SCIENTIFIC ABSTRACT FOKINA, YE.A. - FOLB, I.I.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000413410020-6
• Release Decision: RIF
• Original Classification: S
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• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 20
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

trarls,.i3tor, nolee factor
-,red f-r

NR AT5004892
t-lll',~er Currents of -a M
o ri tt
0
02

c t-, " 1X] [I ) ye 1 11 ,
USSR/Pbysics of the Atmosphere - Dynamic Met4porology, M-2
Abst Journal: Referat Zhur - Fizika.. No 12, 1956, 36o93
Author: Fokina, Ye. A.
Institutiont None
Titlet Types of Monthly Negative Temperature Anomalies Tashkent
Original
Periodical: In book: Meteorol. i gidrol. v Uzbekistane,, TaBhkentj, AN UzSSR,
1955, 179-186
AbBtractt None
Card 1/1

AF701511a,7 fRilli.SUE ISLA_.,,~O -LVIE-1 AD IPL~2 - S
Fo~~Y ~.A. and KRYLO), 0. V. (Inrtitute of Physi-11al uheiiiistt7, Academy of
Sciences, US31t).
013 MYSTV FOjUn"!iW0,3~I i~Deteriiiiriation of
oxidation-reduction properties of surfaces). In Problej-,V kinatiki i kataliza
(Problems of KineLics and Catalysis), vol. ",. -Lzdatollsuvo Akademil iiauk
sl.,Ut, 1955. SeAion V: iiew experimental i:iethoda. p. 248-255.
'-"he adsorption of phenol was sLudied in order to develop a ii.ethod for the
deternination of t,e number aud nature of acid and alkaline centers on the
surface. It was delermined gravimetri-.!ally on a quartz sprin,-_-, balance connected
with an ampule containing phenol. The adsorption of Bhenol was conducted
at 23-250C; desorption, at 25, 100, 200, 300, and 380 C; adsorption at 100OC;
desorp-6ion at 100, 200, 300, and 3`00C; adsorption at 2000~v', desorption at
200, 300 and 380oc- A sti0y of the kineUcs of adsorpLion and desorption
of phenol was car.Aed out on acidic, alkaline an,-! amphoteric adsorbent3.
e1, and Vie aluiainosili-.ate
BeO., ',igO, ZnO, CdO, CaO, Ca(0102, A12031 s"'-a
crLckin Y catalyst. Tiie catalytic acLivity oC Lhe ai;ove t;aLalyst wer6 also
studiod in the decomposiLon ofisopropyl alcohol. The experimental data are
coin-Diled in Table i (p. 250). The adsorpAon of 1-henol by all the catalysts
except 3'02 and A1203-SiO21 is very stable (chemisorption).
V3

Ye. A. and C'. V. H.`YD37
IIID 81,2 - S,
'i'he curve in Fig. 1 (p. 251) shows the quasi-isobars of sbsorpLion (calculated
from the saturation points of thg, kinetic adsorptioin isotherms). 'ihe amount
of phenol adsorbed at 25 C 6n lm. catalytic surface is appro~,ijiately the same
(5-Omm) on di-rcerent catalysts while the Ltability of tile bond between
phenol and catalyst di-ffers for different catalyst. _,ata. oil the desorption
of phenol from BeO and MgO at various temperatures are compiled in TLble 2
(p. 252).
Kinetic isotherms of adsorption of phenol on BeO are shown in ii 2 (p. 253)-
Analo-ous isotherms were found for ZnO, i,igO, A etc.. with t1le exception of
0 1203P
CaO. Ca(OH)2, silica gel and aluminosilicate. Kineti-, isotherms of adsorption
of phenol on aluminosilicate at various temoeratures are shown in iiZ. 3 (P. 353).
To establish the acidic nature of the caualytic surface, adsorption of pyridine
was conducted in the same manner as tile adsorption of phenol. Tile experimental
data are compiled in Table 3 (p. 254). Study of the decomposition of isopropyl
al,--ohol showed that the dehydration ability of tile catalyst changes as in the
adsorption of pyridine, and tile dehydrogenation ability of -'~he catalyst as in
tile adsorption of phenol.
Adsorption of pyridine may be used for determination 01' LIIC- acidic 1,roperties
2/3

AF701597 LTH--ASURE AID 8~2 - I
of the surface. It is advisable to determine also the heat of adsorption
and the enerpy of ac'4-,ivation. A dijailar method t;iay be used for determination
of the electronic nature of the catalytic surface.
The effect of the adsorption of meri.,ury, an electron-dorior, and oxygen, an
electron-acceptor on the catalytic nature of oxides of Be, Zn and _;~ was studied.
1"ercury and oxygen were supplied to tiie catalyst simultaneously with the vapors
of isopropyl alcohol. Oxygen decrea.-;es the rate of decomi~o:5iton of half of
the initial value - see ref. 19. Three tables, 3 dia.-ramse 19 references, 12
dussian (194,--1954).
3/3

ZH&BBDVA, GjM.; FOKINA, Ye.A.
. I
3"ect of the method of introducing modifying additives 9n the
properties of oxide catalysts. Izv.Aff SSSR.otd.khim.nauk 86
no.6:963-971 Ky 155. (MLRL 9:4)
l.Inatitut fisichaskey khtsit Akademli nauk SSMt.
(catalysts)

xv~
USSR/ Physical Chemisty - Kinetics. Combustion. Explosives. Topochemistry. B-9
Catalysis
Abs Jour : Referat Zhur - Xhimiya, No 4, 1957, 11284
Author : Krylov O.V., Roginskiy S.Z., Pokins Ye. A.
Inst : Department of Chemical Sciences, W&_aWffT-'Uf Sciences USSR
Title : Study of the De~endence of Catalytic Activity of Binary Compounds of
Metals of the Second Oroup with Non-Metals Upon e Position of Elements
in the Periodic System of'Mendeleyev. Comhunicatlon 1. Catalytic Decom-
position of Isopropyl Alcohol over Oxides of Alkaline-Earth Metals.
Orig Pub : Izv. M SSSR, Otd. khim. n., 1956, No 6, 668-675
Abstract ; In a flow-unit, at 314-4660, a study was made of decomposition of isopro-
pyl alcohol in the presence of the catalysts CaO (I), SrO (II), B&O (M)p
CaCO (17) B&CO (V) or**002 (VI).- In the I-ITI series catalytic ac-
tivi?y of 'the o2des increases* ftir all'the oxides dehydrokenstion of
alcohol preidominat6s 6yer'the-dehydration. Energies of activation E of
dehydrogenatibn (~n cal/i3ole), I 12000-16ooo, on 11 11000, on ITT 6000.
Values of E of dehydratioii are higher -(in_6al/mole): on 1 22000-26000,
on 11 25000, on 111 12000. At the same time E values of dehydration
1/2

USSR/ Ehysical Chemistry Kinetics. Combustion. Explosives. Topochemistry. B-9
Catalysis
Abe Jour : Referat Zhur Khimiya, No 4, 1957, 11284
over carbonates (24000 on IV) 17000 on V) are lower than dehydrogenation
E values (39000 on IV, 26000 on V) and approximate the dehydrogenation
E over oxides.* On the basis of these data the assumption is made con-
cernifig the presence'in oxides of carbonate admixtures-which cause the
dehydration. Dehydrog6nation E over VI, of 16000 cal/mole, is close
to dehydrogenation E over I. Literature data concerning catalytic pro-
perties of solid alkalies inelicate widespread use of allcalir, catalysis.
2/2

1. ct t YC
IRYWY, O.Y.: ROGINSKIY, S.Z.; FOUNA, Ye.A.
Investigating the dependence of catalytic activity of binary
metal compounds of the second groirp with nonmetals on the position
of the elemients in M.I.Mendeleev's periodic table. Report No.2:
Catalytic decomposition of siopropyl alcohol on oxides of metals
from the side subgroup of the second group. Izv.Al SSSR Otd.khim.
usuk no.4:421-43o Ap 157. (MIRA 10:11)
1. Institut fisicheakoy khimii AN SSSR
(Catalysis) (Isopropyl alcohol) (Oxides)

KRYIoOVg 0,V,; YOKINA, Ye.A.
Study of sulfide stability with the aid of S35 during catalytic
dooomposition of inopropyl alcohol. Probl. kin. i kat. 9.-294-303
1,57. (MIRA 1113)
(Sulfides) (Catalysis) (Sulfur-Isotopes)

I J1 7 r
KRYWYO O,V.; YOKINAg Te.A.
Stud.v of acid-base properties of catalytic nurface bT the differ-
ential Isotope method. Probl. kin. I kat. 9:304-313 57.(MM 110)
(Adsorption) (Grenol) (Carbon-Isotopes)

