SCIENTIFIC ABSTRACT GERASIMOV Y L - GERASIMOV Y L

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• Collection: Scientific Abstracts
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• Release Decision: RIF
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• Document Creation Date: November 2, 2016
• Document Release Date: September 24, 2001
• Sequence Number: 3
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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fuAls and natural oosbustible gasexi therefore 1. x I and N
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ho i-hystewhemical p"perties of thooe fuels are determined salely
by uO. Frcm theea, 2 basic concerts are d6rived o-q)ression5 for the 00
Renumd wliocular weight of the organic utter, al-ecific gr,4vity of 00
fulils, volmUle mtter, and calorifia value. The "dogma of' carbonize- 00
tionO is Wo ratio of the "limiting density* to thu ~~o%:.Ity of U.e 60
actual oombusible mass. Ihe 1111miting density" is Uio d1e.%:iity a solid
Puml wu14 have if it were ampletely carbonized, I.e., it would
ocnAint or CO or KH (K is defined abovs). wCalorific Is
oalar.':lc vnlue of I cc. of solid fuel.
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ng 41,114 4
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If deriml fmm 3 cqwtxmw dal,timil. of flit- -thd if,],
welill tilt (OffalkliOU Of molid flittAl 0 1 M(l. I
Ist , + 1); 12I.M. - M
And nwlliux (A the metall oudir M(P..
310,n. Thus, I + _2 -3 -Iiitl, - Wb *0. 4hilb,
1111166 Of thM C(Mili(ICTA(KIllit OCKI by tl~ 14 Midd,14 (IAL.
k MI&A. for Al"O. Fv(j, CIA), NO J. ..11.1 Cu (I
Tbrn )ill uffing tqtmtion c1751 P Off
lopritham of ill-pacru. lepi-ion iniftit. f#* flit ltipwl
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(waclorts denote the o"Aur fructioll Ill tht. it" W pllj~ md I
so of
I in Ow leamitbtw% the mobt fraction oil Ili,, om-Ir 16,,t,
Hall r iff () pm'tirt. At t-4uil. P It. flit mit, lost im.th xo*
oxidr. wid X. - INI'llhi'M INI'llAI'M - P. , P,
K, (w Fe Alloy, ithif Alu, Co. %I, 'kild Cit 1, t.41.-l fit Ill.
mn#r 4A 1~4110- 11401'. 1 tit, vqtwtjon% fix torlill.m.l. -11-
-MM~ CUJJ KIM) 110 U,-All fit t 4h-S. 1 file efilliblorla Ill J.,X 111j,1
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aw
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1
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it*
$40'. M"01
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AT 111121 U r

IS 11
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6

GLASIMOV, Ya. L
p~ jPT39
MAY IWI
otial - Metallurgy
'Activity of Metal Oxides in Fluxes with Silicon
.lKoxide and Calola Wds," Ya. 1. Gerasimov (MW),
6 pp
"Stall' Vol VII, No 5
b calculating the components of slag In equilibrium
with binary and ternary metal system, use is made
of tentative formulAe, Trizarily based on solanty data
end azalogiea. More 'work is required in this field.
lExperbwnts were conducted on fluxes of MeO-SIO2,
110 - 8102, CoO - C&O, and others.
IBT39

0
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It a 11 it"
tl Im
L it y 4 ll~ A. I
to. 11
1"114 filifontion cobalt Ud T. I
P.Stisannor. And L. 1k
VII.Ill 114. V.6 MOMS,. Colo po'k, And
..I \vI I F.. a ,I's he It Itill 1-111liq us I lonaIr fillit,
j ('.of .0 '\,it osith ),,Is% Imr,-klml Illik.11 1-111c V,A) I
1'e'l), If NO # w6. iltr4ligat"I toy ill mon, 14
(4 0 0 0
so a Is v a 0 41 41 u #1 0 a to
so I I a 6 j -rl"
'01111,
11.01 tell 11 Is 14-1. 1 1'.111v I milph, I-
thtre-tiotwovml I
fill. -1.1.% ON 111tr(les. (21 I-ror ottals.%J., (31
file mic"rotiv imiloclints, the livir.
114ts.itl 4111oll'A's Owing Ituoltorts, jeolorfrorl"-
I'l.virlit , It, it-, '.'ml
-Iflulomr. illih I I Mile 4mill-I 4 %,37 A. fill
-ti,l X W -N t-v ',Sit I h-P, The 001 1- FrA inlif
Ilrol4*1 I .1041,I)Ift .41 94nol 14'
1.1"I" lot *111'. 34p 'jil'i 18%, NJ(I 0 Ir,4N. ;I his 4,;
Not .. O-t rv : m Ilikil. with C4.41. leffifirmicol it
A!""WA "44,014,11 Ali 41 lisp 4 It 1441' It I% diotioully I-
.lot 1. "41oplell evell iflor I'l it". %%'fill Isit), at
11 Isr"It is Almost attsiml in 3 hrd, at MXV ferti-
tiuli,111% is Answr tortit viopw to thAt at I Pill% and btm",or%
Isrutmully OmIlItrits ill lin. Mis 01 the "IA1-
tooW All jill"111.0 mi ;I funrilial to tellip.. on I Woo.
ile'lling. Own, hor 0,11, U-Sinnillit rwtko At M)". in-
frald, T4 fix, lo, In, top "), "IW in I be
tollcor "" I Proll'.0111,11t lilt ors;A-r 160 NMI., below I IiAl
of Xfo, x1i". oto,tvir VIM% in Inivetor alf the rate almove
Ihot Aw '*'0. It title, other I In's locating at I IM". the
truloorlit'stfIrtt tow NioNi, pir"Itl Itutt, tm Co.(). till. lose.
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if
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- - to 0; 4111~
0 1, 0 0400 so* go 00 11

7- '-z
54)9s 1 M 0-
C/4
SkWy of the roactions Involv*4 in the formation of c-
ball and ekkel larrites 11. VA. 1, 0110111OW',
Isi lilw)
lutiow)-*r CA. 43. &354;.

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and NA)
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110
-
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were InmUgated afUr hasting at 11001C. for 30
l 110
s
Ivourt. JAw solubility of C60 and NIO In spine
6
M#Orr#t)g wag notW at this temlcra-
tu niatIon of forritm rich In iron oxhim at
see
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V
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LO 0 * S

GFRASIUM, Ya. 1.
12 Lo 15 Mmy 194t, !!o9co-.,-, first conference Was hold cn hif-tor., of' Sovict chemistry,
conw-ned tT Commission on the History of Chemistry, Acad Sci '-'SSR. "-ny pF,.rc-rs were
presented by (ostensibly) rtembers of this Commission.
"Work of V.F.Alekseyev or, -~he Dependent Sol,nbllity of Liquids." ("oscow State U imeni
V.V.Lomonosov)
"Materials cn the History of Soviet Chemical Science," by Acad Sci USSR in
.oscow-Leningred 1950.
M3492

SIHOOV, YU. ?~, XLYACi.104GURVICE, L. L.. MUSTPOY, YA. 1.
Iron-Cobalt Alloyn
I
Deoxidation of cobalt ferrite by hydrogen. Vest, Mosk, un, 5 no- 10,19"0,
9. Monthl List of Russian Accessions, Library of Congress, Nov-ir'ber, 1952ITM Uncl.

J"
0d
ypMdca of Rare Metals II. Equilibrium of
i "Oolfromto With Hydrogen," T. N. Rezukhina,
Y, Vt' A. Morooova, Moscov State U
V. LCOonosov
*Oi~liz Xhis" Vol MCV, No 1, PP 93-99
6d equil const of reduction of manganese volf-
te;1vab R At temp 950-1,1000C. Calcd free
; ~ am h
eat of formation of volfrjunate both at
taq and urK%r std conditions - Data for high
rii,~;qiAtt accurate (�l~), but data for std
~p!s4"kwe if d&tA'for
I Aftwi A

(I 7v 1 1-1 ii ~ '~rV
at 1.
USSRItheadstry - ik-1frim
Lr 51
,,c, th Ey - Cen,"
j;_.ujjj)j,jw cf 1, d. c
"Thermoc4-mudes of Rare LA.,tals. A
:,.c~sc(-.; U imcni
T-H 'Ju. F. Smianov, Ya. 1. Garasixiov, 1 t C,,, p
. TZ,2ZI.~tjjr j
IT. 'A7,011lonozo 'r
Fiz num" 'r-, IV Ilk, 3, vj~ 305-311
X-ray anv.l of ~roilucts of roduction vith i:,,of Fe ;th lifferont Fe:O ratios
2C"/
sho,ued -it 550-1, 1.00"C anly o,.n, itter.-otal ic COI!_;Z "isurati cowsts of
or ccinxt.. I_c~l ~'rct~
,rectiction of Fe'Jol -i'Ah H, and set up e ~,y at C50--, 1500
1/7.; 7-' 20,_
anj h,~-.at. 0 rea;~:t_cn 1/7F k6 -
18 5'.* 7

Ya. 1.
"Whads"Y'A' auvft OW cob"11
mar q
wjhwOWVmvdes of UVO X04dUs Vto 6VdUft4M of Cobalt ftlfftuete Vdth HYdrO844' Tue
p16 ftoken* T* to MiNWISMS, V*A* 9 Ise to GWwdW*v Mosom UGtG 9 1100d X*V*
L
saw ns Kma" va IV$ Ob 30 go W-3ft
Iww 401 of pooduou of "deauda ICA R 2 of *0 AAS with dm*" Coll raulm
aw"d at Ima mft m -1 alk"S SwOk 007ID6 (Idth at "W" of v) md oaf, (Ift
at ="'a of eel an ftmm4 Nowwod rehAlm oomAs of so%
idth H-1 at 90D4 1000
aid sib YAP ft, *pIl ~ e"*U, Caled fm wwra at 9W.I,IWO 9M id offs* of

GXWIMDY, Tn. I.,
J.H.Sechemor's vorke on the aelubility of carbonic an)Wdride in ealt eolu-
tic,ne. Trudy Inst.ist.set. 4:277-296 152. (MLU 6: 7 )
(Carbon dioxide)

044 y f
with por-
trait and bibligraphy 141 m"Ufcam"ms, G. M. K.

ANTIPINA, T#V.t YROST, A.Y., professor, radaktor (deceased]; GIRASIMOT, Ta.O.
prrfessor, redaktar. ~ba*
[Kinetics of chemical reactions; practical studies in physical chemistry)
Wmiaheekaia kinistiks; prektiohaskis rabotj po fiticheske-i shimii. Pod.
red. A.Y.Pronta I U.I.Gerealmova. [Moskvaj Isd-vo Hoekov-skogo universitsta,
1953. 42 p. (MLRA 7:6)
(Chemical reactiou--Velocity)
fi

77712777, Ya. 14
iChW441 Abet.,
401. 4$ no. 9
XV 10e, 1954
'Omerail and Phy~lcal Chemistry
for - oltlset"CI1SmW04+H1-=;f~1/1W
1W- The Sim of A and B ta the r In
A + BT, wkk K - pejolp% at 20 6W cal. and
for 'Ad - Ca. 17.0 and 2.016 for Mg,
lj6U*6WZd'=fm 4n. For the remim MnO + He -1
Mn + RIO, A - 39.105 and B - 2.030. For reactim of
the We 1/4 MWOa + He - 'hs PeNt + Ya W + H&O the
A and B values art 9204 and 1441 lorM - Fe (d. C.A. 45,
.=1.774omWi.321forCo(d.C.A.45,OM). luthe
Nitheata.cow.oftbetuttlon'14NiWOi+Hl-'
'Its Ni4W + `611 W + H&O (1) Is obtained through equil.
studies of 3 successhe dppm pas.:. NIW04 - N1 + III-
WA + Y, Oil Ni + 'Is WA - 1/4 N4W 4- 1/4 WOs +
I/n O~. Vt Wot - III IV + 1/1 Os for which coasts. at given
at 850* and 1000' leading to log K - 1.043 for reaction (1)
at 1000'. For the miction of CA. 45. WD5a, CaMoOI,+
Ht - C&MoOa + H.0, the consts. A and B are 14,770 aid
1.5W. For the reaction 31, W(o(h + HI - 11, CaO +
'/I Mo + lljO they are 12,50D and 0.838. Free energies am
given at sevend I
Lemp. for the dissem. MWOj m MO +
W + Vs oil MW04 . 1/1 MWj + 1/1 W + 2 %. Eathal.
d " pies Io,,, the dissom - into gaseous atom
Z::n or JE T discussed on the hub of avs
able dat. ;,.W ~ rtlae:- Vaim Rysselberglie,

