SCIENTIFIC ABSTRACT FLELYSHMAN, V.G. - FLIDLIDER, G.M. (MOSCOW)

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000413320015-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 13, 2000
• Sequence Number: 15
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

50)
AUTHOR: Fleyshman, V. G. SIOV/64-59-1-3/24
TITLEi For a Faster Development of the Chlorine Industry
(Khlornoy promyshlennosti - bystryye tempy razvitiya)
PERIODICAM Xhimicheskaya promyshlennost', 1959, Nr 1, pp 9-16 (USSR)
ABSTRAM For the coming Seven-year Plan an increase in the production
of chlorine by 3.3 as compared with the preceding one is
provided. At present, the major part of the plants of the
chlorine industry is working with electrolyzers BG.K-13 with
a load of 5000 a; during the Seven-year Plan, plants BGK-17
with a load of 20-25.000 a, even with tanks up to 100.000 a,
shall be introduced, raising the capacity of some plants
by 5 - 6. The acceleration of the production of synthetic
fibers also requires an extension in the production of
caustic soda which is carried out abroad according to
different methods (3 tables). Domestic and foreign data of
diaphragm and mercury electrolytic cells are compared,
and investment savings by higher current intensities
(Tables I - 3), and electrolytic tanks with 30-000 and
100.000 a (Table 4) are indicated. The production of
Card 1/3 various inorganic and organic chlorine products is described,
K~W '09

For a Faster Development of the Chlorine Industry SOV/64-59-1-3/24
and the total output of both types to be produced between
1956 - 65 is compared with (Table 5). The production of
methyl chloride, for instance, shall be more than 30 times
in 1965 than in 1957, with an increase in capacity by 50.
The chloroform production shall be increased by 3 in 1965,
and Freon-22 and fluoroplast shall be made of it. Carbon
tetrachloride shall also be produced to an increased
extent and be used for the preparation of Freon-12 and
flaminoenant acid". The vinyl chloride production shall
increase by 10 by 1965, and the entire organochemical
industry based on acetylene shall be much intensified.
The production of phosgene and herbicides shall be
increased, and new plants for the production of different
detergents shall be built. Some tasks of the research
and planning organizations are illustrated, and it is
mentioned among other things that NIIkhimmash will develop anew
dhlorine rotary compressor -with a capacity of 2.000 m3/hour,
and a high-capadity (800 m3 of chlorine per hour) piston
chlorine compressor without sulphuric-acid lubrication
Card 2/3 will be developed at the LenNIIkhimmash for the production

For a Faster Development of the Chlorine Industry SOV/64-59-1-3/24
of liquid chlorine according to the compression method.
The UkrNIIkhimmash will design an automatized evaporating
plant with a capacity of 120.000 ton's/year for
electrolytically obtained lyes, as well as a new automatic
rubber-lined hermetic centrifuge. The Tsentrallnyy
konstruktorskiy byuro gidravlieheskikh mashin (central
Design Office for Hydraulic Machines) shall develop a
hermetic pump with no stuffing box, and release it for
production. Besides the above-mentioned examples, several
other examples of the planned production are indicated.
There are 5 tables.
Card 3/3

AGAFM- T, N.I.; BUATOV, P.S.; ZVMV, B.P.; IYANOV, I.A.; KMGLYr, S-X-;
xIWy, I.M.; J%WSEKAN, V.G.g XMIN, V.A.; SMR, V.A.; JLISKIr, T.N.
Condensation of a solution in vacuum evaporator installatioxwe
Promeenerg. 13 noAW-16 Ap 16o. (MIRA 13:6)
(Byaporating appliances)
I

ALEKSEYEV, G.A., prof.; GMSHPUN, L.D.; FIZYSM421, Ye.V.; CHERNUK, V.Ya~
Macroglobulin reticulolymphomatosis (Waldenstr&ala disease). Terap.
arkh. no.7:17-21+ JI 162. (MLRA 15:8)
1. Iz 3-y kafedry terapii (zav. - chlon-korrespondent MGI SSSR
prof. I.A. Kwairskiy) TSentrallnogo instituta usovershenstvo-
vaniya vracheye (MACROGLOBULINS)

GRINSHAN, L.D.; FIZYSHKAN, Ye.V.; DUBROVSKAYAt V.S.
Diagnostic value of Thorn test. Lab. delo 10 no-5:265-267 164.
(MIRA 17:2)
1. 111 kafedra, terapii (zaveduyushchiy - deystvitellnyy chlen
AMN SSSR I.A.Kassirskiy) TSentrallnogo instituta usovershenstvo-
vaniya vrachey, Moskva.

POCHTAREM, H.; ZILIBERMAN, S., inzfi.-tekhnolog-, Y=SHMIIS. 0.,
inzh. po trudu
Five-day working week in a tobacco factory in Riga. Sots.trud 4
no-3-*113-115 Mr 159. (MIRA 12:4)
1. Direktor Rishakay tabacbnoy fabriki (for Pocbtarenko).
(Riga--Tobacco industry)

1, MIRIN, P; S., and FLIATE, D. M.
2, USSR- (6oo),
4. Yakimov, P. A.
7. Glaring errors in the description, of the production of pulp and paper ("Cellulose
and fiber plants of the.U. S. S. R.' P. K. Krasillnikov, P. A. Yakimov.
Reviewed by P. S. Larin, D. H. Fliate). Bum. prom. 27 no. 6. 1952
9. Monthlj List of Russian Accessions, Library of Congress, rghWry -1953. Unclassified.

r eniuv7; JORDAN, Jozef'
Contemporw-y vipvj on the e'rculation of labyrinthine fluids.
Otolaryng. Pel. 19 no-ItI49-155 165.
1. Z Kliniki Otolaryngologicznej Akademii Medycznej w Gdansku ..
(Kierownilc: prof. dr. mad. J. Iwaszkiewic~rz) i z Zakladu Aha-
tomli Prawidlowej fil--demii Medyc--nej w Gdarsku) (Kiero-~mikt i.
prof. dr. mad. 'Yr. Lasi-naki).

FLIC-INZE, Eugenjus-,
Neurofibromatos.-Is of the tongue in generalized FecklInghausen's
disease. Otolaryng. Pol. 18 no.1:153-155 164.
1. Z KlIniki Otolaryngolocicznej Akademil Medycznej w Gdansku
(K'crownik; prof. dr med.cJ. Iwas--kiewocz).
-M

,FLICINSKI,,,~~pniusz; KOWALCZUK, Ifenryk
General anesthesia with trilene and nitrous oxide in otolaryngo-
logical surgery. Otolaryng. Pol. 18 no,2:259-261 164..
1. Z Kliniki Otolaryngologicznej Akademii Medycznej w Gdansku
(Kierownik: prof. dr. med. J. lwaszkiewicz).
;~g
M~
qu,
MW
-N
-,R i- t- - . , , " 5"t

ME
FLICIVSK nnin m; KO'.-IALCZIFK, Ifenryk
-
Anestbasia in otolaryngological practice in the Academy of
Redleine In Gdansk. CYtolaryng. POI- 1t -10-4:537-541 164
l. Z KlIniki Otolaryngologiewo-I Akadmii Medyczne' ur Gdansk-a
(Kierownike. prof. dr. med. 3. Ivanklewics.

FLICINSKI, Eugeniusz
A case of keloid of the aural concha. Otolaryng. Pol. 19 no.3:
401-402 t65.
1. Z Kliniki Otolaryngologicznej AM w Gdansku (Kierownik: prof.
dr. med. J. Iwaszkiewicz).

ACC NRt AP6036045 SOURCE CODE: UR/0121/66/~';(,,0/010/0016/00ii3~
AUTHORS.- Flid, M. D.; Degtyarenkot N. S.
ORG: none
TITLE: Factors affecting the productivity of resilient grinding of hard alloyal
using grinding wheels
SOURCE: Stanki i instrument, no. 10, 1966, 16-18
TOPIC TAGS: grinding$ metal cutting, grinding wheell metal alloy/ T15X6 metal alloyl
VK2 metal alloy, ASO10M5 grinding wheel, ASO6B1 grinding wheel
ABSTRACT:' Experimental data are presented and empirical relationships are derived to
show that the influence of technological factors and operating regimes on the
productivity of resilient grinding (the contact load is applied throu&, a resilient
element: 1-3 kg/mm) of hard alloys. Grinding wheels AS01OL15 and AS0631 were used on
alloys T15K6, VK2, and several other alloys. Effects of speed (6-30 M/sec), contact
force (1-15 kg), properties of machined metals, contact area, and grinding wheel
--properties on the productivity (mm3/min) were measured and are presented. Empirical
.relationships based oii these curves are established for each of the important
and a general empirical equation for the productivity of resilient
inding'as a function of pertiment parameters is established in the form
tard 1/2
UDC; 6214923.4:621.921.34:621.9.025.7.001.5

