SCIENTIFIC ABSTRACT GINSBURG, B. - GINTER, E.
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100
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December 31, 1967
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SCIENTIFIC ABSTRACT
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.j ti. _77 /75
Production of Some 2,';-Dinitro-phenyl Derive vas SOV/70-29-5
of' Lyvine nn,! oi' Intc!r~.,.ctliate Products of Its Synthesis
otatc w.-- lifficult. In the experimental pnrt directions are
given 1lie formation of: (1) E-N-benzoyl (2) chlorine
hy1r.-to of' G-nmino-eftproiv licid, (3) t-rtmino-ot-bro,no-caproic
acil, (~) the linitro-ph(myl lerivative o' 2, k'5) the
linitro-rhon,1,1 dnrivritiv,i of 7, (6) f-;%'-2,4-,1initro-phpnyl
lysine, (7) e-~,-2,1,-dinitro-phenyl-oc-:i-henzovl. lysine, nnd
(0) E-11-benzo,,rl-d,!1-2,4-dinitro-phonyI lysine. The
microanolysis of the substances was cnrried out by V. D.
Zolotni~ova. There are 10 referonces.
3U2 1ITTED: April 27, 1958
Cn-rd, -~1/3
GINS"Jit" -,.
It; ~ i' tiic,;:,t
.j , I . .
n3port f,A- z-nJ Ul-Urik)n :o:,!' (,ii li,~to %- 'Prt,12~i"r.-,r, Mins~., ii-ill
I'la"! I -kdi .
hl~,t of F(.ul
GINSBURG, B.Ya.,.,-doktor tekhn.nauk
.......... ----
Evaluating the traction fDrce it tractor5 with the help -;X
dimensionless parameters. Mekh. i elek. sots. sellkhoz. 19 nu.
3:9-14 '61. (MIRA 1416)
1. Vsesjyuznyy sel'skok1:ozyaystvennyy institut zaochnogo
obrazovaniya.
(Tractors)
GIMBM, B.S.; LIPSHTIrY, R,A.; KUYIIIIA, S.Z.
.- . ........... .- - "
Resistance of gas turbine metals to vanadium corrosion during the
use ofFulfur-bearing fuel oils. 1881. PO 2haropr. splav.6:140-145
,6o. (MIRA 13:9)
(Gas turbines--Corrosion) (Vanadium)
GINSBURG,- G.D.
I -', ~, ... . ....-
Som data on the tebetisol In !.he Omaukchan bagin. llch.
wip. NINA. Reg. geol. no.4:239-245 164.
(MIRA 1P:12)
and t !i,
uo '1"p,
GDISBURG, L.N prof., doktor po, tek~nioheskite nauki (SSSIO
-
Results from the development and introduction of spinning machines
with higli drafters in the spinning of bast fibers. Tekstllna prom
11 no. 5:13-14 162.
Ji, L"i,Mdl"~Wlik'~"'
kin,
Be AIe-
n P no 0
'08 It
j
FI6 ~'T L 40 hrw inizod rubber, Phencil4brualde
r v4
or a
r robb on.synthdt~
t 8 well is
00
at ~ G:
bb atbd with rolling! A6
itylphendl4cria
'P. a v,~' R
d",
rktaini V" :.or r0
M each c0
i .0 !~d, .1 ng
A
annous CnIorlaes Tae remu
ik d- 6' especially in the ~ib
16 Vail
4 A
1 art
eriments 12, 3 and P
"CM, or
chloride were added to naturaL~
6-4imit 4
vul of ~ a.~b
IMA see, P cad canized rubbers
48, co C4 was not adversel affected b~~
y
dak ~teo,
"I t W4
Pill
i 00,
L80C
LO
Mg
Sence".
f
D:O
~jhe~,
ri
ol~
VW
FJ
w-Z'
0;
f
vie
""roe 0a
Or.
0: 6 Ao nt
OVO ",a do 4bied ther6th.,
"UtOigii' Orig 3- '.art'* JiK`
lot. i
I O~sikoy tokh
nologli iio
Che~icallechnolo
.110 00CII..
Ji ENCL: 00-1
j16j
OTM:: 606:1
0-11 tz~'4
1; L
,~i iaf~ric D,-il i --j*.,~r!.,I Arr-i 1 (Col I ect a ~er- oi-y
anu flyflane., lie.~; MICh I-Istitallb-st Uf 411,- led 1, Ye. 11
with A.L.Tione In and V.M.Putimov wrote a chapter in above book "Serum Medium a a
a Diagnostic of Anthrax Variants," pages 93-101
with N.F.Kopylov, A.L.Tamarin, and R.A.Saltykav - "The Question of Stability of
the Basic Biological Features of Anthrax Vaccine Strain STI-I,I pp. 142-52
GINSBURG, N. N.
May 19V
USSR/Medicine - Anthrax Vaccine
Y ccines
"Results of Application of Anthrax Vaccine STI During 1944-1946," 1. F.
Kopylov, W. N.Ginsburg, Scientific W Research Institute of Epidemiology
and Hygiene of the Soviet Army, 2 pp
Veterinariya, No 5
Mostly tabular results of the use of STI waccine on horses, sheep, pigs,
and deer during the years 1944 to 1946.
PA 17T8
GUSBM, N.N., prof.
Problem of living vaccine In poliomyelitis. Vest. AMR SSSR 13
no.12:39-46 158. (MIRA 12:1)
1. Institut po isuchaniyu poliomiyelita AMN SSSR-
(POLION M ITIS. immunol.
vaccine, live virus (Bus))
GINSBM, T.N.
Soma quentions In the theory of live vaccine and vaccination against
pollorqe1itis with Fabit vaccine. Yop.virus. 4 no.5t620-624 S-0 159.
(MIRA 13:2)
(POLIOMMITI.9, immanol.)
OUSBURGO N.N.; KASTROV, K.T.
P~rodwtion of colonies (plaques) of poliomyelitis virus on human
embryo tissue culture. Vap.virus. 4 no.6t742-743 W-D 159.
(MIRA 130)
1. Institut po izucheniyu pollomiyelita AMN SSSR, Mookva.
(POLIOMTELITIS TIZIS culture)
GINSBURGV M.N.; XASYMOV9 K.T.1 ALITS11TEYNt A.D.
Cwparative study of various methods of titrating virus-neutralizing
antibodies to the poliomyelitis virus in tissue culture. Vop.
virus, 5 no, ls2O-25 Ja-F 160o (MIRA 1414)
1. Inatitut po izucheni Poliomiyelita AMN SSSR, Moskva.
(POLIOMYELITIS~ ANTIGENS AND ANTIBODIES)
11hpacity In
Ali 163.
O"I110A 1'," 5",
_9~MBURG, 11.14; MOTOVA, Yu.M.
Comparative study of vaccina-l. and arat-~ax
embryonal tissue culture. Zhur. mikrobtol., epLd, ; -*z-nI.i;1, ~,
3-7 N 163. '.
1. It 1nstituta imeni Gwna~,3j- A1,114 -7 S, S 1 ~ ,
ii,%; m;
;i C
if
if
i
f
V
io
z
4L. -I
IK
K H &I, lN p ya.lv . ; t" I , 1.1 . N . -, F11,10";V~A, Yo-l."
Karyonio trJ L ,, wdy of Jie. c(, :1 respGrise (,f s hr.,p, I e-laver tissi, a cu I Lure s
of humati embryo to infeztian by vacriwil ntr%ins of bacteria. Dokl. AN
SSSR 158 no.5:11-qO-1192 0 164. MIRA 17:10)
1 . I i i v, t. I i. u (, o p 1 d em J o I ol, 11. 1 in I k ro 1) ~ o I o~ -..' i i in. N. F. Gliml , I eya AM N SSSS R.
