SCIENTIFIC ABSTRACT GLADYSHEVSKIY, YE. - GLADYSHEVSKIY, YE.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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KRIPYAUVICH, P.I.; (;UII)YL;Iii-:VJe,,LY 4, L, r, ~.r-,-stallirie structLu-es of com add rich iz bv:r 'Lli i in the .7 pow I 'Y un Systems No - Be and W - Be. ~:ris tall ograf iia 8 no.3:449-451 IV-Je 163. (RULA. 16.3-1) 1. L'vov5kiy -II.-di.-~-rsitet ii-i-jud I.Frar~:o. I L 18097-63 EWP(q)/8WT(m)/BDS AFFTcAsD JDIJG NR: AP3004096 S/0070/63/008/004/0595/0599 AUTHORS: Kri.,yakevich, P. I.j Glady*shevskiZ, Ye. I.; ~arechro!hx_0,_S_,; Yevdokimenko, V. _~ e ; M =US iy,-7.71. ; Frank6vich, D.__ P. TITLE: Some patterns in ~he grvstgLj,~themistry of intermetallic compounds of rare- eartft metals SOURCE: KristUografiya, v. 8, no, 4, 1963, 595-599 TOPIC TAGS: crystal chemistry, rare earth , morphotropic series, isostructural series, lattice, atomic number ABSTRACT: The authors have used data from the literature as well as their own experimental work to study the intermetallic compounds of rare-earth metals. The aspects studied include isostructure, morphotropy, dependerce of lattice constants on atomic number, and the formation of tertiary compounds. In view of inadequate data on isostructural compounds, the exact cl:aracter of such series cannot be predicted, but it is thought unlikely that conple've isostructural series will be found for the rare earths (i.e., series including all the rare earths). The compounds will most probably form a morohotropic series of identical compositions Card 112 L 1809?-63 ACCESSION NR: AF300ho96 or a morphotropic series of varying compositions. In most morphotropic series, beginning with some particular rare earth, a certain structural typo gives way to another., as occurs at the boundary botween rhe cerium and yttrium groups. Such series are commonly polymorphous. Successive changes in atomic number lead in some series to changes in both compositioR and structure. The atomic radius, which does not change consistently with increase in atomic number, is an effective characteristic in daLermining isostructural and morphotropic series. Comp'.ands of certain structural types that are absent in double systems may show up in tertiary or quaternary systems. ,An ex mqle is the existence of compounds of Th2Zn 7 and TWM12 a m (:"e' - M A~. in the syst 7ilaAlthouf;[i they are absent in the syst m Cel"An, They exist in the related double systems Ce-Fe and Th-Mn. Orig. art. has: I figure and 1 table. ASSOCIATION% Llvovskiy gosudarstvenry*y universitet im. L Franko .,(Llvov State, University) SUBMITTED- 113111ar63 SUB CODE: PH DATE ACQ: 15Aug63 NO REF SOV: OlJ4 ENCLi 60 0-MERt 007 Card 2/2 G-LADYSIfFV-)KIY; Ye.I., KRIPYAKEVICH, V.I.; FRANKFIVICH, D.P. Orystalline strut~t-.ire of rnre Parth metni compoundo cr:n-aLnina 1 11 ,) . Krirlal.-)grafii,-t 3 no.~:?~;!--7-39 5-0 163. berylliw(Hel -, I NIRA It'410) 1. univir,'Ltet irl. I.Franko. GLADYSHEVSKIY, Ye.1,; TELEGUS, V.S.; MARKIV, V.Ya. Crystalline st-ucfLure of the compound Ta,:Ga Kr:L.-;tallografiia 8 no.6:921-923 N-D'63- 1 3' (MIRA 17:2) 1. Llvovskiy gosudarstvennyy univei-sitet imeni Iv. Franko. _VVjq)jj9,WTjp)LBD8 AF ASD JD 12 .NR: AP3003479 SOMOA, 3/006' A67 AUTHOR Altunina, L N.jt 0ladY*phevs1dX,, Ye.:I. ZA"6 Kolobnev.. M LM. Mysico-chemioal ancaysis of the e -qt 1~n the. 