SCIENTIFIC ABSTRACT E.A. DAIDBEKOVA - B.YA. DAIN

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000509520017-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 12, 2001
• Sequence Number: 17
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

DAIDBEKOVA, Z.A.; KURBANOVA, Y.M.
Idthofacies characteristics of sediments In the producing formation
of the lower Kura Valley in connection with their oil potential.
Azerb. neft. khoz- 38 no.8;13-15 Ag '59. (MRA 13:2)
(Kura Valley--Petroleum geology)

DA~DBEKOVAO E.A.
Minoral and geochemical facies of sediments in the flysch formation
of the southeastern Caucasus. Trudy AzNII DN no.9:1+4-53 160.
(Caucaffus--Flysch) (MIU 14:5)

~,DAIDBEKOVA, E.A.; POKIDIN, A.K.
Lithological and thermographic characteristics of carbonate rocks
in the southeastern Caucasus. Trudy AzNII DII no.10.122-130 :60.
(MIRA 14:4)
(Caucasus-Rocks, Carbonate)

DAIDBEKOVA, E. At, Doc GEOL 09ft M I N&M SC 1 9"PETROGRAPHY
-9 -L
OF THE FLYSCH FORMATION OF lk SOUTHEASTERN CAUCASUS." BAKU,
1961, (JOINT COUNCIL OF AZERBAYDZHAN INST OF PETROLEUU
AND CHEM IMENI IA* AZIZBEKOV AND INSTITUTES AND INSTITUTIONS
OF ACAD SCI AzSSR FOR GEOL AND MINERAL SCIENCES). (KL-DV,
11-619 212).
-58-

__ D~I~B~_KQU,-",I-IMGIMOVA, B.M.
Hydrotroilite in deposits of the akchagyl stage in the Kura Lowland.
DokJL. AN SSSR 137 no-3t678-680 Mr 161. (MIRA 14:2)
1. Azerbayzhanskiy nauchno-issledovatel'skiy institut po, dobyehe
nefti. Predstavleno akademikom N.M.Strakhovym.
(Kura Lowland-Hydrotroilitei

DAIDBEKOVA, E.A.; POKIDIN, A.K.; ISMAYLOVA, R.S.
Mineralogy of clays of Cretaceous sediments of the southeastern
Caucasus, Blul.MOIP.Otd.geol. 36 no.6:37-.48 N-D 961.
(111RA 15:7)
(Caucasus-Clay)

DAIDBEKOVA, E.A.; BABAYEVA, R.S.; GRIGORIYANil), Z.G.; KURBANOVA, F.M.,
I TBRAG1140VA, B.M.; SHAMAILOVA, O.D.
Granulometric tyreB of rockn and allothigerie mirierals. Trudy
GIN rio.115:29-.67 165- (MIRA 18-12)

f
A-
S/075/60/015/004/013/030/XX
B02O/B064
AUTHORS- Yordanov, N, and Daiyev, Khr.
TITLE, Photometric Determination of Cerium by Means of o-Tolidin,,
PERIODICAL: Zhurnal analiticheskoy khimii, 1960, Vol. 15, No 4.
pp, 443 - 445
TEXT- The present paper describes a new, unpublished method for a more
selective and accurate determination of tetravalent cerium with o--tC-.'1idino
(3,31-dimethyl benzidine)l the qualitative reaction has been known sincp
long, but has hitherto not been used for quantitative cerium determination
Cerium was separated from the disturbing components together with the rare
earths in the form of oxalates. If there are no rare earths present in th
analyzed material, lanthanum nitrate is added, and the oxalates are el
precipitated. A 12 mg/ml La(NO 3)3 solution was used in the experiments
Since the lanthanum nitrate available contained approximately 0 14% Ce. it
was purified by the method of V~, M. Klinayev and N N Senyavin (Ref 12)
The optical density of the solution was measured with a photoelectric
Card 1/3

Photometric Determination of Cerium by Means S/075/60/015/004/013/030/XX
of o-Tolidine B020/BO64
colorimeter of the type !M-M (FEK-M) with a blue filter (permeability
maximum at 410 m~L). Fig. 1 shows that the solutions follow the Beer law
at concentratioris up to 3 rCe/ml. The molar extinction coefficient is
approximately 9500. The reaction with o-tolidine is 20 times as sensitive
as with H202" The coloring produced remained stable for several hours
under the chosen conditions, and vanished only on the following day The
yellow color remains unchanged for 20 minutes after the addition of the
reagent; then it fades gradually (Fig, 2) A change of pH between 0 and A
has no appreciable effect upon the sensitivity of the reagent When using
12 mg of La(NO 3)3 as a collector, the coprecipitation. of 10 - 200 T Ce
proceeds quantitatively.. Table 1 shows the reproducibility of thexthod.
which is mainly due to the quantitative conversion of CeIII to Ce , and
also the stability of the oxidation products of o-tolidine The effect of
Fe, Al, Mn, and Ti in amounts of Ce4Fe - 1:10,000, Ce:AI,1~3,000,
Ce:Mn-1:350, and Ce~Ti=1000 was studied for the purpose of using this
method for cerium determination in minerals and rocks. Fig- * shows the
calibration curve used to determine cerium by means of .:, tolidine The
time dependence of the optical density is illustrated in F'ig 2 Table 2
Card 213

Photometric Determination of Cerium oy Means S/075/60/015/004/013/'030/XX
of o-Tolidine B020/BO64
shows that under the above conditions, the coprecipitation of cerium
proceeds practically quantitatively, that even in the presence of com-
paratively large iron and aluminum quantities, no soluble cerium oxalate
complexes o~ these elements are formed, and that in the precipitation of
both hydroxides and oxalates, no coprecipitation of manganese takes place
in the presence of hydroxylamine hydrochloride. The fact that a number of
elements is not coprecipitated with lanthanum oxalate, is also related to
the separation of the latter in acid media. Thorium, yttrium, neodymium,
praseodymium, ytterbium, terbium, and samarium have no disturbing effect.
The method described was used to determine the cerium content in apatite,
titanite, and monzonite (Table 3). There are 2 figures, 3 tables, and
12 referencess 6 Soviet, 5 German, and 1 British
ASSOCIATION: Sofiyskiy gosudarstvennyy universitet (Bolgariya) (Sofiya
State University (Bulgaria))
SUBMITTED: July 9, 1959
Card 3/3