GERA$M, Ya. I. Prof.,REZUKHINA, T. N. Docent, and SIVANOV, Yu. P. Docent
"Ibe Equilibrium of Tungstates of Bivalent Metals with Hydrogen," a paper
Iven at the All-University Scientific Conference "Lomonosov Lectures", Vest, Moak,
no, No.e. 1.953,
I
Tranalation U07895, I Mar 56

ldliii
ING, V.P.; GJWIKOV, Ya.I., professor, redaktor; XISKW,, V.7.,
redhtktor; tWZW."lP.W.7VVftnlcheski7 redaktor.
[phase rvl6j Pravilo Ust. Pod red. IL.I.Gerasimova. (Kosimal
lsd,-Yo Mo6kovskogo univeralteta, 1934. 172 p. (KLU 8)
A4144UU WA v%4UbrlvO

4 1; : , l-'. -I q, I ~.l,
_ I , - 1 i I I
I I I;,_ ~ I .
SEUMHORAU)VA, V.I.; GEMD(OV, Ta.I.,
, OWYA, N.S., takhnicheekly redaktor
Clefmatoxetz7; pmatical work in pbvoloal chemistry] Refraktonetrila;
rakticheakis raboty po fisichaskol khtmii. Pod red. IA.I.Gerasimova.
xosk"~ Ivd-vo Hoskovskogo univerelteta, 1954. 22 p. (MIRA 8:3)
f
Refractometry)

DOI,
us
i a 1 1
w V,` and Goanimov, Ya. I.
!thii.'T~herwdynamic Characteristics of Bi-Metallic Systems by
Cadmium BismutiLe System.
0 :an ~jectromotjve Force.
it 1! iAT. Dim. Vol. 28p Ed. 4, 713-728, Apr
Ab4r&~t of~'the characteriatica'of liquid metal smeltinga (Cd-Bi) by
Otan electromagnetic force. The studies are performed by
of the atoms of cadmium in a temperature
rati n'or lo-90
al:of 400 to 600 Eighteen references; tables; gmphs.
Mon: M-11VI ~tomonosovls!moscow State Institute.
IniL6
X953
w
I.- w..
h

AMOR, LIM Wvovich; 2]MH4D-T-. TLij., professor,
redaktor-, GAUMNA, 1.8, reda T.A.
tekbnIchaskiy redaktor.
(Cryoscogr-, laboratory work in physical chemistry] Krioskopitat
praktichasklo raboty po fivicbeskay khimit. Pod red. LALI.
Oeraslwva. [Hook-ral lad-vo Hookovskago univ.,1955. 21 P.
Wak a:12)
1. Chlen4torrempondent AN SSSR (for Oerasimov).
(Cryoscopy)

NOVOSIMOVA, A.Y., otv.red.; VOLIHOTICH, S.I., red.; GMSIMOV, Ta.l.,
red.; TURITAT, Tu.I., red.; TURIYETA, L.P., red.
(Department of Chemistry of Xosoov State University] KlAmi-
cheakii fakalltat Morkovskogo ordena Lenina i ordena Trudovogo
trasnogo Inamed gosudarstvannogo universiteta imeni K.T.Lomonoso-
vs. Kbelma, 1955. 59 p. (KINA 13t6)
I# Moscov. Universitet.
(Koscow University) (Moscow--Chemistry--Study and teaching)

GERASIMOV, Ys.lo. prof.; UOYOSSLOYA, A.Y., prof., otv,red,
...WWWOM"N"Mm.,
LFrogram in physical chemistry; for the Chemictr7 Yaculty) Programma
po fisicheskoi khimii (dlia khimicheakogo fakullteta). 1956- 7 P.
(MM 11:3)
1. Moscow. Univerattat. 2. Chlon-korrespondent AN SSSR (for
Novoselova)
(Chemistry, Physical and theoretical-Study and teaching)

YROST, Andray Vladimirovich. professor; DOIGOPOLOV, U.N.. sostavite."
TOMBITIffA, X.V.. doktor khimichaskikh nauk, otvetstvennyy redaktor;
re"ktor; KOROBOV, Y.T., Itandidat khimicheskiU
Iffia, redaktor; SKIRKOVA, I.Y., kandidat khimicheskikh nauk. redaktor;
THURBUT, V.H., doktor khimichaskikh nauk, rodaktor; TILICUM, N.D.
doktor te4michaskikh nauk, redaktor; SHCHKIN, V.V.. redaktor izda-
talletva; Z)UNKOVA,-Ye.y.. takhnichaskiy redaktor
[Papers an kinetics and catalysis] Trudy po kinetike i katalizu.
Moskva, Isd-vo kkadeali nauk SSSR. 1956. 538 P. (KLRA 9:7)
1. Chlen-korrespondent AN SSSR (for Gerasimov)
(catalysis) (Hydrocarbons) (Chemical reaction)

YA
USUIRWaical Chemistry .. Geme.ml Questions, B-1
Abst Journal: Referat Zbur, - D-Iniya, No 19, 1950', 6o659
Author to Ta.
Institution: None.
Title: Subjezt and Ltml-t-,s rif Pb~y-Edcal Chmistry
Original
Periodical: Vestm. Movk. un-ta* 1956, N: 2, 133-142
1
Abstract: Pap-r based on addreas deUlyt-red at the meeting of sclentiric
commil of Ybysical Chemibtry Division of the Department VL
chataistrYA"iWarxim- State University.
Card 1/1

TOPCHITEIrA, X.V.-, PASAOTA. V.H.; SIWWOVA, Z.F.; ALIKAHIN. I'P.; NOVOSBLOVAO
A.V.; SPITSYN, V.I.-, IMOKO, I.Ir ; 121mg"'A I SHRYANOV,
A.S.; TIMT173V, A.P.; -POTAPOV, V:M,;--GTRAlk# L-go
U.S. Prubevallskii; oatuary. root. Moak, un. Ser. mat. mekh.. astron..
fit., Win, 11 no,W05-207 156. (MIRA IN12)
(Prshavallskil. ftenii Stapanovicb, 1879-1956)

GMASIMV, Ia.
"La Reduablon Ptkrblma Hydrogene des Tungstates de Metaux Transtoires et Autres
Proprietes Themookmamiques de ces Sels.11 PaDer Dresented at the 16th International
Congress of Pure and Applied I~hemistry, Paris' 18'-24 Jul 1.957

USSR/Physical Chemistry - Thermodynamics, Thermochemistry.. B-8
Equilibria, Physical-Cbemical Analysis, Phase Transitions.
Abs Jour : Referat, Zhur - Khimiya, 11o 1, 1958, 358
Author : I.A. Vasil'yeva, Ya.I. Gerasimov, Yu.P. Simanov.
Inst :
Title : Equilibrium of Tun,sten Oxides and HydroCen.
0
Orig Pub : Zh. fiz. khimii, 1957, 31, No 3, 682-691
Abstract : The bibliographical data concerningthe existence of two
temperature modifications of WO were confirmed experimen-
tally. It was noted that the siructure of intermediate W
oxides formine at the reduction of W03 was determined by
the structure of the initial preparat on. A lisb of inter-
planar distances of WO WO and WO
JQ1 at2.~2 f,c2 produced at the
reduction of the hidl- ar ur mod at,")n of WO I,
Is jven. It was made clear that the reduction of W83 II
In the temperature range from 600 to 7910 proceeded In
four staLgs and that at temperatures below 5840
Card 1/2

USSR/Physical Chemistry - Thermodynamics, Thermochemistry, B-8
Equilibria, Physical-Chemical Analysis, Phase Transitions.
Abs Jour Ref Zhur - Khimiya, No 1., 1958, 358
proceeded in three staGes, the intermediate oxide W02.72
disappearing. Based oa the obtained experimental
data, the followinC; standard thermodynamical proper-ties
of WO311 were computed: a H?98 -205.3 kcal per mole,
4 Zg98 " -186.2 kcal per mole, S~98 ~ -63-90 kcal per
mole and SO - -17.4 kcal Per degree and moie.
298'
Card 2/2

MM/Physical Che-,dstry . Thez~amics, Thermochemistry, Equilibria,
Physical-Chamiwa Analysisj, Phase Transitions. B-8
Aba Jour: Referat. Mmmal Ihimlyap No 3, 19A 7119-
Author I.A. Vasillyeva, Y&J. Gerasimov, Yu.P. Simnov, T.N. &~zu-
last kbina
Title CoMper Tungstate - Hydrogen Equilibrium and Thermodynamic
Maxacteristies of MW04.
Oe-g Pab: 22t. fiz. kbizaii, 1957, 31, No 4, 825-831-
Abst-aftz: The pressure of saturated CuWO4 (I) vapors vas messared by
X=dsen effusion method (with a tantalum ampoule) lu the range
from 1098 to 32810K. The obtained data comply with the equa-
tia-. logp (mm of mere. col.) - -2714.1/T + 0.9474. The eva-
poration heat of I is 1LA16 eal per mole. The I - hydrogen
equilibrium vas investigated by the circilation method in the
Cox& I/P -6-
plffal Cal-ebemimi Analysis, Phase Transitions - B-8

ov
Thermochenistry, Equilibria,
USSR/ftysic&l Cherlstry - TlJrm~~cs'
Mysical-Chemical Analysis, Phase Transitions. B-8
Abs Jour: Referat. Murnal Kbinlya, No 3, 1958, T120-
Author R.D. Mrshakmp Ta.I. Gerasimov.
Inat
Title Rquillbriwn of Solid Solutions of (F el-X)WOL, -with, lfydxogen.
OzIg Pabot Zh- fiz. Xhivali, 1957, 31, No 5) 996-1001.
Abstra&.: The equilibrium of the tungstate (1) of -Lhe composition (Fe
0.66MOO.34)WO4 with the gas mixture % + %0 vas stadied by
the circUation method at 902 to 1050' and the eclailibrium,
of I of the ccmosition N0.41ft.59)WO4 was studied by the
method at 9T10- It vas found roentgenographically that
Metallic V, Fe7W6 and MaO appear at the initial reduc ion sta-
ges. The sww phases appear also as final reduction products,
The eonstuts of the I lattice inw"ease with the reduction.
At 967 to lo5oo, log K9 - -10060/4-575T + 1.144. The course
Card 1/2 -8-

VSSPVPhYsic&l Cheadstry - Thermodynamics, Thermchenestrf, Equilibria,
Fbimiftl-CharaLcal Analysis, Phase T-ransiticins. B-8
Abs Joar: Pefamt. 2hurnal Rhimiya, NO 3, 19581 71X-
of curves of the K. depen4ence on the oVg---.i content in I
confirms tlukt the tomposition of the initial mixed I changes
in oonsequence of a seconUry reaction between I and MrAO libe:,-
wted at the reduction: (FeXMItl-x)W04 + nao
The elxnges of Isobar potentials of I reduction reacticm, And
of tM production reaction of I solid solution from pure salts
were crAquted. The formation of the solid solution is accom-
panied by a noticeable postive divergence from the laws of
ideal solutions.
Card 2/2 -9-

1, W
usmvp'.~Yzic*.l chemistI7 Thermoky=mics, Theniochemist,_-j.. Fquilib.-ia,
nya,Lcal-Chenacal Au&Iysis) Phase Traasitiws-
Abe Jour: Referat. Zhurnal PA-1ya, No 3) 1958) 7118-
Author A.V. Nikollskaya, P.P. Oto%ftv, Ya. I. Ge=BlA-Ov
Inst
Title Bt;udy of 1hftm)dyzazdc Properties of Binary Metallic Systems
by R.N.p. Nothod. II. Systm CaWux - Copper.
Orig Pub:.Zh.:ft%. khUdip 1957) 31) go 51 1007-1012-
Abstract: The:sTstem 04 . Co vas investigated by the e.m.f. method
(repart It 09h1a., 1955j, 93245). The electromotive forces
C!d/CdCl2/(CdxCul_,)+ of 20 liquid
alloys ~ of various composition in the rano from 0 .948 to
o.46o:&tozw.6 Pats of COod) were mewured frm 575 to 6500)
the. reaultv having been reproducible with + 0.1 v. The values
of the loprithm of the activity factor CdTiog /cdl were com-
puted from the e.m.f - and NCd. The partial heats (LCd) and the
Card 1/2 -4-