ACC NRs AP6036045
Q C (CIr vXPy F~IkACIIIII
where q -,productivity; a- izg ~banding strength of machined metal; v - grinding
speed; PY - grinding force; P - grinding area; CI; C'T I Kz' Kk' X' Y' and z are
constants which are tabulated for the two types of grinding wheels tested. This
equation is also solved for the necessary grinding force (P ) to give a certain
Y,
.productivity, and an example of the necessary calculations..is presented. Orig. art.
has: 5 figuress 3 formulas, and I table.
SUB CODEt 13/ SUBM DATE, nons/ ORIG REP, 003

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FLID, H. M.
USSR/Chemistry - Hydrogenation Jun 1946
Chemistry - Dehydrogenation
"The Kinetics and Mechanism of Cataly-tic Hydro- and Dehydrogenation," M. Ya. Kagan and
R. M. Flid, 13 pp
"Zhur Fiz Khim" Vol XX, No 6
Describes method and results of experiments using benzol, toluol, hexamthylenej and
methylhexamethylene. Graphs, tables and chemical formula.
PA 18T78

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pitie RSS. 21, English);
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lei ftwflon Ctifur + CJIsCIfs z4 CJI* + callicill
we stwikd In both loevad and reverse directlacts ovvr a
I'd (10% Pd on Si(h gel) and a CrA (Xr~ Crt0j an SA
gel) catislyst. The temp. mop inwrttilatmi w" W-
170* for the Pd. 327-3W' for the CrA)j cStitirt. Them
w4ti no It evolved. The activation energ" of the fof-
rctvtw rcutions ue an
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ItS.-ad. on CrAh. IkWmpuntim ol
cyclotwune over CrM in abornee of a 11 acmptcw Nith
filmrstion of It.) has an activation enffgy o( 40 ks. ral-
The rate date Indicitte, the conjuWe deb."tro"tion it a
reversible firm -onlrr rrwilon. It is retarded by toluene
ocul brnxvw over IM, but not over CrA. The dchydro
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, I was atmilf1l. rcdL:-.cd Cu. ZnO. ZnO (0.5
Rild 61~10 "411,M). nhunlatirn Silicate, Illufninunt loilio4v!
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trented wilh NnOll, Al..Ol, illics Kel, and H&PO. on C.
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allyl -tic, is vivwcd a.1 a collthillcul roctfoll of 11thydro-
xenation tiliff hydrugeiinfloa wlfli cumbineit R atwording tu: t
CITIXIWI-11011 + I -.;~ CIT"ClICI-10 (."JAorbell) + 1-11.1 1 .
14t. 4 CJI,:(-'I-ICIIO ;=! I + HIC110 6,hathed): HIC110 1

FLID, R. I".
USSR/Chemistry -,Reaction Kinetics Dec 53
"S. V. Gorbachev's Article on.thi Theory of Self-
Accelerating Reactions,"'R. M. Flid
Zhur Fiz Xhim, Vol 27, No 12, PP 1885-6
Discusses--g. V. Gorbachev's comparison (Zhur Fiz
Khim, Vol 26, p 1504, 1952) between N. A. Shilov's
kinetic eqs and those of Christiansen and Kramers.
Disagrees with his conclusions on the ground that
he used erroneous derivations of both set of eqs.
275T19

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and im is the Wak strength of the sci it'- fl.rxt~-. 1,
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of the khafted and ca-loaimed base Cas- -Cs hd~IM"I
te d ., C-A. Zfi, AMS) by fit - log ( Cm, - C& K. - ,
Exp(l. values at y as a function of ;, -e - v
Minx. of !.O?I~Lf 11CI to which trt ~dd-~j 1 .5' fk-~Af & ~
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of )~ vs- &0 is usez . giving L - Q Ilk) P..' '' -1-
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USSR/Kinetics. Combustion. Explosions. Topochemistry. Catalysis. B-9
Abs Jour : Ref Zhur - Xhimiya, No 8, 1957, 26250
Author : M.Ya. Kagan, R.M. Flid, N.S. Prostakov
Inst : Moscow InstI:tu-f_e_or_7tne Chemical Technology
Title : Kinetics of Contact Isomerization of Allyl Alcohol into Pro-
pionic, Aldehyde.
Orig Pab : Tr. Mosk. in-ta tonkoy khim. tekhaol., 1955, vyp. 5, 45-49
Abstract : The'dependence of the yield of propionic aldehyde at the con-
tact isomerization of allyl alcohol on temperature and con-
tact duration was studied; Cu precipitated on pumice was
used as catalyst. In the authors' opinion, the catalyst
activity is dropping during the work in consequence of the
poisoning of the catalyst by a polymer film dorming on its
surface. The drop of the catalyst activity is accelerated
by the temperature rise and does not depend on the volume
speed of the allyl alcohol flov. The reaction under study
is of the zero order at 200 to 2200; the activity energy
and the constants of the isomerization speed were computed.
Card 1/1

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Subject
Card 1/1
Authors
Title
Periodical
Abstract
Institut~on
USSR/Chemistry
Pub. 152 - 6/20
AID P - 3569
FlidJ- R. M. and I. I. Moiseyev
Interaction of some components of catalysts during the
liquid-phase hydration of acetylene
.1 11
: Zhur. prikl. khim., 28,'~"711-717, 1955
: The reactions of mercury and of sulfates of mercury with
ferrous and ferric sulfates have been studied. The
experiments were carried out at 90-950C in sulfuric acid.
The effect of S04-ion, aluminum sulfate and sodium
sulfate on the voltage is determined, and the data com-
iled in tables. Six tables, 1 drawing, 10 references,
Russian (1946-1954).
: Moscow Institute of Fine Chemical Technology im. Lomonosov.
Chair of Technology of Basic Organic Synthesis
Submitted : Mr 30, 1953

UNK

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17, 12W . 1005
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AcOll over Zri(6A'C~, on a mrricr %Qj~ At
with the cafrier of dc6assi-d C, fumLlf"-~,- o, Via i ~
C(byllyl acmte deptalds rnil CG the P~rtial p-,cisui,
Ac-011; tht low~x mncn. of uOij teads to pyt Ligiizr
yield3 Of VinYl ACetate 211d L-Wer Yiel& i etbyllyl
In erpts. at 277G-00' vrith A4~ c=-ricr, ircm-ved spacic
velcxity of the grs milt. mi3es the Yield cf
tate~ Pa---~Ce ot ~hzYl ft(:Ctate gind AcOll ilvtr the Catalyst
at 220-W, d= not Yidd dthyttyl mertate. Tbtnr,,~-
dy7r-,a-.Pjc analym$ of JU reailtj ImIlmles t1lat
acetate frrmq du'c,-tly from ejfs :Ep,l the jjll~cr a., A~, H,
Whtrels viayl ficeta-tc forras from ctrij and munumuerjr
Acolf, "I. F~ZZff r

lj
NI

'Al.
20-2-31/60
AUTHORSs Flid, R. M. , Mironovj V. A.
TITLE: The Kinetics of Liquid Phase Hydrobromination of Acetylene
in the Presence of Mercury Salts (Kinetika zhidkofaznogo
gidrobromirovaniya atsetilena v prisutstvii soley rtuti)
PERIODICAL: Doklady Akademii Nauk SSSR, 1957, Vol- 114, Nr 2, PP-347-350
(USSR)
ABSTRACTs There exist relatively few scientific papers on the catalytic
interaction in the liquid phase of acetylene with hydrohalides
in presence of mercury salts. Acetylene hydrobromination has
been investigated only in the gaseous phase. According to the
data available, there are formed, in addition to bromovinyl,
also different isomers of dibromethane or their mixtures.
From reactions of hydrochlorination and hydroiodination only
asymmetrical adducts were identified among the dihalide deri-
vatives. Because production of both isomers of dibromethane
appeared to be possible, the authors of the paper under re-
view carried out the investigation outlined in the title of
Card 115 the present paper. A The influence of the relation between

20-2-31/60
The Kinetics of Liquid Phase Hydrobromination of Acetylene in the Presence
of Mercury Salts
reagents upon the degree of conversion of acetylene.. It was
determined that the total degree of acetylene conversion as
well the yield of vinylbromide and ethylidendibromide do not
depend on the relation between the reagents, this relation va-
rying within the limits HBr a C H 00 1 4. The dependence
obtained made it possibleg compMely obviously, to determine
the zero-kinetic order of the reaction with respect to hydro-
bromine. B. The influence of the contact duration upon the
speed of the acetylene hydrobromination. The kinetic measure-
ments showed, (1), that the formation of 1,1-dibromethane is
the result of a simultaneous attachment of two molecules of
HBr and C H , without vinylbromide partLeipating as interme-
diate progu2t; thus the reactions cf formation of vinylbromide
and of ethylidendibromide are two independent parallel re-
actions; and (2), that both parallel reactions are of fimt
order with respect to acetylene with a hampering by the two
reaction products. C. The influence of the concentration of
acetylene hydrobromination. As can be seen from Chart Nr 2
of the present paper, cc increases monotonously when the
Card 2/5 concentration of HgBr2 isoincreased, 0~1 goes through a maxi-

