SCIENTIFIC ABSTRACT S.G. FRIDMAN - S.YE. FRIDMAN

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December 31, 1967
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SCIENTIFIC ABSTRACT
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~. ~. Klpri,,anov, A. I. an-11 Frid;!,,on, ~. ~). a 1,11t, Mer. zhurnal, 1-.148), I,,~ue 1, p. 2?-44, - 15 SO: U-3'42, 11 '"arcl~ 53) (lotol'is, Iny':,Ii SUAny, No. 10, 4(j, :,01j1. 1',, 112 g. -'Awlimt Ili.. 1"'I'Tal b, IN ~ liv -~i,l %va., 'I'm15 td.hd it lilt. IINOI "'I, 1 .30) 'It t'lillit Wilp.. th! llkt. ktpt N' 1;1~ M owlill (0111I crilfIL pf,,1110 "t IS, I If I V- I, I. I I, I IS I Iill C(IS 117, IN 1111 1 -.1mic lim"."V). vi'l-te'l I 115% /?.1 wit, i"Howm-11, $)'It 11). 3iW; NII, all, yellow, Ili, 210"; Ar wit, fir'llil,g I with nl- V(011 ,)III c"Ilvd. IT'SO, to 50-V 1!;I,e -10'~ I heatc.1 ill, St V- CI! to 00 .7o, ('11trwil a mabstalle.., Ill. IST-s" C-mg. CI Ilml i. ullath,lud III. rellaxing with Etoll or INIC011 will Wrilli. fied III% I and 11c1. bell.we ~imi- larly. It,-ming 13.0 K. /~ITINC.Ii.COICIIICIIINI-'t,llcI ill M Ins. ViOlf ivithn ttilticited mixt. of 1.1.5 g. CuCI: Sims 7 it g,NJI6C,N3I5niin at IW, and adding -10 in' Ait. I ICI gave ,It pot., I'llich %va, ext'l. repeAte'l1v with lint HSO nn,l the ext. liclar-litol willi N-If'Off. yieldilig 131~', e1hyl 111, 1~:)* (frnnI tit- Oil)-. 110 snit, lit. 193-4' (from MOM. Similarly. (1.1 g. ill 50 lilt, MOII treatrIl with'I nit. 30~"o ate. fict, (1.5 K. CUCII, and 3.11 g. '411,C.N', jtay,! 3.7 g. 1-iiietheallninatropyl (MMV41(f. 111. 1-111 ((1`0111 dit. EWIII~ $111111AFIF W;I-4 forilml 6011,0, tipadim(WAY1 f ifte. lit. V41* (;.,.\I. K: Of Amlectalli I Wors of thistolecarblislylle adds. 1. 2. Beci=xerboxylic acid end 6-bacuothimiscublis add. S. G. Fridnhin (In5t. (IIII. Chem., Acad. 56. U171kirk S.S.R.). Air. O&A(Aff Kkim. (I. Gen. Chem.) ZO, 1191-8 (low). -2-fiestizatho4zdel arboxyli, Oid (1). m. 108' (5 g.). warvwd 2 hrs. with 6 C. PC4 un a water both. then treated with ice wittleri gave 91%,it the yelkso, aeidthitioride. m. IOD- 2*(IrnmC.11, Warming this with MeOll 30 min. gave the Ale Wft #4 1, oil 4W 16"Oll .111 111101f), alid, P.1011 g4VV the P;I rilff, M. P) I " I"I"NO1,01,11111 Ito (,.I($ SAVe Oft refluxing 3 hr~, I 1w :41447AIM I %,vIA.vt M", In. I M4' I from) (CIC11011 ; P,mk. in, 11K. (from Ftolf). Smillally. fill. ,11 elite. dnvm;,. X(CII0,011 riv, 112* Orurn ViOll-Ale,CO); puralt, M. Ill (fr-m Sle.co). ethyl ester. domwip 142* (from ViOll-Me,W), Addn. of "d. slowly to "it g. CUCI, mind al~rj 'h I g. 1~) KC.NS. And v~..rititnt thr most. with 40 ml. AcOll 13 !;hl. 10 50* Itov;-. wt it%wro. with hot 11,4!) and addri. of M1,014. almott Ill. 1:14'. IlLhij (71, K I atj.j.d nh oirritis too !bx) C. KOJI anti Z)O mi. 11,0 at I(W. fu$)wpJ Ity heating to VW until MI. evolves, then to 1.50' if,pwilasirms), dolts. %ith 11,0.andneu. tralizationorith 110. gave which. in the crude &tit,,. bmted :1 his. with list x, M). IIC(Nll aild a little z". yieldcd off Itrutratir.11 O'n st oth S.oll 71)cm, 6-MethAeSZOASatale. It. 251-2'. 'rills (L~t K.) tu'lleti with 210 C. 140 with dd,In 4 V) g. K.Nin(As raw 11.5 It. 6-beasto. thWolifKarbaryfir aiiif. tit. 245' (I"tits M4110; this tx,ikd wilbricess"'(X%gave the m. 1424% which with Salf0h xuvie lilt frvrWIj1A1,WsW,. nj.M"(IrumCsJI4). its it jetitmi gave the fcollavt,ing "ten: Ft, M. 64' (Imm -Ill NOW, drtx"p 179' (frottl (1011,041 (p,fae. m. 172,1; j-4o`,I!.Vza-%I%~f- propyl tit. 16W (P-jo. too. 140): and dW)rfAyi d-Nimp. '.'M' l(rotit EtOll-lotteCIP). I gave the dwide. m. 210 .(rum A.4pll). The arnico4kytesttrscittA Atvtt tm det-d of a qr,Wfit Isopp". tiff. G. %t. K-4pod C, 14 Andooolkyl Mets ol IbWolocs(boxyllc acids 1 .1 - bomodlissolocatboxylic and 6. bontothivoliKarbox) lic acids. S. G. VMmau. J. Geoe. Clem. USS.K. IU. t=4,.XI9SOXffngf, trun%tAtitmil.-Sre C.k 45. 157W. R M. S. "Y' ~,Iet.* of thialitleciaboxylic Addai 11. 102. Jecaliticitylic .id d 2. am 0- .,Yl ~ W., tialecarbarylk acid, S. (;~ etifinan. hi'l A*, ,, "' . client') 20. 1:01 -130M.- 3.21-SICI Ills) C.) I,,,;) 1 1) '11N.Iheated With 45 g. BsCl I hr~ [n$ A strain 1,2111 Ill. pt.011j.1 %ith!i~( Noolf, it"d it 1, Ill 11-11 11CI, gave 4111";, 11-pitthy/4. 1. 14, U~n k,. " 1:!1, , " I, I I (I".111 ifil. Noll). Thk 1 .4, 01f .1111 IAA g. KhIn0J and W MI. it 14-111rd OX ~ I-P/WXy1-64eXl14k6J1d1If- (fr,-,, AdIff); beating with PCI# r PhIl r, at list* save 95", of the Worlde, M. 177' If yirldi the Aft Cliff' in. 150". The ith in Ult 2 hirs. gave the 2-d&4AyAjms*,wikrJ ratp, 6ulaltj &S be 110 wit. in. 2M-20" l(forit (CII,(!I)j1; Picrale, in. 189* (from ~Jrlco). The J-dittAylanopkipropyl fit" IliCt sail, In. 20&4* yto, is 0111a)IJ; P-Qle, Irs. 157*1: and 2- (1-piperidyl) ethyl Cliff 178,~ yiel,l) 111(7 jail, 11, f CUal were sintilorly pit-1.1. rom fell,- (W g.) heated with m jg~ P-OINCJI.Coci I hr. on A ~tvdflt bath save 32"; 6-spiethyl. tit. '219' (front AcOlf, then -bkb 0~'-5 X-) treated In 100 Mi. 1-01; U.So. With 0-5 I'll. -111-L IICI and then. With jilow heathill oil a .140"A bath, With 13 9. IK?Wd. KrC11(h gd,fed in SInAtl 1". 16013ij. $aVe. after the USUA UtAtatt fit. 07" ;, iva tau of 2.(P thelteeatid, tit. 3110 (frous AcOll). h.4i.1 jib pCI, in pIjC1 grive be Worigir 19-,' "). it C,11.). WhIL11. heatol Itfk NICOIL JA%t file It( 2LU 01* (((wit C.H.J. 'unt- forty Int.&A. -It: 1111'r 1.1 otir. fig. Ovial C4114% ell(? I110 wil. In. M,4, (dra"0101'. Ituin htoil) 1. .1 r4of (Vi`;), al, 159 (V)* (iroul J1,1011) 1110 sall. tit. 234' Wrt,onim,; It,"it ') I/M tan. tn~ HtOlf)J; 2-(1. perkly(itAyi citer ("a" 244' ((rum NOP) 1; the amode, from the chlaride aml Oil oaastratu both, tit. 2014' (ftoin AvOID, RnIuctiont of the lliftO dt-61(11. by hCUtilIg With "Mi Still IICI J-AVC thC corresponifing depirs. of tayboxy k '" Ad: Are cite, (.71'. 1. tu.21.4* ((tool -fit. I El tiler (4 V ). in. 2a4-5'. awsfe at. Onxii dd. 1; tOll); "-dirlAyla min, wthyi e,trr i W.), ai. 3;11.p' ffr,nn silty t4tS1,1, in. t(r_" dil. ~ (front dil. LtOll); -(i-pip4rtdylJr(hYI e,t" (45'j). nt. 1441. 'c'. %I. K,.Upnfl C.A. 48. 