SCIENTIFIC ABSTRACT FIRSOVA, M.M. - FIRSOVA, YU.V.
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CIA-RDP86-00513R000413220020-7
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December 31, 1967
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SCIENTIFIC ABSTRACT
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Category : USSR/Solid State Fhysics - R6chcmicn1rPr6p6rtieb1of E-9
Crystals and Folyerystalline Compounds
fibs Jour i Rof Zhur - Fizikp, No 3, 191-57, No 6771
Author : Zubov, V.G., Firsovs.
Inst : Moscow Univornty, 6tt
Title ; Concerning the Elpstic Properties of High Taipporature Quortz
Orig Fub : Dokl. AN SSSR, 19=5, lop, No 3, 493..494
Abstrpct : The Bergron-Schefor !:-,cthod was used to study the temperature
behavior of the i~lastic constants ofj9 quartz in the te-m-
pereture renge fron 578 -- 635'. As'tho temperature is in-
creesod, Cl, C md C12 increase monotoni lly, 044 ro-
n't Ut'hin he of experive"'
nains conEta t linits ntel error. At
58C0, C 033 and C12 reverses its sip. 0 C C
66) Oij- 12,
/2 incr I x lof 2.
cases monotonical1v from 50 x 10- to ~ yono7clln
m 17 x 1610 dyne/cm2 0 3 x 10
012 increaucs fm at 5800 t 6
n 12 at 615 -- 6200. The blroticity ofe quartz in-
dy a/c-
creRsen with tomperatura.
Ce.rd t 1/1
SOV/70-3-6-11/25
AUTHORS: Zhdanov~ G*89, Zubov, V.G., Ivanov, A.T.-and Pirsova, M.M.
VITLE; On the-Blastic Properties of Quartz Irradiated by Neutrons
(Ob uprugikh svoystvakh kvartsa, obluchennogo neytronami)
PERIODICAL: Kristallografi7a, 1958, Vol 3, Nr 6, pp 720-725 (USSR)
ABSTRACT: The elastic constants of quartz, irraaiated in a reactor
by fast neutrons, have been measured by the mthod of
Bergmann and Schaeffer. After irradiation by
2.1019 neutrons/em2 increasing errors which lay in the
limits of 0.9 to l.?% for a relative decrease in the
density of quartz of 0.18% were found in the-'experiment
for measuring the elastic constants. Comparison with
the temperature variation of the elastic constants showed
that the temperature and radiation changes in the elastic
constants corresponding to the same change in density
were sharply distinguished. The results agree qualitatively
with the work of Mayer and Gigon (J. Fbys.Rad., 1957,
'V01 18.) p 109) on the elastic moduli of irradiated quartz.
Measurements were made on blocks about 20 x 20 x 4 mm.
cut perpendicular to the crystallographic axes. Your
series each of three plates were used, careful controls
being kept. The frequencies used were 8-10 Me/s. Wittels
and Sherill (Phil.Mag., 1957, Vol 48, p 24) contrasted the
Cardl/2
SOV/70-3-6-11/25
On the Elastic Properties of Quartz Irradiated by Neutrons
changes in the elastic constants produced by thermal and
radiation-produced expansion of the crystal lattice.
Although qualitatively the anistropy is the same the
actual values for it are quite different. This is shown:,,.
experimentally. The structural meaning of the results
obtained is not discussed. Acknowledgments to
Academician I.K. Kikoin and V.L. Karpov. There are 4 tables.
There are 11 references, 3 of which are Soviet, 8 English.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet ir.
M.V. Lomonosov~x (Moscow State Universityimeni
M V. Ljlon~5g)
SUBMITTED: June
Card 2/2
ztrBovp V.G..,- OSIPOVAp Le 4. FIRSOVA, M.M.
Eff6ot of constant voltage on the intensity-and width of Haman
spectrum lines of6,6-4uartz. Kristallograftia 6 no.5:777-778
S-0 '161. (MM 14:10)
1. Mbskovskiy gosudarstvennyy universitet imeni. M.V.Lomonosova.
(FAMAn effect) (Quartz)
ZUBOV, V. G.; ?~A 4,11N,&
Characteristics of the elAstic behavior of quartz in the o(. - /I
-transition region. Kriotallografiia 7 no.3:,469-471 )tp-Je 162,
(MIRL 16:1)
1. Moskovskiy gosudar8tven'M7 universitet imeni M. V.
Lomonosova,
(Quartz Elastic properties)
GOVOROVAJ, Ye.Z.; FIRSOVA, M.M.
Interaction of natural oscillations in crystals. Kristallografiia
9 no.4:459-465 JI-Ag 164.
(MIRA 17:11)
1. M6skovskiy gosudarstvennyy universitet imeni Lomonosova.
f +
t
V. G i rsova, ~l M. s
n -n ft I,
lari ar 10
q.
KI-istalloqrafiya, V. 9, no. 6, 1964, P64-43r,9
-n,PT,7 TA-13: quartz, diOleCtriC cOnstant. temnerature variation,
r L ty content
.1 21~1.- is a ront-inuation c?f an --irl ley 1 M'cSt- ll;At- ic-In r,
a
a nc
the diele-tric cons t an t a
I e Irl i 5 app
r, 5 e erT%P 1 Cry e (i
Caro
AP 50 0 G.'? 9 0
T!-~,-~ results have disclosed a 'nifm,IJ-n unnhser-,,ed Dhenome-
non, name1v that the dielectri-c constant negins to increase rapidiy
;n-T the appl:cation of the constant eleci:ric field, passes
af:--er wh4c!7 il~ decreas-z. 7
of reach!-71,4 -"',e Max.:71'.7'
r-p,- a,- L on oaL
'.slr~-~ thecrv o A. I -
'40
.-,---a KX.-IV, -,915, pp. 12 t n''
always present in the quartz,
Of the crystal. These dissociated .,)ns -,ave su 'r 1 c i e n t
participate in all the electri-c -3-)ces3es nc-~r-rinic in
c rv 5a IVhen the electric field is applie(-,. 0 f.L g .art. has: 5
fiqures.
ASSOCIATION: Moskavskiy gosudarstvenny*y uni,;ersitet im. M. V.
Card 2/4
ACCESSION NR: AP5000290
T.omonosova (14gLscqw.~tate University)
SUBMITTEE: 17Mai.,64
SUB CODE: SS 1EIll
NR REF SOV- 004
Card 3/4
ENCL: 01
OTHER: 004
Card 4/4
A '19
~P ;7
L 07839-67 ENT(l) lj]~(c)
ACC XR: AP6D24670 SDURCE CODE:
0
'AUTHOR: -Govoroya, Y6,.Z.;__ZA9vp V. G.; Firsova, M. M. 4q.
ORG: Moscow S UnivorsA~Z in. V. M. Lononosov (Moskovskiy gosudarstvonnyy
univorsitot)
ITITLE: Certain features of acoustic wave Interaction in crystals
SOURCE' Kristanografiyat Y. no no. 4, 1966, 628-631
I.",I
~TOPIC TAGS: acoustic wave,".ultrasonic wave propagation, ammonium compoundp
;acoustic diffractiong.single cryatall quartz crystal
ABSTRAC`r: 'This in a,continuation of earlier work (Kristallografiya v. 9, no. 4,
459 _- 465, 1964), where the authors observed in a-quartz, by an ultrasonic dif_
lfraction*mothod,-tho appearance of longitudinal osci3-lation modos accompanying
,.transverse oscillations,, The present article is devoted to a similar study with
:Singlo-cr7s
'~a AbP in which there are no piozoooofficionts causing longitudinal
oscillationsp and In which the elastic nonlinoarity is larger than in quartz,
,Ike
!rosults have shown that the transverse mode is continuously accompanied by a second
iharmonio of a longitudinal mode In the saime direction. In the general case.this
Card 3/2 UW: 48-0:339~47_
L 07839-67
ACG NR: Ap6o2467o"'
ilongitudinal mode is weaker than the mode exciting itv but under certain-goomotrioal
I
~,rosonanco conditions the diffraction maxima on the longitudinal mode become com-
!parable in brightness with the original transverse mode. The result is shown to
:agree with a general formula derived for the Fropagation of an elastic wave in a
~nonlinear crystalline modiumt whereby under certain conditions the second-harmonic I
Ilongitudinal Oscillation can increase spontaneously and jivo rise eventually to a
ifirst h=wniep which was not prosent'hitherto. 7his bnorgy transfer from one har-I
imonic to another is in good agreement with the results of E. Formi, J. Pasta and
Is. H. Ulam (Studios of Nonlinear Problemsg LA-1940, OTSp US Department of Commorco,I
iWashing-ton, D. C.)p who investigated directly the energy transitions in the spee-_ !
itrum of a vibrating string with nonlinear parameters. The present experiments, like I
'Ithe observations of Fermi et al.j only permit observation of this *oooss but still
'offer no theoretical explanation, The authors thank.I. S. z,,F Fen.ina. and
I. D. Zaytsova for proparing the high grado ADP crystals. Orig. a i
and 4 formulas.
