SCIENTIFIC ABSTRACT GLADYSHEVSKAYA, YE. - GLADYSHEVSKIY, YE.

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• Collection: Scientific Abstracts
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• Release Decision: RIF
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• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2002
• Sequence Number: 1
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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Liyli
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GLUYSHEVSKAYA, Ye.j.
MaINOVSKIT, H.S.; GLADYSHIVSKAYA, TO-1.
. -
Thermal d9composition of aromatic hydrocarbons in the presence of ethylene
oxide. Zhur. Priklad. KMx. 25, 218-24 152. (WRA 5:3)
(CA 47 no.22:12276 153)
1. I.Irranko, State Uhiv., Lvov.

":, ~ I v I.-.- V-k-
. .. - ~ , I- . I .
CHXRKLSHIN. Ye.Ye.; GL&DISH M 111T, Te.l.
- ""moo"
Chamical activity of aluminum-mposium alloys. Nauk.zap.L'viv.uu.
9:81-92 148. (XIaA 10-5)
I.Kafedra obehakey L neorganicheakor khImJI.
(Aluminum-Magassium alloys)

CHKMSHIN, Ya,YP. (Cherkashyn, MIA.); GLADYSIMVSKIY, Y9.1. Madychevelk7i,
IE. 1. ] N4AU*WA%MwLzdft4$O
Chemical properties of intermetallic phases. Part 3: Chemical
reactions In the Y -phase of Al-Mg alloys. Nauk, zap. Vviv. un.
13:63-68 149. (MIRA 12:10)
l.Kafedra obahchey I neorganichookoy, khtmii LIvovekog goau-
daretvennogo universitata imed 1. Franko.
(Aluminum.p,Agnesium alloys)

CUMSHIN, YeJe. [Charlmehyu, IE.11.]- G YSHEVSKIT, Yo.l. (FIladyshevalkyi,
"P.,
IE.I.1; KRYPYAUVICH, P.I. [Krypliakavy-a , f.
Chemical properties of intermetallie phases. Part 4: X-ray studies
of extraction residues. Nhuk zap. Vviv. un. l3t69-76 149.
(14IRA 12-10)
l.Kafedra obshchey i neorganichookoy khimii Llvovskogo gosudPirstvennogo
universiteta imeni 1. Franko.
(Phase rule and equilibrium) (Alloys--Metallography)

et
To-
Moo
A%re O't Jrst
-Te -
'606,
GO
'erI
0jr.
SeV
reo 'Ole
tsevos 0l ~te
'ILoe'D,

-*am SMI - ~-
Solid Solutions

I I
GLADISHNVS*,KIT, Ye,!.; YoJ6.
hemical prw~eitj-.,~s of "im
of the reWliao% after
copper and '5~. 0,
1. Knfedra neorganich-.o;,-. khimil.
(magnesium alloys)

tMIR/PbYsics Crystallograpby, Cu4MOz I Jul 51,
"Crystalline Structure of the Ternary Phase Cu4MgSu;P
7"0. 1. Gladyshevskiy, P. I. Kripyoxkewich, M. Yu.
Tlislyuk, LIvov State U imeni I. r,,ranko
ftDok Ak Nauk SSSR" Vol LXXXV, No 1, pg 81-84
WAU, the purpQse cf , investlgatiW -lbo-reletjoir of th--teMM7
phase CuMgSn (found by Gladyshevskiy, Kripyakevied,
Agg~,Y*, Ye, Cherkashin in 1950) to the otherphases
the system Cu.-Mg-Sn, the authors conducted thermAl
4md roentgenological phase analyses, and also inves-
tigations of the microstructure of alloys for the
"ries Cu MgSn-Cu, to find that the liquidus curve
9f. these alloys pass through the max in the c&ze a
24TI-00
coupt close to Cu4x9Sn and temp-r50+100,
ahown to be homogeneous'according to the microstruc-~
tam. Give results of roentgenographic studies
Of pwdered Cu4MgSn. Submitted by Acad D. S.
Belyeakin 23 Apr 50.
224T100
U3

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. I - ;- aR '-- --- -- -

GLADYSHEVSKIT, Ye. 1.
Dissertation: "Solid Solutions an Bases of Aetal Caai -"'~qpm LIvor
State U, Vvov 1953
W-30C)28
%k)'. "kele'raAaM ZhArual, No- 5, Deo 1953, Moscow, AN W;SR

G1, ~T V_~ H E \/!~~ ~ ~~ ~c, I,
USSR/ Physical Chemistry - Thermosynamics. 7hermochemistry. Equilibriun. B-8
Fhysicochemical analysis. Phase transitions
Abs Jour : Referat Zhur - Khimiya, No 4, 1957, 11162
Author : Gladyahevskiy Ye.I.,_ Cherkashin Ye.Ye.
inst : L'Vov University
Title : Mutual Solubities of Nickelareenide Compounds NiSb and N'3srL2'
Orig Pub : Nauk. zap. L'v-ivs'k. un-ta, 1955, 34. 51-55
Abstract
Using the microstructure method, x-ray phase structure analysis and preci-
sion measurements of identicity periods, the authors have investigated the
system NiSb-Ni 3SrL2, characterized, in contrast to the prey-iously investi-
gated-,L) -compo~mds, by different content of transition metal and absence
of continuous solid solutiona of the metals being substituted (Sb and Sn)
in the binary system. Alloys were produced from Ni, Bb and Sn and were
then annettled for 40 hours at 600P followed by hardening In cold water.
There was ascertained the formtion of a continuous series of solid so-
lutions with replacement of all Sb atoms by Sn atoms and additional in-
corporation of Ni atoms in the NiSb structure.

U Y -_D r, t- V -)K I
USSR/ Physical Chemistry - Thermosynamics. Thermochemistry. Equilibrium. B-8
Physicochemical analysis. Phase transitions
Abs Jour : Referat Zhur - KhimiYa, No 4, 1957, 11182
Author : Gladyshevskly Ye.I.,- Cherkashin Ye-Ye.
Inst : L,vov university
Title : Mutual Solubities of Nickelarsenide Compounds NiSb and "'3Sn2'
Orig Pub : Nauk. zap. L'vivs'k. un-ta, 1955, A. 51-55
Abstract : Using the microstructure method, x-ray phase structure analysis and preci-
sion measurements of identicity periods, the authors have investigated the
system NiSb-Ni3Sn2, characterized, in contrast to the previously investi-
gated-J -compo~mds, by different content of transition metal and absence
of continuous solid solutions of the metals being substituted (Sb and Sn)
in the binary system. Alloys were produced from Ni, Bb and Sn and vere
then annealed for 40 hours at W follaved by hardening in cold Vater.
There was ascertained the formtion of a continuous series of solid so-
lutions with replacement of all Sb atoms by Sn atoms &nd additional in-
corporation of Ni atoms in the NiSb structure.
Card 1/1

k, rI , U 7 -0 n L_ V -) K I
USSR/ Physical Chemistry - Thermsynamics. Thermochemietry. EVilibrium. B-8
Physicochemical analysis. Phase transitions
Abs Jour : Referat Zhur - Khimiya, No 4, 1957, 11182
Author : Gladyshevskiy Ye.I.,_ Cherkashin Ye.Ye.
Inst : L'VOV university
Title : Mutual Solubities of Bickel.-4-senide Compounds NISb and N13sn2'
Orig Pub : Nauk. zap. L'vivs'k. un-ta, 1955, 34, 51-55
Abstract : Using the microstructure method, x-ray phase structure analysis and preci-
sion measurements of identicity periods, the authors have investigated the
system NiSb-Ni3Sn2, characterized, in contrast to the previously investi-
gated,x) -compofinds, by different content of transition metal and absence
of continuous solid solutions of the metals being substituted (Bb and Sn)
in the binary System. Alloys were produced from Ni, 8b and Sn and were
then annettled for 40 hours at 600P followed by hardening in cold water.
There was ascertained the formation of a continuous series of solid so-
lutions with replacement of all Sb atoms by Sn atoms and additional in-
corporation of Ni atoms in the Ri-S~t dtructure.
Card 1/1

I-,j .9 . V 7 -_D M L V --')Y\ I I ~ ~ C , . _L ,
USSR/ Physical Chemistry - Thermosynamics. Thermochemistry. Equilibrium. B-8
Physicochemical analysis. Phase transitions
Abs Jour Referat Zhur - Khimiya, No 4, 1957, U182
Author Glady8hevskiy Ye,I.,- Cherkashin Ye.Ye.
Inst L'vov University
Title Mutual Solubities of Nickelarsenide Compounds NiSb and N13sn2.
Orig Pub Nauk. zap. L'vivs'k. un-ta, 1955, 34, 51-55
Abstract Using the microstructure method, x-ray phase structure amLlysis and preci-
sion measurements of identicity periods, the authors have investigELted the
system NiSb-Ni 3Sn2, characterized, in contrast to the previously investi-
gated,J -compounds, by different content of transition metal and absence
of continuous solid solutions of the metals being substituted (Sb and Sa)
in the binary system. Alloys were produced from Ni, Sb and Su and were
then annenled for 40 hours at W followed by haxdening in cold water.
There was ascertained the formation of a continuous series of solid so-
lutions with replacement of all Sb atoms by Sn atoms and additional in-
corporation of Ki atoms in the NiSb structure.
Card 1/1

~7 11 ri -1) 1 -7D rl L \1 __)K I '1~ ~ C ,
USSR/ Physical Chemistry - Thermosynamics. Thermochemistry. Equilibrium. B-8
Physicochemical analysis. Phase transitions
Abs Jour Referat Zhur - Khimiya, No 4, 3-957, 11-182
Author Gladyshevskiy Ye,I., Cherkashin Ye.Ye.
Inst ---L J-Vo-v -UnUiers fty~
Title Mutual Solubities of Nickelarsenide Compounds NiSb and N'3s"2'
Orig, Pub Nauk. zap. L'vivs'k. un-ta, 1955, 34. 51-55
Abstract Using the microstructure method, x-ray phase structure analysis and preci-
sion measurements of identicity periods, the authors have investigated the
system NiSb-Ni 3Sn2, characterized, in contrast to the previously investi-
gated J -compo~mds, by different content of transition metal and absence
of continuous solid solutions of the metals being substituted (Sb and Sn)
in the binary system. Alloys were produced from Ni, Sb and Sn and were
then annealed for 40 hours at 6W0 followed by hardealng in cold vater.
There was ascertained the formation of a continuous series of solid so-
lutions with replacement of a-11 Sb atoms by Sn atoms and additional in-
corporation of 411 atoms in the NiSb stnicture.
Card 1/1

