SCIENTIFIC ABSTRACT FAVORSKAYA, L.V. - FAVORSKAYA, T.A.

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• Collection: Scientific Abstracts
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• Document Release Date: August 22, 2000
• Sequence Number: 14
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

A V,,~~ A Y A
137-58-5-9319
Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 5, p 75 (USSR)
AUTHORS: Ponomarev, V.D., Stolyarova, Ye.I., Koz'min, Yu.A.,
Favorskaya, L.V., Shalavina, Ye.L.
TITLE- A Leac'hing 7reatment of Dust From Furnaces of Lead Plants
(Shchelochnoy sposob pererabotki pyley svintsovykh zavodov)
PERIODICAL: Izv. AN KazSSR. Ser. gorn. dela, metallurgii, str-va i
stroymaterialov, 1956, Nr 4 (15), pp 3-17
ABSTRACT: The authors present a technology of a dust-processing system
intended to increase the extraction of Cd, TI, and In from roasted
dusts issuing from smelting furnaces in lead plants. The system
possesses the following advantages: 1) the TI is extracted in the
early stage of dust proce55ingi namely, during aqueou5 leaching;
the extraction of metallic TI constitutes 52-57%; the electrolytic
TI, obtained by means of a two-stage electrolysis process, is
99.998% pure; 2) large amounts of Pb, Zn, and As are extracted
into solution in the process of alkaline leaching. Cd and In re-
main in the residue. Owing to the considerable reduction in the
weight of the leaching residue (down to 1/6- 1/11), the amount of
Cd and In contained in it is 6- 11 times greater than it was in the
Card 1/1 original dust. G. S.
1. Lead ores--Processing 2. Metals--Separation 3. E_Iectrolysi~

USSR/Chemical Technology. Chemical Products and Their Application. J-6
Mineral Salts. Oxides, Acids, Bases.
Abs Joar: Referat Zh.-Xh., No 8, 1957, 27432
Author : _L.V. F& varova
19NAken, Ye.I. Stol,
Inst, : AciAWn-W of Sciences of Kazakh SSR
Title :Speed of Decomposition of Zinc Oxide Minerals by Caustic
Soda Solution
Orig Pub: Izv. AN YazSSR, Ser. gorn. dela, stroymaterialov i metallurgii,
1956, vyp. 6, 92-103.
Abstract: The speed and the conpleteness of the interaction reaction of the
minerals smithsonite (ZnC0j) (1) and calamine (Zn,~,SiO,.H;O) (II)
with N&OH solution (III) was studied. The decomposition of I
and 11 was studied with regard to the dependence on the concen-
tration of M, temperature, the speed of -the pulp agitation, the
magnitude of the caustic modulus of the solution and the fineness
of the mineml grains. It is shovm that silica and soda prcduced
Card 1/2 -4-

USSR/Chemical, Technology. Ch,--vdcal Products and Their Application. j-6
Mineral Salts. Oxides,Acids, Bases.
Abs Jour: Referat Zh.-Kh., No 8, 1957, 27432
at the decomposition of I and II do not pass completely into th,~-
solution in consequence of their limited solubility in III and
produce a film on the surface of the mineral, vhich sharply slows
the reaction down being a basical diffusion resistance. The
temperature and concentration of III influence the solubility
and the conditions of formation of the film of reacticm products.
Card 2/2

PONOMAUV, V.D.; STOLTAROVA, Ye.I.; KOZIMIN. Yu.A.; FAVORSKAYA,-1.-V-', -
SHALAVINA, Ye.L.
Alkali method of treating lend refinery flue dusts. Izv.AN KazRkh.
SSR.Ser.gor.dein met.. strol. i stroimat. no.4:1-17 '57. (MIRA 11:4)
,(Flueash) (Lenching)

r
137-58-5-9323
Translation from; Referativnyy zhurnal, Metallurgiya 1958. Nr 5, p 76 (USSR)
AUTHORS: Favorskaya, L.V., Stolyarova, Ye.l.
4-------------
TITLE: Conditions Required for the Formation of A rsenates of Triva -
lent Thallium (Usloviya obrazovaniya arsenatov trekhvalentnogo
talliya)
PERIODICAL. Izv. AN KazSSR. Ser. gorn. dela, metallurgii, str-va i
stroymaterialov, 1957, Nr 4 (15), pp 53-58 4.r. Yazakh.)
ABSTRACT: The conditions required for the formation of arsenates of T1
were studied on synthetic sulfuric-acid solutions containing the
sulfate of T13+ and As acid. An aqueous solution of ammonia Was
added, under stirring, to 50 cm3 of the solution being investi~-
gated, after the latter had been heated to 400C. Upon reaching a
definite pH value, a precipitate was observed in the solution. The
precipitate was removed and the solution was tested for TI. The
process of precipitation of T1 in the presence of As was studied
as a function of the acidit of the medium on a solution contain-
ing 0.46 g/1 of TI, 2.3 g~f of As, and 52.9 g/1 of Fe. Maxi-
mum TI concentration, in a solution containing As and having a
Ca rd I /Z pH of 1.2 amounts to 0.03 g/1 . In order to determine the

137-58-5-93.13
Conditions Required for (cont.
approximate composition of precipitates obtained in various media, experi-
ments were conducted on a solution which contained 0.4 g/I TI, 3.78 g/1 As,
and 52.9 g/1 H2S04* At a p14 of 1.6-2.0, the composition of precipitates of
TI arsenates is nearly identical, and the molar TI-As ratio in the precipitate
amounts to 1:2. At a pH > 4 the precipitates undergo a change in color, while
the TI-As ratio increases and, at a pH of 8.67, becomes equal to 1:0.5.
G.S.
1. Thallium arsenates-Production 2. Thallium arsenates--Precipitation
3. Arsenic acids--Ghemical reactions 4. Thallium--(,hemical reactions
Ca rd 212

FAYMSFAIA, L.T.; PONOKLMWA., YeqIq.
Aressure of thallium sulfate vapor. Izv.AN Kazakh-SM.
Ssr,metabog I ognMe no~2:30-33 160o (NIU 1318)
iftallium sulfate) (Vapor pressure)

S/137/62/000/007/009/072
A052/A1O1
AUTHORS: Favorskaya, L. V., Nikiforova, 0. A., Gurlyeva, A. 1.
TITLE: On the possibility of extracting scandium from wolframites and
beryls
PERIODICAL: Referativnyy zhurnal, Metallurgiya, no. 7. 1962, 26, abstract 70170
("Tr. Kazakhsk. n.-i. in-ta mineral'n. syr1ya", no. 5,1961, 269 -
274)
TEXT: The possibility of extracting So from slags of Fe-W production was
inves%ated. Up to 85% so can be extracted into solution from a slag ground by
80% to 200 when decomposing the slag with 18% 11C1 solution, the temperature
80 - 90OC; the relation liquid phase-: solid phase - 4.; 1. Prom the solution
obtained So can be precipitated sufficiently fully by means of Na~SV6 .' Silico-
fluoride precipitate, after being hydrated with 40% NaOH, contains 6 - 8% SC20
To extract So from beryl the calcium sulfate method of processing was used. Afier
melting beryl, sulfating and lixiviating the melt, a solution was obtained con-
taining r~25 g/l BeO, 36 g/1 A1203 and -90 mg1l Sc~03 The losses of Be with
Card 1/2

On the possibility of...
S/137/62/000/007/009/072
A052/A101
alumoammonia alum precipitated from the solution are -5%. After evaporating the
solution, BeS04 crystallizes out and So and Fe remain in the solution. When pre-
cipitating Fe(OH) with the excess of 40 NaOH a co-precipitation of So takes
place. The obta&d Fe precipitate contains when completely extracted
1-9% S0203
A.rom the solution. So can be separated from Fe by precipitating oxalates in the
presence of a large amount of Ca.
[Abstracter's notes Complete translation]
L. Voroblyeva
Card 2,/2

r
7
ACCESSION NR*. ARW15659 S/0081/63/000/021/0318/0318
s.-2103
'SOURCE: RZh. KhImlya, Ab
AUTHOR: Nikiforova, G.A.; Favorskays, L. V.; Ponomarev, V. 0.
TITLE: Precipitation of sc4ndlum with sodium fluosillcate
CITED SOURCE: Tro Kazakhsk. n.-I* In-ta mineralln. sy*rlya, VY*0- 7. 1962,
253-257
16;;~ TOPIC TAGS: scandlum, sodium fluosilicate, scandlum fluoride, scandium precipl-
tation, sodium fluoscandate
ASSTRAM A mixture of scandium fluoride and sodium h*xafluoscandate forms during!
the sodium fluosilicate precipitation of scandlum from chloride solutions.- The
scandium fluoride content In the precipitate Increases as heating Is prolonged
'-and after 4.)wwrs of heating the precipitate eantains only scandlum fluorldee
13ibi. with 11 references* Authors' summary.
DATE ACQ: ogoec63 SUB COOE: CH ENCL: 00
Card 1/1

ACCESSION NR; AR4015658 s/oo8l/63/000/021/0318/0318
SOURCE: RM Khimlya, Abs. 2IL42
AUTHOR: Nikiforova, G. A.; Favorsk
V.; Ponomarev, V. D.
TITLE: Coprecipitation of scandlum with calcium from synthetic solutions under
the influence of sodium fluosillcate
CITED SOURCE: Tr. Kazakhsk. n.-T. in-ta mineralln. sy*rlya, vy*P. 7, 1962,
258-265
TOPIC TAGS: scandium, calcium, sodium fluosilicate, scandium-calcium coprecipi-
tation, miscibility threshold, abnormal mixed crystal, dispersion factor, scandium
fluosilicate, calcium fluosilicate
ABSTRACT: This study concerned the codeposition of small amounts of Sc and Ca
during their precipitation from chloride solutions In the presence of sodium
fluosilicate. it was established that a definite miscibility threshold is 0
served during the coprecipitation. The solid phase Ca:Sc ratio of 1:1.5*10- re-
mains constant when the concentration of components in the solution is varied
prior to precipitation. This definitely indicates the formation of abnormal mix-
ed crystals of Ca and Sc fluorides. Diagrams of the coprecipitation of 5c and Ca
Card 1/2

ACCESSION NR; AR4015658
at constant initial concentrations of one component and variable concentr4tions
of the other are characteristic of solid solutions, the latter being represented
In some cases by abnormal mixed crystals.' The dispersion factor decreases as the
concentration of one component (Ca) in the Initial solution lessons, tending to
zero values. This attests to the existence of a minimum miscibility threshold
which is characteristic for the formation of abnormal mixed crystals. Bibl. with:
10 references. Authors' summary.
nATF AM- AQI)pr(%l RIJR Mngs tH FNCL! CO

S/137/63/000/001/004/019
A0061AI01
AUTHORS: Favorskaya, L. V., Nikiforova, G.A.
TITLE: Side extraction of soandium from beryllium
PERIODICAL: Referativnyy zhurnal, Metallurgiya, no. 1, 1963, 19, abstract 10123
("Tr. Kazakhsk. n.-i. in-ta mineral'n. syrlya", 1961, no. 6,
239 - 243)
TEXT: The initial material was a ferrous product, obtained during the
,ajddjjj_Fig of beryllium and containing 0.04% S0203. A 1 g batch of the product
was -;FM-lved in a least HC1 amount with preheating to 900C. The insoluble pre-
cipitate was filtrated-off, and CaC12 was added as a precipitating agent. Prior
to the :Vecipitation of oxalates the solutions were neutralized with ammonia.
The t~*Mtes were precipitated by solid oxalic acid at pH 2.5 - 3.0, 700C, and
stirring during 15 minutes. The oxalates were allowed to settle for 24 hours
and were then filtrated. The washed precipitate was dried and roasted at 7000C
for I 9T-Pir. The oxides obtained were dissolved in HCl for refining from Ca and
Mg,1ML.Mxides were precipitated from the chloride solutions by ammonia, dried
Card 1/2,
7- 11
Y

