SCIENTIFIC ABSTRACT FILIPPOV, YU.F. - FILIPPOV, YU.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000413120012-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 13, 2000
• Sequence Number: 12
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

28440
S/185/61/006/00:2/014/020
Absorption of waves of finite D21U/D304
(Solut on periodical in space). In the first approximation (c ase
a) kx
fix wS Wt (12)
V
O

case b) REX os
V, V.Oe- C kX Wt (I q !i

V
)

13)
O
2 2 2

"'0
'VOUS U;

where OUI
q U3 (U02 +

"
W2 dp
0
+

14)
U3-(,-!O! 2

NO
+
U.)

us
- U02 +
l (

u,,2) - N70u,20
(u02 -Fuf Po u
c,

,
+ - . 2
UO C3 + UU

-
+
l) ;f
o

Card 316
7 t
n
3
0 U
P.
P

28440
S/1-85/61/006/QO2/014/020
Absorption of waves of finite ... D210/D304
(1&0 + it.), + It., VjU~~ UJI + U.2
(16)
'u. is the v'elocity of sound, ua Hox/ ua. Hoy/
..Different points of the wave front move with. different
velocities which leads to rupture. Formulae for the mcmeni of rup-
ture in h perfectly conducting medium are deduced. Expressions for
the density, the intensity of the magnetic field and temperature
are obtained. An expression for t e wave absorDtion coeffi-cient
is deduced (with accuracy up to "M: where
112
+ q3 .1.
2
C_ U
Co (24)
A, flu'.
-16 + 2 A,
Al-L LUO)
U2
Card 4/6.

28440
S/18 61/006/002/014/020
Absorption of waves of finite ... D210YD304
. ...............
U2. TN)-2( ~,
I - NO, + Ul
2A,!- I +
u2 UZ
2u.2 u.2
V
2 2 + PO LU2 I
S.[ US qu. 2+ U2 u 0 UO
U2 r I+
A2. 8 its u.2 2v, u2 21&2 Lip jj2
0
2. 3
u2 2 u U.
0
!L U U 1+ P. U5
2U.' u2 VO
2y! dd
7-- qt& &2 UIVO, 2 2 2 dUO2 3
Aa~ 0 1 50 + 110V0 I+ PO
3~L
Nr W) + 2 09 +
U91 r" a3 W) TO "a NO
T-1
OP 0,)[!U-(I-g, +
+ 4po UO VO
1&2 2V. its)
T.,
U20 2 u 2
PPIO, 0OP +
u +
Li
Card 5/6

S/18~5A610/006/002/014/020
Absorption of waves ot' finite D210 D304
being the absorption coefficient for waves of infinitely small
ag-olitude
U2
c3wk I-
80 2.
po _0
+ L
U,+ + ~U-U_,
It is stated that the contribution of non-linear effects to 6
cannot be neglected. Z.A. Golldberg is mentioned for his contribu-
tions in this field.'Some of his results are said to be erroneous.
The author expresses his thanks to Professor V.L, Herman for pro-
posing the subject of the paper. There are 5 Soviet-bloc referen-
C e 8
ASSOCIATION: Instytut radiofizyky ta elektroniky AN URSR, m,.
Kharkiv (Institute of Radio Physics and Electronics,
AS UkrSSR9 Khar1kov)
SUBMITTED: May 28g 1960
Card 6/6
A

s/Ai/6i/oo4/005/011/02l
E,025/E135
AUTHORs
TITLE: Magneto-sound oscillations in eesonators.
PERIODICALt Izvestiya 'rys shikh uchobnykh zavedeniy,
Radiofizika, v.4, no.5, ig6i, 924-935
TEXT: The disperisive equations for the self-oscillation of
cylindrical resonators:of arbitrary cross-section filled with a
conducting midium in an external magnetic field are stated in
general form. In the calculations the equations are linearized
and the magnetic field.assumed to be directed along the axis of
the resonator and the dispersion of the medium assumed to be
negligible. The equations of motion-and the equations for the
harmonic oacillations:are derived. Solutions are found for the
harmonic oscillations and for the velocity and intensity of the
magnetic field involving constants obtained from the boundary
conditions at the ends 'of the resonator. The dispersion equation
is derived and the particular cases of zero magnetic field and
negligible thermal effects are treated. The case when the
amplitude of one component of the oscillation is much greater
Card 1/2

s/14i/61/004/00f)/011/021
Magneto-sound oscillations in ... E025/El35
than the other is discussed for high frequencies with both high
and low magnetic fields: new modes of-oscillation ariae in the
latter case. The particular cases of a rectangular retionator and
of toroidal resonators of both rectangular and circular sections
are treated. In calculating the effects of dispersion,, account
is taken of absorption in the medium, in the boundary layer and
that due to ohmic losses on che end walls. Acknowledgments are
expressed to V.L. German for proposing the subject. In a post-
script, written during proof-reading, the author mentions that a
similar investigation was published by R. Gajewski and Mawardi
(,Phys. Fluids, V-3, 820 (ig6o)). There are 3 referencest
1 Soviet-bloc, I Russian translation from non-Soviet PiLblication
and 1 non-Soviet. The English language reference readst
Ref.l: R. Gajewski, Fhys.Fluids, v.20 633 (1959).
ASSOCIATION: Institut radinfiziki i elektroniki-AN USSR
(Institute of Radiophysics and Electronics, AS Ukr.
Card 2/2 SSR)
SUBMITTED: Sept .ember 20, 1960

S/141/61/004/005/012/021
E025/E135
AUTHORz Filippov Yu.F.
TITLE& on the absorption of magneto-sound waves in wave.guides
PERIODICAL: Izvestlya v-ysshikh uchebnykh zavedeniy,
Radiofizika-9 v.41 no.5,~19611 936-941
TEM The absorption coefficient of the waves on propagation
in a viscous conducting medium is -defined and an expression
derived for the mean energy of the waves in the waveguide in terms
of the constants of the medium, the velocity of motion and the
magnetic field. Assuming the dissipative effects to be small the
solution of the equations of magnetic hydrodynamics for an ideal
medium is taken as a first approximation. A rectangular waveguide
with ideally conducting walls is considered and an exprossion given
[Abstractor,s note3 The derivation is omitted.3 for the
absorption coefficient of the mn-harmonic. A number of particular
cases are given separately for both high and low frequencies.
The absorption coefficient in the boundary layer is defined and
an expression for a rectangular waveguide based on a method due to
Ldndau and Lifshits given for it. Simplified forms given for a
Card 1/2

On the absorption of magneto-sound.. S/141/61./004/005/012/021
Z025/E135
number of particular cases show that the losses in the boundary
layer ere not negligible. Accountis taken of the finite
conductivity of the walls by the use of the approximate condition
of Leontovich leading to additional damping of the waves. The
absorption due to finite conductivity is determined for the same
particular cases, as its that due to the medium and to the boundary
layer. To determine the total, absorption for any harmonic these
three coefficients are additive.
There are 4 referenceal 3 Soviet-bloc and I non-Soviet-blo4.~.
The English language reference reads as follows:
Ref.ls R. Gajewski, Phys.Fluids, v..2, 633 (1959)
ASSOCIATION& Institut iradiofiziki I elektro.niki AN USSR.
(Inst.itutfe'of Radiophysics and Electronics, AS UkrSSR)
SUBMITTEDi September*20, 1960
Card 2/2

FILIPPOV, YU*F4
Interaction of'magnetoacoustle waves. Izv. vys. ucheb. zave;
radiofiz. 6 no.5s932-940 163, (HIRA 16:12)
1. Institut radiofiziki i elektroniki AN UkrSM.

L 60159-65 MM-2/WTU)
Accmum m. Am3.4505 UW0141/65/0C6/O(12/02W0300
5 38 -224 5 .2Z
AUTHOR. Filijarov, Yu. ji~
TITLE to Cont
ritution to the th of.propagation oi' stat Ary wavea cif finite
ampUtude in ferrilt,
Zi 300
SOURCE: INM. iNadioti 19~4 8 rid k 1965t: M
TOPIC TAGS ferrite ii: va 4e 1- arrite. vave,propegation., 0epersiollp fer-
eta, INUU7
rite rionllLarlty- f
ABSTRACT: In view of the4acreasin .' In
&I ~tmat_lft the propagation of eleatrcmagnet-
wkvez of finite mplitude iii ferrite naterials, -the author points out, that the
I t
n
eg ec of diep-ersiort in,e94!11er inve stigat ions of aaah waves is unjustified,
I &I-nee the preaence of diepeitsion pl_nya *.e sume role :`m a. ferri-.e as di.isipation
'in gas d~ynezicc, and Limits the- diztorticn of the frout of the wave propegating inIl
the ferrite. BZf means of an_ analysis of Maxwell' a equations it is ghmi that the
frequency cof thit sUtionax-,f mave produced as a rerna-, of dispersioin depimds not
00-Y 0.11 the PT,01)ertied Or the itediM and the angle between the magn-stic field 19M
the direction of propagation of the wave, but also on the arnlitude of lbe wave.
"ition, the de componerct of the ferrl-te magnet-ft.-eition is chargt~d by lisper-o
In aed
I 0-on. The statlonoxy pulses, can propagate in the Verrite if a -lefillite ratio
1/2
d-
!tw
%~y
7

co'd 2
I PRO I

FlALIFPC-V,-Yu.Gqf inghonor.
%I'
-o'lexi ble P
Ilastic pipe usedAn foreign agriculture. G16.r.l mel.
9 no-7:58-60 J'l '57. WLqA 10.-8)
(Pipe. Plantic)

DERBENEVP S.I.,, kand. te,kbn. nauk; 141RONOV., K.M.; -LI-L-II!O-V
Yu.G., rod.
(Now developmentis in tba teobniques of mill retting of
flax and hemp in tho socialist countries of Europe] Nc-
voe v tekhnike zavodakoi mocbki Itna I konopli v sotsiall-
stiobaskAkh strmuAh Evropy. Moskvap 1963. 13 p.
(KERA 170)
1. Mosoowa WentrallmVy inatitut naucIm-takhnicheakoy
informataii legkcrl prorqohlennosti.