TACHM, A.A.; NIKOL'SKAYA, A. V.;
StudyInd; the thernodynamic properties of binary metallic systems
by the electromotive force method. Part 3: The copper-antimony
system (with all-ry in English). Zhur. fiz. khim. 31 no.6:1395-
1400 JO 157. OURA 10:12)
1, Moskovekiy gosudarstvenW universitat im. H.V. Lomoncisova.
(Thermochemistry) (Copper) (Antimony)

itt i, I HIM I
11-Jill, ~1!11 I hi 11 ii -Oi: 1"1111i 1! gmh A

AUTHORt Gerasimov 153 --58-1-27/29
TITLEt Correlation Between the Law of Ideas Conservation
and the Thermodynamic Condition of Chemical Equi.
librium (Svyazl mezhdu zakonom sokhraneniya massy i
termodinamicheskim usloviyem khimicheskogo ravnovesiya)
PERIODICALi Izvestiya vysshikh uchebnykh zavedeniy, Khimiya i
khimicheakaya tekhnologiya, 1958, Nr 1, pp. 183-184
(USSR)
LBSTROTs The aforesaid law for a chemical reaction the atoi-
chiometric equation of which is written in a general
form VlA, + It+ .. maybe
P212 + 91 11; + % 1 2
written as algebraical sum of the products of the molar-
-number multiplied by the molecular weight lilt
V1 M 0 (1). It is interesting to compare the term
m of the fundamental condition of thermodynamic equi-
i
librium for a chemical reaction. It is favorable, in view
Card 1/5 of such a comparison, to apply the values A , viz. the

Correlation Between the Law of Mass Conservation and the Thermo.
dynamic Condition of Chemical Equilibrium 153--58-1-27/29
chemioal*potentials, not with respect to mol, but with
respect to 4 gramm of the substance. In other words,
the specific values are applied instead of the
MDlar-magnitudes. Then the condition of the chemical equis
librium assumes the following form:T'Ai-ji . (- - 'd M 0
(2). The conditions (1) and (2) are obBervedt the former
in any chemical systems, the latter with an equilibrium,
The author combines both of them for the latter case and
multiplies (1) with a random constant K and adds (1) and
(2) "IT 1 + K) -j M 0 (3) . The condit ion of chemical
equilibrium is thus maintained if and when all specific
chemical potentials are increased for a random term K of
a sum which is common to all components, whereas the mom
lar-magnitudes are increased for an amount proportional
to the mass of the substance. The values FA, (ore,) can-
not be calculated by means of the thermodynamical methods
Card 2/5 since these values comprise the specific inner zero energy

Correlation between the Law of Maus Conservation and the 153-58-1-27/29
Thermodynamic Condition of Chemical Equilibrium
U i,o* The calculation of this latter value by means
of the Einshteyn (Einstein)-relation does not solve
the problem for the following reasonst The principle
of relativity of classic mechanics requires the in.
variability of all physical rules governing the ob.
servation of a real object in any inertial. system of
coordinates. At the transition of one system of coorm
dinates to any other which moves rectilinoarly and ren
gularly at a velocity "v" in relation to the former
system, it may be assumed that the energy of the real
object (with a mass m) changes for the term:
2
mV of a sum. Since it makes no difference in which
2
inertial system of coordinates the material object is
considered, the energy of the object cannot be clearly
determined. It contains any term of a sum which is
Card 3/5 proportional to the mass. Consequently, the law of

Correlation Setween the Law of Mass Conservation and the
Thermodynamic Condition of Cberaical Equilibrium 153-58-1-27/29
energy-conservation has only a concrete quantitative
value if the form of the motion or an exchange of mo-
tion take place which are considered in aT~f inertial
system of coordinates selected at random (e, g. in a
chemical process (Reference 1)), The uncertainty of
the absolute value of the inner energy of the obje-.t
causes also an equal uncertainty of the chemical po-
tential, The equation (2) conserves its quantitative
value in this connection due to the law of mass-con-
servatiQn in the chemical process. The latter law
plays t~e role of the energy conservation law in appli.
cation to the equation (2) with chemical transformatiois,
viz. it guarantees the fulfillment of this law with the
uncertainty of the absolute values of energy, The au"
thor is of opinion that the above considerations can be
profitably utilized in teaching the bases of thermody-
namics and chemical thermodynamics.
Card 4/5 There is.1 Soviet reference.

Correlation Between the Law of Mass Conservation and the 153-58-1-27/29
Thermodynamic Condition of Cheiaical L;quilibrium
ASSOCIATIOM Moskovskiy ,,osudarotveniVy universitet imer.i M. V.
(I.
Lomonosova, Kafedra fizicheskoy khimii 460scow State
Jniversity imeni L.'. V. Lomonosov, Chair for Physico-
Chemistry)
SU13j"ITTED3 November 2o, 1957
Card 5/5

5W
AUTHORt Gerasimov. Ya.I. Corresponding I'lember, -'r/55 6 - 2 -13 5
Tc-ademy of Sciences, USSR
TITLEt Ginihteme on Thermodynamics and the Struoture of Sc~Lutions
(~oveohc',aniye po t(,rmodinamike i otroyeniyii rv,,tvorov)
PERIODICAL: Vestnik kloskovskogo mtematilti, mekhniki, astro-
nandi, fiziki, khimii, it)56,hr 2,,pp 21~1,257 (K-1)
A.BSTRACTs
Card 1/ 2
The meeting which took place from Jonuary 27 30, 1958 was
organized by the Faculty of Chemistry of the Moscow State
University and by the Section of Chemical Sciences of the
Academy of Sciences of the USSR. There were 600 participators
from 75 scientific institutes in 34 towns of tYA USSR and from
Hungary (Sh.Lendlyel, E. Beres), Eastern Germany (G. Falken-
hagen, 0. Kelbg), Poland (S. Mints, K. Zemborak); 70 lectures
were given.
On thermodynamics of solutions of electrolytes there spoke s
A..Ye. Glauberman (L'vov), N.A. Izmaylov (Kharlicov) K.P.
31ishchenko (Leningrad) K.B. Yatsimirskiy (Ivanovo) B.P.*Nikol'
skiy (Leningrad), G. Falkenhagen and G. Kelbf; (Eastern
Germany), I.R. Yukhnov-skiy (Llvov) G.I. Mikulin (Verkhneye,
Donbass) V.A. Kozheurov (Chelyabinsk) Sh. Lend'yel ('Iungary)

Conference (n The rmodYnauiies and the Structure of 3oiUtions '35/35
F J.1 4
A.I,';. ',7ukhotin (Leningrad) Ye.N. Vasenko (L'jov) V.P. Vasillyev
(Ivanovo) G.I. Akhumov (Leningrad) S.A. Shchukari,,v (Leningrad).
On thermodynamics of solutions of nonclectrolytei3i
M.I. Shakhparonov (Moscow) A.Z.. Golik (Ki,rev) 1.:7,. Fisher
and V.S. Kuzm-.'oh (Minsk) K. Zerborak (Foland) anti '.1.V.
Sventoslavskiy, G.L. Starobinets and V.F. Tihavyy (Vinsk)
Y.F. Lantrata and A.F. Alabyshev (Len-inurad) I.R. Krichevskiy
and N.E. Khazanova (Moscow) B.B. Kudryavtscv (.,,,oscom) V.r.
Nozdrev (Moscow) A.V. Storenkin and A.G. Morachevskiy (Lenin-
grad) I.T. Sryvalin and O.A. Yesin (Sverdlovsk) j..V. Bartenev
and A.A. Remizov (Moscow) D.S. Tsiklis (Moscow) U".D.Yefremova
(Moscow) M.I. Usanoviel- (Aima-Ata) L.7. Lanshina (Voscow)
On the structure of solutions :
O.Ya. Samo.TIOV (Moseuw) A F. Kapustinskiy 0"oscow) V.L'.
Chulanovskiy (Leningrad) ~.L. Levshin and Ye.C. Baranova and
L.D. Derkacheva and L.V. Levshin (Moscow) B.S. Neporent (Le-
ningrad) M.P. Vuks (Leningrad) S. Hints (Poland) R.P.
Roshchina (Kiyev) N.G. Shlenkina (Tula) A.M. Sarzhevskiy and
A.V. Sevchenko (Minsk) L.V. Levshin (!Sosc~.,w) Bertenev
Card 2/2 (16oscow) M.A. Styrikovich (Moscow) Yu.1. Solov"yev (Moscow).
USCOI,I-DC;-'30.,5'27

GMSIMV, Ys.l.-, XRNSTOTNIKOV. A.R.
Thermodynonics of zinc oxide reduction by carbon monoxide and carbon,
Izv,vyo uchab# zav.; tevet. met. no.3:.54-62 ' 58.
(MIRA 11:11)
1. Moskovski7 gosudarstvennyy universitet i MoRkovskiy institut tavet-
n7kh metallov t zolota.
(Oxidation-Peduction reaction) (Zinc oxide)

aIRASIMV. Ta.l.; TLPVSXTBV, A.M.; POZHAWKATA, G.V.
Determining thermodynamic parameteis of chromium-cobalt allc,ys
by measurements of saturated chromium vapor. Isel. po zharopr.
splav. 3:56-60 158. (MIRA 11,11)
(Chromium-oobalt alloys--Thermal properties)
(Vapor pressure--Measurement)

BOV/55-58-6-30/31
AUTHORS: Gerasimov, Ya. I., Yeremin, Ye. N., KiBelev, A. V., Lebedev,
Topchiyeva, K. V., Shakhparonovt M. 1.
TITLE: Training and Education of Teachers of Higher Schools,
and of Scientists and Researchers '0 pu.tyakh podgo-
tovki prepodavateley vysshey shkoly i nauohnykh re.botnikov)
PERIODICALt Vestnik Moskovskogo univeraiteta, Seriya matematiki, mekhaniki,
astronomii, fiziki, khimii, 1958, Nr 6, pp 235 - 238 (USSR)
ABSTRACTs According to the opinion of the authors the actual training
and education of qualified specialists in the fie'd of natural
sciences suffers from certain drawbacks: They firist go through
a three-years' stage as candidates. This kind of activity is
in no way a guarantee for thoroughly penetrating into all
necessary fields of theoretical and experimental work in the
domain of physics and physical chemistry, and of the other
sciences related therewith. Besides the time is too short for
defending and proving again the truth of the scientific in-
vestigations carried out. It is obvious that the 'brevity of
time prevents the candidates from ascending in their investiga-
tions from a perfunctory to a more scientific level. There is
Card V3 no possibility of selecting certain more interesting themes,

Training and Education of Teachers of Higher SOV/55-58-6-30/31
Schools, and of Scientists and Researchers
mad the like. Finally the time is too short for giving the
candidate a sufficient pedagogical training. Consequently, it
is suggested to replace the term of three years for candidates
by a five years' term for assistants-on-trial during which time
the practical work and the seminaries will be-conducted accord-
ing to pedagogical principles and the scientific investigations
will be carried out in accordance with the ~Ians of the Chair.
Ths examination on the special scientific training: can only
be passed, if the aasistant-on-trial adduces the proof of having
made a number of particular scientific reports~.'avd of having
passed the examination on the fundamentals of marxiam and
leninism, as well as that of foreign languages. After having
completed his trial term and having successfully passed the
final examination, he m4y become candidate lecturer at his own
or at any other school. By a well-controlled guidance of the
sesistant-on-trial, an excellent selection is wartanted of
first-class men of science. Besides, this system irill success-
fully further and advance the scientific work of the assistants-
on-trial. The authors believe that the chief result of this
Card 2/3