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sit
al

V6.1-R/Chomistry - Crystallography
Csxd 1/1 Pub. 22 - 24/53
Authors I Gladyahevskiy, Ye. 'Z., and Kripyakevichf P. I.
Title Arrangements of Cu and Mg atoms in the CuMgSn strLicture
PeriOdiCAl t DOk. AN SSSR 102/4, 743-746, Jun 1, 1955
Abstraot t It was established expertmentally that the tribl~ xetalil~ CuMgSn do:ipaunA
n t q)b~nd
belongs to the CaF structural Type and that tibe ~~b at(MIP i, his aft
2
occupy the cifoical vore- dense shells and the Ott, M1 M19 *i.;Dms are arkangod
in the tetrahedral vacuum. The determinaticn Of the Qlto~i pdsiticns~ in the
structure of GuftSn was made forthe purpose of Oomparl~j with, the
tural ABC types which are derivatives of Oft." tn ad6Won to:th a Oam;
arrangement the authors also determined,th fe~ span Ofithe crystal'.14i-
tice for the CuMg3n system. Six referencest :4.be~man! FmAish q!O 1,
USSR (1937-1952). Tables; diagrams.
Institution The Iv. Franko State University, L'vov
Anademician N. V. Belov, Decembor 24, 1954

KRIPYAKHVICH,.P.I.: GLADYSHWSKIY. Ye.I.
Crystal stni-Auro of JrB812, VB812 &nd IffbBe,2. Dolrl.All SSSR JCA
no.1:824W S '55. (KW !1:2)
l.L'vcvukiy gesudaretvn4nyy universitat imAnt lv.lvrttnko. Prod-
stawleno akademikom N.V.Pelvvym.
(Chromium-ber7llium alloyi.)(Vanadium-beryllium allorv)(Iliobiun-
beryllium alloys)

mist-c", PI-I 110 C.
USSIVPhys i cal Ch~.,' - - - I, n~mi ~iQ
Equilibi-iLuns, PhjL;-.Cn(2ri. .'In-Ll.
Yobs Jour Ref 2,hur - Paii,liya; 11z) 7, 1957, 22-,11,.
1 1- F. Chermshin.
Author E. 1.
T _4 t 1,2 Solid c3olutions on the Pkime of Aetalli-c ('j:,IpounCI,-,.
1i i, IL , rub n. n2uv:~an. !()56, L, Ile 6.,
Formation conditions of solid sc)".~t~ons of Una 'ril comporll.'Ilt,
in bin-ary i;ictailic conpounh ur(! ;xtu,,uxled on the basir) of
literavy ili,Aerial and ~xperiinentnl duta furni~:had by
structural und micro:;tructuval analyst2s. Solubil.itlf of metalti
was studied in metallic com-;ounds cif Uie ~Iglm, (stvu.,.-
tu.,e 0~, nd MGCu2 tyPe), in clectronic corapaunds
(s Lructure ofX -, nnd ~ -brnoses ilyp~), in nlck;ul-fir:;t~ni""!
couipoumh; of Cd12, tIIA-c -riA iii-dn), In sillcidl;!ti ind
in somo Lia4ruple. alloys. ~- serie.-3 Qf new cuontA`num; Solid
solution5 -Aetallic alloys mas fuim,! nd their struc-
tllr~-' I.W.S ~*;olubility of mn, i*l, S)n ind ,:,I) in
111'cu, is ltmit,~k~ 'L)~, ,I maxiinux, ele-.,-Lronlt~ coaceulvati,,,m, ~Aiich
for zillInG till! t' I's(, Of N9CU2
card
Card 2/2

Rpm
x~- i, -
FL7- 1
7 "i
..........
r 1
7!~7z 7~
-L~ c~
Lj-
77,

USSII/ '11i ermcd, iirurd,, Thcrmoch:_~ir..;..Oxy. EquUibrja.
Mysicai-Cher-ical. Anal~s_Jq. Phwie Transiti.civ;.
Abs Jour R(~fera,, 2hur Pir) 6, 1957, 18505
Autho r Ye.Ye. Cherkaohin,,Y&,,j. Gladyshey,~kIZ, M.Y"'I. T.::31yuk.
1rist. I115titute of Organic a~_d-rn-oreaniE chemistry of jicaiemy
of Sc7ericos of US61R.
T ~. t1 Study of Sy-,tcm Copper - Magnesium - Tin in llani,-e of CU
CUAS - CuMgSri.
Orig Pvb Lw. Sekt,)ra i'Iz,-khJm. anallIza IOM Xi 27,
Abstract -The stvicture of ailoy," pertaining to the _iysten Cu - 'Mg
Sn was z5tv.,iied microscopically and roentgeno;-;ra~hically.
ar-_, hoin
~~he cross-section Cu2t",cl - CuMp,,n ge-
tht range of 0 to 15 at 4 of Sn; alonr, the
c:,, --section (:~i2Mg - Sn the maximum solubility is 12 at
'D f 3- Tb(! lattice spacing rises in the i:ivst case
from 7.020 to 7.248 kX and to 7.1"77 M tn the ceccind.
Card 1/2 - 185 -

6-
kUTHOR: Gladyshevskiy, -Ye I.' ana KriDvakevich, i.l.
,TITLE.- Tile Crystal StrucLures of UIle Compolln(is III(I-11~ej,", IVBe
LA n d Ta-B e (Kri~;tal 1-ic I ~ e i 3 k, a y as IL r u k f~ U Y' NE' (L II E, I I L Y
MoBe 12) VIB e 12 a~iid TaBe 12')
'3ERIODICAL: Kris Lallo~ rafiya, /45
VO 1. L', 11
(USSR).
ABSTRACT: Be forms com~,,ounds of Lhe ThIn 12 type Cr, ,,' aiid !4b.
An investigation to See whether there we-re aralc,_~:(Dus compounds
with Mo, W and Ta has been Made, The existence of a comi)ound
of Mlo and Be wit'L a composition about I.IoBe 1~ anL'. a ~etragcnal
unit cell (space group P42) with, a-=10.2'/ a_nul cz:4_20 _131 a-nd
Z~4 (S.G. Gordon al. , J. Lie;,_als, 2, 6,J)'t , -waE 'Omown.
The com-pound i~IbBe with aad c~4.24'/ EX ,vas also known
(Dokl.Ak.iiauk SSSk~ 104, 32, 1~~55)- filo was m(-ILe-J. vjith Be in
u
a BeO crucible under argon in ail Ej. iuri~acc Fj.,-id tj'he, resuitirE;
allo,y WP found to contaia 1)2-5 atomic I/o' of Be. IL tva.,~ aineaied
at 400 and on q 'uenchinK was foumi to Lave ia
Structure. Iileasur-ri:ents of an X-ray powder
(5'/-4 iiiii dia. Cal-iiera, unfilLered Cr j'I-I,I'Ii;I.TJ~)jl')
Cardl/~ CoTil m-,-rcer.,-.ents of ThbIn shuvj." i.!I~ve ,!!is
parison wit'n 12

t2
The Crystal Struct(ires of tlle Compounds MoBe ~XT ---nd. TaBel-
1 121 1
structure and therefore t~`ie f,~rmuia, MoDel-,- ~~L.e ceLi
are a~7.23'/ + 0.00L~ ai~.,; c = 4,253 + 0.002 E-1,
were calculated for a strurtitre ut' tiie TiAltil.) L" j"-aoe
lVaut"m "Vitil .2 Mo ill (a). 6 B~-, in (t) -z"itL
x=0.-)61 and 8 i3e in (j) wit!,- ai-~i ver,-)- E,D:-,,~i a~-ree-:-.ent
ith the ex-,)erimientaii data wa-- foLind, S i c ti,*~: w~
w e as dD.-ie
Raeuchle and Batchelder (Acta
were found to have obtained exactly simil,-t-T., 1 e
compound '.'/Be 12 wa6 similarly prepared a--- wa.,: TaBe 1 and tlieir
unit cells were found to be a='~.220 + 0.004, c:=4.224 + 0.002 ia
and a='~.322 + 0.004, c=4.24'~ � 0.002 KX, ire-,
The
ThMni, strucTure is tlius foLind for tiae compotuno,~. of V, 11'o) Ta,
Cr, Lo and W with Be. In tl~e Mo-Be and W-be ner
comDounds richer in Be ts",an MoBe (abo~i-~ "'S Be) !,.(Ive boon
found whicli have cubic-face cen4~'d cells with ~%=11.60 and 11-59
KX respectively. I.V. Emol'yaninov particip;~Le-d. in the %vork.
There are 2 tables and 4 ref erences. 1 o i-_ Slavic.
ASSOCIATION. Ivan L,-ranko State University, lkov.
t-'.,-ird 2/4- (L'vovskiy Gosudarstveimyy 1. Franko)

1371-58-5-10--112h
T-;-anslation frorn~ Referativnyy zhurnal. Niutallur.oiva 1);8. Nr 5 p 2 3 i I USS Rl
AUTHOR. Gladyshevskiy, Ye
TITLE~ NIlItUal Solubility of Electronic Compou.nds in Siker Aliov~! %%i,~
Cadmium and Zinc (Vzaimnaya rasworimont eleklroritividl ;o-
yedineniy v splavakh serebra s kadrmv ~ni . t,;wkoni,
PERIODICAL: Dopovidi la povidomlemiya. un-t. Nr
Part 3, pp 190-i95
ABSTRACT. Metallographic and X-ray nivtllod~ iiri:- ernploved to
gati' tile 1111.1tual solubility cit 3 Imir-, ot illc"1111(
C0111DOLIMIS. AgZn-A~;Cd j-'d '% /I,, -A ~Cdj ob-
taining in an Ag-Cd-Zn system. E%-z!minii1ion I- w.t ros
sec tions ot tile sys'em 11, ( Ollipwsil lorl~ " or rc~porld ill,,, it) III(-
thi-ciretica I va lue., of vlv( "rollic ( ol"t I-lit rol~Im- I! SOO silt[ -100
Th(- ~J [IOYS '.N Crt' Illadt' Of t 11011II(Itt Ity fILLI-C Is Ill , C rzkr-lll,
c r ut ib I e~, und e r ( I rna I I it c . I rif I tAv ru it it iiv,i I ed to r 100 IIQL1 r
500 and 4000 \~ ith substiquent quem hing lit ki-ocr Pha.;L'
pcz-fornied by the pwxder niethod, Ve irrodizs!ion. A-
5000 there I,-; a C0171111MOLIS 5olid solillim, hetw-,en tile ~~ electrollic
Card 1/2 compounds ol ApZn-AgCd. When Temperciturt, \vii~; rk,dut ed 10