Pri4datuvlem, akn,A~-!,'7.ikom A.N.bakulevvnn.
UR/0016/66/000/001/1012
Swxm 00M
44
ikslovi -
g AN
f 6 :4td olw& 910
r*
~djon: ph"-Acuio by maorophages in vitro o anthriw
-bae at W~iring Ujoioe of ~~hoei Camunioation 2* Results of q~MV~:,
i"S I Zhur* vdkrb~io olU, todudologii i immnabiologii, no. 1, 1966p 5!1)64!
,TOPI~O 'ZAGS: A~thrsxg ~46teria, rJAent animal
V 10 U01 ',6 discussioi'of'ths result's of comparativi
vs
464pock,of Phapaytosiq by maorophages obtained mjlI'~?N,
Aut 4 ihe IA04#4 i ~
I ! , i.. IgIz,
lip ot onthiax bacilli avirulent (8U-1)
r* 66rml WAhr*i0ftLqq Om
z(V
~nd virula* OkO4 ~~gs pi,,, ;11/12MOf Teenkovskiy vaccine)*'
irhaj 69calstj 'i Is
thst ViCiroAh wd rep'oductim of bacteria of
lstrsiot STTA! rho *M:N had, cerbain characteristics in the
'is Olt! ana 40"Pbagee A quantitative evaluation of
Ithe t*sults otii 41A-not rerveal wky advantAge of immme macro.-A
Ipha6m over n' ma *a ihiVie,:inttft5ityvf phWcytodsp but in the
train$
ipr0*000 of of givAh of becteds of both a
n6tW to 0, 044 thab Jams and noml nacrophaps Of I
-P Ok,~~ wAt ~4so and Virmleat str&W with
UDO: 619 n23
~rd V2:
2719"6
ACC !W
APM
icallylident
icai aotiv#yj~which varied within the limits of 35-50 cells per I mmo
'Mm ~sthod worked out ~y the authors for making calculations made it possible to
JobtAn data whlqb obje6tt4ely chaiactirize the process of phagocytosis and its
Aynablo develoomot. g, art'~:h of 3,figures and 1 table, [JPRS]
lisumout o6 i;: J, DATEJ
SUBM
OjDe~64
d
J!!
C
Lur-:Y, L. 1.
~ru
in, 'I I b Va
ACC NRiAP6023617 SOURCE CODE: UR/0105/66/000/007/0085/0069:1
AUTHOR:_"wburg, S. A. (Doctor of technical sciences); Stavrovskiy, A. N.(Engineer);!
Shlimovich, V. D. (Engineer) -2 7
ORO: VNIN
TITLE: Special-purpose computers for calculating economic distribution of active
loads In power systems [A review]
SOURCE: Elektrichestvo, no. 7, 1966, 85-89
TOPIC TAUS: electric power system, electric power transmission, special purpose
computer
ABSTRACT: Based on 1957-65 Soviet, 1955-62 Western, and 1959-64 Japanese literature,
a review is presented which covers the followipg points: Scope of problems and type-
(mostly analog) of computer.Representation of incremental-rate characteristics of
plants.Allowancefor network losses. Uses of special-purpose computers and economic
officiency:(a) prediotion of load diagram, (b) counseling the dispatcher, and
(c) automatic control. Data re uses of special-purpose computers-in the_.fo11ovjr4,,
power systems is presented: Estonian Power Systeml Sverdlovsk, Chelyabinsk, Bashkir
ASSR, Donbass Power Systemsl Ural Joint Dispatching System; European-SSSR Joint
Dispatching System; Altay Power System; Georgian SSR Power System; West-Siberian
Joint Dispatching System; Hungarian Joint Dispatching System; S. California, Edison
Cc; West Penna; Ohio, Edison Cc; Colorado Public Service Cc; unnamed Soviet Power
Systeml Kusu, Tubu, Japanese System; Tugoku, Tokyo 31)rstem. Orig. art. has: 1 table.
SUB C0DE:_qqjq SM DAM none / ORIG REF3 023 / OTH REF: 020
rf
SHROVA) V., as-.irunt; Y.'.GLIVA, K.;
Ia;sembly-linc work and w,-.jTo I aymu,iit ots. tnic 6 no.
1(.5-115 AG 161. (1, Ii--i JI 14: 8 )
1. Kafedrin. politahonomii t1rall-skogo Costiduirstvonnogo univorsi_
teta (for .-;pirova).~,Nachallnik otdola truda i 7arLbotroy platy
fabriki "Uralo1mvIll (for Yarlina). 3. Nachaltnik honstruktor-
o byuro Hoskovskoy obuviioy C4.1,riki im,_,ni Kzii,r i., va (for
okoi, a 0
RitiLqn). 4. Sturshiy inzh. gruppy u:gini7.atsii proizvod:,tvt,,
fLbriki "Urallobuv" (for Girsburg).
(bhoe induatry) (Assembly-I j ne riethods)
(Wage payment syoLem,;,%
U.SSIVChemi.-try - Or;.-,.:nlc Cf-7.pt,%Ind~1 of Silicul
Chemistry - Gl-ani C
"Success in the Field of ChelsdAr" of 5ilicoll ur;-.oldc CC.1;1p(IluldL3'tl jj. 'Ya.
'oCc
oyl, 114 rIp
"Uspeklii h-hi:-dill Na I
Sulmmai~, of all iwrl~ chm~~.istr.v of i,(,:i( rir , llicvn vr,,zinlc
,mince 19.33. L'o3t of tho: cc r1literial i b -~cj unt i -, I.: k,Lk.r Lhan Uof (, c
PA 28A,9T2
/chemistry - 1, Nov/D" 53.
C
aTbla DI'== -N*thod for the Syntbesis of AUxbotic
Organoe-I ntea Compounds," A. Ya. Yakubovich,
V. A. 01-naburg, Moscow
"Uspekb 3011m" Vol Xx, No 6, Pp 734-758
Revimm this field thoroughly, pointing out that
the met3mod, as far as aliphatic ccmpds are con- -
cerned, vas developed by a group of IJSSR inveatt-
gatAws headed by A. N. Nesmeyanov. Lists reac-
tion data and properties of many resulting pro-
ducts in connection with the synthesis or
193T20-
USMIChemistry - Organoelemental. NOYIDDC 51
Cowpounds (Contd 1,
%M Satangboaphorus and organoareenic compda (sub-
stituted ybosphines and araines, halogenoal)Wl
pbowpbonic and arsonic acids, pboaphine ozides,
arsine ozides, etc). Reviews own work. As for
an P vxA As ccapds are concerned, lists same dU*&
obtadned by G. Kway. Bibliography (57 reft) So
about 54 Russian, 50% foreign.
193T20
GINSMi
Synthesis of hetirolirgank comporunds of the allphistli
weriesbythedistonjethod. 1. ~Mfheslsof compounds of
elements of gfoup V: anti'"y, arsinic. and bisillnuth
otganic conippon-is. S. TrMak-
311,v. J, (;,o,. C-w. (ITF.S.R.) 9-74(illw)(KIIII.
_
llawl.Aion).- ';,v C.A. 47, IROW., 11. Strithesis of
0wriloal Abst-
VoL. 48 NO- 9
Apr. 25, 1954 compounds of group V elements --organ* " qkrvs com-
pounds. A. Ya. Yakidwich and V. Ant-linti I Ibid.
1575 -St-v C.A. 47, 92,541. com.
pounds of elements of group IV. QfL&A"41con cotn-
pounds. A. Va. Vokultovich and V. ... Uiitsbuig. [bid.
Organic ChumistrY C, 1. IV. Syntheal.4of rompounda
of clettionts of group IV. Otganotin comraim-1 ... V&.
mul C,. I ~ C2.v
M'7-32. - Sv C.A. 47, 92576.