S/137/63/000/001/004/019
Side extraction of scandium from beryllium Aoo6/Alol
and roasted at 7000C. The optimum amount of the precipitating agent is 2 g Ca%
per 1 g ferrous product. The extraction of So is then 86%. To refine the So
product from Fe salts, it waa dissolved in HCI, and oxalates were again preci-
pitated from the solution. The product obtained after roasting the oxalates con-
tained 98% S0203- The extraction of So from the ferrous oake into the final
product was 78.6%.
0. Svodtseva
(Abstracter's note: Complete translation]
Card 2/2

ROMANOVA, A.D.; f&XQI~SKAXA, L.V.; PONOIIAREV, V.D.
Use of infrared spectroscopy in studying the extraction mechanism
of scandium with tributyl phosphates. Izv. AN Kazakh. SSR. Ser.
tekh. i khim. nauk no.2t68-74 163. (MIRA 17t2)

ROMANOVA, A.D.; FAVORSKATAO L.V.; PONOMAREV, V.D.
Composition of the complexes of hydrachlWic acid and scanditm
extrRated with tributyl phosphate. Izv. AN Kazakh. SSR. Ser.tekh.
i khim.nauk no.3t49-55 164. (MIRA 17:2)
".A
I

NIKIFOROVA, G.A.; FAVORSKAYA, L.V.; FONOMAR~'V, V.D.
Goprecipitation of scandium and aluminwri under the effect on their
solutions of sodium silleofluoride. Trudy Inst. met. i ob _. All
Kazakh. SSR 9:85-89 164. 170)

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FAVORSKAYA, Ef. A. PA 29/49T36
/900
Tectonics
"Ike Geologic Situation bf the Upper Memozoic and
Cenozoic Magmatio Formations in the Soutbbrn Maritime
Area," M. A. Fav orakaya., 6 pp
_"1z Ak frauk SSSR, gar Geol" No1
Studies recent development of volcanism. in the Boutb,-,.
arn-maritime area, with partloulkr attention to the
exiens Ivu spread of multistage intrusive fornations in
this region.
1D. 29J491-36

/Oct
Clinkers
"Tertiary Tuffaceous Clinkers of Southern Primorskiy
fl=71- M. A. Favorskaya) 4 pp
1z Ak Rank SSSB, Ser Geol" No,
Ipubject tuffacsom clinkers (tufolavy) date to Faleo-
~;'#ene in age and lie oneroded surfact of TJpper
:'Cretaceous and Lovvir Tertiary effusives and grani-
t
oids breaching'th6se effusives' Primorskiy uffav
ieous clinker Is closest in cbemical cOMposition
:~.'~o the red vairiity (others are black and yellov) of
'4rmenian tuffaccous clinkers.
.3/5OT37

LA
A-
Akoi.
Nook U.S.S.R., S&. Gaw7wo. fMkUm- -Data
a" for the cbem. owspo. of vffusion cwnpltxes
#m = mu~ chometerjok of nch wage of devriop-

my ran.
'n'4
ldo4s",Vbwns at tho cad
I Ufr
AUAIVW4

FAVORSIAU, N.A.
Role of processes of cont"Ination and metasomation in the formation of
Tertiary wasoultic Intrusions of various regions of the Far ftst* Trudy
Inst.geol.mank 146:92-111 153 MIA 6M)
(Par 2"t-looks. igneous) (looks. Igmeoun-Far Iket)

. FAVORSKAYA.M.A.
Relation of tin mineralization to magmatism. Izv.AN SSSR. Ser.
geol. 20 uo.4:20-30 Jl-Ag '55- (MIRA 8: 10)
(Tin ores)

FAYCRSKAYA, N.A._ ---
Some secondary changes In acidic offuslons in the @authors FAwItIw
Territory. Im.AN 8381. Ser.geol. 21 no-7-'~'i-78 JI 156,,
(MZRA 9: 10)
1. Institut geologil rudmrkh sestorothdonly, petrografil, Uineralogil
I gookhtell Akadoull nauk SSSR, Moskva,
(Maritime Twritary-Racke. Igneous)

YL
'~ VIAN'M,
C52-rif -0-MIA ~Br-
WCei ~ ", - -1 .11 NO MR- ~=-. MN�l

AUTHOR: None given 5-3-12/37
TITLE: Chronicle of the Petrographic Section (Khronika petrografi-
cheskoy sektaii)
PERIODICAL: Byulleten' Moskovskogo Obshchestva Ispytateley P -rirody, Otdel
Geologicheskiy, 1957, No 3, PP 157-158 (USSR)
ABSTRACT: The following reports were delivered at ameeting of the Petro-
graphic Section of the Moscow Society of Naturalists during
the period from 7 February to 28 March 1957: T.V. Molihanova
reviewed the book by Van-Bemmelen "Geology of Indonesig; S.F.
Gavrilova reviewed a number of publications by Soviet and
foreign scientists on contact metamorphism; *M.A. Favorskaya
on "Petrography of Eruptive Rocks in PolymetaT D-e-p-od-1-ts-6f
Mexico"; Ye.A. Kuznetsov on some foreign publications of 1956
about African carbonatites; Ye.M. Epshteyn on "Province of
Ultrabasic Rocks in the Northern Part of the Siberian Plateau";
A.D. Rakcheyev on "Some Weak Points of Metamorphism Hypo-
thesis", and L..A....Milo,~anov reviewed 14 articles published
In Nos.- 9 and 10 of tlki 63-lection of LIVOT Mineral6gical sociww for
AVAILABLEs Library of Congress
Card 1/1

IrAVORSKAYA, K.A.
~ob I=of -the origin of dike@ and their relation to the process of
ore formation. ISY.AN SSSI.Ser.gool. 22 no.1:4-10 Ja 157.
(MIRL 10;3)
1. Inatitut geologit ruduykh mestoroVdanty, petrografti, mineralogii
i gookhtaii AN SSSR, Moskva.
(Dikes (Geology)) (Ore deposits)

TSINZERLING, Te.V.
Metamorphism of quartz from an ore vein on contaot with a porphyrite
dike. Zap. Voss. min. ob-,wa 86 no.4:4ffi-495 '57. (MIRA 11:1)
1.Institut geologli rudnykh mostorozhdaniy, petrografii. minor&-
logii i gookhiall I Inatit'ut kristallografii AN SSSR. Moskva.
(Itocks, Crrstalline and metamorphic)

FAVORSKATA, M.A.
Development Of Young volcannea In tho Sikhotfi-hlinl Hariga. Trudy Lab,
vulk. no-13:233z242 158. (MIRA 12:3)
Sikhote-Alln' Range--Vol.canoes)

FAVORSKATA. M.A.
Association of the rare metal and complex mineralization with
intrusives and effueives in cert4ln areas of the Pacific ore
belt. Sov.geol. 2 no.12:71-87 D '59. (MIRA 13:5)
1. Institut geologii rudnykh mestorozhdenty, petrografii,
mineralogii i geokhimli.
(Soviet Far Xnot--Ore deposits)

FAVOR-SKAYA, M. A -
"New Data on the Relationship Fetween Magnatism and Mineralization in
the Pacific Ocean Ore BeltN
report presented at the Firs4w, All-Union Gonference on the Geology and
Metallurgy of the Pacific Ocean Ore Belt, Vladivostok, 2 October 1960
So: Geologiya Rudnykh Hestorozhdeniy. No. 1, 1961, pages 119-127

AFARAWYEV, G.D.; APANABOYEV, L.M.; BELIXOT, B.P.; KOPTEY-
DVCRUIXOT, V.S.; MIMYLOT, IT.A.; MONICH, T.K.;_.jtATCRSKAYA,
HLA-.-, -prinimall uchastiyal DISTANOTA, A.H.; YgIh~~~
NARMIN.,A.S.; YMKOVSKATA. Yu.V.; USTIM , U.K., doktor
geolwmin. neuk, otv. red.; HEMANOVA, G.P., red. isd-va; BYKO-
Up Y.Yes tekhn. red#
[Principles of the geological mapping of intrusive and extruaive
formations as'exemplified by petrogra*phio studies in Kazakhstan,,
Transbalkalls, the Northern.Cauessua, and Maritime Provir-cal
Printsipy goologicheskogo kgrtirovaniia intruzivnykh i effusiv-
nykh formsteii na primers yetrogrefichoskikh issledovenil So--
vernogo Kovkaza, K82akhatens, Zabaikollis i Primort-'a. Moskva,
Goo.nauchno-takhn. izd-vo lit-ry po,geol.i okhrane nedr, 1960.
341 p. (MIRA 14:5)
1. Akedemiyi nauk SSSR. Institut geologii rudnykh meatorozhdonly,
petrografii, mineralogii i-gookhimii. 2. Sotriidnik Institute geolo~-
gichaskikh nauk AN Kas."d~R (for konich). 3. Sotrudnik Vaeaoyuzno-
go goologichaskogO Institute ( for Mikhaylov) 4. Sot'rudniki
Moskovakogo goeUdaratvannogo universitsits (for YunkQvukay*r Dista-
nova)
(Rocks. Igneous)

AFAHASIUM, G.D., otv.red.; USTIYSV, Ye.X-.q doktor geol.-min.nauk, red.;
GAPMVA, G.M., doktor geol.-min.nsuk, red.; KOPTEV-DVORNIKOV,
V.S., doktor geol.-min.nauk, red.I.LNBZW. A.P., doktor geol.-
min.nauk, red,, FAVORSKAYA, K.A.o do'ktor gool.-min.nauk, red.;
CHMPIKOVA, I.K., red.izd-ye; DOROUIM, I.N., takhn.red.
(Petrographic provinces, igneous and metamorphic rocks] Fetro-
graficheskie provintaii, izvershenn" i metamorficheakis gorays
porody. Koskva, Izd-vo Akad.nauk SSSR, 1960. 343 P. (Doklady
sovetskikh geologov. Problems 13), (KIRA 13:9)
1. International Geological Congresw* 21st, Copenhagen, 1960.
2. Chlen-korrespondent AN WSR (for AtEnselyev).
(petrography)

Ai SEE f:4$ IR11 F I
AN
17 R
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oo
0,
A,
P;ri
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4, W...
UF F I?
g - V4 -
3~ n.. h
Up 1 "R
n
k ~2~*g ply;; 1
9 c
g6

PAVOWUTA g X.; XIGAT, T.
on volcanology.
no.4:130-132 Ap 160.
(Volcanoes)
Uv. AN SSSR. Sw. geol. 25
(MIRA 13:11)

~A-14*~Aq RUB# M.Ge; KIGAY, V.A.; IZOKH, 9,.P.; GAPEMAI G.14.;
PREOWZHFIISKAYA,, G.K.; USTIMp YO.K., doktor geol. -mineral. nauk,
otv.red.; ROZANOV$ Yu.Ap rpd.izd-va; ULYANOVA, O.G... t6khmi-ed.
[Magmatic activity and metallogenio features of the Sikhote-Altnt
Range and the Lake Khanka region] Nagmatizm 81khote-Alinia I Prikkan-
kaiskogo ralona i ago metallogenicheskie osobennosti. Moskva, lad-vo
Akad. na:4 SSSR.. 1961. 3Z7 po (Akademiia nauk SSSR. Institut geologii
ruftykh mestorozhdenlip petrografiip mineralogii i geok~imii. Trudyp
no.45). (Sikhote-Alin' Hange-Rockep Igneous) (KnU 15:3)
(Mmuka, Uke region-Rocks, Iienous)