67,k. It 'kThIms"AtIon.2f IRM S, G. Pridnian. Zhur. q 4 V ;Q; J*- -TTN%~, t Blom- quist and Diuguld ("C.A4 obtained 2-nitro-.I-thio- % cyanoanitine which they erroneously assurned to be 2-, amino4-nitrobenzothiatole. On acetytation of their prod- i d not 2- de an net they obtained 2-nitro-4-thiocyanoa"tanil ucetylamido-4-nitrobentothiatole; further on diaxotitation th obtained 2-nitro-4-thiocyanocblorobenzene Rnd not- " " 11orro4-t4trobenzoth c iazole. Following Challenger and 2 Peters (C.AJ 22, 3162) Ph%-Ht was convert-A to t-thlo- cyanonnilint, which gave the N-Ac deriv.. which nitrated to P-nitro-p-,thlocyanoutetunilide, which gave o-nitrc-p~ I thlocyanonniftne. Pjixed m.p. dems. of 2-nitro-l-tho- cyatioacetanilide and B. and DA alleged 2-amino,4-nitro- benzothiazole gave no depression; nor was a depres,ion ob- of 'line nnd seryed In mixed m.pi. 2-nitro-4-thiocyanoant Allmmd 2-amirlo-f-Wirobenzothlizole. Since emorical for-- hi ili A h d h b f ~~ cs are au e cnzot nes an o t t t thipcvp4oan idcn(W, analy*4 4.41;jcould not be used for dectsign ai to S 011 4as 4mo and D. Authentic'Anijr!~-P- tru re 7 thik an04 pp #13% N-Ac dcriv V~ . y i ltro-P-thlocyaaw$~~Zeoe. M. M'. n .. of atliylene and bylvnollf~ r at ti"Ca t - A4 ObShChF& MM - A . 97&-WJ(l were nrepd.- loor tftts gis-a(Whistanilaic arenO." sbow,,d rwtivity. bat ' the be5t wcm below Pydbcnmmhffi; the most "Ye WRO atnine. 1.42) aare 80% AfirNCH3CHiHrJ1DP. m. 28P. after wwk-I jiftorf;1M.no1 Md Soch KnTC1., Ing rrith MVICO. 2-PiPCr* ' m. (CHJtC11Br;. mN 08-700.: PI dine VC 3- i rAr"Me . .Cff: . from PION e, 11to, AM 11C. bm; j 1 10'. 'Z-Bromethilande. by the &kndmcycr reuction. 1leatins5r.bcnzyItWNMrT* fln4 2.5 rnl. AcCH&CI on gil zteam bath I br.. 3oln. In MO.' with EtrO, addn. of 10% NnOlf. and filtration Pria ;90 M. 99,; PkM14. M. "' 1 19, . Refluxing 27.4 g. "bent-tidine, 18.4 'P"11 17 idi l RCI t C( h hl ld l 6 V 1 e- noet or c , ant . . 1 g ( ry Xj y h HePh 8 bra., followed by addn. of 1110 and extri. of the *q., 1117" with Etro. save 0070 dim, Rh 173:4"; WO &all- rit. 174*. Agialorro"Sly ... ob.- Wned: 70% PANUCHIC11iffM6. th 100-6* (di-MCI s44, 170-7*): p-E?COX*1f.N11CHCF1,M3ftl. 32', * 181 5 (110 alt. m. Picrale, rn' 137-8 DrC#H&N1T1C1fxC11,NC**%, 327p. bt ISD-V, on. 44" Wt. in. 20.13"); PACHIMUCH.C111NAVer. 20%. b* 115- 17* (di-110 jqlt. in. 203-7'). H"fing 20.4 s. AftibF. (CIIJaXill in 20 ml. pyridint with 1.1.6 g. p-MCOCIfir CHIC] 15 firs.. adding 15 s. 5olid VaOll. N-AtIng 0.6 br- an etrum ti;.ith. filtering, and di-,tg. rave -13~1 N.Ndimr1h* ;10nalt.m M-9' Ref'uxing5.5g.Nle2.NCifiCligNTIPh la 10 ral. pyrklint- with 5.5 g. 2-hrvnjutio.Lzvi= !~. irra., hrai- ing 20 min ~ with 10 g. solid NaOll. filtering, and ill-sig. gave 1.45 r- diarnii.r. th 145-50"; Perchlufate. tn. 109". SIMPlarly Waal obtaln~d the N~~ntyl axatq, 40%, th 18a-5*; prrchlorWo. lit. 139"; it3 pirrate could not be obtained In solid Statt cf. U-S. .0,440.730. C.A. 43, 1914). Similarly vms ob. .mined " h-d li 1,inirL irrin amini, - M-00 : tba product vrasjmpm, find none of itz salt-i wen 9titairied in vpOd stat 11TA"g 9.0 a. 2-benzylamlno-+M~tl iyltbiazoir. 4.6 1.- Namih" JIM att 175 AVePh 2 hts:, ddlt 14 uevubtr, ClIjur.1fur, 'KA4 bofthig 12 bri, tat SM, 1k (-Nl* atow, b4 I (titidt); the Pdrcuaae; M. t4 With give the free bdse, an oil, yleldluc k Ldt-RCI Salfi- cauxIng US C., Na aft of Vftlan otfilatole wftb C. pCol gave' ,2 pyl Chtowe In ptolf a ft". 3 tit .1y OPYI)SAIt N'.*s * Ur _UcU - 2W4 a'Rue M. tf%G* FA 010n0 so . M. 2% 6P:"Ie. m4 M51; di-MCI t4ft. tn. 102*. The ftme I .-The folldwing Int"med4tes w"t pcodact tc auAhed In the g3me Yku fcom tht 11CUS OC tztiAed by candensation of outilatt with dialkytamtnoal RC1 Wt Listend of the free base Sitnllat( w"tobtlatird: 11-Aid" X. drscrilk-d In Part I (above): FhN1fC1r2C[rtN1Vi1~ 76% 1 - 1: - IN - Y - WA31 - I'- thiald dmilfuj - fl-kyr H%4,M 1 F2, lu 1611-7* (&UCT idtf, m. ST4-51% VKrdm be lsa--3* (di , G-Irc? Ph IVI[CIF: Clio C110"Cittq. R)C- 6 14," , affili 17, M. C1 salt, in. 221;-0*); p6-AfeaHjZ&rC'[r'jYArq, df-HO Jill, M. 164'); b, 120-3* (di-HO s4ft. m. 17""), -AfeJWf,- 847C. he 170-3"(dipicrafe, ch. N11CUsCiltIVAlet, 61, N 1.11-34 (di-MC1fdft. in. 180,; d4-110 m1e. hygrosccPic); Otro. p-r-10 4nake. GS,7*. , 133-6* W-ffa sal:..m. 160A m. 47-9" VOL-rae, m . 201'; dr-110 talf, m. 144--S*); S'- PACHIMUCI&CHIC1119wrt. m5o b4 I-VY-a- w-fra cy? ditdug. 78 m.68.5 kall, m. 207*). 11catfitt 42.6 c, ife',NCIfCEI.NRPh.2I[Ct agtfec. 9217u- with 27 g. NH4CNS itt 100 mi. PhCl 16 hts. at 100'. fillfta-'. 071-41 (krddarcdle, rn. 144'); tion. sain. of the pnt. In hot HjO, clarification, and coolirg N*-($-P~.-ml.-24hicz.-?yLleikyttxtdiamixe, m. 09* (H1Tr m2r. gavc 5070 CGIOTICS3 PhN(CsNltt)clfgclftAvAfetjIC4*1'3, mJ m. 213-:5 ): 10-70' (from BuOIQ: Na-CO* do" not liberate the free V41 bt IF", (614,crdr 13 bLis6. but treatment with 10170 N&OH gave the free base, at., 177 di 410 rL/J. hy,Uorop C1. All the above pQli~~ 111-2' (From DuOI4)-. MCI jall. m. 10'. Similarly wese at prazf ca few-1j. have ant ihistaininic proptaies bttt no, 6 prcrA! 45% PAN(CS1V11jC1fC11,JVCj1m. m, 114-16'; I'hzV(.C-5NIft)Cil,Cif,Cfll,VCIHI*, 40%, ta. 112% 52% ~O tit. 14 &t-&0 4*41 -8'-, PACI 2 fj 4, 55%, tn. 131 tC.5N1!j C113 1, Immet, as w. 105*- PACIrtly CSNIIJ- 1C1hCUjC11.-NUej, 23%, m.*;102*. _ - . - 5noalkyl)- kqI-ItnItItS With ftej. SufAtIttletits (d tbt P- a f otm motio-HO Wts wA do not fortwt deti". [o',Y4.6 9. FhN(CSNHjClTjCfhNUev wu Wed 6 tat. ITIC1, Ithig in i delayt4 vigams ryadloa,' the mixt-heate7u, hr. Itt SO-901k, d0d; "Ith VtO, txtd.,wfth B 0'((04rc AJ:CT12CI,dcw). spade olk extd. wkhl USSR - &-'rhimlyt derivatives of ethylede- and trimethyltnedi- Inet. 1. U. S._G. Fridmtn J. G44. CUM. M.O.- F-IR. 23, translation), -S-1 - tf. L. 11. F11110A44A1, 6 c~ V Thlocarbocyanlacs with arylory groups In 8,10-pilsirlo-21- A. 1. KIIIA2110y, Zh. M. Dmnova, anti S. G. Flillmall. Ukraito. Kkint. Zhar, 20, &U-, (1) faryl - (a) Pit. U S 8 R (d) 0-Meoc.11. W I-cmill, 161.3'nd U) '_7C,olfil tire prelml, fly cumicitsing o IWNCtff,SII with Ar0Cll,,COlII (aril groul" % Yield, and ni.i). giveri)- 0, " ' 9; b, 7, . 119,; c. 7). 123*, d, 779. W; e, M, 1112iW~, f, W, 119'. Quater.jary iuilts (U) of the loll..,liX I tire prepd. by heming I Ill", fl-Mce'll'S00 t 1: 1.1 molar ritifl) 3 lits. tit 115k-10" Wallillig the masi with 1 ,10, and crytij. from JIj0 (aryllroup, 5+4o, find m.p given): a, 27, 157-41; 6. 61, 15W: c, M. W 1-71; J, .47: 103'; e,59, f,61. Ilil-2*. 8, 10-Diaryloxythic-car- i bocy-anine ifyci(M)are obtairicil by licativig 3 fill. dry CjIfr 14, 1 X. of the follorviitg 11, will OJI r,. e-fortirate I hr. at 115-20', oll1r. with M011, -trid wlflh~g hot aq. K1 Or NLkCIO4 to the boiling mixt. (aryl group,,ani'lli, 0,; Ykid, M.P.,411 11 niav. Ullq)rptiol) speviju ill mp g v[!)). a, 2,X3-4 , &S1, b, CIO.-, 20, 1 -, 15~5' Is)&- 7% 4501; d, I -, 14, IM, .590: e, CIO.