IORDANOVY N.;_PAjnY, Khr.
Separation of small amounts of rare earth elements from min-
erals and rocks by chlorination with carbon tetrachloride.
Zhur.anal.khim. 17 no.4.-429-431 J1 162. MRA 1516)
1. Institute of General and Inorganic Chemistry, Bulgarian
Academy of Sciences, Sofia.
(Rare earths-Analysis) (Carbon tetrachloride)

1(4DANOV, N.; DAIYEV., Kh. [Daiev.. Kh.1
- ~~- 11-1.
The NP NP N' N' tetramethyl o-tolidine (Tetron) as reagent in
determining Lall quantities of cocidants (Au'IIII)p Ce (IV)v
Brll~ etc.) Doklady BAN 16 no.1:69-72 963.
1, Predstavleno chl*-korr, N, Penchevym.

10'00011, l1.; DAIEV, F.'rjr.
"I F . I _i
I. trhjt~ov ~,r -1 - [,~'Af ~,, el ement.z Jp.
-if, - r,,,t in effun ive, int :-.; I v ~~ ,-r.~,. !,., ~-ph I - r4- t I. Pim
Bulgarl-la.TkAklady Il n~ .11 164'
1. 1'reds'llvien") N... 7'enuh.~,.ryx.

,DAIKHZS, A. I.
Professor Wis. Mironovich Burakor; on hie '10th birthday. Vast.
otorin. no.2z,123 '62. (MIRA l5t2)
(BURAKOVI, ILOIA MIRONOVICH, 1891.)

RUBIN, S.S.; DAIUTSKIY, A.F ; ILICHENKO.. V,A.; KARASYUK, I.M,
Methods of studying the root systermof agricultural plants.
Bot. zhur, 47 no.8:3276-1184 Ag 162. (MIRA 15:10)
le Umanskiy sellskokhozyayBtvemyy institit imeni A.M. Gorlkogo.

DAILIDONIE21E, Jadvyga; L., red.
(Tuberculosis, an infectious diseasej Tuberkuil.oze -
uzkrociar-.a liga. Vilnius, Vaistybine polit'nes ir
mokslines lit-ros leid k1a, 1(A-3. 16 1). (In Litluanianl
W11AP. 17:7)

DAILID0111111E, J.
Tuberculosis morbidity in the Republic according to fluoro-
graphic data. Sveik. apsaug. 9 no.3:36-39 YJr164
1. Respublikinio tuberkuliozes dispanserio n-r. L-
jdytoja.
~k

DAILIDONIENE, J.
Tuberculosis morbidity in the Republic according to fluorographic
data. Sveik. Apsaug. no.3-36-39 164.
1. Lietuvos respublikinio tuberkuliozes dispanserio vyr.
gydytoja.

DARUCA, Victor, Prof.
Celestial phenomena in December 1961. Gaz mat fiz 13 no.10:559-560)01"
(Mechanics, Celestial)

DAIIM~ACA, Victor, prof.
Data on cole-itial phenomnna in February 1962. 3az -at fiz 13 rc).12:
663-664 D 161.

DAIMACA, Victer, pi-cf.
-
Celestial phenomena of Mnrch 1962. GRz mat fiz 14 no.1:54-55 Ja 162.

DAIMACA., Victor), prof.
Celestial phenomena of April 1962. Gaz nit fiz '14 no.2:110-111 F '(,-,

DATMACA, Victrr, prof.
C?!le.5ttal p~.encmenA ib MAy 162. Gaz 7nt fiz 14 nc. 3:167-168. llx 162

DAIMAGA, Victor, prof.
The celestial phenomena in June 1962. Gaz mat fiz 14 nc..4:
220-221 Ap 162.

---- DAIMACA, Victor, prof.
The celestial phenomena in July, 1962. Gaz mat fiz 14 nQ.5:
279-280 My 162.

DAINACA, Victor, prof.
Celeatial phenomena in the month of August, 1962. Gaz mat fiz
14 no.6:333-334 Je 162.

DAIMACAY Victor, prof.
Celestial phenomena in September 1962. Gaz mat fiz 14 no.7:
391-392 Jl 162,

DAIMAGA, jicUrj, prof.
Celestial phenomena in Octobbr 1962. Gaz mat fiz
14 no*8:445-446 Ag 162.

DAIMACA_,, -Victor,,- vmf.-
Celestial phenomenon in Noveraber 1962. Gaz mat fiz 14 no.9003-504
S 162.

PAIMACA, Victor, prof.
Celestial phenomena in December 1962. Gaz mat fiz 14 no.10:559-560
0 s62.

I __RkIKkU, --Viztar,-prqf .
Celestial phenomena in January and February 1963, Gaz mat fia 14~0 ,
no.11/12:653-655 N-D '62. 1

_kA:IMAqA, Victor, prof.
Celestial phenomena in March 1963. Gaz mat f12 15 no.1:55-56
ja 163.

P*n4cl Victor. Prof.,
01 ~-- - -A
Celestial phenomena in April 1963. Gaz mat fiz 15 no.2snO-lll F
163.

DAIMACA, Victor.4rof,
qmpxmm--,--
Celestial phenomena In YAy 1963. Gaz mat fiz 15 no.3:166-167
Mr 163.

f j,,, -, ~, t. C A Vi c tc 1, .I.C)i,.
p : I
A- J t- I-Cll I I P,'l I I P, L 'J1 . ( i ~k Z : 11 '. ' ' I :~ ~ ', n,,.4:.'2 11 F I ~, 'I

DAM4ACA, Victor. Prof.
Celestial phenomena in July 1963. Gaz mat fiz 15 no.5:277-278
My 163.