AUTHORS: Krylov, 0. V., Fokina, Ye. A.
% XNW"
62-58-3-2130
TITLE: The Investigation of the Catalytic Activity of the Binary
Compounds of Metals of the Second Group With Nonmetals as
Dependent on the Position of the Elements in the Mendeleyev
Periodic System (Izuoheniye zavisimosti kataliticheskoy
aktivnosti binarnykh soyedineniy metallov vtoroy gruppy s
nemetallami at polozheniya elementov V periodicheskoy siateme
Mendeleyeva). Communication 3. The Catalytic Decomposition
of Isopropyl Alcohol on the Sulfides of Metals of the Second
Grottp (Soobshcheniye 3. Kataliticheskoye razlozheniye izo-
propilovogo, spirta na sullfidakh metallov vtoroy gruppy)
PERIODICALs Izvestiya Akademii Hauk SSSR Otdeleniye Xhimicheskikh Nauk,
1958, Nr 3, pp. 266-276 (USS~j
ABSTRACTz This paper represents part of
of the catalytic properties of
(metals of the 2nd group) with
Beside the sulfides of the 2nd
samples (of Pb and Bi) were also
Card 1/ 2 paper describes the investigation
the systematic investigations
binary metallic compounds
metalloida of the
metal group some
investigated~ The
of sulfurous zinc
6th group.
sulfide
present
ZnS and

The Investigation of the Catalytic Activity of the Binary 62-58-3-2/30
Compounds of Metals of the Second Group With Nonmetals as Dependent on the
Position of the Elements in the Mendeleyev Periodic System. Communication
5. The Catalytic Decomposition of Isopropyl Alcohol on the Sulfides of
Metals of the Second Group
similar types of zinc. Table 1 shows the results of the per-
formed experiment. The dehydrogenation and dehydration of
isopropyl alcohol on the sulfides were also investigated (see
tables 3-6). It became evident that all investigated sulfides
except PbS are dehydrogenizing catalysts. The catalytic
activity of the sulfides Zn and Cd is higher than that of ZnO
and CdO. It was further found that a modification of the
method of synthesis of the sulfide causes a modification of
its catalytic properties. Under the conditions of the de-
composition of isopropyl alcohol (in the layer) the activity
of ZnS is higher than of ZnO. The activation energy of the
dehydrogenation (in the layer) increases with an increasing
filling of the surface. There are 8 figures, 6 tables, and
17 references, 16 of which are Soviet.
ASSOCIATIONs Institut fizicheskoy khimii Akademii nauk S3SR
(Institute for Physical Chemistry,AS USSR)
SUBMITTED: January 8, 1957
Card 2/2

5(4) SOV/62-58-12-3/22
AUTHORS: Krylov, 0. V., Kushnerev, M. Ya., Fokina, Ye. A.
TITLE: Investigation of the Dependence of the Catalytic Activity of
Binary Compounds of Metals of the Second Group With Non-Metals
Upon the Position of the Elements in the Mendeleyev Periodic
System (Izuchenlya zavisimosti kataliticheskoy aktivnosti bi-
narnykh soyedineniy metallov vtoroy gruppy s nemetallami ot
polozheniya elementov v periodicheskoy sisteme Mendeleyeva)
Communication 4: Catalytic Decomposition of Isopropyl Alcohol
on Zinc Selenide and Telluride (Soobshcheniye 4. Katalitiches-
kaye raziozheniye izopropilovogo spirta na selenide i telluride
tainka)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye kh.4micheskikh nauk,
1958, Nr 12, PP 1413-1421 (USSR)
ABSTRACT: The present paper deals with the in-testigation of the catalytic
activity of selenides and tellurides of metals of the second
group with respect to the dehydration and dehydrogenation of
isopropyl alcohol. It is a continuation of the investigations
carried out'with the oxides and sulfides of metals of the same
Card 1/3 group (Refs 1-3). The invpstigation methods employed are de-

SOV/62-56-12-3/22
.L
Investigation of the Dependence of the Catalytic Activity of B*nary CompoundG
of Metals of the Second Group With Non-Motals Upon the Position of the
Elements in the Mendnleyev Periodic System. Communication 4: Catalytic
Decomposition of !9cpropy.1 Alcohol on Zino Selsnide and Telluride
scribed (Refs 1-3). The ZnSe preparation was supplied by Y1. S.
Belenlkiy, the ZnTe preparation by N. A. Gory-anova, and chem-
ically pure tellurium by A. V. Novoselova. The decomposition
Of is,)propyl alcoh(.1 on ZnSe and ZnTe within the temperature
range 20-140' was investigated. It was found that the reaction
in p:71nelple develops in the direction of dehydiogenation. In
'he reaction a decrease of the catalytic activity of ZnSe and
ZnTe is obse-ved. The activation enex-gy of the dehydrogenation
of alcohol on ZnSe increases from 15 to 21 kcal/mol. The ZnSe
sample annealed in a:Lr at 6000 wan les5 active -,han that not
annealed. Elementary tellurium has a low cataly-v"Ic activity.
Radiographic and alootroncgraphic investigations a.9 a result
of compariaon of thexmodynamic character~Wcs showed that the
phase oh&agep of the catalyst are due to impu=-ities in the
basic sample anti on temperature effects, 'out in no case on 'the
course of .-latalys".a. There aze 11 fig-arsq, 3 tables, and
10 references, 7 of which are Sovieto
Card 2/3

SOV/62-58-12-3/22
Investigation of the Dependence of the Catalytic Activity of Binary Compounds
of Metals of the Second Group With Non-Metals Upon the Position of the
Elements in the Mendeleyev Periodic System. Communication 4: Catalytic
Decomposition of Isopropyl Alcohol on Zinc Selenide and Telluride
ASSOCIATION: Institut fizicheskoy khimii Akademii nauk SSSR (Institute of
Physical ChemistryAoademy of SciencesUSSR)
SUBMITTED: June 1, 1957
Card 3/3

AUTHORS: Krylov, 0. V., Fokina, Ye. A. S07/2o-12o-2-~o/63
TITLE: On the Catalytic Properties of Calcium 0:-,ide (0 katalitichaskikh
svoystvakh ohici kalltsiya)
PERIODICAL: Doklady Akademii nauk SSSR, Vol. 12o, Nr 2, 11511"
PP. 333 - 335 (USSR)
ABSTRACT: First, reference in made to variotin pertinent papers published
previously. The inve3til-otion of the rules -overning the basic
catalynia as against the acid catalysis and the oxidation-
reduction catalysis is very intcresting. The dehydration of
cyclohexane, the decomposition of isobiityl alcohol and of
bated. The calcium oxide
hydrazines on calcium oxide in investij-
was produced by a dehydration of Ca(011)2 at 6ooo in a vacuum
in the same container, in which the catalytic reaction was
investigated. The reaction products were analyzed by freezing out.
Besides, an additional analysis for H2 was carried out. The
hydrogen was made to pass through a palladium capillary. The
kinetic curves of the doYration of inopropyl alcohol in the
Card 1/3 adsorbed layer at 100- 200 aro givon in a diagrlm. Tho amatint

On the Catalytic Properties of Calcium Oxide SOV/2o-12o-2-3o/63
of dosorbed hydrogen at 180-200 0 is equal to the amount of
acetone. At lower temp2ratureB a 10-20~ excess of hydrogen is
0
found. This is explained by the more pronounced adsorption
of acetone on CaO. With an initial pressure of C 6H12 amounting
to 0,2 mm the dehydration of cyclohexane proceeds at 300-450 0
with a satisfactory velocity. Further details are given. These
results are well reproducible. The activation energy of de-
hydration is 30,5 Kcal/ mol. A stoichometric decomposition of
C6H12 into C 6H6 + 3H2 was not observed. In another diagram the
kinetic curves of the decomposition of hydrazine upon the
absorbed layer at 50-2000 are Civen. Thin investiffation proves
that it is possible to carry out three reactions of hydrogen
separation upon CaO. Two of thene reactions, the dehydration
of alcohol and of cyclohexane proceed in the same direction
as upon electron semiconductors. The direction of the third
xeaction, the decomposition of hydrazine differs from the
direction taken by the reaction upon netala and semiconductors.
The authors express their gratitude to the Corresponding Member
AS USSR, S.Z.Roginskiy for his advice and a number of valuable
Card 2/3 suegestions. There are 4 figures and 13 references, 9 of which

113
. On the Catalytic Propertiec of C;ilcium- 07ide SOV/2o-12o-2-3o/0
are Soviet.
PRESENTED: January 2, 1958, by S.I.Vollfhovich, ile:,-iber, Acadeiy of
Sciences, US'JR
SUBMITTED: December 31, 1957
16 caldim oxide-4atalytie properties
Card 3/3

0.2 0 0
-544)
AUTHORS: Krylovo O.V.j Yokina, Ye.k.
66869
SOV/76-33-11-31/47
TITLE: Investigation of Some Catalytic Reactions on the Surface of
Calcium Oxide
PERIODICAL: Zhurnal fizicheskoy khimii, 1959P Vol 33, Nr 11, pp 2555-2558
(USSR)
ABSTRACT: In continuation of a previous paper (Ref 1) the authors
investigated the decomposition of iaopropanol and hydrazine
as well as the dehydration of ethane and cyclohexane on
calcium oxide. The decomposition of isopropanol was carried
out in an adsorbed layer according to a method described
earlier (Ref 2). The curves (Fig 1) are given of the decom-
position of isopropanol at freezing out (-116c)Cj)rjf the reac-
tion products (acetone), in which case in the eas remainod
mainly hydrogen and the product of dehydrogenation7 proprienso
The hygrogen content was at 1000C - 64.3%, at 1500C _ 7 4 -_K,
at 180'U - 78-8% and at 220*C- 84.0 -86.3%. The activation
energy varied at 100-150 Cin dependence on the degree of
filling in the range, 21-30 kcal/mol and at 180-200OCfrom 32
to 36 kcal/mol. Ethane did not show any change on calcium at
Card 1/2 0-4 Tim.-Jig UP to 6000% above 60OoCa small degree of pressure