Training and Eduoation of Teachers of Higher SOV155-!ia-6-30131
Schoolep and of Ocientists and Researchers
roorganisation will be a good training both in the scientific
sector and, in the pedagogical field, and will theritfors be
Me best way of forming first-class higher achool instructore.
Card 3/)

AUTHORS: Yeremin, Ye.N. , Ziselev, ,',.V. , .kuratov, S.M.
Topchiyeva, K.V., FrofEBsors; thakhparonov, 11.1,, Doctor of
Chemical Sciences and Lebedev, V.P., Potsent
TITLE- The National Economy Needs Phypico-Chemists (Narodnomm kho-
zynystvu nuzhny fiziko-khimiki)
PERIODICAL: Vestnik vysshey shkoly, 1958, il%r 7, PP 14-16 (US,,',R)
ABSTRACT: The authors stress the necessity of creating special faculties
an physico-chemistry in universities. At present, faculties
train chemists whose kncwledge of physics is rather limited.
The student is not trained in a special branch of chemistry,
end the shortage of time does not allow hin to develop his
knowledge of practical methods,
ASSOCTATION: Moskovskiy P_-osudarstvennyy universilet imeni Lotronoscva
(The Moscow State University imeni L070nOSOVI)
Card 1/1

AUTHORS: Ccrasimov, Ya. I., Correspondine Me,-,.ber 30-58-7-35/419
!SFVS~SR, 3 M _~r_ronov, M. I., Doctor oi nemical Scionoes
TITLE: Tharmodynamics and the Structure of Soliitions (Te=odinamiha
i stroyeniye rautvor~,v) Trnnaaction s of the Conference in
Mo~~Icow (SoveshchaniYe V Mos!.Vo)
PERIODICAL: Veatnik Akademii n:iuk SSSR, '958, Nr 7, pP. 122 - 124 (USSR)
ABSTRACT: This conference was callt.,,I 1,i thc Dc:.,,!rt.:-,ont of Chornical
Sciences of the AS USSR V. Chemistry Department of Moscow
University (Otdeleniya 1;hi-,,-iichcskikh nauk Akademii nauk SSSR i
khimichaskiy fakulltet Moskovsko-o univ-~rciteta); it convenea
froa January 27th to January 3ot~- It was attended by about
600 physicists, che-ists and thermal power enjineers from the
Soviet Union as well as from the people's democracies. Problems
of statistical mechanics were diEcussed. In the development of
modern molecular theory of solution,% new nothods are being
worked out. The theory deals with new methods of mechanical sta-
tistical computation of the thernodynamic and kinetic properties
of multicomponent systems. The existing methods permit a
nufficiently exact computation of the free ener6l as ivell as of
Card the properties of the diluted solutions of electrolyti)s and non-

..7 --8 1
Thermodynanics and the Structure of Solutions. -7-35/49
Transactions of the Confere.-ice in Mo.,:cow
-eloctrolyten connected with it; amonj the mentioned me,thods
those suj~:estod by N.V.Bogolyubov, and his collaborators are of
greatest itaportance. In the reportz; ?.nd discussions on 'the sta-
tisitical theory of solutions p~irticipl-,ted.A.Ye.GlnLuberm;m. A.Z.
Golik, O.A.Yezin, G.Kellb-, Ger,---Yj De-.iocratic Republic (GDR)F
V.A.hozheuicv, G.I.Mil-ulin., 11.I.U.,;anrjvich, G.Fallkenkhaien, German
Democratic Republic, I.Z.Fishcr, I.R.Yukhnovskiy and otliers.
The nain part of the reports and infor7~ations dealt with the
problenD of the molecular structure of the solutions, The consid-
erettion of some proble--s of the theory of fluctzl~-Aion pli.-yed an
important part. G.M.Bartenev, M.V.FLI:s, I.R.Kricherskiy, B,,B~
Kud-ryavtsev, Y.F.I;ozdreT, G.F.Roshchina, V.P.Skripov and others
participated in the reports and the discussion concerning the
problens of the theory of fluctu%tions and critical phenomena.
Great attention was laid to investi---tion3 of solvatation, asso-
ciation and dissociation of molecules in the solution by optical
and thermodynamic methods. N.A.IznjrlOV, V.L.LeTshin, Sh.
LvidVel,lbint.-:nry (VeYjJriy.-i), A.Ye.Lutskiy, S.Mints, Poland
(Palfsha), V.FAIV~ollskiy, G.L.St%robincta, J~%.Y.Sukhotin, Yu-I-
Card 2/4 SolovlyeT, M.I.Us:-.novich, B.M.Chul-inov,,kiy, K.B.Tataimirskiy and

T*h-,-x,:!oi!yj~u::icc -~j.O t~:v, SII--,,,ct~-.-,~ of !3)1~",iu: 7 /1,; 1)
of the in '~,,-)-Cow
oU:,er3 delivered rc,tortn z.:id on those -Iroble::.s.
So:m ,-robIc,3 concerninr, phc,-,o:-.cnolo,;icI.l t.-.crnodyn:~:-iics of
liquid colutions Lnl ~.lloy-- wore ,.!,-o f2iscussed. T'-c li~iits of
ti~::Iic~Jion of t!-.(: Ifir:,t lr-.%f by Konov-,lov and the second law
I - :
by VruvnI:iy '.1c:,
if %,:IJ
)-' , t.,.-4rd com;~o..e~-,t
u,i the !;olubility of s,:Ilts in vater inventiuzted. Tile ther-mo-
dyn ,!; I i- c-~rD,:crtiett of a series of mu,tallic alloys ivere inve-
oti ---ted and ti.e ro-,ilt-- of re.,carch vior'~~ of oversnturated
solutions %.e-rc TicntioncL!. The lne-arinZ of the rc?orts and Oiscus-
joined '-,,y: K.* Zc:-:b--,)~ O.A.Yesin, A.G.
!Ior,-:xhcv.,.I-iy, V.7.SvcntorIav,-':-4y, (1-01 ra),
S!.Ulltn, cv, ot...,r-,. On of V~r, Co;-.-~ittee
4
of io's of t ~: A3 (I
011 t- -,Lrj-;~n of for the of
Zcic,:tific in thir, field. V-,c, confere::ce recorded the
Lrhievc.-m,~2to arde=om In the dcvclo~I,-.cnt of reseurch worl, in this
Car 3 3/4 NICIII for a cucce:~sful development.

MA 'I " T4 6 ~ 0
Conference on the thermodynamics a~d structure of solutions.
Yest*Xookoun*Ber,mat.,nekh.,astron.,fis.,khim. 13 no.2:251-
253 '58- (Kin 12; 2)
1. Chien korrespondent AN SSSR-
(Thermodynar4ics) (Solution (Chemistry))
I

T11 OR S Gerasimov, Ya. 1. , Shatenslitu.,~,,.. A. T. 114 7
,.,,r'LE: Yakoy Iosifovich 01"shunakiy (Yakov Iosifovici 01~shanskiy)
Obitu,iry Votice (Ifelkroloc.)
PERIODICAL*~ Mir-nal f izicheskoy k1jimi-i : 1'55E, Vol '2, itr
PP.. 1166 - 1107 (USSIO
AMTRACT: Yakov losifovich Doctor of Chemical Si-iences'
died at the a,~e of 46 on Jzuiuarj, 6, 1'1`5,'~~ He ' eld lectures in
the field of physical chemictry :md de.,At with the invcsti~:ations
r
in the field of Vie physical clie:-.--.-,ti-.T of hiji te-mocraturer,
Ith relation to tl)e Vieory of V,u for--.%t~on of rocks and
r
, A.
nerala. these beinc an inportant contrib,,,.1.ion to the theory of
the formation of majmatic milfide de;j-)z;jt6,,. ac well as to the
tbeor~~ and practice of mot,lllur~.-.ical He developod
solic, original theories for the (-~iuilil)r~iim up to 2500 0C. His
last works dealt with V-~u t-leor,-r of Vie develop.--.ent of tber.-lal
waters, in which lie chowed that the sali:t~Discan dis.)Iay a mij;ra-
tiov of subctanoe, althou.-h Viey ,.-,iy 'ne pr-xtlcully unsolvab1c;
lie ullso z,.howed t~;ut a rearran, ~c--e-t cf t,.e w-r~icles in the solid
C ard 1j ~2 pli!,we tales place. In connection ne no:.ie propol"als

Ya.kov Iosif"ovich Ollslianakiy
for the use of radioactive
about: lo works, including
carried out hi!~:self.
-,(e -~2 5--46/47
ivotope;3, and he pulbh_S*;,ied -Itoj;ether
experi~::ental vork;3 which lie had
Card 212 1.. ~).
, o -

GIMMINOVO Ta.-I
Resolutions of the Conference on Thermodyngmic6 !md Structure of
4alutions. Zhur. fiz. 1-him. 32 no. 6,1443-1445 Je 158. (MIRA 11:8)
1. Prodgedatell orgkomitata Sovejabehadya po ter-lodinamike i
stroyealyu rastyorov.
(Solution(Chamistry))

-5(4)
'76
AUTHORS: Vveher, A. A,, Geranimov, Ya. 1, C~CV/' --'2-12-27/3---
0-
TITLEt Investigat."on of Thermo~dynamic Pro~or t 4 e Sof B- nary eta!
--f Eli?ctrorriotive Forces
S~,stema by Means ~jf 'he e 3 6
he e 0
(Issladovaniye termod-inamicheskikh svoystv dvoynykh
inotallicheskikh sistem retodom olektrodvi;-.hushchikh sil)
I'L The. Copper-Antimony System in S,,~Iid State (11'. Sistema medl-
aurlma v tverdom sostoyariii)
PERIODICAD. Zhurnal fizic lie skoy khimii I 1?"') 6, V-~11 ~,, Nr 12, j)i) 28 55-28~10
(USSR)
ABSTRACTt Measurements wore carr~od out, on copper-antimorky and pure-copper
electrodes in a fusion of potassium chloride and lithium
chloride ccoitainirE s=e copper-1-chlor-ide. From the values
obtained the eq-tiations for the deperidence of the eleitromotive
force (EU) upon the temperature %,ere developed. The values
calculated show a maximum deviation of I,' from th.~ measured ones.
Entropies for copper, antimony, and th,? c3mpounds Cu,,Sb and
CUISb at a temperature (if 775-"K were then calculated. These
I
entrzopy 7alues deviate somewhat. llr= the test results, which
Card 41/2 may be due to the method of approx;rnation and the influence of

Investigation of the "I'llic- -,-.c,dy nani` ~~ Pr-q-ert'ios of S ()V/7 6 - 1z 2 - 12 - 2',7/32
Binary Metal Sir8i ems by Means of t~,~e Methc-J ~f =-c~ tive Forces.
IV. The Coppe,---Antimi.~ny System -in Solid Stat.?
t)fho-r 1'Fi,,tt.;.rs wlij'cih were c.-,:nsirlfr~rod. The positive entropies
in the format-'on, .-,f ceppexr-a-t-imony alloys can be explained by
,~Ihur,gen the in the Cu Sb and Cu SbIattices.
2 3
7he system 4E, heat coefficients
ayj0i. negati-;e is-ijarf,- Aizs riglt be explained by tbc
u-ppearun~-& cf :,nmp~urds. Th,~ Coefficients
f~.r the (%_Sb are;
..1.81+ 0.02 krai/ at.
r
There are fig-~-r;~13;4 t,11')-',~3, ar.1 -forz?nnes, 7 of whi-ch are
I Ovi e t.
ASSOCIATIOJ-. Ilookcvskly gosudarsven-.%yy 111. V, Lomonosr,,-,rp.
(M6,11r:6111
SUBMITTED: Jilar:;h
Card IC12