'AIN,
j4,
ACC WRt A Stu SOURCE CODE; UR/0126/65/020/005/0770/iii4l
MUM' Pavlov V A Fil:tvpov# Ye. I'; F izen, Ao
qyl?r
ORG:, Institute of Metal P isics.'AN SSSR (Institut fiziki metallov AN SSSR)
TITLB: Strengthening AV andV95 aluminum alloys by'thermomechanicaL treat
SOURCE: Fizika metallovi Metallovedenlye, v. 20, no. 5, 1965,170474
TOPIC TAGS: aluminum, aluminum alloy, M-11A~
mechanical A4oi- Au&4"u~r-f-) M4.J &24",k/p Au." ~4 A41, VIS' AU4"41.
ABSTRACT: AV and V95 aluminam-alloy bars.:12 mm in diameter were solution annealed,
water qvienched, and then subjected to low temperature thermomechanical treatment .
(LTTHT).- preheated to 100-300Ct-rolled-in-one p48-841th a reduction of 20%, and-
water..
quenched. LTTMT was followed by aging at 15nC (" alloy) or 120C (V95 alloy). LTTHT
with rolling at 150C signifieantly improved the strength characteristics of AV alloy
(see Fig. 1)...After LTTMT and aging for 6 hr at 150C the alloy had a tensile strength
of 41.3 kg/mm2, 4 yield stretigth of 34 kg/MM2, an R,, hardness of 70, a work-hardening
factor of 0.7, and an elongation of 15%, compared t; 32.5 kg/mm2, 26.0 kjj/zm2, 7'0, 0.41
and 22% for conventionally treated alloy. LTTMT also accelerated thc decomposition of
UQC. 669. 715:539743
Card 1/2

WA,
ntwt
cr k1k/
9v
Pig. Deformation temperature do-.
pendence of tensile, stirength (o,3). --
yield strength (a0.2),' olongation (6)0
and worL
~-har ening factor (q) of AV,
alloy oge4 at iSOC for 6 hr
the solid soiu't'i-o'n'.'-'Convbntii,)nAlly.,tieated alloy.,required 12 hr aginI% at 1,50C. while
thermomechanically treatedialloy-required only (V.,'hr. .Alloy V95 exhibited almila r be-
havior-*but was much less respimaive to-LTTM.T. After LTTMT and aging at 120C for 6 hr,
V95 had a tensile strength of :60.3 kg/MM29 a yield strength of.47.5 kl;/mm' , an .RB
hardness of 83 a work-hardenjAg factor,-of 1.0 and an elongat-' on of 7.8% compared to
2 'co entionally
57.6 kg/m , 42.2 kg/mm2, 82,'0.920 and 92 for av treated alloy. Orig
art. has: 7 figures and 2 tab-lea.
JDVJ.
SUB CODE: 11, 131 SUBM DATE-.' 29Jan65/ 001G. RM .003/ ATD PRESS: C//
Cord M
a- W,
a"t
A! ii vi ,

ACC NR, AP70-072~7~1 SO U R dc-60,1FL ~: R /0 li'67-Xfo-i~W-66 /00 Ti-/O-'�-O-
AUTHOR: Belousov, N.K,; Mheyeva, Yeaffe Pavlov, V.A. - Filippovt Yu"r.*,,
Frizen, S.A. .............
ORG: Institute of the Ph;fsice of Metals, AN SSSR (Institut fizLki
metallov AN SSSR)
TITLE: Effect of plastic deformation and aging on mechanical properties
of Al-Mg alloys
SOURCE: Fizika. metallov i metallovedeniye, v. 22, ~o. 6, 1966, 904-908
1-foA OA 010"~N'Qs'
W
TOPIC TA~~'Sl- Yidm&nYsm.magnesiumt*"' in, Y9 -4mmmechanical,4treatments,
aluminum a loy) mechanical prop erty, mimmm- *14-Ay corrosion resistance
AMgll alloy
ABSTRACT: A'siriei-of speciiiiins of AMgll-aluminum-magnesium aiioy (10..7.% magnesiim4
was solution annealed at 460C for 2 hr, water quenched and subjected to
.thermomechanical treatment, rolled with a reduction of 20Z in one pass or
,40% in two passes with reheating at 20, 100, 200# 300 or 400C, and then
)aged at 175-;-200C for 1-10 hr. The beat combination of mechanical
properties was shown by specimens rolled'with 40% reduction at 200C,
Card 1/2 UDC: 669.7153539-37

AM NRI AF7002741
,Aich Wid ~L 56-.2'or; 5 5 iiid'-ai
or 33.0'k8/mm2,and sit elongation of 10% in. the as-rolled or aged (1 hr at
200C) condition. Corre'sponding figures for the specimens rolled at 200C
and aged at the same temperature for 1 hr were 51.5 kglmm2, 31.0 kg/MM2
and 10%. As a rule,, aging loweted the yield strength without affecting
.the elongation. The increase in defon saon temperature slightly lowered,
the hardness. Aging at 100-200C at first lowers the hardness but sub
-sequently raises it, but not over the level attained by deformation. -I
stress-corrosion teots, specimens rolled at 200C with 20% reduction. as-
'rolled or aged at 200C.for 1, 5 or 10 hr, withbtood 90 day tests without
.cracking-but-showed-some signs 6f intergi~Anu3ar corrosion. Specimens
rolled with h reddctlon'of 40Z showed a susceptibility to - exfoliation.
SUB CODE: lj,, 131 ;SUBH DATEI
ATD PRESSt 5114
13Jun66/ ORIG HEY:
005/ OTH REFS 00

SOURFE 6 7Dt.-'_ OOD 009 1-2~fi02'.'
V( 7'
1AUMOR: Hikiforov; Yu. F. ~'Yu:,M.
I - . . -_JT~M I "F-' . .. . .
TITLE: Determination of dimensions of the range and bearing strobes in the case of
i
!~~49matic operation of a radar station with a digital computer
190URCE: Ref. zhe VodW transportp Abs. 9V166
!REF SOURCE: Sb. Vyehial. tekhn. na morsk. transp. M., Transport, 1966., 62-66
TOPIC TAGS: navigation radar, digital computer., gate signal
ABSTRACT: During automatic tracking of the target with the aid of circular-ocan radar,,
an increase in the strobe dimension leads to an increase in the probability of obtain-
ing the vessel and simultaneously to an increase in the probability of a false signal,
and also to a decrease of the resolution of the radar. To increase the probability of
correct observation of the target) the strobe should include both the last determined
point and the extrapolAted point. The dimensions of the strobe are determined by the
semi-axis of the overall error ellipse of the measurements, equal to the sum of the
measurement-error ellipses betweenthe point of the last observation and the extrapo-
lated point during one revolution of the antenna. After choosing the coordinate sys-
tem., -oiie-kei~oids;the measurement- error tensor (ellipse) in the form of a matrix.. :in
which"Wi-bi&-Bis of the last determined point still remain unlMown., and the semi-
axes of the error ellipses remain constant. We calculate the values of the major afid
minor semi-axes of -the error ellipsep characterizing the position and dirumsions of the(
Card 3/2 uDc: 621-396.969-3: 347-799
_1;N j4
M,

ACC NRs ARW35393
strobe relative to the last determination of the ship position. We then d#Aermine the
initial and final limita in bearing, the initial and final limits in rangej, the number
of added error ellipses., and the length oZ the radius vector in the directIlLon, of re-
lative motion*' 1 Illuatrations Bibliograpby., 2 titleso Ve Yakarov [Tranitlation of
-abstract]
M CCDZs 09, 17
rd 2/2
I -AmftAkIbw
J~
~. ~_Mm
141 YS
R

FILIPPOV, Yu*M,
wft--~ft
Vitamin C index and the
.poisoning. Veterinariia
early diagnosis of pesticide
42 no.9169-70 S t65,
(mi r(A 18 t n)

FILIPPOVS YU.M.
Iffsot of amall doses of DDT o2i the blosyntba&3A of ascarblo
aoid in rat organs* Vop. Idt. 23 no.1:70-73 Ja-F 164.
(MIRA 3.7t8)
oi
Of.1- 1. Kafedra g1jiyerq pitanlya (zav. - prof. F.Ye. Badagyan)
TSentrallnogo instituta us,overshenstvovaniy vraobey, Moskva.

SOKOLOV, Petr Vludimirovich; FILIPPOV Yulm inzh.,, retsenzent;
FERGOVSKIYp -P.B.p reds"'
(Denigning drying and heating machines for wood] Pro6ktiro-
vanie sushillrykh i nagrova*tellnykh ustanovok d1la drevesiny.
Moskvao Lesnaia promyshlennostly 1965. 330 p.
(MIRA ISO)

L 10358-66- Evr Am
ACC NRv AP5028190- SOURCE CODE:- UR/0346/6 5/000/009100614ri-07i
AUTHOR: FIlipR2v' Yu. M#
ORG- -none,
TITLEf Vitamin C as an early- diagnostl..c sign in poisoning by Pe ticides-
SOURCE: Veterinariya, no, 9, 1965, 69-70
TOPIC TAGS: ascorbic acid, pestlcide,~.:toxicology, organosphorus compound, orgi Iino-
chlorine compound
ABSTRACT: Sublethal dos *es of DDT mg/kg), chlorophos (150 mg/kg), and methyl.
nitrophos (25 mg/kg) markedly suppressi .id the biosynthesis of ascorbic acid In the
liver, spleen, brain.- kidneys, and othe-r organs of rats. Smaller doses, on the other
hand, intensified the- -production of ascorbic -acid,. apparently due to the defense re-
-action-of the-body (compencatory-4ncrei:ise in response to the toxic action of the pes-
ticides). Still smaller doses adminIsTervd over 30 days significan tly affe-c-t-ed - the
synthesis of ascorbic acid in. most of .1he organs. The vitamin C test is 'thus a high.
1y sensitive toxicological Indicator., .1he author'notes that the minimum doses,of the
pesticides te~iiia-c*ann'ot- be re garde,d,ai safe,judgivg from body weight changes fol-
lowing repeated internal adRdmistratiam'of =all doses of the ccnapounds. Rats which
UDC: .619 615.19 616-07
Cord 1/2
M., IT
i"~i9

- . -~~L~ ....
-117- 'i
I .. 1- .I
. - 5 -, - .117il , 'GRI, ~ -1 -'1- -, ~ -` " ~' II
Wl -_ -
1~ I'll NI'l

KOSTTUCIMIKO, A.D.; LISTVIN, K.S.-, FILIPPOV, Yu.N., red.; ROZHDAYKINA, V.K.,
tekhn.red.
[The use of fertilisere on leading collective farms of the
Kalinin Province] Primenenie udobrenii v peredovykh kolkhosakh
Xalini-nakol oblasti. [Kalinin] Kalininskoe knithnoe izd-vo,
1957, 41 (H IRA 11: 1)
PiKalinin Province-Fertilizers and man-area)
M

FILUPOV Yu N zaUo!uw.'sotanK1nJk
ftiene wmluation- of gamm, ray radiating sources on railroad
tracks. Artcm.-.. telem.. i eviazi 5 no.6:12-13 Ja 161. O.U.RA 34:9)
1. voevoyuznyy nauchno-issledovatellskiy institut zheleznodoro?j-
bnoy gigipnv.
.' (Railroads-Track)
Own-ma rays-Industrial applicationn)
(Railroads-Brakes)
A