DAIMCA, Victorp prof.
Celestial phenomena in August 1963, Gaz mat fiz 15 no*6:
335-336 Je 163.
9

DAIMAGA, Victor, prof.
Celestial phenomena in September 1r)63. Gaz mat fiz 15 no.7-390-
391 Jl 163.

DAIMAGA Victor, porof,
Celestial phenomena in November 1963. Gaz mat fiz 15 nc.,9004-
505 3 163.

DARUCA, Victor, prof.
Celestial Phenomsna in December 1963. Gaz mat fiz 15
rio.10:558,559 0163.

DAIMACAJ, Victor, prof.
Celestial pheremena in October 1963. Gaz mat fiz 1r)
no. 8: 447-478 Ag 163.

DADD.CA, Victor, prof.
Colustii~T-Phenoviena in January 19".4, 6uz mat Fiz 1~ I'0-11:
667-668 N 163.

TAIMACA, Victor, Prof.
1 1 (
A.stron-,mlcal data. Guz mat fiz 15 nr~J;-;721, : 1~ 3,

..-DA324ACA, Victor, prof.
Planetary phenomena in May 1964. Gaz mat fiz 69 no. 4:
156-157 Ap 164.

DARIAICA, Victor, prof.
Astronomical data. Gaz mat fiz 69 no. 5:197 MY '64.

"', A 1 M."t C A , ,v,~~Ctorl 3~rof.
P 7 an el a ry phenc I d u-,~ ::-, ,, ~- -. -, .,? 1 r, ~ . , - ,~? ;! -, - ~ ~ " 1
I T
11 c, . 6 - ~ Y-1 - 2 ' 12 ; t- 01-

DAIMACAP Victor
Planetary pt.enornfina ir 1964. Gniz mat, fiz i,'~ r,-'. 7-
278 JI '64.

!-A NMACAY Prof.
Astronoml,~od :uta. -mal. fiz 69

,;~ l'-7, -,- 14, 1 . ~ -, '. pn~,; . ; , * 'I
-- .-I I - , ., - - . I
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1 ' ~ "7 t'rAl'Y P""Il -~ f ;*' ~ ; i - " ~ - - I .
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DAIMACA, Victor, prof.
Astroromical data* Gaz mat fiz 69 no.9060 S '64.

DAIMACA, Victor, Prof.
Astronomical data. Gaz mat fiz 69 no,lot4oo-4ol 0 164.

DAIMkCA, Victor, prof. (Buoureati)
Astronomical data. Gaz mat fiz 69 no.11:439-440 N 164.

DAIMACA, Victor, prof.
Astronomleal data. Gaz mat fia ?0 no.2:75 F 165,

DAIMACA, Victor, prof.
Astronomical data. Gaz mat fiz 70 no.4:159 Ap 165.

prof .
Astronomical data. Gaz mat fiz 70 no.3:119 Mr 165.

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IN is if lill", alas UP 'to
A Is A,-&* 40 IPIP4 1"I ,IT 1, 1 as 0 a 0 U J--s
0 A 16901111111 00
pfacItSd!-..V 1, -.00
::Aj -00
0 0 t
it
0 voluenstlif; photogalvanic effect in solutions ot elec
trolytes. 1. Photogalvanic affect of *%&late$ It. Vu
h Z. kina. B-- I ....... jm-,kv I.A.
0: Ua4sand A. 1 -00
-00
CArm., Mad il'sit. Ukr. S. S. R. 12, ki ONXIIII.,
0 jr A A photoge.1vanic eflect wa% nh~erved on smooth I't and
0 I't-black electrodes in a soln. I-( K,C,O,. It i% shown thai
90C :nhc ritert I~ due to the phw-h~tn. protv,,t takitisli,o,
the vol. of flit- rict-trolyfe and is derident 4 111, 20
4111411 wave length, The effect k explained on I te batiq of th. kin 060
Irmix)rary disturbon~ c4 the ionir equil. in the qtAti. ~'1-09
B. Z. Kanlich 00
oa
10'
10
0
woo
Its 00
;V &SO-SLA AITALLURGICAL 1.119RA11641 CLASUPICATION is 00
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0
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and the 1,11111417 Illwl'All-'ns, -.cluw 4. ill,
owmd im.-i wit ')'~ ti"ll If .".I[
m%, of '.f. It,
I fir iv..

I If
IlK to A, 1.1 ll'ill I~K.- It. , oil,
mill.. snd I'llit'Vttil Alt A i 1.41r; 111t,.111p.11CIll illillICIS"ll
tvfw is dile go) life SAtfl. "t thr -Ill. -Ilh If Wme evolfij~ 0
ti(In. ¬ the rate (d rvulutlwl v-afcrlv chaloar, %ltIj A
-
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. 1., ,4,
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'l
ic see
l
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Ill,
.
......... . Oil.
.0 0
-00

00 00
00
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it V If AA I I I of 1 0 IN Of 4 1
n it, At o; it 4, 14 Kis q a It lot if m of n 4 1
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A

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11174
00 A
*0
of
of
of.-M
00 4
of 0
so
of
ad
ol NaCIO gm In two directions, (1) witb
dOt 3CJO-ogQ- - Ot and (2) withlorusatim
"deblowelaw-lOCK),-+0'. niartmovalfibe
heterogenow admixts. dmgu the direction of the kinctic
cam of the evolution of 0. The curve attains an auto-
catalytiacharacter. Filtersoldiffertutporositymmused
fortbeffitration. The purer solus. were awre stable. A
N&CIO Soln. UM& from vtry h Icals, proved to be
The catalyiK =tba decmpa. of
N-164niab-mb 4kvctWm, but It Is Jew mkeabk In tbe
m
sese I= with formation, 91 chlorates. The inywigation
ks& to dw assumption that both diftetirms of the de-
compa. of NaW at based an the mms "WY=.
a. M..
ASSALA NATALWO&CAL LIMSATOW CLU&MION
~ 21MM21" -
lee
*0*
-00
000
lee
Ii
: 90 0
Coe
%o
46 0
we 9
lee
wool
Wool
UWATIMMIi
0 &;a a . a asil _Goes 6 *1* 0 0 0 a 0 a 0 0 0 6 0 a 6 6 a