MW/Chenistry - Organophosphorus Cont- Sep 52
pounds
"Synthesis of Organo-Elemental Compouads of the
Aliphatic Series by the Diazo Method. II. Syn-
thesis of Compounds of Group V Elements - Organo-
Phosphorus Compounds," A. Ya. Yakubovich., V. A.
Ginsburg
"Zhur Obshch Kbim" Vol 22, NO 9, PP 1534-1542
The diazo method of synthesizing organo-~-'_-~~ment&l
coxqAa of the &Iiphatic series can be used for ob-
taining organophosphorus compds. Phosphorous
232T19
tribraimide and trichloride react with diazomet'ha
dLiazoetban p and diazabutane to form the corres-
ponding primary alpha-halogenoalkylphosphorus
courpda whose properties and derivs are dpscribed-
Phosphorus pentachloride reacts with diazomethaM
sa& diazoethane to form the corresponding secomd-
ary and tertiary alvb -balogenoalkyl deri-s of
Phosphorus. Phosphorus oxychloride and oxybroiside
in --logous reactions do not form compds having
the C - P b~cxA
I
23M9
7hosOIT11C Ac~Jds
SS"F, 21
Dc
sc-e 7~roverLle,5 f74
Accessionss Library of COngress., Junc. 195~, Uncl.
Sol MonthlyList2f RusBian
YAKUBOVICII, A. Ya.; GINSBURO, V. A.
tic'
Oynthe,air; of Iletero-Organic Compoundi; of the AlipiatIc Series by the
Diazo Method VII Syntliesis of Compotmids of Elements of the V Group- Organophosphoi-is
Compounds- Trichloromethylphosphonic Acid and Its Transformaticiiis," 'e.'hur Obshchei F-bim
214) 2250-6 (19511).
D. Z~ellnskfi Institute of' OrganIc Chemistry of the Academy of L;uilen-er an~ M. V.
f
Lomonor~ov State Univerir.ity, Moscow.
Report B-85365, 3 Jur, 55
GINSBM' V.'k.
"Fluorine chemistry". Val.l. J.5imens, ed.(Tranalatad by IaL,lauxiants,
and others]. Reviewed by V.A.Ginaburg. Khim.aauka i prom. 1 19-3:360
'56. (nn 9:9)
(Fluorine) (Simons, Joseph, 1897-)
AUTHORS~ G b u V~ A. I., ~ ))b n A,
The Synthes)s of th~- Elezlcn' 0--arc- of ti,
TITLE, I 'e
AlA-'phat.:. Ser--~- ri ( Sin-,.e7
d it, p *, c e 1) i a 7 r~ 14h d
~rj,y alifat-,cheskogn rvala
diazoinetodc,m) , VIII vn~- S"'rithe&,,v of uj~e Ej~njefil Orga-
ni.~: ComFounds oaf th-~, V4-'r, f'xci;p Cimpounds.
Experiments f,~,r *he Synth-s-,,~ :~f D-, an~ Ty~haltce Alkyl.-
phosphanim ani S--)m~- F---a-1--t:.--,,-j-" -,)f tijo Aliyl~hl,)ridc- Deriva-
tiveg of Phosphoruo (VIII eloment~)u V
y~, s - yol ol, -la 01;.v+y sinteza
gruppy. F(,sf,)r
i t r :. ra 'I o -. d;A I J( iJ f 11 fk ry y e r - 1'.V a, -
khlcraJk,,l laykr, pro,k,l,-,dn,ykk, f,-4f -r.
PERIODICAL: Zhurnal Ot9b-h.?y Khim~~ 1) 1~ 8 V, 2 P Nr
j,j): 7
ty wl, ex+c-nd rnel.-
13,~! r,-, r an,,- om.
PoUrj& 0 f tyjt:- a I rjlj.T
secondarY and Li f0kyllflllo~pll '-els' to *.he
Card 1/3 given sol'esi- I -hey f~~uv~ ~heil '.,n-, -,III r- :-methy:41chl -,zc-
The Synthevia of the Eloinent
of the Aliphat", Ac-.~)rding
Method, V111- The of'
Compounds of the Vh Gr-op Ci~rr,
pounds. Experiments f,-)r th- SynthEs4ti c-f D, arA Tr--
halide Alkylphoqphin~--., aril S-Dmf~ R-,q- t, n, -.,f th~
Alkylchlori.d,b- Derivat-lv--, of Pl~--jlilcruL'
phosphin- anl rea~.t w)zr.
dlazoir.,~-Iiarl.- bli! char or~ th- hele.
the di hn-3 v c i ill
Aing.
In tile".-: pla- :)mp a.
ted strur1r.-i- w,?t~ obta-,-o,, wlvd~ az, ri~-aids their pro-
Per.T~eL~ wero sim,.la- to *~,~?op sol,.', ty prxl~l-i? I',- r M I rig
in the react,-,or ~,f '-Ii. al3pLa'~~c with
h t r --d e ~hlor4nation
Trach) cr ani t r L p, t*,,F
of t~e h ~- T,.,~ n 1 j d t,a, r) n- t r Jl
I
(tr ' phcsihirA---h-1,vA~~' di fch'-Or':'UlFthyl)-
phoephi'll -, ard jlOSPh,,T~ - a, -A we-- scparated in form
ari.,- ir.;~ sa, jr-:e~ r cavr:;-1 C)U* Witt
9
regar 'j t r-. al; i st -, 11c - 1: 1 - of th
morlti.ozioi P w;i8 shown thal tlie '~hlorometh,yl-
and enteY
tb-~ esterE, ~.f mett y 1,~ne-
Card 2/, an -1 e t h v ~ I - .. -
d iingly
The Synthesis of the Element Organic Compounds of the 79-2-13-3-38/61
Aliphatic Series Aocording to the Diazo Method. VIII.
The Synthesis of the Element Organic Compounds of the
Vth Group. Phosphorus Organic Coompounds. Experimento
for the Synthesis of Di.- and Trihalide Alkylphosphines
and Some Reactiorf; of the Alkylehloride Derivativej of 11hoophorua
with triethyl-phosphite, The chloromethyltrimethyl- and
ohloromethyltriethoxysilane are analogously converted to
the trimethylsilyle. and triethoxy!iilyleriethylphosphintite.
In the chlorination of tri- (chloromethyl)-phosphine oxi-
de with phoBphorus pentachloride the tri- (trichlorome=
thyl)-phosphine dichloride was obtained,, which in hydro-
lysis converted to tri-(trichloromethyl)..phosphinehydrom
xychloride. This product can not be hydrolized and con-
verts with aniline to the oxide of the tr'.-. (trichioro=
methyl)-.phosphine.
There are 6 references, 4 of which are Soviet.