FILIPPOVY YU.N.
Group method of wax patternwtking. Lit. proizv. no.805-36
Ag 163. (MMA 16s10)
T 7-1

FILIPPOV Yu.N.
~:~
Various stages of inhibition.of oxidative processes by tissue
lipids. Radiobiologiia 4 no.4:493-497 164.
(AURA 17:11)

1,111MAVLEV, A&I~L FILliTOV, Yu.N., 3 IMONOV, V.V.
Chotailimdnescence and antioxidativo properties of himaRn 11pide,
Trudy M01P. Otd. biol. 2105-&) 165.: (MIRA 18 16)
Q
'A ;3L

10
ZHUfUtVLEV, SIMION V, V-V-
Chemiluminescence and antiuxidizing properties Gf human lipido.
Blofizikla 9 no.6:671-677 164. (I.M., 18:7)
1. Listitut blofiziki Ministerstva zdravookhraneniya SSSR, Moskva.

j I.-;- -.
~'i -*,-, ~ . - ~ ;."", f~~ - -:
Fi~ Win&
,;~. -,, 1, f -,, m
, 2 i~i %. , .
-: ,, -. mi ~~ IE I P ,

VTATKIN, G.P.; OSTROUKHOV, M.Ya.; Prinimali uchastiye: KHOLZAKOV, V.I.;
j_NIKOLISKIY, M.A.;
KOPYRIN, I.A.; TARASHCHUK, ff.T.4_EjLjFEQZ,-juAP.
CHISTYAKOV, A.Ye..,- PDZNCV's L.I*
Investigating the process of "t furnace smelting for
the production of nickel vatte.. [Sbor. trud.] Nauch.-issl.inst.met.
no-4:71-81 161. (MIRA 15:3-1)
(Nickel--Metallurgy)
(Blast furnaces)

06'MOUKHOV, M.Ya.; TARA HCHUX., N,T,,; FILIPPOVj Yu,P.; KHOIZAKOV, V.I.
Blast furnace smelting of (midised nickel ores for the production
of matte,. TSvetemet, 34 noo9tS2-83 S 161. (KM 3-4:10)
(Nickol-YAtallurgy)

FILIPPOV, Yu. S.; TSARFIN, Ya. A,
Simple preparative chromatognphic apparatus. Zav. lab. 28
no,22:1507-1508. 162o (MIRA .16:1)
1e Vladinirokiy nauchno-ioslodontellakly institut ainteti-
oheikikh smol.

3(2)
AUTHOR
TITLE:
PERIODICAL:
ABSTRACT:
Card 1/2
Filippovt,Yu. S... SOV/6-59-9-13/1.9
Determination of Geographical Names and Collection of
Data for the Topographic Map
Geodeziya i kartografiya, 1959, Nr 9, PP 52-55 (USSR)
At the Yakutskoye aerogeodezichebkoye predpriyatiye (Yakutiya
Aerogeodetic Service), the geographical names in the topo-
graphi.c survey are determined on the basis of data obtained
from the natives. The natives are,either consulted, or they
are asked to identify the corresponding objects (on photoplans
or maps). The latter method is preferred. Practice has also
shown that always two natives have to be consulted, and riot
at the aame timei In the case of contradiction, a third rative
is called. On some photoplans, several objects bore.the name
"byllbapyn". It was found that this word means "I do not
understand''I in the Yakutian language. The author demands the
development of a specification for determining and transorib-
ingthe Yakuti.an geographical names. This is also necesue.ry
because at present - instead of the phonetic transcription -
the Yakutian letters are represented by Russian ones, and,
thus the names are unintelligible not only for the Russis.ne

NOW-
.De-ter.minaticir of Geographical Names anI Collection sov/6-59-9-13/19
of Data for the Topographic Map
,but also for the.Yakutians.- Some measuring methods of
determining the height of river banks, trees and shrubs are
pointed out, and the determination of river widths and depths
is described in brief. Some recommendations for surveying
blockhouses, roads, footpaths, and bridges are given. There
are 2 figures.
Card 2/2
7'i
~"~zqlxl R, -11-m I W-
-Ig

-FILIPFOV) YUOVO
The tuenty-fifth anniversary of the Scientific-Editorial Cartographical
Board. Izv.,AN SSSR. Ser. geog. no-5t155 S-0 163. (KRA 16:10")

FILIPPOV, Yu.lf.; VENDIUD, V.P.
Electrosynthesis of ozone.
1987-1992 S 162.
Part 7. Zhur. fiz. Ithim. 36 nc.g.-
(MIRA 17:6)
lo Moskovskiy gc-,udarstvermyy uriversitet imeni Lononosova.
. q

VENDILLOY V.P.; FILIPPOV, Yu.VI
Electrical theory of ozonizers. Part 10. Zhur. fiz. khim. 36
no.9s2O58-2061 S 962. (MIRA 17:6)
1. Moskovskiy goaudarstvannyy univemitat imeni Lomonosova.

YEWLIYANOV,
Eleatrosynthesis of ozone. Part 9. Zhur.fiz.khim. 36 no.10s
2263-2267 0 162.
(MIRA 17.4)
1. Mosiovskiy gosudarstvenriyy universitet imeni Lomonosova.

"I'AMOYIDUCH, V.G.; FILIPPOV Yu V.
Electrosynthesid of ozone In a cycling system. Part 7. Zhur.flz,khim.
37 no.ls23-29 Ja
1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova.

5SD/A5D(a)-5/Ar-W1-
14 NR:,AP4044079:, S/0169/64/000004/003O/C032,
Au ri[ORS: pop aVicht VL.P SU4 GyGovich, B. G. Filippov, Yt(. V.
TITLE; Rotator temp erature on electric discharge in the ozonizer
SOURCE: r-110500W. Universite-,- VeBtr!ik. Seriya 2. KIiimlyat no, 4,
1Q~64, 30-32
TOPIC TAGS: otonizer, eldc-tric di'scharge, rotator temperaturc
spect-roscopic determination, ozone synthesis-, -1-f dict-harer
j ge, spark
ABSTRACT: The rotator temp~arature upon discharge ;:)f the ozoilizer:
iri;~Pr various conditions wis stud' e~ s-.ectrosc-.- i allv 1~c- d,!termine
means of increasing the efficiency oi -- ozone syntaisis. Tne rotator
temperature of the ozonizer (fig. 1) was determin-~d under Static
orditions at 4-10 kv, 200D hertz frejuencies, C'. 11iours 3xposure,
u5ing (1) 95% He t 5% N mixtures at 750, 400, 100 and 2 mm Hg
~-,ressure, (2) N 4-0 mixLres containing 10, i~- ~:nl 0, 3. t700 mm
2 2
1/4

n d
a ta
I-A
.7_
L -17618-65
ACCESSION NR: AP40440M
fig; (3) ai'r, at 4p: Hg 4 8 and 10 kv and 1.5, 2.6, %,0 -And
4.5 nia current, respectivibi, and (k) moist air al: 400, 100, 20 and
7.~M 1. T and in mcist -~Lir e ---ato:* Iemper-
In the He-N, mixt
~,(as inoEpenden~-L'f 1)rUe's'Csure; t t"O V -2 -,,.,:-2 rc, '-Ure "-% f L 1-1
~irid ofl ic, mni,--, 3
-eraLLre increagea sii-gnt -iy wi.Lri increajt-- Tfie
ra t ure increased wit'-, increase 4n voila~-e nn~- cc-L:3ea,U~ntly with
the rotator, temperature and ozoni.~~,r (i i r j n I t e G1 P-:~ -a
-11'Y ArCl ffiui6~- gases wa:3 ~y -j t' -H I ~a U
Cl'eiiiei'yariov Yu. M, Fiiiipcv; iu. ~1
1(j62)) for the average ternpqrature of t T lower than
N, g were
1 spectroscopicaily. '7 !-11 s ,,i ~, s 3.)C 7' i n
lues obtainec ed in that
v,.4 s in the dis-
,-;ie iatter measurp-mants were of tpmperntiires w-) I' r,-
-.ar~oe channel, and riot of the averaged '.eLaPeraLa--.3s. Examination
-i 3;--c-tra of the ozonizer discnarge bet-4cer. ~-,-as3 ar.,i -,rcn eiec-
".-Cn iines cletected; ie'l -~c '~"ie 1, U. i t"ne indi-
i i -s r n r ge s ;x,e re f, i w ri r~ r ~4 r a j7 :4 r) 1 1: n a rae&
,Y T
-r-~6t in 1~fie work." Uri art- i,L~5: figure

jf~~. AIM tMkNA '--I
7
17818-65
CCESSIO14 MR: AP4044079-
I SSOCIATION: MGU KaPedra flzicheskoy khimii (Trio.-cow 3t~,-te University,
Department of Physical Chemistry)
,,UBMITTED: 03Mar64
ENCL: 01
LI;UB CODE: IG,. EE UR REF SOVt 003 OTHER: 000

SMOYLOVICH., V.G.; JaLIPPOV, Yu.V.
Electrosynthesis of ozone. Part 10. Zhur.fiz.khim- 38 no.llt2712-
2714 N 164- (MIRA 18:2)
1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova.

--------- -
POPOVICH, M.P.; FILIPPOV, YU.V.
- ii~woi
Spectroscope study of a discharge In an ozonizer. Vest. Mosk.
un. Ser. 2: Xhim. 20 no.1:3-4 Ja-F 165. OMIRJA 18:3)
1. Kafedra fizichIeskoy khimii, Moskovokogo universiteta.