V V Vu OF W V v WIM vjff!ffl~
so go 0 00 00 0 C ;
00 1 0, 0 0* fee 00 0 0000 4 0 oiw
Is to a 4. 11 U 11 1 " a .
A a r. It A
1 -1, AA 4
00 4 It - . 1.
00 la,,"m sfijMq spite of disfalved P*Wdvf Im.
0g y6 in. ti. p. Kutsays and H. A. Libefffool. 1)"Perido
A ;tpNdvA a*d AMA' "4'
to x.I. 19". Ms. 1 2. 4:1 4~ Its fiti,-ian, 45. I's FJ1811-11, 01
_TW A I ISO hull .*- I ..... 1 .4 Ote 'j- tfuln I'd
eras w-,11 as Fe Isms emackics with the nuck a Isrealmic
0 avra TheprsmAty lee
act rn 1xith CoLles j3 an clectionve Im-ttan taking pt.,,~
06 91, within the complex of the ion -hy,fral rd shell
00 V 0
00 4100
040
FO 0
As* ILA SIVAItUMEAL 019441s,98 (L*sI1ftC.TC.
~4_ ~ 3: ,I'll- 11. 1 1- . -A : fDo 0
OF 0,
all
I u.11
A I
0 to to to 0 at Of a K a of a. .1 An a 4 4
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0 0

DADjj i . Ya; IONSAYA, B. F.; LIBFqZ011, Z. A.
_13
Tnst of Fhysical Chemiotry i;-imi L. V. Pisamhevskiy, Acad. cof' Se-J.
tl:v--actions in the S ~.rc.rums oC -.Iuctrcri AL.1nity oC *-. ons c)-' :ivaLurit
and Iron." Zhur. Fiz. I~Iim., Vol. 17) 11,0. 1;,, 1~443

I ]II1111 ro 9 111PUllutt 11 U 0 11 te is
AL 13
All
f a

A
A
.
-
a
-ALJL,
'-
*vv1J
OsWillis iiso r

RI*Om-&ALW&=c:= of chromova kas. IL Va.
40VA100
P
R
S
S
$
r A
I R
.
.
.
f
.
.
.
Oww &&
d =
191. 410 1-1110IM41; Cf. C.A. 38. -The kote-trawr
t Mitilt of the %bissimckin food ol CrSO. is ot UX) A.
Clusits"iti H, cown. do not Change the 9sectrums which Is
W-ribecl tohytf.sted Cr** Ions
##
ctm-
Thi
lift I
i
t
t
c
s
.
s
n
a
t
erva
AfThilly OPM-titime of
t:db orhirm.dats. Theffirveilvedniniftmll-
ft
t
y
;
:~
Ultiraviolet light. Mrsawnd In a Inicit.
,
0 0
l
.
j

00 Imf rt. Is Iscrtawd citly I A times by a 404oM lovirrtse lit
W cown, Tlw &&lo. of Cr,180.)o in different avots.
00 oloc isof t the YkM of He. Le., Cr*** is not rc.
~
!r
0 I, ; this explains a girrister quantum yield
,,U,
vL, tr
04 than that 4111falned (for Ve. The quantuill vilh-ifnev 6
61-PAI 0-41 InvaminA artiowntritistilly vsjoh %.,xAt III
'lit, pholollyttrolywo, of clutsco'll. 1hu. It I.On .~f
11"I TALHICIP11110 In like PM-I~A but like fle,
must Devur IMMO the Mispitit ion-hydratitin Uy*,
ith
h
f
l
I
e
Dn II
t
fwnsat
a transition state fmiti hkh It J.
lifirfaird 111frfily. latirt W A1106)
j
1'4 AS* W L aOtt A LLVOGICAL _L'T -&IU&t CLAUJINCOSOM
46
ts U it 0 1 4
0
V
4 to
- A.- -7
JL-L-&
10 41. caff-tt-
i
zoo
got
ago
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004)
00
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as
III. CC It A
Psoctills AND pacpWill ~kolo
Pb*Whemic&l reactions in electrolyte solutions It
Ya, 1),iin. I qwkho Ehim. 13, 'At .70.1~ IWA.
.101 'AD lit~r~t%arv 10,1~11- up 1'. Volt
UTALk KAL LITIIIATW2 CtASSIFICATION
meow -.--7- -77----~
b U S AV so as -0 at 'a i il i X- i 11
K
00*00*00*04,000orsooo000*6400000*000040
0
0 0 0 0 * 0 0 0 0 0 0 0 0 0 0 6
0 0 0 0 0 0
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00
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Aft A a pw 0 N a I it IN 9 a a 3 1 9
1 &4 d"
0 9 ro~ 0 0 0 0 0 0 0 0 0 0 6 0 0 0 0 a

Naar data aa Weetranie transport bands In ele4ttralyte
molutiou. W Yc PAIn Ak4J. Nakk S SA M , i
Scr. Fts. 12, 313 As( 11.4-10 Al,--ci-oon ~ur%" vi, 14krit
on wilns~ of Fr(ClO,)g arol CuiCI0.1, in 110),
Ste(J", Ruoff and in loins collfg. va,641.1c: atilt& -of
IICIC)4. 11sucfiacitlifie,14.wIlls,"frozen in a vacinno 21111
illuntinatled with ultraviolet lixibltr a m.11 dewrl.,jan,tit of
0 can be observed as well as torinAtinit 4 Fe * ' wnt4 from
ultraviolet absorption by Fe * ' * kms, it i. shown that t1w
Photochent. effect takes IjIAcc tin hydrated ions only
The long-wave thr"huld (A the absorption 1-nd L, lhilte.]
toward lorager wave Icngths in AIc. wAns. fit incrt,l,sing tool.
wt. I'hckt(KhCnl. tCSt3 in AIV. %110W 2ji incremw in 11 anti
Aldehydes in the uAvent uptin illumination. N.P. -4