66869
Investigation of Some catalytic Reactions on BOV/76-33-11-31/47
the Surface of Calcium Oxide
increase could be observed and hydrogen was found in the
reaction produc a., The dehydrogenation experiments carried out
wi h a c e
t Zolohex put at disposal by G.V.1sagulyants, showed
(Fig 3 kinetic decompooition curve at 400'C wid varied initial
pressure) that the dependence of the initial reaction rate is
linear with the pressure of the cyolohexane (Fig 4). The
activation energy of the dehydrogenation is 30-5 kcal/mol at
300-4500cwhich is in accordance with data by A.A.Balandin and
I.I.Brusov (Ref 4), and M.Ya.Kagan and R.M.Flid (Ref 5).
Hydrogen was determined as the dehydrogenation product. The
hydrazine decomposition was also investigated in the adsorbed
layer 8f the calcium oxide and it was established that at
50-200 Cthe main-reaction products are hydrogen and nitrogen.
There are 6 figures and 7 references, 6 of which are Soviet.
ASSOCIATION: Akademiya nauk SSSR,Institut fizicheskoy khimii.Moskva
(Academy of Sciences, USSR, Institute of-Physical Chemis
Moscow)
Card 2/2

F
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oil I V Mv
vil 110, all
13 it

KRYLOV, O.T.; FOKINA, Te.A.
Isotopic study of the heterogeneous surfaces of oxide
catalysts used in the decomposition of isopropyl alcohol.
Part 1: Calcium-oxide. Kin. tikat-.1 no. 3:421-430
s-o 16o. (MIRA 13:11)
1. Institut fizichookoy khimli AN SSSR.
(Isopropyl alcohol) (Catalysts) (Garboa--Isotopes)

B017/BO55
AUTHORS: Krylov, 0. V., Fokinaq Ye. A.
TITLE: Application of the Isotopic Exchange Method for the
Investigation of Surface Inhomogeneity of Oxide Catalysts
by Decomposition of Isopropyl Alcohol. II. Aluminum Oxide
and Zinc Oxide
PERIODICAL: Kinetika i kataliz, 1960, Vol. 1, No. 4, pp. 542-547
TEXT: Studies on the nature of active centers on the surface of Al 203
were carried out by N. P. Keyyer (Ref. 2), A. A. Babushkin and A. V.
Uvarov (Ref. 3), and V. E. Vasserberg and A. A. Balandin (Ref- 4). By
examining the decomposition of isopropyl alcohol on the lay%-r adsorbed on
aluminum oxide by the differential isotope method, they found that the
aluminum-oxide surface was inhomogeneous. Dehydration of isopropyl
alcohol occurs on only 4-6% of the alumlnum-oxide surface. The results
obtained by studying the dehydration of.isopropyl alcohol on aluminum
oxide appear in Figs. 1 and 2. The specific activity of all reaction
S/195/60/001/004/006/015
Card 1/3

Application of the Isotopic Exchange Method fo~- S/195/60/001/004/006/015
the Investigation of Surface Inhomogeneity of BO17/ '0055
Oxide Catalysts by Decomposition of Isopropyl
Alcohol. II. Aluminum Oxide and Zinc Oxide
products desorbed during isopropyl-alcohol dehydration ivas found to be
constant. Desorption and dehydration of isopropyl alcohol on A1203 is
illustrated in Fig. 4. The kinetics of isotopic exchange between iso-
propyl alcohol adsorbed on Al 203and isopropyl alcohol in the gaseous
phase is graphically shown in Fig. 3. The decomposition of isopropyl
alcohol on zinc oxide was investigated by the differential isotope
exchange method whereby both dehydrogenation and dehydration products of
isopropyl alcohol were found to have constant but different specific
activity levels. Fig, 5 gives a graphic representation of the results
obtained at decomposition of isopropyl alcohol on ZnO. Dehydrogenation
and dehydration of isopropyl alcohol occur at different active centers of
the zinc oxide surface. Dehydration occurs mainly at active centers having
a lower activation energy. The kinetics of isotopic exchange between
isopropyl alcohol adsorbed on ZnO and isopropyl alcohol in the gaseous
phase is shown in Fig. 6. Isotopic exchange reactions of isopropyl
alcohol adsorbed on ZnG and Al203 are much delayed, thus indicating the
Card 2/3

Application of the Isotopic Exchange Method for S/195/60/001/004/006/015
the Investigation of Surface Inhomogeneity of B017/B055
Oxide Catalysts by Decomposition of Isopropyl
Alcohol, II. Aluminum Oxide and Zinc Oxide.
inhomogeneity of the active surface of the catalyst. There are 7 figures
and 6 Soviet references.
ASSOCIATION: Institut fizicheskoy khimii AN SSSR (Institute of Physical
Chemistry of the AS USSR)
SUBMITTED: March 23, 1960
Card 3/3

o
AUTHORS:
TITLEt
PERIODICALi
S/076/61/035/003/019/023
B121/B206
Krylovq 0. V. and Pokinal Ye. A.
Catalytio properties of new semiconductors with the structure
of zinoblende
Zhurnal fizicheskoy khimii, v. 35, no. 3, 1961, 651-659
TEXT: The decomposition of isopropyl alcohol and hydrazine in the adsorption
laye~r of the catalysto GaAs, Ga Se f GaAs,G Se 3GaAs-Ga Gaj , and
2 3 a2 3 ' 2seP ~ e3
CuBr was studied. These compounds of the types A IIIBV and A IIIBVI were
2 3
prepared by N. A. Goryunova and placed at the authors' disposal. According
to N. A. Goryanova, V. S. Grigor'yeva et al. (Ref. 13: Zh. tekhn. fiziki,
25, 1675, 1955), compounds of the AIIIBVI type form solid solutions with
2 3
compounds of the AIIIBV type. The kinetic curves of the decomposition of
isopropyl alcohol and hydrazine on these catalysts were recorded. From their
course it may be seen that the decomposition of isopropyl alcohol at
130-2700C mainly proceeds in the form of dehydrogenation. The main decom-
Card 1/4
PI -,-

S/076J61/035/003/019/023
Catalytic properties ... B121/B2o6
position products of hydrazine (90-2500C) are ammonia and nitrogen. The
catalyst GaAs 19 not poisoned during the decompgsition of 4.sopropyl alcohol.
The activation energy at temperatures below 220 C is :sl3-l.'j kcal/molep and
at temperaturen above 225 OC, -20-25 kcal/mole. The activa-.ion energy of the
decomposition of N 2H4 on GaAs at 100-2000C is approximately 16.5 kcal/mole.
Besides dehydrogen 'ation, other reactions nccur on Ga2Se 3' The aotivation
energy of dehydrogenation amounts here to 14-19.5 kcal/mole. At 125-2000C,
the decomposition of hydrazine on Ga23e, proceeds at a satJ.3factory rate.
The decomposition of isopropyl alcohol on Ga2 To 3 proceeds slowly at low
temperatures, and 100~ dehydrogenation sets in at elevated temperatures. A
transition point lies at 145 0C. At temperatures below 145 0 C, the activation
energy of the decompooltion of isopropyl alcohol is 2-3 kcal/molet and at
temperatures above 145 C, it is '11-19 kcal/mole. The decomposition of
hydrazine on Ga2Te 3 takes place at temperatures of 100-200 C. The catalytic
activity of the compounds GaAs-Ga2 Se 3 and 3GaAs-Ga2 Se3 was only studied from
the hydrazine decomposition, and it was established that the rate of reaction
Card 2/4

S/076/61/035/003/019/023
Catalytic properties ... B121/B206
is slightly higher than on the catalysts GaAs and Ga 2Se 3' On CuBr, isoproRrl
0 0
alcohol decomposes at 200-270 C at a considerable rate. At 200 C,a 61%
dehydrogenation takes place, and up to 2700C this proportion decreases to
36%. The activation energy of the reaction 0varies from 26 to 31 koal/mole.
Hydrazine on CuBr starts decomposing at 250 C, accompanied by side reactions
and simultaneous chemical change of the catalyst under the formation of
metallic copper, It was further established that in the series Ge, GeAB,
ZnSe, CuBr and during the conversion of ZnTe to ZnSe and ZnS, and of Ga.2 Te3
to Ga2SeV which groups of compounds show identical crystalline structure
and similar lattice parameters, a decrease of the catalytic action sets in
with simultaneous increase of the activation energy df the catalytic reac-
tion, w-ith an increase of the width of the forbidden band (i. e., with in-
creasing ionic character of the bond). Semiconductors with bonds of highly
ionic character have therefore poor catalytic properties. The authors thank
S. Z. Roginskiy, Corresponding Member AS USSR, for advice. V. M. Frolov and
Yu. N. Rufov are mentioned in connection with the study of the catalytic
properties of pure germanium. There are 8 figures# 2 tablesp and 19 refer-
enaes: 12 Sov.let-bloc and 7 non-Soviet-bloo. The four most recent refer-
Card 31/4

