SCIENTIFIC ABSTRACT YE.TS. CHUKOVSKAYA - N.A. CHUKSANOVA

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000509110014-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 12, 2000
• Sequence Number: 14
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

S/661/61/000/0006/012/081
Thermal telomerization D205/D302
29, 660, 784, (1957); J. L. Speier, J. A. Webster and G. H. Bar-
nes, J. Amer. Chem. Soc., 79, 974, (1957).
ASSOCIATION: In'stitut elementoorganicheskikh soyedineniy
Akademii
nauk SSSR, Moscow (Institute of Elemental Organic
Compounds, Academy of Sciences USSR, Moscow)

". I
FIWYDLINA,.R.Kh.; YEGOROVj;~Yu.P.; ; TSAO I (TS'ao I);
LUBUZH, Ye.D.
Rearrangement occurring in the process of the thermal telome4-
zation of ethylene with silicon hydrides. Izv. AN SSSR. Otd.
khim.nauk no.7;1256-1261 Jl 161. (MIRA 14:7)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.
(Ethylene) (Silicon hydrides) (Polymerization)

23499
'S/ 61/137/004/024/031
102
1407 B1 03YB208
AUTHORSt Freydlinag R.Kh., Corresponding Member AS USSRp
Chukovskayag Te*Ts.l Teao-Ij and Wesmeyanov# keNep
1c-a-&e-5T6-fa-K--
TITLEs Telomerization and polymerization of ethylene with silicon
hydrides in the presence of titanium-tetrachloride-
PERIODICALs Boklady Akademii.nauk SSSR# v. 137, no. 4, 1961, 885
888
TEXTe The authors studied the telomerization of ethylene vitht 1)
Bili-
oo-ohloroformp II) methyl diohloro-silane, and III) triethyl
silane in
the presence of TiCl4 wh ich oatalyzes (initiates) these
reactions accord-
ing to the formula CH,3SiO12H + nCE2- CER-40H 3SiCl 2(CH2CER)nHe
They used
a steel autoclave in which the reaction was carried out under
pressure and
by heating. Ethylene was found to be telomerized smoothly and
with a goo
degree of conversiov in oases I and IIo In case I, some telomer
homologsix
with the structure SiCl 3 Cn"2n+ll where n - 2, 4, 6, 8, were
isolated from
Card 115

2149
S102X61/137/004/024/cr3l
Telomerization and polymerization of ... B103 208
the mixture of telomerization products. The constants of these
substances
(Table 2) and of their methylation products (Table 3) are in good
agree-
ment with those previously obtained by the authors (Ref.2, BAN,
1139 1209
1957)o The normal structure of their alkyl groups was confirmed
by in-
frared spectra. Ad M A mixture of telomer homologs with a
structure
CH Sial C H was formed at 180 - 2000C and at a maximum pressure of
-3 '2 n 2n+1
280 atm: This reaction is complicated by the -formation of liquid
hydro-
carbons due to ethylene polymerization. Table 4 gives the
constants Of 0
some methyl-alkyl dichloroLsilanes with n - 2, 4, 6, 8. Ad III.
At 130 C,
ethylene is polymerized to polyethylene with no telomers being
formed.
This difference in the course of the reaction is said to be due
to a dif-
ferent reducing power of the individual silicon hydrides studied*
Tri-
ethyl silane, e.g., contains electron~-donor groups bound to
silicong and
is therefore a more powerful reducing agent than trichloro-silane
and me-
thyl-dichlaro-silane. This might be the reason why-these silicon
hydrides
with TiCl4yield products that are reduced to a different extent*
X-ray
structure analysis (performed at laboratoriya
rentgenostrukturnogo analiza
(Laboratory of X-Ray Structural Analysis) and laboratoriya fiziki
polimerov
aard 2/5

B/020161/137/004/024/031
i T el omeri zat ion and~polymerization of B1 03/B208.
r a of the Institut elementoorganichiskiW i.
(1aboratory of Polyme Phy ics)
e:
,,.soyedinehiy (Institute of-Blemental-organio Compounds))
discdosed~'that th
~po
lyethylene,obtained by the authors is identical with low-pressure
poly-
ethylene,and.the produot.'obtained by diazomethane decomposition
(x-ray
pictures of the two latter polymers were made available by V.A.
Sergeyev
Thermomechan int of 1350C for the authors'
'A ical analysis showed a melting po
'polyethylene, which also correbponds.to low-pressure'polyethylene Its
'molecular weight was 26670, deteimined from the viscosity in
tetrahydro-
J
nephthalene at 13500 This 'indicates.that the authors' polyethylene is
practically identical with the two polyethylenes mentioned (analogous
data,
in Ref- 49 S. Nitashep Xhimiya i tekhnologiya polimerov, 1960, 54).-
P
~7. There are 2 figures, 4'tables and 6 referencest 5Soviet-blog and
1,non-
So,viet-bloo.
SnMITTEDt December 8' .1960
J"
Card 3/5

8/020
61/1

'

Telomerization and:.pol
Ymerizati

n-,ofr...

37/004/02
4/031
J
B103/11208-

3T. Man., OC

20
D

~CoeAtWt-

HANA.'

ART.0
AA"Itu

HaAA.

A JIHT.'~
AHIMIC

HARA-

A -7"-c
auKH

u 0A.

Table 2

,
C~H,Sl
07

0
7-J00
t
OAS
-

I 2M

34 08

33

I-I sl
C,
C

148

14

0-151

1:

401

1,4352

C1583

J677

42:92

42:7

t

H:,s
I~f-
c:
87 (30 i1m)

5
7-8v
1.
406
1.4440

0092,

t094
I

52 63

1
. 52,
2

c ""SIC1.

I
1w (10 wo

Wo"Mm))
ifiloo

W400

1,0746

110744

111111

11vt Ir

r

T*Oavix4 3

J-

Kiln., Ic

n2Q
D

JWR

Table 3

COAX"Hemlic

MT.
Aasts"

AAA.

AARNble

NASA. Uume

AAA

BUNICA.

CH.91(CH.

62

62

1
m
1,38211

0 Gm
'

3.6649
3
7
3
4
8

34.53

4H.SI(EN:

to

HS

I:
t,4WO
1

7167
0

0.7181
1
4
4
4
.
j

44,12

(upm 251)

;j

Z

~

2,

H.).
3(

1-163

1

63

.4t62

4154

7118
0

0.7422
~
63
.57

53.41

c),s)s

82
4kiv)

82.3
mm)
1,4=
1

0

Card 4/5-

B

x
OA.

17. oc

20

n

D

m

AIR

Coepumple

%G

IIIIIA I

A&UHMO

ASHUNG;
"alA

WUM

'

U

C
I
ICI Ii.
H
-

ill
l

100.5
too
1 4190
42A0
,.
i0044
LOW
33.%
33,87
,
M
!,
a
49
1
1147-1148
1
1 MO
I
1
1 4312
I
1
w
I

.4,1
4320

SIC Cil.
'
E

5

0 (31 um)

32 mm)
III
1
.
1 4M

. I 4M

:

,
t

5259

H
,,sIpsCHs

fl
90 ym)
(6-
94
t Mu
)
I A
: -k5o
1 4440
-
0,1~qu
O.-kst

6t A8

AMMINA, R.Kh,; CHUKOVSKAYA, Ye,TS.
Uaing oxidation-reduction systemin for the-initiation
of the reaction
of 1-octene with carbon tetrachloride. Isv, Aii
o,,aa.uTA.khim.nauk
no.lOtl783-1788 0 162. 1 (MIRA 15:10)
1. Institut elementoorganiolieskikh eoyedineniy AN SSSR.
(Octene) (Carbon tetrachloride) (Oxidation-.reduction
reaction)

L 1?o67-63 E.jp(j)/2: 1F (c )/F.-,iP(q)/&,,T (M)/ i3DS
3/062/63/0W/004/018/022
41FFT(;1ASD Fc-4/Pr-4/Pad, P1-VMV/JD/H*,,/'~,,Y
AUTHOR: Yes Ts and Freydlina, R. Kh.-
TITLE: Tddition:of*silicon..bLdrides-to unsaturated compounds in.the.
presence-of, nickel 'carbonyl
PERIODICAL: Akademiya~:nauk SSSR, :-..Iz-vest:Lya. Otdeleniye
khimicheskikh nauk.,
no.. 4, 1963,. 761-!-763
TEXT: Nickel tetracarbonyl catalyzes the cyanoethylation of
methy]4LCh-10-1-
rosilaneland triethylailane, as well:.as-.the.addition of
triethylsilane to acro-l"
16bn--al 110-1200 with a.-yield of 60-70%. The addition leads to the
formation
of products containing .the silyl .group in the alpha-position to the
functional
eroup of the unsaturated compound. A definite congruence is noted
between the
capability of the unsaturated compound to form pi-complex with nickel
tetracar-
bonyl and its capability to add silicon hydrides in the presence of
nickel te-
tracarbonyl, The most important English-language reference reads as
follows:
G. K. Schrauzer,,-J. Amer-Chem I..Sac. 81, 531 (1959); Ber., 94, 642
(1961).
card 1/2