6AY
L V Pizatshavskil Mom of Pledion chernistiv
It % " I #.,Ito I .~. 94, A h, ,, 17. ". IN I ., 1 .11% - I. 1 4
k . I

rATT,1j 11. YJA.
A.
MR/Chemistry - Tung~,ak Reduction of Jun 48
Chemirstry - Molybdates, Reduction of
*New Data on the Stziwture of Molirbdenm and Tung-
sten Blue Derl7atiires,* Z. M. 7&ysberg, B. Ta.
1xin, Mast of Phys Chem immi L. V. Piaarzh8T8tiy,
Acad Sol Tzrainian SSR, 5 3/4 PP
wv=w obehoh xhie vo:L xvn7i(n=)., ito 6
Napares and Investigates absorpti-m spectra of
molybUte an)L turgatate reduction products In
preaence of p~Lospharous, sillcon, boron and
arsenic salts. Compounds hu-Te various spectra
aneL can be regiLraled as dariTatives of molybdenum
&n& turigaten blue. Submitted 28 Jdn 1947.
IM 9A9T9

01;
51 i ; i ; ;.
; g. '1W 'IF. ;4 i
l
601 op IF W. ow.- re
It 2 1 .J 1 1 JL4 It LC ff IN I &
00 o, It, t 00

-00

,00
1
i .00
Pbotoothemkoll oxidides-tteductiloo reacdons In site.

0 of WOO porchlocator
N'
8
ml
l
00 s,
n, Ani
,
Zkxr. Fil. Kho" Y;
(Y' FV Th~m ) 22'
(BA).&F
12KOU=r
0
000 At Fe(ClOd
+ 0131 IICIO
A -00
-
~
.
q.
o
,
hAS An MI
LjUft=tb 4 MAII. near 240 ma; the Ah.
Ago
=
-"t:m te small Inten-Lity i at tYl m..
::00
Iii1le 93% Ht0H Is eadiffUtuted for w ter. the max. re-
fw
ill
b
h
l C* o
0o most tala
ected
u, t
e limx
ave port of the
InAins a
41tertrutio 14 Whitt! toward fed to Mit the i 1. rr3rhM at ;:0*
4 X) Mo. Mme. of MO M Pr(Clodo + 0.15 J/ HC10.

,
00
00 .,.,1 .1 01xv M 4(m), T 0.V9 If 1100, in 98,70 P.
toll
go had this ist 48DodmidSWitim. mp.. thepovitioncif the 000
max. rormaining - 71w mix. coo. lxx2ds to
;Z
" Ago
lod
whIle the Ions-wave pun
obwirption by 9~W
of the band is due to prodws of Wvoly%ls at loydrooltrits.
In this part. the lAmbelt-fleter law is not onilid. them
d (
id
l
l
i
h
h
ts are use
or e
at
Mu
uc
e Mec
ng t
anism 0(the photo-
chew, reductim of Pe in The present* of Etoll.
469
J. Bikirrmin not

&to its .(r.L("fK4t L'troars"Re CL.SSWICAF.00 CZ-
lot
,

b It
or - OF a 4
An L 4 a 14
to I? j to 6( 111111% plan llz~La
3
0 0 0 :10 0 too go 0 0 o 0 o o * 0 0 1o o 0,00 q 0 0 * 0 0 0 o 6660 4 o 0 0

YA.
UM/Chemistry, Spectra, Absorption Ju 1 48
Chenistry Iron, Arric
"Nature of the Ultraviolet Bands Adsorbing Tri-
valent Iron Ions," B. Ya. Dain., A. A. Kaohan, Irst
Phys Chem Imeal L. V. Pisarzherskly, Acad Sol USSR.,
31 PP
*Dok AkNauk SM" Vol LXI, No 3
Reports experiments Results confirm view that
speotrum band of Fe3+ ions is an 'eleotron trans-
fer speotrum." Submitted 24 Apr 48.
PA
11/49T12

AYSBERG, Z.N.; DAIN, B.Ya.
Chemical nature of the derivatives of molybdenum and tungsten blues.
Dop.AN URSR no-5:33-38 149. (KLRA 9:9)
1.Institut finichnoi khtmit Imeni L.V.Piea--zhevalkogo AN URSR Viddil
fotoldiimii.Predstaviv diyaniy chlen AN URSR O.I.Brodslkiy.
(Pigments)

ita 49
Ions
Catalysic
0 "Baterogeneous Phenomena in the Photoreduction Proc-
1-4 ass of Ions in a Tatravalent Series," B. Is. DaAA,
A. A.,Kachan, Inst of Physicoch-m imeni L. Vo~
Ploarihevskiy, Acal Sci UffiR, 3 ~14 pp
UN
"Dok kk Nauk SSM" Vol LMI. No I
XxTerIT-ments citel nnh~c;w tlat in the photoreduction
reaction of a per,lblorate in a tetraNelent seriesp
Influenca of the valls of the container on the basic
proceis is very great. and is of a clearly catalyt1r,
in -54/42Z=
USM/Paysica (Contd) Jul 49
nature. Aftereffect is not completely explained,
but il connected with the obserwed catalytic effect.
BMW ted by Acad A. N. Terenin 3 May 49.
54/49T102

dAwvv
W-J. TONCERNINU THE NATURE OF THY. REACTION OF .
CHI,OROPIIYLL WITH INORGANIC IONS. M. S. Ashkinazi.
All T.S.GlIkman, and B. IYaJDAM(Dahj. fTranslate4by]
L. V. PIsjrzhe,,, ill jPis4rjrvsby) from Miklady AkAd. Njuk
13, 743.6(12501. 8p. 0UCRI.-Trann-90)
u6