20-2-341/60
The Kinetics of Liquid Phase Hydrobromination of Acetylene in the Presence
of Mercury Salts
mum, and 0G increases rather sharply. This fact can be con-
nected with2the increase in the probability of the collision
between the acetylene molecule and two molecules of the ca-
talyzer when the concentration of HgBr2 is increased. There
exists reason to assume that the reaction is catalyzed by the
ion HgBr because HgBr , being saturated with respect to
the coorhnation, can Aardly participate in the activation
of acetylene. On basis of kinetic equations, speed constants
of the reactions were computed for all four concentrations
of the catalyzer; the values~f these constants increase as
the concentration is increased. The authors of the paper
under review maintain that the activation of acetylene is
based on a withdrawal of the doublets of cK,-electrons. If
the limiting stage of acetylene hydrobromination is supposed
to be its activation, a "sympathy" must exist between the
potential of oxidation, as measure of its acceptoric quality,
and its catalytic activity. Reproduction Nr 2 of the pre-
Card 3/5 sent paper shows that the linear dependence between lg K

20-2-31/60
The Kinetics of Liquid Phase Hydrobromination of Acetylene in the Presence
of Mercury Salts
(constant of the speed of the reaction) and E for both re-
actions of hydrobromination, and the total conversion cf
acetylene is preserved. In this context, the only possible
cause for the increase in speed of the reaction is the de-
crease in activation energy as the value of E increases.
The linear form of the function 1g K makes it possible to
state that the acetylene activation is the limiting stage
of the processes of hydrobromination. There are 2 figures,
2 tables, and 4 references, 1 of which is Soviet.
ASSOCIATIONs Moscow Institute for Fine Chemical Technology imeni
M. V. Lomonosov
(Moskovskiy institut tonkoy kbimicbeskoy tekhnologii
im. M. V. Lomonosova)
PRESENTEDs December 14, 1956, by I. N. Nazarov, Member of the Academy
SUBMITTEDi December 7, 1956
Card 4/5

20-2-31/60
The Kinetics of Liquid Phase Hydrobromination of Acetylene in the Presence
of Mercury Salts
AVAILABLIo Library of Congress
card 5/5

AT
AUTHORS: Rapoport, I. B., Flid, R. M., and Lis,K. 20-2-23/50
-------------- Z_
TITLE: On the Polymerization and Cyclization Reactions of
Isobutylene (0 reaktaii polimerizatsii i tsiklizatsii
izobutilena).
PERIODICAL: Doklady AN SSSR, 1957o Vol. 116, Nr 2, pp. 244-247 (USSR)
ABSTRACT: The polymerization of olefines with different numbers of
carbon atoms takes place at not high temperatures; at
elevated and non-elevated pressures and in the presence of
various catalysts which possessproperties of acids. Thermo-
dynamical data on the polymerization of isobutylene show
that the reaction very thoroughly takes place at 100-2000C.
A rise of temperature reduces the activity of the catalyst
due to its poisoning with resin products. The products of
polymerization are the satne on aluminum-silicate catalysts,
independent of the fact whether these latter are synthetic
or taken from nature. Dimers and trimers are the chief
products. The speed of polymerization of isobutylene is much
higher than that of butylene (according to Kazanskiy and
Rozengart). The polymerization of butylene on aluminum-
Card 1/4 silicate catalysts is accompanied by an isomerization under
A

On the Polymerization and Cyclization Reactions of 20-2-23/50
Isobutylene
formation of various isomeriv octenes. At 3700C olefinelike
and at 450-5000C aromatic hydrocarbons form. Higher compounds,
up to pentamers, can also form on various catalysts.
According to thermodynamic calculations the aromatization
reaction is also possible for isobutylene. The thermodynamic
analysis made by the authors as well of the gross reaction
as of its individual stages leads to the following main
conclusions: 1. The gross reaction 2C A _3H +C H (CH
4 0 2 6 4 3)2
(0-P M-1 P-) (table 1) is possible (when P~ - 1 atmosphere)
with a practically complete conversion of isobutylene
already at lower temperatures (120-1300C) under a predominant
formation of m-xylol. The equilibrium of the stage of
cyclization of isooctene to isomeric (cis- and trans-, o-,
M-0 P-) dimethylcyclohexanes is practically independent
on temperature displaced to the right. 2. The degree of
dimerization of isobutylene decreases with increasing
temperature, With increasing pressure the reaction is some-
what displaced to the right. 3. A -dquilibrium yield of
Card 2/4 a xylol-mixture in dehydrations of isomeric (cis- and trans-,

On the Polymerization and Cyclization Reactions of 20-2-23/'50
Isobutylene
0-9 M-9 P-) dimethylcyclohexanes increases with increasing
temperature. A full conversion can practically be attained
at a temperature of 6000C (when P - 1 atmosphere). After
some considerations on further possibilities and desired
investigations the authors state that the present paper is
dedicated to the study of the polymerization and aromatization
reactions over the catalyst MoO 3- Al203* The experimental part
with the usual data and conclusions follows: 1. The poessibili-
ty of a polymerization with subsequent aromatization of iso-
butylene over a molybdenilm-aluminum-catalyst was for the
first time proved. 2. At temperatures up to 2000C the
polymerization reaction over the above-mentioned catalyst
proceeds under formation of di-, tri- and still higher
polymers. The direction of reaction changes with increasing
temperature and aromatic hydrocarbons appear in the product
of the catalysis. 3. In the fration boiling at 132-1480C,
which had formed on the passage f isobutylene over the
Mo-Al-catalyst at 4000C, up to 60% para- and meta-xylol,
i.e. about 6 g per 1 m3 gas were determined.
Card 3/4

On the Polymerization and Cyclization Reactions of 2O-;2-R3/5Q
Isobutylene
There are 4 tables and 7 references, 6 of which are Slavic.
ASSOCIATION: Moscow Institute for Fine Chemical Technology imeni
M. V. Lomonosov (Hoskovskiy institut tonkoy khimiebieskoy
tekhnologii im. M. V. Lomonosova).
PRESENTED: By B. A. Kazanskiy, Academician, May 4, 1957
SUBMITTED: May 3, 1957
AVAILABLE: Library of Congress.
Card 4/4

?LIDO R,M,; NVCWBOVAO N.Y.
&.11WIation of benzene with dimethyl other. Xhim. muka I
promo 3 no'2:286-287 158* (XIDA IDO
0
1, WDskovskly institut tonkoy khimicheakoy tokhnologii Im. move
Lomonosovas
(Benzene) (AlRylation) (F-ther)

FLID, R.M.; IRASOTKIN, A.Ye.; SHPICHIUTSXATA, L.S.; CHIRIKOVA, A.V.;
MMYY, A.P.; BARATS, M.I.; KRUPTSOV, PiK.; BOXANINA. Ye.T.
IfIffect of alcaline admixtures on Qatalytic oxidation of primar7
alcohols to aldebydes. Xhim.nauk i prom- 3 no-5:683 158.
1. Moskovsk1y institut tonkoy khimicheskoy tekhnologii. im. M.V.
Lomonosava.
(Alcohol) (Oxidation) (Cataaysts)

SOV/81-59-i6-56362
Translation from: Referativnyy zhurnal. Khimiya, 1959, Nr 16. pp 52-53 (USSR)
Flid,_Djj,, Golynets, Yu.F.
TITLE; On the Physical Interpretation of I.M. Sechenov's Equation
PERIODICAL: Tr. Mosk. in-ta tonkoy khim, tekhnol., 1958, Nr 8, PP 111-115
ABSTRACT-, It has been proposed to express the change in the solubility of gases in
salt solutions depending on the relative decrease of the free energy in
the dissolution of the salt in the solventAZm by the equation ln(So/S)
k m dlnAZ , where 3 and S is the solubility in the pure solvent and In
'fo m
the salt solution, m tRe molarity of the solution and k is a constant.
With the aim of verifying this equation the experimental data on the solu-
bility of helium, argon, nitrous oxide and acetylene in aqueous solutions
of various salts have been elaborated. The Integration has been carried
out graphically. In all cases the experimental data are well described by
the mentioned equation. In the absence of the interaction of the gas and
salt molecules the value of k is the same for the various salts. For he-
lium and argon, for instance, the values of k are equal for the systems
containing KC1, NaCl and NaNO The difference In the values of k for
Card 1/2 different salts or the deviat~o'n from the linear dependence of ln(S,/S) on
M

On the Physical Interpretation of I.M. Sechenov's Equation SOV/81-59-16-56362
jo'dln 4Z. poihts to the interaction of the gas and the salt. Such an interaction
takes place especial4y between acetylene and ZnC12. The detection of acetaldehyde in
the soiution formed as a result of the hydration of acetylene points to the same fact.
V. Kogan.
Card 2,12