-AUTHORS: Geyderikh, V. A. SOV/2o-12o-6-30/59
Corresponding Member, Academy of Sciences, USSR.Vecher, A. A,
TITLE: Thormodynamics of the Production of the Highest Iron Anti.monids
(Termodinamika obrazovaniya vysshego antimonida zhelaza)
PERIODICAL: Doklady Akademii nauk SSSR, 1958, Vol 12o, Ur 6.,
pp 1274 - 1276 (USSR)
ABSTRACT: This is an investigation of the production of FeSb 2 from the
elements according to the reaction Fe(so1id)+2Sb(solid)=FeSb
2
by means of the e.m.f.method. This was done by Investigating
the dependence of the e.m.f.of the cell Fel Fe2+, XCI+LiCl
(solution)lFeBb 2+Sb upon temperature in the interval 410 . Ooo,,
12 melts with a varying composition (within the heterogeneous
range FeSb2+Sb of the phase diagram of the Fe-Sb system) were
investigated. The experimental methods have been described
already earlier. The results of all experiments were interDreted
by means of the method of least squares, The equation
Card 1/3 E- 0,1497 - 0,00004 T (in Volts) was found for the function

Thermodynami..-s of the Production of the Highest Iron SOY/2o-12o-6.1o/19
Antimonide
E-T(T). By means of this equation It is possible to compute
the variations of the isobaric-isothermal potential, of
enthalpy and of entropy in the production of FeSb 2 by means
of this reaction: AZ.-nFE--6,9+0,0016T (Kzal/mol).
A H--6,9+ 0,4 (kcal/mol).-2,30+ 0.1 (kcai/gram atom),
A S-1,~� 0,4 (kcal/degree..MolT-0,6t'O,1 (kcal/degree,gram aton).
Differences between these resulta and that obtained by other
authors and the possible causes for this fact are mentioned,
Finally the theoretical calculation of tZ by means uf the
equation for the liquidus range of the meltability diagram of
the Fe-Sb system is presented. The agreement attained is
satisfactory. There are 1 figure and 8 references, 6 of whi~~h
are Soviet .
ASSOCIATIOV: Moskovskiy gosudarstvennyy universitet im.M.Y.,Lomonosova
(,Moscow State University imeni M..V.Lomoncsov)
SUBMITTED; Uarch 1, 1956
Card 2/3

Thermodynemion of the Production of the Highest Iron SOY/2o-12o-6-30/59
Antimonift
1. Antimorgi-iron systems--Production 2. Antimony-iron system---Therrx)d,,rnea:.(..
propertSes 3. Antimony-iron systems-Enetropy 4. Antimony-t_ron
.--Erithftlpy 5. Mathemtics--Applications
Card )/3

.18(6)
AUTHORS3 Alekseyev, X. V., Gerasimov, Ya.I.. SOV/20--121-3-26/47
Corresponding Me~be_r_,I-a~----
TITLEs The Investigation of the Structure of the Liquid Bi-Sn Alloys
(1asledovaniye struktury zhidkikh splavov Bi--Sn)
PERIODICAL: Doklady Akademii nauk SSSR, Vol 121, Nr 3, PP 488-491 (USSR)
ABSTRACTr The properties of the liquid alloys are deturmined essentially
4y the force of the intermolecular bonds and by the grouping
of the molecules. Therefore it is important experimentally to
determine the structure of the liquid alloys and the (at least
qualitative) connection between the structure of the alloy
and its properties. First, an equation is given for the cal-
culation of the curve of the radial distribution (for the case
that the liquid consists of several kinds of atoms). The
authors investigated the system Bi-Sn by means of the electron
diffraction instrument IM-4 which was adapted to experiments
at high temperatures. The method of the free films which was
suggeated by A. I. Bublik and B. Ya. Pines (Ref 2) did not give
the expected results. +he best results were obtained when the
Card 1/3 film of the free metal was fastened by very thin quErtz layers.

SOV/20-1 21 -3-26/47
The Investigation of the Structure of the Liquid Bi-Sn Alloys
The preparation of the samples is discussed in a few lines.
Xtesurements were carried out at t - 2900. the curves of the
experimental intensity were deduced from th6 data of these
measurements and are shown in a diagram. Tho positions of the
diffraction maxima are given in a table, First the authors
give a detailed report on the pure metals, For Sn, the position
of the maxima agrees well with the data found by other authors.
I~he structure of liquid Bi depends in it high degree on
temperature. For the intensity curves of the intermediary
alloys the following rule was foundr There JB a gradual trans-
ition from the type of pure Sn to the type ;f pure Bi without
any additional maxima. Ihe values obtained for normalized in-
tensity were used for the calculation of the radia" distribution
function. The integrals were 'calculated by means of an
electronic computer. The curves of radial distribution are
given in a figure.. 1t is advantageous to SLbdivide the in-
vestigation of these curves into 3 stages% 1) Pure Bi and pure
Sn, 2) alloy of eutectic composition; in this case the first
maximum of the radial distribution is the result of the super-
Card 0 position of 3 maxima, The place of the first maximum corresponds

5 -C L) V/2 CI - ~ 2z 2 6 / 4 7
The investigation ef the Stru-.ture of the Liq,,i-,d Bi,Sn Alloys
irell with the leRst distance between the atoms in liquid
Sri (3,25 -- 3;35 A). According to the calculations discussed
by the author, -i.8 Sn atoms are located at a distance of
3,35 A around a given Sri atom Moreover, 2 1 Bi atoms are
located at a distance of 3 65 k But if B.J is located in the
center of the ccordi-nation sphere. 2 Sn atoms (r - 3:,85 1)
and 5,,2 Bi a-~oms (T ~ 4,45 1) are arranged arounei this Bi
atom. These results imply a distinctly exp-ressed tendency
towards miorobeterogeneity 3) Ailloys of a zompooition which
in between eutectic composition and tin pure components. In
this oase, the maxims are not resolved into thei:, components
and their position does not coincide with the poisition of the
maxima of the pure components. These phenomena may be caused
by the total misLibility of the components. Thert are 3 figures,
I! table, and 10 TeferenoeB, 8 of which are Soviets
ASSOCIATIONi Moskovskiy gosud.arstvenryy universitet im. M. V. Lomonosova
(Moscow State University imen-t M. V. Lomonosov)
SUBMITTED.R April 16, 1958
Card 3/3

G
AUTITC1.3: SOV,'12 a - 12'- 5-2 1/56
It U
V Geyderikh, V. A.
Acade;.iy of Scie.-:ces, USSR, e..ier, A... t.
Tj'?TE. The Tilermodynamic Properties of tIi-:? Solid Solutions
Cu-M and Fe-Co ( ~,,voystva tverdyl-h
rastvorov Cu-Ni i Fe-co)
PERIODICAL: Doklaly A'.:ademii naul: SSSR, 1958, Vol 122, I-Ir
PP 834 - o7.6 (usn)
ABSTR t.CT: The authors determined the free ener~;y, t.'-Ie i-~eat
or for-i-tion, and tl~e entropy of fo-mation of the
alloys cl~-Ni and also the activity of 4 ron in the
allays Fe-Co by the met.'iod of electromotive forces.
The electromotive force of thle alloys Cu-Ni was
measured in a Gaalv~~nic ele:-,ent: Cu(solid)IC11"
(,-lei t) CuJ+KJ-+IiaJ)ICu-!Ti(L-.-Iloy). T,,e alluys were
~rcdtzced from nic::el- r.~-.d Zinc Powder bL, pras-ing
and subsequent anneali,,U(for a ~Izrdtion cl~. up
to 100 hours Lt 1050-12500C) !--n(' ana lyzed after
the smelting test. The results obI,:-.J-ed by tliese

Card 1/It experimento ~ro shown by a The elect:=otive

les of V:C, 05011/2o-122-5-24/!"
force p---,rfoctlZ~ cc,,:,,,' , t :.nd re~jrodrzcible
0
wi'.Idn a li:iiit of evro--n or 195 to 2"'0. Frxi tl,o
edoctromotive force and its te i-lor;-turo
V.~C ac-tivi~.t; (U cu ), t~.(l rc-!~.tive lxat content
I
.U -t:id L`:e ci~ -,,i-t,~.re of tale
Cu were tle!,-mr ined f01' eL'--C1I Of tile
alloYs. By means of C;r:-phical into,--ration t~ie
heat -md entrapy of f,Dr-Xtion of 'U'ii:3
system, were then, fou!A. Forl--mlae Lare given for the
de-cri.:tion of the exleri7:iental results
T-ic- s~
'u-:ti fo--.-is a continuoun serios
of oolid --olutions. Acc-)rdin. to t 4 - ven
4 the ~.-.uthors, t-P o:,-stcm, Ciz-111i furnl..-hes positive
devi:,.tions from Raoult's (Raull ) whi,:~h, however,
are leso t~ioce for t7,.e sz,stem Au-Fe and Au-Ni.
Howe-,-Cr, tj-~C CI(CO-IS ei)tropy CA t'-e mix~i:rtl (-izbytoch-
naya entropiya smeoheniy..) of Vi,-~ :'11-1,ys 'u-1:i are
..e I 7'-Aivi~ .o -) -1(..rod 1,.A io,, ()f' %t in t h e
Car, 2, 1
L1-(:,ys Cu-Ni cou.10 ',)(- u,,;co,-rt~-;,-c-d ~~y .?hic

The Thormodynamic Pro-perties of the Solid SO.IjUt4onS SOV/2o-122-5-24/56
Cu-ITi and F*-Co
investi.--t ions because the difference with rcspect
to diffrangibility between the copper- and nickel
atoms i-- too However, measure~2ents of the
A c rl~ .. ea
, -ctric ro-i~:ta.,ice and t~ie m, ;-, tic _ropertieB of the
cop:)er-n.4c',-eI ,.lljyj indlicate t~~.e exioti~nco of a
certain or~_*er in t,ic~r- This orde--ed sta-~e '.s probably
n,ee,ted 4'C~ self-action of t-e free electrons
Co-
(valonce elfctrons-) of cop~,er and nic'~:el. An ordercd
state in Cu-Ni-Iloys is. accor.,!iz,-- to the authors'
opinion, :_Iuito possible. The ordered state of the
Cu-Ni-alloys exercises consille.-able influe:.:ce upon
t,.-,e values of Vie excos-- ei:tropy of for:,iation. The
highly ne~;ative values of Vie exce3s entropy (if calculated
fro.-,, relativelX low positive he-As of formation) give
positive exceso free ent:rGies. The electromotive force
increa.,~es i:iorc! rapilly th_,n linearly with increasing
tem.peratu_,e. 11-~cfron it follows 1) that with in-
creasing the positive deviations from
C~Ird 5/4 RI,)Ultls Invi rrtiJ~Ily dec.-ease, and 2) the heat

The Tnermody' i,,-:iic Propc-rties of the Solid Solitions SOV/2o-122-5-24/56
cu-Ni c)
and Fe
t'-.e ertropy of formntion Of CD "Der-3i" C alloys depends
R-i-ther of t,.e stn,.cture
cop,~cr-zinc -1137s -e-, lo '-e nccec
~~z 1-y. The
v-Ax,c!Z; of the acLivity of i--on in Fe-Co'-Le-alloys
fou.nd by the ;.uthor3 -ohm,.-n 'uy -,. di,,,,~ram r-rd nLree
well t:,c- r. -.-al Lo o",t., i:led T.S,-.,ov et ~1.(Rcf 11).
F- (:~. - ~ - r.1, f iE; d 1 c c e:, , IT f , I'; I c! i ar c
S,., T:.~, --,--tv c, Loimonoc- ova
Ly ,O-_. L V)
SUB'-'!TT"Z'D: july 1, 1)~`
Card 4/4

24(8)t 180) S011/20-123-5-27/50
AUTr,ORS:
Co
Vecher, A. A., Go rresponding Member,
Academy of Sciences, USSR
TITLE: The Thermodynamic Properties of the Alloys of Copper With
Palladium (Termodinamioheakiye avoystva splavov medi s
palladiyem
PERIODICAL; Doklady Akademii nauk SSSR, 1950, Vol 123, fir 5, pp 666-869
(USSR)
ABSTRACT: The authors determined (by the method of
electromotiveforoes) tile free energy, the heat and the
entropy of mixing of copper-palladium alloys. For this pur-
pose, the electromotive force of the galvanic element
Cu/Cu+(halide solution)/ Cu-Pd (alloy) was measured. The
method of these measurements was described in a previous
paper (Ref I). Melts of potassium chloride and lithium chloride
of eutectio composition and also of sodium iodide and potas-
sium iodide of minimunmelting temperature (- 590 0C) were
used as electrolytes. In the first case, 1% CuCl was added
to the electrolyte, in the second case Cui. In the
Card 1/3 majority of the experiments, molts of potassium iodide$ sodium