137-58-'1 !Q5Z)-s
MkItUd I SOILIbIlIfy of Ele( fron-f I. oil!
400' C L1 b tc A g C drat: -; 4o I III ,I'I,,UlIe 1, , t1d III "..id o: , hi, ~ (.It, * ~1100kl-; -ulki
, Ion there appvo r~ I limil rd ow,, I - pp\ '0 W 110111"L t), Cd 7v AoZn. I ht-
SOILIbIlIty O~ Z11 III .~"Cd
I on-1v -moi Iv I , Bt-l\t con Ag; ZrI8
and A95Cd8 1hcrc ;i toil' i- iwi- ~ukd ohil :ori ~, I -";I floll".. J, -I
I ~, c on fi rr-n ed t) y-I-i I-) o ~ 1,%I !ImWI I I I'Oll4o111 L' 11 1 T.A 11 7 ~ 'I ') y ~I ) II I I e
Ag Zn 3- Ag Cd j I on c. It, ~t.hm I I 1 101 1. , III-) , III-' I,ttou- ioti(i
o k J lit- I 1i %e -!c,lwJ III
the h1crawre d,i,ii . 1300.og r.ipfiv 21) rcl,i n( i--.
Ca rd 212

137-58-5-10414
Translation from. Refcrativnyy zhurnal, NlCtiilkirgiya. 1958. Nr 5, p ~' 18 (USS R)
A UTHORS: Cherkashin, Gladyshevskiy, Kripyakevich [Chcr~ashvrl ye.Ye.
Gladyslievs'kyy, Ye.l., Kryp"yakevych, P.I.]
TITLE: Compounds of the Transition Metal-,; With Beryllil,1111, sillcon
Germanium, and Tin (Soyedincniya perekhodnykh rric,allov
berilliyern, kremniyem, germaniyern i olovoni) t Spoluky
perekhidnykh metaliv z beryltyern, krenintyk-m, t,,crmam\,cm
i olovoill ]
PERIODiCAL: Dopovidi ta poviclornlennya. L'%,ivs'k. un-t. 1957. Nr T.
pp 180-183 (in Ur-iniro.)
ABSTRACT: An investigation is made of binary and ternary sysferns (Nin
Cr, V, Nb, Mo, and W with Be; Co+Si, Nt i-Si. Co lGe. Nii Gc.
Co+Sn, and Ni+Sn with 10n). X-raV and 111iCro4,Tructural analvl,-
were mad,.-, rel-,UltilIg in the discovel'y Of 1-7 11L-W % 0111j)0%1Mk Mid
determination of the crystal sfructUl-eS Of 14' Of the-C. (See
Tableon Card 2)
Card 1/2

137-58-5-1041-i
Compounds of the 'Transition (cont
Compound StrUCtural Tvpe syngoti~, Lathcv periods, k~
Mn Be Md C11, C (11) 1,-
Gr Be I M n I V I' t 1' A I,' )11,A I L S
MO Be 7 -10 -1. 8 0
V BC12 7. 2 5 1 -1. 8 o
Nb Be, 2 7. ~~i7 7
Go, Mn Si CS CI 2.827
Co, Mn Ge CLII Mn Al 5. 7-
Ni ) Mn Ge u 8
GoZ MnSn
Ni~ Nin Sn
?Vln3Go3S',' &'d Z11.' Hexagotiol (-x 58 , k 7. 4:~,!
Mn3Ni3Si
7;2
7.402
IvIn and Be form coupounds of variable composition MnB(~3 3 vith a %t:de
interval of homogeneity. The COMpOLInd-S CONInSn and Ni )MnSii li:ive
points of 950 and 10500C, respectively. and -are fcrronla~~'nct;t
1 uherr~ical
Ca rd 2/2

. ., , . I ~_ I . " - -r
:- ~ -, 1 -1-1 1 .
, - "'1i1 , : ,.v
KRIPIY~KEVICH, P.I. [Kryptyakovych, P.I.'j; GUDY-);fP;ITSKTT, TP.T.
[Hladyahevs'kyi, E.I.]
X-ray analysis of chromium-beryllium 11ol- .ri- , --rcentage
of beryllium. Dop. ta pov. LIviv. mi. iin,'I' pt.3: 157.
" IPA 11::~)
(Chromium-boryllium

CHERKASH111, Tnvgfiniy dotil-l-at. atv.
refi.; 7,1,;'!:')KoV, V.S.. rAd.; ';A)?Ai R, T.V., t-khrod.
rmntric mnalysig of chomic;,l Hquillbrium dinrramn nf system
contnining asqnctntod comi)onnntn] Motrika ravnovesimi klilmi-
chenkol dinprtimmy siqtn-i ti assotniirovannyml komponontioll.
lzd-v~ T,',,nvqrnrn univ., !958. 106 p. (MIRA 11:12)
(Syatems (ChRmintry))

AUTHOR - Gladyshevski.,-,
TITLE: DISCUJ31uli 0:~ Lectm-f
PEHIODICAL: Zhurnal V,)l 3
pp. 6135-St'l (UjL~R)
ABSTRACT; The 57
repor,"
h at
offered himself and I I
X-ray stru~--tul-%l
thu
T1,3ir aim wao to tjjtj -_j r I j
r St !L
TaNi3 and t0 .;t u~-.t,r,2 fjC
they had v, i::vv:ii,-;-te t,.Ir ,i(*:L(j
z3 ~~ ~ 11 ti t
NbNi3-TaNi~as a:] af ;I ~
1;v
of which i's ~o bc f6U1-1r,1 Ill t1le Mi
These alloys wc- ro 1,1 T-~j h
u c
-fre::U,ricy stove rhcrmal tr':~atmenil o f ii LO h, ~111: 0
homogen4zinC blirninr "It )',loo" ciliis,- h e
homoEenized allo,,, v-re ')urned ~'.OLL- -Ill ~i
aml~oulc- at 10000 and tilen
Card 1/3 way viere

Discussion on Lecture.9
analy s is The
do not indicatp in th,~ llexa-c-nal the
c,)mi~ound dov- nc,T to the tvj- 'If". `:-iASn or Ti-'i-,- Ths
arrangement of lines on thin ;:,.:i the-r-
intensity curi-co, und to th,,-E3t~ E~-Z,o Por t'he
type ~-TiCu (witii ~--dered atc:i~ic Tl,.u-- t.,itz
data by K~,..rluoon -ire and T~6,i
are o f t ,, e s a m e E; t ~-u c T, u r e a nd b t? 1 ri t~i
0 t 1) lcu;
,jujt Ls 1 -ts ~he :~iilt,,rilarv al 1,D,
(rhombi-~; syng(-*- )
Finally the pr~)Ileul of Ti:ll- com
and its relati,~n to lljlTi3 and T~L'.', t.,-, bc--
When t h c. da t, a e L 3 t i i 1,7 i? S (~ 11 t "'. e ~l uc U ~2
of TiNi a-e r4 cht l'o r c, i f t nt.i r,,L, c u ~3 s(~ r,. e --3 c
soild shuti,ns',1b!1i',-Tii.'i !"-,d T:-,I,'i Til,-L- siEias
1~robable and should 1~e ,;hedkc-d exa!FTS A
narrow heterogencus doiaz,ir-, b--t-ni~en fh,~m, ('~~sos kii-wit
where the heteroj;erious domaan co-ild net 1,-! found by iaepnr-~
of the j;iethod of .-.iicrojtructit-l- 'but wliorll L!~ Via,z
by means of the x-ray :,tructurv; Tho
speaker hopes that it will be lozisli'le, to ~lm t.-
the x-ray sti-licturai :-,f "'Ie ?[..
Card 2/3 Ni- Ti-Ta -Nb in tli(! alloys, , r-.j ~ uced 1. -1 --)v a ad

Discussion on Lectures
Ye. N. Pylayeva.
ASJOCIATION: Gosudarstvenriyy univeruitet im Llvvv
(Llvov"tp-te UnivQrjity imeni Fr-anko)
j
Vil -., ;~, - / - I
~ j 44 4
Card 3/3

17/47
AUTHORS i Cherkashin, Ye. Yo. , Gladycjhevskiy 'ie,. L, KripyakevIch
P. I~ , KuzIma. Yu,
TITLEt X-Ray Structural Investigations jf St-:.ie 5,;ote--ia of Transition
Metals (Rentgenostrukturnoye issledovaniy:! ne'.:Jtovykh sistem
perekhodnykh metallev)
PERIODICAL% Zhurnal Neorganicheskoy Vhim, i 1 9118 V.j-. 3 Ni- i pp .11-50
(USSR)
ABSTRACT: By the X-ray structural method alloys -in the followin,3 systemg
were investigatedt Mn Be Or Be V No De, If Be Ta - Be
I*b-- Be , Lin- Fe - 3 i- Mn , Fe Sn , An C P3 i.7n Cc- Go Mij C,) Ni
?,in-Ni -Si,, 11r, - Ni.- Ge ; Un -Ni .,'in, 1,41 (" 11 !3"1 ';;-1. V-M
Zr-Cr-Ni, ',,r -1b -11J., Zr- Fri Ni Zr Co fl i
By the investiagtions of the systems the ~ol`owing now c;om
pounds vrere determined which occur at 40 0 6C1
MnBe 8 (at t - IIOCI0Cj the compoBition is UnBe 3 13 ' f the type
IIgCuj , CrBe (ThMn VBe~ -2~ Nb3e, . (Thlin
4. 12 12) 12 ( "'~tn ,.,) 12)ln
NbBe NbBe MoBe WBe CO MnSi (Cf3CL) '.An CO 31
Card 1/2 29 5 1 24X. ' 12,~x 2 .3 3 2

'P~ -.,') 3 17/47
X-Ray Structural Investigations of Some Systems of ~:ran,41 t.i:-.in Metals
(AgZn2) , MnCoSi., "In 12 CO3S15Un .3 I'Li3Si., (b1g7n 2) "'n"' S'
CC ItnGe (Cu MnAl) Ni UnGe (Cu MnAi)
2 2 2 2 ~c litf-3r. (CU 11nAll
2 2
Ni 2MnSn (CU2',,1nAl) ZrUnNi (11t,,Cu," z V~iNl I (Idgcu')
in the systems Mo -13e, V Be and Ta Be c-xii,;,,juz,ds with a
tetragonal structure occur., The compos.Lt;t~,n determined
for the first time is the fc~lovvtngR rdol3e., WDe 12 and TaaB.,2
All these compounds belong, to Tne type &"Irlj9 In the
system Un.-Fe-:3i the following scl-id occari
Mn3Si and Fe 33i" In the systeal b1n 'Cc S.1 ")olid 130212tic'11
of cobalt and silicon in P Mn occur anti oolutions of cobalt
in Mn Si 3 and Co in MnSi.. In the system Zr Fe Ni a solid
sol--Zon of Ni in ZrCo 2 occurs-, Tn the system Zr- Co Ili a
solid colution of Ni in ZrC.D,) o:-,curfi, ~hijre are ' f1gure
and 11 references, 5 of which are Soviet-
ASSOCIATION: Llvov3kiy Uosudaratveiuyy universitet i:.'1 , T,. Wranko
(L'vov State University Lmeni I., Frank,))
SUBMITTEDs June 25,, 1957
Card 2/2