-. M. W: f_ 1-1 11, 10; 80, MR. Sly I Yl flyc,; (IV) nre prqKI. by htnt in x e(plimolar 44 t1w 1`141"winic 11 alld P--NI L- N~41 I Clio 20 it, In. fit IX-* in ArA oddhil, lint all. KI or NaCIO., :tit(,' cryl,tK. from V1011 (aryl s:rOm" All;')n' 7, yield, 11I.P., and aWorption vprt-tr;s Ill mij givvn): a. I-, M, 21f)-l'. 520; b. CIO,% 117, 22213-5% U)-. c. CIO.-. Pry, li'6-7" ;V210; d' CIO,-, 01, 212-15'. 620; e, 1-,05, 5M. Nt!"AtIctl0l, v( U radk3k in the 8- Or Pllift~ the :t4-Alflivion qlwctl,.t (V) (A the dy'l.. cl"ii3miig it Ilv 9 -If) inp und r/ and itivrcsing it by _17-33 1:11, for Tit: the V 4 Vw twitshmfiftard dycs 11; 1 Wh i(4-, C.A . 44, 76S I "hvit. W j s S P~ USSR/Ch'DMiStr,Y Card 1/1 Authors Fridman, S. G. Title 2-Alkoxymothyl- and 2-arylcorymothyl-6-amino'benzthiazoles Periodical Zhur. Obahchei Xhim. 24, Ed. 4. 642 - 654, April 1954 Abstract The aynthosis of 2-aLkoxymethyl- and 2-aryloxymothyl-6-aminobanzthiazoles can be accomplished in two ways: 1) through condensation of o-amino- phonylmorcaptan with alkoxyacetic acids we obtain 2-alkoxymetbylbenz- thiazoles and then nitrate the obtained bases and 2) through condensa- tion of 5-nitro-2-aminophonylmorcaptan with alleoxy-and aryloxyacetic chlorides we obtain 2-alkoxymethyl-and 2---rvloxy=ethyl-6-nitrobenzthi- azoles. By reduction of the 6-nitro derivatives the author boped to obtain Interesting aminea. Twenty-five references; 5 USSR since 1906; 4 Germin since 1893; 2 SvIss since 1933; 1 French-1947; 13 D1811ch since 1928. Tables. Ini3titutlon Institute of Organic Chemtatr7 at the Acad. of Eclences U~x-SSR Subnitted October 15, 1953 and f. ces.' clitits, U.S.S.R. 24, us slif tlm).--Sec VA. 49, dMi. It. L. If. VraNtly- �0' & VSSR/Cheritatry Card 1/1 Author Fridman, S. G. Title t 4-alkoxymothyl- and 4-aryloxymethyl-',3(p-aminophanyl)-thiazolei3 Periodical t Zbur. 0b. Xhim. 24, Ed. 5p 909 - 916, May 1954 Abstract Numeroub 4-alkozymethyl-2-phonylthiazoles were syntheafted. Nitra- tion of the latter yielded homologous p-nitrophenyl derivatives. The reaction of 4-cblorometbyl-2-(p-nitrophenyl)-thiazole with phenole resulted in the formation of homologous aryloxy derivatives. Roduction of 4-alkoxymethyl- and 4-aryloxymethy-2-(p-nitrophenyl)- thiazoles produced homologous aminee. Four references. Tables. Institution Acad. of Scs. Ukr-SSR, Institute of Organic Chemistry Submitted December 7., 1953 u5snkhemistry Card . 1/1. Authors Fridman, S. 0. Title 2-alkoxymethyl-and 2-aryloxymethyl-4-(D-aminonhenyl)-thiazoles Periodical Zhur. Ob. Khim., 24, Ed. 6, 1059 - 1063, June 1954 Abstract Numerous 2-alkoxymethyl- and 2-aryloxymethyl-4-(p-nitrophenyl)-thiazoles were obtained as result of the reaction of 2-chlorome~hyl-4-(p-nitrophen- yl)-thiazole with alcoholates and phenolates. Reduction of the formed nitroozoles resulted in the formation of 2-alkoxymethyl- and 2-aryloxy- mothyl-4-(p-aminophenyl)-thiazoles. The exrerimental procedure is desc- ribed in detail. Four references. Tables. Institution : Acad. of Sc. Ukr-SSR, Institute of Organic Chemistry Submitted : December 7, 1953 -AV A Ux f and- tkoxyme J-~ Arun Obsp firf 1-C4,lin 11%~J"`~-, 111CIft"111,110 irl -fj )0 att. CIM, io 79 fig ~Tf;u. t, s (Y-1 p1q.1. OIL Oi,,IVIII~ "00-,, 1" (1.5 hr. at 11:1-o' :wjh,.mi toUca juJ,fm:a;:vr not in, 11~!~q It 1% itil A)"). i~t czlcl~ g.. fit.3 (111), .,. tm,; 0.,! 1, TI!C~A-- 1uIj5t:il1Z1~1 ~-ii. III am-f! -Cht at 1) 2' 4:ot: phenyj)~Zhl:c-le Uv), 1:1, 2-,'~' Ib -mtlv (,il*v p-( i,'-'J!, Jz~ductlvu of (h, 0:7,; 1,011 -fiR73 .~tof la pi. 13" tlii~ I.mo-Itc! :.A! Ph, -1 21 V, Pt, P!;. FRIDKAN, S 0 K PRIANOV. A.1. Cyanins dyes from the isomeric pyridothiatoles. Ukr.khiz.zhur. 22 no.6:767-771 156. (MLRA 10:7) 1. Inatitut organichoskoy khisli AN USSR. (Cyantile dyes) 171criflitive15 ofIflyrida [3, 1 (_f d 12 Z'31 S. Aj 13 _- 7172F. u0mri"ej It. /_ [!'! -41~' '1,( 7 fit 11,1\1114T ~Ov' IT with 48 g. X;t'S'?ir..0 ill 101) 111. Ftf)" If) ;1611., co"ling, and gradually adtfinz %1,1 after 10 min. at 70-SW asd with H~Q. 62"; diritro-4,4'4ipytidyl dijfd_.,6f'e, m. :10~' ff-m A(( 0 1 This (19.6 gJ'%ml W K. Z11 dliq addttl jrl 1.5 1'r5. to Hin -uiig, addii. A 40 nul. bo . , g AcOff gave. aftcr I hr. rt Ila AWt6 md refluxinx 3 hm longrr, Ada. of .!\Cl-,% -440% N'3011 aild Cjtn. ivith C11C%, IM-dilk(aza.1c, in, 140* (ftota lif-roizic); t'~Fflle' in. '-'OS'; MCI tali, in. 2_3S* (frmlf 1,1119 with a! gave 36';r, decunip. 156% wilicti fr(%tcll %vitli SOCI..' flt~.Ji with NIC01-1. gave 560/10 Are ester, M. 171*, Lbo formed from flie acil and CHIN,. TUe ester and NH,Off gave 71% rorrespl:,nding amide, m. 242', while the estrr and M,:011 soln. of N, 11,0 gave 83'~'o corresponding hydrazide, m. 2:32". providcd the reaction is run at r4yjti temp.; at clcvatcd temp. t1c dfazq'! 11 It-ring k draml-Trpatrint f the hy wit Ahea W; 24 1 QsHONS. -&-dicyWeliYde pve Ayci'roxy.- acid heattd to 175- bmWiiiie d0ii4~: tX1- 2W. - The frft -80 - pyrUatf."Idgasok. ma 103* (from 1:40). jWAW US ;% ff X~ Privauves of mido-T' V-6 Distr, MEMAE2C Clicl, j 217- 14 C" the a,;' 'oh j,"j ;: yi Witt.' V,,!ICd IIISO~ P0. U.011 Vni gLjwly w1&d 16 it, cf-illed. fls~k)4 Ul~%cA by cifdr. at 14' of 4,1 C. ll;.iNOw, in 7.5 rd. lffO; dter tf'ir ti-Ir t fif. W-A "W fit-Itinj CO (CAUX 16 Mill. tht Milt. ai ~qlcfc-4, (tic fifulte coaw., With Naoll, ar'l cxf.l. witf-, CHC4 ~LtMLig 4 K, ca. 7 E ' t Uinvint), To JO m 1. wnaf. w3 y 't`IdId 2 g, KQNO. (Olowe-4 bir ILd4n. at - IC-' Lf,5 C. I v. W,1!! 11404 fctl~nml by 6-2 g. Na~',Oj ija 25 fnl~ crjtlzt-4. HS~ di---Mi-XE. -VVZIS kCPt :~) tL7S. at. V, 'jUZr(hcd ir ir~, 4;'.! Wald4e, m a n"d F, at -11' 1.3 C. Nla, N Ck ffi. 4 -a: 1, VIP; after swre--r 0.5 he asad jmat-.-Qc,t-:, T"luv, ti-te mixt. wv-s ntt~trali=-d =-I v~=d- WitfI: efleft; rxt. wat avrr AlI(% and the cdacurt f ILtrd with CHC[k J~,' ljnE 1.6 Y. TZ 10 nit. v~mcd. lic kad ~Ul ml. HIO' ~I:L-3 -113' 11iis wa-, with 0.2.5 NuNOt in 2 fcZ-,wf,f by LS g in 3 -,I to 4Y and ~rs- zt O~ 11-e nq~- fiftrc't -0 t,~ I~Lid W.al,~d -Ull 14-4) .