-L--34 3 7 7;;-66--EWT (_mY/NW _P~_t_VE TI IJP(c) JJ)/*/JW
ACC NR- AP6010743 SOURCE CODE: UR100761r)6104010031053110536
AVrHOR: Samoylovich. V. G. ; P0_221!~M.~P-; Ymwl!y
&~=Y~ujf,; Filippov, Yu. V.
ORO- Moscow te Univerolty im, M. V. Lomonosov (Moskovskly gosudarstvennyy
wiiversitet)
TIMLE: The electrical theory of ozonizers. Xl!,' Burining voltage in 0.lcygen-ozonO mixtures
SOURCE: Zhurnal fizicheskoy khimil, v. 40, no. 3, 1966, 531-536
WPIC TAGS: electric theory, gas discharge, oxygen, ozone
ABSTRACT: The authors used a flat ozp)?Izer (discharger) to measure the burning voltage of
a discharge in oxygen and o3ygen-ozon4vihixtures at various gas presBul-eS and with various
dircharge Intervals. Thevaue of the field applied to the oxygen and the oxygen-ozone mix-
tures is determined. In brder to avoid any gradient in ozone!,conoentratlon, the ozone was
produced externally and Introduced. Discharge gaps from 0.1 to 4.0 mm were usedo with
prescures from 50 to 750 min Hg. The ozone concentration was 0.65 to 7.0% by volume.
[The- ratio of the elemental n _qxygen upon 6~-I-ision with elec-
trons was determined. It YAm established by the experiments that the curve of the buiming
Corti 1/2
UDC: 641.13 -

L 34377-66
ACC NRt AP6010743
C)
voltage as a function of ozone concentration Is linear. OrIg. art. has: 6 tables, 4 figures,
and 4 formulas.
SUB CODE: 07,20/ 1 SUBM DA!!~.- 07Dec64/ ORIG REF: 006/ OTH REF: 005
Cara 2/2
515"

-35809 W'~--mff(m)-/Eg(t
ACC NRI AP6014899 SOURCE CODE: UR/0076M/039/012/3092/3095
UTHORt Samoylovich, V. Popovicbp M. P ; YeR2j.!.7qnov,_Yu.
ORG: Moscow State University im. M, V, Lomonosov (Moslcovskiy
gosurePsEvennyy universitet)
TITLE: Electric theory of ozonizer s-kj X1. Discharge in helium at
varioun pressures and discharge gaps
SOURCE.,, Zburnal fizicheakoy kbimii, v, 39, no. 12, 1965* 3092-3095
TOPIC TAGS: ozone, ele ctric theory,
ABSTRACT: The equipment used in the experiments (illustrated in a
figure) consisted basically of an upper aluminum electrode with a
diameter of 15 mm and a height of 50 mm and a lower aluminum electrode
with 9. diameter of 10 mm, pressed into a base made of organic glass.
The article gives als-o a diagram of the electric circuit. Using this
equipmontj, measurements were made by the oscillographic method of the
combustion pressure during a discharge in beliumvlMessurement.9 of the
combustion pressure in helium were made at gas pressures of 750p 6000
400, 200, 100, and 50 mm Hg for discharge gaps of O,k5, 1.00 2.0, 3-0,
1y"2 UDC: 541,1

L 35809-66
C NR, AP6014899
4.o,.5,,0,, and 7.0 mm, The value of E/p was found to remain constant and
to be oqual to-1,4 volts/Om-mm H9 for discharge gaps from 2 to 7 rm and
for prossures not less then 200 mm Hgo An evaluation of the electron
temperature gave a value of 2.7 electron volts, Orig, art. has-* 5
figurea and 1 table.
SUB CODE: 20/ SUBMDATE:, 23Nov64/ ORIG REF: 004/ OTH REP: 001
ccw ;2/2

mff_~ -4.
%Cposla and u9cornpooiltion of SommuniA tot viscubw
dl#c get. 1. Sonsitised decomposition of atumanim Ito a
lowill 4 44v.
144 ale I'll
Kk,-. 24, 17111- .6111111-11, .11 XII. 111, A
IghtwIllog 111whattv ill fill- plv~rllve 4.1 Its ASO Na vaj.w Ha-
iti rtiotojectitm Hith the th"oy of -ro,rigriv, H
X=!. lit lia, it INK. Auld No a Sir%. vatal~jtk-
vic -wn:ltilillot VMCO ill lig %A- -1111ilAr it. that lotiod ill
L
011111ll mom
10-
"W', 4,41- New
I N, -I OM.;~ h Ju

.00,
Syn" AM docoolimmill" td AMMOWA in olochrical
U. ~ llft*1004 01110WHAS *I MOMIA 18
41 LP. Lelovilev, V. V
tow
1. Dy state Unly., momcow).
Zkmr. Pis. Kkior. 24 100PAO(IOW) - d. C.A. 45, 4330.--
The s"tbcsb of NW, i. the ;;Z;~ .1 nPor, of its, ill,
&M Cd In a Slow dlsc%wp was studied. The effect of fig
Ivem ki
ta: cams. An
detining tbc=Y
Av=tion Of the obscmed
The the evergles of tile
A mechanism. occurring by
mmll,was the Clectm.
synthesk of N119. WOVU, WINownton

00~~
USWINmicall Chod 81#7' - Eleatro B-12
Abs ituro: Worst# ~_ gblr=3 go g, 19580 3982
Author 1u.V. P=Lpj?oy Yu.X-Temllyanov.
Inst
Title Electrica: vmll:P~q~ Pf ftl"r's. 1.:Static Volt-kmere
Charactercitics-'of Otoa";
Orig ]mot Zh. -fit. ~:Wmi I,,-: .1957P 11'_`~No" W..W3
Abstract: The study of static volt-aXpere characteristics (Svc) of
ozonizers (0) with spark pps of 1.0., 2.1., 2.9 amA 4.2 m was
carried out. It.vex found that the SVC my be represented In
the first approximtion as two stmight segmts, the slant
of which is deterndued correspondingly to the tot&I electric
capacity and the capacity of. the dielectric barriers. Basing
on the w=dmtIon of the SVC, it was concb1ded that the volt-
age on t1m oyark pp of the 0 remains constant d~trlng the
discharam burning and does not depend on the intAmsity of the
Card 1/2 23-

YVIL'YANOV, Tu.K.; FILIPPOV, YU.V..111",.-
The electrical theory of ozonizers. Part 2: The theory of
dynamic characteristics of oxonizere (with summary In ZnglIeb).
Zhur,fis.khlm.31 no.7:1628-1635 J1 157. (MIRA 10:12)
1. Kookovskly gosudarstvannn universitat im. K.V. Lomonosova.
(ozone) (Chemical apparatus) (Squations)

5(4,)
AUTHORS: Filippov, Yu. V.j Yemellyanov, Yu. M. 30V/76-32-12-25/32
TITLE: -~M__e___Electrical Theory of Ozonators (Elektricheskaya teoriya.
Dzonatorov) III. Electric Current in Ozonators (III.
Slektricheskiy tok Y ozonatorakh)
MICDICAL: Zhurnal fizicheskoy khimii, 1958, Vol 32, Hr 12, pp 2817-2823
(USSR)
ABSTRACT: Based on a previously outlined theorj (Refs I and 2),.the
expressions for the dependence of the actual and average values
of the current passing through the ozonator on the terminal
voltage of the ozonator and its constructive parameters are cal-
culated. The static actual volt-ampere characteristic of an
ozonator below the critical voltage is represented by a straight
line passing through the origin of coordinates (as is the case
with all condensers); the inclination of this straight line is
determined by the aggregate electric capacity of the ozonator.
If the voltage exceeds the critical value, the characteristic
takes the.form of an asymptote, again approaching the straight.
linge passing through the origin of coordinates. The inclination
of the straight line is now only determined by the dielectric
Card 1/2 barriers of the ozonator. Accordingly, the entire volt-ampere

The E:Lectrical Theory of Ozonators. III. Electric DOT/76-32-12-25/32
Current in Ozonators
characteristic is S-shaped. The static volt-ampere characteristic
for the average values of the current consists of two straight
lines intersecting at the point of critical voltages There
are 2 figures and 5 references, 2 of which are Soviet.
ASSOCIATION: Moskovakiy gosudaratvennyy universitat im. M. V. Lomonosova
(Moscow State University imeni M. V. Lomonosov)
SUBMITTEDs June 15, 1957
Card 2/2

AUTHOR: Pilippov, Yu.V. cl/055j59/000/04/017/026
11004/BO07
TITLE: The Elsiotrosynthesis of Ozone-11
PERIODICAL: Vestnik Moskovskoeo univeraiteta. Seriya matematiki, mekhanikil
ast ronomi.i, fiziki,,khimil, 19599 Nr 49 PP '153-186 (USSR)
ABSTRACT: This iii a summarizing report on the work carried out by theauthor
in cooperation with Yu.M. Yemellyanov, V.P. Vendillo, Yu.N. Zhitnoyl
and V.G. Samoylovich a the laboratoriya kataliza i gazovoy
alektrokhimii MGU (Laboratory for Catalysis and Gas Electrochemistry
of Moscow State University). The author refers to N.I. Kobozevq
S.Se Vasillyev, and Ye.H. Yeremin (Ref 1), according to whom the
kinetics of chemical reactions in electric discharges may be
tion if time ia substituted by u/V1
expressed by the kinetio equa
'
the fa.otor of the specific discharge energy (u - active power of the
discharge, v - volume velocity of the gas flow). Figure I shows the
oonstraction of the ozonizer used, and figure 2 the experimental
device. In the individual sections the author deals with the
following subjects: 1) The electrical theox7 of ozonizers: figure 3
(static volt-ampere characteristic , figure 4 (oacillogram of the
dynamic characteristic), figure 5 ~simulating scheme of an ozonizer),
figure 6 (theoretical dynamic characteristic). Herefore, equation"
Card 1,13 (2) and (3) are derived. Figure 7 (oscillogram amperage voltage),

The Electrosynthesis of Ozone '.;/055/59/000/04/017/026
B004/BO07
figure 0,(dependence of the voltage in the discharge gap on the
ozone concentration)t figure 9 (dependence of active power on voltage),
figure 10 (dependence of the coefficient I of the power of discharge
on voltage)f figure 11 (dependence of volte4~e on gas pressure),
figure 12 (dependence of voltage on the length of the discharge gap).
The author discusses the kinetics of the elaotrosynthesia of ozonep
the dependence on the diffusion coefficient Dp and derives equation
(15)- Figure 13 shows the kinetic curve according to equation 15)
as well as according to equations (8) (D - 0) and (10) (D - oo~.
Figure 14 shows the.de3endence of the fictitious decay coefficient
on the gas velocity 2 The action of several ozonizers connected in
parallel as well as in series and the influence of the length of the
reaction zone- 3) The influence of temperature: figure 15 (influence
of the logarithm of the decay- and formation coefficients on 1/T).
The author discusses the low activation energy of 1700 oal/mole.
Figure 16 (dependence of ozone concentration on u/v The temperature
dependence of the decay coefficient is discussed. 4~.The influence
of the length of the discharge gap: Figure 17 kinetic curves for
discharge gaps of different length, figure 18 ~dependence of the
Specific power of discharge on the length of the discharge gap at
Card 2/3 constant voltage), figure 19 (dependence of -equilibrium concentra-