SOURCE CODE:
AUTHOR: re -Is; ftLajovs ](u~ S.
ORG: Institute of Chemical Physics, AcaftMLqf_&jjna"WIn9titut khimichaskay
fiziki A)mdemii nauk SSSR
TITLE: Exchange effect in elastic scattering of p9larized identical nuclei
SOURCE: Zhurnal ekoperimentallnoy I teoreticheskoy fiziki. Pielma v redaktalyu.
Prilozheniye, v. 2. no. 6# 105p R66-269
TOPIC TAGS: elastic scatteringp proton polarization, Coulomb interaction
ABSTRACT: In view or the increasing importance of experiments on the polarization of
the products of direct nuclear reactions) for the purpose of explaining their con-*
crete mechanism or determining the spectroscopic characteristics or the nuclei.4 the
authors analyze theoretically the elastic scattering of Coulomb-interacting polarized
identical particles. It in shown that when a crepletely polarized bea1i.-ft.scattered
by a coinpletely polarized target interference takes place only when the polarizations
of the beam and the target coincide. This is the quantum analog of a fact well known
In opticop that there is no interference between two light rays -which are polarized
in mutuaDy perpendicular planers. In the general case it follows from the analysis
that the intensity of the oscillations of the exchange term depends essentially on
the degree of polarization of the bean and of the target,, an illustrated In Fig. 1
for the case of particles with spin I n 1e This can serve as a basis for a new meth-
od of detecting polarization of slow charged particles. Since the procedure for ob-

taining polarized targets is being contitriously per-
fected and there are now alre&V tventy different
methods for accomplIshing this, the proposed method
can find application in a lugs group of experimentsp
including measurement of polarization of slow protons
and of nuclei of light and medium elementsp vhich is
of particular importance in connection with the ever
increasing use of multiply-charged. ions in nuclear
pbysies. Orig, aft, bast 1 figure and It forwalas.
SC
MM JM23: 2,qJU165/ 4X= Wt 002/
18 Aa--Wjd-
40.
40.
v -
at.
41
4#
41 #t6
49
I a A A a a
Fig. 1. Oscillation intens
ty yse target polarization
for particles with spin I
02H MW: 001

OWCS1 natuio-and sictietwo 0, 44'~iim of..,

#J. A
an
d
T
M
I
f
a
'
MO
7: 4, W d;! J yg i i k - S. -5, A ~ 0
. Acd.
. , NEY
Xv.
.16" 19 -4H[ly 707of a tued
1 iala-Sized Hille
N Spec

y idlWamolybdic; ifte 110twigstic"
=
0, nod the
--jillcotungstiti,w phosphomolylx
ldIA/M
t
i
i
d
h
ih
a
d
L
1
W
t)
o
u
uct$ t
ere
e.
*
u
%d
et
on pro
gVO
,
w4M 016tte
The: various; blttci sli= oalva, Slight
,percen I Wt wid after
tage of-thti c6nolumnul e,94, ore
s - 11 1
''Contalived
-"reduction
NU:W2 .6d
50
50
ic
. -
ip..
-
and. 1.56 ~ V 2.33 j
W4 2.40
Nay film(lar-to Otid -
.
'
.
ral-k ' M
Asi I Me spect curves a
Ittlit ubwMtloA% -almost alwayx
obeyUnzbert-'Gftr's la*), I
" t, Is tioncluded Ouit tita'arI&W
.
~
lm~dz. and the'bWes proditced therefrom huvt very Similar!
-
"
blues
'structurm. Theiviore. It. Is pmposcd-, to vall
the

"ket"Poljr a"-pf Ow reduced-verl
N, It-$
-

WaR/Chemistry - ChlaropbyU 21 Sep 51
"Photochemical Properties of the Xron-Chlorophyll
Complex," U. S. AsbIrinazi, B. Ya. Dain., Inst c,-F
Phys Chem imeni Pisarzhevskiy, Acad Sci USSR
"Dok Ak Nauk SSSRI' Vol L=, No 3, Pp 385-388
The iron-eblorophyll complex, prepd by chem means
inboth the oxidized and the reduced form, gives
absorption curves vith intensity peaks at 610
m=icrons for the oxidized and 645 millimicrons
for the reduced form. Upon exposure of the oxi-
dized forz to a 1,000 watt lamp, intensity peaks
appeared at 64,0 - 650 millicrow after 4 bro of
I PI ("I']
UM/Chanistry - Chlgghyll 21 Sep 51
(C td)
exposure and at 610 vaillimicrons after 10 bra Of
expoevre, Visible light is capable of redmir4g
the oxidized iron-chlorophyll Complex &B NhOvn W
other absorption = curves. The same effect Is
prodiw9d, -ay light from a mercury qpftz I&M, OUIY
=oh faster. Temp between 10 - 2r has no effect
on photo reduction.
-210231-
Pi