FRRYDLINA, R.Kh4; CLMKOV~KAYAp Ye.TS.
Telomerization of allyl compounds b;r-silicon hydrides
in the
presence of diayelohexylperoxydicarbonate. Dok1. AN
SSSR 150
no.5.-1055-1058 Je 163. . (KIRA 16:8)
1. Chlen-korrespondent AN SSSR (for Freydlina).
(Allyl compounds) (Polymerization) (Silane)

2%8?5-65 wt(m)/RPF(c)/7/WP(j) Pc Ji AP-r -It T? v
AN SSSR. Dnk Iidv, v, I'Q,
p 1, me r zat i on, teli~~mey,
Th e n v

~~N N A P 50 0 99 5
n6 u C e d Iii the present-2 o f r ;t r n v
kcajoce the dame caiomara aa when LaLLiated by
. - 'j
ber, E071 per;xfde. The authors assume that the reaction (1) conilats
Of'
folloving steps:
"I, - Fe
P r c on 9 t an t 9 C K

NR: APS001995
q m ii r. I nn 1 11 1 a r I p i
11 a -I C.
't ~ a ~ -3
a a e
Fe" M- Fe- ICI) CC I; n
b CC; I i OC! C H IC H', a I r. r fr.i i

- -Z ~7
. lw 1.) - A~ ;, 1, , . 1 1, ") q ~
1~ c ~ r -- ~ 1 1 A -, 1-~ , ,
i -
. . " -1 1 .

FREYDLINA, Ya.Kh.; CIIUKOVSKAYAj Ye.-TS.-I CHIM011,
Yu.P.
Effect of ethylene oyide or amines on the chain
transfer
with a modifier in the telomerization of ethylene by
car-
bon tetrachloride. Dokl. AN SSSR 162 no.2:359-361 It,
165.
(141RA 19- 5)
1. Inatitut, element6organicheskikb soyedineniy AN
SSSR.
2. Chlen-korrespondent AN SSSR (for Freydlina).

Fl?"N NP: LP'19238
7;: Frf~ydlina, R. 'Ch.; Ye. 7s.
'cr
P__r at me
I.,' rs 'F Mr
z -r., v
ABSTF~ACT - An Author Certificnite'--has been issued for a
preeparative method for
-cy-I 1,
-Y.
none
Ell
'r
000 OTKER: OOG
A 4018
Card 1

CHUKIIVSKAYA, 'fe.TS.; KAITISHOVA, A.A.; FREYDLINA, R.Kh.
--I..,,-'-- :~~ - ~
Reactions of carbon tetrachloride with unsaturated
compounds
in the presence of dicyclohexyl peroxydicarbonate or
oxidation-
reduction systems. Izv. AN SSSR. Ser. khim. no.3:461-465
165.
(MIRA 18%5)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.

CHUKOVSKAYA, Ye.TS.,- KAWSHOVA, A.A.; FREYDLINA,
R.Kh.
Reaction of chlorofo#m with 1-heptene initiated by
iron penta-
carbonyl in conjunction with amines. Dokl. AN SSSR
164 no.3:
602-605 S 165. (MIRA l8t9)
1. Institut elementoorganicheskikh soyedineniy AN
SSSR.
2. Chlen-korrespondent AN SSSR (for Freydlina).

C rl", F 1. ",7l'-',K-'.Y.I,
I ',vdrl dle trensfer 1 r the roan t.1 o' v- f, r.
~L ~ (-, h Ch-MeF vlth
v-ltiylrLlkvl and oUer others in tht~ prosf~rce
of"irc- r--,irita-
ca.--bcnyl. 4--.Iv.Afl SISSH. Ser.!:him. 166.
1. T-n-,3tl Wt.
~hy 21, 3.965.

L 36988-66 LVP(J)/LWT(m) M
ACF-MR=C66b~~Iff- S
AUTHOR: Freydlina, R. Kh. ; Huzlmina, IN. A.; Chukovskaya, Ye. Ts.
ORG: Institute of Heteroorganic Compounds, Academy of Sciences,SSSR
(Institut
elementoorganicheskikh soyedineniy Akademii nauk SSSR)
TITLE: Hydride transfer in reactions of silanealwith vinyl-alkyl
and simple ethers
in the presence of iron pentacarbonyl
SOURGE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 1, 1966,
176-179
TOPIC TAGS: chemical reaction, silane, vinyl compound, organosilicon
compound, carbonyl iron I 1?7ee1j.9A.V.:;'*YU
ABSTRACT: When silanee react with nucleophilic unsaturated
compounds (olefins.
vinyl-alkyl ethersAin the presence of small quantities of iron
pentacarbonyl, satu-
rated and unsaturated organosilicon compounds are formed. The
reaction does not
occur under the same conditions with electrophilic unsaturated
compounds
(acrylonitrile). The purpose of this work was to determine whether
this trans-
formation has a homolytic or heterolytic mechanism. Data are given
which permit
the assumption that there is a heterolytic chain mechanism engaging
hydride
transfer. The experiments were carried out in sealed &lass ampules
in an argon
atmosphere. An analysis of the reaction mixture was made by
thegas-liquid
UDC: 546.287+547.27+541.124+539.175

L 3b9bd-bb
ACC NRz AP6008512
0
chromatographyl method. This method revealed that in the
presence of iron penta-
carbonyl, the sirfiple ethers are split off by triethylsilane
with the formation of -
triethylalkoxysilane and hydrocarbon. Orig. art. has: I table.
SUBCODE: 07/SUBMDATE: ZIMay65/ORIGREF: 006/UTHREF: 004
2/2

CHUKREYZV, A. (Petropavlovsk-Kamhati3kiy)
He is from Kamchatka. Poah.delo 9 no.8:19 163. (MM 160)
(Kamchatka~Firemnj
4

C14UYRMV A. - G. -
L-mbering-Accounting
Records of individual savings in the process of production. Les.
prom. 12 no. 6, 1952.
9. M thly List of Ru August, 1952 Unclassified.
on ssian A-cce$31ons, Library of Congress, PSI.

CHUKREYEVP F.Ye.
Digit-printing device for ih Al-100 analyzer. Prib. i
tekh.
eksp. 8 no-5917-M S-0 163. (MIRA 16:12)
1. Institut ato=oy energii AN SSSR,

-------------------------------
Y f .V
Category : USS~/Nuclear Physics - Structure and Properties of
Nuclei C-4
Abs Jour :Ref Zhur - Fizika., No 2. 1957 No 3191
Author :Estulin, I.V., Popov.. V.S., Chukrejev, F-Ye.
Inst :Moscow State University'
Title :Folariz4tion - Direction Correlation of Successive Gamma
Quanta
From COOO and Na24.
Orig Fab :Zh. eksperim. i teor. fiziki, 1956, 30, No 6, 1052-1057
Abstract :Description of apparatus for measuring the
polarization-direction
correlaticn of gamma'quanta emitted in cascade. This apparatus,
the
polarization sensitivity of which was first determined
e3periinent4ly,
was used to perform measuremefits' on gamma quanta from CooU and
WA24.
The even parity of the first two excited states of N16o and Mg24
was
proven.
Card 1/1

HALDIN, S.A.; GAVRIWVSKIT, V.V.;
CHUKRZTEV. F.Te,.
Scintillations in high-pressure helium i,nduced br alpha
particles.
Atom.energ- 3 no-10:331-334 0 '57. (MIRA 10210)
(Scintillation counters)

t! L) le, 1< E E F
I V
AUTHCR: Baldin, S.A., Gavrilovski~,, V.V.Xbukreyev~ Me. 89-10-13/36
TITLE: W, -Particles Induced
Scintillati-o-ni7-in-N-i-gH--]Fr-e-ssure Helium
(Staintillyatift, v gelii pri vy-sakikh davleniyakh pod dejstvkem
cr -obastits)
PMRIODICAL: Atoma*a Energi;Vaj 1957, Vol 3, Wr Ii, PP 331-334 (USSR)
ABSTRACT: The scintillations were investigated because the attempt
was macle
to find'& sufficiently effective method of establishing the polar-
ization degree of a neutron beam of 2 - 20 MeV. This method is
based upon the registration of the coincidences between the
scattered neutrons-and the recoil nuclei in the scintillation
chwaber filled with gas which is filled with pure helium of some
10 at pressure. The dependence of the counting velocity upon
pressure of the various gas mixtures (pure He. He + Xe, He + Ar,
He + 09, He + N2) was measured and the corresponding curves are
shown. There are 7 figures.
SUBMITTM: February 5, 1957
AVAIMLE: Library of Congress
Cara i/1

KARADZHA'YEV, K.V.[translatqr]; MANIKO,
V.L[translator]; GHUKREYEV,
-ft,~ ~olator]; SMOLYAN, G.L., red.; VLASOVA,
N.A.,
tekhn. red.
(Semigmiketor radiation counters]
Poluprovodnikovye schet-
chikCiziluchenji; sbornik statei. Moskva,
Gosmatomizdat,
1%2. .. 311 P. (MIRA 16:5)
(Nuclear counters)

, V. V.; MANKOI V. I.; CHUKREYEV,_F. Ye.
"Broperties of the"Fl-9-nucleus levels excited in the
reaction 018 (p) )N15.11
report submitted for Intl Conf on Low & Medium Energies
Nuclear Physics,
P'Wris, 2-8 Jul 64.
Kurchatov Inst, Moscow.