The Electroeynthesia of Ozone 13/055j59/000/04/017/026
B004/BOO7
tion on the length of the discharge gap at constant amperage),
figure 20 (dependence of the power of discharge on the length of the
dischw!ge gap at constant,voltage), and figure 21 (dependence of
equilibrium concentration on the length of 'the discharge gap at
constant voltage). 5) The influence exerted by gas pressure:
Figure 22 (kinetic curve at decreased pressure). The course of this
curve is analyzed mathematically. 6) Ozone synthesis from gas
mixturos: figures 23 and 24 (mixtures of oxygen and argon)l figures
25 and 26 (mixtures of oxygen and nitrogen), Mention is also made
of the,m'xtl..-'e 02 + 002. In conclusion, the author deals with the.
ohemical mechanism of ozone formation, the interaction of elementag
and tho reaction in the presence of nitrogen. On the strength of
these results ozonizere with the required efficiency as well as the
optimumi operational conditions may be calculated. There are 26
figureii and 35 references, 20 of which are Soviet.
ASSOCIATION: Kaf edrIL f iZicheskoy khimii (Chair of Physical Chemistry)
SUBMITTED: April 1959
Card 3/3

VEOILLO, V.r.; TROLITANOVO Tu.M.; FILIMY, ~ru-v.
Laboratory apparatus for producing ozone. Zav.lab. no.11:1401-1402
'59- (MIRA 13:4)
I.Rookovskiy gosudaretvannyy universitet im. N.Y.Lomonosova.
(Ozone)

Electrosynthesis of ozone. Yest.Mosk.un.Ser.mat., mekh,,astron./
fiz.,Khim. 14 no.4:153-.186 159. (M A 13:g)
Xafedra fisichaskoy khtmii Hookovskego universitsta.
(Ozone)
M~g ;~l Z-.V~1--

28(4.) SOV/32-25-4-52/71
AUTHORS: Yemellyanov, Yu. M., Filippovy Yu. V.
TITLE: Automatic PrGssure and Gas Consumption Regulating System
(Sistema avtomatiohoskogo regulirovaniya davleniya i ras-
khoda gaza)
PERIODICAL: ',?avodskaya Laboratoriya, 1959, Vol 25, Hr 4,
I?P, 490 - 491 (IJSSR)
A13STRACT: A setup has been designed which can be used to maintain auto-
natir.ally a constant gas pressure in laboratory plants (Fig).
Basicallyq it consists of two manootats and a contact mano-
meter. The working principle on which it is based is that of
a merour*anomete'r olooing an electric circuit as soon as
the pressure in tho plant in--reases. The electric contact
actuates a water jet pump produce a vacuum, in one of the
ranostlats, which in turn causes the pTessure in the plant
to diminish. As socn as the pressure desired is produced the
mercury in the maLiameter sinks to such a point as to break
the electric rJrnuit. so that the vacuum pump is de-energized.
:t the pmeaw-- is to 16 adjusted to very small pressure differ-
Card '/2 enree a conta,.-t manometer Yrith several contacts is required.

Lutomatic Pressure and Gas Consumption R9gulating SOV/32-25-4-52/71
SyBteM
The apparatus Jeucribed could be used for stabilizing gas
consumpticn. vr-' thin a range of 2-350 1 per hour. The power
SOUTtle zonsisted r-f two batteries 7.5-L-30 with a capa(,%ity
of 50 ra,,"ho-,ir and 1,5 -,-. There is i figure.
ASSOCIAT:CON: Moakovskiy gcsuaarstvannyy univerzitet im. M. V. Lomonosova
(Mosoov State Tinivermkity Laemi M. V. Lomonosov)
Card 2/>

5%(4) SOV/76-33-5-13/33
AUTHORS: Yemel 13,anov, Yu. M. .-Fq4 Us Ve (Moscow)

TITLE's 'TgMetwricheskaya teoriya
The Elect
rical Theory of Ozonizers
*
ozonatorov). 4. On the Active Energy of Ozonizers (4.0b
aktivnoy ;uoshchnosti ozonatorov)
PERIODICALs Zhurnal f.lzichaskoy Ichimiij 1959, Vol 33, Nr 5,

-1042
p 1046 (USSR)
p
ABSTRACTi The formula for the energy of the ozonizer is derived from
the assumptions of the passage of the current through an
ozon .izer maintained in a previous paper (Ref 2). It can be
- I
physicallyinterpreted in the simple form U-V
) as
(I
b
c
,
passing through with
the difference of the Coulomb current 1
.
'
in 1 see and the reactive ourrent I
the ignition voltage V
r
.
The energy is a linear function of the voltage on the ozonizer.
The experimental aftertest was carried out bj means of the
calorimetric passage method. This method consists in measuring
the tem;erature increase of the cooling liquid of -the ozonizer
and comparing it to an equivalent energy by whIch temperature
increase 1;3 not brought,about by discharge but in a way by
Card 1/2 which measurement is rendered possible. A figure shows the

The Electrical Theory of Ozonizers. 4. On the
Activo Energy of Ozonizers
agreement of the measuring values with the values determined,.
especially in the case ofozonizers with a small spark gap.
Longer spark gaps (2-5 - 4.2 am) show deviations from the
linear connection because of complications already mentioned
in reference 5. There are I figure and 7 references, 5 of
which are Goviot.
,ASSOCIATION; Hoskovskiy gosudarstvennyy universitet im. M. V. Lomonosova
(Moscow State University imeni M. V. Lomonosoy)
SUUUTEDs October"101 1957
Card.0

5 (Q
-AUTRORS:
TITLE:
PERIMICAL:
Filippov, Yu. V., Yemellyanov, Yu.
Eleo,~rioal Theory of Ozonisers. V.
'Coefficient of'Ozonizers
Zhurnal fizichaskok khimli, 1959,
M. SOV/70'-33-8-17/39
On the Problem of tbe Power
Vol 33, Nr 8, PP 1780 - 4787
ABSTRACT: Publications contain different data regarding the power coeffi-
cient PC~ of ozonizers (0), i.e. the ratio between the active
power RP of the (0) and the voltampere power (VP), ELS well as
regarding the de.perdence of (PC) on different parameters. Ua-u-
allys (VP) is considered the product of the effective current-
and voltage valueal here, howeveri a complex expression W ?a
obtained for the (PC) % of (0) which is very inconvenient In
practice. A simple:c expression for the determination of the
(PC) 711 is obtained if (VP) is reE;arded as the product of the
amplitude value of the voltage and the mean current -Talue. Both
ways of determination are considered, and from the equations ob-
tained it is found that 'Ybdoes not depend on the ouTrent fre-
quency, and increases rapidly to a maximum at voltages abo7a the
critical voltage,, and approaches asymlitotically the zero point.
Card '1/3 (at a voltage tesiding to oo). Considerations of ;he simplifiod

Elect:rical Theory of Ozonizers. V. On the Preblem of SOV/76--33-8- -'1 '17/39
the Power Coefficient of Ozonizers
equation (3)v i.e. the (PC) *9,1, resulted in an equation (8) for
Irl"Max which containe no expre85ions other than the capacity of
the diacharge space (DS) and the diele~-,tricl barriers of' (0).
Thus, ih,.� maximum of (PC doie not depend on the electrical pro-
pertios of the gaa irt (O~ but on the dimensions of (0) only.
Experimental determitaticne regarding the dependence of' 1~1 on
the voltage were carried out for (0) of different (DS) values
I.Or, 2.1, 2.9 and 4.2 mm) at different rates of oxygen flow
3 - 340 1 ye:? hou:1). The unit has already beer. dez~n:ribpd (Ref 91
~
the (AF) was detiirtainsd aalo-~-~ -mat~ically (Ref 7). The anplitude
values of the ~,oltagp were lZalculated from tha affeetive values
determinsd by meana; of a static kilovoltmeter FS-11q..The mean
W.C
current value was measured by a milliaometer ( th a ou:prous
oxiae Ta-41). The measurement results of the (PC)
(Table 1) show, in asoordance with the theoretical oonsidera-
i-ions made ab,o-ra, that the (PC) passes through a maximum as the
voltage inoreases. The roltaeos at-14, V as wc-11 an the
max max,
-,ralae itself, inorease at an inoreaee in "he (DS). The
Card 2/3 max

'Electrical Theorl of Ozeinizars. V. On the Problem (?f SOV/76-33-8-T7/3",9
the P,,,)wer Coefficient of Oz,3nizel'a
(PC) depends.on the ~rata of oxygen flow, which will be explained
in a fut-,~Te paper, *,,iere I ". is shown as well that +;.,IiF,. iz dus to
a change In the gas ,omposition In the course of o7onj, formation.
There are 3 f'A. jMSres, 2 tables., and references, 4 of whiah ar-a
Soviet,
ASSOC:[ATION: Moskovskiy gosudarat-i-ennyy. universitet im. M. V. Lownoaaira
(Mosoow State University imeni M. V. Lomonosov)
SUBMITTED. January 2-?,~ 1958
Card 3/3

058h0
5M SOV/76-33-10-38/45
AUTHORS;~ Fi-lippoT, Yu. V.j Vendillo, V, P.
TITLE: Electrical Theory'of Ozontzers. V1. Effect of the Length of the
Discharge Gap on the Elec-trical Characteristics of"Ozonizers,
PERIODI-:AL: Zhurnal fiiicheskoy khimii, 1959, Vol 33, Nr 10,
pp 2358 - 2364 (USSR)
ABSTRACTt The electrical theory of ozonizers allows for an explanation
of some rules governing the variation ir the electrical character-
istics of ozonizers in dependence on the size of the discharge,
gap. The authors made investigations by means of ozonizers (Fi13 1)
with discharge gaps ranging from 0-5 tc 1.25, 2.0; 2.39 3.0, 3.5
and 4.0 mm (Tablet geometrical dimensions of these ozonizers).
The apparatus used has already been described (Ref 2 )4 The voll;-
ampere characteristics of the'ozonizers (Fig 1) indicate that
.the length of the.discharge gap has.different ef-fects or, the
characteristics at potent'-als above and below the critical value,
.At-potentials below the c;,itical value, the slope of the volt-
ampere characteristic varies, while above the critical'potential
it is shifted along the potential ordinate in connection with it
Card 1/2 variation in the discharg~i potential. The discharge potential

05640
Electrical Theory of Ozonizers. VI. Effect of the Length SOV/76-33-10-38/45
of the Discharge Gap on the El"eotrical Characte'ristics of Ozonizers
of currents of almost'aritical potential (spark-over potential)
is a linear function of the discharge gap. This indicates that
Paschen's law is satisfied here. Equations are then deduced for
the dependence of the active ozonizer capacity on the length of
the discharge gap (at constant potential and amperage). when
the discharge gap extends, the active ozonizer capacity passes
through a maximum (at constant potential) the position of which is,
in principle determined ~Ythe (r I ' potential. At constant amperage,
the aative capacity has no extremes values and rises uniformly
with an extension of the discharge gap. There are 6 figures,
1 table, and 5 references, 4-of which are Soviet.
ASSOCIATIONs Mozkovskiy gosudarstyennyy universitet im. M. V. Lomon03oya
(Moscow State University imeni M. V. Lomonosov)
SUBMITTEDt April 3, 1958
Card 2/2
wig
lop
glgy p'i
'NVY,

