SCIENTIFIC ABSTRACT DUBININ, M. - DUBININ, M.M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000411320008-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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DUBIIM;, M. M.
K Vcrprosu o soprotivlenii toku vozdukha sloyev zernenykh materialov.-Zh. Prill. Xhim,*,
1941, T. 14, v. 7-8, s. go6.1913-

DUDIVIVA me me
Ocherednrp Zadachi Rekuperetsii Letuchikh Rest vor ite ley-Khim. Prom., 1946,
S. 20-24. (Bovmestno S. H. S. Puzhey 1. B. A.

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see
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4-1-1-1
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iN/MmisU7 - Adsarptlm Tot *7
- Mm"a, Activated
UMOU"My
Miaracteristio Curve 3quatlon for Active Char-
Sd X. m. Dabinin, Mm, Aced Sol USSR; L. V.
loh, Lab Sorption Processes, Inat Phys Chms
Sol USSR, 3 PP
~
7:d,
Acad Sol" Vol LV, No 4, PP 327-j19.
Ian of adsorption potential to distance from
I
* of adsorbent can be deduced an&l:ytlc*3U lz
10
9 moss, and cannot be used for industrial ad-
to vhloh are pwous bodies of ocuiplex struo-
PaLmIle themy sumsests- use or characterls-
ourve of adsorbout. Authare attampt to desalbs,
I - ?
ammes b7 a v*U-famAsd "nation, In owe V
bodies, active Wm%mlm. ftb-
Dec 3.946.
9

Jun 194T
Adiorption
Obarooal - Activation
"Adsorption of Water Vapors wA the Struoture of Ac-
tivated Charooelo" M. M. VOInin, Academician; Ye. D.
Zaverina, Chea Varfare Acad, That Phys Chas, 4 pp
'vDok Ak,Md Sauk WM, Nova Ser* Vol LVI, No 7
Discusses experimental data,, illustrated vith graph,,
and explains-th- bl-shift-of alsorption branches into
rism-df-h'Ab relative pressures, vith progressive
activation of charcoal and reverse effect in formation
of acid surface oxides.
6OT96

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M. M.
444
Chailstry AdsorptUa, by Active' CaAM
"Problem or the WattlAtion of Vapor Adsorption TAo-
therms of Activai Carbons," Madeadolan M. M. Dablala,
D. P. TlaofaysTs A PP
"Dok Ak Naut SM" Vol LIO No % pp 821-4.
PrasanU method that is Independent of tmparsture
characteristic curves ror varlaus vapars and also
independent of afflnltq cha;aotarlstla curves of in-
dIvIdual vapors during conatant eAsorption. Submit
15 mer 1948.

PA 3/4977
IjSSR/ChGM1Str7 -Carbon, P-4-tITO Jul
Chemlstry - Sorption, Of Water Vapor
QStudjv of the Sorption of Water Upors in Active
Corbon,," Mad M. M. Dubininje. D. Zaverina, 31 PP
ODok Ak Nauk SSW* Vol Ulp No 1 * PP 7942.
Report of empertments. ksh-frae carbon activated by
sorption of vwelous,lamounta of ben2ene or dibutylphtha-
late. Soz;p't-lan and desorption leo~M6rma of vater vapor
were then measured. Tabulates, plots, and d1scuasea
results. Submitted 5 ~by 1948.
I*

DUBININ KIM, altadsolkl TAIWnTAT. D.?.
Obsputation-of adqorptlex isotherms of vaporlike substances on
activated obaro6al, Vokl. AN SSSR 60 no.5:821-824 My 148.
. (Adsorption) (K= 1OS8)

MMthepml try - Girbon - Aetive; Struatur* . Auj 48
Choml:try - Carbonj,' Active, Absentloa by
a Structure and Sorption Proportion of Aotirc
on From Menyl-Alclebyde Tars," Acad M. M,
D~binln, Ye. D. Zaverina, 4 pp
'!Wk Ak Hault SSSR" Vol L11, No 6, PP 1053-6
Tbree sets of active carbons, prepared by treating
VIth carbon di9xide carbon prepared from bakelits
J" 850 - 1, XY)'j, vere tested for adsorption of eub-
stances of varying molecular nizea from aqueous 801U,
tionss,'etich as methylew blue and Congo red. Ra-
suits were compared with those for adsorption of
bezzene vapors at 200. For nuk-rimum adsorption,
35A9T6
MM/Chemistry - Carbon, Active, Aug 48
Structure (Contd)
G~GDIMTIon at 850c) is recommended, wbieh produces
~upecially fine micropores. Submitted 23 Jun 48..
X>

'-,-I C-G~ Ci- \0 CA

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06 A; IL D. Zavrri"; J. Phm Ck*tjL
17 Sep .49 ~-V pr M-1004; 6 1114-8.-Mbo
1-
This aructs describes tesU in *Mch a S660111 Of bitch' Min'
C01M, ObIAILMOd 10 TUIOW CM&tW*S, Wtft subjectod to pro.
Cressive medratim with carbon d6o" at a Waperstv" of UOT.
Also kayeallgat" wu Uw kinetic of combmtku of reautow car -
boom in uwir relation to dw camStSoms of oxtractios of cok*s.
Anevalvationtsgivmottlimp, , KychRrwWr6mtksOfth*ob-
talmd specien of each miles of earbomm actordIft to the swas-
W mr#4 admorpolam d Ow moid" with varkm simed OvIlecuka.
a The adowpim innitherms of bes"m vapors for all carba"
09 Were Moav!r!~ U a tamporature of ZOV to a *W Interval of
--b-A Id
W06on, vm4*40. The CammeciJam beftfou thG CkMP La"rac-
two at acti" miam carbom Uk the proct" of proor&w..
(33)
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UUM/CheaiaU7 Carbon -Taul
Chemistry Absorption
"Sorption and Structure of Active Carbona:
In. Cbang* in the type of Porosity In Carbloi*
and Scrptloal of Water Vapor," M. M. Dubia
7e. D. Zaverina, 14 pp
Mhur Piz Ehim' Vol M=, go 1, PP 57-70.
Studies curves of laothe=a of sorption and
dosorptim of water vapors on carbon obtainoA;
frcot a%pr, which contain various quantities 1~~' J~"
adsorbed benzene vapara. Berealed that block
'lue'vith tanzene of most active parts of catty
WAWA,,
USM/Chemlatry - Carbon (Ccntd)
surface leada- to displacement of Ocrition
ieotherma Into field of high relative prcvff=
&Irzilar to tbat observed, during FrO9r0BaiT*
carbon Activation. These results ccwreapimd 7',
to tnothasis. on nature of water vapor D=ptl
ui,rvs Deven graphs and ton tables Of OX90ri- 1.
mental results. Submitted 19 May 48. 7

VOSR/Chadstry Ads6r9tion Apr beg
Cbmistry - Carbon
"Sorption and the Structure of Active Carbons:
IV, Structwe and Sorption. Properties of Active
Carbon Obtal d From Phenol-A3.dehyde Resins,"
M. M. Dabinin, Ye. D. Zaverina, Dept of Cbem Scil
Acad Sci UM, Moscow, 141 Pp
"Zhur Piz ]Mdm" Vol So % PP 469-83.
Studied progressive activation of coke from pbe=3-
fonaldehyde realms by C02 at 750-10000 C.
Zvalmted character of porosity of the carbon
obUlmd by of the adsorption of
57A9TIO
UM/amistry 3datoption (Contd) Apr 149
dU#Olvad m%teriaIs with molecees of various
sit". Submitted 4 Yhl 48.
57A9Tio

DUBLINUIP -
"Sorption and Structure of Activated Carbon. V. Activated Carbon from
Resinous Charcoal.," Zhur. fiz. khim., 23, No.O. 1949

W ud" cwhem. M. 1,L. min, K. 11.
zelmd", GW D. P. TIMMICOWS. ZUK - WAS-A". 23,
112"(190); d. C.A. 44, W-Expd. WA of the
Previews Show that thm am 3 main tim of &4-.
=too : (1) carboas having wr WWII porn.
as cadwas to wbkk The wt. km* is Ins than W";
beir ad Im ImIkem la We 0 (We t.1fili
116 The =gm . ftleortmed P. The Zu. !NXI.W _P"~
. PW PC""" c mw 44 a* coast., an - r."--
~
to Oemp.),; carboas having no ZZU pores, vxb "
twtvm ob2idws wt. Jos of tow than 76ro or non-
iblif e - M - X liv
Is jwupottknial to -
t (3) to type; Its WAkwm 14 the rAm of
DMIM-11%

Iva
Chmistry A ej~
"Strzatural Types of Active Carbon@ Acad
M. M. 3)ab-q,,' ,Yo. D. Mierina, 4 Pp
*Dok Ak Nauk ssSR" Vol LXV, No 3F pp 295-8
ConsiOrs adsorption potential as a func~, ,on
of carbon structure. Massif Is's structural
types of active oarbone by characteristic
curves. ExUbllaies tvo limiting struotural
types Of active carbons. 71rat type corre-
spondA to carbons moderately activated to
charring not exceeding 50~,. and second to
39/49T9
(Contd)
mr 49
6~bons ful3,v activated to abarring not exceeding
75%- submitted 25 Jan 49.
39/74M

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PO/Chesittry - Carbon, ActlVe sop 49
;I., Adsorption
the Structure and Adsorption Properties of Zinc-
blorlde Activated Carbona,- Acad M. M. DLbinin,
0. D., Zaverina, 4 Pp
Dok Ak Wauk SSSR" Vol LWIII, No 1, 91-4.
Z vith method of activation by gaseous substances,
od of obtaining active carbons by thermal decom-
tion of organic materials in presence of Inorganic
vating substances has obtained vide usage. Using
chloride is inorganic activating substance,
led adsorptlon properties and structure of
vated carbons of progressing activation, character
2/qon6
ilm/chemistry - Carbon, Active Sep 49
Adsorption (Contd)
of poroolty of vhIch varied vithin vide limits.
,ftbaitted 2 Jul 49.

a 8 C 9 er a 0 x L a to 0 py WJ P V 00 AJ* W A 10 AX V X 30 A 11 0 4
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T", and7averin, Ye. D,
IlAdoorntion and Structure of Adsorbc.;nts,ft -i -7if-
ev
of the Depart?%ent of Cherical Sciences,, Vestnik Acad. Sci., 315C
an
Tilis was of particular interest to scientists at the nst.) eonj.
Acad. Sci uho at the present time are studying local natural adsorbcmts (Lentonite
clays).