Catalytic properties
S/07 61/035/003/019/023
B121YI3206
enoes to Engliah-language publioationa read as followst G. -M. Schwab,
Semiconduotor,,3 surface physics, Philadelphia, p. 2831 1957; G. -M. Schwab,
Advances in Catalysis, N. Y., 9, 229, 1957; G. -M. Schwab, G. Greger, S.
Krawczynski, J. Penzkofer, Z. phys Chem.,~N. F.), 15, 363, 1958; W. E.
Garner, Advances in Catalysis, N. i., 9, 9, 1957.
ASSOCIATION: Institut fizicheskoy khimii Akademiya nauk SSSR (Institute of
Physical Chemistry of the Academy of Sciences USSR)
PRESENTED:
SUBMITTED:
May 19, 1959
July 15, 1959
Card 4/4

GAZIYE:V, G.A.; KRYLOV, O.V.; ROGINSKIY, S.Z.; SAMSOIOV, k-Y.V.: FOUNA, Ye.A.;
YANOVSKIY, M.I.
Dehydrogenation of cyclohexane on certain carbides, borldes, and
silicides. Dokl. AN SSSII 140 no.4:863-866 0 161. OIUR,-~ 14;9)
1. Chlen-korrespondent AN SSSR (for Iloginskiy)
(Cyclohexane) (Dehydroeenation) (Ltalysts)

S/204/62/002/005/003/007
E075/EI36
AUTHORS: Krylovs O.V., Kushnerev, M.Ya., and Fokina, Ye.A.
TITLE: Formation of active surface in the catalysts for
the polymerization of ethylene oxide
PERIODICALi Neftekhimiya, v.2, no-5, jL962, 697-704
TEXT: In view of the low activity of technical Beo and mg0v
the authors studied the preparation of-the active oxide catalysts
by decomposing Be and Mg hydroxides and carbonates. The action of
catalytic poisons (1120 and C02) was also investigated. A ~TacBain
balance was used to follow the decomposit 'ion and the adsorption
kinetics of ethylene oxide (related to polymerization kinetics).
C02 and 1120. Adsorption of ethylene o 'xide occurs before
polymerization, the rate of adsorption being proportional to log -t
(t = time). Subsequent polymerization takes place at a constant
rate which depends on the number of active polymerization centres
on the catalyst surface. The catalytic activity groves with the
degree of decomposition of the hydroxides. The most, active MgO
has 30-50% of its surface covered by water. For Be(OH)2 the most
active catalyst results after its complete dehydration.
Card 1/2

Formation of netive surface in the ... S/204/62/002/005/oo3/007
E075/E136
Freshly prepared MgO and Beo reduce their high activity on
exposure to air, whilst their surface areas decrease by only
10-20%. This is explained by the preferential adsorption of water
on the active centres, which lowers the adsorption and
polymerization of ethylene'oxide. Initial adsorption Of C02 leads
to the increase of ethylene oxide adsorption, but decreases the
polymerization rate by a factor of 4-5. Further C02 adsorption
has no effect. It is inferred from the adsorption kinetics that
the active centres are Mg2+ or Be2+ ions interacting with the
oxygen in ethylene oxide molecules.
There are 9 figures and 1 table.
ASSOCIATION: Institut khimicheskoy fiziki AN SSSR
(Institute of Chemical Physics, AS USSR)
SUBMITTED: May 5, 1962
Card 2/2

FOKINA, Ye.A.; TRETYAMV, I.I.1 KRMV, O.V.; RKOVA, S.A.
"Untersuching des Mechanismis der Adsorption und des Isotopenaus6nothes von C02 an
HgO und Mg(OH)2.n
Third Worldng Conference on Stable Isotopes, 28 October to 2 November 1963, Leipzig.

FOKINA, Ye.A.; 2~VADSKIYp E.A.
Effect of magnetic fields on martensite transformation in steel.
Fiz. met. i metalloved. 16-no.2011-313 Ag 163. (NIRA 16s8)
1. Institut fiziki metallov AN SSSR.
(Steel-Metallogra hy)
11~
(Magnetic fields

-W-Y---, FOKM,-,-Yi. A-.; MMUWA~-~ A.---- - --- - --
KRYWV, 0. V.; KUSHNEREV) a.
"Elementary mechanism of heterogeneous catalytic polymerization of ethylene
oxide."
report submitted to 3rd Intl Cong on Catalysisp Amsterdam, 20-25 Jul 64.

ACCESSICK NR; AP403515a
AUTHOM Kry*lovs 0o Vol Foldnap Too A*
TITIB: Relationship betveen the catalytic activity of some cemiconductors,od the
forbidden zone vidtla
SMCE: Kinetika I, kataUzp To 5p not 2j. 19640 284-M
TOPIC TAM: semiconductor catalysts, forbidden zone., forbidden zone vidth,
catalyais, gadolinium semiconductor, germanium oemicowluctor, indlun oemidonductor.0
zinc semiconductor., copper scmiconductor
ABSTRACT: Having found earlier thar, the catalytic activity of ihe iooelectronic,
acrics of germardum nemiconductora (Go GaAs ZLISC,, CuDr) in the decompouitloa of
Ixopropyl alcohol and hydrazine decreanco from Ge to CuDr, tha awl-hora carried
out a Btudy to correlate the catalytic activity with the width of the forbidden
zone. They studied decomponition of icopropyl alcohol In the adsorption laycr'(i12
steady-state conditionn) at low preacum on the surface of the following semicon-
ductora: Map BP., GWWp Ga&a*Ga28e-A GaAs43Gv/,>So GaSb., p GaGe, GaTc,. InAsp InSb.,
%To in tha twPoraturo Interval 50-32W# 6vor moot of theoe acmiconductorap-i
C, rd 11/2
-k.1~

ACCESSION IM: AP4035152
alcohol is dehydrogenatede The above date were compared with thoue obtained by
the authors when decomposing alcohol over GdSj CuBr, %Sej~ G Te Ge ZnO, ZnS#
ZnSe and ZnTe, It in shown that catalytic activity declin6s Mh ~h,e inscreasing
width of the forbiddcn zoae, With thatj, the decline of the rate conataat may be
caused by the decline of ko rather than the inercace in E. This fact may be ex-
plained by catalysis neox the transition point from the impurity band to the coa-
ductivity band* It is shown in which canea the compennation affect is observed.
s~mbatie ebange of E and log k0. "Gratitude Is expressed to 8. Z. Roglnsldy and
V. 14. Frolov for valumbla discussions." Oris. art# han:
10 figluvo) 3 fonw1m.
1 table.
ASSOCIAMORt L3.0titUt Ithimicbeakoy fiziki AN SWE (LmUtute of Chemical PbpIcs
AN SSSR)
GUMMED: 25jui62 DATE ACQ: M&A ENCL: 00
so CME: 00 No MW 8"s 020 on=: 002

KRYLOV, O.V.; MARKOVAP Z.A.; TRETIYAKOV, I.I.; fQrINA.,. Ye.A.
Machanism of adBorption and lootope exchange of C02 on MgO
and Mg(011) 2* Kin. i kat. 6 no.1:128-136 Ja-F 165. (MIRA 18:6)
1. Institut khimicheskoy fiziki AN SSSR.

L61052-!,65-
-r7c: Z riDu wo LP50i 500
URR/0190/69/0 -11,1006/b9U/0991,
r'Q'; 64 r r
MIMS: ZzTlovt 0. V~; Kushnersvt M. Ta-t Varkovs, Z. A_ FokAna
'_c4anlo= of 'khe heteropne2ua qatelytid _o1rwrimt1=11af et iene oxid
p by
SOTIMCE: VYsok-ozo1eku1yarrqye wyedineni", Y. T# no. 6, 1965, 984-991
f
ITOPIC TMAM polymer, resint etfqleme oxidet heterogeneous catalysiv, reaction
4
mechanism
Ti-
t -wi-th--tW view -of -eatahllahing-
ABSEUCTC _OMMIACL OU
for the selection of etbylane oxide polymerization 6atalyats. The vark is an
1 on of the work of 0. T. Krylov, Ye. A. Tokina (Sb. Kataliticlteskiye re&kti;ii
~hidkoy faze, Izd. AN. KazWt, Alma--Ata, 1963# strr, 5U9). were
perfo=med at 25C. The experimental results a-re m=~,_ized in Fig. * an the
'E_hcloaure. A reaction mechanism for the reaction is proposed. Orio:. art. hast 4
io~aphs, I aq~mtion, and 3 illustrations.
JASISOCTATIO-9f Institut khimichaskoy fiAki, AN. SSSR (Institute for Uiemiftl
'AF SQSO
Card

i
. i -
I
I
i Card 2/3 ".- -1 . II . f

rg ff
."ZM
-,L-61052,65L
ACCESSICH IM AP5016500
01.
fs
Cask
Fig. I. mmg(x in the specific catalytic
activity of IV
Period aetal hydroxides
1--cmd
4,