5M 3/076/60/034/01/034/044
AUTHORSs Filippov, Yu. V.. Zhitnev,.Yu. N. B004/BO07
TITLE: Ozonizers! Made From Pji~Aticiq
PERIODICALs Zhurnal fitioheskoy.khimiio 19609 Vol 34P Nr 1, pp 209 210
ABSTBACTs The authors point out the use of plastics, which are more
easily workable as dielectric layer of the ozonizer instead
of glass..They describe suoh an oz
,pnizer, which they produced
at n
from viniplast (Fig 1). Vir!IL~a V"has good electric breakdow
strength (15 - 35 kv/mm)-2a.' sufficient dielectric constant
(6 - 4), and is resistive both to ozone and to the electric
discharge. The characteristic features of the ozonizer pro-
duced weres.Operating voltage 80kv, frequency 1500 CPS,
temperature of coollng water 20 , oiqgen pressure 780 torr,
amperage 6.5 mat power 14 '!,- Figure 2 shove the dependence of
the ozone concentration on the factor U/V (Power of the
ozonizers gas velocity). There are 2 figures.
ASSOCIATIONI kvski osudaretve ny universitet im. M. Lomonosova
TMO101SIC11iow Hale University Imeni Ma V. Lomonosoyl
~UB Ej7jD bldfftfflu er - Tt:~_q- I V.77
arl
it

AUTHORS:
TITLE:
PERIODICAL:
S/07
JOY60/034/05/24/038
BO B002
Yemellyanovp Yu'o 9.9 Filipj)ovj Yue Yo
Ele otrical Theory of Ozonizerao VII. The Effect of the Porma-
tion of Ozone on the Current-~-qoltage of Ozonizere
Zhurnal fizicheekoy khimii; 19609 Vol. 34v Woo 59
PP. 1083-1087
TEM The'authors of the present paper carried out special investigations
of the effect of the concentration of ozone on the current-voltage char-
acteristias and capacity of the 'ozonizero They used a device described in
Ref..I. The concentration of ozone was iodometrically determined, and the
capaoity of the discharge was measured by means of a calorimeter and an
osoiLloscope. The gtatic current-voltage characteristics, the discharge
capacitieslat different voltages, the concentration of ozoneq and the
burning voltages of the discharge at different rates of oxygen passage
are given in Tables 1-3. It was found that the burning voltage of the dis-
obarge in the ozonizer rises linearly with increasing concentration of
ozon,a,, The effective capacity of the barriers of the ozonier (calculated
from the dynamic oharge-voltage characteristics) depends on the terminal
Card 1/2

2lootrioal Theory of Ozonizerso VII. The S/076/60/034/05/24/038
Effsot of the Formation of Ozone on the B010/B002
Current-voltage of Ozonizers
voltage of the ozonizera This may be explained by a successive propagation
of the ilisoharge on the surface of the electrode. The active capaoity of
the ozonizer may, be calculated with suff icient accuracy if the depend enoe
of the biLquing voltage of the discharge on the ozone concentration and the
change Jn the effective capacity of the barrier of the ozonizer are taken
into acclaunt, There are 4 figtxres, 3 tablos, and 9 references: 5 Sovietq
2 Germang and 2 Swiss.
ASSOCIATION: Moskovskly goaudarstvennyy universitat ima M.,V, Lomonosova
(Moscow state University im'eni M,.V, Lomonosov)
SUBMITTED: July 21, 1958

S/076/60/034/05/37/038
B01O/B0O3
AUTHORS: Vendillop~Vc-P*-O:Yemollya 0v, Yu...M., Filippov,
Ln Lai, __Yj
TITLE- Calculation of,Laboratorr Ozonizers
PERIODICAL:, Zhurnal fizicheskoy khimii, 1960, Vol. 34j No- 5t
PP-~ 1145-1147
TEXT-- The electrical theory of ozonivers (Ref. 3) and experimental
resul ;to on the kinetics of the ozone ynthesialobtained in the
laboratoriya kataliza i gazovoy elektr0khimii MGU (Laboratory of
Catalysis and Gas Electrochemistry of MSU) permit the calculation of
ozonizers having the necessary capacify or a cerwn concentration of
ozone.- The caloulation method described is suitable for any ozonizer. V/B/"
Proceeding from1he curves of dependence (Fig. 1) for the concentration
ofozone on the kaotor U/v N - capacity of the ozoraizert v - oonsumption
of ge's)-the equations for the calculation of ossonizers are derived. The
caloitlation method is illustrated by an examplea. It is recommended to use
a working voltage of 8-9 kv6 For feeding the ozonizeri machine generators
-Card 1/2

CalciiLation of Laboratory Ozonizers S/07 60/034/05/37/038
B01 OYBOO3
or vaeuum-tube generators of different -types may be used (3r-2A (ZG-2A),
~.r -1o .(ZG-10)f3r -11 (ZG-11) It.and other ) along withotl,- - correaponding
amplifl-e'_r$_T_Y_-30'0 (U-3001Y-500 (U~-50 Y-600 (U-60 )%and TY-5 JM-5)j.
In order to raise the voltage (to 8-9 k1i transformers of the types
HON-10 (KOM-101A OM-0-5/10 (OM-0-5/10'1~land X-5/10 (0S-5/10 ~Jmay be
used. 7Te__vo_1Tdg_e may be regulated by laboratory autotransformers of the
types AATP-1 (LATR-I)%and AATP-2 (LATR-2). The transformer operation
3- 6 and
may be controlled by means of kilovoltmoters of the types C-96 : W ~ 46
-7f,' Ms-N, voltage dividers of the typesAPE-1 (Me-l'A-ind
BKC
ASE-2 (DNYe-2), or bD e of mMjamieters with rectifiers of the
)~ m_ans
types, 1-k-312 (Ts-3_2 41 (TO-41)r and others). There are 2 figures and
4 Soviet references.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosova
(Moscow State University imeni W. V. Lomonosov)
SUBMITTED: September 30P 1959
'Coard 2/2

syt076/60/034/012/024/027
B020/BO67
AUTHORS YGM411yanovp Yu# U41'Zilippovi YU. V.
TITLE: Equivalent Electric Circuit of Ozonizers (Reply to the
Article by V. V. Yaotreboy '.'On the Problem of an Equivalent
Electric Circuit of Ozonizers")
PERIODICAL: Zhurnal fizicheskoy khimii, ig6o, Vol- 34, No- 12p
pp. 2841-2843
TEXT: In the.article by V. V. Yastrebov (Ref,; 1) a number of objections
are*made to'the equivalent-electric oiroixit of the ozonizer. A now
equivalent ozonizer.circuit is suggested which consists of an electric
system of three aeries-conneoted condenearep the central one of which is
shuntod by two thyrotroas and a resistor. The authors point to the fact
that V. V.. Yastrebov has not observed this principal difference between the
equivalent circuit of the apparatus and its model. The equivalent circuit
should be a combination of simple elements of the electric system which
in the calculations replaces part of the actual electric system. Purther-
more, it-replaoss any devioe-~only as souxos or consumer of electric
Card 1/3

Equivalent Electric Circuit of Ozonizere (Reply S/076/60/034/012/024/027
to the Irtiole by V. V.. Yastrebov "On the. B02O/B067
Problem of an Equivalent Electric Circuit of
Ozonizerell
energy, it can, however# not be regarded.a,s its model. The equivalent
circuit suggested corresponds to these three requirements: it allows the
theoretical calculation of the most important electric characteristics of
ozonizerep i*e., of the external static and dynamic volt-ampere character-
istics, of the active power and the power factor. The authors refute
V. V. Yastrebov's opinion that the ozonizer circuit suggested by the
authors (Fig. 1) does not allow the interpretation of other types of
current curves which are obtained when studying real ozonizers. The elec-
trio system suggested by V. V. Yastrebov is only one of the possible
ozonizer models and oann 'ot be regarded as equivalent circuit since it
contains also thyratrons besides simple elements. The results obtained
by V. V. Yastrebov when studying the qualitative dependence of the shape
of the current curve of the ozonizer on the lumped voltage in the
thyratron system and the magnitude of the shunt do not correspond to the
facto. Fig# 2 shows the oscillogram of the voltage curve in the discharge
interval which was experimentally obtained by the authors. The shape of
this curve correbponds to the theory of electric ozonizers. The flat
Card 2/3

E4ui*alent Electric Circuit of Ozonizers (RePlY 5/076/60/034/012/024/027
t6-the-Artiole by Vo V. Yastrabov "on the B020/BO67
Problem of an Equivalent Electric Circuit of
Ozonizers")
peaks of this curve confirm the voltage regulation in the discharge
interval during the ignition of discharge. Henoeq the following may be
concluded:1) the obJectione made by Ve V, Yastrabov against this
equii~alent ozonizer oirouit are not substahtlated and do not take account
of the principle difference between the equivalent'oirouit and IL model,
2) the electric system suggested by V. V. Yast:rebov is no equivalent
oircuit of ozonizers but only its faulty model. There are 2 figures, and
7 Soviet references.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M.V. Lomonosova
(Moscow State University imeni It. V. Lomonosov)
SUBNETTED: October 7t 1959
Card 3/3

88711
S/076J61/035/001/015/022
B004/BO60
/X J/C;20
AUTHOS: Samoylovich, V. 0. and Pi )OV
TITLE: Electrical theory of ozonizers. 7111. Effect of frequency
upon the electrical characteristics of ozonizers
PERIOMICAL: Zhurnal fizicheakoy khimii, 'v. 35o no. 1, 1961, 201-205
TEXT: The problem of increasing the power of ozonizers by an increase of
frequency is dealt with here. A report is given of the effect of
frequencies between 300 and 3000 cps upon the course of the voltampere
chara.ateristics Im W f(VO for an ozonizer with a 1-mm discharge gap.
eff
(IM W I The measurements were made on electrodes cooled down to.
mean
250C, 600 mm Hg, the throughput rate of 0being 100 1/h. The frequency
was obtained by means of a ~P-10 (ZG-10) Sound generator with a -T~-5 (TU-5)
amplifier. Fig. I shows the v-a characteristics for the various
frequencies. It was noted that a change of frequency did not cause any
change of voltage V9in the discharge gap. The critical voltage lar also
Card 1/4
i$
t