5W
AUTHOR: Fli SOV/76-32-10-17/39
TITLE: The Kinetics and Mechanism of the Catalytic Conversion of
Acetylene(Kinetika i mekhanism kataliticheskikh prevrashcheniy
Lilsetilcnc') II. On Some Problems of the Reaction Mechanism
of tile Addition of Various Molecules to Acetylene (II.
0 nekotorykh vorposakh mckhanizma real-tsiy prisoyedineniya
razlichnykh molelcul k -tsetilenu)
PERIODICAL: 'Z.*.,,1.rral fizicheskoy khimii, 1958, Vol 32, Nr lo,
pp 2339 - 2346 (USSR)
ABSTRACT: The catalytic addition reactions of water, hydrogen halides,
acetic acid, hydrogen cyanide etc. to acetylene
can take place in the liquid or vapor-(gaseous) phase.
Mercury (II) salts, copper (I) salts and in some
cases the salts of zinc, cadmium, silver and other
met --1 E7 c; --:--od as catalysts. Carothers (Karozers),
et al. (Refs 4-7) continued the work by Nef
and I.:.;old (Injolld) (Refs 8-10) and assumed that the
Card 1/4 catLlyst leads to an isomerization of acetylene to

The Kinetics and Mechanism of the Catalytic Conversion SOV/76-32-10-17/39
of Acetylene. II. On Some Problems of the Reaction Mechanism of the
Addition of Various Molecules to Acetylene
isoacetylene. B.N.Dolgov (Ref 13) and P.G.Seroeyev
(Ref 14) investigated the hydration process of acetylene
iii Lhe presence of mercury (H) srlts and gave an
incorrect re,)resentation, tU'r-.ing into account the
work by A.2.ElItekov (Ref 15). A great number of
investiuations ((Refs 16-20) show a reaction mechanism
according to Trhich a nercury - acetylene complex compound
(called BiGine-1.1i complex compound) is formed in
the first st.?'-e. The second sta,ge represents a
solvolysis of thil, complex compound. A. N. Nesmeyanov et al
(Refs 22-24) showed that Pb4+ and Sn4+ form complex
compounds with acetylene but that they can riot serve
as catalysts. Acetylene reacts with the complex formers
according to the type of a donor-acceptor interaction,
with acetylene donating the n-electrons and the complex
former accepting them. A.A.Klebanokiy et al (Ref 26)
observed an increase in the acidity of the solution
Card 2/4 in this case. The effrct of the medium on the reaction

The Kinetics and Idechanism of the Cat,':lytic Conver:-,ion SOV/7 6_72-10-17/39
of Acetylene. IT. On Some Problemn of the Reuction Muchaniom of the
Addition of Various Idoloculen to Acetyleno
of acetylene with a contact solution is shown by
the example of mercury chloride. The catalyst must
have the capability to form a complex compound with
acetylene as well as with the molecule to be added.
The activation of acetylene is obviously based on
its deformation by the donation of some of the n-
electrons to the catalyst. For a selective carryinG
out of the catalysis processes the initial mixture
should have an excess of that component to which
the catalyst has the least affinity. There are 30
references, 20 of which are Soviet.
ASSOCIATION: Moskovskiy institut tonkoy I-chimicheskoy tekhnologii im.
(M.
M.V.Lomonosova ,oscow Institute of Fine Chemical
Technology)
SUBMITTED: May 10, 1957
Card 3/4

The Kinctica and Ilechaniam of the Catal.-,tic Converoian SOY/76-.'2-10-17/39
of Acetylene. II. On Some Problems of the Reaction Mechanism of the
Addition of Various Molecules to Acetylene
Card 4/4

FLID, RX., Doe hem Sci -- (divs) " StudY in tho field of cata-
lytic of ancetylene." ros, 1059- 19 --)r.
(I in of Higher Education USSR. Yor, Insti W-Le of T-iiio V,v-,,,:-.TsQtjnojoO~--
in !.'.V. Lomononov). 200 copiof~ Lict of autliorli. :pp 13-19
(Xl,, 40-59, 101)

PHA31 r BOOK EXPLA)ITATION 3OV/353T
Akademlya nauk Xazakhakor SSR. InstLtut kht-l-henklkh nauk
Trudy, t. 5 (Transactions f the Institute or Chemla &I 3clencent
FAzakh 331t, Academy of 3:1ences, Vol 5) Alma-Ata, Xzd-vo
hkademil. nauk Kazakhakor SSR* 1959. 154 p. ItOOO copies
printed.
MA.s X.D. Zhukova; Tech. Ed.t Z.P. R*rolclna; Editorial lbard or
Series: O.V. Sokollxkiy (Res . Ed.). W.4. Outsalyuk. and
B.V. 34vorov (Romp. Secrsta"3-
PQRPOSZs This collection of articles Is intended Arpersonnal of
scientific research laboratories. laborstorlea or industrlkl
enterprises. anJ faculty members of schools of higher education.
COV9MZt The collection reviews problems of liquid-phase catalytic
dro-
oducts
It
.
hydrogenation to upgrade and r*ectivace various pr
y
ganatIon Of unsatursted bonds or various types, adsorption of
hydrogen an different catalysts. chrom tographic separation of
mixtures. and the street or halogen 6L.9s Zf alkali metal
a
M
tOU
l
the rate or hydrogenation reactions promoted by various &
cat"to are described. Conditions of catalytjo hydrogenation
t natural tat. sunflower oil. an.1 such synthetic products as
terg or high molecular fatty acids are set cut. Dehydration
:.
of the but&" traction carrieS out In combinatlon, with laomerl-
sation I* analysed. Principles of Wecting catalysts and re-
&averating them aft reviewed MA the formation of adsorption
potentials an metia catalysts to explained. Zsch article presents
a*ncluslona drawn on the basis of ex9tri"atal findings.
forence� ampamy ,~st of the axticlos.
00 Chromato
'
&.ran. V.P.. It N. Xha3encVa, sndfDLV__-12kqk,
p
_
1~~~tfon-air-xi-xmurwi or mitr
Obenzene-M
ns Product; 28
0010dova- L.S.. and D.V. Sokol-skly. Study or jVarc..Oatlon Rest-
ri. or latur" Pat& and Their Simplest Synthetic Analogues. the
gets. of lilgh-Molepular-Patty Acids 36
OolOdOva. L.3.. V.V. Sokol-mkly. " Te.A._b2d_-yacbSrA_ ZloatI04
and Mechanism or Hydrogenation of 3unrr6wer Oal In SoIQUOUX
, 44
.k1YAaQx_A_r_ Problem of Porma ton of Adsorption Potanitais
Lu t
-6i metal catalysts 50
k~A_1.. " D.V. 30"l-akly. Potentloattric Study of
Ion of-ftnzalacetuna Over Skeleton "I Catalysts
zu
buyalk1na'j"A. a_V_ra!12Yj1Lk and D V. Sokol'-
_
I '
aftn
r
Dc
n-
e
- ydrol om*rization a m ommerci&I Praction o
.
j
Over Oxid: Catalysts
64
V P K.M. VIAsOva, and D.V. 3oko2*skly. Catalytic Ro-
duction Pa't rx 72
(Koskovskly inatitut tOnkoy kn1mIche3kay tekhnologil
Lomonosova--Y.Oscow Inatitute of IlAs Che-ical Tech-
0, IOU Imenl X.Y. ro, co3ov). Soe PrInciples of Selecting Cat&-
iyets for Liquld-Phaae Hydration or Acetylene to Acetaldcbyde al
,j5hc,tLW91QY__X_X., anI D.V. Sokollakly. Some rAthois of Reactivating
h
t
e
A02 eton Nickel Catalyst 92
Shchoglov, N.J., and O-v- Sokol-skly. Etydrogenation or Acetylene
In trA Liquid Phaae 97
Sokol -;kly. D.Y.. and L.P. Dunina. rq4rogenation or a sadium,
Ult . PrOP10110 Acid 6~_Or_Plitlnua
__Aokol-skaya, A " and D.V. Sokol-skly. Hydrogenation of Cinnamle
-
'
-
-
Alcohol-pt
r
0
r
be 1
y 10
Card 4/5

50) SOV/156-59-1-29/54
AUTHORS: Flid, R. M.p Basova, R. V., Chirikova, A. V.
TITLE: The Kinetics of the Catalytic Synthesis of Vinyl Acetate in
the Presence of Zinc Aluminate (Kinetika kataliticheskogo
sinteza vinilatsetata v prisutstvii alyuminata tsinka)
PERIODICAL: Nauchnyyedoklady vysshey shkoly. Khimiya i khimicheskaya
tekhnologiyaq 1959, Nr 1, pp 117-119 (USSR)
ABSTRACT: Previous works of the authors (Refs 1 and 2) suggested the
possibility of a selective synthesis of vinyl acetate. Different
from industrial production a surplus of acetylene was not
used but the ratio C 2H2 : CH COOH was equal to or less than-
1, whereby the capacity of t~e contact mechanism is much
increased and the separation of vinyl acetate is facilitated.
The kineticq was investigated in the temperature interval
0
230-270 . In the first test run the acetylene partial pres-
sure was varied and the acetic acid partial pressure main-
tained constant. In the second test run pC 2H2 - const. and
PCH3COOH variable. The tabulate d data show that the reaction
Card 1/2 depends neither on the partial pressure of acetylene nor on