BURIYANOVAJ I.%.: FAVORSKAYA, M.A.
Origin of pi3low lavas in the southern Range.
Izv.AN SSSR Ser.geoL,26 no.12-3-12- D 16-11. (,:IIU 1].- 12)
1. Institut geologii rudnykh mestorozhdoniyt petrografli,
mineralogii i geokhimii AN SSSR, Mosk7a.
(Sikhote-Aling Range-lava)

VOLCUMNAYA., I.K.; mwww~ KAU. M.A., FRIMI-JaM. D.I.
Petrographic and goomorphologic otudies of Cenozoic effusives carried out
in a region of Kawhatka. Sov.geol, 6 nol2t91-109 F 163, (KUU 1614)
lo Institut geologii. rudnykh mesVrozhdeniy, petrogxafii, mineralogii
I geokhimii.
(Nawhatka--Petrology) (Kamchatka-Geomorphology)

FROKHOROV, Kirill Valentinovich; FAVORSKAYA, M.A., doktor geol.-
min, nauk, otv* redo ----
(Tertiary granitoids of Kamchatka) Tretichnye granitoidy
Kamchatki. Moskva, Izd-vo "Nauka," 1964. 132 p.
(MIRA 17:5)

eks~irfir f5viilk ; ll'AV~'-,,~M!'f'A jC~.-., ~. ;-~ , k ~. -:'
[Irneons activJty of the Te!,yukhe region (southern
Marit,line Territory) anti the cbiraclter~stlcs cr tlle
developm.ent of some volefinr-plutonic fo-mationi
MatIm TetlukhInskogo rnAona (AzImot) F.-Imorle)
zakonomernostl ravAtila nukotorykh vulkano-plutcni-
che.-flkikh formatsil. Moqkvat Nauk:t, P65. 2i0

SHATALOVY Ye.T.; KOPTEV-DVORIIIKOV, V.S.; RUB, M.G.j RODIMIOV, D.A.;
SHIPULIN, F.K.; FAVORSKAYA, M.A
[Criteria of the relationship between mineralization and
igneous activity as applied to the study of ore regions;
basic principles of metallogenetic studies and the plot-
ting of metallogenetic and forecasting maps of ore deposits]
Kriterii sviazi orudeneniia a magmatizmom primenitellno k
izucheniiu rudnykh raionov; osnovnye printsipy metallogeni-
cheskikh issledovanii i Bostavleniia metallogenicheskikh i
prognoznykh kart rudnykh raionov. Moskva, Nedra 1965.
292 p. IRA 18:4)

VOLMON,. Fol.1 FAVCROFAYAp MA9
In somwy of Acedudelm Swaoi Sorgooviah ftirwvo Iwo
All SWP.# Ott* oool* 30 U06 1013-14 0 06% (IMA l8t32)

ACC NRt Ulfl6offNT0001664~161W 166
AF6ol8685 SOURCE CODEi
AWHORt Daskina# Ve A@,, Favorskaya, Me As
ORGt none
TITIEt Conference on use of mathematical methods and electronic computers In geology
SOURCE: AN SSSR. Izvestlyas Serlya geologichookaya, no* 4, 1966, 156-160
TOPIC TAGS: electronic computer, geologic conference, riathematic model, vineralogyp.
geocherdstry, geomorphology, paleontology, stratigraphy
ABSTRACTi, A conference on the use of mathematical methods an.d electronic-.
computers In- g - o was
I ference operated in nine sections:
a lithology,,
petrography and mineralogy# geochemistryy structural geology,, industrial
,geophysics, geology and prospecting, hydrogeology and engineering geo-
:1ogy, geomorpholog)r., prospecting methods, formal geological theories,
:paleontology'and stratigraphy* A total of 115 reports were presentedl
chairman of the conference was So 3$ Mind& Corresponding Member of
the Academy'of Sciencese The -principal problem's discussed were: Us;
of mathematics in the problem of geological time* Mathematical approach
!to certain genetic problems# Including the dietribution, of minerals*
Opological mappinitand methods forcompiling geological maps* Computa-
Card 1/2 UDCt 006.Q 512.244-6.81#142.--351*114k

L 29114-66
ACC NR. AP6018685
tions, of reserves of mineralse Methods t6r identification of samples by
electronic computers., Collection and storage of data* Organization and
'planning of use of mathematical methods and use of computers. A few of
.the reports presented at each of the section meetings are summarized*
,at the institutes of the Academy of Sciences and at the Miftist!Z of
Geology and Conservation of Mineral Reammese The remFolutlons adoPEid--
a siaWr cogefWW 1"&rW'j&6-biWjffgely ignored. .7he neXt
LUI-Union Conference on thie problem will-be-held in 1966.," fJ-PRJS
SUB CODEt 08, 12 SUEM DATE-i none
:It was noted that inadequate attention is'being given to such problems

ZAKORINA, NOA.1 LAZEMA; 0.8-.1 PETROV A.A.; SKVORTSOVAO G.V.; FAVORSKAY P.
L.- -
Various setups f4r-tbe spectral-Inotopic determination of gas a in metals.
e
Vent. LOU 20 no.lbrl,32 #65o (MRA 18s7)

21(4) SOV/ 112-59-2-3388
TranBlation from: Referativnyy zhurnal. Elektrotekhnika, 1959, Nr 2, p 166 (USSR)
AUTHOR: Rozen, 0., Sukhova, L., Kheyker, D., and Favorskaya, N.
TITLE: Using Radioactive Isotopes for Quality Control Of Roll -Strip iZterials
(Primeneniye radioaktivnykh izotopov dlya kontrolya kachestva rulonnykh
materialov)
PERIODICAL: Stroit. materialy, 1958,'/Nr 3, pp 34-35
ABSTRACT: VNIIAsbeettmement has used methods which permit continuously
controlling average weight and thickness of. a moving cardboard or pergamin
strip and, consequently, its density or porosity. The weight has been
determined by a contactless instrument designed by A. N. Slatinskiy (its
scheme is presented) which depends on absorption of beta-rays by the material;
TeZ04 is used as a source, an ionization chamber as a detector. The strip
thickness is determined by an inductance primary element. The strip passes
between two rolls, one of which is movable; the latter is displaced by thickness
Card 1/2

SOVI 112-59-2-3388
Using Radioactive Isotopes for Quality Control of Roll-Strip Materials
variations and moves a primary-element core; this results in an output voltage
across the primary element which linearly depends on the displacement value.
The contactless weight -determining instrument is calibrated by cigarette-
paper standards in the range of 220-970 g/m2. A table giving the instrument
checking data and a plot of porosity against water absorption in per cent are
presented. This outfit for continuous material -porosity control is being
adopted at the Leningrad "Kartontol' " and Odessa Roofing-Felt Factories.
Two illustrations.
M. L. G.
Card 212

~Aecd:Pwa d mobi&* in Oup. Ill. Reductive
daitlaga d of Gkittale,
Terent'ev. and N.
['A tg&j),, d. C-A. Its, 695oh - ......
C. Zn dust wd 4 c. NMCI with ~ irtv IL,- i z) ;u min.
C-470 a ClistiLlate of &3,*tj crude jkatoir, ru. oi i . I u tj g,
9MAnind 10 160 Ull, MCOU twas mfdcti 20 g. N;LOJ I in I(A)
Mt. HSO. the Wis. heattril to 1J.P. and trvll,,i sh"lly ~ifll 10
C. Zadwt over 2his. Aflcr licating 12 In ~ ~m a jicatu txAth
with stkring, the McOl-i w4s diad. itud ilic It
StOM dIltd., yiMing WVV crude ikalt4t; pits v

ISAGULYMOS, V.I.; TISHKOVA, V.N.; IPAVORSYAYA, N.A.; OGANUSYAH, R-0-
Substituted hindered phenole and their use as antioxidante for
petroleum products. Trudy NMI no-23!42-61 158. (MIRA 12:1)
(Phenols) (Alkylation) (Petroleum products-Additi4es)
~Y,
I

ISAGULIANTS, V.I. (Leningrad); TISHKOVA, T.N. (Leningrad); IPAVMSrAYA, N.A.
(Leningrad); OGMSIAN. RoO* (4ulagrad)
Sabstituted shadod phenols and their use as antioxidant additives
of mineral oil products. Tr, from the *meian. Xem.tud.kosl.NTA 12
no.4-.363-381 159. rll_ (MUI 9: 4)
1. Lenlogradl Tudomanyoffetes.
(Phenole) (Mineral oils)

30650
S/081/61/000/020/085/089
B11O/B147
AUTHORS: Isagulyants, V. I., Tishkova, V. N. ; _jgjgxsk&ya.,_ _N.A.
TITLE: Synthesis of mineral-oil and motor-fuel additives on the
basis of substituted phenols
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 20, 1961, 410-411,
abstract 20U160 ([Tr.] Groznensk. neft. in-t, ab. 23,
ig6o, 132-136)
TEXT: Schemes for the synthesis of multifunctional additives of the
following types are givent metallic salts of sulfides and disulfides of
alkyl phenolol metallic salts of diether dithiophosphoric acids, whose
ether groups were obtained from disulfides of alkyl phenols; dialkyl
amino salts of diether dithiophosphorio acids, whose other groups were
obtained from disulfides of alkyl phenolal Ca and Ba phenolates obtained
by chloromethylation of the condensation products of alkyl phenole with
CH20, by reaction of the chloromethylated products with metallic salts of
diether dithiophosphoric acids, and by subsequent treatment with C&(OH )2
Card 1/2

30650
S/08 61/000/020/085/089
Synthesis of mineral-oil and... B1 10XB147
or Ba(OH) 2- A new method was worked out for synthesizing the oxidation-
inhibiting additive 2,6-di-tert-butyl-4-meth 1 phenol (I) by alkylation. of
dicresol (mixture of p-oresole and m-cresols~ with the butane-butylene
fraction in the presence of H2so 4* By treatment with aqueous alkali in
the presence of a solvent, the alkylate 15 separated into a solution of I
in the solvent and into an aqueous alkaline solution which contains other
alkylation products of dicresol. The periods for which sthylated
gasoline with an addition of I and some of its synthesized homologs
remain stable are indicatedo (Abstracter's note: Complete translation.]
Card 2/2

ISAGULIANTS, V.I.; FAVORSKAYA, N.A.
Synthesis of new antioxidant additives. Trudy MINMiGP no,28:
56-67 '60. (MIRA 1414)
(Antioxidants)

365La
s/o8y62/000/006/074/117
B149 B1 08
L) 1 -12.,
AUTHORBs Isagulyants, V. 1.
TITLE: Synthesis of now antioxidant additives of the screoned phenol
type
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 6, 1962, 535, abstract
6i213 (Sb. "Prisadki k maslam i toplivam", M., Gostoptekhiz-
dat, 1961, 94 - 102)
TEXT:' The additives 2,21-methylene-bis-(6-tort-butYl-4-mothylphenol) (Ij
disulfide-4,6-ditert-butyl-3-mot Ipbenol (II), and 2,21-mathylone-bis-
(4,6-ditert-butyl-3!~-mathylphonolr (III) were synthesized and 6tudied.
The methods worked out for the preparation of (II) and (III) permit the
use of*the by-product in the preparation of ionol (4,6-di-tert-butyl-3-
methylphenol). As antioxidant additive, (I) added in the amount of 0.0%
to ethylated'benzine is more effective than ionol; (II) adde in the
amount of 0.005% to synthol (a motor fuel fraction 150 - 220 9C, containing
8~4 of unsaturated hydrocarbons) has the sarte effectiveness as ionol. The
effectiveness of (II) in the test with transformer oil is next to that of
Card 1/2

S/081/62/000/006/074/117
Synthesis of new ... B149/B108
ionol. As an additive (0 005%) to synthol, (III) is also next to ionol.
However, a test of (111) 6% added) with transformer oil gave negative
results. [Abstracter's note: Complete'translation.j '
Card 2/2

ISAGULYANTS, V.I.J FAVORSKAYA, N.A,; TISHK(YVA, V.N.
Syntheols of 2j 6-di-tort-buty3~-4,.-nethylphonol. Zhur.prikl.khis.
34 no&3:693-04 Mr 161. (MIRA 14:5)
(Cremol)
gmig

FAVORSKAYA T A - TOLSTOPYATOV, G.M.; GALIDING, 14.11.
- 11
-
Synthesis and study of the transformations of acetylenic
c4-glycols. Part 9: Molecular rearrangements observed in -
the reactions of 3,4-dimethyl-l-hexyne-3,4-diol with
hydrochloric acid. Zhur. ob. khtm. 35 no.4:593-597 Ap 165.
(MIRA 18: 5)
1. Leningradskiy gosudarstvennyy universitet.