88711
Elect:rical theory of ozonizers. B/076/61/035/001/015/022
B004/BO60
remained constant. According to Ref. 4 the v-a characteristics are
described by the equations IM (2/n)V0Ctotal W for V, < F2 Vc, (1);
Im = (2/n)(V 0 - V9)COW for Vo li~ V,r (2). [Abstracter's Note: Cc is
not defined . In both cases, the course of the curves as a function of
frequency was found to fit the theory. The critical current I cr
V ti is also a linear function of frequency. As regards the
total or
effective energy U of the ozonizer it is noted that measurements must be
made under conditions, where U remains constant. From U - V 9(IM - Icr)
(5) and I M - Icr - Ia the active current,, this was observed to be the
case, when I -const. As is shown by the table, this has been confirmed
by experiments. For I eonst, U does not depend on the frequency. The
linear relationship between 1/iL and 1/W was confirmed experimentally for,
the power coefficient it. in accordance with the theoretical findings.
There are 6 figures, 1 table, and 7 references: 6 Soviet-bloc and 1
Card 2/4
an

89575
S/076,/61/035/002/012/015
B107/220
AUTHORS: Filippovp Yu. V. and Yemellyanov, Yu. M. (Moscow)
TITLE: Electrosynthesis of ozone.
I.*Kinetics of.ozone synthosis under flow conditions
PERIODICAL: Zhurnal fizicheskoy khimii,-v. 35, no. 2, 1961, 407-415
TEXT: The paper is mainly atheoretical.study of the kinetics of ozone syn-
thesis in the ozonizer under flow conditions. The investigation is substan-
tiated by some experimental data. For the kinetics of ozone synthesis, the
equation
dX
k' kIx (1), where x is the ozone concentration, t the time, ko, and k,
0
constants, has been derived by S. S. Vasillyevt X. I. Kobozev, and Ye. N.
Yeremin (Zh. fiz. khimii, .1, 619, 1936). When t is replaced by U/vj.the
U
solution of the equation will be x x (1 - exp(-k,-) (2); x - k_/k is
P v P o 1
the equilibrium concentration of the ozone, U/v is the ratio of capacity to
volume rate of the gas. flow. A further equation for the kinetics of ozone
Card 1/*

8/076/61/035/002/012/015
Electrosynthesis of ozone ... B107/B220
synthesis has been derived by H. Becker (Wiss. Ver6ff. Siemens Konz.,~_lf 76
1920; 1, 242, 1923/1924): a U/v ts,
x ~ -1--+--b-u (3), where a and b are constan
7,-
The investigation has shown that these equations correspond to the critical
cases of ozone-transport in d gas flow. (3) holds for the case of ideal
mixing, and (2) for the case of ideal displaqqtnent, i.e., in the absence of
diffusion. For the general case, the differeri'~ial equation
d2x dx
D~~_' - v - - klx + kof 0 (8) has to be solved f where D is the diffusion
dl2 Ldl I
coefficient, 1 the coordinate along the axis of the ozonizer, and v L the
linee.:r flow velocity. In equation (8), -the change of volume is not con-
side3,ed. As G. M. Panchenkov has shown (Uch. zap. MGU, no. 174, 53, 1958)t
this may have a substantial influence upon kinetics under flow conditions.
Because of the slight conversion, the volume change in the electrosynthesis
of os:one amounts to 3% only. Under the boundary conditions, where the ozone
is removed from the reaction space merely by mass transfer, the equation for
the ozone concentration at the outlet of the ozonizer (1 L) is solved as
follows:
Card 2/6
-_4

89575
S/076/61/035/002/012/015
Electrosynthesis of ozone
B107/B220
2 2 2
a a v ~k 11
1 2 L vL
X=x 2 19) where a TD_
p 2 1,2
a exp(-a L) a2 exp(
1 2
the d!Lrect calculation of the kinetic constants from this equation is very
compliuated. The following indirect solution is possible:
2 2
IrL x P v aI exp(-a 2L) -A2 exp(-alL)
T In x x L In 2 2 (10). Here, the left-
p al - a2
hand side is the decomposition "constant" of ozone, calculated from the aqua
tion for ideal displacemen t: x - x p exp (-k IL/vL)) - Fig. 1 showa the
good agreement of the theoretical curve with experimental data. For the
tests, an ozonizer of L - 35 cm was used; the external and inte-mal diameters
were 41.9 and 39-7 mm, respectivelys'for the outer electrode, and 35.6 mm and
33-0 mm, respectivelyfor the inner electrode; discharge capa.city was about
120 w. The apparatus is described in detail in a previous paper of the
authors (Zh. fiz. khimii, 31, 8~6, 1957). As a table shows, the decomposi-
tion constant of the ozone increases with increasing flow velocity and
Card 3#
4, 9

89575
S/076J61/035/002/012/015
Electrosynthesis of ozone ... B107/B220
tends toward the critical value 0.340 sec Using this value for ki, the
curves for several values of-D were .calculated (Fig. 2). In most cases,.
equation (10) can be reduced.- Thue,
v x
L ln P v a (11) holds for higher flow velocities. As to the
1 X - X L 2
p
accuracy of this approximation see Legend to Fig. 2. Equation (9) may be
reduced to x - x p(I - exp(a 2Q) (14)- Calculation shows that the error is
below 1~. under the above-described experimental conditions; for industrial
conditions where the reaction space is considerably longer than 35 am, the
range of application of equation (14) is extended significantly. Further-
more, the usefulness of the equations (1) set up by S. S. Vasillyev,
N. I. Kobozev, Ye. N~ Yeremin and (2) by H. Becker for an approximate calcu-
lation was examined. Their comparison with experimental data shows clearly
that the former is more suitable. There are 5 figures, 1 table, and
10 references: 9 Soviet-bloc and 1 non-Soviet-bloc.
Card 4/6

35/002/012/0
/076/61/0 15
O;qynthesis of 'ozone'
B107
/13220
"'IS30CIVION: ~,Xoiikovskiy-gosuderstvenny3r.universitet im. M. V.'Lomonosova.
(me'
I~meni M. -V.
scow Lomonos
ov)
SUB14ITTED v J
A une ;16 1959..-:
'LegendAo "the
Fig.' 1: Dependence -of.. k on: thellow'.velocity of oxygenv.
I- ki, 4oints zep, :values ,.the 'curve is theoretically calculatf
ree Iit experimentaV~- id,.
f or D ai 15 cm /see,-
7,,
1.4
I'll fit,
.41 -
Carcl V6.

5/07 61/035/003/01 23
B121YB206 ?V0
AUTHORSt Filippov, YU& Vs and Vendillo. V. P.
TITLEt Eleotrosynthesie of ozone. II. Synthesis of ozone from
oxygen-argon mixtures
PERIODICUt Zhurnal fizicheskoy khimii, v. 35, no. 3, 1961, 624-628
TEXTi T.he' kinetics of the synthesis of ozone from oxygen-argon mixtures has
been studied for a wide range of 'compositions. Experiments were conducted
with an apparatus described already previously (Ref. lt V. P. Vendillo, Yu.
M. Yemel'y~anovj Yu. V. FilippovP Zavodsko Laboratoriyaj*no. il, 1401, 1959).
The synthesis of ozone was made in a glass ozonizer with a-c of 1250 cps and
a constant voltage of 8 kv. The flow rate of the reaction gas through the
ozonizer was varied between 10-200 1/hr. The analysis of the reaction pro-
duct3 f037 OZOne was made iodometrioally. Mixtures of the following argon
content vere used for the synthesis of ozonel 4, 9.5,10'j)Q,37, 48, 62t 70,
80, and 510% by volume of A. It was established that the equilibrium con-
centration of ozone decreases linearly with an increase of the argon content
in the mixturesp a reaction of first ordor existing therefore. For the
Card 1/2

S/07 61~035/003/015/023
Electrosynthesis of ... BI 21 Y520
a ko
equilibrium concentration x eq Of the Ozone, the equation xeq a k k (2)
holds (a - initial concentration of oxygen in the mixturej k0 - constant of
formation of ozone; k, = constant of decomposition of ozone). T)-,e constants
ot deconposition and formation of ozone increase with rising argon content
of the ,n?action mixtures, while the ratio k0/(k 0+kj) is independent of the
argon content of the mixture and equals 0.0506. This increase of the kinetic)
constants with an increase of the argon content is explained by the uneven
energy distribution of the electric discharge among the components of the
mixture, In the formation and decompoaition reactions of the ozone, argon
remains inactive, since the degree of conversion of oxygen to ozone is inde-
pendent of the composition of the mixture. S. S. Vasil'yev, N. I. Kobozev,
and Ye.-N. Yeremin are mentioned. The3!e are 3 figures, I table, and 5
Soviet-bloc references.
ASSOCIATIONt Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosova
. (Moscow State university imeni M. V. Lomonosov)
SUBMITTEDt
Card 2/2
July 9, 1959

AUTHOR.Us
S/M/k6l/035/009/007/015
B1 06/B1 10
Filippov, Yu. V.# and Kobozev, N. I.
TITLEt Eleczrosynthesis of ozone. III. Effect of temperature of
ozonizer electrodes an ozone synthesis
PERIODICAL: Zhurnal fizicheskoy khimiit v- 35, no. 9,A961, 2078 - 2082
TEXTt The cooling of electrodes during electrosynthesis of ozone is very
important sin!:,~, 1,n discharges in ozonizers considerable
amounts of energy are set froe %hich cause strong heating of the gas in
the discharge ~hawibar ard 3--' the electrodes themselves. The authors
experimentally eTudied the effect of electrode temperature on ozone
synthesis since -,a'rlication da-11a on this problem are insufficient and
partly contradil,tory. The ~?xperimental installation was similar to a
previously do.92ribed appafatus (Ref. 8: Yu. V4, Filippov, Yu. M. Yemellyanotj
Zh. fiz. khimii, ~',, bu6. 1957; Ref. 9t V. P. Vendillo, Yu. B1. Yemellyanov,
Yu. V. Filippov '. &.vodsk. laboratorilra 25, 1401, 1959), and differed only
by the devicp ~ior the eiectrodes of the ozonizer and keeping their
temperature= shows this device. It consists of two
Card 1/04,