L 13?hB-65 EWTI (m _na_.~ Pt /Anf --Is.-
7 Z: N4
AP4947883
6 ~_U RE Zhurnal eksperim-ental 'noy i teoret i -1-ecik
I I ~3 I 19 8
p-roton alpha react ion., arq,._, -_i-
-7
This :.s a con t i n ua
tLnj_Tk- v 44, 870, 1963),
1/3

8 -6 5
DN N.R AP4047883
Y was
7-

ON: None
OlUpr64 EUCLe 00
SUB CODE: NP NR REF SOV: 002 OTHER: 014
7oro

ACC NRs AR6017394 SOURCE CODE: uWO058165100010121AO321AO32
AUTHOR: Mrnaukhov., N. D.;_Phu _v Jo
TITLE: Transistor attachment for the introduction of a two-group
oper.&UM mode In
the Al-100 amlyzer
SOURCE: Refo sho Fizikap Abs. 'IM21
REF SOURCE: Tr. 6-y Nauchno-tekhn, konfer*ntaii po yadern.
radioelektron. T. 2. M.P
Atomizdat, 105j.: 30~.
TOPIC TAGS: pulse height anaXyzer,, transistorized circuit,, pulse
counting, multi-
channel analyzer/ AI-100 pulse height anOyser
AMTRACT: A transistor attatbment for the Al-100 analyzer is
described; it permits
a two-group registration of pulses. In the development of the
elements and of the
circuit of the attachment, special attention was paid to the
following questions:
a) possibility of operation of the analyzer in the 100-channel
variant and the small-
est changes in its circuitry;'b) linear registration of pulses
from the first de-
tector from the lst to the 49th channels, and linear registration
from the second de-
tector from the 51st to the 99th channel; c) pulses of the first
group must not be
registered in the second group and vice-versa. The Complete
schematic diagram of the
attachment is presented, and the operation of the analyzer with
the attachment in the
two-group mode"" is;considered in detail. Structural1y the
attachment is in the form
of a separate block, which is connected by means of a plug
disconnect to the input
unit of the analyzer. L. S. [Translation of abstract)
SUB CODE: 20, 09

~,379-166 - FNT-
A~R601779'0 SOURCE CODE: UR/0058/66/ooo/ool/Ao44/Ao44
AUTHORS: Karnaukhov, N. D.; 2�feyev F. Ye, C7-1
TITLE: ansistorized number printer for the Al-100 analyzer 40
SOURCE: Ref. zh. Fizikai Abs. IA396 ( ~ I 1~ 0
REF SOURCE: Tr. 6-y Nauchno-tekhn. donferentaii-32o Y-adern.
radioelektronx T. 2. M.,
Atomizdat, 1965, 120-124
spectrum
TOPIC TAGS: spectrun analyzer, computer output, data
readout/AI-100,,analyzer
ABSTRACT: The proposed number printer is divided into three
parts: the code block,
the commutation unit, and the control circuit. The process of
writing out the
readings from one decade or group of four flipflops, with a
scale factor 16, is
considered. The commutation unit is intended to produce the
required access sequence
of the analyzer flipflops. The printer de7relops a signal
denoting the-ena-of the
channel for the control circuit. The latter performs the
function of the operator
in the case of manual writing down of the spectrum. V. L.
(Translation of abstract]
SUB CODE: 20, 09

Usm/ingineering:-, Architecture

Card

1/1 Pub 106
5/9-

~.,Autliors
Chi reev G
Nt Engineer
'Title
t -Interior: architectural works of -the new Moscow
State Universitt:
Periodical-
om; a~:_
pr
-Abstract:
re1gar~ Inew MoscowI StIata UhiIv.ersit
tructural data
g the interior of th

Illustrations; darwloge'.
diagrams.
Institution

Subinitted

1. ~CHUKREYEV, N.G.
2. USSR (600)
4. Decoration and Ornament, Agehitectural
7. Methods employed in the decorative work on the construction
of the Yoscow State
University, Mekh.trud.rab- 7 no. 4:, 1953.
9. Monthl List of Russian Accessions, Library of Congress,
APRIL 1953, Unal.

C~) Ij r/
CHUKRBYCV, Nikolay Grigorlyevich
lf~rilltkhe use of plastic materials in the manufacturing
of large panels]
?ri'menenie formoplasta v proizvodetve krupnykh panelei.
Moskva,
Gos.izd-vo lit-ry po stroit. i arkhit., 1955, 23 P. (MLU
ll'-l)
(Building materials) (Wall board)

CHERWAY, Nikolay Grigorlyevich. Insh.; TIMIN, L.Te.,
inph., nauchnyy
SCMSUA, L.K., tekhh.red.;
I My YeL-,,. tekhu,red.
kUsing powdered-fuel oinders in large-panel
constraction) Ispoll- '
sovanie'sol pylevidnogo topliva dlia drapnoblochnogo
stroitel.'stva.
Xoskva, Goe.izd-vo lit-ry po stroit., arkhit. I
stroit.materialam,
1959. 79 P. (KIRA 12:5)
(Cinder blocks)

~ !~ 'I , g ~
- ;~, -; W
: w k u
~t': 10 -~IMIJ,1'25!V~r-- - , V .
~-- --, -

,671310
/A ;1 j 0 0
67627
sov/8i-59-14-50262
Translation from: Referativnyy zhurnal, Khimiya, 1959, Nr 14, P
322 (USSR)
AUTHORS: Smirnov, M.V., ~ey N.Ya., Yushina, L.D.
TITLE- The Anode Dissolution and Self-Dissolution (Corrosion) of
1~~elliu~m
and Thorium4m Molten-Chlorides of Alkali Metals
PERIODICAL: Tr. in-ta khimii Urallskiy fil. AS USSR 1958, Nr 2,
Pp 171 - 176
ABSTRACT: The behavior of Be and Th in smelts has been studied.
The anode dis-
solution of metals is accompanied by a high concentration
polarization.
Be passes into the smelt mainly in the form Be+ and partially in
the
form Be+ [sic!]. Th is dissolved mainly in the form of the subion
Th+,
which intensifies the destructive action of the smelt on the
lining.
Da Z 0.1 a/cm2, or the admixtures pass into the smelt. The
corrosion
of Th, Be, Zr and Ti has an electrochemical nature and proceeds
with the
formation of subions of alkali metals.
K. Krivolutskly
Card 1/1

68946
_67 Z/ 6 sov/81-59-24-,85498
Translation from: Referativnyy zhurnal..Khimiya, 1959, Mr 24, P
115 (USSR)
AUTHORS: 22~ ~eyev, ~W.Ya., Smirnov, M.V.
T=: Polarization of Oxide-Carbon Anodes of Beryllium in Molten
Chlorides
PERIODICAL: Tr. In-ta metallurgii. Ural'skiy fil. AS USSR, 1958,
Nr 4, pp, 45 - 5o
ABSTRACT: In continuation of the works published earlier
(RZhKhim, 1957, Nr 11,
37300; 1958, Nr 21, 70226) the polarization of oxide-carbon
anodes of
beryllium with a variable content of.carbon was studied in melts
of
ch~.orWi~. of alkali metals at i from 1,10-4 to.1 a/cm2 and a
temperature
of'tb'6d.-'IThe analysis of the polarization curves shows that
at low-
current densities the following reaction takes place on the
anodet
BeO + C - 2e -4, Be2+ (molten) + C02- On attaining the current
density
limit (0.1 a/cm2).the discharge of the Cl- ion takes place:
2Cl--2e--OC'2
with the subsequent secondary reaction: 2BeO +-'C + C'2--'-
2BeC12 + C02;
due to the latter reaction a ftirther increase in i occurs.
Card 1/1 B. Lepinsklkh

~U THORS: Smirnov, M. V., Chukreyev, N. Ya. SOV/78-3-11-3/23
TI,TLE-. Investigation of the Thermodynamic Reaction of the
Reduction
of Beryllium Oxide With Carbon (Izueheniye termodinamiki
reaktsii vosstanovleniya okisi berilliya uglerodom)
PERIODICAL: Zhurnal neorgan-icheakoy khimii, 1958, Vol 3, Nr
11, pp 2445-2449
(USSR)
ABSTRACT: The reduction of beryllium oxide with carbon
electrodes in a
melt of NaCl and KC1 containing BeCi 2was investigated. A
carbon
monoxide electrode produced by means of charging the carbon
with the pure gas mixture CO and CO 2 served as electrode.
The electric conductivity of the melting mixture was
investigated
in the range of 682 - 10400C. The electrochemical difference
of the potentials between the carbon electrode and the metallic
beryllium electrode in the alkali chloride melt is
E = (2,036 - 5,16.1o-4T).t 0,005 V.
The change of the isobaric potentials of the reaction
Be + 1/2 CO 2 = BeO2+ 1/2 Cgraphite
Card 1/2 AZ - (-93908 + 23,80 T) � 230 cal was investigated.