Photaichomistry at chlorophyll at liquid air temperatwe
A A KAchan and 11, Va. ll.iin it. V. Pi,itylle-lid
Phys -Cheto. Inst., Acatf.".1tri. Ilki, SIA k.. Kiei,) P,,klaJ v
Altild S40A S S.S.R, 190. ), - Oll o.4ing floll'
rmlin it) liquill-ally tellill . lilt abirptimi "~(I. ill th, till
abilarption band of chlor-1,hyll Imi V Ill ill %oln. ill F1011
(0-046400111 9A) Inertlawl; prolringed irridwifon with
vi%it)lr or with atair-ultravi,ilet liKht (high-1wrAlure fix I mil-I
prMijivs on further chaolge,l if A-wi'liOn .II
Ill a 1:3 mill. fit 1`1011 with F1,0 Ow
same inerease of Abomption In the fell oil to itipli,i
Artemp. In this mix ed sol vent, irrjtjiat ion %it 13 l1wr uIll.1 -
vic)Irl ill liquid-air it-iort. produt " a dmrrt_ ,( the 3",tf.
cion ill the red. ithich twrstitstm ~t.imlmjz ill th-Lak .( th.
fiquid-air trinji.. bill t"PIvAl"i Oil "0111111K 1411 to U-111
tclilp. rhe chAnse taking p4tv lilt ulivi%vitrt utmli4timt it
liquiol-Air temp. is attributed In dismien. isitti .1 j~. chitir-
Phyll i,m will an electron. It ime aisum". uith Tcrenin.
that list pos. ion splits off a prnfon. the %lability n( t1w
,iystent at liquid-air trinp. in the mixed I-.-tOI I + Ft 4 1
-ilvrol oppeirs to be dur to A fit.ou"i of the I-twoti I,v
V40, ill I Ill- hrin of the ocrili'l... #,,,I I:t,l ll I *. Flu, pf'.1
dt" Rill tALC PIAM In "ll. it, CMil A.9tv I s,,j,!-jjgjl,
(juAnIA are ot.tifficirnt to jw,vhi~ i-,%, .! -1. _1 gi,,e
Title -nly W UnItAble elCittil tAtC, "IthIl 111,1V 1111CMCt
with the "vent. N. Tlj,,,i

1. ASiMAZI9 M. S.; GLIKKAN, 0. S.; DAYN, B. YA..
2. USSR (600)
4. Iron Salts
7. Nature of the interaction of chlorophvll with iron salts, Ukr. khim.
shur., 17, no. 1. 1952.
9. Monthl List of Russian Accessions, Library of Congress, April - 1953, Uncl.

DA-1-14, 13. )a.
Chemical Abuts
Vol. 48 No, 9
May 10j 1954
Biologi(IAI CherAstry
Intqrgcfion of chlorophyll with Iron salts. 'At. S. Aqli-
kinaziYT. S. Glikman. widl). Ya. Dain. Ukraie. Khim.
Zhur. 18, 49-54(10.52): cf. C.A7.4"M-M.-Rcittration of
the gre. viows staterneut that the rhanges in allAwpliki'll SVWC.-
t'. chlorophyll on the arldn. of Fe "' or Ile* "are due to
complex formation rather than ph-!-
Daw-h
zj

DAM. B.Ya.
Research of T.D.Grotthus in photochemistry and the theory of colors.
Ukr.khim.zhur. 20 no.1:93-99 154. (MLRA 7:3)
1. Institut fizicheskoy khimil im. L.V.Pisarzhevskogo Akademii nauk
USSR. (Grotthus. Theodor D., 1785-1822)

USSR/ Chemistry Physical chemistry
Card 1/1 Pub. 116 - 8/25
Id
Authors a Kostryukova, E. P*j and Daunt B. Ya.
Title I Photochemical reduction of thionine
~Periodieal I Mr. khimo zhur. 21/1s 48-53s 1955
Abstract The photochemical reduction of a thiazine type dye (thionine).possessing
high light sensitivity in the. visible zone of the spectrum was
investigated during its reaction with ethyl alcohol, thiourea and.glucose..
It was found that the photochemical reduetion reaction of the dye is
unavoidably connected with the phototransfer of the hydrogen from the
reducing agent to the molecule of the dye. The affect of-temperature
on the reduction process is explained. Seven references 4 USSR
(md 3 USA (19254951). Tables; graphs; drawing.
Institution: Acad. of Sc., Ukr. SSR, The L.V.Pisarzhevskiy Institute of Phys.
Chemistry
Submitted February 'CO. 1954

6.
USSR / Physical Chemistry. Molecules, Chemical Bond, ?, - 4
Abs Jour : Ref Zhur - Khimiya, Ito 8, 1957, 25753
AuthDr : M.S. Ashkinazi, I.P. Gerasimova, B.Ya. Dain.
Inst : Academy of Sciences of USSR
Title : Influence of Water on Absorption Spectru;-, and 11hotosensiti-
vity of Iron Pheophorbide.
Orir, Pub Dokl. AN SSSR, 1956, 108, No 4, 655-658
Abstract The absorption spectra of oxidized pheophorbide a (I) in al-
cohol, acetone, acetonitrile, chloroform (II), ~.,enzene and
toluene in the range of 500 to 700 nya were photzgraphed. It
was shown in accordance with earlier found regularities
(RZhY,him, 1956, 25216) that the s jrctrum of carefully dehy-
drated I is characterized with the ma-dmum absorption in ran-
ge of 620 to 625 mu. After an addition of water (III), the
spectrum changes sharply, the maximum at 620 to 625 mu di-
sappears nearly completely and a band at 675 to 6~~O mu
pears simultaneously. The described effect is displayed in
Card 1/2 - 13 -

USSR / Physical Chomi,-;try, Molecules. ChorUcal Bond, P-4
Abs Jour : Ref Zhur - Khimiya, No 8, 1957, 26753
Abstract : various solvents to different degrees depending )n the misci-
bility of the solvent with III. The authors ascr.~`.ie the mlh-
sorption at 675 to 680 mu to associations consisti~ij oC TIl
and I molecules; in the authors' opinion, the ~brm, ation of as-
sociations of molecules of I connected with molecules of III
is also possible. It is shown that the reduction of I (ap-
pearance of absorption maximum at 650 mu; see above note) lm-
der the action of visible light takes place considerably ea-
sier in presen*6& of III, in which occasion the sr,~ctrun of
oxidized I always appears after the inlet of air. ~'he pho-
tosensitivity of I in presence of III proves, in the authors'
opinion, the specific influence of III not only on the spec-
tra, but also an the photo-chemical behavior of 1.
Card 2A 14 - so