'Yetem 1Q. 17T jregion of 0-73% by weij;ht of Ge SOURCEI Zhurnal neorggdoheskoy Mlndij v, 8, no., 3.673-1677 TOPIC TAGS: Al, Si, Ce, s-ray analysis ABSTRACT: The joint solubility of silicon.and ceri-j= in.,pluminum a P,tudied. In equilibrium with a solid soll~tion of ~Jio aliz~inum4ba 64 alloy, there is tesides Si and Alj~000 a, owpound jwd 6 siblid: sclti~ tion Iof aluminum in CeSi2. The approx1pate compost .()n-0. p,OMD ov X is si; 35 at. % Al, 45 at. 20 at., % Coe (1 w U... 25:1Wfee) X-ray analysis of the solid'solution Ce (S10 01&ica~e that its structure is related to type Apha-ThSl-j. M mUjh wnteht of aluminum in solid solution C*(5ij.Al)2 is 20-22 wt%. Orig.:~ art. has: 6 figures. ..... ... .. 777- t .1", !It V Li itaI -1 up (4 MW a Ale ION MR s, APW4349i~, -6/0 15~1926:. AUTHORS: Glady*shevsk 1W Y** mevich, 1 V ~ crtti-Ni-si ternary TITLE t systm SOURCEs Zhurnal neorganichele vtt: 8.. n! q: kh a'. 19~ 915-1920 TOPIC TAOS: Cr, Ni, 81,,~Ohromlum, nickel silicon ' tem of;1 ABSTRACT: Authors studied ift~ternary phase equjli~rium ' ndi d~ chrOMium-nickel-silica. Phase equilibrium fi arel ~01 own In. n ' ; a diagram in the form of an, is tfiermal., 0 cross sea M rA of Or-Ni-31 system at 8500:. Authors found that the!& loys 1 ve il three additional ternary systa:ms besides the two i 1.n,'~erPt0tjiljja;,. , ternary systems found previoUsly in'i a the pieswwopl largalii6unt of silica. These freshly4oufid te 'nary systemsAxi n. h1h-T r i t g s 00,66.rm that~ and Ta phases. X-ray and miorostructural metho t e comp coition of the T phase.belongs~to:the stru~ture~oj the' Cu'&- Si type. The alloys containing about 1%'6f,H by,weight M96 28 7 77 ACCZSSIOX M! AP3004349 1 Grji*31 oomposition havis a covqpcfiltio~, correep6nds to'a structwe ot the TI ft or~WaFtscit P11 I' K lat tatit iFlob i d~ t i fo~ th th s' e u o, e ors express . r au r gx py : I:intei-.pretation of the resultB.41 Ori ~rt, hass If igmv 2 J and ; tables. ASSOCIATION i 1,1vovokly gooudaretvenny*y univereilbmi 'im. :T v~~ Franko (Lyov state university) SUBM-TV-ED: 110at62 DATE ACQ: Wug63,~ ENC LI 001 SUB CODE: CH NO REIP~ SOVI 011 OTI Ow.- r 2/42 J' W4tJ -L-14955-63 W(olzaiwitz~s -AMCIW- D/ AMMIM IRS AP3004356. S/0078/63/00$, M~190: AUMOR: Gia"hevskiy, Ye. I.; P2javaj N.~M.j Fedorov, T.~ ;4. MM Wtual solubility of r1rconim, niobium M& hefaium'16 SOURCES Zhurnal neorganicheakoy k~L' V. r 330 "P.To TM: zirconium carbide-aidbium carbide-hafidum phase composition,, orystal lattice, lattice parameter, LU03F ~Wrosti.*Wn. iirconium carbide, nibbim carbida,, h4ftium csibidep Mrconiui 6exbidemploblum darbide-hafnium carbide system,mutual solubility, idree3lupt Mbide-ni6bium oar- bide-hafnium carbide alloy ABSTRACT: The mutual solubility of comlxments of the ternary ZrC-Molm sy" i has Ire= investigated, Alloys were prepared by. Melting of si ered t onsumable-electrode arc furnace in spbe 4 mate 119 an unc an argon Ptao vacuum at 2DOW for 50 hr.. The,x- dIffracti ashowed tbiLt 411 tbrea components have. unlimited mutual solubility. The ldittic parameter indreases continuously with Increasing conteut. ZxC and HfC (see Table I im'd Fig.. I a. -Enclosures). Orig. art. has: 3 figures and I table. Card 1141 SAVITSKIY, Ye.M.; BARON, V.V.; YEFIMOV, Yu,V.; GLAWSHEVS10Y, Ye.l. Investigating the structure and properties of some allaya In the system vanadium - niobium - silicon. TnIdy Inst. met,, no.12-166-178 '63. (min 10".o) (Vanadium-niobium-sili con alloys-44atallography') (Phase rule and equilibrium) Gladyshevskiy, Ye. I. Yu. B. Kuzria, Ye. I. Gladyshevskiy, and Ye. Ye. Cherkanidn. Physicochemical investigation of the Mb-Co-Si system. Title: Seminar on refractory metals, conpounds, and alloys (Eiov, Aprij. 