L-62542-65
';R! AP5011754
4
L.- v. Sadovskiy, V. D.
:TITLE.- Effect of a pulsed.magnetic flel on the teffj~erature interval of marte 3-tic---
trans formationAn steel
iSOURCE: MA~ metallov i metalloveddniye, V. 19 no. 4, 1965, 592-595
""OPIC TAGS- martensitic transformation,-: stee-I., magnetic treatment
ABSTRACT: Several grades of steel ware studied in an attempt to detemine the ef-
fect which an applied pulsed magnetic field has on the position of ':h~~ marternsitic
transformation temperature range. The - chemical compositions of the steeis studied
are given in table 1 of the Enclosure. Tue magne-lometric method w&i used to det"L--i
mine the martensite points and the quantity of ferromagnetic phase. The amplitude
of the field was 400,000 oersteds at a frequency of 5 kc. It was found that the
temperature of martensitic transformation in steels and iron-base carbon-free al-
loys is shifted toward the higher temperature side under the action of a pulsed mag-,
,netic field. -the amount of this shIft at a givc!n superc(yoling vaRe increases with
J
Card 1/3
Main: ~=N-
R
W
RN
IN
U 'MON t

~i, 7,
7"
L tw 7 5 E N, -11 /rv P
-IT/ Ew t- Ew (k b
wd), P ESP
z /E-iv
Pf-4/Pad
ACCFSSION N R: AP5013810 UR/0126f651019/005/072210725
669.112.227.34 .0 538.69
AUTHOR: Fokina, Ye. A.-;. SlairnavP 1. V. Sadovskly, V. D.
a--ii i-za-ffo-n-o f aus I
TITLE: Dest b tt!a t h"-pcwerful-mptlaed,maj~nctic field
SOURCE: Fizika metallav.i'metal.javedeniye, v. 19, no'. 5, 1965, 722-725
abiltied au4teititei mirtensite
TOPIC TAGS1 dentabilized austedicol :ata
tran3formation, pulsed ~manetid field, plastic defomation, auparcoaled
austertite, kinetic rawnimum
AkSTPACT- The authara itweatigated the eff/- t -L PU186 ~ignetic ffetd.onl
, -c - -1 -7
i--stenite,utabilized byr__p st~~.deformatlonAn 5(7-KI?21122 teel (0.49% C,
"6R- u
0. 3 - S, jsothermal
Nt; '2. C14% Cr, 0. 26% Kn ata
ywA
~0 tc-nperaLureg above the utarte-~7,1,e "loint in N12"Ya'.19
7 7 1 11. 7 07, C r, 0. '13Z Mn, 0, 48-, 5 J); -mar! erzq ion
c-cicled to the LcmperaLurc ra- ge --r zax -m-, in
c1l, LE 4up
I All,
N124GI. ateel (0.03% C, 23.6% M 3. 61 Mn) (0 to -19(~*C). 1b e wiaunt. of
I mar-E-ensite in the specimens waa coatrolled tty the magnetcmetric methad.
Ca

L 56075-65 -
-ACCESSIOU HR-..- APS013810
Tne pulsed-mag nett-,at ton of the specIzens vas ~accomplishad in an InstAllati oil
or geric -u1 p ma At--- d6scribed by FAkidavr
r rating superpmwerr -a Iq e dgne c e
vad2hiy (Fizika metallov I metal lovedeniye, 1958, 6, 561 11-, C field
it--do In the c-?.,p,,Aimento reached 500 k-nergteda and the C-7CCAteUCY, ftPPrOTi-
(30 0 c p a .it was establighad that tLC -
e n al I eas es leadc to de-g t qb 11 j z~! t t nn n f a V-31 eT1 i t U. L h v
ol' 2wrtens-Ite trans f or=a-t ion being then a fivict ton of rhc intenr;fty
of the field applied. Tlie increase in the derree of plastic delo-nmation leads
to an increaue irt the magnitude of the threshold field. lbe pulced r-agnetic
field destabill7ea austenite follcrwing the lstter'!i thermal sta!:)ilization., III
alloy!3 with isothermal martensite tranaformation, aupercooled ta a tmperatura
r,,.n,,v below the kinetic naximum (to the temperature of liquid ritrogen) the
pul3ed magnetic field induces a martensite. transfor-mation, the degrre of thia
f-r-ansformation also being a function of the intensity of the field applied.
IlThe authors consider it their pleasant duty to opre3q their apgreciation to
I T.C. Fakidcr;r and E. A, ZavddskLy for 'techuicnl avalstance In conducting the
ying --u?er-powerr-, i I --
iments einplo 5-1 putlae4 wmeuntle- fields. iinii to N. A. Boro-
and E. L Estrin 'for their kindneag in praviding alto iarvicimei-11
Y
2/3
7

7& -
ij I

L 4186-66 VWT(m)/EPF(0/E'dA(d) UP(c),
~Z)IZW WAWA:(c)
ACCESSION NR: APS016535 UR/0126/65/019/0,36/0932/0933
MJV/JD
AUTHOR% rok Smirnov, L. V.; Sadovskiy, V. D.- Prj~ IF*
in2A---X9-!Jj ; I k_ul, A
TITLE: On the problem of-the effect of a constant magnetic field on the martensAti
transformation in steel
SOURCE: Fizika metallov i metallovedeniye, v. 19, no. 6, 1965, 932-933
TOPIC TAGS: martensitic transformation, constant magnetic field, strong magnetic
field, liquid helium, steel
ABSTRACT: At the Institute of Physics of Metals experiments were performed on
5OKh?123 steel In a slowly increasing then constant (for 6 min) magnetic field of
40 kOe ih a solenoid with a superconducting winding at liquid helium temperature.
Without the magnetic field, this steel does not undergo a martensite transformation
on cooling to -1960C, but cooling to the liquid helium temperat'ure causes the forma-
tion of 8-9% martensIte. When the field was applied, an additlonal 12% martensiteij
Was formed. Similar experiments with the same steel carried out at the Physics
Institute gave analogous results. In another steel, 50Kh2N22,,,jn which no marten-.,
site is formed on cooling in liquid heliumi the application of constant magnetic
Card 1/2

L 4186-66
ACCESSION NR: APS016535
field of 43.5 kOe caused the formation of 8% martensite. It is concluded that the!
I action of the magnetic field on the martensite transformation should not be at-
tributed to the influence of the mechanical forces arising duri-ng pulsed magnetiza4
i tion, since the field used was constant, not pulsed. "The authors thank N v
and V. R. Karasik for affording them the opportunity to carry out the,
experiments.'
itute of Physics of
ASSOCIATION: Institut fiziki-metallov AN SSSR (Inst' Metals,-.
qq, 5- >'
SUB14ITTED: 26Feb65 ENCL: 00 SUB CODE: MH
NO REF SOVt 004 OTHER: 000
Card 2/2

ADONIH, A.N., kand.tekhn.nauk; ALIVXRDIZA , K.S., kand.tekhn.nauk;
AMITAK, V.A., Imnd.tekhn.nauk; ANISIMOV, Te.P., inzh.; APMOV,
K.A., dotsent; A IKIY, V.N., insh.; BOGDAHOV, A.A., kand.
tekhn.nauk; GORBINKO, L.A., inzh.; DANIBLYAN, A.A., insh.;
DA OV, V.N., prof,; IVANKOV, R.A., insh.; KORIINTAV, K.I., insh.;
LAVMJWMO, P.N., inzh.; LISIX. N.P., insh,; LOYLIA, S.A., kand.
tekhn.nauk; LOGINOV, B.G., kand.takhn.nauk; NIHINZON, G.M., kand.
tekhn.nauk; HOLCHANOV, G.V., kand.takhn.nauk; XMVIYBV, I.M.,
prof.; NUSHIN, A.Z., insh.; CLIMUNG, D.Ta.. inzh.; PODGORNOT,
M.I., inzh.; FATIMM, I.L., kond.takhn.nauk; YOKINA, Ts.D.0 inshe;
IWISM, A.M., insh. Ldoosasadj; IIRSHOV, P.R., vedushchii-red,;
MMINA, N.A.. tekha.red.
(Reference book on petroleum productionj Spravochnik po dobyche
nefti. Koakwa, Gos.nauchno-tekha.izd-vo neft. i gorno-toplivnoi
lit-ry. Vol.2. 1959. 589 p. WELA 13:2)
(Oil fislds~-Production methods)

PAVLOV., A.V.;--~PKI.NA, Y6.1,
Distribution of germanium in the cross section of a simple coal
seam. Inform. Bbor. NlIGA no.30.-42-51 162. (MIRA 17:1)

T-'~(',IOVAII I.V.; Y0.11.
DIZ.,cover-los mild fjv6r.*,:,. Irv. Arav. 22 nc~.9.76 163.
(141PUA 17:4)
1.0tial istorii meditsiny i 5ovetokogo zdravookliraneniya
lriotltuta organizatali zdrtviookhr~ineniya i iatorii me-ditsiny
imen! N.A.