-1 -- T AUTHOR: Fridman, S.G. 307/79-28-1 TITLE: Triaminopyridothiazole and Its Condensation Products With Dicarborvi Compounds (Triaminopiridotiazol i yego produkty kondensatsii s di- karbonil'nymi soyedineniyami) PERIODICAL: Zhurnal obshchey khimii, 1958, Vol 2e, Nr 11, VP 5078-3063 (US-IR) ABSTRACT: The scope of the present paper was the synthesis of the hitherto unknown 2,5,6-triamiropyrido [--',I-dj thiazole (1) and its condenia- tion with dicarbonyl compounds, as well as to find out the physio- logical activity of the reaction products formed therefrom. The condensation products of this triamine with the dicarbon,"! com- pounds pyrazino-[5,6-b3pyrido L2,_5-djt'-ia7L)1ires (A) con,;ist of a complex condensed system at' ritroc ,en hetera cycles: NH 2 0= R N R HZ_ C + C~ Mll~\N"_~ 11~(NH N, 2 Concerning their structlire thej are clo~;e ',o the nteridines. Com- pound (1) was obtained from .2, 6-diaritino- --ni tropjri dine arl the Card 113 thiazole (II) by thicnYanation '~'Scheme !). Bj reiuction %' ,i1) was SOV-19-28-1 1-!) `55 Triaminopyridothiazole and It3 Condensation Products With Dicarbon- Y! Compounus transformed into (1) in good yield, which was identified in the form of the dichlorine hjdrate, sulfate. To prove the prejence of two amino groups in the ortho position products of the condensa- tion of the base (I) with the quinones (X) and (.U) were synthe- sized. The condensation with symmetrical dicarbonv] co-:ocunds leads to derivatives of the 2-aminopyrazino-[5,~,-b]PYI-'i-lo [~,3-dl_lhiazole (AIRj~R 2)' the condensation with unsymmetrical ones to tile -orma- tion of two isomers. The condensation of the phenyl glyoxal, for instance, is illustrated by scheme 4. It may be concluded there- from that in the condensation with pyrotartaric acid mainly a pyrazinopyridothiazole (G) must be-obtained. The synthesized deri- vatives of the 2-amino pyrazine[5,6-bj-pyrid,)-L~, 3-d] thiazole are given in the table. They are stable compounds and ~;bnnot be characterized by melting L_ointj so that in ti-~- table cnl h C! maxima and minima of the absorption curves of their _-~lu- tions in the ultraviolet could be 6iven.- There are 1. table and 8 references, 5 of which are Soviet. Card 213 Triair,inopyridothiazole and Its Condensation i1roductj L.0 7,'ith Dicarbonyl Compounds " Y/ 7 9 - -, b - 1, " -5 ASSOCIATION: Institut organicheakoy khiriii Akademii naue Ukrainskoy SSR (Institute of Organic Chemistry of the Acadei,,iy of Sciences of the Ukrainskays. SSR) SUBMITTED: July 15, 1957 Card 3/3 AtTHOR: Fridman, S. G. SOV/79-29-1-33/74 ZTTLE: Condensation of Triaminopyrido [2,3-d3 Thiazole With Carboxylic Acids (Kondensatslya triaminopirido [2,3,-d] tiazola s karbo- novymi kislotami) PERIODICALt Zhurnal obshchey khimii, 1959, Vol 29, Nr 1, PP 153-156 (USSR) ABSTRACT: The objective of this paper was the condensation of 2,5,6-tri- aminopyrido C20-11 thiazole with carboxylic acids. The conden- sation of the ortho-diamino derivatives of the aromatic and heterocyclic series with carboxylic acids leads to the forzaa- tion of compounds which contain the imidazole cycle. It is known that the amino group of pyridine in position 3 reacts more readily than that in position 2; as a consequence, it may be expected that on the condensation of 2,5,6-triaminopyrido [2,3-d] thiazole (A) with carboxylic acid derivatives of the imidazo 6-d.3 pyrido [2,3-d] thiazole of the structural 5 formula B are formed. At present, the condensed heterocyclic ~ ~ systems with pyrazine and imidazole rings attract the attention of chemists. The imidazo-pyrido thiazoles mentioned have hitherto been unknown. By heating 2,5,6-triaminopyrido [2,3-di Card 1/3 thiazole with carboxylic acids of the aliphatic series in Condensation of Triaminopyrido [2,3-dj Thiazole SOV/79-29-1-33/74 With Ca-iboxylic Acids 15 ~* hydrochloric acid solution for 2-3 hours it vras possible to obtain the corresponding alkyl derivatives'of the iMida2o [5,6-d] pyrido [2,3-d] thiazole. The benzoic, mandelic, and phenylacaUc acid did not react under these conditions. The derivatives uf imidazo [5,6-d] pyrido (2,3-d] thiazole obtaiined are listed in the table which pives yields, analyses, .maxima and minima of the absorption curves in ultraviolet. On melting 2,5,6-triaminapyrido [2,3-dj thiazole with urea the 2-amino-6-oxy-imidazo (5,6-d] pyrido [2,3-d] thiazole (VIII) was formed (Table). The heating of triaminopyrido thiazole with carbon disulfide brought about the formation of the 2-amino-6-mercapto-imidazo (5,6-d] pyrido (2,3-d] thiazole (IX)(Table). The derivatives of imidazopyridothiazole are crystalline compounds, possess high melting points and are readily soluble in water. Their elementary analysis,except the sulfur analysis according to Carius, is complicated. On standing their solutions darken and separate dark-colored precipitates. There are 1 table and 6 references, 2 of which are Soviet. Card 2/3 Condensation of Triaminopyrido 12,3-di Thiazole SOV/79-29-1-33/74 With Carboxylic Acids ASSOCIATIOU: Institut organicheskoy khimii Akadenii nauk Ukrainskoy JSR (Institute of Organic Chemistry of the Academy of Sciences, Ukr SSR) SUBMITTED: November 18, 1957 Card 3/3 5/079/60/030/05/25/074 B005/B126 AUTHOR: Fridman, S. G~ TITLE: The Condensation of o-Diamino Derivatives of 2-Methylbenzo- thiazole With Carboxylio Acids. 11. Thiazolo Benzimidazolel PERIODICALt Zhurnal obshchey khimli, 1960p Vol. 30, No. 5, Pp~ 1520-1526 TEXTs The author describes the condensation of isomeric o-diamino derivatives of 2-methylbenzothiazole with carboxylic acids. By this condensation all theoretically possible isomers of thiazolobenzoimidazole with a common carbon-oarbon bond were synthesized. These compounds were previously unknown. By condensation of 2-methyl-6,7-diaminobenzothiazole with carboxylic acid, derivatives of angular thiazo1o(4,5-g)benzoimidaz- ole (I) are formed; by condensation of 2-methyl-4,5-diaminobenzothiazole with carboxylic acid, derivatives of angular thiazolo(5,4-g)benzoimidaz- ole (II) are formed; and finally, by condensation of 2-methyl-5,6-di- aminobenzothiazole with carboxylic acids, derivatives of linear thiazolo (495-f)benzoimidazole (III) are formed. The schemes of these three types of reactions are given. Each of the three above isomeric heterocyclic Card 1/3 The Condensation of o-Diamino Derivatives of S/07 60/030/05/25/074 2-Methylbenzothiazole With Carboxylic Acids. B005X126 II. Thiazolo Benzimidazole initial products was condensed with the following carboxylic acids. formic acid, acetic acid, propionic acid, glycolic acid, lactic acid, benzoic acid, phanylacetic acid, and succinic acid; apart from these the condensation was also carried out with urea and carbon disulfide. In Table I all the synthesized thiazolobenzoimidazoles are compiled (10 de- rivatives each of types (I), (II), and III)). All these compounds form colorless crystals which melt above 100 . The majority of them are easily soluble in hot