"Soviet Chemistry in the Stalin Epoch (In Honor of I. V. Stalin's 70th Birthday)," Uspekhl
Khim., 19, No. 1, 1950. Moscow, -c1950-.

aA
v ~s 16 %W 01, M.M.
zwbo S. 1. veravo, A. #A-
di L : I Kbio". It. 1-61,
W-6; . Robiwo =
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9w. I

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x t mm" (I
absif -::C'~ rW.A-.R E.5 pub! a witr3 k Ha
ft" (f Pam) 61 Ifi- wrAt" tO
and thr" with "PI sAwbod b"sm Ot
the i"Ahrm W a ft t. - VjWg(j%Jpjp (cf. C.A. 44.
lum) ws imma so r "me km Omm 0.4. to CVfding
P IL, IMA 0 F WIS 6"Itet
Itojur I* tbmil of
on ads f as cOwt 0
tbn;l = ml(~
i. ZW-- p is Cos. Homm-f-
yjrid (2&-36%1, ME: "by :rwtd'v z.c I. I-. - I.. 15
thm" that ebtabod ja adintim by C(h. Aed"110"
OW P" shod mmtk*l "Suits. The
with w" LN-14 at gwo Wde SwIler.
of c who, butios Wwfdw with
Ob t bated with ZoCU yielded C
the t t F was 0.& c4 do Ud tyW
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F ((QWT 'cl 4.g., 1:001
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nd ftow KP A~~ , I
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gmt the an to tonow wwdft abo.
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Pon ). "W aymbau mor" -, 14' am It',
AVA its limiting traw (cc./C.): 0 Z~ ttur
vca. d.W.
Me staaolard submancor. brattinch 8
the pw*4w distsitiotOon; a - the Amt, Adeowbad
ma-4.); 0/0. - 'be rd&tivv l"emel 0 :4 /M
TW. of tb*=
arou I Wairt Is (a V"Y the Palm-
The aim ud Ir
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cfit tbe=T far the am ;Wa- y4's-doomy(C.A.
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4 Al I'
till
plo
I'l I .. .6 rp"I
auto (witit.) dold 6 the V,411 flort %,44k I fmil.
The g&2 ThotmM Is itthytrite. foot wheh J, - *.;'.I - 4,11.
A471,1," In vvwAiuved at 20% hetween I and *11) tum. on
12 h., 3 7yins, sclivalrof lqzri~ 111VVICIrtits in
coth. F4,10,11 11116"t (3). W. anti omn= .111"i"In
Mclvrc &-ed - H - Mh-d#J 1:1 x 110 P0431~whroor
R - kIg ( W11/6) 0) 4114 F - 0.115 k I '.~ 0# 111 L I ItoP A4-
Morptim Wootherns (3) is verifie'l by p1cotting the t-zptl. flat&
in a log a. (k# 2.12 X ILO/p)f diagram: straight lints ate
obolahted which fit the dAta betwev Ih avid p%; h - 1, 8.
10. MU. 75, tw 101) deproading an the chour4ml, p, - I(K) for
nil FAMpkS, Iletilt"O WISIMplixi it Mot 111fallorr4l ill 211*
OU fit* VdInt IM11114CIR in CWJCf tot 4141. 1$'# AM) It frOM CqWA6rJG
M, Then. forum the value of 0 and from It - B!(2.IU Nis
k to deid.; from It and (7) 0 for ttbv!e" is
abuked The oraluom al 0 for the diffevert ftmpln ate
I I%) around a taws value ILM. This to in
-5 vvclnent with the th"WrInany "Id. Value toof
(Pcmj I'L,.u.) - 0.40. where P is t he perwbur (C.A - 44,
MIM). Frunt E, The Value 01 14'. is aho det4, WA cam-
to K*# as detd. from benteone advaqotbna; the ratio
= loom values for the diffe"!nt sampka awMateff between
toothey wiole katits (+15%). The agirvoruwat with the
theory is thus good but only seadquant.. owing to the ap-
pecamulico" Involved In (3) and (41. M. itaud4n

AdemPUes of 44"s by "tivo cubms. A4. M. Dummalm
and H. D. /Lav*rinal. PAUdy Abod, AWY-fiff.
72. -Tbr equAtium #A the adaur"We hffi~
threat sWirable to arlittv cArtions of the lot ~*-*J
type. ie. with rrt4tivtAy Ane makeopmetis. a - (111`6/0 .
call, kit WO.) 11. wheft W I - limtkists vw,
4 the *dMisillion Ikker. v - MA. few. of the v_qWmrd
and The ct a esp. I-4(#/
ft 1.40110 the m'.1114,11
mimarption Imormol a. wvtv tested by Has thavail k
1.01.4 1,41P)JO. article R till ( 9V I
F N - k
its i,tAttun 6 (lecived ous the
&W,rc Adamp6m iwjttwftu witb the aid of lkftayi's
(C.A. 14, 24:111) miatico,
&1 WMAW COM-) OW 4 (W-Immirl - 4.37 r WS
.4 r
RNA r27#?f9 istd=fly, 3bett"'Oulk!
"all. fail) of slanalaeato activation (Small maot
&M). is (Ime admorp" of Call. srolelf Celle vagmat a#*.
rVelft she graipwally drili. "Mo. 11, 11W c'. %_ 6 Mill,
mk4l. I
b-4.;g (/M& (IF0111111HOtIll. 11 ).1lWhlfrAliW.I
10"hellm Illml It" Cliff latmusi kid a -
poo 12.12 x 1 /0)10. witha in madfininks/g. And
in am. Its; it MWS m a~]O to 4(X) Ines. 114 (UPW
Ut CC the =.). From the mots, P lot clift, MA a
for Ceffl. the ty comelf. 0 (ratio of # of CIf. and of Cal I.
&I equial is found - O.U. "is chorks satim(Aclucal
with 0 ITPe - 0.49 r4fi-d. (nwit the j,4rwkt*. 11 J
Cliff and 110 C4 C*I If. 'j ILI..

Methods of stud3ring the structure of bLig-hly dispersed and porous bodies;
transactions of the corScrmce of June 25-29., 1951.
QR 473-A6
1. Porosit,.r. 2. Adsorption.
I. Dubinin, I-likhail l-Likhailovich, 1901 - ed.

J" Mrtiti&tidli Of tfie- Adsorption of Bqazew vapoi
-:Oa 'AatI4ite&-da;bon'Blackp". Acad M. M. Dubinin
DIP
f
.*Wk Ak WgLuXISW Vol UCKVJ 555-558
nonpoirous cMnnel black Spheron Orade
h L.tj"- U= at 1,0000,
la- ex 09, -vac: Vat progres-
0
o'
-,,at 9 'di
6 ve oxide by,
4 adtlyat ~5O..~ vith carbou
11-3,21-1, 55-lP s~A
'Adi shd"d that adiarptl6i
-face of
-20,t .$.Adiorptioa by pore Sur
pordue, -Ciiiiony "teio
Pe4~ ln~ addo to of-. 9d.
-T!
Alon (Contd)- 1 Ireb 51-1.
Adsorp
type Oy nonporous carbon) as result of activatiodp''
proving formation of porous structure.