AUTHORS-~ Py!.iyc,-,;-a- Y-3.N.. Y-.1- 78-3-7-28/44
--------------
TIM-D Tll.- Crj- t~k.'j -f ~rii! Cott , 0 N" Nb ard Ni Ta
;1 3
Ni ~if~ -- Ni Ta)
1 3
C)58, vo
.3, Nx- 7, pl) ~626--!631
PERIODICAL;
(USSR.)
Lim'
ABSTRAM M~
ct vrith respa;.-,~,
Tht- rls-ill-twi Obt&in-O
&M N-'3T& 'bA,',..;,rg to the strac-.,aml
~,ypt T*tj=l of' atomi Ls the follav-
2- Nt, Ta) In. Z,
I
N, -n W t~ Nl~ Jn (f) vr-ili x Zf
f0. K*jfft are -rro folloving,
0
car-3 1/- N~,v 7',-t f oll,~,Trs;

Tht Cr
14.-jr
,,v3 t-- S w !8-3-7 '28/44
and NA-31"
5 - 0 9 .66 .77,
TO, N~, rv-.3 W k la fot-im cork of
T a x
S
ASSOCIATION; Ir... A.A.B:),vb.. AkaAem4. SSSR i
r,,!LW(
It:, C hl-a (,-i, A.A.Buyk~,- AS USSR ind Vvo--
S * -I ur I. F
SUBMITYED, j ? ~9,
3,
ra n 4- interrnotp-!
cm-j ~/ ~',

AUTHORS: Gladyshevskiy., Ye.1, and Kuzlma, Yu,3, i,()V/21
TITLE: A Roentgenovraphic Structural Investigation of Vanadium
Germanium Alloys (!~entt;enostrukturnoye issledovaniye splavov
vanadiya s germaniyem)
PERIODICAL: Dopovidi Akademii nauk Ukrainslkoi R'31i, 19513, Nr 11,
pp 1208-1211 (USSR)
ABSTRACT: The authors carried out roentgenographic and metallographic
investigations of th,~ seven alloys c,f vanadium with i7erma-
nium containing from 29.1 to 83.5 atomic per cont of' vana-
dium. The alloys were obtained out of 199.9:'~ pure vanadium
and 0,9,-7,t pure germanium. The existence of a new comoound,
was establisned~ This comDound has a structure of
V G
Re !. n5S'3 (lattice constants and other characteristics are
%
as follows: a 7.280 -~ 0,002 kX; c - 4~960 1 0.002 kX;

Ge ~ o.61). quickly cooled alloys,
' = 0.676; xV 0.25; x In I
7T
the compound V5Ge3 exists in equilibrium with ;-ermanium and
the compound V Ge. ?.I, Kripyakevich participated in the
'
g this investigation
discussion of ~.Ie problems raised durLn
There are 3 tables, 1 traph and 4 references', 2 of wh1oh
Card 1/2 are Soviet, I Gerwan and 1 unidentified.

SOV/21 -58-11 -1 7,h,,'
A iioentgenocraphic ~;tructural Investigation of Vanadium - Germanium Alloys
ASSOCIATION: Llvovskiy gosudarstvennyy universitet imeni Iv. Franko
(L'vov 3tate University imeni Iv. Franko)
PRESENTED: By Member of the AS UkrSSR, V.N. "~vpchnikov
SUB1,1TTED: May 19, 1958
Russian title and Russian names of individuals and institu-
NOTE
tions appearing in this article have been used in the trans-
literation.
Card 212

GlJkDYSKHVSKlY, Ye.I. [IlladyahevaNyl, DC.1.1; KM'MA, YU.B.
Crystal stnicture of ternary, compoundn In the syntens Co - No -
Go and Ni - Hn - Ge. Na:nk.zap.L'vIv.un, 46:115-117 '58.
(14IIbl 12:7)
(Systons (Chemistry))

KRIPTAK9VICH, P.1, [Kryp ,lakevych, P.1 ]; GLADYSHEVSKIY, Ye.I,*'-
I.
[Hiadysheva 'kyi, ili.I.], VALUTSLY, Y.T." Milli.s't v,il r. 41-pri
uchastii studentok: TICTI)OKIANK0. V.I. [Ilvdo"enko, T.I.];
BORUSEVICH, L.K. [Borusevjrch, L.K.]
Crystal structure of the compounds ZrH1 40 ZrXnNi, and ZrT0:5Ki 1.5'
Nauk.zap.L'vjv.-,,n. 46:118-123 '58. (HIRA 12-7)
(systems (Chemistry))

G ILA DY -0 H:,,V FK ly- , Y e . IRiPlYkK~~1IC,1j, 11. T. Yu. '-I,.
"The -Irystal Ftructure- of fernar%y Compou.,A!F In the "?,y6tems
and Cr--Co--'-i"
a report presented at 3yirposium of the InternatLon-al Union of
Crystallography Lenin-rad, 21-27 'L-),Y 1959
u

AUTIIOR- Gladys~.evskiy Y I
IITLE, The Cry!7talli~rje s F, S 2
and CeGe2
BaSi2 7- CoGe9,
PERIODICAL; Devov'Ji Akademii
'194 2T7
pp ~ --
ABSTRACT: The author !Al': o I th'~
c omoound BaS I and 12 s I L i x r .-i i id L
z~tructure of
he
a 11 e
me
, a 11 (j.,rr a ph i
I D -~y c bar -
ium and Lri -'In, if-.
w ~! -
porcelain cru4bie;i t.'C' EIC,
C'f'

I pu--2 ~-11
pure barium anc
f1. - t-i dthe

X 4 S
i tence of compound BaS.,, Th~-s
e

s --f ay
has a metallic shlirmmer arid-erisfly c, x--,,1--'17.?,,- in h;---
air, G' r4d constarc~ are
0,01 kX; c = 4-82 0,0-- 'r,XI I , ccord-
ing to specific we- ght i D c
Card 1/3 n1lulbor. of atol:Ji:

The Crystalline Structure of
~'Iiis 'ac to r , tne ~-lczthcr pre F,- -`--a ,,om~ounj
B;,,, Itas a i7itruclure or A'7B The and
atolule dat'l ave owfl irl I'-
the intermotal"ic t~-ompnurid ("u,'(w. IL~-, prov-
e, d ,I f, i- s, i n eq u i I i 1, v i t t m 1~~/ 1 t. I I tl, o~lvI 1.:~ ru c, -
ture of the a-ThS41. 2 type -::h;,-I,e a .'I )Of',
c, = 1-1 ~ 153 0. 005 kx . ca 3" 7-' Cj TILE,
p 0 E; i t i on 0i ts, I I t, a 11)
ZGe = 416, ConapomAs CeCru f-ri-. ic tl*,'!,U.,.l#
with -Prma,-4.um, n t,: ra f on d I n I - ~, ~xa -
mined structuret indic~iz- -F ~, z - ~)~
connections -mith an,~ v:--ith
atoms of -(,rrran*L= in Cr-Ge, !,t tInk, en~l of ~4rt;cle
the author nresents lii~- 1' k
vich . for his cantributiQn :c thi,--, s, tu(-,.y 1-11t:re art.
4 tab-los an,,! 1~ ref~lrenic-z- q S,:) ye t
and 2~ Ger,-,an
Card 2/3

of the C E3
The Crystalline Structul-
van
v o v S'K i
rariko
AS60CIATION: L~
S t. r
1 nr Y C
P R E S E 'i I TP E DOctober 11,
A,b Ukr6~~ia
Card 3/3

'A S/07o/6o/oo)/oo4/oo5/o.l'_,
'~ . woo Et32/E'i6o
AUTFORS: Gladyslievskiy, Ye.I.. and Kripyalcovich, 11.1.
TITLE'. The :rystal StructurePof the Compound U Ge
PERIODICAL~ Kristallografiya, 1960. Vol. 5- No.
pp. 574 - 576
TEXT-. Two compourids in the Li-Ge system were discovered by Pell
(J. Phys. Chem. Solids, 3, L-2, 74-7, 1957) - "L14 G e " a ad LI P
0 0 0 0, spectively.
with m.p. -750 + 10 and 600 + 1.0 rc
Cryst allo,~ra phic -cons i di erat ions si-iow the correct formula of them
former compound to be Li 15 G e'l,X-ray povider photographs were
taken of alloys containing 14, 17, 20, _13 and 25 at~ !,I Ge, The
compound with 20~,, Go was shown t~ be a MiXtUre of Ge and "Li 'I Ge4
This compound was cubic with a :-- 10~761 -, 0.00-2 I~X and inviteti
comparison with Cu 15 sill (a = 9, 694' KX) and Na 15 Pblf (iA = 1.3.29KX)..
Intensities were calculated with tiiiiE; structure and compared
well with those observed- The st 6 ucture is therl one Isrith
Z and space groups 145d -- Ta Jja%rijj1, 1~2' Li ii-i ]-'(a)
Card 1/2

) ') 2 5 05
.',/0 '10/6C)/005/OuV00,5/ 0 12
E I T),I/E- 60
The Crystal 6tructure of the Compo IRu ~1 15 Ge /I
pos it ions ; Ii. Li in ~tu(e) positions with (~Ic,-,Z)
(O.L'2. o.t6, 0.-)611; and 16 Ge in I.b(c) posi:Aons with
0.206. The Ge atoms are 1'-2-coordinatecl with " polyll(!dron
interuiediated betveen an _Lcosaliedrou and the hexagonal allalo-vic
of a cubo-ocLalledron. LiI are surrouded by a dk~foj-mcd cubo.
oc t aliedron . Li II at ouis are survouwlked by a l")-gron simi La- to
the configuration around Mili (") )i- ' alpha-I-In.. The 2tructure is
close packed. There are 2 table, and 3 references; 2 Eii,,j:li--;Il
and I German.
ASSOCINPION. L ~ vovs k iy -11-OSLIclarstveiinyy Universitet :ull..
1. Franho (Llvov State University-iiii
I - Franko)
SUBMITTED- January --5. .1-960
C a r (1 2/ 2