1963). Source: Atomnaya energiya, v. 15, no. 3, 1963, 266-267 kmji-i- jlg!:~rt- - 'T't MOONYWO *Olt 7-71 uw ZT!, F;z T'i AM W th m OF, j; or !T, TR'i FW iii, Ah 6 ~f ]m A W-iiOd ~ID-V- --4 V-P ar Ixom: iM, ite 'Are'vepor, el~ r t Jr. .c sj 0 0 i, J~ :j a M -'HM AT4 y 04810& 00. 17 G V. 10 ~i t d**':' "; -"' d an. iutp~,- 16464 1 e it ra b yll t le 4 a ln P~T.RACT j se r U, n. f sm L, T Ui Inest oal't !-Cbp -,toh!C~4-60~1 illj~664 ro yt,:CiAlangi a 1, 1 OY!, e 'Talto h or 1! r cruci -1 `u* hel i um mi, h4", d t hi ic, #0 c x d a UN46, For SOO. a 2 t A t J1 C., lA ~'i;1 ~6' + 7!7 :j Tt i.' ii , !I I T waimb cat ly r aw ( yii"o At Tom -6 t loft f 'd idra wa#*,c 13C t h appoun S.W , S-" rev ous y ,c S r -0 -1: 'R U N Z t -jv tyiP0 indl j6jjj6-'T:', 10 'a Ulw- fo r 4~p t-t tc uq "A 9, va ups.; o:t m c, r( 1 010;i 1j. INO' 1 ~;:;ji: to I Qne i, !-~,SOOMITTEOI.-, `13Juh 64 v t ~V IN 1j r 6 ~1*_~Z_!f~:,!~ lilt W-8,00gim NRi, Accgmw T ~ -i~ I -P tj A I:y B va 14: 1! Sidthvdt.~i v isooku-obve _V* lit hdnkizh)..~ -qOv6fihchqWyaf,,-~,I MOO:! TOPIG-t-AGS.-ili mi, 0 q 4# V xx a q .0's 71 0 jrhentilm i4ioy,jung~slbin 0461alil- ON 1di 6' 1 ABSTRACT Tble:s!~Oj tobf W X~ lih plrO PIN qarbowolR~ e,pompos. on gn prprm. fiav_-e:~.'r'e'c,e:6d y.-'com e"Intitl wkdespreiidu'sie'llill.- OA OY n M.'s 0. -Wofd I q g at- 2~06, l;~ Ofi.* _;t,-Thd'phiW6'iequwbr re es a. -~r Jd awo 46U_61ii'~'.Welre tbnstrucw.~ W jq'jo e lid the.-sta flitypUtun0beh-thd ufft-,,_eM,. p 01"WA,( e formadon of kL-e`a&6Ide, do;rr,6i V~O:n- tm L v 1/2 Ali z L-238?5i;6 IN, T, to L-48-tWeen':s :T M.. i bib Fv dw COMO= 31RejQ:1w", Id wwaslo'Widl 6 be 16- -ftbx- t "'WiLth tub" u us! lu elk z 14 h- WO--toUd. sclutlOwbas, law I iodo ~-Fiid ~Oob WiAiiipl a F thMA$. Re lt 10 V 2600, ;if it do:; zi:j. ': ~ 1. ": i !,.". 1.1 ~4gH ENCLIl, i 0 Sim Xoomr 4' 6umprTED: ~05A ~ql rf: Qo#~~ f f.o.. it: 4T 1: Jill!, oo w ~/2 it ,aii p EV, 1A x7ts i0 4 61 yo YOU 61 640. i7 SVC tol viegovamove Roves 80,lUURRQC 9W roe -Cl N. Oy rRy str am ~E MMOT tul (C iii iki POU06.4re", to' 50027U: iii. diffeiiededain tWelootrolm, r udol TIOM A ft SUBUMEW Ruc i c0 ' ;V RICT: SOV3 00.9 - I o" ' ij jm~ ........ . . r4 E-W 0 tf ACCESSION NR: AP4012388 3/0021/64/000/002/0209/0212 AUTHOR: Glady4shovs'ky*y, To. I. TITLE: Crystal structure of E)jGe sub 2 SOURCE: AN UkrRSR. Dopovidi, no. 2, 1964, zog-23.2 TO?IC TAGS: metal, alloy. stool, europium, germanium, Eu Go sub 2, X-ray diffraction, c-.7stal structure. Cd I sub 2, Co Cd sub 2 ABSTRACT; The crystal structure of the compk:.,und EuGo. was invastigated by the .,-ray diffraction Dwthod. It was estio:blishcd that this Go-richest compound of Eu with Go has a structure of a now type/spance grcup P3ml D" 1 Da in 1 (a), 'd 2 Ge in 2(d) with z - 0.405+ 0.005, a = 4.102+ 0.003 A, c 4.99,5- 0.003 A, 0/a 1.218/relatod to the AlB2 typo. The symmetry