Yommovicy, redaktor; DUBINIS M.N., akedeaft.
. rettaktor; KOZWY, T.Y., proremmor, rodaktor; PIWORtyrrr.
professor, redaktor; BANKTITSIR, A.L., redaktor isdatel4stya; ~Axmijl.
TOOT*, takhnicheakiy redaktor
Duitrii Ivanovich Mendeleev-, his life and works] Duitrii Ivanorich
Mendeleev; shisn' I tmdv. [Moskva] 1957. 254 p. (MLRA 10:2)
1. Akedemiya.nauk SSSR. Otdolenlye khinichaskikh nauk
(Mendeleev, Dmitrii Ivanovich. 1834-1907)

DUBININ M. ~L
==:=:=U-
"Surface Properties and Pore Structure of Carbon Adsorbents"
(Section 10) a paper submitted at Industrial Carbon and ewq*tft Conference,
24-26 SeP157, loondon. , &"tur
C-3,800,117

L)ki In I" IN-) / I Y I -M -
USM/Physical Chemistry - Surface Phenomena, Adsorption) Chmato-
graphy.. lon Xnterch&W. B-13
Abe Jour: 'Referat. Zhurz,1111 jk' 2,11958.0, IOU.
Author : M.1j.-MADID.
inst :-Ka-idemy of Sciences of USSR.
Title Letter to The Editor.
Orig Pub: Izv. AN OR,, c+A. khin. n-P 19M No 3P 392.
Abstract: Mie SwlicsbilitY of the isotherm equation of Dabinin and
Pjtftsbkevich was established on-the basis of a careful experi-
mmtal determination of adsorption isotherms Of C06 vapors at
200 and Of 92 at -1950 on activated carbons (AC) of the lst
structural type. This permits to apply the method of "mole-
cular probes" to the experimental determlnation of the distri-
bution of AC micropore volumes according to their dimen ions,
if a set of substances with more or less globular molecules
of various dimen ions was at hand, because the border volume
Card 1/2 -15-

') t V: I ~,_; I
vu h
UWPhysical 6emistry - Mrface Phenomena, Adsorption, Chromato-
graphy) Ion Int4rchange. B-13
Abs Jaur: Iteferat. 2birmal Mdmiya, Wo 2, 1958) 4015.
Author :-M.M. Du:~iAlpl-Ye. D. Zaverinap D.P. Timofeyev.
Inst : Academy of Sciences of USSR.
Title :Adsorption Properties of Carbon Adsorbers. Report 1.
Amalysis of Earlier Obtained Experimental Data.
Orig Pab: Izv.AN SSSR, Otd. khIa. n.., 1957p No 6., 670-6TT.
Abstract: adsorption data referring to 12 different sub-
stances on two activated carbon specimens were analTzed in
detail and a good conformity with the e3Werlence vitb the
earlier developed potential theory of vapor adsorption on adsor-
bers with heterogeneous surface was shown. The part of the car-
bon structure in the adsorption process was made clear and it
was shown that in the case of well adsorbed vapors (activity
factor (J~-1.5), the degree of filling (F) of the rdcropore
Card 1/2 _19-

UM/Physical Ch~Ltry Surface Phenomena., Adsorptiony Chronato-
graphy, Ion Interchange. B-13.
Abs Jour: Referat. Zhurnal Rhimiya, No 2., 1958, 4ol4.
Author B.P. Bering, M.M. Dubinin, Ye. G. Zbukovskaya, A.I. Sakharor,
V-V. Serpinskly----
Inst
Title Study of Porous Structure of Solid Bodies by Sorption Methods.
III. Gravimetric Methods of Measuring Sorption and Desorption
Isotherms of Nitrogen and Benzene Vapors.
Orig Pub: Zh- fiz. 1rhimli, 1957, 31, No 3, 712-716.
Abstract: With a view to select and substantiate the most rational methods
of measuring Isotherms of vapor sorption (IS) on solid bocUes,
an improved vacum installation vas constructed; this inst&Ua-
tion permits reliably to take down the IS of N2 at a low teape-
rature and the IS of benzene vapors at the room temperature by
the gmvimetric method. The IS-s determined with the described
Card 1/2 -17-

, 'DMWphysical Chemistry - aarface Phenowns., Adsorption, Mzvmto-
gmphy, Ion Interchange. B-13
Abs Jour: Refexat. Murnal Miimiy&,No 2, 1958, WA.
insta.Uation for N2 at -1950 on silica gel and for benzene
va.pore at 2DO on a"Iyated carbon coincided precticLUv with
corresponding IS-s taken dovn by the valumetric 02) or gravi-
metric methods by other authors on other installations. (See
Part II in FMMlimp 195TP 26362.)
Card : 2/2 -18-

lJoglIll"I",0lt'~ /"
DUBININ. M.K.t ZHUX, G.S.; ZATMINA, Ts.D.
Studies on the porouB structure of solids by adsorption methods.
Phrt 4r On the relation between various types of pores in active
carbon [with summary in IMIIsh]. Shur. fis. khtm. 31 no.5rll26-
1135 Mr 157. (MIR& lotil)
1. rnatitut fisichakoy khinii AN SSSR.
(Carbon, Activated) (Adsorption)

ef h 1"41 1 -C~ 4r/. -0/,
USSWPhysical Chemistry - Surface Phenomew, Adsorption, Chrowato-
gm]*yp Ion Interchange. B-13
Abs Jour: Referat. Zhurnal FbIalyao No 2,, 1958,, 3995-
Author B.N. Vasillyevp B.P. Beringp N.M. Dubinin, V.V. Serpinskiy-
Inat Acadeqr of Sciences of USSR,
Title Study of Adsorption Under High Pressure.
Orig Pub: Dokl- AN SSSRp 1957, 1141 No l.- 131-134-
Abstract: The COp adsorption on two silica gel specimens in the range
from --85 to +400 and under the presm2re of from 0 to 85 atm
was studied using the instrument described earlier (FMhXhim,
1957p T4T86). The adsoqtion hys&eresis loop is observed
only inothe range from -W to -2D . The isotherms of -30
and -50 bring to a not coinciding distribution of pore volumes
according to their radii. The total substance cmtent a differs
noticeably under high pressures from Gibbs' adsorption. It is
shown that the mean density % of C02 in the adsorbed state
Card V2 -5-

USSR/Physical Chemistry - Surface Phananena, Adoorptionj, Chromato-
graphy, Ion Interchas, . B-13
Abs Jour: Referat. Zhurnal Rhimlys, lo 2, 1958, 3995.
is greater than the density of a normal liquid (for exe le,
by 14% at 250). The dwaacteristic curves of the potential
adsorption theory depend somewbat an the teaWeratum near
ter (0 and 250). At the computation of these curves by VV and
I w only one and the saw curve is obtained for all the tem-
pearatures including 0 and 250. The breaking point observed on
the adsorption Isosters; is explained as an indtastion of a phase
transition Of C02 in adsorbed state - "two-dimensional crystal-
lization analogue." The capillarily condensed substance in the
soTion space is in the state of supercooled liquid down to
-85r .
Card 2/2 -6-

WKW1911CH) Vs 149) E1T11r-111,-M.-14 ., LSONVUN, Ye. A., SARACHOV, A. I.
"Examination of the Porous Structure of Activated Charcoals."
Paper submitted for presentation at Fourth Int'l Conference an Electron
Microscopy, Berlinp GFR, 10-17 Sep 58.
Institute for Physical Chemistry, USSR Acad. Sci. Moscow.
C-3,800,829, 25 Jul 56-

J, ' - ,. , ,-- -
"iE'S1'S"H'V'1"U" G. V'.; )MWOLMO, 0 F.,
If
"The.adsorption from vapors and Uq7.lids.
report presented at the rourth All-Unicm Cmforews an Colloidal Cbsuletry,
Tbilisi, Georgian 3W, 12-16 May 19% (Yoll ibix, 20,5, P..6-77-9, 158, Taubman, A.B)

DBININ,#A., skad..oty. red.: RAZUKOVA, L.Le, red. Ird-va,; MARKOVICH.
S*M., tekhn. red.
[Methods of studying the structure of highly-dispersed and porous
materials; proceedings iDf the conforencej Metody iseledovanie
etruktury vysokodisporenykh i porietykh tel; trudy soveshchaniia.
Moslcva, Izd-vo Akad. nauk SSSR. 1958. 294 p . (KIRA 11:12)
1. Soveahchaniye po metodam issledovaniya struktury vysokodisperenykh
i poristykh tel. 2d. Leningrad. 1956.
(Porosity)
(Ad lorptidn)
(00%*blds)

AUTHORS: Dubinin, M. X., Zhukovskaya, Ye. G. 62-58-5-2/27
TITLE: On the Adsorption-Propertiea of the Carbon-Adsorbents
(0b adsorbtsionnykh evoyetvakh uglerodnykh adsorbentov)
Communication 2: Investigation of the Adsorption-Propertiee
of Active Coals by Benzene-and Nitrogen-Vapors (Soobehoheniye
2. Iseledovaniya adeorbtaionnykh evoystv aktivnykh ugley po
param benzola i azota)
PERIODICAL: Izvestiya Akademii Nauk SSSR Otdeleniye Xhimicheskikh Nauk,
1958, Nr 5# pp. 535 - 544 (UhSR)
ABSTR"T: As is known, nitrogen-and benzene-vapors are used as standard
substances for the investigation and classification' of the
adsorption-properties of active coals. Up till now, a con-
gruence of the adsorbing properties of active coals above
nitrogen-and benzene-vapors has not yet been found, however.
The purpose of this work is the investigation of this problem.
The adsorbing properties of some samples of active coals above
benzene-vapors at 2o C and nitrogen-vapors at -1950C were in-
vestigated above all. It was found that in both cases the ad-
Card 1/2 sorption depends on the dispersive interaction of the molecules