SUBMITTED: January 25, 1957,
Card 3/3
AUTHOM t Ginsburg, V. A,,, Privezentseva, N, F~ ,,9-28 z 59/6i
TITLEs On Io7_in_eTrM-r*.tive9 of Methylphosphine (0 yodistykh
proizvodnykh tmetilfosfina)
PERIODICILs Zhurnal Obahchey Khimi i ~ 1,)511, Voll - ?~.'i Nr
pp. 756 739 (USSR)
LBSTRACTt Of the iodine anhydridea of phosphorue organic acids
only phenyldi--;.odo-phosphine has been described until
now. It was synthetized according to ref 2 by the reac.
tion of pheny1dachlorophosphine with gaseous hydrogen
iodide as hydriodide. It was shown that for the synthesis
of the alkyl-phosphine iodide the reaction of chloroan.
hydrides of alkylphosphinic- and alkylsubphosphinic acids
with hydrogen iodide can be valid. Ai33s shown in this
work by the formation of iodine derival-4ves in methylu
phosphine, In treating dichloranhydride of the methyl-
phosphinic acid with gaseous hydrogen iodide dark-.green
crystals of the iodine derivative CH.PJT4 are precipitaw
Card 1/3 ted, which, dissolved in water convefts To methylphos.
on Iodine Derivatives of Methylphosphine '119-28-3 -39/6!
phinJc acid w1th strong sepaiation of 4odine~ As is
known" pentaiodide is very unstable. According to
FurBman and Lipkir. (Ref. 3) some compounds of three,
valent phosphorus (triphenylphosphite!) form a number
of iodine derivatives with a complex-bound iodine-. among
them (C 6H5 0)3Pi4 and (C 6H50)'p 9 In order to prove
that the methyltetTLtiodide Fhosphorun synthetited by the
authors derives from five-valent phosphorus as regards
its structurn it. wag treated with an excees of dry sodium
ethyiat--:s on which occasion a diethylmethylphosph-inate
resuiv,edundegonditions excluding oxidation; this excludes
to a ~7ertain extent the possibility of a complex structure
in form of CH 3Pi 2' 12Besides methylti-traiodide of phos.
phorus. a resinous product was (obtained which on the aca
tion of water converts to mothylphosphinic acid. All in
all the reaction process can be represented by the following
formulai 3CH POC1 8 HJ ---)2 CH Pi CH 4 6 E[Cl.
3 2 4 3P0 (0H)2
In the reaction of methyidich1lorcphosphine with hydrogen a
1~rystalline product is obtained which has the composition
CH 3Pi 2' HJ, methyldi-iodophosphine It aegms that the alio
Card 2/3 phatio dichlorophosphines react with HJ similar to the
On Iodine Derivatives of Methylphosphine 79-28 5-39/61
aromatic ones (Refs. 1, 2)1 CH PCI 5HJ H Pj . dj + Hel.
3 2 3 2
The free methyliodidephosphine is obtained by the action
of yellow phosphorus in carbon dioulfide. &1l reactions
within the eeries of methylphosphine 4.~%dides are repre-
sented by the last scheme.
There are 5 references, 1 of which is Soviet.
SUBMITTED: January 25, 1957,
Card 3/3
AVT~ORS: Yak-,~bc,vic-l-, A. Ya. ,~,inshur,,. V.
TITLE, On the InLr-rructicn -~,.-twee!- lilpira.-ine aril Di6ulfide
'0 v:-.aimodLystvij E~dra,,-,ina s
Ex:.werlnlents for tbe (Opyty
in I c z a d i -1 L:, i A -, n a)
r';"RIODIr AL
-Y Kh i m 'L 1 pr, 10`51 - 1035 (USSR)
ABSTRACT: One ~f the., auUorH formerly Luo tu,a% ~!ordina to
,mc~rl~ried method by Kaluz on c'm"i ion!i %lkylendi-
C-ap. bc c.Maired. In `-ii,; -,,,,ovk Lhe authors
synthesi~~ed by analc,:ous meth'ids the L-t-imylaj, representa.-
tives of com-.~cund &EilEs th,? d."l:;Gth.LCcyanoj-en
s ON - 14-~ Sw1cch wL., unknovr, htri;~rLc, The of this
synthesis -Ln be rerresew.ea as L*o."Ic-,,,%:.:
MI2Ni!2 +- M 2 ~ 2NaOff (.1111CSSITl."2 (1
(2)
(Nl!c,~;scooc H, (2)
(I"Iff"331141)7c'. cooc2
Card . 1'11
.39/60
On the In ter act or, Hydr a, 1 -1 C- Firid -,a r I, i n Di!;-~
Eyp,~rir,,.enf L for t I. ~'-pAhc j-~ of Dii Jo, [I!(,' J,4 P(
If:
2
t r r;
fill
K m
e r e a,; t n o
r :1"111 phr,!j; the
G 2 d I C S c 0 C I
2 2
orl V, 3
-7)
C:, e Lr. C G e
i ~,-,A The
Z~.% fl ~s t! eth~vl thi -Cy'anate.
av,er 0 Um F. a 2 " ")
T p e f C: I- r;-- 1Y, C f ul 1-,01 otsorved in t'ijs
~' 1F .4
rase. ~ ,., in the deccmr~c:-,i~,-ori -f the iiaml;ydride of the
hy I T c. ~-, .1 ,-1 ~i sd i t, h i:, alb c, nan di chl or ocarbon~-c ac id the di.-
is(~thic,:Yi,~.orlsrk was roz, ~i -~ nc 7as tha" tie
k y 1 a rt, or. ir heatinj ani
'!-eretv fr,rri, alk 'I
I y The:~., aro Q relerenoely,
Card 2/1
75-2t-~-4 - J9/6()
On thu Interactif)n Between 11yarazine and Carbon Disulfide
Exprii.-IcntB for the Synthesis of Diisothiocyanopen
SIRIMITTED: January 25, 1957
~:, .,I
11 , I ~, If.?
T I T 1,
6 R
ell
e ~-Oj.jc nt
AB~;TRACT!
4,
he
k Y 1r, Gul~
D to no,
O
L
t'~j
~a
0-
Immont5 under
reac 7 A
f3 4- .
(Ill cooRl
t
of
i,i!pPa r
~':i o
1Y)d tic t; on M e th-od ft r F I u I-) rine Den vrj t IV E -9 0 a S
of 3ilicor.. Tin ard ;ulfur
the u,,zthc,rL3 already before in thi- synt~w 3i ,3 of thyl si lane-
fluorldes (Ref 3):
T Ix
Rm-Ex IA=4 Ij
SIT 4 R'Sip 3 ~3jyll
_'hu ren(,ti, 'P. of acetyl flijorid~_, ck-,np,,und3 cjf* sulfur
,11a3 InvuSti,,.ated at the example uf di;~iethyl sulfat(I. On that
occaujon formcd meti:y] r;st,?r of the fluorsulfonic acid
with a yield of 60 /. at con.~Iuction of' acetylfluoride va,~ur
into boilint; diraethyl sulfate. From the experimentai results
copies out t'-Lt tho reantiox, of the carboxylic acid fluorides
with alkovi co.apownds of vario4s ele;iunfs is u commonly
important metliod for the synthesis OIL, the con-
crned flaorine compounds. As the in4tial products - alkorj
-,-,,:im)ndi of the concerned elLr7,:?rts and carboxylic acid
in Z;~.neral are easily accessible conpni.,nds., the
3escribed u-ietaod earns -,eneral pre;)P-rative interest.
In an exper:Lmental. pa)rt exactly are de3crilb'A illie synthesis
the of diethy'r-thoxy tin fluoride diethyl tin
an (I
79-26-4 110 '/60
jrtluch '.1c;thod I'or Derivat~vcs )f thu Or,:,an,:~eItal Cornpounda
f 1;.ic,ri.("e tin tetrafluDride . trib,tt'_~xi f lu.')i sl larie diethyl-
ethjli;rifILiDr.,;ilaz)e :inl, )i the enter
a-v ,,-f which
S/079/60/030/uuil-
S7 00C., B001/B067 8230-D
AUTHORS: Gi sbu Privezentsevaj N. F., Rodionov&L N.
Du ovi akarov, S. P., Yakubovich, A. Ya.