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o
. 4
.
-
.
,
33. Rj8l1~CIC11:C:CM" on 1142fing with Iftil at"I
0 3
MOO
CaM IQ FW is k9onlefixed to C1liCC%Ir.CI and CICII
:

d
0 clicAfe:cff.. with simultaneous funuatkM (A propyne.
Clip-CIICI, SfejC:ClfCllO and a diinrric ronilml. C,gllit-
00.3
Ch. Ito 103-P. Ill.' 1.44157. Corrinidr flervitil too
0OW
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AI
IIII CLASWICATI" see
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TALLUACKAL LITIN

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FAVORST,kYA, T. A.
"Research In the Field of Molecular Transpoeltions in the Unsaturated Aliphatic Halogen
Derivatives - The Action of Hydrochloric Acid on Dimethyl Acetylenyl Carbinol in the
Presence of Ammonium Chloride and CuDrIc Chloride or CuDrous Chloride." Muir. Obahch.
KhIm., 9, 110- 5, 1939. Laboratory oi Organic Chemistry', Sclentific-Research Chemical
Institute, Leningrad State University. Received 30 May 1938.
Report U-1517, 22 Oct 1951

4-0 WIN t OWWWW'so-W~-_6
0 6 0 0 0 0 0 0 0 0 4 000000000f0
. - - ~~;- two ii~40 00 Ito
ro
V FOY ~ .1
f # I 1 0 it to is W is to it lot$ 101#11 APS)IIIIII 11 u as 4 b V 0 61 a it 41 1 0
06 AI A a 1, a A. I_ 1--L. 1, 1 - &A Ill QC 111? U I
A tit P-* O&I'lat so
to a 111 00
00 butyurdial h al"14 fnrmr-f, Ulwn 1 ra,~-14 with MI, -00
0 either n1swar or in the prr~iarr of OW1 anol NII.Cl. it
loan compounds Ill. The siattlest of bordleimark &a. f4mv 'Or" I~Aoi-y .41 ..... I-jaeftivote fit". 1-;. 71 01% .00
6 00 mothyttilkYlethYnykatbiad is So P9900CO of IN11101141- 1. .1,1 1 AIR. -00
00 sium chloride and cuprous ckloodda. T.A.Fatwra and
1 446- as a cAtalyst. a mht.,J It And 3~lhyl
111r
A, 1. Zakh4rovs. J. Gf it, C".
00 tC(011).' dirne (MI. bj. M 81. it,., a wr2w, W.- OACIZI, at'. .41116
t
11 CX11 is all.m,-d w o4nd Im 4 bes. with 17#0 cc. nwwdf' O.WAC, a." ' I-MUd. 1.4"Wil. Sill,. 39.10. %tRj
60 C -40
110. fit K. 010 wu# A a. NJI.Cf. It giveto a "lilt. tit Wfz rhe'laut. ad III irk thr litill. Oz6atully
I.--- 4A %it'. Jr 11.9141. a*.* uttledlRel With 11111V 44 0111111S. Wt 9~1- It UtAl. 'A 2.10 .00
:0 t.42M3, AIR 33-M. isrut 114 it. I-clalanti'l-Itarthyl-1.1.1. W"'D W11"'11 k. 11"i if th. -I%I, i. All"d 111'"r ~40
00 J; pentadiroir (W 741",dis O.O.W. a" 1AW. )Ak tismajObloo. lliso"111V ...Ikvtt.j tolff w1wil It 14011110
%tand a m:;that with CtIC1 "i'll lfCj NMI OICI.N11.0. bilt it She ]let I. Absent. too 0:
34.44. Whtn I is alloorrst in
00 0: 1~ 11110
Nif.Cl 4041 d troor (Iftnn lit #10. It is coorrtledl In I'm HI A I t1j"111r% &k W
W4. never tolvil9s.
00 j! &1-1% air ON Wtok-h i%(firtSLWCAIAIY%I. ago
U."1.47714.%IR34.40. This reacts with titalele anhydride
are all fulach slowar that) 1h.- .4 the t1a#jTSfkXWjjI1j do
o: to give a mitt. from whk-h, after hydrolysis. 2 wools. In. Stedcriv%. UcA3dy1orsllC1tuft~t1T1
W 218-20' and 350-1', am obtained. All thew teactiom
we Analogous to thaw of %fcCCICICII, but So more yose (IV). lhw4l-3*. it.' 0.77M. 46 1.43062. sobs 1.45=4,
00 Afils,31.7,16IRs.32.0. SoonelVisalwasysfocanctildwins
slowly. TV. The action of hydrechloork acid am alltyt-
0 asthysyscartainot in the tifteemet at cuponow Copric itar"nerisatiort of U to 111. When IV is hydra". it forms
1.09 &j~CII.CFkCO%lr sohio-h tracts with -.00
"IF ChIladde And ammonium chloride. T. A. Fava key* and Ito give a IlytaI44.1hor, all. ltj~l W. Ity'Itolm.4 It with an .06
1. A. FavtwikAya i Ibid. 451 Oo.-Ht,Co and Call, in the
WI P".3cocar of Pootell. Koll give ",D-*)% PtC(011)CiCII _q. ANIJIV. IA111111 '00
01. U1 is bydrWy" usaal,r I" cooditialm. it isamrfius to
IM-7'. it',- 0.9749. d.-6 OXM, 41'. O.K1W. W1 which then forms I and IV. V. Reacticana of dime"- logo
t.4.w. .,*,* 1.4407. MR. M.M. NiRs 31.01; ph.;.
01 00
saa,,tkiar, its. A-1 3'. At (lit, j4jojr litste. 1I1% lrfjr*ctbyl S
be 0
too
.141. 0:
0, fioi` - &JMU - _.. , -
too
I V Irk AM I I I aw 0'-m a I V-
-10 W to it do is a it o1 11 a of n 49 of to A 1 14 044 i~
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00
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1'. A. Fairmshays. /hoot. o1 7-
oleo (011)CICII WW Hur formort, no noalftj jo~ th,
00 vwkd The only pit-dont is 3-floorthyl.l.
*0 (3). 1%# d." 1.3141). 41.11. 131110.
it: 1141m. no- '-was, slu m.m. 'nsm ihr
Stwo 1.411ifly al"I "MAI'W'j, J" Iloor 1111141 1111"1111%
t4 IpAtis thowtils thr wrirt lot 110orromoliair
00 USIVIV Ow md"w romillods. 441talnell fridel thr 411hwhic,
00 Whrol III In it'", tow I"ImIllorl is a ljljll~l' lb,p 4% it'. will.-Is
vrfy camilly and calltalt lw wt%l. 1-1, Itioll. III
0111110 "WAlk.41 1.1'.1111cloo Imik-air that it is a 11161. A %1..C -
v cill allot c1lo'chlrell ellL It. 91.
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tb. 4-16 Offiks III,=
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004 UM a ndw am. of mm, 1 in" 00 &b,"
ode IJIM41.17490
wbighb c :c
IF cc CH: 10cm- 4
www Pam sw a h".
ITM, -ccm.": 10CHIVRIM"
60COM. bw 704-1.86,
*IAIM
bw IN40. dr WN14. 1.47M.
0 KOOOkpof
jo;W 77
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,
I.SIML TIND'at
400
40: lk*- TU IMMOCC of the Wkw dedy. wu cmArmW to -600

00 remk Ifto himmewimstim of the *thy" conipd. by p"p-
'
k
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J"
14-SLA MITALWOCAL WflAlbef CLASSOKAIM" ~rr 1-M, be
I ac" Ift1mv
C., Oft 814131 dw 4" Isl
U a AV *3 At .. . . . . - I I- I I I I " . I -. Z- IA A % a lid
al.m. man tc fg k" a I
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a F v 33 It x b v a v 9
40 POCIP11411411 wilts
Of AY*AdC Marks. VU. Rol
with bv*odderk
A St. 4047 30 14
Sat 43 W30911)).
Old -1, d:
I'dr,0.. OiR - OAM,
mtWort Pvt. binild" tho
jta~lo
CJU' a Una sat. cd NMI
Do
pend to aCWhoOts bts 134-7 '. 410 1 AAW, ar
AA1473, 1.4016C "' roaked froo 2 1 of
12"120wha hr. I IIWW wftk conco, 110 or wffh
In Viv
to retan sal up to 701% U. b. 1314"',
Iowa
dills" *Alt. OW OJIU, 0,1" 14440, nj'*' LON14,
on iiWif wood. MCI also gsve rbe to a smo amt. of*
dk64iWi,' d.14-4 IM147. al."
I-4MW,"-U as baling wft 10% K~M revoltived W7w
"a' Ibe chlorkk. "Solired b
=ww*="w..Ohd by fc"rau at.
Geri. 0-69-6
. 00
lee
lee
lee
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it 11 V u It a Is 0 a U, 4 6.
a ~1,s Is n

.
A-M r.
? L Q are
,.o "V 0
ii
so

rilbably a inellivirthilafliticlarbitmil
h w
hi
A
/10 _69
i
r ICON liftivatives of Otho"k b Wkj" c
as p
I. W
C-Ulu, 1 (111411 tile K %1"04 freatillent); the 141,19
Matiml
�Odwivativ"oidmpiodpolymetbyworil4p. 1. P rep: "
P
cubjual. b. mu', tannut be set.l. froin I byimple diiin.