SUB CODE: 20/ SUBM DATE: O&Up&/ ORIG- MW 004/1 OTH MW: 003
be
~-FIRSQVAO, N.M.
Morphology of the thyroid gland and the economic productivity of
the Tajik breed sheep, Report No.:Ls Macromorphology of the
thyroid gland in wethers and young rams of the Tajik breed.
Trudy KirgNOAGE no.W7-80 165.
Morphology of the thyroid gland and the economic productivity
of the Tajik broad sheep& Report No*2x Effect of iodine feeding
on weight gains in wathers and young rame or the Tajik breed,
Ibid,t8O-84
Morphology of the thyroid gland and the economic productivity
of the Tajik bEreed sheep. Report No.3c Effect of iodine feeding
on the wool produotion in mother sheep, ewe lambs and yound rams
of the Tajik breed. Ibid.a84-87 (KRA 18%1:L)
1. 1z Tadzhikskogo nauchno-i9sledovatel'skogo instituta sel"Skogo
khozMst~ia i Wedry gistologii (zav, - prof. A.A.Braun)
Kirgizakogo gosudarstvannogo meditsinakogo instituta.
TT
FIRSOVA,
25~0/6 Firsova, N.N. 0 Psikhoraitizatsii V Svyfizi 5 3heJyL.I--tnc-Lltsev:.q--,* -R-ren'! '-I=i.
Za~ijmi. V SB; froblemy Vosstanovit, Lecheniya Invalidov Otf..chez;tv.
Voyny. Astrakhan', 19,48, S. 113-24.
SO: Latopis' Zhurnal Statey, No. 30, Yoscow 1948
~,' T F," *, , ~ i -, - :- .
Vyyar,novsHy, A. Yu. and Firsova, N, N - "Schizophrenia MI ran*c-J(-'rre:33il.-e
""'6 e-,
psychoses Iiiririg the Twar", Trudy Astralli. cos. med. in-ta, '101. Ix-, 194-, P. 194-
9o.
SO: U-3,04.2, 11 March 53, (Letopis 'Zhurnal Inyl-h SLate-.-, I-To. 08, 191,n).
0 sostoyanli polkhcm'vrologioheSkOy romoshchi Naseleniyu v Astrakhanskoy Oblwti
p. 5.52 V ob Aktualln. probl. neVrOPdtOl _i Psikhiatrii- Ruvbvshev, 1957.
SDIONOV; S. (g,Petrozavodsk) FIRSOVA 0 h.-konstruktor,-
.Odessa); PETRYAY.GV, V.
YIASLOV., V.j VARSUM MINg=
Readars report.. advise, suggest. Zhil.-kom. khoz. 12
no.1:15 A t62. (MIRA 15: 6)
1. Predeedatell domovogo komiteta domoupravleniya No.13
Sovetakogo rayona,, g Gorlkiy (for Petrvanov).
iMunicipal services5--
2V :-, , ~ ~- ~ , . - ~- -.
FIRSOVA) O.D.
Work of the Crimean Provincial Oncological Dispensary in in-
creasing oncological knowledge among medical personnel. Vop.
onk. 7 no.113100-102 161. (MIRA 15:5)
1., Iz Krymskogo oblastnogo onkologicheskogo, dispansera, (glav-
vraeb - O.D. Firsova).
(CANCER)
A, p~k
'W
XAGIB, Akhmed; (Moskva)
Methodology for performing bronchospirometry, Eksper, kchir. i
anest. 8 no.431-33 Jl-Ag 163. (MIM 17 t 5)
FIRSOVA~ P. P.
FIRSOVA, P. P. "Change of the.Phagocytic Reaction of the Blood In Patients
With Intlamnatory Processes and Under the Influence of Pathogenetic
Therapy." Sub 24 Dec 52, Acad Med Scl. UST. (Dissertation for the
Degree of Candidate in Medical Sciences).
SO: Vechernaya Moskva January-December 1952
YIRSOVA. P.P.
sthods for studying respiration In pulmonary patients [with surnAry
In BuglIsh] Ikeper.khir. I no,4s43-49 Jl-Ag 156 (MIRA-Ils2o)
1. Is Institute, khirargii imeni A.T. Vishnevskogo (dlr. -chlen-
korrespondent AMR SSSR prof. A.A. Vishnevskiy) AMR SSSR.
(PINSPIRATICK, function tests
preopo in cardiopulm, surge# new appare (Rua))
(IMSPIRATION,
now appnr. for preop. funct.tests in enrdiopulm. surgo
(Rug))
(IMSPIRATION,
funct. die., technics & appar.
FIRSOVA. F.P
(Moskva)
Differential diagnosis of thoracic tumors vith Minor's test. nin.
me&. 34 no.12:71-76 D 156. (KISA 10:2)
le Is 2-go khtrurgicheskogo otdelaniya (sav. - Prof. G.V.Alipov)
Instituts kh1rugil iment AsVoVishnavskogo AHN SSSR (dir. - chlen-
korrespondent AMU SSSR prof* A.A.Vishnevskiy)
(THORAX, neoplasms
neurilemona, diag., evesting test)
(,MURILWWA, diag ~
thorax, sweating test)
FIRSOVA.. P.P.
A simplified method for pecialized Ibronchospirometry. Report No,2.
(with summary in English? Jksper.khir. 2 no.5*58-61 S-0 157.
(MIRA 11:2)
1. Iz 2-go khirurgiobeekogo otdeleuiya (zav. - prof. G.V-Alipov)
Institute khirurgii imeni A.Y.Vishnevokogo AMN SSSR (dir. - daystvi-
tellny7 chlen AMU SSSR prof. A-A.Visbnevskiy-)
(RESPIRATION. fanot. tests
bornehospirometry, simple method (Rue))
USSR/General Problems of Pathology. Neoplasms. U
A'bs,Jour: Ref,Zhur-Biol., No 8, 1958, 37293,
Author :-Firsuva, P.P., Pyltsov, X.M.
Inst
Title The Clinic of~Lung Plasmocytoma.
Orig Pub: Klinich. meditaiina., IM)_ 35P HO 7, 98-102.
Abstract: Theauthors describe three personal observations of
extra medullary lung plasmocytomas and analyzed 8 canes
in the world of literature. The tumor was more fre-
quently situatedAn the upper lobes of the lung, in
the form of an isolated structure inclosed in a thin
capsule. On section, the tumor appeared white-yellowish
or gray-yelIowish in color, was fragile, and consisted
of mature plasma cells of 10-12 microns in diameter.
Card 1/2
FIRSOVA, P.P. (Hookm).
--PNW*-
Pneumograph with a,measuring system. Acep. khir, 3 ao.605-56 H-D 13810
(PHYSIOLOGIGAL UTARATUS) (RI*PIFATION) (KIRi 12: 1) ,
A
VOROPAYNV, H*14*; KAZAYSV. P.N.; 7IRSOVA. P.P.
Angiopneumograpbr in lung cancer. Sov.mad. 22 no.2:49-52 7 158.
(MIFIA ll*-4)
1. Iz 2-go khirurgichaskogo (zav. - prof. G.A.Alipov) i rentgano-
logicheakogo (sav. - prof. PAI.Kazayev) otdolaniy Insituta
khirtLrgii imeni A.Y.Vishnovskogo (dir. - doyetvitellnyy ablen
Akademil meditainskikh nauk SSSR Drof. A.A.Vishnevskly) Akadekmii
maditsinskikh nauk SSSR.
(IIJM NEOPIASKS. diag,
angiopneumography (Rua))
(ANGIOGRORT, in various dis.
lung cancer, angiopneumograpIT Otus))
KRTMSKIT, L*J)*, kaud.med.nauk; ?IRSOTA, P,Pe, Icand.med.uauk (Koskva)
Unusual case of thymoma. Arobl. andoki gorm. 5 no.5:111-114
S-0 '59. OaRA 13 :5)
1. Is Institute. khirurgii imeni A.V. Vishonvokogo (dir. - doym-tvi-
telinyy chlen ANN SSM prof. AA. Vishnevskiy).
(THYMOVA case reports)
OV
UY.. A.A.; _gM AvZZ.; RUITRIMAp ?.Ye, [deceased]
(Minical picture of nonparanitio aysto of the pericardiumi,
Rhirurgiia 37 p#10-12 Ja 161, (MMA 34s2)
1. Iz InstitutA khirurgii imeni AIDV. Viabnevskogo (dir, - dayst-
vitellnyy ob3,e7A AMN SWR profs A*A* Vielaievskiy)*
(paloARDIUM-TUMORS) (CYSTS)
FIRSOVA, P P.