TITLE: Reaction of Nitrogen Oxides With Polyfluorinated
Xthylella .13ynthesis and Reduction of Polyfluorinated
Nitroso Compounds
PERIODICJ,L: Murnal obahchey khimii, 1960, Vol. 30, Ho. 7:
pp. 2406 - 2409
TEXT: In Continuation of the papers (Refs, 1-7) on the reactions of
nitroeyl halides with halogenated olefins the authors studied the reac-
tion of N 203 with polyfluorinated ethylenes where nitrosolcompounde
might have been expected as is the case with non-fluorinated unsaturated
compounds. In the reaction of N 203 in the gaseous state with tetrafluoro
ethylene at room temperature a liquid of deep-blue color, 2-nitro-1,1,2,2-
tetrafluoro-nitroso-ethane, is readily formed (Refs. 60). Besides this
main product (yield more than 60%) a dinitro derivative of tetrafluoro
Card 113
Reaction of Nitrogen Oxides With Polyfluorinated S/079/60/030/007/018/020
Ethylenes4 Synthesis and Reduction of Poly- Booi/Bo67 82300
fluorinated Kitroso Compounds
ethylene and a small amount of non-identified high-boiling products is
formed. In the same way a chlorine-containing nitro-nitroso compound is
formed from N20 3and trifluoro-chloro ethylene. The nitroso compounds
synthesized by the authors and some other scientists (Refs. 3,8,9), as
well as other polyfluorinated nitroso compounds, are rather stable, and
form no dimers. In the infrared spectrum the nitroso compounds obtained
from tetrafluoro ethylene show characteristic frequencies of the valence
vibrations of the bonds N - 0 and C - X at 6.2 g and 12.25 g which
practically agree with the frequencies observed in analogous compounds
by J. Mason (Ref. 10). The same nitroso compounds are formed in the re-
action of NO with tetrafluoro- or trifluoro-chloro ethylene on irradia-
tign with ultraviolet light. The reduction of the nitro-nitroso com-
pounds with hydriodic acid in ether medium yields the acid fluoride of
nitro-difluoro-acetohydroxamix acid which was separated as etherate
(NO2CF2CFClNO), The structure of the nitro-nitroso compound which was
obtained from N 0 and trifluoro-ohloro ethylenelshowe that in the
2 3
Card 2/3
Reaction of Nitrogen Oxides With Polyfluorinated S/07 60/030/007/018/020
Ethylenes. Synthesis and Reduction of Foly- BOO1 Y3067 82300
fluorinated Nitroso Compounds
reaction the addition of N203takes pla'ce in such a way that the nitroso
group is linked with the carbon atom which has a higher electron density.
There are 17 references: 4 Soviet and 4 German.
SUBMITTED: June 4, 1959
Card 3/3
of) G,
El/079/60/030/007/019/020
BOO1/B067 823ol
AUTHORS: 1GinRburg,,.V._A., Privezentseva, N. F., Shpanaki-Y. V. A.,
Rodionova, N. P-., Dubov, S. S., Khokhiov~v A. m.,
Makerov, S. P., YakuSovich, A. Ya.
TITLE: Reaction of Halogens, Nitrogen Oxide, and Polyfluorinated
Ethyl neslin Ultraviolet Light. Synthesis and Thermal
Decomposition of Polyfluorinated Aliphatic Nitroso
Compounds
PERIODICAL: Zhurnal obahGhey khimii, 1960, Vol. 30, No. 7,
pp. 2409 - 2415
TEXT:. In continuation of their earlier paper (Ref. 1) the authors
studied the reaction of polyfluorinated ethylene with NO and halogen in
ultraviolet light. They assumed that atomic chlorine or bromine would
also lead to the formation of P-halogen nitrosolcompounds. In fact, the
authors of the present paper showed that in the reaction of nitrosyl
chloride with symmetrical difluoro-dichloro ethylene, 1,2-difluoro-
11212-tricliloro-nitroso ethane results in good yields. This compound
Card 1/3
Reaction of Halogens, Nitrogen Oxide, and B/079/60/030/007/019/020
Polyfluorinated Ethylenes in Ultraviolet B001 /Bo67 82301
Light. Synthesis and Thermal Decomposition of
Polyfluorinated Aliphatic Nitroso Compounds
proved sufficiently stable and could be isolated (compound 6 in the
Table). The experiments showed, as had been theoretically expected, that
in all cases the corresponding nitroso alkanes were obtained in suf-
ficient yields on irradiation of the gas mixtures NO + Cl 2 or NO + Br2
with polyfluorinated ethylenes (such as tetrafluoro-,trif2uoro-chloro-,
or trifluoro ethylene at the ratio olefin : NO : Hal 2 - 1 : 1 . 1/2)
(Table). These compounds have an intensive blue color, and are stable
liquids. Besides them also the corresponding alkylene dihalides as well
as 0-nitrogen halide compounds are always separated from the reaction
mass. Probably they are products of a partial oxidation of the nitroso
compounds. In reducing the nitroso compounds obtained from trifluoro
ethylene by means of hydrogen iodide the corresponding fluorides of the
chloro-difluoro- and bromo-difluoro-acetohydroxamic acids are formed
which indicates the addition of the halogen to the CF 2 group of the
olefin in the reaction between NO, Hal 2' and olefin. The pyrolysis of
Card 2/3
Reaction of Halogens, Nitrogen Oxide, and S/079/60/030/007/019/020
Polyfluorinated Ethylenes in Ultraviolet B001/B067 82301
Light. jynthesis and Thermal Decomposition of
Polyfluorinated Aliphatic Nitroso Compounds
the C1CF2CP2NO and NO2CF2CF 2NO nitroso compounds at 120-1300 yields the
polyfluorinated othylenimines ClCF2CP2N - CFCF2Cl and NO2CF2CF2N -X
- CFCF 2N0 2' respectively. There are 1 table and 8 references: 3 Soviet,
I US, and 2 German.
SUBMITTED: June 4, 1959
Card 3/3
. G.Ye.; DUBOV, S.S.; MAULROV, S.F.; YAKUBCVICH,
,__q I14~W.
A,ya,
S.vnthesis of asters of thioazocarboxylic acids. Zhur.ob.khim.
30 no.8:2689-2692 A 160. (MIRA 13:8)
(Azo comroundu5 (Acitla)
GINSBRG, V.A.; VASIL'YlVAP M.N.; DUDOV, B.S.; TAKUBOVICH, A-Ya.
Reactions of phosphites with a20 compounds. Zhur. ob. khim. 30
no.9:2854-2863 S 160. (MIRA 13:9)
(Phosphites) (Azo compounds)
',OINSMG. V.A.; TADBOV104 A-Ta.
Reaction of aldeWes with trialk7l phosphites. Zhur. ob. khim. 30
no.120979-3987 D 160. (MIR& 13t12)
(Aldehydes) (Phosphorous acid)
GUSBURG, V.A..; YADBOVICIL A.Ta.
Addition of triaWl phoophites to acrylic systems. Mmr. ob. khix.
30 no.12:3987-3992 D 160. (NIRA 13112 )
(Phosphorous acid) (Acrylic acid) (Acrylouttrile)
DUWVP S.S.; GIMBURG2 VOA*1, KADIfiAj M.A.; RODIONOVAp N.P.; RODKINp S.A.;
A.S.; UXUBOVICHS
Mal
Appearance of the &so group in vibration and electron a ectra.
Zhar.MO 6 mo*5096-597 161. = 14:10)
(Aso oompoundo-Spectra)
YANUBOVICH, A.Ya.; SOLOVOVA, O.P.; DUBOV, S.S.; CIIELOB-")V, Y.N.; STEFMOV-
SKAYA, gIlISBURG, V.A.
Structure and polymerization of compounde containing a trifluoro-
vinyl group. Zhur. VKhO 6 io.6:709-711 '61. (MIW, 14:12)
(Vinyl compound polymers)
YAKUBOVICII, A.Ya.; STEFANOVSKAYA, N.N.; MIXIIAYLOVSXIY, L.P.; FAYERW, S.L.;
SODY10VA, O.P.; ROZENSIITEYN, S.M.; GDSBURG, V.A.
structure and polymerization of compounds containing a trifluoro-
vinyl group. Zhur. VKhO 6 no.6:712-713 '61. (MIRA 14-12)
(Vinyl compound polymers)
YAKUBOf;CH, A.Ya.j GINSBURG, V.A.; WAROV, S.P.
