganicheakoy khimii
(Kiyov State University imeni T. G. Shevchonko,
Chair of Inorganic Chemistry)
SUBMITTE"DI: June 12 1959
Carl 2/?

GOLUBj A.M. [11caubp A.M.]v MM,khim.rAuk
analysis, Nauka. i zhyttia 10 no. 12:40-
41 ~D 1150. (MIRA 14:4)
(Xurnakov, Nikolai Somenovich, 1860-194-1)
(Chemistry# Analy-tical)

"/6" /009 /0, P,/'XX
127!, J~ ;, ~1,
2 /Bol
Golp;~,_.A.11. &nd Rlomr,ncnk~!, L.1-
VITLE: R)~or.,anlde Complexes of Lead
3. Anion Complexes of Lend Wi th the Ccord-, r t,,:)n
PERIODICAL: Ukrminskiy khimicheskiy zhurnal, 2~6 No. A
PP. 418-422
TEXT: The authors of the present paper stud,.~-i :) the effect of th~, n~.-
trate iona on thia lead complex formation, 2) thv value of the
diBSOciation conatant of rhodanide complexes, aril ~)' d_ata zr the i s :-'. 11 -
tion of the molecular lead rhodanides with the c,)vr-_ir.,t:on -~;-,ber 6. T1-
determine the composition and stability of the nitra*,~, _eai complexcul
the solutions of lead perchlorate (with con,-,tant con~~entraticr) and
sodium n2.trate wore potentiometrically irivectigated. A saturated calorie'-
electrode served aB reference electrode and 'lead ama~cam as indicator
The Pb(Clo 4) 2concentration was 0.01 M, -.hat of !3,cd-,u~. r.-.~rate ~) 2-2 M
The equil~brlum electrode potentials were -,h.,_r7'_i!A(PFTV-1 )
potent iometer. The reduction of the lead elec!rode pot-n-ial w.-th in.
Card 1/3

116165
Rhodanide Comploxes of Lead. S/07;~/61--,/'C26/'004,"000/01.5/'XX
3. Anion Coaplexes of Lead With the, B02 ~/BO64
Coordination Number 6
creasing nitrate icn concentrations in the system Pb" - NO 3* H20
Indicates tho formation of lead nitrate complexes. The PbNO, ompiz., ta , n
was graphically determined on the basis of the po*,:!rticmetric data The
dissociation constant was calculated and found tr,1,Efairly -,table; it
amounts to 0.16 an the average, V. M. Samoylenkc assisted n invcstirat-tC
the nitrate lead complexes. Furthermore, a potentaometri~. invest,.gat.,.on
r-as made (:if 1he formation of the lead rhod-Inide ccmpiexe., of the anzc%
t
ype at conalant ionic strength of the solut:ons c" wft~3 mairtainet!
with perc*hlorate jons. The fnrmation of the
was confirmed an(). the actual value :.-,f it,~ dissc.:;iation c2nstar.*, waE
found to 'be 1.83.10'2 at an ionic stiength of 6 ~1. On the tas:s cf
K.B. Yataimlrskiyls data and by me~-.ns of the aferementioned cc-nstant.
7. The th,,rd
the solubility product of Pb(CNS),, was fc,urd to b-
problem wui siolvel,ii '.,y crystallizing KCNS - Pb~~CNS f Tte
anal:is:is. of the iialt obtained yielded:
Card 2P

8,6165
Rhcdanide af LeFd S/C-"1311601n~2~-- /00410091 0'~./XX
3
,. Anic-ti C..mple~:e:3 t:,f L
ead With PO ~~ ~/'BC64
thf: Coord:inatic7 N-amber 6
I'll CKS K
28-73, 48-56, 21-71% as nampa-,i wi-n *~~v lhv~reliru-
C om') 02'. t A ol, 2~. :0, 4 8 - (114 21.96% tor KPl, (VIS)

C: nseqjimt IY t1ji; leud r hoduni-cip ccmIlex w-, th th'- c~~.):A;n,Lt ori numt.,r m-:v
be obtfilned only in the solutij- bu t a 1 9 c a - r7 0 7- :: OMI. F, r d
There arc, 2 fi~-
pjre;~. 2
tables ani 5 refere
ncef,: 3 c -,r,. 2 US
kSSOCIEATION: X yevak y goBudarstvennvy un lver,,~itet
SUUTTTED:
Card 1/3