On the Adsorption-Properties of the Carbon-Adsorbents. 62-58-5-2/27
Communication 2: Investigation of the Adaorption-Properties of Active Coals
by Benezene-and Nitrogen-Vapors
(of the vapors) with the surface of the active coals. The
coefficient of affinity of the characteristic nitrogen-ourves
was calculated. The fundamental causes of the difference of
the adsorption-volumina. of nitrogen and benzene for the points
of the beginning of the hysteresis of the isothermal lines
of adsorption were analysed. More rational methods of volume-
-determination of the micro-and transit-pores (perekhodnyye
pory) of active coals were described and substantiated. The
problem of the selection of a standardized vapor for the
characteristic of the adsorption-properties of active coals
was discussed. There are 4 figures, 6 tables and 21 references,
17 of which are Soviet.
ASSOCIATION: -Institut fizichaskoy khimii Akademii nauk SSSR (Institute
for Physical Chemistry AS USSR)
SU13MITTED: March 13, 1957
L.Activated carbons--Adsorptive properties 2. Vapors--Adsorption
Card 2/2 3. Benzene--Applicationir 4~ Nitrogen--Applications

ADTHORS: Ka-'leta, 0., Dubinin, 11. E. SCV/6 2 -;, 0 - 9 - 3 /2
TITLE: Investigation of the Kinctics of t,e Thermal Dc-co..-,po3ition
of Solid Materials (Iosledovaniye kinetiki
razlozheniya tverdykh voohcheetv) Communication 1 T'.
Thermal Decomposition of Lead Carbonate (Soobs-.cheniye 1.
Termicheskoye razlozheniye uj;lekislo.-o ovintsa-)
PERIODICAL: Izvestiya Akademii nau? SSSR. Otdeleniye khimichcckikh nau;:,
1958, lir 9, PP 1031 - 1036 (USSR.)
A3STRACT: In the study of the kinetics of the thermal decomposition
of solid materials two methods were employed: the gravi-
metric method and the manometric method. Both methods,
however, have deficiencies. The authors t"rierefore
investigated the kinetics of the thermal decomposition
of solid materials by weighing the Gaseous reaction
products which were adsorbed onto cooled activated char-
coal during the reaction. This method makes neastire7ent
at reduced pressure possible, but care must 'Le taken
to always maintain a good supply of heat throu~,hout the
experiment. The decomposition of the lend carl-on.-Ao pro-
Card 1/2 ceeds at a rate proportional to the sur~'ace area of the

Investigation of the Kinetics of the Thermal S07/62----8-5-7/26
Decomposition of Solid Materials. Communication 1: T,ne Thermal De-
composition of Lead Carbonate
undecompoood material (without the auto-catalytic
effect of a solid reaction product). The activation
energy of the thermal decomposition of the lead carbonate
and the factor of the exponential function were calculated.
The activation energy was found to be 41 500 cal/nolo,
while the magnitude of the exponential fac or V"'Is Cal-
culated to be (0.5 � 0-5).1010 9-cm- ..Vec- . There are 4
figures, 1 table, and 4 referenceo, 1 of -.7rich is Soviet.
ASSOCIATIOIN: Fiziko-matematicheskiy fal:ulltet Karlova universiteta v Pra.,-,e
(Dept. of Physics and Mathematics of Charles Uni,,erzity,
Fra_-ue)
SUBMITTED: April 17s 1958
Card 2/2

AUTHORSt Nikolayevt K. M.9 Dubinin, bf. U. SOY/62-58-10-2/25
TITLE: The Adsorption Properties of the Carbcn Adsorbents
(Ob adeorbtbionnykh svoystvakh uglerodnykh adsorbentov)
Information 3,- Investigation of the Adsorption Isothermal
Lines of Gases and Vapours on Activated Charcoal Within a
Wide Temperature Range Including the Critical Range
(Soobshcheniye 3- Issledovaniye izoterm adsorbtsii gazov i
parov na aktivnykh uglyakh v shirokom intervale temperatur,
vklyuchayushchem kriticheskuyu oblast')
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1958, Nr 10, pp 116r--1174 (USSR)
ABSTRACT: As only some of the data worked out in this field contributed
to the solution of the problem of the physical adsorption of
substances in gas or vapor phase on adsorbents of diverse
porous structure, the authors of this paper investigated the
wide, temperature range including the critical range with
respect to the adsorption isothermal lines of nitrogen,
krypton, xenon, tetrafluorethylene, and hexafluoropropylene on
two types of activated charcoal that belong to the outer
Card 1/3 members of the series of activated charcoal of the first

The Adsorption Properties of the Carbon Adsorbents. sov/62-5e-10-2/25
Information 3.- Investigation of the Adsorption Isothermal Lines of Gases
and Vapours on Activated Charcoal Within a Wide Temperature Range Including
the Critical Range
structural type. As a result of the analysis of the
experimental data and the investigation of the properties of
the state of the adsorbed substances within the range of
critical temperatures the authors proposed rational methods
of determining the characteristic adsorption isothermal
lines of substances in vapor or gas phase. In agreement with
the potential theory of adsorption the coefficients of the
affinity of the characteristic curves do not depend on the
carbon structure; the volumes of the adsorption space have
to be regarded as constant quantities for each activated
Charcoal if no ultra-porosity effect �s present. Equations
for the adsorption isothermal lines for the vapor and gas
state of the substance to be adsorbed in the phase of
equilibrium. volum9s were proposed for the activated charcoal
of the first structural type; these equations correspond to
one and the same equation of the characteristic curve. Theae
equations of the adsorption isothermal lines are
Card 2/3 experimentally founded. There are 9 figures, 2 tables, and

The Adsorption Properties of the Carbon Adsorbents. SOV/62-58-10-2125
Information 3-- Investigation of the Adsorption Isothermal Lines of Gases
and Vapours on Activated Charcoal Within a Wide Temperature Range Including
the Critical Range
23 references, 6 of which are Soviet.
ASSOCIATION: Institut fizicheekoy khimii Akademii nauk SSSR
(Institute of Physical Chemistry of the Academy of Sciences,
USSR)
SUBMITTEM May 179 1957
Card 3/3

WBrip, Ml~,~kadezlk
A .
The order of tha.day is the organization of the amteur-cheidets'
movement. On. takh. 3 no.llzl-3 N '58- (MIRA 11:12)
I (Chemists)

76-32-5-33/47
AUTHORS: Dubinin, M. M., Nikolayev, K. M., Sarakhov, A. I.
TITLE: Using the a-Ionization Manometer iA Sorption Investigations
(Primeneniye a-.ionizatsionnogo manometra v sorbtsionnykh
icaledovaniyakh)
PERIODICAL: Zhurnal fizicheskoy khimiiq 1958, Vol. 32, Nr 5, PP-1155-1159
(USSR)
ABSTRACT: In order to avoid the many disadvantages of mercury manometers
in measurements of sorption-investigations a variant of the
a-ionization manometer was developed under collaboration of
the Radium Institute of the AS USSR; this manometer was pro-
duced and used in the present investigations. From the dia-
grams and the description can be 3een that radium was used
as radioactive source, which was laid in a thin layer on a
plate-shaped base of gold, this production having been made
by the RIAN of the USSR. The dimensions of the ionization
chamber depended on the field of the pressure measurements,
with two chambers present for a wide field of pressure
Card 112 (1.1o,,4 to 1000 torr), one for high and another for low

76-32-5-33/47
Using the a-Ionization Manometer in Sorption Investigations
pressures. A scheme of the amplifier plant which is an altera-
tion of that described by Downing and Mellen (Ref 7) is also
given. The d?qoribed manometer has a measuring sensitivity
of 2.o . 10" A/ torr in the interval from 1.1o-2 to
150 - torr and is calibrated according to an Hg-manometer,
with a measuring accuracy of a mean value of 1 - 2.% being
achieved. The measurements carried out with nitrogenf~krypton
xenon and tetrafluorethylene on coal showed, compared with
measurements by means of Hg-manometers, a good applicability
of the a-ionization manometer for investigations of adsorp-
tion phenomena. The described manometer is an experimental
apparatus and still has to be further developed. Finally the
authors thank Professor V. M. Vdovenko and D. M. Ziv, as well
as Ta. Yu. Rib. There are!6 figures and 11 references, 8 of
which are Soviet.
ASSOCIATION: Akademiya nauk SSSR,Inotitut fizicheskoy khinii Moskva
(Moscow.Institute of Fhysic3 and C%cmiatry; j AS UY~R)
SUBMITTED: -TulY*17v 1957
Card 2/2 Manometers--Design 2. Alphaparticles--Ionization
effects 3. Ionization cha-mbers--Performance