water and alcohol; the 2-alkyl-substituted derivatives are also soluble in benzene and ether, All thiazolobenzoimidaz- oles are easily soluble in diluted hydrochloric acid and eaoily form dihydrochlorides and picrates. The compounds of the type (III) are more easily soluble in water and organic solvents than the isomeric derivative3 of the types (I) and (Ii)~ The above table 'gives the acid radical of the initial product, the production yield, melting point, gross formula, and percentage content of heteroelements (F, S) for each compound synthesized. The reaction conditions on the condensation differed according to the acid used as initial product. Table 2 gives the ultra- violet absorption maxima for the three isomeric derivatives which are no. Card 2/3 The Condensation of o-Diamino Derivatives of S/07 60/030/05/25/074 2-Methylbenzothiazole With Carboxylic Acids. B005YB126 II. Thiazolo Benzimidazole substituted on the imidazole ring. These derivatives are formed by condensation of isomeric 2-methyl-o-diaminobenzothiazole with formic acid. A diagram shows the absorption curves of these three derivatives in alcoholic solution. The reaction conditions on the production of the 30 thiazolobenzoimidazoles are fully described in the experimental part. There are 1 figure, 2 tables, and 3 referencess 1 Soviet, 1 British, and I German. ASSOCIATION: Institut organicheskoy khimii Akademii nauk Ukrainskoy SSR (Institute for Organic Chemistry of the Academy of Sciences of the Ukrainskaya SSR) SUBMITTEDs May 11, 1959 7 Card M., FRIDMIW, S.G. Condensation of 4-diamino derivatives of 2-methylbanzothlazole with 9(-dicarbonyl compounds. Part 1: ThinzoloquInovilineas Zhur. obAhis. 30 no.5:1685-1693 Wr 160. (14M 13*-5) 1. Inatitut organicheekoy kbimli Akademli nauk Ukrainskoy SSR. (Banzothiasole) (Quinoxaline) 121 0. Synthesis of folio acid analogs. Zhur.priki.irbim. 33 no-7: 356-363 Jl 16o. (MIRA 13SV 1. Inatitut organicheskoy Wall AN USSR. (Glutamdo &aid) FRIIIAAN, S.G. Thiazolobenzothlacliazoles and thiazolobensoselenadiazoles dyes based on them. Zhur. ob. khim. 31 n0-4:1096-1106 Ap (KM A 3. Institut organiabeskoy khimii Akademii nauk Ukrainskoy (Benzothiadiazole) (Benzoselenadiazole) (Dyes and dyeing) and 161. 14:4) SSR. FRL)MAN, S.G.; GOLUB?, D.K. I.- 2-methyloxazolo-.(5., 4-g)-benzothiazole and dyes prepared from it. Zhur.ob.khim. 31 no-10:3394-3400 0 161. (I-MU 14:10) 1. Institut organicheskoy khimii Akademii nauk Ukrainskoy SSR. (Benzothiazole) (Oxazole) (Dyes and dyeing) FRIDMAN, S.G. ------------ Dyes with thiazolobenzimidazole and thiazolobenzotriazole rings. Zhur.ob.khim. 32 no.5:1461-1.467 My 162. (MIRk 15.5) 1. Institut organicheskoy khiaii AN Ukrainakoy SSR. (Gyanine dyes) (Banzotriazole) (Benzimidazole) FRIDNAN S.G.; KOTOVA, L.I. Derivatives of imidazobenzothiadiazole.. imidazobenzoselenodiazole, imidambEnzotriazole, and imidazoquinoxaline. Zhur.ob.khim. 32 no.9:2871-2882 S 162. (MIRA 15:9) 1. Institut organicheskoy khimii AN Ukrainskoy SSR. (Benzothiazole) tBenzothiadiazole) (Quinoxaline) 3/07 63/033/001/012/023 1)205YD307 AUTHOR: Fridman, S. G. TITLE: Thiazolodihydrobenzoboradiazoles PERIODICAL: Zhurnal obahchey khimiij v. 33, no. 1, 1963, 207-213 i~TEXT: The condensations of 2-methyl-6t7-diaminobenzothiazole, ,2-methyl-415-diaminobenzothiazole, and 2-methyl-5,6-diaminobenzo- ithiazole with phenylboronic acid, by boiling in toluene solutions ~for four hours and removing the water formed as an azeotrope, re- sulted in the formation of respectively 2-methyl-7-phenylthiazolo- ;(5,4-e)-6,8 dihydrobenzo-2'tll,31-boradiazole (1), 2-methyl-5-phe- !nylthiazolo~-4,5-e)-416-dihydrobenzo-21,11,31-boradiazole (II), and 2-methyl-6-phenylt-Iiiazolo(4,5-f)-5,7-dihydrobenzo-21$11,3'- 1;boradiazole (III), in 85, 82 and 62~6 yields. The structures were iconfirmed by the methods of synthesis, analysis, and acid hydro- ~lysis. The uv absorption spectra of alcoholic solutions of I - III 1were similar to. those of corresponding 2-methylphenylbenzimidazo- Iles, but differed from the starting a-diamino derivatives of 2-me- LP qr-d_ -1 ZZ ,Thiatolodihydro~enzoboradiazoles S/079,/63/033/001/012/023 D205/D307 ~thylbenzothiazoles. Treatment of I and II with ethyl iodide, di- ~ethyl sulfate or ethyl 2-toluene sulfonate gave crystalline com- containing boron, which lost B on washing in alcohol, giving~ the o-diamino derivatives of the quaternary salts of the correappnd- !ing f-methylbenzothiazoles. Symmetric and asymmetric trimethynecy- .anine dyes were then prepared by heating respectively (a) the qua- ternary iodoethylates with ethyl orthoformate in pyridine, and (b) the tosylatei3 derived from I and II with the iodoethylate of 2-Ca- ,acetanilidoviny;Lbenzothiazole, in (CH5CO)2 0, in the presence of :triethylamine. The yielde of the 4 dyes ranged from 43 to 63%. ,There are 3 figures and 1 table. SUBMITTEDs February 5, 1962 i0ard 2/2 FRIDMAN, S.G.; GOLUBI, D.K. 2-Mothylthiazolo(4,5-e]benzoxazole and 2-motVlthiazolo[5p4-f]benzo- xazole. Zhur.ob.khim. 34 no.1:280-284 Ja 164. (MIRA 17%3) Uk~ IR 1. Institut organichaskoy khimli AN FRIDMAN, S.G. Reactivity of methyl groups in some trAcyclic nitrogen heterocycles. Zhur. ob. khim. 35 no.8:1364-1368 Ag 165. (MIRA 18:P') 1. Institut organicheskoy khimil AN UkrSSR. Fridman, Savd1yo Ly:vrevich 611.91 Fe Organizatsiya irhozynystvennogo roschets no stroitel'stva ekektrostentEly 4cost-necaunting orgenization in the conetruction Gf electric Fower str-tlane/ Mos"n, Gosenergoizdnt, 1955. 190 T). tablee. YRIDMAN, S.L,,--jnzh.-akonomiat Lowering production costs of precast reinforced concrete. 3-nerg. stroi. no.2:3-7 159 (KIRA 13:3) 1. Planovoye upravleniya Kinlaterstva stroltellstva elektroatantoiy. (Precast concrete) FRIDMAN, S. L. Cand Tech Sci - (diss) " Interaction of trawl and ship in lifting catch on the stern of the trawler." ZRaliningrad7, 1961. 16 pp; (Kaliningrad Technical Inst of the Fish Industry and Economy); 160 copies; price not given; list of author's works at end of text (i2 entries); (KL, 6-61 sup, 227) FRIDMAN, S. L. Cand Tech Sci - (diss) "Problem of use of current supply lines to submersed electric motors for telemeasurements in wells." Baku, 1961. 