: it. T ~A~
-do of &0 Il -boiling by-product. be
Synthesis ol I atto gave a high
hi
( d State truly.). J. Gto. C". ( . . --
17. 841-9(1947)(in Russian).- In an e I m of em , s nut-
83% whk-h gim Axl imi Irralintrit aith AIN(h; t
terial.d: I.3-M4,J.1* -1:' I.W.17. **.' I eAlivC.
'
,
09 a work to sianple ring rusuplit. (C.A. 46, a study W" 1l,. "hich it
1 ,mur). it I
1.:aw. .11
UNKIII, Ili A"IA*AYA"lOjWOPYAAd4fbimOl j contallailulM %tit% tilutil 411111. .4 t1h.
of Himill on "Mylifillirthylelle Pvt tiled.,mr, 11411 'Itel-Illoilly .,I
.00
elf lim wm rimle by 1115111. over Koff Inthl I by t i fillW64"I elf lite i4mlide stilh Klifill I, ItAw VINIXI I "he#$
Milk KMQO.. rAlre i. h. 14l."', 4 0 0.
111%
the Milo, prit. wt. rtid. With FI,' 1; alwo tile Nbs(h w4-
800

j
0
0
11
1 1.4300. Thir by-pe-luett of fortuatiin of I a'.
IM11W Willi wairt lite nelstral rr-Ollet w:&, 1. 44

zoo
go ;79 timurtial 4SIK"I. 'd tile hubdr. .41"Wril hy r3millAtiml 4
tlie allyl to'hi-mil; tile fillidle It'.11 lite N1811h m evalm. roe
and extri. with HIM x4ve m ati-filit-aft.lit mielAylethyl. Zee
I Ohe dwid no, 44'. SLIS.1 %Vhell tile 4y"the-tis
was Willi .4 lift. rewtim milit.
71

ee
*on with d1l. 110).. Cut ittlAid. by.priklud was ioulated;
'
14
1
II
' IAW7
A
0
-
I
.
.d.
this wissahrimmilum. h. 101 3
. .
9
C`lhlih. T,.I.
11thl
31101: C
1
ittl
at
WI 1 jeee

00
.
.
r
I Usis 111
W
y
p
trient of with culled. tit 1: 1 IICI g4vr the -Anic, chloride.
1 1-
'41199
?-owlkW-J-,Ck4wo-I-Awxroef. b. 154-3% dV 1).9119,
i
se sa,
'
IA*mlM,7. Which im oxidati-i Willi K%Ino, gAve l
W ?00
V
acidt it% mvtoo .44milett by mid4lit"I ..I I .I lite &tx) -,00
i'mIlds. L'tufulmild Owt 1.0411 the 6.11.1c an't the, 4.1-Ridi,
;-
0
U: wrie the luslitle Arti%'. .4 2
0
Of
The chlortile (15 K.) ImitkA III hm. with 114) cc. Ill'T
it
lethyWlyflsirlin,if
d Nl'~ illeth
N)" I
l
i
II.SLA dItALUFMAL 01101410411 CiAlill'KATION .
A
l
y
K.CO, pvc
MO. Ivy 01110.,,ni-litti,mi tit &A.
O.St R.-AA1.41
'T
U n AT -0 Is 1 4-6

Oe
Rx.i

it 11
IT It at it K a It OF an a
4,14
so
0 0 0 0 We 0 0 0 a
0 a 0 0 0 0 o o : Tit _066,144-06609090600900 0,
0:01

qw/cbmdotry - convex Sian
Rydrocarbons
Improblem in Conversion Train Zthylsn* Eydro-
parbon. Derivatives to the Simplest Pouwtby-
j~no cycle Derivatives.& II; Interaction of
a, Ilimthyl, xelhyl-phenyl- and DImthyl-Allyl-
Cirbinois With Sulfuric Acid and Xydroohlorlo
A~Id,- T. A. Favorskays, Sh. A. Mridmn, lab
IMni Aced A- YO. ftVcrsk:17,, rAulwad State
ft-d of TAnin V, 9i.-Pp
01%ur ftshch Whim" Vol Mn, No 12
Roaction of 2-chloro-2-methyl-k-pentene Vith a
3D% solution of kCO 3 gave dine thylailyloarbiml.
67/749T38
MM/Chmistry - Conversion mea 48
(Contd)
Action of concentrated Hal on wthyllbenylalIql-
oarbinol,gave, the chlorobydrin Vh1cbL libersted
Ml upon heating Vith-a ]:~, CO, olutich and
y~eldsd 2-phenyl~.l, 4-penladignZ Action"Of
on methylpbanylallyloarbinal yielded
6t/40138

FAVORSKAIki 7. h.
T, A. Pavorstain and Sh. A. Fridman. Concerning the que,3tion of the transi-
tion from derivatives of ethylene hydrocarbons to derivatives of simplest
polymethyl cycles. N. On the Interaction of di-methyl, met1kirl-phenyl-
and di-phanyl-allyl-carbinole with hydrochloric and sulfuric acids. D. 20130.
It is shown that the bgrdrochloride of di-methyl-allyl-carbinol upon saponi-
fication with a 10 percent solution of KOH gives an originally unsaturated
alcohol. A c7clic alcohol is not formed. The action of concentrated hydrochloric
acid on methyl-phenyl-allyl-carbinol and on diphonyl-allyl-carbinol to studied.
The action of dilute sulfuric acid on methyl-phenyl-allyl-carbinol and
diphenyl-allyl-carbinol to studied also.
The A. E. Favorskil LaboroRtory
Leningrad State University
Holder of Lenin Order
1~krch 15, 1947
SO: J. Gen. Chem. (USSR) Z& (80) Wo. 12. 1948

UW/Cbsmie" - Synthesis Jan 49
ChWdfftr7 - OIYC010
"Synthesis of Dimetbylacetylenylpberiyletbylone-
#Iycol and the Study of Its Interatlon With
Sulfuric Acld," T. A. Favorekaya, A. N. Shirshova,
-ftUdp' lab Imeni Aced A. Ye. Favorskiy, Leningrad
State Ord. of Lenin U, 5 314 pp
"Zbur Cbshch "In" V01 NO 1
Muring synthesis, ketc, alcohol of dimethyl-
bentoy .lcarbinol:. is reduced to dimethylbeazyl-
carboaol. Structure of the glycol Is shown In
Its decomposition by heating with an alkaline
58/49T43
UBM/Chemietr7 Synthesis (Contd) Jan 49
solution and oxidation by lead tetra-acetate'.
~Xts Interaction vItb. 10 and 20% B2804 is studled.
Submitted 20 Dec 4T.
.58/49M

Syutb*Ws of mortitylstAylallykafbinsil and its irapia-
foratallitions wder IM loBwmce of Millaric acid. T_ A.
.Pavtorilwye atul M. A. I'Mman (A. A. ZIPIAnsw I-'AAtr
tAllinglail). /blef~ (AIAW)Wf 4Khjxl. I
v .1. (e,". .
Chests.) 20, 413- IMUMM.-Addii. avrr 6 hr%. oil Y) St.
MelttCO and INS g. Cill: CIJCff plit In;j(j X, %Ig in rjoyl mi.
1-.1#0 (after activalkin with Niel) U1141 %titting I hr. pvc
X1176 Is. IM-40" d- 11M41
el:, WMIO.xv 1XIIII). ISO one exist. fill rad;infa w,ts fill'
wilir-I losit 14 211% ykbl of a subistes"Orr, Is. irtT it(
CO Kr"Up for halwers. asset hirh frave, ."fly (CO'll), test
011flatioln. fvlosetitison of the expl. Uiikil Ili duplicite thise
result. Uniting W g. rArbirsol vokith 3AN) ini. 25% 110),
I hr. rit irdul gave X 6. original aler. and 17.15 a. CO11,.1).
It 166,1', d; (IN011. it." 0.101513, sell 1.4444, uk"61aA as
fill thr loasis at its axplatifin vinh
'*hiiiO4lohltF'lCOaiatlCll,;CliC(411. Inaildn..1lorre
sel.re obtained Distaff anotes. of tichydrstwat pt(wluct%. Crill,,
1, . PIV fish*. 411.1 1 11.7111-11, all I 1AAM, street lit dome,. I.,
10.5 6 , Nil fntt-lifen 11-011 PLO., will, ;.N"~ ll.~A So. It Ilse,
porpit. off Ilse nit bill.4 it &,1w its 2 1 Ile

,a #I
jiw -1 - -1 a# os&*OyimNykwbbd wd IN tramw
formido6 wqbn sme as by V 1, wW. T. A, Favor. -
s"ys and Sh. A. Frid~ (A. A. Zm--ow State Univ.
~ r"i "). J. Gen. Chm. U.S.S, R. 30. 437-42(1950
lwnrl. trandatim).-Sm C.A. 44, TMU, , R., M'. S.

Tfsmsmi~ from the dorivativesi of sithyleak hydirocaf.
bow Is Ike derivatives at the Simplest polymetkilkne
Cycles. III. Ikenction of m;lUiy_4&_"ykrclfrpr"` TYkaf
Isimmol willbbysimblovil: and Sulfuric acids. 1'.,A ~Avsvn
skayn and Sh. A. Fridumts jA A. A-Litrov, SlAw Univ..
I ZAP 1).8fAkht-I X1110111, (J. 114711, Chests.) 20,
it ~tqmlvs),); cli:1C.A. 43. 317 th-Thr actio"t of 11,4).
(1) locads it% finitAile
estristmillin to till atut
tv Ift'l Kit...
if mItAlkirs tit Y.Phemo.
t
2 fromortiovess: fill% "JorniflK I's Alt-CM.C111011,01.0 And
(me raps"Ol."i W a 44C Imgf. ArCII k11, Off 15J.5 a
t j
and 98 it. Pillit I.. UN At Mit (Ill NI'll "We
of'. J.. I IM12.
Is v
1.41111, (.141 Is I A hr.. anh Lml fill.
Lm-, 14A SAW 471"', 4 1." a.) .4 A 1.11411111 Ills RVII11,;
.FA)70 IW. 11N) jnkn.~Impilmjg) X.%W U1`6 tot the smite suit.
stancc. tisia don not ILAW it CATbLJ1IYI 910UP. 6 IstiSt"I" to
lit in C.11. and to KNI110., litit fmcts with Na; a Purified
.4111plor, to- I (s= till 0 ,111097, 0., 091 01thfAtilln
I (* 4
SAvir 111611 4':11 01,11po. whiff, MrStal gave thr un-
I I
.hAI1CVd tittillIC1. 4 frelipir.1 mlitiAlitill wilb 0118 gave
costly smut AcI`b .11,1 $got evvist, kett-Itc. while IIN(h gave
,Nll!t a jgAce of (COlII)j. tmily healing with KNIAN le-
$Ult"l in ftwtnation tot it i.AsIl aciol. C.S111jos, tn. 7W. which
fit& matioling its it drNimitto forctiorlics Soupy Wit bisist Chitler
.11 Conip" - Thi, "Cid toas flue PhMeXC4.11,11 (filixed
Iti'lo. 'Irprew.itto wish Ali assillornlic SoImOr fill", MeM191
ata,l loIV -MICIAIV); jotolliblY it "4% A MISS- tit 'lift'
The R."at.
114M),11 and UIPACHOISUMI I.
itillicale that the fra.-titt" I".1tict .4 1 Wish II.Ah was
It. The "%I'll, julithlit foloill (hr (vaiclions oxiolizell
with KMnth. imlocatinsAn Admits - -if ~Ior III..* lotomwilly
MI. ICIAIIIV Aill t,
ICS111101113 HkAttkI 13 fillillint. I f4akA it, reAct with 1. 1 11,:1
so the "`&' in 15 till" 1"41 Ilikkil 114:1 SAW to 3 hr, ~141W
11, IS ""St. -4 '"W Aful uol,il& .1dowule.. 1%. 1.11 40.
Wilkh 1151111ol Mot IV W'.1 It, '1"j, , ,, '41". thett. .4.
1.441.1 A 01TIAil atilt. -4 C"ll", hot W "'. M w.
If 1krQ41. RA I ftj~.%. 41tol is~qhlll, ,,I,
kNim". .411.1 t-1,111111C A, po'.14bly I.Militl flown 161,
Itt'Ot'll.i, it t It, flu. L.11.1 -Al 1, W.111
~!"M I'mot I$ to,ill ff. ."I. JIL-ld'. b.
"I:, 1 1111-0, a..- 1 A. I
11114v
Ltv~
while oxiobiticitt with Not K\InL). save AffpbC(t)jj).
(ft' Ar"'% ublCh "A'o Allool OtItAinselt fl(Wn
the Unmi-I CI )-#IV. f.doolve), A 4 "(If As ThV
virchor chh"Or I.-ILA .1th m,
al, . 'Nat 111 readily ywhf^l
IV, "Ilhil %'04-11111V Allis 111410% &1khyjlI&, A.
Well . otvic 4.1 ill di-. "Itutro.1 %Jsr all clu,lr S14te. too.