AUTHOR3 i
nilhj 64AL Jd. M.F Sarakhovp A. I. f SC7/ 76-32-6-32/46
Ry a b i k 6'Iff-1w
TITLN's Methods and Techniques of Physico.ohemical Inveatigations
(Metody i tekhnika fiziko-khimicheakogo issledovaniya)
A Low-Pressure Poremeter (Yoromer nizkogo davloniya)
PERIODICAL: Zhurnal fizicheskoy khimii, 1958, Vol- .52, Nr 6,
PP~ 1404-1406 (USSR)
ABSTRACTs In order to make possible measurements of pore size in
porous materials of 100 4 and less S. A. Semenova (Ref 3)
designed an apparatus which, however, has several
disadvantages. A poremeter is described which does not
have these deficiencies any morel the possibility of
investigation in secured at 5 - 1000 torr, i. e. at a
pore radius offrom 5 to 100 P- A diagram of the apparatus
is given as well as a description of the technique employed.
It may be seen that the dilatometer was somehow changed by
introducing a chromium-nickel wire, on the other hand the
principle of measurement consists of the fact that mercury
Card 1/3 enters the pores of the sample and that the experiments

Methods and Techniques of Physicochemical SOV/ 76-32-6-32146
Investigation6. A Low-pressure Poremetor
may be carried out within a wide pressure interval of
from 30 - 50 torr. In the measurements it must be taken
into consideration that also the in-between-spuce of the
sample and of the ampoule is measuredl in order to obtain
the real values of the porosity special experiments with
model substances must be carried out. The dilatometer can be
used for low-pressure- as well as for high-pressure-metere.
For both measurements the same sample may be used. A
diagram of the measurements carried out with the high-
-pressure instrument of the PA-4 as compared to those of the
described poremeter is given. rinally the authors thank
V. V. Serpinskiy. There are 3 figures and 3 references,
3 of which are Soviet.
ASSOCIATION: Akademiya nauk SSSR)Institut fizicheskoy khimiiMoskva
(Moscow Physics. Institute
.,AS USSR)
SUBMITTEDt July 17, 1957
Card 2/3

Methods and Techniques of Physicochomical !'6-:32-6-32/46
Investigations. A Low-Preacure Foremeter
1. Materials-Porosity 2. Chemical analysis-Instrumentation
Card 3/3

A
5(4)
AUTHOPS: 1.16skvitirt, 11. N., Dubinin, M. 141., SOV/2o-122-5-26/56
Acaclem ician, SaraTTo-v,-1-.T-.-----
TITLE: The Adsorption of Water Vapors on Crystalline Powders
of Halogenides of Silver an(I Lead (Adcojbt::iya parov
vody na kristallicheakikh jporoshkahh ~:%loZenidov serebra
i svintsa)
PERIODICAL: Doklady Akademii naul: SSSR, 1958, Vol 122, Nr 5,
PP 840 - 843 (USSR)
ABSTRACT: The present paper compares the isothermal linez of
adsorption on the typical r-Dpresentatives of the
crystal groups mentioned in the title for a sufficiently
wide temDerature interval. T'ie isot-ermal lines
of t-He ndsorztion of riater vapors were investiqated
by meano of quartz microocales. Preparation of the
'33r'ciits for the experi.,-.ients is discussed in :7hort.
Work with A,,-,J and AgC1 was carried out red
The weiC;1-it of the adsorbents amounted to from 0.75-0-8 U-
The isothermal lines of the adcor,ntion of viator vFe--,c
Card 1/4 measured at 20, 10, 0, and -200 on the crystals of AqJ

The Adsorption of Wter Vapors on Crystalline Powderc SOV/2o-122-5-26/56
of HaloGenides of Silver and Lead
n,
nd A-Cl. All isothermal lines found in thic manner
,
(type II according to the cla3 -4-fIcation ',-.,y Drunauer)
are reversible in the entire intorval of
pre.r.surco and cire fully reproducible ~.t -.11 tomj)cratures.
This ap;)lies no matter vihot.-ier tlc sanplo had been
heated before measurement or not. Thc '.ieat efi*ect
of the adsorotion of water has a vi.~Iue si.-Alar to a t,
of conden-sation heat. The i!;othermal lines of the
adsorotion of water on AgJ and ACCl are descriled
In the ranCe of relative preosure~s of 0.05-0.4 by
the equation of polymolocular ,doorption 6iven by
Brunauer, Em~-ict, and Teller. 11ext, some characteristic
features of the sorption of water on silver iodide
and silver chloride are described. Particular interest
io cati-led by Ue problem of the phare state of t".0 0
water adsorbed on A[;J -~nd A(,-Cl at temperatures below 0
Two diu~;rama show the ioogteric lines for variOU3 valuee
of ad_-.orption on A,-J :ind ACC1; they -aerc calcul.,.ted
Card 2/4 from t';'.O isothermal linen for the tomper-.tures 20, 10, 0

The Adsorption of Water Vapors on Crystalline Powders SOV/2o-122-5-26/56
of HaloE;enides of Silver and Lead
0
and -20 . All isosteric lines for AUJ concist
of 2 linear parts, which intersect in a temperature
in+erval no--- 00. The salient points of these curves
co;respond to the molting of the iron. From the
difference between the anGles of imlination the value
1450 kcal/mol is obtained for t',-.e heat effect of
the transition. The isosteric lines of the adsorption
of water va-)or3 on A-Cl have no slalient point. There-
fore, the hent ef-,'ect of' the adoo1%,Aion at positive
and nel,-ative temperatures is practically equal to
the heat of condensation. In the zorption of water
on PbJ2 a non-equilibrium system vapor adcorbent
was in all caues concerned.There nre 4 fiGures
and 13 reforences, 4 of which are Soviet.
ASSOCIATION: Institut fizicheckoy khimii Akadomii nauk SSSR (In-
stitute of Physical Chemi:3try of ti-e Academy of Sciences USSR)
Card 3/4

is!
1 a ; I fill%
.7 IL
i
pi I
j Liz,
v Vim
qq!~.jj%ei p.
31 1-0 JOHN, a '--Tau.
21 -i ' I '9Z . it
o. 11 .. ..
0 4 pul
us
ve Vil
J%- jig,
I lit!
is

5 (4)
UTHORS.-
A Bering, 'B. P., DubigU M
SOV/62-59-6-5/36
Serpinskiyj V*" V.
TITUt Calculation of the Differential Heatsof Vapour Adsorption on
Active Coal (Vychicloniye differontsiallnykh teplot adsorbtaii
parov na aktivnykh uglyakh)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 6, pp 981-988 (U-SUR)
ABSTRACT: Besides applying other methods, the differential adsorption heat
may thermodynamically be calculated by means of amodelof OB Maoiltim
interaction and the theory cf molecular forces. in a previous
paper by the authcr (Ref 1) it was shown that according to the
potential theory of adsorption the differential heat of an
adsorption isotherm may be computed by the following equation:
q ~m OLRT2 fol In h
- RTlnh (1). Here q denotes the total,
k-
)
,?1na
T
and q the pure differential adsorption beat, %the latont
vaporization heat, otthe thermal coefficient of the spatial
extension of the adsorbed substance, a the adsorption, and h-p/p
.
the relative pressure. The characteristic curves of the volume
Card 1/3 distribution for inhomogeneous adsorption surfaces of different

Calculation of the Differential Heatsof Vapour SOV/62-59-6-5/36
Adsorption on Active Coal
type, in the present case active coal, on the adsorption range
are known from publications. These curves lead to equations for
the adsorption isotherms of different structural types.
BT2 (lg h) 2
(Equations 4 and 5) a = "Yo e 62 M 4)
v
AT lg h
Woo (II) W- Here Wo (Wo') B (A) denote structural
v
characteristics of the adeorbents, P the affinity coefficient,
and v the mole volume. Based upon the equations 1 and 4, or 1 and
5, a term for the differential adsorption heat of vapour of
different substances on active coal may be set up. For the
purpose of facilitating the computation, this equation was
established in variable 9 (of the filling degree of the micro-
pores). By following this equation the differential adsorption
heat at different numerical values 9 was computed for a number
of substances on a standard adsorbent at different temperatures.
Card 2/3 Active coal of the type (I) served as standard adsorbent. The

Calculation of the Differential Heatsof Vapour SOV/62-59-6-5/36
Adsorption on Active Coal.
values obtained for q are given in a table. A figure shows the
dependence of q on 0 for normal heptane, hexane, and pentane.
in an analogous manner the equation holding for the differential
adsorption heat on coal of the second structural type was derived.
For the first type computations of the adsorption heats of
different hydrocarbons were carried out (Table 2). For this
computation it was necessary for the two structural characteristica
We, B (Wo', A) of the adsorbent, tabular values on the pressure
of the saturated vapour, its mole volume, its parachor, and the
thermal coefficient of the volume distribution of the substance to
be adsorbed to be known. Finally, an approximative calculation
method for the differential heat of the alkanes on adsorbents of
the-first structural type was worked out. There are 1 figure,
2 tables, and 12 referencesq 10 of which are Soviet.
ASSOCIATIONs Institut fizichaskoy khimii Akademii nauk SSSR (Institute of
Physical Chemistry of the Academy of Sciences, USSR)
SUBMITTED: October 24, 1957
Card 3/3