VENGROVA, I.V.; (RJSAKOVA, T.V.; ZINOVIYEV, I.A.; POLTANSKATA, T.G.;
FOKINA,--,Te.ll..;-PMOV, B.D., red.
(Significant dates and anniversaries in the history of
medicine for 19601 Znamenatellnye i iubileinye daty istorii
moditsiny 1960 goda. Soot. I.V.Vengrova i dr. Moskva. M-vo
zdravookhranoniia S=o 1959. 53 P. (MIRA 13:1)
1. Moscow. Inotitut organizatsii zdravookhraneniya i lotoril
meditsiny imeni N.A.Somaohko. 2. Zoveduyushchiy otdelom istorli
meditsiny Institute organizataii zdrovookhraneniya i istorii
meditsiny imeni N.A.Samashko (for Petrov).
(KIDICINB--BIOGRAPHY)

FOKMA, U.N. (Mosk7a, 21, Teplyy per., dl. 18, kv. 19)
Albrecht von Haller ('1708-1777) and his activity as anatomist;
250th anniversary of his births Arkh.anat.gie't. i embrs 36 no.2:
83-85 IP '59- (MIRA 12:4)
(ANATOMY@
contribution of Albrecht von Haller (Rue))
(BXOGRAPHIESP
Haller, Albrecht von (Rue))

.,--FOMA, Ye -N --
i!-~
Foreign reviews of Soviet works on the history of m3dicine. Sov.
zdrav. 19 no.501-72 160. (MEDIGM) (min .1319)

FOKINAO Te.14.
"The physician in a socialist society" by A.Mette, 0. Hisgeld, K.Winter.
Reviewed .by E.N.Fokina. Sov.zdrav. 19 no-5:72-73 160. (MIRA 13:9)
(SOCIAL MEDICINE) (METTE9 A.)
(MISGELD# G. ) (WINTER, K.)

ZINOVITLV) I.A. - Y%AL'YUP T.V.,- POLYANSKAXA) T.G.; RABINUVIGH, R.S.;
F KTUA-IU N
Significant and anniversary dates of the history of medicine
during 1962. Sov. zdrav. 20 no.9:76-79 161. (~IIM 14: 12)
1. Iz Instituta organizatsii zdravookhraneniya i istorii meditsiny
imeni. Semashko Hinisterstva zdravookhraneniA SSSR.
(MEDlCINE)

ZINOVIYEV, I.A.; KALIYU, T.V.; POLYANSKIYA, T.G.; RABINOVICH, R.S.;
FOKINAP Ye.N.; PRONINk, N.D., teklm. red.
[Significant aid aniversary dates in the history of medicine
for 1963]Znamnatelinye i iubileinye daty istorii meditsiny
1963 goda. Moskva,, Medgiz, 1962. 61 p. (MIRA 15:11)
(MEDICINE)

ZINOVIIEV, I.A.; MIYU, T.V.; FOLYANSKMA, T.G.j RABINOVIGHj H.S.;
FOKINAI Ye.N.; ZUYEVAq 11.K.s tekhn, red,;
(Significant and jubilee dates in the history of medicine for
19621 Znamenatellnye i iubileinye daty istorii meditsiny 1962
goda. Moskvat Medgizv 1962. 71 p. (MIRA 15:4)
(MEDICINE)

ZINCIVI :CLV, I.A. KJLL'YU, T.V.; PULYLI:61AYA, T.U.; -,ULELUVIGH,
Significant and anniversary datos in t'j lf~jtory olt imedicine:
June. Sov. zdmv. 21 no.2:61-63 162. (1-did, 15:2)
1. Institut orgwtizatsii zdravookhromeniya I istvril med -.-tainy
imeni N.A.Somashko Ministerstva zdravookliranonira SSSH, otdol
istorii meditsiny.
(ML-DICINE)

,- FOKINA, Ye,N. (Moskva)
Control of alcoholism in Rusia,-4worka of A.M.Korovin,.1865-1943.
Sov.zdrav. 21 no.716M4 162. (MIRA 15:8)
(KOROVINP ALEKSANDR NIKHAILOVICII, 1865-1943)
b
.i - ~,*7
,2~.- I 1 1. .. I

ZINOVIYEV, I.A.; PMYANSKAYA, T.G.1 RABINOVICH, R.S*; KALIYU, T.V.;
If FOKINAt-Yox
Significant and anniversary dates in the history of medicine in
1963 - May. Sov.zdrav. 22 no.2:67-68 163. (HIRA 16:i2)
(MEDICINE)

VIENGROVA) I.V.; POLYANSKAYA, T.G.; P-%7jlN(TVIGlf, R.S.; POKIN.116'Ye.1f.
Important wid annivermary dater In the Idstory of inadicino in
j964. Sov. zdrav. 22 no.9s7l-70, 163. (MIRA 17:4)
1. Otdol istorii raeditsinj I l,ovetskogo zdravookhritneniya
Instltuta organizatsil zdravookl-xan()rliyn i Istorii meditsiny
imeni N.A. Semashko.

VENGROVA, I.V.; POLYANSKAYA, T.G.; RABINGVICH, ~e.14-;
PETROV, B.D.9 prof.j red.
[Significant dates and anniversaries of medicine in 19651 0
Znamenatel'rWe i iubileirWe daty istorii medituirW 1965
goda. Pod red. B.D.Petrova. Moskva, Neditsinal 1964. 74 p.
(MIRA 17:12)
1. Zaveduyushchiy otdelom istorii meditsiny i sovetskogo
zdravookhraneniya Instituta organizatsii zdravookhraneniya
i istorii meditsiny im. N.A.Semashko (for Petrov).

FOKINA Ye.N. (MoEkva)
Group of Rui,sian doctors in a painting from the first half of the
19th century by N.I.Podkliuchnikov. Vest. khir. 94 no.ltl26-131
is t65. , (MIRA 18:7)

5(2)95(3)95(4) 05885
AUTHORS: Fialkov, Y&O A. (Dsoeased)q Pok$nas, Z.A. SOV/78-4-11-38/50
TITLEt Physicoohomical Investigation of the Galliumtriohloride-nitro-
benzene System
PERIODICALs Zhurnal neorganioheskoy khimii, 1959, Vol 4, Nr 11,
py 2611-2616 (USSR)
ABSTRACTs Numerous publication data, many of which are'based on papers by
V.A. Plotnikov and his school, prove the distinct capability of
halogen compounds of aluminum of forming complex compounds also
in nonaqueous systems. The halogen compounds of gallium have been
little investigated so far. The papers by LA.Sheka(Refs 9, 10)
are mentioned. The complex compounds mentioned in publications
correspond to those of-aluminum, and are listed in table-I. The
system GaCl 3 -C 6H5NO2 was thermally analyzed; its electric
conductivity and the decomposition potential were measured, and
an electrolysis was carried out, The thermal analysis (Table 20
Fig 2) carried out in Stepanov ampullae (Fig 1) yielded, as in
the case,of Al. two compounds: GaCl 30 06H5N02 (melting point 640),
Card 1/2 and the incongruently melting GaCl 3* 2C6H5N020 The measurement of

05885
Phyeiaochemical Investigation of the SOV/78-4-11-38/5()
Galliumtrichloride-nitrobenzene System
the electric conductivity was carried out by means of a sound
generator of type ZG-109 frequency 1500 c/o, and a tube of type
6E5,as a zero instrument (Figs 29 31 Table 3); herep tho'compound.
Gacl 30 C6H5N02 could be even detectsdat 750. G4C1 3 exhibits much
lower electrolytic properties as compared with A1013 (Fig 4).
The measurement of the decomposition potential yielded 1.15 ve
while the potential computed from the formation heat of G&Cl 3 is
equal to 1.86 v. A similar reduotion of the decomposition
potential in contrast to the value computed was Also observed in
the solutions of aluminum halogen compounds in nitrobenzene
(Refs 26-28)9 and explained by the discharge of the solvated
Al-lone and the depolarizing effect of nitrobenzene. Thi.s should
also prove correct for the system with GaCl 3* There are 4 figures,
3 tablesp and 28 references, 12 of which are Soviet.
ASSOCIATION3 Institut obahohey i neorganiaheakoy khimii Akademii nauk USSR
(Institute of General and Inorganic Chemisti-y of the Academy of
Soienceal UkrSSR)
SUBMITTEDs July 2i 1950
Card 2/2

S/073/63/029/001/003/009
A057/-A126
AUTHORS: Fortunato'v, N.S.,-Fokina, Z.A.
TITLE% The solubility of gallium, indium, And thallium, chloride in sulfur
monochloride
PERIODICAL: Ukrainskiy khimicheskly zhurnal, v. 29, no. 1, 1963, 16 -. 20
TEXT: N.S. Fortungtov published in an eaflier work [Kompleksnaya perera-
bo'tka sullfidnykh rud (Complex reprocessing of sulfid-ic or6s), M. AS UkrSSR,
1 % 9] a method for the digestion of sulfidle polymetallic bres by chlorination
95
with dry chlorine gas in 'sulfur monochlorides (S2C12). The present paper deals
with investigations of th~ behavior of Ga, In, and.T1 chlorideu under such condl-'~-
tions. Quantitative data of the sojubility of-these chlorides in.S2CI2 or S2C121
respectively, with excess chlorine gas at 20 to 120'G were obtained and also re-
sults on-distillation of the chlorides with S2C12- Complex-formation in these
systems will be studied in future investigations.. The solubility 0was measured in
a thermostated cylinder with a stirrer at 20;, 40, 60, 80, and 120 C by determin-
ing Ga as oxide, and In and Tl polarographically~-The analysis of liquid equi-
Card 1/2
L

j r'.
B/073/63/029/001/003/009
The solubility of gallium,- indium, and thallium .... AO5'j/A126
librated phases was carried out at 25, 35, 115, 50, 55 and 65*C. A binodal of
phase separation was drawn for -the system GaCl3-S2Cl2- The complex. 3GaC13- SC14,
which is insoluble in S2CI2, is formed when excess chlorine is added to GaCl3 so-
lutions. GaCl3 is distilled together with S2C12. No TI could be distilled,with
S2C12 from TlCl, and only small amounts (about 10 times less than In the solution)
of InC13 were distilled. The solubility of InCl or TlCl In S2C12 does not
-Lion. The different behavior of
change by passing chlorine gas through the solut
Ga, In, and Tl chloride in S2C12 is apparently connected with the different de-
gree of interaction between these chlorides and S2C12. Possibly relatively sta-
ble GaCl3 solvates are formed, while no reaction occurs with TlCl and 1nCl3- This
decrease in the reaction rate corresponds to known literature data upon the drop
of "complex-formation ability" in the sequence Ga, In, Tl. There are 1 figure
,and 4 tables.
ASSOCIATION: Institut obshchey,i neorganicheskoy khimii AN USSR (Institute of
General and Inorganic Chemistry, AS UkrSSR)
SMIMTED: July 16, 19611
Card 2/2