17 PP with diagrams; (Ministry of Higher and Secondary Specialist Education USSR, Azerbaydzhan Inst of Petroleum and Chemistry imeni M. Azizbekov); 250 copies; free; (KL, 6-61 sup, 22?) FRIDMAN, Sandlya Lazareyjxh;_SI21EL'WIKOVA, L.N., red.; DO."'UNOV, N.I., -r-e-a-. (Cost problems energeticheskom 271 p. (Power engineering-Costs) n power engineering]Voprosy sebestoimosti v stroitellstve. Moskva, Gosenergai-dat, 1962. (MIRA 15:12) 2) /cv AUTHOR Pridman, S. L, T'TLE: Method for determining the highest or-der of -.h,? dif f,~ren'~Ilal equation of a linear elec4r'~! elrculn I ~ PERIODICAL Eleklrosvyazl, no.1, 1962, 50-54 E-XT The anthor suggents a simple method for delonri-ning the hipzh-?bt order of the differential equation describing linear ele-tric any stricture and containing elements of any type. This method take,,; Into a.-,our-'. all the frequencies of the natural oscillation.5 of the sy!!tem, in.-.uding zc-ro natural frequencies. The detemination is effe:ted ty a dire:~, analyslE of thin circuit, without any previous recourse to its charact_"rist.,~c determinant- -Tt~ method I's based on the replacement of the initial --_Ircult hy a !~Impler one, having the same number of natural frequencies a~-. a minimum numbe- of reactance e1em9r.t3. Any electric circuit can be considered as a two-terminal re!~Wcrk WI-h either short-circuited or open termInals. in the --ase, its character- istic equation can be written as. z 0 Card 1/3 Method f~lr determining *he tlghjzst ordt,! AO"JAICA' where z (p) is the lmpedano-~ of the two-t~-rmln,-Ll velmorlk -vtl J~ second ca-,e, the aqua!~!on Is. y ( p) - 0 , -2 ~ . W!-~-'a:- r. -i- f p) t'~ - admit-tan-.9 of the lmo-ter-,ilnal network. Me ~wo-t-~rmlnal rletwo-k-- --.a..-, I~r turn, be repla~-.ed I.--y h-ir c;anonchl rh- :~IrcuP of tht, PL, R, L' 9--;d Fl,~, t.,4p-1c, fo~6 :Pf a -to the r,?twork of" J-Au--ttvp :~oupllng.': between the retwork, Tnr-refor,~-, -,h,~- order- of a nelm-,r1r. ~7on-i~;~ ir;f -r~vpc-E :an or la~u~ of t!~- ord- of v i 1"z . 6b ,~-'h- ~-!-d-'l Of %-4 ~j of t*j~- 121 y- (p) P'g. 61h. "'he d o In a' ne two r K T a,: 4.r!z7j,.; :. c-l ric-loz Tr, i;t t Ix -n- 'W dv~errni~-.iag th:? high-:,, or-dEo, af be N LF; where A ,s --hr: th~ f g? p ,"ard 2/3 32956 9/106/62/000/001/007/009 Method fte determining the highest order ... A055/A101 circuits consisting of homogeneous elements, w,,,, and mCR are, resnectively. thel number of independent circuits of the LR or CRI'Type counted up in the RLC-type networks after the opening of the circuits consisting of homogeneous elements (only R, only L or only C). The ki-value can be equal either to 1 or zero. At the end of the article, four practical examples of the application of the author's method are given. The Soviet personalities mentioned in the article are: Veber, A. A. Kharkevich, E. V. Zelyakh, A. V. Netushilov and S. V. Strakhov. There are 10 figures, 4 Soviet-bloc and 3 non-Soviet-bloc references. SUBMITM: July 4, 1961 Fig. 6: 6) 1, C C C, R'. R, R, Card 3/3 , Akim .1;umoy * ',. Prinimal uchaq , y dic U , V.; . t I t3 SG B ~; MGMAN, S.L.;KULIBATSKIY, K.Ye., otv. rejd.: *.-'J.~, -"0V) L".V., re'd.;'VOLODAIWWA, V.Ye., red. [Textbook on the theory of electrical comunication] Zadnchnik po, teorli elektricheakoi svIazi. 17A.2., pe- rer. 1-~oskva, Sviazliz6at, 1963. )45 p. 0,11hA 17:7) L 07103-67 EWT(m)/&V(t)/ET1 IJP(c) ACC NR: 4106029117 SOURCE CODE: UR/0048/66/030/006/0994/0997 ZZ/ AMOR: Turchinfikaya, M.I.; Fridman, S.L. T I/ ORG; institute of Metal Physics, Academy of Sciences, SSSR ( nstitut fiziki metallov Akademii nauk SSSR) TITLE: JDependence,9f the unidirectional anisotropy on the degree of atomic order in a n "i-m -v4lloy CReport, All-Union Conference on the Physics of Ferro- and icke _p Aaneso Ar~iiferromagnetism held 2-7 July 1965 in Sverdlovag-. 'of, SOURCE: AN SSSR. Izvestiyp. Seriya tizichoskayal v. 30p no. 6, 19661 994-997 TOPIC TAGS: ferromagnetism, antiferromagnetism, magnetic anisotropy, unidirectional magnetic anisotropy, ordered alloy, nickel alloy, manganese alloy ABSTRACT; The authors have investigated the dependence on tho degree of long range order of the low temperature anomalous magnetic properties (in particular, of the unidirectional magnetic anisotropy') of N13 11n alloys. The specimens were 10 cm long 1 mm diameter wires with 7 different degrees 3 of long range order from 0 to 1. The long range order was achieved by quenching the specimens in water from 9000 C and then subjecting them to the heat treatments described by N.V,Volkenshtayn and G.V.Fcdorov (Fiz.metallov i metallovedeniye, 9, 187 (1960)), and the degree of order was de- termined by neutron diffraction and from the order dependence of the saturation 1. FRIBMAII, S. M., Eng. 2. USSR (600) 4. Sorbents 7. Sorbents for oil regeneration by means of thermosiphons and adsorbents, Elsk. sta., 23, No. 11, 1952, 9. monthly List of Russian Accessions, Library of Congress, February .1953. Unclassified. PHASE I BOOK EXPLOITATION 577 Ivanov, V.S.,and Fridman, S.M. Masla i konsistentnyye smazki (Oils and Heavy Lubricants) Moscow, Gosenergoizdat, 1957. 248 p. 10,000 copies printed (Series [title of set]: Spravochnik khimika-energetika, t. 3) Ed.: Gurvich, S.M.; Tech. Ed.: Fridkin, A.M.; Eds. (of set): Golubtsov, V.A.; Gurvich, S.M*; Kostrikin, Yu. M. and Mamet.,AoF. PURPOSE: This manual prepared for the use of chemists and power engineers. It may also be used by workers in laboratories, scientific research institutes, and designing and planning organizations, and by students at vuzes and tekhnikw6iis. COVERAGE: The authors present a detailed study of the physical and chemical characteristics and properties of oils and greases. They also cover in detall the purpose of lubricants, their specifications as' required for use at electric power stations and methods for assuring that these specifications are obftrved. Seventeen authors contributed to the compilation of this manual. The bibliography contains 86 references., all of which are Soviet. Card l/ 4 Oils and Heavy Lubricants 577 2-4, The substitution and blending of lubricants; winter lubri cants 58 Ch. 3. Purifying, Regenerating and Stabilizing Oil 61 3 1. Treatment of power-plant lube oils 61 3-2* Regeneration of power-plant lube oils 70 3-3. Sorbents for regenerating lube oils 77 3-4. Adsorbents 86 3-5. Themosiphon filters go 3-6. Regenerating lubricating oils 94 3-10 Additives for oils 99 3- - Cleaning of oil systems 105 Ch. 4. Oil and Grease Consumption 110 4 1. Consumption of power-plant lube oil 110 4-2. Consumption of lube oil and grease 121 Ch. 5. Testing Oils and Greases 121 5 1. Regulating the quality (grade) of power-plant lube oils. 153 Card 3/4 FRIWAN, S.M. Experlmentnl study of the therapeutic effectiveness In guinea pigs of Uvnrov's nnd antiendoantigenic antibrucellsr