3OV/120-123-5-27i150
The Thermodynamic Properties of the Alloys of Copper With ?alladium
Iodide, and copper iodide of the above-diacuesed composition
were used. The preparing of tho alloys is described in shors;
The exporiments were carried out at temperatures of 600-760
in an atmosphere of purified argon; they took 130-150 hours.
The experimentally found values of the electromotive force
for any composition were plotted against temperature, and
a straight line was drawn through the experimentally found
points. The deviations of the individual valuea of the electro-
motive force are not higher than + 0-5 - 1%. The further
evaluation of experimental data was described in a previous
paper (Ref 2). The second figure shows the ac:tivitg of copper
and palladium in alloys at the temiperature of' 1000 K. The
third figure gives the integral values of the heat, free
energy gnd entropy of the formation 8f copper-palladium alloys
at 1000 K. At temperatures above 600 , the investigated al-
loys were not ordered. A tendency towards ordering is distinct-
ly markedp however, aloo at high temperaturea. This conclusion
may be drawn from the negative deviation of the thermodynamic
I
functions from the ideal laws, from the strongly negative
beat of mixingo and from other phenomena. The thermodynamic
Card 2/3 properties of the copper-palladium alloys at 1000 0K (uhich

SOY/'2o-1 23-')-27i- 50
The T~ermodynaraic Properties of the Alloys of Copper With Palladium
were found by the authors) correspond to the existence of
superstructures in these alloys at lower temperatures.
There are 3 figures and 6 references, 3 of which are Soviet.
ASSOCIATION: Yoskovskiy gosudarstvennyy universitet im. ':'. V. Lomonosova
(Moscow State University imeni 11. V. Lomonosov)
SUBMITTED: August 29, 1958
Card 3/3

18(6)~ 5W SOV/1 5/6-59- 1-4/54
AU2 HC .`~S i Vecher, A. A.,
T'he Construction of a Jart of the Liquilos l,;.,rve of the
System Copper - Antimony Acccrdin,- to Tlc=,dynamic D,'V.
ko-Po2troyeniye chasti krivoy li'Xvi,2,,jFa ::;ed' - -,~rlr'a
po termodinazichoshim dannym)
PMUODICAL: Fauchn;,ye dolclady vysshey shkoly. jiMiya i khimich2skaya
V
tekhnologiya,, 1,0510, Nr 1, pp 16 - 15 ('u3---R)
ABSTUCTt The thermodynamic data used arn not lintel hore bul are civvn
,in two previous publict-tirris by the outhol-.,; (7,cf I,,-,of '21/'
The liquid-Lis curvo botwcon 0 and 40 wVfo of copper and the
position of the r-axinum b,-!,;;onn 50, --n(i 6C~ wtr!' O-f copper
are given a close inveqti.-,ation. For calculating the curve,
the dc~cndcnce 1t- a (.) n-per 0.05 atcr.,.J-,, yields of anti-
0 Sb
mony bct%,.,c-r!r. C-95 -- MC, Sb in tlc t,---rrcr--tura, r--nee
800 - 10000X is calculatud (Table 1). Thc values found are
in aCrcei.-'ent da'a oltainei by ct!,c!r authars (Xa~;ram,
P- '. 2~ ,
Thc bot!x-~?n V~c- --cint and tl.e
Card /2 tc--ctic point of Cu,,Sb ic similarly calculated from

ill ,r - r,--r ,,
Tho Coiatruc-Uon of a Part of Ue M-IliLidlin Cr~cvc, of t"-c
System Copper - Antimony Acecrdij,' to Data
the -condition 2 IC a )+ 1C a -:,"Cu2Sb
C, Cu(ailoy Sb(allo,, 4.575 T
at 8CO 850 K (thv data for this calculpltion -are given
~n refe'n.'I""o 2). The tein,,oraturc de:ondence of tho electro-
motive force of the Galvaric coll
Cul scild :cu+ (in YCI, .- 4 IACI- + CUC1 ;Ip1t)jCu-Sb liquid alloy
sho,.-s that the maximuti .)f t'~,o li,~uidus curvo is rpar the
empound Cv $I and no", as has been prosu::Ld by other
5 2 .1
asa4-hori, near C,,~.,Sb. The ~haso dia,;ram of flie system. Cu-Sb
~s ahowp, Zoo::-e aro 7 fi,~tiros, 21 labIes, and 6 references,
of Vhi-,11 n~-e sovist.
ASS~CIATNIT: Kafcdra fizir"es,-ey khimii Mos!,ovj::c-!-o gosudaTstv~-.nno,,Io
universitete. in, V. Lf.mcno~,,ova (C',,air of nhysical Chemi-
stry of Moscor. State Univ ty imeni M. V. -,omon,:,,srv)
SUBM I .*'Ti;D. June 30, 1958
Card 212

5 k2) SOV/78-4-10-2/40
AUTHORS: Yevoeyev, A. I., Pozharskaya, G. V., Nesmeyanov, An. N.,
Gerasimov, Ya. I.
I.--,.- ~..... ..... ----
TITLE: Vapor Pressure of Lithium Fluoride
PERIODICAL: Zhurnal noorganicheskoy khimiij 1959, Vol 4, NT 10,
pp 2189-2191 (USSR)
ABSTRACT: The determination of the vapor pressure was carried out so-
cording to the effusion method in a nickel ;hamber because
this metal does not react with lithium fluoride. The tempera-
ture of the chamber was measured with a Pt-:PtRh-thermocouple
and a potentiometer of the PPTN-1 type and the galvanometer
of their2l/4 type. The easily volatt'a impurities (Li 2 CO 31
UOH) were removed by heating in vacuo up to 7000, The results
of the determination are presented in table! 11 figure 1 shows
the dependence of the vapor pressure of Lil' on the tempera-
ture in the range of from 926 - 1026*5 0K. 1~rom this the heat
of sublimation for the absolute zero point was found to be
60*64 kcal/mole. The value is in good agreement with the cal-
oulation made by the Inatitut goryuchikh i:3kopayemykh kkademii
Card 1/2 nauk SSSR (Institute of kiniftE. FutW-, I - of the Academy

VLpor Pressure of Lithium Fluoride SOV/76-4-10-2/40
of Sciences, USSR), which gave 60-74�0-1 kcal/mole. There are
1 figure, 2 tables, and 3 references, I of which is Soviet.
ASSOCIATIOV: Moskovskiy goaudaretvennyy universitet im. 9. V. Lomonosova
(Moscow State University imeni M. V. Lomonosov)
SUBMITTED: July 20, 1958
Card 2/2

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5~2) SOV/78-4-10-4/40
'AUTHORS: Yovsayevj: A* M*, Pozharskays., G. V., Nesmayanov, An. If.,
Geraoimovp
TITLE: Vapor Pressure of Aluminum Fluoride
PERIODICALi Zhurnal neorganicheskoy khimiip 1959, Vol 4, Nr 10,
pp 2196-2197 (USSR)
A,BSTRACT: The papen available so far on the problem mentioned in the
title (Refs 1-3) are mentioned In brief and the results ob-
tained by W. Olbrich (Bet 2) and 1. 1. Naryshkin (Ref 3) were
denoted as inexact. The determination of the vapor pressure of
AlF3 was carried out in the temperature range of 980-11230Y, in
a platinum effusion chamber. The device has already been de-
ncribed in a previous paper (Ref 4). The data obtained are
given in table 1. From the experimental data and the heat
capacities (these were calculated in Institut goryuchikh
iskopayemykh Akademii nauk SSSR - Institute of Combustible
klinerale of the Academy of Sciences, USSR) a heat of subli-
mation of 73-46 kcal/mole at Ooi resulted. Table 2 compares
the values obtained with the data of references 1-3. There
Card 112 are I figure, 2 tableel and 4 references, 2 of which are Sovid.-

5(4) SOV/76-33-5-27/33
AUTHORS. Nikol'skays, A. V., Lomov, A. L., Gerasimov, Ya. I. (moscow)
TITLEt The Investigation of the Thermodynamic Properties of Binary
Metallic Systems According to the Method of Electromotoric
Forces (Isaledovaniye termodinamicheskikh svoystv dvoynykh
metallicheakikh sistem metodom clektrodvizhushchikh sil
5-The System Copper - Bismath (5. Sistema med' - vi3mut~-
PERIODICkLt Zhurnal fizicheskoy khimi.4, 1959, Vol 33, Nr 5,
pp 1134 - 1139 (USSR)
ABSTRACT: The concentration chains -Cu solidiGucl, Nacl - KC1
(CaNB'I-N)+liquid (N - molar copper content of the inelt)
were investigated. The investigation was carried out in a
0
temperature interval of from 1150 - 12250K at a concentration
VCu , 0.063 - 0,710. The values for the emf were plotted
as f(T) for each concentration, and a linear dependence was
found. The values for 1150, 1175, 1200, and 12250YL were found
by interpolation. Table 1 shows these valaes. The activity
Card 1/3 of copper with regard to 3olid and to lijjid undercooled

17 7
The Investigation of the Thermodynanic Propertics f;OV/76-33-5-"7/.'.j
of Binary Uetallic Systems According to the Method of Electromotoric
Forces- 5. The System Copper - Bismuth
copper was calculated from the values for the emf. The values
for the logarithm of the act-Jiity coefficient of copper
(IgXCU), the partial heats, and the surplus entropies of
the mixing of copper are also shown in table 1. Table 2
shows the corre.9ponding values fur bismuth. The values for
electrodes with a copper content N> 0.701 -were found by
extrapolation. Figures 1 aud 2 sho-k graphical description
of the partial and integral heats and the mixing entropies.
The system Cu-Bi differs considerably from Racult's law.
The differences decrease with rising temperature. The Ou-Bi
melts are fortned under heat absorptior, the mixing heats
being considerably high. With equiatomic composition their
maximum is 1600 k-.al/g-atLa. The considerable positive differ-
ences of the entropy from the ideal valuus are characteristic
of Cu - Bi melts. This fact is explained by the great
difference of the atomic volumina of the two components.
The retarded chan,;e of the mixing heat and the mixing entro-
0
Card 2/3 pies in the ranae of from 0.3 - 0.7 N C11 is ind'-cated. Hence

The Investigation of the Thermodynamic PropOrtic-9 SOV/76-33-5-27/33
of Binary Metallic Systeris According to the Lethod of Dectromotoric
Forces. ~j. The System Copper - Bismuth
It is concluded that the Cu - Bi melts havu a micr~)hetero-
geneous structure. There are 3 figures, 2 tables, and 12
references, 6 of which are Sovict.
ASSOCIATION: 14ookovskiy gosudarstvennyy univeroitet im. K. V. Lomonosova
(Moscow State University imeni M. V. Lomorosov)
SUBUITTI-1 3 11ovember 11, 1957
Card 3/3

5(10 ~0/'76- 3 3 - 7 - 3 914o
111THORS t Gerauimov, Ya. I., Topchiyeia, K. V., Semiokhin, 11 k.)
TITL-'-': Georgiy Mitrofanovich Panchenkov. On the Occasion of His 50th
Birthday
PERIOLICALt ZhUrnal fizicheskoy khimii, '959, Vol 35, Nr 7,
Pp 1674 - 1675 (USSR)
ABSTRACTi On April 24, 1959 G,~ M. Panchenkov, a well-known Soviet specia-
list in physical chemistry and Professor at the Moskovskiy
institut neftekhimicheskoy i gazovoy promyshlennosti im. I. M.
Gubkinn and Idoskovskiy gosudarstvennyy universitet (Moscow In-
stitute for Petroleum-Chemical and Gas Indastry imeni I. M. Gub-
kin and Moscow State University), celebrated his 50th birthday,
The main fields with which he was concerned care the k '.retice of
hetitrogeneous catalytic processes, the methods of separating
and analyzing isotopes, and the theory of the liquid phase. His
investigations of the mechanism of the transformation of hydro-
carbons on aluminum silica,.e catalysts by the ase of (leuterium
as a marking atom as well as his publications on the ".heory of
viscosity are especially worth mentioning. For the la".ter he was
Card 1/2 awarded the Stalin Prize for the field of sciences in 1952. The