S/o-,o/60/005/00!!/000/01--
E I ) -`/ E 3 6 0
AUTIJOIIS: Kripyakevich, P.I,, and Gladyslievskiy, Yv- I
TITLE, T! C VYS t Z I 1 6 t VLIC L 11 1'U!JN6-j.r
a (I j u m, I -1c
Pall, witll Ma~~l -Slulli
PERIODICAL KI: t stallograf i ya , 1 960~ Vol... I~j NO. Lt.
pp. 577 ... 579
'TEXT No compounds of Pd and M,~; have been fr-und hitherto.
Allcy.:i -,-!-ere prepared by fusing Pd and Mg under fir,,.,;on in a
,.oruridum crucible wi-th an II.F. furnace. The thermal treatment
was concluded at-tli 2-50 hours, anricalinS at 100 0C. X-rav
po,,-,,der photo,,raphs were taken vith Cr radiation. Two compound5
Were f ound. Pdixlg t~ cubic v-rith it ~ 3.16 4 0.01 KX and a
fit lin-Iti-c- lattLcc. Intensitie- calCUICted for a CsCl -typc
~, rUc 'Lure (Pin3m.- ) a gr c ed we I I An a I I o v w:i t h i 5 a t Ms,
conLained neitiier PdMg nor Pd. It wws ictragonal wath
0,01 ~: : 1, 11 e -sv-11 U 4--
,~ - ~.O-l , KX arid 5.!I1 O.OL 1~-x
=ugLo- . an AUCU typk~ ~trllCtUrc and inteasity cal(ulati.oriz
this.- F c, rt h c- c o mpe ~;~ i t i o nPd I g0.9 t 11 1 5 ,z i
c --Arc 1/9,

82e,o6
S/07o/6o/oO5/oo4/oo6/ol2
The Crystal Structures of CortaiIEN02(,E~UG101d-, of P,11adium with
Magnesium
in the space group P4/mim , 1Pd in 1(a) posicions and
O~qMg + O.lPd in l(d) positions. In in alloy witli 65 at.
Mg lines of PdMg and oi a further unidentified compound irere
observed. Similar compounds have been found in the Pd-Zn
and Pd-Cd systems.
Thexe are 3 tables and 7 refez-ences*. 4 German and '_-; English.
ASSOCIATION: Lfvovskiy gosuuarstvcnayy universitet in.
I. Franko (L'Vov State University im.
I. Franko)
SUBMITTED: Januarv 29. 1960
Card 2/2

.q/()70/f,O/()05 /006/002 /009
v E () 3 2/ E ~~ 14
AUTHORS, Gladystievskiv, Ye. 1, Tylkina- M,A, and
Savitskly. Ye.M.
TITLE; X-ray and %1~crc,scopic Stud, of' ilf-lte All,~,ys
PERIODICA1 1960. Vol No
pp, 877 -- 881
TEXT.- A study is reported of phase equilibria :Ln alloys
of rheniuzn and hafnium containing 66~v of H1' by weight. The
existence of' four compounds has been -established and the
crystal structure of two of them has been determined
kHf 5Re 24' structural type.- Ti 5Re 24, a ~ 9,713 , 0.00551
HfRe 2) structural typez MgZn 2, a z 5.248 +. 0~001 A
c = 8.592 + (j.002 4, -,/a = 1.637 , The compound lie 5Re94
(microhardness measured with a load of 100 p; to an acccurcv
of.40 ky;/mm 2was It 1130 kg/nim in (-agt srje:Amens is
Card 1/7

/6('/Oo5/6O;P/002/009
V032/L7. L4
X-ray and Microscopic Study of Hf-He Alloys
found to be in equilibrium with rhenium M kx/mIll
X-rav data ior aimealed alloys with a Large _,otlcentrat ion
of rhetimm ifidiLatc the preqence of a phast~ "All of' unknown
composition o! stT,ucture, The microhardness of llf'Ri! was
27
found to he L 116o kg/mm In Cast alloys t:olltwirling ItIld
50 at.',. Ite in equilibrium with the solid solution based cii
tile CUbie body -cent red modit'ication of' hat'nixim ( o -lit, )
a further phase of unknown structm-e (10 wits deterled Tho
lattet- pliase is probably lif 2Re and its mici-ohardriess is
1980 kg/mm Tablo I yrives the phase composition of the
11fRe alloys
Card 2/7

875)11~
5/070/60/005/006/002/009
E032,/E314
X-ray and Microscopic Study of Hf-Re Alloys
Concentration Phase Composition of
of rhenium Microhardness a I to
by at, Ca S t Annealed at
wt~ % (cast alloys) LOOO 0 C for
150 hrs
99 99.0 Heterogeneous
97 96,8
92.-.7
92
83~5 82.9 Homogeneous.
trace 2nd phase
67zlq 66,6 -ditto-
51.3 50.2 Heterogeneous
31,z0 33.1
Re-trace Iff He')
Re+lif' Re
5
fif Re
1 24
Hf Re
1; 2 It
HfRe,
0 -11f i B
B
Rti-A
A-Re
A
11frize
24
EffRe 2
H-traca -a-lif
lit'--trace B
Table 2 gives the latt ice .:onstatif s of' the wo modificat ions cf
hafnium arid and 11f*16,11
Card 3/7

~% ~iai4.
/()06/()0'-'/009
E032/F3 14
X-ray arid Microszopic Study of 11f -Pe Allf_,Ys
No. of alley
and Pha s t, C/a
heat treatnt,
4. Annealed at 11-1 Re
5 24 9~713,~0.005
iOOO 0 C
.do- Ilf'Re ';.248.0.00l 8.59'VI~0.002 I~bl
1:
2
~do- a-Iff 3.20 0.01 r,.o8 o.w. 1. r8
7. Cast P-Hf 3.50 + 0.01
Table 4 gives tile interatomic di8tan,~es in HfRe 24
Card 4/7

/ooO/oo,,, /()w)
v o,3 2 / I ~ 1 11,
X ray and microscopic stit(tv (.)f' lif*-Ru ~Iluvs
tic (a) tic (C Re g I? e gr , I C-ou'.-d Illa t 1,)r1
No t a I
lif (a) 3.08 (4) 95 1-" -16
08 (1) - 2.7-1 (3) 2.93 (b)
Hf (c) 3.21 (3) 3. 15 (3)
2.71 (1) 1.).91 (6) 6
Re (g 3.21 (1) 2.73
o
2; 93 (2 ) 2, 6'! f 1 2. 44
R~, 2.95 (1) 3-15 Ii) 2. 7' ( 2 2,b! e2)
2.90 1!2)
Card 5/-'

1; /070/oo/of) /ow)
T i Till f,:!, I it 1) r'l a 1) C, v it 1, 1 1 c t
r d I 11a t o r" rl I I Illb ers I'a 1) 1o b g - I I itI I o! I
t a
t it, t oil .,,,Y
22 5 '1, W7
2
2
(1- (2) 2 62 i L) 2 62
8
Ca rd

.;/o-7()../ Oo/ow; /ooib/Oo2l /o(v~
P. 2 /[,,3 1
X- rixy and Microscopic Study of lit -111, A I lovs
There are 6 tables and 9 references~ 2 Soviet. and
7 non-Soviet.
ASSOCIA,rION L' vovsk iy gOSULla I'S t VUIIIIVV Lill LVVI-S
L tile Il i Ir it It It r,1
V! anko
I its L L Lit tMe I. it I I U 1-,[~ i I I me, it I A AIja k c va
AN SSSH (Iti:titituLz, ot*
A A, Baykov, AS USSH I
SUBMITTED February 29, 1960 (initially)
June 2, 1960 I'after re-,rision)
Card 7/7

KRIPYALVIGH, P. 1. ; GLITYSMISKlY, Y,,,. 1.
,, "-() 1.',!
Struct.ura typo Gu Si , Zhur.stru,kt.kh.~m, 2 no.5:573-57 ,
-1 ?4 ( ,~Tj I;'
. L *. - 14: 11)
1. Livovskiy gosudarstvonnyy univarsitA im,~ni Iv,Praliko.
(C ryt; tall agraphy)

GLADYSIIEVSKIY, Ye.I.; KRIPYAHVICH, P.I.; TFSLYUK, M.Yu.; ZARECHNYUK, O.S.,
- I -,- ---YT -
--KUZ"MA9 .9.
Crystalline structures of certain intermetallic compounds. Kris-
tallograftia 6 no.2-267-268 Mr-Ap Ift. (,IIIRA 14:9)
1. Llvovskiy rosudarstvennyy universitet im. I.Fran](o.
(Intermetallic compounds) (Crystal lattic-~?s)

GLADYSIUji-lY, Ye.I.; KRIPYA]CEVICII, P.I., KNIM, Yu.b.; TAESLYM, M.Yu.
New r-epresentatives of the structural types I,fg6(.ulS Si,, and
_11161"'n23. K-1-istallograftia 6 no-5.769-770 S-0 161. (,,MtA 1/,-,10)
1. Llvovskir gosudarstvenayy umiversitfat imeni 1,1~~razika.
(X-ray crystallography)

jg~ 121 C
:,UTHORS:
S ,/0 7
2L1 Og
Gladyshevskiy, Ye. I., Kolobnev, I F
T I T L-',,' Irvesti~r-ticn of i! t:,-2 Al ';U -Ge
tIODIC."L: Z'lurn-,i neo--ganicheskoy khimii., v,
TEXT, T%,;o L.,j(~thurmal s,,~ctions (at 40~-, and at Itl .-,I L11:11-inklm
jart -.f the :-;yste,n Al - Cu - Ce v:ere 1 ol-l ~-; v"Ure
from lu:Anu:-k-J;~0 (~~).98~o Al), clectrolytic coppr ~1,d cerium
a. Ce) , :ind anal,,,zed by V, V. Osh:~h povski.,, C P !.sLch, ik. T`., e
s-jeci,-,,ens --.,iQrP- kept tit 5000C for five day:3 ur. 1 at -`;C ) ftr ten dais,
res-,~ectivel.y, and subsequently quenched in tolifln- A t t a i of --illoys
,,-,s investigat;---d. On 55 specimens in the range fro,--~ t:) LY --velgrt
of
Ce and 0 to 121,",,; by weight of CU, the latti~,-3 -r th, SUI-Ji sclution
in Al (W-i)il SE) aas measured with an accura, Y " _'' ? ~X -,n
t i,
camera -,vith thermostat) (Figs. 1 ;-,nd 2). Po) ~,sh,d ~.,.n:! ~,--t-re prepared
of all a`o b - - - -
~- ys, and 'he microhardne3o was deterrl,in-zi ;;J 1, ,1- 1.nstromient of
the rl?-17-3 (-Pi4T-3) type at 50 9 loads Fig --ection
t 5,-,'
-.)0" in the aluminum corner of the s~,stem F-Z' section
-;;;tght' -.nd
at alloys with a higher cerium content, to
Card 1/6