serum. Zhur.mikrobiol. epid. I immun.,aupplement for 1956:34-35 157 (MIRA 11:3) 1. Iz Odesskogo institute epidemiologii I mikrobiologii. (SER%l THERAPY) (BRUCELDOSIS) FRIIEANI S.Ya. (deceased] Gas exchange in white rate during muscular exercise under con- ditions of a maximum load, Opyt imcbe rege fiziol. fwik. 61 28-31 163 (MRA 17:3) 1. Laboratoriya obahchey fiziologii sporta Loningradskogo naxichno-issledovatellskogo instituta fizicheskoy kulltury i laboratoriya ekologicheekoy fiziologii. ( zave - prof* A.D& Slonim) Instituta. fiziologii imeni Pavlova MI SSSR. FRIDHAN, S.Ya., kandidat maditainskikh nauk Perilimbal novocaine block in the treatment of keratitis. Test. oft. 33 no.5:25-30 S-0 054. (MIRA 7:10) 1. It kafedry glazzWkh bolesney (say. prof. M.L.Krasnov) TSentrall- noge instituta usovershenstvayantya vrache7. (AIMSTHISIA, REGIONAL. periliabal procaine block in keratitis) (PROCATIM, therapeutic use, keratitle, perilimbal block) (IMRATITIS. therapy. proea,ine perilimbal block) YRUW, S. Ya. optochlaamtic arachnitis in an ophthelsological clinic. Say. nod. 19 no.11:27-31 11 155 (KLRA 9:1) 1. Is kafedry glazzykh bolezney (zav.-prof. M. L. Xrasnow) Teentralinogo Instituta unovershenstvovaniya vrachey (dir. V. P. Imbedeva) (AUGhNOID, Aiseasem, arachnitle, opto-chaomtic) YRIDKLN. S.Ya., Imnaidat moditainskikh nauk *Mnual on seleattug glasses." N.M.Galkins Reviewed by S.IA.Fridmm. Vestooft, 69 n0-3139-41 My-Jo 056. (KLRk M) (amomany) (GAMN. N.M.) BELOSTOTSKIYO Ye.K.p doktor med.nauk (deceased]; FRI12jM-,. S.Ya., kandemed. nauk Prescription of eyeglasses in concomitant strabismus. Uch,zap. GRIT glaz.bol. no.7t27-33 162. (MIRA 16:5) 1% Iz otdeleniya okhrany zroniya detey Gosudarstremogo nauchno- isoledovatellskogo instituta glaznykh bolezney imeni Gellmgolltsa. (STRABISMUS) (EYEGLASSM) BFWSTOTSKIY, Ye.M., doktor med.-Tiauk Ldeceased); FRMIAN, S.Ya., kand. med.rauk Color instrument for the examination of binocular vision. Uch.zap, (MII glaz.bol. no.712Z7-231 162. (MIRA 160) 1. Iz otdeleniya okhrany zreniya detey Gosudarstvennogo nauchno- isaledovatellskogo instituta glaznykh bolezney imeni Gellmgolltsa,, (M., INSTRUIENTS AED APPARATUS FOR) (BINOCULAR VISION) FRIO-IAN, S.Ya., kand.med.nauk Teaching activity of the Department for the Protection of Vision in Children of the Gellmgolltsa Institute. Uch.zap. GNII glaz0bol. no.7:289-290 162. (KM 16:5) 1. Iz otdoleniya okhrany zroniya detey 0osudarstrennogo mouchno- inoledovatellskogo instituta glaznykh bolezney imeri Gellmgolltsae (01PHTHAU-10LOGY-STUDY AND TEACHING) BELOSTOTSKIY, Ye.M., doktor med.nauk [deceased]; AVETISOV, E.S... kand. med.nauk; FRIRWI,.S.Ya., kand.med.naul-; SMOL3YANINOVA, I.L., kand.med.nauk; 'EVA-fdVA, A.V., kand.med.nauk Basic problems of diagnosis and treatment of concomitant strabismus. Uch.zap. GNII glaz.bol. no.,7s7.-l2 162. (MIRA 16;5) 1. Iz otdeleniya okhrany zreniya. detey Gosudarstvt=ogo nauebno- issledovateltskogo instituta glaznykh bolezney imeni Gellmgolltsa. (STRABISMUS) USSR/Hufan and A`Lnimal Physiology (Normal and Patholocical). T-11 Nerve and Muacle Myciology, Abs Jour : Ref Yliur - Biol., No 11) 1958, 51198 Authur : Fridrjan, S.Ya. Inst ; State Scientific Research Institute of Child Orthopedics. Title : The Characteristics of Muscle r-hysiolo ", in Traumas of the Supporting and Motor Apparatuses. Orig Pub : V sb.: 6-ya nauchn. sessiya Gos. n.-i. detsk. ortoped. in-ta, 1954, L., 1956, 3o6-316. Abstract : In a unilateral amputation if an extremity, the galvanic excitability (GE) of almst all muscles which have lDut their distal point Df attnclzient is lowered, while the cbronaxy (Ch) is len(,-tLened by 11-21 times as compared with the symmetric chrinaxy of the other extremity. In bilateral amputations, a longhtening of Ch and a lowering Card 1/3 USSR / Human and Animal Physiology. Neuro-muscular Physiology. T-9 Abe Jour : Ref Zhur - Biologiya, No 1, 1959, No- 3724 Author : Uflyand, YU, Ms ', TrIdman S - Ya. Inst : AS Georgian SSR Title : Effact of Meals Tension on Ito Functional Properties OriS Pub : Probl. sovrem. fitiol. nervns i mvahechn. sistez. Tbilisi, AN aruzm, 1956, 465-471 Abstract : The increased contraction effect of a tired skeletal muscle after stretching is conditioned upon the action on the nerve endings in the muscle. Increased con- traction of the cardiac muscle when the intracardiac pressure also riese,basically depends upon stimulation of the nervous elements. The isotonic character of macular contractions in the Intact animal, as vell as in patients with Injary to the tondon) makes the functional state of the muscle and Ito innervation worse. Card 1/2 USSR/Humn and Animal Physiology - Neuro-Muscular V-11 Physiology. Abs Jour Bef Zbur - Biol., No 1, 1958, 4368 in principle, and closely related to the mtor capacity. The weakened activity of the affected muscles was always reflected by a decreased frequency and amplitude of the muscular bio6urrents produced by voluntary contractions. On the affected side) the frequency of the electric os- cillations and their amplitude were markedly lower than those of tile symmetrical healthy muscle. Sometimes, in cases of complete paralysis of some muscles, when their contractions were no more observable, electromyograms showed rare oscillations (10-20 per second). This pro- ves the presence, in the paralyzed muscles, of sinale neuromotor units still having a normal nervous connection with the spinal cord and the brain. The authors think that the results of the experiments show that, aftor liomyelitis, there are foci of lonG-lasting inhibition in the cellular formations of the spinal cord. Card 2/2 -.USSR/Human and Animal Physiology - The Nervous System. V-8 I Abs Jour : Ref Zhur - Biol., No 4, 1958, 18516 surgeons in every way possible avoid keeping a =scle for a prolonged time under isotonic conditions. Card 3/3 unnn, Tu.m., prof.; GOLOVINSKATA, N.V., starshly nauchnvy sotrudnik; TRIDMAN, S.Ta., otarshiy nauchnyy sotrudnik Physiological studies of late results of tendon and muscle trans- plantation In poliomyelitis. Ortop.travm.t protez. 20 no.8:8-15 Ag '59. (MIRA 12:11) 1. 1z fisiologicheekoy laboratorli (zav. - prof. Tu.M. Uflyand) Nauchno-issledovateliskogo detskogo ortopedicheakogo instituta im. G.I. Turnera (dir. - prof. M.N. Goncharova). (POLIOMTZLITIS, surgery) (TMMNS, transplantation) (MUSCLES, transplantntion) MIRZOY_7VAI I* I*# stareho' nauch.'Botrud.; FRIMWI, So Ya., steLrBh. nauch. sotrud. I - Contractures in children in the rehabilitation period of poliomyelitis, Ortop., travm. i protez. 