Georgiy Mitrofatoyiob Panchenkov. On the Occasion 3()V/76-33--7-39/"0
0? His 50th Birthday
metbod of separating boron isotopes devised by G. M. Panchenkov
et. al was demonstrated at the Vsesoyuznaya promyshlenne,ya vystav-
ka (L11-Union Industrial Exposition) and was awarded a diploma
Of the second class, this method also has won general E,pprecia-
tion at international expositions in Geneva, Leipzig, Peking,
and Warsaw. Professor G. M. Panchenkov, who is also a .eacher,
fourAed the Kafedra fizicheskoy i kolloidnoy khimii ikCbair of
Physical and Colloid Chemistry) at the above-mentioned Institute
as well as the Laboratoriya khimii i razdeleniya izoto-Dov v MGU
(Laboratory for Chemistry and Isotope Separation at Moscow State
University), which have been headed by him lip to this day, 2
disfiertations for the degree of Docltor and 15 dissertations for
the degree of Candidate were completed under his supervision,
lie published 2 monographs, about 1oo scientific articles, and
obtained lo patents for his inventions. G. M. Panchenkov is a
member of the International Committee for Constants, Furthermore,
he was awarded the orders 'Trasnaya Zvezda" and "Znak Pocheta"
as *vell as the title of Laureate of t"e Stalin Prize, There Is
Card 2112 1 figure,

24 (8)
AUTHOR: Gersaimay, T~, I., Corresponding Memberl BOY/20-127-1.-65/65
-HINSW, Chaf&Wn of the Committee for
Chemical Thermodynamics of the Department of Chemical Sciences
of the Loademy of Sciences, USSR
TITLE: To All Scientific Workers of the USSR Who Carry out Work That
Is Connected With the Measurement of Thermal Quantities (Ko
Yeem nauchnym rabotnikam SSSRp provodyashchim raboty, svyawznM
a izmareniyam teplovykh velichin)
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 127, Nr 1, Rear Cover
(USSR)
ABSTRACT: The Xomissiya po khimichookoy termodinanike pri Otde:Lenii
khimicheskikh nauk Akademii nauk SSSR (Committee for Chemical
Thermodynamics of the Department of Chemical Scienceg of the
Academy of Sciences, USSR) states that there is no irmiformity
with respect to measuring units in the results published by
vaiious authors concerniag the measurement of thermal quanti-
ties. Thus, it frequenill happens that the nature of calories
and their ratio to absolute joule is not specified. The pro-
bable causes of this lack of uniformity is briefly discussed.
Card ?or the purpose of bringing about uniformity in this respect,

To All 90itntific Workers of the USSR Who wCarry out SOV/20-127-1-65/65
Work That Is Connected With the Measurement of Thermal
Quantities
the above committee suggests that all authors take the follow-
ing into account in their publications: 1) Absolute Joule must
serve as a measuring unit in all published results. RDBUItS
obtained by measurements may also be expreased in calories, but
in each publication the ratio between calory and absolute joule
must be explained. 2) With respect to this ratio, the above
committee is of the opinion that, according to the character
and aitk of the measurements concerned, one of the following
antities may be uned; a) I calory - 4.1868 absolute joule
according to COST 8550-57)s This calory was defined at the 5,
International Conference on the Properties of Water and $team,
London 1956 &a the "International Calory of the Properties
of Ste;z". b~ I calory - 4-1840 absolute joule. This is the con-
version to absolute joule of the ratio 1 calory - 4,1833 inter-
national 3oule, which was accepted in 1934 by the Poistoyannaya
tormodinamiohsakays komiaBiya (Standing Committee on* Therm- -
dynamics~ The above ratio is at present being widely -used in
many countries for the purpose of expressing the results of pa-
Card 2/3 pers on thermochemistry and chemical thermodynamics. As the

To All Scientific Workers of the USSR Who Carry out SOV/20-127-1-65,/65
Work That to Connected With the Measurement of Thermal
Quantities
fundamental measuring unitg absolute joule, is exactly ostab-
lished, selection of one or the other coefficients for the ratio
between the unit calory) beyond the fundamental system and the
fundamental unit ~absolute joule) is no longer of any buoic im-
portance and depends only on prabtical use. From this point of
view, also the ratio I calory - 4.1840 absolute joule iii also
to be preferred for work in the field of chemical therzodyna-
ales for the following reasons: a) In very many publications
such as monographs, reference works, etc., this ratio is al-
ready being used without this fact being expressly mentioned.
b) By using the ratio 4-1840 the averaged data may be compared
without conversion with tho overwhelming majority of data of
foreign publications.
ASSOCIATION: Komiosiya po khimicheakoy termodinamike pri Otdelenii khimi-
cheskikh nauk HSA kkademii nauk SSSR (Committee for Chemical
Thermodynamics of the Department for Chemical Sciences of the
Card 313 Academy of Sciences, USSR)

5W SOV/20--127-3-31/71
AUTHORS: Anikinp A. G., Gerasimov, Ya. I.# Corresponding Member,
As USSR, Gordeyev-"T. V;
TITLE: The Absorption of Ultra-high Frequency Oscillations in Aqueous
and Alcoholic Solutions of RbCl and CsCl-Salts
PERIODICAL: Dokla4y Akademii nauk SSSR, 1959) Vol 127, Nr 3, PP 589-590
(USSR)
AISTRACT: The present paper is the first of a series of investigations
of the above-mentioned oscillations of inorganic and slemen-
tal-organic compounds, carried out for the purpose of finding
maxima on the obtained curves if there is a dependence between
concentration and the temperature. Forman and Crisp (Ref 1)
found such maxima for N&Cl and C&Cl, and it was found that
with 4 decrease of frequency, the m*xJ= shifted to lower
coneentrations. In the case of even lover frequencies, the
maximum would have to shift towards even lover concentrations.
This probable state of affairs was investigated in the prosent
paper by means of the salts mentioned in the title within the
frequency interval of from 3 - 11 megacycles. For the purpose
of being investigated, the solution was introduced into tbe
alternating field of a condenser. Voltage was measured by
Card 1/2 means of the kilovoltmeter S-96. All experiments were carried

SOV/20-127-3-31/71
The Absorption of Ultra-high Frequency Oscillations in Aqueous and Alcoholic
Solutions of HbC1 and CsCl-Salts
out under the some conditions; 0-35 &i 3.6 kv, sample volume
5 0- Absorption was determined from the temperature increase
of the solutions at the various concentrations during the
same irradiation periods. The data obtained are given by ta-
bles 19 2 and figures 1, 2. Results: of the pure solvents,
methyl alcohol absorbed the field more than water, and the
alcoholic solutions absorbed more than the aqueous ones. The
comparative investigations had been carried out at the same con-
centrations in the case of the two solvents. The me a for
RbC1 in alcoh9lic solutions occurred at C - 8.9.10-lmimol~.Jj
1001 2u2.9.10 -'mol%i Cacl:C-1.3-jo-3mol/l, WON -4-3-10--"1iol%,'
and in aqueous solutions for T1 at C-9.3.10-3mol/1' 101)N2'
. 1.7010-3mol%; CsCl:C.1 .3.10- mol/l, 10ON -4-3-10- mol%,,
Thust the assumption concerning the shifting of the maxima
toward lower concentrations at low frequencies was confirmed.
Besides, the maxima for the salts investigated were found for
the first time. There are 2 figures, 2 tables, and 2 reforences,
1 of which is Soviet.
ASSOCIATION: Io:kovskiy gosudaretyenny universitet im. M. V. LomoAosova
scow State University Imeni. H. V. Lomonosov)
SUBMITT D: April 27, 1959
Card 272

AUTHOR-. Ger"im, .."&4 0 Corresponding SOV/20-127-3-71/71
!
'ft
~
Q
%-
hairman of the Commisaion
6e
rr
j USSRj
TITLEt To All Scientific Workers of the USSR Carrying Out Work
That Is Connected With the Measurement of 'Thermal Quantitieo
PERIODICAL: Doklady Akadenii nauk SSSR, 1959, Vol 127, Nr 3, Rear Cover (USSR)
ABSTRACTs The following decision was made at the meeting of the Commission
for Chmmioal Thermodynamics at the Otdoleniye khimicheakikh nauk
Akademii nauk SSSR (Department of Chemical Sciences of the
Academy of Sciences, USSR) on April 20, 1959- It is recommended
that calories be defined in Joule, and to atats what definition
was used, There exist two definitionst (a) 1 Cal - 4-1868 abs.
Joule, which was filed un4er GOST 8550-57, and which corresponds
to the international Cal, determined at the International
Conference on the Properties of Water and Steam, London 1956.
Ths second definition# (b) I Cal - 4.1840 abs- JOU10 CDrresponft
to the conversion of the international value of 4-1833 fixed in
1934 into absolute Joule. Also the latter value may be -ased,
because it is widely known in published works.
Card 'i

AUTHORt Chairman of the Commission SOV12o-128-1-5815a
and Corresponding Member, AS JSSR
TITLEs To All Scientists of the USSR Occupied lNith Measurement of
Thermal Quantities
PERIODICALt Doklady Akademii nauk SSSR, 1959, Vol 128, Nr 1,
flear cover (um)
ABSTRACT: Thin is a publication of a resolution adopted by the Komissiya
po khimioheskoy termodinamike pri Otdelenii khimicheskikh nauk
Akademii. nauk SSSH (Commission for Chemical Thermodynamics at
the Department of Chemical Sciences of the Academy of Sciences,
USSR) at a meeting held on April 2o, 1959. The Commission
suggested to introduce uniform definitions for thermal quantities
according to the kind and purpose of measurementi a) 1 cal -
= 4.186a abs. Joule (GOST 8550-57) in accordance wit), the "In-
ternational Calorie" (London 1956), or b) 1 cal = 4.184c abs,
Joule, which is also a generally accepted equivalent (thermo-
chemistry, chemical thermodynamics).
Card 1/1

0 66183
SOV/20-126-5--37/67
AUTHORS: Zharkova, L. A., Qq.Faslm~v, Ya. Io, Corresponding Member, AS USSR9
Rezukhina, T. N., SimanoV-,-Yu. P.
TITLEi The Equilibrium Between Zinc Tungstate and Hydrogen and the
Thermodynamic Characteristics of ZnWO 4
PERIODICALi Doklady Akademii nauk SSSR, 1959, Vol 128, Nr 5, pp 992-994
(USSR)
ABSTRACT: The thermodynamic characteristics of tungstates and molybdates of
bivalent metals have been investigated at the laboratory of the
authors since 1944. The method of circulation applied so far was
not applicable here as zinc evaporates and is carried away from
the reaction zone. The method devised by J.A.Kitchener and
S. Ignatovics (Ref 10, Fig 1) was therefore employedp yet not the
quantity of the volatile product but the hydrogen content of the
gas mixture in equilibrium was determined, i.e. by measuring the
electromotive force between two hydrogen electrodes, one being
saturated with pure hydrogen and the other with a mixture of
hydrogen and argon. In order to check the precision of the
apparatus, the authors measured the temperature dependence of the
Card 1 /2 equilibrium constant of zinc-oxide reduction (Fig 2,1). Herefrom
e

66183
The Equilibrium Botween Zino Tungstate and Hydrogen BOV/20-128-,Ii-37/67
and the Thermodynamic Characteristics of ZnWO 4
it resulted that it was in good agreement with the values obtained
by Kitchener and Ignatovicz. For the reaction
ZnW04 + 4H2 - Zngas + I + 020, the authors calculated the
reaction constant KI, and determined the phase composition of the
reaction products with the help of radiography. Experimental
results are listed in table 1, 0and figure 2JI indicates the
dependence of lgKP on 1/T. 'AH298 = -327.0 kcal/mol,
AS098 = -11o.66 cal/mol.degmg AZO 285-1 kcal/mol were
2 298 - -
computed by a method developed by M.I. Temkin and L.A. Slivartsman
(Ref 16). There are 2 figures, 1 table, and 16 references, 10 of
which are Soviet.
ASSOCIATION: Moskovakiy gosudarstvennyy universitet im. M.V. Lomonosova
(Moscow State University imeni M.V. Lomonosov
SnMITTED-. July 2, 1959
Card 2/2