SOY/78-3-11-3/23
Th
InveAigat4on of the I ermodynamic Reaction of the Reduction
of Beryllium
Oxide With Carbon
The entropy value of the beryllium oxideis So 3,37 � OP05
Beo
Cal/degree. This value ag-rees with that given in
publications.
There are 2 figures, 1 table, and 21 references, 10 of which
are Soviet.
ASSOCIATION: Urallskiy filial Akademii nauk SSSR,
Laboratoriya elektrokhimil
(Ural Branch7AS USSR, Electrochemical Laboratory)
SUBMITTED: October 2, 1957
Card 2/2

AUTHORS:
Smirnov, M. V., Chukreyev, N. Ys. SOV/76-32-9-33/46
TITLE:
The Anodic Disr~ ~lutio~nof ~Metals~in*Molten Salts (Anodnoye

rastvoreniye metallov v solevykh rasplevakh) II. Beryllium

(II.
Berilliy)
PERIODICAL:
Zhurnal fizicheskoy khimii, 1958, Vol 32, Nr
9, pp 2165-2173

(USSR)
ABSTRACT:
The dissolation of a beryllium
anode in a eutectic melt of

LiCl and KC1 was investigated. The
apparatus used is shown in

figure 1. The results are summarized in
a table. At 500 0C and

with a lowered current density (of the
order of 10 A/CM2)

about one third of the beryllium enters the
electrolyte as a

univalent ion.

Furthermore the polarization of the
beryllium anode was in-

vestigated. The electrolytic cell is
illustrated in figure 2.

The electrolyte was again Li21 - KC1
eutectic, at temperatures
0

0 0
of 400 , 500 , 600 , and 800 C, and with current densities of

10-3
to 5 A/cm 2 (Pigs 3,4, and 5)_ The anode potential in-

creased in
this case from 0,7 to 0,8 V. Below 0,01 A/CM2 the
Ca-zd 1/0
anode
potential does not vary with the curren;. %density and

The Anodic Dissolution of Metals in Molten Salts. II.
SOV/76-32-9-33/46
Beryllium
lies close to the potential of beryllium in alkali chloride
melts without electrolysis. The following equation is valid
with current densities between 0,01 and 0,1 A/cm2:
const + RT Ig i (i ... current density). At still higher
2F
current densities the anode potential suddenly jumps higher
until the equilibrium potential for Be - BeCl is almost reach-
ed. The addition of fluoride to the melt sharply displaces the
beryllium potential to negative values (Figs 7 and 8). In
fluoride-chloride melts the potential of the beryllium anode
varies with the current density (0,001 to 5 A/cm2) from 1,2
to 1.4 V. There are 8 figures, 1 table, and 6 references, 3
of which are Soviet.
ASSOCIATION: Urallskiy filial Akademii nauk SSSR Sverdlovsk
(Ural Branch
AS USSR.Sverdlovsk)
S1JBi%,-.JTTED: April 19, 1957
Cnrd 2/1

%JIJ871
5(2) SOV/78-4-11-24/50
A.UTHORS: Smirnov, M. V., Ch-~ikreyev, H. Ya.
TITLE3 The Behavior of Beryllium i P-8- It Baths in the Presence
of Metallic Beryllium
PERIODICALt Zhurnal neorganicheakoy khimii, 1959, Vol 4, Nr 11,
pp 2536 - 2543 (USSR)
ABSTRACTt Alkaline- earth metals are dissolved in their chlorides
under
the formation of subghlorides. The authors found also for
beryllium (Ref 3 ) that t*he Be+ ion is present in chloride.
mIelts in addition to the Be2+ ion. In order.to.confirm this re-
sult, the reaction of metallic Be in alkali-chloride melts is
investigated here within the temperature range 3517600.0. -The.
reaction.3e2l+Be=2Be+ is measured by -variation of the.redox
potential of a,molybdenum electrode. fie redox potential varied
by 1.3 v, and thus allowed for"the determination of the smallest
Be+,quantities. To make sure whether this was x~ lly, a varia-
tion of the redox potential of-',the.molybdenum.electrode,.the
authors,compared the potentials of the molybdenum electrode
and the~_b.eryllium electrode with those of a'chlorine electrode
Card 1/3 (Table 1). The Be electrode had-a constant potentia .1-of
-2-44 v

05671
Behavior of Beryllium in Fused Salt Baths in SOV/78-4-11-24/50
the Presence of Metallic Beryllium
whereas the potential of the Mo electrode dropped from -1.13 Y
to - 1.82 v. Figure 1 shows the course of the redox potential
during the experiments which were extended to 30 h. The
potentials of the Mo and Be electrode could not be fully com-
pensated because the surface of the latter was passivated. The
weight loss of the'Be anode was measured for the purpose,of
determining the equilibrium constant of the reaction
Be2++Be---l 2 Be+. The scheme of figure 2 shows the apparatus
used. A eutectic LiCl-KC1 melt served as electrolyte, the anode,
an'd cathode space were separated by a BeO pot, and the cathode
was made of molybdenum wire. Results of 20 experiments are
list d in table 2. As the Be anode corrodes in addition to
the anodic dissolution of Be, the authors determined.the disso-
lution rate of Be in chloride melts at the same experimental
temperatures (Fig 3). The results corrected in consideration
of the corrosion of Be in chloride melts and the equilibrium
constant calculated for the experimental temperatures are listed
in table 3. Figure 4 shows the temperature dependence of the
Card 2/3 equilibrium constant which satisfies the empirical equation

05871
The Behavior of Beryllium in Fused Salt B aths in SOV/78-4-11-24/50
the Presence of Metallic Beryllium
logK_(2.36-49Q4/T)�0.10. The corrosion of beryllium (Fig 5)
is accelerated by the addition of fluorine i-ons, the equilib-
rium of the reaction Be2+ -4 2Be+ is, however, shifted
+Be ;~==k 2-
toward the left member due to the formation of complex I-BeF 4
anions. There are 5 figures, 3 tables, and 10 references,
4 of which are Soviet.
ASSOCIATIONs Ural'skiy filial Akademii nauk SSSR IInstitut elektrokhimii
(Ural Branch of the Academy of Scienoes,.USSR, Institute of
Electrochemistry)
SUBMITTED: July 24, 1958
Card 3/3

5W
SOV/20-127-5-37/58
'AUT11ORS:
Smirnov, M. V., 04!!_kreyevp N. Ya.
TITLE:
The-Redox Potential of the System Be'/Be" in a Malt of
Alk.%jj

..metal Chlorides
PERIODICAL:
Doklady kkademii nauk SSSR,
1959, Vol 127, Nr 5, pp iW-io6q

(USSR)
ABSTRACT:
In preceding papers
(Refs 192) the authors found that in

chloride melts which are in
contact with metallic berylliumo

besides.Be++- also ~e+-ions are
oontained. There follows the

determination of 0 0 ++, and %o +
%a/.Be+o EBe/Be a /B a++ on the bas's

of the-corresponding
thermodynamic equations for the equilibrium

potentials of Be and its
mono- and bivalent ions, and the de-

termination of the redox
potential of the system Be+/ lBe++ in

salt melts. Measurement of the
equilibrium pot-ential was car-

r~ed.out in a temperature interval
360-9400 in a measuring call,

which-io-Ahown by figure 1. Asan
electrolyte, an eutectic melt

of LiCl and KOI in argon atmosphere
was used. Figure 2 shows

the-variation of the electromotive force of
the cell

Be.jBeCl 21L'C11KClj C12C with temperature. The isothermal
Card 1/2
line of the equilibrium potential of the beryllium
electrode

SOV/20-127-5-37/58
The Redox Potential of the-Syotem Be+/Be++ in a Malt of Alkali
Metal
-Chloride,s
(E - 1g [Bej , Fig 3) .calculated on the basis of the experimental
.data,-. confirms. that the melt contains Be+-ions, the
concentration
of which decreases with increasing temperature. Table 1 shows
the results of calculation for melts with different beryllium
content71n-the temperature interval 700 - 12000K. Figure 4
showe'the temperature dependence for 0 and EO
le/Be+ Be/Be"""
Empirical equations are written down for this temperature de-
pendence, and the constants of the thermodynamic equation for
the redox potential of the system Be+/I)e++ are calculated.
There are-4 figures, I table, and 3 Soviet references.
ASSOCIATION- Institut elektrokhimii Urallskogo filiala Akadsmii
nauk SSSR
(Institute of Electrochemistry of the Ural Branch of.the
Academy of Sciences, USSR)
PRESENTED: April 13, 1959 by A. N. Frumkin, Academician
SUBMITTED: April 13, 1959
Card 2/2

-za, vyp.
(Abstracts of reports of the All-Union Conference on the Physical
Chemistry of Fused Salts and Slags]Tezisy dokladov Vsesoiuznogo
soveshchaniia po fizicheskoi khimii rasplavlenrWkh solei i shla-
kov. Sverdlovsk., Akad. nauk SSSR, 1960. 70 p. NIRA 15:12)
1. Vsesoyuznoyo soveahchenlye po fizicbeskoy khimii rasplavlen-
nykh soley i shlakov.
(Fused salts) (Slag)