BOV/156-59-1-29/54
The Kinetics of the Catalytic Synthesis of Vinyl Acetate in the Presence
of Zinc Aluminate
that of acetic acid. Therefore the reaction rate can be de-
scribed by a second order kinetic equation: U w K.p C2H2 !PCH3COOH'
From the tabulate experimental data obtained-at-different
temperatures (230 9, 2500, 2700 E - 22,000-+ 600 cal was
calculated as activation energy. There are 3 tables and 2
Soviet references.
ASSOCIATION: Kafedra tekhnologii oanovnogo organicheskogo sinteza Moskovskogo
institute tonkoy khimicheskoy tekhnologii im. M. V. Lomonosova
(Chair of Technology of Basic Organic Synthesis of the Moscow
Institute of Fine Chemical Technology imeni M. V. Lomonosov)
SUBMITTED: July 49 1958
Card 2/2

SOVOIC-55 -1-41/44
AUTKORS: Flid, R.M., Ilinsker, K.S. and Skvortsova, N.F.
TT-TLF: Production of Methyl Chloride by the Catalytic Hydrochlorination
of Dimethyl Ester (Polucheniye khloristogo metila katalitichesk.im
-idrokhlorirovaniyem, dimetilovogo efira)
PE'-IJODICAL: Zhurnal prikladnoy khimii, 1559, lir 1, pp 230-235 (USSR)
ABSTRACT: The dimethyl ester is formed as a by-product in a number of
technological processes, and this raises the problem of its
effective utilization. The authors show that it can be used
for obtaining methyl chloride in its catalytic interaction with
hydrogen chloride. The most active catalyzers are qF-A1203
(375 to 40000; CdCl, on the activated carbon A.R-3 (175 to
3000C) and ZnC12 on the activated carbon AR-3 (120 to 2000C).
At the volume velocity of 300 to 400 1/1 cat.hr the yield of
C113cl attains the following values: 95 to 96'j~j; 85 to 075 and
78 to 821,4o respectively. A preliminary saturation of the cata-
Card 1/2 lyzer surface with hydrogen chloride is necessary for the main-

SOV/80-59-1-41/44
Production of Methyl Chloride by the Catalytic Hydrochlorination of Dimethyl
rster
tenance of high activity of the process.
There are 2 tables and 2 Soviet references.
SUBMITTED: May 13, 1957
Card 2/2

S/ 08,/6-/000/006/003/0 15
B! OI/B20 I
A UTHOR PI id,~ R. M.
T ITLE S..iq.-. principlea of the choicA -.~f ?ataivsts far the
hydration of a,~~etylen-; to acatalaenyde in liquid phas-~,
PERIODICAL t RPf Arat.~vvy snurnnit. Knm.-,ya, no. 6, 1961, 65, at-stract
IbVf4 '613474). ("Pr. In-t8 kh.1m. nauk. AN Kft7SSR",
f .
bi - 9 1 )
TEXT~ A a~,-udy na-i icad--~ ~f th-3 baeir- of r-ho wf-ha-
P-Irim nif hydrat-ion of 0,H,, uni -,f the effr-ot of param~-terq such
,is ralius of 7~ation. itg iorLizatLon potintialv lte affinity to the
tror, "he normal eiectrode potential of tho 7atiln. and the chemAcal
ua~urc~ of the anionv upon the o,,atalyst actLv,ty , The author believes
that salts of On, aad possibly. of Ag may bo promlsJng, n-~n-mercurlal
,~atalyata of the, hydration of a,7~etylevie in liq,4id pha-l~,. Tilt? catalyst
auggested by the author, a sollation of in 62% aolution of' Zn('I?i
hail d-,splayeri an actvilty and spl-4rtivity rnt "Iower than Kuchi-.rovl-q
catalyst undpr laboratury t~opditionz at a pro-%ess temperatwe of
Cari I/ /,

s /0,~ - /,~ I /()POIrO610051
, I J . oi~
Some principles of the- R ,0 1 /B -~o I
on
170 .. - kw.
! 7 r, A,
1~ ba~~racter(s nnt-ij Compl,?~,- transla,.i I
Card ?/2

5(2, 3) SOV/153-2-2-5/31
AUTHORS: Flid, R. M., Golynetsp Yu. F.
TITLE: Investigation of the Solubility of Acetylene in Aqueous
Solutions of Electrolytes in Dependence on Temperature and
Salt Concentration (Izucheniye rastvorimosti atsetilena v
vodnykh rastvorakh elektrolitov v zavisimosti ot temperatury
i kontsentratsii soli)
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniye Khimiya i khimi-
cheskaya tekhnologiya, 1959, Vol 2, Nr 2, pp 173-179 (USSR)
ABSTRACT: The publication references cono.eming.the.problem mentioned
in the title.(Refs 1-5) are rather scarcep and - in the opinion
of the authors - they.indicate too high values in part.
Table 1 and figure 2 give some data on the solubility of
acetylene in waterp in H 2so4w and electrolytic salt solutions
in water, as well as some thermodynamic characteristics of
this process. The analysis of the results obtained leads to
the following conclusions: I)-The values for A 1129, given
in the publications, according to equation (2) and as com-
puted by the authors, differ from one another. This can only
Card 1/4 be explained by the fact that the solubility drop of acetylene

SOV/153-2-2-5/31
Investigation of the Solubility of AoetyleAe in Aqueous Solutions of
Electrolytes in Dependence on Temperature and Salt Concentration
is less distinctly.tarked at temperatures above 250 than in
the range of 0 - 25 . 2) With an increase in the H SO -con-
2 4
centration, the acetylene solubility passes a minimum. With
a rise in temperature, this minimum shifts to lower acid
concentrations. The relative.solubility reduction in aqueous
H 2SO -solutions becomes 0amallere 3) With a rise in temperature
in tAe range of 25 - 70 , the.acetylone.solubility -in the
solutions of the saltainvestigated also passes a minimum.
It is the less distinctly marked, the..higher the concentration
of the salt is. In some solutions near saturation, the mini-
mum stays away, and the acetylene solubility increases steadi-
ly with temperature- 4) At low temperature (250),this solubili-
ty decreases in dependence on the nature of the salt cation
in the following order:
NH+ > K + > Na+ > Li +> Ca 2+ > Mg 2+ > Cd 2+ > Zn 2+ > Mn 2+ > Ni 2+ '21
4
> Cr3+ > A13+. The hydrating capability of the cations rises
in th same order. At highe temperatures, the picture changes:
at 50 and even more at 70 the cations of the above order
Card 2/4 are readjusted. 5) Also the type of the anion has a great

SOV/153-2-2-5/31
Investigation ofthe Solubility of Acetylene in Aqueous Solutions of
Electrolytes in Dependence on Temperature and Salt Concentration
influence on the solubility value. Here, too, a rise in
temperature changes the order of the anions. 6) A change
in the value A Z of the acet7lene dissolution is accompanied
by a change of the values A H and AS. So it can be asserted
that with a change in temperature also the character of in-
teraction between acetylene and water (Table 1) and the dia-
solved salts is changed. The solution heats and entropies
are particularly intensely changed in solutions of those
salts, the cations of which have a considerable polarizing
effect. 7) As is shown in table 2,-the acetylene solubility
at 500 in a zinc chloride solution saturated at this tempera-
ture is very high, and much higher than in pure water. As
the character of change in the values All and AS with
temperature is equal, the authors assume that thersis a
mutual relation between the entropy change ( As T) and the
beat effect of the acetylene dissolution in the solutions
investigated (in accordance with reference 9). Figure 2 shows
Card 3/4 a linear dependence between dS and All which is well ex-

SOV/153-2-2-5/31
Investigation of the Solubility of Acetylene in Aqueous Solutions of
Electrolytes in Dependence on Temperature and Salt Concentration
pressed by equation (4). There are 2 figures, 2 tables,
and 9 references, 5 of which are Soviet.
ASSOCIATION: Moskovskiy institut tonkoy khimicheskoy tekhnologii; Kafedra
osnovnogo organicheskogo sinteza
(Moscow Institute of Fine Chemical Technology;Chair of
Basid Organia, Systmals)'
SUBMITTED: February 7, 1958
Card 4/4

,57 3.2 0 0
4ko 6,7846
AUTHOR: 7lid, R.N. S/153/59/002/06/024/029
B115/BOOO 1
TITLE: The Kinetics of HydrohaloE2Ration of Acetylen in the Liquid
Phase in the Presence of Mercury Salts
PERIODICAL: Izvestiya vyeshikh uchebnykh zavedeniy. Khimiya i khimioheskaya
tekhnologiya, 1959, Vol 29 Nr 6, PP 946-953 (USSR)
ABSTRACT: It was the aim of this paper to investigate the fundamental
rules valid for the addition kinetics of various hydrogen
halides (HC1, HBr, HI) to acetylene in the presence of the
corresponding salts of mercury. Contradictory results are
frequently found in papers published hitherto. Experimental
methods and-apparatus used are described, and the concentra-
tions of the components contained in the contact solutions
(HgX2 and RX) (X being a halogen) are given (Table 1). Products
obtained by the liquid-phase hydrohalogenation of acetylene
independently of the reaction temperatures and the concentra-
tions of the contact solutions are given. Neither the degree
of conversion of the acetylene nor the yields of end products
of the reaction can be changed by changing the RX : C2H2 ratio
Card 1/3 within 0-5 to 4.0 at constant volume. The hydrochlorination of