IMOV, Andrey Tledimirovich, prof. [decessed)i Prinimali uchsatiye:
BUMWIN. I'm,; MIONSKIT, A.A.; GRYAZHOT, T.M.-, DEMM11WA,
K.I.: DINTSES, A.I.; DOERCRAYOT. R.K.-, ZLMOYA, T.R.: ZHWO.
A.T.; XPATIT31T. T.H.Z MATKOVSKIT. D.A.; KOROBOY. V.V.; HOOR.
IMWRSQY, U.S.; R&OVSKIY, A.T.; PMUZ, Te.K.; RUMOVSKIT.
D.M.; RTMOT, M.V.; SXRBBRTAKOVA. Te.K.; STEMIMOVICH, A.D.;
hMIGALIVA, N.Y.; TATIVSKIT, T.K.; TILICHITHT. K.D.; TRIM',
A.G.: 1205T, 0.1.: SHILTAYETA, L.T.; SHCHUIR, T.T.. DMGOPCLOY,
X.31.1 sostavitel ~t I.. *tv. red.; SKWOTA, I.T.j red.;
TMVHIYAVA. X.T.; TASTRIBOT. V.V., red.; KONDRASHKOYA, S.F., red.
iod-val LAZARRYA. L.T., takhn.red.
(Valected scientific works] lzbranap usuchn" trudy. Moskva,
JFzd-vo Kosic.univ., 1960. 512 p. (MIRA 13:5)
1. Chlea-korrespondent AN SSSR (for Gerasimov).
(Chemistry, Physical snd theoretical)

PHASE I BOOK PAILOITATION S' 0 V/3 6 4 0
..Ger-Aiji!jo~VYakov Ivanovich, Aleksandr Nikolayevich Krestovnikov, anj
Aleksey Te-Yg-iy-#V=-ShAkhov
Kb1micheskaya termodinamika v t8vetnoy metallurgii. t. 1: Teoret-
icbeskoye vvedeniye. Termodinamicheakiye svoystva vazbneyshikh
gazov. Termodinamika tainka I yego vazhneyshikh soyedineniy;
spravochnoye rukovodstvo (Chemical Thermodynamics in Ninferrous
Metallargy. Vol. 1: Theoretical Introduction, Thermodynamic
Properties of the More Important Gases. Thermodynamics of Zinc
and Its More Important Compounds; Manual) Moscow, Metallurgizdat,
1960. 230 P, Errata slip inserted. 5,100 ciples printed.
Compiler: M.S. Vendrikb, Candidate of Technical Sciences; Reviewers:
K.V. Astakhov, Doctor of Chemical Sciences, Professor, and N.V.
Gudima, Docent; Ed.: O.M. Kamayeva; Tech. Ed.: V.V. Mikhaylova.
PURPOSE: This book Is intended for engineers, scientific workers,
and students In advanced courses at schools of higher technical
education.
Card a/5

Chemical Thermodynamics (Cont.) SOV/3640
COVERAGE-. This book is the first in a series of eight on the themo-
dynamic properties of nonferrous and rare metals, as well as their
principal compounds' (oxides, sulfides, chlorides, sulfates, and
carbonates). This volume contains basic data on the principles of
chemical thermodynamics, methods of calculating thermodynamic
magnitudes, reference data on the thermodynamic properties of the
more important gaseous participants in pyrometallurgical reactiins,
and data on the thermodynamic properties of zinc and its principal
compounds. A basic bibliography of 75 publications on chemical
thermodynamics and its application to metallurgical processes and
metallograpby is included. No personalities are mentioned. There
are 423 references: 51 Siviet, 171 English, 140 German, 30 French,
12 Japanese, 9 Italian, 4 Dutch, 2 Belgian, 1 Swiss, I Finnish, 1
Romanian, and 1 Norwegian.
TABLE OF CONTENTS:
Preface 3
Accepted Symbols of the More Important Values 5
Card 2/5

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0.0000 -'T 3 !"] '-~'
I SOV/7 9 3 - 69/169
AUTHOR: Geras orres pond Lng Membe, of the Academy
o.f'.. 9'6"iences, USSR, 1.3haivirian of the Corwrission on Chemical
Thermodynainics at the Brarch of Chemical Sciences of t-he
Academy of Sciences, USSR)
TITLE: To All Scientists of USSR, Conducting WIrk Conrected
With Measurements of Therr,,ial Units
PERIODICAL: Zhurnal obshchey khimil, 1960, Vol 1~0, Nr 71, inside
of the journal cover (USSR)
ABSTRACT: This is a resolution adopted by the above commission
on April 20, 1959. The resolution stated that different
s(,I.entists very often use different heat unit's in
their puuitcations. it recommends 'Lhe use of joule as
a Systematic thermal unit. The ealo2le remains only
d - - - ly
as a nonsy3tematic unit and is to be ~" sed only if its
value In terms of Joules is g1ven. The relatLon I
calorie = 4.V840 Joules Ls reco!Tuqe,!de1-,.
Card 1/1

AUTHORS.: Anosov, V.ra.' bolyaYev, A0100 S/076 60/034j/02/042/044
Tollskb~_ A-11.1 Q- &J. BOIOY3007
- - .."M L
hovits i A.A. , INsikin, S.F.,
&UX& 0, Iskrasov, B%V.j Ponomareval X.Se
TITLE: Ajgj2MAj NikolMovich Irestovaikoy (A.D. Xrostovaikov) (On the
Occasion of His 60th Birthday)
PERIODICAL: Zhurnal fisicheskoy khimil, 1960, Vol 34, Nr 2, PP 482--483 (USSR)
ABSTRACT: On Ausust 13, 1959 Doctor of Technical Soienose, Professor
A.R. Itestovaikov attained the age of sixty, He is one of the
lisading Soyiet experts on thermodynamics and is well-knoln by his
fundamental work in the field of chemical thermodynamioe'land its
application in non-ferrous metallurgy. A.N. Krestovnikov worked at
the nauohno-pstrografloheskiy Inatitut Litogea (Scientific Petro-
graphioal-InstituteLithog0a)f the Inatitut prikladnoy mineralogii
i petrografii (Institute of Applied Mineralogy 'and Petrogrgk_hy),
Institut prikladnui taiuvraiogi, i wwfallurgii tsvetay,fai WeLallov
(Insti,tute, of__App;ie.d Mineralogy and Metallurgy of Non-f errous
motals'),f'' ihe Teentral lnyy inotitut tovetnykh metailov _(Oentral
Institute of Not-ferrous Metals), the Kazakhekiy filial AN Sbdh
(Kazakhakiy Branch of the AS USSR), and other researah institutes
Card 1/3 dealiAg with problems of chemical technology, electrochemistry,

Aieksandr Nikolayevich Krestoynikov (A.Y. Krestovnikov) S/076/60/034/02/042/044
(on the Oooesion of Hin 60th Birthdv) BOIO/BO07
and the pbysioal obexistry of metallurgical processes. Under the
supervision of the well-known soientists N.A. Shilov, E.V. Britake,
and N.A. Isgaryshev, A.N. Irestovaikov very soon became a widely
recognized adientist and pedagogue. In 1926 he began bis pedagogical
a0tivitios and leotured at higher technical schools in Moscow and
its neighborhood, as well as at the Moskovakoye vyeshe tekhniobeekoye
uohiliabohe (Moscow Higher Teohnioal Sohool), the Voyonno-khimiohoskaya
akademiya ins X.To. Voroshilova (Military Chemical Academy imeni
1,Y9. Vorashilov), the Institut khimicheakogo mashinostroyeiiiya
(Institute of Chemical Machine Construction), the Metallurgioheskiy
institut sayoda. "Berp i Nolot" (Metallurgical Institute of the Plant
"Oerp i Molot")t the Moskovskiy poligrafiobeakiy institut (Moscow
Polygr*pbloal Institute), the Voyenniy fakulitet goryuche-smazoohnykh
materi4lov (Military Department for Fuels and Lubricants), and others.
ftom 1932 up to the present day A.N. Krestovnikov has been active
at the Institut tevetafth metallov i zolota im. X.I. Xaliuina (insti-
tute of Nonferrous Metals and Gold imeni V.I. Kalinin) and now has
Re MMr of Physioal and dollold Chemistry. Besides'more than 100
publi*ations, A.11. Krestovuikov (together with Corresponding Member
of the AS USSR Professor Ya.I. Gerasimoy) wrote the book "Khimioheskaya
Card 2/3 tormodinamike Y taystnoy metallurgii" ("Chemical Thermodynamics in

Aleksandr filkolayevIch Krestovnikay (A.M. Krestovaikov) 8/076/60/0.')4/02/042/044
(On the Ooos,sios of Ilia 60th Birthday) BO10/BOOT
Non-ferrous Metallurgy"). A.N. Krestoynikoy was awarded the Order of
Leuin in 1953 for his many years of eoientifio and pedagogioal
motivities. There is I figure. /"**' I
Card 3/3

Ya&Iff UrApotlyantat MOM 8/076/60/b34/02/043/044
Bolo/B007
TITLE: Kireyev (on the Occasion or
so bois OUVEUY3
PMIOXCAL. Zhurnal fizioheskoy khimii, 1960, Vol 34, Nr 2, pp 4134-485 (USSR)
ABSTRACT: on October 16t 1959, Doctor of Chemical Sciences V.A. Kireyev
attained the age of sixty, The scientific and pedagogical activities
of the well-known Soyiet expert on physical chemistry began in
1923-1924# In the years from 1927 to 1932 he worked at ths-Fisiko-
khiniohaskiy institut in. L.Ya. larpova (Institute of Physical
Chemistry ineni L.Ts. Karpov). In 1935 V.A. Kireyev took the degree
of Doo, or of Chemical Sciences and became Professor of Physical
Chsmis:ry. His scientific work lay in the field of chemical thermo-
dpamiog in which he mainly carried out determinations of physico-
chemical constants of individual substances, investigations of
solutions and phase-equilibria, and worked out calculation methods
for ahenioal equilibria. In the course of hie activities as Director
of the Xhimicheskiy institut Dalinevostoohniy filial Al SSSH
Vladivostok (Chemio 1 Institute of the Per Eastern Branch of the
'~n ""'D
AS USSRI VLadlvostok and as Scientific Director of the Physical
and Cbemical Laboratory of the Vaesoyuznyy itauohno-iseledovatel'skiy
Card 1/2 kbimiko-farmatsaytiohookiy institut Moskva (All-Union Scientific

Valentin AloksaAdrovioh Kireyev
(On the Occasion of His &Oth Birthday)
S/076/60/034/02/043/044
B010/BO07
Chemiofi-pharmaosutioal Research Institute, Moscow) investigations
were carried out under his supervision of the coking capacity of coal.
V.L. liveyev had already begun hi 11 pedagogical activities in 1924
and taught at the Urallskiy (Ural), Daltuavoetoohniy (Far East),
4or1kovskiy universitet Gor0kiy University), at the Inshenerno-
akonomiohoskiy Institut ~Inotituts of Engineering anti Economics),
and in 1937 he took over the Chair of Chemistry at the Moakovskiy
Inzhenerno-stroitellayy institut im. V.V. Kuybysheva (Moscow Civil
Engineering Institut imexi V.Y.Ivybyehev). The books written by
V.A. Kireyev were translated into several foreign laiWages. He
took part in compiling the great Soviet encyclopedia and is at
present Member of the Editors' College of an abridged chemical
ewyolopsdia. V.A. Kireyev is a member of the Mendellayevskoye
obehohestvo (Neudeleyev Society), the Veesoyuznoye oloshchostvo po
rasprostransaiyu politioheekikh i nauchnykh znaniy (All-Union
Society for the Propagation of Political and Scientific Xnowledge)
ftnd of a number of commissions of the AS USSR; he is also Chairmat
of the GFX khimiohookogo fakullteta XGU (GEX (State Examination
Commission) of the Department of Chemistry of Moscow State University).,
Card 2/2 There is 1 figure. V