23080
12,11 S/078j61/CO6/0o6/oo6/013
B110/3206
tit' Oo
AUTHORSi $mirnov, M. V., Chukreyev, N. Ia.
TITLEt EtfeOt Or t~G nature of aikali-metal cations on the'
equilibrium potential of beryllium in chloride melts
PERIODICAL: Zhurnal'neorganicheskoy.khimii, v. 6, no. 6,.1961,
1361-136a
TEXT: In analogy to'the experimentally proved &ffect of the anions on
the
values of the electrode potentials, the effect of the cations of the.
molten alkali salt (serving as solvent) on the potentials was presumed
by V. A. Pleskov et al. 254 (1946)).
..(Uspekhi khimii, 16, In order to
clarify this dependence i the authors investigated the equilibrium
rotentials ofberyllium. in LiCl melts and the eutectic mixture LiCl
+,KC1
KC1 and CsCl with*O-46 to fO.1 mole % BeCl in a wide.temperature
range.
2
They restricted-.tbArAsdlves to low BeCl concentrations which behaved
2
like ideal solu ions an'd -s"atisfieA'the Nernst equation7.
Chemically pure
LiCl, KC1 and AC1 and BeCl proauced'from BeO and C03~, 8erved.as
initial%'
.2
substances. Thl'~melt was filled into the beryllium olide crucible..
The
Card 1/7

23080,
S/078Y61/006/006/06/oI3
Effect of the nalure of alkali-metal ... 3110/B206-
cylindricai Be e ectrode with a diameter of 5-10 mm contained
only.0.01%
electroneg4tive Impurities. A carbon-chlorine electrode served-as
reference electr4de,' Under equal working conditions (constant
temperatur4
and. rate of intr6duction of chlorine), the potentials of the chlorine
-electrode and the: Be e-lectroae were almost equal in the
electrolytes
LiCl, KC1 and CsC1. The emf measurements with various electrolytes
(Fig. 2) correspond to the* following empirical,equations:
2.00 MOC 016 DeC11+LICI or IMD-DOSD:E-,~2.i27-3,73.IOA.T�0,003,,V
0 lip mcC 0,6, BeCla + LICI Qt 620-rM* - Es - 2,522-277. 10--T �
0,004k -1
8:17 MCC la' ~ BeCit +3LiC1 + 2KC1 At- 421-755*: E.,
2,703-4,97-10,4-T�0.008ty
12 mot % BeC11 + XICI + 2KC1 c-; 393-940*: E4
2,65S-3,5G-J0-4-T.�0,005qV
9:77 mce 16~DeCl,+KCI at 770--1007*:r;,-2.692~3,62-10--.I'�0,0020V
0.60 mc~ BcC1,+.YC1 At 706-1023* -. Es = 2,637-i,8G-10-4-T, -0,003q',(
101. #v( BoCI2+,C-,Cl at 666-9300,r.7=2,807-4,43-10-4-T�0.00541/
0,~7 Mee BeCl, + CsC1 C%b 605-050-: H, = 2,700-2,91-10-4.1- � O,OG3k V
and agreed well with the values by L. Jang and R. G.-Hudson (Trans
Metallurg., Soo. AIME, 215, 589 (1959)- If the thermo emf E T
=-(-0-0076
+ 0-174-10- 4 T) t 0.001 V is inserted, the~following is obtained:
card 2/7

23080
S/078/61/006/006/oo6/o13
Effect of the nature ot alkali-metal ... B110/B206
-2,5i4 + 2,77 10-1 - T0,005 Y
E3
-2,605+4,80-10 -T4-0,009V
RA 2,650 + 3,39. 10-4 T + 0.006 v1
Es 2 634 + 3,49.10-.4T 0,003Y
Es -2,629 + 1,60-10-.T �0,004Y
ET =~2,709+4,25.10--T �0,006 V
R, 2,782 + 2,74-10-4-T � 0,006i Y
On the basis of the investigation results, the isotherms for LiCl (,I)
LiCl + 2 KC1 (II), KC1 (III), pond CsCl (IV)-melts were built-up, the
3
inclination of,which for the value n< 2 corresponds to the coefficient
before the logarithm of the thermodynamic equation of the electrode
0
'In
potential: E =,E + (RT/nF) [Bel if the ion ptrt of the beryllium
Be/Be'
electrolyte is inserted. In BeCl melts with M, A,
concentration in th.e 2
0
n rises from 1.93'(700,K) to 1.64'(,12000K); with (III), from. 1.82
0 0
(1100 K) t0-1-73 (13000K); with (IV), from 1.96 (1000'J to 1.82 (12
00 K)
If the*mean. valence,of Be and.its total concentration the melt are#
0
can'be oal' Int
known E culated from the equatiori o he eldetrode
Be/Be'~- k
Card ;/7
A

23080
S/078/61/006/006/006/013,
enaiure of alkali-m
Effect of th etal ... B110/B206
potentials tBe2+j
E = Eje/Be2+ + (2-3 RT/2P)-lg The following equations
0 536+ 5--7-10
hold- LiCl'melt. EBe/Be2+ -2. T v; 3 LiCl + 2 XCI melt:
E0 2+ -2-702 + 6-4-10- 4. Tv; X01 melts Eo 2+ - -2-727 + 5.3 .10-4
Be/Be Be/Be
XTV; OsOl melt-. Eo 2+ -;-2-834'+ 5-9-10-4-T v. The effect of the
Be/Be
metaLe'ations gets evident,through che difference of LiCl and CsC1
which
0
amounts to 0.276 v at 1000 K. The effective cation radius r in the
ef
equimolecular s"6di-um-.and potass + r,+)/2
ium. chloride is r ef r-,j a
- (0.98 + 1-3~)/2 - 1.16. 'T1~6-kon...potential is then: e/r 1/1.16
- m62 and E 2+ - 7..2,-718 +.5-83-1'O-4-T.v-*.-The. difference between
Be/Be
0 0 2+ Eo 2+
the E . values in different melts equals the emf: E EBe'/Be .-' Be/Be
of the galvanio element Be/Bedi
2P~Mele'HBeC121 Me",01/Be' It is a direct
afeasure for the change ot the isobaric-potential at a triansition of
the
2+
Be ions from,the melt with lower bond energy to the chlorine anion in
Card 4/7

23080
S/078/61/oo6/oO6/006/0115
Effect of the nature of alkali-metal .-B1101B206
the melt with higher bond energy. The emf with the biggest
value, that of
the element Be/BeCl //BeCl , LiCl/Be is: Eo
2' CsCl 2 Be/Be2+(LiCI)
- E0 2+(CsCl 0.296 - 0.2-10-4.T v. For the reaction of the
melts
Be/Be
Li 2BeCl 4+ 2 CsCI 2 LiCl + Cs2BeC1 4f LZ -13650 + 0.92-T
eal/mole BeC12'
Here, 8H 13.6,kcal/mole BeCl 2. and AS 0. For Cs2BeCl 4' the
bond
.2+
energy of the chlorine anions wit#Be is higher than for
U,BeCl 4 melts.
The constancy of the entropy is proof of
a-constant-iongrouplng,-
According to the authorst.'datal' the:following holds for
the-reaotion of
the melts: L12BeCl 4+. 2~011=" 2 LiOl + KZB~ec'14, 5Z27 -8700
- 0.180T
eal/mole BeCl The bond energy of the anion BeCl in Cs BeCl is
still
2' 4 4
higher by 5 kcal/g ion.. The strength or-weakness of-the bond
of Be 2+ with
the chlorine anions-thus d6pen'ds on the..ion potential of
the salt oation6.
The., isobaric., potential for, the. t,tansit.i6n of * EL
B012solxit.ion in a' metal
chloride melt with the ion.potential-el/rl -into the solution
of a melt
Card 5/7

23080
810781611006100610061013
Effect of the nature of alka~lf~metal'..S- 'B11O/B2o6
witly the ion potential ell/r" is:- 8Z = 198 '33 [
(-e-1/r't) (e? 1r4 )j cal/g ion
Becl'. There are 8 figures''and 27 references- 21
Soviet-bloc and 6 non-
2
Sdviet-bloo. The references to the English-language
publications read
as follows: Ref. 3.: K. K. Stern.J.Phys. Chem., 60, 579
(1955); Ref. 11:
L. Jang, R, G, Hudson: J. Electrochem. Soc., 10T_, 986
(1959); Ref. 10:
H. Laitinen, J...W. Pankey. J. Amer. Chem. Soc., L1, 10,53
(1959).,-
ASSOCIATION: Urallskiy filial Akademii nauk SSSR, Institut
elektrokhimii
(Ural Branch of the Academy of Sciences USSR, Institute of
Electrochemistry)
SUBMITTED: MaY 4, 1960~
-Card 6/7