~7846
The Kinetics of Hydrohalogenation of S/153/59/oo2/o6/024/029
Acetylene in the Liquid Phase in the Presence B115/BOOO
of Mercury Salts
acetylene yields vinyl chloride only. According to results
obtained (Table 2), it may be stated that the reaction rate
can be related to acetylene by a kinetic equation oA' first
order which is confirmed by the satisfactory agreement between
the reaction rate oonstants~ Two parallel reactions are taking
place on hydrobromination, with vinyl bromide and 191-dibromo-
ethane being formed. The reaction rate which in relation to
acetylene may be expressed by an equation of first order is
retarded by the products formed. The only product formed by
hydroiodinationg is 19.2-diiodoethane
'IThe influence of tempera-
.
ture on the hydrochloriEna-tion at 25 to 910) and hydroioctina-
tion (at 30 to 1120) has been investigated (Table 3) and from
the results obtained, the activation energies of the processes
mentioned were calculated. From the data (Table 4), a generally
valid linear relation was established between the logarithm
of the velocity constant (k) and the oxidation potential of
the contact solution ('-! ) when the concentration was varied
(Diagram represented). The kinetic equations for the dependence
Card 2/3 of the reaction rates for hydrochlorination, hydrobromination,

67846
The Kinetics of lRydrohalogenation of S/153J59/002/06/024/029
Acetylene in the Liquid Phase in the Presence B115/BOOO
of Mercury Salts
ASSOCIATION:
and hydroiodination on the activity of the contact solution
were derived. The author is of the opinion that the limiting
stage in the processes investigated is the activity of the &
acetylene, the mechanism of which is discussed in detail.
There are I figure, 4 tables, and 6 references, 5 of which are
Soviet.
Moskovskiy institut tonkoy khimicheskoy tekhnologii imeni
M.V.Lomonol3ova CMoscow Institute of Fine Chemical Technol
imeni M.V. LomonosavT
Card 3/3

50)
AUTHORS:
TITI;~`,:
Flid, Chirikova, A.V.
I .
SOV/80-32- 3- j.'
On the Possibility of dCatalytical Gas-Phane Synth-_-sis of Vinyl-
acetate at the Stoichiometric Ratio Of tile ReLCtiCn Components
(0 vozmozimosti provedeniya i7azofw-.nojo katalitichovko,~o sintez.,
.Alatsetata pri stekhiometi-icheskom scotnoshenii komponentov
re.-~.ktsii)
PERIODICAL: Zhurnal prikladnoy khimii, 1959, Vol XMI, IIr 3, pp 6u'o-663
(USSR)
ABSTIIICT: The synthesis of vinylacetate in t he gaseous phase ll~ catalysts
'0"' = 1 -' 1 and 1
in the molar 'ratios C.2H2 -.- 'CH3CC~ 2.is in-
ve-stigated here. Opt-imum.results were ob'.ained at. temperatures
of 270-2750C. The rolume rate .mas 250-300 1 per liter of ca-
talyst and hour._,The degree of conversion of acetic ncid.-is
3CY~) and of acetylene 6-,,/'c at a selectivity of 96-9&;~~. The out--
lit per I liter of catalyst and hour is 6-7 timmes hi-her than
of Qha. prcsent r;ethods. The molazr railio 1 : 2 E:4--,res better
Card 1/ 2 __--id mope coraptant results.

On the Fo3sibility of a Catalytical Gas-Phase Synthesic of Vinylacetate at
the Stoichiqmetric Ratio of the Reaction Components
There are 3 tables and 4 references, 3 of which are Soviet and
1 American.
SUBMITTED: Julv 5, 1,Q57
Card 2/2

5W SOV/76-33-1-20/45
AUTHORS: 21 i AR, M., Mironovp V. A., Ostrovskaya, V. 1,1.9
Aronova, N. I.
TITLE: The Kinetics and Mechanism of the Catalytic Conversion of
Acetylene (Kinetika i mekhanizm kataliticheskikh pre-
vrashcheniy atsetilena). III. The Kinetics of the 1~ydro-
halogenation of Acetylene in Liquid Phase in the Presence
of Mercury Salts (III. Kinetika zhidkofaznogo gidro-aloidiro-
vaniya atsetilena v prisutstvii soley rtuti)
PERIODICAL: Zhurnal fizicheskoy khimii, 1959, Vol 33, Ur 1,
pp 119 - 128 (USSR)
ABSTRACT: The catalytic addition of hydrogen halide to acetylene in
the presence of mercury salts had already been carried out
for several times but the data obtained were incomplete
and contradictory. In the case under review tests were
conducted with EC1) HBrf and HJ. The testing method and
the testing apparatus were already described (Ref 1). The
following products were obtained: On hydrochlorination
vinyl chloride only; on hydrobromination vinyl bromide and
Card 1/3 1,1-dibromoethane, and on hydroiodination only 1,2-diiodo-

The Kinetics and Mechanism of the Catalytic Conversion SOV/76-33-1-20/45
of Acetylene. III. The Kinetics of the Hydrohalogenation of Acetylene in
Liquid Phase in the Presence of Mercury Salts
ethane. The influence of the contact time t on the con-
version degree of acetylene and the yield of reaction
products at various temperatures and varying duration of
the reaction ware Investigated (Table 2). The reaction veloc-
ity is shown by a kinetic equation of the first order (with
respect to acetylene). It is impeded by the reaction pro-
ducts formed. The temperature influence was determined
(Table 3), the activation energies were calculated and an
unusual cbange of the temperature coefficient at the hydro-
chlorination reaction was observed. In all cases, a linear
dependence between the logarithm of the velocity constant
and the values of the oxidation potential of the contact
solution, with various H9X 2- concentrations, was observed.
It is assUmed that acetylene is activated by taking out
a doublet of n-electrons by the catalyzer whereby the
acetylene molecule is deformed. There are 3 figures, 4
tables and 5 Soviet references.
Card 2/3

The Kinetics and Mechanism of tho Catalytic Converoion Q /76-33-1-20/45
"0v
of Acetylene. III. The Kinetics of the Hydrohalogenation of Acetylene in
Liquid Phase in the Presence of Mercury Salts
ASSOCIATION: Institut tonkoy khinicheskoy tekhnolo,-,ii im. Lom=osovs.
(Institute of Fine Chemical Technology imeni Lomonoavv)
SUBMITTED: June 25, 1957
Card 3/3
r

3/15 60/003/02/26/034
BO11YBOO6
AUTHORS: kid.R. t,,,,qhttkova, A. V., Raskina, G. V., Basova, R. V.
TITLE: Investigation in the Field of the Catalytic Synthesis of
Vinyl Aoetatelin the Vapor Phase
PERIODICALs Izvestiya vyashikh uchebnykh zavedeniy. Xhimiya i
khimicheskaya tekhnologiya, 1960, Vol. 3, No. 2, PP. 343-351
TEXT: The authors investigated the thermodynamics of the oatalytic
reaction of acetylene and acetic aoid and found that two parallel reactions
take place$ i.eo monomeric acetic acid reacts with acetylene to give vinyl
acetate, while dimerio acetic acid and acetylene form ethylidene diaoetate.
The direction of the reaction is determined by the relative amounts of
monomer and dimer contained in the acetic acid. ZnO on Al 0 was used as
2 3
catalyst. It is shown in Table 8 that the activity of the catalyst is all
the greateri the lower the roasting tempsrature of the latter was,
Catalysts roasted at 400 0~.' have the highest activity. The authors proved
that catalytic synthesis of vinyl acetate in thevapor phase using molar
ratios of 0 2 H2. CH3COOB - 10 and 1s2 is possible. Zinc acetate on
Card 1/3

A
7
Investigation in the Field of the Catalytic S/153/60/003/02/26/034
Synthesis of Vinyl Acetate in the Vapor Phase BO11/BOO6
activated carbon was used as catalyst (Tables 1 and 4). Optimum condi-
tions for the process are 270-275ot-, a total rate of flow of
250-300 1/1 cat -h . The degree of conversion attained under these
conditions amounts to 30% of the acetic acid (Table 6), 60% of the
acetylene (Table 5) at a selectivity of 96-98%. The efficiency of one
liter of the catalyst per time unit is 6 to 7 times as great as that
hitherto attained. The process can also be carried out in a pseudo-liquid
state over a ZnO/Al 203 catalyst. Respective experiments were made using
a column designed by the NIOPIK (Nauchno-issledovatellskiy institut
organicheskikh poluproduktov i krasiteley (im. K. Voroshilova), Scientific
Research Institute of Organic Semifinished Materials and Dyes (imeni
K. Voroshilov)). A hod for preparing thI75-catalys-E -is suggested 771ii-
authors studied the kinetics of vinyl acetate synthesis over ZnO/Al 203
at 230 o'' and 2700co The kinetics of this reaction is expressed by an
equation of second order, i.e. w - kP C'H -PCH COOH* The activation energy
2 2 3
is E - 22,000 + 600 cal/mole. This paper was read at the Vsesoyuznaya
Card 2/3