L 1. It
T~b~ of *0 kow "dwadwas of tho
to 61 A~ M ~ go $p dMf~d"g 91 tM AM
6y*o
M M. TM rooWn d mo&ylpbmyt-
v soVurk acWs
J. Go'". Ckent
A ~1- vW- -10.
2NXIM)~Fn8l. Iran-lAtkltl). -SWC C.I.
44, ".791f. R. it S.

Trualtion froin dorivadvout of odyleak by"Winom
so dw derivatives of The amphoooth=710" rw
IV. 1110401" of phoorknothylitilly
vbm-. -
new 7
C,weu~~I!!~V. bloclailibbooka". ad
A. Zbolatmv Sute Uaiv,,
Le"illarall). Zhu?. Obj&Ael KUM. (I. Gen. chem.) W.
War) (17-1111MI)i 0, (*A.44.roMj--AlWn.WT6,81, I'M
aini 42 it. acriy1tiuvirthylvnr let 2M till, HIP om 4 bfx.
tit 13 S. h1q; Ili VIM itam ilia the usual decompot.. ba-
7% welboa; hychipropykapbutill (1). his 119-21'.
Reft-ing is. i with as C. 48% HCO.H 1.5 lars. govir
40% 1 phmyi 10 ~*Ih*jfe. he M 90" 111, 0.9618.
411 1.931, fit"fil'i &,I ether. which appdrently has
Ili* Itructillf 3WIT4 *: C11 ('I[# (71.0010. be 138-*)%
The ftsmor with KMaO.
save b#%**jJjp~t*yk** (isolated as ill* seatiorbounisse,
in. 177-7.6% 11CO.H. and I 1-cyck _-_
ll.WW. in. 33'. which with _91NA"O, ir&;~ Itri-
nifthylene: olupimlyslit of flit ether save I
fCOJI and
Aen, hyelcoly-i, was Ineffective. but tgeatn"t with
11 1111111 d4t, I It III And .1 ph,ayl .1 1W.lem o-w, I",
1.42 41. till 1.(klj. all 1 %%hkil .91
uva IN Writ gave 4-phtn*-ijil Ill.. ,I IJJ J% d*
0.1011162. d!* 0.111M. oil.* 11,11k. oilldixtil it" dichronlA'ie to*
-r-phinyloultrte wid. It,. 170', K-4.110-1 AS .11 tall . The
low ill 45"' IICO%II in the reactima with I gave We' ethir
drij 3 a ~ma VIVIll 14 thelvilto.
cmtxat. Addis. 44 MI S. Acl%h anti 114 S. CII#.CItCII$IIt
In MAI t- 12 9. 3619 Ill KIP IIA%e 51~~ .110PAWIls: ell-.
CH.W011. b. W-101'. This (M) x.) redused 1-3 furs.
with till 9. P07, IICOIII give art unfellolvilat miliv.
-turbig at tialus tenitt. 3 his. with 481;; Mthil gave
Illuch oultraciol "it-. And 31% 44 A "list. 44 :-PAraY1-l.4-
k"Iflit Alld 1%, 89 1W. J'
it." 11.' AS Shown by the inult. a
xx .Ino. Oxidation; a small amt. of pcdymff also formed.
The yield Of hylIC4704flk"IS IS FA1W%I 10 M70 it the COACIUM
is full imly I ~5 his. I lie %vitle lravlom IWIfigme'l *till
119% 114:4 Nil A11.1 k C "-1111119 IJ Ilf. i
1.4-swulAdwiar
Itul. 1,,. 112. 14'.,1: IA113.7. a,.* .1..* 1.01115. Which
is readily %Alwod. fly hill all. KjC(N. with Akirtyl-
trimethylevic gAvc T-117e mefAykfkyky% top-ppyha,bs not. h.
life. oith MI, JIL0,11. x,.ve 14 If. CollJ). It. liv-91%
Identified as on the tusi4
olosidai"iby
It' 41* 1 0191. dV aV 1.4401. it:,
(converted af~'jo the Ag sall of the free acid), which
yielits the onf"tuRldilig jMkie. tn. in the C.A.1
with citkni. N11,011. 0. %1. X.M44114,11

ir ~ iTr.T,,zv i ~P A ~'. T 77 =.., r)r,r,,,A
- , -. A . - L . -. --- I
RT-140 (Tertiary acetylenic alcohols. TI. Di-p-rolyl-ethynyl-carl-inol)
Tretichrqe -tsetilenovye splrty.-II M-n-folilatsetilenilk-arbinol.
SO: Zhurnal Obshc-hei Khimij, 20(6): 1068 - 1072, 10,50

-
-
"'-CVCIRbtttXI
IC
Fav avAil
AOI.
wXothvIbenzyI it
T
A
O
.
.
-
;
and 1, 1" yokoviry. Akad. V4Vh-9'=X,-IFI;
rA)Vr.=
Khe'll., Sinte"y Wrnik 2, 113-14(19521).-
To NfcNfgtlr, from 9.2 g. NIg and 40 g. MeBr, in 21W ml.
Et.0 is ,aided GO g. phenyl cyctobutyl ketone in I(Y) tul.
.
Et-.0; after stirring 2-3 firs. at room temp. the mixt. is
treated %ith ice, the org. laver is scpd. and the nq. lavt:r is
acidified xvitli 1:4 IICI and extd. with Et.,O. ITeconihincd
org. layern, after drying over XaSO,, Yield 90%
hid:d~-wetfryiben-yl tile., b, 1()0.5-4.. P:,,- L-53AS. d~
IA~Jlr), Similarly are obtained: 93.5r-O .-tyfWuIy%'C-
tile., b-c J217-1,', W-11 1-53302, d., 1.10M. awl
air., S9%, N.
G. M. KO'(WIal"47

7, 71 T-"

aL~n 040
I - ;A s - .5, q ; I-,
~

nd.

fit
i ri
r 'ITC WitI
l
for
or Powder
On
1111"M P.17 %,flich Ill; t. iTItO I tIlIM.
Ivitil 11;o-I , 1;1;)
'
' ' 1~ fia,'."! -1
11)
12 rul. per I!, -,t I I
Disill. of ti,
1,
!,

do Tj
lf~
dit
hit, 1,
MIMV 4()7" WA:

1. FAVOPSKAYAO T. A.
1
2. 'U33"R (600)
4. Compounds, Unsaturated
7. Structure of unsaturated compounds according to Butlerov and further
development of views on the double bond, Vest. Len. un., 7, No. 2,
1952.
9. Monthly List of Russian Accessions, Library of Congress, February -1953. Unclassified.

USSR/Chendstry - Rydrocarbons Jan 52
"Research in the Field of Tertiary Alcohols With
the Cyclobutyl Radical. I. Interaction of Diiso-
propylcyclobutylearbinol With Hydrochloric and
Sulfuric Acids," T. A. Favorskaya, I. P. Yakovlev,
Lab Imeni A. Ye. Favorskiy, IAningrad State U
"Zhur Obahch Xhim" Vol XXII, No 1, pp Ili-122
Prepd and characterized for the lst time; diiso-
propyleyclobutylcarbinol (1), 1,1-diisopropylcy-
clopentanol-2 (11), diisopropylmethylenecyclobutane
(111), 1,1-diisopropylayclopenteae-2,(IV), 1,2-
diisopropyl-2-chlorocyclopentane (V), 1,2-diiso-'
propyl-methylenecyclopentane (VI). Interaction of
USSR/Chemistry - Hydrocarbons (Contd) Jan 52
I with H2SO4 goes in 2 directions: dehydration but
no Isomerization; and formation of isomeric tile 11.
Interaction of I with EC1 goes in 3 directions,
yielding II, III, and V. II is dehydrated under
action of %P04, is also dehydrated under action of
'Wl to yield "IV and 2 5 -membered cyclic chlorides,
*~e of which seem to be secondary reaction prpd-
u6t. Estiblished iscmerization of one cycle into
anotber In organo-Mg synthes is, by which method I
is formed at same time as II. Formation of isbm-
eric ale results from isomerization of orgsno-Pg-.,.,
complex.
>4

-YAW
Alcohols
Research in the field of tertiary alcohols with cyclobutyl radical. II.
Reaction of methylpherWlcyclobutylcarbinol with bydrochloric and sulfuric
acids. Zhur. ob. khim 22 No. 1. 1952. Laborstoriya im. Akad. A.YE.
Favorskogo Leningradsk go
Monthly List of Russian Accessions, Library of Congress, May 1952, UNCLASSIFIED.
Gosudarstvennogo Ordena Leninan ~ersiteta im. A.A. Zhdanova

UM/Chemistry - Hydrocarbons Fob 52
"Research in the Field of Tertiary Alcohols With , i
the Cyclobutyl Radical . 111. Interaction of Etkql-
phonylcyolobutylearbinol With Hydrochloric and Sol-
furic Acids," T. A. Favorskaya, I. P. Yakovlev, Lab
ifteni Acad A. Ye. Favorskiy, Leningrad Order of
Lenin State U imeni A. A. Zhdanov
"Zbur Obahch Xhim" Vol XXII, No ~, pp 215-220
Prepd for the 1st time ethylphenyleyclobutylcarbi-
nol and products of its dehydration and isomeriza-
tion under action of H,,S04 and BC1 (ethylphenyl-
methylenecyclobutane, 1-methyl-2-phenyl-2-cyclobu-
tylethylene, and 1-chloro-l-ethyl-2-phenylcyclopen-
tane). 209T26
USSR/Chemistry - Hydrocarbons (Contd) Feb 52
Cites mean arithmetic values for relative dispersion
0j FCD of some ales vitb cyclobutyl radical and
their dehydration, substitution, and isomerization
products.
209T16

FAVORSWA, T.A. - TAKOVLEV, I.P.
Tertiary alcohols with a cyclobutyl radical. IV. Reaction of Iso-
propilphanyloYclobutyloarbinol, with hydrochloric and sulfuric acids.
- Zhur. Obahchey Kh1m.22, 1816-21 052. (KLRA 5:11)
OA 47 no.14:6876 153)
1. A. Zhd&nov State Univ.. Leningrad.