Preparation of fluorine derivativem of phosphorua. Zhur.ob.khim.
31 nos5t1517-1518 Mq 161* (KMA 14:5)
(Phosphinic aoid) (Fluorine compounds)
YAKUROVIC111, A.Ya.; GINSBURG V A,; MAKAROV, S.F.; SHWSKIY, V.A.;
,-, -I , !.,
PRIVEZENTAW-IN.F.; MARTYNOVA, L.L.; YIR'YAN, B,3.V.; 11,41h, A.L.
Oxidation, reduction, and disproportionatim of polyfluonitro5oal-
kanev. DA]. AN SSSR 140 no.6-1352-1355 0 l61. (MIRA 14,11)
1. Fredstavlem) akademikami I.L.Knunyantsem i P..I.Kabachnikom.
(Paraffins) (Nitroso compounds) (Oxidation-reduction reaction)
MAYAROV, $.P.; YAKUDOVIC11, A.Ya.; GINSBURG, V.A.1 HIATOV, A.S.,, ENGLIN,
M.A.; PRIVIZENTSEVA, N.F.-,--rnvEZEMM-rA-,- N.Y.; 141KIKROVA, T.Ya.
Reactions of polyfuorinated nitrozoalkanes with amines. Dokl.
AN SSSR 141 no-2:357-360 N 161. (MIRA 14-:11)
1. Predstavleno akademikami I.L.Knunyantsem i M.I.Rabachnikom.
(Nitroso ~,ompounds) (Amines)
DUBOV, S. S.; GINSBURG V. A.
Problem of the appearanoe of the aso group in vibrational and
electron spectra. Zbur. MO 7 no.5:583-584 '62.
(MIRA 15:10)
(Aso compounda-Speotra)
YAKUBOVICH, A.Ya.; FIIATOVI A.S.; S1111ANSKIY, V.A.;
VULSOVA, Yo.S.; UIZNIN, G.Yo.; SERGITMO, L.F.; MARTYNOVA, L.L.;
MAILMV I S. P.
Productionp pyrolysiop and photolysis of polyfluorinated azo
compoundti of the aliphatic series. Dokl. AN SSSR W no.1:88-91
ja 62-. (MIRA 14:12)
1. h-edstAmlsno akademik9mi I.L. Knunyantsem i M.I. Kabachnikom.
(Azo compounds) (Fluorination)
GINSBURG V.A.; UKUBOVICH, A.U.; FIIATOV, A.S.; ZELENIN, G.Ye.;
S.P.; SHPANSKIY., V.A.j KOTFIINIKOVA, G,P.j
SERGITENKO, L.F.; WTINOVA, L.L.
Heteroly-tic transformations of polyfluorinated aso alkanes.
Dokle AN SSSR W no.29354-357 Ja 162o (MIRA 15'~)
1. Predstavleno akademikami I.L.K=Vantsem i H.I.Kabachnikoma
(Azo compounds)
(Fluorine compounds)
7
510201621 142100.'J/0 17/027
B 1 o6/B, 10
11-2121
AUTHORS: Makarov, S. 11 , Shpanskiy, V A . G i ns burv' A
Shchc-kotlkhin, A. I-, Filatov, A f-Martynova, L L
Pavlov,.ikaya, I V., Golovaneva, A F ant ~'akubovch A Y fa
TITLE! Reactions of polyfluorinated nitroBo-alkant!s with Lansaturaf.~.-nl
cl-,mpoundq
PERIOLICAL: kkademiya nauk SSSR Doklady, v 14~', nc. 11--162, 596 - 599
TEXTz Trifluoronitroso methane is used as aii (-xamplc- of some reactions of
polyfluorinatod. nitroso-alkanes with unsaturated compcunds These addition
reactions take place easily (in an autoclave at -70 to 00C) Monomers and
polymers containing I mole of nitroso compound per olefin mole. form.
Styrene and trifluooronitroso methane also form a compound with the molar
rati.o I . 2 which decomposes into I mole of nitroso compound, formaldehyde,
and the corresponding imine when heated to 70 - 800C Therefore it has
the structure C 6H 5CH-CH2 Trifluoronitroso methane aads to dipheny'.
. I I
CF N
CF
C a rd (j1/,'
e,
,0,U/ t 2/ 1,~ (117/027
Rca,.-tions o~ B!06/B' !0
ketei)e even mor,; easily under the forwition of (C 11 ),C-CO Which
0 NCF
decomposea wh.:n healt,~-d to 3000C mainly forj:iing trifluoromethy! isocyanatt,
(.Bp. 330C, yield 35)) and tr,,tces of' trifluoronitrost) mt-thriiju The latter
also reacts with H j=CX alkines (X C1, Br; H CF, C? C1, CFCI" at
F F -1 2 41 )
room temperature in an autop-lave. NCF forms on hpatin6 trifluoro-
ROOCNACOOR
nitroso methane with azodicarbonic acid esters to '00 .)OOC under
pressure Diazoinethane and trifluoronitroso melhane rc-a -t 3t '01)C to
give a polymeric ritron FCF N(O)CIi under ii !7:.-iqr~it ,n
21n
Phosphazines and trifluoronitroso m,.Ahqnc: react v-1, 7.* 1 0
following the scheme (C 611, 3P.=N N~XH 2 t CP 3N0 -- )CH
H ) P=N-N-NCF N2 P=-NCF The of thij reaction
6 5 3 3.1 ----:"('6H5 ~ 3
alou forms from triphenyl phosphine iind trifltiorc-,Ineth~:! Izidk, ,)Ild,~r the
11P.Me nonditions Trifluoronitroso mc-thant- ai;dl
Card '1/ 6
S/02 62/10/003/017/027,
Reactions of polyfluorinated... B1o6YB11o
vigorously when heated to 250C in an autoclave to form NGP which
N 3.
U113 N=C-C=NCH3
decomposes into trifluorinated dimethyl carbodiimide and methyl
isocyanate when heated to 350 - 4000C in vaouo. These reactions demon-
strate the great tendency of the N-0 groups of trifluoronitroso methane
to addition reactions rith nuoleophilic and electrophilic compounds. For
comparison, some additions similar to the above reactions were conducted
with polyfluorinated azomethines: CF 3N-CF2 (Bp. -330C) and CF 3N-CM X
(Bp. -500)- In all cases, the additivity of the C-N groups of these com-
pounds was much lower. On reaction of CF 3N*CF2' with diphenyl ketene
(autoclaved for 12 hre at 18000, not addition, but dimerization of the
initial substanoe took place. The dimer also formed in almost quantitative
yields by reaction between CF 3N-CP2 and pyridine at -70 - 500C- With
aniline, the dimer converts into the anilide of the monomer, when sub-
jected to pyrolysis (> 5000C) it dissociates into the monomer (CP 3N-CP 2)'
Unlike the polyfluorinated azomethines above, difluoro formimine easily
Card 3/6
S/020/62/142/003/017/027
Reactions of polyfluorinated ... B106/B110
reacts with diphenyl ketone to form the adduct (C 6H5)2 CCO-2CF2NH.
Addition reactions with hydrogen fluoride, hydrogen chloride, and mercuric
fluoride following the schemes
HP (CF,),NH
CFsN - Cr., _(CP,)CFjONH CINO. (CFa)sNNO W)
j(CFj)gN]jHg CING,
t-(CF,),NNOj(.!a,.+f7')
are very characteristic for the polyfluorinated azomethines in question.
The tendency of polyfluorinated substances with double bonds to addition
reacdlmwith olefins therefore decreases as follows: N-0 > N-N> N.C.