Investigation in the Field of the Catalytic
Synthesis of Vinyl Acetate in the Vapor Phase
S/15 60/003/02/26/034
B011YB006
Konferentsiya"Puti sinteza iskhodnykh.produktov dlya polucheniya
vysokopolimerov" (All-union Conference "Ways of Synthesizing Initial
Materials for the Preparation of High Polymer Substances"), held at
Yaroslavlly from September 29 to October 29 1958. There are 8 tables and
6 references, 5 of which are Soviet.
ASSOCIATIONs Moskovskiy institut tonkoy khimicheskoy tekhnologii imeni
M. V. Lomonosova (Moscow Institute of Fine Chemical
Technology imeni M. Y. Lomonosovi. Kuskovskiy khimf-cheskiy
zavod (Kuskovskiy Chemical Plai
Card 3/3

5.34oo 77925
SOV/'~-(9 -30 -2 -76/78
AUTHORS: Temkin, 0. N., German, E. D., Flid, R. M.
TITLE: Letters to the Editor. The Part of Proton Acids in
Certain Catalytic Conversions of Acetylene
PERIODICAL: Zhurnal obshchey khimil, 1960, Vol 30, Nr 2, p 699 (USSR)
ABSTRACT: The relation between metal ton activity in solution ani
proton activity in the addition reactions of acetylene
was investigated. Hydration of acetylene was carried
out in contact solution containing Cu2SO4-.HOS04. The
latter was prepared by boiling CuS04 + H2SO4 with metallic
copper In nitrogen. The concentration of CuS04 In all
cases was 0.0128 mole. It was established that con-
version of acetylene decreases with Increase of the
acid concentration, caused by formation of copper
acetylides, until concentration of acid reaches 10%.
At this point, acetaldehyde is formed. Introduction
Card 1/2 of the acetylene Into solution decreases potential of

Lettevs to the Editor. The Part of Proton 77925
Acids In Certain Catalytic Conversions SOV/79-30-2-76/78
of Acetylene
the copper electrode from El to E2. Passing nitrogen
through the contact solution Increases this potential
to a value smaller than El. It was established that
the termination of the formation of acetylides and the
maximum concentration of acetaldehyde takes place
at a definite ratio of potential to proton activity..
There are 5 Soviet references.
Card 2/2

S/076/60/034/008/024/039/XX
B015/B063
AXTHORs Flid, R. M.
TITLE# Xinotics and Mochanism if Utalytio Transformation* of
A.~e ~Ien.~.JIV. Mechanism of the Formation of Disubstituted
Ethane Der vatives From Acetylene
PERIODICAL: Zhurnal Ifizicheskoy khimiij 1960, Vol. 34, No. 8,
pp. 1775 - 1777
TEXTs The author refutes the widespread opinion that the catalytic J
addition of various molecules HX (X - C11, Cl, Br, 1, CH 3COO, etc.) to
acetylene is always consecutive. As the reactions take place in the
presence of a catalyst, the following scheme is proposedi
C 2H2 (gas) + 'X(gas) + B:~--- -CH2 CHX-B (K 3) (3)
CH 2--- CHX-B CH2CHX(g&s) + B (K 4) (4)
CH2=---CHX-B + EX (gas) - C 2H4x2 (gas) + B (Y (5) -
CH 21 CHX-B is the state of the molecules of the vinyl derivative which is
Card 1/3

Kinetics and Mechanism of:~ Catalytic Trans- S/076/60/034/008/024/039/XX
formations of Acetylene. IV. Medhanism of the B015/BO63
Formation of Disubstituted Ethane DerivativesFrom Acetylene
bound to the catalyst B (on the surface or in a solution) in the form of
a 9Qmpjex'1The equilibrium conatants of various addition reactions of
HK to vinyl derivatives indicate that the formation of asymmetric, disub-
stituted ethane derivatives is thermodynamically more probable, and that
only CH3CH12 and CH 3CH(CN)2 are obtained in appreciable quantities within
a wide temperature range. CH 3CHC12 and CH3CHBr2 are obtained in small
quantities up to 450 0C, while practically no ethylene diacetate is formed.
As the experiments of Ref.1 have shown that a catalytic addition of HBr
and CH 3COOH to acetylene gives not only vinyl derivatives but also large
quantities of asymmetric ethylene dibromide and ethylene diacetate, it may
be assumed that the products mentioned are not formed by a consecutive
addition '' Experimental data of Refs.4-6 indicate that, in accordance with
the thermodynamic analysis, asymmetric disubstituted ethane derivati-ves
are sometimes obtained by a direct reaction of molecules (addition of
CH3COOK, HBr, HI) with acetylene. The formation of various isomers C2H 4X2
is ascribed to the different character of the molecular activation of the
Card 2/3

Kinetics and Mechanism of Catalytic Trans- S/076/60/034/008/024/039/XX
formations of Acetylene. IV. Mechaniom of the B015/B063
Formation of Disubstituted Ethane Derivatives From Acetylene
viql derivative by the o&tslyst. One of the two explan&tim suggested
UY tht author is in accordance wit Markovnikov's rule. There are i tnblo
and 6 references$ 4 Soviet, I US, and I German.
ASSOCIATION: Moskovskiy institut tonkoy khimicheskoy tekhnologii im.
Lomonosova (Moscow Institute of Fine Chemical Technology imeni
Lomonosov) ----- -
SUBMITTEDa November 17, 1958
Card 3/3

TEMKIN, O.N.;--FLID, R.M.j
GERMANS E.D.; ONISHCHENKO, T.A.
Soluble complexes of unsaturated hydrocarbons with metal salts.,
and their role in catalytic reactions. Part. 1: Soluble compounds
of acetylene with copper salts. Kin. i kat. 2 no.2:205-213 Mr-A
161. (MIRA 14:
1. Moskovokiy institut tonkoy khimicheskoy tekhnologii imeni
M&Vo Lomonoaovae
(Copper compounds)
(Acetylene compounds)

FLID, R.M.; TEMN, O.N. (Moscow)
Kinetics and mechanism of catalytic transformations of acetylene.
_Part 5: Certain problems in selecting catalysts for the liquid
phaae hydration of acetylenea Zhur. fiz. khim. 35 no.2:452-
459 F 161. (MIRA 16:7)
1. Moskovskiy institut tonkoy khimicheskoy takhriologii imeni
Lomonosova.
(Acetylene) (Hydration) (Catalysts)

YAN TSZYANI-SHEN [Yang Chien,.sh;nglpe FLID, R.M.; MAKHLIN, V.A.
Studies in the field of the liquid phase hydration of acetylene on
catalys~n other than mercury. Izv. lyso ucheb.,zav.; khim. i khim.
tekh. 4ino. 2t,218-224 161- (MIRA 14:5)
1. Moskovskiy institut tonkoy khimicheskoy tekhnologli im.
~.V. Lomonosova. Kafedra tekbnologii oanovnogo organicheskogo
sinteza.
(Acetylene). (Hydration)

s/19,5/62/O03/oo6/o1i/on
E075/E436
AUTHORS:* Temkin, O.N., Flid, R.M., Malakhov, A.I.
TITLE: Soluble complexes of unsaturated hydrocarbons with
metal salts and their role in catalytic reactions
II. Soluble compounds of acetylene with silver salts
PERIODICAL: Kinet-ika it kaia,.1iz,. v-3, no.6, 1962, 915-919
TEXT; in connection with the studies of the mechanism of
hydration of acetylene in silver salt solutions ' it becomes
necessary to elucidate the possibility and conditions for the
formation of the IT-complex. The thermodynamics of the complex
formation were investigated by a potentiometric method (Kinetika
i kataliz, v.2, 1961, 205). The silver electrode was prepared by
depositing AS on a platinum spiral at-the current density of
0.003 A/cm2 and was immersed in aqueous 1 to 7M H2SO4. As
acetylene was' passed through the solutions, the electrode potentia 1.
decreased irreversibly (,A El) and reversibly (A E2)-
.8 El was related to the formation of AS2C2- AE2 decreased with
the increasing concentration Of 112SOlf, but increased and passed
through a.maximum with increasing temperature (from 20 to 100*0
Card 1/3

S/195/62/003/006/011/011
Soluble complexes"...'. E075/E436
in 0.288 M H2S04- This indicated that a'soluble half-acetyli:de'
HC E_E CAg formed in addition to the 1T -complex. The*reactioxis
taking place are as tollowa:
K
+
Ag + C H A H+
aq ~2 2a gY2aq
,q
+ K2 +
Ag + C H AgC H H (IIY
aq 2 2aq 2 aq- aq
......The enthalpy values,for reactions I and 11 are -13.20 and
.+6.86 respectively. Low catalytic activity of silver salts
in the hydration process in comparison with 'that of copper salts
is explained by low values of K, 1Kl (3730C) = o.6 litre/mole]
compared with the corresponding value for Cu (20 litres/mole).
The strong tendency to acetylide interaction prolongs the
formation of the halfacetylide. Moreover high aci.dities
..(6 to 7 M H2S04) necesiary for decreasing the,acetylide
interaction, cause &.strong dehydration of the 1Y-complex, which
Card 2/3