23060
Effect of the natuj~e Pf alkali-m S107816,110061oo6loo61013
B-1101h206
.7,717
3 CL+ZmCL+
+4081788C12
CL
461,9 fgg
70# fgg
AM Ic,
Fi,
g-' 2: Tevipera~, ure -dependence of the emf of the' contine'r with
chlorine--and B ele6trodes'
in melts of various compo ti
on
Card 747

SMIRNOVf H.VD; CHUNRETEV, N.Ya.
StudY of equilibrium between petals and fused
salts by the
electrcoutive force methoo as exemplified by
beryllium in
c1floride melts. Trudy Inst~. alelctrokhim.
UFAN SSSR no.3.
3-15 "62. (MIRA 16:6)
(Beryllium) (Alkali retal chlorides)
(Electromotive force)

SMIRNOV, N.V.; XOMAROV,
rluorids complexes of ber7llium in a chloride-fluoride
melt. Zhure
aeorge khis, 10 noo9s2001-2005 S 965. (KRA AM)

SOV/24-59-2-15/30
AUTHORS:Polovko, A. M., Chukreyev, P. A. (Leningrad)
TITLE: On Accelerating th-e-7e-BTM9-o-r-tFi7e-Reliabilit-,7 of
Electric
Elements in Engineering Systems (Ob.uskorennom ispytanii
nadezhnosti elektroelementov tekhnicheskikh sistem)
PERIODICAL: Izvestiya Akademii nauk SSSR Otdeleniye
tekhnicheskikh
nauk, Energetika i avtomatika, 1~59, Nr 2, PP 99-103*(USSR)
ABSTRACT: One of the characteristics of the reliability is
so-called
intensity of failures X which can be expressed as:
n~t)
N~t)At
i.e. the ratio of the number of failures to the total number
of correctly working elements per unit of time. Knowing the
intensity %. of the component elements the probability of
the correct *ork during an interval t can be expressed as:
p(t) - exp %i
( N
Card 1/4 t)

SOV/24-59-2-15/30
On.Accelerating the Testing of the Reliability of Electric
Elements
in Engineering Systems
where N - number of elements, xi - intensity of failure
of the elements of i-th type. When composite elements are
considered, the relationship of the intensity of the fai-
lures to the loading coefficient k should be known. since
the relationship X = f(k) can only be found statistically.
This requires usually considerable time in order to collect
the necessary data. As an example, Table 1 illustrates the
proportion of failures per 1000 hours of work (secondoolumn)
and time t in thousands of hours elapsing between two
failures (third column) for various electrical apparatus
(first column - electrovacuum apparatus condensers, resis-
tors, relays, rotating apparatus, induc;ive coils). The
acceleration in obtaining the data on the reliability of
the electrical elements can be obtained when X - f(k) is
considered not at random', but can be calculated analytically.
It can beassumed that the ratio of the intensity of failurgs
to the loading coefficient is expressed as a * bk *ck
Card 2/4

SOV/24-59-2-15/30
On Accelerating the Testing of the Reliability of Electric
Elements
in Engineering Systems
There are various methods of determining the coefficients
a I b and c. As an example, a method is shown in the case
of condensers and resistors. The intensity of failures %
(percentage per 5000 hours) related to the coefficient k
is shown in Fig 1, where I indicates the mica condenser,
2 - carbon resistor, 3 - paper condenser, 4 and 5 -
ceramic condensers of first and second type;:eespectively,
6 represents the wire resistor. The ratios are approximat-
ed in the form of coupled segments (Ref 4) which is explained
in Fig 2. Here the curvature of the curves is greater in
the region of mean values of k . They can be approximated
to a straight line for other values of C i e.' they can
be expressed by an equation of the type E& 1), where c
and d - slope of the curve, A. - k0 = f for large and
small k . The formula (2) can be used when n is ex-
pressed as a linear function of k , i.e. where ki -
maximum loading. The calculation can be
the coefficients a , b , m and n
an approximate method. Their values are
simplified when
are determined by
shown in Table 2.
Card 3/4

SOV/24-59-2-15/30
On Accelerating the Testing of the Reliability of Electric
Elements
in Engineering Systems
where the top figure is found graphically and the bottom
one from the expression (3). The method described can
only be applied to simple electric elements since in more
elaborate systems the curve % - f(k) may differ from that
shown in Fig 2. There are 2 tableal 2 figures and 4 refer-
ences, of which 2-are Soviet and 2 English.
SUBMITTED: November 21, 1958.
Card 4/4

SOV/24-59-3-26/33
AITTHORS;Smolitskiy, Kh. L. and Chukreyev. P. A. (Leningrad)
TITLE: On the Comparison Between th~.. Significaime of
Single-Elements
and General Samplings
PERIODICAL: Izvestiya Akademii nauk SSSR Otdeleniye
tekhnicheskikh
nauk, Energetika i avtomatika, 1~59, Nr 3, PP 176-178 (USSR)
ABSTRACT: Single element sampling takes place when every
element is
tested individually for rejects while general sampling takes
place when whole systems are tested. The calculation of gen-
eral sampling is based on the probability Eq (1) where m
is the number of systems, while the single element method
is based on Eq (Q Wh9n,comparing both equations it can
be shown that p m - pkm) for m = 1 Then it can be
pl P2
stated that the probability of the regular working of the
system, consisting of k elements, W is de f inei IF Iks (4) tD
A~ -
(7). When the function f(q) (Eq 8) is introduced, then
Card 1/2

SOV/24-59-3-26/33
On the Comparison Between the Signifiamce of
Single-Elements and
GeAeral Samplings
it can be shown that Eq (9) is true for the condition (10).
Generally, it can be stated that the greater m , n ~ qi
then the smaller the difference between the single element
and general samplings. There are 3 Soviet references.
SUBMITTED: January 27, 1959.
Card 2/2

SMOLITSKIY, Xh.L. (LDningrad); OBUIRMY, P.A. (-Leningrad)
(~iestion of optimum reservatiou of apparatus. Izv. AN
SSSR. Otd.tekh
nauk. Energ. i avtom. no.4t79-85 JTI-Ag 159. (NIIRA 12:
11)
(Automatic control)

86271
S/108/60/015/008/010/010/XX
B019/BO63
AUTHORS: Smolitskiy, Kh. L., Chukreyev, P. A.
TITLE: A Quantitative Characteristic of Reliability
PERIODICALt Radiotekhnikay 1960, Vol. 15, No. 8, pp. 74-80
TEXT: Proceeding from the fact that the various elements of
industrial
apparatus have different periods of service (due to the fact that
some
elements are replaced after some time, while others are not), the
authors
define a characteristic of reliability which he calls the mean
failure
frequency. The total failure frequency of a system is given as
K
u) (t) = 2- N,fi(t) (2), where Ni is the number of elements in a
system
c izi
of the i-th kind, and f,(t) is the mean failure frequency of the
elements
of the i-th kind. It is shown that tic tends to a constant value for
t--m-*oo. Finally, the mean failure frequencies are calculated for
some
frequently occurring distributions of the out-of-operation time
Card 1/2

86271
A Quantitative Characteristic of
Reliability
S/108/60/015/008/010/010/Xx
B019/BO63
I
(exponential distribution, equally probable distribution,
Rayleigh
distribution, and normal distribution), B. R. Levin (Ref.. 2)
is mentioned./
There are 2 figures and 3 Soviet references.
SUBMITTED: November 22, 1959
Card 2/2

BRYAKALOVI G.A. (Leningrad); DOBRONRAVOVA, I.K.
(Leningrad);
GHMEYgV, P.A. (Leningrad); YUSUPOV, R.M. (Leningrad)
Solution of a logic problem using an analog
computer. Izv.
AN SSSR. otd. tekh. nauk. tekh. kib. no.3:168-176
MY-ZD t63.
(MIRA 16:7)
(ELIectronic analog computers)

POPOV# Noval-to-, -Y~9*
td.ng UG tbertal 00nditiOM Of the Siberian winter "
related to the cold reelatanos of technical
equiprent, Was
Into geogo Sibs i Wo Vosto no.3120-29 163,
(HIPA 18#22)

CHUKRE.YEV, V. K.
"Appraisal of the 'dater Regime of $oil and Experiments in Its
Regulation." Cand
Agr Sci, Leningrad Agricultural Inst, Min Higher Education USSR,
Leningrad, 1954.
(KL, No 2, Jan 55)
Survey of Scientific and Technical Dissertations Defended at
USSR Higher Eduoational
Institutions (13)
SO: Sum. No. 598, 29 Jul 55

USSR / Soil Science Tilling. Melioration.- Erosion. IT
Abs Jour Ref Zhur Biologiyaq No 11, 1958, N06 48694
Alithor Chukr ev
inLz - a
Title Mole-Draining the ~ro~is' 7wra-i M'e';'%Vo'd. of
Controlling Their Water-Air Regime
Orig Pub Dokl. VASKHNM, 1957, No 8, 44-48
Abstract The mole-draining of poorly permeable
dust-like
soils together with the simultaneous deepening
of the tillable layer In the Prinev lowland
on the territory of Leningradskaya Oblastf
promoted improved physical and, especially,
water properties of the soils. The mole drains
made without an outlet at the depth of 45-50 cm
acted as regulators for the shifting of the
capillary moisture in the soil. -- P. N. Sofiyeva
Card 1/1

CHUFREYEV, V.K.
Phenological and temperature surveys in 196-9. liat.
po fen.
no.305-39 162 (MIRA 18:1)

V,r,',
lic--thod of mmking oalculations of the suuply -of
molstare In solls
moro eyact, Trudy GGI no.123t48-,42 165-
(~CRA .18:10)

Y8.P. 'Larlingrad)
Effect of vegetable fat.- on the II.pold metabolism in
vitrc,
Vop.pit. 24 no.4-.84-88 Ji-Ag 165.
(MIRA 18-.12)
1, Kafedra, biologicheakoy kh1mU (zav. - prof.
S.V.Uedz~.etski-
Leningradskogo sanitarno-gigiyenicheskogo meditsinskogo
instituta.
Submitted June 9, 1964.