Xffoot of pleural adbesions on the function of external real-Ara-
tion. Grud. khir. no,2:46-51 162, (MIRA .15:4)'
11 is 2-90 khirurgichaskogo otdoleni34 (sav. - prof. 0. V. Alipov)
Instituta kbirurgii imeni A. Vo Vishnevskogo (dir. - deystvitel Inyy
cbleh AMN SSSR prof. A. A. 1fdobnevskiy) JHN SSSR. Adres avtcym:
Moskva, B, Serpukhovskaya ul., d, 28, Institut khirurgii ime-ni
A. V. Viohnevokogo.
(RMRA.DISMES)
,(ADESSIONS(ANATCKY))
Fl-R30VA, P.P.: PECHATNIKOVA, Yo.A.; AKIJMET-nGIB
Physiological basis of surgical approaches to the esophagus.
Vest.khir. zio9319-14 162o (mrRA 15:3)
1, Iz Instituta, khirurgii im. A.V. Vishnevskogo (dir, - pr2f.
A.A. Vishnevdkiy) AMR SWR. Adres avtorovi Moskva,, B. Serpakhov-
skays, ul,, d.27, Institut khirurgii im. A-V. Vishnevskope
(ESOPHAGYJS--SURGERY) (SPIROSCOPE AVD SPIROSCOFY)
FIRSOVAP-P*P*j MAYSYUKp A.P.; NIKONOROVV A.I.
Diagnosis and treatment of cartilaginous formatIons in the
lungs, Khirurgi:La.38 no.12.-28-34,,D 162... (NM 17t 6)
1. Iz Instituta khirgurgii imeni A.V. Viohnevskogo (direktor
dpystvitellnyy chlen AMN SSSR prof. A.A. Vishnevskly) AMN SSSR.
-FMOVA.. R.P.; MAYSMJK, A.F.
3nterocystomas of the thoracic cavity. Grudn. khir. 5 no. 3:
92-94 My%-,To 163. (MIRA 17:1)
1. Adres avtoroviMoskva,, B*Servuldiovskaya ul., d. 27, Tnstitut
khinirgii imeni A.V.Vishnevskogoo
FUCHKOV, N.V.; ~LYT-)J -!.F -
Effect of parasympathicotropic substances on ihe phagocyt:Lc
activity of loukocytes in patients with cancer; prelimina:ry
report. Biul. eksp. biol. i med. 55 no.3:85-86 Rr 163.
(14IRA :18:2)
1. Iz laboratoril patofiziologii (zav. - prof. N.V. Pichkov)
Instituta pediatrii AIIN SSSR I Instituta khirurgii imeni A.V.
Vishnevskogo (direktor - deystvitellnyy chlen AMN SSSR A.11.
Vishnevskiy), Moskva. Submitted May 15, 1961.
SARKISOV, D.S.j--UUPV-A,_P!,P..j NRISUN, A.A. (Moskva)
Giant-csll m43Agn=t thruma. Arkh. pat. 26 no.12:26-31 164.
1. 2-ye khirurgichesk6ye otdeleniye (zav. - doktor med.nauk
M.MiVoropaye-)-i otdol patologicheskory anatomii (zav. - prof.
D.S.Sarkism) Instituta khirurgii imeni Vishnevskogo (dir. -
deystvitelInyy chlen AMN SSSR prof. A.A.Vishnevskiy) AMN SSSR.
ALITER, L.B Joktor ekon. nauk; BLYUMIN, I.G.f doktor ekon. nauk
[;e'ceased]; KARATAYEV, N.K., prof.; REUEL', A.L., doktor
ekon. nauk; STEPANOV, I.G., doktor ekon. nauk; SHTEYN, V.M.,
doktor ekon. nauk; POLYANSKIY, F.Ya,, doktorist. nauk;
BOBKOVI K.I.2 kand. ekon. nauk; VASILEVSKIY, Ye.G., kand,,
ekon. nauk; MOROZOV, F.M.p kand. ekon. nauk; POII%UM, Ye.I.,
kand. ekon. nauk; RYNDINA, M.N., kand. ekon. nauk;_E=~"~ h..,_
kand. ekon. nauk; TSAGA, V.F., kand. ekon. nauk; Zw~ I., red.;
VOSKRESENSKAYA) T., red.; NEZNANOV, V., red.; ULANOVA, L.p tekba
red.
(History of economic theories) Istoriia ekonomicheskikh uchenii.
Moskvav Sotsekgizp 1963. 549 P. (MIRA 17:2)
1. Akademiya nauk'SSSR. Institut ekonomiki.
SLABKINA, A.I.,kand. sellkhoz. nauk; r)VL,.T,N , kand. sell-
khoz. nauk; POTOKIN, V.P.# kand. sellkhoz. naukj
VOLKOVI G.K.0 kand, vet. naukj SHKUDOVA, R.I., red.
(Principles of animal husbandry] Osnovy zhivotnovodstva,
Moskva, Kolosp 1964. 263 P. (MIRA Mill)
88473
S/078/61/006/001/007/019
BO17/BO54
5,21oo
AUTHORS: Mellnikov, A. Kh., Firsova, T. P.
TITLE: Low-temperature Ril~t~ion of Sod'ium Hyperoxide With Water
Vapor
PERIODICALt Zhurnal'neorganicheskoy khimii, 1961, Vol. 6, No. 1,
pp. t169 - 176
TEXT: The reaction of sodium hyperoxide.'(NaO2) with water vapar at -10,
-5, and 0OC and a water vapor pressure of'2.0 - 41.6 mm Hg was ilynamically
investigated by the apparatus shown in Fig.l. Results are compiled in a
table. Fig.2 shows the kinetics of oxygen delivery and the absorption of
water vapor in the reaction of sodium hyperoxide with water vapor. The
0
reaction of sbdium hyperoxide with water vapor between -10 and 0 C
proceeds according to the equation 2 Na02 + nH20 ---,,Na2o2*nH20 + 02' Fig-4
shows the t'ernary diagram of the system Na 0 - 1/2 0 H 0 at 0, -5, and
2 2 - 2
0
-10 C. The heat effect of the formation of sodium peroxide octahydrate
Card 1/2.
88473
Low-temperature Reaction of Sodium Hyperoxide S/078/61/006/001,1'007/619
With Water Vapor B017/BO54
from NaO2 and water vapor is 115-48 kcal, in the reaction with water it is~
29 kcal. In the reaction of granulated sodium hyperoxide with water vapor
at +200C, a monohydrate of sodium hydroxide is formed with delivery of
active oxygen. The octahydrate of sodium hyperoxide was synthesised. Its i
0
specific gravity is 1-56 at 0 C. Two endothermic effects appear tin the
0 0
heating curves, the first at 50 - 70 C, the second at 110 - 130 C. Fig.6
shows the rate of oxygen delivery from the octahydrate of sodium hyper-,
oxide as a function of temperature. I. A. Kazarnovskiy, S. Z. Makarov,
N.,,K'.Grigorlyeva, and V. R. Kotov are mentioned. There are 6 figures and
19 r;firencest 9 Soviet, 9 US, and 1 French.
SUBMITTED: October 8, 1959
gfular fly.
27854
17. 11 T1 kt-~o 12- 7 ~j I Sb S1078/6!/006/010/l."01/010
1/,21110 B121/B101
AUTURS: Mellnikov, A. Kh.p Piraova, T. P., Molodkina, A. N.
TITLE: Production of pure preparations of sodium peroxide and
potassium su~eroxide
PERIODICAL: Zhurnal neorganicheskoy khimii, v. 6, no. 10, 1961, 2225-2229
TEXT: An improved method has been developed for producing pure prepara-
tions of sodium peroxide,(Ka2 02) , and potassium superoxide, K02 , by
oxidizing the metals with oxygen. The apparatus is shown in Fig. 1.
Reaction flask I is filled with the alkali metal by feeding part of the
metal, previously melted in a toot tube, through a capillary tube into
flask 1. Sodium peroxide-wao produced from sodium and oxygen ina two-
stage process. In the first stage, an oxygen pressure of 6-8 mmHg is
applied for about 30 mini the,second stage lasting for 2-2 1/2 hr is
performed under atmospheric pressure. At the beginning of oxidation an
orange-colored luminescence of the metal occurs at 240-2500C, which may be
prevented by reducing the 02 supply. Complete oxidation occurs at a
Card 1/3
27894
S/078/61/006/010/'001/010
Production of pure preparations of... B121/B101
temperature of 3600C at moat. The loose reaction product formed can
easily be removed from the reaction space. The process is easily
reproducible and gives yields of 100 ~ of Na 202' Potassium superoxide is
similarly formed: Metallic potassium is treated in the first stage for
30-40 min at an oxygen pressure of 6-6 mm Hg, and in the second etage for
4-5 hr at atmospheric pressure. The initial temperature in the oxidation
process applied to obtain potassium superoxide is 110-1200C, and the final
temperature is 3500C at most. The KO 2 yield was 92.74-98-34 %. This
process involves a noticeable corrosion of the glass reaction vessel owing
to silicate formation. Thus, high-purity preparations can be obtained only
in vessels resistant to alkali oxides. Proper dooing of oxygen results in
a reaction time only one-fourth or one-fifth that required 'with the use of
air In the first stage (paper by I. A. Kazarnovskiy, S. I. Raylrhahteyn
(Zh. fiz. khimii, 21, i45A 1947)) is mentioned. There are 2 figures,
2 tables, and 3 reYie'iences: I Soviet and 2 non-Soviet. The reference to
the English-language publication reads as follows: A. V. Harcourt, J.