)i C)
investil-ation of h4h-aluminum alloys
co-.,,,-, (,r con t,:~nt (iip to 6C~,o by vieight) werf~ ~iil;u i W,-L e, 1 1 g 4). Three
tern,.iry compounds were 8tudied moro clost~lv- T. lit~-i I c s to Al 9 CU 4 Cal the
narrow range of its homogeneit.- co,respondo to b i (T'- of Ce, 42-5~~
by aeight of Cu and 36.3~u by aetght of Al The -11AII-If%) IN'IrCITI'?sZ "I'llount"I to
3cj,)- It 10 k g/ ,min 2 . The compound i t3 in e,i! I i 1 1 b r I Lim V; 1 t" I --~ hu C... - 11 a I e . Al"CII
T21 T5 an ! other compounds not closoly inv(-o tig,it-~.i . The T,, C Uilipound
corresponds to Al CuCe, its homogeneity range 1 L-'j !I t. t c. 4 7 2~,j by
4
weil,-ht of Ce, 19.0 to 23-9';' by vleight ~)f Cu til 01,~ by weiEjit of
L
Al. The microhardness amounts to 317 + 10 kg/miii T,-. is Ln
-quilibrium
viit~'I the LJ-phase, Al 4 Ce, Al 2 Ce, T1, T 3 and other- not closely inves-
tig,ited. The T compound is in equilibr, ium vi th T, trill T The composition
3 - I
close to T 1: ~'5.6',, by -weight of Ce, z',4-'2i~I' b~y uf Cu and 70.2~-
by weight of Al. There are 5 figures and , rvf~.irenceo: ;cviet and I non-
Sovie t. The reference to English-lunguagre as follows:
Hansen, K. Anderko. Constitution of binary
Card 2/6

S/ 0 2 IV" 62/(j,50100410101012
D2 9 9/ ',)3 0
J'.
I; Y U D
,1,3vi to-rnary compoimds wi:.- "uCturp
C -L: -nauk n-1-.
of ternary sy,;,o'is of -wit"n Si .nd
6o, E.s o 111 a s ',!, e s-stems _:n(I Anvesti~~atod
o' 1.;1y L; 6 r1-" ct'ar.~'.l : -..r; 'i i s c-xitoncc of ',6 now
coripour..~,z vrit'rl Cu 0 tructur(,,, s t~L~ I i ~ilied. The
6 16
L I o -~ 0 L~ C. r C d b y F' 0 1 t i 'I1 1 d. 11 i~7 i O'i il L; f --lU mi ran
o:.- i 1 n a T _,-i;'iamn funiac c ( hv(I i,j c!-. - o i, i~m ~3 i:,1h ro The X-
L
r str~_ict-ur;~,.]_ an,~.lvsis vias carr,.,Lod tjj "~obiro_ rn-, ~~roston
ty p o s t r; c I e be-
lont-'L; to a Clas's of structurcs '."itll larc-e The
Y S, (of cubic
was found to be Sly',"'-Letry (-L" ;:,,e lattice, the
I'd 113

/:,'06/(--,J9/()03/01 0
Invcstigation of high-aluminum alloys ... B107/B101
AS SOC I AT I ON iLlvovski,.r gosudarstvennyy universitet im. Iv. Franko (L'vov
~;tate University imeni Iv. Fr,tnko)
SUB:,IITTED- July 26, 1960
Fig. 1: Lattice constant of the solid uolution of copper and cerium in
aluminum xith llj~ by ,,i-,ight of Ce.
Fig. 2: Lattice constant of the solid solution of copjwr and cerium in
alurninum. Legend- a) For allOY3 ,"ith 5j, by ,,ie;.ght of Ce; for alloyr
with 5'/. by weight of Cu.
Fig. 3: Isother;;:al section thr;.ugh the Al-cornor t-~f tho Al Cu - Ce system
('~ by We
at 5000C ' . ight) . Legend: 1 ) :~.onophase alloy3; 2) diphase alloys;
5) triphase alloys.
Fig. 4: Composition of the alloys pro~'air,,ed and results of the phase analysis
in the Al - Cu - Ce .9,Ysterl itt 4000C by weight). Legend: I ) :,',onophase
alloys; 2) diphase alloys; 3) tri,diase allo"S.
Card 3/6

com. oundo, vii th D-, 9/D:
n, Cj
0; L t
t -'I c o I c u L, e
~6
o r::1 t;ho L - 'J. .1 t
G U 1W C 4
al 2-nary
lo ) , 1-1, - - C o -
13c, Ti, Z-~,', i,,b, ;:f,
X, NI,
Z r , Nb
I CO II S ':
U,o X I I Si, Go li'ho C 0, t o
L -LC)n C C -ns - -ne
'tC',j
c o ni:- o un,, -on 4~ C 1111 S 18
'a
s till co-;--.t i-,mi i~, in view of of th"
t
ct:n be t`ic
.;b, Hl"', 'i!a) OCCL":)y Uile ~-IOSItion C, 1, 121 S r U, 12 u 1. 11, Cf 1::-, Cu si,
1 16
tlype, (co-,rdination n', e r t"Le a-tOlriiC Of I-COI:!')O-
f R
o f C'u. -13 tructiure,
nent is lar.1~2r tliar 1 6 4 r. o c L
aru In the
C Y, Mo , La, W, HE Sc-Uo--3i, Sc-(;o-Ge za-zid,
Li-Cu-Sj., no ,;orrary compoi,,nds off' Lub Cu lb si 7-'tYPe found.
are 1 table and 5 references: 3 'Q'oviet-bloc and 2 non-Swviet-blo c
C,ard 2/3

:j1()l:)-l162/0:),)/00,;101 0/0, 2
Now ternary coi.moun(ls aith ... D 2 q/ i),-,
ASSOCIATIO111: Llvivslky,, derzhavny- universyte-. ~LlvJv ",late Un.-.
versiTy)
W;16 by Acadomioiwl 1.~i-
P
-
SUM!iTTLD: Augus-t- 12, 190
Card 3/ 13

3/192/62/00 3,/CC2/'00 1 /001-
:)267 / D 410 1
Kuz I i:ia , Yu. B. , Tes 1 yuk, !-% Yu. , ftn(t (3.1 ady.
YQ . I
Laves three-component phaqcs in thle system
16 ~~_'L C., L It no. :~j 19'2
Z'%urrzll Strukturnoy k~li'mii' V.
,'56 - '156
T ---'i T In v-ie,.,r of crygtal-chemical tetween Si and
Gia the authors assu~leu that, when the 7-In content a..ouilt~~ io
the system X'n i - Go contains ternary compoundS rol3c;t~ssing the
La-ves -'~aaso structure, just as this was found for the system '-'n - 'Ii
- Si; to ve7ify this assumption they studiM six t~,:'rv:ry alloys con-
-Uainin_~ 25, 22.' 20 , of ~;e, obvined by direct
I 16 - 7, 15 and 1 2 a al
fusion of Very P;re -'etals J_'.-.".(orundiz' cruclbl-:!-; in ihp hydre.-en at-
.Moophorc, usinj the Tammamn furnace. Aft4pr annealing and harzlleninj3,
the alloys were subjecteo. to X-ray analysis (powder method). The
Card 112

S11192 62'IC~0310C -2/001 /-DG4
The Laves three-com1poriont phases ... D2071/J50 1
existenct-, ana crystal structure of two intermetaill(I compol.inds were
det---mined: Ge (structure of the type, a
3 0.7
~~- = 1.572) nd ( 2 ) Xr.:; i
4. 55'- � 0.002 iL, c = 7.635 + 0-003 1, a
~struc-mfe of the :"'irCu2 type, a = 6-762 -~ 0.001 A ). ftere are
3 tables.
ASSOCI~.TIOTN: L'Irovskiy .~oziudar&tvennyy un-iversiti~t im. Iv. '-ranko
(LIvov State Unive.-sity im- Iv. 10-anka)
S u B:.: i TT ED ',,:ay 6, '.961
Card 212

'p
3
31/0-17,E, /-62 1 ~00 7/0,~5/3 1/0 14
3% r(In 'j. V. ye4 -w, .i.
1m, I u
Ye. 1.
t eil; vana',i i ui;i - m:)'1 ybdi2i I u I-,' - !i Coll
Th e tornary phas,! dJ aj~ram of the -,;ystt,;- T - '."o 4 -V -.,o. p0 4- t e d
:-"'~-.Ils of X-ri~-Y miol-ostructural analysizo, i--nd mic~rohardness
M'~;~Sure:nent F4 6.9). J, S, 1 t ~S No new ternar... co'--pounds formed
t4'-j~ fro.-
-th a structure devia ~ cw ~j that -of binary 'i n~i I.:-,) silicides.
7_54
C 0',
) 1 ".0.'.j I ,", _- as 15 Si3
~2) 3et-.-;eeri the iso,~truoturai _t OUfIC,
and Si continuous s,~ri(2s of s o 1 Ji d s o 1 u -~ JIL o n r, : 1- ~, t 1 '(: r.- i P, 11 v I-I i ch
the Si content'varies by 1 to 2/c'. Ph,~! ran~~u of tl-,~! 'hcmojEen(e~~ucl
ternary solid solution ("1".10) 5 Si3 extends above 1500cc hifZ'-er Si
content3. tc--nary eutectic 15i
Card 113

3/078/6-9/--'107/005/0 1/0 14
InvestiCation of tne system. . . //isG
,y of 1,1 i-
oroms at 1~00'C. V'. t 2'COO, so 1 ub 4 1 i
t
-n'~ase V, m e S corigrue 11 t l." , ti""' i, s :.:j 3 if o rm:3 by
5
reaction. .'lle unlimited solub 4 -. it V o-,o in V J s
reduced intro,-.uc-ion of 3i. -ith. about 2 at,:. in "!Lc)3~s rich 4 1,
a s3lid SCIUtl'O", 0,1 the 11) Of
Second
the st;~hili t,,- of V to - i i-ti n,
oying w4th 34 -proves ox o
but co--"~i6'~rabl'l its O"astic, h.. as tj Ci ty On
y . "it'n 0'~
comnression 30/7'0; ~iith 20 at-,Q' ,'io + Si, ax-, fi .-uri?s and
1 tc-Lble., .
AS-`3CI--2:~~N: Instizut metallur.,-~.44- im. L. A. Ba'yk.ova (institute oi-
:.:etal'-,u--E:y imi3nil A. A. Baluko-1); Llvovskiy Zosud-n~stvennyy
ur.-ve r94 tet
i' (Llvov State University)
SU3:-:lT'-'-7l): June 12,
F _4 6- . G, .isothermal section of the s~/stem V-Yo-Si at 8COOC.
Le~and: Afn./'~', = at~L.
0
Card 21/3

5/'078/62,/007/005/011/014
Blol/ 110 --
Investigation of thesystem ... -- - ' .-B-.--. ..
: . AR. db us . I
- - - a x - W ..
Vr
Card 3/3
Fig. 9