MHATOVA., T,S.; ~IYACIIN, V.G.,- CRUOMU, 7e.l.
increasing the,ldurability of ladle brick, Qpeupory 28 no.8:
355-360 - 163.,~, .(KMA.16:9)
1. Vostochnyiinstitut ognsuporov.

IGNATOVA, T.S.; nYAGIN, V.G.; FOPOV, A.D.1 CHUKREYEVA,,
Ye.l.- DIFS14TEEIN, Ye.I.;
0
NAZAROVY K.S.1 MANARYCHEV, A.R.
manufacture and testing of high3,y resistant ladle
firebrick. Ogneupory
29 no.11489-495 164. (MIRA 18al)
1. VostochWy institut ogneuporov (for Ignatoval Fiyagin,
Popov,
Chukre.yeva). 2. Mapitogorskiy metalhirgicheakty kombinat
(for Dikshteyn,
Nazarov, Makarychev).

GHMOV, F.V.; SIRWIROVA, T.M.; YIMMILOVA, L.P.
Mineralogy of bismuth in the oxidation zone, Kora
vyvetr.
no. 3:5-25 160. (MIRA 13:12)
1. Institut geologii rudaykh meatorozhdeniy,
mineralogii i
gookhimii AN SSSR.
(Kazakhstan-Bismuth ores)

0i: N :-OW :--We r-* WO
it u if 14 a 1) W to 10 14MINUMISMAMUM
Is
-611? Of-b - -I "A , a
so
Lille
00
ccetrw of If noolkill figWwWas. -A,41it
04 C f L '39TO
Anti N. Hill )'FPO$ , '11, w **
(It"I) -lht lit'lo, III Will-I In tile I All', 11411'. VIA Ow
oil 11 AIIII .1,7 111,, Z%
reaction vulm Is lkistil tit% the praetk-al irmilly. of
briuldine tit the soln. W" Willett with 1~; %v. .4 111C41. l[Cl
M411.
00 #11 t .00
1) Polls 1-1 2.0. sit 1 2.7-Citillf(SOM)l mut still tile WA-4
tilrdl"l With
u jlh4O&H NsOlf ow aboviv. a. and 1.0-Aculs ottv delit. he
titrat.
00 Ill.40i and the high silly. of the I sailts of a-C, *0
and I.t;-CljI&(SC)JI)I, &lid the poor soly. of $-add and Ing
the join. with 0.1 S MIMI and computing. Foran 9
00 6 high only. of all tither sulfunk addis slid Hiso, In &
NQCI artificial mist. of the c. P. acids consisting of ()Xori
1j.0-,
0 r~ mvin. IA"di~ 4o a. tit the sultogiation num in boiling
fljx;;Nl a. x. 2.6- + *--,7-. 41.11187 a. 1.6- *guA
:0 .ii,: 11,0, filter. w"h the plit. free front unite the (MUM
g- 110kh there w" fixand by this tncthtxl 0.4im)
filtrate and wasIb wairfo and make tip to I I.; neutralize it-,
O.Mr-NI w. !1,6- + 2.7-mid and i).IZM ji. If.S0,
4111110 Oi 25 cv. of the miln. with O.t N NAOIt MiLinst
phirtud- ch.". in.
1 plithalrin. v
0 little up 111 [01) cc. with 111.0 add 27 C.
NaCI with shakit until dilmilm lot slaild owrillaill
~Hrr off file C011I.Na wilit sla-litill 11411"1011 a
110111voi4i 00
\MITI. Oluse 41111 11W IlAsk with the filliate. votillinte the
tkin of the 'IM, it's M 1111U., bw ilic, japt. with 11.0 00
00 j .1 treat with IV. I. IICI outs. (20 S. I and 215 cc.
IICI (d. 1.19) in 1 1. Hift Aker off and wash the
(C..Hh%O%H)j(C.H4.VlIg)v free front Cf. and titrate
together with the filter with 0.1 N.NaOI1 -pin t phenol-
00 phthakin with ovivaskinal boding. ~ In Hit) cc. 1W conla.
27 s. N&CI Is thitativvill O.MW corfIrspimullingr
toIM cc. 0.1 N N&011.~ U.S04 It tkid. with NiM
00
00
00'#: 6111ALkiWFOCAt 1,111N.Tusit CLAWMA110
so iii
- : lid., - - -- -- -_ --- , -_ 9111111 111
4 An I s Ow 0 R I W to 5 to a J; q V
U Vt IV 10 Is Of go it It 0 Is al It it it MO 0 1 114 Ili~d,
0 0 0 ^ 0 6 0 0 0 ~o 0 OK no 0 00 0 0 00 0 0 0 oil
ot IT144 14 0 og
19 : 9 : 0 o1: 0 4 0 0 00 GA
000 o~goooogoo.000006 0040000000000
M _80
Mail
ME

!DLO
A
WS I V UM X 31 32 31 30 X 38 J? X 31 4 A IQ 4) NO
lic 010CHALA 0 OPQ it TIN 9 11 . L .
4 A j a I
I

d AT III

ST cm "T u

s
l
s

,
j I
-1 A, -1
Op It to. INC. 4.0 41. evot4s
. ~07.
l

-A
1, 4010L~s
~A
f_

e
'

iv4LviA3&ll

GI

~Vc fil
Got

09m

Got

00
0 et

0

R09

1

It0

n00

Molff ffwq:)
,

so

e0.

Pull .4,M
I
11

so
90=

do

`WR 01 Poo a 3% *OR-" 31 vorm %01
-

00
00-

M on
IIIIA mpmpaad PF" p =OPP- VIP Aw- IPM
d '
11111111111111P OIAL SUP
109
2
M A
-

1

,
a
p1m pL-j;
q P
R
W

40
00

.W 'p3lald 101 19900A MRS WMPUWRM
Pj.-v aql Not

ru"Orlp 041 at (Wm)
"pw $
j
M

I
-Ing I"Ippj
I fivi
I F
l
,l
U
"
MM" am p "I
o B

00

RO
ar
P
l p- Hwu
If
ru
'

M
-Mkljd XM4j" ap lop pm* AFMP MU-jW#

go

:v :) ).I '(WO16-M It -mw
vpu IN 11 p9m ommmpq3-v,v We p" p 11110
so p mgmt-toil DaL
i4im am IR mm anown W

* 0

,

0 0j;

-

1,14nid 4-i 441i III
~
I
00

03

Itoststaltumall
Its
n
0 M
T T r Ir
marastumck
aftJ444 iia ii $I It 11 al it a & I
_

r a
s f I I f I
All, 11,

ft -A-ALAh- lb-"_*
'
,%~ I* * 0 0 0 0 * 0 0
0 0 0 0 00 6

*;;;;Oeeeo*ooooooo
W it is it
id a V Is so v is Its 4 41 43 &1 41 0-00
A W ONO 4114,~, 1~ A 11
-1-1-m- cc - a I I .,- , a I-A~ A jj
00 11. #,too -7-00
00 A so
00.0 -4111a
so Ponissfic* ot ampkikoloavA,41 dioullimic still midtf i-
s condillosm of ibe dilrect sulfoodflon of usphibideno A A, -to
j (,.Mpt feast. "ad. I.e. 1'. M, A. X. - 16. 00
00 with 4 full- -4 of Uhl' rwl-K I"Ir. 1.6-. 1.-
2,41, us?. stin't
00 8; 04-himilwell, rite 14til-I " A4 fitillill In I fir
mill"ITI 114" ly
U*fisthmc 9 00
so zx. finely jklwd. U4.11. Wat dild , .1 "
V, Illin, Io 11.5 S. $if UsS04.11it), Isralrd lit 1311'
midll~.,ii 000
thetv Im 4 hm. Isn't IKXII"l hats 1 1. ..1 we 11.11
:0 lim-ugh ilms(011), was viddeI Its the sh%. to Wild .11 th~
=00
111.10" 1 bF ppl. Was filtered, Illex,41 lilliale 13"311.11"'1
COO
*0 with Na,Vto,nml evaixi. mi-Irt mliterd immksr lit [00-,
'I lie mail. WA,. VIKArd to Tmilts totilp. And tile slighliv
~.,I 0
00 W
N11 441(31 -it tile di-itil "t-tr Kiflifil,411V X*o
so jilml. *rhe, ppt. was altered oil. the (111tate, CVAIKI. Ill
00 z nituo anti the residue dried at IAW. 'rite acid chImittes
obtained ("Ytn (lit Traidut were ttralvit with betts"le,
00 tile Wa, filt~mdofl .611.1
clitri &third Its the filtlistv. COO
r1doli4c (mbivul 3.4 10, in, 1:16-5 wa. ppid. 4 tvi-
A. H. Krappe see
be*
ties
LA .9VALLURGICAL LITIRAIL41 CLASSIFICATION tie 0
too
41611, 00 all it,
10 At a a If If 01 -c1 IT it of "a it 1 114 6' 1 64 0- rat -
is * 0 00*000*0000000900 0 0 0 0 and
:is 0 0 0 0 0 0 0 0 0 0 0 0 0 0 *If 0 0 a 0 0 0 0 0 0 0 0 0 0 0
0
0 so*