Chem. Boo. (London), jA, 267 (1862).
SUBMITTED: September 15, 1960
Card 2/3
2 27895
S/078/61/006/010/002/010
11-1155 B121/B101
AUTHORS: Melinikov, A. Kh., Firsova, T.P.
I--- -
TITLE: Interaction of sodium superoxide and carbon dioxide In the
presence of water vapor
PERIODICAL: Zhurnal neorganicheskoy khimiiq v. 69 no. 10, 1961, 2230-2236
TEXT: The reaction of sodium superoxide with carbon dioxide in the
presence of water vapor is studied by a dynamic method in the temptyrature
range from -10 to +250C. The apparatus is described in Zh. neorg. khimii,
A, no. 10 (1961). At -10p.0, and 100C, the humidity of the gas mixture
corresponded to saturation; at 250C, relative humidity was 25 or 50 %. it
was found that oxygen was set free but incompletely below 100C (only
"superoxide oxygen"): 2NaO 2 +2C0 2 - Na2C206 +02 (6). Humidity asaists to
form the peroxy-dicarbonate (Na 20..8H20 as intermediate product). The
absorption of carbon dioxide proceeds slowly under these operating condi-
tions. The molar ratio CO 2/02 tot exceeds 1. A significant change of the
reaction process occurs at 250C. Evolution of oxygen proceeds very
Card 1/2
27895
S/078/61/006/010/002/010
Interaction of sodium superoxide and.- B121/B101
quickly and the capability of sodium superoxide to absorb carbon dioxide
decreases; the molar ratio CO 2/92 falls below 0.5. The following reactions
occur: (1) 2ffaO2 +H20 - 2NaOH + 1 1/2 02 (2) 2NaOH + C02 - Na 2CO3 +R20.
Sodium peroxy dioarbonate Na 2C206was synthesized from sodium superoxide or
sodium peroxide, carbon dioxide, and water. The initial peroxides were
ground with a certain quantity-of ice, The concentration of carbon dioxide
in the initial gas mixture did not exceed 1 % by volume and was increased
to 100 % by volume during the reaction. The reaction product is concen-
trated with alcohol and ether, and liberated from adsorbed ether VaDors by
vacuum distillation. IdenticAl products were obtained from sodium peroxide
and sodium superoxide (yield 68-85.9 %); this was confirmed by thermal
analysis. Thermal deoompositi6n of sodium peroxy-dicarbonate occurs with
simultaneous evolution of active oxygen and carbon dioxide:
Na2C206 -Na 2C03 +CO2 +112 0 2 (7). There are 3 figures, 2 tables, and
4 references; 2 Soviet and 2 non-Soviet.
SUBMITTED: September 15, 1960
Card 2/2
ooo 29529
S/078/61/006/011/004/013
B101/B147
AUTHORS: htelOnikov, A. Kh.~.Firsova, T. P-
TITLE: Interaction between sodium peroxide octohydrate and gaseous
carbon dioxide
PERIODICAL: Zhurnal neorganicheskoy khimii, v. 6, no. 11, 1961, 2,170-2473
TEXT: In a previous paper (Zh. neorgan. khimii, 6, no. 10 (1961)), the
authors found that the reaction between NaO and j6 in the presence of
2 2
water vapor yielded sodium peroxy-dicarbonate, Na2 C 206' In this sYnthesis,
Na20 2' 8H 20 was produced-as intermediate stage. Since Na 20206 might be of
practical importance as mild oxidizer, it was synthesized by reacting CO 2
with Na 2 02* 8H20. The latter can easily be synthesized from NaOH and H 202-
Dry CO 2 was conducted over Na 202' 8H20 which was contained as a thin layer
in a flask. The reaction vessel was cooled by water. The synthesis
proceeded in three stages, (1) PCO 2 = 3 mm Hg, 1.5 - 2 hr; (2) p Co 2~ 30 mm Hg,
Card liV,
29529
S/076/61/006/011/004/013
Interaction between sodium peroxide... B101/B147
0.5 hr; (3) alternate filling of the reaction vessel with pure X 2 and
subsequent evacuation for removing the water residues, Experiments were
performed between 0 and 33 0C. 85.7 - 95-5~ yields of Na2 C206 weri~
obtained independent of temperature. The specific weight of this compound
which was pyonometrically determined in benzene was 2X75 at 200C. The
product contained NaHCO 3 as impurity. The following data are given:
Substance Molecular
weight Density,
/cm3
9) Specif c volume,
cD/mole Relative change
of v("lume
2NaO
. 2 110 2.18 50.5 1.00
Na202' 8H 20 222,1 1.57 142 2.51
Na2C206 166 2-075 80.0 1.58
Therefrom it follows that carbonization of octohydrate causes a considerable
decrease of volume. The differential thermal analysis of Na2C206 Y(ith a
Kurnakov pyrometer showed an endothermic effect at 1020C, which corresponds
Card 2/'V 3
W
3/078'?R~00 6/011/004/0 13
Interaction between sodium peroxide... B101/B147
to thermal decomposition of Na 2 C206into Na 2C0 Y From a 30';~ KI solution,
12 is liberated by Na 2C206' The action of water on Na 2C206 ini tia,tes
hydrolysis already at room temperature. Active oxygen)and, especially at
the beginnin8 of the process, CO 2 are set free (Fig. 3 . For this course
of hydrolysis, the follo~iing is assumed: Formation of HaHCO 49 then of
H CO and decomposition into CO and H 0 Decomposition of H 0
2 49 2 2 2- 2 2?
liberation of active oxygen, is the slower process. There are 3 figures,
2 tables, and 2 Soviet references.
SUBMITTED: September 15, 1960
Card 34-3
S/078/62/007/006/004/024
B120130
AUTHORSt Mellnikov, A. Kh.,,Firsova, T. P., Molodkina, A. V.
TITLE: Interaction of potassium hyperoxide with water vapor and
carbun-dioxide
PhRIODICAL: Zhurnal neorganicheskoy khimii, v. 7, no. 6, 1962, 1228-1236
TEXT: When studying the interaction of potassium hyperoxide with water
vapor between -10 and +190C it was shown that practically no peroxide.
oxygen was set free at -100C, while at OOC 3/4 of the original peroxide
oxygen remained in the product, even after 3 hrs. Practically the whole
peroxide oxygen was set free at 19 0C. At 100C and below, the hydrated
compounds K 20 2-nR 20 were formed, wh!. le at 1qoC and above KO2 was converted
to KOH with release of the whol*e active oxygen, and - in the presence of
sufficient water vapor - KOH was formed in various hydrated forms and
solutions. Fig- 3 shows the grgdual change of composition of tho solid
phaseq and Fig. 4 shows the arrangement for studying the interaction
between KO and GO The interaction depende mainly on temperature.
2 2*
Card 1/9
1T
S/07 62/007/006/004'/024
Interaction of potas6ium hyperoxide ... B124YE138
The composition of the end product depends on the transition phase formed
during the first stage of interaction between KO 2 and water vapor. it
100C and belowl hyperoxide oxygen is set free, and potassium peroxodi-
carbonate K 2C 206is formed, while at 500C and above potassium carbonate
ana bicarbonate are formed with the release of all the active oxargen
(Figs. 7 and 8). Bef-ween 10 and 500C, the formation of K C 0 io mainly',
2 2 6 i
determined by the effective removal of the heat of t)ie exothermic reaction
between KO2 and CO 2- No proofs have been found for the formation of
potassium monoperoarbonatep K 2COV and potassium pyrocarbonate, P:.,c 205*
There are 8 figures and 2 tables. The three most important Englioh-
refermaces ares P. W. Gilles, J. L.-Margrave, J. Phys. Chem. 60,
1333 (1956); C. A. Kraus, E. F. Parmenter, J. Amer. Soc. 56, 2385 (1934);
J. R. Partington, A. TJ. Fathallahq J. Amer. Chem.'Soc., 1934 (1950-
ASSOGIATIONs Institut obshchey i neorganicheskoy khimii im. 11. S.
Xurnakova Akademii nauk SSSR (institute of General und Inor-
ganic Chemistry imeni N. S. Kurnakov of the Academy of
Sciences USSR)
Card 2/1
S
Interaction of potassium hyperoxide
SUBMITTED: l1lovember 1, 1960
Card .3/0
S/07 62/007/006/004/024
BI 24YBI 38
Fig. 3. Ternary
diagram for
K 0 - (1/,")0 H 0.