-5.4100 77059
GOV/62-59-12-3/43
AUTHORS: Moskvitinj N. N., Dubinini M.-M., Sarakhov, As 10
TITLE: Study of Adsorption of Water Vapors on Ionic Crystals.
Communication I. Methods and Results of the Study of
Water Vapor Adsorption on the Crystals of' Silver
Iodide and Chloride
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimiche3kikh
nauk, 1959, Nr 12, pp 2080-2087 (USSR)
ABSTRACTt The authovs studied isotherms of adsorption and de-
sorption of water vapor on crystals of silver chloride
and iodide (which can be used as active centers in
cloud seeding) for the temperature interval (+20 to
-20'). Bering and serpinsIcty microbalance Z-B. P.
Bering, V. V. Serpinskiy) Doklady Alcad. nauk SSSR,
94,, Nr 3. 497 (1954)_7 (sensitivity �2.5-1o-7 g)
provided with a special adjustment to eliminate
electrostatic effects CA_ I. Sarakhov, Doklady
Akad. nauk SSSR, 112j r 3., 464 (1957)2, was used.
Card 1/7 It allowed one to measure adsorption on 0.7-0.8 g

'Study of Adsorption of Water Vapors on Ionic 77059
10
Crystals. Communication I. Methods and Results 11/6-2-59-12-:~
of the Study of Water Vapor Adsorption on the
Crystals of Silver Iodide and Chloride
Damplea of adBorbents with the opecific surface of
0.015 2 Every sample was preheated on the balance
pan atmllgO11200 for 8-10 hr to de3orb the substances
adsorbed from the air. All manipulations of silver
halides were performed under red light. The obtained
isotherms are all of type Il of the Brunauer classi-
fication (Figs. 1 and 2 show the adsorption isotherms
for AgI). The adsorption Isotherms for both AgI and
AgCl are reversible in the whole interval of measured
relative pressures, except for the isotherms at -200.,
which are reversible only up to the pressure of vapor
saturation at that temperature, I. e., 0.77 nim. Above
that pressure, desorption points lie on the curve
which is above the adsorption curve, both curves forming
a hysteresis loop. Values for specific surface (S)
of the powders and for the volume of' monomolecular
layers ( aM) were calculated from the corrected
Card 2/7 isotherms (curves 2) for 200, ;qh1ch were calculated

MJ -1 -6.4 1-9
sov/62-59-12-3/43
lot too
V 0
V
0 40 40 of P/Pj
0
Fig. 1. Isotherms
of Water vapor
adsorption on
silver Iodide at
20, 10, and 0 0 .
In the upper left
the beginning sec-
tion of the 200
isotherm is 3hovm
on a large scale.
Card 3/7
4s 4j 46 1 P/P$
77059

77059 sov/62-59-12-3/43
'P"WV
Card 4/7
Fig. 2. Isotherm of water vapor
adsorption on the crystals of silver
iodide at -200.
from the linear equation of the multimolecular
adsorption2theory. For AgCl, a m = 0.54 4 moles/91
S2= 0.08 m /gj for AgI, am = 1.32 ~L moles/g, S = 0.2
m A. Adsorption isotereoof AgI build for the
values of a (a = adsorption) from 1.5 to 3-0 4, moles/
A (see Fig. 5), and show an inflection at 00, in-
dicating phase transition at that temperature. The
C
difference in slopes of both linear sections of the
curves determines heats of transition (fusion of ice),

Study of Adsorption of Water Vapors on Ionic 77059
crystals. Communication 1. Methods and Results SOV/62-59-12-3/43
of the O,tudy of Water Vapor Adsorption on the
Crystals of Silver Iodide and Chloride
which equal 1,450 cal
63 P mole*
Fig. 5. Inosteres of water vapor
adsorption on silver Iodide in
the temperature interval (20)
(-200).
Card 5/T

Study of Adsorption of Water Vapors on Ionic 77059
Crystals. Communication I. Methods and Results so'V/62-59-12-3/43
of the Study of Water Vapor Adsorption on the
Crystals of Silver Iodide and Chloride
Comparison of the iaosteres shows that there is no
increase of the heat of transition with increasing
value of a, indicating that the phase transition
does not take place in the total mass of the adsorbed,
water, but only in the upper adsorption layer.
Adsorption isosteres for AgCl do not have this inflec-
tion, indicating that all the water, adsorbed on the
crystals of AgCl at -200, is in a supercooled state.
This difference--the existence of phase transition
in the water adsorbed on AgI, and its absence in
water on AgCl--can be connected with behavior dif-
ference of these aerosoles when they are used cloud
seeding. There are 6 figures; and 18 references,
8 Soviet, 1 Oerman, 1 U.K., 8 U.S. The 5 most recent
U.S. and U.K. references are: S. Birstein,, J. Meteorol.,
12, N 4,11J24 (1955); V. Shaefer, J. Meteorol.,, 11,
417 (195 ; E. Fournier, D * Albe Quart. J. Roy.
Card 6/7 Meteorol. Soc., 75, N 323, 1 (1949); B. Vonnesut,

Study of Adsorption of Water Vapors on Ionic 7705
Crystals. Communication I. Methods and Results SOVY62-59-12-3/43
of the Study of Water Vapor Adsorption on ".,he
Crystals of Silver Iodide and Chloride
J. Appl. Phys., 18, N 7, 593 (1947); W. Patrick,
W. Kemper, J. Phys. Chem., 112, 369 (19381).
ASSOCIATION: Institute of' Physical Chemistry of the Academy of
Sciences, USSR (Institut fizicheskoy khimii Akademii
nauk SSSR)
SUBMITTED: April 23, 1958
Card 7/7

5(0)
AUT110113i Aetakhovt K. V., Dubinin, M. ht.# sov/76-33-1-43/45
-
Chmutov, K. V. , Nerr-as-ov-7r.-T.
TITLE.,
-
Sergey Aleksandrovich Votnesenakiy (1892-1958 Obituary
~
(Sergey Aleksandrovich Voznesenskiy (1892-1958
)
PERIONCAL-. Zhurnal. fizicheskoy khimii, 1959, Vol 33, Nr 1, pp 234--237
(USSR)
ABSTRACT: S. A. .-doctor oC chemical sciences and
commercial Of' the first degree, died on August 6,
1958. A8 a student, Vozne3onsk--y worked in the laboratory of
Professor N. A. Shilov and was occupied with active carbon for
gas masks for the elaboration of the method by N. D. Zelinskiy.
Later on, Shilov sent him to the kafedra fizicheskoy khimii
Moskovskogo vysshego tekhnicheekogo uchilishcha (Department of
Physical Chemistry of the Moscow School of Technology)
for preliminary atudy for his professorship.
At the same time lie worked at the Moskovskaya sanitarnaya
stantsiya (Moscow Sanitary Station). In 1919 he became
lecturer for chemirtry at the Penzenskiy institut Narodnogo
obrazovaniya (Penza. Institute of liational Education) but
Card 1/3 remained in contac6 with Shilov's.laboratory and, together

Serf,ey Alek sandrovich Yo z tic sonol- -40- (V3 92-1 ~5 8) - SOY/76-33-1-47i /415
Obi tllarL,
"hilov, he publinhod Vany!ern ill ft~u~: 'y 11auchno-
khi;-,,icher-ho~;o irrititill'-1 'Repo'.3'If the
~;cicntific 1-1.eoearch Ino-titutc of iii 1921.
liL the orme year he bccri,:,,e lecLk~l--or at t'~o !,'Opartment of
Physical Chemistry of tht, :.'oqc(j-.: School ol' '2cchnolo.-,,, aT;,, ill
1)23 hi-! we"t to 77cl-lin nwi lVo1-1:(!d ~:.; t'i i'vol'onsor Freundlich.
Irk hc wan fwliL to ill oi,kicr 1A,
GO,.,Mjr(3 pueil.'icntion plantL %no''in 1",2, !ie. particip,,06od in Lhe
Buns~n Con,,.;rcss of Chemdrta. Ill 1912,( ';ccarc!
lecturer Pt the kafedra kolloidnoy lkl,imii (Chair of
Colloidal Chemistry) and in 1921/1 profec-'01, V-11c ellair"!:Itv 01, the
knfedra analiticheckoy 1-hirii Chair U Analytical
Chemistry of the After t,,,e do!,.t,-, o; Shilov in.1930,
he also became th#7 chairran of the neorEanicbeskoy
khimii ( Chair of Inor.,--ini-c Chomictr Tji ln",2 the
khimicheskiy fakultet !'VfU (Department of Chemistry) was converted
into the Voyennaya ankademiya k1ur-ictieskoy (1:ilitary
Academy of Chernicr.' Defense and Voznesenukiy 1kopt his post.
Card 2/3

Sergey Aleksandrovich Voznesenskiy (1892-1958)- SOV/76-33-1-43/45
Obituary
Prom 1921 - 1941 Voznoaonrkiy dirocted the Laboratory of
Water Purification at the Institute "Voo~-Pr,". 1- lr)rili he
became pi-oCessor ane head,of a nhair at the U-.-allskiy
olitekhnichoskiY institut Urars
Polytochnical Institute). jic waa one o-L' tl,-.2 i'ir:-.t to 7,oint cait
the fluoro-ort,,anic compounds and rrotc n. -oiio::r:~jj'. oil
"The Chemistry of Fluorine". In conclusion, an enun_~-ration ul"
the works by S. A. Vozncsenskiy is given, divided into
inorganic chemistry, physic 'al and colloidal chemistry and
water-technology. There are I figure and 65 references, 56 of
which are Soviet.
Card 3/3

"On The Formation Of Porous Structure In Carbon Activation."
report submitted for 4th Intl. Symposium on the Reactivity of Solids, Amsterdam, 30 May -
4 June 196o.