AUTHORS: Butsko, S.S. and Dain, 9-Ya. lj()V/21-58-11-16/28
TITLE: Photochemical Reaction of a-Chlorophyll Oxidation by Ferric
Chloride (Fotokhimicheskaya reaktsiya okisleniya khloro-
filla a khlornym zhelezom)
PERIODICAL: Dopovidi Akademii nauk Ukrains1koi RSR, 1958, Nr 11,
pp 1221-1224 (USSR)
ABSTRACT: The irradiation with light of 400 to 570 m wavelength of
acetone solutions of the mixtures of a-chlorophyll with
FeC13, with an excess of the latter, leads to the formation
of a red-colored photoproduct. This product is stable under
vacuum conditions and preserves its characteristic spectrum
for a long time. However, its contact with the air results
in a sharp change of the spectrum. The spectrum of the final
product is characteristic for ferric porphyrins (the position
of peaks at 640; 580; 510 and 420 m ). The rate of photo-
reaction decreases with an increase in ferric salt concen-
tration. A dark after-effect of the light is observed in
the reaction. This indicates the formation in the course
of the photochemical reaction of stable products which act
as catalyzers during the subsequent process in darkness,
Card 1/2 The authors at;sume that the red photoproduct is a chlorophyll

ilov/21-58-11-16/28
Photochemical Reaction of a-Chlorophyll Oxidation by Ferric Chloride
semi-oxidized in the 7 8 position of the IV ring.
There are 2 graphs and references, 2 of rhich are Soviet
and 1 American.
ASSOCIATION: Institut fizicheskiy khimii imeni L.V. Pisarzhevskogo AN
UkrSSR (Institute of Physical Chemistry imeni L~V. Pisar-
zhevskiy of the AS UkrSSR)
PRESENTED. By Member of the AS UkrSSR, A.I. Brodskiy
SUBMITTED: June 13, 1958
Note: Russian title and Ruasian names of individuals and institu-
tions appearing in this article have been used in the trans-
literation.
Card 2/2

BUTSKO, S.S.-,--nAT
Spectrophotometric analysis of chlorophyll interactions with iron.
Zhur.ob.khim. 28 no.9:2603-261i IS '58. (MIRA 11:11)
1. Institut fizicheakoy khimil All USSR.
(Chlorophyll) (Iron)

50)
AUTHORS: Glikman, T. S., flodlinyayeva, 71. Ye., SOV/79-29-6-4/72
Dain, B. Ya.
TITLE: Spectrophotometric Investigation of Reversible and Irrev-
ersible Conversions of Sulfophthalocyanine of Iron (III) in
Aqueous Solution (Spektrofotometricheskoye issledovaniye
obratimykh i ncobratimykh provrashcheniy sullfoftalotaianina
zheleza (III) v vodnom rastvore)
PERIODICAL: Zhurnal obahchey khimii, 1959, Vol 29, Nr 6) PP 1785-1793
(USSR)
ABSTRACT: The phthalocyanines belong to the small number of dyes which
resemble, as to their structure, tha natural pigments of the
porphyrin class. In that connection many scientists tried to
use these compounds as model of these pigments (Ref 1) in
order to investigate more thoroughly the compounds of this
kind if they are not combined with proteins. In this regard
the ircnphthalocyanines were of special interest; they are
closely related with the hemina the part of which in the
biological redox processes is well-known. The sulfonated
derivatives of these dyes which are readily soluble in water
Card 1/3 show a number of interesting peculiarities which are based

Spectrophotometric Investigation of Re'versible and SOV/79-29-6-4/72
Irreversible Conversions of Sulfophthalocyanine of Iron (III) in Aqueous
Solution
on the fact, that they are capable of reversible and
irreversible reactions in the dark and especially in the
light. Since the solutions of the sulfonated derivatives of
the iron-phthalocyanine are intensely colored the spectro-
photometric method is most suitable for their investigation.
In this paper the rosults of tYdn spectrophotometric investi-
gation of aqueous solutions of these compounds, and of the
conversions taking place in them are described. It was
found that the aqueous solutions of the ferri-sulfo-phthalo-
cyanine (III) represent systems in the state of a hydrolytic
equilibrium. The hydroxide of the ferri-phthalocyanine (III)
which is formed on hydrolysis is unstable and decomposes
slowly and yields ferro-sulfophtbalocyanine (II) and the
free hydroxyl. Exposure to li,,Iht accelerates this process.
The formation of free radicals on standing of the solutions
of ferri-3ulfo-phthalocyanine (III) rhich had been outgassed
in the vacuum was confirmed by introduction of polymerization
chains. The spontaneous decomposition of the hydroxide is
Card 2/3 the cause of the behavior of the aqueous solutions

Spectrophotometric Investigation of Reversible and SOV/79-29-6-4/72
Irreversible Conversions of Sulfophthalocyanine of Iron (III) in Aqueous
Solution
of sulfophthalocyanine of the trivalent iron and the cause
of their slow decolorization in the air. There are 6 figures
and 12 references, 3 of which are Soviet.
ASSOCIATION: Institut fizicheskoy khimii Akademii nauk Ukrainskoy SSR
(Institute of Physical Chemistry of the Acadei.iy of
Sciences,Ukrainakaya SSR)
SUBMITTED: May 12, 1958
Card 3/3

DAM, B. 'Ia. (Prof.)(USSII)
"Photochemistry of Me-complexes of Chlorophyll."
report to be submitted for the Photosynthesis SYmPosium, 5th 11"U. Congress of
Blochemisti-j, Moscow, 10-16 Aug 196.1.

KRYUKOV, Aj.; *IN, B.Ya,
Photochemical reduction of ferric chloride in aromatic hydrocarbons.
Dok1.AN SSSR 138 no.1t153-135 Vq-Je 161. (KLRA 14:4)
1. Institut fizicheakay khimii im. L.V.Pisarzhevskogo AN USSR.
Predstavleno akademikom A.N.Tereninym.
(Iron chloride) (Photochtmistry)