2768~
S/076/61/035/009/007/015
Electr'-).9Y(I'!-~;...._ B106/B110
electrical!,-., 3_-~, ~,ted p,ilts serving for the separate cooling of the inner
and outer Ea~-h part contains a spiral cooler (1, 6) which is
immersed. in :.. bev_- vp.,;s-" filled with a mixture of acetone and dry ice
and attached zo a jaz~k-sore;~ f)r temperature control, a rotary pump (2,5)s
and an alcohol the --.e I "A. 4). All experiments were conducted at an
oxygen pressure of 7`0 irm tig with current of a fre uency of 1500 cps, and
at temperatures if .40~~ ~)6 , -!00,00, 100, and 209C. Rates of oxygen
flow ranged t~~ ',!5 l/br for till these temperatures (except for
200C). At 200CW- tki; concentration of ozone was only deter-
mined. Table -1 sl-ovis elec~:-ica_-, data during the operation of the ozonizer.
The irvestigZIt'~.0-ri3 showed that (1) only at relatively high values of the
ratio F/v (F = v_-liume )-.' tLe discharge zone of the ozonizer, v - rate of
oxygen flow by a. vclume'-,~,mperature strongly affects the ozone concentra-
tion; (2) concen-.ra--ons ef ozone up to 16 % can be obtained by cooling
the electrodes and main-,,t_;niDg large U/v values. Prom Eq. (1) derived by
S. S. Vasillye-, _N, T, Kobozev, and Ye. N. Yeremin (Ref. 12: Zh. fiz.
khimij., .10, 619, 19561 -.he authore calculated the kinetic constants for
formation and deoomposi~,,,on of ozone in the electric discharge:
k + 1: vln(xe/x(; x)'/'U, kc, x,(k _i. k, )/s, (1 (k - constant of
0 0 0
C a r d 2 N_

2766
S/076/h/035/009/007/015
Elect:rosynthesis of ozone B106/B110
ozone formationj k - tonstant of ozone decompositionj a initial ooncen-
tration of oxygenj x G - equilibrium constant of ozonel x ozone concen-
tration for a given U/vj U - active discharge power). The value for U was
calculated theoretically Nef. 13t Yu'. M. Yemellyanov, Yu. V. Filippov,
Zh. f:Lz. khimii, U, 1042, 1959). The calculation of the kinetic constatits
showed-that k + k increases with increasing v. This indicates the effect
0 1
of ozone diffusion along the gas current on the kinetics of ozone EDinthesis.
A comparison of the mean values of the kinetic constants for various
temperatures showed that the temperature only affects the decomposition
constant of ozone which rises with temperature. The constant of ozone
formation, however, does not change with temperature according to a law.
k1 obeys Arrheniuel law. From the inclination of the straight line in a
diagram (log k19 I/T) a value of 1600 cal/mole results for the activation
energy of ozone decomposition. This small value indicates that the de-
composition is not~~ thermal but a photochemical reaction. The diffusion
processes.may be another reason for the low value cf the activation
energy. A decieion between these two possibilities may only be made by a
Card 3/6f-

2768k
S/076/6V63')1/009/007/015
Electrosynthesis of ozone ... 3106/B110
detailed investigation of the mechanism of ozone electrosynthesis. The
fact thatq within the error limit of' the experiment , k 0 does not depend
on tem-3erature, undoubtedly proves that the activation of chemical
reactionaln electric discharps has a nonthermal character. N. Pushin
and M. kaukhoheva (Ref. 6: ZhHFKhO,.L6#576, 1914) are mentioned. There
are 4 figures, 2 tables, and 17 references: 10 Soviet and 7 non-Soviet.
The reference to the English-language publication reads as followss I.
Devine, J. Ele-trochem. Boo., M, 400, 1956.
ABSOCIATIONt MoskovBkiy gosudarstvennyy universitet im. M. V. Lomonosova
(Moscow State University imeni M..V. Lomonosov)
SUBMITTEDs February 4,.1~60
Fig. 1. Scheme of the cool~qg system for the ozonizer electrodes.
Legends See text of the abstract. *i-
Legend -to Table 1: * experiient conducted at v - 79j/hrj ** experiment
conductod at v 29 l/hr; -xi* experiment,c6nducted at v w 9 l/hr.
Card 4/4~

D227/D302
AUTHOILS: Samoylo vichq V.G. and'Filippov, Yu. V.
TITLE: Mechanism and kinetics of ozone synthesis in the electric
discharge
PERIODICAL: Moscow, Univernitet. Vestnik. Seriya II. Khimiyaj,'no. 1,
1962, 44-48
TEXT: In the present work the authors studied the effect of oxygen
pressure and strength of current on the synthesis of ozone in a circu-
lating, system. It was first confirmod that the equilibrium ozone concen-i-
tration is independent of current. The effect of pressure and rapid
decresise of ozone concentration at low,pressure are considered and ex-
pressions for the equilibrium ozone concentrations are given,showing that
the 02;one concentration is (a) independent of pressure when the latter is
high iind (b) proportional to t 'he 4th power of the total pressure when
the latter is low. The kinetics of ozone synthesis are represented by a
first order reaction and the decomposition of ozone by Eq. (3a)
Card 1/2
S/189/62/000/001/00.'L/002

S/189/62/000/001/001/002
Mechanism and kinetics of ,o D227/D302
0
K 0
C 033 0 _Klot
Z-07 % ;= 100 (1 6 (3,a) where K0 = constant of
2 0
formatAon and Ko constant of 0decomposition.. On the basis of the
3
proposod reaction mechanism, the kinetics of ozone synthesis are described
and disscuesedo There are 5 figures and 3 references, 2 Soviet-bloc and
I non-Soviet...bloc. The reference to the English-language publication
reads es follows: Devinst J- Electrochemo Soc. 103, no. 8, 460 (1956).
SUBMITTED% January 3, 1961
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B124YB1 140
AUTHORS: Filippov, Yu. V., and Yemellyanov, Yu. M.
TITLE: Electrosynthesis of ozone. IV. Effect of discharge power
(ozonizer with 1 mm discharge gap)
PERIODICAL: Zhurnal fizicheskoy khimii, v. 36, no. 1, 1962, 181-188
TEXT: Five series of tests were performed at various rates of oxygen flow
to study the effect of the discharge power on the ozone yield in electro-,
synthesis. The equipment used for ozone synthesis has been described
earlier by the authors (Ref. 6: Zh. fiz. khimii 31, 896, 1957; Ref. 8;
Zavodsk. laboratoriya ?5t 14019 1959). The gas pressure was automatically
maintained at 775 � 0,1 mm Hg. Tetrachloromethane was used as a coolant
for the electrodes, the temperature of which was kept constant at
20.0 t 0-050C. The current frequency was 1350 cps. The discharge power
was measured with a flow calorimeter described by the authors in Ref. c,'
(Zh. fiz. khimii 31, 1042, 1959). The ozone content in the gas was
determined iodometrically. As is evident from Fig. 1, the factor U/V1
U being the discharge power and v the volume rate of oxygen flow through
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Electxosynthesis of ozone... B1249110
the oitonizer, is not the only parameter determining the ozone concentration.
One of tile additional factors is the temperature in the reaction zone which
depends on the discharge power. The mean temperature in the reaction zone
of the ozonizer can be calculated by allowing for the effects of the
tempel7ature differences between the gas in the reaction zone and the
cooling liquid which, in turn, involve the gas temperature drop in the
reaction zone, at the walls of the glass electrode, and at the interface
between the cooling-liquid film and the electrode surfaces, The relation
t0 qoa2 t0
max 2A ' e1 (9),
where qo amount of heat volved per see in
e g the volume unit of the reaction
zone, a distance between the electrode surface and the center of the
discharge gap, ;tg = heat-transfer coefficient of .the gas, and tel ~surface
temperature of the electrode, holds for the maximum temperature of the gas
layer in the central part of the reaction zone. For the mean gas tempera-
ture in the ozonizer, the relation
0 qoa2
t + to (10)
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Eleotroeyfithesia of ozone... B124/B116
is valid. By comparing these two equati.onsi one obtains
.0
0, _ 2 (to 0
t. t
9 el Max e
-5
was calculated frdm experimental data to be 14-10 Cal/cm"sec* deg.:
9
Thus, the temperature difference between the gas in the reaction chamber
and the cooling liquid is a linear function of the discharge power.
Mathematical evidence is given for the fact that equilibrium concentration
(i.e.i 12-5 %.by volume) of ozone! is the maximum yield which can b`9
obtained in the given ozonizer with a constant coolant temperature of
200C. The ozone concentration can be increase .d by improving the cooling
of the electrodes.* S-S. Vasillyev,.N. I. Kobozev, and Ye. N. Yeremin
(Ref. 4: Zh. fiz. khimii 1, 619, 1936)'are mentioned. There are
-Soviet.
3 figures, I table, and 11 references: 8.Soviet and 3 non
'ASSOCIATION:- Moskovskiy gosudarstvennyy universitet im,M. V. Lomonosova
(Moscow State University imani M.'V. Lomonosov)
SUBUtTTED: June 8, 1960
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5107616210361005100410$3
BIOI/.BIIO
AUTHORSs Samoylovich, V. G., Vendillo, V. P., andZL1iUovL Yu. V..
TITL;,"; Electrosynthesia of ozone. V. Synthesis of ozone in a flow's
under reduced pressure
PERIODICAL: Zhurnal fizicheskoy khimii, V. 36, no- 5, 1962, 989 -.992
TEXT: To clarify the kinetics of ozone formation, the synthesis of ozone,
was studied at reduced pressures in a device described earlier (Zavodsk.
laboratoriya, 25, 1401, 1959; Zh. fiz. khimii, 33, 2358, 1959). Three
ozonizers, length 250 mm, diameter 35 mm, discharge space 0.5 (1); 2.0 (2),
and 4.0 mm (3) were used, the amperage in ozonizers I and 2 being 44-4 ma
and in ozonizer 3 being 30 ma, the electrodes with water at 22-50C, fre-
quency 1250 c-Ds, flow rate of oxygen 504500 liters/hr, pressure
160 - 780 mm Hg. At falling pressure, the curves for 0 yield (% by
3
volume) versus u/V showed increasingly distinct maxima (Fig. 1). It is
discussed whether these maxima are caused (a) by decomposition of ozone
before the ozonizer on oounter-current diffusion of ozone, or (b) by
decomposition of ozone after the ozonizer. The case (a) is possible since
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Electrosynthesis of ozone ... B101/B110
PV const. has been found experimentally. For the case (~), PV
max max
- const. has also been found on -the basis of the equation dx/dt - k;x. ~
(x W 03 concentration, t - time, k,' - decomposition constant of 0, after
the ozonizer). It is assumed that in practice the,twoc-processea are.; -'i~
combined. There are 3 figures and 2 tables.
ASSOCIATIONs Moskovskiy gosudarstvennyy universitet im. M; V. Lomonosova
(Moscow State University imeni M. V. Lomonosov)
SUBMITTED: July 20, 1960
Fia. 1. Ozone concentration versus u/V for
ozonizer with 0.5 mm discharge space. (1)
780 mm Hg; (2) 620 mm Hg; (3) 440 mm Hg;
(4) 320 = Hg; (5) 160 mm Hg.
Legends Ordinate 0,1 by volume.
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