5.44
00 (8056
, sov/62-60-1-2/37
AUTHORS: Moskvitin, N. N., Dubinin, M. M., Sarakhov, A. I.
TITLE: investigation of Steam Adsorption on Ionic Crystals.
Communication 2. Nonequi~lbrium Sorbtion of Water on
Crystals of L'ead Iodide
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdelentye khimicheskikh
nauk, 196o, Nr 1, pp 9-14 (USSR)
ABSTRACT: Nonequilibrium sorbtion Isotherm* of water vapor on
Pb 12 crystals (specific surface about 0.2 m2 g in
temperature range of 20 to--~)Oo were obtained and studied.
The experiments were conducted ac.-ording to tne method
described by the authors In Izv. AN SSSR. Otd. khIm.
n. 1959, 2080. The data obtained are shown in Figs. 1,
2,,3, and 4. The following conclusions were made: The
sorption Isotherms,in the above Ii-,tervals of pressure,
are irreversible. The process of steam sorption on
Card 114 Pb12 is of a long duration, especially at positive

Investigation of Steam Adsorption on 78056
Ionic Crystals. Communication 2. SOV/662-60-1-2/37
Nonequilibrium Sorbtion of Water on
Crystals of Lead Iodide
ASSOCIATION:
SUBMITTED:
temperatures (equilibrium was not established during
~~5 days at.200). No connection was found between the
absorption behavior of PbI 2 and the properties of its
aerosol particles In the seeding of supercooled clouds.
There are 4 figures; and 16 references, 9 U.S., 7
Soviet. The 5 most recent U.S. references are: E.
Ballou, C. Ross, J. Phys. Chem., 57, Nr 7, 653 (1953).;
R. Beebe, G. Kin ton, M. Polley, W. Smith, J. Am.
Chem. Soc . 2, ~1 I
2 7 0 0950W. Van Voorhis, R Graig,
F. Bartell, J. Phys. Chem., 61, 1513 ('1957); S.
Birstein, J. Meteor., 12, Nr 4, 3211 (1955); W. Patrick,
W. Kemper, J. Phys. Chem., 42, 369 (1938).
Institute of,Physical Chemistry of the Academy of
Sciences USSR (Institut fizicheskoy khimil Akademil
nauk SSSR)
April 23, 1958
Card 2 /t

DUBININ, M. M.
"Modem Chemical Weapons Are Weapons of Mass Destruction."
report submitted for the 6th Pugwash Confereact on Disarmament &:World Security,
Moscow 27 Nov-5 Doc 1960.

S/062/60/000/006/013/025/XX
B02O/BO6O
AUTHORS: Duhinin, U.-M., Zhukovskaya, Ye. G., and Zaverina. Yo. D.
TITLE: Adsorption Properties of Carbon Adsorbents.1 Communication 5.
Characteristics of Water Vapor Sorptio-F-by Active Charcoals
in the Field of High Relative Pressures
PERIODICAL: Izvestlya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1960, No. 6, pp. 966-9755
TEXT; The particular form of water-vapor sorption and desorption
isothermal lines on active charcoals has been repeatedly studied,
especially at the authors' laboratory (Refs. 1 -5). The main ascent zone
of the sorption branch was found to correspond to the isotherm of
monomolecular adsorption. The concave form of the isotherm is a
consequence of the particular adsorption mechanism of water moleoulee on
the primary adsorption centers - the carbon monoxides on the surface - due
to the formation of hydrogen bonds, whereby every adsorbed water molecule
becomes a secondary adsorption center. These processes effect a steep
Card 1/4

Adsorption Properties of Carbon Adsorbents. S/062/60/000/006/013/025/XX.
Communication 5. Characteristics of Water B020/BO60
Vapor Sorption by Active Charcoals in the
Field of High Relative Pressures
ascent of the*adsorption branch of the isotherm (Refs. 3, 5). The main
object of the work concerned was the study of water vapor sorption by
active charcoals with different porous structures in order to clarify the
possibility and the conditions of the capillary condensation course of
water vapors in the intermediate pores. The investigation was extended to
active charcoals with micropores Of at moat 10 A diameter, whose intermediate
porosity was developed to different degrees. From among them q the types
Pl-P5 Ri-R5 were granulated active coals from vegetable substances,
rl-.r4 ~Gl--G4~ granulated active coals from fossils, and A'Y-10-AP4
(AU-10 - AU-14) active coals with developed intermediate porosity; they
are described and thoroughly examined in Ref. 8. Frr the first two types,
the sorption and desorption isothermal lines of beazene vapors were
examined at 200 and at pressures of 1.10-5 to I at, while for the latter
mentioned, the sorption and desorption isothermal lines of benzene vapors
were examined at 20~:', and those of nitrogen at -1950 (Rof- 8). The
adsorption apparatus is accurately described in Ref. 9, Calculated volumes
Card 2/4