2 2 2
(I) Test temperature
-,10 and O'D(,'
(II) tost.temperature
190C. Legends
(A) K02 inl.tia.ls-
S/078/62/007/006/005/024
B124/B138
Imi R' i
mel nikov, Kh. I Firsoval T. P. I Molodkina, ft. 11.
TITLE: Production of pure potassium peroxodicarbonate and study of.'
some of its properties
PERIODICAL- Zhurnal neorganicheskoy khimiij v- 7, no. 6, 1962, 123T-1241
TEXT: The authorn studied the optimum conditions for the convernion of
potassium hyperoxide to potassium peroxodicarbonate, and compared the
properties of the latter with those of peroxodicarbonate obtained
according to E. J. Constam and A. Hansen. They used 98.7% potassium
hyperoxide as initial product. A mixture of CO 2 and kater vapor was
continuously blown.throuGh a thin layer of fine-grained product. The
temperature of the thermostat, in which the reactor was placed, was kept~"
at - OOC; the hyperoxide layer was heated to 100C by the heat rileased
during the reaction. The experiments took 1-2 hre; they were c,9.rri-ed on
until constant weight was reached. Finally, the product was dried with
dry air for 2-3 hrol first at experimental and then at room temperature.,.
Card 1
S/078/62/007/006/0()5/024
Production of pure potassium B124/BI36
The resulting product was light-brown whereas the electrolytic product had
a pale-bluish color. The product obtained by interaction of KO 2 with CO 2...
had an average pvrfty of - 85%. The electrolytic production of K C 0
2 2 6
from saturated K 2CO3 solution was performed in an H-shaped vessel, with a
porous separating wall; platinum wire was used as anode and a platinum
disk as cath9de. A 3CA-10 (VSA-10) selenium rectifier provided alternat-.
ing current of 15-16 v and 0.1-0.3 a. The electrolyte temperature was
-15 to -200C and the purity of the product up to 99.9~. Dry K 2C206
preparations obtained by the two methods are fairly stable, even at room
temperature. Losses of active 'oxygen within I year are only fractions of
I~a at room temperature. The product becomes gradually brighter. The
thermogram obtained by Kurnakov pyrometer (Fig. 2) showed two endothermic
effectso at 155-1600C (thermal decomposition of K 2C 206) and at
198-2000C (decomposition of KHCO 3). The specific gravity of pulle K20206.
obtained from KO 2 was determined pycnometrically in benzene solution,at
Card 2/d
s/07 62/007/00.6/'005/024
Production of pure potassium ... B124YB138
0
20 C. it was 1.97, while for electrolytic K C 0 it was 1-95-
2 2 6
S. Z. 111takarov and I. I. Vollnov are mentioned. There are 3 figures and
2 tables. The English-langoage reference is: 1. R. Partington,
A. U. Fathallah, J. Cheat. Soo.-(London), 1934 (1950)-
ASSOCIATION: Laboratoriyaperekisnykh aoyedineniy, Institut obshchej i
neorganicheskoy khimii im. 9. S. Kurnakova Akademil nauk SSSR,1
(Laboratory of Peroxide Compounds, Institute of General and.
Inorganic Chemistry imeni N. S. Kurnakov-of the Academy of
Sciences USSR)
SUBMITTED: December 3, 1960,
Fig. 2. Thermogram. of potassium peroxodicarbonates (CL) obtained, from
otassium hyperoxide; (6) obtained electrolytically. Legends
R 1000 ohms; (B) R
diff simple 70000 ohmsj (0) time, min,
Card
Un IF,
S/078/63/008/002Y'002/012
BIOI/B186
AUTHORSs P i rs!~ Molodkinat 'At N-P Morozoval T. Gelp
Akeenova, L. V*
TITLEs Synthesis of sodi" peroxocarbonates
PERIODICALt Zhurnal-neorganicheskoy khimii, v. 89 no. 2't 19630 276 264
TEXTs In order to prove the existenoe-ofalkali hydroperoxides and to
develop a simple method for synthesizing alkali pe'roxocarbonates,-CO' was
2.
~bubbled through concentrated solutions of NaGH and H202 at low temperatures.
The filtrate was washed with ether and dried, in air. The ratio NSOH I H-0
2.2
was chosen aoqording to the + &q
-:equations 2MOR + R 0
2 2 M2029a"
0 When
MOH + "2 21~,_MOOH + U2 0 and MOB + 1-5 H202---*MOOH-0-5 H202 + H.200
1), bubbling of 00 throughw
carefully mixing H2P2 'with XaOH (ratios 0-5 2
the mixture at a temperature from 0 to -150C lead after 8 - 10 min to'dis...
solution of the-initially formed sodium peroxide actahydrate and to th~
Card 1/3
5/078/63/008/002/002/01-2
Synthesis of sodium peroxocarbonates B101/B186
sedimentation of a new phase which,vas identified as. Na C *XH 0. Depend-
2 Z(6 2
ing on the drying conditions, x fluctuated between 0.6 and 14 mole.. The
residual 0.6 mole H20 could not be removed without decomposing the substance.,
Thermographio analysis pointed to an endothermic effect at 1260C-Ni'th the
total active oxygen being liberated and Na CO foiming. If themixing ratio
2 3
H 0 j NaOH was I s 1_Y1k9,OH-3H 0 was formed first. 'Bubbling CO~ through
2 2 2
the solution at a temperature between 0 and -200C lead to the formation of
sodium diperoxocarbonate NaHCO *H 0 according to the equation 00
4 2. 2
+ MOOH With the ratio-H 0 v NaOH 1,.5_s 1 NaOOH-0.5H 0*2H 0
4* 2 2 2
was formed as intermediate pToduot, as final product also'KaHCO -it 0. 'The
4
for-mation of thenew phase was finished in 20 to 25 min, longer bubbling
lead to the decomposition of peroxocarbonate,into bicarbonate. The yield'-
of sedimented peroxocarbonate depends on the degree of dilution du.e to the.
solubility of this compound. According to the equation NaOH+ CO 2
+ H202 --- "NaHCO4 tH20, the,sol vent H20does not combine in the compound. At
Card 2/3
/S/078/63/008/002/'002/012
Synthesin of sodium peroxocarbonates B101/B166
'OOC and a ratio of NaOH a H 0 1 1 5-5 the yield was 8094at a ratio of
2
I 1 23 no sodium diperoxcoarbonate was precipitated. This corresponds to.:'
a 12% solubility of,this compound. A thermographic analysis yielded an
endothermic effect at500C with a transformation to Na CO, *H 0 whereby
2 3 2 2
only half of the active oxygen wag libera
ated, ae'Well as an iixothermic
effect at 750C where the remaini j 0 wa's liberated and finally'an endo-~,
ni 2
thermic effoot'at 1000C caused by dehydration. This thermographic result
proves that NaHCO 'H 0 is not identical with compounds of equal gross
4 2
formula, as.e.g. NaHCO H 0 or Na C 0 R 0 02H 9. NaHCO a 0 crystalliiiq
3 2 2 2 2 6' 2 2 2 4* 2
in anisotropio needles. There are 4 figures and 6 tables.
ASSOGIATIONt' Institut obahchey i neorgani:cheakoy ihimii im. N. S1. Kurna-
kova Akademii nauk,SSSR, Laboratoriya perekianykh soyedineuiy
(Institute of General and Inorganic Chemiatry imeni X. S. :
Kurnakov of the Academy of Sciences-USSR,Laboratory of Per-
oxide Compounds)
SUBMITTEDs may 24t 1962,
C
a
rd 3/3
PIRSOVAj V. A., kand. mod. nauk
Campovition of the carebrospinal fluid during treatment for
tuberculous meningitis without the subarachnoid administratiDn
of medicinal substances. Probl. tub. no.3:31;-AA 162,
-(MIRi 15114)
1. Is detskor kliniki (say, - zaaluzbenrO7 dayatell nauki prif.
M. P. Pokhitonova) Instituta, tuborkulaza ANN SSSR (dir. - chlen-
korrespondent AMN SSSR prof. N. A. Sbmelev)
KMNGES-TUBEFCULOSIS)
WROSPINAL FLUID)
0
ACCESSION NR: AT4028334 S10000/63/000/00DIO119/0127,
AUTHOR: Firsova, T. P.; Molodkina, A. N.; Morozova, T. G.; Aksenova, 1. V.
T17LE: Investigation ofthe reaction process of carbon dioxide with alkali solutions
of hydrogen peroxide and the synthesis of peroxocarbonates
SOURCE: Soveshchaniye po khimft perekisny0kh soyedinenLy. Second, Moscour 1961.