AC(*,b/AI,D!
JkUT!f'~)I~: Gladyshevskfy, Ye. I., Kripyakevich, P. I.
ITUI-I': Ln,urmet,,vilic compounds with it 3-urantum type
SOURCE: Vysokotempcraturnyye metallokeramichesklye iT,,at'e.I,!.-%I.:'. Ins'- weta-10-
kor. i spets. ~~pl. AN Ukr.SSR, Kiev, Izd-vo AM Ukr_3311, vc-.~b2, 08
I'Z( T There are 31 systems of Intermetallic compoutidz; wi--I-,'n -a. lranlil;111
type structure, the so called sigma-phase. Tile components -'A' LLese ~systellls are
oil tile one hand elements of sub-groups 4 - 6 of t1le pvrioclii an(i on tl,te
other hand 7 - 10. A similar distnibutlon of compononts 1.,3 also
shown by type cL-Mln and C`3S' compounds. Considering the similar structure -D.'
C_3Si and sigma phases, it can be expected that the lattev wt.11 it.150 be lorml~q
.by elements of sub-groups 11 - 15. This hypothesis was confirmed by tile authors
who discovered a compound with a sigma phase r-trueture in ternary system CrAli-
-S'. None of its binary systems contains a sigma phase, but system Cr-NI shows
a tendency for the formation of such phases, and in system Cr-SI a Cr~,Si type
Card 112

i 6/o i
Intermetallic comi;oun(k; with a ... A A I C) I
ccmpound 13 being Cormed. The (il'scovered sigina phase compo~;iLiori 1~; ~r I 3N
s a - 8.76,), c = 11~~"l M c/, - 0.5 A second ccnpound wa,,;
reveale(! It-, NI) aUoyz wLth Al, obtained at the Institute of Meta.I].u--,-Lrj A:3 USSIR
by Ye. '.;. Savit~;kiy and V. V. Baron. A radiographical. analvsis i3hows that tile
Nb2AI compound belongs to the sLgma phase type. Its constants are: ;' - 9.95;
c = 5-18 M; c/a = 0.52. This Is the first sigma phase containing Al. The
distribuAon ol' atom!3 in i~.s structUrn corresponds to a compLete (Lhe Nb
atoms are in locations with coordination number 15 and 14 and Al-atoms with cc-
ordination number 12). Crystallochemically the compounds approacl, "11c 111)3A1
(Cr2Si' type) compounds and sigma phasez in systems Ub-Re and Nb-11t. Moreover,
the authors have discoverod a number of ternary systems wholse radiographs re-
semble those of sigma phases but are not identical with them.
Card, 2112

--l L2()3
tl~cc. tw~~ CO."
iurus-,Dv&~Ll I)U21
Wtfo (jj.:;CuV-rej!
-cl !I. U,
--v-ued i-t6 tw., t
allic co~-5ou,.Ls wlti. a~c, i
c.
'.It -t ic .-Sloa
si-Ild sc-,~ e1-.- al cc,~-20u"r, so;~c
of the T"c;rt: "--c 3
1. Ya. 7;.-w %~o ~"'he Lvov
Cara 1/2

.J/ /, '// '/' U/
? u/u, ~16(,' '012
The crJutal iW3/.L2()3
U,-ivc-;:.4y -... - ~"-.
S'UiLd~T,L: jzu-~-Lxy it"),
Caxd 2/2

S/ 192/62/0-33/004/002/002
104 2,'_L2 112
'Cr ip,
Airl 11 0711 5: G lnd:,-shnv3,c ty 'T a kov ich, q nd
P. 1. , Kuz Ima,
TITI,E: Cry3tsl structuras of ternary coi-~ipound.,j with low sili-
con content in the vrstoris Cr - Ni - 31 and Cr - Co -
S I
PERIODICA-, Zhurnsl. qtruk1;urno-,, Ichi-1.1, v. .3), no.4, 1962, 414-423
T-'-"XT :This invo3t -lj-r.-,t~on Is R f01].0','[ UD Of a ;)T'0Vi0113 .vorlu by the
authors whore ternary ccr,)ouridi were obt-nined in similar systeris
with :.:n in T)laco of Cr. it is also intended U.) clarify tho Gon.-
dJtions Of 'formrtion of phf(3t':1,9 WIth th~q 'k -U 3Lructure. The 148
alloys In the two s,,,,3tems, contnining no'more than 25 mole % Si,
were hosted in vncuum qt 80000, for 150 h1'3 Or at 11000C for, 30 hrs,
-The,v ware then Lqtudiod with tho aid of -q Dob, *(o and Pro:5ton X-ray
povider cninerss nne, an MOM-6 (,MI16-6) microscooo, In the Cr- - 111 -
Si system at 60000 a now phnse was found with the approximte for-
mula Cr 6 nrid a pattarn con.91!itont, With tho 13 -11
Card 1/3

S/19 62/003/004/002/002
1042X242
Crystal 3trUCtUV0S Of t(WITIT"T
compounds...
structure of Cr,,.o5V',),- None of tilt, 0,vmound,,3 stladled lind
, . . .2, or ) tructUl' - At 110 0C th
the Dqves 2 0
the compound Cr,3.51.1i,... Si was ob3arved, vil-th gp,,(,,e F
- .5 .voup P4/mrwi and
lattice conatt,nts a = 0.761-1, c = 4.561 kX, C/a = 0.520. Tho atruc-
turo vias found by (,,oj:,,p-r!-r* the ob3orved intonsItie,'3 wit'll those of
U
sevor,il ~iossible atori-Ic ~,Iatr'Lbut ions . Another noripound ..,.Ith the
for-111,11a Cr,'Ti5ci, and tho , -1411 3tPUGtI.U'0 Or the A,-i,,,Al superstrue-
ture wa8 o~sorvod at eR00'0C'. It has the space group P213 and a =
6. 108 kX. In the Cr - V'o - Si system two terrinry comp6unds ware
found at 800()C. Ono, Cr,-3Co.Si.-), has the (, -,Mn 3trl-icturo or a
Ti5RO94 supers tructiir C' 3pII&C '~',,'rouo 143d, a 0,687 !C~. The other
'a Cr- o rolated 1;,) thnt of -U. A g a i n
3.5C04.()0'2..5 "."'th a 3trl-lctu"
no Laves phases were onaountnvad . Thorn nre il tnblos.
v
bard 2/3

';i/ 192 / 6') 0,):',1ooe1, 00',2/ 00--
10 42/i 24
n 1 gtr,le j; I I I, Oq of t;t~ I :jnpy compound.9
u
AS 3 OC 1A T 1 ON Lvov,,3lciy g,),vudnratvonnyy universitet Irl. Iv. Franko
(1,vov Strito 'il-niversity im. Iv. F-ranko)
SUMMITTFI): June 26, D61
Card 3/3

SAVITSKIY, Ye.M.; BARON, V.V., YEFIMOV, Yu.V.; GLADYSHIEVSKIY, Ye.I.
System vanad-ium - molybdenum - silicon.. Zhur.neorg.khim. 7
no-5:1117-1125 bly 162. (MIRA 150)
1. Institut rotallurgii imeni A.A.Baykova i Llvovskiy
gosudarstvenn.vi universitet.
(Vanadium-molybdonum-silicon alloys)

SAVITSMY, Yejf.~, TYLKMA, ~LA.; TSYGANOVA, LA~; GLAUSELVSKII, Yz.,I,;
NIJLYAVA, 1.1, P. I- - *- -- - ------- --
Phaz*tfdiagram of the hafnium - rhenium system. ZhiLr.neorg.khim- L0.78
1608.4610 Jl - 62. (MIRA 140~
11%
1. Institut metallurgii imeni A.M~xykova i ldvovvki~i gosudax-stvenriyT
universitet imeni I.Franko.
(Hafnium-rhenium alloys)

GLADYSIMISKIY, Ye. I.; KIEFYAKEVICII, P. I.
"Some regulurltleE; of the crystal chemistry of the rum-earth intemetallk
compounds."
I
report -submitted for 6th Gen Assembl, , Intl Union of' Cx*~,stalloLrntpny, Rome,
" Sep 63 -
Lab of Inorganic CIemistr-,,,, L'vov I. Frankc, State Univ.

S/021/62/000/010/007/008
D251/D307
".UT110113: .arh iv, V. Ya. , I'lladirih4vs I kyy'j Ye. I. , and Ku z, m,a, Yu. B.
TIT LE: :.evi ze-fnary compounds with a structure of the type
,,:r,Cu,,Al
I-
ICD TC!, L ','~,,rleriiya nauk Ukrayinolkoy- -Dopovidd, na. 10,
L i
1962, 1529 - 15:11
TEXT: The authors discuss terna,.,y systems A--B-C, ;ihore A an d 13
,Ire
transition metals and C 7.re elements of the 11113, IV3 and V D , -rou").,
of the periodic table. The aim of the present ,,iorlc is to investii~ate
analO6OUS 3ys-.ems in .,thi-,h 0, is gallium. Compounds of this type are
found, where A ~ Ti, V and B = Fe, Co, Ni, The structure of the com-
pounds resembles that of !.:nCu 2Al, and the lattice constants a~p gi-
ven in tabular form. The space group is '.-m'.m - 05. I-t is sho;,ai that
h
in the systems Ta(Ilb, ,.'o) - Pe(Co, Ni) - G_-, and SC(Zl,) :T-4 Ga,
siL:.Jlar compounds do not exist. The results are ob-.ainec. x-
ray :,,,-'U-hods on ailoys of metals of purity not le,;s than 99.9 fu-
sed in an atmosphere of inert Eas a! 6000C. There are 5 tab7es,
Ca*rd 1/,'

S/02;/62/000/010/007/006
Ne,a ternary compounds wJ th a ...
D251/D307
ASSOCIATION: IjIvivallcyy derzhav-nyy universytet (L'viv State Univer-
sity)
SjB~7:!TTED:
by Frantsevych, Academician
january 15, 1962
Ca,~d 2/2

L 19908-63 FWP (q) /1,7,,7 (M) IF74p (,q) InDS AMd1ASD ADIJ9
Amssiom kPI005411
y
Kuz'ra, La!-h, V. 1, 7. Ya; T.
0 1 r:y *e1,CvTk~y.,_Yu_T-. Z/
f
MILE: X-ra-v r:!!Trac~ion qnalynii of
SOURCE: Poroshkcv:vr,~- met a! IT; r[.f,-!ya, nn,
TOPTC TAL3- `i4'fractior:
Of C
A'I 7L R A CT - Th!!,t,,-'o..,r alloy-9 cf t" t
est- gatt-2,1 I)-, ~Hlf r - e of C ccr en t an Ihe
-ere im, L-6 I I a.Ct 4 O~j
c
--es o' '~T'
rronerl.. -Re thermccounles w-0- Alloy s"Ic!s -,.ere
-,repare~ from the following pugdered e r 4_1 12 'U%:n,,gte-i Carbide (6.0? at. of C),
'g.98L)f non 11am-pb lack,, 99.9%. Thephe-fis ezif-ID)
lungsten .7 ~, rhenium - 99.L"J, a:,~',
riim.s of c-ist alloys --nd of the alloyF at 2C~C, 115-00, ICCO ar,-! ~'TC we-c
1' 111, Cert.4
~etenrined. nt .'~e 2-4~ form !i mu Of,
solid sal,itions. Tvo nc~-,, comrf-un~s w--_-- fcl~7,~': -3. '(,rn-,.ri co~-c,~irri a
3 2~
I r)7 * . Ill. fl~)
cubic ~ at~ice to ti, -it of beta-~'n 7ice cro .'9 + O.OC2
0.-T.-1JC forried at -:,s al,o,,e 2,qO+D1, a c~ibic '.3'
ar.,2 a ternarv car~~rl- - C , ce-
Centered, of t~~e type Tlacl. 7r(-.,ip '3r - 05. , a - L,.063 + 0. CICI A).
Card 1/2