O'VIdtheals and transforala lions of dielft4y.0144 lfg~-
A. Favor,kitytiwid 9.). A. vakhar'-
am, i
owl It
O"'Shchrl Khrlyn. of
-HuAc with C11 rt it; tbe pre~euvc of KC)t I ill Et.0
o
6
aiwe 45 .80% iij.-Bu CMe'OH)Ci C11, 1). 146 -0' 1'. 76-8*
n1j, 1.435~ ailing with 1.15%
IM-7'. in. 56-60~. ThL tile. (5o g.) tre;tted with 1.2 g
UrO in 25 nil. 11,201 antl HO vtL 11,0 pavc 15c" iso-ffit-
t).9j.`y4, jj~j 0.11[35, I&IJI I.-mad;
Tith (0.5 Tn"10 a(Wed to
CMK1]r)r (front 25 g. Mg) and Olt niiKl. stitcr standin,;
ovumight, decompd. with dil. 110 YU&IJ .191,,, unr~~=tr
a1c. and 10 X. product, dr-.iLrrj(,d bdiow. '.o i:wr~-avt t1w.
icld I niole of the Gritnni-c! reagent waj ernployed,
61 prodoer b: 1*44" Identified mn isoI-1l.XAfei0J1)GA1-
-(Off.)C! C11, in. W-i~ i!afttzr long swadiny). dis 6VIM21, I,,V
L-005 (1), mkfizL4 with Pi)(O.ke), tn i~t-lhi k,!. The
fr.-Jidnt after the (!iati. of I Irai; jijr-1NC.1f'e(O,Ir)CA'e-
(010C.; Ii, bir UY140% ii sintu. Heatilig I with ;0 parli ,
We
whirli had it fret: Cl C11 group bill, iv, in'
1" and "), 13") 513*. Tbe forl."Cir, C"!!"O' 11, O"',M3,
Elm Is"O LJOV, had '& C!Cif Upl-ar"d it)
1w! iso-B it C,lh~ 011) Qi(ITI) C' Cir: it If 1~ 1 1 ~ It C~ ~, "C C~!
h) tllf' pfe-'eilvi! of 1111~.Iji; -Ixidathll nitli oilly
AcOll and (('Ojr).. '11a, 2it-1 pro,bxt. 1), d.
6mmol. r- %Y11., apparvidiv :1 It wr'of a
rr~,diwt of 1. Wo pill, wol rt:irring ici-.tt vvj,
UO"'.of I lyere kc-h(C.'L - C" N1, Ko,-~Ipolt

F
cou
lot rk' 43
L A. Rem
at

-7~
Chemical Abst.
VOL 48
Apr. 10t 1954
Organ-to Chcmistry
4F CAW4111 bstitut-4 by(LartfoLn. fer Olt-,Mffar, d if
dIrrivicystir% T A , -rd L A P.~- i~, a
(A A Zh4.n- ~7_1; M;
Kit." Z3 4 17 212 r I IJ!2' If -I C-,; (,E~4 1, 1
ti-i,ti (Nt4o 'CII, -0 _~., - I "',
-i 40, Ph'CHCH'.
8-11~ to 711 A' g-.
" _, ! ~ 1") , I.- 'If 1 2
h- t,d I I !"1. :.1- ;,, -
ialth BaCO, ind ...... of A- 'ili,
indicating drcompri . under milari rundittoriq iio reak-tiall
toek plice Hy,imi-i, of thr h-nihntnin kith Po(Oll), in
wAled tube 0 LIS hit ut 1:30% ~ bcAtrr I h7 at IN)'. 6,A,I,r
14d hrxy1Hv1kynh?~j1jjaj( n,'jj, rj 117-8' (from dil.
Ftolltw Thii tx,i~i with aq 11471 or H;-So. g:%- thil.
original h5-darifnin RI-PhiNing .40 C F1h!CI4rCJ;() W, rnl
W% Etolf nd 41 g K, hr~ in 4r) j ItA),
treatment .-ith CO.. ,Mn J 'If! I,,i 4~-, ald
extn kith rail") pi- i mixt of fmA,wt,s. Ir-i -hirb A-ii
kolat-f III green liqmd J). b 1'-'2' ~w ., high --rn).
wluch,,~pr to kw imi-rr Ph!"HCHS. kith 2 4L-
in F,10Ft it -,wkLq ~t fir,t -i d-p
red hydr-, h- a Y41- - - h.-h ~tz~
that of the abo~~ ddrliv& The red hvdrivinv, i-n :~W~ 9*
(froin Rffl.kcl app-jr~d 1" h,,: tkit ~'j PIL.C(l fufiL.'r,
examn, (if I -Indivated that it w;11 viniposed of PhicW,
PhiCH010, anil Vh,ClICll9. l1hCBrCJl0 (70 g,) In
dry Call, Ir"IcIl with ff--.h Nxslf 511,1pen"M in C.116 13ve
bn dkin a blu, prduct. r-ol-I into '2 fi-tiIetion" b. Ml,-
33' (high vacuutn), anJ L14--R*, txth fr,-c M S ..~d WN
giving with 11 fiti- of PI.,C0 III,] Ph'ClICIM:
T1w diits r"41,,r ~,-nt.flnrd ',i ind the C111) 1;-ip, bur

6k otimbgatmftd byd=totu for MUM
on I idt 'T. A. Favonkays .27"A. Remiwva.
T Vm. Ckem.
tlw).-7&t 48, MV.

Iv
s
Mechanism of transforimation of tert[UL f the
u,nre
cyclooroveme series Under the InG and
OrgAU1 C acids* eAction of dinieth ' top
1. The r Tcyclop I
mill.0, "Ith formic acid. Lul'", iU-_4- loid
herIjbilkivit (A. A. 7114, .11 v,, Lt-tinyr
Zhur, MhChill KAOx, 23, 14&5- ; 11 11 .-In tile relic.
:.tidn of HCO41 with dimettivicyclopropykarbinot (1), it
:forined,! The prowhict h; in. part converted to the tQrrnate
land in part isorarrized to 2,1-dimeth letrohydre1wrox 1111). md, UP W 30% trionefolmate Of V. Renuxing mW
'hTI 12.8 hr%. pye 47Z ,r III
;SI'3w distri. of Ac(Cll,~OH with 119le gave 16-W%,'cor- and it, forinate %~lth I'l HCt 1.51irs-rltCO-70 gave-
:mr*j(Unj; bromide whieh wits shalen with otms KOH or 37 g. I with 80 ral- HCCA"itnt, of 1*1
:N'mOf1-(so1W). yiddlnK 711% aertyleycloproopme (TV). b. 54 t7o and its fonnl%tt, IL $MR" 1 cl-CHCH-UOH)MIJ
I.ttfl, b..It 110 Ul Rtfitxing 12 r. C11
~,109-12*j which wifti Afc.Mgtle c -ve OP-701/r, cmde, 54-,5%, (VI) wlth 1ICWI (1:1) 1.5 hrs. give un~h~nqcd V,
A34 O.ftft do OW53, ftV 1.432-3. 1
d hydrocart-'s coffespondmi to lhO"
Film 1; b. and 1.9 j. mix. stir-~:
50 g.) refluxid 1,5 hm. with 300 ml. 1: 1 HCOJI. and the 9formL
.1)Fdrati., of VI (cf. C.A. . 770a).
'd Irotnje,
tnixt. neutritliad with N(t*CO, and P--td. with HtsO y1vided 06 L,-jt nc T_
i VI With puts 11CW1 6b". Itt. &ct:on, hu
5"" kunra~ted 1 19 2 111, b, 00-31. do. 0.8477, lay IXA)I r nit 1,5 hri. 1-%Ve A JQW Id of 0, jjWj L- h)d,,e(or6O4.:
6& nil'ot i1i y'Irld b.,2W-. rtauxin i 1 1. 003, vIlith &A nok I .:~
'41. which ga, C 11, 1,,, 142-3 Ith D 'a C11c,"i
ve the At 1411 nf the 6frofolldhig am), 5 1 t r
1 104 anti avOlVNI 1114"
react with Mut - double b0flds'
;IV;h. M-121, sonic 061, mized1l and tXfOrfflill.-,b.15~ So A tycl,a product %ituout
; popsibly this w
,;Z;!t dj OARMA0018. Psyl 1.4.
I to-1.431A (oth rhic with 10
or side chat
XsM 8-'10 his. with 1i atirix ,!thCV4reII.-b.IWV,2
"Asm: J2V 1 A484), d 8.6 JFjZWdkyUdrUmA1k*xe I
drill It .Vilth 10,0 RICO
4325 W
If (V) '112-130. du 0.9789 x%t JAWO). Re- 7.
I& frt* (h 13 ml, It 3 IIMTlr I hr. pvt 28% M
t

tradonD-Atloa -01 W
&kohdL d tbA
daa (3 moof tm 67 . Treatrunt of the ekAi-mm!e
Z2
-
.
^Ttlorr-mmt "as =der the In-flU4O-C--
.0 J-Mgerj]

ydr(ItyTai Ut the Product with I I
. %,
cad tnj4 adds U RAudnn of mothyl-hykNO
,Mb
F
ith imi
l
~ k
id
T
A
4 Hisa P~e 11 Anj M, brdroly~., .10 4,C) ILIOMC jrx~~ of;'~

izaa-cm -q.-mre~ &c%dw ~lzlys,
"--u
c1
thzt C
ral
avor-can
W
t
c "
.
.
.
m
vy
and -4. V, Chche.-Wasim ~
m
y
Sxtelwve fi&&j=tsw at Ehe rcwdzr,.~ r~-Qd"-tl a , -t,
w 0'," reACUM at I with 84. RMH fare a m&t. 41 in-
'
4; . da o
amrsbia pmdar-ts. b~j i*-i4

All 14C, ,H lh~ --t- -th -th 21)`~ FLC.-,
f-,, -,--
'Ad"

.9
-th lrmnc~ u jra~. HCwf
M CH CH, !,--~n
.
ad rhe ither products mz~udrd J- ~Lslladuq muflts
-00 2 fthrlr2trwbrlr~turan, III and a r4 t,.,] .1 d,4. -4 1 lp- ,,,p, V
--H(H.'HOHfUl and ~'. b Ml !, K).in(-,, g-s- wm. -i~
-tt oz; K,,:O, t,- h~ 'h, 1-,d '. tb, -,- - ,

1b fare MCCOEt, HCOaL IM MeRt- mr,'li CH. &ad r4t PTC n, m

IN"i

P -
.mAkahthJ1
Z,,
cydopropexte rArles tmder tho kfittme Olriiraw and 1! prax, b, 119-21". X11 1.42-98. glul 0.5 9. J-Mdk)jN-
i2
!orgwc acids. Iff. Reaction of dimethy1cycl i yl
':
VrWo:'
md-i
~blool
Ineth
lc
O
lath
cl TO
I(
rbin6l
= I th 69-711. mlf LOW). ancl polymcri- residue. Amfy
l
o~
ane mud UP-PrNigilf gave W-11% m
l
,
m
'
A
c
rop
y
,
yo
c
op
y
PY
y
lcydo pytearbinot W
N Wudo acid. T.A.Favomays rjwlof'ropykarhinal (V&),
I I - , L,
fu" V-Smcherblnskaya- and 1.4405. d. 0-88M. and 13,17~ 2'Y-ji'Yf;*
N
M
~
r
"
r'661AC
State unit --fi
Ake 78-
963
MI
(J~ 4
.
a
buirltdiol (VO, Ili lm, .1. Ve ( 0 Cf.) n'i

Cf.-C.A. 48, 136M- Slabey, C
.A. 47, Mf, 46,
DifflA
aprolp 11tarbixoJ (1), flom seetyle vloprojmr fluxed 1 hr. with 1: 10 lfSO& gave -q"1d4Y?-24ja
W-O*
tctrahydrof~pa". b. saM 1.411,0, do 0.3624. "0"
g
and cYleld.b.]M-30. Heutluglittreflax2-
1 J(mgetl oxidation of thb with KMnO4 Save
1
h
l
hm. -
1 Cave 31.1% 2.3-dime(AyWmAydrefuram I " ftj I., - . - , t
be 97
t f
I.
clAer (IU),, and 801 -
0 jail of tile (fee 4CU W3.4 Igolattd. V1 rtitaxed I hr. vist
fU U 4
m Cts 0 fr
bli tArr
ilstill
l
o
Oymederesidue. Wit I: IWIM. them was lomed 4