Khimiya perekisny*kh soyedineniy (dhemistry of peroxide compounds); Doklad,y*
soveshchaniy. Moscow, Izd-vo AN SSSR, 1963, 119-127
TOPIC TAGS: carbon dioxide, hydrogen peroxide, perearbonate synthesis, sodi=
.superoxide, potassium superoxide, water vapor, alkali
ABSTRACT: The purpose of this paper is to explain the principle possibility and
conditions of forming perearbonates with the action of carbon dioxide on aqueous
alkali solutions of hydrogen peroxide and to confirm the conclusions of previous
research relative to the character of the reaction of sodium peroxide and potassium-!
peroxide with witer vapor and carbon dioxide. A mixture of aqueous hydro2cide solu_.~
tio4s (sodium or potassium) and,hydrogen peroxide was treated by carbon d1oxide.
Thellprecipitates. obtained were subjected to full quantitative analysis In the
general alkali content.' The results of the.work are presented in tables and
Card 1/2
ACCESSION NR:
thermQgrams. The authors confirm the conclusions of the previous research. A new
method of obtaining true percarbohates of alkali metals which are contained in the
carbonization of aqueous alkali a7blutions of hydrogen peroxide is developed. The
advantages of the proposed method in comparison with known laboratory methods of
producing percarbonates, is contiined in the fact that it does not require a complex
apparhtus, or u1se of organic solvents as well as preliminary stages for cbtaining
:peroxide as initial substances. Orig. art. has: 4 figui'es,.4 tables anei 8 formulas.
'iASSIOCIAT'ION: Xnstitut'obahchey-i neorganicheskoy khimii im. N.S. Xurnakma AN SSSR'
(Institute of General and Inorganic Chemistry AN SSSR)
SUBMITTED: 13Dec63. DATE ACQ:. 06Apr64 ~ENCL:` .00
SUB,CODE: CH NO REP SOV: 005 OTEMR: _001
Card 2/2
ACCESSION NR: AT4028335 S/0000/63/000/004)/0128/0139.
AUTHOR: Mel'nikov, A. Kh.; Firs6va, T. P.; Molodkina, A. N.; Horozova, T.
Aksenova, I. V.
TITLE: Investigation of the reaction of sodium superoxide and potassium superoxide
withuater vapor and carbon dioxide and the synthesis of perearbonates
SOURCE: Soveshchaniye -po khimii perekisny*kh soyedineniy. Second, Moscow, 196lo
10iimiya perekiany*kh soyedineniy (chemistry of peroxide compounds); Doklady*
soveshchanly. Moscow, Izd-vo AN SSSR,'1963, 128-139
TdPIC TAGS: sodium peroxide, potassium peroxide, water vapor,carbou dioxide,
percarbonate, percarbonate synthesis, oxygen, water, sodium superoxidej potassium
superoxide
ABSTRACT: The 'authors investigate the reaction of sodium superoxide and potassium
sup~roxide with water vapor and carbon dioxide at alowered temperature and.study
thei;properties of-the solid phase of the peroxide type formed in the process of this
reaction. The work is divided into twovegments: 1) the investigation of reaction;
process kinetics of sodium and potassium superoxides with water vapor and, carbon
dioxide in the presence of water vapor and 2)-the d~nthdsis and study of properties.
Card 1/2
'ACCESSION NR: .,AT4028335
of 'the peroxide type of solid phases formed in the low temperature reaction of sod-T
ium and potassium superoxides with*carbon dioxide and water vapor. Diagram of the;
illystrations are shown; graphs showing the kinetic curves of oxygen seperation,
.water vapor and carbon dioxide absorption are presented. Tables presenting th
comiosition of potassium and sodium percarbonates are given. The study of the re-,
,action kinetics'shows two directions of the process depenaent on the temperature. Ij.
Within a temperature region of from +100 to -100C, sodium and potassium superoxides~
react with water vapor'knd carbon dioxide, accompanied by a discharge of ouperoxide
oxygen only and,the foimation of sodium and potassium percarbonates. The inter-
mediate phases of the reaction process of sodium and potassium superoxide with water
~vapoe. and carbon; dioxide at low temperatures are synthesized. Some of the properties
previ6usly unpublished (thermo-atability, specific weighta, hydrolysis, etc.) are,
studied.: Orig. art. has: 4 tables, 9 figures, and 9 formulas.
ASSOCIATION: Instituit obshchey L"neorganicheskoy khimU im. NS KurnakoviL AN SSSR,
(Institute of Ceneral and Inorganic Chemistry,'-AN SM)
SUBMITTEW 13Dec63
DATE ACQ: 06Apr64, ENCL: 00
r
OMMRs 019':.'-';~
SUB CODE: CH No REP SOVt .017
Card 2/2
9 078
3/008/CO3/002/020
--bi17 186.
ti D
AUTHORSi Mellnikoi~_'
TITLE: 'iixpor. wit
Reaotion.-o hydrd#efi-'~,1p*rox1dw h hydroxiAes of
line'
alkali.and alk'a" -44r h,z neta~o"
PERIODICAL: Zhurna. A6organiohil'o-k6*y-..'kh'iioii~" 3, 1961 i -560
562,
.
'
i
: '
d'::.A
su gg F 1
TEXT, Chemisorption va
4f i6 i6nt. awAbod of ovo4poing
si
ep e
peroxide co ,
mpounds 6 from scilid
-
,
hydroxides
and hydiro'en
other method
id
9 ar
has the following advanidgei pier-oxitfe -Y&'Po,r on
solid hydroxides and th.4 the, vi~ter' Efet free -in
the reaction create. oofiditio'nsi, 0i .ch,`:~~ij*v4fit.,ihe b'ydrol$sid of~ the
tind -heiio6-1,.- e 6omplei ds6tr'uotton. The.
dissolved peroxide bomio"Oii th
reactions were-studied in, Vacuo. 46dd the~'4enciion
vessel continuously A)WvateT at the
same time j and to contiol t~il.ftebeuxq in Th":10 kor, ib.
dec.isiV6 in ma in t a in ing'' thq"~ hydi0g~i,'j ii6iide'!,oojioenfi~i ion' acting on the
A doth,'.Yeact oh with-nea"I &'
'-hydroxide surface. am y quAniitatilvop tr no-
formation of H 0 to Ll 0'.' Mai, 0""..:~ko ~.Oko A0,okpia*04'.. si~qil.
2 2' in 2- 2 2
Card 1/2
ipet'
Reaction of'hydrogdr oxide'
the reaction occurred. 'only oft~ ',the sur ace--oi.ihe','gr-anulit4d'hyart)xideg it
may be possible to increase the" metal ".pard" xi'de yields --bydnlarZih8-th.e
reaction surface. Therd aire.,f-jigure'-afid tibi-
ASSOCIATION: Institut obeh e- rgan. bh6sk6y-k
~,~neo Ift,
Akademii A t"k-.; ny
nal ~S"~k'-L~bbra or yk...perekiid Ah,.-:-soyo zon
(Institute of Uneral-'and' lnorgini~.'dfiqmietry ilmeni
N. 3..Kurnako~ of,:ih-e~Academy,'-of, Aoi6nc 68. USSR Wwratory
ro'
of Pe xide. d
gard 2/2
FIRSOVA, T.P.; MODODKINA, A.N.; MROZOVAp T.G.; AKSENOVA, I.V.
Synthesis of potassium peroxydicarbonates. Zhur. neorg.
khim. 9 no.5.tlO66-1071 Yq 164. (MIRA 1.7-.9)
1. Laboratoriya perekisnykh soyedinbniy Instituta obshchey i
neorganicheskoy khimii imeni N.S. KUrnakova AN SSSR.
L IWT
W/3WT(*)./ZWPM' -SMS/TiKeY -,P/DD
R' -'45025511 UR/0062/65/000/CI09/1678/1679:
ACCESSION N
541.11+655.39
:o AUTHOR: Firsova, T. P., Molodkina, A., N.; Morozova, T. G.; Aksenova, :1. V.
t:-F TITLE: The melting temperature of potassium superoxide
SOURCE: AN SSSR. Izvestiya. Seriya khimicheskaye, no. 9, 1965, 1678-1679
e air regeneration, life support
TOPIC TAGS: potassium superoxidil
.ABSTRACT: Potassium superoxide (KO.) is of~considerable importance as an agent,
for regeneratina aiO' In this work, samples containing 89-99% KOZ and potassium
peroxide, carbonate, hydroxide and small amounts of water were subjected to dif fer-
ential. thermal analysis. It was found that at atmospheric pressure the-melting
points of various samples r to 530C. At pressure3 of 1-2 mm the
anged from 490
melting points-dropped to 350-415C., In the-course of the experiments.it wa
observed that molten potassium superoxide reacts vi rously with the glass walls
go
the container to form-potassium silicate. This reaction is accompanied by,
o
f
...... evolution of nascent oxygen. Orig. art. has: 3 figures,
]ASSOCIATION: -Institut obshchey i wDrganicheskoy khimii im N. S kurt2akova
_y, Academy.of Sciences SSSR)
nauk SSSR (Institute of General and Inorganic Chemistr
I-Card 1/1
-Ad~kR' Ap6ol4414 SOURCE CODE:-bN/-60--62IT6-6iOO6TOO4-/675f/6755-
AUTIHOR: Firsova, T. P.; Molodkina., A. N.; Morozova, T. G.; Stasevich,--/--
N, N,
ORO: Institute of General and Inorganic Chemistry im. N. S. Kurn;-:Ikov
Academy of Sciences SSSR (Institut obshchey i neorganicheskoy khimii
Akademii nauk SSSR)
TITLE: Preparation and properties of sodium peroxide dihydrate
SOURCE: AN SSSR. Izvectiya. Seriya khimicheskaya, no. 4. 1966, 757-759
TOPIC TAGS: sodium compound, peroxide, heat resistance, thermogram,
dehydration
ABSTRACT: The dihydrate of sodium peroxide was obtained by vacuum
dessicating the octahydrate at &over P20q. A thermogram for the
dihydrate was drawn; its density was deteftined to be 1 "98ito.09 gm/cm3.