22 no.8:41-49 Ag 161. (MIRA 14:12) 1. Iz Gosudaretvennogo nauchno-isoledovatellskogo detskogo ortopedi- cheskogo Instituta im. Go I. Turnera. (dir. - prof. M. No Goncharova) (POLIOffELITIS) (CONTRACTURE) FRIDMAY, S. Ya. Coordinative correlation of the muscle antagonists of the knee joint accordinr to electrcmyographic studies. Trudy LSC2-1I 64: 88-102 161. (MIRA 15:7) 1. Fiziologicheskaya laboratoriya Gosudarst7ennogo wichno- isoledovatellskop,o detskogo ortopedicheskogo instituta imeni G. I. Turners. Mv. laboratorlyey - prof. Yu. M. Uflyand. (ELECTRCMYOGRAPHY) (191EE) BOXASH, Ta.P.; KANAYEV, N.N.; LIKIINITSKAYA, I.I.j FARILOVA, V.A.; TIMESKOV, I.S.; TRETIYAKOV, A.F.; _YgPRAH, S.Ya. (deoeased]; RrNMICH, V.S. (Methodological fundamentals for using functional studies in practical expertise] Matodicheskie oanovy ispoltzovaniia funktsionallnykh issledovanii v ekspertnoi praktike. Leningrad,, Meditsina,, 1965. 228 p. (MIRA 18:12) - ~ . - .1. ~ --- - -- ~ ---1 -1----1.11111-1..---- --- - ". 4. - -1~ FPIDMAN, SL Ye. USSR (600) Beets and, Beet Sugar- Inspection of sugar beets for physical condition and dirt. Sakh. prom. no. 7. 1952 9. Monthl List of Russian Accessions, Library of Congress, October_195Y, Uncl. 2 FRIDMAN, S. Ye. Beets and Beat Sugar Acceptance of beets by sugar content. Sakh. prom. 26 no. 4:17-19 Ap. 152. Monthl List of Russian Accessions, Library of Congress, July 1952. Uiclassified. FRIDMAN, S. Te. Conferenco on raw materials for workers of tile Main Sugar Administration. Sakh.prom. 27 no.4:46-48 Ap '53. NLRA 6:6) (Sugar industry) YRIDKAN, S.Ye. Results of receiving beat@ on the basis of sugar content In 1954. Sa~h.prom.no.6:32-35 155. (MIRA 9:1) l.Glmvoakhar (Sugar industry) FRIDW, S.Ye. 6 - - Outlook for further development of the rav materials supply for the sugar industry. Sakh.prom-30 no-1:3-5 J& 156. MRk 9:6) 1.Qlavs 0 (Sugar industry) (Sugar beets) -ELTMI- -ST ~ Experience of the Zherdevka. Sugar Mill with mechanizing truck unloading and the piling of beets in surface ailes. Sakh.prom. 30 ne.2:58--60 P 156. (KIRA 9--7) l.Glaveakhar, (Zhardavka--Sugar industr7--Iquipmant and supplies) FRI DIAN, S. Ye. Conference an the work of the bases of the Central Scientific Research Institute of the Sugar Industry In storage of sugar boats. Sakh.prom. 30 no.5: 10-11 f4*- 156. (K12A 9: 9) (Subar beets--Storage) 6WRnfitl G-jltaf rerfiuzatm~- 0. Iugar VIC-issium mi tritd, Gat of l4ej pnitive result-5 with tacmifc of sucrose In sugar beitO up In 14 Al IMDKLM, S.Ye. ___ - - - "000 ---- wafta-~ Greats normal operating conditions for tractor-mounted shovels (Concrete loading platforms). Sakh.prom. 30 no.7:36-37 Jl '36. (HLBA 9:11) 1. Roaglaveakhar. (Loading and unloading) FRIDIAN, S.Ye.: DONCHAK, A.S.; UYAVIR, I.Yu. -,-v ~. Obryvko beet stacker-unloader and rqke-type beet loader. Sakh.prom. 30 no-7:50-54 J1 156. (MLRA 9;11) 1. Roaglavaakhar (for Fridman and Donchak); 2. Veasoyuznyy nauchno-isoledovateliskiy institut evskly (for Klyavir). (Sugur induotry-Squipmant and suppliea) FRIBM, Me. -11-1:~'11----M-001911"~ Determining th~lamount of dirt sad trash in sugar beets delivered to sugar plants. Sakh.prom- 30 no.9:36-37 5 '56. (n" 100) 1. Roaglaveakhar. (tiugar beets) FRIDK". S.Te. --?go Ni~-~ new mat-binding machine. Sakh.prou.30 no.11:49-51 1 136. (KM 10:2) lo Rouglavankhar. (Textile uLchinery) FRIWN, S-Ye., agronom-ekonomist increase the sugar content of beets. Hauka i pered.op.v sellkhos. 7 no-7:62-64 JL '57. (IKLRA 10- 8) : (Sugar beets) lAssons of the sugar beat harvest in the R.S.Y.S.R. Sakh. prom. 3; no.5:60-63 Vq '57. (xLRL lotO 1, GosudaretvanzVy Institut po proyaktirovaniyu novogo stroitell- etva i rokonstruktmii prodpriyatiy eakharnoy Drowyehlennosti. (9ugar beat a--Elarvesting) r 9 1 v A/1"? A~ ."31, 4". FRIDKAN, S.Ye. 11-- ,.- . Certain regularitieg 31 no.9:40-42 S 157. 1. Gosplan RSFSR in the growth of sugar beets. Sakh.prom. (MIRA 10:12) (Sugar beets) r (,/(" FRIDMAN S.Ye. I t_~ sugar beets in underground beet storehouses In Krasnodar Territory. Bakh.prom-31 no.9:66 S '57. (MIRA 10:12) (Krasnodar Territory--Sugar beets--Storage) USSR/Goneml Problems. Methodolo,.- --y. History. ~)cientuil'-JcA Institutions and Conferences. Qflestions Concernin~-, Biblio,-raphy mr.' 'J*cian- til'ic Documentation &bs Jour Ref Zhur-Ehimiya, I-To S. Ye. IL-ridman, I. A Raw Material Base of the L~Oth Anniversary Sakharnaya prom-st', 3, 10,58, 6825 Selyuk the :,ugar Industry to of Soviet Rule 1957, 1,10 102 10-13 Author Inst Title Orig Pub Abstract No abstract Card 1/1 FRIDRAN, S.Te. To~-dition of sugar beets. Sakh. prom. 12 no.4:60-61 Ap '58. 11:6) (MIRA 1.Gosplan RSFSR. (Sugar beets) -VaOD-rOA2o-yjo4; LTSWO, T.M.; SnTUJC, I.A. PIRMj -4 (Manual on the procurement, receiving. and storage of sugar bests] Spravochnik po sagotovks, priemko i khransuilu sakharnoi svekly. Moskva, Pishchapromisdat, 1959. 393 P. (Dagar beets) (HIM 13:8) FRIDMI, -..I-.% - Some urgent problems of the storage, transportation I and unload- ing of sugar beets. Bakh-Prom. 33 no.6:19-21 Jo 59. (MIRL 12:,q) (Sugar beets) FRIDRAN, S.Ye. Scientific symposium on sugar beet growing. Sakh. prom. 33 no-11: 63 N '59 WRA 13:3) 1. Gosplan RSTSR. (Sugar beets) FRIDUN, S.Ye. Densit7 of sugarTbeet planting In the R.S.F.S.R. Sakh.prom. no.4:72-73 Ap 60. (MIRA 13:8) (Rusia--Sugar beets) FRIDMAN, S.Ye. ill-Russian Conference of Sugar-.feet Growern. Sakh.prom- 34 no.6: 18-19 Je 16o. (MIRA 13:7) (Russia--Sugar growing--Congresses) FRIDRAN, S,Te. latest in fertilizers, herbicides, and poisonous chemicals for sugar beets. Sakh.prom. 34 no.6:72 Je 16o. (MIRA 13'rP (Sugar beets-Fertilizere and manures) (Herbicides) (Pesticides) ,.YRIDKM, S.Ta. Prospects for the developwnt of sugar manufacture In Siberia and in the last. Sakh.prom. 34 no.7:10-12 Jl 160. (MIRA13:7) 1. Gosplan RSISR. (Siberia--Sugar industry) (Soviet Far Bast--Sugar industry) JrR IDMAN, S. To. Machine for making pressboard plates. Sakh.prom- 34 n0-8:36 Ag 160. (MIR& 13:8) 1. Gogplan RSISH. (Sugar industry-lquipment and supplies). Urgent objectives in the development and consolidation of the raw material supply for the sugar industry. Sakh. prom. 34 no. 12:1-3 1) 160. (MIRA 13:12) ($Mar Industry) FRIDMANq S Ye. Saccharinity of beets and improvement in the operation of sugar- beet-receiving terminals. Sakh.prom.35 no-3:59-61 Mr 161. (MIRA 14-3) 1. "Rosglavpishchesnabsbytayrlyel Vaerosi3iyskom Sovete Narodnogo KhozyaYstva. (Sugar beets)