Table 1 shows the physical constants of the compounds synthesized for the
fir.-:i, time. There are 1 table and 12 referenoesi 4 Soviet and 8 non-
Soviet. The three most recent references to Engligh-language publications
read as follows: E. E. Griffin, R. N. Haszeldine, Proc. Chem. Soc.9 19599
369; 196o, 1151 - 1155; C. E. Griffin, R. N. Haszeldine, J. Chem. Soo.,
1960, 1398; J. Crawford, J. Polym. Sci., Aj, No. 145, 261 (1960).
Card 4/6
S/020J62/142/003/017/027
Reactions of polyfluorinated ... B106/B110
PRESLNTED: June 1, 1961, by M. I. Kabachnik, Academician
SUBMITTED: May 30, 1961
Table 1. Compounds synthesized for the first time.
Lcgendt (a) Compoundi (b) tp. (Fp.), OC/mml (c) determined,
(d) calculated, ~; (e) Fp.),.Non-diBtillable yellow oillaq molecular
weight (in acetic acid) t determined 580, calculated for the pentamer 565.
Gard 5/6
SKIRNOTJ 9. M.1 GINSMIR , T. A.1 TAIMOVICH, A. Ya.
Emotion of fluarmootylene with mercury saite. Zhur. WHO
no,28231-232 163a (MM 1614)
(toetylene) (mercury nits)
GINSBURG, V.A., VIASOVA, Ye.S.) VASILIYEVA, M.N.; MIRZABEKOVA, N.S.1
MAUROVP S.Pq SHCHEXOTIKHIN, A.I.; YAXUBDVICH, A.Ya.
Photoreaction of hexafluor-oasomethane with unsaturated compounds.
Dokl.AN SSSR 149 no.ls97-99 Mr 163. (MIRA l6t2)
1. Predstavleno akademikom M.I.TAbachnikon.
(1zonethane) (Photochemistry) (Unsaturated compounds)
GINSBURG, V.A.; DUBOV, S.S.; MEDVEDEV, A.N.; MARTYNOVA, L.L.; TFTFLIBAUM, B.I.;
- VASTLIPWO M.N.; YAK11130VICH, A.Ya.
Structure of the inclusion complexes of trifluoronitrosomethane with
unsatnrated compounds and the mechanism of their formation. Dokl.
AN SSSR 152 no-5:1104-1107 0 163. (MIRA 16:12)
1. Predstavlano akademikom I.L.Knunyantsem.
" JiSi~'J' ',' , V A.; 141 . , . . ~# . , 1. ~, , I- ~ , :. i . I
I .- . - . .. , - I
.. toct.r,ii fi,-ri -'r ' n - -wiict len f) .f- -. ' -,-,
I I "?, . ~
echfullim, - q - r ~, t, , ". I f'! .--1 01' f - I ' - ,
,)t,. i:111 m. ': 1) . I. t" : I ~ e,- 1 ? , ) ~akl
1 11 . - -
. . ; , I. Y'*~, '11 , ;. , A . '-- .
-( -- -n-,
~ t - , *h,; n #- . , 1u !. .
(Fli~A , ~~ : ~)
StTzlz4-!,!-C, of fdlll,,~tq c," -~,iinF w' ! u r. a tura f d
comr-cund 1 . 7j-,jZ-, ob. kh-m, '~5 no. I. F~7 I(
0
WA (di
2066 /1418/1422:
St (0, NI
OR/0079/65/035/008
t46-161:547.122:547.414.7
a Lebods M..F,; Dubov,
Va
A S.;
y
ljo
'ring
sl~ c*49=11d readtiOD6. Mechanism, of tri-
r0k* Oiattofc
Oorti
no, a
w11469, '1418-1422
VURIP~ i Zh%4tva'46 A.
t**ti9,n$ii4aCtioU EPR spectrum, organic nwoso!~~*",
Pun
~o C!6ip methane
ithano disproportionation was
f
nd.: 4tudied
foo V a In the temperature range.ftlom
a
JVI~
ov~61
-U0 .206:~ eta
b~f the OR spectra indicated t6at in tfie ab
4
d age 6, f ft'* ebf trifluorwitroso"thane dispropor`7
f
jtoi~,* Lo *i~; 4100,66~ ~o 4 11:00;iuti6n, C*dF3NO+.(CjH5o)+ 20% aque6usl NaOH'] is as
0 -4--t CFIRO+O-H
F F
_0
L 00$92-
ACCESSIOKHR: APSOtOdOLI
In the n6it stage,,
Oo,, 4
-0 IIjO+(;?jNOj (M)
0-0
01~~ + CFINO
ry)
hexafluoroazoxymet~a'ne andArifluoronitromethane are formed in a reaction proceed- I
A
in Via the ion-radioal madihism. In the range from -1200 to room temperature,
. 9 : I i
the EPR spectra Widate f6rim,Otion 6fa paramagnetic species at the interphase. I
Examination of the,structu~e of the EPR spectra at -1200C indicates formation of
sevOral#pes of free radi,calls. Th6.hydroxy radicals, doublet with identical in-
tensity'and a splitting of 49= 58 Oetrecombine at -1000C. At 200C the ratio of
,intensities of the:'6 hyper'fine lines: :is c1ose to 144:7.-7.-4:1 which corresponds to
a rsdic4l incorporating a~gioup CF3N.:, Similarly, 6 byperfine EPR lines but with-
out:dodtlet splltilfIg war' iound Wing ethyl etherf chloroform, methyl chloride,
and' et4l chlorldo"as soi*6ts. 1q: CF3NO+ C7HSOH system the doublet splitting,
'Card 2,13
:106 Oh
ACCkSSINI AP~010084
(40 18~ equal to 4" Oe 04ch is about 1. 5 times greater than that found in the sys;-
tam involving e#ihoir tdl~Wa'e or he'kiiine.:~ No EPR spectrum corresponding to trl-
S~;either earbon tetrachloride or trifluoroacatial
Vas Nund usin
to the dimetri
acid ii 961v~nts.!-~ ;The tftj~f6viatj6h of, trifluoronitrosomethans in' a
i0i -raldical (IV) 14:1 the ,4004hoo of, ai reducing -agent involves formation of a w-com-
plix iAtermedlats' i4d pi~Wds ~:scco~,dfnj tothe following mechanism
0 0-0
~dlssociation
00 ......
Bcrx C
Orig. art. has: :4 fitur6i a formulas.
APSOCTATION: none,
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1. .1,111VILLed April 20, 11)(15.
M. M. V. ; GINSBURG, V.N.
It is necessary to plan for the mechanization of labor.
Rosh.-obuv.prom. no.9:9-13 S '59. (MIRA 13:2)
1. Glavrqjr Inzhener Moskovskoy obuvnoy fabriki imeni
Kapranova (for Lev). 2. Starshty inzhener po organizatsit
proizvodstva Mookovskoy obuvnoy fabriki imoni Kapranova (for
Ginsburg).
(*scow--Shoo mamifacture)
..- .- starshiy inzhener po Orgiulizataii proizvodBtva
LUPEKINP L.A.; GINSDURGp,~. I
7be collective of the factory named after Kapranov struggles for
a high quality of footwear. Khozh.-obuv.prom. 4 no.l.-4,-6 Ja 162.
(MIRA 15-3)
1. Glavnyy inzhener obuvnoy fabriki imeni Kapranova (for Lupakin).
(Shoe manufacture)
ARKHIPKIN, 1. M.; GINSBURG, V. No
... ;,".-
Work practices of the "Vostok Productior Combine in Moscow for
the manufacture of standard shoes, Kozh. obuy. proms 5 no, 12:
13-15 D 163. (MIRA 170)
GIMSSURG, Y. P. (Leningrad)
Itme
, N~#~ Turbulent Boundary Layer of a Compressible Fluid."
report presented at the First All-Union Congress on Theorctical and Applied
Mechanics, Moscow, 27 Jan - 3 Feb 1960.