of the EuGez structure and the point . systems occupied in it are the same as for Cd,20 howavor.? in vied of the fact that the coordination proportias of these three structures differ from each other considerably. they should not be regarded as belonging 1-i the sama Card 1/2 ACCESSION M: AP4012588 stractural type. Orig. art. bass 1 figure and 2 tabl83. ASSOCIATION: Llvivslky*y DerzhavrAy*y Univerdy0tot (Llvov Stato University) SUMITTED: 23Fob63 DATE ACQ: o3mar64 ENCL: 00 SUB CODE: HL, EL NO REF SOV: 004 OTHERt 003 COM ACCESSION NR: AP40,14906 S/0226/64/000/004/01.5/0020 AUTHOR: Glady'aiievskly, Ye. I., Lakh, Vj., Skolozdra, R.V., Stadnyflt, B. I. TITLE: A stLdy of Lie mutual solubility of disilicides of the transition rratals belonging to groups IV, V, and VI SOURCE: P!).-ni~',k,iviva metallurgiya, no. 4, 1964, 15-20 TOPIC TAG:)'. ~-Iicidc, disilicide, tranhition element, silicide solubility. solid solution, powder ABSTRACT: At the present time, the practical significance of the disilicitics of the transition metals it; constantly increasing, and great atLention is being given to their invesLigation. Tlic mutual solubility of the disilicides of transition metals belonging to groups IV, V, mid VI his been investigated particularly thoroughly. Thus, of 36 possible binary systems, 20 were Investigated earlier. The present authors have reduced Lhe gap '~still furtherby Invest.i gating the systbms TiSi?, - CbS12'VSi-CrSI2, VSi2 - WS12, ZrS12 - CbS12, ZrSi., - Wsi CbS12 - Mosi P (,bS12 - TaSk, and 6bS12-%VS12, omitting only the scarce disili'Cides 01'hafnium. Radiographic and mrcrographic methods, as well as microhardness measurements, were used. Ile specimens were prepared by fusion of Card 1/4 ACCESSION NR: Ar'4044906 high purity met,11s (content of basic metal not less than 99. 5%) with silicon (99.99k) in an electric arc furnace with a watercooled copper base, using lon-consumable tungsten electrodes and a helium atmosphere, and were annealed at 800C for 1500 hours. Powder- graphs taken In cylindrical chambers (d=57.3 mm) under Cr-K radiation were used for radiographic phase analysis, and lattice constants were determined by the method of Preston in a chamber 86.4 mm in diameter. Samples were etched in miAtirls of con- centrated hydrotluoric and nitric acids. rylicrohardnes8 was determined with a I'MT-3 hardness meter having an accuracy of + 25 daji/mm2 (1 dan/mm2 ~_ 1. 02 k9/mm2). AH the investigated sections MelSi2 - Melr% of the ternary systems Mel - Me II-Si proved to be pseudo-binary with limited or continuous solubility between the silicides. A summary of the results with regard to the mutual solubility or the disilicides is given In Fig. 1 of the Enclosure. Continuous series of solid solutions formed In two of the eight systems (VSi2 - CrS12 and CbSi2 - TaSi2). Like the other series known, these were formed between isostructural disilicides of metals which are very close neighbors in the periodic system (elements of one group, Cb-Ta. or of one period, V-Cr). In die six remaining disilicide systems, limited solid solutions were formed, consisting of non- isostructural compounds. The greatest mutual solubility was exhibited by disilicides Card 2/4 ACCESSION NR: AP4044906 for which the valuea F- 100, TMC1 were the mnallent~ %&,here Y&I,!'