FORTUNATOV, N.S.1 FOKINA. Z.A.; KOPA, M.V.; 1011i'I'LIK, 1-1.
Interaction of tetrachlorides of elements of group IV with cu.-ffur
monochloride. Ukr.khim.zhur. 31 no.2:148-153 165.
(miffil 28:4)
1. Institut obshchey i neorganiche3koy khimii All U~,rSSR.

---1 7
ACC NRI AP6029838 SOURCE CODE: Ull/01)-1?3/66/032/008/0900/0901
AUTHOR: Fortunatov, N. S.; Kublanovskiy, V. S..; Timoshchenko, N. I.; Fokina,_Z. A.
ORG: Institute of General and Inorganic Chemi~tg,_M__Ukr_5SR (Institut obshchey i
neorganicheskoy khimii AN UkrSSR)
TITLE: Chlorination in sulfur chloride medium with help of ultraviolet irradiation
SOURCE: Ukrainskiy khimicheskiy zhurnal, v. 32, no. 8, 1966, 900-901
TOPIC TAGS: chlorination, metal extracting, ultraviolet irradiation, sulfur chloridi
pyrite, sphalerite, molybdenum oxide, vanadium pentoxide
ABSTRACT: A series of experiments were desgfibed in w o4et irradiation
ulfidic jh ul;ravi
-temperature chlor 'Y 1
was applied in low ination-~f nd 4 Jdjqvdres for the pur-
pose of intensification of the process.. Eariie i V iron and zinc from
polymetallic sulfidic ores was found to be only 65-75% complete when conventional,.
low-temperature chlorination in sulfur chloride medium was applied Experimental
chlorination of pyrite, sphalerite, vanadium pentoxide (V20,5), and'-Iolybden,4m tri-
oxide (MO03) was carried out at 137C in a quartz tube irradiated by a PRK-.4nLamp19or
without irradiation. Chemical separation of the chlorination products was described
for each material. The percentage of material chlorinated with and without irradia-
tion was: in the case of pyrite and sphale'rite-78% versus 46% in 30 minj in the
case of V205-100 versus about 60% in 60 min; and in the cast! Of M003-80 versus
Ca;d 1/2 UDC; 66.542.944.03
"->7 V~'
4 rM , ,
M"M

--L-42824-66
ACC NR, AP6029838
about 202 in 20 min. A leveling of the yield at 80Z was observed in case of M003
chlorination because of substitution of sulfur for oxygen in the first stage of the
process. In all cases irradiation significantly increased the chlorination rate,
as shown by the respective positions of chlorination curves with and without irradia-1
tion. Orig. art. has: 2 figures. [JK];[
SU.B CODE: 1l/ SUBM DATE: 23Mar65/ ORIG REF: 0031AT-D PRE55,'S-d66
2

FOXINA, Z.V., zootekhnik-selekteioner.
..
fuld . PatIanIand to underrating broediM stocir. Ptitse-v,odstvo 8 no.506 %
NY 158. (MIRA 110)
1. Ptitsesovkhox "Pinoer.0
(%age)

POKINA,-,Z.V., aspirant
Raising cockerels for breading purposes. Ptitsevodstvo 9 no.4:33-36
AP 159. (MIRA 12:6)
lJoesoymnyy nauchno-Issledovatel'skiy in6titut ptitsevodetva.
(Roosters)

FOKINA, Z. V., Cand Tech Sci -- "Effect of various condi-
tions of rearing~rthe growth, development, and breeding
xv~4 H
qualities of b**sdIag roosters. Len-Pushkin, 1961. (Min
of Agr RSFSR. Len Agr Inst) (KL, 8-61, 255)
- 388 -

or inz.; HOLUBEK, Rudolf, inz.
-4M4.~1 L4
Possibility of using the Puccinellia distans as
.prospective grass for saline soils. Rost vroba
10 no. 3:331-342 Mr 164.
1. Higher School of Agriculture, Department of Feeds,
Nitra.

FOKOV, R. I., Cand of Tech SA -- (diso) "The ErO-Ctlon of MIulti-storied
Industrial, Buildings by the Verticle Flow Method,11 Khar'kov, 1959,
20 pp (Khar'kov Engineering-0 onst ruct Ion Instituto) (KL, 1-60, 123)

FOKOV, R.I., lrand.tekhn.nauk; AGAYAN, M.A., :Lnzh.
Construction of a new type of interlocked industrial building
by assembly-line methods. Prom. .stroi. 40 no-5:4-9 162. (HIRA 15:5~.
1. Kharlkovskiy inshenerno-atroitelinyy institut (for Fokov).
2. Trest Mosstroy No.2 (for Agayan).
(Factories-Design and construction)

SHVIDENKO, Valentin Iosifovich,, prof.1 MATOKIIIN, Vladirlr Pavlovich,
dots., kand. teklm. nauk; R-11MOV, Aleksey Mikhaylovich,
dots., kand. tekhn.nauk;-fD-K Rostislav I-vanovich,, kand.
tekhn. nauk; CRERNYSHEV, Sergey
nauk; YAKDIENKO, L.I.,, red.
[Assembly of multistory industria: bi,"Idings] Hontazh mnogo-
etazhnykh promyshleraWkh zdanii. Rharlkov, Izd-vo Khar*-kov-
skogo univ.,, 1964. 142 p. (MIRA 18:3)

L"'. .- I f
I L 1t6 a ~ I ~, !;,i . L-'r hr: . F -Sji , A , 1 --. 7"1. ; , I . ': . , 1 ; Z;i .
0 - --l-1--
i 'I nm~ing organ.l. zat.!~.,L ,,f r, I i,~ - o!.:: ! u,~ I ~',, ,: oj' a 1~ -. i - Li t. r Ia.l
17,
I ~o ~ Lii ng. Prom.stroi . 42 r(j.",?Z 1-9 1" 5o I RA 'A 8 -. 8 )

YOKS,A.D.; MILLAR.B.Te.; VRIS,M.T.; LCKIZB,L.G.Ctranolator];NIRDUKOV,
an Gayevicho redaktor; KRYUKOV,I.A., redaktor; ICRMNV,]I.N.,
tekhulcheskly redaktor
[Behavior and application of ferrites in the microwave region.
Translated from the linglishl Svoistyq, ferritoy i ikh primenenie
v diapaxone SYCH. Perevod a anglilskogo ij.G.Lanize. ~Konkya, Ixd-
Yo "Soystakoe ,adlo," 1956. 99 p. (KLRL 9:3)
(Ferromagn,stism) - I

MISZELp Leon; TCCS, Branon
NOW 1,
Aboratory appliance blood taking from the finger. Polski
tygod. lek. 9 no.41:1332 11 oot 54.
1. Ze Stpitala.Klejoklego v GlIwIo&ch, odds. wown, 11. ordynator:
dr Leon Miszol. dyrok-tor Sspitala: dr Wladyalav Orlowski*
(3100D,
taking from finger, appar.)
(EMKATOIDGT~ apparatus and instruments,
for blood taking from finger)

ITO;, t
F~-,3
4 9 6, 16-1"
Ak f1d f~., ;1! 1

kDKSHA.-A.G~r-inzh.; MATYGIN, V.M., inzh.
Ways for reducing the acidity-in.-the production of edible
hydrogenated fatc. Masl*-zhir. prom. 29 no.WO-22 Ag 163.
(MIRA 16tlO)
1. Khabarovskiy filial Vaesoyuznogo nauchno-ii3sledovatellskogo
instituts zhirov (for Foksha). 2. Khabarovs)cLy MRS102hirovoy
kombinat (for Matygin).