Adsorption Properties of'Carbon Adcorbents. B/062/60/000/006/013/025/XX
Communication 5. Charaoterifltics of Water B0201B060
Vapor Sorption by Active Charcoals in the
Field of High Relative Pxessures
of intermediate pores-and micropores in active coals are indicated in
Table 1. The method of the sorption balance wan used in the study of water
vapor isothermal lines at 200. Sorption and desorption isothermal lines of
the types R2, R1, R3, and R4 (Fig. 1) exhibit a distinct change of the
slope of the isotherm branches after the section of the steep ascent, and..
more precisely, they exhibit a sharper slope and in the region of high
'pressures a hysteresis loop covering a large zone. The isothermal lines of
the types G3, G4, and R5 (Fig. 2) are shifted toward higher relative
pressures; the zone of the hysteresis loop is fairly large and extends
over almost the whole isotherm. The critical sorption volumes of active
charcoals are intercompared for benzene and water. Calculated scrption
volumes of water in micropores of active charcoals are compared with the
volumes of coal micropores in Table 3. Table 4 gives data derived from
Ref. 8 concerning the volumes of micropores and intermediaie pores of
active charcoals. Table 5 shows the distribution of the volume of sorbed
water between micropores and intermediate pores in critical scrption.
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Adsorption Properties of Carbon Adsorbents-. S/062j6O/0OO/OO6/O13/O25/XX
Communication 5. Characteristics of Water D020/BO6O
Vapor Sorption by Active Charcoals in the
Field of High Relative Pressures
Figs. 3 - 6 illustrate the sorption branohes of 0m sorption isothermal
lines -.,f nitrogen vapors at -1950 and cf water at 200 for typical active
charcoal spe6imens~ There are 6 figureag 5 tables, and 13 references;
'12 Soviei and I US.
ASSOCIATION: Institut fizicheakcy khimii Akadamil. nauk SSSR (Institute of
Physical Chemistry of the Academy of Scienoes USSR)
SUBMITTED: December 13, 1958
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S/062/60/000/009/002/021
B023/BO64
AUTHORSt Ganichenko, L. G., Dubinin--14. M., Zaverina, Ya. D.,
Kiselev, V. F., and Krasil'ni70'V,'Y- G.
TITLEt Study of the Vapor Adsorption on Adsorbents With
Heterogeneous Surface. Communication 2. Experiments With
Organically Substituted Silica Gel
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdelenlye khirnicheskikh
nauk, 1960, No. 9, pp. 1535-1543
TEXTt The adsorption of various vapors on methylated course-porous silica
gel and a demethylated sample obtained therefrom is discussed here. The
conditions of investigation were chosen in such a way that an essential
change-of the specific surface seemed to be unlikely. Coarse-porous com-
mercial silica gel KC.K(KSK) was taken as initial sample and carefully
purified from iron and other impurities. To methylate the surface, silica
gel was repeatedly treated with dichloro dimethyl silane vapors at 2000C.
Then, the vapors were sucked off in vacuum at 100CC, and siliz:a gel washed
with water until the reaction for the chlorine ion was negative. The
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Study of the Vapor Adsorption on Adsorbents slo621601000100910021021
With Heterogeneous Surface. Communication 2. B023/BO64
Experiments With Organically Substituted
Silica Gel
silica gel thus obtained is called C-1 (S-1). A portion of silica gel S-1
was treated with nitric acid vapors at 2000C for 6 h. Thus, the organic
part of the surface was oxidized, the CH 3 radicals substituted by OH
groups, and the methylated silica gel with hydrophobic properties became
hydrophilic. This specimen was called C-2 (S-2). The composition of the
surface of silica gel S-1 and S-2 was determined by an organic analysis.
The analysis was carried out at the same time as the determination of the
weight losses in calcination at 12500. Table 1 shows the analytical
results. It may be seen that the demethylation of the surface leads to an
increase of its degree of hydration. The specific surface of the specimen
changed by 3%. Nitrogen, cyclohexane, benzene, and water were used as
adsorbates. Figs. 1-4 show the sorption branches of the -adsorption iso-
thermal lines of the vapors of these substances. In all cases, the iso-
thermal lines for S-1 are lower than those for S-2. Table 2 gives a
comparison among the specific sorption volumes, The authors explain their
results with the help of the reopective publiihpd data- Summing up% 1) The
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Study of the Vapor Adsorption on Adsorbt~ntj S/OE' ) Y2'4j 010(A1009100 210 21,
With Heterogeneous Surface. Communication 2, B0223 B064
Experiments With Organically Substituted
Silica Gel
substitution of one part of the hydroxyl jroup;i of t0i.? si1iva gPI surface
by methyl groups leads to a reduction of its adsorptive power toward
substances in the vapor phase, and to an increase of the molecular fields
in the occupied monomolecular layers. 2) To determine'the specific surfaces
of the adsorbents with a chemically non-homogeneous surface (on the basis
of the equation by Brunauer, Emmett, and Teller for the adsorption iso-
thermal line), it ifi necessary to select the adsorbates with special care.
They should be as little sensitive as possible to the chemical hetero-
geneity of the siirfaoe. L. N. Kurbatov is mentioned. Thc-re are 5 figures,
4 tables, and 32 reforencest 22 Soviet, 2 US, I British, 6 German,and 1
Swiss.
ASSOCIATION: Institut fizicheskoy khimii Akademii nauk SSSR (Institute
of Physical Chemistry of the Actidemy c-f Sciences USSR).
M3skovskiy gosudarstvennyy universitet im. M.V.Lomonosova
(Moscow State University imeni M. V. I,omonosov)
SUBMITTEDj April 2, 1959
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84849
s/o6 60/000/010/002/018
,:,2 B01 5YB064
6-. / / 9 0 C4,7d
AUTHOR: Dubinin, M. M.
TITLE: Investigation of the Adsorption of Vapors on Adsorbents With
Heterogeneous Surfaces. Information 3. Analysis of
Experimental Data on Silica Gels With Chemically Modified
,Surfaces
PERIODICAL: Izvestiya Akademii nauk SSSR~ Otdeleniye kbimicheakikh nauk,
1960, No. 10, PP- 1739-1750
TEXT: A chemical modification of the surfaces of silica gels by
substituting the hydroxyl groups of the surface by various radicals
changes essentially the adoorptive properties for vapors of organic an
inorganic substances. Usually, the adsorptive power decreases with
increasing number of substituted OH groups. The Brunauer-Emmett-Teller
(BET) equation (1) for the adsorption isothermal line (Ref. 3) can be
applied thereto, and the adsorption am corresponds to the formation of
continuous monomolecular layerB. A decrease in the adsorptive power is
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8h849
Investigation of the Adsorption of Vapors on S/062/60/000/010/002/018
Adsorbente With Heterogeneous Surfaces. B015/BO64
Information 3. Analysis of Experimental Data
on Silica Gels With Chemically Modified
Surfaces
mostly characterized by a reduction of am~ Here, the experiments were
made with silica gels of different porosity of the types CY, (SK), CY,-4
(SK-1), CV-2, (SK-2), CM (SM), C-t-1-1 (sm-1), r-tl-z (SM-2), C-1 (S-1). and
C-2- (S-2); their OH groups were partly replaced by fluorine atoms or CH3
radicals.11and the applicability of the BET equation to the adsorption of
various vapors (IN2f Ar, C6H12' C6H6' H20 ) at -1950C (112) Ar) and 200C,
respectively, was checked (Table 1). For the majority of the systems
investigated, the BET equation is found to hold in the range of relative
equilibrium pressure. Owing to the substitution of the OH groups by
F-atoms or CH3 radicals, am decreases (less for nitrogen and argon vapors
than for cyclohexane, benzene, and water vapors). The change of the
adeorptive properties by chemical modification can be determined most
conveniently by a graphical determination of the affinity coefficient
i.e., by the affinity coefficients of the isothermal lines (Table 2, range
of relative equilibrium pressure; Table 3, relative changes of the
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84849
Investigation of the Adsorption of Vapors on s/o62/6o'/000/010/002/018
Adsorbents With Heterogeneous Surfaces. B015/BO64
Information 3. Analysis of Experimental Data
on Silica Gels.With Chemically Modified
Surfaces
adsorptive power and the values for I). A change of the porosity of
silica gel was found to effect no particular change of a. for N and Ar,
whereas in the case of benzene and cyclohexane a considerable eifect is
observable (Table 4). To achieve a qualitative explanation of the decrease
in the adsorptive power of silica gels due to chemical modification, the
constants C of dispersion interaction were computed (Table 5) according to
Kirkwood (Ref. 5), the van der Waals radii r of the adsorbed molecules were
taken from Tables, and the relative energies of dispersion interaction
were determined (Table 6). The change of the values for C and r of the
surface groups determining the equilibrium spacings of the adsorbed
molecules in the monomolecular layers were found to be the main reason
for the reduced adsorptive power of silica gels for vapors of non-polar
substances due to the substitution of F-atoms and CH~ radicals for the OH
groups of the surface. The reduction of this adsorptive power increases
with substances in which adsorption is controlled by a donor-acceptor
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84849
Investigation of the Adsorption of Vapors on S/062/60/000/010/002/018
Adsorbents With Heterogeneous Surfaces. BO15/Bo64
Information 3. Analysis of Experimental Data
on Silica Gels With Chemically Modified
Surfaces
component. The applicability of the BET equation to determine the
specific surface of adoorbents is discussed on the basis of a semi-
empirical equation (5) for the adsorption ivothermaliline given by
A. V, Kiselev, and the results are given (Table 7). The latter show that
the applicability of the BET equation is limited. The author thanks A. V,
Kiselev for a discussion. There are 2 figures, 7 tables, and 10
references: 6 Soviet, 3 US, and 1 German.
ASSOCIATION: Institut fizicheskoy khimii Akademii nauk SSSR (Institute-
of Physioa2 Chexiatrjr of the Acadeq7 of Sc ences_q~SRJ
SUBMITTED; June 2, A959
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IVANOV, A.K..-. DPININ, N*H.; KIBZW, V.V.
Screw compressors in the gas Industry. Gaz.prom. 5 no-10:40-43 0
,6o. (MIRA 13:10)
(Compreseors)

0/076/60/034/009/015/022
DO 1 cl"/BC 56
AUTHORS:
Dubinin. M. M., Vishnyakova, M. Lt., luhkovskaya, Yt-. G.,
Leontlyev, Ye. A., Luklyano7L-ch, V. M.. and Sarakhov,
A. I.
TITLE: Investigation of the Porous Structure of Soli-33 by Sorption
Methods. V. Application of Different Methodu for Studyine
the Structure of Intermediate and Macro-pores of A,,,-tive
Coals
PERIODICAL~ Zhurnal fizicheskoy khimii, 1960, Vol. 34, No. 9,
pp. 2019-2029
TEXT: A thorough investigation of the structure of intermediate pores,
whose size is between micro- and jaacrc-pores, of some typical kinds of
coal (from the type AY-10 - AY-14 (AU-10 to AU-14)) with intermediate
porosity is carried out by the method of capillary condensation of vapors
(benzene or nitrogen), by pressing in mercury, or by electron microscopy.
Data concerning the volumes of the micro- and intermediate pores of the
investigated kinds of coal are given in a table and Ghow that in all
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Investigation of the Porous Structure of S/076/60/034/009/015/022
Solids by Sorption Methods. V. Application B015/BO56
-of Different Methods for Studying the Structure
of Intermediate and Macro-pores of Active
Conla
samples the volumes of the intermediate pores exc9ed those of the micro-
pores by a multiple. The_sor8tion and desorption 41 experiments carried out
with nitrogen vapors at 195 C and benzene at 20 C a dGvice with quartz
scales. A detailed description of this device is given in Ref. 11. The
sorption isothermal lines (Figs. 1-3) are all S-shaped and have a
hysteresis, the beginning of which corresponds to the equilibrium pressure
(P/ps)o = 0.175 for benzene at 200C and (p/p s)o M 0.45 for nitrogen at
-1950C. For the purpose of determining the porous structure b~r the method
of pressing-in mercury, two pore gauges of the type n A-4 (PA-4)(Ref. 8)
(one for low and one for high pressure) were used, For electro-micro-
scopic examinations a Y21M-100 (UEM-100) electron microucope wa:, used,
carbon replicas were recorded (Fig. 5), and pore diameters frGm 70 to
110 A were found. The summational curves (Figs. 6-8) of the volume of the
intermediate pores with respect to their effective diameters, which were
calculated from the sorption Isothermal lines for benzene find were measured
J
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Investigation of the Porous Structure of S/076/60/034/009/015/022
Solids by Sorption Methods. V. Applicatioi-' BO,15/PO56
of Different Methods for Studying the Structure
of Intermediate and Macro-pores of Active
Coals
by pressing in mercury, showed good agreement. In the caGe of the results
obtained for nitrogen, less good agreement was found. The electron.micro-
scopic values qualitatively confirm the sorption values and the measured
values obtained by pressing in mercury. B. P. Bering and V. V. Serpinskiy
are thanked for their -interest in the present paper. There are 8 figures,
1 table, and 13 references: 12 Soviet and I US.
ASSOCIATION: Akademiya nauk SSSR Institut fizicheskoy khimii
(Academy of Sciences USSR, Institute of Physical Chemistry)
SUBMITTED: December 24, 1558
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