004
00
00-3
go
04,
068
sot
13
.3
00-3
WWWWWWWWWWWWWWWO1, W W a 0 0 0 0 0 0 W 0 IF 0 W Wi
Ads 4 is 9 1411t?U14,114 fill "fra Dun AVAPPIM11 J233 No his?
Imps if go of die*
raft Q.H I It L.mM._r_Q,R ! CM-W MIN b
-- ----
dWAlook Kid and 2-aitta-4.8-
GM2~114)=V& atuf H
Sokuk"S (lost. org. told hu. K:
J~ A (U. S. S. R.) is, 3"
N&03tol N*V.C-ocQ (3-tilim-IA-tiaphthalcm-
Vrlt.); KM) bmted with 4 rrts of KU lot 6 bro. an a
t,, mAd water mail cipin.
meam bath go in
Wit boustne. the c%x_
ISA"t 4-01tro 111001W) gave the
cAWQ#). in. 177 N1tMW of 1,6-nalih.
tb2kWdljUff01MiC Kid Witit 03% HN01 id HSBC~ IAVC
both Ow 3. and the 4-nitre immuers In following ratim:
in 94% ltSO~. 33% 3-nitro aoloo% 4-nitro acki at Xu-6'.
39% and 60% at 6-10", in 91% HoSO, nt 115~ AM'. W' .
and 50%, romp. G. hf. KONAAAIPUIT
v
1 AS11-tLA METALLUNGKALLIT[RAIL4tlCLASUPICAii6N
Ilk SIVIN)AV. - 70 -4 *m - - -- I -
]a. 80.1n.
WON* -4 $041*&* 40 0.1 Get 143killo-cl 1111131
- I F I I I p An
Ef Uis AV so it p 17 It W It 19 AM 't a t, a it cc I a 1 4 V
0 0 0 0 0 * 0 0 Of 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0
0 0 0 0 0 *is 0 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0
-00
-90
-00
Also
=00
use
~19
00
:
00
voe
coo
Use
ties
tie
we

CHUKSAI~'OVA, A. A. PA 234T30
VSSR/Chemistry Lignin 21 Oct 52
-"The Chlorination o:f 'Hydrolyzed Lignin," N. N. Shory-
gina, A. A, Chuksanoval Inst of Org Chemj Acad Sci
USSR
-."Dok Ak Wauk sssR,, vol 86, No 6, PP 1135, 1136
The chlorination of hydrolyzed lignin at room temp
1.,Lwithout catalysts and without an excess of chlorine
takes place with a part of the chlorine going into
the aromatic nucleus in the 6 position. Presented by
Acad A. N. Nesmeyanov 9 Aug 52.
234T30
144
Ir9

NOIN ME M PA, ;14MIO o,

SIRGRYEVA, L,L.; CHIMUNOTA.. SHORYGIMA, N.N,
Action of dlluiod'n'itric acid upon hydrolytic lignin.
Izv. AN SSSR,
O~d. khls. _ sau 'k'no.5:653-654 my '37, (KWA im)
1. Inotitut organichemkoy khimii im. N.D. Zelinskogb
Akademil nauk
SSSR,
(Nitric acid) (Lignin)

5.3400 77o84
SOV/62-59-12-28/43
AUTHORS: Chuksanova, A. A., Sergeyeva, L. L., Shorygina, N. N.
TITLE: Behavior of Lignin Models on Nitration
PERIODICAL: Izvestiya, Alcademii nauk SSSR. Otdeleniye
khimicheskikh
nauk, 1959, Nr 12, pp 2219-2225 (USSR)
ABSTRACT: Nitration of lignin is accompanied by oxidation. The
reaction of nitric acid with lignin model compounds
was Investigated. The following monomers were used
as models:
(1) Ri=Clloll-CI12-Ctl3,
R, C11,
R, "'I - C"',
R 2 H
(111) 111 C112
- C11011 - C113,
112 C112
(IV) III Clio - Clioll - C115,
R2 11
(V)
III CII, - C112 - C11,011,
01
R, = Clis
,,0C113 (VI) III C112 - C113 - C11,011.
R, = 11
0112
(VII) III -Cli, - Co - C113.
R2 = C11,
(Vill) III = C112 - Co -
C113.
113-H
Card 1/3

Behavior of L.ignin Models on Nitration 77084
Sov/62-59-12-28/43
The nitration was carried out in CCl 4 , at 50. 1-(3,4-
Dimethoxyphenyl)-propan-l-ol with 3 M HN03 gave the
following nitro-compounds: 1-(6-nitro-3,4-dimethoxy-
phenyl)propan-1--ol (mp 860), a very small amount of a
dinitrocompound (mp 950) and 2 compounds (C 22H2809 N2)'
(1) Mp 2060, mol. w. 462 (cryoscopy in benzene) oxi-
dation (15% HN03 ) gave 4,5-dinitroveratrole. (2~ D1,0
1340, oxidation gave 4,5-dinitroveratrole. Nitration
of Il gave 3,5-dinitroquaiacol (mo 1220) and a nitro-
compound C 20H2409 N2 (rap 140-1410), mol. w. 416.
Nitration of III with 1 M HNO 3 gave l(6-nit,.rO-3,4-
dimethoxyphenyl)-propan-2-ol (A) (mp 99-1000) and
with 3 M HNO 3j in a*ddition to A. also 1-(6-nitro-3,4-
climethox-ljphenyl)-propan--2-one. Nitration of IV with
1 M HNO gave a mononitro-aerivative (mP 95-961). V
with 1 Ld 3 M HNO 3 gave 1-(6-nitro-3,4-dimethox-yphenyl)-
Card 2/3 propan-3-01 (mp 92-930).

Behavior of Lignin Models on Nitration 77o84
sov/62-59-12-28/43
ASSOCIATION:
SUBMITTED:
Card 3/3
VI with 3 M HNO3 gave a light-brown powder containing
5.32% nitrogen. VII with-3 M HNO 3 gave 1-(6-nitro-
3,4-dimethoxyphenyl)-propan-2-one (mp 125.50). VIII
with 3 M HNO3 gave a dinitroketone (mp 1840) of
unknown structure. This seems to indicate that lignin
contains 60-70% phenyl-propane structural units
capable of being nitrated. The yields are not given.
There is 1 table; 9 references, 3 Soviet, 3 German,
1 Finnish, 2 U.S. The 2 U.S. references are: M.
Kulka, H. Hibbert, J. Am. Chem. Soc., 65, 118o (1943);
Ph. C. Roberti, R. F. Jork, W. S. MacGregor, ibid. 7.2,
576o (1950).
Zelinskiy Institut of Organic Chemistry, Academy of
Sciences, USSR (Institut organicheskoy khimii imeni
N. D. Zelinskiy Akademii nauk SSSR)
March 31, 1958

CHUKSAIIGVA, A.A.; SHORYGINA9 N.N.
Action of nitric acid on /-?-guaiacvl ether of
o(-veratryl g3,vcerol,
Izv.AN SSSR Otd.khim.nauk no.8sl53.1-15.12 Ag 160,
(MIRA, 15:5)
1. Institut organicheskoy khimii im. N.D.Zelinskogo AN
SSSR.
(Ethers) (Glycerol)

CHUKSANOVA, A.A.; GRUSPNIKOV, O.P.; SHORYGINA, N.N.
Study of nt
.6trolignin inhomogeneity. Izv.AN SSSR,Otd.kbim.nauk
no.10;1810-181Z 0 .161. (MIRA 141lO)
1. Institut organicheskoy khimii im. N.D.Zelinskogo AN
SSSR.
(Nitablignin)

CIIWANOVA~ N..4
"Different Forms of Potato Mosaic as Pluwes of a Single
Disease," Trudy
Len. obshch. est., 70, No.3, 1950

VARSHAWVICH, A.A.; CHMMAMVA, N.A.;YAXOVLEVA, N.S,
Xarly diagposis of virus diseases of potatoes by
means of light
analysis. Ust.Len.un. 9 no.1:49-56 Ja 154. (KM 9:7)
(Potatoes-Diseases and pests) (Virus diseases of
plants)