3/195/62/063/oo6/o.11/011
Soluble complexes E075/E436
makes the hydration of acetylene more difficult. There are
6 figures and 2 tables.
ASSOCIATION: Institut tonkoy khimicheskoy tekhnologii
int. M.V.Lomonosova (Insti,tute of Fine Chemical
Technology ime'ni M.V.Lomonosov)
SUBMITTEDs~ October 169 1961
Card 3/3
JI
w
407
R% 1,

FLID R.M.- KRASOTKIN, A.Ye.
Preparation of aldehydes and ketones by a combined catalytic
oxidation and dehydrogenation of alcohols. Kin.i kat. 3
no.2:282-288 Mr-Ap 162. (MIRA 15 -.11)
1. Moskovskiy institut tonkoy khimicheakoy tekhnologii imeni
Lomonosova.
(Aldehydes) kKetones) (Alcohols)

TENKIN, O.N.; nB R.M.; MALAKHOV, A.I.
L~
Soluble eo~iplexes of unsaturated bydrocarbons with Be tal,
salts and their role in catalytic reactions. Part 3: Soluble
~F-complexes of mercury (11) with acetylene. Kin.i kat. 4 no.2:
27~-276 ~h-Ap 163. (MIRA 16:5)
1. *skewskiy institut tonkoy khimicheskoy tekhnologii imeni
Lomonosova.
(Mercury organic compounds) (Acetylene compounds)
(catalysis)

IIIDP R.M.- AIEKSEYEVA., N.F.; KHMELEVSKAYA, T.G.; GAYDAY, N.A.
Kinetics of liquid-phase hydrochlorination of acetylene in the
presence of cuprous chloride. Kin.i kat. 4 no.5:698-705 S-0
163. (MIRA 16:12)
1. Moskovskiy institut tonkoy khimicheskoy tekhnologii imeni.
Lomonosova.

Y,OGILYANSKIY, A.I.; TENKIN, O.N.; FLID, R.M.; BUNINA, R.V.
Potentiometric determination of divalent mercury concentration
using a mercury electrode. Zhur.anal.khim. 18 no.10:1211-1216
0 163. (1AIRA 16:12)
1. M.V.Lomonosov Moscow Institute of Fine Chemical Technology.

FLID, R.M., doktor khim.nauk; KARAKWOV, R.A.
All-Union chemists' conferences in Alma-Ata and Erivan. Vest.
AN SSSR 33 no.2tUg-121 F 163. (KIRA l6s2)
(Cheuiatr7-Congresseis)

TEMINY O.K.; GINZBURG, A.G.; FLID, R.M.
Soluble complexes of unsaturated hydrocarbons with metal
aalts'ind their role in catal?tiC 2edCtiOnS. 1~Lrt 4sTherzo-
dynamics of the formation of soluble 7/j-complexea of ethylene
with Ag*~-and Cu+,ions, Kin. i kat. 5 no.22221-227 Mr-Ap 164.
(KIRA l7z8)
1. Moskovskiy in8titut tonkoy khimicheakay tekhnologii imeni
Lononosova.
IF

TREGER, Yu.A.; R.M.; SPEKTOR, S.S.
Solubility of allyl chloride In water and in aqueous solutions
of HC1. Zhur. fiz. khim. 38 no.2:4178-481 F '6Z. (MIRA 17:8)

TREGER, Yu,,A.; FLID, R.M.; ANTONOVA, L.V.; SPEKTOR, S.S.
Complex lormation of allyl chloride and allyl alcohol with
monovalent copper saltb. Zbur.fiz.khim. 39 no.11:2831-2835
N f65. (MIRA 18:12)

SOV/115-59-7-15/33
9(2,3)
AUTHORSs Lifshits, A.S., Plid, Ya.l.
TITLEs Electronic Circuits for Differentiating Direct Current Yoltages
PERIODICALs lzmeritellnaya tekhnika, 19599 Nr 7, pp 28-30 (USSR)
ABSTRACT% In this paper the authors discuss several differentiating cir-
Cults composed of operational amplifiers. They explain calcula-
tion problems and present experimental characteristics of these
circuits. The experimental investigations were performed by means
of UPT-4 amplifiers which are linear within the limits of voltage
changes at the output of + 100 volts. Such circuits are used for
solving many problems where derivatives of different time func-
tions are required. In computers this operation is reduced to a
differentiatibn of the direct current voltages. In a number of
cases the circuits used for this purpose must provide a differ-
enti4tionin a sufficiently wide frequency range (10-30 cycles).
Known differentiating circuits, shown in fig.1, do not provide
the required characteristics. The authors consider differentiat-
ing circuits with RC and dc amplifiers, and differentiating cir-
Card 1/2 cuits with integrating amplifiers. The experimental characteris-

SOV/115-59-7-15/33
Elecironic circuits for Differentiating Direct Current Voltages
tics plotted at Tj - 0.001 sec and T, = 0.01 sec for a differen-
tiating circuit with a dc amplifier are shown in fig.4. Fig.5
shows the experimental frequency characteristics for a differen-
tiating circuit with an integrating amplifier. There are 2 cir-
cuit diagram sets and 3 graphs.
Card 2/2
DUO` MMM_~

FLID., Ya. I.; LIFSHITS, A.S.
Determining the effective Talue of voltageovarying according to a
random law. Izm.tekh. n0-5:35-38 MY 61. (MIRA 3-4:5)
(Electronic measurements)

GITIS, Ennanuil Isaakovich. Prinimajj uchastiye: SAMOYLENKU, V.I.)
kand. tekhn. nauk; BALTRUSHWICH, A.V.p kand. tekhn. nauk;
ZHDANOV) G.M., prof.., retsenzent; KAYZMER, L.P., kand.
tekbn. nauk., retsenzent; FLID..,-YA.I... kand. tekbn. nauk,, red.
(Automatic control of radio systems; electric and aptomatic
control of radio systems) Avtomatika radioustanovot; elektro-
radioavtomatika. Moskva, Energiia, 1964. 631 p.
(MM 17:3.1)
-0

31270
S/103/61/022/011/011/014
D27!/D306
AUTHOR: Plidlider, G. M. (Moscow)
TITLE: Dynamic characteristics of electromagnetic powder
clutches
PERIODICAL: Avtomatika i telemekhanika, v. 229 no. 11, 1961v
1521-1532
TEXT: The author studied time and frequency characteristics and
transfer functions and treated the clutch as a circuit element
with distributed constants. Two assumptions were made: The mecha-
nical characteristic of the clutch is absolutely rigid, i.e.
M(n) = const
the clutch moment is prcportional to the magnetic flux, i.e.
M kMj (2)
Card 1/9
EF-W "..~~Ncwmw
Vn
0,

31270
S/103/61/022/011/011/014
Dynamic characteristics of D271/D306
The natural dynamic characteristic represents the reaction to a
unit jump of voltage, and the forced characteristic represents the
effect of a unit jump of current. A forced characteristic is more
basic because clutches are current supplied, natural characteristic
is useful when choosing the system of control. The circuit of the
c,lutch is given together with dimensions, A previous paper by the
author is quoted for the general solution of transientq~roceases
(Ref. 4: Avtomatika i telemekhanika, v. 20, no. lo 195 and from
this, the expressions for operator magnetic reluctances fi(p) are
derived, taking into account the permeability in the working gap
(Ile =4-8) and the considerable thickness of the inner pole. The
formula for the magnetic reluctance f c(p) of a thick-walled hollow
cylinder is obtained in the appendix, starting from the thermal
conductance equation and its solution; for large p
f (p) = TO &)(1 + L -
1C 2 e2 - YPT (7)
Card 2/ 9

S/NA'17022/011/011/014
Dynamic characteristics of ... D271 D306
D
where F_ is relative thickness of the cylinder, 1 + correcting
fadtor; for small p
f 1 + PT
2C 1 + (1 - 3) PT (8)
where 8 is a function of thG geometry. When the clutch is supplied
from a low impedance source,
n k k
pTo >> 7, o'-if i (p) 0(ifi(p)
i=1
and when the source is of high impedance
k
O~f i(p) >> pT.
Oard 3/9

S/103 61~HY/011/011/014
Dynamic characteristics of D271YJD)306
where
T Lo
source
- relative magnetic reluctance of circuit parts. The equation of
the forced characteristic is
k 1
Ocifi(p)
(10)
Transfer functions corresponding to the natural j ) and forced
characteristics are tied by the relations e
f - 1 1
- pTo fe - 1/f + -j-T-
1/te 0
Card 4/ 9

31270
3/103/61/022/011/011/014
Dynamic characteristics of D271/D306
With~the current supply the transfer function of the clutch, for
high~frequencies, is
(12)
-To- YP-
where
k
0 + Fi)
2 d-i + 9'1) - 2 (13)
;j = 0 and F, 1 for all disc shaped parts of the magnetic circuit.
Quadratic averaging is used-for finding the transfer function at
low frequencies with the result:
Card 5/9