Attempts to dehydrate to the monohydrate were not successful Dehydrati
at 00 did not reduce the water of crystallization content. it 200 the
water was removed slowly but hydroxide was formed simultaneously, Orig.
art. has: 1 figure and 3 tableu.
SUB CODE: 07/ suBm DATzs 16sep65/ oRiG Rw: oo7/ PTH REP: 007
Card UDC: 541.549ib46.3~J661.49
GOMBOVICH, Semen Rafailovich, insh.; PINK@ Iazarl Tegudovich, insh.;:
BUZMICH# GoA,, kand. tekhn.'nauk, retsenzent- YIRSOVA
lnzh., red@; HATVBMffA. U.N., tekhn. red.
[3quipment for manufacturing slag concrete blockil Oborudovw3le
Me, proizvodstva ehlakobetonAfth himnei* Noskra, Goo. nauchjw-
tekhn. izd-vo mashinostroit. lit-rY,,1957. 3.43 P. (MIRA UV7)
(Concrete blocks)
BAL~OD, R.R.; BOKOLYAR. S.M.; ANDROSOV, A.A., kand.tekhn. neuk. retsenzent,;
Y~SOTA, T.Y., inzh., red.; SHIBNOTA. G.V., tathn. red.; UVAROVA,
A.F.-, -rwkhav--jmd.
[Mechante of an asphalt concrete plantl Mekhantk asfalltobstonnogo
zavoda. Moskva, Goa. nauchno-tekha. izd-vo mashinostroit. lit-ry,
1958. 96 p. (MIRA 11:12)
(Concrete plants--Equipment and supplies)
FIRSOVA, V.A.
Differential diagnosis of tuberculous and serous meningitis.
Pediatriia no.1:82-83 JA-F 154. (MLRA 7:3)
1. Iz detskoy klAniki (saveduyuBhehiy - professor M.P.Pokhitonova)
Institute. tuberkaleza Akademii meditsinskikh nauk SSSR (direlftor
Z.A.Lebedeva). (Tuberculosis) (Keningitia)
FIRSOVA, V.A., mladshiy nauchnyy sotrudnik
""WKQMJ~~
Jkporienoe in treating experimental meningeal tuberculosis In rabbits
(with ou- ry in'Frenohl. Probletubs 34 no*5:42-51 S-0 '56,
(MIRA 10:11)
1. Is detakoy kliniki (sav. - prof. M.P.Pokhitonova) i patomo:rfolo-
gicheskoy laboratorii (sav. - prof. V.I.Puzik) Instituta tuberkulaza
AMN SSSR (dir.*ZOA.Isbedsva)
(TUBIRGUWBIS, HENINGRAL, exper.
4ff. of isoniazid, PAS & streptomycin)
(ISOJIZAZID, off.
on exper. meningeal tuberc., comparison with PAS &
streptomycin, in rabbits)
(PAR&-AKINOBALICYLIG ACID, off.
on expere-emningeal tubero., comparison with isoniazid
& otreptonWein, in rabbits)
(STRMOKYCIM, off .
on.exper. meni eal tuberc., comparison with isoniazid &
PAS, in rabbitle
VASILIVICH. N.4- FIRSOVA, Y.A.1 LIBE VA, L.Y.
Xffectiveness of isonicotinic acid hydra ids therapy In tuberculous
meningitis; experimental and clinical dat: [with summary in Yronch].
Frobl.tub. 35 no.2:19-27 157. (KIRA 10:6)
1. Iz Instituta,tuborkalosa (dir. Z.A.Iebadeve) Aimdemii meditsin-
skikh nauk SSSR.
(ISONUZID,'ther. use
tuberc, soningeol, with PAS & atreptomycin (Rua))
(STE M OKTC1N. ther. use
tubere. meningeal with Isoniasid & PAS (Rum))
(PARA-AXIAALICYLIC ALD.-there use
tuberc.. meningeal. with tooniazid & streptomycin (]Run))
I.- /A-,- "I 'I V -
-i 4 1 -
----F- Tjl-Q 'ullr f, /--4 q-// I -- -- - - -- --- ---- -- ---- --- ---- ---- --
VABILEVICH, N. 0., Cdecea sad] ; ULUIFIHOV. V.F. ; F~~T TABEW 71. L. V.
Treatment of tube.rculous meningitis [with sumary in Preach), Problo
tub. 35 n0-7:78-86 157. (MIRA 11:2)
ther.)
(TUMCUMSISO. KIIIINGIAL,
FIRSOVAt V.A., Cmid sci--(dizo) .,~.-'bcrcul-~)Ilo
tir, in rabbits n:id ito troat-l-ont 1,-;ith iiit,-,vn~Al :,,dvird., t-r-Alon 6f phtbi.-
v-~nidt," Los, 195e-- 14 PP Ocad Lcd Sci TIS-04), 200, conic.:; (IM,"it rzf!
- 1 I-l"1126)
- s 3 -
T-_ T,
KTANKOVSKAYA, R.N..- FIRSOVA, V.G.
IrTeversible-reciprocal system of sodium and potassium carbonates
and bromides. lzv.5skt.fiz.-khim.anal. 22:216-224 133. (MMA 7:3)
1. Kafedra khimii Taroslavskogo gosudarstvennogo pedagogichaskogo
instituts, im. X.D.Ushinakogo.
(Carbonates) (Bromides) (Systems (Chemistry))
FIR5'TO'IJI Vladimir Grigorlyevich; SHIROKOVAII G.M..9 red.
-,~- - - I~w
[Use of radioisotopes in construction] Primenenle radio-
aktivnykh izotopov v stroitel'stve. Moskva$ Strotizdat2
1964- 159 P. (MIRA 17.9)
-.- ~. ~ , -:sl---2~-'-, h7~'".V
c 1~ - : -- . , - -
.i. . - .'-. ,
f i~ r_7
USSR/Chemical Technology - Chemical Products and-Their Application- Food Industry,
1-28
Abst Journal: Ref erat Zhur - Khimiya., No 19., 1956,, 63722
Author: Karnitskaya., N. V.., Firsava, V. I. Makashev, A. P.,, Aldaklmova., A. Ya.
Institution: None
Title: Action of Carbon Dioocice on Botulism Microbe in Fish Processed by Hot
Smoking
Original
Periodical; Vopr. pitaniyu., 1956, No 2., 49-5o
Abstract: Study of the effects of storage of fish, that has been hot-smoked,, in
an atmosphere of C02 (70-90%) on toxin formation by B. botulinus" the
spores of which are found in the intestines of some fish under natural
conditions. It was found that hot-smoked fish of small and medium size
is preserved in C02 In good condition (according to organoleptic char-
acteristi.zs) fnr 15 days as compared with 2-3 days of the controls.
Storage of fish in an atmosphere of C02 neither inbibits nor stimulates
&umination of spores wid. toxin production of B. botulinus.
Card 1/1
FIRSOVAt V. r":
Firiovn, V. P.: "The comparative characteristics of poizzolic soils
under -the argillaceous; cover of tho central portion of tho
Russian plain." LeninCrad State Order of Lenin U :L-..icni
A. A. ZManov. Leninu ad, 1956. (Dissertation for the
Degree of Candidate in Biological Science)
SOs Knizhnava letopint., No 27, 1956. Moscow. Pages 9/,-109; 111.
ZAVALISHII, A.A. [deceased]; FIRSOVA, V.P.
Studying the genesis of Podzole on clayey surfaces in the Central
part of the East European Plain. Sbor. rab. TSentr. muz. pochv.
no.3:7-95 160. (MM 13t9)
(Zast Nuropeankain-Podxol)
(Soil forlhation)
PIES OVA V R -
Some characteristics of
soils formed from loaxV
16o.