SMCMID, F.D., katd. khim. Holub, A.M.], kand.
khju. nat*0 dotseritj Otv. eid.; VIADRO, Sh.Ta., red.; MAMI(;HLTX*
a.A., te)~Ii. rsd.
[33amic prInolples wW Javs of cbevistry) Osnovni poniattia i za-
kal khimii, Kyiv, Tovarystvo dlia posbyrannia polit i nauk.
a=n' UILSR~ 1961. 34 P. (Chmiatry) iM IRA 3.5 11)

LITINETSN=p Im*t Borlsovich[Utyne 1171, I.B.], kand. tekhn. mk;
6.
_.j[,-.LJIobtb, A.M.], kmd. khim. am*, otv. red.; 72
-..,0QK;B Arl
pujWAP- A.Se-P rode
(14.1'.Lwowsov so the famder of plWaical chwdstryl H.V.Lamonoowr..
*awvopaI*%bvyk fiqebzoi Mail. 4iv, 1961. 38 p. (Toyarystvo
dl~* podbVremia politvohvM i nimkovykh -1 Ukraina'kQi RSR.
Ser+6s mo.7 4monomov, Mikhail Vasillevich, 1711-1765) (KMA 1429)

GOLUB, A.M. I'lloliab.1A.M.); XII.IM,IX, G.H. [Kylymuyi, H.1-1.1
-I--,--..-,-.-
MOO of ! It laurves Iri the coagwative stab~llty char acteris tics of
c0u~).exoifl. Dop.AW UFSR no.71932-934 161. (KaU 14:8)
1. KJvevmkiy gooudarstv*wiyv universitet. Predstavleno
akadomilton AN USSR Xu.K.De3 !- okJAjL [Dell- a -kyi, IU.K. ].
(Complex compoundd)
v~ -,
~ I

GOLUB q A,M. ~, SKOPI.ADO V.V.
ww-wowb"lop"ill
Silver welonocywzte complexes in mlxed and !-.ctlanol solutions.
Zhw-. noorg. 6 no.1:140-11,3 161. (MI-A 1/.;2)
2. Kiyoveoldy ;'-c)uud&rut-vemirf univ'ersitat Im. T.G.Shovehealco.
(smmtqql~ (Chomintry)) ' (Silvor cm-apoirids)

GOLUBI A.H.t MODIOX0, F.T.
Potentiamstric investigation of iodide complexes of silver in the
N&wl EMO~ - MaXO~ eutwetic. Zhur.neorr.khim. 6 no.10:2344-2346
0, (MIRA 14t9)
, I t1 ..
1. J:Ayevskiy rosudarstvenroy universitet imeni T.G.Shevchenko,
kafedra n*orranicheakoy kbinii.
(Silver iodide) (Potentionetric analysis)

OOLUSLAA,tj IKKOMOP Lale
Thloeyanwto complexes of 100do Part 4s Effect of indifferent
ims on Uho emposition of the couplexec, Ukr. kbi-. shurs 27
w. linZ l6a,, (MIRA 102)
!~* Uyevokiy pndaretv*My universitat im. T,G, Shavchenkat
kmf6dra mearganicheskI kbiali
(74 C;~~mdn)

.GOLUBg A,,Kp SNOIROBWATIROP TO.Ps
0 (1). Report No. 2. Urk. khim.
sbur. 27 Boo 161. (MM 34:21
10 Uyevskly gonudarat"nowy universitat im. T.G* Shevahankas
I*fWJm-v*4wSwdobs#kqy Irbial I a
(Th&Mva compoumdo)

.ODLUB# AXI GOWZM., 0.1.
"W-Uns doubU salts of lead iodide. Ukr. Whim. shur. 27
imol2Q3$--Ul 161. (MIM 340)
I* tLrmskiy gosudimstysmy =ivernitat i3R. T. G. Shavahankop
kafefts asceptdohaskay Wall.
(ioad UkUft)

GOIA)Bt A.M.; ~QWJZTSP 0*10
I '. k,
lodidW - omplexan'of lead in monaqueom solventso Ukr. kbin. shw. 27
tio.2t241-146 161. (MM 3.40)
1. Xirmskiy goiudarstva=yy uidversitet im. T. G. Sheychenko,
kafedWagarganjaegkoy jr%juji,
(Lead COMOUnds)

GOLUB, A.M. j OGIMNIK, S.S.
-.1 ...... -.. ~ I
Thiacyanide compimme or tin (V Ukr.khim.zhur. 27 no.3:28-1-290
161. (MIRA 14:3.1)
3. Kiyevskiy gosudaretverm" universitet Im. T.G.Shevchenko,
kafelim meorganicheskoy khlimli*
Tin compounds)
hicepmic acl d)
R