L 1990?1-03
'!R: An-' ~l 11
Preliminari hta concerning t~e of a. rhc-bic of
were obtain-d. Cr4g. art. h1-.,3: li L-Iblf,~- and 5 --gures.
1 1, 0,,j!j 7,1 t, t, t!~ .1. Ya. 3t,ate
'J n Or
S73 F7, T 7-': D AT E 3 63 E, VC, L :CO
NO 009
S! T 3 C/.)
C,jrd 2/2

L 18650-63 . . E~P(q)/Wr(m)/BDS AFFTG/ASD jD/JG/,IXT(IJP)
CESSION NR: AP3004M S1002116310ei0looTIOW6108M
AUTHOR: Glady*shevslky*y, Ye. I.'
TITLE: Crystal structures of ailicon-rich ailicides of rare-earth elements of
the ytt group fl
iA I
SOURCE: ANYU]a-SSR. Dopovidi, no. 7, 1963, W6-W
TOPIC TAGS: nilicon-rich rare-earth silicide, rare-eartb ailicide, terbium
silicicle,, holzLium silicide, erbiun silicide, thulium silicidle, lutetium
silicide, dysprosium silicide, ytterbium ailicide, crystal structure, lattice
constant, cell volume
ABST=T: 031, rQntal a= f S -ri h alloyancontaining 33.3, 40.0,
a Th ft -71,
and 50.0 at~ llt, where R is 4nxosl; Yb,?Vor Luk?bave~been studied.
The alloys K t 9. 9-~~ were. brittlo,
I vj1c7_.uM melted from components to 9
gray In color, and had a metallic luster. Microscopic exAmination showed
alloys contai3i#g 40.0 at% rare-earth elements to be the nearest to homog-
Ig &iln~ac~ion pattern examination established the exist-
eneous alloys.i'~.-
ence of Th-Si, Ho-Si, Er-Si,, Tm-Bi, and Lu-Si compoun6 with a hexagonal
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L 18650-63
ACCESSION NRt Ai,3oo4864
structu.re of the AlB12 type and confirmed the existence of Dy-Si and Yb-Si
compounds with a-similar structure. All the compounds most probably have
defective structures (designatc(l RSi,'-n) with an Si con-tent close to 6O.at','
The lattice constants ol RS'2-, compounds vary; a., from 3.745 to 3.847 4, and
C. from 4.050 to 4.146 A for LuS12-n and 7bS'2_,, respectively. Ac 0 dingly
the elementary cell volume decreases monotonic&Uy from 53.1 te, 49.2 3 as the
atomic number of the rare-earth metal increasea; an exc-zption - a Yb, cell
volum, sliphtly larger than that of Tm (50.5 and 50.2, respectivel-) - is
associated with the tendency of Yb to form compounds in which it in a biv&Lent
element. In c1loys containing 33.3ap RP mont of the RSi2-, compotndB are in
equilibrium with Si. The Dy-S12 and Ho,'U2 -n compaunds are in equilibriim
with the more Si-rich compounds O-P the a-C;,IS'2,,type (a - 4-.03 L, b - 3.9:2 K,
c = 13.29 4). The article was presented by Ac mician 1. H. Prsntsevy*ch of
the Academy of Sciences URM. Orig. art. has: 2 tablea.
ASSOCIATION: L'vivsky*y derzhavny*y universy*tet (Lvov State University)
SUMI-MM: o2ju162 DATE ACQ: 2OAug63 am: 00
SUB COIZ: MA 140 RET BGVt 001 0TM-. 009
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ACCESSION NR; AT4035160 s/oooo/63/000/000/0067/0070
AUTHOR: Glady*shevskiy, Ye. I.; Kripyakevich, P. I.; Charkashin, Ye. Ye.;
Zarechnyuk, 0. S.; Zalutskiy, 1. 1.; Yevdokimenko, V. 1.
iTLE; Crystalline structure of intermaLallic compounds of rare-earth elements
SOURCE: AN SSSR. In5EiWt geokhimii i analiticheskoy khimii. Redkozeme I ' ny-,'ryc
elementy* (Rare-earth elements). Moscow, lzd-vo AN SSSR, 1963, 67-70
TOPIC TAGS: rare earth, transition element, geochemistry, binary alloy, ternary
alloy, intermetallic compound, alloy crystal structure, zinc, aluminum, germanium
ABSTRACT: The existence of compounds of the rare-earth elements with metals, their
composition and the type of crystalline structure were investigated, with particu-
lar attention to the similarities and differences between Lhe various rare-earth
elements,as well as between these elements and their neighbors in the periodic
table. The systems of La, Ce, Pr, Nd, Dy, Er, Gd, Tu and Y with magnesium were
investigated first. it was found that there are no c?mplete analogies in these
systems, but that the system Y1Mq is closer to ErlMg than to the La/Ce system. In
the systems of rare-earth elements with zinc, aluminum and germanium, new compounds
were found, the structural parameters of which are given. It is interesting that
thg symm Y/Al differs from the system ErIAI and is similar to the system with
Car 2

ACCESSION NR: AT4035160
I.La, Ce, Pr and Nd. Compounds of La and Ce with Ge have rhombic modifications in
addition to the tetragonal one. Systems with cobalt and it-on wer-- also investiga-
ted and their parameters are given. In the La/Fe system no coN.younds are formed.
A weakeninS tendency to form compounds with a decreasing order number of rare-earth
elements is d]SO found in many systems with-manganese. Finally, the ternary sys-
tems cerium-transition metal (or copper)-aluminum and cerium-aluminum-silicon were
investigated and their lattice constants arc given. Orig.art.has: no graphics.
ASSOCIATION; Ins'"tut geokhimii i analiticheskoy khImii AN SSSR (Institute of
Geochemistry and Analytical Chemistry, AN SSSR)
SUBMITTED: 310ct63 DATE ACQ: 30Apr64 ENCL: 00
SUB CODE: IC, ES NO REF SOV; 000 OTHER: 001
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GLADYSHEVSKIY.. Ye.I.; MARKIV, V.Ya.; KUZ -TA, Yu.B.i G-r--:HX*A~711:1. Ye.Ye.
- -1
Cr-Istal structure ol' certain Lermary ;).c coall.ollfdi.
Titay, i ego splavy no.10.71-73 lu3. (MIRA 17:1)

ACCESSION NR! AP4017725 S/0294/63/001/003/0449/0455
AUTHORS: Fedorov, T. F.1 Glady*shevskiy, Ye. I.
TITLE: Interaction of transition metals of groups 4, 5, and 6 of
the periodic system with carbon
SOURCE: Teplofizika vy*sol%.ikh temperatur, v. 1, no. 3, 1963,'449-455
TOPIC TAGS: carbide, transition metal, titanium zirconium, hafnium,
vanadium, niobium, tantalum, chromium, molybdenum, tungsten, group
4 metal, group 5 metal, group 6 metal, atomic radius, binary system,
ternary system, quaternary system, carbide structure, solid solu-
tion, crystal stin-icture, thermodynamic properties
ABSTRACT: Binary, ternary, and quaternary systems whose components
are Ti, Zr, Hf, V, Nb# Ta, Cr, Mo, and W with carbon are considered
on the basis of published data and research carriea out by the
authors. Tables listing the various structures of carbides of these
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ACCESSION UR: AP4017725
metals and solid solutions of carbides of theszi metals (both con-
tinuous and limited) are presented. Phase equilibrium states of
ternary systems of the metals of these groups and carbon are also
given. All the data show that the phase equilibriums in the sys-
tems of transition metals of groups 4-6 and carbon, with three and
more components# are due to the crystal structures and thermodynamic
properties of the carbides produced in the metal-carbon binary sys-
tems, and also to interactions of the transition metals with one
another (primarily their mutual solubility). The ratio of the di-
mensions of the atoms plays a major role in the properties of the
systems. In view of the similar chemical properties of the transi-
tion metals of groups 4--6, carbon-containing ternary systems and
systems with more components have low probability, with the excep-
tion of systems in which one of the ccmponents is vanadium or
chromium, whose atomic radii are the amallest. Orig. art. has: 2
figures and 3 tables.
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ACCESSION NR: AP4017725
ASSOCIATIONt Institut metallurgii im. A. A. Baykovijt (Metallurgy
Institute); Llvovskiy universitet im. Iv. Franko (L'vov University)
SUBMITTED% 17May63 DATE ACQt 23Kar64 13NCL3 00
SUB CODE: ML, PH UR REP SOVs 010 0119BRi 024
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KUZIMA, Yu.B.; IAKH, V.I.; MARKIV, V.Ya.; STADUYK, B.I.; GLADYSHEVSKIY, Ye.l.
I
X-ray investigation of the system tungsten - rhenium - carbon.
Forosh. met. 3 no.4:40-48 Jl-Ag 163. OURA 16:10)
1. Llvovskiy ordena Lenina gosudarstvennyy universitet im. I.Ya.
..ranko.
(Tungsten-rhenium alloys--Metallography)
(Phase rule and equilibriumi

GLADISHEVSK Ye.I.; KUZ'MA; Yu.B.; KRIPYAKEVICH, P.I.
RUMMOMR25MMOVANly,
Crystal structures of the compounds Mn3KI2SI, V3Ni2U, flb3ft0i,
and of Or and Ta compounds related te them. Zhur.striikt.khim. 4
no.3:372-379 My-Je 163. DaRA 16:6)
1. LIvovskiy go5udarstvennyy univorsitet imeni Iv. Franko.
(Nickel-silicon alloys) (Crystallography)

GLADYSHFVSKIY, YQ.I.; FMES-MIS-ENKO, Ye.l.
Crystal structures of sil.7con-rich silicides or scandium and
yttrium. Zhur.strukt.khim. 4 no.6;861-864 N-D 163.
(MIRA 17W
y universitet Imeni Franko.
1. Llvovskiy gosudarstvennr