(vologda Province--Podzol)
agricultural transformation of Podzolic
parent material. Vast. LGU 15 n0-3;67-78
(MIRA 13:1)
-?IRSOVAI V.P.
:,,.'Playey surfaces Cf the Northeast and the central part of the East
lh=opean Plain an coll-forming rocks. Pochvovedenle no.IIS32-40 N
16o, (MIRA 13:11)
1. Institut b1ologii Urallskogo, filiala. Akademij nauk SSSR.
(Russia, Northern-Soil formation)
Mat luropean'PlAin-Soil formation)
FIRSOVA, V.P.
Xffect of forest fires on soil, Trudy Inst. biol. UYAN SSSR
no.i6:4i-51 16o, (MIRA 13:10)
(Porest fires) (7brest soils).
FIR~-',)VA, V..".
Dynamics of waf,3r soluble subsranc-,As in f ores t '-.:rr-Pcdz-,1 i -- 3r 1 Is of
the pine forests in the Pyshma Valloy. P0Ghvt-,v(-:dtInk no,q,-59~-Of) 'j, 164,
lo Institut biolog,Li Ural'skego filiala AN SvSR* (MIRA 1,7212)
FIRSOVA, V.P.
Effect of forest cutting and cleaning cutovers by burning
on the content and dynamics of water-soluble substances
in turf-Podzolic soils of the trans-Ural region. Pochvove-
denie no.6:32-40 Je 165. (MIRA 18:1,J)
1, Urallskiy filial Instituta biologii AN SSSR. Submitted
MELY 4.- 1964.
M-A
6*~fl K
-ej, itialt ~ XR~~R 'k. 10
ZUBAREVA, R,S.; FIRSOVA~ V.P.
Ecology Opines in the dark-green forests of southeim taiga In
the Central Ural Mountaine. Trudy Inst. biol. UFAN SM no- 43t
203-207 165. (MIRA 1911)
1. Thatitut biologii Urallskogo filiala AN SSSR.
- -~~'-~J -,-
PTLKOV, POT. PIRSOVA, Te.A..,-redaktor; YOKINA. A.P.. takhnichookly re- 1..
d ~ _T
[How to build'your own motor boatj Kak samomu postroit' motornuiu
lodku. Moskva, Izd-vo Glavemorputi, 1951. 53 poiLMIdrofilml
(ULU 10:6)
(Motorboats)
V Ai Ye 4
PHASE I BOOK EXPLOITATION 332
Isayev, S. I.
Polyarnyye siyantya (Polar lights) Moscow, Izd-vo, Glavse"Wrputi, 1952.
60 p. 50,000 copies printed.
Ed. (title page): Khvostikov, I.A.0. Prof.; Ed. (inside book):
Firsova, Ye. A.; Tech. Ed.: Moskvicheva, N. I.
PURPOSE: The book is designed to give a popular introduction to the
study of the phenomenon of aurorae.
COVERAGE: The author discusses the following-problems: a) the origin of
polar lights and the nature of this phenomenon; b) how the
study of polar lights can help us know~more about the upper
atmosphere of the earth. There are 6 references, all Soviet.
Card 1/3
polar lights (Cont.)
TABLE OF CONTENTS
Introduction
TheiDevelopment of Opinion Regarding Polar Lights,
Shapes of the Aurorae'and Their Classification
Aurorae shapes of'vion-radiant structure
Aurorae shapes of radiant structure
Geographical Distribution
Determining Altitude
Low altitude auroras
High altitude aurorae
Polar Lights and Magnetic Storms
The Connection Between Polar Lights and Solar Activity
Accounting for the Spectra
Card 2/3
332
Page
3
5
8
9
10
11
15
16
17
18
25
28
P,olar lights (Cont.)
332
The CompositioiL and Temperature of the Upper Atmosphere For a
Given Polar Light
Theory of Polar Lights
The the.ory of auroral excitation by solar ultraviolet rays
.Corpuscular theory
Polar Lights and the Propagation of Radio Waves
Conclusion
Bibliography
AVAILABLE:
Card 3/3
Library of Congress
is/jzr
May 2721958
35
40
41
42
53
60
62
L-z A, 61 -"L-- L ji PtFUft.AI j. t-_JLY-,L- 1A 20 (CW
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so A,
L
k4ods of invewp the absorptive .;war it "us
(in 11- with the decialm the InterutionAl Congregs of
21
SoU Sciesce In Oxford. im). 1. S. Antipav-Karaw,
and H. S. Firsova. Pek"01Y (V- S. S. R-) 1042, No.
:1 IN) - --A irputi ots the tmw.A wi.
."Lvd. efictlangv .vpsKily. and unwu. of 7, unj suilpfc-p
-16tribicted ljy the ilociety to a slo. of falls. The author,
dad. the exchallp cawlty of the W16 by clectrodialysing
and then treating them with a taht. of CaCh + Ca(OH)s -
Thequ*otity
of Ca &dumbed was detd. potentionietrically. S.
< A ------
.40l ell Ail
t c $I jilo"l,
-7-1- .3 s V
UIL AV 00 M(9 ft ado(;[ Ktttt 1909 KLD n A : XA
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4,6090000 00000 000000100*00000000000*9066
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190
too
FIRSOVA, 7.s.
95110 FIRSOVA, -F,.S.' Vliyaniye Erodirovannosti pochv Ha Ra
Vinogradnikov. Trudy Yubil - zvitiye I Urozhaynoste
.Rozhdeni,7a Dokuc eynOy Sessii, Posvyasc!hch. Stolatiyu So Dnya
hayeva.,m. L.,1949, S. 468-75.
SO: Letopis" No. 33, 1949
F. I
FIRSOTAP TO.S.
.
IfInImm vat
" "J301tv of 001's [With summarY' In Xt9lishl. Pochro-
11odenle no.2:72-76 P 158. (Km. 1113)
1. Pochvenny7 institut I,., T(*Vw D3kucha'.veva AN SSSR.
Soil moisture)
FIRSOVA, Ye. 'S.
Effect of soil forming rocks on the process of water erosiou on
the right banks of the Oka River [with summary in Saglish].
Pochvovedenie no. 9:134-141 158. (MIRA 11:10)
1. Pochvennyy institut imeni V.V.Dokuchayeva AN SSSR.
(Oka Valley--Erosion)
MUM
VASILITSOV, V.D.; VOLCHENKO, M.Ya.; GERTSOVICH, G.B., kand.ekon, nauk;
ZWKOVj Ye.1.1 KOHOVAWVq Ye.A., kand. ekon. nauk; MIAMM, SKAYA,
E.D.j OLEYNIK, I.P.p kand. ekon. nauk,- RAYEVSKAYA,
SKVORTSOVA, A.I.; SOKOLOVA, N.V.; SOTNIKOVAx I.A.; TANDIT, V.S.;
THIGUBMIKO, M.Ye.; M YA4 Y V.; SUBMINA, V.I.; MID, M.N.;
STOROZHE;Vq V.I., kand. istor. nauk., red.; IZPNIKOVA, Ye.j red.;
a"apilovp Gop tekbno red,
(Economy of the peo ple's democrdeies in figures for 1960) Ekono-
mika stran sotsialisticheakogo lageria v tsifraldi 1960 g. Pod
red. G.B.Gortsovicha, I.P.Oloinika,, M.Storozheva. Moslvva, fzd-
vo sotsiallno-okon. lit-ry, 1961. 238 p. ~TURA -15:10
(comma'nist countries,-Economic conditions)
VASILITSOV, V.D.; VOLODARSKIY, L.M.; VOLCHENK01 M.Ya.; GAISTSKAYA,
R.A.; IROV, N.I.; KARINYA, L.F.; K0110VALOV., Ye.A.;
KA=EVSKAYA, E.D.; PETRESKU, NJ.; RUDAKOVI Ye.V.;
SAYFULINAf L.M.; SHVORTSOVAj A.M.; SOKOLOVA, N.Y.; SOTIJIXOVA,
I.A.; STOLPOV, N.D.; SURKO ., Yu.V.; TEN, V.A.; TRIGULENKO,
M.Ye.; ZjBSQYA,_Xu.V.; SHABUNINA, V.I.; YUMIN, M.N.;
HYABUSHKIN, T.V., d-oktor,ekon. nauk, otv. red.; ALAMPIYEV,
P.M., rdd.; PAK,-G.V., red.; GEWIVOVA, D., tekhn.red.
[Ecozvmy of socia34st countries, 1960-1962) Ekonomika stran
sotsializma) 1960-1962gg. Hobkvap,lzd-vo "Ekonomika#" 1964.
261 p. (KRA 16:12)
1. Akademiya nauk SSSR. Institut ekonomiki mirovoy sotsia-li-
sticheskoy pistemy.
(Communist countries--Economic conditions)
AP5016834
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