'
n
0 U1
h
l
IV 4.1
. a
.,
y un
P
, gave L
y
1.10 Iw
-
"
e
re
n
cli
h
*t
i
h
Cm
t
-f- efilds-S-41 (
. 1% 2-111fl
t
. 1
), and 7.5
"
y
i d
e
fl
t
I
ith 130 H
A
SO
I h
815 rtAl-:
% It' ent
ere4
o
ons
P
. w
, -t
g
jL-j"i condit
p
yq1
A
l~bt
w
u
. t
Ux
r. save
n9
t
4
1
n1
ith
t
id
d 57
f
IV b
6

-3* a
C02 alnei a 6:11411 amt. of diStIl
*
l
o
an
race o
y it
ue.
m
,,
p
~ w ,1 material whicla was resolved Into a kdone, CidfO, N 25
t
7,
V 1.44W.- U1 bit 101-3* bm do
1h
-
C1
8418
OM70
t
d
t 1
4531)
"
Th
V 1
d, O.W73. x94 1.4300 (:.4-dinftrqpAexyiAydraxixe, m. 181.1k,
'
H
,
.
u reu
t
a
.
.
,
,
,
us t
I
and'
to both U arA M
rocteds throu
u
h JV
RtM .
.
alut , v,,, small amt. of. probably, (MOC111 Cite C
0
.
r
.
p
g
g , %A 1.479D.
eater's b, about 75
;imetyleyclopropane gave 64 fflethylablik lopf Ca F-
141-
Thi
bi
b
3
l M
t
20
(2
)
le
no
, -
.
s
1
m
V t. 1
.
Jr.
'
I
111 1:5 "IS
isolated
tl O, gave 29 crude h
ydrocarbons. fmai whicl4
fa Prodact, - 10" , that vm very dose to'
o (h
t
f h
d
t
f
e tn
. o
es t
x
prnper
rucasbons
mtned from V
y
j3M): L 4
48
nd 11C0
CA
j
$
H (d
Aqj
.-
,
a
.
JW
t
,
'
and J-cw1ajOrvW-2-b*$*x*.' Acetvlcvv~~ue (5%) wis,

Mccbamism of b=sformation$ of tcrdU7 alcohols of the
~yelopmpme series under the! influence of mineral Anti
orpnic ncids. M Reaction-A of dimethvlcvcl I.
N,10,~inol with b":nic acid and methylpherk3VICYCIN
M-3-5-lorwith dilate formic aci
d~ Lavor,
p
"JU-1
ctivaj); CA. 4
193f.-Thc mictious of tertiary, ales. of the cYcloproll-e-
follow tht tame mechanism regardlesz of whether avg..
-
0 X. dimethylcyclo.
Icids (V lirso, arc-Mployed. Refluxing 4
pTopy1carbinol uitl 170 g. BzOfL in 1740 ml- H204hm.save Z.
and its &"jzoafe (the 142-4% bm 272-4'.
d. lol0j. d. I #r-Z , trl" 'The Latter treated erith
cxcess PhXrcDr gave 2-ateth'i-2 -pen ten"'01 =d PhICOR
-
RMuxizig 6 g. inetb%,.iilmiyk~velorrapvkarbitioI with W
'
CJ
-d. 1:1 11CO.-H 1.5 bis. gave D~-.7% h: CPAR (R -
,
-~Yclo,iropyl), be dn G-MIS. nV 1-5421.. and. 63% j
'
tnixee, and its forrnate, h~ 138-40
.
which could not be ~vpd. by distm. After hydx6*sis wkt1h
"W~ solated, along wita.Acm (cf..
~ R~co~ XIM Alc, wns,i.
C-4. 44, 93a*80- Reaction of 17 x. acetopropyl We. with
P"fgBr from 52 S. PhEr gave 70%. a-mek34-*-,41vxy1-
tr1panw1)iykaejz1*d. b~T 2D0-4', which refluxed with 805770
HCO,-R 2 Jurs. rave 57~,,,
Tht4tter oxidized witk~~
KNlaO4 at roam temp. to I
isolated as the .41 M11 and M.
above
I -glycol way heated 2 days wi&h 2D% XXOanoTeactket;
.took place and no AcPh was, formed- Thus the tertiary 1'
cy,clopropyl ales. rvac, with! acift by isomerization to a! ~
pnmary qAbyknic acid. which then ur;dergoes the observc,111
l
l!
cb=M to the final products. the yields of which we'Li
fected by the p1l of the medium. V. JOLeactlon of tnethyl.~l
butyleycloproWcarbinol with, bydrocMaric acid, and rear-1
tion of dimCthytcyc1opt"vlc=bin*l, melhyfisopropyicycl*-~
-
1
b
k
i
d
k
bb
i

nol. an
a
curb
methyl
ol
w
thi
prorpy
uty
Itloptopy
phosphoms trichloride in the presence of pyridine. T.A.J;
F.ivorskaya- T. V. Gulyacva. and E. S. Colo-tachm-a (A A ~
Zhdan(Tv State Uviv- Lenincra4). Ibid.
AcerYlcyclopropane and Hu4NIglIr gurz 84% vzdh)dbu:~q -j
i~w1vpropv1rzr14nv1, b, W-3". d. 0X76-1, nl,*, 1.44&3. Thi s
(~33 p.) stirred 2 hrs. 'with tVp mi. 1:1 110 rare 311%
his 52-4*, d. 0.79Z4. r5; 1.45W,
(Wc~tificd by KNUO. oxidatkm to acttylcyclopropane &=e"
PiCChil). and 43% t,;& 82-,3*, d.6
0-q,:~13, #.I 1.455a~ ccmfirmed by ozonolysis wMeDUCO and A'
Clcll.-Cli-co.ll, Hydzolyf~3 of the C~hllrric by~SO% aq.
ale . KOH gave a sm3ll amt. of 4-M'
t" nV,' IMW~, d= 0.704 bicid, a rubberv maltic i
ardivL!ride adduct), and cru4ir 1). ql~-
5'. d, 0.8101), x~* 1.4400. whicli on I,reno;)-rii Suve Nle- t
T,0124'
R. PC], was ad&d a mlvt. W :;7..-
nv'rarbznW, and 7.5 g. py,-Wi~7r, w,,in v-nling; afte;
hm- t-be. nrg. 1,-",VT was -;~O ".1nd liog-4-methyi-j- i
nd Slynila; rV-U-
0, -01'1-%T`Ii~*;zr-~~` 1.

Z Mclbv~ ~.6,4

r'.7

FAVORSKAYA, T.A.; GULYAYXVA, T.N.; GOLOVACHZVA, YO.S.
Keehanism of the conversion of tertiary alcohols of the
cyclopropane series under the action of mineral and organic
acids. Part 5. Interaction of methyl- n-butyl-oyclopropylearbinol
with hydrochloric acid. Interaction of dimethyl-cyclopropylcarbinol,
mothyl-isopropyl-eyelopropylcarbinol, and mothyl-YL-butyl-cyclo-
propylcarbinol with phosphorus trichloride in the presence of pyri-
dine. Zhur.ob.khim.23 no.12:2014-2020 D 153. (KLRA 7:2)
1. laningradshy Gosudarstvannyy universitet im. A.A.Zhdanova
Laboratoriya in. alcademika A.Te.lavorskogo.
(Carbinole) (Phosphorus trichloride)

YAVORSWA. T.A.j ANIMMOVA, I.L.& SMfflBMG. Z.A.
Stud.* of condItIons for tbe forWlation of acyl amino acidee
Zhat.ob.khts. 25, no-3250-558 Mr 155 (NLU 81:6)
1, Lenivasdekly Gosudarotysw#Wy universitot
(Amino acIds)(IftnwIstlos)

YAP &Pb.fWjdFbvdV kT A, Fxvcw~
11 .
arid' bh - T
4UWAUW L
"Quwfk,4
23 713-17(19459rngf. tmusLilloti).-To 313 g. Iso-PrCHO
A
all a
and Iml of 1130; a sm; - C~ MO (u r.
to decompri
at 0. was added I drop HSO, and -the re.:ailting paiywr
yield-
v
ith 80
Dr
CCI
waq treated with c6olin
In 60 ml .
-e AK mirror
Identified), dso 0.7810,. xV I.&W. which rav

.
g.
,
,
g
' test. However, when the soln. I wAs treated with me-,
Jg .6% Br deriv., its. 125-0
(cf. Danilov anti Venus-. a tallia Na. it formed a ppt. of the tu~rcantide. which with
~Dauilava, C-4. 28, IG&JR). This (10.57 g.) heated oa a .
%
'steam bath with 1 20 tnt
anti 45-
11
0 lIjO gave brownish liquid, which could be titratcd %ith io-,
'
.
,
,
, .
dine. Treatment of I with AgNtOrAcOVa gaire a bUck
RtO11 8 hri., with 30.8 ml. 60%
' ppt. initially, followed by a grayWh ppt. of the Ag mrrrap-
led under C%, and distd. gave but a few drops
0..
bl
tiffi
t
id
b
i
di
di
bi
h
tide, which gxvc a pnor agrecuicnt nn amilysis with the ex.
'
e
a
e res
ue
ng an un
s
e,
t org. ma
ter, t
s
' pected AfejC(SAg1,CJJO- llcutiug I with a1c. KSII 4 hrs.
,
7- 1 ter of TISONfejCHO. To 2f) g. !so-PrCHO anti M z.: ve a tar. but a reaction,~ithout Leating cave after evapn.'
EtOH was added 25 s. CaCOj followed by.14.2 tnt, the solvents a crpt. solid. which vris impure and con- -
!a
f
,?Br- after standing overnight the mixt. mas washed with
4C
C tained S. halogen. and gave uldchydc and SH tots. This -
ff-,
N
O. and extd. with EtO yielding 16.8% MftCBr
-
l
*
2'
OO-
i
i
b
d
1815
439
T
W
OFJ solid, m. 76-7'. gave a n,,t-dinitraptit-.Tiylhydrazone, tn.
-
b
-
n
vl.
1.
9.
h
,m
s(221r.)
2
,
.
,
),,
(
dry. NaSlf and the m*mt.j
O was treated with 12 S
Et
ml 249-51*. The oily residue
also gage a 2.4-diaitrophenyl-
4
*
.
,
a
stirred 5 hrs. gave 10 g. starting material and n dark resin. .1-8
. The derivs. contained S. Cryst.
hydrazone, at. 2
of the product from EtOll gave an oil which gave a 2,4-
contg. 8 and Br. To 60 g. iso.-PrCITO, 5W nit. dry Ett%, 40ropkt~ylhydrawxr. m. 250-l'. Vie ruol
and 120 g. powd., ary CaCG was added *Ill% %tirring, Ice- -oil Md. cryoscopically. agrecd fairly well
I
oooling and Wuminatio4 with a strong lamp 4f! nil. D
r
ontinued
tirrin
filterin
dr
2 hrs
after 2 Ins C(S11) CffO. Ko%oLj~%~ff
ov"
, c
s
.;
g,
g.
y
-.1%, und distg. there was obtained'78% MeICBrCII0. th
48 Al. 1.41:12 q V 1.41-53 1. This (GO g.) added to 36 S.
Kfiffsuspendii In =) tuldrjr 19t0 and stirred 5 hrs. gave
a )i (1) (aflej~rcmovnj I the Pitt.) Which by
FAJ iodine titra,

-,r
1 A