FCKSHA, L.T.: BALA.KHNICMVA, T.. red.; RAMMOBAUY, M., takhn.red.
(Trade of the Moldavian S.S.R. in the seven-year plan] Torgovlia
Moldavskoi SSR v samiletke. Kishinev, Gos.izd-ro "Kartia Moldo-
veniaska," 1959* 99 p. (MIRA 13:7)
(Moldavia--Retail trade)

FOKSHAUSKIX$--Xu,L.
Some features of the structure of the basement of the southern
Moscow syneclise and the Ryazan trough based an data from
geophysical studies. Geofiz. razved. no.8:56-667 162. (ILTRA 15:7)
(Moscow Basin-Geology, Structitral
(Prospecting-Geophysical methods~

-------------------
The variation of tho'cle -ctrical c?oductivity a cortalu M
a 0 '-"uQilype. 1'. Dft4n
dittance RHO I th QIq- '" IL,
I hlw" -a &w-4T
w" Col. rt~. Wisire
in 3, XIMMu French), c L CA. 53,
-The tel" -Muf .characurlst" of 5 alinys am
2812d.
discimmd on the of 2 hypothem, Otte, a prolmrsed
order-ilLsordei trandorniation, accounts for the rknit of temp.
over willch the chaiudetistic has a ues. slope, fhe other
jWMIN tho same tcnip,-coud. varlation, but postulatex the
rathild disappearance Uf wtaln agglomerates (lactmas)
the Solld win. with larmashig temp; For the Cr,~-Nl
alloys studied, the Hall donst. Is As a. result, for more
of the electrons, there.6 a 2nd=Llianistu of conduction
through'the lacuoas~ This complex method of coodtictlon
1A - !, . . . t'
I occurs, (firectly " a tesult of impurities and dtfect,,irt the
Lu er.level of die conduction band, 9~~er!Lm4
_pp_

Af

f c'
ell! to-
,
some resistant allaVs nt ----P
jDRA, D, Ryl and &ZM- 4cad. to 0
Romine-, Siudis " C*r4d4F
)0-~

l
Investigations M it out In n er to if rcs taut:
i
lli
j
i
h
ibl
f
f
nieta
c n=trrio
nt o
ew t
e
s from the po
v
ev
sernicond.behavior. Wire specimens were prod ' in ractio,
and measurements of elec. resistance were also caff led out in
10
Th
i
d
N1 7D
C
0
v4cuo.
e specimens conta
r 2
ne
.
.4,
;
: Q)
N178.45 Cr 19,40;~(3) N178.11, Cr 20.25, (4) Ni 4111,~
u 68
6
52
The r
ere:
(31 NI 20
Cr 7
2
Cu 71
siAts
1%
.
.
,
.
e
.
w
,
;
,
plotted In a coardinate system of log cAir - elcr. cond. in'
in./ohm sq. tutu.) and'1/7' X 104 (T - abs. te-
`
'
1
f
,and 2 present a wzdcond.'component; 3, In a limilte
tt
mp
,
range; 4 has no such comp
onent and has a typically me
.
lallic behavior; 5 shoWs neither semiconductor co Ponent
inor metallic behavior. It Is hypothesized that a modifica-:
~Iau Lhe Interat. bond taW place owirg to alloying
~j

D. DY
the Orc. "If"I t1wrip
'91)-Z11 giloyl fire jnvc~.Aigatcd as (mictium, of thAr.
att: prCAuctt't rucl
he
~Jlpu, awl -'strilcture,
do' At. - ZU, pufwittl t"W-iu, alidsh, jmrjl~oj 11) 90 W
ot I'll
'I pul 1, " 4,1n, tC!
,vaure (it tilealloys, ~~jllwi 1~
14.320
at
WitJ00-45% wl the s~fllh orl P
113 't no, 41 01w Mlayg th~ utivoi
*Crgy for the therin tranaltitmi of the chuge orri
courl, (cYW a i-~ 4 ML
z 11 the etitirp, rakt W the r-Moy iymem
IVA
yv4cim~ P, flgx~
4
'3i
P.

A
I/Serniconductor Drovirtlesi-ol cadmium. mamon Alto
Y-.!
1i LIN u Volpta Urtlact's erk
(19M); cf. Purkov. CA. 31. 11051a.-A literuture ourny
d the phim dialtain Cd-& revealed 2 definite compounds
CdSb and C". Because of the difference in w.p. of Cd
and Sh, their great,reactivity. and the volatility of Cd. In
order to fm= pure and stable compounds, the melting and
of the alloy was perfanned In evacuated (10-2 to
p M.)
v OfAcnat"Ond Mrtz.b usingCdand9bothigh
5 and for the last series Of
Forty allny$ of vado"
compus. were prepd., In rectamila, ban (3 X 6 X 80 mm.)
with all fares polished by metalkemphic techniques.
Microdnicture, microbartlum, tlec. resistance, and thtnno-
e.m.f. were detd. The structural constituents were "yzed
selective attack rcagwta; the semiconductor roperties
1he allM were evaluated by dett. the clec - rest tanee as
function of compti., the eke. cond. as function of temp., and
the mean coeft. of the tbetnu)--e.mf. Better semiconductor
vroperties wet (ound for Cd3b the clec resistance of which
6 OW times (22.210 ohm-cml and th; mean coeff. of the
thermo-e.m.f. 200 times, that of pum Cd. Inalloyscontg.
excess of metal these values am considerably reduced, but
not In accord with the distribution of the constituents In the
alloy. . No semiconductor properties were found for Cd,Slh.
The theoretically expected correlation between the coeff. of
thermo.t.m.f. a and the elec. cond. v, of differently propor-
tioned alloys of Cd and 6b, a - A - 8 Idg a, was verilled
espil. for the region Cd + CdSb. The expLI. results were
Interpreted In light of the electronic theory of metals and
semiconductors. aad hypotheses were suggested for expluna.
tiou of A'tBv phases, the structural, phys., and semiconduc-
tor properties of ZnSb and CdSb being compared.
M. Ben Elieser-
J

Distrt 4M.(g)/4E2o/4E2d(b) 2 070
trule compounds th kin
o
of the type A11Wv. T. Dultmitil, DHIiiii-.31a
A cad. rep. PQPWdF# MR ones udio'ce-re-eUR wd. MNM
t(1959).-Two compds. of the type A11BTV, U&SU aw
(which crystallize In the reciprocal system of 81 and'
Gt), wem compared in order to det.,lbe Influence of the lat.
tlcc structure an tile sc e haracterlstics and In'
e M,
;What way they vary ime column (of the periodic',
;table) %a a funedon'of the sit. no. of one of its components.,
The comptis, were prepd. by usl tile purest available com-
nents, melting under a protecive layer of anhyd. M Cl
anhyd. KCI 40, and NHXI 11 in a hite crul"IT111
R
necessitatlut on initial excess of 101fir (21r.9 the can 01
Mv%) In order to achieve rigorous stoldilometric compn.,.
then a thermal treatment (48 hrs. at 450-W. Inert atm
I cooling to 2009 at 100/hr.). a subsequent more *dvzQ
purification, and eventual production of a men
The specimens underwent metallographle and mi=crotard.-I
ness study. The semiconductor properties were detd. by,
tom aring the resistivity. measurements, -by detn. of them
elenond. variation with temp. (20-M*) and of the sign
and value of the thermo-e.m.l. * SIncd Mg& was found to
be a seralc6pductor, while MpPb has metallk properties, It
Ilk not the'cr)st. structure which dtts. semicond. This
transition (along the periodic table column) of semiconclac-
tar propertle3 to metallic properties. can be explained bK the
fact that the probAbi It for the electrons In the pedp tral
hecollactloo level Into the valence level
'ay to of the element. Thus,
at
gro I the the char.
,tRUE
I the 't tat, compds. can be predicted.
17 references. At. Ben Bfitsw-

fECSIS, Istvanne; FOKY, Jozoef Patka); FUZI, Dezoo (Budapest)
Forum of innovators. Ujit lap 12 no,17:30 10 S 160.
1. Szegedi Ruhagyar ujitasi eloadojak (for Kofsis).

FOLLK) Feliks; P01MI9dICZ-KACaWtSKAp Jadwiga
Narrow- and wide-pore silicagels as drying agonts. Przem ahem
40 no.12:702-705 D 161.
1. Katedra Technologii Chemicznej, Universytet Jagiellonski,
Krakow. -

FOLIBY I.L.
Pathogenesis of' muscular I-n Vestsi
"1 11 1
AN BSSR. Ser. biial. nav. no.2:111-~-o t;+.
(MIRA 17:11)

AutomRtic Micro bur e t f'~, r Fmp t- r I t. rar i C'n .Lab. dkl!O
nc.8;507-509 161, (MIRA 18,9)
1. Sektor gerontclogi~-* (zav.- prof. V.A. Leonov); AN BSSSR --'
kafedra andokrinclogii (znv.- dotsent N.11A. Draz.-lin) Belo---~5c!koga
e,osudarst-venriogo izistltur.~l Rye
Mul n9k.

Ak4345257 BOCK UPLOITATION S/
Fol'tl Ra?jilll Llrovna !-W,
P-Inciri-es of visual flashing-Light sirviling (Ognovy4 vimuslIncry protleskoyoy
I" Mo!lc ow, -zd-zo lHa3hinnstrovenlymn, 0
r f~., C 0, 1r n e,4 v wo CFV
pies
S rlas~~ )anr, photosensitivity, nignal
1 /-7
,- ~hl-q b-ok was 'or r-5--a-cr r
A
'.n ~Jno! derelopipe,~, Ar~d le-s!cT -1
r c'..
r --ir
1. v z
n f IA s ,)m ri or! Dr n c e c f! m 1: a
Card 1/3