4=1NIPT !, j gM-I 49-.0 polpolkovnik meditoinskay sluzhby.
Some peculiarities of the course of tuberculous meningitis in
adults treated by streptoaWain. Voen.-med. shur. no.9:32-37
S 151. (RLFA 9,9)
(TUBIRCULOSIS)
GIN3U, Bron1r,11WI regr
Polish heavy industry at the 33rd International Povan Fair.
Przogl mech 23 no.9/10:257-259 25 My 164.
1. Chairman of the Commision for Affairs Gonneuted with the
Poznan Fairs of the Administration of Ifeavy Industry, Warsaw.
r r
- 5 Py
r n-h
GINSTLING, A.M.; 010KIIIII, A..P.
Effect of (Aastic vitraticna on some diffusion procerseo of
the woodpvAp and paper manufacture. Part 1: ~,ffect of ul-
traoonic waves on the impregnation of spruce wood with "sulfite"
cooking acid. Izvavys.uchsb.zav.;khim. i khinn.tokh. 3 no.3:
522-526 1 (XI. (MIR,". 14:9)
1. Leningradskiy takhhologichaskiy institut tseIIyulozno--bvmaz-
hnoy promyshleruioutip Wedra protnessov I apparatov khimicho:Aoy
tekluiologii.
(Woodpulp) (Ultrasonic waves)
GINSTLINGY A.M. [deceased]; BAIUM, A.A.
Extraction of gasoline and inorganic admiAtures from polyethylene
in rotation apparatus. Khim. prom. no.9:23-28 S 161. (MIRA 15:1)
(Gasoline)
(Polyethylene)
Z' A:-k,,,di . , . .
HIM,1HU'V~ E!tr Fetrovicht GOSTLIEG, ~ i- *
fd-pinasedl; -.' - I
(i,enct-loun in mixes of hard swbstancesl ilvakt:~-ii v snv-!:I;iKh
tverdykh veshchestv. 2. ispr. i dop. i:~a. I-Ioskva, sLroi-
i zd~lt, 1965. 473 p. OMA
GINT, 1
RUMv-4.j AIMSON. N., rodaktorl WARM, L, tekhntcheekly redaktor
(Disimtogrator method of making silicate mid calcium silicate
building materials] Desintegratornyl sposob Isgotoylenlia allikat-
nykh I sillkal'taitnykh tsdelii. Tallinn, Istanskoe gos. izd-vo.
1952, 107 P, (Nicrofilml (KLRA 7:10)
(Silicates) (Building materials)
YOTAND
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1"AlL Car,~15, w5i ~4 wl ';~el 't ~,D 3 Vlh Un o and -i c o-
'~i it, n u u ,--Y"% If ~.thoxsvi , V f) 1 0 1- t
i
i 1-o a I;rt A i~ t inn. L -Orcci.ksis 'A'.rh
and -tit
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tc I
mm-oil-j o"i fc. r- r %ICU rr .,.I c
vtt Wtq torn re' iMVG(k;'dA. .--I
CZECHOSLOVAKIA / Chemical Technology. Chemical Products and Their 1~30
Application. Food Industry.
Abe Jour Ref Zhur - Khimiya, No 3, 1957, 10328
Author GtLzo, M. and Ginter E
Title The- Stab 1,11 milk oil vitami'll C.
Orig Pub Prumysl. potravin, 1956, Vol 7, No 6, 269-2'[1
Abstract Ube effect of various amounts of milk and whey on the 5t&bi-
li'-I*y of 1-ascorbic acid solutions in distilled and in drin-
king water during the preparation of various foods has been
investigated. It has been established that the addition of
10-20% of milk or of whey results in a marked decrease in
the lose of ascorbic acid. The vitamin C stabilising effect
of milk has been demonstrated in many sauces rich in vitamin
C. The author outlines the basic principles of the applica-
tion of milk as a vitamin C stabiliser in the food processing
industry.
Card. 1/1
qlNTIKR, E. (Brntislava, 14alinowksho 41s/B)
Avitaminosis C & the spectrum of free araino iicidj3 of skeletal muscle
in the guinee pig. Cesk. gnstroenter. 11 no.5:329-334 5 Sept 57.
1. UstRv nre vyakum vysivy bidu, BrntiF;1Pva, riAditel Dr. A. Bucko.
(AMINO ACIDS, metab.
free amino ncids in skeletal musc. in exper. avitaminosis C,
chroratography (Cz))
(MMOLIE, metab.
same)
(SGURVY, exper.
free amino acide in skeletal musc. in Minez pig, chromatog-
raphy (Oz))
1~o
-o, ~:bstlnc-u
E:%CERPTA VEDICA See 2 .1ol. 1215 Physiology May 59
16,18. L.-ASCORBIC ACID AND PROTEIN V. CIIANGES IN I'liE
.iERUNI PROTFIN FRACTIONS AT DII-l-KRENT i'I'AGFS OF C-AVITANIIN-
OSIS I.N GUINEA-111G.S (Czech text) Nutrit.. Br.-,tif-
I'llYSIOL. 1101IFNI. 1958, 7 (.M-240) I'able., I
,;, V
I III I . I t I g 111ficalit
the first week after onutting L-us("rhic acid froun the diet, .1 sig
decrease occurred Ili the albuinins, With Mi Lill I ease Ili the a-globuill, frZictiolls.
This decrease and increase also persisted III thl' further phases of C-avitainitiosis
until death. The 0- and 1-globulinH were mit affi-cled duritiR the first 2 weeks )f
C-avilanimusis. rhe next week (from the 21st day), when the experinli-ntal aninials
began to lose weight, a permanent increase occ,irred Ili the 0-glubtilins, with I
temporary vicrease tit the y-glohulins. which ri turned to normal shortly befort,
the death of the scorbutic unitnals. P.-ague
91CERPTA KLMICA See 2 Vol 12/7 Physiology July 59
2776. L-ASCORBIC ACID AND PROTEIN METABOLISM. VI. FREE AMINO
ACIDS IN SOME GUINEA-PIG TISSUES IN EXPERIMENTAL SCURVY
(Russian text) - Ginter E. Inst. of Human Nutrit.. Physiol. Dept.,
Bratislava - 017STOL. D01tEM. 1958. 7/ 4 (409- 414) Tables 3
In the liver, C avitaminosis resulted in a marked fall in the glutathione level,
an increase In glutamic aeld and a decrease In the glutamine level. In the spleen
of scorbutic guinea-pigs a marked Increase occurred In the amount of free alanine
and a decrease in the level of free glutamine. A slightly significant tendency to a
decrease of free glycins was observed. The spectrum of free amino-acids in the
A
CZECIVOLOVAJUA/Himilan and Animal Phyciolot;y (1;-)rml aild T
Pathological) Metabolism. Vitamins.
Abu Jour 11of Zhur Diol., No 6, 1959, 26273
Au'U.i:)r Giiiter, Emil
Inst
Title L.-Aucorbic Acid a.id Protein Metabolis,n. Il. Nitrous
Dalance in Guinea PiL;s in the Early StaCe of Avitaiaino-
sis.
Ori Pu1b Di3lozria, 1958, 13, No 1, 45-52
Abstract In ~,Towinj-, juinea pit,~s which received scorbuti.,paic ra-
tions, in the first 7 days after terLdnation of L-ascor-
bic acid (I) administration, the excretion of N with
urine considerably increased, as a consequences of which
the p:)sitive aitrous balance deareased. The wei_,ht in -
craase of -:,uiiiea pi._~s on the first day of their de-,)riva-
tion of I was considerably lower thai in 1pinea. pi(;s
which received the same scorbuti6enic ration b,.,t with
Card 1/2